JP2022073418A - Perfume composition for stamp stand, vermilion inkpad, or penetration stamp - Google Patents

Perfume composition for stamp stand, vermilion inkpad, or penetration stamp Download PDF

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JP2022073418A
JP2022073418A JP2020183387A JP2020183387A JP2022073418A JP 2022073418 A JP2022073418 A JP 2022073418A JP 2020183387 A JP2020183387 A JP 2020183387A JP 2020183387 A JP2020183387 A JP 2020183387A JP 2022073418 A JP2022073418 A JP 2022073418A
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stamp
oil
fragrance
mask
fragrance composition
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JP7458639B2 (en
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眞 古谷
Makoto Furuya
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Shachihata Inc
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Abstract

To provide a perfume composition according to the invention for stamp stand, for vermilion inkpad, or for penetrating stamp, which enables the perfume to adhere securely to a targeted part of the object (mask) and thus maximise the perfuming effect of the perfume with the minimum required amount of adhesion.MEANS FOR SOLVING THE PROBLEM: A perfume composition according to the invention for stamp stand, for vermilion inkpad, or for penetration stamp, preferably as mask application, contains at least one or more solvents selected from the group consisting of isoprene glycol, 1,3 butylene glycol, and propylene glycol and a perfume.SELECTED DRAWING: None

Description

本発明は、対象物(マスク)の狙った箇所に確実に香料を付着させることができる為、必要最小限の付着量で香料の芳香効果を最大限に活かす事が可能なスタンプ台用、朱肉用又は浸透印用香料組成物に関する。 In the present invention, since the fragrance can be reliably adhered to the target portion of the object (mask), it is possible to maximize the fragrance effect of the fragrance with the minimum required amount of adhesion. For or permeation stamping fragrance composition.

近年、花粉のみならず、ウイルスや微小粒子状物質(PM2.5)等の大気汚染物質から身を守る為、マスクを着用する機会が増えている。しかし、マスク内は湿度が高く、高温になる為、細菌類(臭気源)が繁殖しやすい環境であり、また、呼気(口臭)がマスク内で滞留しやすい為、長時間マスクを着用する事に多くの人が不快に感じている。前記課題を解決する為に、マスク内の臭気を改善する目的でマスク外面に香料組成物をミスト状に噴きつけるスプレーが市販されている。また、特許文献1には一般的な香料組成物として、皮膚への安全性、油分である香料との相溶性を併せ持つイソプレングリコール、1、3ブチレングリコール、プロピレングリコール等の溶剤と香料の配合系の開示がある。 In recent years, there are increasing opportunities to wear masks to protect yourself from not only pollen but also air pollutants such as viruses and fine particulate matter (PM2.5). However, since the humidity inside the mask is high and the temperature becomes high, it is an environment where bacteria (odor source) can easily grow, and exhaled breath (halitosis) tends to stay in the mask, so wear the mask for a long time. Many people feel uncomfortable. In order to solve the above-mentioned problems, a spray for spraying a fragrance composition on the outer surface of the mask in the form of a mist is commercially available for the purpose of improving the odor in the mask. Further, in Patent Document 1, as a general fragrance composition, a blending system of a solvent such as isoprene glycol, 1,3 butylene glycol, propylene glycol, which has safety to the skin and compatibility with a fragrance which is an oil component, and a fragrance. There is disclosure of.

特開平08-3582公報Japanese Patent Application Laid-Open No. 08-3582

香料組成物の芳香効果を高めるには、マスク外面の鼻の位置に相当する箇所に局所的に香料組成物を付着させることが好ましい。しかしながら、従来のスプレー式の場合、香料組成物がミスト状で噴霧される為、マスク外面の広範囲に付着した香料組成物は芳香効果を十分に発揮できなかった。また、芳香効果を上げる為に噴霧量を増やすと、香料組成物の消費量が早くなり経済的にも問題があった。 In order to enhance the fragrance effect of the fragrance composition, it is preferable to locally attach the fragrance composition to a portion corresponding to the position of the nose on the outer surface of the mask. However, in the case of the conventional spray type, since the fragrance composition is sprayed in the form of mist, the fragrance composition adhered to a wide range on the outer surface of the mask cannot sufficiently exert the fragrance effect. In addition, if the amount of spray is increased in order to increase the aroma effect, the consumption of the fragrance composition becomes faster, which is economically problematic.

本発明は、対象物(マスク)の狙った箇所に確実に香料を付着させることができる為、必要最小限の付着量で香料の芳香効果を最大限に活かす事が可能なスタンプ台用、朱肉用又は浸透印用香料組成物を提供する。 In the present invention, since the fragrance can be reliably adhered to the target portion of the object (mask), it is possible to maximize the fragrance effect of the fragrance with the minimum required amount of adhesion. Provided is a perfume composition for use or permeation marking.

上記の課題を解決するために完成された第1の発明は、イソプレングリコール、1、3ブチレングリコール、プロピレングリコールからなる群から選ばれる1種又は2種以上の溶剤と香料を少なくとも含有するスタンプ台用、朱肉用又は浸透印用香料組成物である。 The first invention completed to solve the above problems is a stamp pad containing at least one or more solvents and fragrances selected from the group consisting of isoprene glycol, 1,3 butylene glycol, and propylene glycol. A fragrance composition for use, red meat, or penetrating stamp.

上記の課題を解決するために完成された第2の発明は、マスク用途としての第1の発明に記載のスタンプ台用、朱肉用又は浸透印用香料組成物である。 The second invention completed to solve the above-mentioned problems is the fragrance composition for stamp stands, red meat or osmotic stamps according to the first invention for mask use.

上記の課題を解決するために完成された第1の発明は、イソプレングリコール、1、3ブチレングリコール、プロピレングリコールからなる群から選ばれる1種又は2種以上の溶剤と香料を少なくとも含有するスタンプ台用、朱肉用又は浸透印用香料組成物である為、対象物の狙った箇所に確実に香料を付着させることができ、必要最小限の付着量で香料の芳香効果を最大限に活かす事ができる。 The first invention completed to solve the above problems is a stamp pad containing at least one or more solvents and fragrances selected from the group consisting of isoprene glycol, 1,3 butylene glycol, and propylene glycol. Because it is a fragrance composition for use, red meat, or penetrating marking, it is possible to reliably attach the fragrance to the target location of the object, and it is possible to maximize the fragrance effect of the fragrance with the minimum required amount of adhesion. can.

上記の課題を解決するために完成された第2の発明はマスク用途としての第1の発明に記載のスタンプ台用、朱肉用又は浸透印用香料組成物である為、マスク外面の鼻の位置に相当する箇所に局所的に香料組成物を付着させることができる。その為、香料組成物の無駄な浪費を極力抑えつつ、効果的にマスク内の臭気を除去でき、不快に感じることなく長時間マスクを着用することが可能である。 Since the second invention completed to solve the above problems is the fragrance composition for stamp pad, red meat or penetrating stamp according to the first invention for mask use, the position of the nose on the outer surface of the mask. The fragrance composition can be locally attached to the portion corresponding to the above. Therefore, it is possible to effectively remove the odor in the mask while suppressing unnecessary waste of the fragrance composition as much as possible, and it is possible to wear the mask for a long time without feeling unpleasant.

以下に本発明を詳細に説明する。
本発明の主溶剤としてはイソプレングリコール、1、3ブチレングリコール、プロピレングリコールを用いる。前記溶剤は単独、あるいは複数混合して使用でき、香料組成物全量中40.0~90.0重量%、好ましくは50.0~80.0重量%の範囲で用いられる。これらの溶剤はいずれも沸点が200℃前後であり、香料と併用配合した際に、香料の揮発量を適切にする事ができる。また、皮膚への安全性、油分である香料との相溶性、抗菌性を有している為、皮膚に直接触れ、細菌類が繁殖しやすい環境であるマスク用途として適している。
また、前記溶剤に加えて他の有機溶媒との混合溶媒を用いる場合、例えば、メタノール、エタノール、プロパノール、ブタノール、ペンタノール、ヘキサノール、ベンジルアルコール等のアルコールや、グリセリン、エチレングリコール、ジエチレングリコール、トリエチレングリコール、ポリエチレングリコール等のジオール類またはトリオール類を用いることができる。その配合量は香料組成物全量に対し1.0重量%~30重量%であることが好ましく、1.0重量%~25重量%であることがより好ましい。
The present invention will be described in detail below.
As the main solvent of the present invention, isoprene glycol, 1,3 butylene glycol and propylene glycol are used. The solvent can be used alone or in combination of two or more, and is used in the range of 40.0 to 90.0% by weight, preferably 50.0 to 80.0% by weight in the total amount of the fragrance composition. All of these solvents have a boiling point of around 200 ° C., and when blended in combination with a fragrance, the volatile amount of the fragrance can be adjusted appropriately. In addition, since it has safety on the skin, compatibility with fragrances that are oils, and antibacterial properties, it is suitable as a mask application in an environment where bacteria can easily grow in direct contact with the skin.
When a mixed solvent with another organic solvent is used in addition to the above solvent, for example, alcohols such as methanol, ethanol, propanol, butanol, pentanol, hexanol, and benzyl alcohol, glycerin, ethylene glycol, diethylene glycol, and triethylene are used. Diols such as glycol and polyethylene glycol or triols can be used. The blending amount is preferably 1.0% by weight to 30% by weight, more preferably 1.0% by weight to 25% by weight, based on the total amount of the fragrance composition.

香料としては、例えば、麝香、霊猫香、竜延香等の動物性香料、アビエス油、アクジョン油、アルモンド油、アンゲリカルート油、ページル油、ベルガモット油、パーチ油、ボアバローズ油、カヤブチ油、ガナンガ油、カプシカム油、キャラウェー油、カルダモン油、カシア油、セロリー油、シナモン油、シトロネラ油、コニャック油、コリアンダー油、クミン油、樟脳油、ジル油、エストゴラン油、ユーカリ油、フェンネル油、ガーリック油、ジンジャー油、グレープフルーツ油、ホップ油、レモン油、レモングラス油、ナツメグ油、マンダリン油、ハッカ油、オレンジ油、セージ油、スターアニス油、テレピン油等の植物性香料を挙げることができる。この香料として、合成香料又は抽出香料等の人工香料を用いることもでき、例えば、ピネン、リモネン等の炭化水素系香料、リナロール、ゲラニオール、シトロネロール、メントール、ボルネオール、ベンジルアルコール、アニスアルコール、βフェネチルアルコール等のアルコール系香料、アネトール、オイゲノール等のフェノール系香料、n-ブチルアルデヒド、イソブチルアルデヒド、ヘキシルアルデヒド、シトラール、シトロネラール、ベンズアルデヒド、シンナミックアルデヒド等のアルデヒド系香料、カルボン、メントン、樟脳、アセトフェノン、イオノン等のケトン系香料、γ―ブチルラクトン、クマリン、シネオール等のラクトン系香料、オクチルアセテート、ベンジルアセテート、シンナミルアセテート、プロピオン酸ブチル、安息香酸メチル等のエステル系香料等が挙げられる。さらに、上記香料の2種以上を混合した調合香料も使用することができる。その配合量は香料組成物全量に対し0.5重量%~30重量%であることが好ましく、1.0重量%~25重量%であることがより好ましい。 Examples of fragrances include animal fragrances such as scented scent, spirit cat scent, and Ryuen scent, Avies oil, Akjong oil, almond oil, angelica root oil, pagel oil, bergamot oil, perch oil, boa barrose oil, kayabuchi oil, and gananga. Oil, capsicum oil, caraway oil, cardamon oil, cassia oil, celery oil, cinnamon oil, citronella oil, cognac oil, coriander oil, cumin oil, cypress oil, gills oil, estgolan oil, eucalyptus oil, fennel oil, garlic oil , Ginger oil, grapefruit oil, hop oil, lemon oil, lemongrass oil, nutmeg oil, mandarin oil, peppermint oil, orange oil, sage oil, staranis oil, terepine oil and other vegetable fragrances. As this fragrance, an artificial fragrance such as a synthetic fragrance or an extracted fragrance can also be used. Alcohol-based fragrances such as annetol, eugenol and the like, n-butyl aldehyde, isobutyl aldehyde, hexyl aldehyde, citrar, citroneral, benzaldehyde, cinnamic aldehyde and other aldehyde-based fragrances, carboxylic, menton, anthracnose, acetophenone, ionone. Examples thereof include ketone fragrances such as γ-butyl lactone, coumarin and cineole, and ester fragrances such as octyl acetate, benzyl acetate, cinnamyl acetate, butyl propionate and methyl benzoate. Further, a blended fragrance in which two or more of the above fragrances are mixed can also be used. The blending amount is preferably 0.5% by weight to 30% by weight, more preferably 1.0% by weight to 25% by weight, based on the total amount of the fragrance composition.

本発明では着色剤を配合してもよく、顔料・染料の両方用いる事ができる。着色剤を配合する事で印影を際立たせ、マスク表面をスタンプで装飾する事ができる。
顔料としては、特に制限されることなく従来公知の有機顔料及び無機顔料を単独又は混合して使用することができる。例えば、アゾ系、縮合アゾ系、フタロシアニン系、キナクリドン系、アンスラキノン系、ジオキサジン系、インジゴ・チオインジゴ系、ベリノン・ベリレン系、イソインドレノン系、アゾメチレンアゾ系、ジケトピロロピロール系などの有機顔料や、カーボンブラック、マイカ、パール顔料、酸化鉄・真鍮等金属顔料などの無機顔料を用いることができる。これらの顔料は通常、ニトロセルロース、エチルセルロース、テルペンフェノール、塩化ビニル/酢酸ビニルコポリマー、ロジンエステル、ポリビニルブチラール、ポリビニルアルコールなどの公知の樹脂などに練り込んで加工顔料としておくと、溶剤と混合する際に容易に分散するので便利である。また、C.I.ベーシックイエロー40、C.I.ベーシックレッド1、C.I.ベーシックバイオレット1、C.I.ベーシックバイオレット11:1、C.I.ベーシックブルー3、C.I.アシドイエロー7、C.I.アシドレッド92、C.I.アシドブルー9等の蛍光染料を合成樹脂中で固溶体とした蛍光顔料等の有機顔料等も適宣選択して用いることができる。
染料としては、モノアゾ系、ジスアゾ系、金属錯塩型モノアゾ系、アントラキノン系、フタロシアニン系、トリアリルメタン系など従来公知の染料を特に制限されることなく使用することができる。
上記染料及び顔料は単独或いは混合して任意に使用することができ、その配合量は香料組成物全量に対して1~30重量%が好ましい。
In the present invention, a colorant may be blended, and both pigments and dyes can be used. By blending a colorant, the imprint can be made to stand out and the mask surface can be decorated with a stamp.
As the pigment, conventionally known organic pigments and inorganic pigments can be used alone or in combination without particular limitation. For example, organic pigments such as azo-based, condensed azo-based, phthalocyanine-based, quinacridone-based, anthracinone-based, dioxazine-based, indigo-thioindigo-based, verinone-berylene-based, isoindrenone-based, azomethyleneazo-based, and diketopyrrolopyrrole-based. , Carbon black, mica, pearl pigments, and inorganic pigments such as metal pigments such as iron oxide and brass can be used. These pigments are usually kneaded into known resins such as nitrocellulose, ethylcellulose, terpenephenol, vinyl chloride / vinyl acetate copolymer, rosin ester, polyvinyl butyral, polyvinyl alcohol, etc. to prepare processed pigments when mixed with a solvent. It is convenient because it is easily dispersed. In addition, C.I. I. Basic Yellow 40, C.I. I. Basic Red 1, C.I. I. Basic Violet 1, C.I. I. Basic Violet 11: 1, C.I. I. Basic Blue 3, C.I. I. Acid Yellow 7, C.I. I. Acidred 92, C.I. I. Organic pigments such as fluorescent pigments obtained by using a fluorescent dye such as Acid Blue 9 as a solid solution in a synthetic resin can also be appropriately selected and used.
As the dye, conventionally known dyes such as monoazo type, disazo type, metal complex salt type monoazo type, anthraquinone type, phthalocyanine type, and triallylmethane type can be used without particular limitation.
The dyes and pigments can be used alone or in admixture, and the blending amount thereof is preferably 1 to 30% by weight based on the total amount of the fragrance composition.

また、本発明で使用する主溶剤、イソプレングリコール、1、3ブチレングリコール、プロピレングリコールには抗菌効果があるが、不十分である場合、公知の防腐・防カビ剤を更に添加する事が出来る。
防腐防・カビ剤としては、フェノール、ナトリウムオマジン、ペンタクロロフェノールナトリウム、1,2-ベンズイソチアゾリン3-オン、2,3,5,6-テトラクロロ-4(メチルスルフォニル)、ピリジン、安息香酸ナトリウムなど、安息香酸やソルビン酸やデヒドロ酢酸のアルカリ金属塩、ベンズイミダゾール系化合物、1,3-ジメチロール5,5‐ジメチルヒダントイン、1又は3-モノメチロール5,5ジメチルヒダントイン、3-ヨード-2-プロピニルブチルカーバメイト等公知の防腐カビ剤を単独或いは混合して任意に使用することが出来る。
Further, the main solvent, isoprene glycol, 1,3 butylene glycol, and propylene glycol used in the present invention have an antibacterial effect, but if they are insufficient, a known antiseptic / antifungal agent can be further added.
Antiseptic and antifungal agents include phenol, sodium omadin, sodium pentachlorophenol, 1,2-benzisothiazolin 3-one, 2,3,5,6-tetrachloro-4 (methylsulfonyl), pyridine, and benzoic acid. Alkali metal salts of benzoic acid, sorbic acid and dehydroacetic acid such as sodium, benzimidazole compounds, 1,3-dimethylol 5,5-dimethylhydantin, 1 or 3-monomethylol 5,5dimethylhydantin, 3-iodo-2 -A known antiseptic fungicide such as propynylbutylcarbamate can be used alone or in combination.

本発明の香料組成物は、上記物質を適量選択して、撹拌機にて常温で約1時間混合分散して製造する。 The fragrance composition of the present invention is produced by selecting an appropriate amount of the above substances and mixing and dispersing them at room temperature for about 1 hour with a stirrer.

実施例及び比較例の香料組成物の配合を表1に示す。
実施例1~3と比較例1~3はそれぞれ同じ配合であり、香料組成物の充填装置が異なっている。実施例1~3は浸透式・気密性のスタンプ(シヤチハタ株式会社製「タートスタンパー丸型11号(品番:XQT-11C)」)に含浸させ、比較例1~3は市販のスプレー容器に充填した。

Figure 2022073418000001
実施例及び比較例について、以下の条件で香気試験を行った。
■香気試験
実施例の香料組成物を含浸したスタンプの1回捺印で消費する重量及び、比較例の香料組成物を充填したスプレーの1回噴霧で消費する重量を共に0.01mgに調整した。次に、マスク外面の鼻の位置に相当する箇所にスタンプ及びスプレーでそれぞれ1回量の香料組成物を付着させ、その状態でマスクを着用し、マスク内の香りの持続時間を官能評価した。
持続時間が1時間以上を「○」、30分以下を「×」とした。 Table 1 shows the formulations of the fragrance compositions of Examples and Comparative Examples.
Examples 1 to 3 and Comparative Examples 1 to 3 have the same composition, and the filling device for the fragrance composition is different. Examples 1 to 3 are impregnated with a penetrating type / airtight stamp (“Tart Stamper Round Type 11 (Product No .: XQT-11C)” manufactured by Shachihata Inc.), and Comparative Examples 1 to 3 are filled in a commercially available spray container. bottom.
Figure 2022073418000001
The aroma test was performed on the examples and comparative examples under the following conditions.
■ Aroma test The weight consumed by one stamp of the stamp impregnated with the fragrance composition of the example and the weight consumed by one spray of the spray filled with the fragrance composition of the comparative example were both adjusted to 0.01 mg. Next, a single dose of the fragrance composition was attached to a portion corresponding to the position of the nose on the outer surface of the mask by stamping and spraying, and the mask was worn in that state, and the duration of the scent in the mask was sensory evaluated.
A duration of 1 hour or more was designated as "○", and a duration of 30 minutes or less was designated as "x".

表1の実施例1~3、比較例1~3より明らかなように、マスク外面にスタンプ式で香料組成物を付着させた方がスプレー式に比べて香りの持続時間が格段に長くなっている。これはスタンプの特性上、マスク外面の鼻の位置に相当する箇所に局所的に香料組成物を付着させる事ができる為であり、結果的に香料組成物の芳香効果を最大限に活かすことが可能となる。一方、スプレー式の場合、香料組成物がミスト状で噴霧される為、マスク外面の広範囲に付着した香料組成物は芳香効果を十分に揮できない。 As is clear from Examples 1 to 3 and Comparative Examples 1 to 3 in Table 1, the duration of the scent is significantly longer when the fragrance composition is adhered to the outer surface of the mask by the stamp type than by the spray type. There is. This is because, due to the characteristics of the stamp, the fragrance composition can be locally adhered to the portion corresponding to the position of the nose on the outer surface of the mask, and as a result, the fragrance effect of the fragrance composition can be maximized. It will be possible. On the other hand, in the case of the spray type, since the fragrance composition is sprayed in the form of mist, the fragrance composition adhered to a wide range on the outer surface of the mask cannot sufficiently exert the fragrance effect.

以上、現時点において、もっとも、実践的であり、かつ好ましいと思われる実施形態に関連して本発明を説明したが、本発明は、本願明細書中に開示された実施形態に限定されるものではなく、請求の範囲および明細書全体から読み取れる発明の要旨あるいは思想に反しない範囲で適宜変更可能であり、そのような変更を伴う香料組成物もまた技術的範囲に包含されるものとして理解されなければならない。 As described above, the present invention has been described in relation to the most practical and preferable embodiments at the present time, but the present invention is not limited to the embodiments disclosed in the present specification. It is not possible to make appropriate changes within the scope of the claims and to the extent that it does not contradict the gist or idea of the invention that can be read from the entire specification, and the perfume composition with such changes must also be understood as being included in the technical scope. Must be.

Claims (2)

イソプレングリコール、1、3ブチレングリコール、プロピレングリコールからなる群から選ばれる1種又は2種以上の溶剤と香料を少なくとも含有するスタンプ台用、朱肉用又は浸透印用香料組成物。 A fragrance composition for stamp stands, red meat or osmotic stamps containing at least one or more solvents and fragrances selected from the group consisting of isoprene glycol, 1, 3 butylene glycol and propylene glycol. マスク用途としての請求項1に記載のスタンプ台用、朱肉用又は浸透印用香料組成物。














The fragrance composition for stamp stands, red meat or penetrating stamps according to claim 1 as a mask application.














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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024046768A1 (en) * 2022-08-31 2024-03-07 Firmenich Sa Fragrance compositions containing 2,3-butanediol and/or 1,3-butanediol
WO2024046769A1 (en) * 2022-08-31 2024-03-07 Firmenich Sa Fragrance compositions containing 1,3-butanediol

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JP2001219632A (en) 2000-02-08 2001-08-14 Mitsubishi Pencil Co Ltd Stamping instrument
JP2005059583A (en) 2003-07-31 2005-03-10 Masaru Watanabe Nail art stamp
FR2867067B1 (en) 2004-03-08 2007-09-07 Oreal COSMETIC ARTICLE FOR SINGLE USE
JP2008017957A (en) 2006-07-12 2008-01-31 Aroma Space:Kk Method for producing aroma generating mask
JP2008230994A (en) 2007-03-19 2008-10-02 Shiseido Co Ltd Cosmetic

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024046768A1 (en) * 2022-08-31 2024-03-07 Firmenich Sa Fragrance compositions containing 2,3-butanediol and/or 1,3-butanediol
WO2024046769A1 (en) * 2022-08-31 2024-03-07 Firmenich Sa Fragrance compositions containing 1,3-butanediol

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