JP2022020444A - Japanese paper yarn made of conifer and manufacturing method thereof and japanese paper fabric using the same - Google Patents

Japanese paper yarn made of conifer and manufacturing method thereof and japanese paper fabric using the same Download PDF

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JP2022020444A
JP2022020444A JP2020123936A JP2020123936A JP2022020444A JP 2022020444 A JP2022020444 A JP 2022020444A JP 2020123936 A JP2020123936 A JP 2020123936A JP 2020123936 A JP2020123936 A JP 2020123936A JP 2022020444 A JP2022020444 A JP 2022020444A
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正登 阿部
Masato Abe
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Washi Cloth Co Ltd
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Abstract

To provide a yarn having uniform quality of Japanese paper fiber even if conifer to be raw material is uneven, a uniform and stable Japanese paper yarn having an excellent tension strength required for a product produced by weaving the yarn, and a Japanese paper fabric.SOLUTION: A manufacturing method of a Japanese paper yarn JY comprises: a measurement step 10 to measure absolute dry weight of conifer chips CT to be raw material; an immersion step 30 to immerse the conifer chips CT and a medical agent NO of an amount calculated based on the measurement result for a predetermined time in water HO of an amount calculated based on the measurement result; a digestion step 40 to digest the immersed conifer chips CT, the medical agent NO, and the water HO; a papermaking step 50 to mill a paper by mixing a cellulose CL extracted from the conifer chips CT at the digestion step 40 and Manila hemp MH; a slit step 60 to slit a Japanese paper JP milled at the papermaking step 50; and a yarn twisting step to twist the Japanese paper JP slit at the slit step 60 to form a Japanese paper yarn JY.SELECTED DRAWING: Figure 1

Description

本発明は、針葉樹、特に国産針葉樹及びその間伐材を原料とする和紙糸及びその製造方法並びにそれを使用した和紙織物に関する。 The present invention relates to a coniferous tree, particularly a Japanese paper thread made from domestic coniferous trees and thinned wood thereof, a method for producing the same, and a Japanese paper woven fabric using the same.

従来、例えば、マニラ麻とさとうきびの絞りかすを原料の一部とする紙糸及びその製造方法としては、例えば、特許第6570101号(特許文献1)に示すような紙糸及びその製造方法が公知である。前記公報記載の紙糸の生産方法は、植物繊維にリグニン含有率が2%未満となるまでリグニンの除去処理を施す除去工程と、前記除去工程で得られた繊維とリグニンの除去処理が行われていない植物繊維とを混合する混合工程と、前記混合工程で得られた混合体を用いて紙を抄く抄紙工程と、前記抄紙工程で得られた紙をスリットするスリット工程と、 スリットされた前記紙を撚って紙糸を生成する撚糸工程とを備えており、リグニン含有率が15%以上の繊維と、リグニン含有率が2%未満の植物繊維とを含む紙から形成された紙を生産するのに適したものであり、これにより、異なる種類の繊維を含む紙を用いて有用な物品を製造することができる。 Conventionally, for example, as a paper thread using Manila hemp and sugar cane pomace as a part of raw materials and a method for producing the same, for example, a paper thread as shown in Patent No. 6570101 (Patent Document 1) and a method for producing the same are known. be. In the method for producing paper yarn described in the publication, a removal step of removing lignin from plant fibers until the lignin content becomes less than 2%, and a removal treatment of fibers and lignin obtained in the removal step are performed. A mixing step of mixing unfinished plant fibers, a papermaking step of making paper using the mixture obtained in the mixing step, a slitting step of slitting the paper obtained in the papermaking step, and slitting were performed. A paper formed from paper containing fibers having a lignin content of 15% or more and plant fibers having a lignin content of less than 2% is provided with a twisting step of twisting the paper to produce paper yarn. Suitable for production, which allows useful articles to be produced using paper containing different types of fibers.

一方で、我が国の森林を構成する主要樹種のうち、針葉樹林の面積は全体の約52%を占めており、我が国の森林面積の約80%を占める人工林においては、その約97%が針葉樹林である。そして、人工林の多くは、その健康状態を維持するために間伐が必要とされているが、間伐材の多くは山に放置されたまま行き場がないのが現状である。 On the other hand, among the major tree species that make up Japan's forests, the area of coniferous forests occupies about 52% of the total, and in the artificial forests that occupy about 80% of the forest area of Japan, about 97% of them are coniferous trees. It is a forest. Many planted forests require thinning to maintain their health, but most of the thinned wood is left in the mountains and has nowhere to go.

すなわち、布の主な原料である綿、ウール、シルクなどは、ほとんどを輸入に頼っている中で、これらの国産の針葉樹、特に、間伐材を利用した紙糸から織られる紙織物は、輸入に大きく頼らず国内資源を利用できる有用な素材となる。 In other words, while most of the main raw materials for cloth, such as cotton, wool, and silk, depend on imports, these domestic conifers, especially paper woven fabrics woven from paper threads made from thinned wood, are imported. It will be a useful material that can use domestic resources without relying heavily on silk.

また、このように製造される天然紙繊維は、環境にやさしい、高い紫外線カット率、高い抗菌性、超軽量などの優れた特徴を持つと共に、紙100%の織物は毛羽がないため、皮膚が敏感な人でも安心して使用することができるという優れた特性を有する。 In addition, the natural paper fibers produced in this way have excellent features such as environmental friendliness, high UV protection, high antibacterial properties, and ultra-lightweight, and 100% paper woven fabric has no fluff, so the skin is fluffy. It has the excellent property that even sensitive people can use it with peace of mind.

このような観点から、出願人は、長年の研究開発、改良を重ねて、国産の針葉樹を原料とする和紙糸及びそれから製造される和紙織物の開発に至った。従来、国産針葉樹、特に針葉樹の間伐材を原料とする前記和紙及び和紙織物は、国内では生産されておらず、出願人はこの種分野の魁けであった。しかしながら、前記和紙及び和紙織物の製造工程は、原料針葉樹からチップを作成する工程、原料チップを蒸解し、原料チップからセルロースを抽出しパルプを形成する蒸解工程、パルプを均一に伸ばし和紙を形成する抄紙工程、和紙をスリットするスリット工程、スリットされた前記紙を撚って紙糸を生成する撚糸工程とを備えるものであったが、国産の針葉樹、特に針葉樹の間伐材を使用する場合、使用する針葉樹の部位や個別の含有水分や乾燥状態においてバラつきがあり、そのため、蒸解工程において、原料チップの溶解する速度にバラつきが生じ、原料チップのうち、乾燥度の高い原料チップは繊維が残り、堅い部分が残留するなどし、繊維長にバラつきが生じ、和紙の品質自体にバラつきが生じるという問題が生じていた。 From this point of view, the applicant has repeated many years of research and development and improvement, and has reached the development of Japanese paper yarn made from domestic coniferous trees and Japanese paper woven fabric manufactured from it. Conventionally, the Japanese paper and Japanese paper woven fabric made from domestic coniferous trees, especially thinned wood of coniferous trees, have not been produced in Japan, and the applicant has been a sword in this kind of field. However, the manufacturing process of the Japanese paper and the Japanese paper woven fabric includes a step of making chips from the raw material conifer, a cooking process of cooking the raw material chips and extracting cellulose from the raw material chips to form pulp, and uniformly stretching the pulp to form Japanese paper. It was equipped with a paper-making process, a slitting process for slitting Japanese paper, and a twisting process for twisting the slitted paper to produce paper yarn, but it is used when using domestically produced coniferous trees, especially thinned coniferous trees. There are variations in the part of the coniferous tree to be used, the individual water content, and the dry state. There was a problem that the fiber length varied due to the remaining hard part, and the quality of Japanese paper itself varied.

特許第6570101号 図3Patent No. 6570101 Fig. 3

本発明は、前記従来の問題点を解決するためになされたものであり、その目的とするところは、原料となる針葉樹にバラつきがあったとしても、和紙繊維の品質自体にバラつきのない糸及びその製織品に必要とされる引張強度に優れる均一な安定した和紙糸及び和紙布を提供することにある。 The present invention has been made to solve the above-mentioned conventional problems, and an object of the present invention is to provide a yarn in which the quality of Japanese paper fiber itself does not vary even if the coniferous tree used as a raw material varies. It is an object of the present invention to provide a uniform and stable Japanese paper thread and Japanese paper cloth having excellent tensile strength required for the woven product.

また、本発明の他の目的は、原料たる針葉樹の有する抗菌性を良好に保持する和紙糸及び和紙布を提供することにある。 Another object of the present invention is to provide Japanese paper thread and Japanese paper cloth which have good antibacterial properties of softwood which is a raw material.

請求項1に係る和紙糸の製造方法は、原料となる針葉樹チップの絶乾重量を計測する計測工程と、前記針葉樹チップと前記計測結果に基づき算出される量の薬剤とを、前記計測結果に基づき算出される量の水に所定時間浸漬する浸漬工程と、前記浸漬された針葉樹チップ、薬剤及び水を蒸解する蒸解工程と、前記蒸解工程で抽出されたセルロースとマニラ麻とを混合し抄紙する抄紙工程と、前記抄紙工程で抄紙された和紙をスリットするスリット工程と、前記スリット工程でスリットされた和紙を撚って和紙糸を形成する撚糸工程と、を備えることを特徴とする。 In the method for producing Japanese paper thread according to claim 1, a measurement step for measuring the absolute dry weight of a coniferous tree chip as a raw material, and the coniferous tree chip and an amount of a drug calculated based on the measurement result are added to the measurement result. A paper making process in which a soaking step of immersing in water in an amount calculated based on the above for a predetermined time, a cooking step of cooking the soaked coniferous tree chips, chemicals and water, and a paper making by mixing cellulose and Manila hemp extracted in the cooking step. It is characterized by including a step, a slit step of slitting the Japanese paper made in the paper making step, and a twisting step of twisting the Japanese paper slit in the slit step to form a Japanese paper thread.

請求項1に係る和紙糸の製造方法にあっては、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた所定の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保つことができる。 In the method for producing Japanese paper thread according to claim 1, in the step of extracting cellulose from the raw material chip of the coniferous tree, it is immersed in a predetermined amount of chemicals and water according to the absolute dry weight of the raw material chip of the coniferous tree for a long time. Since the step is provided, the quality of the cellulose remaining in the cooking step can be kept constant and good.

請求項2に係る和紙糸の製造方法は、 請求項1に記載の紙糸の製造方法において、前記浸漬工程における薬剤は、前記計測工程で計測される針葉樹チップの絶乾重量の50%の水酸化ナトリウムであり、前記浸漬工程における水は、前記計測工程で計測される針葉樹チップの絶乾重量の300%であることを特徴とする。 The method for producing Japanese paper thread according to claim 2 is the method for producing paper thread according to claim 1. In the method for producing paper thread according to claim 1, the chemical in the dipping step is water of 50% of the absolute dry weight of the coniferous tree chips measured in the measuring step. It is sodium oxide, and the water in the dipping step is 300% of the absolute dry weight of the coniferous tree chips measured in the measuring step.

請求項2に係る和紙糸の製造方法にあっては、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた所定の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保たれ、引張強度に優れる和紙糸を製造することができる。 In the method for producing Japanese paper thread according to claim 2, in the step of extracting cellulose from the raw material chip of the coniferous tree, it is immersed in a predetermined amount of chemicals and water according to the absolute dry weight of the raw material chip of the coniferous tree for a long time. Since the process is provided, the quality of the cellulose remaining in the cooking process can be kept constant and good, and Japanese paper yarn having excellent tensile strength can be produced.

請求項3に係る和紙糸の製造方法は、請求項1又は2に記載の和紙糸の製造方法において、前記抄紙工程において、針葉樹チップから抽出されたセルロースとマニラ麻とを混合の割合は一対一であることを特徴とする。 The method for producing washi yarn according to claim 3 is the method for producing washi yarn according to claim 1 or 2, wherein the ratio of mixing cellulose extracted from coniferous tree chips and Manila hemp in the paper making step is 1: 1. It is characterized by being.

請求項3に係る和糸の製造方法にあっては、前記抄紙工程において、針葉樹チップから抽出されたセルロースとマニラ麻とを混合の割合は一対一であるため、針葉樹の保有する抗菌性を好適に保持することができる。 In the method for producing Japanese yarn according to claim 3, in the papermaking process, the mixing ratio of cellulose extracted from softwood chips and Manila hemp is 1: 1 so that the antibacterial property possessed by softwood is preferable. Can be retained.

請求項4に係る和紙布の製造方法は、請求項1乃至3の何れか一に記載の和紙糸の製造方法で得られた和紙糸を織り和紙布を製造する製織工程を、さらに備えることを特徴とする。 The method for manufacturing Japanese paper cloth according to claim 4 further includes a weaving step for manufacturing Japanese paper cloth by weaving the Japanese paper thread obtained by the method for manufacturing Japanese paper thread according to any one of claims 1 to 3. It is a feature.

請求項4に係る和紙布の製造方法にあっては、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた所定の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保たれ、引張強度に優れる和紙糸からなる和紙布を製造することができる。 In the method for producing Japanese paper cloth according to claim 4, in the step of extracting cellulose from the raw material chips of coniferous trees, they are immersed in a predetermined amount of chemicals and water according to the absolute dry weight of the raw material chips of coniferous trees for a long time. Since the process is provided, the quality of the cellulose remaining in the cooking process is kept good at a certain level, and it is possible to produce a Japanese paper cloth made of Japanese paper yarn having excellent tensile strength.

請求項5に係る和紙糸は、請求項1乃至3の何れか一に記載の和紙糸の製造方法で製造されることを特徴とする。 The Japanese paper thread according to claim 5 is characterized in that it is manufactured by the method for producing Japanese paper thread according to any one of claims 1 to 3.

請求項5に係る和紙糸にあっては、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた所定の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保たれるため、品質の一定した引張強度に優れる和紙糸となる。 The Japanese paper thread according to claim 5 includes, in the step of extracting cellulose from the raw material chip of the coniferous tree, a step of immersing it in a predetermined amount of chemicals and water according to the absolute dry weight of the raw material chip of the coniferous tree for a long time. Therefore, the quality of the cellulose remaining in the cooking step is kept constant and good, so that the Japanese paper yarn has a constant quality and excellent tensile strength.

請求項6に係る和紙布は、請求項4に記載の和紙布の製造方法で製造されることを特徴とする。 The Japanese paper cloth according to claim 6 is characterized in that it is manufactured by the method for manufacturing Japanese paper cloth according to claim 4.

請求項6に係る和紙布にあっては、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた所定の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保たれる、品質の一定した引張強度に優れる和紙糸から製織されるので、品質の一定した引張強度に優れる和紙布となる。 The Japanese paper cloth according to claim 6 includes a step of extracting cellulose from the raw material chips of the coniferous tree, which comprises a step of immersing the raw material chips of the coniferous tree in a predetermined amount of chemicals and water for a long time according to the absolute dry weight. Therefore, since the weaving is performed from Japanese paper yarn having a constant quality and excellent tensile strength, in which the quality of the cellulose remaining in the cooking step is kept constant and good, the Japanese paper cloth having a constant quality and excellent tensile strength is obtained.

請求項1に係る和紙糸の製造方法によれば、原料となる針葉樹チップの絶乾重量を計測する計測工程と、前記針葉樹チップと前記計測結果に基づき算出される量の薬剤とを、前記計測結果に基づき算出される量の水に所定時間浸漬する浸漬工程と、前記浸漬された針葉樹チップ、薬剤及び水を蒸解する蒸解工程と、前記蒸解工程で抽出されたセルロースとマニラ麻とを混合し抄紙する抄紙工程と、前記抄紙工程で抄紙された和紙をスリットするスリット工程と、前記スリット工程でスリットされた和紙を撚って和紙糸を形成する撚糸工程とを備えるので、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた所定の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保つことができる。 According to the method for producing Japanese paper thread according to claim 1, the measurement step of measuring the absolute dry weight of the coniferous tree chip as a raw material and the measurement of the coniferous tree chip and the amount of the drug calculated based on the measurement result are measured. A soaking step of immersing in water in an amount calculated based on the results for a predetermined time, a cooking step of evaporating the soaked coniferous tree chips, chemicals and water, and a paper making by mixing cellulose and Manila hemp extracted in the cooking step. Since it is provided with a paper making step of forming a Japanese paper thread, a slit step of slitting the Japanese paper made in the paper making step, and a twisting step of twisting the Japanese paper slit in the slit step to form a Japanese paper thread, cellulose is obtained from the raw material chip of the coniferous tree. In the step of extracting, the step of immersing in a predetermined amount of chemicals and water according to the absolute dry weight of the raw material chips of the coniferous tree for a long time is provided, so that the quality of the cellulose remaining in the cooking step can be kept constant and good. can.

請求項2に係る和紙糸の製造方法によれば、請求項1に記載の紙糸の製造方法において、前記浸漬工程における薬剤は、前記計測工程で計測される針葉樹チップの絶乾重量の50%の水酸化ナトリウムであり、前記浸漬工程における水は、前記計測工程で計測される針葉樹チップの絶乾重量の300%であるので、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた最適の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保たれ、引張強度に優れる和紙糸を製造することができる。 According to the method for producing Japanese paper thread according to claim 2, in the method for producing paper thread according to claim 1, the agent in the dipping step is 50% of the absolute dry weight of the coniferous tree chips measured in the measuring step. Since the sodium hydroxide of the above and the water in the dipping step is 300% of the absolute dry weight of the coniferous tree chips measured in the measuring step, the raw material chips of the coniferous tree in the step of extracting cellulose from the raw material chips of the coniferous tree. Since the process of immersing in the optimum amount of chemicals and water according to the absolute dry weight of the product is provided for a long time, the quality of cellulose remaining in the cooking process is maintained at a constant level and good, and Japanese paper yarn having excellent tensile strength is produced. Can be done.

請求項3に係る和紙糸の製造方法は、請求項1又は2に記載の和紙糸の製造方法において、前記抄紙工程において、針葉樹チップから抽出されたセルロースとマニラ麻とを混合の割合は一対一であるので、前記抄紙工程における針葉樹チップから抽出されたセルロースとマニラ麻とを混合の割合は一対一であるため、針葉樹の保有する抗菌性を好適に保持することができる。 The method for producing Japanese paper thread according to claim 3 is the method for producing Japanese paper thread according to claim 1 or 2, wherein the ratio of mixing cellulose extracted from coniferous tree chips and Manila hemp in the paper making step is 1: 1. Therefore, since the mixing ratio of cellulose extracted from the coniferous tree chips in the papermaking process and Manila hemp is one-to-one, the antibacterial property possessed by the coniferous tree can be suitably maintained.

請求項4に係る和紙布の製造方法によれば、請求項1乃至3の何れか一に記載の和紙糸の製造方法で得られた和紙糸を織り和紙布を製造する製織工程を、さらに備えるので、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた所定の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保たれ、引張強度に優れる和紙糸からなる和紙布を製造することができる。 According to the method for manufacturing Japanese paper cloth according to claim 4, the weaving step for manufacturing Japanese paper cloth by weaving the Japanese paper thread obtained by the Japanese paper thread manufacturing method according to any one of claims 1 to 3 is further provided. Therefore, in the step of extracting cellulose from the raw material chips of coniferous trees, a step of immersing in a predetermined amount of chemicals and water according to the absolute dry weight of the raw material chips of coniferous trees for a long time is provided, so that the quality of cellulose remaining in the cooking step is provided. It is possible to produce a Japanese paper cloth made of Japanese paper yarn, which is kept at a constant level and has excellent tensile strength.

請求項5に係る和紙糸によれば、請求項1乃至3の何れか一に記載の和紙糸の製造方法で製造されるので、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた所定の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保たれるため、品質の一定した引張強度に優れる和紙糸となる。 According to the Japanese paper thread according to claim 5, since it is manufactured by the method for producing Japanese paper thread according to any one of claims 1 to 3, in the step of extracting cellulose from the raw material chip of the coniferous tree, the raw material chip of the coniferous tree Since it is provided with a step of immersing it in a predetermined amount of chemicals and water according to the absolute dry weight of the product for a long time, the quality of the cellulose remaining in the cooking step is kept good at a certain level, and therefore the tensile strength with a constant quality is excellent. It becomes Japanese paper thread.

請求項6に係る和紙布によれば、請求項3に記載の和紙布の製造方法で製造されるので、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた所定の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保たれる、品質の一定した引張強度に優れる和紙糸から製織されるので、品質の一定した引張強度に優れる和紙布となる。 According to the Japanese paper cloth according to the sixth aspect, since it is manufactured by the method for producing the Japanese paper cloth according to the third aspect, in the step of extracting cellulose from the raw material chips of the coniferous tree, it depends on the absolute dry weight of the raw material chips of the coniferous tree. Since it is provided with a process of immersing in a predetermined amount of chemicals and water for a long time, it is woven from Japanese paper yarn having a constant quality and excellent tensile strength, which keeps the quality of cellulose remaining in the cooking process constant and good. , A Japanese paper cloth with constant quality and excellent tensile strength.

本発明に係る和紙布の製造方法を示すフローチャートである。It is a flowchart which shows the manufacturing method of the Japanese paper cloth which concerns on this invention. 計測工程を示す概略図である。It is a schematic diagram which shows the measurement process. 算出工程を示す概略図である。It is a schematic diagram which shows the calculation process. 浸漬工程を示す概略図である。It is a schematic diagram which shows the dipping process. 蒸解工程を示す概略図である。It is a schematic diagram which shows the cooking process. 抄紙工程を示す概略図である。It is a schematic diagram which shows the papermaking process. スリット工程を示す概略図である。It is a schematic diagram which shows the slit process. 撚糸工程を示す概略図である。It is a schematic diagram which shows the plying process. 製織工程を示す概略図である。It is a schematic diagram which shows the weaving process.

以下、本発明に係る和紙布JFを製造するための実施例について、図面に従って説明する。 Hereinafter, examples for manufacturing the Japanese paper cloth JF according to the present invention will be described with reference to the drawings.

図1は本発明に係る和紙布の製造方法を示すフローチャートである。図1に示すように、本発明に係る和紙布JFは、原料となる針葉樹チップCTの絶乾重量を計測する計測工程10と、前記計測結果に基づき薬剤NO及び水HOの量を算出する算出工程20と、前記針葉樹チップCTと前記計測結果に基づき算出される量の薬剤NOとを、前記計測結果に基づき算出される量の水HOに所定時間浸漬する浸漬工程30と、前記浸漬された針葉樹チップCT、薬剤NO及び水HOを蒸解する蒸解工程40と、前記蒸解工程で針葉樹チップCTから抽出されたセルロースCLとマニラ麻パルプMHとを混合し抄紙する抄紙工程50と、前記抄紙工程50で抄紙された和紙JPをスリットするスリット工程60と、前記スリット工程60でスリットされた和紙JPを撚って和紙糸JYを形成する撚糸工程70と、前記和紙糸JYを織って和紙布JFを製造する製織工程80を備える。 FIG. 1 is a flowchart showing a method for manufacturing Japanese paper cloth according to the present invention. As shown in FIG. 1, the Japanese paper cloth JF according to the present invention has a measurement step 10 for measuring the absolute dry weight of the coniferous tree chip CT as a raw material, and a calculation for calculating the amounts of drug NO and water HO based on the measurement results. The step 20 and the dipping step 30 in which the coniferous tree chip CT and the drug NO calculated based on the measurement result are immersed in the water HO in the amount calculated based on the measurement result for a predetermined time, and the immersion step 30 In the cooking step 40 for evaporating the coniferous tree chip CT, the drug NO and the water HO, the papermaking step 50 for mixing cellulose CL extracted from the coniferous tree chip CT and the Manila hemp pulp MH in the cooking step, and the papermaking step 50. A slit step 60 for slitting the paper-made Japanese paper JP, a twisting step 70 for twisting the Japanese paper JP slit in the slit step 60 to form a Japanese paper thread JY, and a Japanese paper cloth JF are manufactured by weaving the Japanese paper thread JY. The weaving step 80 is provided.

原料となる前記針葉樹チップCTは、国産の杉、檜、檜葉等の針葉樹から製造されるものであり、特に、それらの間伐材を使用する場合は、国内資源を有効に利用できることとなる。また、後述する抗菌性に優れた和紙糸、和紙紙の原料としては、高い抗菌性を備える杉、檜、檜葉等の針葉樹が好適である。 The coniferous chip CT used as a raw material is produced from domestically produced coniferous trees such as cedar, cypress, and cypress leaves, and in particular, when thinned wood thereof is used, domestic resources can be effectively used. Further, as the Japanese paper thread having excellent antibacterial properties and the raw material of Japanese paper, which will be described later, coniferous trees such as cedar, cypress, and cypress leaves having high antibacterial properties are suitable.

前記計測工程10は、例えば、図2に示すように、まず、前記針葉樹チップCTの水分率を測定し、前記針葉樹チップCTの重量14を重量計13により測定する(なお、予め、重量を量っておいた前記針葉樹チップCTの水分率を測定するようにしても良い。)。前記針葉樹チップCTの水分率の測定は、例えば、木材水分計12により行われる。前記木材水分計12による測定としては、高周波式水分計や電気抵抗式水分計やマイクロ波透過式水分計等を使用すると良い。また、計測対象の原料は、チップされる前の、適宜大きさに裁断された前記針葉樹でも良い。前記針葉樹チップCTの水分率が計測できれば、前記針葉樹チップCTの重量14から、前記針葉樹チップCTの水分量15が算出され、重量計13により計測される前記針葉樹チップCTの重量14から水分量15を差し引いて絶乾重量11を算出する。 In the measurement step 10, for example, as shown in FIG. 2, first, the water content of the softwood chip CT is measured, and the weight 14 of the softwood chip CT is measured by a weighing scale 13 (note that the weight is measured in advance). The water content of the coniferous chip CT may be measured.) The moisture content of the softwood chip CT is measured by, for example, a wood moisture meter 12. As the measurement by the wood moisture meter 12, it is preferable to use a high frequency type moisture meter, an electric resistance type moisture meter, a microwave transmission type moisture meter, or the like. Further, the raw material to be measured may be the coniferous tree cut into an appropriate size before being chipped. If the water content of the softwood chip CT can be measured, the water content 15 of the softwood chip CT is calculated from the weight 14 of the softwood chip CT, and the water content 15 is calculated from the weight 14 of the softwood chip CT measured by the weighing scale 13. Is subtracted to calculate the absolute dry weight 11.

前記算出工程20では、図3に示すように、前記計測工程10で計測された前記針葉樹チップCTの絶乾重量11に基づいて、前記蒸解工程40において加えられる薬剤NO及び水HOの量を算出する。前記薬剤NOは水酸化ナトリウムであり、加える量は、前記針葉樹チップCTの絶乾重量の50%重量である。そして、加える水は前記針葉樹チップCTの絶乾重量11の300%である。例えば、前記針葉樹チップCTが1000kgであって、前記水分率が30%である場合は、前記針葉樹チップCTの絶乾重量11は700kgであり、加える水酸化ナトリウムNOは350kgであり、加える水HOは2100kgである。また、前記針葉樹チップCTが1000kgであって、前記水分率が40%である場合は、前記針葉樹チップCTの絶乾重量11は600kgであり、加える前記水酸化ナトリウムNOは300kgであり、加える水HOは1800kgとなる。 In the calculation step 20, as shown in FIG. 3, the amounts of the drug NO and water HO added in the cooking step 40 are calculated based on the absolute dry weight 11 of the softwood chip CT measured in the measurement step 10. do. The drug NO is sodium hydroxide, and the amount added is 50% by weight of the absolute dry weight of the softwood chip CT. The water to be added is 300% of the absolute dry weight 11 of the softwood chip CT. For example, when the softwood chip CT is 1000 kg and the water content is 30%, the absolute dry weight 11 of the softwood chip CT is 700 kg, the sodium hydroxide NO to be added is 350 kg, and the water HO to be added. Is 2100 kg. When the softwood chip CT is 1000 kg and the water content is 40%, the absolute dry weight 11 of the softwood chip CT is 600 kg, the sodium hydroxide NO to be added is 300 kg, and water to be added. HO is 1800 kg.

前記浸漬工程30は、図4に示すように、前記計測工程10で計測された前記針葉樹チップCTの絶乾重量11に基づいて算出された重量の薬剤NOを前記針葉樹チップCTともに前記針葉樹チップCTの絶乾重量11に基づいて算出された重量の水NOに浸漬する工程である。例えば、地球釜31に前記針葉樹チップCTの絶乾重量11に基づいて算出された重量の薬剤NOと、前記針葉樹チップCTと、前記針葉樹チップCTの絶乾重量11に基づいて算出された重量の水NOとを混合した状態で24時間乃至48時間程度、浸漬する。そして、この間に、例えば、原料として針葉樹間伐材を使用するとしても、いろいろな部位や伐採されてからの時間、状態、伐採や回収時の季節、天候等において、1ロットの前記針葉樹チップCTにおいて、水分率や硬軟等の木質の状態が大きく相違するものが混在していても、混在された前記針葉樹チップCTが、前記好適な量の前記水酸化ナトリウムNO及び水HOに、比較的長時間である24時間乃至48時間程度浸漬されることにより、前記針葉樹チップCTにおいて水分率や硬軟等の木質の状態の平準化が進み、最終的に製造される和紙糸JYや和紙JF布の強度(引張強度)を高め、品質の向上及び安定を図ることができる。 As shown in FIG. 4, in the immersion step 30, the drug NO of the weight calculated based on the absolute dry weight 11 of the softwood chip CT measured in the measurement step 10 is applied to the softwood tip CT together with the softwood tip CT. This is a step of immersing in water NO having a weight calculated based on the absolute dry weight 11 of the above. For example, the drug NO of the weight calculated based on the absolute dry weight 11 of the softwood chip CT, the softwood chip CT, and the weight calculated based on the absolute dry weight 11 of the softwood chip CT in the earth kettle 31. Immerse in a state of being mixed with water NO for about 24 to 48 hours. During this period, for example, even if conifer thinned wood is used as a raw material, one lot of the conifer chip CT may be used in various parts, the time since logging, the condition, the season at the time of logging and recovery, the weather, and the like. Even if there is a mixture of woody states such as water content and hardness, the mixed softwood chip CT is applied to the appropriate amount of the sodium hydroxide NO and water HO for a relatively long time. By soaking for about 24 to 48 hours, the leveling of the woody state such as water content and hardness in the softwood chip CT progresses, and the strength of the finally produced Japanese paper thread JY and Japanese paper JF cloth ( Tensile strength) can be increased to improve quality and stability.

前記蒸解工程40は、例えば、図5に示すように、前記地球釜31に前記針葉樹チップCTの絶乾重量11に基づいて算出された重量の前記水酸化ナトリウムNOと、前記針葉樹チップCTと、前記針葉樹チップCTの絶乾重量11に基づいて算出された重量の水HOとを混合した状態で24時間乃至48時間程度、浸漬されたものを、160度乃至170度程度の温度にし、かつ加圧された状態で6時間程度蒸煮を行って、前記針葉樹チップCTに含まれるリグニン及び一部のヘミセルロースを溶解・除去して、前記和紙JPの原料となるセルロースCLを抽出する。 In the cooking step 40, for example, as shown in FIG. 5, the earth kettle 31 contains the sodium hydroxide NO and the softwood chip CT having a weight calculated based on the absolute dry weight 11 of the softwood chip CT. A mixture of water HO having a weight calculated based on the absolute dry weight 11 of the softwood chip CT and soaked for about 24 to 48 hours is brought to a temperature of about 160 to 170 degrees and added. Boil for about 6 hours in a pressurized state to dissolve and remove lignin and a part of hemicellulose contained in the softwood chip CT, and extract cellulose CL which is a raw material of the Japanese paper JP.

そして、前記抄紙工程50において、図6に示すように、前記蒸解工程40において得たセルロースCLとマニラ麻パルプMHと混合し、抄紙し、前記和紙JPを製造する。このとき、前記蒸解工程40で前記針葉樹チップCTから抽出されたセルロースCLを50%、及び前記マニラ麻パルプMHを50%の混合割合とすると、前記針葉樹チップCTが有する抗菌性を低下させることなく、保持したまま、以下の各段階の工程で得られる前記和紙JP、前記和紙糸JY及び前記和紙布JFにおいて、高い抗菌性を維持することができる。 Then, in the papermaking step 50, as shown in FIG. 6, the cellulose CL obtained in the cooking step 40 and the Manila hemp pulp MH are mixed and made into paper to produce the Japanese paper JP. At this time, if the mixing ratio of the cellulose CL extracted from the softwood chip CT in the cooking step 40 and the Manila hemp pulp MH is 50%, the antibacterial property of the softwood chip CT is not deteriorated. High antibacterial properties can be maintained in the Japanese paper JP, the Japanese paper thread JY, and the Japanese paper cloth JF obtained in the following steps while holding the paper.

そして、次の工程である前記スリット工程60において、図7に示すように、前記和紙原紙を1~4mm程度の幅の細紙SLに細かく裁断し、前記撚糸工程70において、図8に示すように、スパイラル状に巻き取り、撚糸を行い。和紙糸JYを製造する。そして、前記製織工程80において、図9に示すように、前記和紙糸JYを製織し、前記和紙布JFを製造するのである。 Then, in the slit step 60, which is the next step, as shown in FIG. 7, the Japanese paper base paper is finely cut into fine paper SL having a width of about 1 to 4 mm, and in the plying step 70, as shown in FIG. In addition, it is wound in a spiral shape and twisted. Manufactures Japanese paper thread JY. Then, in the weaving step 80, as shown in FIG. 9, the Japanese paper thread JY is woven to produce the Japanese paper cloth JF.

以上の工程のうち、前記抄紙工程50において得られる前記和紙JPは、前記浸漬工程30において、前記針葉樹チップCTの水分率や硬軟等の木質の状態の平準化を高めて、最終的に製造される和紙糸JYや和紙JF布の強度(引張強度)を高め、品質の向上及び安定を図ることができる。 Of the above steps, the Japanese paper JP obtained in the paper making step 50 is finally manufactured in the dipping step 30 by increasing the water content of the coniferous tree chip CT and the leveling of the woody state such as hardness and softness. It is possible to increase the strength (tensile strength) of Japanese paper thread JY and Japanese paper JF cloth to improve and stabilize the quality.

表1は、従来の紙質試験表である。

Figure 2022020444000002
Table 1 is a conventional paper quality test table.
Figure 2022020444000002

表1に示す紙質試験表によると、従来の製造方法(薬剤及び水の配合量が原料針葉樹の絶乾重量に基づいて計量されたものでなく、また、それらとの長時間の浸漬工程を備えないもの)によって得られた和紙においては、その引張強度(kg/15mm)が、「2,4」、「1,8」、「2,53」、「2,25」、「2,662」であった。 According to the paper quality test table shown in Table 1, the conventional manufacturing method (the amount of the chemical and water blended is not measured based on the absolute dry weight of the raw coniferous tree, and the step of immersing with them for a long time is provided. The tensile strength (kg / 15 mm) of the Japanese paper obtained by (not) is "2,4", "1,8", "2,53", "2,25", "2,662". Met.

表2は、本発明に係る製造工程で得られる和紙JPの製品物性比較表である。

Figure 2022020444000003
Table 2 is a product property comparison table of Japanese paper JP obtained in the manufacturing process according to the present invention.
Figure 2022020444000003

そして、従来の製造方法で製造される和紙に対して、表2に示す本発明に係る製造工程で得られる和紙JPの製品物性比較表では、本発明に係る製造工程で得られる和紙JPのその引張強度(kg/15mm)MDは、「2,74」、「3,14」、「2,77」であり、2,74kg/15mm以上の高い数値で推移しており、これから製造される前記和紙糸JYや前記和紙JF布の強度(引張強度)を高め、品質の向上及び安定に寄与している。 In the product property comparison table of Japanese paper JP obtained in the manufacturing process according to the present invention shown in Table 2, the Japanese paper JP obtained in the manufacturing process according to the present invention is compared with the Japanese paper manufactured by the conventional manufacturing method. The tensile strength (kg / 15 mm) MD is "2,74", "3,14", and "2,77", which are high values of 2,74 kg / 15 mm or more, and the above-mentioned products to be manufactured from now on. It enhances the strength (tensile strength) of Japanese paper thread JY and the Japanese paper JF cloth, and contributes to the improvement and stability of quality.

表3は、前記和紙糸JYの抗菌性試験結果表である。

Figure 2022020444000004
さらに、表3に示す前記和紙糸JYの抗菌性試験結果表に示されるように、本発明に係る製造方法によって得られる前記前記和紙糸JYは、洗濯をしていない状態で抗菌活性値は「5,9」であり、洗濯回数が10回のものでも抗菌活性値は「3,6」であり、高い抗菌活性値を示しており、この数値はJIS L 1902:2015によると、抗菌効果としては「強い効果が認められる」ものとなっている。一方、一般社団法人繊維評価技術協議会による「SEKマーク繊維製品認証基準」では、「抗菌防臭加工」の基準は、抗菌活性値(A)≧2,2であるところ、この基準を十分にクリアするものとなっており、優れた抗菌性を保持することが認められる。 Table 3 is a table of antibacterial test results of the Japanese paper thread JY.
Figure 2022020444000004
Further, as shown in the antibacterial test result table of the Japanese paper thread JY shown in Table 3, the Japanese paper thread JY obtained by the production method according to the present invention has an antibacterial activity value of "" in the unwashed state. The antibacterial activity value is "3, 6" even if the number of washings is 10 times, which is "5, 9", indicating a high antibacterial activity value. According to JIS L 1902: 2015, this value is as an antibacterial effect. Is "a strong effect is recognized". On the other hand, in the "SEK Mark Textile Product Certification Criteria" by the Textile Evaluation Technology Council, the criteria for "antibacterial deodorant processing" are antibacterial activity value (A) ≥ 2,2, which is sufficiently cleared. It is recognized that it retains excellent antibacterial properties.

10 計測工程
20 薬剤等算出工程
30 浸漬工程
40 蒸解工程
50 抄紙工程
60 スリット工程
70 撚糸工程
80 製織工程

CT 針葉樹チップ
NO 薬剤
HO 水
CL セルロース
MH マニラ麻パルプ
JP 和紙
JY 和紙糸
JF 和紙布
10 Measurement process 20 Chemical calculation process 30 Immersion process 40 Steaming process 50 Paper making process 60 Slit process 70 Plying process 80 Weaving process

CT Softwood Chip NO Chemical HO Water CL Cellulose MH Manila Hemp Pulp JP Japanese Paper JY Japanese Paper Thread JF Japanese Paper Cloth

請求項1に係る和紙糸の製造方法は、原料となる針葉樹の間伐材チップの絶乾重量を計測する計測工程と、前記間伐材チップと前記計測結果に基づき算出される量の薬剤とを、前記計測結果に基づき算出される量の水に所定時間浸漬する浸漬工程と、前記浸漬された針葉樹チップ、薬剤及び水を蒸解する蒸解工程と、前記蒸解工程で抽出されたセルロースとマニラ麻とを混合し抄紙する抄紙工程と、前記抄紙工程で抄紙された和紙をスリットするスリット工程と、前記スリット工程でスリットされた和紙を撚って和紙糸を形成する撚糸工程と、を備えることを特徴とする。 The method for producing Japanese paper thread according to claim 1 comprises a measurement step of measuring the absolute dry weight of the thinned wood chips of coniferous trees as a raw material, and the thinned wood chips and the amount of chemicals calculated based on the measurement results. A dipping step of immersing in an amount of water calculated based on the measurement result for a predetermined time, a cooking step of cooking the soaked coniferous tree chips, chemicals and water, and a mixture of cellulose and Manila hemp extracted in the cooking step. It is characterized by including a paper making process for making paper, a slit process for slitting Japanese paper made in the paper making process, and a twisting process for twisting the Japanese paper slit in the slit process to form Japanese paper yarn. ..

請求項2に係る和紙糸の製造方法は、 請求項1に記載の和紙糸の製造方法において、前記浸漬工程における薬剤は、前記計測工程で計測される間伐材チップの絶乾重量の50%の水酸化ナトリウムであり、前記浸漬工程における水は、前記計測工程で計測される間伐材チップの絶乾重量の300%であることを特徴とする。 The method for producing Japanese paper thread according to claim 2 is the method for producing Japanese paper thread according to claim 1, wherein the chemical in the dipping step is 50% of the absolute dry weight of the thinned wood chips measured in the measuring step. It is sodium hydroxide, and the water in the dipping step is 300% of the absolute dry weight of the thinned wood chips measured in the measuring step.

請求項1に係る和紙糸の製造方法によれば、原料となる針葉樹の間伐材チップの絶乾重量を計測する計測工程と、前記間伐材チップと前記計測結果に基づき算出される量の薬剤とを、前記計測結果に基づき算出される量の水に所定時間浸漬する浸漬工程と、前記浸漬された針葉樹チップ、薬剤及び水を蒸解する蒸解工程と、前記蒸解工程で抽出されたセルロースとマニラ麻とを混合し抄紙する抄紙工程と、前記抄紙工程で抄紙された和紙をスリットするスリット工程と、前記スリット工程でスリットされた和紙を撚って和紙糸を形成する撚糸工程とを備えるので、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた所定の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保つことができる。 According to the method for producing Japanese paper thread according to claim 1, a measurement step for measuring the absolute dry weight of the thinned wood chips of the coniferous tree as a raw material, and the thinned wood chips and the amount of chemicals calculated based on the measurement results. The dipping step of immersing the soaked coniferous tree chips, chemicals and water in an amount of water calculated based on the measurement results for a predetermined time, and the cellulose and Manila hemp extracted in the cooking step. A coniferous tree has a paper-making process of mixing and making paper, a slitting process of slitting the Japanese paper made in the paper-making process, and a twisting process of twisting the Japanese paper slit in the slitting process to form Japanese paper yarn. In the step of extracting cellulose from the raw material chips, the step of immersing in a predetermined amount of chemicals and water according to the absolute dry weight of the coniferous raw material chips for a long time is provided, so that the quality of the cellulose remaining in the cooking step is constant and good. Can be kept in.

請求項2に係る和紙糸の製造方法によれば、請求項1に記載の和紙糸の製造方法において、前記浸漬工程における薬剤は、前記計測工程で計測される間伐材チップの絶乾重量の50%の水酸化ナトリウムであり、前記浸漬工程における水は、前記計測工程で計測される間伐材チップの絶乾重量の300%であるので、針葉樹の原料チップからセルロースを抽出する工程において、針葉樹の原料チップの絶乾重量に応じた最適の数量の薬剤及び水に長時間浸漬する工程を備えるため、蒸解工程において残留するセルロースの品質を一定かる良好に保たれ、引張強度に優れる和紙糸を製造することができる。 According to the method for producing Japanese paper yarn according to claim 2, in the method for producing Japanese paper yarn according to claim 1, the chemical agent in the dipping step is 50 of the absolute dry weight of the thinned wood chips measured in the measuring step. % So sodium hydroxide, and the water in the dipping step is 300% of the absolute dry weight of the thinned wood chips measured in the measuring step. Therefore, in the step of extracting cellulose from the raw material chips of the coniferous tree, the coniferous tree Since it is equipped with an optimum quantity of chemicals according to the absolute dry weight of the raw material chip and a process of immersing it in water for a long time, the quality of cellulose remaining in the cooking process is kept good at a constant level, and Japanese paper yarn with excellent tensile strength is manufactured. can do.

Claims (6)

原料となる針葉樹チップの絶乾重量を計測する計測工程と、
前記針葉樹チップと前記計測結果に基づき算出される量の薬剤とを、前記計測結果に基づき算出される量の水に所定時間浸漬する浸漬工程と、
前記浸漬された針葉樹チップ、薬剤及び水を蒸解する蒸解工程と、
前記蒸解工程で針葉樹チップから抽出されたセルロースとマニラ麻とを混合し抄紙する抄紙工程と、
前記抄紙工程で抄紙された和紙をスリットするスリット工程と、
前記スリット工程でスリットされた和紙を撚って和紙糸を形成する撚糸工程と、
を備えることを特徴とする和紙糸の製造方法。
A measurement process that measures the absolute dry weight of softwood chips, which are the raw material,
A dipping step of immersing the softwood chip and the amount of the drug calculated based on the measurement result in the amount of water calculated based on the measurement result for a predetermined time.
The cooking step of cooking the soaked softwood chips, chemicals and water, and
A papermaking process in which cellulose extracted from softwood chips and Manila hemp are mixed and made in the cooking process, and a papermaking process.
A slitting process for slitting Japanese paper made in the papermaking process,
A plying process of twisting washi paper slit in the slit process to form washi yarn,
A method for manufacturing Japanese paper yarn, which is characterized by the above.
前記浸漬工程における薬剤は、前記計測工程で計測される針葉樹チップの絶乾重量の50%の水酸化ナトリウムであり、前記浸漬工程における水は、前記計測工程で計測される針葉樹チップの絶乾重量の300%であることを特徴とする請求項1に記載の和紙糸の製造方法。
The agent in the dipping step is sodium hydroxide, which is 50% of the absolute dry weight of the softwood chip measured in the measuring step, and the water in the dipping step is the absolute dry weight of the softwood chip measured in the measuring step. The method for producing Japanese paper yarn according to claim 1, wherein the content is 300% of that of the Japanese paper yarn.
前記抄紙工程において、針葉樹チップから抽出されたセルロースとマニラ麻とを混合の割合は一対一であることを特徴とする請求項1又は2に記載の和紙糸の製造方法。
The method for producing Japanese paper yarn according to claim 1 or 2, wherein in the paper making step, the mixing ratio of cellulose extracted from softwood chips and Manila hemp is 1: 1.
請求項1乃至3の何れか一に記載の和紙糸の製造方法で得られた和紙糸を織り和紙布を製造する製織工程を、さらに備えることを特徴とする和紙布の製造方法。
A method for producing a Japanese paper cloth, further comprising a weaving step for producing a Japanese paper cloth by weaving the Japanese paper thread obtained by the method for producing a Japanese paper thread according to any one of claims 1 to 3.
請求項1乃至3の何れか一にに記載の和紙糸の製造方法で製造されることを特徴とする和紙糸。
A Japanese paper thread produced by the method for producing Japanese paper thread according to any one of claims 1 to 3.
請求項4に記載の和紙布の製造方法で製造されることを特徴とする和紙布。

A Japanese paper cloth manufactured by the method for manufacturing a Japanese paper cloth according to claim 4.

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004190150A (en) * 2002-12-09 2004-07-08 Nippon Paper Industries Co Ltd Method for producing unbleached kraft pulp
JP2008156799A (en) * 2006-12-26 2008-07-10 Tomoegawa Paper Co Ltd Colored paper braid and method for producing the same
JP2010037670A (en) * 2008-08-01 2010-02-18 Oji Paper Co Ltd Base paper for paper yarn
JP2011047057A (en) * 2009-08-25 2011-03-10 Nippon Paper Industries Co Ltd Method for producing chemical-containing chip for papermaking

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004190150A (en) * 2002-12-09 2004-07-08 Nippon Paper Industries Co Ltd Method for producing unbleached kraft pulp
JP2008156799A (en) * 2006-12-26 2008-07-10 Tomoegawa Paper Co Ltd Colored paper braid and method for producing the same
JP2010037670A (en) * 2008-08-01 2010-02-18 Oji Paper Co Ltd Base paper for paper yarn
JP2011047057A (en) * 2009-08-25 2011-03-10 Nippon Paper Industries Co Ltd Method for producing chemical-containing chip for papermaking

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