JP2021161236A - Method for producing polyolefin foam, method for producing packaging material for packaging, polyolefin foam, and packaging material for food product packaging - Google Patents

Method for producing polyolefin foam, method for producing packaging material for packaging, polyolefin foam, and packaging material for food product packaging Download PDF

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JP2021161236A
JP2021161236A JP2020063981A JP2020063981A JP2021161236A JP 2021161236 A JP2021161236 A JP 2021161236A JP 2020063981 A JP2020063981 A JP 2020063981A JP 2020063981 A JP2020063981 A JP 2020063981A JP 2021161236 A JP2021161236 A JP 2021161236A
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武 保苅
Takeshi Hokari
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Chuo Kagaku Co Ltd
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To provide a method for producing a polyolefin foam which makes it easy to adopt as a packaging material for food product packaging, gives consideration to environmental measures, and avoids labor for quality management before production, a method for producing a packaging material for food product packaging, a polyolefin foam, and a packaging material for food product packaging.SOLUTION: A method for producing a polyolefin foam includes a step of heating a resin composition obtained by kneading at least a polyolefin-based resin and an inorganic filler and producing a molten material, a step of adding 0.5-3 wt.% of water to 100 wt.% of the molten material, further mixing the mixture, and producing a hydrous molten material, and a step of vaporizing moisture contained in the hydrous molten material, and producing a foam, and performs each of the steps with an extruder including a cylinder 101, a screw 111, a charging port 121, a die 131 and a water injection part 141 shown in Fig. 1, and obtains a sheet-like foam.SELECTED DRAWING: Figure 1

Description

本発明は、例えば食品向け包装分野に好適な樹脂組成物を原料とするポリオレフィン発泡体の製造方法、製造した発泡体を用いた包装用包材の製造方法、上記樹脂組成物製のポリオレフィン発泡体、及び上記発泡体製の食品向け包装用包材とに関する。 The present invention relates to, for example, a method for producing a polyolefin foam using a resin composition suitable for the food packaging field as a raw material, a method for producing a packaging material for packaging using the produced foam, and a polyolefin foam made from the above resin composition. , And the above-mentioned foam packaging material for foods.

従来から、建材分野では、断熱材・緩衝材・遮音材・保冷材として、合成樹脂等を配合した樹脂組成物を原料とする発泡体が活用されていた。しかしながら、例えば断熱材では、廃棄時の焼却で煤煙や有毒ガスが発生しやすかったり、燃料カロリーが高かったり、発泡量の不足により所望の幅寸法に成形できなかったり、断熱性が不足してしまったりする問題を抱えていた。 Conventionally, in the field of building materials, foams made from a resin composition containing a synthetic resin or the like have been used as a heat insulating material, a cushioning material, a sound insulating material, and a cold insulating material. However, for example, in the case of a heat insulating material, soot and toxic gas are likely to be generated by incineration at the time of disposal, the fuel calorie is high, the desired width cannot be formed due to insufficient foaming amount, and the heat insulating property is insufficient. I had a chilling problem.

そこで、特許文献1では、発泡体の原料として発泡性ポリプロピレンを採用した場合、ポリスチレン樹脂とポリオレフィン系樹脂(ポリプロピレン樹脂とポリエチレン樹脂)とを混合した再生樹脂を配合することで、焼却時に煤煙が発生しにくく、燃焼カロリーが低く、所望の発泡性及び断熱性を有する発泡体が開示されている。発泡体の具体的な成分は、所定配合による紙ペレット、上記再生樹脂、上記発泡性ポリプロピレン、及び水である。 Therefore, in Patent Document 1, when foamable polypropylene is used as the raw material of the foam, soot is generated at the time of incineration by blending a recycled resin in which a polystyrene resin and a polyolefin resin (polypropylene resin and polyethylene resin) are mixed. There are disclosed foams that are difficult to burn, have low calories burned, and have the desired foaming and heat insulating properties. Specific components of the foam are paper pellets, the recycled resin, the foamable polypropylene, and water according to a predetermined composition.

特開2011−213966号公報Japanese Unexamined Patent Publication No. 2011-213966

一方、食品向け包装分野でも、包装した食品に加わる衝撃の緩和、上記食品の滑りによる位置ずれの抑制、食品を含む総重量の軽減等を期待して、所定の合成樹脂等を配合した樹脂組成物を原料とする発泡体製の包装体が採用されている。すなわち、上記包装体には食品を載置するため、上記発泡体は衛生性も不可欠なことから、食品向け包装分野では実績の乏しい特許文献1の発泡体を採用しにくい。 On the other hand, also in the field of packaging for foods, a resin composition containing a predetermined synthetic resin or the like is expected to alleviate the impact applied to the packaged food, suppress the misalignment due to the slipping of the food, and reduce the total weight including the food. A foam packaging made from a product is used. That is, since food is placed on the packaging, hygiene is also indispensable for the foam, and therefore it is difficult to adopt the foam of Patent Document 1 which has a poor track record in the packaging field for food.

近年、食品向け包装分野での発泡体には、包装体としての強度や剛性・その他各種耐性の発現や原料費の低減を狙い、樹脂組成物に無機フィラーが配合されている。無機フィラーは多種類存在し、包装体の機能や用途に応じて配合する種類や比率が適宜決定されている。また、環境問題への関心が高まるにつれて、合成樹脂の使用量削減に向けた取り組みが盛んになっている。 In recent years, in foams in the field of packaging for foods, an inorganic filler is blended in a resin composition with the aim of developing strength and rigidity as a packaging body and other various resistances and reducing raw material costs. There are many types of inorganic fillers, and the types and ratios to be blended are appropriately determined according to the function and application of the package. In addition, as interest in environmental issues grows, efforts to reduce the amount of synthetic resin used are becoming more active.

一般的に、合成樹脂や無機フィラーを混練した樹脂組成物は、ペレットとして流通されていることがある。発泡体の原料に用いられる樹脂組成物のペレットは、生成時に配合する水の吸水率を高めて発泡体の発泡倍率を上げるために、多孔質に生成されることもある。しかしながら、ペレットが多孔質につき吸水性を伴うと、季節に伴う温湿度等の変動に応じた品質管理に手間が生じかねない。 Generally, a resin composition obtained by kneading a synthetic resin or an inorganic filler may be distributed as pellets. The pellets of the resin composition used as the raw material of the foam may be formed porous in order to increase the water absorption rate of the water blended at the time of formation and increase the foaming ratio of the foam. However, if the pellets are porous and have water absorption, it may take time and effort for quality control according to changes in temperature and humidity with the seasons.

そこで、本発明の目的は、食品向け包装用包材として採用しやすく、環境対策も考慮され、生成前の品質管理の手間を回避するポリオレフィン発泡体の製造方法、包装用包材の製造方法、ポリオレフィン発泡体、及び食品向け包装用包材を提供することにある。 Therefore, an object of the present invention is a method for producing a polyolefin foam, a method for producing a packaging material, a method for producing a polyolefin foam, which is easy to adopt as a packaging material for foods, takes environmental measures into consideration, and avoids the trouble of quality control before production. The present invention is to provide polyolefin foam and packaging materials for food packaging.

すなわち、本発明におけるポリオレフィン発泡体の製造方法は、少なくともポリオレフィン系樹脂と無機フィラーとを混練した樹脂組成物を加熱して溶融物を生成する工程と、上記溶融物100重量%に対して水0.5重量%〜3重量%加えてさらに混合して含水溶融物を生成する工程と、上記含水溶融物に含まれる水分を気化して発泡体を生成する工程と、を含むことを特徴とする。 That is, the method for producing a polyolefin foam in the present invention includes a step of heating a resin composition obtained by kneading at least a polyolefin resin and an inorganic filler to produce a melt, and 0 water with respect to 100% by weight of the melt. It is characterized by including a step of adding 5% by weight to 3% by weight and further mixing to form a hydrous melt, and a step of vaporizing the water contained in the hydrous melt to form a foam. ..

上記樹脂組成物は、化学発泡剤を含まず、上記樹脂組成物に対する上記発泡体の発泡倍率は、4倍以上であることが望ましい。 It is desirable that the resin composition does not contain a chemical foaming agent and the foaming ratio of the foam to the resin composition is 4 times or more.

上記ポリオレフィン系樹脂と上記無機フィラーとの重量比は、85:15〜30:70であることが望ましい。 The weight ratio of the polyolefin resin to the inorganic filler is preferably 85: 15-30: 70.

また、本発明における包装用包材の製造方法は、少なくともポリオレフィン系樹脂と無機フィラーとを混練した樹脂組成物を加熱して溶融物を生成する工程と、上記溶融物100重量%に対して水0.5重量%〜3重量%加えてさらに混合して含水溶融物を生成する工程と、上記含水溶融物に含まれる水分を気化して厚さ500μm〜3000μmのシート状の発泡体を生成する工程と、上記シート状の発泡体を成型する工程と、を含むことを特徴とする。 Further, the method for producing a packaging material for packaging in the present invention includes a step of heating a resin composition obtained by kneading at least a polyolefin resin and an inorganic filler to form a melt, and water with respect to 100% by weight of the melt. A step of adding 0.5% by weight to 3% by weight and further mixing to form a hydrous melt, and vaporizing the water contained in the hydrous melt to form a sheet-like foam having a thickness of 500 μm to 3000 μm. It is characterized by including a step and a step of molding the sheet-shaped foam.

また、本発明におけるポリオレフィン発泡体は、少なくともポリオレフィン系樹脂と無機フィラーとを混練した樹脂組成物を加熱した溶融物と水とを含む含水溶融物中の水分が気化された状態におけるポリオレフィン発泡体であって、上記含水溶融物は、上記溶融物100重量%に対して上記水0.5〜3重量%を含み、上記ポリオレフィン系樹脂は、ポリプロピレン系樹脂を含み、上記無機フィラーは、タルクを含み、上記ポリプロピレン系樹脂と上記無機フィラーとの重量比は、85:15〜30:70であることを特徴とする。 Further, the polyolefin foam in the present invention is a polyolefin foam in a state in which moisture in a hydrous melt containing at least a resin composition obtained by kneading a polyolefin resin and an inorganic filler is heated and water is vaporized. The water-containing melt contains 0.5 to 3% by weight of water with respect to 100% by weight of the melt, the polyolefin-based resin contains a polypropylene-based resin, and the inorganic filler contains talc. The weight ratio of the polypropylene-based resin to the inorganic filler is 85: 15 to 30:70.

また、本発明における食品向け包装用包材は、上記ポリオレフィン発泡体をシート状にしたポリオレフィン発泡体製シートで形成された食品向け包装用包材であって、上記ポリオレフィン発泡体製シートの厚さは、500μm〜3000μmで、食品を載置する底部と、上記底部の外周端縁から連続して上方向に設けられた側壁部と、を備えたことを特徴とする。 Further, the packaging material for foods in the present invention is a packaging material for foods formed of a polyolefin foam sheet obtained by forming the polyolefin foam into a sheet, and the thickness of the polyolefin foam sheet. Is 500 μm to 3000 μm, and is characterized by including a bottom portion on which food is placed and a side wall portion provided continuously upward from the outer peripheral edge of the bottom portion.

本発明によれば、食品向け包装用包材として採用しやすく、環境対策も考慮され、生成前の品質管理の手間を回避する効果を期待できる。 According to the present invention, it is easy to use as a packaging material for food packaging, environmental measures are taken into consideration, and the effect of avoiding the trouble of quality control before production can be expected.

本発明の一実施形態におけるポリオレフィン発泡体の製造方法で用いる押出機の一例である。This is an example of an extruder used in the method for producing a polyolefin foam according to an embodiment of the present invention. 本発明の一実施形態における食品向け包装用包材の製造方法で用いられる発泡体製シートの一例である。This is an example of a foam sheet used in the method for producing a packaging material for food according to an embodiment of the present invention.

以下、本発明の一実施形態におけるポリオレフィン発泡体の製造方法、食品向け包装用包材の製造方法、ポリオレフィン発泡体、及び食品向け包装用包材について説明する。 Hereinafter, a method for producing a polyolefin foam, a method for producing a packaging material for food, a polyolefin foam, and a packaging material for food packaging in one embodiment of the present invention will be described.

<ポリオレフィン発泡体の製造方法の概要>
ポリオレフィン発泡体の製造方法は、少なくともポリオレフィン系樹脂と無機フィラーとを混練した樹脂組成物を加熱して溶融物を生成する第1工程と、上記溶融物100重量%に対して水0.5〜3重量%加えてさらに混合して含水溶融物を生成する第2工程と、上記含水溶融物に含まれる水分を気化して発泡体を生成する第3工程と、を含む。
<Outline of method for producing polyolefin foam>
The method for producing the polyolefin foam is the first step of heating a resin composition obtained by kneading at least a polyolefin resin and an inorganic filler to produce a melt, and 0.5 to 0.5% of water based on 100% by weight of the melt. It includes a second step of adding 3% by weight and further mixing to produce a hydrous melt, and a third step of vaporizing the water contained in the hydrous melt to form a foam.

これらの工程によれば、樹脂組成物に多孔質(吸水性)は不要なため、季節に伴う温湿度等の変動に応じた品質管理の手間を回避すると共に、水分が均一に分散するため均一な気泡を得られ、樹脂組成物として無機フィラーを混ぜ合わせることで、合成樹脂の使用量の削減や生成される発泡体の剛性や強度の向上を期待できる。 According to these steps, since the resin composition does not need to be porous (water absorption), it avoids the trouble of quality control according to the fluctuation of temperature and humidity due to the season, and it is uniform because the moisture is uniformly dispersed. By mixing an inorganic filler as a resin composition, it is expected that the amount of synthetic resin used can be reduced and the rigidity and strength of the produced foam can be improved.

「溶融物」とは、第1工程にて加熱して樹脂組成物を融解して流動性を備えた状態のものである。「含水溶融物」とは、第2工程にて供給された水が溶融物に分散された状態のものである。「発泡体」とは、第3工程にて含水溶融物を大気圧下に開放することで、上記含水溶融物の水分の全部又は一部が気化することにより気泡となり、その後、冷却されることによって、固まった状態のものである。発泡体は、食品向け包装用包材や緩衝材や断熱材に採用されるが、使用可能な限り用途を問わないものとする。 The "molten product" is a state in which the resin composition is melted by heating in the first step to provide fluidity. The "hydrous melt" is a state in which the water supplied in the second step is dispersed in the melt. The "foam" means that by opening the hydrated melt under atmospheric pressure in the third step, all or part of the water content of the hydrated melt is vaporized to form bubbles, which are then cooled. It is in a solidified state. Foams are used as packaging materials for food packaging, cushioning materials, and heat insulating materials, but they can be used for any purpose as long as they can be used.

<樹脂組成物の詳細>
樹脂組成物は、合成樹脂のうち少なくともポリオレフィン系樹脂と、充填剤としての無機フィラーとを混練されていれば特に制限はなく、混練する合成樹脂は、ポリオレフィン系樹脂に加え、必要に応じて例えば、ポリスチレン系樹脂を添加してもよい。
<Details of resin composition>
The resin composition is not particularly limited as long as at least a polyolefin resin and an inorganic filler as a filler are kneaded among the synthetic resins, and the synthetic resin to be kneaded is, for example, in addition to the polyolefin resin, if necessary. , Polystyrene resin may be added.

樹脂組成物は、予め別工程にて製造されたコンパウンドとして供給されてもよい。ここで、コンパウンドとは、合成樹脂のうち少なくともポリオレフィン系樹脂と、充填剤としての無機フィラーとを加熱しながら混練して、押出して、ペレット状にしたものをいう。本発明において、コンパウンドの含水率は1重量%以下、好ましくは0.5重量%以下、さらに好ましくは0.1重量%以下であることが好ましい。 The resin composition may be supplied as a compound previously produced in a separate step. Here, the compound refers to a synthetic resin in which at least a polyolefin resin and an inorganic filler as a filler are kneaded while being heated and extruded into pellets. In the present invention, the water content of the compound is preferably 1% by weight or less, preferably 0.5% by weight or less, and more preferably 0.1% by weight or less.

ポリオレフィン系樹脂は、ポリエチレン系樹脂(PE)やポリプロピレン系樹脂(PP)が該当し、ポリエチレン系樹脂とポリプロピレン系樹脂との混合物でもよいが、好ましくはポリプロピレン系樹脂のみである。 The polyolefin-based resin corresponds to a polyethylene-based resin (PE) or a polypropylene-based resin (PP), and may be a mixture of a polyethylene-based resin and a polypropylene-based resin, but is preferably only a polypropylene-based resin.

ポリプロピレン系樹脂は、例えば、ホモポリプロピレン樹脂、プロピレン−エチレンランダム共重合体、プロピレン−エチレンブロック共重合体、プロピレン−αオレフィン共重合体である。 The polypropylene-based resin is, for example, a homopolypropylene resin, a propylene-ethylene random copolymer, a propylene-ethylene block copolymer, or a propylene-α-olefin copolymer.

無機フィラーは、例えば、10nm〜100μmの粒子状のもので、タルク、炭酸カルシウム、シリカ、クレー、ウォラストナイト、チタン酸カリウム、ゾノトライト、石膏繊維、アルミボレート、繊維状マグネシウム化合物(MOS)、アラミド繊維、カーボンファイバー(炭素繊維)、グラスファイバー(ガラス繊維)、マイカ、ガラスフレーク、ポリオキシベンゾイルウイスカーであり、1種類でも2種類以上の混合物でもよく、好ましくは食品向け包装分野にて実績のあるタルクであり、その平均粒径は、5μm〜15μmであってもよく、6μm〜10μmであってもよく、7μm〜9μmであってもよい。 Inorganic fillers are, for example, particles of 10 nm to 100 μm, such as talc, calcium carbonate, silica, clay, wollastonite, potassium titanate, zonotrite, gypsum fiber, aluminum borate, fibrous magnesium compound (MOS), and aramid. Fibers, carbon fibers (carbon fibers), glass fibers (glass fibers), mica, glass flakes, polyoxybenzoyl whiskers, which may be one type or a mixture of two or more types, preferably have a proven track record in the food packaging field. It is a talc, and its average particle size may be 5 μm to 15 μm, 6 μm to 10 μm, or 7 μm to 9 μm.

<水の割合>
水は、溶融物100重量%に対して、0.5重量%〜3重量%でもよいが、好ましくは0.6重量%〜1.5重量%、より好ましくは0.8重量%〜1.2重量%であり、0.5重量%より少ないと発泡せず所望の物性が得られず、3重量%より多いと均一な気泡が得られず発泡体の物性が不安定になってしまうことが懸念される。
<Ratio of water>
The water content may be 0.5% by weight to 3% by weight, preferably 0.6% by weight to 1.5% by weight, more preferably 0.8% by weight to 1.% by weight, based on 100% by weight of the melt. It is 2% by weight, and if it is less than 0.5% by weight, it does not foam and the desired physical properties cannot be obtained, and if it is more than 3% by weight, uniform bubbles cannot be obtained and the physical properties of the foam become unstable. Is a concern.

<ポリオレフィン発泡体の製造方法の別の特徴>
また、上述の樹脂組成物は、化学発泡剤を含まず、樹脂組成物に対する上記発泡体の発泡倍率は、4倍以上である。
<Another feature of the method for producing polyolefin foam>
Further, the above-mentioned resin composition does not contain a chemical foaming agent, and the expansion ratio of the above-mentioned foam with respect to the resin composition is 4 times or more.

これによれば、化学発泡剤の使用に伴う環境負荷を回避すると共に、化学発泡剤を樹脂組成物に混練しなくても所望の発泡倍率の発泡体を得られる。すなわち、発泡倍率が4倍未満の発泡体は硬く、食品向け包装用包材に適した強度・剛性・弾性等の物性を伴わないことから、食品向け包装用包材としては不向きである。 According to this, the environmental load associated with the use of the chemical foaming agent can be avoided, and a foam having a desired foaming ratio can be obtained without kneading the chemical foaming agent into the resin composition. That is, a foam having a foaming ratio of less than 4 times is hard and does not have physical properties such as strength, rigidity, and elasticity suitable for packaging materials for foods, and therefore is not suitable as packaging materials for foods.

なお、化学発泡剤は、有機系発泡剤及び無機系発泡剤並びに熱分解型及び反応系を含み、例えば、ジニトロペンタメチレンテトラミン(DPT)、アゾジカルボンアミド(ADCA)、4,4′‐オキシビスベンゾスルホニルヒドラジド(OBSH)、炭酸水素塩、炭酸塩、炭酸水素ナトリウム(重曹)、炭酸水素ナトリウムとクエン酸との組合せであり、水等の天然由来の発泡剤を除き、全て含む。 The chemical foaming agent includes an organic foaming agent and an inorganic foaming agent, as well as a thermally decomposable type and a reaction system, and includes, for example, dinitropentamethylenetetramine (DPT), azodicarboxylicamide (ADCA), and 4,4'-oxybis. It is a combination of benzosulfonyl hydrazide (OBSH), hydrogen carbonate, carbonate, sodium hydrogen carbonate (baking soda), sodium hydrogen carbonate and citric acid, and includes all except naturally-derived foaming agents such as water.

さらに、ポリオレフィン系樹脂と無機フィラーとの重量比は、85:15〜30:70であり、好ましくは70:30〜35:65であり、より好ましくは60:40〜40:60である。 Further, the weight ratio of the polyolefin resin and the inorganic filler is 85: 15 to 30:70, preferably 70:30 to 35:65, and more preferably 60:40 to 40:60.

これによれば、85:15よりポリオレフィン系樹脂の重量比が高いと、柔らかくなりすぎてしまい、食品向け包装用包材に適した強度・剛性・弾性等の物性を発泡体が伴いにくく、30:70より無機フィラーの重量比が高いと、シートが得られない。そして、より好ましくはポリオレフィン系樹脂がポリプロピレン系樹脂、無機フィラーがタルクである。 According to this, if the weight ratio of the polyolefin resin is higher than 85:15, it becomes too soft, and it is difficult for the foam to accompany physical properties such as strength, rigidity, and elasticity suitable for packaging materials for foods. If the weight ratio of the inorganic filler is higher than: 70, a sheet cannot be obtained. More preferably, the polyolefin resin is a polypropylene resin and the inorganic filler is talc.

<食品向け包装用包材の製造方法の概要>
食品向け包装用包材の製造方法は、ポリオレフィン発泡体の製造方法で製造されたポリオレフィン発泡体を、押し出して厚さ500μm〜3000μmのシート状の発泡体を得る第3工程と、上記シート状の発泡体を成型する第4工程と、を含む。
<Outline of manufacturing method of packaging materials for food>
The method for producing the packaging material for food products includes a third step of extruding the polyolefin foam produced by the method for producing a polyolefin foam to obtain a sheet-shaped foam having a thickness of 500 μm to 3000 μm, and the above-mentioned sheet-like manufacturing method. Includes a fourth step of molding the foam.

これらの工程によれば、所望の強度・剛性・弾性等の物性を伴う食品向け包装用包材を得られる効果を期待できる。シートが500μmより薄いと成型時又は使用時に破損しやすく、3000μmより厚いと製造コスト高となり費用対効果の低下を招く恐れがある。 According to these steps, it is expected that a packaging material for food packaging having desired physical properties such as strength, rigidity, and elasticity can be obtained. If the sheet is thinner than 500 μm, it is easily damaged during molding or use, and if it is thicker than 3000 μm, the manufacturing cost is high and the cost effectiveness may be lowered.

「食品向け包装用包材」とは、例えば、食品を載置する底部と、上記底部の外周端縁から連続して上方向に設けられた側壁部と、を少なくとも備えた包装体であり、好ましくは上記側壁部の上端縁から連続して外方向に延出しているフランジ部を備え、より好ましくは上記フランジ部の外周端縁から連続して外方向に延出していて上記側壁部の上端縁で形成された開口を覆う蓋部を備えたものである。上記包装体は、いわゆる容器であってもなくてもよく、平面視で矩形状でも円形状でもよく、限定しない。「食品」とは、例えば、精肉や鮮魚等の生鮮品であり、サラダやケーキのようなふんわり感を演出するものと比較して、相対的に高密度かつ重めのものであれば、全て含む。 The "packaging material for food" is, for example, a packaging body including at least a bottom portion on which food is placed and a side wall portion continuously provided upward from the outer peripheral edge of the bottom portion. It is preferably provided with a flange portion that extends outward continuously from the upper end edge of the side wall portion, and more preferably the upper end of the side wall portion that extends continuously outward from the outer peripheral edge of the flange portion. It is provided with a lid covering an opening formed by an edge. The package may or may not be a so-called container, and may be rectangular or circular in a plan view, and is not limited. "Food" is, for example, all fresh products such as meat and fresh fish, as long as they are relatively dense and heavy compared to those that produce a fluffy feeling such as salads and cakes. include.

<各工程同士の関係>
第1工程〜第4工程は、時系列であり、製造効率の向上の観点から、各工程同士の間隔は、所望の発泡体及び食品向け包装用包材の生成に影響しない限りいずれでもよいが、好ましくは直前の工程完了直後に次の工程を開始すると共に、各工程を別々の装置で行ってもよいが、好ましくは第1工程〜第3工程を所定の装置1台、第4工程を別の装置1台で行い、より好ましくは第1工程〜第3工程を押出機、第4工程を成型機で行う。
<Relationship between each process>
The first step to the fourth step are in chronological order, and from the viewpoint of improving the production efficiency, the interval between the steps may be any as long as it does not affect the production of the desired foam and packaging material for food. The next step may be started immediately after the completion of the immediately preceding step, and each step may be performed by a separate device. However, preferably, the first step to the third step are performed by one predetermined device, and the fourth step is performed. It is carried out by another device, more preferably the first step to the third step are carried out by an extruder, and the fourth step is carried out by a molding machine.

<押出機の詳細>
図1に示すように、ポリオレフィン発泡体の製造方法で用いられる押出機Mは、内部に単軸のスクリュー111を備えた加熱冷却式のシリンダー101と、シリンダー101の上流端側に設けられて樹脂組成物が投入される投入口121と、シリンダー101の下流端側に設けられて含水溶融物が押し出されるダイ131と、シリンダー101の上流端側から下流端側までの間に設けられて内部に水を注入する注水部141と、を備えている。
<Details of extruder>
As shown in FIG. 1, the extruder M used in the method for producing a polyolefin foam is a heating / cooling cylinder 101 having a uniaxial screw 111 inside, and a resin provided on the upstream end side of the cylinder 101. The inlet 121 into which the composition is charged, the die 131 provided on the downstream end side of the cylinder 101 to extrude the hydrous melt, and the die 131 provided between the upstream end side and the downstream end side of the cylinder 101 are provided inside. It is provided with a water injection unit 141 for injecting water.

ダイ131は、シリンダー101の出口から原料を押し出して発泡体を所望の形状にて生成する吐出孔を有する治具で、例えば、Tダイやサーキュラーダイであるが、好ましくは発泡体Sをシートに生成しやすい吐出孔を有するTダイである。上記吐出孔の大きさや形状には、特に制限はないが例えばTダイの場合、厚さ(クリアランス)0.01〜0.3mm、幅500mm〜2000mmの長方形状やであってもよい。サーキュラーダイの場合は、直径150〜650mm、厚さ(クリアランス)0.01〜0.3mmの円環形状であってもよい。 The die 131 is a jig having a discharge hole for extruding a raw material from the outlet of the cylinder 101 to generate a foam in a desired shape. For example, a T die or a circular die, but preferably the foam S is used as a sheet. It is a T-die having a discharge hole that is easy to generate. The size and shape of the discharge hole are not particularly limited, but in the case of a T-die, for example, a rectangular shape having a thickness (clearance) of 0.01 to 0.3 mm and a width of 500 mm to 2000 mm may be used. In the case of a circular die, it may have an annular shape with a diameter of 150 to 650 mm and a thickness (clearance) of 0.01 to 0.3 mm.

Tダイ131は、吐出孔を丸孔にしてもよく、こうした丸孔を複数個隣接させて備えていてもよい。こういった構成よれば、押出された棒状の発泡体(棒状発泡体ともいう)が隣接する棒状発泡体と溶融状態で密着結合し、棒状発泡体の集合体を得ることができる。丸孔の配列によってシート状の集合体を得ることもできるし、円筒状の集合体を得ることもできる。ここで、吐出孔としての丸孔の大きさは、直径0.01〜0.3mmであってもよい。 The T-die 131 may have round discharge holes, and a plurality of such round holes may be provided adjacent to each other. According to such a configuration, the extruded rod-shaped foam (also referred to as rod-shaped foam) is tightly bonded to the adjacent rod-shaped foam in a molten state, and an aggregate of the rod-shaped foam can be obtained. A sheet-like aggregate can be obtained by arranging the round holes, or a cylindrical aggregate can be obtained. Here, the size of the round hole as the discharge hole may be 0.01 to 0.3 mm in diameter.

注水部141は、詳細には図示しないが、シリンダー101の外部から内部に通ずる孔に設けられた逆止弁と、別機である定量ポンプから逆止弁を介してスクリュー111付近に向かって水を供給する。換言すれば、注水部141は、樹脂組成物をシリンダー101内で加熱しつつスクリュー111で下流端側に押し進めて融解した溶融物に水を供給して含水溶融物を生成しやすくするものであり、逆止弁は、好ましくはシリンダー101のうちスクリュー111により下流端側に押し進められた樹脂組成物が溶融物に融解し切る箇所に設けられたものである。 Although not shown in detail, the water injection unit 141 is provided with a check valve provided in a hole leading from the outside to the inside of the cylinder 101, and water from a metering pump, which is a separate machine, toward the vicinity of the screw 111 via the check valve. Supply. In other words, the water injection unit 141 heats the resin composition in the cylinder 101 and pushes it toward the downstream end side with the screw 111 to supply water to the melted melt to facilitate the formation of a hydrous melt. The check valve is preferably provided at a position in the cylinder 101 where the resin composition pushed toward the downstream end side by the screw 111 is completely melted into the melt.

<成型機の詳細>
食品向け包装用包材の製造方法で用いられる成型機は、例えば、プレス成型、真空成型、熱板圧空成型、真空圧空成型、両面真空成型、深絞り成型を行う装置である。
<Details of molding machine>
The molding machine used in the method for manufacturing a packaging material for food products is, for example, a device that performs press molding, vacuum forming, hot plate pressure air forming, vacuum pressure air forming, double-sided vacuum forming, and deep drawing.

<各工程と装置との関係>
第1工程〜第3工程を上記押出機で行う場合、第1工程は、樹脂組成物を投入口121からシリンダー101内に投入するところから、シリンダー101内の加熱及びスクリュー111の回転により上記樹脂組成物を融解して溶融物を生成するまでであり、第2工程は、第1工程で生成した溶融物に注水部141の注水により水を供給するところから、シリンダー101内の加熱及びスクリュー111の回転により上記溶融物及び水を分散させて含水溶融物を生成するところまでであり、第3工程は、第2工程で生成した含水溶融物をシリンダー101内からダイ131に送り出すところから、上記含水溶融物の水分の気化によって発泡体を生成するところまで、が該当する。
<Relationship between each process and equipment>
When the first step to the third step are performed by the extruder, in the first step, the resin composition is charged into the cylinder 101 from the charging port 121, and then the resin is heated by heating in the cylinder 101 and rotating the screw 111. Until the composition is melted to produce a melt, the second step is to supply water to the melt produced in the first step by injecting water from the water injection unit 141, and then heat the inside of the cylinder 101 and screw 111. Up to the point where the melt and water are dispersed by the rotation of the above to generate a hydrous melt, and in the third step, the hydrous melt produced in the second step is sent from the inside of the cylinder 101 to the die 131. Up to the point where foam is formed by vaporizing the water content of the hydrous melt.

第3工程においてダイ131として長方形状の吐出孔を有するTダイを用いることもできる。すなわち、第3工程にてダイ131に送り出された含水溶融物がダイ131の吐出孔を通過することで大気圧下に開放されてシート状の発泡体を得ることもできる。 A T-die having a rectangular discharge hole can also be used as the die 131 in the third step. That is, the hydrous melt sent to the die 131 in the third step passes through the discharge hole of the die 131 and is released under atmospheric pressure to obtain a sheet-like foam.

また、第3工程においてTダイ131の吐出孔を丸孔にしてもよく、こうした丸孔を複数個隣接して形成してもよい。こういった構成によれば、押出された棒状発泡体が隣接する棒状発泡体と溶融状態で密着結合し、棒状発泡体の集合体を得ることができる。 Further, in the third step, the discharge holes of the T-die 131 may be round holes, and a plurality of such round holes may be formed adjacent to each other. According to such a configuration, the extruded rod-shaped foam can be tightly bonded to the adjacent rod-shaped foam in a molten state to obtain an aggregate of the rod-shaped foam.

第4工程を上記成型機で行う場合、第4工程は、第3工程で得たシート状の発泡体を上記押出機から成型機に供給するところから、上記シート状の発泡体を成型するところまで、が該当する。 When the fourth step is performed by the molding machine, the fourth step is to mold the sheet-shaped foam from the place where the sheet-shaped foam obtained in the third step is supplied from the extruder to the molding machine. Up to is applicable.

<シート状の発泡体の詳細>
図2に示すように、シート状の発泡体S(以下、「シートS」ともいう。)は、端面視波型である。図2(a)の平面図に示すように、直線状の細線は波型の山側及び谷側の頂点を示す稜線であり、上記稜線間の横幅(隣接する山同士の距離)は不規則であるが、平均200μm〜500μmであり、上記平面図のX−X部分における図2(b)の端面図に示すように、波型の各々の山側及び谷側の縦幅(山の頂点と隣の谷の頂点との垂直方向の距離)は不規則であるが、平均500μm〜1500μmである。シートSの厚みは、特に制限はないが、200μm〜1500μmであってもよいし、300μm〜800μmであってもよい。シートSの形状は、ポリオレフィン発泡体の製造方法及び食品向け包装用包材の製造方法に基づくが、特に、発泡体の発泡倍率、押し出し時のダイの吐出孔の大きさや形状、含水溶融物内の水分量のいずれか1つ又は2つ以上の組み合わせに基づく。シートSは、発泡体の構造上、上記稜線方向に裂けやすいことから、上記稜線方向と平行に伸縮しやすく折り曲げたり丸めたりしやすく、換言すれば、上記稜線方向に沿って伸縮しにくく折り曲げたり丸めたりしにくい。
<Details of sheet-shaped foam>
As shown in FIG. 2, the sheet-shaped foam S (hereinafter, also referred to as “sheet S”) is an end face sight wave type. As shown in the plan view of FIG. 2A, the linear thin line is a ridge line indicating the vertices on the wavy mountain side and the valley side, and the width between the ridge lines (distance between adjacent mountains) is irregular. However, the average is 200 μm to 500 μm, and as shown in the end view of FIG. The vertical distance from the apex of the valley) is irregular, but averages between 500 μm and 1500 μm. The thickness of the sheet S is not particularly limited, but may be 200 μm to 1500 μm or 300 μm to 800 μm. The shape of the sheet S is based on the method for producing a polyolefin foam and the method for producing a packaging material for foods, and in particular, the expansion ratio of the foam, the size and shape of the discharge hole of the die at the time of extrusion, and the inside of the hydrous melt. Based on any one or a combination of two or more of the water contents of. Since the sheet S is easily torn in the ridgeline direction due to the structure of the foam, it is easy to expand and contract in parallel with the ridgeline direction and is easily bent or rolled, in other words, it is difficult to expand and contract along the ridgeline direction and is bent. Difficult to roll.

以下に、本発明におけるポリオレフィン発泡体の製造方法で製造したポリオレフィン発泡体及び上記ポリオレフィン発泡体により食品向け包装用包材の製造方法で製造した食品向け包装用包材の評価試験について説明する。 The evaluation test of the polyolefin foam produced by the method for producing a polyolefin foam in the present invention and the packaging material for foods produced by the method for producing a packaging material for foods by the above-mentioned polyolefin foam will be described below.

<評価試験の概要>
評価試験は、実施例及び比較例として、樹脂組成物の配合、上記配合における重量比、及び溶融物100重量%に対する水の重量%を変えて行った。評価試験における共通条件及び各評価項目の評価方法は、以下のとおりである。
<Outline of evaluation test>
The evaluation test was carried out as an example and a comparative example by changing the composition of the resin composition, the weight ratio in the above composition, and the weight% of water with respect to 100% by weight of the melt. The common conditions in the evaluation test and the evaluation method for each evaluation item are as follows.

<評価試験の共通条件>
ポリオレフィン発泡体の製造方法は、東芝機械社製の押出機にて実施し、シリンダーの加熱温度は160〜220℃、Tダイの吐出孔は厚さ(クリアランス)0.05mm・幅1000mmとし、シート状の発泡体を得るものとする。樹脂組成物は、少なくとも合成樹脂としてポリプロピレン系樹脂、無機フィラーとして平均粒径8μmのタルクを成分とし、化学発泡剤を含んでおらず、多孔質や形状に基づく吸水性を伴っていないコンパウンドとして供給される。
<Common conditions for evaluation tests>
The method for producing the polyolefin foam was carried out by an extruder manufactured by Toshiba Machine Co., Ltd., the heating temperature of the cylinder was 160 to 220 ° C., the discharge hole of the T-die had a thickness (clearance) of 0.05 mm and a width of 1000 mm, and the sheet. It is assumed that a foam in the form of a foam is obtained. The resin composition contains at least a polypropylene resin as a synthetic resin and talc having an average particle size of 8 μm as an inorganic filler, and is supplied as a compound that does not contain a chemical foaming agent and does not have water absorption based on porosity or shape. Will be done.

食品向け包装用包材の製造方法は、プレス成型を行う成型機にて実施し、製造された食品向け包装用包材は、一般的な生鮮品の包装用であり、少なくとも底部及び側壁部を備えており、上記側壁部の上端縁で形成される開口から上記底部までの高さに相当する包装材の深さは25mmである。 The method for manufacturing the packaging material for food is carried out by a molding machine that performs press molding, and the packaging material for food produced is for packaging general fresh products, and at least the bottom and side walls are covered. The depth of the packaging material corresponding to the height from the opening formed at the upper end edge of the side wall portion to the bottom portion is 25 mm.

<発泡体の評価方法>
坪量は、JIS P8124「紙及び板紙-坪量の測定方法」を参考にし、シートから打ち抜いた100mm×100mmの試験片にて測定する。比重及び発泡倍率は、JIS Z8807「固体の密度及び比重の測定方法」を参考にし、島津製作所社製の比重計を使用し、水中置換法で測定する。
<Evaluation method of foam>
The basis weight is measured with a 100 mm × 100 mm test piece punched from a sheet with reference to JIS P8124 “Paper and paperboard-Measurement method of basis weight”. The specific gravity and foaming ratio are measured by an underwater substitution method using a hydrometer manufactured by Shimadzu Corporation with reference to JIS Z8807 "Measuring method of solid density and specific gravity".

<シート及び食品向け包装用包材の評価方法>
シートの縦幅は、ミツトヨ社製のシックネスゲージで測定する。弾性率は、インストロン社製の万能材料試験機を使用し測定する。弾性率を測定するシートの向きは、波型の稜線方向を基準とし、上記稜線方向をMD、MDと直交する方向をTDとする。引張弾性率は、JIS K7161「プラスチック-引張特性の求め方」を転用し、シートから打ち抜いた140mm×15mmの試験片にて測定する。曲げ弾性率は、JIS K7171「プラスチック-曲げ特性の求め方」を転用し、シートから打ち抜いた70mm×15mmの試験片にて測定する。山の数は、シートから打ち抜いた上記TDで50mmの試験片にて目視で算定する。
<Evaluation method for packaging materials for sheets and food products>
The vertical width of the sheet is measured with a thickness gauge manufactured by Mitutoyo. The elastic modulus is measured using an Instron universal material tester. The orientation of the sheet for measuring the elastic modulus is based on the corrugated ridge direction, MD is the ridge direction, and TD is the direction orthogonal to the MD. The tensile elastic modulus is measured with a 140 mm × 15 mm test piece punched from a sheet by diverting JIS K7161 “Plastic-How to determine tensile properties”. The flexural modulus is measured with a 70 mm × 15 mm test piece punched from a sheet by diverting JIS K7171 “Plastic-How to determine bending characteristics”. The number of ridges is visually calculated with a 50 mm test piece with the above TD punched from the sheet.

最終的に、シートの状態として、成形可能かつ上記山の凹凸が均一である場合を『○』、成形可能だが上記凹凸が不均一である場合を『△』、成形不可能な場合を『×』で評価する。また、作業者による包装用包材のパッキングのしやすさとして、問題ない場合を『○』、硬すぎて折り曲げられない場合を『×』で評価する。 Finally, as the state of the sheet, "○" is the case where the sheet is moldable and the unevenness of the mountain is uniform, "△" is the case where the sheet is moldable but the unevenness is uneven, and "×" is the case where the sheet cannot be molded. 』Evaluate with. In addition, as the ease of packing the packaging material by the operator, the case where there is no problem is evaluated by "○", and the case where it is too hard to be bent is evaluated by "x".

実施例1〜4、比較例1及び2の個別条件は、以下のとおりである。 The individual conditions of Examples 1 to 4 and Comparative Examples 1 and 2 are as follows.

<実施例1>
合成樹脂=PP、無機フィラー=タルク、重量比=PP:タルク=45:55、水=1重量%
<Example 1>
Synthetic resin = PP, inorganic filler = talc, weight ratio = PP: talc = 45:55, water = 1% by weight

<実施例2>
合成樹脂=PP+PE、無機フィラー=タルク、重量比=PP:PE:タルク=35:10:55、水=1重量%
<Example 2>
Synthetic resin = PP + PE, inorganic filler = talc, weight ratio = PP: PE: talc = 35:10:55, water = 1% by weight

<実施例3>
合成樹脂=PP、無機フィラー=タルク、重量比=PP:タルク=85:15、水=2重量%
<Example 3>
Synthetic resin = PP, inorganic filler = talc, weight ratio = PP: talc = 85:15, water = 2% by weight

<実施例4>
合成樹脂=PP、無機フィラー=タルク、重量比=PP:タルク=90:10、水=1.5重量%
<Example 4>
Synthetic resin = PP, inorganic filler = talc, weight ratio = PP: talc = 90:10, water = 1.5% by weight

<比較例1>
合成樹脂=PP、無機フィラー=タルク、重量比=PP:タルク=45:55、水=0.3重量%
<Comparative example 1>
Synthetic resin = PP, inorganic filler = talc, weight ratio = PP: talc = 45:55, water = 0.3% by weight

<比較例2>
合成樹脂=PP、無機フィラー=タルク、重量比=PP:タルク=45:55、水=5重量%
<Comparative example 2>
Synthetic resin = PP, inorganic filler = talc, weight ratio = PP: talc = 45:55, water = 5% by weight

<実施例1〜4の個別条件の相違点>
実施例1を基準にする。実施例2は、実施例1に対し、ポリプロピレン系樹脂の重量比を減らし、かつポリエチレン系樹脂を加えたものである。実施例3及び4は、実施例1に対し、樹脂組成物におけるポリプロピレン系樹脂とタルクとの重量比や含水溶融物における水の重量%を変えたものであり、上記重量比の臨界的意義を検討するものでもある。
<Differences in individual conditions of Examples 1 to 4>
Example 1 is used as a reference. In Example 2, the weight ratio of the polypropylene-based resin is reduced and the polyethylene-based resin is added to Example 1. In Examples 3 and 4, the weight ratio of the polypropylene resin and the talc in the resin composition and the weight% of water in the hydrous melt were changed from those in Example 1, and the critical significance of the weight ratio was determined. It is also something to consider.

<実施例1と比較例1及び2との個別条件の相違点>
比較例1及び2は、実施例1に対し、含水溶融物における水の重量%を0.5重量%〜3重量%の範囲外にしたものであり、上記範囲の臨界的意義を検討するものでもある。
<Differences in individual conditions between Example 1 and Comparative Examples 1 and 2>
In Comparative Examples 1 and 2, the weight% of water in the hydrous melt was out of the range of 0.5% by weight to 3% by weight with respect to Example 1, and the critical significance of the above range was examined. But also.

<評価結果>
実施例1〜4並びに比較例1及び2の評価結果を表1に示す。参照の便宜上、同表には上述した個別条件も記載してある。上記評価方法における各評価結果は、上記TDにおける所定の直線上に位置する任意の3点をサンプリングし、その相加平均値にて算定したものである。
<Evaluation result>
Table 1 shows the evaluation results of Examples 1 to 4 and Comparative Examples 1 and 2. For convenience of reference, the table also lists the individual conditions mentioned above. Each evaluation result in the above evaluation method is calculated by sampling arbitrary three points located on a predetermined straight line in the above TD and calculating the arithmetic mean value thereof.

Figure 2021161236
Figure 2021161236

<実施例1〜4の考察>
実施例1を基準にして対比すると、実施例2により、ポリプロピレン系樹脂の減量分をポリエチレン系樹脂で代替し、また、実施例3及び4により、樹脂組成物におけるポリプロピレン系樹脂の重量比を多めにしても、略同等の評価となった。一方、実施例3に対し、実施例4では、上記重量比が85:15〜30:70の範囲外だと、含水溶融物における水の重量%が0.5〜3重量%の範囲内であっても、シートの成形性としては、成形可能だが山の凹凸が不均一である『△』と評価された。
<Discussion of Examples 1 to 4>
Comparing with reference to Example 1, in Example 2, the weight loss of the polypropylene-based resin was replaced with the polyethylene-based resin, and in Examples 3 and 4, the weight ratio of the polypropylene-based resin in the resin composition was increased. Even so, the evaluation was almost the same. On the other hand, in Example 4, when the weight ratio is out of the range of 85: 15 to 30:70, the weight% of water in the hydrous melt is in the range of 0.5 to 3% by weight with respect to Example 3. Even if there was, the formability of the sheet was evaluated as "Δ", which is formable but the unevenness of the mountain is uneven.

<比較例1及び2の考察>
含水溶融物における水の重量%の許容範囲を0.5重量%〜3重量%として考察する。比較例1では、水の重量%を上記許容範囲の最低値を下回るようにしたところ、発泡体の発泡倍率が4倍未満であり、シートの厚みが500μm〜3000μmの範囲外で薄くなり過ぎてしまうことから、シートの状態としては、成形可能だが上記凹凸が不均一である『△』、包装用包材のパッキングのしやすさとしては、硬過ぎて折り曲げられない『×』と評価された。比較例2では、水の重量%を上記許容範囲の最大値を上回るようにしたところ、発泡しすぎてしまい成型可能なシートが得られなかった。
<Discussion of Comparative Examples 1 and 2>
The permissible range of% by weight of water in the hydrous melt is considered as 0.5% by weight to 3% by weight. In Comparative Example 1, when the weight% of water was set to be lower than the minimum value in the above allowable range, the foaming ratio of the foam was less than 4 times, and the thickness of the sheet became too thin outside the range of 500 μm to 3000 μm. Therefore, the state of the sheet was evaluated as "△", which is moldable but the above-mentioned unevenness is uneven, and "×", which is too hard to be bent as the ease of packing the packaging material for packaging. .. In Comparative Example 2, when the weight% of water was set to exceed the maximum value in the above allowable range, the foamed too much and a moldable sheet could not be obtained.

<参考例>
説明の便宜上、比較例とは異なる条件にて行った試験の評価結果を表2に示す。
<Reference example>
For convenience of explanation, Table 2 shows the evaluation results of the tests conducted under conditions different from those of the comparative examples.

Figure 2021161236
Figure 2021161236

参考例1では、樹脂組成物の配合及び重量比が実施例3と同等であるものの、シートの層構成を2種3層(ポリプロピレン系樹脂とタルクとの樹脂組成物層/ポリプロピレン発泡層/ポリプロピレン系樹脂とタルクとの樹脂組成物層)にすると、発泡倍率が4倍未満で、シートとしては硬過ぎてしまう。参考例2では、樹脂組成物の配合及び重量比が実施例1と同等であるものの、発泡体の発泡倍率を1(非発泡)にすると、硬いシートとなる。 In Reference Example 1, although the composition and weight ratio of the resin composition are the same as those in Example 3, the layer structure of the sheet is 2 types and 3 layers (resin composition layer of polypropylene resin and talc / polypropylene foam layer / polypropylene). A resin composition layer of a based resin and talc) has a foaming ratio of less than 4 times, which makes it too hard for a sheet. In Reference Example 2, although the composition and weight ratio of the resin composition are the same as those in Example 1, when the foaming ratio of the foam is set to 1 (non-foaming), a hard sheet is obtained.

M 押出機、S 発泡体、101 シリンダー、111 スクリュー、121 投入口、131 ダイ、141 注水部 M extruder, S foam, 101 cylinder, 111 screw, 121 inlet, 131 die, 141 water injection part

Claims (6)

少なくともポリオレフィン系樹脂と無機フィラーとを混練した樹脂組成物を加熱して溶融物を生成する工程と、
前記溶融物100重量%に対して水0.5重量%〜3重量%加えてさらに混合して含水溶融物を生成する工程と、
前記含水溶融物に含まれる水分を気化して発泡体を生成する工程と、を含む
ことを特徴とするポリオレフィン発泡体の製造方法。
A step of heating a resin composition obtained by kneading at least a polyolefin resin and an inorganic filler to form a melt, and
A step of adding 0.5% by weight to 3% by weight of water to 100% by weight of the melt and further mixing to produce a hydrous melt.
A method for producing a polyolefin foam, which comprises a step of vaporizing the water contained in the hydrous melt to form a foam.
前記樹脂組成物は、化学発泡剤を含まず、
前記樹脂組成物に対する前記発泡体の発泡倍率は、4倍以上である
ことを特徴とする請求項1に記載のポリオレフィン発泡体の製造方法
The resin composition does not contain a chemical foaming agent and does not contain a chemical foaming agent.
The method for producing a polyolefin foam according to claim 1, wherein the foaming ratio of the foam to the resin composition is 4 times or more.
前記ポリオレフィン系樹脂と前記無機フィラーとの重量比は、85:15〜30:70である
ことを特徴とする請求項1又は2に記載のポリオレフィン発泡体の製造方法。
The method for producing a polyolefin foam according to claim 1 or 2, wherein the weight ratio of the polyolefin resin to the inorganic filler is 85: 15 to 30:70.
少なくともポリオレフィン系樹脂と無機フィラーとを混練した樹脂組成物を加熱して溶融物を生成する工程と、
前記溶融物100重量%に対して水0.5重量%〜3重量%加えてさらに混合して含水溶融物を生成する工程と、
前記含水溶融物に含まれる水分を気化して厚さ500μm〜3000μmのシート状の発泡体を生成する工程と、
前記シート状の発泡体を成型する工程と、を含む
ことを特徴とする包装用包材の製造方法。
A step of heating a resin composition obtained by kneading at least a polyolefin resin and an inorganic filler to form a melt, and
A step of adding 0.5% by weight to 3% by weight of water to 100% by weight of the melt and further mixing to produce a hydrous melt.
A step of vaporizing the water contained in the hydrous melt to form a sheet-like foam having a thickness of 500 μm to 3000 μm, and
A method for producing a packaging material for packaging, which comprises a step of molding the sheet-shaped foam.
少なくともポリオレフィン系樹脂と無機フィラーとを混練した樹脂組成物を加熱した溶融物と水とを含む含水溶融物中の水分が気化された状態におけるポリオレフィン発泡体であって、
前記含水溶融物は、前記溶融物100重量%に対して前記水0.5〜3重量%を含み、
前記ポリオレフィン系樹脂は、ポリプロピレン系樹脂を含み、
前記無機フィラーは、タルクを含み、
前記ポリプロピレン系樹脂と前記無機フィラーとの重量比は、85:15〜30:70である
ことを特徴とするポリオレフィン発泡体。
A polyolefin foam in a state in which water in a hydrous melt containing at least a melt obtained by heating a resin composition obtained by kneading a polyolefin resin and an inorganic filler and water is vaporized.
The hydrous melt contains 0.5 to 3% by weight of the water with respect to 100% by weight of the melt.
The polyolefin-based resin contains a polypropylene-based resin and contains
The inorganic filler contains talc and contains
A polyolefin foam having a weight ratio of the polypropylene resin to the inorganic filler of 85: 15 to 30:70.
請求項5に記載のポリオレフィン発泡体をシート状にしたポリオレフィン発泡体製シートで形成された食品向け包装用包材であって、
前記ポリオレフィン発泡体製シートの厚さは、500μm〜3000μmで、
食品を載置する底部と、
前記底部の外周端縁から連続して上方向に設けられた側壁部と、を備えた
ことを特徴とする食品向け包装用包材。
A packaging material for food packaging formed of a sheet made of a polyolefin foam obtained by forming a sheet of the polyolefin foam according to claim 5.
The thickness of the polyolefin foam sheet is 500 μm to 3000 μm.
The bottom on which food is placed and
A packaging material for food products, which comprises a side wall portion provided continuously upward from the outer peripheral edge of the bottom portion.
JP2020063981A 2020-03-31 2020-03-31 Method for producing polyolefin foam, method for producing packaging material for packaging, polyolefin foam, and packaging material for food product packaging Pending JP2021161236A (en)

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