JP2021031416A - Labial cosmetic - Google Patents

Abstract

To provide a labial cosmetic that is excellent in mat appearance, mat finish, stability and lasting moist feeling.SOLUTION: A labial cosmetic contains following components (A)-(C): (A) wax, (B) partially-crosslinked polyether-modified silicone and/or partially-crosslinked polyglycerol-modified silicone, (C) polyethylene glycol.

Description

The present invention relates to lip cosmetics.

Lipstick has a cosmetic effect such as giving color to the applied part and giving a gorgeous impression. In recent years, various effects have been required regarding functions such as usability and color development, and various technological developments have been carried out. In addition, not only usability but also appearance aesthetics may be required. For example, there are cases where a matte finish with less gloss is required, and a technology that contains a large amount of powder is known, but although matteness can be realized, there is no moist feeling and lack of uniformity, so the finish is finished. It was sometimes unsustainable. Not limited to lipsticks, various techniques for giving a matte feeling to cosmetics have been studied. For example, a compound selected from an oil-soluble chamomile extract, cartinine, a derivative thereof and a salt thereof, and a liquid oil containing 0.1% by mass or more and 3.5% by mass or less of a liquid oil, and a paste-like or solid oil agent at 25 ° C. A skin external preparation containing a specific ratio of polyalkylene glycol having a number average molecular weight of 600 or more and 200,000 or less. It has excellent stability over time, has an excellent matte finish, reduces stickiness, and has a long-lasting moisturizing feeling. (See Patent Document 1). Also, for example, an anhydrous cream form containing a moisturizer-free oil phase, a non-emulsifying elastic organopolysiloxane, a photoprotective system capable of blocking UV irradiation, a matting agent and a non-silicone organic oil thickener. There is a technique (see Patent Document 2) in which a composition can simultaneously obtain high sun protection, a long-lasting matting effect, and good stability that are easily spread on the skin and are balanced in the UVA and UVB ranges.

Japanese Unexamined Patent Publication No. 2017-81884 Special Table 2014-516998

Although the techniques of Patent Document 1 and Patent Document 2 can give a matte finish with a good usability, there are cases where a matte appearance cannot be obtained. Further, by combining the techniques of the above two documents, it is possible to obtain a cosmetic having a good spreadability, a matte finish, and a long-lasting moisturizing feeling, but in addition to these effects, there are cases where the appearance is not matte. It was difficult to achieve a matte appearance while maintaining a matte finish, stability, and a long-lasting moisturizing feeling. Therefore, an object of the present invention is to provide a lip cosmetic having an excellent appearance matteness, a matte finish, stability and a long-lasting moisturizing feeling.

As a result of diligent research in view of the above circumstances, the present inventor has excellent stability and matte by combining wax, partially crosslinked polyether-modified silicone and / or partially crosslinked polyglycerin-modified silicone, and polyethylene glycol. We found that a smooth finish and a long-lasting moisturizing feeling can be obtained. Surprisingly, these combinations have been found to have a matte appearance by producing fine droplets on the surface of an oily solid and creating irregularities on the surface to diffusely reflect light, leading to the completion of the present invention. It was.

That is, the present invention describes the following components (A) to (C);
It relates to a lip cosmetic containing (A) wax (B) partially crosslinked polyether-modified silicone and / or partially crosslinked polyglycerin-modified silicone (C) polyethylene glycol.

The present invention relates to cosmetics containing component (C) polyethylene glycol as an active ingredient, component (A) wax and component (B) partially crosslinked polyether-modified silicone and / or partially crosslinked polyglycerin-modified silicone. It is about matting agents.

The present invention uses component (C) polyethylene glycol for matting cosmetics containing component (A) wax and component (B) partially crosslinked polyether-modified silicone and / or partially crosslinked polyglycerin-modified silicone. It is about the matting method of cosmetics.

INDUSTRIAL APPLICABILITY According to the present invention, it is possible to provide a lip cosmetic having an excellent appearance matteness, a matte finish, stability, and a long-lasting moisturizing feeling.

Hereinafter, the present invention will be described in detail. In this specification, "~" means a range including numerical values before and after that, and "%" unless otherwise specified means "mass%".

The component (A) wax in the present invention holds an oil agent in the voids of a crystal card house structure formed in a plate shape. The component (A) in the present invention is not particularly limited as long as it is usually used in cosmetics, and any of synthetic hydrocarbons, natural waxes and synthetic waxes may be used. Specifically, paraffin wax, ceresin wax, ozokelite wax, microcrystalline wax, Fishertroph wax, polyethylene wax, ethylene / propylene copolymer, candelilla wax, carnauba wax, beeswax, rice wax, mokuro, gay wax, Examples thereof include dilox, montan wax, stearyl-modified methylpolysiloxane, and behenyl-modified methylpolysiloxane, and one or more of these can be used. Among these, synthetic hydrocarbons or synthetic waxes are preferable from the viewpoint of stability, and specifically, paraffin wax, selecin wax, ozokelite wax, microcrystallin wax, Fishertropch wax, polyethylene wax, ethylene / propylene copolymer. One or more selected from the group consisting of is preferable. Further, among them, one or two selected from the group consisting of Fischer-Tropsch wax and ethylene / propylene copolymer is more preferable.

The content of the component (A) in the present invention is not particularly limited, but the lower limit is preferably 5%, more preferably 7%, and even more preferably 9%. The upper limit is preferably 20%, more preferably 17%, even more preferably 15%, and even more preferably 12%. This range is more preferable because it is more excellent in stability and sustainability of moisturizing feeling.

The component (B) partially crosslinked polyether-modified silicone and / or partially crosslinked polyglycerin-modified silicone in the present invention is obtained by cross-linking an organopolysiloxane and has a partially three-dimensional cross-linked structure in the molecule. It is a polymer containing an oxyalkylene group or a polyglycerin group. Specifically, but not particularly limited, partially crosslinked polyether-modified silicone, partially crosslinked alkyl / polyether-modified silicone, partially crosslinked silicone / alkyl / polyether-modified silicone, partially crosslinked polyglycerin-modified silicone, partially crosslinked. Examples thereof include type alkyl / polyglycerin-modified silicone, partially crosslinked silicone / alkyl / polyglycerin-modified silicone, and one or more of these can be used. For example, the partially crosslinked polyether-modified silicone may be represented by an INCI name (International Nomenclature Cosmetic Ingredient labeling names): (dimethicone / (PEG-10 / 15)) crosspolymer, (PEG-10 / lauryldimethicone) crosspolymer. , (PEG-15 / lauryldimethicone) crosspolymer, (PEG-15 / laurylpolydimethylsiloxyethyldimethicone) crosspolymer and the like. Examples of the partially crosslinked polyglycerin-modified silicone include (dimethicone / polyglycerin-3) crosspolymer, (lauryldimethicone / polyglycerin-3) crosspolymer, (polyglyceryl-3 / laurylpolydimethylsiloxyethyl dimethicone) crosspolymer, and the like. Can be mentioned. The component (B) in the present invention can be contained in a solid state at 25 ° C. and normal pressure, but is preferable in that it is more uniformly dispersed when swollen with an oil agent. Some of the component (B) in the present invention is commercially available as a mixture with an oil agent, and in the present invention, this commercially available component (B) can also be used. Commercially available products include KSG-210, KSG-240, KSG-310, KSG-320, KSG-330, KSG-340, KSG-320Z, KSG-350Z, KSG-360Z, KSG-380Z, KSG-710, KSG. -810, KSG-820, KSG-830, KSG-840, KSG-820Z, KSG-850Z (all manufactured by Shin-Etsu Chemical Co., Ltd.) and the like can be mentioned.

The content of the component (B) in the present invention is not particularly limited, but the lower limit is preferably 0.3%, more preferably 0.8%, and even more preferably 1.3%. The upper limit is preferably 6%, more preferably 4%, and even more preferably 2%. In the present invention, it is preferable that the solid content is the above-mentioned content, but even when the solid content is swollen in an oil agent and used, the solid content is preferably in the range of the above-mentioned content. This range is more preferable because it is superior in stability and matte finish.

The component (C) polyethylene glycol in the present invention is a polymer compound having a structure in which ethylene glycol is polymerized. The polyethylene glycol of the present invention is not particularly limited as long as it is usually used for cosmetics, and examples thereof include polyethylene glycol having a number average molecular weight of 300 to 6000. The number average molecular weight is measured by the average molecular weight test described in the quasi-drug raw material standard, by the terminal group quantification method, specifically by the hydroxyl value obtained by titration. In the present invention, the number average molecular weight of polyethylene glycol is preferably a lower limit of 200, more preferably 300, and even more preferably 400. The upper limit is preferably 6000, more preferably 2000, and even more preferably 1600. This range is more preferable because it is more excellent in stability and sustainability of moisturizing feeling.

The content of the component (C) in the present invention is not particularly limited, but the lower limit is preferably 0.5%, more preferably 0.8%, and even more preferably 1.2%. The upper limit is preferably 10%, more preferably 5%, and even more preferably 3.5%. This range is more preferable because it is superior in appearance matteness, stability, and long-lasting moisturizing feeling.

In the present invention, although it can be obtained by appropriately containing the component (B) and the component (C), it is preferable because a higher effect can be expected by specifying the mass ratio of the components (B) and the component (C). Such a mass ratio is not particularly limited, and the lower limit of the content mass ratio (B) / (C) of the component (B) and the component (C) is preferably 0.3 or more, more preferably 1 or more, and 2 The above is more preferable, and the upper limit value is preferably 20 or less, more preferably 15 or less, and further preferably 10 or less. This range is more preferable because it has a matte finish and is more stable.

Further, the present invention can contain an oil agent having an IOB value of less than 0.24, which is a liquid component (D) at 25 ° C. Here, the IOB represents the ratio of the inorganic value and the organic value (Inorganic Organic Balance) obtained based on the organic conceptual diagram, and is obtained by the following equation.
IOB = Inorganic / Organic Value The component (D) in the present invention is not particularly limited as long as the IOB value is less than 0.24, and is not particularly limited, for example, liquid paraffin (IOB value 0) and isotridecyl isononanoate (IOB value). 0.16), cetyl ethylhexanoate (IOB value 0.13), polyglyceryl-2 tetraisostearate (IOB value 0.17), decyltetradecanol (IOB value 0.21), pentaerythrityl tetraisostearate (IOB value 0.21) IOB value 0.16), triisosteare (IOB value 0.16), avocado oil (IOB value 0.13), macadamia nut oil (IOB value 0.16), jojoba oil (IOB value 0.07), squalane (IOB value 0.07) Values 0), etc. can be mentioned. These oils can be used alone or in combination of two or more, if necessary, and among them, one or two or more selected from liquid paraffin, isotridecyl isononanoate, and decyltetradecanol are used for appearance. It is more preferable because it is superior in matteness.

The content of the component (D) in the present invention is not particularly limited, but the lower limit is preferably 5%, more preferably 10%, further preferably 20%, and even more preferably 30%. The upper limit is preferably 60%, more preferably 55%, even more preferably 50%, even more preferably 45%. This range is more preferable because it is more excellent in mattness and stability of appearance.

In the present invention, although it can be obtained by appropriately containing the component (D) and the component (C), it is preferable because a higher effect can be expected by specifying the mass ratio of the components (D) and the component (C). Such a mass ratio is not particularly limited, and the lower limit of the content mass ratio (D) / (C) of the component (D) and the component (C) is preferably 3 or more, more preferably 4 or more, and 5 or more. Further, the upper limit value is preferably 100 or less, more preferably 80 or less, further preferably 60 or less, and even more preferably 40 or less. This range is more preferable because it is more excellent in appearance matteness, matte finish, and stability.

Further, the present invention can contain one or more inorganic powders selected from the group consisting of the component (E) calcium carbonate, barium sulfate, and sericite. The component (E) used in the present invention is not particularly limited as long as it is usually used in cosmetics. Further, in the present invention, the component (E) may be subjected to surface treatment or the like, and the surface treatment agent is not particularly limited as long as it is usually used for cosmetics, and is a fluorine compound, a silicone compound, or a hydrocarbon. , Higher fatty acids, higher alcohols, metal soaps, surfactants, water-soluble polymers and the like, which are generally known, can be used. The shape of the component (E) in the present invention is not particularly limited, and examples thereof include a plate shape, a spherical shape, and an amorphous shape. Among these, calcium carbonate and / or barium sulfate is preferable, and calcium carbonate and barium sulfate are more preferable in combination.

The content of the component (E) in the present invention is not particularly limited, but the lower limit is preferably 0.1%, more preferably 0.3%, and even more preferably 0.5%. The upper limit is preferably 10%, more preferably 8%, even more preferably 5%, even more preferably 3%. Within this range, a matte finish and a long-lasting moisturizing feeling are more excellent, which is more preferable.

In addition to the above-mentioned ingredients (A) to (E), the lip cosmetic of the present invention can contain ingredients usually used in cosmetics as long as the effects of the present invention are not impaired. For example, oily components other than components (A), (B) and (D), powders other than component (E), surfactants, fibers, aqueous components other than component (C), ultraviolet absorbers, anti-fading agents, oxidation. Examples include inhibitors, antifoaming agents, beauty ingredients, preservatives, fragrances and the like.

The component (C) polyethylene glycol of the present invention can be used as a method for matting in cosmetics containing the component (A) wax and the component (B) partially crosslinked polyether-modified silicone and / or partially crosslinked polyglycerin-modified silicone. Can be used. In addition, polyethylene glycol of component (C) can be provided for matting cosmetics containing the component (A) and the component (B).

Further, the cosmetic in the method of matting can contain an oil agent having an IOB value of less than 0.24, which is liquid at the component (D) of 25 ° C. Further, the cosmetic in the matting method can contain one or more inorganic powders selected from the group consisting of the component (E) calcium carbonate, barium sulfate, and sericite.

In addition, in order to produce a matting agent or cosmetic for cosmetics containing the component (A) wax and the component (B) partially crosslinked polyether-modified silicone and / or partially crosslinked polyglycerin-modified silicone, the component (C) ) Polyethylene glycol can be used.

The lip cosmetic of the present invention can be obtained by a generally known production method. An example of the manufacturing method is shown below, but the method is not limited thereto. For example, the components (A) to (D) can be obtained by heating and dissolving at 110 ° C., adding the component (E) and other components, filling the container, and molding if necessary.

The use of the matting agent or the matting method of the present invention is not particularly limited as long as it is a cosmetic, but it is particularly preferable to use it for lip cosmetics. Further, when the matte agent of the present invention is used in a cosmetic, an appropriately acceptable component may be contained, and the matte agent of the present invention may be contained at the time of producing the cosmetic.

The dosage form of the lip cosmetic of the present invention is not particularly limited, and examples thereof include oil-based, water-in-oil, emulsified types such as oil in water, and in particular, oil-based or water-in-oil because it is superior in makeup retention. It is preferable, and more preferably oily. Here, the oiliness means that the oil is in a continuous phase and does not substantially contain water. Here, substantially not contained means that it is not contained at all, or even if it is contained, the amount is so small that it does not affect the present invention, and the content is, for example, 5%. Less than, more preferably less than 1%, even more preferably less than 0.1%.

The lip cosmetic of the present invention is not particularly limited as long as it is used for lips, and examples thereof include lipstick, lip gloss, lipstick base coat, and lipstick overcoat.

Hereinafter, the present invention will be described in more detail with reference to examples. It should be noted that these do not limit the present invention in any way.

Example 1 (Products 1 to 28 of the present invention) and Comparative Examples (Comparative products 1 to 5): Lip cosmetics (oil-based solid stick)
The lip cosmetics obtained by the compositions and manufacturing methods shown in Tables 1 to 3 are subjected to (a) matte appearance, (b) matte finish, (c) stability over time, and (d) by the methods shown below. ) We evaluated the persistence of moisturizing feeling. The results are also shown in Tables 1 to 3.

* 1: KSG-310 (solid content 30%) (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 2: KSG-710 (solid content 25%) (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 3: KSG-16 (solid content 25%) (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 4: Red No. 202: Yellow No. 4: Treated with isopropyl titanium triisostearate Titanium dioxide: Black Iron oxide = 6: 6: 10: 1 premixed

(Production method)
A. Ingredients (1) to (16) are uniformly mixed and dissolved at 110 ° C.
B. Ingredients (17) to (21) are added to A, and the mixture is uniformly mixed and dispersed.
C. B is uniformly mixed at 90 ° C., filled in a stick-shaped container, and cooled to room temperature.

(Evaluation method 1)
For the following evaluation items (a), (b), and (d), a usage test was conducted by 20 specialist panels using each sample. Regarding the evaluation item (a), each panel member delivered the oil-based solid stick-shaped lip cosmetic obtained in the comparative example of Examples, and looked at the side surface to determine whether or not it was glossy. For evaluation items (b) and (2), each panel person applies each sample to the lips, and for (b), evaluate whether the cosmetic film is finished on a mat immediately after application, and look in the mirror. Those who did not feel gloss when shaking their face from side to side were considered good, and for (d), after applying the comparative example of the example, they were asked to live a normal life, and after 6 hours, the feeling of moisture continued. Those were considered to be good, and were judged according to the following criteria.

<Evaluation items>
(B) Matte appearance (B) Matte finish (2) Sustaining moisturizing feeling

<Criteria>
(Judgment): (Evaluation)
A: 16 or more out of 20 responded that it was good B: 11 or more and 15 or less out of 20 answered that it was good C: 6 or more and 10 or less out of 20 answered that it was good D: 20 out of 20 5 or less answered that it was good

(Evaluation method 2)
Regarding the evaluation item (c), the stability of each sample when it was filled in a stick-shaped container and then allowed to stand in a constant temperature bath at 50 ° C. for 1 week was evaluated. The sample was taken out from the 50 ° C. constant temperature bath and allowed to stand in the 30 ° C. constant temperature bath for 12 hours, and then the sample immediately after being taken out from the 30 ° C. constant temperature bath was subjected to a sensory test at room temperature (25 ° C.). We asked 20 specialist panels to use each sample and compare the difference in usability with the samples of the same formulation and manufacturing method that were allowed to stand at room temperature for one week. For each sample, ask them to compare whether the sample becomes hard and stretches poorly at the time of application, or the sample becomes soft and the feeling of use is different, and ask them to answer whether it has changed or not, and the change has occurred. The results of the use test were used as the evaluation of high temperature stability according to the number of responses.
<Criteria>
(Judgment): (Evaluation)
A: 16 or more out of 20 responded that they did not change B: 11 or more and 15 or less out of 20 responded that they did not change C: 6 or more and 10 or less out of 20 responded that they did not change Answered that there was no change D: 5 out of 20 responded that there was no change

From Tables 1 to 3, the examples were excellent in all evaluation items such as matte appearance, matte finish, stability over time, and persistence of moisturizing feeling. On the other hand, the comparative product 1 in which the component (A) is replaced with hydroxystearic acid is not satisfactory in terms of matte finish and stability, and the comparative product 2 containing no component (B) has a matte appearance and a matte appearance. The finish and stability were not satisfactory, and the comparative product 3 in which the component (B) was replaced with a (dimethicone / vinyldimethicone) crosspolymer mixture was not satisfactory in stability and contained the component (C). Comparative product 4 is not satisfactory in appearance matteness and long-lasting moisturizing feeling, and comparative product 5 in which component (C) is replaced with 1,3 butylene glycol is satisfied in appearance matteness and long-lasting moisturizing feeling. It wasn't a good thing.

Example 2 Lip essence (underwater oil type)
(Ingredient) (%)
1. 1. (PEG-15 / Lauryl Dimethicone)
Cross-polymer mixture * 1 10
2. (Dimethicone / Vinyl Dimethicone)
Cross-polymer mixture * 3 5
3. 3. Pentaerythrityl tetraisostearate
(IOB = 0.16) 5
4. (Ethylene / propylene) copolymer
(Melting point 90-99 ° C) 1
5. Stearic acid 1
6. Sucrose fatty acid ester 0.5
7. Setostearyl alcohol 0.3
8. Behenyl alcohol 0.2
9. Polyoxyethylene sorbitan monooleate
(20EO) 0.8
10. Phytosteryl oleate 0.1
11. Ethyl oleate 0.1
12. Linoleic acid 0.1
13. Lecithin 2% treated sericite 0.2
14. Remaining amount of purified water 15. Dipropylene glycol 10
16. Polyethylene glycol 1500 5
17. Rosemary extract 0.1
18. Sodium hyaluronate 0.1
19. Hydrolyzed collagen 0.01
20. Edelweiss extract 0.01
21. Peony extract 0.01
22. Ascorbic acid glucoside 0.005
23. Niacinamide 6
24. Rice fermented liquid 0.005
25. Keiketto extract 0.01
26. Ogon extract 0.01
27. Birch bark extract 0.01
28. Tranexamic acid 1
29. Jujube extract 0.01
30. (PEG-240 / decyltetradeceth-20
/ HDI) Copolymer 0.03
31. Glycerin 8
32. Maltose 0.005
33. Orange flower water 15
34. Alkyl acrylate / Vinyl acetate
Copolymer emulsion 5
35. Alkyl acrylate copolymer emulsion 2
36. Humus extract 0.01
(Production method)
A: The components (1) to (12) are uniformly dissolved at 100 to 110 ° C.
B: Ingredients (13) to (36) are uniformly mixed at 80 ° C.
C: Add B to A and emulsify uniformly at 80 ° C.
D: The container was filled to obtain lip essence.
The lip essence of Example 2 was excellent in all evaluation items such as matte appearance, matte finish, stability, and long-lasting moisturizing feeling.

Example 3 Lipstick overcoat (water-in-oil type)
(Ingredient) (%)
1. 1. Fischer-Tropsch Wax * 5 5
2. (Ethylene / propylene) copolymer
(Melting point 90-99 ° C) 1
3. 3. Microcrystalline wax (melting point 84 ° C) 4
4. Isotridecyl isononanoate (IOB value 0.16) 10
5. Octyldodecanol (IOB = 0.26) 15
6. Vaseline (IOB = 0) 10
7. Polyethylene glycol 400 2
8. (PEG-15 / Lauryl Dimethicone)
Cross-polymer mixture * 1 3
9. Di (phytosteryl / octyldodecyl) lauroyl glutamate * 6 (IOB = 0.3) 3
10. Cyrilization treatment Siliconic anhydride * 7 2
11. Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) * 8 5
12. Diisostearyl malate (IOB = 0.28) 5
13. Polyglyceryl triisostearate-2
(IOB = 0.26) Remaining amount 14. Trimethylsiloxysilicic acid 2
15. PEG-9 Polydimethylsiloxyethyl Dimethicone 0.3
16. Lauryl polyglyceryl-3
Polydimethylsiloxyethyl dimethicone 0.1
17. Cyclohexanedicarboxylic acid bisethoxydiglycol 0.5
18. (Caprylic acid / caprylic acid / myristic acid / stearic acid) Triglyceryl 2
19. Purified water 10
20.1,3-butylene glycol 1
21. Glycerin 4
22. Calcium carbonate 2
23. (Diphenyldimethicone / Vinyldiphenyldimethicone / Sylsesquioxane) Crosspolymer * 9 1
24. Polyethylene terephthalate powder
(Average particle size 7 μm) 1
25. Titanium oxide coated borosilicate (Ca / Al) 1
26. Red No. 226 0.5
27. 2% lecithin treated titanium dioxide
(Average particle size 0.25 μm) 0.5
28. Black iron oxide 0.1
29. Mica titanium 0.1
30. Honey 0.1
* 5: CIREBELLE 108 (melting point 79-84 ° C, manufactured by CIREBELLE)
* 6: Eldu PS-203 (manufactured by Ajinomoto Co., Inc.)
* 7: AEROSIL R976-S (manufactured by Aerosil Japan)
* 8: PLANDOOL-H (manufactured by Nippon Fine Chemical Co., Ltd.)
* 9: KSP-300 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Production method)
A: The components (1) to (18) are uniformly dissolved at 100 to 110 ° C.
B: Ingredients (22) to (30) are added to A and uniformly mixed and dispersed.
C: Ingredients (19) to (21) are uniformly mixed at room temperature. C is added to D: B and emulsified at room temperature.
After defoaming E: D, it was heated to 90 ° C. and poured directly into a container, cooled to room temperature, and then a lipstick overcoat was obtained.
The lipstick overcoat of Example 3 was excellent in all evaluation items such as matte appearance, matte finish, stability, and long-lasting moisturizing feeling.

Example 4 Oil-based liquid rouge (ingredient) (%)
1. 1. Fischer-Tropsch Wax * 10 3
2. (Ethylene / propylene) copolymer
(Melting point 90-99 ° C) 2
3. 3. Candelilla wax (melting point 70-75 ° C) 1
4. Decyltetradecanol 10
5. Heavy liquid isoparaffin * 11 (IOB = 0) 1
6. Di (octyldodecyl / phytosteryl / behenyl) lauroyl glutamate * 12 (IOB = 0.3) 15
7. Dimethylpolysiloxane (IOB = 0.27) 5
8. Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) * 8 10
9. Vaseline 10
10. Polyglyceryl triisostearate-2 Remaining amount 11. Polyethylene glycol 1500 5
12. (Dimethicone / (PEG-10 / 15)
Cross polymer mixture * 137
13. Dextrin palmitate * 14 1.5
14. Methyl paraoxybenzoate 0.1
15. Zinc oxide (average particle size 0.3 μm) 1
16. Nylon-12 * 155
17. Titanium oxide coated borosilicate (Ca / Al) * 165
18. Rosemary extract 0.1
19. Purified water 0.1
20. Tripropylene glycol 2
21. Pigment premixture * 4 1.5
22. Isododecane 6
23. Dimethylpolysiloxane (25 ° C. kinematic viscosity 2CS) 3
24. Methyltrimethicone 0.5
* 10: CIREBELLE109 (melting point 91-96 ° C, manufactured by CIREBELLE)
* 11: Pearl Dream 46 (manufactured by Oil and Fat Industry Co., Ltd.)
* 12: Eldu PS-306 (manufactured by Ajinomoto Co., Inc.)
* 13: KSG-210 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 14: Leopard KL2 (manufactured by Chiba Flour Milling Co., Ltd.)
* 15: Organ sole 2002D (manufactured by Atofina Japan)
* 16: Microglass Metashine MT1080RB (manufactured by Nippon Sheet Glass Co., Ltd.)
(Production method)
A: The components (1) to (13) are uniformly dissolved at 100 to 110 ° C.
B: Ingredients (14) to (21) are added to A, and the mixture is uniformly mixed and dispersed.
C: Add components (22) to (24) to B, mix uniformly and defoam.
D: C was heated to 90 ° C. and poured into a container, cooled to room temperature, and then a liquid rouge was obtained.
The liquid rouge of Example 4 was excellent in all evaluation items such as matte appearance, matte finish, stability, and long-lasting moisturizing feeling.

Example 5 Lipstick (oil-based solid type) dish container component (%)
1. 1. (Ethylene / propylene) copolymer 2
2. Polyethylene wax (melting point 83-92 ° C) 1
3. 3. Celesin wax (melting point 76-82 ° C) 1
4. Paraffin 2
5. (Dimethicone / Polyglycerin-3)
Cross polymer * 2 5
6. Isotridecyl isononanoate 25
7.2-Cetyl ethylhexanoate (IOB = 0.13) 5
8. Polyglyceryl triisostearate-2 Remaining amount 9. Heavy liquid isoparaffin * 115
10. Hexa (hydroxystearic acid / stearic acid / rosin acid)
Dipentaerythrityl * 17 (IOB = 0.3) 5
11. Tritridecyl trimeritate (IOB = 0.28) 5
12. Polyethylene glycol 6000 1
13. Polyethylene glycol 400 5
12.2,6-Di-tert-butyl-para-cresol 0.1
13. Methyl paraoxybenzoate 0.1
14. Cyrilization treatment Siliconic anhydride * 7 1
15.2% Silicone treated talc (average particle 5 μm) 1.5
16. Polymethyl methacrylate * 18 2
17. Red No. 202 0.1
18. Barium sulfate (plate shape, average particle size 7 μm) 0.1
19. Water- and oil-repellent treatment Bengala-coated mica titanium * 195
20. Titanium oxide coated synthetic phlogopite (average particle size 13 μm) 0.3
21. Rosemary extract 0.1
22.1,2-Pentanediol 0.1
23. (Acrylate / ethylhexyl acrylate)
/ Dimethicone methacrylate) Copolymer 0.2
24. Polyquaternium-104 0.3
25. Avocado oil 0.1
26. Macademia nut oil 0.1
27. Jojoba oil 0.1
28. Squalene 0.1
29. (Vinylpyrrolidone / Hexadecene) Copolymer 0.5
* 17: Cosmall 168ARV (manufactured by Nisshin Oillio Group)
* 18: Ganz Pearl GM-2800 (manufactured by Aica Kogyo Co., Ltd.)
* 19: Cloisoner Rouge flambe (manufactured by BASF) 2% perfluorohexylethyltriethoxysilane (manufacturing method)
A. Ingredients (1) to (12) are uniformly dissolved at 100 to 110 ° C.
B. Ingredients (13) to (29) are added to A, and the mixture is uniformly mixed and dispersed.
C. After defoaming B, it was heated to 100 ° C. and poured directly into a gold plate-shaped lipstick container, cooled to room temperature, and then lipstick was obtained.
The lipstick of Example 5 was excellent in all evaluation items such as matte appearance, matte finish, stability, and long-lasting moisturizing feeling.

Claims (9)

The following components (A) to (C);
A lip cosmetic containing (A) wax (B) partially crosslinked polyether-modified silicone and / or partially crosslinked polyglycerin-modified silicone (C) polyethylene glycol. The lip cosmetic according to claim 1, wherein the component (C) has a number average molecular weight of 300 to 2000. The lip cosmetic according to claim 1 or 2, further comprising an oil agent (D) liquid at 25 ° C. and having an IOB value of less than 0.24. The lip cosmetic according to any one of claims 1 to 3, further comprising one or more inorganic powders selected from the group consisting of the component (E) calcium carbonate, barium sulfate, and sericite. The lip cosmetic according to any one of claims 1 to 4, wherein the mass content ratio (B) / (C) of the component (B) and the component (C) is 0.3 or more and 20 or less. The lip cosmetic according to any one of claims 3 to 5, wherein the component (D) and the component (C) mass content ratio (D) / (C) are 3 or more and 100 or less. The lip cosmetic according to any one of claims 1 to 6, which is an oil-based cosmetic. A matting agent in cosmetics containing wax and partially crosslinked polyether-modified silicone and / or partially crosslinked polyglycerin-modified silicone containing polyethylene glycol as an active ingredient. Matte of cosmetics using component (C) polyethylene glycol for matting component (A) wax and component (B) partially cross-linked polyether-modified silicone and / or partially cross-linked polyglycerin-modified silicone. Method.