JP2021031410A - Hair cosmetic - Google Patents
Hair cosmetic Download PDFInfo
- Publication number
- JP2021031410A JP2021031410A JP2019150093A JP2019150093A JP2021031410A JP 2021031410 A JP2021031410 A JP 2021031410A JP 2019150093 A JP2019150093 A JP 2019150093A JP 2019150093 A JP2019150093 A JP 2019150093A JP 2021031410 A JP2021031410 A JP 2021031410A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- oil
- mass
- component
- modified silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 18
- -1 alkyl quaternary ammonium salt Chemical class 0.000 claims abstract description 37
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 37
- 239000010696 ester oil Substances 0.000 claims abstract description 6
- 239000003676 hair preparation Substances 0.000 description 15
- 239000004615 ingredient Substances 0.000 description 11
- 238000002156 mixing Methods 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 239000002736 nonionic surfactant Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 125000004122 cyclic group Chemical group 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 3
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 3
- 229940075506 behentrimonium chloride Drugs 0.000 description 3
- 229920006317 cationic polymer Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- NCLNAHJFXIKYBY-UHFFFAOYSA-N 2-hexyldecyl 16-methylheptadecanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C NCLNAHJFXIKYBY-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000013523 DOWSIL™ Substances 0.000 description 2
- 229920013731 Dowsil Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- OQILCOQZDHPEAZ-UHFFFAOYSA-N Palmitinsaeure-octylester Natural products CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 2
- DRRMRHKHTQRWMB-UHFFFAOYSA-N [3-(2-ethylhexanoyloxy)-2,2-bis(2-ethylhexanoyloxymethyl)propyl] 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(COC(=O)C(CC)CCCC)(COC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DRRMRHKHTQRWMB-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- KWABLUYIOFEZOY-UHFFFAOYSA-N dioctyl butanedioate Chemical compound CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC KWABLUYIOFEZOY-UHFFFAOYSA-N 0.000 description 2
- GJQLBGWSDGMZKM-UHFFFAOYSA-N ethylhexyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(CC)CCCCC GJQLBGWSDGMZKM-UHFFFAOYSA-N 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000037308 hair color Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 229940119170 jojoba wax Drugs 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- GLXBPZNFNSLJBS-UHFFFAOYSA-N 11-methyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCCCCC(C)C GLXBPZNFNSLJBS-UHFFFAOYSA-N 0.000 description 1
- ABEXEQSGABRUHS-UHFFFAOYSA-N 16-methylheptadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC(C)C ABEXEQSGABRUHS-UHFFFAOYSA-N 0.000 description 1
- WGKHLTQBAAWSSR-UHFFFAOYSA-N 16-methylheptadecyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCCCCCCCCCCCCCCCC(C)C WGKHLTQBAAWSSR-UHFFFAOYSA-N 0.000 description 1
- WPIOBXGJZUSKGK-UHFFFAOYSA-N 16-methylheptadecyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC(C)C WPIOBXGJZUSKGK-UHFFFAOYSA-N 0.000 description 1
- SAMYFBLRCRWESN-UHFFFAOYSA-N 16-methylheptadecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC(C)C SAMYFBLRCRWESN-UHFFFAOYSA-N 0.000 description 1
- XFBOJHLYDJZYSP-UHFFFAOYSA-N 2,8-dioxoadenine Chemical compound N1C(=O)N=C2NC(=O)NC2=C1N XFBOJHLYDJZYSP-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- NAGVKZOTMXGCCA-UHFFFAOYSA-N 2-ethylhexyl 7-methyloctanoate Chemical compound CCCCC(CC)COC(=O)CCCCCC(C)C NAGVKZOTMXGCCA-UHFFFAOYSA-N 0.000 description 1
- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 description 1
- VDHIEQOYPSVNIM-UHFFFAOYSA-N 2-hexyldecyl 2-ethylhexanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)C(CC)CCCC VDHIEQOYPSVNIM-UHFFFAOYSA-N 0.000 description 1
- OGJDIJKJFYOENF-UHFFFAOYSA-N 2-hexyldecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC OGJDIJKJFYOENF-UHFFFAOYSA-N 0.000 description 1
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 1
- QNJOVLAFLJQFBF-UHFFFAOYSA-N 2-octyldodecyl 16-methylheptadecanoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C QNJOVLAFLJQFBF-UHFFFAOYSA-N 0.000 description 1
- OYRKAUXRSTZVFT-UHFFFAOYSA-N 2-octyldodecyl 2,2-dimethyloctanoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)C(C)(C)CCCCCC OYRKAUXRSTZVFT-UHFFFAOYSA-N 0.000 description 1
- PTPDZZWUOHQSLG-UHFFFAOYSA-N 2-octyldodecyl 2,2-dimethylpropanoate Chemical compound CCCCCCCCCCC(COC(=O)C(C)(C)C)CCCCCCCC PTPDZZWUOHQSLG-UHFFFAOYSA-N 0.000 description 1
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- ODMZDMMTKHXXKA-QXMHVHEDSA-N 8-methylnonyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCCCCCC(C)C ODMZDMMTKHXXKA-QXMHVHEDSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 235000019489 Almond oil Nutrition 0.000 description 1
- 229920006310 Asahi-Kasei Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 1
- 241001135917 Vitellaria paradoxa Species 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940092738 beeswax Drugs 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 229940082483 carnauba wax Drugs 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229960002788 cetrimonium chloride Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- DMMXZLMYEUEJFT-UHFFFAOYSA-N ethyl 16-methylheptadecanoate Chemical compound CCOC(=O)CCCCCCCCCCCCCCC(C)C DMMXZLMYEUEJFT-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000008169 grapeseed oil Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- FPMPNVIMFPEKRN-UHFFFAOYSA-N hexyl 16-methylheptadecanoate Chemical compound CCCCCCOC(=O)CCCCCCCCCCCCCCC(C)C FPMPNVIMFPEKRN-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229940100554 isononyl isononanoate Drugs 0.000 description 1
- 229940093629 isopropyl isostearate Drugs 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940060384 isostearyl isostearate Drugs 0.000 description 1
- 229940113915 isostearyl palmitate Drugs 0.000 description 1
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- 229940039717 lanolin Drugs 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- PIUVNPNBPWVVKZ-UHFFFAOYSA-N octadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC PIUVNPNBPWVVKZ-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- XEIOPEQGDSYOIH-MURFETPASA-N propan-2-yl (9z,12z)-octadeca-9,12-dienoate Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(=O)OC(C)C XEIOPEQGDSYOIH-MURFETPASA-N 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
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- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、毛髪化粧料に関する。 The present invention relates to hair cosmetics.
毛髪は、紫外線、ドライヤーの熱、ブラッシング、洗髪などの影響によって損傷し、指通りが悪化しやすい。さらに近年、パーマやヘアカラー、ブリーチなどの利用が一般化する反面、これらの化学処理に伴うパサつきやハリの低下などの毛髪のダメージも問題となっている。従来から、毛髪のダメージを抑制し、毛髪の感触を向上させるために、様々な毛髪化粧料が開示されている（特許文献１、特許文献２）。
毛髪にハリ・コシやまとまり感を与える技術は年々進歩しているものの、より良好な効果を有する毛髪化粧料及びより使用感の良い毛髪化粧料が求められており、更なる進歩が望まれている。
Hair is damaged by the effects of ultraviolet rays, heat from a dryer, brushing, washing hair, etc., and finger passage tends to deteriorate. Furthermore, in recent years, while the use of perms, hair colors, bleaches, etc. has become common, hair damage such as dryness and reduced firmness due to these chemical treatments has also become a problem. Conventionally, various hair cosmetics have been disclosed in order to suppress damage to hair and improve the feel of hair (Patent Documents 1 and 2).
Although the technology for giving hair firmness and cohesiveness is advancing year by year, there is a demand for hair cosmetics with better effects and hair cosmetics with better usability, and further progress is desired. There is.
本発明は、毛髪の指通り、ハリ・コシ及びまとまり感が良好な毛髪化粧料を提供することを課題とする。 An object of the present invention is to provide a hair cosmetic having good finger passage, elasticity and cohesiveness of hair.
本発明は、下記（Ａ）〜（Ｃ）を含有する毛髪化粧料を提供する。
（Ａ）アミノ変性シリコーン
（Ｂ）モノ又はジ長鎖アルキル４級アンモニウム塩
（Ｃ）分岐構造を有するエステル油
The present invention provides a hair cosmetic containing the following (A) to (C).
(A) Amino-modified silicone (B) Mono or di-long chain alkyl quaternary ammonium salt (C) Ester oil having a branched structure
本発明によると、毛髪のすすぎ時やウェット時、乾燥後の指通りが良好で、ハリ・コシ及びまとまり感が良好である毛髪化粧料を提供することができる。 According to the present invention, it is possible to provide a hair cosmetic that has good finger passage during rinsing, wetness, and drying of hair, and has good firmness, elasticity, and cohesiveness.
本発明で用いられる成分（Ａ）アミノ変性シリコーンは、アミノ基又はアンモニウム基を有しているシリコーンであればよく、末端水酸基のすべて又は一部がメチル基等で封鎖されたアミノ変性シリコーンオイル、末端が封鎖されていないアモジメチコンのどちらでもよい。例えば、好ましいアミノ変性シリコーンとしては、以下の一般式（１）で表されるものが挙げられる。 The component (A) amino-modified silicone used in the present invention may be any silicone having an amino group or an ammonium group, and is an amino-modified silicone oil in which all or part of the terminal hydroxyl groups are sealed with a methyl group or the like. Either amodimethicone with an unblocked end may be used. For example, preferred amino-modified silicones include those represented by the following general formula (1).
［式中Ｒは水酸基、水素原子又はＲ１を示し、Ｒ１は置換又は非置換の炭素数１〜２０の一価炭化水素基を示し、ＸはＲ１、−Ｑ−ＮＨ（ＣＨ２）ｎＮＨ２、−ＯＲ１又は水酸基を示し、Ｑは炭素数１〜８の二価炭化水素基を示し、ｎは１〜５の数を示し、ｐ及びｑはその和が数平均で２以上２０００未満、好ましくは２０以上２０００未満、さらに好ましくは３０以上１０００未満となる数を示す。］ [In the formula, R represents a hydroxyl group, a hydrogen atom or R 1 , R 1 represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms, and X is R 1 , −Q-NH (CH 2 ). n NH 2 , −OR 1 or a hydroxyl group, Q indicates a divalent hydrocarbon group having 1 to 8 carbon atoms, n indicates a number of 1 to 5, and p and q have a sum of 2 or more on average. Indicates a number of less than 2000, preferably 20 or more and less than 2000, and more preferably 30 or more and less than 1000. ]
本発明の毛髪化粧料において上記アミノ変性シリコーンをそのまま又はエマルションの形で使用してもよい。このアミノ変性シリコーンのエマルションは、例えば、アミノ変性シリコーンと溶媒を高剪断で機械混合したものや、アミノ変性シリコーンを水及び乳化剤で乳化したもの、若しくはこれらの組み合わせによって、又は乳化重合によっても調製することができる。 In the hair cosmetic of the present invention, the amino-modified silicone may be used as it is or in the form of an emulsion. This amino-modified silicone emulsion is prepared, for example, by mechanically mixing an amino-modified silicone and a solvent with high shear, emulsifying an amino-modified silicone with water and an emulsifier, or a combination thereof, or by emulsion polymerization. be able to.
上記アミノ変性シリコーンとして、２−８５６６ Ａｍｉｎｏ Ｆｌｕｉｄ、９６９ Ｅｍｕｌｓｉｏｎ、ＢＹ２２−０７９、ＳＦ ８４５１Ｃ、ＳＦ ８４５２Ｃ、ＳＦ ８４５７Ｃ、ＳＳ−３５５１、ＣＢ−１００２ Ｃｏｎｄｉｔｉｏｎｉｎｇ Ａｇｅｎｔ、ＳＭ８７０２Ｃ、ＳＭ８９０４、ＳＭ８７０４Ｃ（すべてダウ・ケミカル日本株式会社／東レ・ダウコーニング株式会社）、ＫＦ−８００３、ＫＦ−８００４、ＫＦ−８００５、ＫＦ−８６７Ｓ、Ｘ−５２−２２６５（すべて信越化学工業株式会社）、ＢＥＬＳＩＬ（登録商標） ＡＤＭ １６５０、ＢＥＬＳＩＬ（登録商標） ＡＤＭ ６０５７ Ｅ、ＢＥＬＳＩＬ（登録商標） ＡＤＭ ８１０３ Ｅ、ＢＥＬＳＩＬ（登録商標） ＡＤＭ ８１０４ Ｅ（すべて旭化成ワッカーシリコーン株式会社）、ＮＩＫＫＯＬ（登録商標） ＮＥＴ−ＡＳＡ（日光ケミカルズ株式会社）、ＸＦ−４２−Ｂ８９２２、ＸＳ６５−Ｂ６４１３（いずれもモメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社）などが市販されている。 As the amino-modified silicone, 2-8566 Amino Fluid, 969 Emulsion, BY22-079, SF 8451C, SF 8452C, SF 8457C, SS-3551, CB-1002 Conditioning Agent, SM8702C, SM8904, SM8704C (all Dow Chemical Japan Co., Ltd.) Company / Toray Dow Corning Co., Ltd.), KF-8003, KF-8004, KF-8005, KF-867S, X-52-2265 (all Shin-Etsu Chemical Industry Co., Ltd.), BELSIL (registered trademark) ADM 1650, BELSIL ( Registered Trademarks) ADM 6057 E, BELSIL® ADM 8103 E, BELSIL® ADM 8104 E (All Asahi Kasei Wacker Silicone Co., Ltd.), NIKKOL (Registered Trademarks) NET-ASA (Nikko Chemicals Co., Ltd.), XF- 42-B8922, XS65-B6413 (both are Momentive Performance Materials Japan LLC) and the like are commercially available.
成分（Ａ）は、まとまり感を持続的に付与するという観点から、本発明の毛髪化粧料全量に対し、アミノ変性シリコーン純分として、０．０５質量％以上であることが好ましく、０．０７質量％以上であることがより好ましい。また、５質量％以下であることが好ましい。具体的な範囲としては、０．０５〜５質量％の配合量が好ましく、さらに好ましくは０．０７〜５質量％である。配合量が０．０５質量％未満であると、まとまり感の持続性が低下する場合がある。５質量％を超えると、べたつき感が強くなる場合がある。 From the viewpoint of continuously imparting a cohesive feeling, the component (A) preferably has an amino-modified silicone pure content of 0.05% by mass or more, preferably 0.07, based on the total amount of the hair cosmetic of the present invention. It is more preferably mass% or more. Further, it is preferably 5% by mass or less. As a specific range, the blending amount is preferably 0.05 to 5% by mass, and more preferably 0.07 to 5% by mass. If the blending amount is less than 0.05% by mass, the sustainability of the cohesive feeling may decrease. If it exceeds 5% by mass, the sticky feeling may become stronger.
本発明で用いられる成分（Ｂ）モノ又はジ長鎖アルキル４級アンモニウム塩は、例えばセトリモニウムクロリド、ステアルトリモニウムクロリド、ベヘントリモニウムクロリド、ステアラルコニウムクロリド、ベンザルコニウムクロリド、ステアロキシプロピルトリモニウムクロリド、ジアルキル（Ｃ１２−１８）ジモニウムクロリドなどが挙げられる。ステアルトリモニウムクロリド、ベヘントリモニウムクロリド、ステアロキシプロピルトリモニウムクロリド、ジアルキル（Ｃ１２−１８）ジモニウムクロリドを用いることが好ましく、ステアルトリモニウムクロリド、ベヘントリモニウムクロリドを用いることがさらに好ましい。これらは１種を単独で、あるいは２種以上を併用しても良い。 The component (B) mono or dilong-chain alkyl quaternary ammonium salt used in the present invention is, for example, cetrimonium chloride, stealtrimonium chloride, behentrimonium chloride, stearalconium chloride, benzalkonium chloride, stearoxypropyltri. Examples thereof include monium chloride and dialkyl (C12-18) dimonium chloride. It is preferable to use stealtrimonium chloride, behentrimonium chloride, stearoxypropyltrimonium chloride, dialkyl (C12-18) dimonium chloride, and more preferably stealtrimonium chloride and behentrimonium chloride. These may be used alone or in combination of two or more.
成分（Ｂ）は、本発明の毛髪化粧料全量に対し、モノ又はジ長鎖アルキル４級アンモニウム塩純分として、０．５質量％以上であることが好ましく、０．９質量％以上であることがより好ましい。また、７質量％以下であることが好ましく、６質量％以下であることがさらに好ましい。具体的な範囲としては、０．５〜７質量％の配合量が好ましく、０．９〜６質量％が特に好ましい。配合量が０．５質量％未満であると、十分なハリ・コシを得られない場合がある。７質量％を超えると、べたつき感が強くなる場合がある。 The component (B) is preferably 0.5% by mass or more, preferably 0.9% by mass or more, as a pure mono or di-long chain alkyl quaternary ammonium salt with respect to the total amount of the hair cosmetic of the present invention. Is more preferable. Further, it is preferably 7% by mass or less, and more preferably 6% by mass or less. As a specific range, a blending amount of 0.5 to 7% by mass is preferable, and 0.9 to 6% by mass is particularly preferable. If the blending amount is less than 0.5% by mass, sufficient firmness and elasticity may not be obtained. If it exceeds 7% by mass, the sticky feeling may become stronger.
本発明で用いられる成分（Ｃ）分岐構造を有するエステル油はエステルを形成するカルボン酸とアルコールのどちらか一方又は両方が分岐構造を有していればよく、モノエステルのほか原料アルコールの価数により、あるいはカルボン酸の有するカルボキシル基の数によりジエステル、トリエステルなどとしたものを用いてもよい。例えば、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、パルミチン酸エチルへキシル、リノール酸イソプロピル、ラウリン酸イソステアリル、ミリスチン酸イソトリデシル、ミリスチン酸２−ヘキシルデシル、パルミチン酸イソステアリル、ステアリン酸２−エチルへキシル、ステアリン酸２−ヘキシルデシル、オレイン酸イソデシル、オレイン酸２−オクチルドデシル、リシノール酸２−オクチルドデシル、イソステアリン酸エチル、２−エチルヘキサン酸セチル、２−エチルヘキサン酸セトステアリル、２−エチルヘキサン酸ステアリル、イソステアリン酸へキシル、イソステアリン酸イソプロピル、ネオペンタン酸２−オクチルドデシル、２−エチルヘキサン酸２−ヘキシルデシル、２−エチルヘキサン酸イソステアリル、イソノナン酸２−エチルへキシル、イソノナン酸イソノニル、ジメチルオクタン酸２−ヘキシルデシル、ジメチルオクタン酸２−オクチルドデシル、イソパルミチン酸２−エチルへキシル、イソステアリン酸ヘキシルデシル、イソステアリン酸イソステアリル、イソステアリン酸２−オクチルドデシル、コハク酸ジオクチル、テトラエチルヘキサン酸ペンタエリスリチルなどが挙げられる。通常毛髪化粧料に用いられるものであれば、特に限定されないが、パルミチン酸エチルへキシル、イソステアリン酸ヘキシルデシル、コハク酸ジオクチル、テトラエチルヘキサン酸ペンタエリスリチルを用いることが特に好ましい。これら１種を単独で、あるいは２種以上を併用しても良い。 The ester oil having the component (C) branched structure used in the present invention may have a branched structure in either one or both of the carboxylic acid and the alcohol forming the ester, and the valence of the raw material alcohol in addition to the monoester. Depending on the number of carboxyl groups contained in the carboxylic acid, diesters, triesters, and the like may be used. For example, isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate, isopropyl linoleate, isostearyl laurate, isotridecyl myristate, 2-hexyldecyl myristate, isostearyl palmitate, 2-ethylhexyl stearate, stearer. 2-Hexyldecyl acid, isodecyl oleate, 2-octyldodecyl oleate, 2-octyldodecyl ricinoleic acid, ethyl isostearate, cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, stearyl 2-ethylhexanoate, Hexyl isostearate, isopropyl isostearate, 2-octyldodecyl neopentanoate, 2-hexyldecyl 2-ethylhexanoate, isostearyl 2-ethylhexanoate, 2-ethylhexyl isononanoate, isononyl isononanoate, 2 dimethyloctanoic acid -Hexyldecyl, 2-octyldodecyl dimethyloctanoate, 2-ethylhexyl isopalmitate, hexyldecyl isostearate, isostearyl isostearate, 2-octyldodecyl isostearate, dioctyl succinate, pentaerythrityl tetraethylhexanoate, etc. Can be mentioned. It is not particularly limited as long as it is usually used for hair cosmetics, but it is particularly preferable to use ethylhexyl palmitate, hexyldecyl isostearate, dioctyl succinate, and pentaerythrityl tetraethylhexanoate. One of these may be used alone, or two or more thereof may be used in combination.
成分（Ｃ）は、本発明の毛髪化粧料全量に対し、０．５質量％以上であることが好ましく、０．６質量％以上であることがより好ましい。また、１０質量％以下であることが好ましく、８質量％以下であることがより好ましい。具体的な範囲としては、０．５〜１０質量％の配合量が好ましく、０．６〜８質量％の配合量がより好ましい。０．５質量％未満であると、十分なハリ・コシを得られない場合がある。１０質量％を超えると、べたつき感が強くなる場合がある。 The component (C) is preferably 0.5% by mass or more, more preferably 0.6% by mass or more, based on the total amount of the hair cosmetic of the present invention. Further, it is preferably 10% by mass or less, and more preferably 8% by mass or less. As a specific range, a blending amount of 0.5 to 10% by mass is preferable, and a blending amount of 0.6 to 8% by mass is more preferable. If it is less than 0.5% by mass, sufficient elasticity may not be obtained. If it exceeds 10% by mass, the sticky feeling may become stronger.
［その他の任意成分］
本発明の毛髪化粧料は、通常毛髪化粧料に使用できる、成分（Ａ）〜（Ｃ）以外の種々の成分を本発明の効果を損なわない範囲で配合することができる。例えば、成分（Ａ）以外のシリコーン化合物（成分（Ｄ）とする）、ノニオン界面活性剤（成分（Ｅ）とする）、カチオン性高分子（成分（Ｆ）とする）、中和剤（成分（Ｇ）とする）、成分（Ｃ）以外の油脂（成分（Ｈ）とする）、ロウ（成分（Ｉ）とする）、溶媒となる水（成分（Ｊ）とする）等を適宜組み合わせて用いることもできる。
[Other optional ingredients]
The hair cosmetic of the present invention can contain various components other than the components (A) to (C) that can be usually used for hair cosmetics, as long as the effects of the present invention are not impaired. For example, a silicone compound other than the component (A) (referred to as the component (D)), a nonionic surfactant (referred to as the component (E)), a cationic polymer (referred to as the component (F)), and a neutralizing agent (referred to as the component (F)). (G)), fats and oils other than the component (C) (referred to as the component (H)), wax (referred to as the component (I)), water as a solvent (referred to as the component (J)), etc. are appropriately combined. It can also be used.
＜成分（Ｄ）＞
成分（Ｄ）は、シリコーン化合物である。具体的には、ジメチルポリシロキサン、メチルフェニルポリシロキサン、環状シリコーン、アルコール変性シリコーン、アルキル変性シリコーン、ポリエーテルシリコーン、脂肪酸変性ポリシロキサン、脂肪族アルコール変性ポリシロキサン、エポキシ変性シリコーン、フッ素変性シリコーン、などを含み、例えば以下の（ａ）〜（ｇ）等が挙げられる。
<Component (D)>
The component (D) is a silicone compound. Specifically, dimethylpolysiloxane, methylphenylpolysiloxane, cyclic silicone, alcohol-modified silicone, alkyl-modified silicone, polyether silicone, fatty acid-modified polysiloxane, aliphatic alcohol-modified polysiloxane, epoxy-modified silicone, fluorine-modified silicone, etc. For example, the following (a) to (g) and the like can be mentioned.
（ａ）ジメチルポリシロキサン：メチルシロキサン構造を持ち、２５℃における粘度が１〜５０，０００ｍＰａ・ｓである重合度のものが挙げられる。
（ｂ）環状シリコーン：環状のメチルポリシロキサン構造を持つシリコーン油であり、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、環状シリコーン樹脂等が挙げられる。
（ｃ）高重合ジメチルポリシロキサン：メチルシロキサン構造を持ち、２５℃における粘度が５０，０００〜２０，０００，０００ｍＰａ・ｓであるものが挙げられ、高重合ジメチルポリシロキサンを本発明のヘアトリートメント剤に配合する場合、液状油に溶解して配合するか、更にカチオン性界面活性剤やポリオキシエチレンアルキルエーテルなどの非イオン性界面活性剤水溶液中で調製した水性乳濁液を配合することが好ましい。液状油としてはジメチルポリシロキサンや、環状シリコーン又はイソパラフィン系炭化水素等を挙げることができる。
（ｄ）ポリエーテル変性シリコーン：ジメチルシロキサン・メチル（ポリオキシエチレン）シロキサン・メチル（ポリオキシプロピレン）シロキサン共重合体、ジメチルシロキサン・メチル（ポリオキシエチレン）シロキサン共重合体、ジメチルシロキサン・メチル（ポリオキシプロピレン）シロキサン共重合体等が挙げられる。
（ｅ）アルコール変性シリコーン：ジメチルポリシロキサンのメチル基の一部をアルコキシ基に置き換えた構造を有し、ステアロキシメチルポリシロキサン、セトキシメチルポリシロキサン等が挙げられる。
（ｆ）アルキル変性シリコーン：ジメチルポリシロキサンのメチル基の一部を長鎖アルキル基に置き換えた構造を有し、アルキル基の置換率及び大きさにより、液体からワックス状の性状を有するものが挙げられる。
（ｇ）アミノフェニル変性シリコーン：Ｎ−（２−アミノエチル）アミノプロピル基又はＮ−（２−アミノエチル）アミノイソブチル基とフェニル基を持つシリコーン油であり、アミノフェニル変性シリコーンを本発明の毛髪化粧料中に配合する場合、液状油に溶解して配合するか、更にカチオン性界面活性剤やポリオキシエチレンアルキルエーテルなどの非イオン性界面活性剤水溶液中で調製した水性乳濁液を配合することが好ましい。また液状油としてはジメチルポリシロキサンや、環状シリコーン又はイソパラフィン系炭化水素等を挙げることができる。これらのシリコーン誘導体は１種又は２種以上を組み合わせて用いることができる。
(A) Dimethylpolysiloxane: Examples thereof include those having a methylsiloxane structure and a degree of polymerization of 1 to 50,000 mPa · s at 25 ° C.
(B) Cyclic Silicone: A silicone oil having a cyclic methylpolysiloxane structure, and examples thereof include octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and cyclic silicone resin.
(C) Highly Polymerized Didimethylpolysiloxane: Examples thereof include those having a methylsiloxane structure and a viscosity at 25 ° C. of 50,000 to 20,000,000 mPa · s, and the highly polymerized dimethylpolysiloxane is used as the hair treatment agent of the present invention. When blended in, it is preferable to dissolve in liquid oil and blend, or further blend an aqueous emulsion prepared in a nonionic surfactant aqueous solution such as a cationic surfactant or polyoxyethylene alkyl ether. .. Examples of the liquid oil include dimethylpolysiloxane, cyclic silicone, isoparaffinic hydrocarbon, and the like.
(D) Polyether-modified silicone: dimethylsiloxane / methyl (polyoxyethylene) siloxane / methyl (polyoxypropylene) siloxane copolymer, dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymer, dimethylsiloxane / methyl (poly) Oxypropylene) siloxane copolymer and the like can be mentioned.
(E) Alcohol-modified silicone: It has a structure in which a part of the methyl group of dimethylpolysiloxane is replaced with an alkoxy group, and examples thereof include stearoxymethylpolysiloxane and setoxymethylpolysiloxane.
(F) Alkyl-modified silicone: A dimethylpolysiloxane having a structure in which a part of the methyl group is replaced with a long-chain alkyl group, and has a liquid to wax-like property depending on the substitution rate and size of the alkyl group. Be done.
(G) Aminophenyl-modified silicone: A silicone oil having an N- (2-aminoethyl) aminopropyl group or an N- (2-aminoethyl) aminoisobutyl group and a phenyl group, and the aminophenyl-modified silicone is the hair of the present invention. When blended in cosmetics, it is dissolved in liquid oil and blended, or an aqueous emulsion prepared in a nonionic surfactant aqueous solution such as a cationic surfactant or polyoxyethylene alkyl ether is blended. Is preferable. Examples of the liquid oil include dimethylpolysiloxane, cyclic silicone, isoparaffinic hydrocarbon and the like. These silicone derivatives can be used alone or in combination of two or more.
シリコーン化合物を毛髪化粧料に配合する場合、その配合量は、シリコーン化合物総量として０．０１〜２５質量％が好ましく、０．０５〜１０質量％がさらに好ましい。 When the silicone compound is blended in the hair cosmetic, the total amount of the silicone compound is preferably 0.01 to 25% by mass, more preferably 0.05 to 10% by mass.
＜成分（Ｅ）＞
成分（Ｅ）は、ノニオン界面活性剤である。ノニオン界面活性剤としては、毛髪化粧料に配合し得るものであれば特に限定されないが、使用感の観点からＨＬＢ値が８以上の親水性ノニオン界面活性剤を用いることが好ましい。かかる親水性ノニオン界面活性剤として具体的には、グリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ポリグリセリン脂肪酸エステル及びそのアルキレングリコール付加物、プロピレングリコール脂肪酸エステル及びそのアルキレングリコール付加物、ソルビタン脂肪酸エステル及びそのアルキレングリコール付加物、ソルビトールの脂肪酸エステル及びそのアルキレングリコール付加物、ポリアルキレングリコール脂肪酸エステル、ポリオキシアルキレン変性シリコーン、ポリオキシアルキレンアルキル共変性シリコーン等が挙げられる。
<Ingredient (E)>
Ingredient (E) is a nonionic surfactant. The nonionic surfactant is not particularly limited as long as it can be blended in hair cosmetics, but it is preferable to use a hydrophilic nonionic surfactant having an HLB value of 8 or more from the viewpoint of usability. Specifically, such hydrophilic nonionic surfactants include glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its sorbitan fatty acid ester. Examples thereof include alkylene glycol adducts, sorbitol fatty acid esters and their alkylene glycol adducts, polyalkylene glycol fatty acid esters, polyoxyalkylene-modified silicones, and polyoxyalkylene alkyl co-modified silicones.
＜成分（Ｆ）＞
成分（Ｆ）は、カチオン性高分子である。カチオン性高分子としては、ヘアトリートメント剤に配合し得るものであれば特に限定されず、カチオン化ヒドロキシエチルセルロース、カチオン化グアーガム、カチオン化ローカストビーンガム、塩化ジメチルジアリル・アクリルアミド共重合体、アクリルアミド・アクリル酸・塩化ジメチルジアリルアンモニウム共重合体を例として挙げることができる。
<Ingredient (F)>
The component (F) is a cationic polymer. The cationic polymer is not particularly limited as long as it can be blended in a hair treatment agent, and is limited to cationized hydroxyethyl cellulose, cationized guar gum, cationized locust bean gum, dimethyldialyl chloride / acrylamide copolymer, and acrylamide / acrylic. An acid / dimethyldialylammonium chloride copolymer can be mentioned as an example.
＜成分（Ｇ）＞
成分（Ｇ）は、中和剤である。中和剤としては、ヘアトリートメント剤に配合し得るものであれば特に限定されず、有機酸及び／又はその塩、無機酸及び／又はその塩を例として挙げることができる。
<Ingredient (G)>
Component (G) is a neutralizing agent. The neutralizing agent is not particularly limited as long as it can be blended with a hair treatment agent, and examples thereof include organic acids and / or salts thereof, inorganic acids and / or salts thereof.
＜成分（Ｈ）＞
成分（Ｈ）は、油脂である。油脂としては、毛髪化粧料に配合し得るものであれば特に限定されず、例えば、オリーブ油、ツバキ油、シア脂、アーモンド油、サフラワー油、ヒマワリ油、大豆油、綿実油、ゴマ油、トウモロコシ油、ナタネ油、コメヌカ油、コメ胚芽油、ブドウ種子油、アボカド油、マカダミアナッツ油、ヒマシ油、ヤシ油等を挙げることができる。
<Ingredient (H)>
The component (H) is an oil or fat. The fats and oils are not particularly limited as long as they can be blended in hair cosmetics, for example, olive oil, camellia oil, shea butter, almond oil, saflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, corn oil, etc. Examples include rapeseed oil, rice bran oil, rice germ oil, grape seed oil, avocado oil, macadamia nut oil, castor oil, palm oil and the like.
＜成分（Ｉ）＞
成分（Ｉ）は、ロウである。ロウとしては、毛髪化粧料に配合し得るものであれば特に限定されず、例えば、ミツロウ、キャンデリラロウ、カルナウバロウ、ホホバ油、ラノリン等が挙げられる。特にホホバ油を用いることが好ましい。
<Ingredient (I)>
Ingredient (I) is wax. The wax is not particularly limited as long as it can be blended in hair cosmetics, and examples thereof include beeswax, candelilla wax, carnauba wax, jojoba oil, and lanolin. In particular, it is preferable to use jojoba oil.
＜成分（Ｊ）＞
成分（Ｊ）は溶媒となる水であり、成分（Ｊ）としては、イオン交換水、蒸留水、脱イオン水、精製水、温泉水、海洋深層水等を使用することができる。成分（Ｊ）の配合量は、本発明の毛髪化粧料全量に対して、例えば５〜９０質量％であり、使用時に所望の感触が得られるのに適した配合量となるように調整することが好ましい。
<Ingredient (J)>
The component (J) is water that serves as a solvent, and as the component (J), ion-exchanged water, distilled water, deionized water, purified water, hot spring water, deep-sea water, and the like can be used. The blending amount of the component (J) is, for example, 5 to 90% by mass with respect to the total amount of the hair cosmetic of the present invention, and is adjusted so as to be a blending amount suitable for obtaining a desired feel at the time of use. Is preferable.
本発明の毛髪化粧料は、上述の成分の他に、通常の毛髪化粧料に用いられる任意成分を、本発明の効果を阻害しない程度に配合することができる。具体的には、増粘剤、防腐剤、香料、保湿剤、抗酸化剤、抗炎症剤、抗菌剤等を挙げることができる。 In the hair cosmetics of the present invention, in addition to the above-mentioned ingredients, any ingredients used in ordinary hair cosmetics can be blended to the extent that the effects of the present invention are not impaired. Specific examples thereof include thickeners, preservatives, fragrances, moisturizers, antioxidants, anti-inflammatory agents, antibacterial agents and the like.
本発明の毛髪化粧料は、常法により製造することができる。剤型としては、液状、クリーム状等の剤型とすることができ、ポリ容器、アルミチューブ容器、パウチ容器などの各種容器に充填される。 The hair cosmetic of the present invention can be produced by a conventional method. The dosage form can be liquid, creamy or the like, and is filled in various containers such as a plastic container, an aluminum tube container and a pouch container.
本発明の毛髪化粧料は、ヘアリンス、ヘアコンディショナー、ヘアトリートメント、ヘアパック、ヘアクリーム、ヘアカラー、リーブオントリートメントなどの製品にすることができる。 The hair cosmetic of the present invention can be a product such as a hair rinse, a hair conditioner, a hair treatment, a hair pack, a hair cream, a hair color, and a leave-on treatment.
本発明の毛髪化粧料はシャンプー等で毛髪を洗浄した後に用いることが好ましい。また、塗布した後、毛髪に残存する余分な毛髪化粧料をすすいで用いることが好ましい。 The hair cosmetic of the present invention is preferably used after washing the hair with shampoo or the like. In addition, it is preferable to rinse off excess hair cosmetics remaining on the hair after application.
以下、実施例により、本発明を具体的に説明するが、これにより、本発明の範囲が限定されるものではない。なお、配合量は、特に断りのない限り質量％である。 Hereinafter, the present invention will be specifically described with reference to Examples, but the scope of the present invention is not limited thereto. The blending amount is mass% unless otherwise specified.
表１及び表２の実施例及び比較例の毛髪化粧料を、定法により調製した。 The hair cosmetics of Examples and Comparative Examples in Tables 1 and 2 were prepared by a conventional method.
そして、各実施例及び比較例の毛髪化粧料について、下記の方法で、使用感の評価を行った。その結果を表１及び表２に示す。 Then, the feeling of use of the hair cosmetics of each Example and Comparative Example was evaluated by the following method. The results are shown in Tables 1 and 2.
使用感（指通り、ハリ・コシ、まとまり感）
専門パネラー３名による使用テストを行った。まず、各パネラーが日常使用しているシャンプーで十分洗髪を行ってから、表１及び表２に示す毛髪化粧料を適量塗布し、髪全体に馴染ませた後洗い流した。下記の判定基準に従って、すすぎ時〜乾燥後の指通り、乾燥後の髪のハリ・コシ及びまとまり感について、絶対評価を行い、合議により判定を行った。判定基準は、指通り、ハリ・コシ及びまとまり感で共通のものとした。
＜判定基準＞
◎：とても良い
○：良い
△：どちらともいえない
×：悪い
Usability (finger passage, firmness, cohesiveness)
A usage test was conducted by three specialized panelists. First, the hair was thoroughly washed with the shampoo that each panelist uses on a daily basis, and then an appropriate amount of the hair cosmetics shown in Tables 1 and 2 was applied, and the hair was thoroughly blended and then washed away. According to the following criteria, the absolute evaluation was performed on the finger passage from rinsing to after drying, and the firmness and cohesiveness of the hair after drying, and the judgment was made by consensus. The judgment criteria were the same for finger passage, firmness and elasticity, and a sense of unity.
<Criteria>
◎: Very good ○: Good △: Neither ×: Bad
注２：コータミン 86W 花王株式会社
注３：KF-8005 信越化学工業株式会社
注４：DOWSIL BY25-320 ダウ・東レ株式会社
注５：DOWSIL SH 200 Fluid 100,000cSt ダウ・東レ株式会社
表１に示すように、アミノ変性シリコーン、モノ又はジ長鎖アルキル４級アンモニウム塩及び分岐構造を持つエステル油を含有する実施例１は、分岐構造を有するエステル油を含有しない比較例１と比較して、指通り、ハリ・コシ及びまとまり感が向上した。 As shown in Table 1, Example 1 containing an amino-modified silicone, a mono or di-long-chain alkyl quaternary ammonium salt and an ester oil having a branched structure is compared with Comparative Example 1 containing no ester oil having a branched structure. As a result, finger passage, firmness, and cohesiveness were improved.
Claims (1)
（Ａ）アミノ変性シリコーン
（Ｂ）モノ又はジ長鎖アルキル４級アンモニウム塩
（Ｃ）分岐構造を有するエステル油 A hair cosmetic containing the following (A) to (C) is provided.
(A) Amino-modified silicone (B) Mono or di-long chain alkyl quaternary ammonium salt (C) Ester oil having a branched structure
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006327954A (en) * | 2005-05-24 | 2006-12-07 | Cota Co Ltd | Hair protective agent |
| JP2007297351A (en) * | 2006-05-02 | 2007-11-15 | Pola Chem Ind Inc | Cosmetic for treatment of hair |
| JP2009078992A (en) * | 2007-09-25 | 2009-04-16 | Shiseido Co Ltd | Hair cosmetic |
| JP2010138107A (en) * | 2008-12-11 | 2010-06-24 | Milbon Co Ltd | Hair-treating agent |
| JP2012171890A (en) * | 2011-02-18 | 2012-09-10 | Kracie Home Products Ltd | Hair rinse composition |
| JP2013023478A (en) * | 2011-07-22 | 2013-02-04 | Paimore Co Ltd | Treatment composition |
| JP2013209323A (en) * | 2012-03-30 | 2013-10-10 | Kose Corp | Hair cosmetic |
-
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- 2019-08-20 JP JP2019150093A patent/JP7358114B2/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006327954A (en) * | 2005-05-24 | 2006-12-07 | Cota Co Ltd | Hair protective agent |
| JP2007297351A (en) * | 2006-05-02 | 2007-11-15 | Pola Chem Ind Inc | Cosmetic for treatment of hair |
| JP2009078992A (en) * | 2007-09-25 | 2009-04-16 | Shiseido Co Ltd | Hair cosmetic |
| JP2010138107A (en) * | 2008-12-11 | 2010-06-24 | Milbon Co Ltd | Hair-treating agent |
| JP2012171890A (en) * | 2011-02-18 | 2012-09-10 | Kracie Home Products Ltd | Hair rinse composition |
| JP2013023478A (en) * | 2011-07-22 | 2013-02-04 | Paimore Co Ltd | Treatment composition |
| JP2013209323A (en) * | 2012-03-30 | 2013-10-10 | Kose Corp | Hair cosmetic |
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