JP2021010706A - Simple multi-functional deodorizer - Google Patents
Simple multi-functional deodorizer Download PDFInfo
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- 239000001913 cellulose Substances 0.000 claims abstract description 18
- 229920002678 cellulose Polymers 0.000 claims abstract description 18
- 239000000284 extract Substances 0.000 claims abstract description 12
- 241001122767 Theaceae Species 0.000 claims abstract 3
- 239000002781 deodorant agent Substances 0.000 claims description 74
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 33
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 16
- 239000008187 granular material Substances 0.000 claims description 14
- 229960000448 lactic acid Drugs 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000002156 mixing Methods 0.000 abstract description 15
- 239000000126 substance Substances 0.000 abstract description 12
- 239000007788 liquid Substances 0.000 abstract description 5
- 238000002360 preparation method Methods 0.000 abstract description 4
- 239000007787 solid Substances 0.000 abstract description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 30
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 21
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 20
- 230000001877 deodorizing effect Effects 0.000 description 18
- 238000000034 method Methods 0.000 description 17
- 229910021529 ammonia Inorganic materials 0.000 description 10
- 238000010998 test method Methods 0.000 description 9
- 244000269722 Thea sinensis Species 0.000 description 6
- 239000002245 particle Substances 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- -1 fatty acid salt Chemical class 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- 241001480057 Quercus salicina Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 240000002657 Thymus vulgaris Species 0.000 description 1
- 235000007303 Thymus vulgaris Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
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- Cosmetics (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
本発明は、成分が一般的な入手が容易で、調製が簡単で、使用が簡易な簡易多機能消臭剤を提供する。 The present invention provides a simple multifunctional deodorant whose ingredients are generally easily available, easy to prepare and easy to use.
従来の消臭剤は、消臭対象の悪臭に限られたものが多かった。天然由来の消臭成分には安定性及び価格の問題があった。合成の消臭成分には基材への配合方法、価格及び安全性の問題があった。一般的には、消臭速度は速くはないものが多いという問題があった。 Many of the conventional deodorants are limited to the malodor to be deodorized. Naturally derived deodorant components have problems with stability and price. Synthetic deodorant components have problems in the method of blending into the base material, price and safety. In general, there is a problem that the deodorizing speed is not fast in many cases.
多機能消臭剤として、天然由来の貝殻粒及び炭素粒を担体外周に結合剤でコーティングしたものがある（例えば特許文献１参照）。消臭剤として合成された物質２種類を各種比率で混合したものがある（例えば特許文献２参照）。また、合成された化合物としては、亜鉛の脂肪酸塩がある（例えば特許文献３参照）。天然由来の消臭原料としては、ウラジロガシ抽出物及びタイム抽出物がある（例えば特許文献４参照）。また天然由来の物質として、アオジモ及びユーカリの主成分がある（例えば特許文献５参照）。 As a multifunctional deodorant, there is one in which naturally-derived shell grains and carbon grains are coated on the outer periphery of the carrier with a binder (see, for example, Patent Document 1). There are two kinds of substances synthesized as deodorants mixed in various ratios (see, for example, Patent Document 2). Further, as the synthesized compound, there is a fatty acid salt of zinc (see, for example, Patent Document 3). Naturally-derived deodorant raw materials include Quercus salicina extract and thyme extract (see, for example, Patent Document 4). Further, as naturally derived substances, there are main components of Aojimo and Eucalyptus (see, for example, Patent Document 5).
しかしながら、特許文献１では、貝殻の再資源活用に貢献できるが、結合剤を用いたコーティングという技術及び時間を要する工程が必要である。特許文献２では、化学合成された化合物を使用しており、酸性悪臭物質の消臭及び価格は一般的なものに比べて特に有利ではない。特許文献３の技術には、合成された亜鉛の脂肪酸塩の有効性が示されているが、実用品に応用した例がみられず、加工についての容易さが残っている。特許文献４の技術では、天然由来の抽出物のメチルメルカプタンに対する消臭効果が特に高くはなく、悪臭酸性物質及び塩基性物質に対する消臭効果は示されていない。特許文献５の技術では、スルフィド及びメルカプタンには消臭効果があるが、酢酸及びアンモニアに対しての消臭効果は高くはない。
そこで、消臭剤の成分として一般的な入手が容易で、配合工程などの調製方法が簡単で、その使用方法は通常の置き型で、消臭対象として多様な悪臭物質に対して有効な消臭剤が望まれていた。However, in Patent Document 1, although it can contribute to the recycling of shells, a technique of coating using a binder and a process requiring time are required. Patent Document 2 uses a chemically synthesized compound, and the deodorization and price of acidic malodorous substances are not particularly advantageous as compared with general ones. Although the technique of Patent Document 3 shows the effectiveness of the synthesized fatty acid salt of zinc, there is no example of application to a practical product, and the ease of processing remains. In the technique of Patent Document 4, the deodorizing effect of the naturally occurring extract on methyl mercaptan is not particularly high, and the deodorizing effect on malodorous acidic substances and basic substances is not shown. In the technique of Patent Document 5, sulfide and mercaptan have a deodorizing effect, but the deodorizing effect on acetic acid and ammonia is not high.
Therefore, it is easy to obtain as a component of deodorant, the preparation method such as the compounding process is easy, the usage method is a normal stationary type, and it is effective for deodorizing various malodorous substances as a deodorant target. An odorant was desired.
かかる実情において本発明者らは、上記課題を解決すべく鋭意研究を重ねた結果、ＤＬ−乳酸、チャ抽出物、水、プロピレングリコール及びセルロース粒を用いることにより、上記課題を解決することを見出し、本発明を完成するに至った。 As a result of intensive studies to solve the above problems, the present inventors have found that the above problems can be solved by using DL-lactic acid, tea extract, water, propylene glycol and cellulose granules. , The present invention has been completed.
本発明により、成分の入手が容易で、調製方法が簡単で、多様な悪臭を消臭できる優れた消臭剤が提供できる。 INDUSTRIAL APPLICABILITY According to the present invention, it is possible to provide an excellent deodorant capable of easily obtaining components, a simple preparation method, and deodorizing various malodors.
以下本発明を詳細に説明する。
本発明に用いられるＤＬ−乳酸は、無臭であり、消臭剤成分に適しており、また液体（融点１７℃）で製品調製を容易にするものである。
本発明に用いるＤＬ−乳酸の配合量は特に限定されるものではないが、全成分の総量に対して５〜２５％が好ましい。配合量がこの範囲より少ないと塩基性悪臭物質の消臭速度が遅くなり、より多いとセルロース粒が容器に付着する傾向がでてくる。Hereinafter, the present invention will be described in detail.
The DL-lactic acid used in the present invention is odorless, suitable as a deodorant component, and is a liquid (melting point 17 ° C.) that facilitates product preparation.
The blending amount of DL-lactic acid used in the present invention is not particularly limited, but is preferably 5 to 25% based on the total amount of all the components. If the blending amount is less than this range, the deodorizing rate of the basic malodorous substance becomes slower, and if the blending amount is larger than this range, cellulose particles tend to adhere to the container.
本発明に用いられるプロピレングリコールの配合量は限定されるものではないが、全成分の総量に対して２０〜４０％が好ましい。 The blending amount of propylene glycol used in the present invention is not limited, but is preferably 20 to 40% based on the total amount of all the components.
本発明に用いられるチャ抽出物は食品添加物であり、固体又は液体のものが用いられる。市販品としては、サンフード１００（固体、三菱ケミカルフーズ株式会社製）及びサンフード水性（液体、三菱ケミカルフーズ株式会社製）等を用いることができる。本発明に用いられるチャ抽出物の配合量は特に限定されないが、固体のものは全成分の総量に対して２〜５％が好ましく、液体のものは１０〜２０％が好ましい。配合量がこの範囲より少ないと消臭効果が低くなり、より多いとセルロース粒が容器に付着する傾向がでてくる。 The tea extract used in the present invention is a food additive, and a solid or liquid one is used. As commercially available products, Sunfood 100 (solid, manufactured by Mitsubishi Chemical Foods Co., Ltd.), Sunfood water-based (liquid, manufactured by Mitsubishi Chemical Foods Co., Ltd.) and the like can be used. The blending amount of the tea extract used in the present invention is not particularly limited, but the solid one is preferably 2 to 5% with respect to the total amount of all the components, and the liquid one is preferably 10 to 20%. If the blending amount is less than this range, the deodorizing effect becomes low, and if the blending amount is larger than this range, cellulose particles tend to adhere to the container.
本発明に用いられる水は全成分の総量に対して１５％以下が好ましい。 The water used in the present invention is preferably 15% or less based on the total amount of all the components.
本発明に用いられるセルロース粒は全成分の総量に対して５０〜６０％が好ましい。市販品としてはビスコパール（レンゴー株式会社製）等を用いることができる。配合量がこの量より少ないとセルロース粒が容器に付着する傾向がでてくる。 The cellulose granules used in the present invention are preferably 50 to 60% based on the total amount of all the components. As a commercially available product, Viscopearl (manufactured by Rengo Co., Ltd.) or the like can be used. If the blending amount is less than this amount, the cellulose particles tend to adhere to the container.
本発明の簡易多機能消臭剤には、前記成分の他に、有機酸類、アルコール類、各種消臭成分、着色剤、界面活性剤、抗酸化剤、又はその他の薬剤などを本発明の効果を損なわない範囲で配合することができる。 In addition to the above-mentioned components, the simple multifunctional deodorant of the present invention includes organic acids, alcohols, various deodorant components, colorants, surfactants, antioxidants, and other agents. Can be blended within a range that does not impair.
以下に本発明の実施例を示し、本発明を詳細に説明するが、本発明はこれらの実施例によって限定されるものではない。なお、配合量などは特に指定がない限り質量で示す。 Examples of the present invention will be shown below and the present invention will be described in detail, but the present invention is not limited to these examples. The blending amount and the like are indicated by mass unless otherwise specified.
ＤＬ−乳酸１２．５ｇ及びプロピレングリコール１２．５ｇをセルロース粒（ビスコパール）２５ｇに含浸させる。チャ抽出物（サンフード１００）２．５ｇを水１０ｇ及びプロピレングリコール１２．５ｇに溶かし、セルロース粒（ビスコパール）２５ｇに含浸させる。この２種類の含浸セルロース粒を混合して、簡易多機能消臭剤を調製する。
簡易多機能消臭剤について、芳香消臭脱臭剤協議会が設定した消臭剤効力試験方法（検知管法）でアンモニアに対する消臭効果を試験した。その結果、τ０．１は１．７時間であった。（τ０．１は、初期濃度が、その１／１０の濃度に達する所要時間を示す）
一方、市販の無機系消臭剤のアンモニアに対するτ０．１は３．３時間であった。また、市販の有機系消臭剤のアンモニアに対するτ０．１は８．５時間であった。25 g of cellulose granules (Viscopearl) are impregnated with 12.5 g of DL-lactic acid and 12.5 g of propylene glycol. 2.5 g of tea extract (Sunfood 100) is dissolved in 10 g of water and 12.5 g of propylene glycol, and 25 g of cellulose granules (Viscopearl) are impregnated. A simple multifunctional deodorant is prepared by mixing these two types of impregnated cellulose granules.
For simple multifunctional deodorants, the deodorizing effect on ammonia was tested by the deodorant efficacy test method (detector tube method) set by the Aroma Deodorant Deodorant Council. As a result, τ 0.1 was 1.7 hours. (Τ 0.1 indicates the time required for the initial concentration to reach 1/10 of the initial concentration)
On the other hand, τ 0.1 of a commercially available inorganic deodorant with respect to ammonia was 3.3 hours. Further, τ 0.1 of a commercially available organic deodorant with respect to ammonia was 8.5 hours.
実施例１で調製した簡易多機能消臭剤について、芳香消臭脱臭剤協議会が設定した消臭剤効力試験方法（検知管法）で酢酸に対する消臭効果を試験した。その結果、τ０．１は１．１時間であった。
一方、市販の無機系消臭剤の酢酸に対するτ０．１は３．６時間であった。また、市販の有機系消臭剤の酢酸に対するτ０．１は２．９時間であった。The simple multifunctional deodorant prepared in Example 1 was tested for its deodorizing effect on acetic acid by the deodorant efficacy test method (detector tube method) set by the Aroma Deodorant Deodorant Council. As a result, τ 0.1 was 1.1 hours.
On the other hand, τ 0.1 of a commercially available inorganic deodorant with respect to acetic acid was 3.6 hours. Further, τ 0.1 of a commercially available organic deodorant with respect to acetic acid was 2.9 hours.
実施例１で調製した簡易多機能消臭剤について、芳香消臭脱臭剤協議会が設定した消臭剤効力試験方法（検知管法）でメチルメルカプタンに対する消臭効果を試験した。その結果、τ０．１は６．９時間であった。
一方、市販の無機系消臭剤のメチルメルカプタンに対するτ０．１は２０時間を超えた。また、市販の有機系消臭剤のメチルメルカプタンに対するτ０．１は２０時間程度であった。The simple multifunctional deodorant prepared in Example 1 was tested for its deodorizing effect on methyl mercaptan by the deodorant efficacy test method (detector tube method) set by the Aroma Deodorant Deodorant Council. As a result, τ 0.1 was 6.9 hours.
On the other hand, τ 0.1 for methyl mercaptan, a commercially available inorganic deodorant, exceeded 20 hours. Further, τ 0.1 for methyl mercaptan, a commercially available organic deodorant, was about 20 hours.
ＤＬ−乳酸１５ｇ及びプロピレングリコール１０ｇをセルロース粒（ビスコパール）２５ｇに含浸させる。チャ抽出物（サンフード１００）４ｇを水１２ｇ及びプロピレングリコール９ｇに溶かし、セルロース粒（ビスコパール）２５ｇに含浸させる。この２種類の含浸セルロース粒を混合して、簡易多機能消臭剤を調製する。
簡易多機能消臭剤について、芳香消臭脱臭剤協議会が設定した消臭剤効力試験方法（検知管法）でアンモニアに対する消臭効果を試験した。その結果、τ０．１は１．４時間であった。
一方、市販の無機系消臭剤のアンモニアに対するτ０．１は３．３時間であった。また、市販の有機系消臭剤のアンモニアに対するτ０．１は８．５時間であった。25 g of cellulose granules (Viscopearl) are impregnated with 15 g of DL-lactic acid and 10 g of propylene glycol. 4 g of tea extract (Sunfood 100) is dissolved in 12 g of water and 9 g of propylene glycol, and 25 g of cellulose granules (Viscopearl) are impregnated. A simple multifunctional deodorant is prepared by mixing these two types of impregnated cellulose granules.
For simple multifunctional deodorants, the deodorizing effect on ammonia was tested by the deodorant efficacy test method (detector tube method) set by the Aroma Deodorant Deodorant Council. As a result, τ 0.1 was 1.4 hours.
On the other hand, τ 0.1 of a commercially available inorganic deodorant with respect to ammonia was 3.3 hours. Further, τ 0.1 of a commercially available organic deodorant with respect to ammonia was 8.5 hours.
実施例４で調製した簡易多機能消臭剤について、芳香消臭脱臭剤協議会が設定した消臭剤効力試験方法（検知管法）で酢酸に対する消臭効果を試験した。その結果、τ０．１は１時間であった。
一方、市販の無機系消臭剤の酢酸に対するτ０．１は３．６時間であった。また、市販の有機系消臭剤の酢酸に対するτ０．１は２．９時間であった。The simple multifunctional deodorant prepared in Example 4 was tested for its deodorizing effect on acetic acid by the deodorant efficacy test method (detector tube method) set by the Aroma Deodorant Deodorant Council. As a result, τ 0.1 was 1 hour.
On the other hand, τ 0.1 of a commercially available inorganic deodorant with respect to acetic acid was 3.6 hours. Further, τ 0.1 of a commercially available organic deodorant with respect to acetic acid was 2.9 hours.
実施例４で調製した簡易多機能消臭剤について、芳香消臭脱臭剤協議会が設定した消臭剤効力試験方法（検知管法）でメチルメルカプタンに対する消臭効果を試験した。その結果、τ０．１は６時間であった。
一方、市販の無機系消臭剤のメチルメルカプタンに対するτ０．１は２０時間を超えた。また、市販の有機系消臭剤のメチルメルカプタンに対するτ０．１は２０時間程度であった。The simple multifunctional deodorant prepared in Example 4 was tested for its deodorizing effect on methyl mercaptan by the deodorant efficacy test method (detector tube method) set by the Aroma Deodorant Deodorant Council. As a result, τ 0.1 was 6 hours.
On the other hand, τ 0.1 for methyl mercaptan, a commercially available inorganic deodorant, exceeded 20 hours. Further, τ 0.1 for methyl mercaptan, a commercially available organic deodorant, was about 20 hours.
ＤＬ−乳酸１５ｇ及びプロピレングリコール１０ｇをセルロース粒（ビスコパール）２５ｇに含浸させる。チャ抽出物（サンフード水性）１５ｇ及びプロピレングリコール１０ｇに溶かし、セルロース粒（ビスコパール）２５ｇに含浸させる。この２種類の含浸セルロース粒を混合して、簡易多機能消臭剤を生成する。
簡易多機能消臭剤について、芳香消臭脱臭剤協議会が設定した消臭剤効力試験方法（検知管法）でアンモニアに対する消臭効果を試験した。その結果、τ０．１は１．４時間であった。
一方、市販の無機系消臭剤のアンモニアに対するτ０．１は３．３時間であった。また、市販の有機系消臭剤のアンモニアに対するτ０．１は８．５時間であった。25 g of cellulose granules (Viscopearl) are impregnated with 15 g of DL-lactic acid and 10 g of propylene glycol. Dissolve in 15 g of tea extract (water-based sun food) and 10 g of propylene glycol, and impregnate 25 g of cellulose granules (Viscopearl). These two types of impregnated cellulose granules are mixed to produce a simple multifunctional deodorant.
For simple multifunctional deodorants, the deodorizing effect on ammonia was tested by the deodorant efficacy test method (detector tube method) set by the Aroma Deodorant Deodorant Council. As a result, τ 0.1 was 1.4 hours.
On the other hand, τ 0.1 of a commercially available inorganic deodorant with respect to ammonia was 3.3 hours. Further, τ 0.1 of a commercially available organic deodorant with respect to ammonia was 8.5 hours.
実施例７で調製した簡易多機能消臭剤について、芳香消臭脱臭剤協議会が設定した消臭剤効力試験方法（検知管法）で酢酸に対する消臭効果を試験した。その結果、τ０．１は２．４時間であった。
一方、市販の無機系消臭剤の酢酸に対するτ０．１は３．６時間であった。また、市販の有機系消臭剤の酢酸に対するτ０．１は２．９時間であった。The simple multifunctional deodorant prepared in Example 7 was tested for its deodorizing effect on acetic acid by the deodorant efficacy test method (detector tube method) set by the Aroma Deodorant Deodorant Council. As a result, τ 0.1 was 2.4 hours.
On the other hand, τ 0.1 of a commercially available inorganic deodorant with respect to acetic acid was 3.6 hours. Further, τ 0.1 of a commercially available organic deodorant with respect to acetic acid was 2.9 hours.
実施例７で調製した簡易多機能消臭剤について、芳香消臭脱臭剤協議会が設定した消臭剤効力試験方法（検知管法）でメチルメルカプタンに対する消臭効果を試験した。その結果、τ０．１は１２時間であった。
一方、市販の無機系消臭剤のメチルメルカプタンに対するτ０．１は２０時間を超えた。また、市販の有機系消臭剤のメチルメルカプタンに対するτ０．１は２０時間程度であった。The simple multifunctional deodorant prepared in Example 7 was tested for its deodorizing effect on methyl mercaptan by the deodorant efficacy test method (detector tube method) set by the Aroma Deodorant Deodorant Council. As a result, τ 0.1 was 12 hours.
On the other hand, τ 0.1 for methyl mercaptan, a commercially available inorganic deodorant, exceeded 20 hours. Further, τ 0.1 for methyl mercaptan, a commercially available organic deodorant, was about 20 hours.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03109072A (en) * | 1989-09-21 | 1991-05-09 | Matsushita Electric Works Ltd | Deodorant and deodorizing spray |
| JP2000325453A (en) * | 1999-05-25 | 2000-11-28 | Matsushita Electric Works Ltd | Deodorant |
| JP2002263178A (en) * | 2001-03-09 | 2002-09-17 | Ishihara Chem Co Ltd | Stationary deodorant |
| JP2003062053A (en) * | 2001-08-28 | 2003-03-04 | Rengo Co Ltd | Deodorant |
| JP2009148326A (en) * | 2007-12-19 | 2009-07-09 | Kao Corp | Depressant for generating urine odor generation |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03109072A (en) * | 1989-09-21 | 1991-05-09 | Matsushita Electric Works Ltd | Deodorant and deodorizing spray |
| JP2000325453A (en) * | 1999-05-25 | 2000-11-28 | Matsushita Electric Works Ltd | Deodorant |
| JP2002263178A (en) * | 2001-03-09 | 2002-09-17 | Ishihara Chem Co Ltd | Stationary deodorant |
| JP2003062053A (en) * | 2001-08-28 | 2003-03-04 | Rengo Co Ltd | Deodorant |
| JP2009148326A (en) * | 2007-12-19 | 2009-07-09 | Kao Corp | Depressant for generating urine odor generation |
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