JP2020130182A - Foamable oil-in-water emulsified product - Google Patents

Foamable oil-in-water emulsified product Download PDF

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JP2020130182A
JP2020130182A JP2020024669A JP2020024669A JP2020130182A JP 2020130182 A JP2020130182 A JP 2020130182A JP 2020024669 A JP2020024669 A JP 2020024669A JP 2020024669 A JP2020024669 A JP 2020024669A JP 2020130182 A JP2020130182 A JP 2020130182A
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oil
mass
fat
water emulsion
oils
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JP7454813B2 (en
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青木 祐子
Yuko Aoki
祐子 青木
西 俊郎
Toshiro Nishi
俊郎 西
雅幸 佐藤
Masayuki Sato
雅幸 佐藤
世里子 遠藤
Yoriko Endo
世里子 遠藤
勇馬 小笠
Yuma Ogasa
勇馬 小笠
窪田 耕一
Koichi Kubota
耕一 窪田
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Nisshin Oillio Group Ltd
Takanashi Milk Products Co Ltd
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Nisshin Oillio Group Ltd
Takanashi Milk Products Co Ltd
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Abstract

To provide a foamable oil-in-water emulsified product capable of obtaining a whipped cream having good emulsion stability and having cool feeling and freshness.SOLUTION: There is provided a foamable oil-in-water emulsified product comprising a fat and oil including 24 mass% or more and 48 mass% or less of a vegetable oil or fat, wherein the vegetable oil or fat contains an oil and fat A and an oil and fat B and the content of a UUU-type triglyceride in the vegetable oil and fat is 14 mass% or more and 24 mass% or less (provided that the oil and fat A, the oil and fat B and the UUU-type triglyceride mean the following). A fat and oil A: a non-cured and non-interesterified oil and fat having an iodine value of 3 to 30 in which the ratio of lauric acid in a constituent fatty acid is 35 mass% or more, an oil and fat B: an interesterified oil and fat having an iodine value of 18 to 48 in which the ratio of lauric acid in a constituent fatty acid is less than 35 mass% and a UUU-type triglyceride: a triglyceride containing an unsaturated fatty acid (U) having 16 or more carbon atoms as a constituent fatty acid.)SELECTED DRAWING: None

Description

本発明は、起泡性水中油型乳化物に関する。また、該起泡性水中油型乳化物を起泡してなるホイップドクリームに関する。 The present invention relates to a foamable oil-in-water emulsion. The present invention also relates to a whipped cream obtained by foaming the foamable oil-in-water emulsion.

植物性油脂を主原料とするホイップドクリームは、生クリームの代替として、ケーキやパンなどのベーカリー食品への、ナッペ、サンド、トッピングなどの用途に使用されてきた。ホイップドクリームに使用される植物油脂としては、例えば、ラウリン系油脂を主体としたタイプ(例えば、特許文献1、2参照)や、パーム油の中融点分別油などのSUS型トリグリセリドを主体としたタイプ(例えば、特許文献3、4参照)が考案されている。 Whipped cream, which is mainly made of vegetable oil, has been used as an alternative to fresh cream for bakery foods such as cakes and breads, as well as for nappe, sand, and toppings. Examples of vegetable oils and fats used in whipped cream are mainly lauric-based oils and fats (see, for example, Patent Documents 1 and 2) and SUS-type triglycerides such as palm oil medium-melting point fractionated oil. Types (see, for example, Patent Documents 3 and 4) have been devised.

上記ラウリン系油脂を主体としたタイプは、冷涼感のある良好な口どけを有するが、乳化が不安定でホイップ前のクリームが保存中に増粘しやすいという課題があった。また、上記SUS型トリグリセリドを主体としたタイプは、良好な口どけを有するが、ラウリン系油脂を主体としたタイプと比較して、冷涼感に劣るものであった。また、ホイップドクリームは、サンド等の用途によっては冷涼感とともに瑞々しさが求められるが、両タイプともにドライな食感になりやすかった。 The above-mentioned type mainly composed of laurin-based fats and oils has a good melting in the mouth with a cool feeling, but has a problem that emulsification is unstable and the cream before whipping tends to thicken during storage. Further, the above-mentioned type mainly composed of SUS type triglyceride had a good melting in the mouth, but was inferior in a cool feeling as compared with the type mainly composed of laurin-based fats and oils. In addition, whipped cream is required to have a cool feeling and freshness depending on the use such as sandwiches, but both types tend to have a dry texture.

特開2006−304713号公報JP-A-2006-304713 特開2009−50235号公報JP-A-2009-50235 特開2006−223176号公報Japanese Unexamined Patent Publication No. 2006-223176 特開2010−68716号公報Japanese Unexamined Patent Publication No. 2010-68716

従って、乳化安定性が良好であり、冷涼感と瑞々しさを有するホイップドクリームが得られる、起泡性水中油型乳化物の開発が望まれている。 Therefore, it is desired to develop a foamable oil-in-water emulsion which has good emulsion stability and can obtain a whipped cream having a cool feeling and freshness.

本発明の課題は、乳化安定性が良好であり、冷涼感と瑞々しさを有するホイップドクリームが得られる、起泡性水中油型乳化物を提供することである。 An object of the present invention is to provide a foamable oil-in-water emulsion which has good emulsion stability and can obtain a whipped cream having a cool feeling and freshness.

本発明者らは上記課題を解決するため鋭意検討した。その結果、起泡性水中油型乳化物において、特定の植物性油脂を併用し、かつ 該植物性油脂中のUUU型トリグリセリド含有量を調節することで、上記課題を解決できることを見出した。これにより本発明は完成された。 The present inventors have diligently studied to solve the above problems. As a result, it was found that the above-mentioned problems can be solved by using a specific vegetable oil and fat in combination with a foamable oil-in-water emulsion and adjusting the UUU-type triglyceride content in the vegetable oil and fat. Thereby, the present invention was completed.

すなわち、本発明は以下のものを提供する。
[1]24質量%以上48質量%以下の、植物性油脂を含む油脂を含有する起泡性水中油型乳化物であって、
前記植物性油脂が、油脂A及び油脂Bを含み、かつ、前記植物性油脂中のUUU型トリグリセリド含有量が14質量%以上24質量%以下である、起泡性水中油型乳化物。
(ただし、油脂A、油脂B、及びUUU型トリグリセリドは、以下を意味する。
油脂A:構成脂肪酸に占めるラウリン酸の割合が35質量%以上であり、ヨウ素価が3〜30である、非硬化非エステル交換油脂。
油脂B:構成脂肪酸に占めるラウリン酸の割合が35質量%未満であり、ヨウ素価が18〜48である、エステル交換油脂。
UUU型トリグリセリド:炭素数16以上の不飽和脂肪酸(U)を構成脂肪酸とするトリグリセリド。)
[2]前記植物性油脂中のS2U含有量が6.0質量%以下である、[1]に記載の起泡性水中油型乳化物。
(但し、S2U型トリグリセリドは、以下を意味する。
S2U型トリグリセリド:2つの炭素数16以上の飽和脂肪酸(S)と1つのUとを構成脂肪酸とするトリグリセリド。)
[3]前記植物性油脂中の前記油脂Aの含有量が前記油脂Bの含有量よりも多い、[1]または[2]に記載の起泡性水中油型乳化物。
[4]前記植物性油脂が、油脂Cをさらに含有する、[1]〜[3]のいずれかに記載の起泡性水中油型乳化物。
(ただし、油脂Cは、以下を意味する。
油脂C:UUU型トリグリセリド含有量が60質量%以上である油脂。)
[5]前記起泡性水中油型乳化物が、乳化剤として、レシチン及び/又はポリソルベートをさらに含有する、(1)〜(4)のいずれかに記載の起泡性水中油型乳化物。
[6]前記起泡性水中油型乳化物が、乳化剤として、有機酸モノグリセリドをさらに含有する、(1)〜(5)のいずれかに記載の起泡性水中油型乳化物。
[7]前記起泡性水中油型乳化物が、乳化剤として、ベヘン酸モノグリセリドをさらに含有する、(1)〜(6)のいずれかに記載の起泡性水中油型乳化物。
[8](1)〜(7)のいずれかに記載の起泡性水中油型乳化物を起泡してなる、ホイップドクリーム。
That is, the present invention provides the following.
[1] A foamable oil-in-water emulsion containing oils and fats containing vegetable oils and fats, which are 24% by mass or more and 48% by mass or less.
A foamable oil-in-water emulsion in which the vegetable oil contains oil A and oil B, and the UUU-type triglyceride content in the vegetable oil is 14% by mass or more and 24% by mass or less.
(However, fat A, fat B, and UUU-type triglyceride mean the following.
Fats and oils A: Non-cured, transesterified fats and oils in which the ratio of lauric acid to the constituent fatty acids is 35% by mass or more and the iodine value is 3 to 30.
Fats and oils B: Transesterified fats and oils in which the proportion of lauric acid in the constituent fatty acids is less than 35% by mass and the iodine value is 18 to 48.
UUU-type triglyceride: A triglyceride containing an unsaturated fatty acid (U) having 16 or more carbon atoms as a constituent fatty acid. )
[2] The foamable oil-in-water emulsion according to [1], wherein the S2U content in the vegetable oil is 6.0% by mass or less.
(However, S2U type triglyceride means the following.
S2U-type triglyceride: A triglyceride containing two saturated fatty acids (S) having 16 or more carbon atoms and one U as constituent fatty acids. )
[3] The foamable oil-in-water emulsion according to [1] or [2], wherein the content of the fat A in the vegetable fat is higher than the content of the fat B.
[4] The foamable oil-in-water emulsion according to any one of [1] to [3], wherein the vegetable oil further contains the oil C.
(However, fat and oil C means the following.
Fats and oils C: Fats and oils having a UUU-type triglyceride content of 60% by mass or more. )
[5] The foaming oil-in-water emulsion according to any one of (1) to (4), wherein the foaming oil-in-water emulsion further contains lecithin and / or polysorbate as an emulsifier.
[6] The foaming oil-in-water emulsion according to any one of (1) to (5), wherein the foaming oil-in-water emulsion further contains an organic acid monoglyceride as an emulsifier.
[7] The foaming oil-in-water emulsion according to any one of (1) to (6), wherein the foaming oil-in-water emulsion further contains behenic acid monoglyceride as an emulsifier.
[8] A whipped cream obtained by foaming the foamable oil-in-water emulsion according to any one of (1) to (7).

本発明によれば、乳化安定性が良好であり、冷涼感と瑞々しさを有するホイップドクリームが得られる、起泡性水中油型乳化物を提供することができる。 According to the present invention, it is possible to provide a foamable oil-in-water emulsion which has good emulsion stability and can obtain a whipped cream having a cool feeling and freshness.

[定義]
本発明において、油脂中のトリグリセリドとは、1分子のグリセロールに、3分子の脂肪酸がエステル結合した構造を有するものである。トリグリセリドの1、2、3位とは、脂肪酸が結合した位置を表す。なお、トリグリセリドの構成脂肪酸の略称として、以下を用いる。S:炭素数16以上の飽和脂肪酸、U:炭素数16以上の不飽和脂肪酸。
[Definition]
In the present invention, the triglyceride in fats and oils has a structure in which three molecules of fatty acids are ester-bonded to one molecule of glycerol. The 1, 2, and 3 positions of triglyceride represent the positions where fatty acids are bound. The following are used as abbreviations for the constituent fatty acids of triglyceride. S: Saturated fatty acid having 16 or more carbon atoms, U: Unsaturated fatty acid having 16 or more carbon atoms.

本発明において、飽和脂肪酸Sは、炭素数が16以上であり、好ましくは16〜24であり、より好ましくは16〜18である。また、トリグリセリド分子に2つの飽和脂肪酸Sが結合するS2U型トリグリセリドの場合、飽和脂肪酸Sは同一の飽和脂肪酸であってもよいし、異なる飽和脂肪酸であってもよい。具体的には、飽和脂肪酸Sとしては、パルミチン酸(16)、ステアリン酸(18)、アラキジン酸(20)、ベヘン酸(22)、およびリグノセリン酸(24)が挙げられる。なお、上記の数値表記は、脂肪酸の炭素数である。 In the present invention, the saturated fatty acid S has 16 or more carbon atoms, preferably 16 to 24, and more preferably 16 to 18. Further, in the case of the S2U type triglyceride in which two saturated fatty acids S are bound to the triglyceride molecule, the saturated fatty acids S may be the same saturated fatty acid or different saturated fatty acids. Specifically, the saturated fatty acid S includes palmitic acid (16), stearic acid (18), arachidic acid (20), behenic acid (22), and lignoceric acid (24). The above numerical notation is the number of carbon atoms of the fatty acid.

本発明において、不飽和脂肪酸Uは、炭素数が16以上であり、好ましくは16〜24であり、より好ましくは16〜18である。また、トリグリセリド分子に3つの不飽和脂肪酸Uが結合するUUU型トリグリセリドの場合、不飽和脂肪酸Uは同一の不飽和脂肪酸であってもよいし、異なる不飽和脂肪酸であってもよい。具体的には、不飽和脂肪酸Uとしては、パルミトレイン酸(16:1)、オレイン酸(18:1)、リノール酸(18:2)、およびリノレン酸(18:3)が挙げられる。なお、上記の数値表記は、脂肪酸の炭素数と二重結合数の組み合わせである。 In the present invention, the unsaturated fatty acid U has 16 or more carbon atoms, preferably 16 to 24, and more preferably 16 to 18. Further, in the case of a UUU-type triglyceride in which three unsaturated fatty acids U are bound to a triglyceride molecule, the unsaturated fatty acids U may be the same unsaturated fatty acid or different unsaturated fatty acids. Specifically, unsaturated fatty acids U include palmitoleic acid (16: 1), oleic acid (18: 1), linoleic acid (18: 2), and linolenic acid (18: 3). The above numerical notation is a combination of the number of carbon atoms of the fatty acid and the number of double bonds.

[起泡性水中油型乳化物]
本発明の起泡性水中油型乳化物は、少なくとも油脂及び水を含むものであり、乳化剤やその他の添加剤をさらに含んでもよい。本発明の起泡性水中油型乳化物は、主に製菓製パン領域で使用されるものである。
[Foamable oil-in-water emulsion]
The foamable oil-in-water emulsion of the present invention contains at least fats and oils and water, and may further contain an emulsifier and other additives. The foamable oil-in-water emulsion of the present invention is mainly used in the confectionery and bakery area.

(油脂)
起泡性水中油型乳化物中の油脂含有量は、24質量%以上48質量%以下であり、好ましくは32質量%以上45質量%以下であり、より好ましくは34質量%以上42質量%以下である。起泡性水中油型乳化物中の油脂含有量が上記数値範囲内であれば、乳化安定性が良好であり、冷涼感と瑞々しさを有するホイップドクリームが得られる、起泡性水中油型乳化物を製造できる。
(Fat and oil)
The oil and fat content in the foamable oil-in-water emulsion is 24% by mass or more and 48% by mass or less, preferably 32% by mass or more and 45% by mass or less, and more preferably 34% by mass or more and 42% by mass or less. Is. When the oil and fat content in the foamable oil-in-water emulsion is within the above numerical range, a whipped cream having good emulsion stability and a cool feeling and freshness can be obtained. Mold emulsion can be produced.

上記油脂は植物性油脂を含み、前記植物性油脂は、少なくとも下記の油脂A及び油脂Bを含み、油脂Cをさらに含んでもよく、油脂A〜C以外のその他の油脂をさらに含んでもよい。起泡性水中油型乳化物に含まれる油脂中の植物性油脂の割合は、好ましくは45〜100質量%であり、より好ましくは70〜100質量%であり、さらに好ましくは、80〜100質量%であり、ことさらに好ましくは95〜100質量%である。なお、本発明において植物性油脂は、植物油脂(植物から得られる油脂)および植物油脂を原料とした加工油脂を意味する。前記加工油脂としては、例えば、合成油脂、エステル交換油脂、水素添加油脂、分別油脂等が挙げられる。 The fat and oil contains a vegetable fat and oil, and the vegetable fat and oil contains at least the following fat and oil B and fat and oil C, and may further contain other fat and oil other than fats and oils A to C. The proportion of vegetable fats and oils in the fats and oils contained in the foamable oil-in-water emulsion is preferably 45 to 100% by mass, more preferably 70 to 100% by mass, and further preferably 80 to 100% by mass. %, More preferably 95 to 100% by mass. In the present invention, vegetable fats and oils mean vegetable fats and oils (fat and oils obtained from plants) and processed fats and oils made from vegetable fats and oils. Examples of the processed fats and oils include synthetic fats and oils, transesterified fats and oils, hydrogenated fats and oils, fractionated fats and oils, and the like.

(油脂A)
油脂Aは、非硬化非エステル交換油脂であって、構成脂肪酸に占めるラウリン酸の割合が35質量%以上であり、好ましくは37質量%以上60質量%以下、より好ましくは40質量%以上55質量%以下であり、さらに好ましくは42質量%以上52質量%以下である。また、ヨウ素価が3以上30以下であり、好ましくは7以上27以下であり、より好ましくは10以上25以下であり、さらに好ましくは13以上23以下である。油脂Aは、構成脂肪酸に占めるラウリン酸の割合およびヨウ素価が上記数値範囲内であれば、乳化安定性が良好であり、冷涼感と瑞々しさを有するホイップドクリームが得られる、起泡性水中油型乳化物を製造できる。
(Fat A)
The fat A is a uncured, transesterified fat and oil in which the proportion of lauric acid in the constituent fatty acids is 35% by mass or more, preferably 37% by mass or more and 60% by mass or less, and more preferably 40% by mass or more and 55% by mass. % Or less, more preferably 42% by mass or more and 52% by mass or less. The iodine value is 3 or more and 30 or less, preferably 7 or more and 27 or less, more preferably 10 or more and 25 or less, and further preferably 13 or more and 23 or less. When the ratio of lauric acid to the constituent fatty acids and the iodine value of the fat A are within the above numerical ranges, the emulsification stability is good, and a whipped cream having a cool feeling and freshness can be obtained. An oil-in-water emulsion can be produced.

油脂Aとしては、構成脂肪酸に占めるラウリン酸の割合が35質量%以上であるラウリン系油脂を用いることができる。ラウリン系油脂としては、例えば、パーム核油、ヤシ油、ババス油、及びこれらの分別油等を用いることができる。これらは1種単独で用いてもよく、2種以上を混合して用いてもよい。 As the fat / oil A, a lauric-based fat / oil in which the ratio of lauric acid to the constituent fatty acids is 35% by mass or more can be used. As the lauric oil and fat, for example, palm kernel oil, coconut oil, babassu oil, fractionated oils thereof and the like can be used. These may be used alone or in combination of two or more.

植物性油脂中の油脂Aの含有量は、好ましくは30質量%以上であり、より好ましくは35質量以上65質量%以下であり、さらに好ましくは40質量%以上60質量%以下である。また、植物性油脂中の、油脂Aの含有量は、下記の油脂Bの含有量よりも多いこと(油脂Aの含有量/油脂Bの含有量>1)が好ましい。油脂Aの含有量が油脂Bの含有量よりも多いことで、乳化安定性が良好であり、冷涼感と瑞々しさを有するホイップドクリームが得られる、起泡性水中油型乳化物を製造できる。 The content of the fat A in the vegetable fat is preferably 30% by mass or more, more preferably 35% by mass or more and 65% by mass or less, and further preferably 40% by mass or more and 60% by mass or less. Further, it is preferable that the content of the fat A in the vegetable fat is higher than the content of the following fat B (content of fat A / content of fat B> 1). Since the content of fat A is higher than the content of fat B, a foamable oil-in-water emulsion is produced, which has good emulsion stability and can obtain a whipped cream having a cool feeling and freshness. it can.

(油脂B)
油脂Bは、エステル交換油脂であって、構成脂肪酸に占めるラウリン酸の割合が35質量%未満であり、好ましくは1質量%以上30質量%以下、より好ましくは5質量%以上25質量%以下であり、さらに好ましくは10質量%以上20質量%である。また、ヨウ素価が25以上55以下であり、好まし28以上52以下であり、より好ましくは31以上49以下であり、さらに好ましくは34以上46以下である。油脂Bは、構成脂肪酸に占めるラウリン酸の割合およびヨウ素価が上記数値範囲内であれば、乳化安定性が良好であり、冷涼感と瑞々しさを有するホイップドクリームが得られる、起泡性水中油型乳化物を製造できる。
(Fat B)
The fat and oil B is a transesterified fat and oil in which the ratio of lauric acid to the constituent fatty acids is less than 35% by mass, preferably 1% by mass or more and 30% by mass or less, and more preferably 5% by mass or more and 25% by mass or less. Yes, more preferably 10% by mass or more and 20% by mass. Further, the iodine value is 25 or more and 55 or less, preferably 28 or more and 52 or less, more preferably 31 or more and 49 or less, and further preferably 34 or more and 46 or less. When the ratio of lauric acid to the constituent fatty acids and the iodine value of the oil / fat B are within the above numerical ranges, the emulsion stability is good, and a whipped cream having a cool feeling and freshness can be obtained. An oil-in-water emulsion can be produced.

油脂Bは、パーム系油脂と上記のラウリン系油脂を含む混合油脂をエステル交換反応することによって得ることができる。ここで、パーム系油脂は、パーム油およびパーム油を原料とする加工油脂(分別油脂、エステル交換油脂、硬化油脂など)を意味する。パーム系油脂としては、パーム油、パーム分別油、パームエステル交換油、パーム極度硬化油等を用いることができる。これらは1種単独で用いてもよく、2種以上を混合して用いてもよい。 The fat and oil B can be obtained by transesterifying the mixed fat and oil containing the palm-based fat and oil and the above-mentioned lauric-based fat and oil. Here, palm-based fats and oils mean palm oils and processed fats and oils made from palm oil (separated fats and oils, transesterified fats and oils, hardened fats and oils, etc.). As the palm-based oil and fat, palm oil, palm fractionated oil, palm transesterification oil, palm extremely hydrogenated oil and the like can be used. These may be used alone or in combination of two or more.

上記のパーム分別油は、好ましくはヨウ素価10〜70のパーム分別油であり、より好ましくはヨウ素価30〜60のパーム分別油である。ヨウ素価10〜70のパーム分別油の具体例としては、例えば、パームオレイン(パーム油を分別して得られる低融点部)、パームスーパーオレイン(パームオレインを分別して得られる低融点部)、パームステアリン、ハードパームステアリン(パームステアリンを分別して得られる高融点部)、パーム中融点部、ハードPMF等が挙げられる。パーム分別油は、2種以上を併用して使用することもできる。
上記のパームエステル交換油は、パーム油やパーム分別油をエステル交換したものである。パームエステル交換油は、2種以上の混合油をエステル交換したものでもよい。パームエステル交換油は、好ましくはパームオレインのランダムエステル交換油であり、より好ましくはヨウ素価50〜60のパームオレインのランダムエステル交換油である。
上記のパーム極度硬化油は、パーム油やパーム分別油を完全水素添加したものである。パーム極度硬化油は、2種以上の混合油を完全水素添加したものでもよい。パーム極度硬化油は、好ましくはパーム油の極度硬化油である。
The above-mentioned palm fractionated oil is preferably a palm fractionated oil having an iodine value of 10 to 70, and more preferably a palm fractionated oil having an iodine value of 30 to 60. Specific examples of the palm fractionated oil having an iodine value of 10 to 70 include palm olein (a low melting point portion obtained by separating palm oil), palm super olein (a low melting point portion obtained by separating palm olein), and palm stearin. , Hard palm stearin (high melting point portion obtained by separating palm stearin), palm medium melting point portion, hard PMF and the like. Two or more types of palm fractionated oil can be used in combination.
The above palm transesterification oil is a transesterification of palm oil or palm fractionated oil. The palm transesterified oil may be a mixture of two or more kinds of mixed oils transesterified. The palm transesterification oil is preferably a random transesterification oil of palm olein, and more preferably a random transesterification oil of palm olein having an iodine value of 50 to 60.
The above-mentioned palm extremely hydrogenated oil is a completely hydrogenated palm oil or palm fractionated oil. The palm extremely hydrogenated oil may be a mixture of two or more kinds of oils completely hydrogenated. The palm extremely hardened oil is preferably a palm oil extremely hardened oil.

植物性油脂中の油脂Bの含有量は、好ましくは15質量%以上であり、より好ましくは20質量以上50質量%以下であり、さらに好ましくは25質量%以上40質量%以下である。 The content of fats and oils B in the vegetable fats and oils is preferably 15% by mass or more, more preferably 20% by mass or more and 50% by mass or less, and further preferably 25% by mass or more and 40% by mass or less.

油脂Bを得るためのエステル交換反応は、特に制限されない。しかし、好ましくはランダムエステル交換反応(非選択的エステル交換反応又は位置特異性の低いエステル交換反応とも言う。)である。エステル交換反応は、通常の方法により行うことができる。エステル交換反応は、ナトリウムメトキシド等の合成触媒を使用した化学的エステル交換、リパーゼ(位置特異性の低いリパーゼ)を触媒とした酵素的エステル交換のどちらの方法でも行うことができる。 The transesterification reaction for obtaining the fat B is not particularly limited. However, a random transesterification reaction (also referred to as a non-selective transesterification reaction or a transesterification reaction having low position specificity) is preferable. The transesterification reaction can be carried out by a usual method. The transesterification reaction can be carried out by either a chemical transesterification method using a synthetic catalyst such as sodium methoxide or an enzymatic transesterification method using a lipase (lipase having low position specificity) as a catalyst.

化学的エステル交換は、例えば、原料油脂を十分に乾燥させ、ナトリウムメトキシドを原料油脂に対して0.1〜1質量%添加した後、減圧下、80〜120℃で0.5〜1時間攪拌しながら反応を行うことができる。 For chemical transesterification, for example, the raw material fat and oil are sufficiently dried, sodium methoxide is added in an amount of 0.1 to 1% by mass based on the raw material fat and oil, and then the pressure is reduced to 80 to 120 ° C. for 0.5 to 1 hour. The reaction can be carried out with stirring.

酵素的エステル交換は、例えば、リパーゼ粉末又は固定化リパーゼを原料油脂に対して0.02〜10質量%、好ましくは0.04〜5質量%添加した後、40〜80℃、好ましくは40〜70℃で0.5〜48時間、好ましくは0.5〜24時間攪拌しながら反応を行うことができる。 For enzymatic transesterification, for example, 0.02 to 10% by mass, preferably 0.04 to 5% by mass of lipase powder or immobilized lipase is added to the raw material fat and oil, and then 40 to 80 ° C., preferably 40 to 40 to 80 ° C. The reaction can be carried out at 70 ° C. for 0.5 to 48 hours, preferably 0.5 to 24 hours with stirring.

(油脂C)
油脂Cは、UUU型トリグリセリド含有量が60質量%以上であり、好ましくは65質量%以上90質量%以下であり、より好ましくは70質量%以上85質量%以下であり、さらに好ましくは70質量%以上80質量%以下である。
(Fat C)
The fat and oil C has a UUU-type triglyceride content of 60% by mass or more, preferably 65% by mass or more and 90% by mass or less, more preferably 70% by mass or more and 85% by mass or less, and further preferably 70% by mass. It is 80% by mass or less.

油脂Cとしては、従来公知の植物性液状油脂を用いることができる。植物性液状油脂としては、例えば、ナタネ油(キャノーラ油等)、米油、大豆油、コーン油、綿実油、ヒマワリ油、ゴマ油、オリーブ油などが挙げられる。これらは1種単独で用いてもよく、2種以上を混合して用いてもよい。 As the fat and oil C, conventionally known vegetable liquid fats and oils can be used. Examples of vegetable liquid fats and oils include rapeseed oil (canola oil and the like), rice oil, soybean oil, corn oil, cottonseed oil, sunflower oil, sesame oil, olive oil and the like. These may be used alone or in combination of two or more.

植物性油脂中の油脂Cの含有量は、好ましくは7質量%以上であり、より好ましくは10質量以上30質量%以下であり、さらに好ましくは13質量%以上27質量%以下である。 The content of fats and oils C in the vegetable fats and oils is preferably 7% by mass or more, more preferably 10% by mass or more and 30% by mass or less, and further preferably 13% by mass or more and 27% by mass or less.

(その他の油脂)
その他の油脂は、上記油脂A〜C以外であれば特に限定されず、従来公知の油脂を用いることができる。その他の油脂としては、例えば、上記のパーム系油脂や、乳脂等を用いることができる。
(Other fats and oils)
The other fats and oils are not particularly limited as long as they are other than the above fats and oils A to C, and conventionally known fats and oils can be used. As the other fats and oils, for example, the above-mentioned palm-based fats and oils, milk fat and the like can be used.

起泡性水中油型乳化物の原材料として、生クリーム、バター、チーズ等を配合することにより、起泡性水中油型乳化物に乳脂を含有させることができる。 By blending fresh cream, butter, cheese or the like as a raw material for the foamable oil-in-water emulsion, the emulsion can be contained in the oil-in-water emulsion.

起泡性水中油型乳化物に含まれる油脂中の乳脂の含有量は、良好な冷涼感と瑞々しさを得るために、1質量%以上55質量%以下であることが好ましく、1質量%以上30質量%以下であることがより好ましく、1質量%以上20質量%以下であることが更に好ましく、1質量%以上5質量%以下であることが特に好ましい。 The content of milk fat in the fat and oil contained in the foamable oil-in-water emulsion is preferably 1% by mass or more and 55% by mass or less in order to obtain a good cool feeling and freshness. It is more preferably 30% by mass or less, further preferably 1% by mass or more and 20% by mass or less, and particularly preferably 1% by mass or more and 5% by mass or less.

(植物性油脂中のトリグリド組成)
植物性油脂中のUUU型トリグリセリド含有量は、14質量%以上24質量%以下であり、好ましくは15質量%以上23質量%以下である。植物性油脂中のUUU型トリグリセリド含有量が上記数値範囲内であれば、乳化安定性が良好であり、冷涼感と瑞々しさを有するホイップドクリームが得られる、起泡性水中油型乳化物を製造できる。
(Triglide composition in vegetable oils and fats)
The UUU-type triglyceride content in the vegetable oil is 14% by mass or more and 24% by mass or less, preferably 15% by mass or more and 23% by mass or less. When the UUU-type triglyceride content in the vegetable oil is within the above numerical range, a whipped cream having good emulsion stability and a cool feeling and freshness can be obtained. Can be manufactured.

植物性油脂中のS2U型トリグリセリド含有量は、好ましくは6.0質量%以下であり、より好ましくは5.0質量%以下であり、さらに好ましくは4.0質量%以下である。また、油脂中にS2U型トリグリセリドは含まれていなくてもよいが、植物性油脂中のS2U型トリグリセリド含有量は、0.1質量%以上でもよく、1.0質量%以上でもよく、2.0質量以上でもよい。植物性油脂中のS2U型トリグリセリド含有量が上記数値範囲内であれば、乳化安定性が良好であり、冷涼感と瑞々しさを有するホイップドクリームが得られる、起泡性水中油型乳化物を製造できる。 The content of S2U-type triglyceride in the vegetable oil is preferably 6.0% by mass or less, more preferably 5.0% by mass or less, and further preferably 4.0% by mass or less. Further, although the S2U type triglyceride may not be contained in the fat and oil, the content of the S2U type triglyceride in the vegetable fat and oil may be 0.1% by mass or more, or 1.0% by mass or more. It may be 0 mass or more. If the content of S2U-type triglyceride in the vegetable oil is within the above numerical range, a whipped cream having good emulsion stability and a cool feeling and freshness can be obtained. Can be manufactured.

(乳化剤)
乳化剤としては、例えば、モノグリセリン脂肪酸エステル、有機酸モノグリセリド、レシチン、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリソルベート(ポリオキシエチレンソルビタン脂肪酸エステル)等が用いられる。これらの中でもモノグリセリン脂肪酸エステルを用いることが好ましく、モノグリセリン脂肪酸エステルに、レシチン及び/又はポリソルベートを併用することがより好ましい。
(emulsifier)
As the emulsifier, for example, monoglycerin fatty acid ester, organic acid monoglyceride, lecithin, sucrose fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, polysorbate (polyoxyethylene sorbitan fatty acid ester) and the like are used. Among these, it is preferable to use a monoglycerin fatty acid ester, and it is more preferable to use lecithin and / or polysorbate in combination with the monoglycerin fatty acid ester.

モノグリセリン脂肪酸エステルは、結晶核を形成しやすいという観点からは、構成脂肪酸として飽和脂肪酸を含むものが好ましく、中でも、ベヘン酸、ステアリン酸、パルミチン酸がより好ましく、ベヘン酸がさらに好ましい。このようなモノグリセリン飽和脂肪酸エステルを使用すると、核形成が起こりやすく、乳化安定性の良い起泡性水中油型乳化物が得られ易い。上記モノグリセリン脂肪酸エステルとしては、例えば、理研ビタミン社製のエマルジーMS、エマルジーP−100、ポエムB−100などを使用できる。 The monoglycerin fatty acid ester preferably contains a saturated fatty acid as a constituent fatty acid from the viewpoint of easily forming crystal nuclei, and among them, behenic acid, stearic acid, and palmitic acid are more preferable, and behenic acid is further preferable. When such a monoglycerin saturated fatty acid ester is used, nucleation is likely to occur, and a foamable oil-in-water emulsion having good emulsion stability can be easily obtained. As the monoglycerin fatty acid ester, for example, Emulgy MS, Emulgy P-100, Poem B-100 manufactured by RIKEN Vitamin Co., Ltd. can be used.

120℃以上で殺菌する超高温殺菌(UHT)を行う場合には、乳タンパクの凝集を抑え乳化安定性を高める観点から、モノグリセリン脂肪酸エステルと、有機酸モノグリセリドとを組み合わせることが好ましい。有機酸モノグリセリドとは、モノグリセリドの水酸基にさらに有機酸が結合したものである。有機酸としてはクエン酸、コハク酸、酢酸、および乳酸等が挙げられ、クエン酸およびコハク酸が好ましく、クエン酸がより好ましい。有機酸モノグリセリドとしては、例えば、太陽化学社製のサンソフト621B(クエン酸モノグリセリド)、サンソフト681SPV(コハク酸モノグリセリド)を用いることが好ましい。 When performing ultra-high temperature sterilization (UHT) in which sterilization is performed at 120 ° C. or higher, it is preferable to combine monoglycerin fatty acid ester and organic acid monoglyceride from the viewpoint of suppressing aggregation of milk proteins and enhancing emulsion stability. The organic acid monoglyceride is one in which an organic acid is further bonded to the hydroxyl group of the monoglyceride. Examples of the organic acid include citric acid, succinic acid, acetic acid, lactic acid and the like, with citric acid and succinic acid being preferable, and citric acid being more preferable. As the organic acid monoglyceride, for example, Sunsoft 621B (citric acid monoglyceride) and Sunsoft 681SPV (succinic acid monoglyceride) manufactured by Taiyo Kagaku Co., Ltd. are preferably used.

レシチンは、ホスファチジルコリン、ホスファチジルエタノールアミン、ホスファチジルイノシトール、ホスファチジン酸、ホスファチジルセリン等のリン脂質が主成分であり、大豆、卵等から得られるペースト状のレシチンや、これを粉末化した高純度レシチン、溶剤で分画した分画レシチン、酵素処理したリゾレシチン等を使用できる。 Lecithin is mainly composed of phospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, phosphatidylate, and phosphatidylserine, and is a paste-like lecithin obtained from soybeans, eggs, etc. Fractional lecithin fractionated in, enzyme-treated lysolecithin, etc. can be used.

起泡性水中油型乳化物における乳化剤の含有量は、起泡性水中油型乳化物全量に対して好ましくは0.1質量%以上2.0質量%以下であり、より好ましくは0.2質量%以上1.5質量%以下である。 The content of the emulsifier in the foamable oil-in-water emulsion is preferably 0.1% by mass or more and 2.0% by mass or less, more preferably 0.2, based on the total amount of the oil-in-water emulsion in foaming. It is mass% or more and 1.5 mass% or less.

また、本発明の起泡性水中油型乳化物は、良好な風味及び乳化安定性を得るために、無脂乳固形分を含んでいてもよい。無脂乳固形分は、無脂肪牛乳、低脂肪牛乳、加工乳、脱脂乳、脱脂粉乳、脱脂濃縮乳、クリーム等の各種乳製品に含まれており、これらの乳製品を配合することにより、本発明の起泡性水中油型乳化物に所定量の無脂乳固形分を含ませることができる。 In addition, the foamable oil-in-water emulsion of the present invention may contain a non-fat milk solid content in order to obtain good flavor and emulsion stability. Non-fat milk solids are contained in various dairy products such as non-fat milk, low-fat milk, processed milk, skim milk, skim milk powder, skim concentrated milk, cream, etc. By blending these dairy products, The foamable oil-in-water emulsion of the present invention can contain a predetermined amount of non-fat milk solids.

起泡性水中油型乳化物における無脂乳固形分の含有量は、起泡性水中油型乳化物全量に対して好ましくは3質量%以上8質量%以下であり、より好ましくは4質量%以上6質量%以下である。 The content of the non-fat milk solid content in the foamable oil-in-water emulsion is preferably 3% by mass or more and 8% by mass or less, more preferably 4% by mass, based on the total amount of the oil-in-water emulsion in foaming. It is 6% by mass or less.

[起泡性水中油型乳化物の製造方法]
本発明の起泡性水中油型乳化物は、例えば、殺菌、均質化、冷却、エージングを順次行う手順で製造することができる。
[Manufacturing method of foaming oil-in-water emulsion]
The foamable oil-in-water emulsion of the present invention can be produced, for example, by sequentially performing sterilization, homogenization, cooling, and aging.

まず、油脂、乳化剤、水などの各成分を混合して予備乳化する。予備乳化には、攪拌可能なタンクやホモミキサーなどを用いることができる。乳化剤は水相、油相のいずれに添加してもよいが、油相に添加しておくことが好ましい。また、脱脂濃縮乳や塩類等を用いる場合、これらは予め水に溶解して用いる。予備乳化は、油相については配合油脂が完全に溶解する温度に加温し、水相については混合後の油相が温度低下を起こさない温度に加温し、油相と水相を混合し、例えば60〜75℃で行うことができる。 First, each component such as fat, emulsifier, and water is mixed and pre-emulsified. For pre-emulsification, a stirable tank, a homomixer, or the like can be used. The emulsifier may be added to either the aqueous phase or the oil phase, but it is preferably added to the oil phase. When defatted concentrated milk, salts, etc. are used, they are dissolved in water in advance before use. In the pre-emulsification, the oil phase is heated to a temperature at which the compounded oil and fat are completely dissolved, and the aqueous phase is heated to a temperature at which the mixed oil phase does not cause a temperature drop, and the oil phase and the aqueous phase are mixed. For example, it can be carried out at 60 to 75 ° C.

予備乳化した後、均質化を行う。均質化は、ホモジナイザーを用いて、従来より起泡性水中油型乳化物の製造に用いられている圧力等の条件を適宜に設定して行うことができる。この均質化の工程において油滴のメディアン径を調整することができる。なお、均質化については、殺菌前に行う前均質であっても、殺菌の後に行う後均質であってもよく、また、前均質及び後均質の両者を組み合わせた二段均質であってもよい。なお、殺菌の方法については、バッチ殺菌、直接加熱殺菌(インジェクション式、インフュージョン式)、間接加熱殺菌(プレート式、チューブラー式、シェル&チューブ式、バッチ式)等の従来公知の殺菌方法を用いることができ、殺菌のレベルとしては、高温短時間殺菌法(HTST)や120℃以上で殺菌する超高温殺菌(UHT)等を適宜選択すればよい。 After pre-emulsification, homogenization is performed. The homogenization can be carried out by using a homogenizer and appropriately setting conditions such as pressure that have been conventionally used for producing a foamable oil-in-water emulsion. In this homogenization step, the median diameter of the oil droplet can be adjusted. Regarding homogenization, it may be pre-homogeneous before sterilization, post-homogeneous after sterilization, or two-stage homogeneity that is a combination of both pre-homogeneous and post-homogeneous. .. As for the sterilization method, conventionally known sterilization methods such as batch sterilization, direct heat sterilization (injection type, infusion type), and indirect heat sterilization (plate type, tubular type, shell & tube type, batch type) are used. As the level of sterilization, a high-temperature short-time sterilization method (HTST) or an ultra-high-temperature sterilization (UHT) that sterilizes at 120 ° C. or higher may be appropriately selected.

その後、乳化物を冷却することにより、本発明の起泡性水中油型乳化物を製造することができる。冷却は、短時間で目的の温度まで冷却できる設備を用いて行うことが好ましく、このような設備としては、例えば、プレート式熱交換器、チューブ式熱交換器、掻き取り式熱交換器などを挙げることができ、このような設備を用いて短時間で1〜7℃の温度範囲まで冷却することが好ましい。このような温度範囲であると、製品の粘度増加も抑制できる。冷却後、例えば1〜2日程度放置し安定化させる(エージング)。その後、充填され、製品となる。 Then, by cooling the emulsion, the foamable oil-in-water emulsion of the present invention can be produced. Cooling is preferably performed using equipment that can cool to the target temperature in a short time, and examples of such equipment include a plate heat exchanger, a tube heat exchanger, and a scraping heat exchanger. It can be mentioned, and it is preferable to cool to a temperature range of 1 to 7 ° C. in a short time by using such equipment. Within such a temperature range, an increase in the viscosity of the product can be suppressed. After cooling, it is left to stabilize for about 1 to 2 days (aging). After that, it is filled and becomes a product.

[ホイップドクリーム]
本発明のホイップドクリームは、本発明の起泡性水中油型乳化物を起泡してなるものである。具体的には、例えば、本発明の起泡性水中油型乳化物を、泡立器具、または専用のミキサーを用いて空気を抱き込ませるように攪拌することによって、起泡状態を呈するホイップドクリームを製造することができる。なお、ホイップする際に、グラニュー糖、砂糖、液糖などの糖類や、アルコール類、香料、増粘安定剤、生クリーム等を添加してもよい。
[Whipped cream]
The whipped cream of the present invention is obtained by foaming the foamable oil-in-water emulsion of the present invention. Specifically, for example, the foamable oil-in-water emulsion of the present invention is whipped to exhibit a foaming state by stirring it using a foaming device or a dedicated mixer so as to embrace air. Cream can be produced. When whipping, sugars such as granulated sugar, sugar, and liquid sugar, alcohols, flavors, thickening stabilizers, fresh cream, and the like may be added.

上記のようにして得られたホイップドクリームは、食品の各種用途、例えば、ショートケーキ等のナッペ用や、ロールケーキ、パン、パイ、シュー、デニッシュ、クッキー、ビスケット等のサンド用等に好適に用いることができる。 The whipped cream obtained as described above is suitable for various uses of foods, for example, for nappes such as shortcakes, and for sands such as roll cakes, breads, pies, shoes, Danish pastries, cookies and biscuits. Can be used.

以下、本発明を実施例によってさらに詳細に説明する。しかし、本発明は以下の実施例の内容に限定して解釈されない。 Hereinafter, the present invention will be described in more detail by way of examples. However, the present invention is not construed as being limited to the contents of the following examples.

<分析>
油脂中のUUU型トリグリセリド含有量及びS2U型トリグリセリド含有量は、ガスクロマトグラフ法(JAOCS,vol70,11,1111−1114(1993))に準じて測定した。
ヨウ素価は、基準油脂分析試験法(2.3.4.1−1996)に従い、ウィイス−シクロヘキサン法により測定した値である。
<Analysis>
The UUU-type triglyceride content and the S2U-type triglyceride content in fats and oils were measured according to a gas chromatograph method (JAOCS, vol70, 11, 1111-1114 (1993)).
The iodine value is a value measured by the Wies-cyclohexane method according to the standard fat analysis test method (2.3.4.1-1996).

<油脂原料>
油脂A:
パーム核油(ヨウ素価18.1、ラウリン酸含有量46.2質量%、日清オイリオグループ株式会社製)を油脂A−1として使用した。
油脂B:
60質量部のパーム油と40質量部のパーム核油との混合油をランダムエステル交換した油脂(ヨウ素価39.1、ラウリン酸含有量18.8質量%)を油脂B−1として使用した。
油脂C:
菜種油(UUU型トリグリセリド含有量81.5質量%、日清オイリオグループ株式会社製)を油脂C−1として使用した。
ハイオレイック菜種油(UUU型トリグリセリド含有量81.3質量%、日清オイリオグループ株式会社製)を油脂C−2として使用した。
その他油脂:
パーム油(S2U型トリグリセリド含有量44.9質量%、日清オイリオグループ株式会社製)を、その他油脂(略号:PMO)として使用した。
パーム油中融点画分(S2U型トリグリセリド含有量67.5質量%、日清オイリオグループ株式会社製)を、その他油脂(略号:PMF)として使用した。
パーム核部分硬化油(ヨウ素価6.9、ラウリン酸含有量46.2質量%、日清オイリオグループ株式会社製)を、その他油脂(略号:PHPKO)として使用した。
<Raw materials for fats and oils>
Oil A:
Palm kernel oil (iodine value 18.1, lauric acid content 46.2% by mass, manufactured by Nisshin Oillio Group Co., Ltd.) was used as fat and oil A-1.
Oil B:
A fat and oil (iodine value 39.1, lauric acid content 18.8% by mass) obtained by randomly transesterifying a mixed oil of 60 parts by mass of palm oil and 40 parts by mass of palm kernel oil was used as the fat and oil B-1.
Oil C:
Rapeseed oil (UUU type triglyceride content 81.5% by mass, manufactured by Nisshin Oillio Group Co., Ltd.) was used as fat and oil C-1.
Hyoleic rapeseed oil (UUU type triglyceride content 81.3% by mass, manufactured by Nisshin Oillio Group Co., Ltd.) was used as fat and oil C-2.
Other fats and oils:
Palm oil (S2U type triglyceride content 44.9% by mass, manufactured by Nisshin Oillio Group Co., Ltd.) was used as other fats and oils (abbreviation: PMO).
The melting point fraction in palm oil (S2U type triglyceride content 67.5% by mass, manufactured by Nisshin Oillio Group Co., Ltd.) was used as other fats and oils (abbreviation: PMF).
Partially hydrogenated palm kernel oil (iodine value 6.9, lauric acid content 46.2% by mass, manufactured by Nisshin Oillio Group Co., Ltd.) was used as other fats and oils (abbreviation: PHPKO).

<乳化剤>
ベヘン酸モノグリセリド(商品名:ポエムB−100、理研ビタミン株式会社製)
ステアリン酸モノグリセリド(商品名:エマルジーMS、理研ビタミン株式会社製)
ソルビタンステアリン酸エステル(商品名:ポエムS−250K、理研ビタミン株式会社製)
クエン酸モノグリセリド(商品名:サンソフト621B、太陽化学株式会社製)
ショ糖ステアリン酸エステル(商品名:リョートーシュガーエステルS−1670、三菱ケミカルフーズ株式会社製)
ポリソルベート(商品名エマゾールO−120V、花王株式会社製)
リゾレシチン(商品名:EMULTOP IP、カーギルジャパン株式会社製)
レシチン(商品名:YELKIN、Archer Daniels Midland Company社製)
<Emulsifier>
Behenic acid monoglyceride (trade name: Poem B-100, manufactured by RIKEN Vitamin Co., Ltd.)
Stearic acid monoglyceride (trade name: Emulgy MS, manufactured by RIKEN Vitamin Co., Ltd.)
Sorbitan stearic acid ester (trade name: Poem S-250K, manufactured by RIKEN Vitamin Co., Ltd.)
Citric acid monoglyceride (trade name: Sunsoft 621B, manufactured by Taiyo Kagaku Co., Ltd.)
Sucrose stearic acid ester (trade name: Ryoto Sugar Ester S-1670, manufactured by Mitsubishi Chemical Foods Co., Ltd.)
Polysorbate (trade name: Emazole O-120V, manufactured by Kao Corporation)
Lysolecithin (trade name: EMULTOP IP, manufactured by Cargill Japan Limited)
Lecithin (trade name: YELKIN, manufactured by Archer Daniels Midland Company)

<油脂の配合>
油脂原料を、表1および2に示す配合(質量%)で混合し、例1〜12の油脂を調製した。調製した油脂の分析値を表1及び2に示した。
<Mixing of fats and oils>
The fats and oils raw materials were mixed in the formulations (mass%) shown in Tables 1 and 2 to prepare the fats and oils of Examples 1 to 12. The analytical values of the prepared fats and oils are shown in Tables 1 and 2.

Figure 2020130182
Figure 2020130182

Figure 2020130182
Figure 2020130182

<起泡性水中油型乳化物の製造1>
41.5質量部の例1〜12の各油脂に、0.04質量部のレシチン、0.08質量部のベヘン酸モノグリセリド及び0.08質量部のリゾレシチン、を溶解させて油相を調製した。同時に、39.0質量部の水に、16.0質量部の脱脂濃縮乳(無脂乳固形分含有量32質量%)、3.12質量部の粉飴、0.1質量部のリン酸塩及び0.08質量部のポリソルベート、を溶解させて水相を調製した。次に、水相に油相を加え、60〜70℃に調温しながら、ホモミキサーにて予備乳化を行い、予備乳化後6MPaの圧力下で均質化した。その後、85℃、15分のバッチ殺菌を行い、約10℃まで冷却した。その後5℃の冷蔵庫にて約18時間エージングを行い、例1〜12の起泡性水中油型乳化物を得た。
<Manufacturing of foamable oil-in-water emulsion 1>
An oil phase was prepared by dissolving 0.04 parts by mass of lecithin, 0.08 parts by mass of bechenic acid monoglyceride and 0.08 parts by mass of lysolecithin in each of 41.5 parts by mass of Examples 1 to 12. .. At the same time, in 39.0 parts by mass of water, 16.0 parts by mass of defatted concentrated milk (non-fat milk solid content 32% by mass), 3.12 parts by mass of powdered candy, and 0.1 parts by mass of phosphate. An aqueous phase was prepared by dissolving salt and 0.08 parts by mass of polysorbate. Next, an oil phase was added to the aqueous phase, and pre-emulsification was performed with a homomixer while adjusting the temperature to 60 to 70 ° C., and after pre-emulsification, homogenization was performed under a pressure of 6 MPa. Then, batch sterilization was performed at 85 ° C. for 15 minutes, and the mixture was cooled to about 10 ° C. Then, it was aged in a refrigerator at 5 ° C. for about 18 hours to obtain a foamable oil-in-water emulsion of Examples 1 to 12.

<起泡性水中油型乳化物の分析・評価1>
例1〜12の起泡性水中油型乳化物について、それぞれ、以下のホイップ適性の指標となる分析・評価を行った。結果を表3及び4に示した。
<Analysis and evaluation of foamable oil-in-water emulsion 1>
The foamable oil-in-water emulsions of Examples 1 to 12 were analyzed and evaluated as the following indicators of whip suitability, respectively. The results are shown in Tables 3 and 4.

1.瑞々しさ
十分立てにした各起泡性水中油型乳化物(ホイップドクリーム)を食して、各サンプルの瑞々しさを、以下に示す4段階基準に従い、専門パネラー(6名)により点数付けした。平均点に応じて、以下の通り◎、○、△、×の4段階で各サンプルの瑞々しさを評価した。
〔点数付けの基準〕
3:非常に瑞々しかった。
2:瑞々しかった。
1:瑞々しさが乏しかった。
0:ドライであった。
〔評価基準〕
評価◎:2.5点以上
評価○:1.5点以上2.5点未満
評価△:0.8点以上1.5点未満
評価×:0.8点未満
1. 1. Eat each foaming oil-in-water emulsion (whipped cream) that has been sufficiently fresh, and score the freshness of each sample by specialized panelists (6 people) according to the following 4-step criteria. did. The freshness of each sample was evaluated on a scale of ⊚, ◯, Δ, and × according to the average score as follows.
[Criteria for scoring]
3: It was very fresh.
2: It was fresh.
1: The freshness was poor.
0: It was dry.
〔Evaluation criteria〕
Evaluation ⊚: 2.5 points or more Evaluation ○: 1.5 points or more and less than 2.5 points Evaluation △: 0.8 points or more and less than 1.5 points Evaluation ×: less than 0.8 points

2.冷涼感
十分立てにした各起泡性水中油型乳化物(ホイップドクリーム)を食して、各サンプルの冷涼感を、以下に示す4段階評価基準に従い、専門パネラー(6名)により点数付けした。平均点に応じて、以下の通り◎、○、△、×の4段階で各サンプルの冷涼感を評価した。
〔評価基準〕
3:非常に冷涼感が感じられた。
2:冷涼感が感じられた。
1:やや冷涼感が感じられた。
0:冷涼感が感じられなかった。
〔評価基準〕
評価◎:2.5点以上
評価○:1.5点以上2.5点未満
評価△:0.8点以上1.5点未満
評価×:0.8点未満
2. 2. By eating the foamable oil-in-water emulsion which was cool feel sufficiently stand (whipped cream), the cool feeling of each sample, in accordance with 4-stage evaluation criteria shown below were scored by expert panelists (6 persons) .. The coolness of each sample was evaluated on a scale of ⊚, ◯, Δ, and × according to the average score as follows.
〔Evaluation criteria〕
3: A very cool feeling was felt.
2: A feeling of coolness was felt.
1: A slightly cool feeling was felt.
0: No feeling of coolness was felt.
〔Evaluation criteria〕
Evaluation ⊚: 2.5 points or more Evaluation ○: 1.5 points or more and less than 2.5 points Evaluation △: 0.8 points or more and less than 1.5 points Evaluation ×: less than 0.8 points

3.乳化安定性
5℃で一晩以上保存した60gの各起泡性水中油型乳化物を100mlビーカーに入れ、20℃恒温槽で2時間静置し、調温した。プロペラ撹拌翼を付けたスリーワンモーターを用いてビーカー中の起泡性水中油型乳化物を20℃下、160rpmで撹拌し、起泡性水中油型乳化物が凝固・増粘するまでの時間を計測した。
〔評価基準〕
評価◎:非常に良好(50分以上)
評価○:良好(30分以上50分未満)
評価△:可(15分以上30分未満)
評価×:不可(15分未満)
3. 3. Emulsification stability 60 g of each foamable oil-in-water emulsion stored at 5 ° C. for one night or longer was placed in a 100 ml beaker and allowed to stand in a constant temperature bath at 20 ° C. for 2 hours to control the temperature. The foamable oil-in-water emulsion in the beaker is stirred at 160 rpm at 20 ° C. using a three-one motor equipped with a propeller stirring blade, and the time until the oil-in-water emulsion in foaming solidifies and thickens. I measured it.
〔Evaluation criteria〕
Evaluation ◎: Very good (50 minutes or more)
Evaluation ○: Good (30 minutes or more and less than 50 minutes)
Evaluation △: Yes (15 minutes or more and less than 30 minutes)
Evaluation ×: Not possible (less than 15 minutes)

Figure 2020130182
Figure 2020130182

Figure 2020130182
Figure 2020130182

<起泡性水中油型乳化物の製造2>
例4の油脂配合を使用して、ベヘン酸モノグリセリドをステアリン酸モノグリセリドに置き換えた以外は、<起泡性水中油型乳化物の製造1>と同様にして起泡性水中油型乳化物を調製した(例13)。また、例4の油脂配合を使用して、乳化剤を、0.25質量%のレシチン、0.0625質量%のベヘン酸モノグリセリド、0.0625質量%のソルビタン脂肪酸エステルおよび0.125質量%のショ糖脂肪酸エステルに置き換えた以外は、<起泡性水中油型乳化物の製造1>と同様にして起泡性水中油型乳化物を調製した(例14)。
<Manufacturing of foamable oil-in-water emulsion 2>
A foamable oil-in-water emulsion was prepared in the same manner as in <Production of foamable oil-in-water emulsion 1> except that the behenic acid monoglyceride was replaced with stearic acid monoglyceride using the oil-and-fat formulation of Example 4. (Example 13). Also, using the oil formulation of Example 4, the emulsifiers were 0.25% by weight lecithin, 0.0625% by weight bechenic acid monoglyceride, 0.0625% by weight sorbitan fatty acid ester and 0.125% by weight sho. A foamable oil-in-water emulsion was prepared in the same manner as in <Production of oil-in-water emulsion 1 in foaming> except that it was replaced with a sugar fatty acid ester (Example 14).

<起泡性水中油型乳化物の分析・評価2>
例13および例14の起泡性水中油型乳化物について、<起泡性水中油型乳化物の分析・評価1>と同様の評価を行った。結果、例13および例14とも、例4の評価結果と比較して、乳化安定性が○であった(例4は◎)以外は変わらなかった。
<Analysis / evaluation of foamable oil-in-water emulsion 2>
The foaming oil-in-water emulsions of Examples 13 and 14 were evaluated in the same manner as in <Analysis / Evaluation 1 of Foaming Oil-in-Water Emulsions>. As a result, both Example 13 and Example 14 did not change except that the emulsion stability was ◯ (in Example 4 was ⊚) as compared with the evaluation result of Example 4.

<起泡性水中油型乳化物の製造3>
上記<起泡性水中油型乳化物の製造1>において、例3の油脂配合を使用して、予備乳化した乳化物100質量部に対して、生クリーム(乳脂含有量35質量%、高梨乳業株式会社製)を5、20、30、57質量部の割合でそれぞれ混合した。各混合乳化物を6MPaの圧力下で均質化し、その後、85℃、15分のバッチ殺菌を行い、約10℃まで冷却した。その後5℃の冷蔵庫にて約18時間エージングを行い、例15〜18の起泡性水中油型乳化物を得た。
<Manufacturing of foamable oil-in-water emulsion 3>
In the above <Production of foaming oil-in-water emulsion 1>, fresh cream (milk fat content 35% by mass, Takanashi dairy industry) was used with respect to 100 parts by mass of the emulsion pre-emulsified using the oil and fat formulation of Example 3. Co., Ltd.) was mixed at a ratio of 5, 20, 30, and 57 parts by mass, respectively. Each mixed emulsion was homogenized under a pressure of 6 MPa, then batch sterilized at 85 ° C. for 15 minutes and cooled to about 10 ° C. Then, it was aged in a refrigerator at 5 ° C. for about 18 hours to obtain a foamable oil-in-water emulsion of Examples 15-18.

<起泡性水中油型乳化物の分析・評価3>
例15〜18の起泡性水中油型乳化物について、<起泡性水中油型乳化物の分析・評価1>と同様の評価を行った。結果を表5に示した。
<Analysis and evaluation of foamable oil-in-water emulsion 3>
The foamable oil-in-water emulsions of Examples 15 to 18 were evaluated in the same manner as in <Analysis / Evaluation 1 of oil-in-water emulsions with foaming properties>. The results are shown in Table 5.

Figure 2020130182
Figure 2020130182

<起泡性水中油型乳化物の製造4>
例3および例4の油脂配合をそれぞれ使用して、油脂の含有量を35.0質量%とし、水の含有量を45.5質量%に変更した以外は、<起泡性水中油型乳化物の製造1>と同様にして起泡性水中油型乳化物を調製した(例19および例20)。
<Manufacturing of foamable oil-in-water emulsion 4>
<Foamable oil-in-water emulsification, except that the oil and fat content was changed to 35.0% by mass and the water content was changed to 45.5% by mass by using the oil and fat formulations of Examples 3 and 4, respectively. Foamable oil-in-water emulsions were prepared in the same manner as in Production 1> (Examples 19 and 20).

<起泡性水中油型乳化物の分析・評価4>
例19および例20の起泡性水中油型乳化物について、<起泡性水中油型乳化物の分析・評価1>と同様の評価を行った。結果、例19および例20とも、例3および例4と同様の評価結果が得られた。
<Analysis and evaluation of foamable oil-in-water emulsion 4>
The foamable oil-in-water emulsions of Examples 19 and 20 were evaluated in the same manner as in <Analysis / Evaluation 1 of oil-in-water emulsions with foaming properties>. As a result, the same evaluation results as in Example 3 and Example 4 were obtained in both Example 19 and Example 20.

<起泡性水中油型乳化物の製造5>
38.5質量部の例4の油脂に、0.13質量部のレシチン、0.11質量部のステアリン酸モノグリセリド、0.08質量部のクエン酸モノグリセリド及び0.12質量部のソルビタンステアリン酸エステルを溶解させて油相を調製した。同時に、55.39質量部の水に、5.38質量部の脱脂粉乳(無脂乳固形分含有量95質量%)、0.10質量部のリン酸塩及び0.16質量部のポリソルベート及び0.03質量部のショ糖脂肪酸エステルを溶解させて水相を調製した。仕込みタンク内で水相に油相を加え、混合物を68℃〜72℃で15分間程度、撹拌しながら分散混合して予備乳化した。次いで、得られた予備乳化物を8.0Mpaで均質化し、続けて130℃10秒で間接殺菌(プレート式UHT殺菌)した。間接殺菌後にプレートで5℃まで冷却し、更に5℃の冷蔵庫で約18時間エージングすることにより、例21の起泡性水中油型乳化物を得た。
<Manufacturing of foamable oil-in-water emulsion 5>
In 38.5 parts by mass of the fat and oil of Example 4, 0.13 parts by mass of lecithin, 0.11 parts by mass of stearic acid monoglyceride, 0.08 parts by mass of citric acid monoglyceride and 0.12 parts by mass of sorbitan stearic acid ester. Was dissolved to prepare an oil phase. At the same time, 55.39 parts by mass of water, 5.38 parts by mass of defatted milk powder (non-fat milk solid content 95% by mass), 0.10 parts by mass of phosphate and 0.16 parts by mass of polysorbate and An aqueous phase was prepared by dissolving 0.03 parts by mass of sucrose fatty acid ester. The oil phase was added to the aqueous phase in the charging tank, and the mixture was dispersed and mixed at 68 ° C. to 72 ° C. for about 15 minutes with stirring to preemulsify. Then, the obtained preliminary emulsion was homogenized at 8.0 Mpa, followed by indirect sterilization (plate-type UHT sterilization) at 130 ° C. for 10 seconds. After indirect sterilization, the mixture was cooled to 5 ° C. on a plate and further aged in a refrigerator at 5 ° C. for about 18 hours to obtain a foamable oil-in-water emulsion of Example 21.

<起泡性水中油型乳化物の分析・評価5>
例21の起泡性水中油型乳化物について、<起泡性水中油型乳化物の分析・評価1>と同様の評価を行った。結果、例21は、例4と同様の評価結果が得られた。また、プレート式UHT殺菌を行った例21の起泡性水中油型乳化物において、凝固や著しい増粘は観察されず、乳化安定性は良好であった。
<Analysis and evaluation of foamable oil-in-water emulsion 5>
The foamable oil-in-water emulsion of Example 21 was evaluated in the same manner as in <Analysis / Evaluation 1 of the oil-in-water emulsion in foaming.> As a result, in Example 21, the same evaluation result as in Example 4 was obtained. In addition, in the foamable oil-in-water emulsion of Example 21 subjected to plate-type UHT sterilization, no coagulation or significant thickening was observed, and the emulsion stability was good.

Claims (8)

24質量%以上48質量%以下の、植物性油脂を含む油脂を含有する起泡性水中油型乳化物であって、
前記植物性油脂が、油脂A及び油脂Bを含み、かつ、前記植物性油脂中のUUU型トリグリセリド含有量が14質量%以上24質量%以下である、起泡性水中油型乳化物。
(ただし、油脂A、油脂B、及びUUU型トリグリセリドは、以下を意味する。
油脂A:構成脂肪酸に占めるラウリン酸の割合が35質量%以上であり、ヨウ素価が3〜30である、非硬化非エステル交換油脂。
油脂B:構成脂肪酸に占めるラウリン酸の割合が35質量%未満であり、ヨウ素価が18〜48である、エステル交換油脂。
UUU型トリグリセリド:炭素数16以上の不飽和脂肪酸(U)を構成脂肪酸とするトリグリセリド。)
A foamable oil-in-water emulsion containing oils and fats containing vegetable oils and fats of 24% by mass or more and 48% by mass or less.
A foamable oil-in-water emulsion in which the vegetable oil contains oil A and oil B, and the UUU-type triglyceride content in the vegetable oil is 14% by mass or more and 24% by mass or less.
(However, fat A, fat B, and UUU-type triglyceride mean the following.
Fats and oils A: Non-cured, transesterified fats and oils in which the ratio of lauric acid to the constituent fatty acids is 35% by mass or more and the iodine value is 3 to 30.
Fats and oils B: Transesterified fats and oils in which the proportion of lauric acid in the constituent fatty acids is less than 35% by mass and the iodine value is 18 to 48.
UUU-type triglyceride: A triglyceride containing an unsaturated fatty acid (U) having 16 or more carbon atoms as a constituent fatty acid. )
前記植物性油脂中のS2U型トリグリセリド含有量が6.0質量%以下である、請求項1に記載の起泡性水中油型乳化物。
(但し、S2U型トリグリセリドは、以下を意味する。
S2U型トリグリセリド:2つの炭素数16以上の飽和脂肪酸(S)と1つのUとを構成脂肪酸とするトリグリセリド。)
The foamable oil-in-water emulsion according to claim 1, wherein the content of S2U-type triglyceride in the vegetable oil is 6.0% by mass or less.
(However, S2U type triglyceride means the following.
S2U-type triglyceride: A triglyceride containing two saturated fatty acids (S) having 16 or more carbon atoms and one U as constituent fatty acids. )
前記植物性油脂中の前記油脂Aの含有量が前記油脂Bの含有量よりも多い、請求項1または2に記載の起泡性水中油型乳化物。 The foamable oil-in-water emulsion according to claim 1 or 2, wherein the content of the fat A in the vegetable fat is higher than the content of the fat B. 前記植物性油脂が、油脂Cをさらに含有する、請求項1〜3のいずれか一項に記載の起泡性水中油型乳化物。
(ただし、油脂Cは、以下を意味する。
油脂C:UUU型トリグリセリド含有量が60質量%以上である油脂。)
The foamable oil-in-water emulsion according to any one of claims 1 to 3, wherein the vegetable oil further contains the oil C.
(However, fat and oil C means the following.
Fats and oils C: Fats and oils having a UUU-type triglyceride content of 60% by mass or more. )
前記起泡性水中油型乳化物が、乳化剤として、レシチン及び/又はポリソルベートをさらに含有する、請求項1〜4のいずれか一項に記載の起泡性水中油型乳化物。 The foamable oil-in-water emulsion according to any one of claims 1 to 4, wherein the foaming oil-in-water emulsion further contains lecithin and / or polysorbate as an emulsifier. 前記起泡性水中油型乳化物が、乳化剤として、有機酸モノグリセリドをさらに含有する、請求項1〜5のいずれか一項に記載の起泡性水中油型乳化物。 The foamable oil-in-water emulsion according to any one of claims 1 to 5, wherein the foaming oil-in-water emulsion further contains an organic acid monoglyceride as an emulsifier. 前記起泡性水中油型乳化物が、乳化剤として、ベヘン酸モノグリセリドをさらに含有する、請求項1〜6のいずれか一項に記載の起泡性水中油型乳化物。 The foamable oil-in-water emulsion according to any one of claims 1 to 6, wherein the foamable oil-in-water emulsion further contains bechenic acid monoglyceride as an emulsifier. 請求項1〜7のいずれか一項に記載の起泡性水中油型乳化物を起泡してなる、ホイップドクリーム。 A whipped cream obtained by foaming the foamable oil-in-water emulsion according to any one of claims 1 to 7.
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