JP2012019766A - Foaming oil-in-water emulsified oil and fat composition for chilled distribution whipped cream - Google Patents

Foaming oil-in-water emulsified oil and fat composition for chilled distribution whipped cream Download PDF

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JP2012019766A
JP2012019766A JP2010162126A JP2010162126A JP2012019766A JP 2012019766 A JP2012019766 A JP 2012019766A JP 2010162126 A JP2010162126 A JP 2010162126A JP 2010162126 A JP2010162126 A JP 2010162126A JP 2012019766 A JP2012019766 A JP 2012019766A
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oil
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Tamio Arishima
民男 有島
Toshihide Isobe
敏秀 磯部
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Kaneka Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a foaming oil-in-water emulsified oil and fat composition for producing chilled distribution whipped cream extremely excellent in melting in the mouth when eating, like cotton candy, while retaining conventional shape retention.SOLUTION: This foaming oil-in-water emulsified oil and fat composition with 20-40 wt.% oil and fat content includes in the total oil and fat of an oil phase part, 10-40 wt.% of oil and fat (A) which has a total amount of ≥40 wt.% of triglyceride with a total carbon number of 36 and 38, as the constituent fatty acid, and has a rising melting point of ≥30°C, and 20-80 wt.% of oil and fat (B) as lauric oil and fat having 40-70% SFC at 15°C. The total amount of the oil and fat (A) and the oil and fat (B) is 60-100 wt.% in the total oil and fat of the oil phase part. Furthermore, the foaming oil-in-water emulsified oil and fat composition includes in the oil phase part, an emulsifier which has 0-5 HLB and behenic acid as the main constituent fatty acid, at 0.005-0.1 wt.% in the total foaming oil-in-water emulsified oil and fat composition, and is to be used for chilled distribution whipped cream.

Description

本発明は、チルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物に関する。   The present invention relates to a foamable oil-in-water emulsified oil / fat composition for chilled circulation whipped cream.

従来、製菓、デザート用途のホイップドクリームは、牛乳から分離して製造される天然の生クリームが用いられてきたが、コスト的に安価であり、物性、特にホイップ前の原液の保存安定性、ホイップ時の作業性、ホイップ後の作業性などが優れていることから、乳脂肪の一部を植物性油脂に置き換えたコンパウンドタイプや油脂全てを植物性油脂とした純植物性タイプなどのホイップドクリームが開発され、それが主流となりつつある。それら植物性油脂を用いたホイップドクリーム用起泡性水中油型乳化油脂組成物は、植物性油脂を組み合わせ、更に乳化剤、増粘剤などの改良剤を用いて乳化することで製造できることから、それら原料、特に油脂組成によってホイップドクリームの食感及び物性を大きく変更させることが可能である。昨今では、特にライトな食感を好む傾向にあり、口溶け感に重点が置かれている。   Conventionally, whipped cream for confectionery and dessert applications has been used natural fresh cream produced separately from milk, but it is inexpensive in terms of physical properties, especially the storage stability of the stock solution before whipping, Because of its excellent workability during whipping and workability after whipping, whipped such as compound type in which part of milk fat is replaced with vegetable oil and pure vegetable type in which all fat is vegetable oil Cream has been developed and is becoming mainstream. The foamable oil-in-water emulsified oil and fat composition for whipped cream using these vegetable oils and fats can be produced by combining vegetable oils and emulsifying using an improving agent such as an emulsifier and a thickener. It is possible to greatly change the texture and physical properties of the whipped cream depending on the raw materials, particularly the oil and fat composition. Nowadays, there is a tendency to prefer a particularly light texture, and emphasis is placed on the feeling of melting in the mouth.

ヤシ油やパーム核油などのラウリン系油脂は、口溶けなどがシャープで冷感を感じやすいSFCが縦型の油脂であり、それらの硬化油と共にホイップドクリーム用起泡性水中油型乳化油脂組成物に用いられ、主に低油分のライトクリームに使用されている。しかし、従来の硬化油脂を含むホイップドクリーム用起泡性水中油型乳化油脂組成物は、硬化によって生じる高融点成分を含有するために舌上で溶け難く、食感が悪化する。   Laurinic fats such as coconut oil and palm kernel oil are vertical fats and oils that have a sharp mouth melt and are easy to feel cold, and foamed oil-in-water emulsified oils for whipped cream along with their hardened oils. Used mainly in low-oil light cream. However, the conventional foamable oil-in-water emulsified oil / fat composition for whipped cream containing a hardened oil / fat contains a high-melting-point component produced by hardening, so that it is difficult to dissolve on the tongue and the texture is deteriorated.

上記の問題を解決することを目的に、例えば、油相部中に油脂としてパーム核油分別高融点部を含有する水中油型乳化油脂組成物を用いることにより、十分な耐熱保形性を有し、かつ口溶けが良好な凍結用ホイップクリーム(特許文献1)があるが、パーム核油分別高融点部の配合量が多くチルド流通用途での口溶け感は不十分である。また、水分量が55〜73重量%であり、油脂分が25〜43重量%であって、油脂中の55重量%以上が10℃におけるSFCが65〜98%の範囲のラウリン系油脂であり、ホイップさせた状態もしくはこれをケーキ等にデコレーションした状態で凍結保存し解凍しても、型崩れまたはひび割れあるいは組織の荒れあるいは変色、風味劣化が起こすことなく、優れた風味の凍結耐性を有する起泡性水中油型乳化物があるが(特許文献2)、硬化油が使用されているために食感として不十分である。また、油脂の総炭素数を規定することで常温域(約15〜35℃)において良好な保形性を有し、口溶け性が良好で、常温保管時の経時的乳化安定性に優れ、常温保管時にも起泡済水中油型乳化脂が硬くなることのない優れた常温流通型起泡済水中油型乳化脂を与える起泡性水中油型乳化脂用油脂組成物があるが(特許文献3)、チルド流通用途としては口溶けが重く、不十分なものあった。   For the purpose of solving the above problems, for example, by using an oil-in-water emulsified oil / fat composition containing a palm kernel oil fractionation high melting point part as an oil / fat in the oil phase part, sufficient heat-resistant shape retention is achieved. However, although there is a whipping cream for freezing (Patent Document 1) that melts well in the mouth, the blended amount of the palm kernel oil fractionation high melting point is large, and the mouth-melting feeling in chilled distribution applications is insufficient. Further, the moisture content is 55 to 73% by weight, the fat and oil content is 25 to 43% by weight, and 55% by weight or more in the fat and oil is a lauric fat and oil having an SFC in the range of 65 to 98% at 10 ° C. Even if it is frozen and stored in a whipped state or decorated in a cake, etc., it does not lose its shape, cracks, rough structure, discoloration, or flavor deterioration, and it has excellent flavor freezing resistance. Although there is a foamy oil-in-water emulsion (Patent Document 2), since a hardened oil is used, the texture is insufficient. In addition, by defining the total number of carbon atoms in fats and oils, it has good shape retention in the normal temperature range (about 15 to 35 ° C.), good mouth meltability, excellent emulsification stability over time during storage at normal temperature, Although there is a foamable oil-in-water emulsified fat composition that gives an excellent room temperature circulation type foamed oil-in-water emulsified fat that does not become hard even during storage (Patent Document) 3) The melting of the mouth was heavy and insufficient for chilled distribution applications.

特開2006−304713号公報JP 2006-304713 A 特開2009−50235号公報JP 2009-50235 A 特開2007−282535号公報JP 2007-282535 A

本発明の目的は、従来の保型性を維持しながら、食した際に綿飴の如く極めて口溶けが良好であるチルド流通用のホイップドクリームを作製するための起泡性水中油型乳化油脂組成物を提供することである。   The object of the present invention is to provide a foamable oil-in-water emulsified oil and fat for producing a whipped cream for chilled distribution that has a very good mouth melt when eaten while maintaining the conventional shape retention. It is to provide a composition.

本発明者らは上記課題を解決するために鋭意研究を重ねた結果、高融点油脂として硬化油脂ではなく、ある特定の総炭素数である上昇融点30℃以上の油脂と特定のSFCであるラウリン系油脂を油相部に配合し、更にHLBが0〜5の主要構成脂肪酸がベヘン酸である特定の乳化剤を併用することにより食した際に綿飴の如く極めて口溶けが良好であるホイップクリームを作製できることを見出し、本発明を完成するに至った。   As a result of intensive studies to solve the above problems, the inventors of the present invention are not a hardened fat as a high melting point fat, but a fat having a specific melting point of 30 ° C. or higher and a specific SFC, lauric acid. A whipped cream with a very good mouth melt like a cotton candy when mixed with a specific emulsifier in which the main component fatty acid having an HLB of 0 to 5 is behenic acid is blended in the oil phase part with a base oil and fat. The inventors have found that it can be produced, and have completed the present invention.

即ち、本発明の第一は、油脂含量が20〜40重量%の起泡性水中油型乳化油脂組成物であって、油相部の油脂全体中、構成脂肪酸の総炭素数が36と38のトリグリセライドの合計量が40重量%以上であり且つ上昇融点が30℃以上である油脂(A)の含有量が10〜40重量%であり、15℃のSFCが40〜70%であるラウリン系油脂である油脂(B)の含有量が20〜80重量%であり、油相部の油脂全体中油脂(A)と油脂(B)の合計量が60〜100重量%であり、油相部にHLBが0〜5の主要構成脂肪酸がベヘン酸である乳化剤を起泡性水中油型乳化油脂組成物全体中0.005〜0.1重量%含有するチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物に関する。好ましい実施態様は、油脂(A)がパーム核ステアリンである上記記載のチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物に関する。より好ましくは、0〜10℃で冷蔵保管した時の結晶化率が45〜90重量%である上記記載のチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物、更に好ましくは、起泡性水中油型乳化油脂組成物全体中、油相部にレシチンを0.02〜0.5重量%含有する上記記載のチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物、特に好ましくは、起泡性水中油型乳化油脂組成物全体中、水相部にホエー蛋白質を0.05〜5重量%含有する上記記載のチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物、に関する。本発明の第二は、上記記載のチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物を含んでなるホイップドクリームに関する。   That is, the first of the present invention is a foamable oil-in-water emulsified oil / fat composition having an oil / fat content of 20 to 40% by weight, wherein the total number of carbon atoms of the constituent fatty acids is 36 and 38 in the whole oil / fat in the oil phase part. Laurin system in which the total amount of triglyceride is 40% by weight or more, the content of oil (A) having an ascending melting point of 30 ° C. or more is 10 to 40% by weight, and the SFC at 15 ° C. is 40 to 70% The content of the fat (B), which is a fat, is 20 to 80% by weight, the total amount of the fat (A) and the fat (B) in the whole fat and oil in the oil phase is 60 to 100% by weight, and the oil phase part Foamed water for chilled whipped cream containing 0.005 to 0.1% by weight of an emulsified oil-in-water emulsified oil / fat composition containing an emulsifier whose main constituent fatty acid having an HLB of 0 to 5 is behenic acid The present invention relates to an oil-type emulsified oil / fat composition. A preferred embodiment relates to the foamable oil-in-water emulsified oil / fat composition for chilled circulation whipped cream as described above, wherein the oil / fat (A) is palm kernel stearin. More preferably, the foamable oil-in-water emulsified oil / fat composition for chilled circulation whipped cream as described above having a crystallization rate of 45 to 90% by weight when stored refrigerated at 0 to 10 ° C., more preferably The above-mentioned foamable oil-in-water emulsified oil / fat composition for chilled circulation whipped cream, comprising 0.02 to 0.5% by weight of lecithin in the oil phase part of the entire foamable oil-in-water emulsified oil / fat composition, Preferably, in the whole foamable oil-in-water emulsified oil / fat composition, the foamable oil-in-water emulsified oil / fat composition for chilled circulation whipped cream as described above containing 0.05 to 5% by weight of whey protein in the aqueous phase part Things. 2nd of this invention is related with the whipped cream which comprises the foamable oil-in-water type emulsified oil-fat composition for the above-mentioned chilled distribution whipped cream.

本発明に従えば、従来の保型性を維持しながら、食した際に綿飴の如く極めて口溶けが良好であるチルド流通用のホイップドクリームを作製するための起泡性水中油型乳化油脂組成物を提供することが可能となる。   According to the present invention, a foamable oil-in-water emulsified fat and oil for producing a whipped cream for chilled distribution that has a very good mouth melt when eaten while maintaining the conventional shape retention, according to the present invention. It becomes possible to provide a composition.

以下、本発明につき、さらに詳細に説明する。本発明の起泡性水中油型乳化油脂組成物は、特定の油脂含量であり、特定の組成且つ上昇融点である油脂(A)と、特定のSFC(固体脂含量)であるラウリン系油脂からなる油脂(B)とを特定量有し、さらに油相部に特定のHLBで構成脂肪酸が特定の乳化剤を特定量有する。なお、該起泡性水中油型乳化油脂組成物は、チルド流通ホイップドクリーム用として用いる場合に、より効果を享受できる。   Hereinafter, the present invention will be described in more detail. The foamable oil-in-water emulsified oil / fat composition of the present invention has a specific oil / fat content, a specific composition and a rising melting point (A), and a specific SFC (solid fat content) lauric oil / fat. The oil and fat (B) to be formed has a specific amount, and the constituent fatty acid has a specific amount of a specific emulsifier in a specific HLB in the oil phase part. The foamable oil-in-water emulsified oil / fat composition can be more effective when used for chilled distribution whipped cream.

本発明の起泡性水中油型乳化油脂組成物全体中の油脂含量は、20〜40重量%が好ましい。20重量%より少ないとホイップしにくい場合があり、40重量%より多いと食した際に所望する口溶け感が悪化する場合がある。   The oil / fat content in the entire foamable oil-in-water emulsified oil / fat composition of the present invention is preferably 20 to 40% by weight. If it is less than 20% by weight, it may be difficult to whip, and if it is more than 40% by weight, the desired melt-dissolving feeling may be deteriorated when eaten.

本発明の油脂(A)は、上昇融点が30℃以上であり且つ構成脂肪酸の総炭素数が36と38のトリグリセライドの合計量が油脂(A)全体中40重量%以上である。なお、前記油脂の上昇融点の測定は、基準油脂分析法2.2.4.2融点に準じて測定すれば良い。なお、油脂(A)としては、パーム核ステアリンの使用が好ましい(表1参照)。   The fat (A) of the present invention has an ascending melting point of 30 ° C. or higher, and the total amount of triglycerides having 36 and 38 total carbon atoms of the constituent fatty acids is 40% by weight or more in the whole fat (A). The rising melting point of the oil / fat may be measured according to the standard oil / fat analysis method 2.2.4.2 melting point. In addition, as fats and oils (A), use of a palm kernel stearin is preferable (refer Table 1).

Figure 2012019766
Figure 2012019766

前記油脂(A)の含有量は、起泡性水中油型乳化油脂組成物の油相部の油脂全体中10〜40重量%であることが好ましい。10重量%より少ないと、ホイップドクリームとして十分な保型性が得られない場合があり、40重量%より多いと、所望する良好な口溶け感が低下する場合がある。   It is preferable that content of the said fats and oils (A) is 10 to 40 weight% in the whole fats and oils of the oil phase part of a foamable oil-in-water type emulsified fat composition. If it is less than 10% by weight, sufficient shape retention as a whipped cream may not be obtained, and if it is more than 40% by weight, the desired good meltability in the mouth may be lowered.

本発明の油脂(B)は、15℃のSFCが40〜70%のラウリン系油脂である。SFCが40%より低いと、ホイップ時に十分な保型性が得られない場合があり、70%より高いと、所望する良好な口溶け感が低下する場合がある。油脂(B)の含有量は、油相部の油脂全体中20〜80重量%であることが好ましい。20重量%より少ないと、所望する良好な口溶け感が得られない場合があり、80重量%より多いと、ホイップ時に十分な保型性が得られない場合がある。ここでSFCの測定は、基準油脂分析試験法2.2.9固体脂含量(NMR法)に準拠すればよい。   The fat / oil (B) of the present invention is a lauric fat / oil having an SFC of 40 to 70% at 15 ° C. If the SFC is lower than 40%, sufficient shape retention may not be obtained at the time of whipping, and if it is higher than 70%, the desired good meltability may be lowered. It is preferable that content of fats and oils (B) is 20 to 80 weight% in the whole fats and oils of an oil phase part. If it is less than 20% by weight, the desired good melt-dissolving feeling may not be obtained, and if it is more than 80% by weight, sufficient shape retention may not be obtained during whipping. Here, the measurement of SFC may be based on the standard fat analysis test method 2.2.9 solid fat content (NMR method).

本発明の起泡性水中油型乳化油脂組成物において、油脂(B)が多くなると油脂(A)は少なくて良く、油脂(A)と油脂(B)の合計含有量は、油相部の油脂全体中60〜100重量%が好ましい。60重量%より少ないと、所望する良好な口溶け感が得られない場合がある。   In the foamable oil-in-water emulsified oil / fat composition of the present invention, the amount of oil / fat (A) may be small when the amount of oil / fat (B) increases, and the total content of oil / fat (A) and oil / fat (B) is 60-100 weight% is preferable in the whole fats and oils. If the amount is less than 60% by weight, the desired good meltability may not be obtained.

本発明の起泡性水中油型乳化油脂組成物の油相部には、HLBが0〜5で且つ主要構成脂肪酸がベヘン酸である乳化剤を含有することが好ましい。該乳化剤の構成脂肪酸全体中のベヘン酸の量は、50重量%以上である。また該乳化剤の含有量は、起泡性水中油型乳化油脂組成物全体中全体中0.005〜0.1重量%が好ましい。0.005重量%より少ないと、結晶化が不十分となり良好なオーバーランや硬さが得られない場合があり、0.1重量%より多いと、所望する良好な口溶け感が得られない場合がある。ベヘン酸が主要構成脂肪酸である乳化剤としては、特に限定はないが、グリセリン脂肪酸モノエステル、ポリグリセリン脂肪酸エステルであることが好ましい。   The oil phase part of the foamable oil-in-water emulsified oil / fat composition of the present invention preferably contains an emulsifier having an HLB of 0 to 5 and a main constituent fatty acid of behenic acid. The amount of behenic acid in the total fatty acid constituting the emulsifier is 50% by weight or more. The content of the emulsifier is preferably 0.005 to 0.1% by weight in the whole foamable oil-in-water emulsified oil / fat composition. If the amount is less than 0.005% by weight, crystallization may be insufficient and good overrun or hardness may not be obtained. If the amount is more than 0.1% by weight, the desired good meltability may not be obtained. There is. The emulsifier in which behenic acid is the main constituent fatty acid is not particularly limited, but is preferably a glycerin fatty acid monoester or a polyglycerin fatty acid ester.

本発明の起泡性水中油型乳化油脂組成物の水相部及び/又は油相部には、ポリグリセリン脂肪酸エステルを合計で起泡性水中油型乳化油脂組成物全体中0.1〜3重量%含有することが好ましい。0.1重量%より少ないと、乳化安定性が低下し原液の保管時に固化が生じたり、十分なホイップ性が得られない場合があり、3重量%より多いと、ホイップ時に十分なオーバーランが得られなかったり、風味、食感が悪化する場合がある。   In the water phase part and / or oil phase part of the foamable oil-in-water emulsified oil / fat composition of the present invention, the total amount of polyglycerin fatty acid ester is 0.1 to 3 in the total foamable oil-in-water emulsified oil / fat composition. It is preferable to contain by weight. If it is less than 0.1% by weight, the emulsification stability will be reduced and solidification may occur during storage of the stock solution, or sufficient whipping properties may not be obtained. If it is more than 3% by weight, sufficient overrun will occur during whipping. It may not be obtained, and the flavor and texture may deteriorate.

本発明の起泡性水中油型乳化油脂組成物の油相部には、起泡性水中油型乳化油脂組成物全体中全体中0.02〜0.5重量%のレシチンを含有することが好ましい。0.02重量%より少ないと、ホイップ時に十分なオーバーランが得られない場合があり、0.5重量%より多いと、乳化安定性が低下し、原液の保管時に固化が生じたり、十分なホイップ性が得られない場合がある。   The oil phase part of the foamable oil-in-water emulsified oil / fat composition of the present invention may contain 0.02 to 0.5% by weight of lecithin in the whole foamable oil-in-water emulsified oil / fat composition. preferable. If the amount is less than 0.02% by weight, sufficient overrun may not be obtained during whipping. If the amount is more than 0.5% by weight, the emulsification stability is lowered and solidification occurs during storage of the stock solution. Whipability may not be obtained.

本発明の起泡性水中油型乳化油脂組成物の結晶化率とは、BRUKER製minispecシリーズ「mq20 NMR Analyzer」(解析ソフト:BRUKER the MINISPEC)を用いて、本発明の起泡性水中油型乳化油脂組成物の油相部を抽出せずに原液のままで測定した値から、油相部の油脂を曇点が0℃未満のサラダ油とした以外は同配合の起泡性水中油型乳化油脂組成物を原液のままで測定した値を引いた値を、測定した起泡性水中油型乳化油脂組成物の油分(重量%)で割って算出できる起泡性水中油型乳化油脂組成物の油相中の油脂結晶量(%)のことである。   The crystallization rate of the foamable oil-in-water emulsified oil / fat composition of the present invention is the foamable oil-in-water type of the present invention by using the minispec series “mq20 NMR Analyzer” (analysis software: BRUKER the MINISPEC) manufactured by BRUKER. The foaming oil-in-water emulsification of the same composition except that the oil and fat of the oil phase part was changed to salad oil having a cloud point of less than 0 ° C from the value measured in the stock solution without extracting the oil phase part of the emulsified oil and fat composition Foamable oil-in-water emulsified oil and fat composition that can be calculated by dividing the value obtained by subtracting the value measured for the oil and fat composition from the stock solution by the oil content (% by weight) of the measured foamable oil-in-water emulsified oil and fat composition It is the amount of fat and oil crystals (%) in the oil phase.

本発明の起泡性水中油型乳化油脂組成物は、冷蔵条件下(設定温度2〜5℃)で少なくとも3日間保管した時の結晶化率が45〜90重量%であることが好ましく、より好ましくは55〜80重量%である。結晶化率が上記範囲であると、オーバーランも十分となり、食した際に綿飴の如く極めて口溶けが良好であるホイップクリームとなる。結晶化率が45重量%未満の場合は、オーバーランが不十分であり口溶け感が低下したり、ホイップ後の硬さが軟らかく保型性が得られない場合がある。また結晶化率が90重量%を越えると、十分なオーバーランが得られず口溶け感が低下する場合がある。   The foamable oil-in-water emulsified oil / fat composition of the present invention preferably has a crystallization ratio of 45 to 90% by weight when stored for at least 3 days under refrigerated conditions (set temperature 2 to 5 ° C.). Preferably it is 55 to 80 weight%. When the crystallization rate is in the above range, overrun is sufficient, and a whipped cream that has a very good mouth melt like a cotton candy when eaten. When the crystallization rate is less than 45% by weight, the overrun is insufficient and the meltability in the mouth is lowered, or the hardness after whipping is soft and the shape retention may not be obtained. On the other hand, if the crystallization rate exceeds 90% by weight, sufficient overrun may not be obtained and the meltability may be lowered.

本発明の起泡性水中油型乳化油脂組成物の製造例を、特に限定するわけではないが以下に例示する。   Although the manufacturing example of the foamable oil-in-water type emulsified oil-fat composition of this invention is not necessarily limited, it illustrates below.

本発明における起泡性水中油型乳化油脂組成物は、前記油脂と前記乳化剤を用いれば、それ以外の配合に限定は無く、通常のホイップクリームの配合物、例えば、乳原料、乳化剤、塩類、糖類、増粘剤、香料、着色料などを使用して、常法に従って製造することができる。常法に従うとは、例えば60℃に加熱した水相に当該原材料を溶解し、同様に60℃に加熱した油相に当該原材料を溶解、混合し、予備乳化を行なった後に、UHT殺菌などを用いて殺菌後、均質化を行い、5〜10℃に冷却すれば、目的の水中油型乳化油脂組成物を得ることができる。   In the present invention, the foamable oil-in-water emulsified oil / fat composition is not limited to any other composition as long as the oil / fat and the emulsifier are used, and a normal whipped cream composition, for example, a milk raw material, an emulsifier, a salt, It can be produced according to a conventional method using saccharides, thickeners, fragrances, coloring agents and the like. According to a conventional method, for example, the raw material is dissolved in an aqueous phase heated to 60 ° C., and the raw material is similarly dissolved and mixed in an oil phase heated to 60 ° C. When the mixture is sterilized and then homogenized and cooled to 5 to 10 ° C., the desired oil-in-water emulsified oil / fat composition can be obtained.

前記乳原料は、起泡性水中油型乳化油脂組成物の水相部に含有され、例えば、牛乳、脱脂乳、全脂濃縮乳、脱脂濃縮乳、脱脂粉乳、全脂粉乳、バターミルク、バターミルクパウダー、ホエー蛋白質、濃縮ホエー、ホエーパウダー、生クリーム、加糖練乳、無糖練乳、バター、チーズ、カゼイン蛋白質、カゼインナトリウム、UF膜やイオン交換樹脂処理などにより分離、分画した乳蛋白質などが挙げられ、ホイップ性を充分に保つためには、ホエー蛋白質を含有させることが好ましい。   The milk raw material is contained in the water phase part of the foamable oil-in-water emulsified oil / fat composition, for example, milk, skim milk, full fat concentrated milk, skim concentrated milk, skim milk powder, whole milk powder, butter milk, butter Milk powder, whey protein, concentrated whey, whey powder, fresh cream, sweetened condensed milk, unsweetened condensed milk, butter, cheese, casein protein, sodium caseinate, milk protein separated and fractionated by UF membrane or ion exchange resin treatment, etc. In order to keep the whipping property sufficiently, it is preferable to contain whey protein.

前記においてホエー蛋白質は、純分として起泡性水中油型乳化油脂組成物全体中0.05〜5重量%含有することが好ましい。0.05重量%より少ないと、乳化安定性が低下し十分なホイップ性が得られない場合があり、5重量%より多いと、起泡性水中油型乳化油脂組成物製造中、加熱ラインで焦げなどが発生しやすくなり、製造面において問題が生じる場合がある。ここで言うところのホエー蛋白質とは、チーズの製造時に生じるホエー分や限外濾過などから得られるラクトアルブミン、ラクトグロブリンなどのカゼイン蛋白を除いた乳蛋白質のことであり、蛋白含量80%のものが一般的で、好適である。   In the above, the whey protein is preferably contained in a total amount of 0.05 to 5% by weight in the whole foamable oil-in-water emulsified oil composition. If the amount is less than 0.05% by weight, the emulsion stability may be lowered and sufficient whipping properties may not be obtained. If the amount is more than 5% by weight, a foaming oil-in-water emulsified oil / fat composition may be produced during heating. Burning or the like tends to occur, which may cause problems in manufacturing. Whey protein as used herein refers to milk protein excluding casein proteins such as lactalbumin and lactoglobulin obtained from whey and ultrafiltration produced during cheese production, and has a protein content of 80%. Is common and preferred.

前記乳化剤としては、HLBが0〜5で且つ主要構成脂肪酸がベヘン酸である乳化剤やレシチン以外に、更に別の食品用の乳化剤であれば適宜配合しても特に問題はない。   As the above-mentioned emulsifier, there is no particular problem even if it is properly blended as long as it is an emulsifier for food other than the emulsifier and lecithin whose HLB is 0 to 5 and the main constituent fatty acid is behenic acid.

前記塩類としては、食品用途に用いられるものであれば特に限定はないが、例えばリン酸のナトリウム塩、カリウム塩、又はクエン酸のナトリウム塩などを挙げることができる。   The salt is not particularly limited as long as it is used for food applications, and examples thereof include sodium phosphate, potassium salt, and sodium salt of citric acid.

前記糖類としては、例えば、上白糖、三音糖、グラニュー糖、ざらめ糖、加工糖、液糖などの砂糖類、水あめ、ブドウ糖、異性化糖、果糖、麦芽糖、乳糖などの糖類、還元水あめ、還元麦芽糖水あめなどの糖アルコール類などを使用できる。   Examples of the saccharide include sugars such as white saccharose, tritone sugar, granulated sugar, rough sugar, processed sugar, liquid sugar, sugar syrup, glucose, isomerized sugar, sugars such as fructose, malt sugar, lactose, and reduced water candy. Sugar alcohols such as reduced maltose syrup and the like can be used.

前記増粘剤としては、例えば、グアーガム、キサンタンガム、寒天、ペクチン類、アルギン酸ナトリウム、カラギーナン、ジェランガム、ローカストビーンガム、アラビアガム、CMCなどを挙げることができる。   Examples of the thickener include guar gum, xanthan gum, agar, pectin, sodium alginate, carrageenan, gellan gum, locust bean gum, gum arabic, and CMC.

前記香料、着色料としては、適宜使用され、通常食品用途に使用されるものであれば特に限定はない。   The fragrance and colorant are not particularly limited as long as they are used as appropriate and are usually used for food applications.

本発明の起泡性水中油型乳化油脂組成物は、ホイップ後にチルド領域で長時間保管してもクリームが硬くなりにくく、チルド流通に好適な従来の保型性を維持できるため、該起泡性水中油型乳化油脂組成物を用いたホイップドクリームは、チルド流通に好適であり、また食した際に綿飴の如く極めて口溶けが良好である。   The foamable oil-in-water emulsified oil / fat composition of the present invention can maintain the conventional shape-retaining property suitable for chilled distribution because the cream is difficult to harden even if stored for a long time in the chilled region after whipping. The whipped cream using the water-in-oil type emulsified oil / fat composition is suitable for chilled circulation, and has a very good mouth melt like a cotton candy when eaten.

以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。   EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to these examples. In the examples, “parts” and “%” are based on weight.

<結晶化率の測定方法>
実施例・比較例で得られた起泡性水中油型乳化油脂組成物の原液1.5gをNMR管に入れて、所定の条件で保持した後にBRUKER製minispecシリーズ「mq20 NMR Analyzer(解析ソフト:BRUKER the MINISPEC)」で測定した値(x)を得た。また、起泡性水中油型乳化油脂組成物の油相部の油脂を曇点が0℃未満のサラダ油(ナタネ油)のみとした以外は、測定する起泡性水中油型乳化油脂組成物と同配合で作製した起泡性水中油型乳化油脂組成物の原液1.5gを所定の条件で保持した後に前記Analyzerで測定した値(y)を得た。そして以下の式に従って、結晶化率(%)を算出した。
結晶化率=(x−y)/起泡性水中油型乳化油脂組成物試料中の油分(重量%)×100
<Measurement method of crystallization rate>
The stock solution 1.5 g of the foamable oil-in-water emulsified oil / fat composition obtained in Examples and Comparative Examples was put into an NMR tube and held under predetermined conditions, and then the BRUKER minispec series “mq20 NMR Analyzer (analysis software: BRUKER the MINISPEC) ”(x) was obtained. In addition, the oil and fat in the oil phase part of the foamable oil-in-water emulsified oil and fat composition is only salad oil (rapeseed oil) having a cloud point of less than 0 ° C. After holding 1.5 g of the foamable oil-in-water emulsified oil / fat composition prepared in the same composition under predetermined conditions, a value (y) measured by the Analyzer was obtained. And according to the following formula | equation, the crystallization rate (%) was computed.
Crystallization rate = (xy) / foamable oil-in-water emulsified oil / fat composition oil content (wt%) × 100

<ホイップ方法>
実施例・比較例で得られた起泡性水中油型乳化油脂組成物を4kg、グラニュー糖320gをカントーミキサー(CS型20:関東混合機工業株式会社製)に入れ、高速攪拌条件(450rpm)でホイップし、状態を確認しながら、液状、表面の状態、硬さにより最適点でホイップを停止した。
<Whipping method>
4 kg of the foamable oil-in-water emulsified oil / fat composition obtained in Examples and Comparative Examples, and 320 g of granulated sugar were placed in a can-to-mixer (CS type 20: manufactured by Kanto Blender Kogyo Co., Ltd.), and high-speed stirring conditions (450 rpm) The whip was stopped at the optimum point according to the liquid state, surface state and hardness while confirming the state.

<食感の評価方法>
食感の官能評価は、実施例と比較例で得られた起泡性水中油型乳化油脂組成物をホイップしたものを熟練した専門パネラー10名に試食をしてもらい、評価結果を集約した。その際の評価基準は以下の通りであった。◎:口溶けが非常に良好、○:口溶け良好、△:やや食感が重たく、口溶けが悪い、×:非常に食感が重たく、口溶けが非常に悪い。
<Evaluation method of texture>
For sensory evaluation of the texture, 10 expert panelists who had whipped the foamable oil-in-water emulsified oil / fat compositions obtained in Examples and Comparative Examples were sampled and the evaluation results were collected. The evaluation criteria at that time were as follows. ◎: Very good mouth melt, ○: Good mouth melt, △: Slightly heavy texture, poor mouth melt, ×: Very heavy texture, very poor mouth melt.

<オーバーランの測定方法>
オーバーランとは、ホイップ性の指標となるものであり、ホイップした起泡性水中油型乳化油脂組成物に含まれる空気の割合を%で示すもので、下記の式で求めた。その際、オーバーランの値によって、以下の基準で評価した。◎:120%以上(最良)、○:110%以上且つ120%未満(良)、△:100%以上且つ110%未満(可)、×:100%以下(不可)。
オーバーラン(%)=[(一定容積の起泡性水中油型乳化油脂組成物の重量)−(一定容積のホイップ後の起泡性水中油型乳化油脂組成物の重量)]÷(一定容積のホイップ後の起泡性水中油型乳化油脂組成物の重量)×100
<Measurement method of overrun>
The overrun is an index of whipping property, and indicates the ratio of air contained in the whipped foamable oil-in-water emulsified oil / fat composition in%, and was determined by the following formula. At that time, the evaluation was made according to the following criteria according to the overrun value. A: 120% or more (best), B: 110% or more and less than 120% (good), Δ: 100% or more and less than 110% (possible), ×: 100% or less (impossible).
Overrun (%) = [(weight of a certain volume of foamable oil-in-water emulsified oil composition) − (weight of foamable oil-in-water emulsified oil composition after whipping)] ÷ (constant volume Of the foamable oil-in-water emulsified oil and fat composition after whipping

<ホイップ直後の起泡性水中油型乳化油脂組成物の硬さの評価>
ホイップした直後に、起泡性水中油型乳化油脂組成物を直径50mm、深さ20mmの円柱状の容器に入れた後、クリープメーター「RE2−33005S(株式会社山電製)」を用いて直径16mmの円柱状のプランジャーにて、10mm深度、速度5mm/秒、測定回数1回でホイップ直後の硬さを測定した。その際、以下の基準で評価した。
◎:0.3N以上且つ0.35N未満(最良)、
○:0.25N以上且つ0.3N未満、
或いは0.35N以上且つ0.4N未満(良)、
△:0.2N以上且つ0.25N未満、
或いは0.4N以上且つ0.45N未満(可)、
×:0.2N未満、或いは0.45N以上(不可)。
<Evaluation of hardness of foamable oil-in-water emulsified oil / fat composition immediately after whipping>
Immediately after whipping, the foamable oil-in-water emulsified oil / fat composition was put into a cylindrical container having a diameter of 50 mm and a depth of 20 mm, and then the diameter was measured using a creep meter “RE2-30005S (manufactured by Yamaden Co., Ltd.)”. The hardness immediately after whipping was measured with a 16 mm cylindrical plunger at a depth of 10 mm, a speed of 5 mm / second, and a single measurement. At that time, the following criteria were evaluated.
A: 0.3 N or more and less than 0.35 N (best),
○: 0.25N or more and less than 0.3N,
Or 0.35N or more and less than 0.4N (good),
Δ: 0.2N or more and less than 0.25N,
Or 0.4N or more and less than 0.45N (possible),
X: Less than 0.2N or 0.45N or more (impossible).

<構成脂肪酸の総炭素数の測定法>
構成脂肪酸の総炭素数は基準油脂分析試験法2.4.6.1トリアシルグリセリン組成に準じてガスクロマトグラフィー「6890N Network GS System(Agilent Technologies社製)」を用いて測定した。
<Measurement method of total carbon number of constituent fatty acids>
The total number of carbon atoms of the constituent fatty acids was measured by gas chromatography “6890N Network GS System (manufactured by Agilent Technologies)” according to the standard fat and oil analysis test method 2.4.6.1 triacylglycerol composition.

(製造例1) エステル交換油の作製
エステル交換油は、下記の方法で作製を行なった。パーム油50重量部、パーム核オレイン50重量部の原料油脂を反応容器に仕込み、減圧下で攪拌しながら加熱を行い、90℃、30mmHgに達するまで脱水を行なった。次に、ナトリウムメチラートを原料油脂100重量部に対して0.1重量部加え、窒素気流中で攪拌しながら、90℃で30分間反応を行なった。その後、油脂原料と同量の温水(約70℃)を加えて洗浄を実施した。洗浄した水のpHが8になるまで繰り返し温水で洗浄を実施した後、減圧下攪拌しながら加熱し90℃、30mmHgに達するまで脱水を行なった。次に活性白土を原料油脂100重量部に対して2重量部加え、減圧下攪拌して30分間脱色反応を行なった後に全量ろ過を行い、活性白土の除去を行なった。最後に250℃、2mmHgで60分間脱臭を行い、エステル交換油を得た。
Production Example 1 Production of Transesterified Oil The transesterified oil was produced by the following method. Raw material fats and oils of 50 parts by weight of palm oil and 50 parts by weight of palm kernel olein were charged into a reaction vessel, heated with stirring under reduced pressure, and dehydrated until reaching 90 ° C. and 30 mmHg. Next, 0.1 parts by weight of sodium methylate was added to 100 parts by weight of the raw oil and fat, and the reaction was performed at 90 ° C. for 30 minutes while stirring in a nitrogen stream. Thereafter, washing was performed by adding the same amount of hot water (about 70 ° C.) as the fat and oil raw material. Washing was repeatedly carried out with warm water until the pH of the washed water reached 8, followed by heating with stirring under reduced pressure and dehydration until reaching 90 ° C. and 30 mmHg. Next, 2 parts by weight of activated clay was added to 100 parts by weight of the raw oil and fat, and the mixture was stirred under reduced pressure and subjected to a decolorization reaction for 30 minutes, and then the whole amount was filtered to remove the activated clay. Finally, deodorization was performed at 250 ° C. and 2 mmHg for 60 minutes to obtain a transesterified oil.

(製造例2) 結晶化率測定用起泡性水中油型乳化油脂組成物の作製
表2に示す配合に従って、起泡性水中油型乳化油脂組成物を作製した。即ち、油相部の油脂30重量部を60℃に加温後、大豆レシチン0.2重量部、ポリグリセリン脂肪酸エステル(HLB=4.5)0.05重量部、ベヘン酸ポリグリセリン脂肪酸エステル(HLB=2.3)0.05重量部を溶解して油相部とした。一方、60℃の温水64.37重量部にキサンタンガム0.01重量部、グアーガム0.05重量部、ポリグリセリン脂肪酸エステル(HLB=11.6)0.15重量部、ヘキサメタリン酸ナトリウム0.07重量部、ショ糖脂肪酸エステル(HLB=11)0.05重量部を溶解、更に脱脂粉乳4.5重量部、ホエイ蛋白質0.5重量部を溶解して水相部とした。上記、水相と油相を混合し、60℃で20分間攪拌して予備乳化液とした。この乳化液を直接蒸気注入式滅菌機にて、142℃で4秒間滅菌処理を行なった後、6.0MPaで均質化処理した後にプレート式の冷却装置にて最終温度を5℃まで冷却し、容器に充填して起泡性水中油型乳化油脂組成物を得た。得られた起泡性水中油型乳化油脂組成物を、実施例1、比較例4,5,7で得られた起泡性水中油型乳化油脂組成物と同じ条件で保持した後、前記「結晶化率の測定方法」に従って測定値(y)を得た。測定値(y)は1.1であった。
(Production Example 2) Preparation of foamable oil-in-water emulsified oil / fat composition for crystallization rate measurement According to the formulation shown in Table 2, a foamable oil-in-water emulsified oil / fat composition was prepared. That is, after heating 30 parts by weight of fat in the oil phase to 60 ° C., 0.2 parts by weight of soybean lecithin, 0.05 parts by weight of polyglycerol fatty acid ester (HLB = 4.5), polyglycerol fatty acid ester of behenate ( HLB = 2.3) 0.05 part by weight was dissolved to obtain an oil phase part. On the other hand, in 64.37 parts by weight of warm water at 60 ° C., 0.01 parts by weight of xanthan gum, 0.05 parts by weight of guar gum, 0.15 parts by weight of polyglycerin fatty acid ester (HLB = 11.6), 0.07 parts by weight of sodium hexametaphosphate Parts, 0.05 parts by weight of sucrose fatty acid ester (HLB = 11) were dissolved, and 4.5 parts by weight of skim milk powder and 0.5 parts by weight of whey protein were dissolved to obtain an aqueous phase part. The aqueous phase and the oil phase were mixed and stirred at 60 ° C. for 20 minutes to obtain a preliminary emulsion. This emulsion is directly sterilized at 142 ° C. for 4 seconds with a steam injection sterilizer, homogenized at 6.0 MPa, and then cooled to a final temperature of 5 ° C. with a plate-type cooling device. The container was filled to obtain a foamable oil-in-water emulsified oil / fat composition. The obtained foamable oil-in-water emulsified oil / fat composition was held under the same conditions as those of the foamable oil-in-water emulsified oil / fat composition obtained in Example 1 and Comparative Examples 4, 5, and 7, then, The measured value (y) was obtained according to “Measurement method of crystallization rate”. The measured value (y) was 1.1.

Figure 2012019766
Figure 2012019766

(製造例3) 結晶化率測定用起泡性水中油型乳化油脂組成物の作製
表2に示す配合に従って、起泡性水中油型乳化油脂組成物を作製した。即ち、ベヘン酸ポリグリセリン脂肪酸エステル(HLB=2.3)の量と、水量を変えた以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。得られた起泡性水中油型乳化油脂組成物を、実施例2で得られた起泡性水中油型乳化油脂組成物と同じ条件で保持した後、前記「結晶化率の測定方法」に従って測定値(y)を得た。測定値(y)は1.1であった。
(Production Example 3) Preparation of foamable oil-in-water emulsified oil / fat composition for crystallization rate measurement According to the formulation shown in Table 2, a foamable oil-in-water emulsified oil / fat composition was prepared. That is, a foamable oil-in-water emulsified oil / fat composition was obtained in the same manner as in Production Example 2 except that the amount of polyglycerol fatty acid ester of behenate (HLB = 2.3) and the amount of water were changed. The obtained foamable oil-in-water emulsified oil / fat composition was held under the same conditions as the foamable oil-in-water emulsified oil / fat composition obtained in Example 2, and then according to the above-mentioned “Method for Measuring Crystallization Rate”. A measured value (y) was obtained. The measured value (y) was 1.1.

(製造例4) 結晶化率測定用起泡性水中油型乳化油脂組成物の作製
表2に示す配合に従って、起泡性水中油型乳化油脂組成物を作製した。即ち、ベヘン酸ポリグリセリン脂肪酸エステル(HLB=2.3)を添加せず、ポリグリセリン脂肪酸エステル(HLB=4.5)の量を変えた以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。得られた起泡性水中油型乳化油脂組成物を、比較例1,3で得られた起泡性水中油型乳化油脂組成物と同じ条件で保持した後、前記「結晶化率の測定方法」に従って測定値(y)を得た。測定値(y)は1.1であった。
(Production Example 4) Preparation of foamable oil-in-water emulsified oil / fat composition for crystallization rate measurement According to the formulation shown in Table 2, a foamable oil-in-water emulsified oil / fat composition was prepared. That is, foaming water was added in the same manner as in Production Example 2 except that the amount of polyglycerol fatty acid ester (HLB = 4.5) was changed without adding behenic acid polyglycerol fatty acid ester (HLB = 2.3). An oil-type emulsified oil / fat composition was obtained. The obtained foamable oil-in-water emulsified oil / fat composition was held under the same conditions as the foamable oil-in-water emulsified oil / fat composition obtained in Comparative Examples 1 and 3, and then the above-mentioned “Method for Measuring Crystallization Rate”. The measurement value (y) was obtained. The measured value (y) was 1.1.

(製造例5) 結晶化率測定用起泡性水中油型乳化油脂組成物の作製
表2に示す配合に従って、起泡性水中油型乳化油脂組成物を作製した。即ち、ベヘン酸ポリグリセリン脂肪酸エステル(HLB=2.3)の量と、水量を変えた以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。得られた起泡性水中油型乳化油脂組成物を、比較例2で得られた起泡性水中油型乳化油脂組成物と同じ条件で保持した後、前記「結晶化率の測定方法」に従って測定値(y)を得た。測定値(y)は1.0であった。
(Production Example 5) Preparation of foamable oil-in-water emulsified oil / fat composition for crystallization rate measurement According to the formulation shown in Table 2, a foamable oil-in-water emulsified oil / fat composition was prepared. That is, a foamable oil-in-water emulsified oil / fat composition was obtained in the same manner as in Production Example 2 except that the amount of polyglycerol fatty acid ester of behenate (HLB = 2.3) and the amount of water were changed. The obtained foamable oil-in-water emulsified oil / fat composition was held under the same conditions as the foamable oil-in-water emulsified oil / fat composition obtained in Comparative Example 2, and then according to the above-mentioned “Method for measuring crystallization rate”. A measured value (y) was obtained. The measured value (y) was 1.0.

(製造例6) 結晶化率測定用起泡性水中油型乳化油脂組成物の作製
表2に示す配合に従って、起泡性水中油型乳化油脂組成物を作製した。即ち、油相部の油脂含量と、水量を変えた以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。得られた起泡性水中油型乳化油脂組成物を、比較例6で得られた起泡性水中油型乳化油脂組成物と同じ条件で保持した後、前記「結晶化率の測定方法」に従って測定値(y)を得た。測定値(y)は1.1であった。
(Manufacture example 6) Preparation of the foamable oil-in-water type emulsified oil-fat composition for crystallization rate measurement According to the mixing | blending shown in Table 2, the foamable oil-in-water type emulsion oil-fat composition was produced. That is, a foamable oil-in-water emulsified oil / fat composition was obtained in the same manner as in Production Example 2 except that the oil / fat content of the oil phase part and the amount of water were changed. The obtained foamable oil-in-water emulsified oil / fat composition was held under the same conditions as the foamable oil-in-water emulsified oil / fat composition obtained in Comparative Example 6, and then according to the above-mentioned “Method for measuring crystallization rate”. A measured value (y) was obtained. The measured value (y) was 1.1.

(実施例1) 起泡性水中油型乳化油脂組成物1の作製と評価
表2に示す配合に従って、油相部の油脂配合を変更した以外は製造例2と同様にして起泡性水中油型乳化油脂組成物1を得た。得られた起泡性水中油型乳化油脂組成物1を5℃(設定値)で4日間保持した後、前記方法で該乳化油脂組成物中の油脂の結晶化率を求めたところ74.3%であった。次に得られた起泡性水中油型乳化油脂組成物1を上記記載の方法にてホイップを行なった後に食感、オーバーラン、硬さの評価を実施し、その結果を表2にまとめた。
(Example 1) Production and evaluation of foamable oil-in-water emulsified oil / fat composition 1 According to the formulation shown in Table 2, a foamable oil-in-water composition was produced in the same manner as in Production Example 2 except that the oil / fat composition in the oil phase was changed. Type emulsified oil and fat composition 1 was obtained. The obtained foamable oil-in-water emulsified oil / fat composition 1 was held at 5 ° C. (set value) for 4 days, and then the crystallization rate of the oil / fat in the emulsified oil / fat composition was determined by the above method to be 74.3. %Met. Next, after the foamable oil-in-water emulsified oil / fat composition 1 thus obtained was whipped by the method described above, the texture, overrun, and hardness were evaluated, and the results are summarized in Table 2. .

(実施例2) 起泡性水中油型乳化油脂組成物2の作製と評価
表2に示す配合に従って、油相部の油脂配合を変更した以外は製造例3と同様にして起泡性水中油型乳化油脂組成物2を得た。得られた起泡性水中油型乳化油脂組成物2を5℃(設定値)で4日間保持した後、前記方法で該乳化油脂組成物中の油脂の結晶化率を求めたところ、76%であった。次に得られた起泡性水中油型乳化油脂組成物2を上記記載の方法にてホイップを行なった後に食感、オーバーラン、硬さの評価を実施し、その結果を表2にまとめた。
(Example 2) Production and evaluation of foamable oil-in-water emulsified oil / fat composition 2 According to the formulation shown in Table 2, a foamable oil-in-water composition was produced in the same manner as in Production Example 3 except that the oil / fat blending was changed. Type emulsified oil and fat composition 2 was obtained. After the obtained foamable oil-in-water emulsified oil / fat composition 2 was held at 5 ° C. (set value) for 4 days, the crystallization rate of the oil / fat in the emulsified oil / fat composition was determined by the above method, and was found to be 76%. Met. Next, after the foamable oil-in-water emulsified oil / fat composition 2 thus obtained was whipped by the method described above, the texture, overrun and hardness were evaluated, and the results are summarized in Table 2. .

(比較例1) 起泡性水中油型乳化油脂組成物3の作製と評価
表2に示す配合に従って、油相部の油脂配合を変更した以外は製造例4と同様にして起泡性水中油型乳化油脂組成物3を得た。得られた起泡性水中油型乳化油脂組成物3を5℃(設定値)で4日間保持した後、前記方法で該乳化油脂組成物中の油脂の結晶化率を求めたところ、42.3%であった。次に得られた起泡性水中油型乳化油脂組成物3を上記記載の方法にてホイップを行なった後に食感、オーバーラン、硬さの評価を実施し、その結果を表2にまとめた。
(Comparative example 1) Production and evaluation of foamable oil-in-water emulsified oil / fat composition 3 According to the formulation shown in Table 2, a foamable oil-in-water composition was produced in the same manner as in Production Example 4 except that the oil / fat composition was changed. A type emulsified oil / fat composition 3 was obtained. After the obtained foamable oil-in-water emulsified oil / fat composition 3 was held at 5 ° C. (set value) for 4 days, the crystallization rate of the oil / fat in the emulsified oil / fat composition was determined by the above method. 3%. Next, after the foamable oil-in-water emulsified oil / fat composition 3 thus obtained was whipped by the method described above, the texture, overrun and hardness were evaluated, and the results are summarized in Table 2. .

(比較例2) 起泡性水中油型乳化油脂組成物4の作製と評価
表2に示す配合に従って、油相部の油脂配合を変更した以外は製造例5と同様にして起泡性水中油型乳化油脂組成物4を得た。得られた起泡性水中油型乳化油脂組成物4を5℃(設定値)で4日間保持した後、前記方法で該乳化油脂組成物中の油脂の結晶化率を求めたところ、93.7%であった。次に得られた起泡性水中油型乳化油脂組成物4を上記記載の方法にてホイップを行なった後に食感、オーバーラン、硬さの評価を実施し、その結果を表2にまとめた。
(Comparative example 2) Production and evaluation of foamable oil-in-water emulsified oil / fat composition 4 According to the formulation shown in Table 2, a foamable oil-in-water composition was produced in the same manner as in Production Example 5 except that the oil / fat blending was changed. A type emulsified oil / fat composition 4 was obtained. The obtained foamable oil-in-water emulsified oil / fat composition 4 was held at 5 ° C. (set value) for 4 days, and then the crystallization ratio of the oil / fat in the emulsified oil / fat composition was determined by the above method. 7%. Next, after the foamable oil-in-water emulsified oil / fat composition 4 thus obtained was whipped by the method described above, the texture, overrun and hardness were evaluated, and the results are summarized in Table 2. .

(比較例3) 起泡性水中油型乳化油脂組成物5の作製と評価
表2に示す配合に従って、油相部の油脂配合を変更した以外は製造例4と同様にして起泡性水中油型乳化油脂組成物5を得た。得られた起泡性水中油型乳化油脂組成物5を5℃(設定値)で4日間保持した後、前記方法で該乳化油脂組成物中の油脂の結晶化率を求めたところ、43.3%であった。次に得られた起泡性水中油型乳化油脂組成物5を上記記載の方法にてホイップを行なった後に食感、オーバーラン、硬さの評価を実施し、その結果を表2にまとめた。
(Comparative example 3) Preparation and evaluation of foamable oil-in-water emulsified oil / fat composition 5 According to the formulation shown in Table 2, the foamable oil-in-water composition was produced in the same manner as in Production Example 4 except that the oil / fat composition in the oil phase was changed. A type emulsified oil / fat composition 5 was obtained. After the obtained foamable oil-in-water emulsified oil / fat composition 5 was held at 5 ° C. (set value) for 4 days, the crystallization rate of the oil / fat in the emulsified oil / fat composition was determined by the above method. 3%. Next, after the foamable oil-in-water emulsified oil / fat composition 5 thus obtained was whipped by the method described above, the texture, overrun, and hardness were evaluated, and the results are summarized in Table 2. .

(比較例4) 起泡性水中油型乳化油脂組成物6の作製と評価
表2に示す配合に従って、油相部の油脂配合を変更した以外は製造例2と同様にして起泡性水中油型乳化油脂組成物6を得た。得られた起泡性水中油型乳化油脂組成物6を5℃(設定値)で4日間保持した後、前記方法で該乳化油脂組成物中の油脂の結晶化率を求めたところ、92.3%であった。次に得られた起泡性水中油型乳化油脂組成物6を上記記載の方法にてホイップを行なった後に食感、オーバーラン、硬さの評価を実施し、その結果を表2にまとめた。
(Comparative example 4) Preparation and evaluation of foamable oil-in-water emulsified oil / fat composition 6 According to the formulation shown in Table 2, a foamable oil-in-water composition was produced in the same manner as in Production Example 2 except that the oil / fat formulation in the oil phase was changed. A type emulsified oil / fat composition 6 was obtained. After the obtained foamable oil-in-water emulsified oil / fat composition 6 was held at 5 ° C. (set value) for 4 days, the crystallization rate of the oil / fat in the emulsified oil / fat composition was determined by the above method. 3%. Next, after the foamable oil-in-water emulsified oil / fat composition 6 thus obtained was whipped by the above-described method, the texture, overrun and hardness were evaluated, and the results are summarized in Table 2. .

(比較例5) 起泡性水中油型乳化油脂組成物7の作製と評価
表2に示す配合に従って、油相部の油脂配合を変更した以外は製造例2と同様にして起泡性水中油型乳化油脂組成物7を得た。得られた起泡性水中油型乳化油脂組成物7を5℃(設定値)で4日間保持した後、前記方法で該乳化油脂組成物中の油脂の結晶化率を求めたところ、93.7%であった。次に得られた起泡性水中油型乳化油脂組成物7を上記記載の方法にてホイップを行なった後に食感、オーバーラン、硬さの評価を実施し、その結果を表2にまとめた。
(Comparative example 5) Production and evaluation of foamable oil-in-water emulsified oil / fat composition 7 According to the formulation shown in Table 2, a foamable oil-in-water composition was produced in the same manner as in Production Example 2 except that the oil / fat composition in the oil phase was changed. A type emulsified oil / fat composition 7 was obtained. The obtained foamable oil-in-water emulsified oil / fat composition 7 was held at 5 ° C. (set value) for 4 days, and then the crystallization rate of the oil / fat in the emulsified oil / fat composition was determined by the above method. 7%. Next, after the foamable oil-in-water emulsified oil / fat composition 7 thus obtained was whipped by the method described above, the texture, overrun and hardness were evaluated, and the results are summarized in Table 2. .

(比較例6) 起泡性水中油型乳化油脂組成物8の作製と評価
表2に示す配合に従って、油相部の油脂配合を変更した以外は製造例2と同様にして起泡性水中油型乳化油脂組成物8を得た。得られた起泡性水中油型乳化油脂組成物8を5℃(設定値)で4日間保持した後、前記方法で該乳化油脂組成物中の油脂の結晶化率を求めたところ、71.4%であった。次に得られた起泡性水中油型乳化油脂組成物8を上記記載の方法にてホイップを行なった後に食感、オーバーラン、硬さの評価を実施し、その結果を表2にまとめた。
(Comparative Example 6) Production and evaluation of foamable oil-in-water emulsified oil / fat composition 8 According to the formulation shown in Table 2, a foamable oil-in-water composition was prepared in the same manner as in Production Example 2 except that the oil / fat blending was changed. A type emulsified oil / fat composition 8 was obtained. The obtained foamable oil-in-water emulsified oil / fat composition 8 was held at 5 ° C. (set value) for 4 days, and then the crystallization rate of the oil / fat in the emulsified oil / fat composition was determined by the above method. 4%. Next, after the foamable oil-in-water emulsified oil / fat composition 8 thus obtained was whipped by the method described above, the texture, overrun and hardness were evaluated, and the results are summarized in Table 2. .

(比較例7) 起泡性水中油型乳化油脂組成物9の作製と評価
表2に示す配合に従って、油相部の油脂配合を変更した以外は製造例2と同様にして起泡性水中油型乳化油脂組成物9を得た。得られた起泡性水中油型乳化油脂組成物9を5℃(設定値)で4日間保持した後、前記方法で該乳化油脂組成物中の油脂の結晶化率を求めたところ、90.7%であった。次に得られた起泡性水中油型乳化油脂組成物9を上記記載の方法にてホイップを行なった後に食感、オーバーラン、硬さの評価を実施し、その結果を表2にまとめた。
(Comparative example 7) Production and evaluation of foamable oil-in-water emulsified oil / fat composition 9 According to the formulation shown in Table 2, a foamable oil-in-water solution was produced in the same manner as in Production Example 2 except that the oil / fat blending was changed. A type emulsified oil / fat composition 9 was obtained. After the obtained foamable oil-in-water emulsified oil / fat composition 9 was held at 5 ° C. (set value) for 4 days, the crystallization rate of the oil / fat in the emulsified oil / fat composition was determined by the above method. 7%. Next, after the foamable oil-in-water emulsified oil / fat composition 9 thus obtained was whipped by the method described above, the texture, overrun and hardness were evaluated, and the results are summarized in Table 2. .

以上の結果より、実施例の起泡性水中油型乳化油脂組成物は何れも、オーバーラン及びホイップ直後の硬さが良好であることから従来の保型性を維持できており、更に食した際に綿飴の如く非常に口溶けが良い。一方比較例においては、比較例1,2,3以外の起泡性水中油型乳化油脂組成物を用いたホイップドクリームは口溶けが悪く所望した食感とはなっておらず、比較例1,3の起泡性水中油型乳化油脂組成物を用いたホイップドクリームは、口溶けは良かったもの、十分なオーバーランとホイップ直後の硬さが得られず、軟らかく十分な保型性が得られず、また比較例2の起泡性水中油型乳化油脂組成物を用いたホイップドクリームは、やや口溶け感が重たく、十分なオーバーランが得られず、ホイップ直後の硬さも硬すぎるために作業性の悪いものであった。   From the above results, all of the foamable oil-in-water emulsified fats and oil compositions of the examples were able to maintain the conventional shape retention because they had good hardness immediately after overrun and whipping. In the case of cotton candy, it melts very well. On the other hand, in the comparative example, the whipped cream using the foamable oil-in-water emulsified oil / fat composition other than Comparative Examples 1, 2 and 3 does not dissolve in the mouth and does not have the desired texture. The whipped cream using the foamable oil-in-water emulsified oil / fat composition of No. 3 had good meltability in the mouth, but did not provide sufficient overrun and hardness just after whipping, and soft and sufficient shape retention was obtained. In addition, the whipped cream using the foamable oil-in-water emulsified oil / fat composition of Comparative Example 2 has a slightly heavy mouth-melting feeling, a sufficient overrun is not obtained, and the hardness immediately after whipping is too hard. It was bad.

Claims (6)

油脂含量が20〜40重量%の起泡性水中油型乳化油脂組成物であって、油相部の油脂全体中、構成脂肪酸の総炭素数が36と38のトリグリセライドの合計量が40重量%以上であり且つ上昇融点が30℃以上である油脂(A)の含有量が10〜40重量%であり、15℃のSFCが40〜70%であるラウリン系油脂である油脂(B)の含有量が20〜80重量%であり、油相部の油脂全体中油脂(A)と油脂(B)の合計量が60〜100重量%であり、油相部にHLBが0〜5の主要構成脂肪酸がベヘン酸である乳化剤を起泡性水中油型乳化油脂組成物全体中0.005〜0.1重量%含有するチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物。 A foamable oil-in-water emulsified oil / fat composition having an oil / fat content of 20 to 40% by weight, wherein the total amount of triglycerides having 36 and 38 total fatty acids in the fatty acid in the oil phase is 40% by weight Oil and fat (B), which is a lauric oil and fat having a rising melting point of 30 ° C. or higher and a fat and oil (A) content of 10 to 40% by weight and an SFC of 15 ° C. of 40 to 70% The amount is 20 to 80% by weight, the total amount of oil and fat (A) and fat and oil (B) in the whole oil phase part is 60 to 100% by weight, and the HLB is 0 to 5 in the oil phase part A foamable oil-in-water emulsified oil / fat composition for chilled whipped cream containing 0.005 to 0.1% by weight of an emulsifier whose fatty acid is behenic acid in the entire foamable oil-in-water emulsified oil / fat composition. 油脂(A)がパーム核ステアリンである請求項1に記載のチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物。 The foamable oil-in-water emulsified oil / fat composition for chilled circulation whipped cream according to claim 1, wherein the fat (A) is palm kernel stearin. 0〜10℃で冷蔵保管した時の結晶化率が45〜90重量%である請求項1又は2に記載のチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物。 The foamable oil-in-water emulsified oil / fat composition for chilled circulation whipped cream according to claim 1 or 2, wherein the crystallization rate when stored refrigerated at 0 to 10 ° C is 45 to 90% by weight. 起泡性水中油型乳化油脂組成物全体中、油相部にレシチンを0.02〜0.5重量%含有する請求項1〜3何れかに記載のチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物。 The foamable underwater for chilled circulation whipped cream according to any one of claims 1 to 3, wherein the oil phase part contains 0.02 to 0.5% by weight of lecithin in the entire foamable oil-in-water emulsified oil / fat composition. Oil type emulsified fat composition. 起泡性水中油型乳化油脂組成物全体中、水相部にホエー蛋白質を0.05〜5重量%含有する請求項1〜4何れかに記載のチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物。 The foamable underwater oil for chilled circulation whipped cream according to any one of claims 1 to 4, wherein the foamable oil-in-water emulsified oil / fat composition contains 0.05 to 5% by weight of whey protein in the aqueous phase. Type emulsified oil and fat composition. 請求項1〜5何れかに記載のチルド流通ホイップドクリーム用起泡性水中油型乳化油脂組成物を含んでなるホイップドクリーム。 A whipped cream comprising the foamable oil-in-water emulsified oil / fat composition for chilled distribution whipped cream according to any one of claims 1 to 5.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014171439A (en) * 2013-03-11 2014-09-22 J-Oil Mills Inc Fat composition for breads, and method of making breads
JP2017201927A (en) * 2016-05-11 2017-11-16 株式会社カネカ Edible foaming cream and edible whipped cream
JP2017205096A (en) * 2016-05-17 2017-11-24 理研ビタミン株式会社 Emulsifier for foamable oil-in-water type emulsion composition

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Publication number Priority date Publication date Assignee Title
JP2000116349A (en) * 1998-02-13 2000-04-25 Taiyo Kagaku Co Ltd Cream
JP2004107535A (en) * 2002-09-19 2004-04-08 Snow Brand Milk Prod Co Ltd Oil-in-water type emulsified oil and fat composition having foaming ability
JP2006304713A (en) * 2005-04-28 2006-11-09 Taiyo Yushi Kk Frozen whipped cream

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000116349A (en) * 1998-02-13 2000-04-25 Taiyo Kagaku Co Ltd Cream
JP2004107535A (en) * 2002-09-19 2004-04-08 Snow Brand Milk Prod Co Ltd Oil-in-water type emulsified oil and fat composition having foaming ability
JP2006304713A (en) * 2005-04-28 2006-11-09 Taiyo Yushi Kk Frozen whipped cream

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014171439A (en) * 2013-03-11 2014-09-22 J-Oil Mills Inc Fat composition for breads, and method of making breads
JP2017201927A (en) * 2016-05-11 2017-11-16 株式会社カネカ Edible foaming cream and edible whipped cream
JP2017205096A (en) * 2016-05-17 2017-11-24 理研ビタミン株式会社 Emulsifier for foamable oil-in-water type emulsion composition

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