JP2020015902A5 - - Google Patents
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- JP2020015902A5 JP2020015902A5 JP2019121320A JP2019121320A JP2020015902A5 JP 2020015902 A5 JP2020015902 A5 JP 2020015902A5 JP 2019121320 A JP2019121320 A JP 2019121320A JP 2019121320 A JP2019121320 A JP 2019121320A JP 2020015902 A5 JP2020015902 A5 JP 2020015902A5
- Authority
- JP
- Japan
- Prior art keywords
- solvent
- precursor
- precursor solution
- initiator
- free radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002243 precursor Substances 0.000 claims 30
- 238000000034 method Methods 0.000 claims 29
- 239000002904 solvent Substances 0.000 claims 25
- 150000003254 radicals Chemical class 0.000 claims 18
- 239000003999 initiator Substances 0.000 claims 17
- 229920006037 cross link polymer Polymers 0.000 claims 10
- 239000000499 gel Substances 0.000 claims 10
- 229920000642 polymer Polymers 0.000 claims 10
- 238000006116 polymerization reaction Methods 0.000 claims 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 6
- 230000015556 catabolic process Effects 0.000 claims 6
- 239000003638 chemical reducing agent Substances 0.000 claims 6
- 238000006731 degradation reaction Methods 0.000 claims 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 6
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims 4
- 238000000354 decomposition reaction Methods 0.000 claims 4
- 238000010438 heat treatment Methods 0.000 claims 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 3
- 125000005262 alkoxyamine group Chemical group 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 claims 3
- -1 methacrylic acid radical Chemical class 0.000 claims 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- 239000003153 chemical reaction reagent Substances 0.000 claims 2
- XLSMFKSTNGKWQX-UHFFFAOYSA-N hydroxyacetone Chemical compound CC(=O)CO XLSMFKSTNGKWQX-UHFFFAOYSA-N 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 238000005979 thermal decomposition reaction Methods 0.000 claims 2
- 239000008096 xylene Substances 0.000 claims 2
- HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 claims 1
- HSOOIVBINKDISP-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(CCC)OC(=O)C(C)=C HSOOIVBINKDISP-UHFFFAOYSA-N 0.000 claims 1
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 claims 1
- PNJLSKTVCRNRBO-UHFFFAOYSA-N 1-tert-butylperoxy-2,5-dimethylhexane Chemical compound CC(C)CCC(C)COOC(C)(C)C PNJLSKTVCRNRBO-UHFFFAOYSA-N 0.000 claims 1
- HQOVXPHOJANJBR-UHFFFAOYSA-N 2,2-bis(tert-butylperoxy)butane Chemical compound CC(C)(C)OOC(C)(CC)OOC(C)(C)C HQOVXPHOJANJBR-UHFFFAOYSA-N 0.000 claims 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims 1
- FDSUVTROAWLVJA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)COCC(CO)(CO)CO FDSUVTROAWLVJA-UHFFFAOYSA-N 0.000 claims 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims 1
- UZFMOKQJFYMBGY-UHFFFAOYSA-N 4-hydroxy-TEMPO Chemical compound CC1(C)CC(O)CC(C)(C)N1[O] UZFMOKQJFYMBGY-UHFFFAOYSA-N 0.000 claims 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 claims 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- VEBCLRKUSAGCDF-UHFFFAOYSA-N ac1mi23b Chemical compound C1C2C3C(COC(=O)C=C)CCC3C1C(COC(=O)C=C)C2 VEBCLRKUSAGCDF-UHFFFAOYSA-N 0.000 claims 1
- 238000007605 air drying Methods 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims 1
- 230000001588 bifunctional effect Effects 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 239000003431 cross linking reagent Substances 0.000 claims 1
- 230000003635 deoxygenating effect Effects 0.000 claims 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims 1
- 150000002009 diols Chemical class 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 239000008103 glucose Substances 0.000 claims 1
- 125000001976 hemiacetal group Chemical group 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 claims 1
- XVWOLKBRGCIQGK-UHFFFAOYSA-N n-tert-butyl-1-diethoxyphosphoryl-n-$l^{1}-oxidanyl-2,2-dimethylpropan-1-amine Chemical compound CCOP(=O)(OCC)C(N([O])C(C)(C)C)C(C)(C)C XVWOLKBRGCIQGK-UHFFFAOYSA-N 0.000 claims 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 230000003068 static effect Effects 0.000 claims 1
- 238000002210 supercritical carbon dioxide drying Methods 0.000 claims 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16/046,692 | 2018-07-26 | ||
| US16/046,692 US10836855B2 (en) | 2018-07-26 | 2018-07-26 | Method to produce colorless, high porosity, transparent polymer aerogels |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2020015902A JP2020015902A (ja) | 2020-01-30 |
| JP2020015902A5 true JP2020015902A5 (enExample) | 2022-06-30 |
Family
ID=67438425
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019121320A Pending JP2020015902A (ja) | 2018-07-26 | 2019-06-28 | 無色で高多孔性の透明なポリマーエアロゲルを製造する方法 |
Country Status (3)
| Country | Link |
|---|---|
| US (2) | US10836855B2 (enExample) |
| EP (1) | EP3599258B1 (enExample) |
| JP (1) | JP2020015902A (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10836855B2 (en) | 2018-07-26 | 2020-11-17 | Palo Alto Research Center Incorporated | Method to produce colorless, high porosity, transparent polymer aerogels |
| US11614409B2 (en) | 2018-12-20 | 2023-03-28 | Palo Alto Research Center Incorporated | Printed sensor with vibrant colorimetric particles |
| US11612852B2 (en) | 2020-05-28 | 2023-03-28 | Palo Alto Research Center Incorporated | Tunable, rapid uptake, aminopolymer aerogel sorbent for direct air capture of CO2 |
| US12270569B2 (en) | 2021-03-11 | 2025-04-08 | Palo Alto Research Center Incorporated | Reversible water-absorbing constructs comprising phase-change polymer filaments |
| US12491494B2 (en) | 2021-04-02 | 2025-12-09 | Genesee Valley Innovations, LLC | Moisture swing CO2 sorbents with enhanced capacity and kinetics |
| US11965793B2 (en) | 2021-05-18 | 2024-04-23 | Xerox Corporation | Stress engineering of transparent materials |
| CN120865650A (zh) * | 2025-09-28 | 2025-10-31 | 天津嘉泰伟业化工有限公司 | 一种低溶剂残留可发性聚苯乙烯材料及其制备方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2736342B1 (fr) | 1995-07-07 | 1999-01-29 | Univ Claude Bernard Lyon | Procede pour la fabrication d'aerogels de silice monolithiques et aerogels de silice ainsi obtenus |
| JP3296153B2 (ja) | 1995-09-06 | 2002-06-24 | 住友化学工業株式会社 | スチレン系重合体の製造方法、スチレン系樹脂組成物及びその成形品 |
| US5891971A (en) * | 1997-08-15 | 1999-04-06 | Xerox Corporation | Polymerization processes |
| KR100593427B1 (ko) | 1998-03-12 | 2006-06-28 | 루사이트 인터내셔널 유케이 리미티드 | 폴리머 조성물 |
| US6716948B1 (en) | 1999-07-31 | 2004-04-06 | Symyx Technologies, Inc. | Controlled-architecture polymers and use thereof as separation media |
| JP2004182944A (ja) * | 2002-12-06 | 2004-07-02 | Denki Kagaku Kogyo Kk | 樹脂組成物及びシュリンクフィルム |
| US7732496B1 (en) | 2004-11-03 | 2010-06-08 | Ohio Aerospace Institute | Highly porous and mechanically strong ceramic oxide aerogels |
| US20090178966A1 (en) * | 2005-10-07 | 2009-07-16 | Kyoto University | Process for Producing Organic Porous Material and Organic Porous Column and Organic Porous Material |
| US8110258B2 (en) | 2005-11-25 | 2012-02-07 | Advanced Glazing Technologies Limited (Agtl) | Glazing unit with transparent filler |
| JP5068765B2 (ja) * | 2005-12-14 | 2012-11-07 | ノバルティス アーゲー | シリコーンヒドロゲルの製造方法 |
| JP2011526958A (ja) | 2008-06-30 | 2011-10-20 | エスティーシー． ユーエヌエム | 耐久性のある、ポリマー−エアロゲルベースの超疎水性コーティング：複合材料 |
| WO2010080238A2 (en) | 2008-12-18 | 2010-07-15 | 3M Innovative Properties Company | Telechelic hybrid aerogels |
| US8691883B2 (en) | 2009-02-11 | 2014-04-08 | Samsung Electronics Co., Ltd. | Aerogel-foam composites |
| WO2012154602A1 (en) | 2011-05-06 | 2012-11-15 | Showers Robert James | Aerogel window film system |
| US9931280B2 (en) * | 2013-10-03 | 2018-04-03 | Dentsply Sirona Inc. | Dental composite compositions for reduced shrinkage stress |
| US10421253B2 (en) | 2016-10-05 | 2019-09-24 | Palo Alto Research Center Incorporated | Polymer aerogel for window glazings |
| WO2019006184A1 (en) * | 2017-06-29 | 2019-01-03 | Blueshift Materials, Inc. | POLYMER AEROGELS BASED ON HYPER-RAMIFIED POSS |
| US10626224B2 (en) | 2017-10-09 | 2020-04-21 | Palo Alto Research Center Incorporated | Method to produce transparent polymer aerogels using chain transfer agents |
| US10836855B2 (en) | 2018-07-26 | 2020-11-17 | Palo Alto Research Center Incorporated | Method to produce colorless, high porosity, transparent polymer aerogels |
-
2018
- 2018-07-26 US US16/046,692 patent/US10836855B2/en active Active
-
2019
- 2019-06-28 JP JP2019121320A patent/JP2020015902A/ja active Pending
- 2019-07-22 EP EP19187670.5A patent/EP3599258B1/en active Active
-
2020
- 2020-10-13 US US17/069,611 patent/US11760824B2/en active Active
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