JP2020002276A - Thermochromic ink composition for writing instrument and writing instrument using the same - Google Patents
Thermochromic ink composition for writing instrument and writing instrument using the same Download PDFInfo
- Publication number
- JP2020002276A JP2020002276A JP2018123783A JP2018123783A JP2020002276A JP 2020002276 A JP2020002276 A JP 2020002276A JP 2018123783 A JP2018123783 A JP 2018123783A JP 2018123783 A JP2018123783 A JP 2018123783A JP 2020002276 A JP2020002276 A JP 2020002276A
- Authority
- JP
- Japan
- Prior art keywords
- bis
- temperature
- acid
- pyridine
- reversible thermochromic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 73
- 239000000049 pigment Substances 0.000 claims abstract description 103
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- 150000001875 compounds Chemical class 0.000 claims abstract description 53
- 238000002844 melting Methods 0.000 claims abstract description 21
- 230000008018 melting Effects 0.000 claims abstract description 21
- 239000003094 microcapsule Substances 0.000 claims abstract description 18
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- 239000012429 reaction media Substances 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
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- 230000008859 change Effects 0.000 claims description 26
- 238000004042 decolorization Methods 0.000 claims description 10
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- 125000004432 carbon atom Chemical group C* 0.000 description 46
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
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- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002984 plastic foam Substances 0.000 description 1
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- IZQHTCYPZWOMFQ-UHFFFAOYSA-N propan-2-yl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OC(C)C IZQHTCYPZWOMFQ-UHFFFAOYSA-N 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- FKRCODPIKNYEAC-UHFFFAOYSA-N propionic acid ethyl ester Natural products CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000010979 ruby Substances 0.000 description 1
- 229910001750 ruby Inorganic materials 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 1
- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YCGURODZFQJGTO-UHFFFAOYSA-N tetradecyl 4-phenylbenzoate Chemical compound C1=CC(C(=O)OCCCCCCCCCCCCCC)=CC=C1C1=CC=CC=C1 YCGURODZFQJGTO-UHFFFAOYSA-N 0.000 description 1
- PVJXQWMBHUOOCK-UHFFFAOYSA-N tetradecyl decanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCC PVJXQWMBHUOOCK-UHFFFAOYSA-N 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- ZDIXOWNDGFVYNK-UHFFFAOYSA-N tridecan-3-one Chemical compound CCCCCCCCCCC(=O)CC ZDIXOWNDGFVYNK-UHFFFAOYSA-N 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- AAEAAZAPXYHUIW-UHFFFAOYSA-N tridecyl butyrate Chemical compound CCCCCCCCCCCCCOC(=O)CCC AAEAAZAPXYHUIW-UHFFFAOYSA-N 0.000 description 1
- JFOWPZXGNKSOTH-UHFFFAOYSA-N tridecyl decanoate Chemical compound CCCCCCCCCCCCCOC(=O)CCCCCCCCC JFOWPZXGNKSOTH-UHFFFAOYSA-N 0.000 description 1
- VBCBSDJKFLGBIX-UHFFFAOYSA-N tridecyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCC VBCBSDJKFLGBIX-UHFFFAOYSA-N 0.000 description 1
- INJZMNQWJIWOEA-UHFFFAOYSA-N tridecyl dodecanoate Chemical compound CCCCCCCCCCCCCOC(=O)CCCCCCCCCCC INJZMNQWJIWOEA-UHFFFAOYSA-N 0.000 description 1
- QEIJVPZRDAHCHE-UHFFFAOYSA-N tridecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCC QEIJVPZRDAHCHE-UHFFFAOYSA-N 0.000 description 1
- GKAVWWCJCPVMNR-UHFFFAOYSA-N tridecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCC GKAVWWCJCPVMNR-UHFFFAOYSA-N 0.000 description 1
- CTWLAMKOJQOQLN-UHFFFAOYSA-N tridecyl tetradecanoate Chemical compound CCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC CTWLAMKOJQOQLN-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 229940113164 trimyristin Drugs 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- VNHZHSYTJBADIV-UHFFFAOYSA-N undecyl 4-hydroxybenzoate Chemical compound CCCCCCCCCCCOC(=O)C1=CC=C(O)C=C1 VNHZHSYTJBADIV-UHFFFAOYSA-N 0.000 description 1
- 229940057402 undecyl alcohol Drugs 0.000 description 1
- ZBUPFBRWKJDEAX-UHFFFAOYSA-N undecyl decanoate Chemical compound CCCCCCCCCCCOC(=O)CCCCCCCCC ZBUPFBRWKJDEAX-UHFFFAOYSA-N 0.000 description 1
- JHDNXONYKMEEBK-UHFFFAOYSA-N undecyl dodecanoate Chemical compound CCCCCCCCCCCOC(=O)CCCCCCCCCCC JHDNXONYKMEEBK-UHFFFAOYSA-N 0.000 description 1
- NCSMRDAYUUPTTK-UHFFFAOYSA-N undecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCC NCSMRDAYUUPTTK-UHFFFAOYSA-N 0.000 description 1
- MRXRZUAPYOLFFW-UHFFFAOYSA-N undecyl octanoate Chemical compound CCCCCCCCCCCOC(=O)CCCCCCC MRXRZUAPYOLFFW-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Images
Landscapes
- Pens And Brushes (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
本発明は筆記具用熱変色性インキ組成物とそれを用いた筆記具に関する。更に詳細には、高温環境下であっても筆跡が不用意に消色することがない筆記具用熱変色性インキ組成物とそれを用いた筆記具に関する。 The present invention relates to a thermochromic ink composition for a writing instrument and a writing instrument using the same. More specifically, the present invention relates to a thermochromic ink composition for writing implements in which handwriting is not inadvertently erased even in a high temperature environment, and a writing implement using the same.
現在市販されている摩擦熱消色性筆記具には、消色温度が50〜65℃程度の水性インキ組成物が適用されている(例えば、特許文献1参照)。そのため、筆記した手帳等を夏場の自動車内等の高温状態下に放置した際に消色してしまうことがあり、消色温度の高温化が望まれている。
また、前記摩擦熱消色性筆記具には、着色剤として(イ)、(ロ)、(ハ)3成分を用いた可逆熱変色性マイクロカプセル顔料が広く用いられているが、水性媒体への溶解性が低いことから、より高温な融点を持つ(ハ)成分が好まれている。
しかしながら、(ハ)成分の水性媒体への安定性を考慮しながら、消色温度を高温化した場合、適用できる(ハ)成分の融点が高くなり過ぎてしまい、摩擦熱での消去が不可能又は困難なものとなるため、消色温度は摩擦熱発生の上限となる110℃以下にする必要がある。
An aqueous ink composition having a decoloring temperature of about 50 to 65 ° C. is applied to a friction heat decolorable writing instrument currently on the market (for example, see Patent Document 1). Therefore, when a written notebook or the like is left in a high temperature state such as in an automobile in summer, the color may be erased, and it is desired to increase the color erasing temperature.
In addition, the reversible thermochromic microcapsule pigments using three components (a), (b), and (c) as coloring agents are widely used in the frictional heat decolorable writing implement. Because of its low solubility, the component (c) having a higher melting point is preferred.
However, if the color erasing temperature is raised in consideration of the stability of the component (c) in an aqueous medium, the melting point of the applicable component (c) becomes too high, so that erasure with frictional heat is impossible. Or, it becomes difficult, so that the decoloring temperature needs to be 110 ° C. or less, which is the upper limit of the generation of frictional heat.
本発明は、高融点の(ハ)成分を用いた際にも、消色温度を110℃以下とすることで、水性媒体中でのマイクロカプセル顔料の安定性が高く、且つ、摩擦熱での消色が可能な範囲で消色温度を高温化することができる筆記具用熱変色性インキ組成物と、それを用いた筆記具を提供するものである。 According to the present invention, the stability of the microcapsule pigment in an aqueous medium is high and the frictional heat is reduced by setting the decoloring temperature to 110 ° C. or less even when a high melting point component (c) is used. An object of the present invention is to provide a thermochromic ink composition for writing implements capable of increasing the decoloring temperature within a range where decoloring is possible, and a writing implement using the same.
本発明は、(イ)電子供与性呈色性有機化合物、(ロ)電子受容性化合物、(ハ)前記(イ)、(ロ)の呈色反応をコントロールする反応媒体とからなる可逆熱変色性組成物をマイクロカプセルに内包させた可逆熱変色性顔料を着色剤として用いた水性インキ組成物であって、前記(ハ)成分が、80℃〜130℃の範囲に融点があり、可逆熱変色性組成物全量中60〜90質量%の範囲にある筆記具用熱変色性インキ組成物を要件とする。
更に、前記可逆熱変色性顔料の消色温度が75℃以上110℃以下であること、前記可逆熱変色性顔料(着色剤A)と、消色温度が40℃以上70℃以下である可逆熱変色性顔料(着色剤B)を併用すること、前記着色剤Bの色相が着色剤Aの色相と異なり、二種類の消色温度TA,TB(TA>TB)で二段階に色相変化を生じること、前記着色剤がインキ組成物全量中10〜40質量%の範囲で添加されることを要件とする。
更には、前記いずれかに記載の筆記具用熱変色性インキ組成物を内蔵した筆記具を要件とし、前記筆記具による筆跡を摩擦熱で変色する摩擦部材を備えてなること、前記摩擦部材が二種類からなり、紙面との摩擦により、一方がTBからTAの範囲の摩擦熱を発し、他方がTA以上の摩擦熱を発するものであることを要件とする。
The present invention provides a reversible thermochromic composition comprising (a) an electron-donating color-forming organic compound, (b) an electron-accepting compound, and (c) a reaction medium for controlling the color reaction of (a) and (b). An aqueous ink composition using, as a colorant, a reversible thermochromic pigment in which a hydrophobic composition is encapsulated in microcapsules, wherein the component (c) has a melting point in the range of 80 ° C to 130 ° C, The requirement is a thermochromic ink composition for writing implements in the range of 60 to 90% by mass of the total amount of the color changing composition.
Further, the decolorizing temperature of the reversible thermochromic pigment is 75 ° C. or more and 110 ° C. or less, and the reversible thermochromic pigment (colorant A) has a decoloring temperature of 40 ° C. or more and 70 ° C. or less. be used in combination discoloring pigment (colorant B), the hue of the colorant B is different from the hue of the colorant a, two types of color erasure temperature T a, in two steps at T B (T a> T B ) It is required that a hue change occurs and that the colorant be added in a range of 10 to 40% by mass based on the total amount of the ink composition.
Further, a writing implement incorporating the thermochromic ink composition for a writing implement according to any of the above is a requirement, comprising a friction member that discolors handwriting by frictional heat with the writing implement, wherein the friction member is from two types. becomes, due to friction with the paper, one emits a frictional heat in the range of T a from T B, the other is a requirement that as it emits more frictional heat T a.
本発明は、水性媒体への溶解性が低い高融点の(ハ)成分を用いた際にも、摩擦熱で発揮できる110℃以下を消色温度とすることが可能となるため、水性媒体中でのマイクロカプセル顔料の安定性が高く、且つ、摩擦熱での消色が可能な範囲で消色温度を高温化でき、自動車内等の高温状態下に放置した際に消色し難い筆跡を長期に亘って安定形成できる筆記具用熱変色性インキ組成物と、それを用いた筆記具となる。
更に、インキ安定性が高い、着色(1)から着色(2)、更に消色へ色変化する二段変色インキを構成できるため、より商品価値が高い筆記具用熱変色性インキ組成物と、それを用いた筆記具となる。
According to the present invention, even when a high melting point component (c) having low solubility in an aqueous medium is used, the colorless temperature can be set to 110 ° C. or lower, which can be exhibited by frictional heat. The stability of the microcapsule pigment is high, and the decolorization temperature can be raised within the range where decolorization by frictional heat is possible, and handwriting that is difficult to decolor when left in a high temperature state such as in an automobile A thermochromic ink composition for a writing instrument that can be formed stably over a long period of time, and a writing instrument using the same.
Furthermore, a thermochromic ink composition for a writing instrument having a higher commercial value can be formed because a two-stage color changing ink having high ink stability and changing color from coloring (1) to coloring (2) and further to decoloring can be constituted. It becomes a writing instrument using.
着色剤としては、(イ)電子供与性呈色性有機化合物、(ロ)電子受容性化合物、(ハ)前記両者の呈色反応の生起温度を決める反応媒体からなる可逆熱変色性組成物をマイクロカプセルに内包させた可逆熱変色性顔料が用いられる。 As the colorant, a reversible thermochromic composition comprising (a) an electron-donating color-forming organic compound, (b) an electron-accepting compound, and (c) a reaction medium which determines the temperature at which the color reaction of the two occurs. A reversible thermochromic pigment encapsulated in microcapsules is used.
前記可逆熱変色性組成物は、所定の温度(変色点)を境としてその前後で変色し、高温側変色点以上の温度域で消色状態、低温側変色点以下の温度域で発色状態を呈し、前記両状態のうち特定の温度域ではいずれか一方の状態しか存在せず、もう一方の状態は、その状態が発現するのに要した熱又は冷熱が適用されている間は維持されるが、前記熱又は冷熱の適用がなくなれば元の状態に戻る、ヒステリシス幅(ΔH)が比較的小さい特性を有する(図1参照)。
また、大きなヒステリシス特性を示す、即ち、温度変化による着色濃度の変化をプロットした曲線の形状が、温度を変色温度域より低温側から上昇させていく場合と逆に変色温度域より高温側から下降させていく場合とで大きく異なる経路を辿って変色し、完全発色温度(t1)以下の低温域での発色状態、又は完全消色温度(t4)以上の高温域での消色状態が、特定温度域〔t2〜t3の間の温度域(実質的二相保持温度域)〕で色彩記憶性を有する加熱消色型(加熱により消色し、冷却により発色する)の可逆熱変色性組成物も適用できる(図2参照)。
本発明において、前記可逆熱変色性組成物を用いた際における「筆跡の熱消色時」とは、完全消色温度(t4)以上となった状態をいう。
The reversible thermochromic composition undergoes a color change before and after a predetermined temperature (color change point) as a boundary, a decolored state in a temperature range above the high temperature color change point, and a color development state in a temperature range below the low temperature color change point. Present, only one of the two states exists in a specific temperature range, and the other state is maintained while the heat or cold required for the state to develop is applied. However, it returns to its original state when the application of the heat or the cold is stopped, and has a characteristic that the hysteresis width (ΔH) is relatively small (see FIG. 1).
In addition, it shows a large hysteresis characteristic, that is, the shape of the curve plotting the change in the coloring density due to the temperature change is lower than the color change temperature range from the higher temperature side in contrast to the case where the temperature is increased from a lower temperature side than the color change temperature range. The color changes along a route that is significantly different from that in the case where the color is developed, and the color development state in a low temperature range below the full color development temperature (t 1 ) or the decoloration state in a high temperature range above the complete decolorization temperature (t 4 ) is obtained. Reversible heat of a heat decoloring type (color decolored by heating and colored by cooling) having a color memory property in a specific temperature range [temperature range between t 2 and t 3 (substantially two-phase holding temperature range)] Discolorable compositions can also be applied (see FIG. 2).
In the present invention, “when the handwriting is thermally decolored” when the reversible thermochromic composition is used refers to a state in which the temperature is equal to or higher than a complete decoloring temperature (t 4 ).
以下に各(イ)、(ロ)、(ハ)成分について具体的に説明する。
(イ)成分、即ち電子供与性呈色性有機化合物は、色を決める成分であって、顕色剤である(ロ)成分に電子を供与し、発色する化合物である。
前記電子供与性呈色性有機化合物としては、フタリド化合物、フルオラン化合物、スチリノキノリン化合物、ピリジン化合物、キナゾリン化合物、ビスキナゾリン化合物、ジアザローダミンラクトン化合物が挙げられ、そのうち、発色時に蛍光性を有するためには、ピリジン化合物、キナゾリン化合物、ビスキナゾリン化合物、ジアザローダミンラクトン系化合物が用いられ、ピリジン化合物が好適に用いられる。
前記ピリジン系化合物としては、
4−(4′−メチルベンジルアミノフェニル)−ピリジン、
2,6−ジフェニル−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ジフェニル−4−(4′−N−フェニル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−メチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′−エチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′−プロピルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ブチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ペンチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ヘキシルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ヘプチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′−オクチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′−メチルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′−エチルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′−プロピルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ブチルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ペンチルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ヘキシルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ヘプチルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′−オクチルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′−メチルオキシフェニル)−4−(4′−N−フェニル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−エチルオキシフェニル)−4−(4′−N−フェニル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ブチルオキシフェニル)−4−(4′−N−フェニル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ヘキシルオキシフェニル)−4−(4′−N−フェニル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−オクチルオキシフェニル)−4−(4′−N−フェニル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−メチルオキシフェニル)−4−(4′−N−クロロエチル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−エチルオキシフェニル)−4−(4′−N−クロロエチル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ブチルオキシフェニル)−4−(4′−N−クロロエチル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ヘキシルオキシフェニル)−4−(4′−N−クロロエチル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−オクチルオキシフェニル)−4−(4′−N−クロロエチル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−メチルオキシフェニル)−4−(4′−N−エチルオキシエチル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−エチルオキシフェニル)−4−(4′−N−エチルオキシエチル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ブチルオキシフェニル)−4−(4′−N−エチルオキシエチル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ヘキシルオキシフェニル)−4−(4′−N−エチルオキシエチル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−オクチルオキシフェニル)−4−(4′−N−エチルオキシエチル−N−メチルアミノフェニル)−ピリジン、
2,6−ビス(2′−メチルオキシフェニル)−4−(4′−ジブチルアミノフェニル)−ピリジン、
2,6−ビス(2′−エチルオキシフェニル)−4−(4′−ジブチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ブチルオキシフェニル)−4−(4′−ジブチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ヘキシルオキシフェニル)−4−(4′−ジブチルアミノフェニル)−ピリジン、
2,6−ビス(2′−オクチルオキシフェニル)−4−(4′−ジブチルアミノフェニル)−ピリジン、
2,6−ビス(2′−メチルオキシフェニル)−4−(4′−N−イソブチル−N−エチルアミノフェニル)−ピリジン、
2,6−ビス(2′−エチルオキシフェニル)−4−(4′−N−イソブチル−N−エチルアミノフェニル)−ピリジン、
2,6−ビス(2′−プロピルオキシフェニル)−4−(4′−N−イソブチル−N−エチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ブチルオキシフェニル)−4−(4′−N−イソブチル−N−エチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ペンチルオキシフェニル)−4−(4′−N−イソブチル−N−エチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ヘキシルオキシフェニル)−4−(4′−N−イソブチル−N−エチルアミノフェニル)−ピリジン、
2,6−ビス(2′−ヘプチルオキシフェニル)−4−(4′−N−イソブチル−N−エチルアミノフェニル)−ピリジン、
2,6−ビス(2′−オクチルオキシフェニル)−4−(4′−N−イソブチル−N−エチルアミノフェニル)−ピリジン、
2,6−ビス(2´−ノニルオキシフェニル)−4−(4′−N−イソブチル−N−エチルアミノフェニル)−ピリジン、
2,6−ビス(4′−メチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ジメチル−3,5−ビスカルボエトキシ−4−(4′−ジメチルアミノフェニル)−ピリジン、
2−(2′−オクチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−6−フェニル−ピリジン、
2,6−ジエチルオキシ−4−(4′−ジエチルアミノフェニル)−ピリジン 4−(4−メチルオキシフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−フェニル−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−メチルフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
2,4,6−トリス(4−ジメチルアミノフェニル)−ピリジン、
4−(2−クロロ−4−ジメチルアミノフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(3−ニトロフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−メチルオキシカルボニルフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−ジメチルアミノフェニル)−2,6−ビス(2−チエニル)−ピリジン、
4−(4−ジメチルアミノフェニル)−2,6−ビス(2−フリル)−ピリジン、
4−(2−クロロ−4−ジメチルアミノフェニル)−2,6−ビス(2−チエニル)−ピリジン、
4−〔4−(1−ピペリジニル)フェニル〕−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−モルホリノフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(9−ジュロリジニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−メチルフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−メチルオキシフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−メチルオキシフェニル)−2,6−ビス(4−モルホリノフェニル)−ピリジン、
4−(4−フルオロフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−N−オクチルオキシフェニル−N−メチルアミノ)−2,6−ジフェニルピリジン、
4−(4−クロロフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−ニトロフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−N−2−シアノエチル−N−メチルアミノフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(2,5−ジメチルオキシフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−ジエチルアミノフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−ビフェニルイル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−ピロリジニルフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−イソインドリニルフェニル)−2,6−ビス(4−ジメチルアミノフェニル)−ピリジン、
4−(4−N−2−シアノエチル−N−メチルアミノフェニル)−2,6−ジフェニルピリジン、
4−(4−N−メチル−N−フェニルアミノフェニル)−2,6−ジフェニルピリジン、
4−(4−N−クロロエチル−N−メチルアミノフェニル)−2,6−ジフェニルピリジン、
4−(4−N−エチルオキシエチル−N−メチルアミノフェニル)−2,6−ジフェニルピリジン、
2,6−ビス(2′,4′−ジメチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジエチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジプロピルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジブチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジペンチルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジヘキシルオキシフェニル)−4−(4′−ジメチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジメチルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジエチルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジプロピルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジブチルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジペンチルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジヘキシルオキシフェニル)−4−(4′−ジエチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジメチルオキシフェニル)−4−(4′−ジプロピルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジエチルオキシフェニル)−4−(4′−ジプロピルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジプロピルオキシフェニル)−4−(4′−ジプロピルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジブチルオキシフェニル)−4−(4′−ジプロピルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジペンチルオキシフェニル)−4−(4′−ジプロピルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジヘキシルオキシフェニル)−4−(4′−ジプロピルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジメチルオキシフェニル)−4−(4′−ジブチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジエチルオキシフェニル)−4−(4′−ジブチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジプロピルオキシフェニル)−4−(4′−ジブチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジブチルオキシフェニル)−4−(4′−ジブチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジペンチルオキシフェニル)−4−(4′−ジブチルアミノフェニル)−ピリジン、
2,6−ビス(2′,4′−ジヘキシルオキシフェニル)−4−(4′−ジブチルアミノフェニル)−ピリジン、
等が挙げられる。
Hereinafter, the components (a), (b), and (c) will be specifically described.
The component (a), that is, the electron-donating color-forming organic compound, is a component that determines color and is a compound that gives an electron to the component (b) as a color developer and develops a color.
Examples of the electron-donating color-forming organic compound include a phthalide compound, a fluoran compound, a styrinoquinoline compound, a pyridine compound, a quinazoline compound, a bisquinazoline compound, and a diazarhodamine lactone compound. As the pyridine compound, a pyridine compound, a quinazoline compound, a bisquinazoline compound, a diazarhodamine lactone compound are used, and a pyridine compound is preferably used.
As the pyridine compound,
4- (4'-methylbenzylaminophenyl) -pyridine,
2,6-diphenyl-4- (4'-dimethylaminophenyl) -pyridine,
2,6-diphenyl-4- (4'-N-phenyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-methyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2'-ethyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2'-propyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2'-butyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2'-pentyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2'-hexyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2'-heptyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2'-octyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2'-methyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2'-ethyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2'-propyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2'-butyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2'-pentyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2'-hexyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2'-heptyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2'-octyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2'-methyloxyphenyl) -4- (4'-N-phenyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-ethyloxyphenyl) -4- (4'-N-phenyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-butyloxyphenyl) -4- (4'-N-phenyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-hexyloxyphenyl) -4- (4'-N-phenyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-octyloxyphenyl) -4- (4'-N-phenyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-methyloxyphenyl) -4- (4'-N-chloroethyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-ethyloxyphenyl) -4- (4'-N-chloroethyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-butyloxyphenyl) -4- (4'-N-chloroethyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-hexyloxyphenyl) -4- (4'-N-chloroethyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-octyloxyphenyl) -4- (4'-N-chloroethyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-methyloxyphenyl) -4- (4'-N-ethyloxyethyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-ethyloxyphenyl) -4- (4'-N-ethyloxyethyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-butyloxyphenyl) -4- (4'-N-ethyloxyethyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-hexyloxyphenyl) -4- (4'-N-ethyloxyethyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-octyloxyphenyl) -4- (4'-N-ethyloxyethyl-N-methylaminophenyl) -pyridine,
2,6-bis (2'-methyloxyphenyl) -4- (4'-dibutylaminophenyl) -pyridine,
2,6-bis (2'-ethyloxyphenyl) -4- (4'-dibutylaminophenyl) -pyridine,
2,6-bis (2'-butyloxyphenyl) -4- (4'-dibutylaminophenyl) -pyridine,
2,6-bis (2'-hexyloxyphenyl) -4- (4'-dibutylaminophenyl) -pyridine,
2,6-bis (2'-octyloxyphenyl) -4- (4'-dibutylaminophenyl) -pyridine,
2,6-bis (2'-methyloxyphenyl) -4- (4'-N-isobutyl-N-ethylaminophenyl) -pyridine,
2,6-bis (2'-ethyloxyphenyl) -4- (4'-N-isobutyl-N-ethylaminophenyl) -pyridine,
2,6-bis (2'-propyloxyphenyl) -4- (4'-N-isobutyl-N-ethylaminophenyl) -pyridine,
2,6-bis (2'-butyloxyphenyl) -4- (4'-N-isobutyl-N-ethylaminophenyl) -pyridine,
2,6-bis (2'-pentyloxyphenyl) -4- (4'-N-isobutyl-N-ethylaminophenyl) -pyridine,
2,6-bis (2'-hexyloxyphenyl) -4- (4'-N-isobutyl-N-ethylaminophenyl) -pyridine,
2,6-bis (2'-heptyloxyphenyl) -4- (4'-N-isobutyl-N-ethylaminophenyl) -pyridine,
2,6-bis (2'-octyloxyphenyl) -4- (4'-N-isobutyl-N-ethylaminophenyl) -pyridine,
2,6-bis (2'-nonyloxyphenyl) -4- (4'-N-isobutyl-N-ethylaminophenyl) -pyridine,
2,6-bis (4'-methyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-dimethyl-3,5-biscarboethoxy-4- (4'-dimethylaminophenyl) -pyridine,
2- (2'-octyloxyphenyl) -4- (4'-dimethylaminophenyl) -6-phenyl-pyridine,
2,6-diethyloxy-4- (4'-diethylaminophenyl) -pyridine 4- (4-methyloxyphenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4-phenyl-2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-methylphenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
2,4,6-tris (4-dimethylaminophenyl) -pyridine,
4- (2-chloro-4-dimethylaminophenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (3-nitrophenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-methyloxycarbonylphenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-dimethylaminophenyl) -2,6-bis (2-thienyl) -pyridine,
4- (4-dimethylaminophenyl) -2,6-bis (2-furyl) -pyridine,
4- (2-chloro-4-dimethylaminophenyl) -2,6-bis (2-thienyl) -pyridine,
4- [4- (1-piperidinyl) phenyl] -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-morpholinophenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (9-julolidinyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-methylphenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-methyloxyphenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-methyloxyphenyl) -2,6-bis (4-morpholinophenyl) -pyridine,
4- (4-fluorophenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-N-octyloxyphenyl-N-methylamino) -2,6-diphenylpyridine,
4- (4-chlorophenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-nitrophenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-N-2-cyanoethyl-N-methylaminophenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (2,5-dimethyloxyphenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-diethylaminophenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-biphenylyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-pyrrolidinylphenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-isoindolinylphenyl) -2,6-bis (4-dimethylaminophenyl) -pyridine,
4- (4-N-2-cyanoethyl-N-methylaminophenyl) -2,6-diphenylpyridine,
4- (4-N-methyl-N-phenylaminophenyl) -2,6-diphenylpyridine,
4- (4-N-chloroethyl-N-methylaminophenyl) -2,6-diphenylpyridine,
4- (4-N-ethyloxyethyl-N-methylaminophenyl) -2,6-diphenylpyridine,
2,6-bis (2 ', 4'-dimethyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-diethyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dipropyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dibutyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dipentyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dihexyloxyphenyl) -4- (4'-dimethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dimethyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-diethyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dipropyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dibutyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dipentyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dihexyloxyphenyl) -4- (4'-diethylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dimethyloxyphenyl) -4- (4'-dipropylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-diethyloxyphenyl) -4- (4'-dipropylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dipropyloxyphenyl) -4- (4'-dipropylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dibutyloxyphenyl) -4- (4'-dipropylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dipentyloxyphenyl) -4- (4'-dipropylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dihexyloxyphenyl) -4- (4'-dipropylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dimethyloxyphenyl) -4- (4'-dibutylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-diethyloxyphenyl) -4- (4'-dibutylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dipropyloxyphenyl) -4- (4'-dibutylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dibutyloxyphenyl) -4- (4'-dibutylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dipentyloxyphenyl) -4- (4'-dibutylaminophenyl) -pyridine,
2,6-bis (2 ', 4'-dihexyloxyphenyl) -4- (4'-dibutylaminophenyl) -pyridine,
And the like.
前記キナゾリン系化合物としては、
2−(4′−ジメチルアミノフェニル)−4−メチルオキシ−キナゾリン、
2−(4′−ジメチルアミノフェニル)−4−フェニルオキシ−キナゾリン、
2−(4′−ジメチルアミノフェニル)−4−(4′′−ニトロフェニルオキシ)−キナゾリン、
2−(4′−ジメチルアミノフェニル)−4−フェニルチオ−キナゾリン、
2−(4′−N−フェニル−N−メチルアミノフェニル)−4−フェニルオキシ−キナゾリン、
2−(4′−ピペリジノフェニル)−4−フェノキシ−キナゾリン、
2−(4′−ジメチルアミノフェニル)−4−(4′′−クロロフェニルオキシ)−キナゾリン、
2−(4′−ジメチルアミノフェニル)−4−(4′′−メチルオキシフェニルオキシ)−キナゾリン、
2−(4′−ジメチルアミノフェニル)−4−(N−フェニル−N−メチルアミノ)−キナゾリン、
2−(4′−ジメチルアミノフェニル)−4−モルホリノ−キナゾリン、
2−(4′−ジエチルアミノフェニル)−4−フェニル−キナゾリン、
2−(4′−ジエチルアミノフェニル)−4−メチル−キナゾリン、
2−(1′−エチル−2′,2′,4′−トリメチル−テトラヒドロキノリン−6′−イル)−4−フェニルオキシ−キナゾリン、
2−(1′−エチル−2′,2′,4′−トリメチル−テトラヒドロキノリン−6′−イル)−4−メチルオキシ−キナゾリン、
2−(1′,2′,2′,4′−テトラメチル−テトラヒドロキノリン−6′−イル)−4−フェニルオキシ−キナゾリン、
2−(1′−エチル−2′−メチル−テトラヒドロキノリン−6′−イル)−4−フェニルオキシ−キナゾリン、
2−(1′,3′−ジメチルインドリン−5′−イル)−4−フェニルオキシ−キナゾリン、
2−(3′,4′−ジメチルベンゾモルホリン−7′−イル)−4−フェニルオキシ−キナゾリン、
2−(4′−ジエチルアミノフェニル)−4−(2′′−フェニルオキシエチルオキシ)−キナゾリン、
2−(4′−ジエチルアミノフェニル)−4−(2′′−N−フェニル−N−エチルアミノエチルオキシ)−キナゾリン、
2−(4′−ジメチルアミノフェニル)−4−(2′′−モルホリノエチルオキシ)−キナゾリン、
2−(4′−ジベンジルアミノフェニル)−4−(2′′−フェニルオキシエチルオキシ)−キナゾリン、
2−(4′−ジエチルアミノフェニル)−4−(2′′−フェニルオキシエチルチオ)−キナゾリン、
2−(4′−ジエチルアミノフェニル)−4−〔2′′−(1−ナフチルオキシ)エチルオキシ〕−キナゾリン、
2−(3′,4′−ジメチルベンゾモルホリン−7′−イル)−(2′′−フェニルオキシエチルオキシ)−キナゾリン、
等が挙げられる。
As the quinazoline compound,
2- (4'-dimethylaminophenyl) -4-methyloxy-quinazoline,
2- (4'-dimethylaminophenyl) -4-phenyloxy-quinazoline,
2- (4'-dimethylaminophenyl) -4- (4 "-nitrophenyloxy) -quinazoline,
2- (4'-dimethylaminophenyl) -4-phenylthio-quinazoline,
2- (4'-N-phenyl-N-methylaminophenyl) -4-phenyloxy-quinazoline,
2- (4'-piperidinophenyl) -4-phenoxy-quinazoline,
2- (4'-dimethylaminophenyl) -4- (4 "-chlorophenyloxy) -quinazoline,
2- (4'-dimethylaminophenyl) -4- (4 "-methyloxyphenyloxy) -quinazoline,
2- (4'-dimethylaminophenyl) -4- (N-phenyl-N-methylamino) -quinazoline,
2- (4'-dimethylaminophenyl) -4-morpholino-quinazoline,
2- (4'-diethylaminophenyl) -4-phenyl-quinazoline,
2- (4'-diethylaminophenyl) -4-methyl-quinazoline,
2- (1'-ethyl-2 ', 2', 4'-trimethyl-tetrahydroquinolin-6'-yl) -4-phenyloxy-quinazoline,
2- (1'-ethyl-2 ', 2', 4'-trimethyl-tetrahydroquinolin-6'-yl) -4-methyloxy-quinazoline,
2- (1 ', 2', 2 ', 4'-tetramethyl-tetrahydroquinolin-6'-yl) -4-phenyloxy-quinazoline,
2- (1'-ethyl-2'-methyl-tetrahydroquinolin-6'-yl) -4-phenyloxy-quinazoline,
2- (1 ', 3'-dimethylindoline-5'-yl) -4-phenyloxy-quinazoline,
2- (3 ', 4'-dimethylbenzomorpholin-7'-yl) -4-phenyloxy-quinazoline,
2- (4'-diethylaminophenyl) -4- (2 "-phenyloxyethyloxy) -quinazoline,
2- (4'-diethylaminophenyl) -4- (2 "-N-phenyl-N-ethylaminoethyloxy) -quinazoline,
2- (4'-dimethylaminophenyl) -4- (2 "-morpholinoethyloxy) -quinazoline,
2- (4'-dibenzylaminophenyl) -4- (2 "-phenyloxyethyloxy) -quinazoline,
2- (4'-diethylaminophenyl) -4- (2 "-phenyloxyethylthio) -quinazoline,
2- (4'-diethylaminophenyl) -4- [2 "-(1-naphthyloxy) ethyloxy] -quinazoline,
2- (3 ', 4'-dimethylbenzomorpholin-7'-yl)-(2 "-phenyloxyethyloxy) -quinazoline,
And the like.
前記ビスキナゾリン系化合物としては、
4,4′−(エチレンジオキシ)−ビス〔2−(4−ジエチルアミノフェニル)−キナゾリン〕、
4,4′−〔プロピレンジオキシ(1,3)〕−ビス〔2−(4−ジエチルアミノフェニル)−キナゾリン〕、
4,4′−〔ブチレンジオキシ(1,3)〕−ビス〔2−(4−ジエチルアミノフェニル)−キナゾリン〕、
4,4′−〔ブチレンジオキシ(1,4)〕−ビス〔2−(4−ジエチルアミノフェニル)−キナゾリン〕、
4,4′−(オキシジエチレン)−ビス〔2−(4−ジエチルアミノフェニル)−キナゾリン〕、
4,4′−エチレン−ビス〔2−(4−ピペリジノフェニル)−キナゾリン〕、
4,4′−エチレン−ビス〔2−(4−ジ−n−プロピルアミノフェニル)−キナゾリン〕、
4,4′−(エチレンジオキシ)−ビス〔2−(4−ジ−n−ブチルアミノフェニル)−キナゾリン〕、
4,4′−シクロヘキシレン−ビス〔2−(4−ジエチルアミノフェニル)−キナゾリン〕、
等が挙げられる。
As the bisquinazoline compound,
4,4 '-(ethylenedioxy) -bis [2- (4-diethylaminophenyl) -quinazoline],
4,4 '-[propylenedioxy (1,3)]-bis [2- (4-diethylaminophenyl) -quinazoline],
4,4 '-[butyleneoxy (1,3)]-bis [2- (4-diethylaminophenyl) -quinazoline],
4,4 ′-[butyleneoxy (1,4)]-bis [2- (4-diethylaminophenyl) -quinazoline],
4,4 '-(oxydiethylene) -bis [2- (4-diethylaminophenyl) -quinazoline],
4,4'-ethylene-bis [2- (4-piperidinophenyl) -quinazoline],
4,4'-ethylene-bis [2- (4-di-n-propylaminophenyl) -quinazoline],
4,4 '-(ethylenedioxy) -bis [2- (4-di-n-butylaminophenyl) -quinazoline],
4,4'-cyclohexylene-bis [2- (4-diethylaminophenyl) -quinazoline],
And the like.
前記ジアザローダミンラクトン系化合物としては、
2−(ジメチルアミノ)−8−(ジメチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジエチルアミノ)−8−(ジエチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−プロピルアミノ)−8−(ジ−n−プロピルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジ−n−ブチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジメチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジエチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(N−エチル−N−i−ブチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(N−エチル−N−i−アミルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(N−エチル−N−n−ヘキシルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジ−n−アミルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(n−オクチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジメチルアミノ)−8−(ジエチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジエチルアミノ)−8−(ジメチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(モルホリノ)−8−(ジエチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ピペリジノ)−8−(ジエチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(N−メチルピペラジノ)−8−(ジエチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ピロリジノ)−8−(ジエチルアミノ)−4−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジエチルアミノ)−8−(ジエチルアミノ)−4−メチル−4′,5′,6′,7′−テトラクロロ−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジエチルアミノ)−8−(ジエチルアミノ)−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジ−n−ブチルアミノ)−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(N−エチル−N−i−アミルアミノ)−8−(N−エチル−N−i−アミルアミノ)−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジエチルアミノ)−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(N−エチル−N−i−アミルアミノ)−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ピペリジノ)−8−(エチルアミノ)−4−メチル−7−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジエチルアミノ)−4−メチル−7−メチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジエチルアミノ)−4−メチル−7−エチル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジエチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジ−n−ブチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(N−エチル−N−i−アミルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ピペリジノ)−8−(ジエチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(N−メチル−N−シクロヘキシルアミノ)−8−(ジエチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジメチルアミノ)−8−(ジエチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(i−アミルアミノ)−8−(ジエチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ピロリジノ)−8−(ジエチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(N−メチルピペラジノ)−8−(ジエチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(モルホリノ)−8−(ジエチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(N−メチル−N−ベンジルアミノ)−8−(ジエチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−[ジ(2−メトキシエチル)アミノ]−8−(ジエチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジエチルアミノ)−4−(4−メトキシフェニル)−スピロ[5H−[1]ベンゾピラノ(2,3−d)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジエチルアミノ)−4−(4−クロロフェニル)−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジ−n−ブチルアミノ)−8−(ジエチルアミノ)−4−(4−メチルフェニル)−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−[ジ(2−エトキシエチル)アミノ]−8−(ジメチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジエチルアミノ)−8−[(2−メチルフェニル)アミノ]−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(2,6−ジメチルモルホリノ)−8−(ジエチアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジシクロヘキシルアミノ)−8−(ジメチルアミノ)−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
2−(ジブチルアミノ)−8−[(4−クロロフェニル)アミノ]−4−フェニル−スピロ[5H−[1]ベンゾピラノ(2,3−g)ピリミジン−5,1′(3′H)−イソベンゾフラン]−3′−オン、
等が挙げられる。
As the diaza rhodamine lactone compound,
2- (dimethylamino) -8- (dimethylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3 '-On,
2- (diethylamino) -8- (diethylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3'- on,
2- (di-n-propylamino) -8- (di-n-propylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3' H) -Isobenzofuran] -3'-one,
2- (di-n-butylamino) -8- (di-n-butylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 ′ (3 ′ H) -Isobenzofuran] -3'-one,
2- (di-n-butylamino) -8- (dimethylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -iso Benzofuran] -3'-one,
2- (di-n-butylamino) -8- (diethylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 ′ (3′H) -isobenzofuran ] -3'-one,
2- (di-n-butylamino) -8- (N-ethyl-Ni-butylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3'-one,
2- (di-n-butylamino) -8- (N-ethyl-Ni-amylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 ' (3′H) -isobenzofuran] -3′-one,
2- (di-n-butylamino) -8- (N-ethyl-N-n-hexylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3'-one,
2- (di-n-butylamino) -8- (di-n-amylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 ′ (3′H ) -Isobenzofuran] -3'-one,
2- (di-n-butylamino) -8- (n-octylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -Isobenzofuran] -3'-one,
2- (dimethylamino) -8- (diethylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3' -ON,
2- (diethylamino) -8- (dimethylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3' -ON,
2- (morpholino) -8- (diethylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3'- on,
2- (piperidino) -8- (diethylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3'- on,
2- (N-methylpiperazino) -8- (diethylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3 '-On,
2- (pyrrolidino) -8- (diethylamino) -4-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3'- on,
2- (diethylamino) -8- (diethylamino) -4-methyl-4 ', 5', 6 ', 7'-tetrachloro-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5 1 '(3'H) -isobenzofuran] -3'-one,
2- (diethylamino) -8- (diethylamino) -spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 ′ (3′H) -isobenzofuran] -3′-one;
2- (di-n-butylamino) -8- (di-n-butylamino) -spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -iso Benzofuran] -3'-one,
2- (N-ethyl-Ni-amylamino) -8- (N-ethyl-Ni-amylamino) -spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '( 3'H) -isobenzofuran] -3'-one,
2- (di-n-butylamino) -8- (diethylamino) -spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3' -ON,
2- (di-n-butylamino) -8- (N-ethyl-Ni-amylamino) -spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H ) -Isobenzofuran] -3'-one,
2- (piperidino) -8- (ethylamino) -4-methyl-7-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran ] -3'-one,
2- (di-n-butylamino) -8- (diethylamino) -4-methyl-7-methyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 ′ (3′H ) -Isobenzofuran] -3'-one,
2- (di-n-butylamino) -8- (diethylamino) -4-methyl-7-ethyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 ′ (3′H ) -Isobenzofuran] -3'-one,
2- (di-n-butylamino) -8- (diethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran ] -3'-one,
2- (di-n-butylamino) -8- (di-n-butylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3' H) -Isobenzofuran] -3'-one,
2- (di-n-butylamino) -8- (N-ethyl-Ni-amylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 ' (3′H) -isobenzofuran] -3′-one,
2- (piperidino) -8- (diethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3'- on,
2- (N-methyl-N-cyclohexylamino) -8- (diethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H)- Isobenzofuran] -3′-one,
2- (dimethylamino) -8- (diethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3' -ON,
2- (i-amylamino) -8- (diethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3 '-On,
2- (pyrrolidino) -8- (diethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3'- on,
2- (N-methylpiperazino) -8- (diethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3 '-On,
2- (morpholino) -8- (diethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3'- on,
2- (N-methyl-N-benzylamino) -8- (diethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H)- Isobenzofuran] -3′-one,
2- [di (2-methoxyethyl) amino] -8- (diethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H)- Isobenzofuran] -3′-one,
2- (di-n-butylamino) -8- (diethylamino) -4- (4-methoxyphenyl) -spiro [5H- [1] benzopyrano (2,3-d) pyrimidine-5,1 ′ (3 ′ H) -Isobenzofuran] -3'-one,
2- (di-n-butylamino) -8- (diethylamino) -4- (4-chlorophenyl) -spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H ) -Isobenzofuran] -3'-one,
2- (di-n-butylamino) -8- (diethylamino) -4- (4-methylphenyl) -spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 ′ (3 ′ H) -Isobenzofuran] -3'-one,
2- [di (2-ethoxyethyl) amino] -8- (dimethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 ′ (3′H) -Isobenzofuran] -3'-one,
2- (diethylamino) -8-[(2-methylphenyl) amino] -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 ′ (3′H) -iso Benzofuran] -3'-one,
2- (2,6-dimethylmorpholino) -8- (diethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran ] -3'-one,
2- (dicyclohexylamino) -8- (dimethylamino) -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -isobenzofuran] -3 '-On,
2- (dibutylamino) -8-[(4-chlorophenyl) amino] -4-phenyl-spiro [5H- [1] benzopyrano (2,3-g) pyrimidine-5,1 '(3'H) -iso Benzofuran] -3'-one,
And the like.
前記(ロ)成分の電子受容性化合物としては、活性プロトンを有する化合物群、偽酸性化合物群(酸ではないが、組成物中で酸として作用して成分(イ)を発色させる化合物群)、電子空孔を有する化合物群等がある。
活性プロトンを有する化合物を例示すると、フェノール性水酸基を有する化合物としては、モノフェノール類からポリフェノール類があり、さらにその置換基としてアルキル基、アリール基、アシル基、アルコキシカルボニル基、カルボキシ基及びそのエステル又はアミド基、ハロゲン基等を有するもの、及びビス型、トリス型フェノール等、フェノール−アルデヒド縮合樹脂等を挙げることができる。又、前記フェノール性水酸基を有する化合物の金属塩であってもよい。
以下に具体例を挙げる。
フェノール、o−クレゾール、ターシャリーブチルカテコール、ノニルフェノール、n−オクチルフェノール、n−ドデシルフェノール、n−ステアリルフェノール、p−クロロフェノール、p−ブロモフェノール、o−フェニルフェノール、p−ヒドロキシ安息香酸n−ブチル、p−ヒドロキシ安息香酸n−オクチル、レゾルシン、没食子酸ドデシル、ビス(4−ヒドロキシフェニル)スルホン、ビス(4−ヒドロキシフェニル)スルフィド、ビス(3−アリル−4−ヒドロキシフェニル)スルホン、4−ヒドロキシフェニル−4−イソプロポキシフェニルスルホン、4−ベンジルオキシフェニル−4−ヒドロキシフェニルスルホン、1,1−ビス(4−ヒドロキシフェニル)エタン、1,1−ビス(4−ヒドロキシフェニル)プロパン、1,1−ビス(4−ヒドロキシフェニル)n−ブタン、1,1−ビス(4−ヒドロキシフェニル)n−ペンタン、1,1−ビス(4−ヒドロキシフェニル)n−ヘキサン、1,1−ビス(4−ヒドロキシフェニル)n−ヘプタン、1,1−ビス(4−ヒドロキシフェニル)n−オクタン、1,1−ビス(4−ヒドロキシフェニル)n−ノナン、1,1−ビス(4−ヒドロキシフェニル)n−デカン、1,1−ビス(4−ヒドロキシフェニル)n−ドデカン、1,1−ビス(4−ヒドロキシフェニル)−2−メチルプロパン、1,1−ビス(4−ヒドロキシフェニル)−3−メチルブタン、1,1−ビス(4−ヒドロキシフェニル)−3−メチルペンタン、1,1−ビス(4−ヒドロキシフェニル)−2,3−ジメチルペンタン、1,1−ビス(4−ヒドロキシフェニル)−2−エチルブタン、1,1−ビス(4−ヒドロキシフェニル)−2−エチルヘキサン、1,1−ビス(4−ヒドロキシフェニル)−3,7−ジメチルオクタン、1,1−ビス(4−ヒドロキシフェニル)シクロヘキサン、1,1−ビス(4−ヒドロキシフェニル)−3,3,5−トリメチルシクロヘキサン、1−フェニル−1,1−ビス(4−ヒドロキシフェニル)エタン、2,2−ビス(4−ヒドロキシフェニル)プロパン、2,2−ビス(4−ヒドロキシフェニル)n−ブタン、2,2−ビス(4−ヒドロキシフェニル)n−ペンタン、2,2−ビス(4−ヒドロキシフェニル)n−ヘキサン、2,2−ビス(4−ヒドロキシフェニル)n−へプタン、2,2−ビス(4−ヒドロキシフェニル)n−オクタン、2,2−ビス(4−ヒドロキシフェニル)n−ノナン、2,2−ビス(4−ヒドロキシフェニル)n−デカン、2,2−ビス(4−ヒドロキシフェニル)n−ドデカン、2,2−ビス(4−ヒドロキシフェニル)エチルプロピオネート、2,2−ビス(4−ヒドロキシフェニル)−4−メチルペンタン、2,2−ビス(4−ヒドロキシフェニル)−4−メチルヘキサン、2,2−ビス(4−ヒドロキシフェニル)ヘキサフルオロプロパン、2,2−ビス(4−ヒドロキシ−3−メチルフェニル)プロパン、9,9−ビス(4−ヒドロキシ−3−メチルフェニル)フルオレン、1,3−ビス[2−(4−ヒドロキシフェニル)−2−プロピル]ベンゼン、ビス(2−ヒドロキシフェニル)メタン、1,1,1−トリス(4−ヒドロキシフェニル)エタン、2,2−ビス(3−メチル−4−ヒドロキシフェニル)ブタン、4−t−ブチル−2´,4´−ジヒドロキシベンゾフェノン等がある。
前記フェノール性水酸基を有する化合物が最も有効な熱変色特性を発現させることができるが、芳香族カルボン酸及び炭素数2〜5の脂肪族カルボン酸、カルボン酸金属塩、酸性リン酸エステル及びそれらの金属塩、1、2、3−トリアゾール及びその誘導体から選ばれる化合物等であってもよい。
As the electron-accepting compound of the component (b), a group of compounds having an active proton, a group of pseudo-acidic compounds (not an acid, but a group of compounds which act as an acid in the composition to form a color of the component (a)), There is a group of compounds having electron vacancies.
As an example of a compound having an active proton, compounds having a phenolic hydroxyl group include monophenols to polyphenols, and further, as a substituent thereof, an alkyl group, an aryl group, an acyl group, an alkoxycarbonyl group, a carboxy group and an ester thereof. Or phenol-aldehyde condensed resins such as bis- and tris-type phenols having an amide group, a halogen group and the like. Further, a metal salt of the compound having a phenolic hydroxyl group may be used.
Specific examples are described below.
Phenol, o-cresol, tert-butylcatechol, nonylphenol, n-octylphenol, n-dodecylphenol, n-stearylphenol, p-chlorophenol, p-bromophenol, o-phenylphenol, n-butyl p-hydroxybenzoate N-octyl p-hydroxybenzoate, resorcinol, dodecyl gallate, bis (4-hydroxyphenyl) sulfone, bis (4-hydroxyphenyl) sulfide, bis (3-allyl-4-hydroxyphenyl) sulfone, 4-hydroxy Phenyl-4-isopropoxyphenylsulfone, 4-benzyloxyphenyl-4-hydroxyphenylsulfone, 1,1-bis (4-hydroxyphenyl) ethane, 1,1-bis (4-hydroxyphenyl) propane, 1,1-bis (4-hydroxyphenyl) n-butane, 1,1-bis (4-hydroxyphenyl) n-pentane, 1,1-bis (4-hydroxyphenyl) n-hexane, 1,1-bis ( 4-hydroxyphenyl) n-heptane, 1,1-bis (4-hydroxyphenyl) n-octane, 1,1-bis (4-hydroxyphenyl) n-nonane, 1,1-bis (4-hydroxyphenyl) n-decane, 1,1-bis (4-hydroxyphenyl) n-dodecane, 1,1-bis (4-hydroxyphenyl) -2-methylpropane, 1,1-bis (4-hydroxyphenyl) -3- Methylbutane, 1,1-bis (4-hydroxyphenyl) -3-methylpentane, 1,1-bis (4-hydroxyphenyl) -2,3-dimethylpentane, 1,1-bis 4-hydroxyphenyl) -2-ethylbutane, 1,1-bis (4-hydroxyphenyl) -2-ethylhexane, 1,1-bis (4-hydroxyphenyl) -3,7-dimethyloctane, 1,1- Bis (4-hydroxyphenyl) cyclohexane, 1,1-bis (4-hydroxyphenyl) -3,3,5-trimethylcyclohexane, 1-phenyl-1,1-bis (4-hydroxyphenyl) ethane, 2,2 -Bis (4-hydroxyphenyl) propane, 2,2-bis (4-hydroxyphenyl) n-butane, 2,2-bis (4-hydroxyphenyl) n-pentane, 2,2-bis (4-hydroxyphenyl) ) N-hexane, 2,2-bis (4-hydroxyphenyl) n-heptane, 2,2-bis (4-hydroxyphenyl) n-octane 2,2-bis (4-hydroxyphenyl) n-nonane, 2,2-bis (4-hydroxyphenyl) n-decane, 2,2-bis (4-hydroxyphenyl) n-dodecane, 2,2- Bis (4-hydroxyphenyl) ethyl propionate, 2,2-bis (4-hydroxyphenyl) -4-methylpentane, 2,2-bis (4-hydroxyphenyl) -4-methylhexane, 2,2- Bis (4-hydroxyphenyl) hexafluoropropane, 2,2-bis (4-hydroxy-3-methylphenyl) propane, 9,9-bis (4-hydroxy-3-methylphenyl) fluorene, 1,3-bis [2- (4-hydroxyphenyl) -2-propyl] benzene, bis (2-hydroxyphenyl) methane, 1,1,1-tris (4-hydroxyphenyl Ethane, 2,2-bis (3-methyl-4-hydroxyphenyl) butane, 4-t-butyl-2', there are 4'-dihydroxybenzophenone, and the like.
The compound having a phenolic hydroxyl group can exhibit the most effective thermochromic properties. However, aromatic carboxylic acids and aliphatic carboxylic acids having 2 to 5 carbon atoms, carboxylic acid metal salts, acidic phosphoric acid esters and the like thereof It may be a compound selected from metal salts, 1,2,3-triazole and derivatives thereof, and the like.
前記(イ)、(ロ)成分による電子授受反応を特定温度域において可逆的に生起させる反応媒体の(ハ)成分について説明する。
前記(ハ)成分としては、アルコール類、エステル類、ケトン類、エーテル類、酸アミド類が挙げられる。
前記化合物を用いてマイクロカプセル化及び二次加工に応用する場合は、低分子量のものは高熱処理を施すとカプセル外に蒸散するので、安定的にカプセル内に保持させるために炭素数10以上の化合物が好適に用いられる。
アルコール類としては、炭素数10以上の脂肪族一価の飽和アルコールが有効であり、具体的にはデシルアルコール、ウンデシルアルコール、ドデシルアルコール、トリデシルアルコール、テトラデシルアルコール、ペンタデシルアルコール、ヘキサデシルアルコール、ヘプタデシルアルコール、オクタデシルアルコール、エイコシルアルコール、ドコシルアルコール等が挙げられる。
The component (c) of the reaction medium that causes the electron transfer reaction by the components (a) and (b) to reversibly occur in a specific temperature range will be described.
Examples of the component (c) include alcohols, esters, ketones, ethers, and acid amides.
When applied to microencapsulation and secondary processing using the compound, since low-molecular-weight ones evaporate outside the capsule when subjected to high heat treatment, they have 10 or more carbon atoms to stably hold in the capsule. Compounds are preferably used.
As the alcohols, aliphatic monovalent saturated alcohols having 10 or more carbon atoms are effective, and specifically, decyl alcohol, undecyl alcohol, dodecyl alcohol, tridecyl alcohol, tetradecyl alcohol, pentadecyl alcohol, hexadecyl alcohol Alcohol, heptadecyl alcohol, octadecyl alcohol, eicosyl alcohol, docosyl alcohol and the like.
エステル類としては、炭素数10以上のエステル類が有効であり、脂肪族及び脂環或いは芳香環を有する一価カルボン酸と、脂肪族及び脂環或いは芳香環を有する一価アルコールの任意の組み合わせから得られるエステル類、脂肪族及び脂環或いは芳香環を有する多価カルボン酸と、脂肪族及び脂環或いは芳香環を有する一価アルコールの任意の組み合わせから得られるエステル類、脂肪族及び脂環或いは芳香環を有する一価カルボン酸と、脂肪族及び脂環或いは芳香環を有する多価アルコールの任意の組み合わせから得られるエステル類が挙げられ、具体的にはカプリル酸エチル、カプリル酸オクチル、カプリル酸ステアリル、カプリン酸ミリスチル、カプリン酸ドコシル、ラウリン酸2−エチルヘキシル、ラウリン酸n−デシル、ミリスチン酸3−メチルブチル、ミリスチン酸セチル、パルミチン酸イソプロピル、パルミチン酸ネオペンチル、パルミチン酸ノニル、パルミチン酸シクロヘキシル、ステアリン酸n−ブチル、ステアリン酸2−メチルブチル、ステアリン酸3,5,5−トリメチルヘキシル、ステアリン酸n−ウンデシル、ステアリン酸ペンタデシル、ステアリン酸ステアリル、ステアリン酸シクロヘキシルメチル、ベヘン酸イソプロピル、ベヘン酸ヘキシル、ベヘン酸ラウリル、ベヘン酸ベヘニル、安息香酸セチル、p−tert−ブチル安息香酸ステアリル、フタル酸ジミリスチル、フタル酸ジステアリル、シュウ酸ジミリスチル、シュウ酸ジセチル、マロン酸ジセチル、コハク酸ジラウリル、グルタル酸ジラウリル、アジピン酸ジウンデシル、アゼライン酸ジラウリル、セバシン酸ジ−(n−ノニル)、1,18−オクタデシルメチレンジカルボン酸ジネオペンチル、エチレングリコールジミリステート、プロピレングリコールジラウレート、プロピレングリコールジステアレート、ヘキシレングリコールジパルミテート、1,5−ペンタンジオールジステアレート、1,2,6−ヘキサントリオールトリミリステート、1,4−シクロヘキサンジオールジデシル、1,4−シクロヘキサンジメタノールジミリステート、キシレングリコールジカプリネート、キシレングリコールジステアレート等が挙げられる。 As the esters, esters having 10 or more carbon atoms are effective, and any combination of a monohydric carboxylic acid having an aliphatic and alicyclic or aromatic ring and a monohydric alcohol having an aliphatic and alicyclic or aromatic ring , Aliphatic and alicyclic esters obtained from any combination of polyhydric carboxylic acids having an aliphatic and alicyclic or aromatic ring and monohydric alcohols having an aliphatic and alicyclic or aromatic ring Alternatively, esters obtained from any combination of a monovalent carboxylic acid having an aromatic ring and a polyhydric alcohol having an aliphatic and alicyclic or aromatic ring are mentioned, and specifically, ethyl caprylate, octyl caprylate, caprylate Stearyl acid, myristyl caprate, docosyl caprate, 2-ethylhexyl laurate, n-decyl laurate, myris 3-methylbutyl phosphate, cetyl myristate, isopropyl palmitate, neopentyl palmitate, nonyl palmitate, cyclohexyl palmitate, n-butyl stearate, 2-methylbutyl stearate, 3,5,5-trimethylhexyl stearate, stearin N-undecyl acid, pentadecyl stearate, stearyl stearate, cyclohexylmethyl stearate, isopropyl behenate, hexyl behenate, lauryl behenate, behenyl behenate, cetyl benzoate, stearyl p-tert-butyl benzoate, dimyristyl phthalate , Distearyl phthalate, dimyristyl oxalate, dicetyl oxalate, dicetyl malonate, dilauryl succinate, dilauryl glutarate, diundecyl adipate, azelaic acid Lauryl, di- (n-nonyl) sebacate, dineopentyl 1,18-octadecylmethylenedicarboxylate, ethylene glycol dimyristate, propylene glycol dilaurate, propylene glycol distearate, hexylene glycol dipalmitate, 1,5-pentane Diol distearate, 1,2,6-hexanetrioltrimyristate, 1,4-cyclohexanedioldidecyl, 1,4-cyclohexanedimethanol dimyristate, xylene glycol dicaprinate, xylene glycol distearate, etc. No.
又、飽和脂肪酸と分枝脂肪族アルコールのエステル、不飽和脂肪酸又は分枝もしくは置換基を有する飽和脂肪酸と分岐状であるか又は炭素数16以上の脂肪族アルコールのエステル、酪酸セチル、酪酸ステアリル及び酪酸ベヘニルから選ばれるエステル化合物も有効である。
具体的には、酪酸2−エチルヘキシル、ベヘン酸2−エチルヘキシル、ミリスチン酸2−エチルヘキシル、カプリン酸2−エチルヘキシル、ラウリン酸3,5,5−トリメチルヘキシル、パルミチン酸3,5,5−トリメチルヘキシル、ステアリン酸3,5,5−トリメチルヘキシル、カプロン酸2−メチルブチル、カプリル酸2−メチルブチル、カプリン酸2−メチルブチル、パルミチン酸1−エチルプロピル、ステアリン酸1−エチルプロピル、ベヘン酸1−エチルプロピル、ラウリン酸1−エチルヘキシル、ミリスチン酸1−エチルヘキシル、パルミチン酸1−エチルヘキシル、カプロン酸2−メチルペンチル、カプリル酸2−メチルペンチル、カプリン酸2−メチルペンチル、ラウリン酸2−メチルペンチル、ステアリン酸2−メチルブチル、ステアリン酸2−メチルブチル、ステアリン酸3−メチルブチル、ステアリン酸1−メチルヘプチル、ベヘン酸2−メチルブチル、ベヘン酸3−メチルブチル、ステアリン酸1−メチルヘプチル、ベヘン酸1−メチルヘプチル、カプロン酸1−エチルペンチル、パルミチン酸1−エチルペンチル、ステアリン酸1−メチルプロピル、ステアリン酸1−メチルオクチル、ステアリン酸1−メチルヘキシル、ラウリン酸1,1−ジメチルプロピル、カプリン酸1−メチルペンチル、パルミチン酸2−メチルヘキシル、ステアリン酸2−メチルヘキシル、ベヘン酸2−メチルヘキシル、ラウリン酸3,7−ジメチルオクチル、ミリスチン酸3,7−ジメチルオクチル、パルミチン酸3,7−ジメチルオクチル、ステアリン酸3,7−ジメチルオクチル、ベヘン酸3,7−ジメチルオクチル、オレイン酸ステアリル、オレイン酸ベヘニル、リノール酸ステアリル、リノール酸ベヘニル、エルカ酸3,7−ジメチルオクチル、エルカ酸ステアリル、エルカ酸イソステアリル、イソステアリン酸セチル、イソステアリン酸ステアリル、12−ヒドロキシステアリン酸2−メチルペンチル、18−ブロモステアリン酸2−エチルヘキシル、2−ケトミリスチン酸イソステアリル、2−フルオロミリスチン酸2−エチルヘキシル、酪酸セチル、酪酸ステアリル、酪酸ベヘニル等が挙げられる。
Further, an ester of a saturated fatty acid and a branched aliphatic alcohol, an unsaturated fatty acid or a saturated or branched fatty acid having a branched or substituted ester of an aliphatic alcohol having 16 or more carbon atoms, cetyl butyrate, stearyl butyrate and Ester compounds selected from behenyl butyrate are also effective.
Specifically, 2-ethylhexyl butyrate, 2-ethylhexyl behenate, 2-ethylhexyl myristate, 2-ethylhexyl caprate, 3,5,5-trimethylhexyl laurate, 3,5,5-trimethylhexyl palmitate, 3,5,5-trimethylhexyl stearate, 2-methylbutyl caproate, 2-methylbutyl caprylate, 2-methylbutyl caprate, 1-ethylpropyl palmitate, 1-ethylpropyl stearate, 1-ethylpropyl behenate, 1-ethylhexyl laurate, 1-ethylhexyl myristate, 1-ethylhexyl palmitate, 2-methylpentyl caproate, 2-methylpentyl caprylate, 2-methylpentyl caprate, 2-methylpentyl laurate, 2-methylstearate Met Butyl, 2-methylbutyl stearate, 3-methylbutyl stearate, 1-methylheptyl stearate, 2-methylbutyl behenate, 3-methylbutyl behenate, 1-methylheptyl stearate, 1-methylheptyl behenate, caproic acid 1 -Ethylpentyl, 1-ethylpentyl palmitate, 1-methylpropyl stearate, 1-methyloctyl stearate, 1-methylhexyl stearate, 1,1-dimethylpropyl laurate, 1-methylpentyl caprate, palmitic acid 2-methylhexyl, 2-methylhexyl stearate, 2-methylhexyl behenate, 3,7-dimethyloctyl laurate, 3,7-dimethyloctyl myristate, 3,7-dimethyloctyl palmitate, 3,3 stearic acid 7-Jim Octyl, 3,7-dimethyloctyl behenate, stearyl oleate, behenyl oleate, stearyl linoleate, behenyl linoleate, 3,7-dimethyloctyl erucate, stearyl erucate, isostearyl erucate, cetyl isostearate, isostearin Stearyl acid, 2-methylpentyl 12-hydroxystearate, 2-ethylhexyl 18-bromostearate, isostearyl 2-ketomyristate, 2-ethylhexyl 2-fluoromyristate, cetyl butyrate, stearyl butyrate, behenyl butyrate, and the like. Can be
更に、色濃度−温度曲線に関して大きなヒステリシス特性を示して変色し、温度変化に依存して色彩記憶性を与えるためには、特公平4−17154号公報に記載された5℃以上50℃未満のΔT値(融点−曇点)を示すカルボン酸エステル化合物、例えば、分子中に置換芳香族環を含むカルボン酸エステル、無置換芳香族環を含むカルボン酸と炭素数10以上の脂肪族アルコールのエステル、分子中にシクロヘキシル基を含むカルボン酸エステル、炭素数6以上の脂肪酸と無置換芳香族アルコール又はフェノールのエステル、炭素数8以上の脂肪酸と分岐脂肪族アルコール又はエステル、ジカルボン酸と芳香族アルコール又は分岐脂肪族アルコールのエステル、ケイ皮酸ジベンジル、ステアリン酸ヘプチル、アジピン酸ジデシル、アジピン酸ジラウリル、アジピン酸ジミリスチル、アジピン酸ジセチル、アジピン酸ジステアリル、トリラウリン、トリミリスチン、トリステアリン、ジミリスチン、ジステアリン等が挙げられる。 Further, in order to exhibit a large hysteresis characteristic with respect to the color density-temperature curve to change the color and to provide a color storage property depending on the temperature change, a temperature of 5 ° C. or more and less than 50 ° C. Carboxylic acid ester compounds exhibiting a ΔT value (melting point−cloud point), for example, a carboxylic acid ester containing a substituted aromatic ring in the molecule, an ester of a carboxylic acid containing an unsubstituted aromatic ring and an aliphatic alcohol having 10 or more carbon atoms A carboxylic acid ester containing a cyclohexyl group in the molecule, an ester of a fatty acid having 6 or more carbon atoms and an unsubstituted aromatic alcohol or phenol, a fatty acid having 8 or more carbon atoms and a branched aliphatic alcohol or ester, a dicarboxylic acid and an aromatic alcohol or Esters of branched aliphatic alcohols, dibenzyl cinnamate, heptyl stearate, didecyl adipate, adipine Dilauryl, dimyristyl adipate, dicetyl adipate, distearyl adipate, trilaurin, trimyristin, tristearin, dimyristin, distearate, and the like.
炭素数9以上の奇数の脂肪族一価アルコールと炭素数が偶数の脂肪族カルボン酸から得られる脂肪酸エステル化合物、n−ペンチルアルコール又はn−ヘプチルアルコールと炭素数10乃至16の偶数の脂肪族カルボン酸より得られる総炭素数17乃至23の脂肪酸エステル化合物も有効である。
具体的には、酢酸n−ペンタデシル、酪酸n−トリデシル、酪酸n−ペンタデシル、カプロン酸n−ウンデシル、カプロン酸n−トリデシル、カプロン酸n−ペンタデシル、カプリル酸n−ノニル、カプリル酸n−ウンデシル、カプリル酸n−トリデシル、カプリル酸n−ペンタデシル、カプリン酸n−ヘプチル、カプリン酸n−ノニル、カプリン酸n−ウンデシル、カプリン酸n−トリデシル、カプリン酸n−ペンタデシル、ラウリン酸n−ペンチル、ラウリン酸n−ヘプチル、ラウリン酸n−ノニル、ラウリン酸n−ウンデシル、ラウリン酸n−トリデシル、ラウリン酸n−ペンタデシル、ミリスチン酸n−ペンチル、ミリスチン酸n−ヘプチル、ミリスチン酸n−ノニル、ミリスチン酸n−ウンデシル、ミリスチン酸n−トリデシル、ミリスチン酸n−ペンタデシル、パルミチン酸n−ペンチル、パルミチン酸n−ヘプチル、パルミチン酸n−ノニル、パルミチン酸n−ウンデシル、パルミチン酸n−トリデシル、パルミチン酸n−ペンタデシル、ステアリン酸n−ノニル、ステアリン酸n−ウンデシル、ステアリン酸n−トリデシル、ステアリン酸n−ペンタデシル、エイコサン酸n−ノニル、エイコサン酸n−ウンデルシ、エイコサン酸n−トリデシル、エイコサン酸n−ペンタデシル、ベヘニン酸n−ノニル、ベヘニン酸n−ウンデシル、ベヘニン酸n−トリデシル、ベヘニン酸n−ペンタデシル等が挙げられる。
A fatty acid ester compound obtained from an odd aliphatic monohydric alcohol having 9 or more carbon atoms and an aliphatic carboxylic acid having an even carbon number, n-pentyl alcohol or n-heptyl alcohol, and an even aliphatic carboxylic acid having 10 to 16 carbon atoms Fatty acid ester compounds having a total of 17 to 23 carbon atoms obtained from acids are also effective.
Specifically, n-pentadecyl acetate, n-tridecyl butyrate, n-pentadecyl butyrate, n-undecyl caproate, n-tridecyl caproate, n-pentadecyl caproate, n-nonyl caprylate, n-undecyl caprylate, N-tridecyl caprylate, n-pentadecyl caprylate, n-heptyl caprate, n-nonyl caprate, n-undecyl caprate, n-tridecyl caprate, n-pentadecyl caprate, n-pentyl laurate, lauric acid n-heptyl, n-nonyl laurate, n-undecyl laurate, n-tridecyl laurate, n-pentadecyl laurate, n-pentyl myristate, n-heptyl myristate, n-nonyl myristate, n-myristate Undecyl, n-tridecyl myristate, N-pentadecyl listinate, n-pentyl palmitate, n-heptyl palmitate, n-nonyl palmitate, n-undecyl palmitate, n-tridecyl palmitate, n-pentadecyl palmitate, n-nonyl stearate, stearic acid n-undecyl, n-tridecyl stearate, n-pentadecyl stearate, n-nonyl eicosanoate, n-undersi eicosanoate, n-tridecyl eicosanoate, n-pentadecyl eicosanoate, n-nonyl behenate, n-behenate Undecyl, n-tridecyl behenate, n-pentadecyl behenate and the like can be mentioned.
ケトン類としては、総炭素数が10以上の脂肪族ケトン類が有効であり、2−デカノン、3−デカノン、4−デカノン、2−ウンデカノン、3−ウンデカノン、4−ウンデカノン、5−ウンデカノン、2−ドデカノン、3−ドデカノン、4−ドデカノン、5−ドデカノン、2−トリデカノン、3−トリデカノン、2−テトラデカノン、2−ペンタデカノン、8−ペンタデカノン、2−ヘキサデカノン、3−ヘキサデカノン、9−ヘプタデカノン、2−ペンタデカノン、2−オクタデカノン、2−ノナデカノン、10−ノナデカノン、2−エイコサノン、11−エイコサノン、2−ヘンエイコサノン、2−ドコサノン、ラウロン、ステアロン等が挙げられる。
更には、総炭素数が12乃至24のアリールアルキルケトン類、例えば、n−オクタデカノフェノン、n−ヘプタデカノフェノン、n−ヘキサデカノフェノン、n−ペンタデカノフェノン、n−テトラデカノフェノン、4−n−ドデカアセトフェノン、n−トリデカノフェノン、4−n−ウンデカノアセトフェノン、n−ラウロフェノン、4−n−デカノアセトフェノン、n−ウンデカノフェノン、4−n−ノニルアセトフェノン、n−デカノフェノン、4−n−オクチルアセトフェノン、n−ノナノフェノン、4−n−ヘプチルアセトフェノン、n−オクタノフェノン、4−n−ヘキシルアセトフェノン、4−n−シクロヘキシルアセトフェノン、4−tert−ブチルプロピオフェノン、n−ヘプタフェノン、4−n−ペンチルアセトフェノン、シクロヘキシルフェニルケトン、ベンジル−n−ブチルケトン、4−n−ブチルアセトフェノン、n−ヘキサノフェノン、4−イソブチルアセトフェノン、1−アセトナフトン、2−アセトナフトン、シクロペンチルフェニルケトン等が挙げられる。
As ketones, aliphatic ketones having a total carbon number of 10 or more are effective, and 2-decanone, 3-decanone, 4-decanone, 2-undecanone, 3-undecanone, 4-undecanone, 5-undecanone, 5-undecanone, -Dodecanone, 3-dodecanone, 4-dodecanone, 5-dodecanone, 2-tridecanone, 3-tridecanone, 2-tetradecanone, 2-pentadecanone, 8-pentadecanone, 2-hexadecanone, 3-hexadecanone, 9-heptadecanone, 2-pentadecanone , 2-octadecanone, 2-nonadecanone, 10-nonadecanone, 2-eicosanone, 11-eicosanone, 2-heneicosanone, 2-docosanone, lauron, stearone, and the like.
Further, arylalkyl ketones having a total carbon number of 12 to 24, for example, n-octadecanophenone, n-heptadecanophenone, n-hexadecanophenone, n-pentadecanophenone, n-tetradecano Nophenone, 4-n-dodecaacetophenone, n-tridecanophenone, 4-n-undecanoacetophenone, n-laurophenone, 4-n-decanoacetophenone, n-undecanophenone, 4-n-nonylacetophenone, n-decanophenone, 4-n-octyl acetophenone, n-nonanophenone, 4-n-heptyl acetophenone, n-octanophenone, 4-n-hexyl acetophenone, 4-n-cyclohexyl acetophenone, 4-tert-butyl propiophenone , N-heptaphenone, 4-n-pentylacetop Non, cyclohexyl phenyl ketone, benzyl -n- butyl ketone, 4-n-butyl acetophenone, n- hexanophenone, 4-isobutyl acetophenone, 1-acetonaphthone, 2-acetonaphthone, cyclopentyl phenyl ketone.
エーテル類としては、総炭素数10以上の脂肪族エーテル類が有効であり、ジペンチルエーテル、ジヘキシルエーテル、ジヘプチルエーテル、ジオクチルエーテル、ジノニルエーテル、ジデシルエーテル、ジウンデシルエーテル、ジドデシルエーテル、ジトリデシルエーテル、ジテトラデシルエーテル、ジペンタデシルエーテル、ジヘキサデシルエーテル、ジオクタデシルエーテル、デカンジオールジメチルエーテル、ウンデカンジオールジメチルエーテル、ドデカンジオールジメチルエーテル、トリデカンジオールジメチルエーテル、デカンジオールジエチルエーテル、ウンデカンジオールジエチルエーテル等が挙げられる。 As the ethers, aliphatic ethers having a total carbon number of 10 or more are effective, and dipentyl ether, dihexyl ether, diheptyl ether, dioctyl ether, dinonyl ether, didecyl ether, diundecyl ether, didodecyl ether, ditriethyl ether Decyl ether, ditetradecyl ether, dipentadecyl ether, dihexadecyl ether, dioctadecyl ether, decanediol dimethyl ether, undecanediol dimethyl ether, dodecanediol dimethyl ether, tridecanediol dimethyl ether, decanediol diethyl ether, undecanediol diethyl ether, etc. No.
酸アミド類としては、アセトアミド、プロピオン酸アミド、酪酸アミド、カプロン酸アミド、カプリル酸アミド、カプリン酸アミド、ラウリン酸アミド、ミリスチン酸アミド、パルミチン酸アミド、ステアリン酸アミド、ベヘニン酸アミド、オレイン酸アミド、エルカ酸アミド、ベンズアミド、カプロン酸アニリド、カプリル酸アニリド、カプリン酸アニリド、ラウリン酸アニリド、ミリスチン酸アニリド、パルミチン酸アニリド、ステアリン酸アニリド、ベヘニン酸アニリド、オレイン酸アニリド、エルカ酸アニリド、カプロン酸N−メチルアミド、カプリル酸N−メチルアミド、カプリン酸N−メチルアミド、ラウリン酸N−メチルアミド、ミリスチン酸N−メチルアミド、パルミチン酸N−メチルアミド、ステアリン酸N−メチルアミド、ベヘニン酸N−メチルアミド、オレイン酸N−メチルアミド、エルカ酸N−メチルアミド、ラウリン酸N−エチルアミド、ミリスチン酸N−エチルアミド、パルミチン酸N−エチルアミド、ステアリン酸N−エチルアミド、オレイン酸N−エチルアミド、ラウリン酸N−ブチルアミド、ミリスチン酸N−ブチルアミド、パルミチン酸N−ブチルアミド、ステアリン酸N−ブチルアミド、オレイン酸N−ブチルアミド、ラウリン酸N−オクチルアミド、ミリスチン酸N−オクチルアミド、パルミチン酸N−オクチルアミド、ステアリン酸N−オクチルアミド、オレイン酸N−オクチルアミド、ラウリン酸N−ドデシルアミド、ミリスチン酸N−ドデシルアミド、パルミチン酸N−ドデシルアミド、ステアリン酸N−ドデシルアミド、オレイン酸N−ドデシルアミド、ジラウリン酸アミド、ジミリスチン酸アミド、ジパルミチン酸アミド、ジステアリン酸アミド、ジオレイン酸アミド、トリラウリン酸アミド、トリミリスチン酸アミド、トリパルミチン酸アミド、トリステアリン酸アミド、トリオレイン酸アミド、コハク酸アミド、アジピン酸アミド、グルタル酸アミド、マロン酸アミド、アゼライン酸アミド、マレイン酸アミド、コハク酸N−メチルアミド、アジピン酸N−メチルアミド、グルタル酸N−メチルアミド、マロン酸N−メチルアミド、アゼライン酸N−メチルアミド、コハク酸N−エチルアミド、アジピン酸N−エチルアミド、グルタル酸N−エチルアミド、マロン酸N−エチルアミド、アゼライン酸N−エチルアミド、コハク酸N−ブチルアミド、アジピン酸N−ブチルアミド、グルタル酸N−ブチルアミド、マロン酸N−ブチルアミド、アジピン酸N−オクチルアミド、アジピン酸N−ドデシルアミド等が挙げられる。 Examples of acid amides include acetamide, propionamide, butyric amide, caproic amide, caprylic amide, capric amide, lauric amide, myristic amide, palmitic amide, stearic amide, behenic amide, and oleic amide. , Erucamide, benzamide, caproic anilide, caprylic anilide, capric anilide, lauric anilide, myristic anilide, palmitic anilide, stearic anilide, behenic anilide, oleic anilide, erucic anilide, caproic acid N -Methylamide, caprylic acid N-methylamide, capric acid N-methylamide, lauric acid N-methylamide, myristic acid N-methylamide, palmitic acid N-methylamide, stearic acid N-methylamide , Behenic acid N-methylamide, oleic acid N-methylamide, erucic acid N-methylamide, lauric acid N-ethylamide, myristic acid N-ethylamide, palmitic acid N-ethylamide, stearic acid N-ethylamide, oleic acid N-ethylamide, laurin Acid N-butylamide, myristic acid N-butylamide, palmitic acid N-butylamide, stearic acid N-butylamide, oleic acid N-butylamide, lauric acid N-octylamide, myristic acid N-octylamide, palmitic acid N-octylamide, N-octylamide stearate, N-octylamide oleate, N-dodecylamide laurate, N-dodecylamide myristic, N-dodecylamide palmitate, N-dodecylamide stearate, Olay Acid N-dodecylamide, dilauric amide, dimyristic amide, dipalmitic amide, distearic amide, dioleic amide, trilauric amide, trimyristic amide, tripalmitic amide, tristearic amide, trioleic acid Amide, succinamide, adipic amide, glutaric amide, malonamide, azelaic amide, maleic amide, succinic N-methylamide, adipic N-methylamide, glutaric N-methylamide, malonic N-methylamide, Azelaic acid N-methylamide, succinic acid N-ethylamide, adipic acid N-ethylamide, glutaric acid N-ethylamide, malonic acid N-ethylamide, azelaic acid N-ethylamide, succinic N-butylamide, adipic acid N- Butylamide, glutaric acid N-butylamide, malonic acid N-butylamide, adipic acid N-octylamide, adipic acid N-dodecylamide and the like can be mentioned.
また、前記(ハ)成分として、下記一般式(1)で示される化合物を用いることもできる。
前記式(1)で示される化合物のうち、R1が水素原子の場合、より広いヒステリシス幅を有する可逆熱変色性組成物が得られるため好適であり、更にR1が水素原子であり、且つ、mが0の場合がより好適である。
なお、式(1)で示される化合物のうち、より好ましくは下記一般式(2)で示される化合物が用いられる。
前記化合物として具体的には、オクタン酸−4−ベンジルオキシフェニルエチル、ノナン酸−4−ベンジルオキシフェニルエチル、デカン酸−4−ベンジルオキシフェニルエチル、ウンデカン酸−4−ベンジルオキシフェニルエチル、ドデカン酸−4−ベンジルオキシフェニルエチル、トリデカン酸−4−ベンジルオキシフェニルエチル、テトラデカン酸−4−ベンジルオキシフェニルエチル、ペンタデカン酸−4−ベンジルオキシフェニルエチル、ヘキサデカン酸−4−ベンジルオキシフェニルエチル、ヘプタデカン酸−4−ベンジルオキシフェニルエチル、オクタデカン酸−4−ベンジルオキシフェニルエチルを例示できる。
Further, as the component (c), a compound represented by the following general formula (1) can also be used.
Among the compounds represented by the formula (1), when R 1 is a hydrogen atom, a reversible thermochromic composition having a wider hysteresis width is preferably obtained, and further, R 1 is a hydrogen atom; , M is more preferably 0.
In addition, among the compounds represented by the formula (1), a compound represented by the following general formula (2) is more preferably used.
Specific examples of the compound include 4-benzyloxyphenylethyl octanoate, 4-benzyloxyphenylethyl nonanoate, 4-benzyloxyphenylethyl decanoate, 4-benzyloxyphenylethyl undecanoate, dodecanoic acid -4-benzyloxyphenylethyl, 4-benzyloxyphenylethyl tridecanoate, 4-benzyloxyphenylethyl tetradecanoate, 4-benzyloxyphenylethyl pentadecanoate, 4-benzyloxyphenylethyl hexadecanoate, heptadecanoic acid Examples thereof include 4-benzyloxyphenylethyl and 4-benzyloxyphenylethyl octadecanoate.
更に、前記(ハ)成分として、下記一般式(3)で示される化合物を用いることもできる。
前記化合物として具体的には、オクタン酸1,1−ジフェニルメチル、ノナン酸1,1−ジフェニルメチル、デカン酸1,1−ジフェニルメチル、ウンデカン酸1,1−ジフェニルメチル、ドデカン酸1,1−ジフェニルメチル、トリデカン酸1,1−ジフェニルメチル、テトラデカン酸1,1−ジフェニルメチル、ペンタデカン酸1,1−ジフェニルメチル、ヘキサデカン酸1,1−ジフェニルメチル、ヘプタデカン酸1,1−ジフェニルメチル、オクタデカン酸1,1−ジフェニルメチルを例示できる。
Further, as the component (c), a compound represented by the following general formula (3) can also be used.
Specific examples of the compound include 1,1-diphenylmethyl octanoate, 1,1-diphenylmethyl nonanoate, 1,1-diphenylmethyl decanoate, 1,1-diphenylmethyl undecanoate, and 1,1-dodecanoate. Diphenylmethyl, 1,1-diphenylmethyl tridecanoate, 1,1-diphenylmethyl tetradecanoate, 1,1-diphenylmethyl pentadecanoate, 1,1-diphenylmethyl hexadecanoate, 1,1-diphenylmethyl heptadecanoate,
更に、前記(ハ)成分として下記一般式(4)で示される化合物を用いることもできる。
前記化合物としては、マロン酸と2−〔4−(4−クロロベンジルオキシ)フェニル)〕エタノールとのジエステル、こはく酸と2−(4−ベンジルオキシフェニル)エタノールとのジエステル、こはく酸と2−〔4−(3−メチルベンジルオキシ)フェニル)〕エタノールとのジエステル、グルタル酸と2−(4−ベンジルオキシフェニル)エタノールとのジエステル、グルタル酸と2−〔4−(4−クロロベンジルオキシ)フェニル)〕エタノールとのジエステル、アジピン酸と2−(4−ベンジルオキシフェニル)エタノールとのジエステル、ピメリン酸と2−(4−ベンジルオキシフェニル)エタノールとのジエステル、スベリン酸と2−(4−ベンジルオキシフェニル)エタノールとのジエステル、スベリン酸と2−〔4−(3−メチルベンジルオキシ)フェニル)〕エタノールとのジエステル、スベリン酸と2−〔4−(4−クロロベンジルオキシ)フェニル)〕エタノールとのジエステル、スベリン酸と2−〔4−(2,4−ジクロロベンジルオキシ)フェニル)〕エタノールとのジエステル、アゼライン酸と2−(4−ベンジルオキシフェニル)エタノールとのジエステル、セバシン酸と2−(4−ベンジルオキシフェニル)エタノールとのジエステル、1,10−デカンジカルボン酸と2−(4−ベンジルオキシフェニル)エタノールとのジエステル、1,18-オクタデカンジカルボン酸と2−(4−ベンジルオキシフェニル)エタノールとのジエステル、1,18-オクタデカンジカルボン酸と2−〔4−(2−メチルベンジルオキシ)フェニル)〕エタノールとのジエステルを例示できる。
Further, a compound represented by the following general formula (4) can be used as the component (c).
Examples of the compound include diesters of malonic acid and 2- [4- (4-chlorobenzyloxy) phenyl)] ethanol, diesters of succinic acid and 2- (4-benzyloxyphenyl) ethanol, and succinic acid and 2- (4-benzyloxyphenyl) ethanol. [4- (3-methylbenzyloxy) phenyl)] diester with ethanol, diester with glutaric acid and 2- (4-benzyloxyphenyl) ethanol, glutaric acid and 2- [4- (4-chlorobenzyloxy) Phenyl)] ethanol, diester of adipic acid and 2- (4-benzyloxyphenyl) ethanol, diester of pimelic acid and 2- (4-benzyloxyphenyl) ethanol, and suberic acid and 2- (4- Diester with benzyloxyphenyl) ethanol, suberic acid with 2- [4- (3-methyl Benzyloxy) phenyl)] diester with ethanol, diester of suberic acid with 2- [4- (4-chlorobenzyloxy) phenyl)] ethanol, suberic acid with 2- [4- (2,4-dichlorobenzyloxy) ) Phenyl)] diester with ethanol, diester of azelaic acid with 2- (4-benzyloxyphenyl) ethanol, diester of sebacic acid with 2- (4-benzyloxyphenyl) ethanol, 1,10-decanedicarboxylic acid Diester of 1,18-octadecanedicarboxylic acid with 2- (4-benzyloxyphenyl) ethanol, 1,18-octadecanedicarboxylic acid with 2- [4- (2-methylbenzyloxy) phenyl)] It can be exemplified ether.
更に、前記(ハ)成分として下記一般式(5)で示される化合物を用いることもできる。
前記化合物としては、1,3−ビス(2−ヒドロキシエトキシ)ベンゼンとカプリン酸とのジエステル、1,3−ビス(2−ヒドロキシエトキシ)ベンゼンとウンデカン酸とのジエステル、1,3−ビス(2−ヒドロキシエトキシ)ベンゼンとラウリン酸とのジエステル、1,3−ビス(2−ヒドロキシエトキシ)ベンゼンとミリスチン酸とのジエステル、1,4−ビス(ヒドロキシメトキシ)ベンゼンと酪酸とのジエステル、1,4−ビス(ヒドロキシメトキシ)ベンゼンとイソ吉草酸とのジエステル、1,4−ビス(2−ヒドロキシエトキシ)ベンゼンと酢酸とのジエステル、1,4−ビス(2−ヒドロキシエトキシ)ベンゼンとプロピオン酸とのジエステル、1,4−ビス(2−ヒドロキシエトキシ)ベンゼンと吉草酸とのジエステル、1,4−ビス(2−ヒドロキシエトキシ)ベンゼンとカプロン酸とのジエステル、1,4−ビス(2−ヒドロキシエトキシ)ベンゼンとカプリル酸とのジエステル、1,4−ビス(2−ヒドロキシエトキシ)ベンゼンとカプリン酸とのジエステル、1,4−ビス(2−ヒドロキシエトキシ)ベンゼンとラウリン酸とのジエステル、1,4−ビス(2−ヒドロキシエトキシ)ベンゼンとミリスチン酸とのジエステルを例示できる。
Further, a compound represented by the following general formula (5) can be used as the component (c).
Examples of the compound include diesters of 1,3-bis (2-hydroxyethoxy) benzene and capric acid, diesters of 1,3-bis (2-hydroxyethoxy) benzene and undecanoic acid, and 1,3-bis (2 Diesters of -hydroxyethoxy) benzene and lauric acid, diesters of 1,3-bis (2-hydroxyethoxy) benzene and myristic acid, diesters of 1,4-bis (hydroxymethoxy) benzene and butyric acid, 1,4 Diesters of bis (hydroxymethoxy) benzene and isovaleric acid, diesters of 1,4-bis (2-hydroxyethoxy) benzene and acetic acid, and diesters of 1,4-bis (2-hydroxyethoxy) benzene and propionic acid Diester, diester of 1,4-bis (2-hydroxyethoxy) benzene and valeric acid Diester of 1,4-bis (2-hydroxyethoxy) benzene and caproic acid, diester of 1,4-bis (2-hydroxyethoxy) benzene and caprylic acid, 1,4-bis (2-hydroxyethoxy) benzene And diesters of capric acid, 1,4-bis (2-hydroxyethoxy) benzene and lauric acid, and diesters of 1,4-bis (2-hydroxyethoxy) benzene and myristic acid.
更に、前記(ハ)成分として下記一般式(6)で示される化合物を用いることもできる。
前記化合物としては、こはく酸と2−フェノキシエタノールとのジエステル、スベリン酸と2−フェノキシエタノールとのジエステル、セバシン酸と2−フェノキシエタノールとのジエステル、1,10-デカンジカルボン酸と2−フェノキシエタノールとのジエステル、1,18-オクタデカンジカルボン酸と2−フェノキシエタノールとのジエステルを例示できる。
Further, a compound represented by the following general formula (6) can be used as the component (c).
As the compound, diesters of succinic acid and 2-phenoxyethanol, diesters of suberic acid and 2-phenoxyethanol, diesters of sebacic acid and 2-phenoxyethanol, diesters of 1,10-decanedicarboxylic acid and 2-phenoxyethanol, A diester of 1,18-octadecanedicarboxylic acid and 2-phenoxyethanol can be exemplified.
更に、前記(ハ)成分として下記一般式(7)で示される化合物を用いることもできる。
前記化合物としては、4−フェニル安息香酸デシル、4−フェニル安息香酸ラウリル、4−フェニル安息香酸ミリスチル、4−フェニル安息香酸シクロヘキシルエチル、4−ビフェニル酢酸オクチル、4−ビフェニル酢酸ノニル、4−ビフェニル酢酸デシル、4−ビフェニル酢酸ラウリル、4−ビフェニル酢酸ミリスチル、4−ビフェニル酢酸トリデシル、4−ビフェニル酢酸ペンタデシル、4−ビフェニル酢酸セチル、4−ビフェニル酢酸シクロペンチル、4−ビフェニル酢酸シクロヘキシルメチル、4−ビフェニル酢酸ヘキシル、4−ビフェニル酢酸シクロヘキシルメチルを例示できる。
Further, a compound represented by the following general formula (7) can be used as the component (c).
Examples of the compound include decyl 4-phenylbenzoate, lauryl 4-phenylbenzoate, myristyl 4-phenylbenzoate, cyclohexylethyl 4-phenylbenzoate, octyl 4-biphenylacetate, nonyl 4-biphenylacetate, and 4-biphenylacetic acid. Decyl, 4-biphenyl acetate lauryl, 4-biphenyl acetate myristyl, 4-biphenyl acetate tridecyl, 4-biphenyl acetate pentadecyl, 4-biphenyl acetate cetyl, 4-biphenyl acetate cyclopentyl, 4-biphenyl acetate cyclohexylmethyl, 4-biphenyl acetate hexyl And cyclohexylmethyl 4-biphenylacetate.
更に、前記(ハ)成分として下記一般式(8)で示される化合物を用いることもできる。
前記化合物としては、4−ブトキシ安息香酸フェノキシエチル、4−ペンチルオキシ安息香酸フェノキシエチル、4−テトラデシルオキシ安息香酸フェノキシエチル、4−ヒドロキシ安息香酸フェノキシエチルとドデカン酸とのエステル、バニリン酸フェノキシエチルのドデシルエーテルを例示できる。
Further, a compound represented by the following general formula (8) can be used as the component (c).
Examples of the compound include phenoxyethyl 4-butoxybenzoate, phenoxyethyl 4-pentyloxybenzoate, phenoxyethyl 4-tetradecyloxybenzoate, esters of phenoxyethyl 4-hydroxybenzoate with dodecanoic acid, and phenoxyethyl vanillate. Can be exemplified.
更に、前記(ハ)成分として下記一般式(9)で示される化合物を用いることもできる。
前記化合物としては、p−ヒドロキシ安息香酸オクチルの安息香酸エステル、p−ヒドロキシ安息香酸デシルの安息香酸エステル、p−ヒドロキシ安息香酸ヘプチルのp−メトキシ安息香酸エステル、p−ヒドロキシ安息香酸ドデシルのo-メトキシ安息香酸エステル、p−ヒドロキシ安息香酸シクロヘキシルメチルの安息香酸エステルを例示できる。
Further, a compound represented by the following general formula (9) can be used as the component (c).
Examples of the compound include benzoic acid ester of octyl p-hydroxybenzoate, benzoic acid ester of decyl p-hydroxybenzoate, p-methoxybenzoic acid ester of heptyl p-hydroxybenzoate, and o- Examples thereof include methoxy benzoate and benzoate of cyclohexylmethyl p-hydroxybenzoate.
更に、前記(ハ)成分として下記一般式(10)で示される化合物を用いることもできる。
前記化合物としては、p−ヒドロキシ安息香酸ノニルのフェノキシエチルエーテル、p−ヒドロキシ安息香酸デシルのフェノキシエチルエーテル、p−ヒドロキシ安息香酸ウンデシルのフェノキシエチルエーテル、バニリン酸ドデシルのフェノキシエチルエーテルを例示できる。
Further, a compound represented by the following general formula (10) can be used as the component (c).
Examples of the compound include phenoxyethyl ether of nonyl p-hydroxybenzoate, phenoxyethyl ether of decyl p-hydroxybenzoate, phenoxyethyl ether of undecyl p-hydroxybenzoate, and phenoxyethyl ether of dodecyl vanillate.
更に、前記(ハ)成分として下記一般式(11)で示される化合物を用いることもできる。
前記化合物としては、1,3−ビス(2−ヒドロキシエトキシ)ベンゼンとシクロヘキサンカルボン酸とのジエステル、1,4−ビス(2−ヒドロキシエトキシ)ベンゼンとシクロヘキサンプロピオン酸とのジエステル、1,3−ビス(2−ヒドロキシエトキシ)ベンゼンとシクロヘキサンプロピオン酸とのジエステルを例示できる。
Further, a compound represented by the following general formula (11) can be used as the component (c).
Examples of the compound include diesters of 1,3-bis (2-hydroxyethoxy) benzene and cyclohexanecarboxylic acid, diesters of 1,4-bis (2-hydroxyethoxy) benzene and cyclohexanepropionic acid, and 1,3-bis A diester of (2-hydroxyethoxy) benzene and cyclohexanepropionic acid can be exemplified.
更に、前記(ハ)成分として下記一般式(12)で示される化合物を用いることもできる。
前記化合物としては、4−フェニルフェノールエチレングリコールエーテルとシクロヘキサンカルボン酸とのジエステル、4−フェニルフェノールジエチレングリコールエーテルとラウリン酸とのジエステル、4−フェニルフェノールトリエチレングリコールエーテルとシクロヘキサンカルボン酸とのジエステル、4−フェニルフェノールエチレングリコールエーテルとオクタン酸とのジエステル、4−フェニルフェノールエチレングリコールエーテルとノナン酸とのジエステル、4−フェニルフェノールエチレングリコールエーテルとデカン酸とのジエステル、4−フェニルフェノールエチレングリコールエーテルとミリスチン酸とのジエステルを例示できる。
Further, a compound represented by the following general formula (12) can be used as the component (c).
Examples of the compound include a diester of 4-phenylphenol ethylene glycol ether and cyclohexanecarboxylic acid, a diester of 4-phenylphenol diethylene glycol ether and lauric acid, a diester of 4-phenylphenol triethylene glycol ether and cyclohexanecarboxylic acid. -Diesters of phenylphenol ethylene glycol ether and octanoic acid, diesters of 4-phenylphenol ethylene glycol ether and nonanoic acid, diesters of 4-phenylphenol ethylene glycol ether and decanoic acid, 4-phenylphenol ethylene glycol ether and myristin Examples include diesters with acids.
前記(ハ)成分のうち、本発明の可逆熱変色性顔料(着色剤A)には、融点が80℃〜130℃の範囲にあるものが適用され、それより融点が低いものは、二種類の変色温度域を呈するインキに併用される可逆熱変色性顔料(着色剤B)に適用される。
前記融点が80℃〜130℃の範囲にある高融点のものは、経時的にも水性インキ媒体中に溶出し難いため、特に安定性に優れるとともに、可逆熱変色性組成物全量中の60〜90質量%、より好ましくは65〜80質量%で適用することで、適量比率の混合物となり、可逆熱変色性顔料が摩擦熱で消色可能な範囲である110℃以下の消色温度を構成でき、更に色濃度も満足できるものとなる。60質量%未満では、低温化が進み、低融点の(ハ)成分を環境温度で消去され難い消色温度75℃以上とすることが困難であり、90質量%を越える量では、高融点の(ハ)成分を消色温度110℃以下とすることが困難であり、更に着色剤として十分な色濃度が得られ難くなる。
Among the components (c), those having a melting point in the range of 80 ° C to 130 ° C are applied to the reversible thermochromic pigment (colorant A) of the present invention, and those having a lower melting point are two types. This is applied to a reversible thermochromic pigment (colorant B) used in combination with an ink exhibiting the above color change temperature range.
The high melting point having a melting point in the range of 80 ° C. to 130 ° C. is hardly eluted in the aqueous ink medium even with the elapse of time, so that it has particularly excellent stability and 60 to 60% of the total amount of the reversible thermochromic composition. By applying at 90% by mass, more preferably at 65 to 80% by mass, the mixture becomes a mixture of an appropriate ratio, and the reversible thermochromic pigment can constitute a decoloring temperature of 110 ° C. or less, which is a range in which the pigment can be decolorized by frictional heat. , And the color density is also satisfactory. If the content is less than 60% by mass, the temperature is lowered, and it is difficult to make the low melting point component (c) a decoloring temperature of 75 ° C. or higher, which is difficult to erase at ambient temperature. It is difficult to make the component (c) have a decoloring temperature of 110 ° C. or lower, and it is difficult to obtain a sufficient color density as a colorant.
前記可逆熱変色性組成物は、前述の(イ)、(ロ)、(ハ)成分を必須成分とする相溶体であり、各成分の割合は、濃度、変色温度、変色形態や各成分の種類に左右されるが、一般的に所望の特性が得られる成分比は、(イ)成分1に対して、(ロ)成分0.1〜100、好ましくは0.1〜50、より好ましくは0.5〜20、(ハ)成分5〜200、好ましくは5〜100、より好ましくは10〜100の範囲である(前記割合はいずれも質量部である)。
The reversible thermochromic composition is a compatibilizer containing the above-mentioned components (a), (b), and (c) as essential components, and the proportion of each component is determined by the concentration, the discoloration temperature, the discoloration form and the content of each component. Although it depends on the type, generally, the component ratio at which desired characteristics can be obtained is (B) component 0.1 to 100, preferably 0.1 to 50, and more preferably (B)
前述の高融点の(ハ)成分を用いて、前記割合で適宜調整することで、可逆熱変色性顔料の消色温度を75℃以上110℃以下とすることが好ましい。
消色温度を前記範囲とすることで、摩擦体を用いた擦過で発生させうる摩擦熱によって筆跡を消色することが可能となるとともに、環境温度における高温状態であっても不用意に筆跡が消色することが抑制される。
It is preferable that the decolorizing temperature of the reversible thermochromic pigment be 75 ° C. or more and 110 ° C. or less by appropriately adjusting the above ratio using the above-mentioned component (c) having a high melting point.
By setting the decoloring temperature to the above range, it is possible to decolor the handwriting by frictional heat that can be generated by rubbing using a friction body, and even in a high temperature state at an environmental temperature, the handwriting is inadvertently generated. Decoloring is suppressed.
更に、各種光安定剤を必要により添加することができる。
前記光安定剤は、(イ)、(ロ)、(ハ)成分からなる可逆熱変色性組成物の光劣化を防止するために含有され、(イ)成分1質量%に対して0.3〜24質量%、好ましくは0.3〜16質量%の割合で含有される。又、前記光安定剤のうち、紫外線吸収剤は、太陽光等に含まれる紫外線を効果的にカットして、(イ)成分の光反応による励起状態によって生ずる光劣化を防止する。又、酸化防止剤、一重項酸素消光剤、スーパーオキシドアニオン消光剤、オゾン消光剤等は光による酸化反応を抑制する。
前記光安定剤は単独で用いてもよいし、2種以上を併用して用いてもよい。
Further, various light stabilizers can be added as required.
The light stabilizer is contained to prevent light deterioration of the reversible thermochromic composition comprising the components (a), (b) and (c), and is contained in an amount of 0.3 to 1% by mass of the component (a). To 24% by mass, preferably 0.3 to 16% by mass. Among the light stabilizers, an ultraviolet absorber effectively blocks ultraviolet light contained in sunlight or the like and prevents light deterioration caused by an excited state due to a photoreaction of the component (a). In addition, antioxidants, singlet oxygen quenchers, superoxide anion quenchers, ozone quenchers, and the like suppress oxidation reactions due to light.
The light stabilizers may be used alone or in combination of two or more.
前記可逆熱変色性組成物は、熱可塑性樹脂や熱硬化性樹脂中に分散したり、或いは、マイクロカプセルに内包することによって可逆熱変色性顔料として用いられる。
尚、マイクロカプセル化は、従来より公知の界面重合法、in Situ重合法、液中硬化被覆法、水溶液からの相分離法、有機溶媒からの相分離法、融解分散冷却法、気中懸濁被覆法、スプレードライング法等があり、用途に応じて適宜選択される。更にマイクロカプセルの表面には、目的に応じて更に二次的な樹脂皮膜を設けて耐久性を付与させたり、表面特性を改質させて実用に供することもできる。
前記マイクロカプセル顔料は、内包物/壁膜=7/1〜1/1(質量比)の範囲であることが好ましく、壁膜の比率が前記範囲内にあることにより、発色時の色濃度及び鮮明性の低下を防止することができ、より好適には、内包物/壁膜=6/1〜1/1(質量比)である。
前記マイクロカプセルに内包させることにより、化学的、物理的に安定な顔料を構成でき、粒子径0.01〜50μm、好ましくは0.1〜30μm、より好ましくは0.5〜20μmの範囲が実用性を満たす。
尚、平均粒子径の測定は、マウンテック社製の画像解析式粒度分布測定ソフトウェア「マックビュー」を用いて粒子の領域を判定し、粒子の領域の面積から投影面積円相当径(Heywood径)を算出し、その値による等体積球相当の粒子の平均粒子径として測定した値である。また、全ての粒子或いは大部分の粒子の粒子径が0.2μmを超える場合には、粒度分布測定装置(ベックマン・コールター株式会社製、製品名:Multisizer 4e)を用いてコールター法により等体積球相当の粒子の平均粒子径として測定することも可能である。
The reversible thermochromic composition is used as a reversible thermochromic pigment by being dispersed in a thermoplastic resin or a thermosetting resin, or by being encapsulated in microcapsules.
The microencapsulation is performed by a conventionally known interfacial polymerization method, in situ polymerization method, in-liquid curing coating method, phase separation method from an aqueous solution, phase separation method from an organic solvent, melting dispersion cooling method, air suspension. There are a coating method, a spray drying method, and the like, which are appropriately selected according to the application. Furthermore, a secondary resin film may be further provided on the surface of the microcapsules according to the purpose to impart durability, or the surface characteristics may be modified for practical use.
The microcapsule pigment preferably includes inclusions / wall film in a range of 7/1 to 1/1 (mass ratio). When the ratio of the wall film is within the above range, the color density and the color density at the time of color development are improved. It is possible to prevent a decrease in sharpness, and it is more preferable that the inclusion / wall film is 6/1 to 1/1 (mass ratio).
By being encapsulated in the microcapsules, a chemically and physically stable pigment can be constituted, and the particle diameter is practically in the range of 0.01 to 50 μm, preferably 0.1 to 30 μm, more preferably 0.5 to 20 μm. Satisfy the nature.
The average particle diameter is measured using the image analysis type particle size distribution measurement software "Macview" manufactured by Mountech Co., Ltd., and the area of the particle is determined from the area of the particle area to obtain a projected area circle equivalent diameter (Heywood diameter). This is a value calculated and measured as the average particle diameter of particles equivalent to an equal volume sphere based on the calculated value. When all or most of the particles have a particle size of more than 0.2 μm, an equal volume sphere is obtained by the Coulter method using a particle size distribution analyzer (manufactured by Beckman Coulter, Inc., product name: Multisizer 4e). It can also be measured as the average particle size of the corresponding particles.
本発明では、前述の高融点(ハ)成分を用いた可逆熱変色性顔料(着色剤A)とともに、消色温度が40℃以上70℃以下である可逆熱変色性顔料を着色剤Bとして併用することにより、着色(1)から着色(2)、更に消色へと加熱温度に応じて多段的な色相変化を発現する筆記具用熱変色性インキ組成物となる。そのため、興趣に富んだ、より商品価値の高い筆記具を構成できる。 In the present invention, a reversible thermochromic pigment having a decoloring temperature of 40 ° C. or more and 70 ° C. or less is used as a colorant B together with the reversible thermochromic pigment (colorant A) using the above-described high melting point (c) component. By doing so, a thermochromic ink composition for a writing instrument that develops a multi-stage hue change depending on the heating temperature from coloring (1) to coloring (2) and further to decoloring is obtained. For this reason, a writing implement that is rich in interest and has a higher commercial value can be configured.
前記可逆熱変色性顔料の変色について説明する。
前記可逆熱変色性顔料は、消色状態からの降温により完全発色温度(t1)に達すると完全に発色状態になり、発色状態からの昇温により完全消色温度(t4)に達すると完全に消色状態になる顔料である。
具体的に、前記可逆熱変色性顔料の色濃度−温度曲線におけるヒステリシス特性は、図2において、縦軸に色濃度、横軸に温度が表されている。温度変化による色濃度の変化は矢印に沿って進行する。ここで、t4は完全に消色した状態に達する温度(以下、完全消色温度と称す)における濃度を示す点であり、t3は消色し始める温度(以下、消色開始温度と称す)における濃度を示す点であり、t2は発色し始める温度(以下、発色開始温度と称す)における濃度を示す点であり、t1は完全に発色した状態に達する温度(以下、完全発色温度と称す)における濃度を示す点である。
また、t1〜t3間の上方直線と、t2〜t4間の下方直線と垂直距離が変色のコントラストを示す尺度であり、t1〜t2間の縦線と、t3〜t4間の縦線との中央値間の距離がヒステリシスの程度を示す温度幅(以下、ヒステリシス幅ΔHと記す)であり、このΔH値が大きい程、変色前後の各状態の保持が容易である。
ここで、t4とt3の差、或いは、t2とt1の差(Δt)が変色の鋭敏性を示す尺度である。
The discoloration of the reversible thermochromic pigment will be described.
When the reversible thermochromic pigment reaches a complete color development temperature (t 1 ) by lowering the temperature from the decolored state, it completely changes to a color developing state, and when the temperature rises from the color developing state, it reaches a complete color erasing temperature (t 4 ). It is a pigment that is completely decolored.
Specifically, the hysteresis characteristics in the color density-temperature curve of the reversible thermochromic pigment are shown in FIG. 2 in which the vertical axis represents color density and the horizontal axis represents temperature. The change in color density due to the temperature change proceeds along the arrow. Here, t 4 is fully reached decolored state temperature (hereinafter, complete decoloring referred to as temperature) and a point showing the density at, t 3 is the temperature begins to decoloring (hereinafter, referred to as decoloring starting temperature ) is a point showing the density at, t 2 begins to color temperature (hereinafter, is a point showing the density at referred to as coloring initiation temperature), t 1 is the temperature to reach completely colored state (hereinafter, complete coloring temperature )).
Further,
Here, the difference between t 4 and t 3 or the difference (Δt) between t 2 and t 1 is a measure of the sharpness of discoloration.
一例として、色相の異なる着色剤A、Bにおける視覚変化を図3の色濃度−温度曲線により具体的に説明する。便宜上、低温消色側着色剤Bを可逆熱変色性顔料B、高温消色側着色剤Aを可逆熱変色性顔料Aと呼ぶ。
一方の可逆熱変色性顔料B(低温消色側着色剤B)の完全消色温度(t4)より高温側に他方の可逆熱変色性顔料A(高温消色側着色剤A)の完全消色温度(t’4)を満たすため〔以下、可逆熱変色性顔料Bと区別するため可逆熱変色性顔料Aは(t’)と記載する〕、可逆熱変色性顔料A、Bが共に発色した着色(1)の状態から昇温していき、完全消色温度(t4)に達すると、可逆熱変色性顔料Bが消色して着色(2)になり、完全消色温度(t’4)に達すると、可逆熱変色性顔料Aが消色するため、着色(2)から消色への色変化が視認される。
降温により完全発色温度(t1=t’1)に達すると、可逆熱変色性顔料A及び可逆熱変色性顔料Bが発色して着色(1)に戻る。
尚、非変色性の着色剤を添加することにより、着色(1)、着色(2)、着色(3)の色変化が視認され、三通りの筆跡が視認できるものとなる。
As an example, a visual change in the colorants A and B having different hues will be specifically described with reference to a color density-temperature curve in FIG. For convenience, the low-temperature decoloring side colorant B is referred to as a reversible thermochromic pigment B, and the high-temperature decoloring side colorant A is referred to as a reversible thermochromic pigment A.
Complete decolorization of the other reversible thermochromic pigment A (high-temperature decoloring side colorant A) to a higher temperature than the complete decoloring temperature (t 4 ) of one reversible thermochromic pigment B (low-temperature decoloring side colorant B). In order to satisfy the color temperature (t ′ 4 ) (hereinafter, the reversible thermochromic pigment A is described as (t ′) to distinguish it from the reversible thermochromic pigment B), both the reversible thermochromic pigments A and B are colored. The temperature is increased from the colored state (1), and when the temperature reaches the complete decoloring temperature (t 4 ), the reversible thermochromic pigment B is decolorized to become colored (2), and the complete decolorizing temperature (t) When ' 4 ) is reached, the reversible thermochromic pigment A decolorizes, so that a color change from coloring (2) to decoloring is visually recognized.
When the temperature reaches a complete color development temperature (t 1 = t ′ 1 ) due to the temperature drop, the reversible thermochromic pigment A and the reversible thermochromic pigment B develop color and return to coloring (1).
By adding a non-color-change coloring agent, the color changes of coloring (1), coloring (2), and coloring (3) are visually recognized, and three types of handwriting can be visually recognized.
また、他の例として図4により具体的に説明すると、一方の可逆熱変色性顔料Bの完全消色温度(t4)より高温側に他方の可逆熱変色性顔料Aの完全消色温度(t’4)を満たすため、可逆熱変色性顔料A、Bが共に発色した着色(1)の状態から昇温していき、完全消色温度(t4)に達すると、可逆熱変色性顔料Bが消色して着色(2)になり、完全消色温度(t’4)に達すると、可逆熱変色性顔料Aが消色するため、着色(2)から消色への色変化が視認される。
尚、降温により完全発色温度(t’1)に達すると、可逆熱変色性顔料Aが発色して着色(2)に戻り、更に降温させて完全発色温度(t1)に達すると、可逆熱変色性顔料Bが発色して着色(1)に戻る。
Further, as another example, referring to FIG. 4 more specifically, the complete decoloring temperature (t 4 ) of one reversible thermochromic pigment B is set higher than the complete decoloring temperature (t 4 ) of the other reversible thermochromic pigment A. In order to satisfy t ' 4 ), the temperature of the reversible thermochromic pigments A and B is increased from the state of coloring (1) in which both of the pigments have developed, and when the temperature reaches the complete decoloring temperature (t 4 ), the reversible thermochromic pigment is When B loses color and becomes colored (2) and reaches the complete decoloring temperature (t ′ 4 ), the reversible thermochromic pigment A loses color. It is visually recognized.
When the temperature reaches the complete color development temperature (t ′ 1 ) due to the temperature decrease, the reversible thermochromic pigment A develops color and returns to coloring (2). When the temperature is further decreased to reach the complete color development temperature (t 1 ), the reversible thermochromic pigment A reaches the complete color development temperature (t 1 ). The discolorable pigment B develops color and returns to coloring (1).
また、他の例として図5により具体的に説明すると、一方の可逆熱変色性顔料Bの完全消色温度(t4)より高温側に他方の可逆熱変色性顔料Aの完全消色温度(t’4)を満たすため、可逆熱変色性顔料A、Bが共に発色した着色(1)の状態から昇温していき、完全消色温度(t4)に達すると、可逆熱変色性顔料Bが消色して着色(2)になり、完全消色温度(t’4)に達すると、可逆熱変色性顔料Aが消色するため、着色(2)から消色への色変化が視認される。
尚、降温により完全発色温度(t’1)に達すると、可逆熱変色性顔料Aが発色して着色(2)に戻り、更に降温させて完全発色温度(t1)に達すると、可逆熱変色性顔料Bが発色して着色(1)に戻る。
Further, as another example, referring to FIG. 5, the complete decolorization temperature (t 4 ) of one reversible thermochromic pigment B is set higher than the complete decolorization temperature (t 4 ) of the other reversible thermochromic pigment A. In order to satisfy t ' 4 ), the temperature of the reversible thermochromic pigments A and B is increased from the state of coloring (1) in which both of the pigments have developed, and when the temperature reaches the complete decoloring temperature (t 4 ), the reversible thermochromic pigment is When B loses color and becomes colored (2) and reaches the complete decoloring temperature (t ′ 4 ), the reversible thermochromic pigment A loses color. It is visually recognized.
When the temperature reaches the complete color development temperature (t ′ 1 ) due to the temperature decrease, the reversible thermochromic pigment A develops color and returns to coloring (2). When the temperature is further decreased to reach the complete color development temperature (t 1 ), the reversible thermochromic pigment A reaches the complete color development temperature (t 1 ). The discolorable pigment B develops color and returns to coloring (1).
更に、他の例として図6により具体的に説明すると、一方の可逆熱変色性顔料Bの完全消色温度(t4)より高温側に他方の可逆熱変色性顔料Aの完全消色温度(t’4)を満たすため、可逆熱変色性顔料A、Bが共に発色した着色(1)の状態から昇温していき、完全消色温度(t4)に達すると、可逆熱変色性顔料Bが消色して着色(2)になり、完全消色温度(t’4)に達すると、可逆熱変色性顔料Aが消色するため、着色(2)から消色への色変化が視認される。
降温により完全発色温度(t1)に達すると、可逆熱変色性顔料Bが発色して着色(3)になり、更に降温させて完全発色温度(t’1)に達すると、可逆熱変色性顔料Aが発色して着色(1)に戻る。
Further, as another example, referring to FIG. 6, the complete decolorization temperature (t 4 ) of one reversible thermochromic pigment B is set higher than the complete decolorization temperature (t 4 ) of the other reversible thermochromic pigment A. In order to satisfy t ' 4 ), the temperature of the reversible thermochromic pigments A and B is increased from the state of coloring (1) in which both of the pigments have developed, and when the temperature reaches the complete decoloring temperature (t 4 ), the reversible thermochromic pigment is When B loses color and becomes colored (2) and reaches the complete decoloring temperature (t ′ 4 ), the reversible thermochromic pigment A loses color. It is visually recognized.
When the temperature reaches the complete color development temperature (t 1 ) due to the temperature drop, the reversible thermochromic pigment B develops a color and becomes colored (3). When the temperature is further lowered to reach the complete color development temperature (t ′ 1 ), the reversible thermochromic pigment B Pigment A develops color and returns to coloring (1).
前記いずれの場合においても、可逆熱変色性顔料B(着色剤B)の完全消色温度(t4)(TA)よりも5℃以上高温側に可逆熱変色性顔料A(着色剤A)の完全消色温度(t’4)(TB)を有することにより、色変化を明瞭に視認でき、好ましくは10℃以上、より好ましくは15℃以上である。
更に、前記可逆熱変色性顔料Bの完全消色温度(t4)よりも5〜70℃高温側に可逆熱変色性顔料Aの完全消色温度(t’4)を有することにより、色変化を発現させ易く、好ましくは10〜60℃、より好ましくは15〜50℃である。
尚、後述する摩擦体によって生じる摩擦熱により変色させる場合は、前記可逆熱変色性顔料Bの完全消色温度(t4)よりも15〜40℃、好ましくは20〜35℃高温側に可逆熱変色性顔料Aの完全消色温度(t’4)を有することにより、摩擦熱で色変化を発現させ易い。
また、前記可逆熱変色性顔料Bの完全消色温度(t4)が50℃以上、好ましくは55℃以上、より好ましくは60℃以上あり、完全発色温度(t1)が0℃以下、好ましくは−5℃以下、より好ましくは−10℃以下であり、可逆熱変色性顔料Aの完全発色温度(t’1)が0℃以下、好ましくは−5℃以下、より好ましくは−10℃以下であることにより、変色した状態を常温下で保持させ易くなる。
In any of the above cases, the reversible thermochromic pigment A (colorant A ) is placed at a temperature higher by 5 ° C. or more than the complete decoloring temperature (t 4 ) (TA) of the reversible thermochromic pigment B (colorant B). Has a complete decoloring temperature (t ′ 4 ) (T B ), the color change can be clearly recognized, and it is preferably 10 ° C. or more, more preferably 15 ° C. or more.
Further, by having the complete decoloring temperature (t ′ 4 ) of the reversible thermochromic pigment A higher by 5 to 70 ° C. than the complete decoloring temperature (t 4 ) of the reversible thermochromic pigment B, Is easy to express, Preferably it is 10-60 degreeC, More preferably, it is 15-50 degreeC.
When the color is changed by frictional heat generated by a friction body described later, the reversible thermochromic pigment B is heated to a temperature higher by 15 to 40 ° C., preferably 20 to 35 ° C. than the complete decoloring temperature (t 4 ). by having a complete decoloring temperature of discoloring pigment a (t '4), which makes it easy to express the color change in friction heat.
Further, the complete color erasing temperature (t 4 ) of the reversible thermochromic pigment B is 50 ° C. or higher, preferably 55 ° C. or higher, more preferably 60 ° C. or higher, and the complete color developing temperature (t 1 ) is 0 ° C. or lower, preferably Is −5 ° C. or lower, more preferably −10 ° C. or lower, and the full color development temperature (t ′ 1 ) of the reversible thermochromic pigment A is 0 ° C. or lower, preferably −5 ° C. or lower, more preferably −10 ° C. or lower. By this, it is easy to maintain the discolored state at normal temperature.
次に、前述の加熱により消色状態となる着色剤を含むインキ組成物について説明する。
前記着色剤は、水及び/又は有機溶剤と必要により各種添加剤を含む筆記具用ビヒクル中に分散してマーキングペン用、ボールペン用、万年筆用、筆ペン用等の筆記具用インキとして利用できる。
前記各種添加剤としては、樹脂、粘度調整剤、分散剤、沈降防止剤、消泡剤、浸透剤、pH調整剤、保湿剤、防かび剤、防腐剤、防錆剤等が挙げられる。
Next, an ink composition containing a colorant that is brought into a decolored state by the above-described heating will be described.
The coloring agent is dispersed in a vehicle for a writing implement containing water and / or an organic solvent and, if necessary, various additives, and can be used as an ink for a writing implement such as a marking pen, a ballpoint pen, a fountain pen, and a brush pen.
Examples of the various additives include a resin, a viscosity adjuster, a dispersant, an antisettling agent, an antifoaming agent, a penetrant, a pH adjuster, a humectant, a fungicide, a preservative, and a rust inhibitor.
そのうち、筆記具用インキに用いられる筆記具用ビヒクルとしては、有機溶剤を含む油性ビヒクル、或いは、水と、必要により有機溶剤を含む水性ビヒクルが挙げられる。
前記有機溶剤としては、エタノール、プロパノール、ブタノール、グリセリン、ソルビトール、トリエタノールアミン、ジエタノールアミン、モノエタノールアミン、エチレングリコール、ジエチレングリコール、チオジエチレングリコール、ポリエチレングリコール、プロピレングリコール、ブチレングリコール、エチレングリコールモノメチルエーテル、エチレングリコールモノエチルエーテル、エチレングリコールモノブチルエーテル、ジエチレングリコールモノメチルエーテル、ジエチレングリコールモノエチルエーテル、ジエチレングリコールモノブチルエーテル、プロピレングリコールモノブチルエーテル、エチレングリコールモノメチルエーテルアセテート、スルフォラン、2−ピロリドン、N−メチル−2−ピロリドン等を挙げることができる。
Among them, examples of the vehicle for writing implement used in the ink for writing implement include an oil-based vehicle containing an organic solvent or an aqueous vehicle containing water and, if necessary, an organic solvent.
Examples of the organic solvent include ethanol, propanol, butanol, glycerin, sorbitol, triethanolamine, diethanolamine, monoethanolamine, ethylene glycol, diethylene glycol, thiodiethylene glycol, polyethylene glycol, propylene glycol, butylene glycol, ethylene glycol monomethyl ether, and ethylene glycol. Monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate, sulfolane, 2-pyrrolidone, N-methyl-2-pyrrolidone, etc. It can gel.
尚、本発明のインキ組成物には、必要により染料や顔料を併用することもできる。
染料は、水性媒体に溶解可能な酸性染料、塩基性染料、直接染料が全て使用可能である。
顔料は、カーボンブラック、群青、二酸化チタン顔料等の無機顔料、アゾ系顔料、フタロシアニン系顔料、インジゴ顔料、チオインジゴ顔料、スレン顔料、キナクリドン系顔料、アントラキノン系顔料、スロン系顔料、ジケトピロロピロール系顔料、ジオキサジン系顔料、ペリレン系顔料、ペリノン系顔料、イソインドリノン系顔料等の有機顔料や蛍光顔料を例示できる。
更に、アルミニウム粉やアルミニウム粉表面を着色樹脂で処理した金属顔料、透明又は着色透明フィルムに金属蒸着膜を形成した金属光沢顔料、蓄光性顔料、芯物質として天然雲母、合成雲母、ガラス片、アルミナ、透明性フィルム片の表面を酸化チタン等の金属酸化物で被覆したパール顔料等を用いることもできる。
The ink composition of the present invention may contain a dye or a pigment, if necessary.
As the dye, acid dyes, basic dyes, and direct dyes that can be dissolved in an aqueous medium can all be used.
Pigments include inorganic pigments such as carbon black, ultramarine blue, and titanium dioxide pigments, azo pigments, phthalocyanine pigments, indigo pigments, thioindigo pigments, threne pigments, quinacridone pigments, anthraquinone pigments, sullon pigments, and diketopyrrolopyrrole pigments. Organic pigments such as pigments, dioxazine pigments, perylene pigments, perinone pigments, and isoindolinone pigments, and fluorescent pigments can be exemplified.
Further, a metal pigment obtained by treating an aluminum powder or a surface of an aluminum powder with a coloring resin, a metallic luster pigment having a metal deposited film formed on a transparent or colored transparent film, a luminous pigment, and a core substance of natural mica, synthetic mica, glass flakes, alumina A pearl pigment or the like in which the surface of a transparent film piece is coated with a metal oxide such as titanium oxide can also be used.
前記筆記具用インキとしては、ビヒクル中に剪断減粘性付与剤を含む剪断減粘性インキ、ビヒクル中に水溶性高分子凝集剤を含み、顔料を緩やかな凝集状態に懸濁させた凝集性インキを挙げることができる。
前記剪断減粘性付与剤を添加することにより、顔料の凝集、沈降を抑制することができると共に、筆跡の滲みを抑制することができるため、良好な筆跡を形成できる。
更に、前記インキを充填する筆記具がボールペン形態の場合、不使用時のボールとチップの間隙からのインキ漏れを防止したり、筆記先端部を上向き(正立状態)で放置した場合のインキの逆流を防止することができる。
前記剪断減粘性付与剤としては、キサンタンガム、ウェランガム、構成単糖がグルコースとガラクトースの有機酸修飾ヘテロ多糖体であるサクシノグリカン(平均分子量約100万乃至800万)、グアーガム、ローカストビーンガム及びその誘導体、ヒドロキシエチルセルロース、アルギン酸アルキルエステル類、メタクリル酸のアルキルエステルを主成分とする分子量10万〜15万の重合体、グルコマンナン、寒天やカラゲニン等の海藻より抽出されるゲル化能を有する増粘多糖類、ベンジリデンソルビトール及びベンジリデンキシリトール又はこれらの誘導体、架橋性アクリル酸重合体、無機質微粒子、ポリグリセリン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリエチレングリコール脂肪酸エステル、ポリオキシエチレンアルキルエーテル、ポリオキシプロピレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、脂肪酸アミド等のHLB値が8〜12のノニオン系界面活性剤、ジアルキル又はジアルケニルスルホコハク酸の塩類。N−アルキル−2−ピロリドンとアニオン系界面活性剤の混合物、ポリビニルアルコールとアクリル系樹脂の混合物を例示できる。
Examples of the writing implement ink include a shear-thinning ink containing a shear-thinning agent in a vehicle, a coagulable ink containing a water-soluble polymer coagulant in a vehicle, and suspending a pigment in a moderately coagulated state. be able to.
By adding the shear-thinning agent, it is possible to suppress aggregation and sedimentation of the pigment and to suppress bleeding of the handwriting, so that a good handwriting can be formed.
Further, when the writing implement to be filled with the ink is a ball-point pen, it is possible to prevent the ink from leaking from the gap between the ball and the tip when not in use, or to reverse the flow of the ink when the writing tip is left upward (upright state). Can be prevented.
Examples of the shear thinning agent include xanthan gum, welan gum, succinoglycan in which the constituent monosaccharide is an organic acid-modified heteropolysaccharide of glucose and galactose (average molecular weight of about 1,000,000 to 8,000,000), guar gum, locust bean gum and the like. Derivatives, hydroxyethylcellulose, alginic acid alkyl esters, polymers having a molecular weight of 100,000 to 150,000 having alkyl ester of methacrylic acid as a main component, glucomannan, thickener having gelling ability extracted from seaweeds such as agar and carrageenin Polysaccharides, benzylidene sorbitol and benzylidene xylitol or derivatives thereof, crosslinkable acrylic acid polymer, inorganic fine particles, polyglycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyethylene glycol fatty acid ester, poly Carboxymethyl ethylene alkyl ethers, polyoxypropylene alkyl ethers, polyoxyethylene alkyl phenyl ether, nonionic HLB value, such as fatty acid amide is 8-12 surfactants, salts of dialkyl or dialkenyl sulfosuccinic acid. Examples thereof include a mixture of N-alkyl-2-pyrrolidone and an anionic surfactant, and a mixture of polyvinyl alcohol and an acrylic resin.
前記水溶性高分子凝集剤としては、ポリビニルピロリドン、ポリエチレンオキサイド、水溶性多糖類等が挙げられる。
前記水溶性多糖類としてはトラガントガム、グアーガム、プルラン、サイクロデキストリン、水溶性セルロース誘導体等が挙げられ、水溶性セルロース誘導体の具体例としてはメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシエチルメチルセルロース、ヒドロキシプロピルメチルセルロース等が挙げられる。
Examples of the water-soluble polymer coagulant include polyvinyl pyrrolidone, polyethylene oxide, water-soluble polysaccharides, and the like.
Examples of the water-soluble polysaccharide include tragacanth gum, guar gum, pullulan, cyclodextrin, a water-soluble cellulose derivative, and the like. Specific examples of the water-soluble cellulose derivative include methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxyethyl methyl cellulose, and hydroxypropyl methyl cellulose. And the like.
前記高分子凝集剤と共に、側鎖にカルボキシル基を有する櫛型高分子分散剤を用いることにより、前記高分子凝集剤による着色剤(可逆熱変色性顔料)のゆるい凝集体の分散性を向上させることができる。
前記側鎖にカルボキシル基を有する櫛型高分子分散剤としては、側鎖に複数のカルボキシル基を有する櫛型高分子化合物であれば特に限定されるものではないが、側鎖に複数のカルボキシル基を有するアクリル高分子化合物が好適であり、前記化合物として日本ルーブリゾール社製の商品名:ソルスパース43000を例示できる。
By using a comb polymer dispersant having a carboxyl group in the side chain together with the polymer flocculant, the dispersibility of a loose aggregate of a colorant (reversible thermochromic pigment) by the polymer flocculant is improved. be able to.
The comb polymer dispersant having a carboxyl group in the side chain is not particularly limited as long as it is a comb polymer compound having a plurality of carboxyl groups in the side chain. Acrylic polymer compound having the following formula is preferable, and examples of the compound include Solsperse 43000 (trade name, manufactured by Lubrizol Japan Ltd.).
更に、有機窒素硫黄化合物を含有させることにより、インキ組成物を筆記具に充填して実用に供する際、振動による着色剤の沈降をいっそう抑制させることができるため、マイクロカプセル形態である可逆熱変色性顔料の使用時に有利である。
これは、可逆熱変色性顔料のゆるい凝集体を側鎖にカルボキシル基を有する櫛型高分子分散剤によって分散させる分散性をより向上させるものである。
前記有機窒素硫黄化合物としては、チアゾール系化合物、イソチアゾール系化合物、ベンゾチアゾール系化合物、ベンゾイソチアゾール系化合物から選ばれる化合物が用いられる。
前記有機窒素硫黄化合物として具体的には、2−(4−チアゾイル)−ベンズイミダゾール(TBZ)、2−(チオシアネートメチルチオ)−1,3−ベンゾチアゾール(TCMTB)、2−メチル−4−イソチアゾリン−3−オン、5−クロロ−2−メチル−4−イソチアゾリン−3−オンから選ばれる一種又は二種以上の化合物が用いられ、好ましくは2−(4−チアゾイル)−ベンズイミダゾール(TBZ)、2−メチル−4−イソチアゾリン−3−オン、5−クロロ−2−メチル−4−イソチアゾリン−3−オンから選ばれる一種又は二種以上の化合物が用いられる。
前記有機窒素硫黄化合物としては、(株)パーマケム・アジア製、商品名:トップサイド88、同133、同170、同220、同288、同300、同400、同500、同600、同700Z、同800、同950、北興産業(株)製、商品名:ホクスターHP、同E50A、ホクサイドP200、同6500、同7400、同MC、同369、同R−150を例示できる。
尚、前記側鎖にカルボキシル基を有する櫛型高分子分散剤と、有機窒素硫黄化合物の質量比率は1:1〜1:10、好ましくは1:1〜1:5であり、前記範囲を満たすことにより、可逆熱変色性顔料のゆるい凝集体の分散性、及び、振動によるマイクロカプセル顔料の沈降抑制を十分に発現させることができる。
Further, by containing an organic nitrogen sulfur compound, when the ink composition is filled in a writing implement and put to practical use, the sedimentation of the colorant due to vibration can be further suppressed, so that the reversible thermochromic property in the form of microcapsules is obtained. This is advantageous when using pigments.
This further improves the dispersibility of dispersing a loose aggregate of the reversible thermochromic pigment with a comb-type polymer dispersant having a carboxyl group in a side chain.
As the organic nitrogen sulfur compound, a compound selected from a thiazole compound, an isothiazole compound, a benzothiazole compound, and a benzoisothiazole compound is used.
Specific examples of the organic nitrogen sulfur compound include 2- (4-thiazoyl) -benzimidazole (TBZ), 2- (thiocyanate methylthio) -1,3-benzothiazole (TCMTB), and 2-methyl-4-isothiazoline- One or more compounds selected from 3-one and 5-chloro-2-methyl-4-isothiazolin-3-one are used, preferably 2- (4-thiazoyl) -benzimidazole (TBZ), One or more compounds selected from -methyl-4-isothiazolin-3-one and 5-chloro-2-methyl-4-isothiazolin-3-one are used.
As the organic nitrogen sulfur compound, manufactured by Permachem Asia Ltd., trade names: Topside 88, 133, 170, 220, 288, 300, 400, 500, 600, 700Z, 800, 950, manufactured by Hokuko Sangyo Co., Ltd., trade names: Hoxter HP, E50A, Hocside P200, 6500, 7400, MC, 369, and R-150.
The mass ratio of the comb-type polymer dispersant having a carboxyl group in the side chain and the organic nitrogen sulfur compound is 1: 1 to 1:10, preferably 1: 1 to 1: 5, and satisfies the above range. Thereby, the dispersibility of the loose aggregate of the reversible thermochromic pigment and the suppression of sedimentation of the microcapsule pigment due to vibration can be sufficiently exhibited.
更に、筆跡の紙面への固着性や粘性を付与するために適用される水溶性樹脂を添加すると、前述の側鎖にカルボキシル基を有する櫛型高分子分散剤と有機窒素硫黄化合物を含むインキ中で前記着色剤の安定性を高める機能がいっそう向上する。
前記水溶性樹脂としては、アルキッド樹脂、アクリル樹脂、スチレンマレイン酸共重合物、セルロース誘導体、ポリビニルピロリドン、ポリビニルアルコール、デキストリン等が挙げられ、好ましくはポリビニルアルコールが用いられる。
更に、前記ポリビニルアルコールは、けん化度が70〜89モル%の部分けん化度型ポリビニルアルコールがインキが酸性域でも可溶性に富むため、より好適に用いられる。
前記水溶性樹脂の添加量としては、インキ中に0.3〜3.0質量%、好ましくは0.5〜1.5質量%の範囲で添加される。
Further, when a water-soluble resin applied for imparting stickiness or viscosity to the paper surface of the handwriting is added, the ink containing the comb-type polymer dispersant having a carboxyl group in the side chain and the organic nitrogen sulfur compound is used. As a result, the function of increasing the stability of the colorant is further improved.
Examples of the water-soluble resin include an alkyd resin, an acrylic resin, a styrene-maleic acid copolymer, a cellulose derivative, polyvinyl pyrrolidone, polyvinyl alcohol, dextrin, and the like. Preferably, polyvinyl alcohol is used.
Further, the polyvinyl alcohol is more preferably used because a partially saponified polyvinyl alcohol having a saponification degree of 70 to 89 mol% is rich in solubility even in an acidic region of the ink.
The water-soluble resin is added in an amount of 0.3 to 3.0% by mass, preferably 0.5 to 1.5% by mass in the ink.
また、前記インキをボールペンに充填して用いる場合は、オレイン酸等の高級脂肪酸、長鎖アルキル基を有するノニオン性界面活性剤、ポリエーテル変性シリコーンオイル、チオ亜燐酸トリ(アルコキシカルボニルメチルエステル)やチオ亜燐酸トリ(アルコキシカルボニルエチルエステル)等のチオ亜燐酸トリエステル、ポリオキシエチレンアルキルエーテル又はポリオキシエチレンアルキルアリールエーテルのリン酸モノエステル、ポリオキシエチレンアルキルエーテル又はポリオキシエチレンアルキルアリールエーテルのリン酸ジエステル、或いは、それらの金属塩、アンモニウム塩、アミン塩、アルカノールアミン塩等の潤滑剤を添加してボール受け座の摩耗を防止することが好ましい。 When the ink is used by filling it into a ballpoint pen, a higher fatty acid such as oleic acid, a nonionic surfactant having a long-chain alkyl group, a polyether-modified silicone oil, thiophosphorous acid tri (alkoxycarbonylmethyl ester), Triesters of thiophosphorous acid such as tri (alkoxycarbonylethyl ester) thiophosphorous acid, phosphoric acid monoesters of polyoxyethylene alkyl ether or polyoxyethylene alkylaryl ether, phosphorus of polyoxyethylene alkyl ether or polyoxyethylene alkylaryl ether It is preferable to add a lubricant such as an acid diester or a metal salt, an ammonium salt, an amine salt or an alkanolamine salt thereof to prevent wear of the ball seat.
その他、必要に応じてアクリル樹脂、スチレンマレイン酸共重合物、セルロース誘導体、ポリビニルピロリドン、ポリビニルアルコール、デキストリン等の樹脂を添加して紙面への固着性や粘性を付与したり、炭酸ナトリウム、燐酸ナトリウム、酢酸ソーダ等の無機塩類、水溶性のアミン化合物等の有機塩基性化合物等のpH調整剤、ベンゾトリアゾール、トリルトリアゾール、ジシクロヘキシルアンモニウムナイトライト、ジイソプロピルアンモニウムナイトライト、サポニン等の防錆剤、石炭酸、1、2−ベンズチアゾリン3−オンのナトリウム塩、安息香酸ナトリウム、デヒドロ酢酸ナトリウム、ソルビン酸カリウム、パラオキシ安息香酸プロピル、2,3,5,6−テトラクロロ−4−(メチルスルフォニル)ピリジン等の防腐剤或いは防黴剤、尿素、ノニオン系界面活性剤、還元又は非還元デンプン加水分解物、トレハロース等のオリゴ糖類、ショ糖、サイクロデキストリン、ぶどう糖、デキストリン、ソルビット、マンニット、ピロリン酸ナトリウム等の湿潤剤、消泡剤、分散剤、インキの浸透性を向上させるフッ素系界面活性剤やノニオン系の界面活性剤を添加してもよい。 In addition, if necessary, a resin such as an acrylic resin, a styrene-maleic acid copolymer, a cellulose derivative, polyvinylpyrrolidone, polyvinyl alcohol, or dextrin is added to impart sticking property or viscosity to paper, or sodium carbonate or sodium phosphate. , An inorganic salt such as sodium acetate, a pH adjuster such as an organic basic compound such as a water-soluble amine compound, a rust inhibitor such as benzotriazole, tolyltriazole, dicyclohexylammonium nitrite, diisopropylammonium nitrite, and saponin; Sodium salt of 1,2-benzthiazolin-3-one, sodium benzoate, sodium dehydroacetate, potassium sorbate, propyl paraoxybenzoate, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine Preservative or Are fungicides, ureas, nonionic surfactants, reduced or non-reduced starch hydrolysates, oligosaccharides such as trehalose, sucrose, cyclodextrin, glucose, dextrin, humectants such as sorbitol, mannitol, sodium pyrophosphate , A defoaming agent, a dispersant, and a fluorine-based surfactant or a nonionic surfactant for improving ink permeability.
前記インキの全質量に対し、好ましくは10〜40質量%、より好ましくは10〜35質量%の可逆熱変色性顔料を含有することができる。顔料の含有量が上記の範囲であることにより、望ましい発色濃度が達成でき、更にインキ流出性の低下を防止することができる。 The ink may contain a reversible thermochromic pigment in an amount of preferably 10 to 40% by mass, more preferably 10 to 35% by mass, based on the total mass of the ink. When the content of the pigment is in the above range, a desired color density can be achieved, and further, a decrease in ink outflow property can be prevented.
特に、前記着色剤Bが、着色剤全量中、70質量%以下とすることが好ましい。
着色剤Bが着色剤全量中70質量%以下、好ましくは60質量%以下であれば、インキ全体での着色剤Aの色濃度を高くすることができ易いため、着色(1)の状態に加え、着色(2)の状態においても明瞭な色相で視認性が高い筆跡が得られる。
In particular, it is preferable that the colorant B is 70% by mass or less based on the total amount of the colorant.
When the content of the colorant B is 70% by mass or less, preferably 60% by mass or less based on the total amount of the colorant, the color density of the colorant A in the entire ink can be easily increased. Even in the state of coloring (2), a handwriting with high visibility can be obtained with a clear hue.
本発明の筆記具用熱変色性インキ組成物は、水と水溶性有機溶剤を含む水性媒体中、又は油性媒体中に、一種又は二種以上の消色性着色剤とともに、必要により各種添加剤を投入、攪拌して調製される。
また、剪断減粘性を有するインキについては、水性媒体中に、二種以上の消色性着色剤、各種添加剤を投入して攪拌、溶解し、更に、これとは別に調製した溶媒中に剪断減粘性付与剤を分散した分散液、或いは、剪断減粘性付与剤を直接投入し、攪拌することにより調製される。
The thermochromic ink composition for writing implements of the present invention, in an aqueous medium containing water and a water-soluble organic solvent, or in an oily medium, together with one or two or more decolorizable colorants, if necessary, various additives. It is prepared by charging and stirring.
For inks having a shear thinning property, two or more decolorizable colorants and various additives are added to an aqueous medium, stirred and dissolved, and further sheared in a solvent separately prepared. It is prepared by directly adding a dispersion in which a viscosity reducing agent is dispersed or a shear thinning agent, and stirring.
前記インキを収容する筆記具について説明する。
ボールペンに充填する場合、ボールペン自体の構造、形状は特に限定されるものではなく、例えば、軸筒内に剪断減粘性インキを充填したインキ収容管を有し、該インキ収容管はボールを先端部に装着したボールペンチップに連通しており、さらにインキの端面には逆流防止用の液栓が密接しているボールペンを例示できる。
前記ボールペンチップについて更に詳しく説明すると、金属製のパイプの先端近傍を外面より内方に押圧変形させたボール抱持部にボールを抱持してなるチップ、或いは、金属材料をドリル等による切削加工により形成したボール抱持部にボールを抱持してなるチップ、金属又はプラスチック製チップ内部に樹脂製のボール受け座を設けたチップ、或いは、前記チップに抱持するボールをバネ体により前方に付勢させたもの等を適用できる。
又、前記ボールは、超硬合金、ステンレス鋼、ルビー、セラミック、樹脂、ゴム等の0.3〜2.0mm、好ましくは0.3〜1.5mm、より好ましくは0.3〜1.0mm径程度のものが適用できる。
前記インキを収容するインキ収容管は、例えば、ポリエチレン、ポリプロピレン、ポリエチレンテレフタレート、ナイロン等の熱可塑性樹脂からなる成形体、金属製管状体が用いられる。
前記インキ収容管にはチップを直接連結する他、接続部材を介して前記インキ収容管とチップを連結してもよい。
尚、前記インキ収容管はレフィルの形態として、前記レフィルを樹脂製、金属製等の軸筒内に収容するものでもよいし、先端部にチップを装着した軸筒自体をインキ収容体として、前記軸筒内に直接インキを充填してもよい。
また、前記インキ組成物を出没式のボールペンに収容する場合、出没式ボールペンの構造、形状は特に限定されるものではなく、ボールペンレフィルに設けられた筆記先端部が外気に晒された状態で軸筒内に収納されており、出没機構の作動によって軸筒開口部から筆記先端部が突出する構造であれば全て用いることができる。
出没機構の操作方法としては、例えば、ノック式、回転式、スライド式等が挙げられる。
前記ノック式は、軸筒後端部や軸筒側面にノック部を有し、該ノック部の押圧により、ボールペンチップを軸筒前端開口部から出没させる構成、或いは、軸筒に設けたクリップ部を押圧することにより、ボールペンチップを軸筒前端開口部から出没させる構成を例示できる。
前記回転式は、軸筒後部に回転部を有し、該回転部を回すことによりボールペンチップを軸筒前端開口部から出没させる構成を例示できる。
前記スライド式は、軸筒側面にスライド部を有し、該スライドを操作することによりボールペンチップを軸筒前端開口部から出没させる構成、或いは、軸筒に設けたクリップ部をスライドさせることにより、ボールペンチップを軸筒前端開口部から出没させる構成を例示できる。
前記出没式ボールペンは軸筒内に複数のボールペンレフィルを収容してなり、出没機構の作動によっていずれかのボールペンレフィルの筆記先端部が軸筒前端開口部から出没する複合タイプの出没式ボールペンであってもよい。
A writing instrument for storing the ink will be described.
When filling the ball-point pen, the structure and shape of the ball-point pen itself are not particularly limited. For example, the ball-point pen has an ink storage tube filled with shear-thinning ink in a shaft cylinder, and the ink storage tube has A ball-point pen which communicates with a ball-point pen tip mounted on the ink-jet head and further has a liquid stopper for preventing backflow close to the end face of the ink can be exemplified.
The ballpoint pen tip will be described in more detail. A tip formed by holding a ball in a ball holding portion formed by pressing and deforming the vicinity of the tip of a metal pipe inward from an outer surface, or cutting a metal material by a drill or the like A chip formed by holding a ball in a ball holding portion formed by the above, a chip provided with a resin ball receiving seat inside a metal or plastic chip, or a ball held by the chip is moved forward by a spring body. Energized ones can be applied.
Further, the ball is made of cemented carbide, stainless steel, ruby, ceramic, resin, rubber, or the like, having a thickness of 0.3 to 2.0 mm, preferably 0.3 to 1.5 mm, more preferably 0.3 to 1.0 mm. Those having a diameter of about the same can be applied.
As the ink storage tube for storing the ink, for example, a molded body made of a thermoplastic resin such as polyethylene, polypropylene, polyethylene terephthalate, or nylon, or a metal tubular body is used.
In addition to directly connecting the chip to the ink storage tube, the ink storage tube and the chip may be connected via a connecting member.
The ink storage tube may be a form of a refill, and the refill may be housed in a shaft cylinder made of resin, metal, or the like, or the shaft cylinder itself having a tip mounted on a tip may be used as an ink container. The shaft cylinder may be directly filled with ink.
When the ink composition is stored in a retractable ball-point pen, the structure and shape of the retractable ball-point pen are not particularly limited, and the writing tip provided on the ball-point pen refill is shafted in a state where it is exposed to the outside air. Any structure can be used as long as it is housed in a cylinder and the writing tip protrudes from the opening of the shaft cylinder by the operation of the retracting mechanism.
As a method of operating the retracting mechanism, for example, a knock type, a rotary type, a slide type, and the like can be given.
The knock type has a knock portion at a rear end portion or a side surface of the shaft tube, and a configuration in which a ballpoint pen tip is protruded and retracted from a front end opening portion of the shaft tube by pressing the knock portion, or a clip portion provided on the shaft tube. , The ball-point pen tip is made to protrude and retract from the front end opening of the barrel.
The rotary type has a configuration in which a rotating portion is provided at a rear portion of the barrel, and the ball-point pen tip is made to protrude and retract from a front end opening of the barrel by rotating the rotating portion.
The slide type has a slide portion on the side of the barrel, and a configuration in which the ballpoint pen tip is made to protrude and retract from the front end opening of the barrel by operating the slide, or by sliding a clip portion provided on the barrel, A configuration in which the ballpoint pen tip is made to protrude and retract from the front end opening of the barrel can be exemplified.
The retractable ballpoint pen is a composite type retractable ballpoint pen in which a plurality of ballpoint pen refills are accommodated in a barrel, and a writing tip of one of the ballpoint pen refills protrudes and retracts from a front end opening of the barrel by operating a retracting mechanism. You may.
前記インキ収容管に収容したインキの後端にはインキ逆流防止体が充填される。
前記インキ逆流防止体組成物は不揮発性液体又は難揮発性液体からなる。
具体的には、ワセリン、スピンドル油、ヒマシ油、オリーブ油、精製鉱油、流動パラフィン、ポリブテン、α−オレフィン、α−オレフィンのオリゴマーまたはコオリゴマー、ジメチルシリコーンオイル、メチルフェニルシリコーンオイル、アミノ変性シリコーンオイル、ポリエーテル変性シリコーンオイル、脂肪酸変性シリコーンオイル等があげられ、一種又は二種以上を併用することもできる。
前記不揮発性液体及び/又は難揮発性液体は、増粘剤を添加して好適な粘度まで増粘させることが好ましく、前記増粘剤としては表面を疎水処理したシリカ、表面をメチル化処理した微粒子シリカ、珪酸アルミニウム、膨潤性雲母、疎水処理を施したベントナイトやモンモリロナイトなどの粘土系増粘剤、ステアリン酸マグネシウム、ステアリン酸カルシウム、ステアリン酸アルミニウム、ステアリン酸亜鉛等の脂肪酸金属石鹸、トリベンジリデンソルビトール、脂肪酸アマイド、アマイド変性ポリエチレンワックス、水添ひまし油、脂肪酸デキストリン等のデキストリン系化合物、セルロース系化合物等を挙げることができる。
更に、前記液状のインキ逆流防止体と、固体のインキ逆流防止体を併用することもできる。
The back end of the ink stored in the ink storage tube is filled with an ink backflow preventer.
The ink backflow preventive composition comprises a non-volatile liquid or a hardly volatile liquid.
Specifically, petrolatum, spindle oil, castor oil, olive oil, refined mineral oil, liquid paraffin, polybutene, α-olefin, α-olefin oligomer or cooligomer, dimethyl silicone oil, methylphenyl silicone oil, amino-modified silicone oil, Examples thereof include polyether-modified silicone oil and fatty acid-modified silicone oil, and one or two or more of them can be used in combination.
The non-volatile liquid and / or the non-volatile liquid are preferably thickened by adding a thickener to a suitable viscosity. As the thickener, silica whose surface is subjected to hydrophobic treatment, and whose surface is subjected to methylation treatment are used. Fine particle silica, aluminum silicate, swelling mica, clay-based thickeners such as bentonite and montmorillonite subjected to hydrophobic treatment, fatty acid metal soaps such as magnesium stearate, calcium stearate, aluminum stearate, zinc stearate, tribenzylidene sorbitol, Examples thereof include fatty acid amides, amide-modified polyethylene wax, hydrogenated castor oil, dextrin compounds such as fatty acid dextrin, and cellulose compounds.
Further, the liquid ink backflow preventive and the solid ink backflow preventive may be used in combination.
マーキングペンに充填する場合、マーキングペン自体の構造、形状は特に限定されるものではなく、例えば、軸筒内に繊維集束体からなるインキ吸蔵体を内蔵し、毛細間隙が形成された繊維加工体からなるマーキングペンチップを直接或いは中継部材を介して軸筒に装着してなり、前記インキ吸蔵体とチップが連結されてなるマーキングペンの前記インキ吸蔵体に凝集性インキを含浸させたマーキングペンや、チップの押圧により開放する弁体を介してチップとインキ収容管とを配置し、該インキ収容管内にインキを直接収容させたマーキングペン等を例示できる。
前記チップは、繊維の樹脂加工体、熱溶融性繊維の融着加工体、フェルト体等の従来より汎用の気孔率が概ね30〜70%の範囲から選ばれる連通気孔の多孔質部材であり、一端を砲弾形状、長方形状、チゼル形状等の目的に応じた形状に加工して実用に供される。
前記インキ吸蔵体は、捲縮状繊維を長手方向に集束させたものであり、プラスチック筒体やフィルム等の被覆体に内在させて、気孔率が概ね40〜90%の範囲に調整して構成される。
また、前記弁体は、従来より汎用のポンピング式形態が使用できるが、筆圧により押圧開放可能なバネ圧に設定したものが好適である。
When filling the marking pen, the structure and shape of the marking pen itself is not particularly limited, for example, a fiber processed body in which an ink occluding body composed of a fiber bundle is built in a shaft cylinder and a capillary gap is formed A marking pen made by mounting a marking pen chip directly or via a relay member on a shaft cylinder, wherein the ink occluding body is impregnated with cohesive ink in the ink occluding body of the marking pen in which the ink occluding body and the chip are connected. For example, a marking pen or the like in which a chip and an ink storage tube are arranged via a valve body that is opened by pressing the chip and ink is directly stored in the ink storage tube can be exemplified.
The chip is a porous member having interconnected pores whose conventional porosity is generally selected from a range of 30 to 70%, such as a resin processed body of a fiber, a fusion processed body of a heat-fusible fiber, and a felt body, One end is processed into a shape suitable for the purpose, such as a shell shape, a rectangular shape, a chisel shape, or the like, and is provided for practical use.
The ink occluding body is formed by bundling crimped fibers in a longitudinal direction, and is provided inside a covering such as a plastic cylinder or a film, and is adjusted to have a porosity in a range of approximately 40 to 90%. Is done.
The valve body may be of a general-purpose pumping type, but is preferably set to a spring pressure which can be pressed and released by writing pressure.
更に、前記ボールペンやマーキングペンの形態は前述したものに限らず、相異なる形態のチップを装着させたり、相異なる色のインキを導出させるペン先を装着させた両頭式筆記具であってもよい。 Further, the form of the ball-point pen and the marking pen is not limited to those described above, and may be a double-headed writing instrument on which a tip of a different form is mounted or a pen point for leading out ink of a different color is mounted.
尚、前記筆記具用インキ組成物を収容した筆記具を用いて被筆記面に筆記して得られる筆跡は、冷却具や加熱具により変色させることができる。
前記冷却具としては、ペルチエ素子を利用した冷熱変色具、冷水、氷片等の冷媒を充填した冷熱変色具、冷蔵庫や冷凍庫の適用が挙げられる。
前記加熱具としては、抵抗発熱体を装備した通電加熱変色具、温水等を充填した加熱変色具、ヘアドライヤーの適用が挙げられるが、好ましくは、簡便な方法により変色可能な手段として摩擦部材が用いられる。
In addition, the handwriting obtained by writing on a writing surface using the writing implement containing the ink composition for a writing implement can be discolored by a cooling tool or a heating tool.
Examples of the cooling device include a cooling and discoloring device using a Peltier element, a cooling and discoloring device filled with a coolant such as cold water and ice chips, a refrigerator and a freezer.
Examples of the heating tool include a heating color changing tool equipped with a resistance heating element, a heating color changing tool filled with hot water, and the like, and a hair dryer. Used.
前記摩擦部材としては、弾性感に富み、擦過時に適度な摩擦を生じて摩擦熱を発生させることのできるエラストマー、プラスチック発泡体等の弾性体が好適である。
尚、消しゴムを使用して筆跡を摩擦することもできるが、摩擦時に消しカスが発生するため、消しカスが殆ど発生しない前述の摩擦部材が好適に用いられる。
前記摩擦部材の材質としては、シリコーン樹脂やSEBS樹脂(スチレンエチレンブタジエンスチレンブロック共重合体)、ポリエステル系樹脂等が用いられる。
前記摩擦部材は筆記具と別体の任意形状の部材(摩擦体)とを組み合わせて筆記具セットを得ることもできるが、筆記具に摩擦部材を設けることにより、携帯性に優れる。
キャップを備える筆記具の場合、摩擦部材を設ける箇所は特に限定されるものではないが、例えば、キャップ自体を摩擦部材により形成したり、軸筒自体を摩擦部材により形成したり、クリップを設ける場合はクリップ自体を摩擦部材により形成したり、キャップ先端部(頂部)或いは軸筒後端部(筆記先端部を設けていない部分)に摩擦部材を設けることができる。
出没式の筆記具の場合、摩擦部材を設ける箇所は特に限定されるものではないが、例えば、軸筒自体を摩擦部材により形成したり、クリップを設ける場合はクリップ自体を摩擦部材により形成したり、軸筒開口部近傍、軸筒後端部(筆記先端部を設けていない部分)或いはノック部に摩擦部材を設けることができる。
As the friction member, an elastic body such as an elastomer or a plastic foam which is rich in elasticity and can generate appropriate friction when rubbing to generate frictional heat is suitable.
Note that the handwriting can be rubbed by using an eraser, but eraser scum is generated at the time of friction. Therefore, the above-described friction member which hardly generates eraser scum is preferably used.
As the material of the friction member, silicone resin, SEBS resin (styrene-ethylene-butadiene-styrene block copolymer), polyester-based resin, or the like is used.
As the friction member, a writing instrument set can be obtained by combining a writing instrument and a member having an arbitrary shape (friction body) separately. However, by providing the friction element in the writing instrument, portability is excellent.
In the case of a writing instrument provided with a cap, the place where the friction member is provided is not particularly limited.For example, when the cap itself is formed by a friction member, the barrel is formed by a friction member, or a clip is provided. The clip itself can be formed by a friction member, or a friction member can be provided at the tip (top) of the cap or at the rear end of the barrel (portion where the writing tip is not provided).
In the case of a retractable writing instrument, the location where the friction member is provided is not particularly limited.For example, when the shaft cylinder itself is formed by a friction member, or when a clip is provided, the clip itself is formed by a friction member, A friction member can be provided in the vicinity of the opening of the barrel, at the rear end of the barrel (where the writing tip is not provided), or at the knocking part.
尚、前記摩擦部材は、二種類以上設けることも可能である。その場合、紙面との摩擦により、一方が筆跡変色温度であるTBからTAの範囲の摩擦熱を発し、他方が筆跡消色温度であるTA以上の摩擦熱を発するものとすることが好ましい。そうすることで、筆跡摩擦時の力加減を気にすることなく、各摩擦部材に応じて所望の変色段階を容易且つ確実に発現できるものとなる。 Incidentally, two or more kinds of the friction members may be provided. In that case, due to friction with the paper surface, that one emits a frictional heat in the range of T B is a handwriting discoloration temperature T A, the other is assumed to emit T A more frictional heat is handwriting decoloring temperature preferable. By doing so, a desired discoloration step can be easily and reliably developed according to each friction member without worrying about the force applied during handwriting friction.
以下に実施例を記載する。尚、実施例中の部は質量部であり、平均粒子径は粒度分布測定装置(ベックマン・コールター株式会社製、製品名:Multisizer 4e)を用いてコールター法により等体積球相当の粒子を測定した値である。
また、融点はメトラー・トレド社製、FP81HTで測定した値である。
Examples will be described below. The parts in the examples are parts by mass, and the average particle diameter was measured by a Coulter method using a particle size distribution analyzer (manufactured by Beckman Coulter, product name: Multisizer 4e) by the Coulter method. Value.
The melting point is a value measured by FP81HT manufactured by METTLER TOLEDO.
実施例1
可逆熱変色性顔料の調製
(イ)成分として2,6−ビス(2,4−ジエチルオキシフェニル)−4−(4−ビス(4−メチルフェニル)アミノフェニル)ピリジン1部、(ロ)成分として2,2−ビス(4′−ヒドロキシフェニル)ヘキサフルオロプロパン5部、(ハ)成分としてステアリン酸2−(4−ベンジルオキシフェニル)エチル〔融点82℃〕50部からなる可逆熱変色性組成物をマイクロカプセルに内包して可逆熱変色性顔料を調製した。
前記可逆熱変色性顔料は、平均粒子径2.0μm、完全消色温度(t’4)80℃、完全発色温度(t’1)42℃であり、温度変化により橙色から無色に変色する。
Example 1
Preparation of reversible thermochromic pigment (1) 2,6-bis (2,4-diethyloxyphenyl) -4- (4-bis (4-methylphenyl) aminophenyl) pyridine as component (a), component (b) Reversible thermochromic composition comprising 5 parts of 2,2-bis (4'-hydroxyphenyl) hexafluoropropane as a component and 50 parts of 2- (4-benzyloxyphenyl) ethyl stearate [melting point 82 ° C.] as a component (c) The product was encapsulated in microcapsules to prepare a reversible thermochromic pigment.
The reversible thermochromic pigment has an average particle size of 2.0 μm, a complete color erasing temperature (t ′ 4 ) of 80 ° C., and a complete color developing temperature (t ′ 1 ) of 42 ° C., and changes color from orange to colorless with a change in temperature.
筆記具用熱変色性インキ組成物の調製(図2参照)
前記可逆熱変色性顔料20部、キサンタンガム(剪断減粘性付与剤)0.33部、尿素10部、グリセリン10部、ノニオン系浸透性付与剤〔サンノプコ(株)製、商品名:ノプコSW−WET−366〕0.55部、変性シリコーン系消泡剤〔サンノプコ(株)製、商品名:ノプコ8034〕0.13部、防黴剤〔ゼネカ(株)製、商品名:プロキセルXL−2〕0.13部、水58.86部からなる、温度変化により橙色から無色と変色する筆記具用熱変色性インキ組成物を調製した。
Preparation of thermochromic ink composition for writing implement (see Fig. 2)
20 parts of the reversible thermochromic pigment, 0.33 part of xanthan gum (shear-thinning agent), 10 parts of urea, 10 parts of glycerin, nonionic penetrating agent [San Nopco Co., Ltd., trade name: Nopco SW-WET] -366] 0.55 part, modified silicone antifoaming agent [manufactured by San Nopco Co., Ltd., trade name: Nopco 8034] 0.13 part, fungicide [Zeneca Co., Ltd., trade name: Proxel XL-2] A thermochromic ink composition for writing implements, consisting of 0.13 part and 58.86 parts of water, which changes color from orange to colorless with a change in temperature was prepared.
ボールペンの作成
前記インキ組成物をポリプロピレン製パイプに吸引充填し、樹脂製ホルダーを介して0.5mmステンレス鋼ボールを先端に抱持したボールペンチップと連結させた後、前記パイプの後方より、ポリブテンを主成分とする粘弾性を有するインキ逆流防止体(液栓)を充填し、更に尾栓をパイプ後端に嵌合させ、遠心処理による脱気を行うことでボールペンレフィルを得た。
次いで、前記ボールペンレフィルを先軸胴と後軸胴からなる軸胴内に組み付け、キャップを嵌合することで熱変色性ボールペンを得た。尚、前記後軸胴の後端部には、SEBS樹脂製の摩擦部材が装着される。
Preparation of Ballpoint Pen The ink composition was suction-filled into a polypropylene pipe, and connected to a ballpoint pen tip holding a 0.5 mm stainless steel ball at the tip via a resin holder. A ballpoint pen refill was obtained by filling a viscoelastic ink backflow preventer (liquid tap) having a main component, further fitting a tail plug at the rear end of the pipe, and performing deaeration by centrifugation.
Next, the ballpoint pen refill was assembled in a shaft barrel composed of a front barrel and a rear barrel, and a cap was fitted to obtain a thermochromic ballpoint pen. A friction member made of SEBS resin is attached to the rear end of the rear barrel.
筆跡の変色挙動
前記ボールペンにより筆記して得られる筆跡は、室温下(25℃)では橙色の筆跡が視認され、加温して80℃になると可逆熱変色性顔料が消色(t’4)して無色になる。
この状態から冷却して42℃になると顔料が完全に発色(t’1)して鮮やかな橙色の筆跡が視認された。
Discoloration Behavior of Handwriting In the handwriting obtained by writing with the ballpoint pen, an orange handwriting is visually recognized at room temperature (25 ° C.), and when heated to 80 ° C., the reversible thermochromic pigment is decolorized (t ′ 4 ). It becomes colorless.
When the temperature was cooled to 42 ° C. from this state, the pigment was completely colored (t ′ 1 ) and a bright orange handwriting was visually recognized.
実施例2〜3、比較例1〜4
前記実施例1の筆記具用熱変色性インキ組成物において、可逆熱変色性顔料を変更した以外は同様にして筆記具用熱変色性インキ組成物を作製し、熱変色性ボールペンを得た。得られた実施例のインキはいずれも変色不良を生じることなく、長期的に変色特性を保持していた。
各実施例及び比較例の顔料組成と各インキの濃度保持性試験及び筆跡消去試験の結果について以下の表に示す。
A thermochromic ink composition for a writing instrument was prepared in the same manner as in the thermochromic ink composition for a writing instrument of Example 1 except that the reversible thermochromic pigment was changed to obtain a thermochromic ballpoint pen. All of the obtained inks of Examples had no discoloration defect and retained the discoloration characteristics for a long period of time.
The following table shows the pigment compositions of the examples and comparative examples, and the results of the density retention test and handwriting erasure test of each ink.
表1に示した高温保持試験と筆跡消去試験の評価については以下の通り。
高温保持試験
JIS P3201白色筆記用紙A上に連続した丸を筆記した後、用紙を70℃の環境下に1時間放置した。その後、室温にて筆跡の状態を目視により確認した。
各記号は以下の通りである。
◎:筆記時と同等の鮮やかな筆跡が視認される。
×:筆跡が消えてしまい視認できない。
The evaluations of the high-temperature holding test and the handwriting erasure test shown in Table 1 are as follows.
High-Temperature Retention Test After writing a continuous circle on JIS P3201 white writing paper A, the paper was left in an environment of 70 ° C. for 1 hour. Thereafter, the state of the handwriting was visually checked at room temperature.
Each symbol is as follows.
:: Vivid handwriting equivalent to that at the time of writing is visually recognized.
×: Handwriting disappeared and could not be visually recognized.
筆跡消去試験
JIS P3201白色筆記用紙A上に連続した丸を筆記した後、付属の摩擦体で加熱した際の各筆跡を目視で確認した。
各記号は以下の通りである。
◎:容易に消去できた。
○:時間を要するが消去できた。
△:筆跡は薄くなったがきれいに消去できなかった。
×:消去できず、筆跡が残った。
Handwriting erasure test After writing continuous circles on JIS P3201 white writing paper A, each handwriting when heated with an attached friction body was visually observed.
Each symbol is as follows.
A: Erasable easily.
:: Elimination was possible although it took time.
Δ: Handwriting was thin but could not be erased cleanly.
×: Handwriting remained without erasing.
実施例4
可逆熱変色性顔料Aの調製
(イ)成分として2,6−ビス(2,4−ジエチルオキシフェニル)−4−(4−ビス(4−メチルフェニル)アミノフェニル)ピリジン2部、(ロ)成分として2,2−ビス(4′−ヒドロキシフェニル)ヘキサフルオロプロパン5部、(ハ)成分としてステアリン酸2−(4−ベンジルオキシフェニル)エチル〔融点82℃〕50部からなる可逆熱変色性組成物aをマイクロカプセルに内包して可逆熱変色性顔料Aを調製した。
前記可逆熱変色性顔料Aは、平均粒子径2.0μm、完全消色温度(t’4)80℃、完全発色温度(t’1)42℃であり、温度変化により橙色から無色に変色する。
Example 4
Preparation of reversible thermochromic pigment A (2) 2,6-bis (2,4-diethyloxyphenyl) -4- (4-bis (4-methylphenyl) aminophenyl) pyridine as component (b) Reversible thermochromic comprising 5 parts of 2,2-bis (4'-hydroxyphenyl) hexafluoropropane as a component and 50 parts of 2- (4-benzyloxyphenyl) ethyl stearate [melting point 82 ° C.] as a component (c). The composition a was encapsulated in microcapsules to prepare a reversible thermochromic pigment A.
The reversible thermochromic pigment A has an average particle diameter of 2.0 μm, a complete color erasing temperature (t ′ 4 ) of 80 ° C., and a complete color developing temperature (t ′ 1 ) of 42 ° C., and changes color from orange to colorless due to a temperature change. .
可逆熱変色性顔料Bの調製
(イ)成分として9−エチル(3−メチルブチル)アミノ−スピロ[12H−ベンゾ(a)キサンテン−12,1′(3′H)イソベンゾフラン]−3′−オン2部、(ロ)成分として2,2−ビス(4′−ヒドロキシフェニル)ヘキサフルオロプロパン5部、(ハ)成分としてカプリン酸4−ベンジルオキシフェニルエチル〔融点64℃〕50部からなる可逆熱変色性組成物bをマイクロカプセルに内包することで可逆熱変色性顔料Bを調製した。
前記可逆熱変色性顔料Bは、平均粒子径2.0μm、完全消色温度(t4)64℃、完全発色温度(t1)−14℃であり、温度変化によりピンク色から無色に変色する。
Preparation of reversible thermochromic pigment B 9-ethyl (3-methylbutyl) amino-spiro [12H-benzo (a) xanthene-12,1 '(3'H) isobenzofuran] -3'-one as component (a) Reversible heat consisting of 2 parts, 5 parts of 2,2-bis (4'-hydroxyphenyl) hexafluoropropane as component (b), and 50 parts of 4-benzyloxyphenylethyl caprate [melting point 64 ° C.] as component (c) The reversible thermochromic pigment B was prepared by encapsulating the discolorable composition b in microcapsules.
The reversible thermochromic pigment B has an average particle size of 2.0 μm, a complete erasing temperature (t 4 ) of 64 ° C., and a complete coloring temperature (t 1 ) of −14 ° C., and changes color from pink to colorless due to a temperature change. .
筆記具用熱変色性インキ組成物の調製(図4参照)
前記可逆熱変色性顔料A10部、可逆熱変色性顔料B10部、キサンタンガム(剪断減粘性付与剤)0.33部、尿素10部、グリセリン10部、ノニオン系浸透性付与剤〔サンノプコ(株)製、商品名:ノプコSW−WET−366〕0.55部、変性シリコーン系消泡剤〔サンノプコ(株)製、商品名:ノプコ8034〕0.13部、防黴剤〔ゼネカ(株)製、商品名:プロキセルXL−2〕0.13部、水58.86部からなる、温度変化により朱色から橙色、さらには橙色から無色と二段変色する筆記具用熱変色性インキ組成物を調製した。
Preparation of thermochromic ink composition for writing implement (see FIG. 4)
10 parts of the reversible thermochromic pigment A, 10 parts of the reversible thermochromic pigment B, 0.33 part of xanthan gum (shear-thinning agent), 10 parts of urea, 10 parts of glycerin, nonionic penetrating agent [manufactured by San Nopco Co., Ltd.] (Trade name: Nopco SW-WET-366) 0.55 parts, modified silicone antifoaming agent (manufactured by San Nopco Co., Ltd., trade name: Nopco 8034) 0.13 parts, fungicide (Zeneca Co., Ltd.) Trade name: Proxel XL-2] A thermochromic ink composition for writing implements, consisting of 0.13 parts and 58.86 parts of water, was prepared which changes color from vermilion to orange, and further from orange to colorless in two steps according to temperature change.
ボールペンの作成
前記インキ組成物をポリプロピレン製パイプに吸引充填し、樹脂製ホルダーを介して0.5mmステンレス鋼ボールを先端に抱持したボールペンチップと連結させた後、前記パイプの後方より、ポリブテンを主成分とする粘弾性を有するインキ逆流防止体(液栓)を充填し、更に尾栓をパイプ後端に嵌合させ、遠心処理による脱気を行うことでボールペンレフィルを得た。
次いで、前記ボールペンレフィルを先軸胴と後軸胴からなる軸胴内に組み付け、キャップを嵌合することで熱変色性ボールペンを得た。尚、前記後軸胴の後端部には、SEBS樹脂製の摩擦部材が装着される。
Preparation of Ballpoint Pen The ink composition was suction-filled into a polypropylene pipe, and connected to a ballpoint pen tip holding a 0.5 mm stainless steel ball at the tip via a resin holder. A ballpoint pen refill was obtained by filling a viscoelastic ink backflow preventer (liquid tap) having a main component, further fitting a tail plug at the rear end of the pipe, and performing deaeration by centrifugation.
Next, the ballpoint pen refill was assembled in a shaft barrel composed of a front barrel and a rear barrel, and a cap was fitted to obtain a thermochromic ballpoint pen. A friction member made of SEBS resin is attached to the rear end of the rear barrel.
筆跡の変色挙動
前記ボールペンにより筆記して得られる筆跡は、室温下(25℃)では顔料Aと顔料Bが混色となった鮮やかな朱色を呈しており、キャップに装着した摩擦体を用いて摩擦すると、64℃になると顔料Bが消色(t4)して顔料Aによる鮮やかな橙色の筆跡が視認され、さらに加温して80℃になると顔料Aが消色(t’4)して無色になる。
前記鮮やかな朱色と、鮮やかな橙色と、無色に可逆的に変色する状態変化は、加温により順次、適正に視認判別でき、段階的な色変化のバリエーションに富むものであった。
Discoloration behavior of handwriting The handwriting obtained by writing with the ballpoint pen has a bright vermilion color in which pigment A and pigment B are mixed at room temperature (25 ° C.), and is rubbed using a friction body attached to a cap. Then, at 64 ° C., the pigment B is decolorized (t 4 ), and a bright orange handwriting by the pigment A is visually recognized. When the temperature is further raised to 80 ° C., the pigment A is decolorized (t ′ 4 ). It becomes colorless.
The vivid vermilion, vivid orange, and colorless reversibly changing state were sequentially and appropriately visually discriminated by heating, and were rich in stepwise color change variations.
実施例5〜6
前記実施例4の前記筆記具用熱変色性インキ組成物において、可逆熱変色性顔料A(顔料A)と可逆熱変色性顔料B(顔料B)を変更した以外は同様にして筆記具用熱変色性インキ組成物を作製し、熱変色性ボールペンを得た。得られたインキはいずれも変色不良を生じることなく、長期的に変色特性を保持していた。
また、紙面上に形成した筆跡を、前記摩擦部材で擦過したところ、擦過部分が他の部分とのコントラストに優れた明瞭な色相に色変化を生じた。更に擦過を続けると、擦過部分はきれいに消去することができた。
各実施例の顔料組成について以下の表に示す。
In the thermochromic ink composition for writing implements of Example 4, the thermochromic properties for writing implements were changed in the same manner except that the reversible thermochromic pigment A (pigment A) and the reversible thermochromic pigment B (pigment B) were changed. An ink composition was prepared to obtain a thermochromic ballpoint pen. All of the obtained inks maintained the discoloration characteristics for a long time without causing discoloration failure.
Further, when the handwriting formed on the paper surface was rubbed with the friction member, the rubbed portion changed color to a clear hue excellent in contrast with other portions. When the rubbing was further continued, the rubbed portion could be erased cleanly.
The following table shows the pigment composition of each example.
t1、t’1 完全発色温度
t2、t’2 発色開始温度
t3、t’3 消色開始温度
t4、t’4 完全消色温度
t 1 , t ′ 1 complete color development temperature t 2 , t ′ 2 color development start temperature t 3 , t ′ 3 decolorization start temperature t 4 , t ′ 4 complete decoloration temperature
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Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004149726A (en) * | 2002-10-31 | 2004-05-27 | Pilot Ink Co Ltd | Polychromatic and color-changing water-based ink composition for writing utensil and ballpoint pen using the composition |
JP2005213361A (en) * | 2004-01-29 | 2005-08-11 | Pilot Ink Co Ltd | Ink composition for thermochromic color-memory writing utensil |
JP2008126562A (en) * | 2006-11-22 | 2008-06-05 | Pilot Ink Co Ltd | Heat-sensitive multi-color discoloration stationery |
JP2008273075A (en) * | 2007-04-30 | 2008-11-13 | Pilot Ink Co Ltd | Thermal discoloring writing utensil |
JP2008290259A (en) * | 2007-05-22 | 2008-12-04 | Pilot Ink Co Ltd | Multi-color ball-point pen |
JP2009066845A (en) * | 2007-09-12 | 2009-04-02 | Pilot Ink Co Ltd | Writing implement or refill for writing implement |
WO2009060972A1 (en) * | 2007-11-09 | 2009-05-14 | Sakura Color Products Corporation | Discolorable ink composition and writing utensils |
JP2010132822A (en) * | 2008-12-05 | 2010-06-17 | Matsui Shikiso Chem Co Ltd | Reversible thermochromic hysteresis composition |
JP2016011397A (en) * | 2014-06-30 | 2016-01-21 | 株式会社パイロットコーポレーション | Ink composition for reversible thermochromic stamp, and stamp containing the ink composition |
JP2016083779A (en) * | 2014-10-22 | 2016-05-19 | 三菱鉛筆株式会社 | Heat discoloration writing instrument and friction member |
JP2016107521A (en) * | 2014-12-08 | 2016-06-20 | 株式会社パイロットコーポレーション | Thermochromic writing utensil and thermochromic writing utensil set |
-
2018
- 2018-06-29 JP JP2018123783A patent/JP7101548B2/en active Active
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004149726A (en) * | 2002-10-31 | 2004-05-27 | Pilot Ink Co Ltd | Polychromatic and color-changing water-based ink composition for writing utensil and ballpoint pen using the composition |
JP2005213361A (en) * | 2004-01-29 | 2005-08-11 | Pilot Ink Co Ltd | Ink composition for thermochromic color-memory writing utensil |
JP2008126562A (en) * | 2006-11-22 | 2008-06-05 | Pilot Ink Co Ltd | Heat-sensitive multi-color discoloration stationery |
JP2008273075A (en) * | 2007-04-30 | 2008-11-13 | Pilot Ink Co Ltd | Thermal discoloring writing utensil |
JP2008290259A (en) * | 2007-05-22 | 2008-12-04 | Pilot Ink Co Ltd | Multi-color ball-point pen |
JP2009066845A (en) * | 2007-09-12 | 2009-04-02 | Pilot Ink Co Ltd | Writing implement or refill for writing implement |
WO2009060972A1 (en) * | 2007-11-09 | 2009-05-14 | Sakura Color Products Corporation | Discolorable ink composition and writing utensils |
JP2010132822A (en) * | 2008-12-05 | 2010-06-17 | Matsui Shikiso Chem Co Ltd | Reversible thermochromic hysteresis composition |
JP2016011397A (en) * | 2014-06-30 | 2016-01-21 | 株式会社パイロットコーポレーション | Ink composition for reversible thermochromic stamp, and stamp containing the ink composition |
JP2016083779A (en) * | 2014-10-22 | 2016-05-19 | 三菱鉛筆株式会社 | Heat discoloration writing instrument and friction member |
JP2016107521A (en) * | 2014-12-08 | 2016-06-20 | 株式会社パイロットコーポレーション | Thermochromic writing utensil and thermochromic writing utensil set |
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