JP2019536883A5 - - Google Patents
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- Publication number
- JP2019536883A5 JP2019536883A5 JP2019539740A JP2019539740A JP2019536883A5 JP 2019536883 A5 JP2019536883 A5 JP 2019536883A5 JP 2019539740 A JP2019539740 A JP 2019539740A JP 2019539740 A JP2019539740 A JP 2019539740A JP 2019536883 A5 JP2019536883 A5 JP 2019536883A5
- Authority
- JP
- Japan
- Prior art keywords
- alkali metal
- mixture
- sulfur
- salt
- sulfide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims description 85
- 239000000203 mixture Substances 0.000 claims description 50
- 239000007788 liquid Substances 0.000 claims description 36
- 229910052783 alkali metal Inorganic materials 0.000 claims description 35
- 229930195733 hydrocarbon Natural products 0.000 claims description 30
- 150000002430 hydrocarbons Chemical class 0.000 claims description 27
- 150000001340 alkali metals Chemical class 0.000 claims description 25
- 239000004215 Carbon black (E152) Substances 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 21
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 20
- 229910052717 sulfur Inorganic materials 0.000 claims description 14
- 239000011593 sulfur Substances 0.000 claims description 14
- -1 alkali metal hydrosulfide Chemical class 0.000 claims description 13
- 229910052977 alkali metal sulfide Inorganic materials 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 4
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 150000003464 sulfur compounds Chemical class 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 2
- 238000005119 centrifugation Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000002244 precipitate Substances 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 238000004062 sedimentation Methods 0.000 claims 1
- 239000002006 petroleum coke Substances 0.000 description 9
- 239000000446 fuel Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 3
- 239000010763 heavy fuel oil Substances 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 239000010761 intermediate fuel oil Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662404119P | 2016-10-04 | 2016-10-04 | |
| US62/404,119 | 2016-10-04 | ||
| US15/446,299 | 2017-03-01 | ||
| US15/446,299 US20170253816A1 (en) | 2016-03-03 | 2017-03-01 | Method for recovering alkali metal from hydrocarbon feedstocks treated with alkali metal |
| US201762513871P | 2017-06-01 | 2017-06-01 | |
| US62/513,871 | 2017-06-01 | ||
| PCT/US2017/055213 WO2018067753A1 (en) | 2016-10-04 | 2017-10-04 | Process for separating particles containing alkali metal salts from liquid hydrocarbons |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019536883A JP2019536883A (ja) | 2019-12-19 |
| JP2019536883A5 true JP2019536883A5 (enExample) | 2020-11-12 |
| JP6817656B2 JP6817656B2 (ja) | 2021-01-20 |
Family
ID=61831294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019539740A Active JP6817656B2 (ja) | 2016-10-04 | 2017-10-04 | 液体炭化水素からアルカリ金属塩を含む粒子を分離するための方法 |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP3523396B1 (enExample) |
| JP (1) | JP6817656B2 (enExample) |
| KR (1) | KR102211995B1 (enExample) |
| CN (1) | CN109890944B (enExample) |
| CA (1) | CA3039380C (enExample) |
| ES (1) | ES2836679T3 (enExample) |
| SG (1) | SG11201902990UA (enExample) |
| WO (1) | WO2018067753A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20230012008A (ko) * | 2020-05-19 | 2023-01-25 | 인라이튼 이노베이션즈 인크. | 아스팔텐 함유 공급원료의 정제 및 전환 방법 |
| KR20230012007A (ko) * | 2020-05-19 | 2023-01-25 | 인라이튼 이노베이션즈 인크. | 하류 오일 전환의 성능을 개선하기 위한 방법 |
| TW202216971A (zh) * | 2020-10-19 | 2022-05-01 | 大陸商中國石油化工科技開發有限公司 | 一種生產燃料油的方法和系統及其應用以及燃料油及其應用 |
| WO2023042175A1 (en) * | 2021-09-17 | 2023-03-23 | Enlighten Innovations Inc. | Compositions and methods for making carbon fibers from asphaltenes |
| CN119799355B (zh) * | 2025-01-08 | 2026-07-24 | 中南大学 | 一种石油焦电化学脱硫方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1300816A (en) * | 1915-09-11 | 1919-04-15 | Standard Oil Co | Process of desulfurizing petroleum-oils. |
| US3791966A (en) * | 1972-05-24 | 1974-02-12 | Exxon Research Engineering Co | Alkali metal desulfurization process for petroleum oil stocks |
| US3849297A (en) * | 1972-06-08 | 1974-11-19 | Exxon Research Engineering Co | Process for removing metals from petroleum residua |
| US3904511A (en) * | 1973-10-05 | 1975-09-09 | Mobil Oil Corp | Process for eliminating unstable hydrogen from lubricating oil stock |
| US6210564B1 (en) * | 1996-06-04 | 2001-04-03 | Exxon Research And Engineering Company | Process for desulfurization of petroleum feeds utilizing sodium metal |
| US8088270B2 (en) | 2007-11-27 | 2012-01-03 | Ceramatec, Inc. | Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides |
| US9475998B2 (en) | 2008-10-09 | 2016-10-25 | Ceramatec, Inc. | Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides |
| US9688920B2 (en) * | 2009-11-02 | 2017-06-27 | Field Upgrading Limited | Process to separate alkali metal salts from alkali metal reacted hydrocarbons |
| CN104818047A (zh) | 2009-11-02 | 2015-08-05 | 塞拉麦泰克股份有限公司 | 用碱金属和烃对石油原料的提质 |
| US20160053185A1 (en) | 2009-11-02 | 2016-02-25 | Field Upgrading Limited | Process to separate alkali metal salts from alkali metal reacted hydrocarbons |
| DE102011013470A1 (de) * | 2010-07-26 | 2012-01-26 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren und Mittel zur Entfernung von Metallen aus hochsiedenden Kohlenwasserstofffraktionen |
| ES2650952T3 (es) * | 2012-02-03 | 2018-01-23 | Field Upgrading Limited | Proceso para desulfurar materias primas de petróleo |
| MY173980A (en) * | 2013-04-15 | 2020-03-02 | Enlighten Innovations Inc | Process to separate alkali metal salts from alkali metal reacted hydrocarbons |
-
2017
- 2017-10-04 JP JP2019539740A patent/JP6817656B2/ja active Active
- 2017-10-04 WO PCT/US2017/055213 patent/WO2018067753A1/en not_active Ceased
- 2017-10-04 KR KR1020197012851A patent/KR102211995B1/ko active Active
- 2017-10-04 CN CN201780067716.5A patent/CN109890944B/zh active Active
- 2017-10-04 SG SG11201902990UA patent/SG11201902990UA/en unknown
- 2017-10-04 EP EP17784812.4A patent/EP3523396B1/en active Active
- 2017-10-04 CA CA3039380A patent/CA3039380C/en active Active
- 2017-10-04 ES ES17784812T patent/ES2836679T3/es active Active
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