JP2019516135A - 四元モリブデン/タングステンテルル酸塩結晶の使用及びデバイス - Google Patents
四元モリブデン/タングステンテルル酸塩結晶の使用及びデバイス Download PDFInfo
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- JP2019516135A JP2019516135A JP2018554737A JP2018554737A JP2019516135A JP 2019516135 A JP2019516135 A JP 2019516135A JP 2018554737 A JP2018554737 A JP 2018554737A JP 2018554737 A JP2018554737 A JP 2018554737A JP 2019516135 A JP2019516135 A JP 2019516135A
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- 239000013078 crystal Substances 0.000 title claims abstract description 115
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 229910052750 molybdenum Inorganic materials 0.000 title claims abstract description 21
- 239000011733 molybdenum Substances 0.000 title claims abstract description 21
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 229910052721 tungsten Inorganic materials 0.000 title claims abstract description 20
- 239000010937 tungsten Substances 0.000 title claims abstract description 20
- SITVSCPRJNYAGV-UHFFFAOYSA-L tellurite Chemical compound [O-][Te]([O-])=O SITVSCPRJNYAGV-UHFFFAOYSA-L 0.000 title claims abstract description 11
- 239000000382 optic material Substances 0.000 claims abstract description 8
- 229910052714 tellurium Inorganic materials 0.000 claims abstract description 6
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims abstract description 5
- XHGGEBRKUWZHEK-UHFFFAOYSA-L tellurate Chemical compound [O-][Te]([O-])(=O)=O XHGGEBRKUWZHEK-UHFFFAOYSA-L 0.000 claims description 3
- 230000005540 biological transmission Effects 0.000 abstract description 17
- 230000005284 excitation Effects 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 20
- 230000003287 optical effect Effects 0.000 description 15
- 238000002834 transmittance Methods 0.000 description 13
- 229910052790 beryllium Inorganic materials 0.000 description 8
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 4
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 3
- 229910013641 LiNbO 3 Inorganic materials 0.000 description 2
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- 238000013461 design Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
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- 235000003270 potassium fluoride Nutrition 0.000 description 2
- 239000011698 potassium fluoride Substances 0.000 description 2
- 230000001902 propagating effect Effects 0.000 description 2
- -1 rare earth ion Chemical class 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000010897 surface acoustic wave method Methods 0.000 description 2
- 231100000701 toxic element Toxicity 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000003667 anti-reflective effect Effects 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
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- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- NKTZYSOLHFIEMF-UHFFFAOYSA-N dioxido(dioxo)tungsten;lead(2+) Chemical class [Pb+2].[O-][W]([O-])(=O)=O NKTZYSOLHFIEMF-UHFFFAOYSA-N 0.000 description 1
- CKTSUEBQFPDKMB-UHFFFAOYSA-N dipotassium;fluoro(dioxido)borane Chemical compound [K+].[K+].[O-]B([O-])F CKTSUEBQFPDKMB-UHFFFAOYSA-N 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- 230000007274 generation of a signal involved in cell-cell signaling Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000010330 laser marking Methods 0.000 description 1
- 238000007648 laser printing Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
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- 238000003754 machining Methods 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
Images
Classifications
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/11—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on acousto-optical elements, e.g. using variable diffraction by sound or like mechanical waves
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/0009—Materials therefor
- G02F1/0072—Mechanical, acoustic, electro-elastic, magneto-elastic properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/10—Controlling the intensity, frequency, phase, polarisation or direction of the emitted radiation, e.g. switching, gating, modulating or demodulating
- H01S3/11—Mode locking; Q-switching; Other giant-pulse techniques, e.g. cavity dumping
- H01S3/1123—Q-switching
- H01S3/117—Q-switching using intracavity acousto-optic devices
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/14—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range characterised by the material used as the active medium
- H01S3/16—Solid materials
- H01S3/1601—Solid materials characterised by an active (lasing) ion
- H01S3/1603—Solid materials characterised by an active (lasing) ion rare earth
- H01S3/1611—Solid materials characterised by an active (lasing) ion rare earth neodymium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/14—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range characterised by the material used as the active medium
- H01S3/16—Solid materials
- H01S3/163—Solid materials characterised by a crystal matrix
- H01S3/164—Solid materials characterised by a crystal matrix garnet
- H01S3/1643—YAG
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- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Electromagnetism (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Optical Modulation, Optical Deflection, Nonlinear Optics, Optical Demodulation, Optical Logic Elements (AREA)
Abstract
Description
本発明では、高性能の音響光学デバイスを製造するために、新規なモリブデン/タングステンテルル四元化合物が音響光学媒体として使用される。使用される材料は無毒であり、高品質且つ大寸法である単結晶が容易に得られ、結晶の物理的特性は高品質の音響光学材料に対する全の要求をほぼ満足するため、重要な潜在的な使用価値がある。このような材料は光透過波帯がいずれも3〜5umの波帯を覆うことができるということは注目に値する。このような材料は高結晶系結晶、中結晶系結晶及び低結晶系結晶を含む多様な構造を有するため、実用化の要求に応じて材料を選択することができる。
ここで、α−BaTeMo2O9結晶は特許文献3により製造されるものであり、β−BaTeMo2O9結晶は特許文献4により製造されるものであり、Cs2TeMo3O12結晶は特許文献5により製造されるものであり、Cs2TeW3O12結晶は特許文献6により製造されるものであり、Na2TeW2O9結晶は非特許文献1により製造されるものである。
α−BaTeMo2O9結晶は、二軸結晶、斜方晶系、mm2点群に属する。結晶は光透過範囲が0.38〜5.53μmであり、透過率が80%程度であり、コーティングされた後の透過率が99%以上に達し、比較的大きな屈折率(nz=2.42@0.4μm)を示す。α−BaTeMo2O9結晶は、大寸法且つ高品質の単結晶を容易に成長させる性能、耐潮解性、耐劈開性、適度な硬度(Mohs〜4.7)、機械的に加工されやすい性能、比較的大きな光損傷閾値等の優れた物理的化学的性能を有する。
<実施例2:β−BaTeMo2O9結晶>
<実施例3:Cs2TeMo3O12結晶>
<実施例4:Cs2TeW3O12結晶>
<実施例5:CdTeMoO6結晶>
<実施例6:Na2TeW2O9結晶>
2 集束系
3 入力ミラー
4 レーザー結晶
5 音響光学変調器
6 出力ミラー
Claims (5)
- 四元モリブデン/タングステンテルル酸塩はテルル(Te)及びタングステン(W)又はモリブデン(Mo)を同時に含む四元酸化物である四元モリブデン/タングステンテルル結晶を音響光学材料とする
ことを特徴とする使用。 - 前記四元モリブデン/タングステンテルル酸塩は、β−BaTeMo2O9、α−BaTeMo2O9、Cs2TeMo3O12、Cs2TeW3O12、Na2TeW2O9又はCdTeMoO6である
請求項1に記載の使用。 - 前記四元モリブデン/タングステンテルル酸塩結晶を音響光学媒体として音響光学デバイスを製造する
請求項1に記載の使用。 - 前記音響光学デバイスは、音響光学変調器、音響光学偏向器又は音響光学フィルターであることを特徴とする請求項3に記載の使用。
- 音響光学媒体、圧電トランスデューサ及びインピーダンス整合ネットワークを含む音響光学デバイスであって、前記音響光学媒体は請求項1に記載の前記四元モリブデン/タングステンテルル結晶である
ことを特徴とする音響光学デバイス。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611161381.7A CN106526905B (zh) | 2016-12-15 | 2016-12-15 | 一类四元钼/钨碲酸盐晶体的应用及器件 |
CN201611161381.7 | 2016-12-15 | ||
PCT/CN2017/104968 WO2018107876A1 (zh) | 2016-12-15 | 2017-09-30 | 一类四元钼/钨碲酸盐晶体的应用及器件 |
Publications (2)
Publication Number | Publication Date |
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JP2019516135A true JP2019516135A (ja) | 2019-06-13 |
JP6630852B2 JP6630852B2 (ja) | 2020-01-15 |
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JP2018554737A Active JP6630852B2 (ja) | 2016-12-15 | 2017-09-30 | 四元モリブデン/タングステンテルル酸塩結晶の使用及びデバイス |
Country Status (4)
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US (1) | US10866437B2 (ja) |
JP (1) | JP6630852B2 (ja) |
CN (1) | CN106526905B (ja) |
WO (1) | WO2018107876A1 (ja) |
Families Citing this family (1)
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CN106526905B (zh) * | 2016-12-15 | 2019-02-05 | 山东大学 | 一类四元钼/钨碲酸盐晶体的应用及器件 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4761786A (en) * | 1986-12-23 | 1988-08-02 | Spectra-Physics, Inc. | Miniaturized Q-switched diode pumped solid state laser |
US6560005B2 (en) * | 2001-08-07 | 2003-05-06 | Tkd, Inc. | Acousto-optic devices |
CN102031563B (zh) * | 2010-09-30 | 2012-05-30 | 山东大学 | 高温相钼酸碲钡晶体及其制备方法与应用 |
CN102623886A (zh) * | 2012-04-06 | 2012-08-01 | 山东大学 | 基于BaTeMo2O9晶体的全固态拉曼激光器 |
CN106094265A (zh) * | 2016-08-26 | 2016-11-09 | 中国电子科技集团公司第二十六研究所 | 驻波型光纤声光调制器 |
CN106094266A (zh) * | 2016-08-26 | 2016-11-09 | 中国电子科技集团公司第二十六研究所 | 多波长光纤声光移频器 |
CN106526905B (zh) * | 2016-12-15 | 2019-02-05 | 山东大学 | 一类四元钼/钨碲酸盐晶体的应用及器件 |
-
2016
- 2016-12-15 CN CN201611161381.7A patent/CN106526905B/zh active Active
-
2017
- 2017-09-30 WO PCT/CN2017/104968 patent/WO2018107876A1/zh active Application Filing
- 2017-09-30 JP JP2018554737A patent/JP6630852B2/ja active Active
- 2017-09-30 US US16/313,033 patent/US10866437B2/en active Active
Also Published As
Publication number | Publication date |
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JP6630852B2 (ja) | 2020-01-15 |
US20190227349A1 (en) | 2019-07-25 |
US10866437B2 (en) | 2020-12-15 |
WO2018107876A1 (zh) | 2018-06-21 |
CN106526905A (zh) | 2017-03-22 |
CN106526905B (zh) | 2019-02-05 |
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