JP2019202258A - Method and apparatus for re-dissolving hydrogen molecules in disk-type electrolytic cell - Google Patents

Abstract

To provide a method and an apparatus for re-dissolving hydrogen molecules in a disk-type electrolytic cell, with an increased total amount of hydrogen molecules dissolved in electrolytically reduced water and secured purity of the hydrogen molecules.SOLUTION: There is provided a method for re-dissolving hydrogen molecules, including: introducing raw water from central water supply ports 33 and 63 of two electrode plates 40 and 60; flowing out the raw water radially along cathode/anode chambers 42 and 62 on corresponding surfaces of the two electrode plates 40 and 60; thereby generating a dissolving action on cathode water and hydrogen molecules in nascent state; providing an ion membrane 50 between the two electrode plates 40 and 60 so that oxygen molecules generated by electrolysis are not mixed into the cathode water; removing hydrogen and oxygen molecules from the cathode/anode chambers 42 and 62 by the cathode water and anode water, which are then merged into upper and lower gas collecting and guiding chambers; causing the hydrogen molecules and the cathode water to generate a mutual dissolving action again in a gas collecting water conducting chamber 78; re-dissolving more hydrogen molecules in the cathode water; thereby increasing a concentration of the hydrogen molecules in the cathode water.SELECTED DRAWING: Figure 4

Description

  The method and apparatus for re-dissolving hydrogen molecules in the disk-type electrolytic cell of the present invention is mainly applied to a technique for increasing the total amount of dissolved hydrogen molecules (including negative hydrogen ions) in electrolytic reduced water.

  In recent years, molecular hydrogen medicine has attracted attention as a new topic in preventive medicine research, and recently, the protection and mitigation effects of various animal disease patterns by inhalation of hydrogen and injection of hydrogen saline have been demonstrated. Hydrogen molecules are safe gas that is odorless, colorless, tasteless and nontoxic, is the smallest antioxidant in outer space, and has the ability to remove free radicals that cause all diseases. For this reason, experts and scholars from all over the world are entering the research one after another, and through the publication of papers and clinical demonstrations, it has been confirmed that hydrogen molecules have good effects in health care, beauty and disease prevention. In the future, it is predicted that a new stage of water molecular medicine will be opened.

  The functional study of hydrogen molecules and the pathological mechanism thereof are gradually becoming clear, but specialized techniques and devices are required for the inhalation-type hydrogen or hydrogen saline injection described above. Therefore, if hydrogen molecules can be introduced into daily drinking water, it will be an economical and easy health care method, which will not only bring new light to the health industry, but also a new hope for the hydrogen industry. .

  However, there are many problems that must be overcome immediately in terms of hardware. Conventionally used electrolysis devices include a conventional flowing water type porous electrolytic cell, a stationary hydrogen water electrolytic cup, and a porous flowing water type electrolytic cell. However, since hydrogen has a very low solubility in water, the total amount of hydrogen molecules dissolved in electroreduction water produced by a general electrolysis device is not sufficient. The problems that occur in the three types of electrolytic cells that are conventionally used are described below.

  In the case of a conventional flowing-water type porous electrolytic cell, the electrode holes are generally designed to be circular, square, rectangular, or are constituted by mesh electrodes. Since both the cathode water and the anode water flow paths are provided on the surface of the electrode plate, a large number of recesses appear in the hole diameter vertical cross section of the electrode hole, and a “stagnation zone” is formed. The “stagnation area” means an area where the water flow becomes slow. Due to this region, agglomeration phenomenon occurs in the hydrogen generated at the cathode, and even larger bubbles are generated. In other words, hydrogen that has just been generated at the cathode cannot be rapidly dissolved in water, and this phenomenon gradually reduces the amount of hydrogen molecules dissolved in the cathode water.

  In addition, taking a static hydrogen water electrolysis cup as an example of a horizontally installed electrolytic cell, at present, the following problems are mainly faced. That is, since gas has a lighter mass than water, it has the physical property that a lighter one rises in either hydrogen or oxygen, and the following phenomenon occurs.

  1. First, hydrogen (hydrogen molecules or negative hydrogen ions) generated above the cathode forms bubbles due to agglomeration and rapidly rises above the cup. Therefore, the hydrogen generated at the cathode is actually completely underwater. Does not dissolve. As a result, a situation in which the content of hydrogen molecules generated in the cup is insufficient is invited.

  2. Oxygen generated below the anode is not led out smoothly due to insufficient pressure above, and often stays in the hole (vertical cross section) below the anode. This phenomenon rapidly increases the impedance of the electrode.

  3. The electrolyte solution required under the anode (that is, in the anode chamber) is introduced into the anode chamber from above the cathode, that is, from the inside of the cup via a hole or a hydrophilic ion membrane. Here, since the hole actually communicates with the yin and yang polar chamber, the following contradiction occurs. That is, if the hole is too small, the upper electrolyte solution is difficult to be introduced into the lower anode chamber, while if the hole is too large, water is easily introduced, but the oxygen and ozone generated at the lower anode rise and rise upward. It becomes easy to mix in the cathode water, and contamination occurs. In addition, when the electrode solution required in the anode chamber is introduced through a hydrophilic ion membrane, the ion membrane above the anode chamber is immersed for a relatively long time because of the impedance of the membrane. Without it, it will not get wet enough. Therefore, a rest of a certain time (about 10 minutes or more) is essential for electrolysis in a cup. Due to this phenomenon, hydrogen water cannot be continuously generated in the case of a cup, which is the greatest adverse effect.

  Further, in the case of a commonly used porous flowing water electrolytic cell, most of the electrodes are erected upright. That is, the electrodes are designed so that one electrode is arranged on each of the left and right sides, and the water flow is directed from the bottom to the top. That is, it is designed so that water is supplied from below the electrolytic cell and drained from above the electrolytic cell. In this case, after the gas leaves the electrode, the lighter the gas, the faster it moves from bottom to top according to the physical property that it rises, and hydrogen that did not dissolve in water in the cathode chamber is rapidly derived. This is mainly because it is difficult to provide gas accommodating spaces on the left and right sides of the electrode in the electrolytic cell. Therefore, generally, after the cathode water is led out of the electrolytic cell, it is introduced into a specially designed gas storage chamber to increase the amount of dissolved hydrogen molecules. The above structure is mainly to compensate for the innate deficiency in the conventional electrolytic cell, but there is a problem that the space is unnecessarily increased, and the structure cost is also increased. Thus, there are still challenges and traps to overcome.

  The inventor of the present invention is currently engaged in the manufacture and design of related products, and has many years of practical experience and knowledge. Therefore, as a result of positively investing in the spirit of innovation and improvement on the problems and jars that exist in the above-mentioned conventional electrolytic cell, a hydrogen molecule remelting method and apparatus in a disk-type electrolytic cell was completed.

  The technical means applied by the present invention to solve the first problem and the effect on the prior art are as follows. First, hydrogen molecules of electrolyzed reduced water that is not completely dissolved in the cathode water have multiple layers in the mutual dissolution phenomenon. More hydrogen molecules are redissolved in water by combining the cyclic hydrogen dissolution chamber and the pressure rise.

  The technical means applied by the present invention to solve the second problem and the effect on the prior art are to form a negative / anode chamber by notching radial holes in the annular negative / positive electrode plate. In addition, since the negative / anode chamber constitutes a negative / anodic water flow path, the generation of larger bubbles due to the hydrogen agglomeration phenomenon can be avoided by quickly removing the hydrogen in the nascent state from the cathode chamber. This effectively increases the amount of hydrogen dissolved.

  The technical means applied by the present invention to solve the third problem and the effect on the prior art are as follows. By providing a gas collecting water guiding chamber below the anode electrode plate, oxygen and ozone generated by the anode electrode plate are reduced. Accommodate quickly and avoid contamination of the oxygen and ozone into the cathode water above. Through experiments, it was proved that the amount of hydrogen molecules dissolved in the cathode water can be effectively increased by the measures described above, and the purity of the hydrogen molecules in the cathode water can be secured.

FIG. 1 is a three-dimensional assembly diagram in bottom view according to the first embodiment of the present invention. FIG. 2 is a three-dimensional assembly cross-sectional view in front view according to the first embodiment of the present invention. FIG. 3 is a three-dimensional assembly cross-sectional view of the base and the lower gas collection headboard in the first embodiment of the present invention. FIG. 4 is a three-dimensional exploded view according to the first embodiment of the present invention and an enlarged view of A part, K part... G part. FIG. 5 is a three-dimensional exploded view according to Example 1 of the present invention and an enlarged view of the S part. FIG. 6 is an assembly cross-sectional view showing the conductive state of the negative / anode electrode plate in Example 1 of the present invention. FIG. 7 is an assembled cross-sectional view showing the supply of raw water during electrolysis in Example 1 of the present invention, and an enlarged view of C and Y parts. FIG. 8 is an assembly view showing a cross section EE in FIG. 7. FIG. 9 is an assembly cross-sectional view showing the derivation of cathodic water and anodic water during electrolysis in Example 1 of the present invention. FIG. 10 is an assembly view showing a JJ cross section of FIG. 9. FIG. 11 is an assembly view showing the FF cross section of FIG. 9. FIG. 12 is an assembly view showing the RR cross section of FIG. 9. FIG. 13 is a three-dimensional exploded view of Example 2 of the present invention. FIG. 14 is an assembled cross-sectional view of the second embodiment of the present invention and an enlarged view of the H portion.

  In order that those skilled in the art can easily understand the details of the structure of the present invention and the functions and effects that can be achieved, the following detailed description will be given in combination with the drawings with specific examples.

  1 to 5 will be referred to for a method and apparatus for re-dissolving hydrogen molecules in a disk-type electrolytic cell. Mainly, the base 10, the conductor 20, the lower gas collecting water guide board 30, the anode electrode plate 40, the ion membrane 50, the cathode electrode plate 60, the upper gas collecting water guide board 70, the cover body 80, the water supply / drainage connector 90, and a plurality of water stop washers. Q is included.

  The base 10 has a disk shape, and a hollow covering convex portion 11 for covering the water supply / drainage connector 90 is provided at the center so as to extend downward. Two grooves 111 are provided outside the covering projection 11 and are stopped by two water washers Q. Two tenons 112 for locking the water supply / drainage connector 90 are provided outside the covering projection 11. A plurality of partition plates 12 arranged radially at equal intervals are provided on the upper surface of the base 10, and an anodic water flow path 121 is formed between the partition plates 12. Two insertion holes 13 are provided on both sides of the upper surface of the base 10 so that the two positive electrode conductive portions 45 of the anode electrode plate 40 are inserted and fastened to the base 10 by two spacers R and two nuts N. ing. The covering projection 11 is provided with a conductive spacer tube 14, a raw water supply spacer ring 15 and an anode water drain spacer ring 16 in this order from the inside to the outside. A female screw 141 for fastening the conductor 20 is provided inside the conductive spacer tube 14. Between the inner wall of the raw water supply spacer ring 15 and the conductive spacer tube 14, a plurality of equally spaced spacer ribs 151 are provided so that the raw water supply flow channel 152 is formed on the inner wall of the raw water supply spacer ring 15. In addition, between the inner wall of the anodic drainage spacer ring 16 and the raw water supply spacer ring 15, spacer ribs 161 are equally spaced so that an anodic drainage channel 162 is formed on the inner wall of the anodic drainage spacer ring 16. A plurality are provided. An anode water drain port 163 is provided at a location corresponding to the anode water flow path 121 in the anode water drain spacer ring 16. A plurality of equally spaced anode water drain holes 164 are provided at locations corresponding to the circumferential outer edge of the covering projection 11 in the bottom of the anode water drain flow channel 162. A flange 17 is provided on the upper surface of the base 10 so as to correspond to the outer edges of the plurality of partition plates 12. As a result, a coupling groove 171 for combining the lower gas collecting water guide plate 30 is formed between the inner wall of the base 10 and the flange 17. A male screw 18 for mating the base 10 and the cover body 80 is provided at a location corresponding to the inner wall of the cover body 80 in the outer wall of the base 10. A water stop washer Q can be press-fitted at a location corresponding to the upper side of the male screw 18 in the base 10, and a groove 19 used for water stop when the base 10 and the cover body 80 are mated is provided. Yes.

  A male screw 21 and a positioning convex edge 22 are provided at the upper end of the conductor 20 so that the water stop washer Q and the nut N can be fastened to the center position of the cathode electrode plate 60. A male screw 23 and a positioning convex edge 24 are provided at the lower end of the conductor 20 so as to be fastened to the female screw 141 in the conductive spacer tube 14 at the center of the base 10. A groove 25 is formed between the two positioning convex edges 22 and 24 so that the water stop washer Q is pressed to stop the water. In addition, a conductive portion 26 is provided at the lower end of the conductor 20.

  The lower gas collection diversion board 30 has a disk shape, and two hole studs 31 are provided at locations corresponding to the two insertion holes 13 of the base 10 in the lower gas collection diversion board 30. . The outer diameters of the two holed studs 31 correspond to the inner diameters of the two insertion holes 13, and the two holed studs 31 can be inserted through the two insertion holes 13. Two fisheye holes 311 that penetrate therethrough are provided inside the two studs with holes 31 so that the two positive electrode conductive portions 45 of the anode electrode plate 40 can be inserted. Two water-stop washers Q for water stop are provided above the two fish eye holes 311. A raw water supply spacer ring 32 is provided at the center of the lower gas collecting water guide plate 30, and a plurality of raw water supply ports 33 are provided at locations where the circumference of the outer wall of the raw water supply spacer ring 32 is equally divided. ing. A raw water supply groove 34 is provided on the circumferential outer edge of the raw water supply port 33. The raw water enters the raw water supply groove 34 from the plurality of raw water supply ports 33 and then flows out from the inside to the outside radially from the raw water supply groove 34. The circumferential inner wall of the upper surface of the lower gas collection diversion board 30 is provided with a plurality of equally-positioned positioning fitting grooves 35 for fitting and positioning the upper gas collection diversion board 70. A plurality of equally-spaced anode water drain ports 36 are provided on the circumferential outer edge of the upper surface of the lower gas collection guide plate 30. A plurality of anode water drain passages 361 are provided at the inner circumferential edge of the anode water drain port 36. Further, a projecting ring 362 for stopping the ion membrane 50 is provided on the circumferential outer edge of the plurality of anode water drain ports 36. A groove 321 is provided below the raw water supply spacer ring 32 at a location corresponding to the inner wall of the raw water supply spacer ring 15 of the base 10 so that the water stop washer Q is pressed to stop the water. Since a groove 37 that presses a water stop washer Q and can stop water is provided at a location corresponding to the inner wall of the coupling groove 17 of the base 10 in the outer wall of the lower gas collecting water guide plate 30. Mixing of water and anode water is prevented. A flange 38 is provided at a location corresponding to the circumference of the plurality of anode water drain ports 36 on the upper surface of the lower gas collection guide plate 30. Since the water level of the anode water is increased by using the flange 38, the ion membrane 50 can be sufficiently wetted. A blocking edge 39 is provided at a position corresponding to the circumferential inner edge of the plurality of anode water drain ports 36 on the bottom surface of the lower gas collection guide plate 30. As a result, a gas collecting water conducting chamber 391 for collecting oxygen molecules and conducting anode water is formed on the bottom surface of the lower gas collecting water guiding plate 30, so that oxygen and ozone generated in the anode electrode plate 40 rapidly Is housed in. Therefore, mixing of the oxygen and ozone into the upper cathode water is avoided.

  The anode electrode plate 40 has a disk shape. A shaft hole 41 is provided at the center of the anode electrode plate 40, and the inner diameter of the shaft hole 41 corresponds to the outer diameter of the raw water supply spacer ring 32 of the lower gas collection water guide panel 30. A plurality of hollow and radially arranged anode chambers 42 are provided on the circumferential surface of the anode electrode plate 40. The anode chamber 42 may be V-shaped. As a result, a plurality of water supply ports 43 are formed at locations corresponding to the raw water supply grooves 34 of the lower gas collection diversion board 30, and raw water can be introduced into the plurality of anode chambers 42 from the plurality of water supply ports 43. On the outer circumferential edge of the anode electrode plate 40, a plurality of recessed positioning portions 44 are provided that are arranged at equal intervals and used for guidance when positioning with the cathode electrode plate 60. Two positive electrode conductive portions 45 are provided at locations corresponding to the two insertion holes 13 of the base 10 and the two fisheye holes 311 of the lower gas collecting water guide plate 30 in the anode electrode plate 40. The two positive electrode conductive portions 45 are provided with two male screws 46 for tightening the nut N.

  A round hole 51 is provided in the center of the ion membrane 50, and the inner diameter of the round hole 51 corresponds to the inner diameter of the raw water supply spacer ring 32 of the lower gas collection water guide plate 30. The ion membrane 50 can be a proton exchange membrane. The outer diameter of the ion film 50 is larger than the outer diameters of the anode electrode plate 40 and the cathode electrode plate 60. During electrolysis, hydrogen molecules can pass through the ion membrane 50, whereas oxygen molecules cannot pass through the ion membrane 50. Therefore, it is possible to avoid a situation in which oxygen and ozone generated in the anode electrode plate 40 are mixed into the upper cathode water.

  The cathode electrode plate 60 has a disk shape. A shaft hole 61 is provided at the center of the cathode electrode plate 60, and the inner diameter of the shaft hole 61 corresponds to the outer diameter of the male screw 21 at the upper end of the conductor 20. When the male screw 21 at the upper end of the conductor 20 is inserted into the shaft hole 61 of the cathode electrode plate 60, the water stop washer Q and the nut N can be tightened to the center position of the cathode electrode plate 60. A plurality of hollow and radially arranged cathode chambers 62 are provided on the circumferential surface of the cathode electrode plate 60. The cathode chamber 62 may be V-shaped. The anode chamber 42 of the anode electrode plate 40 and the cathode chamber 62 of the cathode electrode plate 60 are completely the same in shape, size and position. A plurality of water supply ports 63 arranged at equal intervals are provided between the shaft hole 61 and the plurality of cathode chambers 62 in the cathode electrode plate 60, and raw water is supplied from the plurality of water supply ports 63 to the plurality of cathode chambers 62. Can be introduced. On the outer circumferential edge of the cathode electrode plate 60, a plurality of recessed positioning portions 64 are provided that are arranged at equal intervals to guide alignment with the positioning portion 44 of the anode electrode plate 40. Thereby, the anode chamber 42 of the anode electrode plate 40 and the cathode chamber 62 of the cathode electrode plate 60 are completely meshed with each other.

  The upper gas collecting water guide plate 70 has a disk shape. In order to fit and position the upper gas collection diversion board 70 and the lower gas collection diversion board 30 at locations corresponding to the plurality of positioning fitting grooves 35 in the lower gas collection diversion board 30 in the upper gas collection diversion board 70. A plurality of positioning fitting blocks 71 are provided. A groove 72 that allows the water stop washer Q to be press-fitted is provided at a location corresponding to the projecting ring 362 of the lower gas collection diversion board 30 in the upper gas collection diversion board 70. As a result, the ion membrane 50 is pressed by the water stop washer Q of the upper gas collection diversion board 70 and the projecting ring 362 of the lower gas collection diversion board 30 to form a water stop action. Can be avoided. An accommodation concave groove 73 for accommodating the male screw 21 and the nut N at the upper end of the conductor 20 is provided at the center of the bottom surface of the upper gas collection guide board 70. Raw water supply grooves 74 are provided at locations corresponding to the plurality of water supply ports 63 of the cathode electrode plate 60 in the bottom surface of the upper gas collection guide plate 70. After the raw water is supplied from the plurality of raw water supply ports 63 to the raw water supply groove 74, the raw water can flow out from the inside to the outside radially from the raw water supply groove 74. A plurality of equally spaced cathode water drain ports 75 are provided on the outer circumferential edge of the upper gas collection guide board 70. A plurality of equally spaced cathode water drain channels 76 are provided at locations corresponding to the circumferential inner edges of the plurality of cathode water drain ports 75 in the bottom surface of the upper gas collection guide plate 70. A plurality of gas collecting water conducting chambers 78 are formed on the upper surface of the upper gas collecting water guiding plate 70 at a position corresponding to the circumferential inner edge of the plurality of cathode water drain ports 75 in the upper surface of the upper gas collecting water guiding plate 70. A plurality of annular blocking edges 77 are provided. A plurality of notches 79 for collecting hydrogen molecules and introducing the cathode water are provided on the upper surfaces of the plurality of annular blocking edges 77, so that the hydrogen generated by the cathode electrode plate 60 is quickly accommodated. Is done.

  A female screw 81 for mating the cover body 80 and the base 10 is provided at a location corresponding to the male screw 18 of the base 10 on the inner wall of the cover body 80. An upper position inside the cover body 80 is provided by providing a plurality of staggered annular blocking edges 82 at locations corresponding to the plurality of annular blocking edges 77 of the upper gas collecting head 70 in the cover body 80. A plurality of hydrogen-dissolving chambers 83 are formed. A plurality of notches 84 for collecting hydrogen molecules and conducting cathodic water are provided on the upper surfaces of the plurality of annular blocking edges 82. Cathodic water can flow in a plurality of gas collecting water conducting chambers 78 and a plurality of hydrogen dissolving chambers 83 in an S-shape that is continuous in the vertical and vertical directions, and is a mutual dissolution phenomenon that occurs due to the rise of hydrogen and the fall of cathodic water. Causes more hydrogen molecules to dissolve in water. In the center of the cover body 80, a penetrating cathode water drain connector 85 extending upward is provided. Outside the cathode water drain connector 85, a water stop washer Q can be press-fitted, and a groove 86 for connecting a cathode water drain tube (not shown) is provided. Thereby, the cathode water containing abundant active hydrogen can be derived from the cathode water drain connector 85 and the cathode water drain tube (not shown).

  A hollow shaft column 91 is provided at a location corresponding to the conductive spacer tube 14 of the base 10 in the center of the water supply / drainage connector 90. The hollow shaft column 91 is provided with an elastic member S and a negative electrode conductive column 98 (see FIG. 6), and the upper end of the negative electrode conductive column 98 is connected to the conductive portion 26 of the conductor 20 by the elastic force of the elastic member S. Can be brought into firm contact. A negative electrode wire (not shown) can be connected to the lower end of the conductive column 98. On the upper surface of the water supply / drainage connector 90, two positive electrode conductive pieces 99 (see FIG. 6) having elasticity are provided corresponding to the two positive electrode conductive portions 45 of the anode electrode plate 40. Accordingly, the lower ends of the two positive electrode conductive portions 45 in the anode electrode plate 40 can be brought into firm contact with the two positive electrode conductive pieces 99. A positive electrode wire (not shown) can be connected to the lower ends of the two positive electrode conductive pieces 99. A covering recess 92 is provided at a location corresponding to the covering protrusion 11 of the base 10 in the water supply / drainage connector 90, and the outer diameter of the covering protrusion 11 of the base 10 is the covering recess of the water supply / drainage connector 90. This corresponds to an inner diameter of 92. Two tenon grooves 93 are provided at locations corresponding to the two tenon 112 in the covering recess 92. The two tenons 112 can be turned into and out of the two tenon grooves 93 and are used for quick attachment and detachment of the water supply / drainage connector 90. An anode water drain groove 94 and a raw water supply groove 95 are provided coaxially inside the covering recess 92. The inner diameter of the anode water drain groove 94 is larger than that of the raw water supply groove 95. An anode water drain connector 96 is provided at a location corresponding to the anode water drain groove 94 in the outside of the water supply / drain connector 90. An anode water drain tube (not shown) can be connected to the anode water drain connector 96. A raw water / water supply connector 97 is provided at a location corresponding to the raw water / water supply groove 95 in the outside of the water supply / drainage connector 90.

  The present invention, which is a combination of the above component structures, provides a method and apparatus for re-dissolving hydrogen molecules in a disk-type electrolytic cell. The actual operation is applied as follows.

  FIG. 7 is an assembly cross-sectional view showing the raw water supply during electrolysis in Example 1 of the present invention, FIG. 7 is an enlarged view of the C part and the Y part, and FIG. 8 is an assembly view showing the EE cross section of FIG. refer. When the raw water flows in, the raw water is introduced from the raw water / water supply connector 97 of the water supply / drainage connector 90 into the raw water / water supply groove 95, and first, from below through the raw water / water supply flow path 152 formed by the inner wall of the raw water / water supply spacer ring 15 of the base 10. To flow into. Most of the water is introduced from the plurality of water supply ports 63 of the cathode electrode plate 60 into the raw water supply groove 74 of the upper gas collecting water guide plate 70, and then the plurality of waters arranged radially from the raw water supply groove 74 in the cathode electrode plate 60. It flows into the cathode chamber 62. A small amount of water flows into the raw water supply groove 34 from the plurality of raw water supply ports 33 at the outer edge of the raw water supply spacer ring 32 in the lower gas collection water guide plate 30 and then from the raw water supply groove 34 to the plurality of water supplies of the anode electrode plate 40. It flows into the plurality of anode chambers 42 arranged radially via the port 43.

  FIG. 9 is an assembly cross-sectional view showing derivation of cathodic water and anodic water during electrolysis in Example 1 of the present invention, and is an assembly drawing showing JJ, FF, and RR cross sections of FIG. 9. Please refer to FIG. 10, FIG. 11, and FIG. At the time of electrolysis of the raw water, the raw water is electrolyzed in the plurality of cathode chambers 62 in the cathode electrode plate 60 and the plurality of anode chambers 42 in the anode electrode plate 40, respectively. In the plurality of anode chambers 42, oxygen, ozone, and anode water are respectively generated. Since the cathode electrode plate 60 and the anode electrode plate 40 separate the ion film 50, during electrolysis, hydrogen molecules can pass through the ion film 50, whereas oxygen molecules cannot pass through the ion film 50. . Thereby, the situation where oxygen and ozone produced | generated with the anode electrode plate 40 mix in upper cathode water is avoided. Also, the cathode water quickly dissolves and removes the nascent hydrogen produced in the cathode chamber 62, and first flows into the cathode water drain port 75 from the cathode water drain channel 76 of the upper gas collecting water guide 70. Thereafter, the gas is introduced into the upper gas collecting water introduction chamber 78 from the notch 79 of the annular blocking edge 77 from below to above through the cathode water drain port 75. Thereby, hydrogen molecules can be collected above the hydrogen dissolution chamber 83. Also, the cathode water flows in a plurality of gas collecting water conducting chambers 78 and a plurality of hydrogen dissolving chambers 83 so as to form an S-shape that is continuous vertically and vertically, and a mutual dissolution phenomenon that occurs due to the rise of hydrogen and the fall of cathode water. In this way, more hydrogen molecules are dissolved in water, and by applying pressure, more hydrogen molecules are redissolved in the cathode water, and the concentration of hydrogen molecules in the cathode water is increased. Finally, the cathode water rich in hydrogen may be derived from the cathode water drain connector 85 and the cathode water drain tube (not shown). On the other hand, oxygen and ozone generated in the anode chamber 42 are quickly taken away by the anode water, and first flow into the anode water drain port 36 from the anode water drain channel 361 of the lower gas collecting water guide plate 30 and then the anode water drain port. The gas is introduced from the blocking edge 39 to the lower gas collecting water guide chamber 391 via the upper side 36 through the lower side. Oxygen and ozone are rapidly accommodated above the gas collecting and guiding chamber 391, so that the situation where the oxygen and ozone are mixed into the upper cathode water is avoided. Moreover, oxygen and ozone are discharged from the anode water drainage groove 94 of the water supply / drainage connector 90, the anode water drainage connector 96, and the anode water drainage tube (not shown) using the anode water. Furthermore, since the water level of the anode water rises by using the flange 38, the ion membrane 50 can be sufficiently wetted.

  FIG. 13 which is a three-dimensional exploded view of the second embodiment of the present invention, and an enlarged sectional view of the H portion of the second embodiment of the present invention regarding the hydrogen molecule remelting apparatus in the disk-type electrolytic cell provided by the present invention. Reference is made to FIG. The anode chamber 42 of the anode electrode plate 40 and the cathode chamber 62 of the cathode electrode plate 60 may be porous. The lower gas collecting water guide plate 30 and the upper gas collecting water guide plate 70 are provided with a plurality of radially arranged spacer ribs 341 and 741 corresponding to the porous anode chamber 42 and the cathode chamber 62. As a result, a plurality of anode water flow paths 342 and cathode water flow paths 742 are formed between the plurality of spacer ribs 341 and 741, respectively, so that oxygen and ozone generated in the porous anode chamber 42 can be quickly generated by the anode water. The nascent hydrogen generated in the porous cathode chamber 62 can be taken away and rapidly dissolved and removed by the cathode water.

  As described above, the method and apparatus for re-dissolving hydrogen molecules in the disk-type electrolytic cell provided by the present invention has actually been completed, and the total dissolution amount of hydrogen molecules in the cathode is effectively 30% or more. It has been proved that it can rise to In the present invention, the hydrogen dissolution chamber and the gas collection chamber are integrated into a complete module. Therefore, not only cost reduction but also quick attachment / detachment is possible, so after-sales service becomes easy, and contribution to the future hydrogen industry is expected. Furthermore, since the present invention is the first creation that does not exist in the current market and has industrial utility value, it satisfies the requirements for the practicality and inventive step of the invention patent. Therefore, a patent application is filed with you based on the provisions of the Patent Law.

DESCRIPTION OF SYMBOLS 10 Base 11 Covering convex part 111 Groove 112 Tenon 12 Partition plate 121 Anode water flow path 13 Insertion hole 14 Conductive spacer pipe 141 Female screw 15 Raw water supply spacer ring 151 Spacer rib 152 Raw water supply flow path 16 Anode water drain spacer ring 161 Spacer rib 162 Anode Water drainage passage 163 Anode drainage 164 Anode drainage 17 Flange 171 Coupling groove 18 Male thread 19 Groove 20 Conductor 21 Male screw 22 Positioning convex edge 23 Male screw 24 Positioning convex edge 25 Groove 26 Conductive part 30 Lower gas collection Water guide plate 31 Stud with hole 311 Fish eye hole 32 Raw water feed spacer ring 321 Groove 33 Raw water feed port 34 Raw water feed groove 35 Positioning fitting groove 36 Anode water drain port 361 Anode water drain channel 362 Projecting ring 37 Groove 38 Flange 39 Blocking edge 391 gas Collection water guide chamber 40 Anode electrode plate 41 Axial hole 42 Anode chamber 43 Water supply port 44 Positioning portion 45 Positive electrode conductive portion 46 Male screw 50 Ion film 51 Round hole 60 Cathode electrode plate 61 Axis hole 62 Cathode chamber 63 Water supply port 64 Positioning portion 70 Upper Gas collecting water guide 71 Positioning fitting block 72 Groove 73 Housing concave groove 74 Raw water supply groove 75 Cathode water drain port 76 Cathode water drain channel 77 Annular blocking edge 78 Gas collection water guide chamber 79 Notch 80 Cover body 81 Female screw 82 Annular blocking edge 83 Hydrogen dissolution chamber 84 Notch 85 Cathode water drainage connector 86 Groove 90 Water supply / drainage connector 91 Hollow shaft column 92 Covering recess 93 Mortise groove 94 Anode water drainage groove 95 Raw water supply groove 96 Anode water drainage connector 97 Raw water supply connector 98 Negative electrode conductive column 99 Positive electrode conductive piece S Elastic member R Spacer N Nut Q Water stop washer

Claims (17)

A method for re-dissolving hydrogen molecules in a disk-type electrolytic cell,
Mainly, the raw water is introduced from the central water supply port of the two electrode plates, and flows out radially along the negative and anode chambers on the corresponding surfaces of the two electrode plates, thereby dissolving the cathode water and the nascent hydrogen molecules. Is generated,
An ion membrane is provided between the two electrode plates so that oxygen molecules generated after electrolysis are not mixed into the cathode water, and hydrogen molecules and oxygen molecules are removed from the negative / anode chamber by the cathode water and the anode water. Take it away and merge it into the upper and lower two gas collection chambers to generate reciprocal action between hydrogen molecules and cathode water in the gas collection chamber and re-dissolve more hydrogen molecules in cathode water. A method for increasing the concentration of hydrogen molecules in the cathode water. A device for re-dissolving hydrogen molecules in a disk-type electrolytic cell,
Mainly, the disk-type electrolytic cell has two gas collecting water guides, two negative / anode electrode plates, and one ion membrane inside the disc-shaped base and cover body. A water supply and drainage connector is provided,
Above the base is provided with one gas collection headboard and an anode electrode plate, and at the center of the base is provided with a water supply / drainage connector extending downward,
Below the cover body, one gas collection headboard and a cathode electrode plate are provided, and in the center of the cover body, a cathode water drain connector is provided to extend upward,
Two gas collection water guide chambers are provided at locations corresponding to the upper part of the base and the lower part of the cover body of the two gas collection water guide boards,
A water supply port is provided in the center of the two negative / anode electrode plates, and a plurality of hollow and radially arranged negative / anode chambers are provided on corresponding surfaces of the two negative / anode electrode plates,
The ion membrane is provided between two negative / anode electrode plates,
The water supply / drainage connector is provided with a raw water supply connector and an anode water discharge connector,
Raw water is introduced into the negative and anode chambers from the water supply ports of the two electrode plates, and hydrogen molecules and oxygen molecules generated after electrolysis are carried away by the cathode water and the anode water, and are respectively supplied to the upper and lower gas collecting water conveyance chambers. A device that increases the concentration of hydrogen molecules in the cathode water by merging and generating a mutual dissolving action between the hydrogen molecules and the cathode water in the gas collecting water conveyance chamber and re-dissolving more hydrogen molecules in the cathode water.   The device for re-dissolving hydrogen molecules in a disk-type electrolytic cell according to claim 1 or 2, wherein the polarities of the two negative / anode electrode plates are interchangeable with each other.   A plurality of partition plates arranged radially at equal intervals are provided on the upper surface of the base, and an anodic water flow path is formed between the partition plates. A conductive spacer is formed in the center of the base from the inside toward the outside. A pipe, a raw water supply spacer ring and an anode water drain spacer ring are provided in order, and a raw water supply flow path is formed on the inner wall of the raw water supply spacer ring between the inner wall of the raw water supply spacer ring and the conductive spacer pipe. A plurality of equally spaced spacer ribs are provided, and an anodized water drainage channel is formed between the inner wall of the anodized water draining spacer ring and the raw water supply spacer ring on the inner wall of the anodized water draining spacer ring. A plurality of spacer ribs are provided, and an anode water drain port is provided at a location corresponding to the anode water flow path in the anode water drain spacer ring. Remelting apparatus of the hydrogen molecules in the disk-type electrolytic cell according to claim 2, equally spaced anode water drainage hole is plurality in the circumferential outer edge at the bottom of the water drainage passage.   By providing a flange at the inner peripheral edge of the upper surface of the base, a coupling groove for combining the gas collecting diversion board is formed between the inner wall of the base and the flange, and the coupling groove of the outer wall of the gas collecting diversion board is formed. The apparatus for re-dissolving hydrogen molecules in a disk-type electrolytic cell according to claim 2, wherein a groove corresponding to is provided with a groove that presses a water stop washer to prevent mixing of cathode water and anode water.   A covering convex part is provided at the center of the base so as to extend downward, a covering concave part is provided at the center of the water supply / drainage connector, and a water supply / drainage connector is provided at a corresponding position of the covering convex part and the covering concave part. The apparatus for remelting hydrogen molecules in a disk-type electrolytic cell according to claim 2, further comprising a tenon and a tenon groove that enable quick engagement with the base.   The apparatus for remelting hydrogen molecules in a disk-type electrolytic cell according to claim 2, wherein the base and the cover body are provided with corresponding male and female screws for mating the base and the cover body.   The circumferential outer edges of the two electrode plates are arranged at a plurality of equal intervals for guiding the alignment of the two electrode plates so that the negative / anode chambers of the two electrode plates completely correspond and can be engaged with each other. The apparatus for re-dissolving hydrogen molecules in a disk-type electrolytic cell according to claim 2, wherein a positioning portion arranged is provided.   By providing a plurality of staggered annular cut-off edges between the cover body and the gas collection headboard, a plurality of hydrogen dissolution chambers are formed at an upper position inside the cover body, and the plurality of ring cut-offs are formed. The edge is provided with a plurality of notches for collecting hydrogen molecules and conducting cathodic water, and the cathodic water is an S-shape that is continuous vertically and vertically in a plurality of gas collecting water conducting chambers and a plurality of hydrogen dissolving chambers. The re-dissolution of hydrogen molecules in the disk-type electrolytic cell according to claim 2, wherein more hydrogen molecules are dissolved in water due to a mutual dissolution phenomenon caused by the rise of hydrogen and the fall of cathode water. apparatus.   The ion membrane can be a proton exchange membrane, the outer diameter of the ion membrane is larger than the outer diameter of the two electrode plates, and a corresponding projecting ring at the outer circumferential edge of the two gas collection guide plates A water stop washer can be press-fitted in the groove, and a water stop action is formed by press-fitting the ion membrane with the projecting ring and the water stop washer of the two gas collection baffles. The device for re-dissolving hydrogen molecules in a disk-type electrolytic cell according to claim 2, wherein a mixed flow of cathode water and anode water can be avoided.   3. The plurality of positioning fitting grooves and positioning fitting blocks for fitting and positioning the two gas collecting water guides to each other are provided at corresponding positions on the circumference of the two gas collection water guides. Device for re-dissolving hydrogen molecules in a disk-type electrolytic cell.   A conductor is provided at the center of the cathode electrode plate, a conductive portion is provided at the lower end of the conductor, a conductive spacer tube is provided at the center of the base, and a cathode electrode is provided inside the conductive spacer tube. A female screw capable of fastening the conductor of the plate is provided, and two insertion holes through which the two conductive portions on both sides of the anode electrode plate can be inserted are provided on both sides of the base. A hollow shaft column is provided at a location corresponding to the conductive spacer tube, and an elastic member and a conductive column are provided on the hollow shaft column, and the upper end of the conductive column is a conductive portion of the conductor by the elastic force of the elastic member. The negative pole wire can be connected to the lower end of the conductive column, and two elastic pieces having elasticity correspond to the two conductive portions of the anode electrode plate on the upper surface of the water supply / drainage connector. Provided, 2 Remelting apparatus of the hydrogen molecules in the disk-type electrolytic cell according to claim 2, the lower end of the positive electrode conductive strips can be connected to the positive electrode wire.   The apparatus for re-dissolving hydrogen molecules in a disk-type electrolytic cell according to claim 2, wherein the negative / anode chambers of the two negative / anode electrode plates are V-shaped.   The negative / anode chambers of the two negative / anode electrode plates are of a porous type, and the two gas collecting heads are provided with spacer ribs arranged radially corresponding to the negative / anode chambers, and between the plurality of spacer ribs. The apparatus for re-dissolving hydrogen molecules in a disk-type electrolytic cell according to claim 2, wherein a plurality of negative / anodic water channels are formed in each.   Two raw water water supply grooves are provided at locations corresponding to the water supply ports of the two electrode plates of the two gas collecting water guides, and the outer peripheral circumferential locations of the two gas collecting water guides are equidistantly shaded.・ Multiple anode water drains are provided, and there are a plurality of equally spaced negative and anode water drainage channels around the inner edge of the negative / anodic water drain, and raw water is fed from the two electrode plates. After flowing into the two raw water supply channels in the two gas collection heads, respectively, they flow radially from the inside to the outside through the two water inlets into the negative / anode chambers of the two electrode plates, and finally the negative / anodic water drainage. The device for re-dissolving hydrogen molecules in a disk-type electrolytic cell according to claim 2, which can be discharged from the flow path via a negative anode water drain port.   A blocking edge is provided at a position corresponding to the circumferential inner edge of the plurality of anode water drains among the bottom surface of the gas collection guide plate corresponding to the base, thereby collecting oxygen molecules and anode water on the bottom surface of the gas collection guide plate. A gas collecting water conducting chamber for conducting water is formed and oxygen and ozone generated in the anode electrode plate are rapidly accommodated, so that mixing of the oxygen and ozone into the upper cathode water is avoided. An apparatus for re-dissolving hydrogen molecules in the disk-type electrolytic cell described in 1.   A flange is provided at a position corresponding to the circumferential inner edge of the plurality of anode water drainage ports on the upper surface of the gas collection guide board corresponding to the base, and the ion membrane is formed by raising the water level of the anode water using the flange. The device for re-dissolving hydrogen molecules in a disk-type electrolytic cell according to claim 15, wherein the device is sufficiently wetted.