JP2019172646A - Pest control composition, aerosol product, and controlling method - Google Patents
Pest control composition, aerosol product, and controlling method Download PDFInfo
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
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Abstract
Description
本発明は、害虫防除組成物、エアゾール製品、並びに害虫の防除方法に関する。 The present invention relates to a pest control composition, an aerosol product, and a method for controlling pests.
スズメバチ、アシナガバチといった刺咬性の強いハチが人に対し危害を及ぼすことが知られている。これらハチに対しては、例えば、特許文献1〜3におけるエアゾール製品を用いて、駆除・防除する方法がとられている。 It is known that bees with strong bites such as wasps and wasps cause harm to humans. For these bees, for example, a method of extermination / control using an aerosol product in Patent Documents 1 to 3 is employed.
しかしながら、ハチに対して、殺虫効果がより優れるエアゾール製品が求められている。
本発明の目的は、従来品よりも効果が優れるハチ用防除組成物、エアゾール製品、ならびに、害虫の防除方法を提供することにある。
However, there is a need for aerosol products that have a better insecticidal effect against bees.
An object of the present invention is to provide a bee control composition, an aerosol product, and a method for controlling pests, which are more effective than conventional products.
本発明者は、上記課題を解決すべく鋭意検討の結果、以下の構成がハチに対し優れた殺虫効果が有ることを見出し、本発明に至った。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that the following configuration has an excellent insecticidal effect on bees, and have reached the present invention.
即ち本発明は、
〔1〕フェンプロパトリンである(a)成分と、モンフルオロトリン、フタルスリン、プラレトリン、メトフルトリン、ピレトリン、およびシフェノトリンのうち少なくとも1種である(b)成分と、パラフィン系溶剤である(c)成分とを含有することを特徴とする害虫防除組成物。
〔2〕前記(b)成分に対する前記(a)成分の配合割合(a/b)は、0.5〜1.5である、〔1〕記載の害虫防除組成物。
〔3〕〔1〕または〔2〕に記載の害虫防除組成物を用いたエアゾール製品
〔4〕〔3〕に記載のエアゾール製品を用いてハチを防除する方法。
That is, the present invention
[1] The component (a) which is fenpropatoline, the component (b) which is at least one of monfluorothrin, phthalthrin, praretrin, metfurthrin, pyrethrin and siphenothrin, and the paraffinic solvent (c) A pest control composition comprising an ingredient.
[2] The pest control composition according to [1], wherein a blending ratio (a / b) of the component (a) to the component (b) is 0.5 to 1.5.
[3] Aerosol product using the pest control composition according to [1] or [2] [4] A method for controlling bees using the aerosol product according to [3].
本発明によれば、殺虫効力の優れた害虫防除組成物、エアゾール製品、ならびに、害虫の防除方法を提供することできる。 According to the present invention, it is possible to provide a pest control composition, an aerosol product, and a pest control method having excellent insecticidal efficacy.
〔ハチ用防除組成物〕
本発明の防除組成物は、フェンプロパトリンである(a)成分と、モンフルオロトリン、フタルスリン、プラレトリン、メトフルトリンおよびピレトリンのうち少なくとも1種である(b)成分と、パラフィン系溶剤である(c)成分とを含有する。
[Control composition for bees]
The control composition of the present invention is a component (a) that is fenpropatoline, a component (b) that is at least one of monfluorothrin, phthalthrin, praretrin, metfurthrin, and pyrethrin, and a paraffinic solvent (c ) Component.
〔(a)成分〕
本発明の防除組成物は、(a)成分として、フェンプロパトリンを含む。本発明のエアゾール剤に使用するフェンプロパトリンの含有量は、組成物全体量に対し0.01〜3.0質量%である。0.01質量%未満の場合、十分な効果が得られず、一方で3.0重量%を超えても格別メリットはない。
[(A) component]
The control composition of the present invention contains fenpropatoline as the component (a). Content of the fenpropatoline used for the aerosol agent of this invention is 0.01-3.0 mass% with respect to the composition whole quantity. When the amount is less than 0.01% by mass, a sufficient effect cannot be obtained. On the other hand, even if it exceeds 3.0% by weight, there is no particular merit.
〔(b)成分〕
本発明の防除組成物は、(b)成分として、モンフルオロトリン、フタルスリン、プラレトリン、メトフルトリン、ピレトリン、およびシフェノトリンのうち少なくとも1種を含む。本発明のエアゾール剤に使用する(b)成分の含有量は、組成物全体量に対し0.01〜3.0質量%である。
[Component (b)]
The control composition of the present invention contains at least one of monfluorothrin, phthalthrin, praretrin, metfurthrin, pyrethrin, and ciphenothrin as the component (b). Content of (b) component used for the aerosol agent of this invention is 0.01-3.0 mass% with respect to the composition whole quantity.
〔(c)成分〕
本発明の防除組成物は、(c)成分として、パラフィン系溶剤を含む。例えば、ノルマルパラフィン、イソパラフィンを用いることができる。本発明に使用する溶剤は、組成物全体量に対し40〜75質量%であり、好ましくは50〜70質量%である。
[Component (c)]
The control composition of the present invention contains a paraffinic solvent as the component (c). For example, normal paraffin or isoparaffin can be used. The solvent used for this invention is 40-75 mass% with respect to the composition whole quantity, Preferably it is 50-70 mass%.
本発明の防除組成物における、(b)成分に対する(a)成分の配合割合(a/b)は、0.5以上1.5未満であることが好ましい。 In the control composition of the present invention, the blending ratio (a / b) of the component (a) to the component (b) is preferably 0.5 or more and less than 1.5.
〔エアゾール製品〕
本発明の防除組成物を用いてエアゾール製品とする場合は、公知のエアゾール缶に防除組成物を充填した後、さらに噴射剤を充填し、エアゾール製品とする。噴射剤としては、例えば、液化石油ガス(LPG)、ジメチルエーテル(DME)、各種フルオロカーボン等の公知の噴射剤を用いることができる。本発明に使用する噴射剤の含有量は、エアゾール剤全体量に対し25〜60質量%である。
[Aerosol products]
When making the aerosol product using the control composition of the present invention, after filling a known aerosol can with the control composition, it is further filled with a propellant to obtain an aerosol product. As a propellant, well-known propellants, such as liquefied petroleum gas (LPG), dimethyl ether (DME), various fluorocarbons, can be used, for example. Content of the propellant used for this invention is 25-60 mass% with respect to the aerosol agent whole quantity.
(任意成分)
本発明の防除組成物は、必要に応じて、他の殺虫剤、補助溶剤、忌避剤、殺菌剤、消臭剤、芳香剤等を配合してもよい。
(Optional component)
The pest control composition of the present invention may contain other insecticides, co-solvents, repellents, bactericides, deodorants, fragrances and the like as necessary.
補助溶剤としては、モノラウリン酸ソルビタン、モノオレイン酸ポリオキシエチレンソルビタンなどの脂肪酸エステルをはじめとする界面活性剤、アルコール類、ラベンダー油、ハッカ油、リモネン等を用いることができる。 As the auxiliary solvent, surfactants such as fatty acid esters such as sorbitan monolaurate and polyoxyethylene sorbitan monooleate, alcohols, lavender oil, peppermint oil, limonene and the like can be used.
〔対象害虫〕
本発明の防除組成物を用いて、スズメバチ類、アシナガバチ類、アリガタバチ類等のハチを防除が可能となる。また、以下の害虫にも有効である。
鱗翅目害虫:ノシメマダラメイガ(Plodia interpunctella)等の
メイガ類、イガ(Tinea translucens)、コイガ(Tineola b
isselliella)等のヒロズコガ類等
双翅目害虫:アカイエカ(Culex pipiens pallens)、コガタアカ
イエカ(Culex tritaeniorhynchus)、ネッタイイエカ(Cul
ex quinquefasciatus)等のイエカ類、ネッタイシマカ(Aedes
aegypti)、ヒトスジシマカ(Aedes albopictus)等のエーデ
ス属、シナハマダラカ(Anopheles sinensis)等のアノフェレス属、
ユスリカ類、イエバエ(Musca domestica)、オオイエバエ(Musci
na stabulans)等のイエバエ類、クロバエ類、ニクバエ類、ヒメイエバエ類
、タネバエ(Delia platura)、タマネギバエ(Delia antiqu
a)等のハナバエ類、ショウジョウバエ類、オオキモンノミバエ(Megaselia spiracularis)等のノミバエ類、オオチョウバエ(Clogmia alb
ipunctata)等のチョウバエ類、クロバネキノコバエ類、ブユ類、ヌカカ類等。
網翅目害虫:チャバネゴキブリ(Blattella germanica)、クロゴキ
ブリ(Periplaneta fuliginosa)、ワモンゴキブリ(Perip
laneta americana)、トビイロゴキブリ(Periplaneta b
runnea)、トウヨウゴキブリ(Blatta orientalis)等。
膜翅目害虫:イエヒメアリ(Monomorium pharaosis)、クロヤマア
リ(Formica fusca japonica)、ルリアリ(Ochetellu
s glaber)、アミメアリ(Pristomyrmex pungens)、オオ
ズアリ(Pheidole noda)、ハキリアリ(Acromyrmex spp.
)、ファイヤーアント(Solenopsis spp.)、アルゼンチンアリ(Lin
epithema humile)等のアリ類。
隠翅目害虫:ネコノミ(Ctenocephalides felis),イヌノミ(C
tenocephalides canis),ヒトノミ(Pulex irritan
s),ケオプスネズミノミ(Xenopsylla cheopis)等。
シラミ目害虫:コロモジラミ(Pediculus humanus corporis
),アタマジラミ(Pediculus humanus humanus)、ケジラミ
(Phthirus pubis),ウシジラミ(Haematopinus eur
ysternus),ヒツジジラミ(Dalmalinia ovis),ブタジラミ(
Haematopinus suis)、イヌジラミ(Linognathus set
osus)等。
等翅目害虫:ヤマトシロアリ(Reticulitermes speratus),イ
エシロアリ(Coptotermes formosanus)、アメリカカンザイシロアリ(Incisitermes マイナー)、ダイコクシロアリ(Cryptotermes domesticus)、タイワンシロアリ(Odontotermes formosanus)、コウシュンシロアリ(Neotermes koshunensis)、サツマシロアリ(Glyptotermes satsumensis)、ナカジマシロアリ(Glyptotermes nakajimai)、カタンシロアリ(Glyptotermes fuscus)、コダマシロアリ(Glyptotermes kodamai)、クシモトシロアリ(Glyptotermes kushimensis)、オオシロアリ(Hodotermopsis japonica)、コウシュウイエシロアリ(Coptotermes guangzhoensis)、アマミシロアリ(Reticulitermes miyatakei)、キアシシロアリ(Reticulitermes flaviceps amamianus)、カンモンシロアリ(Reticulitermes SP.)、タカサゴシロアリ(Nasutitermes takasagoensis)、ニトベシロアリ(Pericapriterme nitobei)、ムシャシロアリ(Sinocapritermes mushae)トウ
半翅目害虫:ヒメトビウンカ(Laodelphax striatellus)、トビ
イロウンカ(Nilaparvata lugens)、セジロウンカ(Sogatel
la furcifera)等のウンカ類、ツマグロヨコバイ(Nephotettix
cincticeps)、タイワンツマグロヨコバイ(Nephotettix vi
rescens)等のヨコバイ類、トコジラミ(Cimex lectularius)
、タイワントコジラミ(Cimex hemipterus)等のトコジラミ類、キジラ
ミ類等
鞘翅目害虫:ヒメマルカツオブシムシ(Anthrenus verbasci)、ハラ
ジロカツオブシムシ(Dermestes maculates)等のカツオブシムシ類
、タバコシバンムシ(Lasioderma serricorne)等のシバンムシ類
、ヒラタキクイムシ(Lyctus brunneus)、マツノキクイムシ(Tomi
cus piniperda)等のキクイムシ類、ナガシンクイムシ類、ヒョウホンムシ
類等
ダニ目害虫:ケナガコナダニ(Tyrophagus putrescentiae)等のコナダニ類、コナヒョウヒダニ(Dermatophagoides farinae)、ヤケヒョウヒダニ(Dermatophagoides ptrenyssnus)等のヒョウヒダニ類、ホソツメダニ(Cheyletus eruditus)、クワガタツメダニ(Cheyletus malaccensis)、ミナミツメダニ(Cheyletus moorei)、イヌツメダニ(Cheyletiella yasguri)等のツメダニ類、アオツツガムシ(Leptotrombidium akamushi)等のツツガムシ類、フタトゲチマダニ(Haemaphysalis longicornis)、等のマダニ類
ワラジムシ類:ワラジムシ(Porcellio scaber)、ホソワラジムシ(Porcellionides pruinosus)、オカダンゴムシ(Armadillidium vulgare)等
ムカデ類:トビズムカデ(Scolopendra subspinipes mutilans)、アオズムカデ(Scolopendra subspinipes japonica)、アカズムカデ(Scolopendra subspinipes multidens)、ゲジ(Thereuopoda hilgendorfi)等
ヤスデ類:ヤケヤスデ(Oxidus gracilis)、オビババヤスデ(Parafontaria laminata laminata)等
クモ類:カバキコマチグモ(Chiracanthium japonicum)、セアカゴケグモ(Latrodectus hasseltii)等
[Target pest]
By using the control composition of the present invention, it is possible to control bees such as wasps, wasps, and scallops. It is also effective against the following pests.
Lepidopterous pests: Japanese medusa such as Plodia interpuntella, iga (Tinea translucens), Japanese moth (Tineola b)
dipteran pests such as mossellella, etc .: Culex pipiens pallens, Culex triaeenorhynchus, Cyprus squid
ex quinquefasciatus), Aedesika (Aedes)
aegypti), Aedes genus such as Aedes albopictus, Anopheles genus such as Anopheles sinensis,
Chironomidae, Musca domestica, Musci (Musci)
house flies such as na stabulans, fly flies, fungi, flies flies, Delia platera, onion flies (Delia antiqu)
a) and other flies, Drosophila, flea flies such as Megaselia spiracularis, Clogmia alb
butterfly species such as ipuncta), black-winged mushroom flies, flyfish, nukaka and the like.
Reticulate pests: German cockroach (Blatella germanica), Black cockroach (Periplaneta fuliginosa), American cockroach (Perip
laneta americana), Periplaneta b
runnea), Blattella orientalis, and the like.
Hymenoptera: Monomorium phalaosis, Black ant (Formica fusca japonica), Luritari (Ochetellu)
s graver, Prismmyrmex pungens, Pazule noda, Hachiriary (Achromylmex spp.).
), Fire Ant (Solenopsis spp.), Argentine Ali (Lin)
ants such as epithema humile).
Lepidoptera: Cat fleas (Ctenocephalides felis), Dog fleas (C
tenocephalides canis), human flea (Pulex irritan)
s), Xenopsilla cheope and the like.
Lice eye pests: Pediculus humanus corporis
), Head lice (Pediculus humanus humanus), pheasant lice (Phythrus pubis), bovine lice (Haematopinus eur)
ysternus), sheep lice (Dalmalinia ovis), pig lice (
Haematopinus suis, dog lice (Linognathus set)
osus) and the like.
Coleopterous pests: Reticulitermes speratus, Termite (Copttotermes formosanus), American termite (Incitermes minor), Cyptotermes domesticus (Glypoptermes satsumensis), Nakajima Termite (Glyptotermes nakajimai), Caterpillar Termites (Glyptotermes fuscus), Gyptotermes kodamai, Teresa pylori es kushimensis), giant termite (Hodotermopsis japonica), Kou Shu Ye termite (Coptotermes guangzhoensis), Amami termites (Reticulitermes miyatakei), R. flavipes (Reticulitermes flaviceps amamianus), Kang Mont termites (Reticulitermes SP.), Takasago termite (Nasutitermes takasagoensis), Nitobe Termite (Pericapriterme nitobei), Musca termite (Sinocapritermes mushae) Hemiptera: Pteridomyceae (Laododelfax striatellus), Green planthopper (N ilaparvata lugens), white-spotted planthopper (Sogatel)
leafhoppers such as la furcifera, Nephotettix
cinchticeps), Newanettix vi
leafhoppers such as rescens) and bed bugs (Cimex electrarius)
Larvae such as Colex hemipterus, Coleoptera such as pheasants: Anthrenus verbasci, der L ass, and dermis ass Bark beetle (Lyctus bruneus), pine bark beetle (Tomi)
cus piniperda) bark beetles such as, Naga Shinkuimushi such, Hyouhonmushi, etc. Acarina pests: Tyrophagus (Tyrophagus putrescentiae) grain mites such as, farinae (Dermatophagoides farinae), house dust mite such as pteronyssinus (Dermatophagoides ptrenyssnus), Hosotsumedani (Cheyletus eruditus ), Crawfish tick mites (Cheeletus malaccensis), tick mites (Cheeletus moorei), crested ticks (Cheeletiella yasguri), and the like, Ticks (Haemaphysalis longicornis), ticks etc. Isopoda: sow bugs (Porcellio scaber), bombardier sow bugs (Porcellionides pruinosus), Oka pill bugs (Armadillidium vulgare), etc. centipede class: Tobizumukade (Scolopendra subspinipes mutilans), Aozumukade (Scolopendra subspinipes japonica), Millipedes such as Scorpendra subspinipes multidens, Theopododa hilgendorfi: Oxidus gracilis, Parafontarala la inata laminata), etc. Spiders: Kabakikomachigumo (Chiracanthium japonicum), redback spider (Latrodectus hasseltii), etc.
〔害虫の防除方法〕
本発明のエアゾール製品を対象となる害虫に直接噴霧すればよい。
本発明の防除組成物を用いたエアゾール製品でハチを防除する場合、例えば、噴射量9g/秒以上16g/秒以下で噴霧すればよい。
また、本発明の防除組成物をあらかじめ住宅の玄関、軒下、ベランダ等に噴霧しておくと、例えば、ハチが接近することを予防するためにも利用することができる。
[Pest Control Methods]
The aerosol product of the present invention may be sprayed directly on the target pests.
When bees are controlled with an aerosol product using the control composition of the present invention, for example, spraying may be performed at an injection amount of 9 g / second to 16 g / second.
Moreover, if the control composition of the present invention is sprayed in advance on the entrance, under the eaves, or the veranda of a house, it can be used to prevent, for example, the approach of bees.
以下、実施例により本発明を具体的に説明するが、本発明はこれらの実施例によって限定されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention concretely, this invention is not limited by these Examples.
表1(単位は質量%)に記載の処方に従い、常温で噴射剤以外の成分を混合した後、エアゾール缶に充填し、さらに噴射剤をエアゾール缶に充填し、ハチ用エアゾール製品を作製した。
なお、エアゾール用資材は以下のものを使用した。
缶:AE480WON WD/WN WN GD 東洋製缶製
バルブ: ステム孔:φ1.2×3 ハウジング孔:φ2.0 ベーパ―タップ無し 丸一製
ボタン: 噴口径:φ2.3mm 東洋エアゾール工業製
In accordance with the formulation described in Table 1 (unit: mass%), components other than the propellant were mixed at room temperature, and then filled into an aerosol can, and the propellant was further filled into an aerosol can to produce a bee aerosol product.
The following materials were used for the aerosol.
Can: AE480WON WD / WN WN GD Toyo made valve: Stem hole: φ1.2 × 3 Housing hole: φ2.0 No vapor-tap Maruichi button: Injection hole diameter: φ2.3mm Toyo Aerosol
n-パラフィン:ネオチオゾール、三井化学工業(株)製
iso-パラフィン: アイソパーG、エクソン・モービル社製
モノラウリン酸ソルビタン: NIKKOL SL-10、日光ケミカルズ株式会社製
モノオレイン酸ポリオキシエチレンソルビタン(20E.O.):NIKKOL TO-10V、日光ケミカルズ株式会社製
n-paraffin: Neothiozole, manufactured by Mitsui Chemicals, Inc.
iso-paraffin: Isopar G, Exoron-Mobil sorbitan monolaurate: NIKKOL SL-10, Nikko Chemicals monooleic acid polyoxyethylene sorbitan (20E.O.): NIKKOL TO-10V, Nikko Chemicals
[効力試験]
表1で作成したエアゾール処方に従いエアゾール製品を作成し、以下の試験を行った。
[Efficacy test]
An aerosol product was prepared according to the aerosol formulation prepared in Table 1, and the following tests were performed.
[試験サンプルの作成]
(1) 15cm×15cm×3mmのガラス板にエアゾールを2g相当噴霧した。
(2) 温室(直接風雨に曝されず、日中の日光には曝される)に設置した。
(3) 21日間日光下に曝したものを評価サンプルとした。
[Creation of test sample]
(1) 2 g of aerosol was sprayed onto a 15 cm × 15 cm × 3 mm glass plate.
(2) Installed in a greenhouse (not directly exposed to wind and rain but exposed to sunlight during the day).
(3) Samples exposed to sunlight for 21 days were used as evaluation samples.
[効力試験]
(1) 供試虫として、セイヨウミツバチ10頭をSUS製のザル(外径13cmm、高さ5cm、16メッシュ)に入れた。
(2) ザルの上に、防除組成物を処理した面を下にして評価サンプルを置き、クリップで固定した。
(3) クリップで試験サンプルを固定した時点を試験開始とし、30分後の苦死虫数をカウントした。
(4) 苦死虫数をカウントし、苦死虫率を求めた。
(5) これら試験を1反復行い、効力を確認した。
[Efficacy test]
(1) As test insects, 10 honey bees were placed in a SUS monkey (outer diameter 13 cm, height 5 cm, 16 mesh).
(2) On the monkey, the evaluation sample was placed with the surface treated with the control composition facing down, and fixed with a clip.
(3) The test was started at the time when the test sample was fixed with the clip, and the number of moribund insects after 30 minutes was counted.
(4) The number of moribund insects was counted to determine the mortality rate.
(5) These tests were repeated once to confirm the efficacy.
表2に試験結果を示す。
以上説明したように、本発明に係る害虫防除組成物は、優れた殺虫効力を示す。
As described above, the pest control composition according to the present invention exhibits excellent insecticidal efficacy.
Claims (4)
A method for controlling bees using the aerosol product according to claim 3.
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