JP2019151567A - Mist cosmetic - Google Patents
Mist cosmetic Download PDFInfo
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- JP2019151567A JP2019151567A JP2018036442A JP2018036442A JP2019151567A JP 2019151567 A JP2019151567 A JP 2019151567A JP 2018036442 A JP2018036442 A JP 2018036442A JP 2018036442 A JP2018036442 A JP 2018036442A JP 2019151567 A JP2019151567 A JP 2019151567A
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 46
- 239000003595 mist Substances 0.000 title claims abstract description 33
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 25
- 239000007921 spray Substances 0.000 claims abstract description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 claims description 3
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001035 drying Methods 0.000 abstract description 16
- 239000002245 particle Substances 0.000 description 8
- 238000005507 spraying Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002781 deodorant agent Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 230000001877 deodorizing effect Effects 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 230000035943 smell Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000010696 ester oil Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- 230000002688 persistence Effects 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003676 hair preparation Substances 0.000 description 2
- 239000000077 insect repellent Substances 0.000 description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
- 229940041616 menthol Drugs 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 239000003504 photosensitizing agent Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 229960001325 triclocarban Drugs 0.000 description 2
- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- IYLLULUTZPKQBW-UHFFFAOYSA-N Acrinol Chemical compound CC(O)C(O)=O.C1=C(N)C=CC2=C(N)C3=CC(OCC)=CC=C3N=C21 IYLLULUTZPKQBW-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000017788 Cydonia oblonga Nutrition 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- 102000016943 Muramidase Human genes 0.000 description 1
- 108010014251 Muramidase Proteins 0.000 description 1
- 108010062010 N-Acetylmuramoyl-L-alanine Amidase Proteins 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 1
- 229960001950 benzethonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229960003260 chlorhexidine Drugs 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ACGUYXCXAPNIKK-UHFFFAOYSA-N hexachlorophene Chemical compound OC1=C(Cl)C=C(Cl)C(Cl)=C1CC1=C(O)C(Cl)=CC(Cl)=C1Cl ACGUYXCXAPNIKK-UHFFFAOYSA-N 0.000 description 1
- 229960004068 hexachlorophene Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 239000004325 lysozyme Substances 0.000 description 1
- 235000010335 lysozyme Nutrition 0.000 description 1
- 229960000274 lysozyme Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- -1 oxyalkylene alkyl ether Chemical class 0.000 description 1
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- 229960003742 phenol Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229940081510 piroctone olamine Drugs 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- XZPFBBWPPPGSDO-UHFFFAOYSA-M sodium;n,n-dimethylprop-2-enamide;2-methyl-2-(prop-2-enoylamino)propane-1-sulfonate Chemical compound [Na+].CN(C)C(=O)C=C.[O-]S(=O)(=O)CC(C)(C)NC(=O)C=C XZPFBBWPPPGSDO-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、ミスト化粧料に関する。 The present invention relates to a mist cosmetic.
ミスト化粧料は、皮膚や毛髪等に必要な成分を均一に付着させる目的で使用される。例えば、両性樹脂とカチオン性樹脂と油分とアルコールと水とを含有し、ノンガスタイプの噴霧容器に充填する毛髪化粧料（特許文献１）、毛髪セット用ポリマー、液状のポリアルキレングリコール、固体のポリオキシアルキレンアルキルエーテル等、及び炭素数１４〜２０の脂肪族アルコールを含有する毛髪化粧料（特許文献２）、セルロース、アミノ酸等、油性成分及び水を含有する、霧状に噴霧して用いられるジェル状毛髪化粧料（特許文献３）が報告されている。これらは、両性樹脂・カチオン性樹脂、整髪セット用ポリマーや油性成分といった高粘度成分をミスト状に噴霧することにより毛髪に均一に付着させる化粧料である。
また、皮膚に適用するミスト化粧料としては、カチオン界面活性剤、ノニオン界面活性剤、水溶性無機塩及びアルコール０．５〜１５質量％を含有する液体皮膚清浄剤（特許文献４）、クインスシードエキス、カルボキシメチルセルロース、Ｎ，Ｎ−ジメチルアクリルアミド−２−アクリルアミド−２−メチルプロパンスルホン酸ナトリウム共重合体を含有し、口径がφ０．２５ｍｍ〜φ０．５５ｍｍであるポンプ式スプレー容器に充填されたミスト化粧料（特許文献５）が報告されている。
Mist cosmetics are used for the purpose of uniformly attaching necessary components to the skin and hair. For example, hair cosmetics (patent document 1) containing amphoteric resins, cationic resins, oils, alcohols and water and filled in non-gas type spray containers, polymers for hair setting, liquid polyalkylene glycols, solid poly Hair cosmetics containing an oxyalkylene alkyl ether and the like and an aliphatic alcohol having 14 to 20 carbon atoms (Patent Document 2), cellulose, amino acids and the like, oily components and water, and a gel used by spraying in a mist form A hair-like cosmetic (Patent Document 3) has been reported. These are cosmetics that uniformly adhere to the hair by spraying a high viscosity component such as an amphoteric resin / cationic resin, a hairdressing set polymer or an oily component in a mist form.
Moreover, as mist cosmetics applied to the skin, a liquid skin cleanser containing a cationic surfactant, a nonionic surfactant, a water-soluble inorganic salt and an alcohol of 0.5 to 15% by mass (Patent Document 4), quince seed Mist filled with a pump spray container containing an extract, carboxymethylcellulose, sodium N, N-dimethylacrylamide-2-acrylamido-2-methylpropanesulfonate, and having a diameter of φ0.25 mm to φ0.55 mm Cosmetics (Patent Document 5) have been reported.
しかしながら、特許文献４及び５の化粧料は、いずれも皮膚上に洗浄成分や保湿成分を液状で付着させるミスト化粧料であって、皮膚に適用後速やかに乾燥させることを目的としているものではない。従来のミスト化粧料においては、皮膚に噴霧されたミストの乾燥が速やかでない場合、皮膚上の有効成分が衣類などの被覆物に転写してしまい効果が減少してしまうことが指摘されている。
そこで本発明の課題は、皮膚等へミストを適用後速やかに乾燥し、かつ皮膚等の上に抗菌成分を保持させることのできるミスト化粧料を提供することにある。
However, the cosmetics of Patent Documents 4 and 5 are both mist cosmetics in which a cleaning component and a moisturizing component are attached in liquid form on the skin, and are not intended to be dried quickly after application to the skin. . In conventional mist cosmetics, it has been pointed out that when the mist sprayed on the skin is not quickly dried, the active ingredient on the skin is transferred to a coating such as clothing and the effect is reduced.
Accordingly, an object of the present invention is to provide a mist cosmetic that can be dried quickly after application of mist to the skin and the like and can retain an antibacterial component on the skin and the like.
本発明者は、前記課題を解決すべく種々検討した結果、エタノール３０質量％以上、抗菌成分及び水を含有する組成物を、ノズル口径が０．５ｍｍ以下であるノンガスタイプのポンプ式噴霧容器に充填したミスト化粧料とすれば、皮膚等に噴霧した時にミストを広範囲の対象面に均一に適用することができ、速やかに乾燥することにより、抗菌成分が皮膚等の対象部位から衣類などの皮膚への接触物へ転写することを抑制できるため、対象部位に付着し優れた抗菌成分の残留性、抗菌効果、使用感が得られることを見出し、本発明を完成した。 As a result of various studies to solve the above problems, the present inventor applied a composition containing 30% by mass or more of ethanol, an antibacterial component and water to a non-gas type pump type spray container having a nozzle diameter of 0.5 mm or less. If the mist cosmetic is filled, the mist can be uniformly applied to a wide range of target surfaces when sprayed on the skin, etc., and quickly dry, so that antibacterial components can be removed from the target site such as the skin such as clothing. As a result, it was found that excellent antibacterial component persistence, antibacterial effect, and feeling of use can be obtained by adhering to the target site.
すなわち、本発明は、エタノール３０質量％以上、抗菌成分及び水を含有し、ノズル口径が０．５ｍｍ以下であるノンガスタイプのポンプ式噴霧容器に充填されていることを特徴とするミスト化粧料を提供するものである。 That is, the present invention provides a mist cosmetic containing 30% by mass or more of ethanol, an antibacterial component and water, and filled in a non-gas type pump type spray container having a nozzle diameter of 0.5 mm or less. It is to provide.
本発明のミスト化粧料を用いれば、ミストを広範囲の皮膚等の対象部位に均一に適用することができ、適用されたミストが速やかに乾燥することにより、適用部に抗菌成分が十分量残存し、さわやかな使用感と優れた抗菌効果が得られる。また、本発明のミスト化粧料を用いれば、皮膚等の対象部位へ適用後速やかに乾燥するため、適用後に対象部位と接触する衣類等への転写が低減され、抗菌成分等の薬剤の効果が減少しない。 If the mist cosmetic of the present invention is used, the mist can be uniformly applied to a target site such as a wide range of skin, and the applied mist dries quickly, so that a sufficient amount of antibacterial components remain in the application part. A refreshing feel and an excellent antibacterial effect can be obtained. In addition, if the mist cosmetic of the present invention is used, it dries quickly after application to the target site such as skin, so transfer to clothing etc. that comes into contact with the target site after application is reduced, and the effects of drugs such as antibacterial components are effective. Does not decrease.
本発明のミスト化粧料は、エタノール３０質量％以上、抗菌成分及び水を含有する。 The mist cosmetic of the present invention contains 30% by mass or more of ethanol, an antibacterial component and water.
本発明の化粧料において、エタノールは、化粧料の媒体、清涼感付与、速乾性向上及び殺菌の目的で用いられる。
本発明の化粧料中のエタノールの含有量は、清涼感付与、速乾性向上の観点から、３０質量％以上である。清涼感付与、速乾性向上の観点から３０質量％以上含まれるが、４０質量％以上が好ましく、４５質量％以上がより好ましく、５０質量％以上がさらに好ましく、６０質量％以上がよりさらに好ましい。また、皮膚がかさつかない等の感触の観点から、９０質量％以下が好ましく、８５質量％以下がより好ましく、８３質量％以下がさらに好ましく、８０質量％以下がよりさらに好ましい。具体的には、３０質量％以上９０質量％以下が好ましく、４０質量％以上８５質量％以下がより好ましく、４５質量％以上８５質量％以下がさらに好ましく、５０質量％以上８３質量％以下がさらに好ましく、６０質量％以上８０質量％以下がよりさらに好ましい。
In the cosmetic of the present invention, ethanol is used for the purpose of cosmetic medium, imparting a refreshing feeling, improving quick drying, and sterilizing.
The content of ethanol in the cosmetic of the present invention is 30% by mass or more from the viewpoint of imparting a refreshing feeling and improving quick drying. 30 mass% or more is contained from a viewpoint of a refreshing feeling provision and quick-drying improvement, but 40 mass% or more is preferable, 45 mass% or more is more preferable, 50 mass% or more is further more preferable, and 60 mass% or more is further more preferable. In addition, from the viewpoint of feel such that the skin is not soft, it is preferably 90% by mass or less, more preferably 85% by mass or less, further preferably 83% by mass or less, and still more preferably 80% by mass or less. Specifically, it is preferably 30% by mass or more and 90% by mass or less, more preferably 40% by mass or more and 85% by mass or less, further preferably 45% by mass or more and 85% by mass or less, and further preferably 50% by mass or more and 83% by mass or less. Preferably, 60 mass% or more and 80 mass% or less are more preferable.
本発明の化粧料は、抗菌成分を含有する。抗菌成分は、化粧料適用皮膚等に抗菌作用を付与する目的で用いられる。
抗菌成分としては、イソプロピルメチルフェノール、塩化ベンザルコニウム、トリクロサン、ピロクトンオラミン、塩化ベンゼトニウム、塩化アルキルトリメチルアンモニウム、臭化セチルトリメチルアンモニウム、トリクロカルバン、サリチル酸、パラベン、クロルヘキシジン又はその塩、リゾチーム又はその塩、アクリノール、グルコン酸、アルキルジアミノグリシン又はその塩、ポピドンヨード、ヨウ化カリウム、ヨウ素、クレゾール、感光素１０１号、感光素２０１号、フェノキシエタノール、１，２−ペンタンジオール、ハロカルバン、３，４，４−トリクロロカルバニリド、トリエチルシトレート、レゾルシン、フェノール、ソルビン酸、ヘキサクロロフェン、銀担持ゼオライト、銀担持シリカが挙げられる。
これらの抗菌成分のうち、抗菌効果、防臭効果の観点から、イソプロピルメチルフェノールが好ましい。
The cosmetic of the present invention contains an antibacterial component. The antibacterial component is used for the purpose of imparting an antibacterial action to skin to which cosmetics are applied.
Antibacterial components include isopropylmethylphenol, benzalkonium chloride, triclosan, piroctone olamine, benzethonium chloride, alkyltrimethylammonium chloride, cetyltrimethylammonium bromide, triclocarban, salicylic acid, paraben, chlorhexidine or a salt thereof, lysozyme or a salt thereof Salt, acrinol, gluconic acid, alkyldiaminoglycine or a salt thereof, popidone iodine, potassium iodide, iodine, cresol, photosensitizer 101, photosensitizer 201, phenoxyethanol, 1,2-pentanediol, halocarbane, 3,4, Examples thereof include 4-trichlorocarbanilide, triethyl citrate, resorcin, phenol, sorbic acid, hexachlorophene, silver-supported zeolite, and silver-supported silica.
Of these antibacterial components, isopropylmethylphenol is preferred from the viewpoint of antibacterial effect and deodorizing effect.
本発明の化粧料中の抗菌成分の含有量は、抗菌効果、消臭効果、皮膚上での残留性、使用感の観点から、０．０１質量％以上が好ましく、より好ましくは０．０２質量％以上であり、さらに好ましくは０．０５質量％以上であり、また、０．２質量％以下が好ましく、より好ましくは０．１５質量％以下であり、さらに好ましくは０．１０質量％以下である。抗菌成分の好ましい含有量の範囲は、０．０１質量％以上０．２質量％以下であり、より好ましくは０．０２質量％以上０．１５質量％以下であり、さらに好ましくは０．０５質量％以上０．１０質量％以下である。 The content of the antibacterial component in the cosmetic of the present invention is preferably 0.01% by mass or more, more preferably 0.02% by mass, from the viewpoints of the antibacterial effect, the deodorizing effect, the persistence on the skin, and the feeling of use. % Or more, more preferably 0.05% by mass or more, and preferably 0.2% by mass or less, more preferably 0.15% by mass or less, and further preferably 0.10% by mass or less. is there. The range of the preferable content of the antibacterial component is 0.01% by mass or more and 0.2% by mass or less, more preferably 0.02% by mass or more and 0.15% by mass or less, and further preferably 0.05% by mass. % Or more and 0.10% by mass or less.
本発明の化粧料は、水を含有する。水は、抗菌成分の媒体として機能する。本発明化粧料中の水の含有量は、抗菌成分を溶解できる量以上であればよく、０．１質量％以上６９質量％以下が好ましく、１５質量％以上５０質量％以下がより好ましく、２０質量％以上４０質量％以下がさらに好ましい。 The cosmetic of the present invention contains water. Water functions as a medium for antimicrobial components. The water content in the cosmetic composition of the present invention may be at least an amount capable of dissolving the antibacterial component, preferably 0.1% by mass or more and 69% by mass or less, more preferably 15% by mass or more and 50% by mass or less, and 20 More preferably, it is at least 40% by mass.
本発明の化粧料には、前記成分の他、メントール、液体油、１，３−ブチレングリコール、グリセリン、ノニオン界面活性剤、カルボン酸又はその塩、水溶性高分子、虫よけ成分、保湿成分、香料等を含有させることができる。本発明において、制汗剤は配合してもしなくても問題ないが、配合しない方が成分（Ａ）の皮膚への残留性、使用感の点からより好ましい。
メントールの含有量は、冷感付与の観点から、０．００５質量％以上１質量％以下が好ましく、０．０５質量％以上０．８質量％以下がより好ましい。また、液体油としては、２５℃で液体状の油が好ましく、炭化水素油、エステル油、エーテル油が好ましく、エステル油がより好ましい。エステル油としてはジカプリン酸ネオペンチルグリコール等のジ脂肪酸グリコールがより好ましい。液体油の含有量は、０．０１質量％以上０．０９質量％以下が好ましい。
The cosmetic of the present invention includes menthol, liquid oil, 1,3-butylene glycol, glycerin, nonionic surfactant, carboxylic acid or salt thereof, water-soluble polymer, insect repellent component, moisturizing component, in addition to the above components. , Fragrances and the like can be included. In the present invention, there is no problem whether or not the antiperspirant is blended, but it is more preferable not to blend it from the viewpoint of the persistence of the component (A) on the skin and the feeling of use.
The content of menthol is preferably 0.005% by mass or more and 1% by mass or less, and more preferably 0.05% by mass or more and 0.8% by mass or less from the viewpoint of imparting a cool feeling. The liquid oil is preferably a liquid oil at 25 ° C., preferably a hydrocarbon oil, an ester oil, or an ether oil, and more preferably an ester oil. As the ester oil, difatty acid glycol such as neopentyl glycol dicaprate is more preferable. The content of the liquid oil is preferably 0.01% by mass or more and 0.09% by mass or less.
本発明の化粧料は、ノズル口径が０．５ｍｍ以下であるノンガスタイプのポンプ式噴霧容器に充填されているミスト化粧料である。 The cosmetic of the present invention is a mist cosmetic filled in a non-gas type pump spray container having a nozzle diameter of 0.5 mm or less.
本発明の化粧料が充填されている噴霧容器は、液化石油ガス等のガスエアゾール式ではない。当該噴霧容器としては、ディスペンサー、エアスプレー（空気を圧縮する高圧式容器）、ゴム弾性利用の噴霧容器、電動スプレー、手動アトマイザー等が利用できる。本発明に用いる噴霧容器においては、化粧料をミスト状に噴霧して、速乾性を得る点からノズル口径（直径）は０．５ｍｍ以下である。噴霧されたミストの速乾性の観点からより好ましいノズル口径は０．４ｍｍ以下であり、より好ましくは０．３ｍｍ以下であり、さらに好ましくは、０．２ｍｍ以下である。また、ノズル径の下限は噴霧性の点から０．０５ｍｍ以上が好ましい。 The spray container filled with the cosmetic of the present invention is not a gas aerosol type such as liquefied petroleum gas. As the spray container, a dispenser, an air spray (a high-pressure container that compresses air), a rubber elastic spray container, an electric spray, a manual atomizer, or the like can be used. In the spray container used in the present invention, the nozzle diameter (diameter) is 0.5 mm or less from the viewpoint that the cosmetic is sprayed in a mist form to obtain quick drying. From the viewpoint of quick drying of the sprayed mist, the nozzle diameter is more preferably 0.4 mm or less, more preferably 0.3 mm or less, and still more preferably 0.2 mm or less. The lower limit of the nozzle diameter is preferably 0.05 mm or more from the viewpoint of sprayability.
本発明のミスト化粧料の噴霧容器は、適用部位での速乾性の点から、噴射口から噴射方向に１０ｃｍ離れた地点における噴霧液滴の平均粒径が４０〜５５μｍとなる噴射手段とするのが好ましい。噴霧液滴の粒径分布は、例えばレーザー回折式粒度分布計（ＳＹＭＰＡＴＥＣ ＨＥＬＯＳ ＆ ＲＯＤＯＳ ＪＥＯＬ．Ｌｔｄ社製）により測定することができる。 The spray container for mist cosmetics of the present invention is a spray means in which the average particle diameter of spray droplets at a point 10 cm away from the spray port in the spraying direction is 40 to 55 μm from the viewpoint of quick drying at the application site. Is preferred. The particle size distribution of the spray droplets can be measured by, for example, a laser diffraction particle size distribution meter (manufactured by SYMPATEC HELOS & RODOS JEOL. Ltd.).
本発明の化粧料は、皮膚化粧料、さらに皮膚に清涼感を付与する化粧料、デオドラント剤、保湿剤、虫よけ剤として用いるのが好ましく、デオドラント剤として用いるのがより好ましい。
特に皮膚に適用した場合には、体の前面、腕全体、背中、脇から脇腹、頭、足、脚等の広い範囲に均一にミストを適用でき、かつそのミストは速やかに乾燥し、かつ抗菌剤が皮膚上に残存するため、速乾性、清涼感、デオドラント効果に優れたデオドラント剤として有用である。
The cosmetic of the present invention is preferably used as a skin cosmetic, a cosmetic that imparts a refreshing feeling to the skin, a deodorant agent, a moisturizing agent, and an insect repellent, and more preferably used as a deodorant agent.
In particular, when applied to the skin, the mist can be applied uniformly over a wide area such as the front of the body, the entire arm, back, side to flank, head, feet, legs, etc., and the mist will dry quickly and be antibacterial. Since the agent remains on the skin, it is useful as a deodorant agent that is excellent in quick drying, refreshing feeling, and deodorant effect.
次に実施例を挙げて本発明を更に詳細に説明する。 EXAMPLES Next, an Example is given and this invention is demonstrated still in detail.
実施例１〜５及び比較例１〜２
表１に示す組成のデオドラント剤を、ノズルを有するポンプ式噴霧容器に充填して、化粧料を製造した。得られた化粧料を０．１ｇ噴霧した際の各化粧料の速乾性、噴霧時の平均粒径、及び噴霧後に衣類を着用した場合の防臭効果を評価した。
Examples 1-5 and Comparative Examples 1-2
The deodorant agent having the composition shown in Table 1 was filled in a pump-type spray container having a nozzle to produce a cosmetic. The quick-drying property of each cosmetic when 0.1 g of the resulting cosmetic was sprayed, the average particle size during spraying, and the deodorizing effect when clothing was worn after spraying were evaluated.
（速乾性の評価）
１０名の被験者（専門パネラー）が、各化粧料を手の甲に１回噴霧（約０．１ｇ）し、噴霧直後の速乾感を、下記の基準で評価した。結果を１０名の平均値で表１に示した。
＜評価基準＞
速乾感強度５：とても早く感じる。（塗布直後に乾燥したことを感じる）
速乾感強度４：早く感じる。（塗布後１秒以内に乾燥したことを感じる）
速乾感強度３：やや早く感じる。（塗布後３秒以内に乾燥したことを感じる）
速乾感強度２：やや遅く感じる。（塗布後５秒以内に乾燥したことを感じる）
速乾感強度１：遅く感じる。（塗布後、乾燥までに５秒以上かかると感じる）
(Evaluation of quick drying)
Ten subjects (special panelists) sprayed each cosmetic on the back of the hand once (about 0.1 g), and the quick drying feeling immediately after the spraying was evaluated according to the following criteria. The results are shown in Table 1 as average values of 10 people.
<Evaluation criteria>
Quick-drying strength 5: Feels very fast. (I feel dry immediately after application)
Quick-drying strength 4: Feel fast. (I feel dry within 1 second after application)
Quick-drying strength 3: Feels a little faster. (I feel dry within 3 seconds after application)
Quick-drying strength 2: Feels a little slow. (I feel dry within 5 seconds after application)
Quick-drying strength 1: Feels slow. (I feel that it takes more than 5 seconds to dry after application)
（噴霧時の平均粒径の評価）
噴霧液滴の粒径（１．２〜１０２μｍ）の測定は、レーザー回折式粒子径分布測定装置（ＳＹＭＰＡＴＥＣ ＨＥＬＯＳ ＆ ＲＯＤＯＳ ＪＥＯＬ．Ｌｔｄ社製）で評価を行った。各化粧料をレーザーから１０ｃｍ離れた場所からレーザーに向かって１回噴霧（約０．１ｇ）した際の噴霧液滴の粒径（μｍ）を測定した。結果を表１に示した。
(Evaluation of average particle size during spraying)
The measurement of the particle size (1.2 to 102 μm) of the spray droplets was evaluated with a laser diffraction particle size distribution measuring apparatus (manufactured by SYMPATEC HELOS & RODOS JEOL. Ltd.). The particle size (μm) of the spray droplets when each cosmetic was sprayed once (about 0.1 g) toward the laser from a location 10 cm away from the laser was measured. The results are shown in Table 1.
（噴霧後に衣類を着用した場合の防臭効果の評価）
脇部を９５％エタノールで清拭後、各化粧料を脇部に１回噴霧（約０．１ｇ）し、１０秒後にＴシャツを着用し、その上に作業着を着用し、１０時間後の脇の匂いを専門評価者（ｎ＝１０）が、下記の基準で評価した。結果を１０名の平均値で示した。結果を表１に示した。
＜評価基準＞
５：全く匂わない。比較例１の匂いよりも匂いが大変弱くなっている。
４：匂わない。比較例１の匂いよりも匂いがやや弱くなっている。
３：どちらとも言えない。比較例１の場合の匂いと同じレベル。
２：やや匂う。比較例１の匂いよりも匂いがやや強くなっている。
１：匂う。比較例１の匂いよりも匂いが大変強くなっている。
(Evaluation of deodorizing effect when clothing is worn after spraying)
After wiping the side with 95% ethanol, spray each cosmetic on the side once (about 0.1 g), wear a T-shirt after 10 seconds, wear work clothes on it, and after 10 hours An expert evaluator (n = 10) evaluated the odor of the side of the scent by the following criteria. The result was shown by the average value of 10 persons. The results are shown in Table 1.
<Evaluation criteria>
5: Does not smell at all. The odor is much weaker than that of Comparative Example 1.
4: Does not smell. The odor is slightly weaker than the odor of Comparative Example 1.
3: I can't say either. The same level as the odor in Comparative Example 1.
2: It smells a little. The odor is slightly stronger than the odor of Comparative Example 1.
1: It smells. The odor is much stronger than that of Comparative Example 1.
Claims (5)
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| WO2023223839A1 (en) * | 2022-05-18 | 2023-11-23 | 株式会社 資生堂 | Sunscreen cosmetic |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001163752A (en) * | 1999-12-06 | 2001-06-19 | Lion Corp | Skin cosmetic |
| JP2001278777A (en) * | 2000-03-30 | 2001-10-10 | Kose Corp | Skin detergent |
| JP2015117239A (en) * | 2013-11-14 | 2015-06-25 | ライオン株式会社 | Antiperspirant composition |
| JP2015124169A (en) * | 2013-12-26 | 2015-07-06 | ライオン株式会社 | Bilayer type powder-containing cosmetic |
| WO2015146398A1 (en) * | 2014-03-26 | 2015-10-01 | 株式会社マンダム | Deodorant composition and deodorant agent |
| WO2015146590A1 (en) * | 2014-03-28 | 2015-10-01 | 株式会社マンダム | Deodorant or refreshing cosmetic material, and non-aerosol type spray product |
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001163752A (en) * | 1999-12-06 | 2001-06-19 | Lion Corp | Skin cosmetic |
| JP2001278777A (en) * | 2000-03-30 | 2001-10-10 | Kose Corp | Skin detergent |
| JP2015117239A (en) * | 2013-11-14 | 2015-06-25 | ライオン株式会社 | Antiperspirant composition |
| JP2015124169A (en) * | 2013-12-26 | 2015-07-06 | ライオン株式会社 | Bilayer type powder-containing cosmetic |
| WO2015146398A1 (en) * | 2014-03-26 | 2015-10-01 | 株式会社マンダム | Deodorant composition and deodorant agent |
| WO2015146590A1 (en) * | 2014-03-28 | 2015-10-01 | 株式会社マンダム | Deodorant or refreshing cosmetic material, and non-aerosol type spray product |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023223839A1 (en) * | 2022-05-18 | 2023-11-23 | 株式会社 資生堂 | Sunscreen cosmetic |
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