JP2019137642A - Oily solid hair cosmetics - Google Patents
Oily solid hair cosmetics Download PDFInfo
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- JP2019137642A JP2019137642A JP2018022835A JP2018022835A JP2019137642A JP 2019137642 A JP2019137642 A JP 2019137642A JP 2018022835 A JP2018022835 A JP 2018022835A JP 2018022835 A JP2018022835 A JP 2018022835A JP 2019137642 A JP2019137642 A JP 2019137642A
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- oily solid
- oils
- hair cosmetic
- solid hair
- hair
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- 239000007787 solid Substances 0.000 title claims abstract description 56
- 239000003676 hair preparation Substances 0.000 title abstract description 6
- 239000002537 cosmetic Substances 0.000 claims abstract description 42
- 239000003921 oil Substances 0.000 claims abstract description 31
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 10
- 239000000194 fatty acid Substances 0.000 claims abstract description 10
- 229930195729 fatty acid Natural products 0.000 claims abstract description 10
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 9
- 239000010696 ester oil Substances 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 abstract description 6
- 230000007547 defect Effects 0.000 abstract description 5
- 230000002688 persistence Effects 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 28
- 239000000203 mixture Substances 0.000 description 10
- 239000001993 wax Substances 0.000 description 10
- 238000002156 mixing Methods 0.000 description 8
- -1 sucrose fatty acid ester Chemical class 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 4
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 description 4
- 239000004166 Lanolin Chemical class 0.000 description 3
- 240000007594 Oryza sativa Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 235000019388 lanolin Nutrition 0.000 description 3
- 229940039717 lanolin Drugs 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000004200 microcrystalline wax Substances 0.000 description 3
- 235000019808 microcrystalline wax Nutrition 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- RKJGFHYCZPZJPE-UHFFFAOYSA-N 2,2-bis(16-methylheptadecanoyloxymethyl)butyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C RKJGFHYCZPZJPE-UHFFFAOYSA-N 0.000 description 2
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 2
- NCLNAHJFXIKYBY-UHFFFAOYSA-N 2-hexyldecyl 16-methylheptadecanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C NCLNAHJFXIKYBY-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
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- 238000000034 method Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229940062000 polyglyceryl-2 triisostearate Drugs 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- ICHWOIDNXFYVKZ-UHFFFAOYSA-N 1-(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CCC(OC(=O)CCCCCCCCCCCCCCC(C)C)OC(=O)CCCCCCCCCCCCCCC(C)C ICHWOIDNXFYVKZ-UHFFFAOYSA-N 0.000 description 1
- WAYINTBTZWQNSN-UHFFFAOYSA-N 11-methyldodecyl 3,5,5-trimethylhexanoate Chemical compound CC(C)CCCCCCCCCCOC(=O)CC(C)CC(C)(C)C WAYINTBTZWQNSN-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- ABEXEQSGABRUHS-UHFFFAOYSA-N 16-methylheptadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC(C)C ABEXEQSGABRUHS-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- BRORPGSJXSLXKN-UHFFFAOYSA-N 6-methylheptyl 3,5,5-trimethylhexanoate Chemical compound CC(C)CCCCCOC(=O)CC(C)CC(C)(C)C BRORPGSJXSLXKN-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 240000001548 Camellia japonica Species 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- LPGFSDGXTDNTCB-UHFFFAOYSA-N [3-(16-methylheptadecanoyloxy)-2,2-bis(16-methylheptadecanoyloxymethyl)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCC(C)C)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C LPGFSDGXTDNTCB-UHFFFAOYSA-N 0.000 description 1
- DRRMRHKHTQRWMB-UHFFFAOYSA-N [3-(2-ethylhexanoyloxy)-2,2-bis(2-ethylhexanoyloxymethyl)propyl] 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(COC(=O)C(CC)CCCC)(COC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DRRMRHKHTQRWMB-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- KQZNFGJQTPAURD-NBWQQBAWSA-N ascorbyl dipalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](OC(=O)CCCCCCCCCCCCCCC)[C@H]1OC(=O)C(O)=C1O KQZNFGJQTPAURD-NBWQQBAWSA-N 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000018597 common camellia Nutrition 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 229940060384 isostearyl isostearate Drugs 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- BPCXHCSZMTWUBW-UHFFFAOYSA-N triethoxy(1,1,2,2,3,3,4,4,5,5,8,8,8-tridecafluorooctyl)silane Chemical compound CCO[Si](OCC)(OCC)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCC(F)(F)F BPCXHCSZMTWUBW-UHFFFAOYSA-N 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は油性固形毛髪化粧料に関する。 The present invention relates to an oily solid hair cosmetic.
一般に油性固形化粧料としては、リップスティック、リップグロス、アイシャドウ、およびファンデーションなどのメイクアップ料が知られており、近年はヘアスタイルとしてまとめ髪が流行していることから、女性向けのオイルバームやヘアスティックなどの整髪料も市場に増えてきている。また、油性固形化粧料は、液状油および固形油を主骨格として構成され、使用時のなめらかさツヤ感などの化粧効果が得やすいといった特徴を持つ。 In general, makeup oils such as lipsticks, lip glosses, eye shadows, and foundations are known as oily solid cosmetics. In recent years, hair has become popular as a hairstyle. Hairdressing charges such as hair sticks are also increasing in the market. Oily solid cosmetics are composed of liquid oil and solid oil as a main skeleton, and have a feature that it is easy to obtain a cosmetic effect such as a smooth luster when used.
油性固形化粧料は型を用いて成型し、使用時には型から外す場合が多い。特に固形状の化粧料を得る場合は、金属や樹脂の型に化粧料を溶融して充填し、冷却して形状を整えたものを型から外し、化粧料容器に装着するものや、化粧料容器にそのまま溶融した化粧料を充填し、冷却して形状を整え成型するものがある。いずれの場合も、型を用いて成型し、型からはずす場合が多く、型や容器との離型性が悪いと、表面の剥がれや傷が生じ、外観が損なわれることが問題となっていた。 Oily solid cosmetics are often molded using a mold and removed from the mold when used. In particular, when obtaining a solid cosmetic, a metal or resin mold is melted and filled with a cosmetic, and after cooling and adjusting its shape, the mold is removed from the mold and attached to a cosmetic container. Some containers are filled with a melted cosmetic as it is, cooled and shaped to form. In either case, the mold is often molded and removed from the mold, and if the releasability from the mold or the container is poor, the surface may be peeled or scratched and the appearance may be impaired. .
このような課題を解決する発明として、例えば、ＨＬＢが１２以下のショ糖脂肪酸エステルを必須成分とし、紛体および油性成分を配合した油性固形化粧料では、塗布時ののびが良く、溶融充填性や保型性の低下を招くことなく、マットな質感を得られると記載されている（特許文献１）。また、特定のエステル化合物とトリデカフルオロオクチルトリエトキシシランで表面処理した紛体を用いた技術では、離型性が良く、使用時の滑らかな密着感・潤い感に優れると記載されている（特許文献２）。また、型との離型性が良く、外観の欠損に関する技術として、分岐鎖を持つ固形油および特定のエステル油などを用いる技術が挙げられる（特許文献３）。 As an invention for solving such a problem, for example, an oily solid cosmetic comprising an sucrose fatty acid ester having an HLB of 12 or less as an essential component and blended with a powder and an oily component has good spreading at the time of application, It is described that a matte texture can be obtained without incurring a decrease in mold retention (Patent Document 1). In addition, it is described that the technology using the powder surface-treated with a specific ester compound and tridecafluorooctyltriethoxysilane has good releasability and is excellent in smooth adhesion and moisture feeling during use (patent) Reference 2). Moreover, the technique using a solid oil with a branched chain, a specific ester oil, etc. is mentioned as a technique regarding the defect | deletion of an external appearance with the good mold release property (patent document 3).
このように、従来から多くの油性固形化粧料が提案されているが、毛髪に対する効果、特にスタイル持続性に関する効果はほとんど研究されていない。固形油としてワックスを配合することで、その持続効果が期待できるが、多量に配合すると容器との離型性は悪くなり、伸びが悪くなるといった懸念がある。毛髪に均一に塗布するために硬度を調節すると、高温安定性が低下し、持ち運びの際に剤が溶けてしまう可能性がある。本発明は上記したような従来技術の現状に鑑み、スタイル持続性が良く、容器との離型性に優れ、高温環境下における安定性が良好であり、塗布時の伸びが良い油性固形毛髪化粧料を提供することを目的とする。 As described above, many oily solid cosmetics have been proposed so far, but the effect on hair, particularly the effect on style sustainability, has hardly been studied. By blending wax as a solid oil, the sustaining effect can be expected. However, when blended in a large amount, there is a concern that the releasability from the container is deteriorated and the elongation is deteriorated. When the hardness is adjusted in order to uniformly apply to hair, the stability at high temperature is lowered, and the agent may be dissolved during carrying. In view of the current state of the prior art as described above, the present invention is an oil-based solid hair makeup with good style sustainability, excellent releasability from a container, good stability in a high temperature environment, and good elongation during application. The purpose is to provide a fee.
本発明者は上記課題を解決すべく、鋭意研究を重ねた結果、分岐鎖を持つワックス、分子量が２５０以上であって炭素１４以上の脂肪酸と分岐高級アルコールからなる２５℃で液状のエステル油、融点が７５℃以上の固形油を特定の配合量で含有する油性固形毛髪化粧
料が上記目的を達成できることを見出し、本発明を完成するに至った。
As a result of intensive studies to solve the above-mentioned problems, the present inventor has found that a wax having a branched chain, an ester oil having a molecular weight of 250 or more and consisting of a fatty acid having 14 or more carbon atoms and a branched higher alcohol at 25 ° C., The present inventors have found that an oily solid hair cosmetic containing a solid oil having a melting point of 75 ° C. or higher in a specific blending amount can achieve the above object, and has completed the present invention.
本願第一の発明は、下記成分（Ａ）〜（Ｃ）を含有することを特徴とする油性固形毛髪化粧料である。
（Ａ）分岐鎖を持つワックス
（Ｂ）分子量が２５０以上であって炭素１４以上の脂肪酸と分岐高級アルコールからなる
２５℃で液状のエステル油から選択される一種又は二種以上
（Ｃ）成分（Ａ）以外の固形油から選択される一種又は二種以上
1st invention of this application is an oil-based solid hair cosmetic characterized by containing the following component (A)-(C).
(A) a wax having a branched chain (B) a molecular weight of 250 or more, consisting of a fatty acid having 14 or more carbon atoms and a branched higher alcohol. One or more selected from solid oils other than A)
本願第二の発明は、油性固形毛髪化粧料に含まれる成分（Ａ）〜（Ｃ）の配合量が下記であることを特徴とする請求項１に記載の油性固形毛髪化粧料である。
（Ａ）分岐鎖を持つワックス 油性固形毛髪化粧料全量に対し２．０〜５．０質量％
（Ｂ）分子量が２５０以上であって炭素１４以上の脂肪酸と分岐高級アルコールからなる
２５℃で液状のエステル油から選択される一種又は二種以上
油性固形毛髪化粧料全量に対し１０．０〜１５．０質量％
（Ｃ）成分（Ａ）以外の固形油から選択される一種又は二種以上
油性固形毛髪化粧料全量に対し２０．０〜３０．０質量％
The second invention of the present application is the oily solid hair cosmetic according to claim 1, wherein the blending amounts of the components (A) to (C) contained in the oily solid hair cosmetic are as follows.
(A) Wax having a branched chain 2.0 to 5.0% by mass with respect to the total amount of the oily solid hair cosmetic
(B) One or two or more types selected from ester oils having a molecular weight of 250 or more and comprising a fatty acid having 14 or more carbon atoms and a branched higher alcohol at 25 ° C.
10.0-15.0% by mass based on the total amount of oily solid hair cosmetic
(C) One or more selected from solid oils other than component (A)
20.0-30.0% by mass based on the total amount of oily solid hair cosmetic
本発明によれば、容器との離型性が良く、高温環境下における安定性が良好であり、毛髪に塗布した時の伸びとスタイル持続性に優れる油性固形毛髪化粧料を提供することができる。 According to the present invention, it is possible to provide an oily solid hair cosmetic that has good releasability from a container, good stability in a high temperature environment, and excellent elongation and style sustainability when applied to hair. .
以下、本発明の油性固形毛髪化粧料を具体化した実施形態について詳細に説明する。 Hereinafter, the embodiment which actualized the oil-based solid hair cosmetics of this invention is described in detail.
本発明で用いられる成分（Ａ）である分岐鎖を持つワックスは、特に限定されないが、２０℃で固体であるポリエチレンワックス、（エチレン／プロピレン）コポリマー、マイクロクリスタリンワックス、パラフィンワックス、トリ（ベヘン酸／イソステアリン酸／エイコサンニ酸）グリセリルなどが挙げられる。これら固形油のうち、特にマイクロクリスタリンワックスがスタイル持続性の面で良い。また配合量としては２．０〜５．０質量％が好ましい。この配合量が２．０質量％未満ではスタイル持続効果が得られず、５．０質量％以上だと容器との離型性が悪くなるため好ましくない。 The wax having a branched chain that is the component (A) used in the present invention is not particularly limited, but is a polyethylene wax, (ethylene / propylene) copolymer, microcrystalline wax, paraffin wax, tri (behenic acid) that is solid at 20 ° C. / Isostearic acid / eicosannic acid) glyceryl and the like. Of these solid oils, microcrystalline wax is particularly good in terms of style sustainability. Moreover, as a compounding quantity, 2.0-5.0 mass% is preferable. If the blending amount is less than 2.0% by mass, the style sustaining effect cannot be obtained, and if it is 5.0% by mass or more, the releasability from the container is deteriorated, which is not preferable.
本発明で用いられる成分（Ｂ）である分子量が２５０以上であって炭素１４以上の脂肪酸と分岐高級アルコールからなる２５℃で液状のエステル油としては、通常化粧料で使用されているものであれば特に制限されない。例えば、トリイソステアリン酸トリメチロールプロパン、トリイソステアリン酸ポリグリセリル−２、テトラエチルヘキサン酸ペンタエリスリチル、テトライソステアリン酸ペンタエリスリチル、ヘキサ（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル、ジイソステアリン酸プロパンジオール、ジイソノナン酸ネオペンチルグリコール、ペンタイソステアリン酸ジペンタエリスリチル、イソステアリン酸イソステアリル、イソステアリン酸ヘキシルデシル、イソノナン酸イソデシル、イソノナン酸イソトリデシルなどが挙げられる。これらエステル油のうち、特にヘキサ（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル、トリイソステアリン酸トリメチロールプロパン、トリイソステアリン酸ポリグリセリル−２、イソステアリン酸ヘキシルデシルが良く、これらから選ばれるエステル油を１種または２種以上を含有してもよい。また配合量としては１０．０〜１５．０質量％が好ましく、１０．０質量％未満では毛髪に塗布した際の伸びが悪くなり、１５．０質量％以上だと高温安定性の低下が認められるため好ましくない。 As the component oil (B) used in the present invention, an ester oil which is liquid at 25 ° C. and is composed of a fatty acid having a molecular weight of 250 or more and having 14 or more carbon atoms and a branched higher alcohol, is usually used in cosmetics. There is no particular limitation. For example, trimethylolpropane triisostearate, polyglyceryl-2 triisostearate, pentaerythrityl tetraethylhexanoate, pentaerythrityl tetraisostearate, hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, propanediol diisostearate, diisononane Examples thereof include neopentyl glycol acid, dipentaerythrityl pentaisostearate, isostearyl isostearate, hexyldecyl isostearate, isodecyl isononanoate, and isotridecyl isononanoate. Of these ester oils, hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, trimethylolpropane triisostearate, polyglyceryl-2 triisostearate, and hexyldecyl isostearate are particularly preferred. You may contain a seed or two or more sorts. Further, the blending amount is preferably 10.0 to 15.0% by mass, and if it is less than 10.0% by mass, the elongation when applied to hair is deteriorated, and if it is 15.0% by mass or more, a decrease in high-temperature stability is recognized. This is not preferable.
本発明に用いられる成分（Ｃ）である固形油としては、通常化粧品用に使用されるものであれば、特に制限されず、炭化水素類、ロウ類、油脂類、脂肪酸類、高級アルコール類、エステル類、硬化油類、シリコーン系ワックス類、フッ素系ワックス類等を適宜使用することができる。より具体的には、例えば、カルナウバロウ、キャンデリラロウ、ミツロウ、ライスワックス、硬化ヒマシ油、ステアリン酸、パルミチン酸、１２−ヒドロキシステアリン酸、セチルアルコール、ステアリルアルコール、水添ホホバ油、ステアリル変性ポリシロキサン等が挙げられ、これらから選ばれる固形油を１種または２種以上を含有してもよい。また配合量としては２０．０〜３０．０質量％が好ましく、２０．０質量％未満では高温安定性が低下し、３０．０質量％以上だと毛髪に塗布した際の伸びが悪くなるため好ましくない。 The solid oil which is the component (C) used in the present invention is not particularly limited as long as it is usually used for cosmetics, hydrocarbons, waxes, fats and oils, fatty acids, higher alcohols, Esters, hydrogenated oils, silicone waxes, fluorine waxes, and the like can be used as appropriate. More specifically, for example, carnauba wax, candelilla wax, beeswax, rice wax, hydrogenated castor oil, stearic acid, palmitic acid, 12-hydroxystearic acid, cetyl alcohol, stearyl alcohol, hydrogenated jojoba oil, stearyl-modified polysiloxane The solid oil selected from these may contain 1 type (s) or 2 or more types. Moreover, as a compounding quantity, 20.0-30.0 mass% is preferable, and if it is less than 20.0 mass%, high temperature stability will fall, and when it is 30.0 mass% or more, the elongation at the time of apply | coating to hair will worsen. It is not preferable.
油性成分中の固形油以外の油性成分としては、通常化粧品に用いられる任意の液状および半固形油を使用することができる。液状および半固形油としては、動物油、植物油、合成油等の起源を問わず、液状油には揮発性油分も含まれる。具体的には炭化水素類、ラノリンおよびラノリン誘導体類、油脂類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、シリコーン油類、フッ素系油類等が挙げられ、より具体的には、例えばワセリン、流動パラフィン、スクワラン、ポリイソブチレン、ポリブテン、ラノリン、ヒマシ油、オリーブ油、２−エチルヘキサン酸セチル、トリオクタン酸グリセリル、イソステアリン酸、オレイルアルコール、ジメチルポリシロキサン、ポリエーテル変性ポリシロキサン、フッ素変性シリコーン、パーフルオロポリエーテル等が挙げられ、揮発性油分としては、沸点２６０℃以下の低沸点イソパラフィン、低分子鎖状ジメチルポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン等が挙げられる。 As the oil component other than the solid oil in the oil component, any liquid or semi-solid oil usually used in cosmetics can be used. As liquid and semi-solid oils, volatile oils are also included in liquid oils, regardless of origin, such as animal oils, vegetable oils, and synthetic oils. Specific examples include hydrocarbons, lanolin and lanolin derivatives, fats and oils, hydrogenated oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, and the like. For example, petroleum jelly, liquid paraffin, squalane, polyisobutylene, polybutene, lanolin, castor oil, olive oil, cetyl 2-ethylhexanoate, glyceryl trioctanoate, isostearic acid, oleyl alcohol, dimethylpolysiloxane, polyether-modified polysiloxane, fluorine-modified Examples of the volatile oil include low boiling point isoparaffin having a boiling point of 260 ° C. or lower, low molecular chain dimethylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and the like.
本発明の油性固形毛髪化粧料には、本発明の効果を損なわない範囲で、必要に応じて、各種成分、例えば、紫外線吸収剤、保湿剤、皮膜形成剤、退色防止剤、酸化防止剤、消泡剤、防腐剤、香料、界面活性剤、動植物エキス、生理活性成分、水等を適宜配合することができる。 In the oily solid hair cosmetic composition of the present invention, various components such as an ultraviolet absorber, a humectant, a film forming agent, an anti-fading agent, an antioxidant, as long as the effects of the present invention are not impaired. Antifoaming agents, preservatives, fragrances, surfactants, animal and plant extracts, physiologically active ingredients, water and the like can be appropriately blended.
本発明の油性固形毛髪化粧料は、常法に従い、８０〜１００℃で加熱・溶融した油性成分を充分に攪拌混合し、溶融状態で、容器、樹脂又は金属等のモールド等に充填し、放冷して製造されるもので、スティック状、ペンシル状、ケーキ状、またドーム状およびピラミッド状のような任意の立体形状等に成形されて用いられる。 The oily solid hair cosmetic composition of the present invention is prepared by thoroughly stirring and mixing oily ingredients heated and melted at 80 to 100 ° C. according to a conventional method, filling them in a molten state into a mold such as a container, resin or metal, and releasing them. It is manufactured by cooling, and is used after being molded into an arbitrary three-dimensional shape such as a stick shape, pencil shape, cake shape, dome shape or pyramid shape.
以下、実施例により本発明を具体的に説明するが、これらの実施例により本発明の技術範囲が限定されるものではない。尚、実施例に記載の各種試験（官能評価および保存安定性）に関する試験法を下記に示す。また、以下の表に示す水中油型毛髪化粧料の配合量は、それぞれ質量％で示す。 EXAMPLES Hereinafter, although an Example demonstrates this invention concretely, the technical scope of this invention is not limited by these Examples. In addition, the test method regarding the various tests (sensory evaluation and storage stability) described in the Examples is shown below. Moreover, the compounding quantity of the oil-in-water type hair cosmetic shown in the following table | surface is each shown by the mass%.
（１）スタイル持続性
各実施例および各比較例で得られた油性固形毛髪化粧料を、長さ１０ｃｍ、重さ１ｇに調整した毛束に塗布し、３０℃湿度９０％の高湿度下状態で２時間放置し、塗布直後から高湿度下２時間後までの髪の広がりを測定し、下記基準に従って評価した。
＜評価基準＞
〇：髪の広がりが１０．０ｍｍ未満で、殆ど髪の広がりが認められない
△：髪の広がりが１０．０ｍｍ以上２０．０ｍｍ未満で、やや髪の広がりが認められる
×：髪の広がりが２０．０ｍｍ以上で、明らかな髪の広がりが認められる
(1) Style sustainability The oily solid hair cosmetic obtained in each Example and each Comparative Example was applied to a hair bundle adjusted to a length of 10 cm and a weight of 1 g, and in a high humidity state at 30 ° C. and 90% humidity. The hair spread from immediately after application to 2 hours under high humidity was measured and evaluated according to the following criteria.
<Evaluation criteria>
◯: The hair spread is less than 10.0 mm and almost no hair spread is observed. Δ: The hair spread is 10.0 mm or more and less than 20.0 mm, and the hair spread is slightly recognized. ×: The hair spread is 20 Clear hair spread is recognized at 0.0mm or more
（２）離型性試験
各成分を９０℃以上で溶解させ、均一混合を行い、ポリプロピレン容器（直径３５ｍｍ、
深さ１５ｍｍ）に流し込み、引抜強度測定用治具を容器中央部に差し入れ冷却し、引抜強度測定用治具を油性固形毛髪化粧料に固定する。その後、Ａ＆Ｄ社製フォーステスターＭＣＴ−２１５０を用いて、油性固形毛髪化粧料を３００ｍｍ/ｍｉｎ．の速度で引っ張り、ポリプロピレン容器から油性固形毛髪化粧料が引き剥がされる際の力を計測。本測定値が３０．０Ｎ未満であった場合、離型性が良好とした。
(2) Releasability test Each component was dissolved at 90 ° C. or more and mixed uniformly to obtain a polypropylene container (diameter 35 mm,
Then, the drawing strength measuring jig is inserted into the center of the container and cooled, and the drawing strength measuring jig is fixed to the oily solid hair cosmetic. Thereafter, the oily solid hair cosmetic was applied at 300 mm / min. Using a force tester MCT-2150 manufactured by A & D. Pulling at a speed of, measure the force when the oily solid hair cosmetic is peeled from the polypropylene container. When this measurement value was less than 30.0 N, the releasability was good.
（３）官能評価による塗布時の伸び性
１０名の被験者によって２５℃に保たれた室内で、各実施例および各比較例で得られた油性固形毛髪化粧料を、長さ１０ｃｍ、重さ５ｇに調整した毛束に塗布し、塗布時の伸びの良さを下記基準に従って評価した。
＜評価基準＞
◎：被験者の８名以上が塗布時の伸びが良いと判断
〇：被験者の６名以上が塗布時の伸びが良いと判断
△：被験者の４名以上６名未満が塗布時の伸びが良いと判断
×：被験者の４名未満が塗布時の伸びが良いと判断
(3) Elongation at the time of application by sensory evaluation In a room maintained at 25 ° C. by 10 subjects, the oily solid hair cosmetic obtained in each Example and each Comparative Example was 10 cm in length and 5 g in weight. It applied to the hair bundle adjusted to, and the good elongation at the time of application was evaluated according to the following criteria.
<Evaluation criteria>
◎: Eight or more of the subjects judged that the elongation at the time of application was good ◯: Six or more of the subjects judged that the elongation at the time of application was good △: Four or more of the subjects less than 6 people said that the elongation at the time of application was good Judgment ×: Less than 4 subjects judged that the elongation during application was good
（４）高温安定性
５０℃の恒温槽に１週間より保存した各油性固形毛髪化粧料を取出し、直ちに上蓋を取り、下記基準に従って、各組成物を目視により評価した。
＜評価基準＞
◎：外観に全く変化は見られず、折れや欠損もない
〇：折れや欠損はないが、外観に僅かな変化が見られる
△：外観の変化が認められ、折れや欠損がある
×：組成物が溶け出し、容器の外部に漏れ出ている。
(4) High temperature stability Each oily solid hair cosmetic stored for 1 week in a thermostatic bath at 50 ° C. was taken out, the upper lid was immediately removed, and each composition was visually evaluated according to the following criteria.
<Evaluation criteria>
◎: No change in appearance, no breaks or defects ○: No breaks or defects, but slight changes in appearance △: Appearance changes observed, folds or defects ×: Composition Things are melting out and leaking out of the container.
実施例１〜１６、比較例１〜４
表１および表２に記載の油性固形毛髪化粧料を常法により調製し、耐圧容器に充填した後、前記各種試験を実施して評価を行なった。その結果を表１および表２に併せて示す。
Examples 1-16, Comparative Examples 1-4
The oily solid hair cosmetics described in Table 1 and Table 2 were prepared by a conventional method and filled in a pressure resistant container, and then the various tests were carried out for evaluation. The results are also shown in Table 1 and Table 2.
表１および表２より明らかなように、本発明の成分を用いた実施例１〜１５の油性固形毛髪化粧料は比較例１〜４の油性固形毛髪化粧料に比べていずれも優れた性能を示した。 As is clear from Tables 1 and 2, the oily solid hair cosmetics of Examples 1 to 15 using the components of the present invention have superior performance compared to the oily solid hair cosmetics of Comparative Examples 1 to 4. Indicated.
以下、本発明の油性固形毛髪化粧料のその他の処方例を実施例１６として挙げる。なお、実施例１６の油性固形毛髪化粧料についても、容器との離型性が良く、高温環境下における安定性が良好であり、毛髪に塗布した時の伸びとスタイル持続性に優れることが分かった。 Hereinafter, other formulation examples of the oily solid hair cosmetic composition of the present invention will be described as Example 16. In addition, it was found that the oily solid hair cosmetic of Example 16 also had good releasability from the container, good stability in a high temperature environment, and excellent elongation and style sustainability when applied to hair. It was.
実施例１６
配合量（質量％）
（１）マイクロクリスタリンワックス ３．０
（２）ミリスチン酸オクチルドデシル １２．０
（３）コメヌカロウ １０．０
（４）ミツロウ １５．０
（５）ヒマシ油 ５２．２９
（６）コメ胚芽油 ２．０
（７）ツバキ種子油 １．０
（８）クルミ種子油 １．０
（９）ユチャ種子油 ３．０
（１０）ジパルミチン酸アスコルビル ０．２
（１１）パラメトキシケイ皮酸エチルヘキシル ０．０１
（１３）香料 ０．５
Example 16
Blending amount (% by mass)
(1) Microcrystalline wax 3.0
(2) Octyldodecyl myristate 12.0
(3) Rice bran 10.0
(4) Beeswax 15.0
(5) Castor oil 52.29
(6) Rice germ oil 2.0
(7) Camellia seed oil 1.0
(8) Walnut seed oil 1.0
(9) Yucha seed oil 3.0
(10) Ascorbyl dipalmitate 0.2
(11) Ethylhexyl paramethoxycinnamate 0.01
(13) Fragrance 0.5
（製法）
上記組成の油性固形毛髪化粧料は、常法に従い、８０〜１００℃で加熱・溶融した油性成分を充分に攪拌混合し、溶融状態で、容器、樹脂又は金属等のモールド等に充填し、放冷して製造した。
(Manufacturing method)
The oily solid hair cosmetic composition having the above composition is prepared by thoroughly stirring and mixing oily ingredients heated and melted at 80 to 100 ° C. in a conventional manner, filling them in a molten state into a mold such as a container, resin or metal, and releasing them. Made by cooling.
また、いずれの実施例の毛髪化粧料を使用した場合にも、頭皮に炎症、その他副作用と考えられる症状は発現せず、本発明に係る油性固形毛髪化粧料は安全性にも優れることが明らかであった。
In addition, when the hair cosmetic composition of any of the examples is used, it is clear that the scalp is free from inflammation and other symptoms that are considered to be side effects, and the oily solid hair cosmetic composition according to the present invention is excellent in safety. Met.
Claims (2)
（Ａ）分岐鎖を持つワックス
（Ｂ）分子量が２５０以上であって炭素１４以上の脂肪酸と分岐高級アルコールからなる
２５℃で液状のエステル油から選択される一種又は二種以上
（Ｃ）成分（Ａ）以外の固形油から選択される一種又は二種以上 An oily solid hair cosmetic comprising the following components (A) to (C).
(A) a wax having a branched chain (B) a molecular weight of 250 or more, consisting of a fatty acid having 14 or more carbon atoms and a branched higher alcohol. One or more selected from solid oils other than A)
（Ａ）分岐鎖を持つワックス 油性固形毛髪化粧料全量に対し２．０〜５．０質量％
（Ｂ）分子量が２５０以上であって炭素１４以上の脂肪酸と分岐高級アルコールからなる
２５℃で液状のエステル油から選択される一種又は二種以上
油性固形毛髪化粧料全量に対し１０．０〜１５．０質量％
（Ｃ）成分（Ａ）以外の固形油から選択される一種又は二種以上
油性固形毛髪化粧料全量に対し２０．０〜３０．０質量％
The amount of the components (A) to (C) contained in the oily solid hair cosmetic is as follows.
(A) Wax having a branched chain 2.0 to 5.0% by mass with respect to the total amount of the oily solid hair cosmetic
(B) One or two or more types selected from ester oils having a molecular weight of 250 or more and comprising a fatty acid having 14 or more carbon atoms and a branched higher alcohol at 25 ° C.
10.0-15.0% by mass based on the total amount of oily solid hair cosmetic
(C) One or more selected from solid oils other than component (A)
20.0-30.0% by mass based on the total amount of oily solid hair cosmetic
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002302415A (en) * | 2001-02-01 | 2002-10-18 | Shiseido Co Ltd | Oily solid cosmetic |
| JP2008094790A (en) * | 2006-10-13 | 2008-04-24 | Nippon Shikizai Inc | Bar like oily solid cosmetic |
| JP2009235007A (en) * | 2008-03-27 | 2009-10-15 | Kose Corp | Oily cosmetic |
| WO2010087004A1 (en) * | 2009-01-30 | 2010-08-05 | 高級アルコール工業株式会社 | Oily hair cosmetic |
| JP2010202621A (en) * | 2009-03-06 | 2010-09-16 | Kracie Home Products Ltd | Hairdo agent |
| JP2010235759A (en) * | 2009-03-31 | 2010-10-21 | Kose Corp | Oily solid perfume composition |
| JP2015101581A (en) * | 2013-11-28 | 2015-06-04 | 日本メナード化粧品株式会社 | Oily solid cosmetic |
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2018
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|---|---|---|---|---|
| JP2002302415A (en) * | 2001-02-01 | 2002-10-18 | Shiseido Co Ltd | Oily solid cosmetic |
| JP2008094790A (en) * | 2006-10-13 | 2008-04-24 | Nippon Shikizai Inc | Bar like oily solid cosmetic |
| JP2009235007A (en) * | 2008-03-27 | 2009-10-15 | Kose Corp | Oily cosmetic |
| WO2010087004A1 (en) * | 2009-01-30 | 2010-08-05 | 高級アルコール工業株式会社 | Oily hair cosmetic |
| JP2010202621A (en) * | 2009-03-06 | 2010-09-16 | Kracie Home Products Ltd | Hairdo agent |
| JP2010235759A (en) * | 2009-03-31 | 2010-10-21 | Kose Corp | Oily solid perfume composition |
| JP2015101581A (en) * | 2013-11-28 | 2015-06-04 | 日本メナード化粧品株式会社 | Oily solid cosmetic |
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