JP2019127451A - Myriapod pest-attracting perfume - Google Patents
Myriapod pest-attracting perfume Download PDFInfo
- Publication number
- JP2019127451A JP2019127451A JP2018009567A JP2018009567A JP2019127451A JP 2019127451 A JP2019127451 A JP 2019127451A JP 2018009567 A JP2018009567 A JP 2018009567A JP 2018009567 A JP2018009567 A JP 2018009567A JP 2019127451 A JP2019127451 A JP 2019127451A
- Authority
- JP
- Japan
- Prior art keywords
- pest
- multipod
- flavor
- extract
- essence
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
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Abstract
Description
本発明は、食品香料を含有する多足類害虫誘引香料に関する。 TECHNICAL FIELD The present invention relates to a multipod pest inciting flavor containing a food flavor.
トビズムカデ、アオズムカデ、アカズムカデ等のムカデは、野外環境に生息し、毒腺のある顎肢を用いて小型の虫等を捕食する。しかし、ムカデは温暖な環境を好む習性を有するため家屋等に侵入することが多く、家屋等での人との接触により刺咬被害を引き起こすことがある。そこで、ムカデ等の多足類害虫を防除する毒餌剤が利用されている。このような毒餌剤では、誘引成分を配合することで害虫に対する誘引性が向上されている。 Centipedes such as tobism kade, oomukade, akazukade, etc. inhabit the field environment, and feed on small insects and the like using the jaw limbs with poisonous glands. However, centipedes often invade houses and the like because they have the habit of preferring a warm environment, and contact with people in the houses and the like may cause bite damage. Therefore, poison baits that control multipod pests such as centipede are used. In such a poison bait, the attractiveness to pests is improved by blending an attractant component.
例えば、アカムシを含有する食毒剤がある(例えば、特許文献1を参照)。特許文献1の食毒剤は、アカムシを含有することで、アリ類に対する高い誘引性を発揮し、効果的にアリ類を防除するものである。 For example, there is a food poison containing a red beetle (see, for example, Patent Document 1). The food poisoning agent of Patent Document 1 exhibits a high attractiveness to ants by containing Akamushi and effectively controls ants.
誘引成分の誘引性は、害虫の種類によってその効力の発現に差が生じる。しかしながら、特許文献1の食毒剤は、アリを主な防除対象としたものであり、多足類害虫の防除に最適化されたものではない。そのため、特許文献1の食毒剤は、多足類害虫に対して必ずしも高い誘引性を示すものではない。 The attractiveness of the attractive component differs in the expression of its efficacy depending on the type of pest. However, the poisoning agent of Patent Document 1 mainly targets ants, and is not optimized for the control of multipod pests. Therefore, the poisoning agent of patent document 1 does not necessarily show high attractiveness with respect to a polypod pest.
本発明は、上記問題点に鑑みてなされたものであり、ムカデ等の多足類害虫に対して高い誘引性を示す多足類害虫誘引香料を提供することを目的とする。 The present invention has been made in view of the above problems, and an object of the present invention is to provide a multipod pest inciting fragrance which exhibits high attractiveness to polypod pests such as centipede.
上記課題を解決するための本発明に係る多足類害虫誘引香料の特徴構成は、
食品香料を含有する多足類害虫誘引香料であって、
前記食品香料は、フレッシュミルクオイル、ストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、アップルオイル、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスからなる群から選択される少なくとも1種であることにある。
In order to solve the above-mentioned problems, the characteristic constitution of the multilegged insect pest inducing fragrance according to the present invention is as follows:
A multi-legged pest attractant fragrance containing a food fragrance,
The food flavor comprises fresh milk oil, strawberry essence, acetoin, mango essence, persimmon extract, camembert cheese flavor, apple oil, persimmon extract, persimmon extract, banana extract, nori flavor, squid paste, and maple essence It is at least one selected from the group.
本構成の多足類害虫誘引香料によれば、上記の食品香料を含有することにより、多足類害虫、特にムカデに対する優れた誘引性を発揮することができる。 According to the multipedia insect pest inducer of this configuration, by containing the above-mentioned food flavor, excellent attractability to multipedia insect pests, particularly centipede can be exhibited.
本発明に係る多足類害虫誘引香料において、
前記食品香料は、ストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスからなる群から選択される少なくとも1種であることが好ましい。
In the multipod pest attractant fragrance according to the present invention,
The food flavoring agent is at least one selected from the group consisting of strawberry essence, acetoin, mango essence, persimmon extract, camembert cheese flavor, persimmon salt extract, persimmon extract, banana extract, banana extract, nori flavor, squid paste, and maple essence. It is preferably a species.
本構成の多足類害虫誘引香料によれば、上記の食品香料を含有することにより、毒餌剤に配合する際に可溶化のために界面活性剤を添加する必要がない。その結果、多足類害虫誘引香料を含有する毒餌剤の摂食性を低下させることなく誘引性を向上させることができる。 According to the multi-legged insect pest inducer of the present configuration, by containing the above-mentioned food flavor, it is not necessary to add a surfactant for solubilization at the time of blending into a poison bait. As a result, the attractiveness can be improved without reducing the feeding ability of the poisonous bait containing the multipod pest attractant.
本発明に係る多足類害虫誘引香料において、
前記食品香料は、水溶性であることが好ましい。
In the multipod pest attractant fragrance according to the present invention,
The food flavor is preferably water-soluble.
本構成の多足類害虫誘引香料によれば、食品香料が水溶性であることで、毒餌剤に配合する際に可溶化のために界面活性剤を添加する必要がない。その結果、多足類害虫誘引香料を含有する毒餌剤の摂食性を低下させることなく誘引性を向上させることができる。 According to the multi-legged insect pest inducer of this configuration, the food flavor is water-soluble, so that it is not necessary to add a surfactant for solubilization when it is mixed with the poison bait. As a result, the attractiveness can be improved without reducing the feeding ability of the poisonous bait containing the multipod pest attractant.
本発明に係る多足類害虫誘引香料において、
多足類害虫防除用毒餌剤の誘引成分として用いられることが好ましい。
In the multipod pest attractant fragrance according to the present invention,
It is preferably used as an attractant component of a poison bait for controlling a multipod pest.
本構成の多足類害虫誘引香料によれば、多足類害虫防除用毒餌剤の誘引成分として用いられることで、多足類害虫に対する優れた誘引性を発揮して、多足類害虫に多足類害虫防除用毒餌剤を摂食させることができるため、多足類害虫を効果的に防除することができる。 According to the multi-legged pest attractant fragrance of this configuration, it is used as an attracting component of a poisonous bait for controlling multi-legged pests. Since a poisonous pest for poisonous pest control can be fed, polypod pests can be effectively controlled.
本発明に係る多足類害虫誘引香料において、
前記多足類害虫防除用毒餌剤に、0.1〜4.9重量%添加されることが好ましい。
In the multipod pest attractant fragrance according to the present invention,
It is preferable that 0.1 to 4.9% by weight be added to the poison bait for controlling a multipod pest.
本構成の多足類害虫誘引香料によれば、上記の範囲で添加されることで、多足類害虫に対する優れた誘引性を発揮することができる。 According to the multipedia insect pest inducer of the present configuration, by being added in the above-mentioned range, it is possible to exhibit excellent attractiveness to multipedia insect pests.
本発明に係る多足類害虫誘引香料において、
界面活性剤と併用されないことが好ましい。
In the multipod pest attractant fragrance according to the present invention,
It is preferable not to be used in combination with a surfactant.
本構成の多足類害虫誘引香料によれば、界面活性剤と併用されないことで、多足類害虫誘引香料が含有される毒餌剤の摂食性を低下させることなく誘引性を向上させることができる。 According to the multi-legged pest attractant fragrance of this configuration, the attractiveness can be improved without reducing the feeding property of the poison bait containing the multi-legged pest attractant fragrance by not being used in combination with the surfactant. .
本発明に係る多足類害虫誘引香料は、食品香料を含有する多足類害虫誘引香料である。本発明の多足類害虫誘引香料は、多足類害虫防除用毒餌剤に配合し、毒餌剤の多足類害虫に対する誘引性を向上させる誘引成分として用いることが可能である。以下、本発明の多足類害虫誘引香料に関する実施形態の一例として、多足類害虫誘引香料を配合した多足類害虫防除用毒餌剤について説明する。ただし、本発明は、以下に説明する実施形態や図面に記載される構成に限定されることを意図しない。 The polypod pest attractant according to the present invention is a multipod pest attractant containing a food fragrance. The polypod pest attractant of the present invention can be blended in a poisonous bait for controlling polypod pests and used as an attracting component for improving the attractiveness of the poison bait to polypod pests. Hereinafter, as an example of an embodiment relating to the multipod pest inciting fragrance of the present invention, a multiplicative pest control poison bait formulated with a multipod pest inciting fragrance will be described. However, the present invention is not intended to be limited to the configurations described in the embodiments and drawings described below.
<多足類害虫防除用毒餌剤>
多足類害虫防除用毒餌剤は、誘引成分である本発明の多足類害虫誘引香料、害虫防除成分、摂食促進成分である糖類、保湿成分である多価アルコール、及び水を含有する薬液を含むことが好ましい。薬液は、ゲル状体、マット体、及びシート体等の薬液保持体に保持されていることが好ましい。
<Poisonous bait for multipod pest control>
A poison bait for controlling a multipod pest, comprising the multipod pest inducing fragrance of the present invention as an attractant component, a pest controlling component, a saccharide as a feeding promoting component, a polyhydric alcohol as a moisturizing component, and a chemical solution containing water Is preferred. The drug solution is preferably held by a drug solution holder such as a gel-like body, a mat body, and a sheet body.
<薬液>
[多足類害虫誘引香料]
ムカデは、動物性蛋白質からフルーツ、樹液等の植物由来の物質まで幅広い食性を有し、特に好む食物は諸説ある。本発明者らは、ムカデの誘引性について詳細に検討を行ったところ、ムカデは特定の種類の食品香料に強く誘引される傾向があることが判明した。この新たな知見に基づき、特定の種類の食品香料を含有させた結果、優れた誘引効果が認められた。本発明の多足類害虫防除用毒餌剤が含有する食品香料は、フレッシュミルクオイル、ストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、アップルオイル、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスが挙げられる。これらの食品香料は、単独で使用してもよいし、複数種を組み合わせて使用してもよい。さらに、本発明者らによるムカデの誘引性についての検討過程において、多足類害虫防除用毒餌剤に界面活性剤を添加した場合に、ムカデに対する摂食性が低下する傾向があることが明らかとなった。そのため、本発明の多足類害虫誘引香料は、界面活性剤と併用されないことが好ましく、界面活性剤の添加が不要となる水溶性の食品香料を含有することが好ましい。そのような水溶性の食品香料として、例えば、ストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスが挙げられる。薬液中の多足類害虫誘引香料の含有量は、0.1〜5重量%が好ましい。薬液が薬液保持体に保持された多足類害虫防除用毒餌剤の状態では、多足類害虫誘引香料の含有量は、0.1〜4.9重量%が好ましい。このような範囲であれば、多足類害虫に対する優れた誘引性を発揮することができる。多足類害虫防除用毒餌剤中の多足類害虫誘引香料の含有量が0.1重量%未満であると、多足類害虫の誘引性が不十分なものとなる場合がある。一方、多足類害虫防除用毒餌剤中の多足類害虫誘引香料の含有量が4.9重量%を超えると、多足類害虫防除用毒餌剤を閉鎖空間に設置した場合等に、臭気が過剰に強くなる虞がある。
<Chemical solution>
[Multipod pest attractant]
Centipedes have a wide range of eating habits from animal proteins to plant-derived substances such as fruits, sap, etc. There are various foods that they particularly like. The present inventors have conducted a detailed study on the attractiveness of centipedes, and found that centipedes tend to be strongly attracted to specific types of food fragrances. Based on this new finding, as a result of containing a certain kind of food flavor, an excellent attraction effect was recognized. The food flavors contained in the poison bait of the present invention for controlling pests of the pests are fresh milk oil, strawberry essence, acetoin, mango essence, persimmon, persimmon extract, camembert cheese flavor, apple oil, persimmon extract, persimmon extract, banana Essence, Nori flavor, squid paste, and maple essence. These food flavors may be used alone or in combination of two or more. Furthermore, in the process of examining the attractiveness of centipede by the present inventors, it has become clear that the feeding ability to centipede tends to decrease when a surfactant is added to the poison bait for controlling a multipod pest. The Therefore, the multipod pest attractant fragrance of the present invention is preferably not used in combination with a surfactant, and preferably contains a water-soluble food fragrance that does not require the addition of a surfactant. Such water soluble food flavors include, for example, strawberry essence, acetoin, mango essence, persimmon extract, camembert cheese flavor, persimmon salt extract, persimmon extract, banana extract, nori flavor, squid paste, and maple essence Be The content of the multipod pest-inducing fragrance in the drug solution is preferably 0.1 to 5% by weight. In the state of the poisonous bait for controlling polypod pests in which the chemical solution is held in the chemical solution holder, the content of the polypod pest attractant is preferably 0.1 to 4.9% by weight. If it is such a range, the outstanding attraction with respect to a polypod pest can be exhibited. If the content of the multipod pest attractant in the poisonous bait for controlling polypod pests is less than 0.1% by weight, the attractability of the multipod pest may be insufficient. On the other hand, when the content of the multipodal pest-inducing flavoring agent in the poison bait for controlling a multipodal pest exceeds 4.9% by weight, the odor, for example, when the toxic bait for controlling a multipodal pest is installed in a closed space May become excessively strong.
[害虫防除成分]
薬液の主成分の一つである害虫防除成分は、ムカデ、ヤスデ等の多足類害虫の駆除に有効な成分であることが好ましい。そのような成分として、ネオニコチノイド系殺虫剤、カーバメート系殺虫剤が挙げられ、特に、ネオニコチノイド系殺虫剤が好ましい。ネオニコチノイド系殺虫剤としては、例えば、ジノテフラン、アセタミプリド、イミダクロプリド、クロチアニジン、チアクロプリド、チアメトキサム、及びニテンピラムが挙げられ、特に、ジノテフランが好ましい。なお、ジノテフランには、不斉炭素に基づく光学異性体や幾何異性体が存在するが、それらも害虫防除成分に含まれる。カーバメート系殺虫剤としては、プロポクスル、カルバリル、メソミル、チオジカルブが挙げられ、特に、プロポクスルが好ましい。これらのネオニコチノイド系殺虫剤、及びカーバメート系殺虫剤は、単独で使用してもよいし、複数種を組み合わせて使用してもよい。薬液中の害虫防除成分の含有量は、0.1〜1.0重量%が好ましい。このような範囲であれば、薬液が薬液保持体によって保持された状態においても、害虫防除成分の効果を奏することができる。薬液中の害虫防除成分の含有量が0.1重量%未満である場合、害虫防除成分が不足し殺虫効果が不十分なものとなる。一方、薬液中の害虫防除成分の含有量が1.0重量%を超える場合、害虫防除成分の濃度が高くなるため、薬液を適切に調製し難くなる。
[Pest control ingredients]
It is preferable that the pest control component which is one of the main components of a chemical | medical solution is a component effective in control of multipod pests, such as centipede and yasuda. Such components include neonicotinoid insecticides and carbamate insecticides, and neonicotinoid insecticides are particularly preferable. Examples of neonicotinoid insecticides include dinotefuran, acetamiprid, imidacloprid, clothianidin, thiacloprid, thiamethoxam, and nitenpyram, with dinotefuran being particularly preferable. In addition, although the optical isomer and geometrical isomer based on asymmetric carbon exist in dinotefuran, they are also contained in a pest control component. Examples of carbamate insecticides include propoxul, carbaryl, mesomyl and thiodicarb, and propoxur is particularly preferable. These neonicotinoid insecticides and carbamate insecticides may be used alone or in combination of two or more. As for content of the pest control component in a chemical | medical solution, 0.1 to 1.0 weight% is preferable. If it is such a range, even in the state where a medical fluid is held by a medical fluid carrier, an effect of a pest control ingredient can be produced. When the content of the pest control component in the chemical solution is less than 0.1% by weight, the pest control component is insufficient and the insecticidal effect becomes insufficient. On the other hand, when the content of the pest control component in the drug solution exceeds 1.0% by weight, the concentration of the pest control component becomes high, and it becomes difficult to properly prepare the drug solution.
[摂食促進成分]
薬液の主成分の一つである摂食促進成分は、糖類であることが好ましい。糖類としては、例えば、グルコース、及びフルクトース等の単糖類、スクロース、マルトース、及びトレハロース等の二糖類、三温糖、グラニュー糖、及び上白糖等の精製糖が挙げられ、特に、三温糖が好ましい。これらの糖類は、単独で使用してもよいし、複数種を組み合わせて使用してもよい。また、糖類だけではなく、ソルビトール、キシリトール等の糖アルコール、及びその他の甘味料を摂食促進成分として配合することも可能である。薬液中の摂食促進成分の含有量は、10〜70重量%が好ましい。このような範囲であれば、多足類害虫に対する優れた摂食性を発揮することができ、さらに、低温でも摂食促進成分が結晶化することがないため多足類害虫防除用毒餌剤の保存性に優れる。薬液中の摂食促進成分の含有量が10重量%未満であると、多足類害虫の摂食性が不十分なものとなる場合がある。一方、薬液中の摂食促進成分の含有量が70重量%を超えると、低温環境において摂食促進成分が結晶化する虞がある。
[Feeding promoting ingredient]
The feeding promoting component which is one of the main components of the drug solution is preferably a saccharide. Examples of saccharides include monosaccharides such as glucose and fructose, disaccharides such as sucrose, maltose and trehalose, purified sugars such as trin heating sugar, granulated sugar and white sucrose, and particularly trin heating sugar preferable. These saccharides may be used alone or in combination of two or more. Not only sugars, but also sugar alcohols such as sorbitol and xylitol, and other sweeteners can be blended as feeding promoting ingredients. As for content of the eating promotion component in a chemical | medical solution, 10 to 70 weight% is preferable. Within such a range, it is possible to exert an excellent feeding property against polypod pests, and furthermore, since the feeding promoting component is not crystallized even at low temperature, preservation of poison bait for multipod pest control Excellent in quality. If the content of the feeding promoting component in the drug solution is less than 10% by weight, feeding properties of the multipod pest may be insufficient. On the other hand, if the content of the food intake promoting component in the drug solution exceeds 70% by weight, the food intake promoting component may be crystallized in a low temperature environment.
[保湿成分]
薬液の主成分の一つである保湿成分は、多価アルコールであることが好ましい。多価アルコールとしては、例えば、グリセリンや、1,3−ブチレングリコール、プロピレングリコール、ジプロピレングリコール、トリプロピレングリコール、ジエチレングリコール、トリエチレングリコール、ヘキシレングリコール、及びベンジルグリコール等のグリコール類が挙げられ、特に、グリセリンが好ましい。これらの多価アルコールは、単独で使用してもよいし、複数種を組み合わせて使用してもよい。薬液中の保湿成分の含有量は、10〜40重量%が好ましい。保湿成分の含有量がこのような範囲であれば、多足類害虫防除用毒餌剤を設置後、乾燥、変質を防ぎ、多足類害虫誘引香料による誘引性を長期間にわたって維持することができる。薬液中の保湿成分の含有量が10重量%未満であると、設置後に多足類害虫防除用毒餌剤が早期に乾燥、変質し、ムカデに対する誘引性及び摂食性を維持できない虞がある。薬液中の保湿成分の含有量が40重量%を超える場合、保湿成分の濃度が高くなるため、薬液を適切に調製し難くなる。
[Moisturizing ingredient]
The moisturizing component that is one of the main components of the chemical solution is preferably a polyhydric alcohol. Examples of polyhydric alcohols include glycerin and glycols such as 1,3-butylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, diethylene glycol, triethylene glycol, hexylene glycol, and benzyl glycol. In particular, glycerin is preferred. These polyhydric alcohols may be used alone or in combination of two or more. The content of the moisturizing component in the chemical solution is preferably 10 to 40% by weight. If the content of the moisturizing component is in such a range, after installation of the poison bait for controlling a multipod pest, drying and deterioration can be prevented, and the attractiveness by the multipod pest inducing perfume can be maintained for a long period of time . If the content of the moisturizing component in the drug solution is less than 10% by weight, there is a risk that the poison bait for controlling a multi-legged insect pest prematurely dries and degenerates after installation and can not maintain attractiveness and feeding properties to centipede. When the content of the moisturizing component in the drug solution exceeds 40% by weight, the concentration of the moisturizing component becomes high, which makes it difficult to properly prepare the drug solution.
[その他の成分]
薬液には、本発明の効果に支障を来たさない限り、必要に応じ、カビ類や菌類等を対象とした防カビ剤、抗菌剤、殺菌剤、ビトレックス等の苦味剤、pH調整剤、着色剤等を適宜配合してもよい。防カビ剤、抗菌剤、及び殺菌剤としては、ヒノキチオール、2−メルカプトベンゾチアゾール、2−(4−チアゾリル)ベンツイミダゾール、5−クロロ−2−メチル−4−イソチアゾリン−3−オン、トリホリン、3−メチル−4−イソプロピルフェノール、オルト−フェニルフェノール等が挙げられる。また、上述したように、多足類害虫防除用毒餌剤に界面活性剤を添加した場合、ムカデに対する摂食性が低下する傾向があるため、多足類害虫誘引香料を配合する多足類害虫防除用毒餌剤は、界面活性剤を含有しないことが好ましい。
[Other ingredients]
If necessary, the chemical solution may be an antifungal agent for molds and fungi, an antibacterial agent, a bactericidal agent, a bitter taste agent such as Vitrex, and a pH adjuster, as long as the effects of the present invention are not impaired. Further, a colorant or the like may be appropriately blended. Antifungal agents, antibacterial agents and bactericidal agents include hinokitiol, 2-mercaptobenzothiazole, 2- (4-thiazolyl) benzimidazole, 5-chloro-2-methyl-4-isothiazolin-3-one, trifolin, 3 -Methyl-4-isopropylphenol, ortho-phenylphenol and the like. In addition, as described above, when a surfactant is added to the poison bait for controlling a multipod pest, there is a tendency for the feeding property to the centipede to decrease, so a multilegal pest control containing a multipod pest attracting perfume It is preferable that the poison bait does not contain a surfactant.
<薬液保持体>
本発明の多足類害虫誘引香料を含む薬液を保持する薬液保持体としては、薬液をゲル化剤を用いてゲル化させたゲル状体、薬液をマットに吸収させたマット体、薬液をシートに吸収させたシート体等が挙げられる。例えば、薬液保持体としてゲル状体を用いる場合、ゲル状の多足類害虫防除用毒餌剤を形成することができる。これにより、多足類害虫防除用毒餌剤は、取り扱いが容易なものとなり、さらに、長期間にわたって乾燥することなく、多足類害虫を防除することができる。ゲル化剤としては、例えば、吸水性樹脂、キサンタンガム、カラギナン、ローカストビーンガム、及び寒天等が挙げられる。ここで、本発明者らは、ゲル化剤の種類によって摂食性に相違があることを見出し、ゲルの性状に注目してムカデに対する摂食性を検討したところ、曳糸性の高いゲルではムカデに対する摂食性が低下する傾向があることが判明した。そのため、ゲル化剤としては、曳糸性が低い吸水性樹脂が好ましい。そのような吸水性樹脂として、自重の100倍以上の水を吸収することができるアクリル酸重合体部分ナトリウム塩架橋物等のアクリル酸系吸水性ポリマーが挙げられる。薬液とゲル化剤とは、重量比として、20:1〜70:1で配合されることが好ましい。薬液とゲル化剤との配合比がこのような範囲であれば、ムカデが摂食しやすい硬さ、及び含水率の粒状の毒餌剤が得られ、ムカデに対する高い防除効果を奏することができる。薬液とゲル化剤との配合比が20:1より小さい、即ち薬液をゲル化剤に対して20:1の配合比よりも減らすと、多足類害虫誘引香料による誘引性が十分に効力を示さず、多足類害虫を効果的に誘引できない虞がある。薬液とゲル化剤との配合比が70:1より大きい、即ち薬液をゲル化剤に対して70:1の配合比よりも増やすと、多足類害虫防除用毒餌剤の粘度が過度に小さくなり、取り扱いの面で不便なものとなる虞がある。
<Chemical solution holder>
As a drug solution holding body for holding a drug solution containing the multi-legged insect pest attracting perfume of the present invention, a gel-like body obtained by gelling the drug solution using a gelling agent, a mat body obtained by absorbing the drug solution in a mat, a sheet The sheet | seat body etc. which were made to absorb in are mentioned. For example, when a gel-like body is used as a drug solution carrier, it is possible to form a gel-like poison bait for controlling a multipod pest. Thereby, the poisonous bait for controlling multipod pests becomes easy to handle, and furthermore, it is possible to control multipod pests without drying over a long period of time. Examples of the gelling agent include water-absorbent resins, xanthan gum, carrageenan, locust bean gum, and agar. Here, the present inventors have found that there is a difference in the feeding property depending on the type of gelling agent, and when the feeding property to centipede was examined paying attention to the properties of the gel, the gel having high spinnability was to the centipede. It turned out that there is a tendency for food intake to decrease. Therefore, the gelling agent is preferably a water absorbent resin with low spinnability. As such a water-absorbing resin, acrylic acid-based water-absorbing polymers such as acrylic acid polymer partial sodium salt cross-linked products capable of absorbing water 100 times or more of their own weight can be mentioned. The drug solution and the gelling agent are preferably blended in a weight ratio of 20: 1 to 70: 1. If the compounding ratio of the drug solution and the gelling agent is in such a range, it is possible to obtain a granular poison bait with hardness and moisture content easy for the centipede to feed, and to exert a high control effect on the centipede. When the compounding ratio between the chemical solution and the gelling agent is less than 20: 1, that is, when the chemical solution is reduced from the compounding ratio of 20: 1 with respect to the gelling agent, the attractiveness by the polypod pest attractant is sufficiently effective. It is not shown, and there is a possibility that a polypod pest cannot be attracted effectively. When the compounding ratio of the chemical solution and the gelling agent is larger than 70: 1, that is, when the chemical solution is increased from the mixing ratio of 70: 1 to the gelling agent, the viscosity of the bait for controlling polypod pests is excessively small. This may be inconvenient in handling.
マット体は、繊維材料からなる繊維質担体である。シート体は、繊維材料からなるメッシュ状繊維シート、織布、不織布、編物等である。繊維材料としては、例えば、パルプ、リンター、木綿、麻、羊毛、絹等の天然繊維、レーヨン等の半合成繊維、ポリエステル(ポリエチレンテレフタレート、ポリブチレンテレフタレート等)、ナイロン、アクリル、ビニロン、ポリエチレン、ポリプロピレン、アラミド、ポリフェニレンサルファイド等の合成繊維が挙げられる。薬液保持体としてマット体、又はシート体を用いる場合、必ずしも多足類害虫誘引香料を薬液中に均一に溶解させる必要はなく、多足類害虫誘引香料が薬液中に分散した状態でも、薬液を薬液保持体に含浸させることで多足類害虫に対する誘引性を発揮することができる。そのため、薬液に界面活性剤を添加することなく、多足類害虫誘引香料に水溶性の低い食品香料を用いて、比較的容易に多足類害虫防除用毒餌剤を調製することができる。 The mat body is a fibrous carrier made of a fiber material. The sheet body is a mesh-like fiber sheet made of a fiber material, a woven fabric, a non-woven fabric, a knitted fabric or the like. Examples of fiber materials include natural fibers such as pulp, linter, cotton, hemp, wool, and silk, semi-synthetic fibers such as rayon, polyester (polyethylene terephthalate, polybutylene terephthalate, etc.), nylon, acrylic, vinylon, polyethylene, and polypropylene. And synthetic fibers such as aramid and polyphenylene sulfide. When using a mat or sheet as the chemical solution holder, it is not always necessary to uniformly dissolve the multipod pest attractant fragrance in the chemical solution, and even if the polypod pest attractant fragrance is dispersed in the chemical solution, By impregnating the drug solution holder, it is possible to exhibit the attractiveness to multipedales pests. Therefore, a poisonous bait for controlling polypod pests can be prepared relatively easily by using a food aroma having low water solubility as a polypod pest attractant fragrance without adding a surfactant to the chemical solution.
以下、本発明の多足類害虫誘引香料を含有する多足類害虫防除用毒餌剤を用いて実施したムカデの誘引性、及び摂食性に関する実施例について説明する。なお、以下の実施例では重量の単位として「g」が示されているが、任意の倍率でスケールアップが可能である。すなわち、単位「g」は、「重量部」と読み替えることができる。 Hereinafter, examples relating to the attractiveness of centipede and the feeding ability implemented using the poisonous bait for controlling multipod pests containing the multipod pest attractant of the present invention will be described. In the following examples, “g” is shown as a unit of weight, but scale-up can be performed at an arbitrary magnification. That is, the unit "g" can be read as "part by weight".
〔実施例1〕
誘引成分として本発明の多足類害虫誘引香料であるアセトイン1g、及び鮪エキス1g、害虫防除成分としてジノテフラン0.3g、摂食促進成分として三温糖40g、保湿成分としてグリセリン20g、その他の成分としてイソチアゾリン系抗菌剤0.02g、及びビトレックス0.002gを、精製水に混合して100gとすることで、薬液を調製した。さらに、吸水性樹脂(三洋化成、サンフレッシュ)0.3gに薬液10gを分注して膨潤させることで、実施例1の多足類害虫防除用毒餌剤を得た。
Example 1
1 g of acetoin, which is a multipedia insect pest inducer according to the present invention, as an attractant component, and 1 g of apricot extract, 0.3 g of dinotefuran as a pest control component, 40 g of three-point sugar as a feed promoting component, 20 g of glycerin as a moisturizing component, other components As a solution, 0.02 g of an isothiazoline antibacterial agent and 0.002 g of Vitrex are mixed with purified water to make 100 g, thereby preparing a drug solution. Furthermore, a poison bait for controlling polypod pests of Example 1 was obtained by dispensing 10 g of a chemical solution into 0.3 g of a water-absorbing resin (Sanyo Kasei, Sunfresh).
実施例1の多足類害虫防除用毒餌剤は、ゲル状の粒状体の集塊となり、取り扱いが容易であった。 The poisonous bait for controlling multipod pests of Example 1 became agglomerates of gel-like granules and was easy to handle.
〔実施例2〕
誘引成分として本発明の多足類害虫誘引香料であるストロベリーエッセンス1g、及び鰹・鮪エキス1g、害虫防除成分としてジノテフラン0.3g、摂食促進成分として三温糖20g、保湿成分としてグリセリン20g、その他の成分としてイソチアゾリン系抗菌剤0.02g、及びビトレックス0.002gを、精製水に混合して100gとすることで、薬液を調製した。さらに、パルプ製マット体(12mm×6.3mm×厚み15mm)に薬液4gを分注して保持させることで、実施例2の多足類害虫防除用毒餌剤を得た。
Example 2
1 g of strawberry essence, which is a multipedia insect pest inducer according to the present invention as an attractant component, and 1 g of acupuncture and moxibustion extract, 0.3 g of dinotefuran as a pest control component, 20 g of tribasic sugar as a feed promoting component, and 20 g of glycerin as a moisturizing component A chemical solution was prepared by mixing 0.02 g of an isothiazoline-based antibacterial agent and 0.002 g of Vitrex as the other components in purified water to make 100 g. Further, 4 g of the chemical solution was dispensed and held on a pulp mat body (12 mm × 6.3 mm ×
〔実施例3〕
誘引成分として本発明の多足類害虫誘引香料であるフレッシュミルクオイル1g、及びアップルオイル1g、害虫防除成分としてジノテフラン0.3g、摂食促進成分として三温糖20g、保湿成分としてグリセリン20g、その他の成分としてイソチアゾリン系抗菌剤0.02g、及びビトレックス0.002gを、精製水に混合して100gとすることで、薬液を調製した。さらに、パルプ製マット体(12mm×6.3mm×厚み15mm)に薬液4gを分注して保持させることで、実施例3の多足類害虫防除用毒餌剤を得た。
[Example 3]
1 g of fresh milk oil, which is the multipedia insect pest inducer according to the present invention as an attractant component, and 1 g of apple oil, 0.3 g of dinotefuran as an insect pest control component, 20 g of three-point sugar as a feed promoting component, 20 g of glycerin as a moisturizing component, others A chemical solution was prepared by mixing 0.02 g of an isothiazoline-based antibacterial agent and 0.002 g of Vitrex as the components of the above in purified water to make 100 g. Further, 4 g of the chemical solution was dispensed and held on a pulp mat body (12 mm × 6.3 mm ×
石膏を流し込んだプラスチックケース(幅21cm、長さ37cm、高さ28cm)に供試虫(トビズムカデ)を1匹放ち、馴化させた後に、実施例1の多足類害虫防除用毒餌剤(ゲル状体)2g、実施例2の多足類害虫防除用毒餌剤(マット体)、実施例3の多足類害虫防除用毒餌剤(マット体)を夫々プラスチックケースに設置して、トビズムカデの行動を観察したところ、実施例1〜3の多足類害虫防除用毒餌剤は、何れもムカデに対して優れた誘引性、摂食性、及び致死効果を示した。 After releasing one test insect (Tobizumkade) in a plastic case (21 cm wide, 37 cm long, 28 cm high) poured with plaster and acclimatized, the poisonous bait for controlling polypod pests of Example 1 (gel-like) Body) 2g, Poisonous bait for controlling polypod pests of Example 2 (mat body), and Poisonous bait for controlling polypod pests of Example 3 (mat body) are placed in plastic cases, respectively. As observed, the poison bait for controlling a multipod pest of Examples 1 to 3 all exhibited excellent attractiveness, feedability and lethal effect on centipede.
様々な食品香料について誘引性確認試験を行い、ムカデに対する高い誘引性を有する食品香料を選定した。誘引性確認試験では、石膏を流し込んだプラスチックケース(幅21cm、長さ37cm、高さ28cm)に供試虫(トビズムカデ)を1匹放ち、馴化させた後に、食品香料のサンプル2gを入れたシャーレ(直径3.8cm、高さ1cm、蓋に直径2mmの小孔を6つ開口)をプラスチックケースに設置して、トビズムカデの行動を1時間観察した。プラスチックケースはサンプル毎に3つ用意し、シャーレへのトビズムカデの平均接触回数を求めた。図1は、食品香料へのトビズムカデの平均接触回数を示すグラフである。図1には、コントロールとして水道水2gを入れたシャーレへのトビズムカデの平均接触回数(2.9回)を合わせて示している。 An attractiveness confirmation test was conducted on various food flavors, and food flavors having high attractability to centipedes were selected. In the attractiveness confirmation test, a test insect (Tobism cadet) was released in a plastic case (width 21 cm, length 37 cm, height 28 cm) into which plaster was poured and acclimated, and then a petri dish containing 2 g of a food flavor sample. (A diameter of 3.8 cm, a height of 1 cm, 6 small holes with a diameter of 2 mm on the lid) were placed in a plastic case, and the behavior of Tobism cadet was observed for 1 hour. Three plastic cases were prepared for each sample, and the average number of contacts of the Tobism cadet on the petri dish was obtained. FIG. 1 is a graph showing the average number of contact of Tobism cadet with food fragrances. FIG. 1 also shows the average number of contact times (2.9 times) of the Tobism cadet with a petri dish containing 2 g of tap water as a control.
誘引性確認試験の結果、平均接触回数が5回以上である食品香料を、ムカデに対する誘引性が高い食品香料として選定した。具体的には、図1において破線より上側に示したフレッシュミルクオイル、ストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、アップルオイル、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスが、平均接触回数が5回以上となり優れた誘引性を有することが確認された。 As a result of the attractiveness confirmation test, a food flavoring having an average contact count of 5 times or more was selected as a food flavoring having a high attractiveness to centipedes. Specifically, fresh milk oil, strawberry essence, acetoin, mango essence, persimmon extract, camembert cheese flavor, apple oil, persimmon salt extract, persimmon extract, banana extract, nori flavor shown above the broken line in FIG. It was confirmed that squid paste and maple essence had excellent attractiveness with an average contact number of 5 or more.
〔実施例4〜10、比較例1〜2、参考例1〕
実施例1に準じて表1に示す各種の組成で多足類害虫防除用毒餌剤(ゲル状体)を調製し、摂食性確認試験を実施した。
[Examples 4 to 10, Comparative Examples 1 and 2, Reference Example 1]
According to Example 1, the poisonous bait (gel-like body) for controlling a multi-legged insect pest was prepared with various compositions shown in Table 1, and a feeding test was conducted.
摂食性確認試験では、石膏を流し込んだプラスチックケース(幅21cm、長さ37cm、高さ28cm)に供試虫(トビズムカデ)を1匹放ち、馴化させた後に、自由移動中のムカデの前方、又は静止中のムカデの頭部付近に実施例4〜10の各ゲル状体を提示し、摂食回数を記録し、摂食率(%)を下式により求めた。比較例1及び2、並びに参考例1のゲル状体についても同様の試験を実施した。試験結果を、表1に示す。
摂食率(%) = Ce/Cd × 100
Cd:ゲル状体の提示回数
Ce:摂食回数
In the feedability confirmation test, one test insect (Tobism kade) is released in a plastic case (width 21 cm, length 37 cm, height 28 cm) in which gypsum is poured, and after acclimating, it is in front of a freely moving centipede, or Each gel-like body of Examples 4 to 10 was presented near the head of a resting centipede, the number of times of eating was recorded, and the eating rate (%) was determined by the following equation. The same test was performed on the gel-like bodies of Comparative Examples 1 and 2 and Reference Example 1. The test results are shown in Table 1.
Feeding rate (%) = Ce / Cd × 100
Cd: number of gel-like presentations Ce: number of eating
摂食性確認試験の結果、誘引成分として本発明の特徴構成を備えた多足類害虫誘引香料を含有する実施例4〜10の多足類害虫防除用毒餌剤では、複数種類の食品香料を含有する実施例4〜6、8〜10、及び食品香料を1種類のみ含有する実施例7の何れでも摂食率が41%以上となり、多足類害虫誘引香料によって誘引されることにより、優れた摂食性を示すことが確認された。また、本発明に規定する多足類害虫誘引香料の好ましい含有量の範囲である0.1〜4.9重量%で多足類害虫誘引香料を含有する実施例4〜9の多足類害虫防除用毒餌剤のうち、摂食促進成分の含有量が最も少ない実施例4の摂食率が最も低く、摂食促進成分の含有量が最も多い実施例9の摂食率が最も高くなることから、摂食促進成分の含有量が多い程、多足類害虫防除用毒餌剤の摂食性が向上する傾向が確認された。実施例10は、本発明に規定する多足類害虫誘引香料の好ましい含有量の範囲である0.1〜4.9重量%から外れた値(アセトイン0.04重量%、鰹・鮪エキス0.04重量%)で多足類害虫誘引香料を含有するように調製されている。実施例10では、多足類害虫誘引香料の含有量以外の組成が同一である実施例6の多足類害虫防除用毒餌剤と比較して、摂食率が低下することが確認された。なお、実施例4〜10の多足類害虫防除用毒餌剤は、ゲル状の粒状体の集塊となり、中でも薬液とゲル化剤との配合比が30:1である実施例5と、薬液とゲル化剤との配合比が50:1である実施例4、6、7、9、及び10とは、適度な硬さを有し取り扱いが容易であった。薬液とゲル化剤との配合比が70:1である実施例8は、他のものと比較して粘度がやや低くなったが、十分な取り扱い性を有するものであった。このように、本発明の特徴構成を備えた多足類害虫誘引香料を含有する実施例4〜10の多足類害虫防除用毒餌剤は、誘引性、摂食性、及び取り扱い性に優れるものであり、多足類害虫の防除に適することが確認された。 As a result of the feeding property confirmation test, the poisonous bait for controlling polypod pests of Examples 4 to 10 containing the polypod pest attractant with the characteristic constitution of the present invention as an attracting component contains a plurality of types of food fragrances. In any of Examples 4 to 6, 8 to 10, and Example 7 containing only one kind of food flavor, the feeding rate was 41% or more, and it was excellent by being attracted by a multipod pest attractant flavor. It has been confirmed to show food intake. Further, the polypod pests of Examples 4 to 9 containing the polypod pest attractant in a range of 0.1 to 4.9% by weight, which is a preferable content range of the polypod pest attractant defined in the present invention. Among the poisonous baits for control, the feeding rate of Example 4 with the lowest content of the feeding promoting component is the lowest, and the feeding rate of Example 9 with the highest content of the feeding promoting component is the highest From the results, it was confirmed that the higher the content of the feeding promoting component, the higher the feeding ability of the poisonous bait for controlling polypod pests. Example 10 is a value deviating from 0.1 to 4.9% by weight, which is a preferable content range of the multipod pest attractant perfume stipulated in the present invention (acetoin 0.04% by weight, persimmon and persimmon extract 0) .04% by weight) are prepared to contain a polypodal pest attractant. In Example 10, it was confirmed that the feeding rate was reduced as compared with the poisonous bait for controlling polypod pests of Example 6 having the same composition except the content of the multipod pest attractant fragrance. The poisonous bait for controlling multi-legged pests of Examples 4 to 10 is an agglomeration of gel-like granules, and in particular, Example 5 in which the compounding ratio of the drug solution to the gelling agent is 30: 1 and the drug solution Examples 4, 6, 7, 9, and 10 in which the blending ratio of the gelling agent and the gelling agent was 50: 1 had moderate hardness and were easy to handle. Example 8 in which the compounding ratio of the drug solution to the gelling agent was 70: 1 had a slightly lower viscosity than the others, but had sufficient handleability. Thus, the poisonous bait for controlling polypod pests of Examples 4 to 10 containing the multipod pest attractant fragrance having the characteristic configuration of the present invention is excellent in attractability, feeding ability, and handleability. It has been confirmed that it is suitable for the control of polypod pests.
一方、誘引成分として多足類害虫誘引香料を含有していない比較例1の多足類害虫防除用毒餌剤では、誘引成分以外の組成が同一である実施例6の多足類害虫防除用毒餌剤と比較して、摂食率が低下することが確認された。誘引成分として本発明の多足類害虫誘引香料とは異なる食品香料(ヨーグルトフレーバー、及び鮭オイルフレーバー)を含有する比較例2の多足類害虫防除用毒餌剤では、誘引成分以外の組成が同一である実施例6の多足類害虫防除用毒餌剤と比較して、摂食率が低下することが確認された。このように、本発明の特徴構成を備えていない比較例1及び2の多足類害虫防除用毒餌剤は、何れも摂食率が37%以下の低い値であり、摂食性が劣るものであることが確認された。 On the other hand, in the poisonous bait for controlling a polypod pest of Comparative Example 1 that does not contain a polypod pest attractant as an attracting component, the poisonous bait for controlling a polypod pest of Example 6 having the same composition other than the attracting component is used. It has been confirmed that the feeding rate is reduced as compared with the drug. In the poisonous bait for controlling multipod pests of Comparative Example 2 containing a food flavor (yogurt flavor and coconut oil flavor) different from the multipod pest attractant of the present invention as an attracting component, the composition other than the attracting component is the same. It was confirmed that the feeding rate was lower than that of the poisonous bait for controlling polypod pests of Example 6 as described above. As described above, the poisonous bait for controlling multipod pests of Comparative Examples 1 and 2 not having the characteristic configuration of the present invention has a low feeding rate of 37% or less, and is inferior in feeding ability. It was confirmed that there was.
なお、界面活性剤を含有する参考例1の多足類害虫防除用毒餌剤は、界面活性剤以外の組成が、摂食促進成分を60重量%含有し摂食率が最も高い88%であった実施例9の多足類害虫防除用毒餌剤と同一であるにも関わらず、摂食率が0%であった。このことから、多足類害虫防除用毒餌剤に界面活性剤を添加した場合、ムカデに対する摂食性が低下することが確認された。以上の結果より、誘引性確認試験においてムカデに対する誘引性が高い食品香料として選定したもののうち、水溶性が高いストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスは、多足類害虫防除用毒餌剤を調製する際に、可溶化剤として界面活性剤を添加する必要がないため、多足類害虫防除用毒餌剤に含有させる食品香料としてより適することが確認された。 In addition, the poisonous bait for controlling multipod pests of Reference Example 1 containing a surfactant contained 88% by weight of an ingredient for promoting feeding and had the highest feeding rate of 88%. Despite being identical to the poisonous bait for controlling polypod pests of Example 9, the feeding rate was 0%. From this, it was confirmed that when a surfactant is added to the poison bait for controlling a multipod pest, feedability to centipede decreases. From the above results, among the food flavors selected as highly attractive to centipede in the attractiveness confirmation test, strawberry essence having high water solubility, acetoin, mango essence, persimmon, persimmon extract, camembert cheese flavor, persimmon extract, persimmon extract, persimmon Extract, Banana Essence, Nori Flavor, Squid Paste, and Maple Essence do not require the addition of a surfactant as a solubilizing agent when preparing a bait for controlling polypod pests. It was confirmed that it is more suitable as a food flavor to be contained in a poison bait.
本発明の多足類害虫誘引香料は、ムカデ、ヤスデ等の多足類害虫を誘引し駆除する用途として毒餌剤や捕獲器に利用可能であり、多足類害虫のうち特に、トビズムカデ、アオズムカデ、アカズムカデ等のムカデ類に対して好適に利用可能であり、さらにはワラジムシ、ダンゴムシ等にも利用可能である。 The multipod pest attractant perfume of the present invention can be used in poisonous baits and traps for the purpose of attracting and controlling multipod pests such as centipedes and millipedes, and among the multipod pests, in particular, tobism cadets, aosm cadets, It can be suitably used for centipedes such as akazum cadet, and can also be used for warabimu, dandelion, and the like.
Claims (6)
前記食品香料は、フレッシュミルクオイル、ストロベリーエッセンス、アセトイン、マンゴーエッセンス、鰹・鮪エキス、カマンベールチーズフレーバー、アップルオイル、鰹塩辛エキス、鮪エキス、バナナエッセンス、ノリフレーバー、イカペースト、及びメープルエッセンスからなる群から選択される少なくとも1種である多足類害虫誘引香料。 A multi-legged pest attractant fragrance containing a food fragrance,
The food flavor comprises fresh milk oil, strawberry essence, acetoin, mango essence, persimmon extract, camembert cheese flavor, apple oil, persimmon extract, persimmon extract, banana extract, nori flavor, squid paste, and maple essence A multipod pest attractant perfume that is at least one selected from the group.
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