JP2019073504A - Oily solid cosmetic - Google Patents
Oily solid cosmetic Download PDFInfo
- Publication number
- JP2019073504A JP2019073504A JP2018192285A JP2018192285A JP2019073504A JP 2019073504 A JP2019073504 A JP 2019073504A JP 2018192285 A JP2018192285 A JP 2018192285A JP 2018192285 A JP2018192285 A JP 2018192285A JP 2019073504 A JP2019073504 A JP 2019073504A
- Authority
- JP
- Japan
- Prior art keywords
- component
- cosmetic
- mass
- oil
- oily solid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- WBYWAXJHAXSJNI-VOTSOKGWSA-M trans-cinnamate Chemical compound [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
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- LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
- LOIYMIARKYCTBW-UHFFFAOYSA-N trans-urocanic acid Natural products OC(=O)C=CC1=CNC=N1 LOIYMIARKYCTBW-UHFFFAOYSA-N 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、油性固形化粧料に関するものである。 The present invention relates to an oily solid cosmetic.
メークアップ化粧料には、肌のくすみや毛穴等の欠点をカバーするファンデーションやコンシーラー、頬に色彩を与えて表情を豊かにみせるチークカラー、瞼や口唇に彩りを与えるアイカラーや口紅等がある。近年、電子機器の発達により写真を撮る機会が増え、またTwitter(登録商標)等のSNS(Social Network Servic)で自身の顔写真をネットワーク上で広く公開する機会が増えているため、最近では特に写真映えのするメイクに関心がもたれ、まるでストロボを当てて撮影した時のような立体感を感じる「ストロボメイク」が注目を集めている。ストロボメイクの代表的な手法の一つとして、ハイライト化粧料を用いるものがある。ハイライト化粧料は、高く見せたい部分に使用して、顔を明るい印象に仕上げ、立体感を付与する化粧効果を持つものであり、これらを用いることで、顔に部分的にツヤを付与し、陰影効果により立体感を演出する手法である。ストロボメイクの効果を高めるため、オイルづやを付与するハイライト化粧料の要望が高まっている。このようなハイライト化粧料は、ファンデーション等のメークアップ化粧料の上に用いられることが多く、使用の際に下の化粧膜にヨレ等の崩れを起こさせないことも重要な品質である。従来のハイライト化粧料は、使用時に既に塗布されているファンデーション等のメークアップの化粧膜を崩すことが少なく、使用しやすい粉体化粧料が多かった。これまでにもツヤや立体感を与える化粧料の開発がなされ、たとえば、低次酸化チタンで着色された干渉色を有さない雲母チタン系顔料を配合し立体感を付与する下地化粧料(特許文献1)や、特定粒径のマイカと真珠光沢顔料を含有するツヤ感を有する粉末状化粧料(特許文献2)などが開発されてきた。 Make-up cosmetics include foundations and concealers that cover defects such as skin dullness and pores, cheek colors that give colors to cheeks to make facial expressions look rich, eye colors and lipsticks that add color to wrinkles and lips, etc. . In recent years, the development of electronic devices has increased the opportunity to take pictures, and the opportunity to widely publicize their own face photos on networks via social networks (SNS) such as Twitter (registered trademark) has also increased. There is an interest in the makeup that reflects the photo, and the "strobe makeup", which feels a three-dimensional effect as when shooting with a strobe, is attracting attention. One of the representative techniques for stroboscopic makeup is to use highlight cosmetics. Highlight cosmetics are used for parts that you want to show high, finish the face with a bright impression, and have a cosmetic effect that gives a three-dimensional effect, and using these to give a partial gloss to the face , It is a method to produce a three-dimensional effect by the shadow effect. In order to enhance the effect of stroboscopic makeup, there is a growing demand for highlight cosmetics that impart oil. Such highlight cosmetics are often used on makeup cosmetics such as foundations, and it is also an important quality that they do not cause the cosmetic film below to collapse when used. Conventional highlight cosmetics are less likely to break up makeup films such as foundations and the like already applied at the time of use, and many powder cosmetics are easy to use. Underlying cosmetics that have been developed to give gloss and three-dimensional effect, for example, are blended with a mica titanium-based pigment that does not have an interference color colored with low-order titanium oxide to give a three-dimensional effect (patented Literature 1) and powdery cosmetic materials (patent document 2) having a glossy feeling containing mica having a specific particle diameter and a pearlescent pigment have been developed.
しかしながらファンデーションや下地化粧料は、望む部位のみに局所的ににツヤを与えるものではなく、粉末化粧料は主成分が粉体であるため、ファンデーション等の化粧膜を崩さずに使用することは容易であるが、オイルづやを与えることができなず、真珠光沢顔料で輝きを付与する方法では、技巧的なツヤとなり自然な立体感を十分に得られない場合が多い。油性固形化粧料は、油剤の持つツヤを付与することができ、携帯性、指や小道具での使用の簡便性には優れるが、メークアップの上に塗布すると、そもそもの化粧膜を崩しやすいという使いづらさがあった。 However, foundations and foundation cosmetics do not give gloss locally only to the desired part, and powder cosmetics are mainly powder, so it is easy to use without breaking makeup films such as foundations. However, oil can not be given, and in the method of imparting brilliance with pearlescent pigments, it is often a technical gloss and a sufficient natural three-dimensional effect can not be obtained. The oily solid cosmetic can impart the luster of the oil and is excellent in portability and ease of use with fingers and props, but when applied on makeup, it is easy to break the cosmetic film in the first place It was awkward to use.
かかる事情を鑑み、本発明者らは鋭意研究を重ねた結果、メークアップの上から塗布しても下のメークアップを崩すことがなく、かつ、ストロボメイク効果の高いオイルづやを付与するため、あえて結晶阻害を引き起こすワックスと脂肪酸デキストリンエステルとの組み合わせを用いたワックスオイルゲルが優位であると仮説を立て、精緻な検討によりその好適な組み合わせと、そのオイルづやの持続性が、皮膜形成剤を組み合わせることで実現することを見出し、本発明を完成するに至った。 In view of such circumstances, as a result of intensive studies, the present inventors do not break down the make-up even if applied from above the make-up, and in order to impart oil stains with a high stroboscopic make-up effect, It is hypothesized that wax oil gels using a combination of wax and fatty acid dextrin ester that dare to cause crystal inhibition is superior, and the combination and the durability of the oil stains combine film forming agents by careful examination It has been found that the present invention can be realized by the present invention.
本発明は、化粧膜の上から塗布することを特徴とする油性固形化粧料に関し、更に詳しくは下の化粧膜がヨレず、滑らかに塗布することができ、ツヤ感とその持続性により顔を立体的に魅せるストロボ効果のある油性固形化粧料に関するものである。 The present invention relates to an oil-based solid cosmetic composition characterized in that it is applied from above the cosmetic film, and more specifically, the lower cosmetic film can be applied smoothly without smearing, and the face can be applied by its glossiness and its durability. The present invention relates to an oily solid cosmetic having a stroboscopic effect that is attractive in three dimensions.
以下、本発明を詳細に説明する。
本発明の成分(A)デキストリン脂肪酸エステルは、脂肪酸とデキストリンとのエステルである。本発明においては、デキストリンと好ましくは炭素数12〜22の高級脂肪酸とのエステルが用いられ、具体的には、ラウリン酸デキストリン、パルミチン酸デキストリン、ミリスチン酸デキストリン、ステアリン酸デキストリン、ベヘニン酸デキストリン、ヤシ油脂肪酸デキストリン、(パルミチン酸/オクタン酸)デキストリン等が挙げられる。これらの中でもパルミチン酸デキストリン、ミリスチン酸デキストリン、(パルミチン酸/オクタン酸)デキストリンが好ましく用いられる。デキストリン脂肪酸エステルの市販品としては、例えば、レオパールKL2、レオパールKE2、レオパールTT2、レオパールTL2、レオパールMKL(以上、千葉製粉社製)等が挙げられる。本発明における成分(A)は、1種又は2種以上を組み合わせて用いることができ、その含有量は2〜20質量%(以下、単に%とする)であるが、塗布時のなめらかさの点において、7〜15%が好ましく、更に好ましくは10〜13%である。
Hereinafter, the present invention will be described in detail.
Component (A) dextrin fatty acid ester of the present invention is an ester of fatty acid and dextrin. In the present invention, an ester of dextrin and preferably a higher fatty acid having 12 to 22 carbon atoms is used. Specifically, dextrin laurate, dextrin palmitate, dextrin myristate, dextrin stearate, dextrin behenate, dextrin coconut Oil fatty acid dextrin, (palmitic acid / octanoic acid) dextrin, etc. may be mentioned. Among these, dextrin palmitate, dextrin myristate, and (palmitic acid / octanoic acid) dextrin are preferably used. As a commercial item of dextrin fatty acid ester, for example, leopearl KL2, leopearl KE2, leopearll TT2, leopearl TL2, leopear MKL (all manufactured by Chiba Flour Co., Ltd.), etc. may be mentioned. The component (A) in the present invention may be used alone or in combination of two or more, and its content is 2 to 20% by mass (hereinafter referred to simply as “%”). In terms of point, 7 to 15% is preferable, and 10 to 13% is more preferable.
本発明の成分(B)ワックスは、化粧料に用いられるものであれば、特に限定されず、炭化水素系、エステル系、天然及び合成系のいずれでも使用することができる。具体的には、パラフィンワックス、セレシンワックス、オゾケライトワックス、マイクロクリスタリンワックス、フィッシャートロプシュワックス、ポリエチレンワックス、エチレン・プロピレンコポリマー、キャンデリラワックス、カルナウバワックス、ビーズワックス、ライスワックス、モクロウ、ゲイロウ、ジロウ、モンタンワックス、シリコーンワックス等が挙げられ、これらの1種又は2種以上を用いることができる。その融点は伸び広がりの点において、35℃以上が好ましく、更に好ましくは70℃以上である。 The component (B) wax of the present invention is not particularly limited as long as it is used for cosmetics, and any of hydrocarbon type, ester type, natural and synthetic type can be used. Specifically, paraffin wax, ceresin wax, ozokerite wax, microcrystalline wax, Fischer-Tropsch wax, polyethylene wax, ethylene / propylene copolymer, candelilla wax, carnauba wax, bees wax, rice wax, rice wax, rice flour, gay wax, Examples thereof include zileu, montan wax, silicone wax and the like, and one or more of these may be used. The melting point is preferably 35 ° C. or more, more preferably 70 ° C. or more in terms of elongation and spread.
本発明における成分(B)の含有量は、0.5〜10%であるが、ツヤの点において、1〜8%が好ましく、更に好ましくは2〜6%である。 The content of the component (B) in the present invention is 0.5 to 10%, but in terms of gloss, 1 to 8% is preferable, and more preferably 2 to 6%.
本発明において、成分(A)及び(B)の含有量の合計が化粧料中で5〜30%であり、塗布時のなめらかさの点において9〜25%が好ましく、より好ましくは12〜18%である。また成分(A)と(B)は質量割合(A)/(B)が0.5〜10であり、ツヤとなめらかさのバランスの点において1〜7が好ましく、より好ましくは2〜5である。 In the present invention, the total content of the components (A) and (B) is 5 to 30% in the cosmetic, and 9 to 25% is preferable in terms of smoothness upon application, and more preferably 12 to 18 %. Moreover, mass ratio (A) / (B) of components (A) and (B) is 0.5-10, 1-7 are preferable at the point of the balance of gloss and smoothness, and more preferably 2-5 is there.
本発明の成分(C)油溶性皮膜形成剤は、揮発性油等の油剤に可溶で、乾燥後に皮膜を形成するものであって、化粧料に通常使用されるものであれば特に制限されず、例えばテルペン系樹脂、シリコーン樹脂、炭化水素系樹脂、酢酸ビニル系樹脂等を利用することができる。具体的には、トリメチルシロキシケイ酸、ポリメチルシルセスキオキサン、アクリル変性シリコーン等のシリコーン系樹脂、ロジン変性フェノール樹脂、ロジン酸エステル等のロジン酸系樹脂、キャンデリラ樹脂、酢酸ビニル系樹脂、ポリイソブチレン等が挙げられる。これらの中でも、トリメチルシロキシケイ酸、ポリメチルシルセスキオキサン、アクリル変性シリコーン等のシリコーン系樹脂が化粧持続性の点において、好ましく用いられる。 The component (C) oil-soluble film-forming agent of the present invention is particularly limited as long as it is soluble in an oil such as volatile oil and forms a film after drying and is generally used in cosmetics. For example, terpene resins, silicone resins, hydrocarbon resins, vinyl acetate resins and the like can be used. Specifically, silicone resins such as trimethylsiloxysilicic acid, polymethylsilsesquioxane, acrylic modified silicone, rosin modified phenolic resin, rosin acid based resins such as rosin acid ester, candelilla resin, vinyl acetate based resin, poly Isobutylene etc. are mentioned. Among these, silicone resins such as trimethylsiloxysilicic acid, polymethylsilsesquioxane, acrylic-modified silicone and the like are preferably used in view of cosmetic persistence.
本発明における成分(C)の含有量は、0.1〜10%であるが、化粧持続性と乾燥感の点において、2〜8%が好ましく、更に好ましくは3〜6%である。 The content of the component (C) in the present invention is 0.1 to 10%, preferably 2 to 8%, and more preferably 3 to 6% in terms of cosmetic persistence and dryness.
本発明の油性化粧料は上記(A)〜(C)成分の他に、油性成分、粉体、界面活性剤、水性成分、紫外線吸収剤、酸化防止剤、美容成分油防腐剤、香料等の通常油性化粧料に用いられる成分を本発明の効果を妨げない範囲で、適宜配合することができる。 The oily cosmetic composition of the present invention includes, in addition to the components (A) to (C), an oily component, a powder, a surfactant, an aqueous component, an ultraviolet light absorber, an antioxidant, a cosmetic component oil preservative, a perfume and the like. The components that are usually used for oil-based cosmetics can be blended appropriately as long as the effects of the present invention are not impaired.
油性成分としては、通常化粧料に用いられる油であれば特に制約なく使用することができ、動物油、植物油、合成油等の起源や固形油、液体油、揮発性油等の性状を問わず、炭化水素類、油脂類、エステル油類、脂肪酸類、高級アルコール類、フッ素系油類等を使用することができる。具体的には、流動パラフィン、スクワラン、ワセリン、ポリイソブチレンの炭化水素類、オリーブ油、ミンク油、マカデミアンナッツ油等の油脂類、イソオクタン酸セチル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、ジオクタン酸ネオペンチルグリコール、トリ(カプリル酸/カプリン酸)グリセリル、ホホバ油、トリ2−エチルヘキサン酸グリセリル、リンゴ酸ジイソステアリル等のエステル類、イソステアリン酸、オレイン酸等の脂肪酸類、オレイルアルコール、イソステアリルアルコール等の高級アルコール類、パーフルオロデカン、パーフルオロオクタン、パーフルオロポリエーテル等のフッ素系油剤類、蔗糖脂肪酸エステル、デンプン脂肪酸エステル、イソステアリン酸アルミニウム、ステアリン酸カリウム、12−ヒドロキシステアリン酸、アシル化アミノ酸アルキルアミド等の油性ゲル化剤類等、油溶性美容成分等が挙げられる。 As the oil component, any oil generally used in cosmetics can be used without particular restriction, regardless of the origin of animal oil, vegetable oil, synthetic oil, etc. or properties of solid oil, liquid oil, volatile oil, etc. It is possible to use hydrocarbons, oils and fats, ester oils, fatty acids, higher alcohols, fluorinated oils and the like. Specifically, liquid paraffin, squalane, petrolatum, hydrocarbons of polyisobutylene, oils such as olive oil, mink oil, macadamian nut oil, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, Neopentyl glycol dioctanoate, glyceryl tri (caprylic acid / capric acid), jojoba oil, glyceryl tri-2-ethylhexanoate, esters such as diisostearyl malate, fatty acids such as isostearic acid, oleic acid, oleyl alcohol, Higher alcohols such as isostearyl alcohol, fluorinated oils such as perfluorodecane, perfluorooctane, perfluoropolyether, sucrose fatty acid ester, starch fatty acid ester, aluminum isostearate , Potassium stearate, 12-hydroxy stearic acid, oily gelling agents such as acylated amino alkyl amide, an oil-soluble cosmetic ingredients, and the like.
粉体成分としては、通常化粧料に用いられる粉体であれば特に制約なく使用することができ、球状、板状、針状等の形状、煙霧状、微粒子、顔料級等の粒子径、多孔質、無孔質等の粒子構造等により特に限定されず、無機粉体類、光輝性粉体類、有機粉体類、色素粉体類、金属粉体類、複合粉体類等が挙げられる。具体的には、酸化チタン、酸化亜鉛、酸化セリウム、硫酸バリウム等の白色無機顔料、酸化鉄、カーボンブラック、チタン・酸化チタン焼結物、酸化クロム、水酸化クロム、紺青、群青等の有色無機顔料、タルク、白雲母、金雲母、紅雲母、黒雲母、合成雲母、絹雲母(セリサイト)、合成セリサイト、カオリン、炭化珪素、ベントナイト、スメクタイト、酸化アルミニウム、酸化マグネシウム、酸化ジルコニウム、酸化アンチモン、珪ソウ土、ケイ酸アルミニウム、メタケイ酸アルミニウムマグネシウム、ケイ酸カルシウム、ケイ酸バリウム、ケイ酸マグネシウム、炭酸カルシウム、炭酸マグネシウム、ヒドロキシアパタイト、窒化ホウ素等の白色体質粉体、酸化チタン被覆雲母、酸化チタン被覆オキシ塩化ビスマス、酸化鉄雲母チタン、紺青処理雲母チタン、カルミン処理雲母チタン、オキシ塩化ビスマス、魚鱗箔、ポリエチレンテレフタレート・アルミニウム・エポキシ積層末、ポリエチレンテレフタレート・ポリオレフィン積層フィルム末、ポリエチレンテレフタレート・ポリメチルメタクリレート積層フィルム末等の光輝性粉体、ポリアミド系樹脂、ポリエチレン系樹脂、ポリアクリル系樹脂、ポリエステル系樹脂、フッ素系樹脂、セルロース系樹脂、ポリスチレン系樹脂、スチレン−アクリル共重合樹脂等のコポリマー樹脂、ポリプロピレン系樹脂、ウレタン樹脂等の有機高分子樹脂粉体、ステアリン酸亜鉛、N−アシルリジン等の有機低分子性粉体、シルク粉末、セルロース粉末、デキストリン粉末等の天然有機粉体、赤色201号、赤色202号、赤色205号、赤色226号、赤色228号、橙色203号、橙色204号、青色404号、黄色401号等や、赤色3号、赤色104号、赤色106号、橙色205号、黄色4号、黄色5号、緑色3号、青色1号等のジルコニウム、バリウム又はアルミニウムレーキ等の有機顔料粉体あるいは更にアルミニウム粉、金粉、銀粉等の金属粉体、微粒子酸化チタン被覆雲母チタン、微粒子酸化亜鉛被覆雲母チタン、硫酸バリウム被覆雲母チタン、酸化チタン含有二酸化珪素、酸化亜鉛含有二酸化珪素等の複合粉体、ナイロン、ポリエステル、レーヨン、セルロース等の維等が挙げられる。これらはフッ素化合物、シリコ−ン油、粉体、油剤、ゲル化剤、エマルションポリマー、界面活性剤等で表面処理されていてもよい。これらの粉体は、1種又は2種以上を用いることができ、更に複合化したものを用いても良い。 The powder component can be used without particular limitation as long as it is a powder generally used for cosmetics, and it has a spherical, plate-like, needle-like shape, particle shape such as fumes, fine particles, pigment grade, etc. It is not particularly limited by the particle structure of the porous or nonporous material, and inorganic powders, luster powders, organic powders, pigment powders, metal powders, composite powders, etc. may be mentioned. . Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, iron oxide, carbon black, titanium / titanium oxide sinter, chromium oxide, chromium hydroxide, bitumen, color blue and the like Pigment, talc, muscovite, phlogopite, pyromica, biotite, synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, aluminum oxide, magnesium oxide, zirconium oxide, antimony oxide , Diatomaceous earth, aluminum silicate, magnesium aluminum metasilicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride etc., white powder, titanium oxide coated mica, oxidized Titanium coated bismuth oxychloride, iron oxide mica titanium, Bright powder such as blue treated mica titanium, carmine treated mica titanium, bismuth oxychloride, fish scale foil, polyethylene terephthalate · aluminum · epoxy laminated powder, polyethylene terephthalate · polyolefin laminated film powder, polyethylene terephthalate · polymethyl methacrylate laminated film powder, etc. Organic resin such as polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, copolymer resin such as styrene-acrylic copolymer resin, polypropylene resin, urethane resin Molecular resin powder, Organic low molecular weight powder such as zinc stearate and N-acyl lysine, Natural organic powder such as silk powder, cellulose powder and dextrin powder, Red No. 201, Red No. 202, Red No. 205, Color No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, Red No. 3, Red No. 104, Red No. 106, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 5, Organic pigment powder such as green No. 3 and blue No. 1 with zirconium, barium or aluminum lake or metal powder such as aluminum powder, gold powder or silver powder, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, sulfuric acid Composite powders such as barium-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and fibers of nylon, polyester, rayon, cellulose and the like can be mentioned. These may be surface-treated with a fluorine compound, silicone oil, powder, oil, gelling agent, emulsion polymer, surfactant and the like. These powders may be used alone or in combination of two or more, and may be used in combination.
本発明の油性固形化粧料では特に成分(D)として光輝性粉体を含むと立体感がより得られるため好ましい。成分(D)の含有量としては0.1〜25%が好ましく、さらに好ましくは5〜15%、より好ましくは5〜10%である。 In the oily solid cosmetic of the present invention, it is particularly preferable to include a glitter powder as the component (D) because a three-dimensional effect can be obtained. As content of component (D), 0.1 to 25% is preferable, More preferably, it is 5 to 15%, More preferably, it is 5 to 10%.
界面活性剤としては、化粧料一般に用いられている界面活性剤であればいずれのものも使用でき、非イオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤等が挙げられる。
水性成分としては、水に可溶な成分であれば何れでもよく、水の他に、例えば、プロピレングリコール、1,3−ブチレングリコール、ジプロピレングリコール、グリセリン、ジグリセリン、ポリグリセリン、アロエベラ、ウイッチヘーゼル、ハマメリス、キュウリ、レモン、ラベンダー、ローズ水等の植物抽出液が挙げられる。本発明の油性固形化粧料においては、安定性の点において水性成分は化粧料中に5%未満であることが好ましく、若しくは1%未満、最も好ましくは0.05%未満である。
As the surfactant, any surfactant which is generally used in cosmetics can be used, and nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, etc. Can be mentioned.
The aqueous component may be any component soluble in water, and in addition to water, for example, propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerin, diglycerin, polyglycerin, aloe vera, winch Plant extracts such as hazel, hamamelis, cucumber, lemon, lavender and rose water can be mentioned. In the oily solid cosmetic of the present invention, the aqueous component is preferably less than 5%, or less than 1%, most preferably less than 0.05% in the cosmetic in terms of stability.
紫外線吸収剤としては、例えばアントラニル系、ブチルメトキシジベンゾイルメタンやイソプロピルジベンゾイルメタン等のジベンゾイルメタン系、メトキシケイ皮酸エチルヘキシル、メトキシケイ皮酸イソプロピルや4−メトキシケイ皮酸2−エトキシエチル等のケイ皮酸系、サリチル酸エチルヘキシル等のサリチル酸系、カンファー系、ベンゾフェノン−3等のベンゾフェノン系、ビス-エチルヘキシルオキシフェノールメトキシフェニルトリアジンやエチルヘキシルトリアゾン等のトリアジン系、ベンゾトリアゾール、ベンザルマロネート系、ベンゾイミダゾール系、ビス-ベンゾアゾリル系、p-アミノ安息香酸系、オクトクレリン等のジフェニルアクリレート系、ウロカニン酸系等が挙げられる。 UV absorbers include, for example, anthranil, dibenzoylmethanes such as butylmethoxydibenzoylmethane and isopropyldibenzoylmethane, ethylhexyl methoxycinnamate, isopropyl methoxycinnamate, 2-ethoxyethyl 4-methoxycinnamate, etc. Cinnamate, salicylic acid such as ethylhexyl salicylate, camphor, benzophenone such as benzophenone-3, triazine such as bis-ethylhexyl oxyphenol methoxyphenyl triazine and ethylhexyl triazone, benzotriazole, benzalmalonate, Examples thereof include benzoimidazole type, bis-benzoazolyl type, p-aminobenzoic acid type, diphenyl acrylate type such as octocrelin, and urocanic acid type.
酸化防止剤としては、例えばトコフェロール、アスコルビン酸等、美容成分としては例えばビタミン類、消炎剤、生薬等、防腐剤としては、例えばパラオキシ安息香酸エステル、フェノキシエタノール、1,2−アルカンジオール等が挙げられる。 Antioxidants include, for example, tocopherol, ascorbic acid, etc., cosmetic components include, for example, vitamins, anti-inflammatory agents, herbal medicines, etc., and examples of preservatives include, for example, p-hydroxybenzoic acid ester, phenoxyethanol, 1,2-alkanediol, etc. .
本発明の油性固形化粧料は、連続相が油相であり、室温(約25℃)において流動性を有さない剤型をいい、皿に充填されたもの、クリーム容器に充填されたもの、スティック状の他、2色以上を組み合わせた多色状の形態としても良い。本発明の油性固形化粧料は、例えばファンデーション、下地、白粉、チークカラー、アイシャドウ、アイブロウ、コンシーラー、口紅、マスカラ、アイライナー等のメーキャップ化粧料に好適に用いられ、特に額、鼻筋、頬、顎に塗布し、顔にツヤのある立体感を付与することができる点において、ハイライト化粧料に特に好適に用いることができる。 The oily solid cosmetic composition of the present invention has a continuous phase as an oil phase and has a form which does not have fluidity at room temperature (about 25 ° C.), which is filled in a dish, filled in a cream container, In addition to the stick shape, a multicolor shape in which two or more colors are combined may be used. The oily solid cosmetic composition of the present invention is suitably used, for example, in makeup cosmetics such as foundation, base, white powder, teak color, eye shadow, eyebrow, concealer, lipstick, mascara, eyeliner etc. It can be particularly suitably used as a highlight cosmetic in that it can be applied to the jaws and give the face a glossy three-dimensional effect.
次に実施例をあげて本発明をさらに説明するが、本発明はこれによって何ら限定されるものではない。
実施例1〜17及び比較例1〜11:ハイライト化粧料(固形)
表1、2及び3に示す組成のハイライト化粧料を下記方法により調整し、「メークアップを崩さずに塗布することができる滑らかな伸び広がり」「自然なツヤ感の付与」「化粧持続性」乾燥感のなさ」「立体感の付与」「の各項目について以下に示す評価方法及び評価基準により官能評価を行い、判定基準による判定結果を表中に併記した。
EXAMPLES The present invention will next be described by way of examples, which should not be construed as limiting the invention thereto.
Examples 1 to 17 and Comparative Examples 1 to 11: Highlight Cosmetic (Solid)
Highlight cosmetics of the composition shown in Tables 1, 2 and 3 are adjusted by the following method, and "Smooth spread and spread that can be applied without breaking up make-up", "Gendering of natural gloss feeling", "cosmic sustainability The sensory evaluation was carried out according to the evaluation method and evaluation criteria shown below for each item of “no sense of dryness”, “imposition of three-dimensional effect” and “judgment criteria” and the judgment results based on the judgment criteria are also described in the table.
*1:レオパールTL2(千葉製粉社製)
*2:レオパールMKL2(千葉製粉社製)
*3:レオパールTT2(千葉製粉社製)
*4:KF−7312J(固形分50%デカメチルシクロペンタシロキサン溶液)(信越化学工業社製)
*5:SILFORM FLEXIBLE RESIN(モメンティブ・パフォーマンス・マテリアルズ・ジャパン社製)の50%イソドデカン溶液
*6:KP−545(固形分30%デカメチルシクロペンタシロキサン溶液)(信越化学工業社製)
*7:AEROSIL R−976S(日本アエロジル社製)
*8:FLAMENCO SUPERPEARL(BASF社製)メチルポリシロキサン処理
*9:PDM−10L(トピー工業社製)メチルポリシロキサン処理
* 1: Leopard TL2 (manufactured by Chiba Powder Co., Ltd.)
* 2: Leopard MKL2 (manufactured by Chiba Powder Co., Ltd.)
* 3: Leopard TT2 (manufactured by Chiba Powder Co., Ltd.)
* 4: KF-7312J (solid content 50% decamethylcyclopentasiloxane solution) (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 5: 50% isododecane solution of SILFORM FLEXIBLE RESIN (manufactured by Momentive Performance Materials Japan) * 6: KP-545 (solid content of 30% decamethylcyclopentasiloxane solution) (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 7: AEROSIL R-976S (manufactured by Nippon Aerosil Co., Ltd.)
* 8: FLAMENCO SUPERPEARL (manufactured by BASF) methylpolysiloxane treatment * 9: PDM-10L (manufactured by TOPY INDUSTRIES, LTD.) Methylpolysiloxane treatment
(製造方法)
A.成分(1)〜(13)を均一に混合溶解する。
B.Aに成分(14)〜(16)を加え、均一に混合分散する。
C.Bを容器に充填し、冷却してハイライト化粧料(固形)を得た。
(Production method)
A. Ingredients (1) to (13) are mixed and dissolved uniformly.
B. Ingredients (14) to (16) are added to A and mixed and dispersed uniformly.
C. B was filled in a container and cooled to obtain a highlight cosmetic (solid).
(評価方法)
化粧品専門パネル20名が表1、2及び3の実施例及び比較例のハイライト化粧料を、顔全体に下記評価用パウダーファンデーションを塗布した後、額から鼻筋(いわゆるTゾーン)及び頬の目の下付近に1回塗布して評価をおこない、「メークアップを崩さずに塗布することができる滑らかな伸び広がり」、「自然なツヤ感の付与」、「化粧持続性」、「乾燥感のなさ」、「立体感の付与」について下記評価方法にて評価した。
また、「メークアップを崩さずに塗布することができる滑らかな伸び広がり」については、応力の測定による確認を行い、また「立体感」については、写真撮影により立体感の効果を確認した。
(Evaluation method)
After applying the highlight cosmetic compositions of the Examples and Comparative Examples in Tables 1, 2 and 3 to the entire face, the 20 specialized cosmetic panels applied the powder foundation for evaluation described below to the forehead, nasal muscles (so-called T zone) and cheek eyes It is applied once in the vicinity and evaluated. "Smooth spread and spread that can be applied without breaking up make-up", "Natural feeling of gloss", "Consistency of makeup", "No sense of dryness" The following evaluation methods were used to evaluate "impartation of three-dimensional effect".
In addition, for “smooth spread that can be applied without breaking up makeup”, confirmation was made by measurement of stress, and for “stereoscopic effect”, the effect of stereoscopic effect was confirmed by photography.
<評価用パウダーファンデーション>
(成分) (%)
(1)タルク 20
(2)マイカ 残量
(3)酸化チタン 25
(4)赤酸化鉄 1
(5)黄酸化鉄 2
(6)黒酸化鉄 0.3
(7)無水ケイ酸 *10 5
(8)(ビニルジメチコン/メチコンシルセスキオキサン)
クロスポリマー *11 5
(9)ポリメタクリル酸メチル *12 7
(10)ポリエチレン末 *13 5
(11)パラオキシ安息香酸メチル 0.2
(12)流動パラフィン 2
(13)2−エチルヘキサン酸グリセリル 4
*10 CHIFFONSIL P−3R (平均粒子径5μm、球状、日揮触媒化成社製)
*11 KSP−100 (平均粒子径5μm、球状、信越化学工業社製)
*12 MR−5C (平均粒子径6μm、球状、綜研化学社製)
*13 ミペロンPM−200 (平均粒子径10μm、球状、三井化学株式会社製)
(製造方法)
A.成分(1)〜(11)をスーパーミキサーで均一混合する。
B.成分(12)〜(13)を、均一混合する。
C.Aに、Bを添加混合する。
D.Cを粉砕処理する
E.Dを容器に充填し、プレスして固形粉末状の評価用パウダーファンデーションを得た。
<Powder foundation for evaluation>
(Component) (%)
(1) Talc 20
(2) Mica remaining amount (3) Titanium oxide 25
(4) Red iron oxide 1
(5) Yellow iron oxide 2
(6) Black iron oxide 0.3
(7) Silica * 10 5
(8) (vinyl dimethicone / methicone silsesquioxane)
Cross polymer * 11 5
(9) Polymethyl methacrylate * 12 7
(10) Polyethylene powder * 13 5
(11) Methyl parahydroxybenzoate 0.2
(12) Liquid paraffin 2
(13) Glyceryl 2-ethylhexanoate 4
* 10 CHIFFONSIL P-3R (average particle size 5 μm, spherical, manufactured by JGC Catalysts Chemical Co., Ltd.)
* 11 KSP-100 (average particle size 5 μm, spherical, Shin-Etsu Chemical Co., Ltd.)
* 12 MR-5C (average particle size 6 μm, spherical, manufactured by Soken Chemical Co., Ltd.)
* 13 Miperon PM-200 (average particle size 10 μm, spherical, made by Mitsui Chemicals, Inc.)
(Production method)
A. Ingredients (1) to (11) are uniformly mixed in a super mixer.
B. Ingredients (12)-(13) are mixed uniformly.
C. Add B to A and mix.
D. Grind C
E. D was filled in a container and pressed to obtain a powder foundation for evaluation in the form of a solid powder.
(評価方法)
「メークアップを崩さずに塗布することができる滑らかな伸び広がり」はハイライト化粧料の塗布時に、下に塗布したファンデーションの化粧膜がヨレることなく、なめらかに塗れるかかどうか、「自然なツヤ感の付与」は自然なツヤ感を付与できているか技巧的なツヤになっていないかどうか、「化粧持続性」は経時でツヤ感が失われていないか、「乾燥感のなさ」は使用時および使用後に乾燥感を感じないかどうかについて、「立体感の付与」は顔の陰影を演出でき、ストロボ撮影をした時のような立体感を感じるかどうかについて、専門パネル各自が以下の基準に従って絶対評価を行ない、更に全パネルの評点の平均点を以下の判定基準に従って判定した。
<評価基準>
(評点):(評価)
6点 : 非常に良好
5点 : 良好
4点 : やや良好
3点 : 普通
2点 : 悪い
1点 : 非常に悪い
<判定基準>
(判定):(評点の平均点)
◎ : 5点を超える
○ : 3点を超える5点以下
△ : 2点を超える3点以下
× : 2点以下
(Evaluation method)
“Smooth stretch and spread that can be applied without breaking up make-up” is “natural” whether or not the cosmetic film of the foundation applied underneath can be applied smoothly when the highlight cosmetic is applied. "Tendering of gloss" means whether natural glossiness can be imparted or is not technical gloss, "sustainability" does not lose glossiness over time, or "no dryness" is not As to whether the sense of dryness does not feel when used and after use, “adding a three-dimensional effect” can produce shadows on the face, and the professional panel members can use the following methods to determine whether they feel a three-dimensional effect like flash photography. The absolute evaluation was performed according to the criteria, and the average score of all panel scores was determined according to the following criteria.
<Evaluation criteria>
(Score): (Evaluation)
6 points: very good 5 points: good 4 points: somewhat good 3 points: average 2 points: bad 1 point: very bad <criteria>
(Judgement): (average score)
:: more than 5 points ○: 5 points or more exceeding 3 points 点: 3 points or less exceeding 2 points ×: 2 points or less
表1〜3の結果に示すとおり、実施例のハイライト化粧料は、全ての項目で優れたものであった。成分(D)を多く含有する実施例17は、真珠光沢顔料による技巧的な仕上がりが感じられ、自然なツヤ感にやや劣るものであった。一方成分(A)を多く含有する比較例1は、塗布時の滑らかさで満足いくものでなかった。成分(A)の含有量が少ない比較例2、成分(B)の含有量が多い比較例3は、自然なツヤ感が十分ではなく、それに伴って立体感も満足いくものではなかった。
一方、成分(B)の含有量が少ない比較例4は、塗布時の滑らかな伸び広がりが劣るものであった。成分(A)及び(B)を多く含有する比較例5は化粧料が硬くなってしまうため、塗布時に下のファンデーションの化粧膜を引っ張ってしまい、化粧膜を崩してしまうものであった。また、成分(A)及び(B)の含有量が少ない比較例6はファンデーションの化粧膜が滲んでしまい、均一に塗布ができず、十分な化粧効果が得られないないものであった。
成分(A)/(B)が大きい比較例7では塗布時の滑らかな崩れ感がなく、ファンデーションの化粧膜を引っ張ってしまいヨレてしまった。また一方で成分(A)/(B)が小さい比較例8ではツヤが十分ではなく、立体感を得られないものであった。
成分(C)を多く含有する比較例9は、塗布時の滑らかさが不足し、さらに塗布後につっぱり感からくる負担感や乾燥感を感じてしまった。一方で成分(C)の含有量が少ない比較例10は、ツヤの持続性を感じられなかった。
成分(A)に代えて12−ヒドロキシステアリン酸を使用した比較例11では、塗布時の滑らかさが得られるものではなかった。
As shown in the results of Tables 1 to 3, the highlight cosmetic of the example was excellent in all the items. Example 17 containing a large amount of the component (D) felt a technical finish with a pearlescent pigment, and was somewhat inferior to the natural gloss. On the other hand, Comparative Example 1 containing a large amount of the component (A) was not satisfactory in smoothness upon application. In Comparative Example 2 in which the content of the component (A) is small, and Comparative Example 3 in which the content of the component (B) is large, natural glossiness is not sufficient, and along with that, the three-dimensional effect is not satisfactory.
On the other hand, in Comparative Example 4 in which the content of the component (B) was small, the smooth elongation at the time of coating was inferior. In Comparative Example 5 containing a large amount of the components (A) and (B), the cosmetic becomes hard, so the cosmetic film of the lower foundation at the time of application is pulled, and the cosmetic film is broken. In addition, in Comparative Example 6 in which the content of the components (A) and (B) is small, the cosmetic film of the foundation blurs, and uniform application can not be performed, and a sufficient cosmetic effect can not be obtained.
In Comparative Example 7 in which the component (A) / (B) was large, there was no smooth feeling of collapse at the time of application, and the cosmetic film of the foundation was pulled and the film was curled. On the other hand, in Comparative Example 8 in which the components (A) / (B) were small, the gloss was not sufficient and a three-dimensional effect could not be obtained.
In Comparative Example 9 containing a large amount of the component (C), the smoothness at the time of application was insufficient, and further, the feeling of strain and dryness coming from the feeling of pinching after application was felt. On the other hand, Comparative Example 10 in which the content of the component (C) was small did not feel the durability of the gloss.
In Comparative Example 11 in which 12-hydroxystearic acid was used instead of the component (A), the smoothness upon application was not obtained.
(応力の測定)
直径3cm、高さ1.2cmの容器に実施例1と比較例3及び11を、それぞれ6gずつ100℃溶解90℃充填にて溶融充填を行った。一晩25℃にて放置後、テクスチャーアナライザー(英弘精機社製)を用い、直径8mmのプローブを0.5mm/1秒の速度で3mm押し込み、プローブにかかる応力を測定し、その結果を図1に示す。
(Measurement of stress)
In a container having a diameter of 3 cm and a height of 1.2 cm, 6 g each of Example 1 and Comparative Examples 3 and 11 were melted and filled at 100 ° C. melting and 90 ° C. filling. After standing overnight at 25 ° C., using a texture analyzer (manufactured by Eiko Seiki Co., Ltd.), a probe with a diameter of 8 mm was pushed in at a speed of 0.5 mm / second for 3 mm to measure the stress applied to the probe. Shown in.
図1は縦軸に応力、横軸にプローブが油性固形表面に触れてからの時間を表している。実施例1のハイライト化粧料はプローブが進入するまでにかかる力の大きさが最も小さく、且つ、一定の力でプローブが進入していくことがわかる。これが塗布時の滑らかさに寄与すると予測され、実施例1は下の化粧膜を崩すことなく均一に塗布できていることが考えられる。一方で比較例3、11ではプローブが進入するまでにかかる力が大きく、さらに進入していく段階の波形を観察しても、凹凸があり、一定の力で塗布することができず、下の化粧膜を崩れさせてしまうと考えられる。 In FIG. 1, the vertical axis represents stress, and the horizontal axis represents the time after the probe touches the oily solid surface. The highlight cosmetic of Example 1 has the smallest magnitude of force applied until the probe enters, and it can be seen that the probe enters with a constant force. It is predicted that this contributes to the smoothness upon application, and it is conceivable that Example 1 can be uniformly applied without breaking the cosmetic film below. On the other hand, in Comparative Examples 3 and 11, the force applied until the probe enters is large, and even when the waveform at the entering stage is observed, there is unevenness, and it can not be applied with a constant force. It is thought that the cosmetic film is broken.
(写真撮影による立体感の評価)
評価者は洗顔後、10分間安静にしたのち、下地化粧料を用い、更に前記評価用のパウダーファンデーションを全顔に塗布し、その状態でストロボを使用して全顔の撮影を行った。
次に実施例1をTゾーン及び頬の目の下付近に、塗布量は指でハイライター化粧料の表面を優しくなでるように取り、重ね塗りはせずに塗布した状態で、ストロボを使用せずに全顔の撮影を行った。比較例3のサンプルについても、同様な操作を行い、ストロボを使用せずに全顔の撮影を行った。
それぞれ撮影した顔画像を解析により、L値が84〜92の範囲、ハイライト効果が得られた範囲を点線で囲んだ画像を作成した。図2〜4よりわかるように、ハイライト化粧料を使用しないストロボ撮影写真(図2)と、実施例1を使用した写真(図3)では、ハイライト効果が得られた範囲が近しい分布を示しており、ストロボを使用したような仕上がりである「ストロボメイク効果」を有する。一方で比較例3を使用した写真(図4)は、顔の陰影が不足しており、立体感のある仕上がりに乏しいものであった。
(Evaluation of stereoscopic effect by photography)
After the face wash, the evaluator rested for 10 minutes, and then applied the powder foundation for evaluation to the entire face using the base cosmetic, and photographed the entire face using a strobe in that state.
Next, take Example 1 so that the surface of the highlighter cosmetic is gently rubbed with a finger in the vicinity of T zone and under the cheek eyes, and in a state where it is applied without over-coating, without using a strobe. I shot the whole face. The same operation was performed on the sample of Comparative Example 3 and shooting of all faces was performed without using a flash.
Each face image taken was analyzed to create an image in which the L value is in the range of 84 to 92, and the range in which the highlight effect is obtained is surrounded by a dotted line. As can be seen from FIGS. 2 to 4, the strobe photograph without the highlight cosmetic (FIG. 2) and the photograph using the example 1 (FIG. 3) show that the range where the highlight effect is obtained is close to the distribution It has a "strobe makeup effect" that is shown and looks like using a strobe. On the other hand, in the photograph using Comparative Example 3 (FIG. 4), the shadow of the face was insufficient, and the finish with a three-dimensional effect was poor.
実施例19:油性頬紅
(成分) (%)
(1)パルミチン酸デキストリン *1 10
(2)マイクロクリスタリンワックス(融点77〜82℃) 4
(3)トリメチルシロキシケイ酸 *4 6
(4)トリイソステアリン酸ジグリセリル 30
(5)2−エチルヘキサン酸セチル 20
(6)ジメチルポリシロキサン(25℃、動粘度20CS) 2
(7)ビタミンC 2
(8)セスキオレイン酸ソルビタン 2
(9)赤色202号 0.5
(10)黄色4号 0.5
(11)黒色酸化鉄 0.1
(12)タルク 残量
(13)疎水化処理無水ケイ酸 *7 2
(14)メタクリル酸メチルクロスポリマー末 *14 3
(15)ポリエチレン末※15 0.2
(16)酸化亜鉛 2
(17)酸化チタン 3
*14:マツモトマイクロスフェアM−305(松本油脂製薬社製)
*15:ミペロンPM−200(三井化学社製)
(製造方法)
A:成分(1)〜(8)を加熱し、均一溶解する。
B:Aに成分(9)〜(17)を加え、均一に分散する。
C:Bを金皿に流し込み、冷却固化して油性頬紅得た。
得られた油性頬紅は、メークアップを崩さずに塗布することができる滑らかな伸び広がり、自然なツヤ感の付与、化粧持続性、乾燥感のなさ、立体感の付与に優れたものであった。
Example 19: oily blush (component) (%)
(1) Dextrin palmitate * 1 10
(2) microcrystalline wax (melting point 77 to 82 ° C.) 4
(3) Trimethylsiloxysilicate * 4 6
(4) Diglyceryl triisostearate 30
(5) cetyl 2-ethylhexanoate 20
(6) Dimethylpolysiloxane (25 ° C., dynamic viscosity 20 CS) 2
(7) Vitamin C 2
(8) Sorbitan sesquioleate 2
(9) Red No. 202 0.5
(10) Yellow No. 4 0.5
(11) Black iron oxide 0.1
(12) Talc residual amount (13) Hydrophobicized treated silica * 7 2
(14) Methyl methacrylate crosspolymer powder * 14 3
(15) Polyethylene powder ※ 15 0.2
(16) Zinc oxide 2
(17) Titanium oxide 3
* 14: Matsumoto Microsphere M-305 (manufactured by Matsumoto Yushi Pharmaceutical Co., Ltd.)
* 15: Miperon PM-200 (made by Mitsui Chemicals, Inc.)
(Production method)
A: Components (1) to (8) are heated and uniformly dissolved.
B: Add components (9) to (17) to A and disperse uniformly.
C: B was poured into a gold plate and solidified by cooling to obtain oily blush.
The obtained oily cheek blush was excellent in smooth extension and spreading that can be applied without breaking up make-up, imparting of natural glossiness, maintaining of makeup, not having dryness, and imparting of three-dimensional effect. .
実施例20:油性コンシーラー
(成分) (%)
(1)ミリスチン酸デキストリン *2 10
(2)キャンデリラワックス(融点70〜75℃) 4
(3)トリメチルシロキシケイ酸 *4 6
(4)トリイソステアリン酸ジグリセリル 30
(5)2−エチルヘキサン酸セチル 20
(6)香料 0.5
(7)トコフェロール 0.5
(8)ペンチレングリコール 0.5
(9)セスキオレイン酸ソルビタン 2
(10)赤色酸化鉄 0.5
(11)黄色酸化鉄 0.4
(12)黒色酸化鉄 0.1
(13)タルク 残量
(14)(ビニルジメチコン/メチコンシルセスキオキサン)
クロスポリマー *11 5
(15)ラウロイルリシン *16 2
(16)疎水化処理無水ケイ酸 *7 1
(17)無水ケイ酸 5
(18)トリエトキシカプリリルシラン処理
微粒子酸化亜鉛 *17 5
(19)ラウロイルアスパラギン酸Na処理
微粒子二酸化チタン *18 7
※16:アミホープLL(味の素社製)
※17:MZX−508OTS(テイカ社製)のトリエトキシカプリリルシラン3%処理
※18:ASIチタンCR−50(大東化成工業社製)
(製造方法)
A:成分(1)〜(9)を加熱し、均一溶解する。
B:Aに成分(10)〜(19)を加え、均一に分散する。
C:Bを金皿に流し込み、冷却固化して油性コンシーラー得た。
得られた油性コンシーラーは、メークアップを崩さずに塗布することができる滑らかな伸び広がり、自然なツヤ感の付与、化粧持続性、乾燥感のなさ、立体感の付与に優れたものであった。
Example 20: Oil-based concealer (component) (%)
(1) Dextrin myristate * 2 10
(2) Candelilla wax (melting point 70-75 ° C) 4
(3) Trimethylsiloxysilicate * 4 6
(4) Diglyceryl triisostearate 30
(5) cetyl 2-ethylhexanoate 20
(6) Flavoring agent 0.5
(7) Tocopherol 0.5
(8) pentylene glycol 0.5
(9) Sorbitan sesquioleate 2
(10) Red iron oxide 0.5
(11) Yellow iron oxide 0.4
(12) Black iron oxide 0.1
(13) Talc remaining amount (14) (vinyl dimethicone / methicone silsesquioxane)
Cross polymer * 11 5
(15) lauroyl lysine * 16 2
(16) Hydrophobicized silica * 7 1
(17) Silica 5
(18) Triethoxy caprylyl silane treatment
Fine particle zinc oxide * 17 5
(19) Lauroyl aspartate Na treatment
Fine particle titanium dioxide * 18 7
※ 16: Ami Hope LL (made by Ajinomoto Co.)
※ 17: Triethoxy caprylylsilane 3% treatment of MZX-508 OTS (made by Tayca) ※ 18: ASI titanium CR-50 (made by Daito Kasei Kogyo Co., Ltd.)
(Production method)
A: Components (1) to (9) are heated and uniformly dissolved.
B: Add components (10) to (19) to A and disperse uniformly.
C: B was poured into a gold dish and solidified by cooling to obtain an oil-based concealer.
The obtained oil-based concealer was excellent in smooth extension and spreading that can be applied without breaking up makeup, imparting of natural glossiness, cosmetic persistence, insensitivity to dryness, and imparting of a three-dimensional effect. .
実施例21:油性ハイライト化粧料
(成分) (%)
(1)パルミチン酸デキストリン *1 6
(2)マイクロクリスタリンワックス(融点76〜80℃) 4
(3)トリメチルシロキシケイ酸 *19 3
(4)イソドデカン 10
(5)2−エチルヘキサン酸セチル 15
(6)香料 0.5
(7)トコフェロール 0.5
(8)マカデミアナッツ油 5
(9)カプリリルグリコール 0.5
(10)セスキオレイン酸ソルビタン 2
(11)タルク 残量
(12)中空シリカ末 *20 8
(13)疎水化処理無水ケイ酸 *7 1
(14)酸化鉄被覆雲母チタン *21 0.3
(15)ステアロイルグルタミン酸2Na処理
二酸化チタン *22 7
※19:SR−1000(モメンティブ・パフォーマンス・マテリアルズ・ジャパン社製)
※20:SILICA MICRO BEAD BA−1(日揮触媒化成社製)
※21:RELIEF COLOR PINK(日揮触媒化成社製)
※22:NAI−チタンMP−1133(三好化成社製)
(製造方法)
A:成分(1)〜(9)を加熱し、均一溶解する。
B:Aに成分(10)〜(15)を加え、均一に分散する。
C:Bを金皿に流し込み、冷却固化して油性ハイライト化粧料を得た。
得られた油性ハイライト化粧料は、メークアップを崩さずに塗布することができる滑らかな伸び広がり、自然なツヤ感の付与、化粧持続性、乾燥感のなさ、立体感の付与に優れたものであった。
Example 21: oily highlight cosmetic (component) (%)
(1) Dextrin palmitate * 1 6
(2) Microcrystalline wax (melting point 76-80 ° C) 4
(3) Trimethylsiloxysilicic acid * 19 3
(4) Isododecane 10
(5) cetyl 2-ethylhexanoate 15
(6) Flavoring agent 0.5
(7) Tocopherol 0.5
(8) Macadamia nut oil 5
(9) Capriryl glycol 0.5
(10) Sorbitan sesquioleate 2
(11) Talc remaining amount (12) Hollow silica powder * 20 8
(13) Hydrophobicized silica * 7 1
(14) Iron oxide coated mica titanium * 21 0.3
(15) Stearoyl glutamic acid 2Na treatment
Titanium dioxide * 22 7
* 19: SR-1000 (Momentive Performance Materials Japan)
* 20: SILICA MICRO BEAD BA-1 (manufactured by JGC Catalyst Chemical Co., Ltd.)
※ 21: RELIEF COLOR PINK (made by JGC Catalyst Chemical Co., Ltd.)
※ 22: NAI-titanium MP-1133 (manufactured by Miyoshi Kasei Co., Ltd.)
(Production method)
A: Components (1) to (9) are heated and uniformly dissolved.
B: Add components (10) to (15) to A and disperse uniformly.
C: B was poured into a gold dish and solidified by cooling to obtain an oily highlight cosmetic.
The obtained oily highlight cosmetic composition is excellent in imparting a smooth stretch and spread that can be applied without breaking up makeup, imparting of natural glossiness, maintaining of makeup, having no dryness, and imparting of three-dimensional impression Met.
Claims (8)
成分(A)デキストリン脂肪酸エステル2〜20質量%
成分(B)ワックス0.5〜10質量%
成分(C)油溶性被膜形成剤0.1〜10質量%
を含有し、成分(A)及び(B)の含有量の合計が化粧料中で5〜30質量%であり、かつ成分(B)の含有量に対する成分(A)の含有量の質量割合(A)/(B)が0.5〜10であって、メークアップ化粧料を施した上に用いる油性固形化粧料。 The following (A) to (C);
Component (A) dextrin fatty acid ester 2 to 20% by mass
Component (B) wax 0.5 to 10% by mass
Component (C) oil-soluble film forming agent 0.1 to 10% by mass
And the total content of the components (A) and (B) is 5 to 30% by mass in the cosmetic, and the mass ratio of the content of the component (A) to the content of the component (B) ( A) / (B) is 0.5-10, and it is oil-based solid cosmetics used after giving makeup makeup.
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JP2022545574A (en) * | 2019-10-31 | 2022-10-27 | 花王株式会社 | Skin treatment method |
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