JP2019032954A5 - Lithium ion secondary battery - Google Patents

Lithium ion secondary battery Download PDF

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Publication number
JP2019032954A5
JP2019032954A5 JP2017152090A JP2017152090A JP2019032954A5 JP 2019032954 A5 JP2019032954 A5 JP 2019032954A5 JP 2017152090 A JP2017152090 A JP 2017152090A JP 2017152090 A JP2017152090 A JP 2017152090A JP 2019032954 A5 JP2019032954 A5 JP 2019032954A5
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concentration
magnesium
secondary battery
ion secondary
surface layer
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JP2017152090A
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JP7081908B2 (en
JP2019032954A (en
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Priority to JP2017152090A priority Critical patent/JP7081908B2/en
Priority claimed from JP2017152090A external-priority patent/JP7081908B2/en
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Publication of JP2019032954A5 publication Critical patent/JP2019032954A5/en
Priority to JP2022085939A priority patent/JP7237221B2/en
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Publication of JP7081908B2 publication Critical patent/JP7081908B2/en
Priority to JP2023029518A priority patent/JP2023076432A/en
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Claims (5)

ニッケル、マンガンおよびコバルトを有する正極活物質を有し、Has a positive electrode active material with nickel, manganese and cobalt,
前記正極活物質は、内部および表層部に、マグネシウムおよびハロゲンを有し、The positive electrode active material has magnesium and halogen inside and on the surface layer.
前記表層部のマグネシウムの濃度は、前記内部のマグネシウムの濃度より高く、The concentration of magnesium in the surface layer is higher than the concentration of magnesium inside.
前記表層部のハロゲンの濃度は、前記内部のフッ素の濃度より高いリチウムイオン二次電池。A lithium ion secondary battery in which the concentration of halogen on the surface layer is higher than the concentration of fluorine inside.
ニッケル、マンガンおよびコバルトを有する正極活物質を有し、Has a positive electrode active material with nickel, manganese and cobalt,
前記正極活物質は、内部および表層部に、マグネシウムを有し、The positive electrode active material has magnesium inside and on the surface layer, and has magnesium.
前記表層部のマグネシウムの濃度は、前記内部のマグネシウムの濃度より高い、リチウムイオン二次電池。A lithium ion secondary battery in which the concentration of magnesium on the surface layer is higher than the concentration of magnesium inside.
ニッケル、マンガンおよびコバルトを有する正極活物質を有し、Has a positive electrode active material with nickel, manganese and cobalt,
前記正極活物質は、内部、表層部、および結晶粒界およびその近傍に、マグネシウムおよびハロゲンを有し、The positive electrode active material has magnesium and halogen inside, on the surface, and at and near the grain boundaries.
前記表層部のマグネシウムの濃度は、前記内部のマグネシウムの濃度より高く、The concentration of magnesium in the surface layer is higher than the concentration of magnesium inside.
前記結晶粒界およびその近傍のマグネシウムの濃度は、前記内部のマグネシウムの濃度より高く、The concentration of magnesium at and near the grain boundaries is higher than the concentration of magnesium inside.
前記表層部のハロゲンの濃度は、前記内部のハロゲンの濃度より高く、The concentration of halogen on the surface layer is higher than the concentration of halogen inside.
前記結晶粒界およびその近傍のハロゲンの濃度は、前記内部のハロゲンの濃度より高The concentration of halogen in and near the grain boundaries is higher than the concentration of halogen inside.
いリチウムイオン二次電池。Lithium-ion secondary battery.
ニッケル、マンガンおよびコバルトを有する正極活物質を有し、Has a positive electrode active material with nickel, manganese and cobalt,
前記正極活物質は、内部、表層部、および結晶粒界およびその近傍に、マグネシウムを有し、The positive electrode active material has magnesium inside, on the surface layer, and at and near the grain boundaries.
前記表層部のマグネシウムの濃度は、前記内部のマグネシウムの濃度より高く、The concentration of magnesium in the surface layer is higher than the concentration of magnesium inside.
前記結晶粒界およびその近傍のマグネシウムの濃度は、前記内部のマグネシウムの濃度より高いリチウムイオン二次電池。A lithium ion secondary battery in which the concentration of magnesium at and near the grain boundaries is higher than the concentration of magnesium inside.
請求項1または請求項3において、In claim 1 or 3,
前記ハロゲンは、フッ素であるリチウムイオン二次電池。The halogen is a lithium ion secondary battery which is fluorine.
JP2017152090A 2017-08-07 2017-08-07 Lithium ion secondary battery Active JP7081908B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2017152090A JP7081908B2 (en) 2017-08-07 2017-08-07 Lithium ion secondary battery
JP2022085939A JP7237221B2 (en) 2017-08-07 2022-05-26 lithium ion secondary battery
JP2023029518A JP2023076432A (en) 2017-08-07 2023-02-28 Manufacturing method for positive electrode active material and manufacturing method for lithium ion secondary battery

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JP2017152090A JP7081908B2 (en) 2017-08-07 2017-08-07 Lithium ion secondary battery

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JP2019032954A JP2019032954A (en) 2019-02-28
JP2019032954A5 true JP2019032954A5 (en) 2020-09-17
JP7081908B2 JP7081908B2 (en) 2022-06-07

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Publication number Priority date Publication date Assignee Title
KR20210151153A (en) * 2019-04-12 2021-12-13 가부시키가이샤 한도오따이 에네루기 켄큐쇼 Method of manufacturing a cathode active material
KR102566003B1 (en) * 2019-05-03 2023-08-11 주식회사 엘지에너지솔루션 Method for preparing positive electrode for secondary battery, positive electrode manufactured through the method and lithium secondary battery comprising the same
JP7232431B2 (en) * 2019-10-09 2023-03-03 住友電気工業株式会社 Electrodes, battery cells, cell stacks, and redox flow battery systems
CN111129450B (en) 2019-12-02 2023-09-29 华为技术有限公司 Positive electrode material of lithium ion battery and preparation method thereof
US20230044210A1 (en) * 2019-12-27 2023-02-09 Semiconductor Energy Laboratory Co., Ltd. Positive Electrode Active Material Layer, Active Material Layer, Positive Electrode, Secondary Battery, and Vehicle
CN115516689A (en) * 2020-05-22 2022-12-23 株式会社半导体能源研究所 Secondary battery and vehicle including the same
KR20210146521A (en) 2020-05-27 2021-12-06 주식회사 엘지에너지솔루션 Diagnostic method of cause of degradation of lithium secondary battery
CN114094061A (en) * 2021-10-09 2022-02-25 温州大学 Rice-grain-shaped manganese carbonate composite graphene high-performance lithium storage material and lithium battery
WO2023242670A1 (en) * 2022-06-17 2023-12-21 株式会社半導体エネルギー研究所 Lithium-ion secondary battery
CN115863610B (en) * 2023-01-05 2024-01-30 厦门海辰储能科技股份有限公司 Positive electrode material, positive electrode plate, electrode assembly, energy storage device and electric equipment

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AU2003212009A1 (en) * 2002-02-15 2003-09-04 Seimi Chemical Co., Ltd. Particulate positive electrode active material for lithium secondary cell
JP4259393B2 (en) * 2003-05-15 2009-04-30 日亜化学工業株式会社 Positive electrode active material for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery
CN1329307C (en) * 2003-09-16 2007-08-01 清美化学股份有限公司 Composite oxide containing lithium, nickel, cobalt, manganese, and fluorine, process for producing the same, and lithium secondary cell employing it
JP4777733B2 (en) * 2005-09-29 2011-09-21 Agcセイミケミカル株式会社 Method for producing lithium-containing composite oxide
JP6476776B2 (en) * 2014-11-13 2019-03-06 日立金属株式会社 Positive electrode active material, positive electrode, and lithium ion secondary battery

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