JP2019012723A - Electronic component and manufacturing method thereof - Google Patents

Electronic component and manufacturing method thereof Download PDF

Info

Publication number
JP2019012723A
JP2019012723A JP2017127211A JP2017127211A JP2019012723A JP 2019012723 A JP2019012723 A JP 2019012723A JP 2017127211 A JP2017127211 A JP 2017127211A JP 2017127211 A JP2017127211 A JP 2017127211A JP 2019012723 A JP2019012723 A JP 2019012723A
Authority
JP
Japan
Prior art keywords
case
sealing body
electronic component
jis standard
manufacturing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2017127211A
Other languages
Japanese (ja)
Other versions
JP6767316B2 (en
Inventor
卓実 松本
Takumi Matsumoto
卓実 松本
満 米田
Mitsuru Yoneda
満 米田
孝也 酒井
Takaya Sakai
孝也 酒井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nichicon Corp
Original Assignee
Nichicon Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nichicon Corp filed Critical Nichicon Corp
Priority to JP2017127211A priority Critical patent/JP6767316B2/en
Publication of JP2019012723A publication Critical patent/JP2019012723A/en
Application granted granted Critical
Publication of JP6767316B2 publication Critical patent/JP6767316B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Electric Double-Layer Capacitors Or The Like (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

To provide an electronic component in which a thin plate case and a sealing body are sealed by welding, and to provide a manufacturing method thereof.SOLUTION: A manufacturing method of electronic component includes a first step of fitting a metal sealing body 3, having a shape capable of sealing the opening of a metal case 2 and to which an external lead-out terminal is fixed by hermetic seal, to the opening circumference of the case 2 housing an element 1, and then joining the opening circumference of the case 2 by laser welding, and a second step of further joining at least a part of a juncture laser welded in the first step by ultrasonic soldering. The material of the case 2 and the sealing body 3 is preferably selected from a group consisting of pure aluminum of JIS standard A1000, an aluminum-manganese alloy of JIS standard A3000, and aluminum-magnesium alloy of JIS standard A5000, and it may be a different material.SELECTED DRAWING: Figure 3

Description

本発明は、電子部品およびその製造方法に関する。   The present invention relates to an electronic component and a manufacturing method thereof.

外部引出端子をハーメチックシールで封止した金属製封口体とアルミニウムケースを封止する手法としては、例えば下記の特許文献1に記載されるようなレーザー溶接が一般的に挙げられ、封口体とケースの合金番号が同じであれば、レーザー溶接の実施にさほど問題はないが、合金番号が異なる場合には、レーザー溶接が困難になり歩留り悪化の原因になる。特にマグネシウムを相当量含有したアルミニウム合金と純アルミニウムやマグネシウムの含有が少ないアルミニウム合金との溶接においては非常に困難さを増す。   As a method for sealing a metal sealing body in which an external lead terminal is sealed with a hermetic seal and an aluminum case, for example, laser welding as described in Patent Document 1 below is generally cited. If the alloy numbers are the same, there is no problem in carrying out laser welding, but if the alloy numbers are different, laser welding becomes difficult and the yield deteriorates. In particular, it is very difficult to weld an aluminum alloy containing a considerable amount of magnesium and a pure aluminum or an aluminum alloy containing little magnesium.

マグネシウム含有アルミニウム合金と純アルミニウムやマグネシウムの含有が少ないアルミニウム合金を溶接する場合、レーザー出力を高くする必要があるが、薄板(厚さ6mm以下)の場合、接合部に穴が空くなど溶接が困難であった。さらにハーメチックシールを備えたアルミニウム材の溶接では、レーザー出力を高くして熱をかけ過ぎるとハーメチックシール部の気密性が低下するので、レーザー溶接による溶接物の温度が高くなりすぎないよう短時間で溶接を終えなければならない。しかしながら、このような短時間での溶接では、溶接部の強度が弱くなり、溶接部の気密性も低くなるという問題があった。   When welding a magnesium-containing aluminum alloy and pure aluminum or an aluminum alloy containing little magnesium, it is necessary to increase the laser output, but in the case of a thin plate (thickness of 6 mm or less), welding is difficult due to a hole in the joint. Met. Furthermore, in welding aluminum materials with hermetic seals, if the laser output is increased and heat is applied too much, the hermeticity of the hermetic seal will decrease, so that the temperature of the welded product by laser welding will not be too high. We must finish the welding. However, such short-time welding has a problem that the strength of the welded portion is weakened and the airtightness of the welded portion is also lowered.

一方、アルミニウムの溶接手法としては、例えば下記の特許文献2に記載されるような超音波はんだによる接合が知られている。この超音波はんだによる接合は、接合時の温度がレーザー溶接より比較的低いため、ハーメチックシール部の気密性低下の問題はないが、レーザー溶接に比べると溶接時間が長くなり熱ストレスとしてはかえってレーザー溶接より高くなるため、ケース内部の温度が高温となりケース内部に収納した素子に含浸された電解液が気化して内圧が上昇し、漏液する懸念があった。   On the other hand, as an aluminum welding technique, for example, joining by ultrasonic soldering as described in Patent Document 2 below is known. In this ultrasonic soldering, the temperature at the time of joining is relatively lower than that of laser welding, so there is no problem of lowering the hermeticity of the hermetic seal part. Since it becomes higher than welding, the temperature inside the case becomes high, and there is a concern that the electrolyte impregnated in the element housed inside the case is vaporized to increase the internal pressure and leak.

特開2000−067826号公報JP 2000-067826 A 特開平5−069120号公報JP-A-5-069120

本発明は、従来技術における上記の問題点を解決し、ハーメチックシールを有する封口体と金属製ケースの接合において歩留り向上が実現可能な電子部品およびその製造方法を提供することを課題とする。
本発明者等は、種々検討を行った結果、電子部品の製造におけるハーメチックシールを有する封口体とケースの接合の際に、歩留り向上が実現できることを見出して、本発明を完成した。
This invention solves said problem in a prior art, and makes it a subject to provide the electronic component which can implement | achieve a yield improvement in joining of the sealing body which has a hermetic seal, and metal cases, and its manufacturing method.
As a result of various studies, the present inventors have found that the yield can be improved when the sealing body having a hermetic seal and the case are joined in the manufacture of an electronic component, thereby completing the present invention.

前記の課題を解決可能な本発明の電子部品は、
開口部を有する金属製ケースと、前記ケースの内部に収納された素子と、前記開口部を封口する金属製封口体からなるものにおいて、
前記封口体がハーメチックシールで封止された外部引出端子を有し、
前記封口体の一部が前記ケースに嵌め入れられるとともに、前記封口体と前記ケースの開口側先端とをレーザー溶接にて接合した接合層と、少なくとも前記接合層の表面に超音波はんだによるはんだ層を有することを特徴とする。
The electronic component of the present invention capable of solving the above problems is
In a metal case having an opening, an element housed in the case, and a metal sealing body that seals the opening,
The sealing body has an external lead terminal sealed with a hermetic seal,
A part of the sealing body is fitted in the case, a bonding layer in which the sealing body and the opening-side end of the case are bonded by laser welding, and a solder layer made of ultrasonic solder at least on the surface of the bonding layer It is characterized by having.

また、本発明は、上記の特徴を有した電子部品において、前記ケースおよび前記封口体の材質が、JIS規格A1000系の純アルミニウム、JIS規格A3000系のアルミニウム−マンガン系合金および、JIS規格A5000系のアルミニウム−マグネシウム系合金からなるグループより選ばれるものであることを特徴とするものである。   Further, according to the present invention, in the electronic component having the above characteristics, the material of the case and the sealing body is JIS standard A1000 series pure aluminum, JIS standard A3000 series aluminum-manganese alloy, and JIS standard A5000 series. It is selected from the group consisting of aluminum-magnesium alloys.

また、本発明は、上記の特徴を有した電子部品において、前記接合層の厚さが、前記ケースの厚みの1.25倍以上であることを特徴とするものである。   According to the present invention, in the electronic component having the above characteristics, the thickness of the bonding layer is 1.25 times or more the thickness of the case.

また、本発明は、電子部品を製造するための方法であって、当該方法が、
素子が内部に収納された金属製ケースの開口周縁に、当該ケースの開口を封止可能な形状を有し、外部引出端子がハーメチックシールで封止された金属製封口体を嵌め入れ、前記ケースの開口周縁をレーザー溶接により接合する第1の工程、および、
前記第1の工程にてレーザー溶接した接合部分の少なくとも一部を、さらに超音波はんだ付けにより接合する第2の工程
を含むことを特徴とする。
Further, the present invention is a method for manufacturing an electronic component, the method comprising:
A metal sealing body having a shape capable of sealing the opening of the case and having an external lead terminal sealed with a hermetic seal is fitted into the opening periphery of the metal case in which the element is housed. A first step of joining the peripheral edges of the openings by laser welding, and
The method further comprises a second step of joining at least a part of the joining portion laser-welded in the first step by ultrasonic soldering.

また、本発明は、上記の特徴を有した電子部品の製造方法において、前記ケースおよび前記封口体の材質が、JIS規格A1000系の純アルミニウム、JIS規格A3000系のアルミニウム−マンガン系合金および、JIS規格A5000系のアルミニウム−マグネシウム系合金からなるグループより選ばれるものであることを特徴とするものである。   Further, according to the present invention, in the method of manufacturing an electronic component having the above characteristics, the case and the sealing body are made of JIS standard A1000 series pure aluminum, JIS standard A3000 series aluminum-manganese alloy, and JIS. It is selected from the group consisting of standard A5000 series aluminum-magnesium alloys.

また、本発明は、上記の特徴を有した電子部品の製造方法において、前記ケースの材質と前記封口体の材質が異なるものであることを特徴とするものである。   According to the present invention, in the method of manufacturing an electronic component having the above characteristics, the material of the case and the material of the sealing body are different.

本発明によれば、熱ストレスの少ないレーザー溶接を行った後に超音波はんだ付けを行うことによって、熱ストレスによる素子への影響を抑制しながら、電子部品を構成する金属製ケースと金属製封口体の材質が異なる場合であっても接合箇所を気密状態にて封止でき、製品の歩留り向上を実現することができる。   According to the present invention, by performing ultrasonic soldering after performing laser welding with less thermal stress, the metal case and the metal sealing body constituting the electronic component are suppressed while suppressing the influence of the thermal stress on the element. Even if the materials are different, the joint portion can be sealed in an airtight state, and the yield of the product can be improved.

本発明の電子部品の製造方法における製造工程を示す写真で、左側の写真は、素子1のタブと封口体3に固定された外部引出端子のリードピンを接合した後に、ケース2内に素子1を収納し、ケース2の開口周縁に封口体3を嵌め入れる前の状態を示しており、右側の写真は、封口体3をケース2に嵌め入れた後、ケース2の開口周縁をレーザー溶接および超音波はんだ付けにより接合した後の状態を示している。A photograph showing a manufacturing process in the method of manufacturing an electronic component according to the present invention, the photograph on the left shows the element 1 in the case 2 after joining the tab of the element 1 and the lead pin of the external lead terminal fixed to the sealing body 3. The state before storing the sealing body 3 into the opening periphery of the case 2 is shown, and the photograph on the right shows the state where the opening periphery of the case 2 is laser welded and superposed after the sealing body 3 is inserted into the case 2. The state after joining by sonic soldering is shown. 左側の写真は、本発明の製造方法を用いて製造される電子部品の、ケース(接合箇所の下側、材質:A3004材)と封口体(接合箇所の上側、材質:A5083材)の接合箇所におけるレーザー溶接表面の状態を示す写真であり、右側の写真は、接合箇所における溶接断面の状態を示す写真である。The photograph on the left shows the joint location of the case (lower part of the joint, material: A3004) and the sealing body (upper part of the joint, material: A5083) of the electronic component manufactured using the manufacturing method of the present invention. Is a photograph showing the state of the laser welding surface in the right, the photograph on the right is a photograph showing the state of the weld cross section at the joint. 本発明の電子部品の溶接部断面概略図である。It is a welding section section schematic diagram of the electronic parts of the present invention.

本発明における第1の工程(レーザー溶接工程)では、電解液を含浸された素子が内部に収納された金属製ケースの開口周縁に、当該ケースの開口を封止可能な形状を有する金属製封口体を嵌め入れ、金属製ケースの開口周縁をレーザー溶接により接合するが、このレーザー溶接を実施する前、すなわち、素子をケースの内部に収納する前または収納した後に、素子の接続タブとハーメチックシールで封口体に固定された外部引出端子のリードピンを溶接して接合する。本発明では、ケース2の開口周縁に封口体3を嵌め入れた際、封口体3の嵌め入れ側の一部がケース2内に入り込み、ケース2の開口周縁側の内壁面と封口体3が密接して重なった部分が存在し、この重なった部分がレーザー溶接される。
そして、第2の工程(超音波はんだ付け工程)においては、レーザー溶接した接合部分の少なくとも一部を、さらに超音波はんだ付けし、ケース2と封口体3との気密性の向上を図る。
In the first step (laser welding step) of the present invention, a metal seal having a shape capable of sealing the opening of the case around the periphery of the opening of the metal case in which the element impregnated with the electrolyte is housed. Insert the body and join the opening edge of the metal case by laser welding, but before performing this laser welding, that is, before or after storing the element inside the case, the connection tab and hermetic seal of the element And welding the lead pins of the external lead terminals fixed to the sealing body. In the present invention, when the sealing body 3 is inserted into the opening periphery of the case 2, a part on the insertion side of the sealing body 3 enters the case 2, and the inner wall surface and the sealing body 3 on the opening peripheral side of the case 2 are There are closely overlapping portions, and these overlapping portions are laser welded.
In the second step (ultrasonic soldering step), at least a part of the laser welded joint is further ultrasonically soldered to improve the airtightness between the case 2 and the sealing body 3.

図1には、本発明を用いて電子部品を製造する際の様子が写真により示されており、左側の写真には、素子1の接続タブと封口体3に固定された外部引出端子のリードピンを接合した後、ケース2内に素子1を収納する際の状態が示されており、右側の写真には、ケース2の開口周縁に封口体3を嵌め入れ、ケース2の開口周縁をレーザー溶接し、更に超音波はんだ付けにより接合して得られた電子部品の外観が示されている。   FIG. 1 shows a photograph of an electronic component manufactured using the present invention. The left photograph shows a lead tab of an external lead terminal fixed to the connection tab of the element 1 and the sealing body 3. The state when the element 1 is housed in the case 2 is shown after the bonding is performed. The right-hand photo shows that the sealing body 3 is fitted into the opening periphery of the case 2 and the opening periphery of the case 2 is laser welded. Further, the appearance of the electronic component obtained by joining by ultrasonic soldering is shown.

本発明では、レーザー溶接工程を実施する際、接合部分の気密性を向上させるために、レーザー溶接による接合部分の溶接深さ(接合層の厚さ)を、ケース2の厚みの1.25倍以上とすることが好ましく、レーザーによる入熱を抑えつつも、封口体3に形成されているハーメチックシールにガラスクラックが生じない程度にまで溶接を深く入れることが重要である。また、レーザー溶接の際には、溶接部に電解液が付着しないようにし、電解液量を低減させ溶接時の電解液の気化を極力抑えることも重要である。
本発明の製造方法では、電子部品の製造に使用される一般的なレーザー溶接装置がいずれも使用でき、溶接条件は、使用するケースと封口体の材質によって適宜選択することができる。
In the present invention, when the laser welding process is performed, the welding depth (the thickness of the joining layer) of the joining portion by laser welding is 1.25 times the thickness of the case 2 in order to improve the airtightness of the joining portion. It is preferable to make the above, and it is important to deeply weld to such an extent that glass cracks do not occur in the hermetic seal formed in the sealing body 3 while suppressing heat input by the laser. In laser welding, it is also important to prevent the electrolyte from adhering to the welded portion, to reduce the amount of the electrolyte, and to minimize the evaporation of the electrolyte during welding.
In the production method of the present invention, any general laser welding apparatus used for the production of electronic components can be used, and the welding conditions can be appropriately selected depending on the case used and the material of the sealing body.

本発明では、電子部品を構成する金属製ケースと金属製封口体が同じ材質(同種金属)であっても異なる材質(異種金属)であっても、確実に接合箇所を気密封止することができる。
本発明においては、前記ケースと前記封口体の材質は、JIS規格A1000系の純アルミニウム、JIS規格A3000系のアルミニウム−マンガン系(Al−Mn)合金および、JIS規格A5000系のアルミニウム−マグネシウム系(Al−Mg)合金からなるグループより選ばれものであることが好ましい。
In the present invention, even if the metal case and the metal sealing body constituting the electronic component are made of the same material (same metal) or different materials (heterogeneous metal), the joint portion can be surely hermetically sealed. it can.
In the present invention, the materials of the case and the sealing body are JIS standard A1000 series pure aluminum, JIS standard A3000 series aluminum-manganese (Al-Mn) alloy, and JIS standard A5000 series aluminum-magnesium ( It is preferably selected from the group consisting of (Al—Mg) alloys.

図2には、ケースとしてA3004材(Al−Mn合金)を使用し、ハーメチックシールを有する封口体としてA5083材(Al−Mg合金)を使用した際の、接合箇所におけるレーザー溶接表面の状態(左側の写真)と、接合箇所における溶接断面の状態(右側の写真)が示されており、右側の写真から、ケース(接合部から写真の下側方向に延びた色の濃い部分)の厚みよりも深い位置まで、実質的に断面V字状に溶接されていることがわかる。   FIG. 2 shows the state of the laser welding surface at the joint (left side) when A3004 material (Al—Mn alloy) is used as the case and A5083 material (Al—Mg alloy) is used as the sealing body having a hermetic seal. ) And the state of the weld cross section at the joint (right photo). From the right photo, the thickness of the case (the dark part extending from the joint to the lower side of the photo) is shown. It can be seen that the welding is substantially performed in a V-shaped cross section up to a deep position.

本発明における第2の工程(超音波はんだ付け工程)では、レーザー溶接した接合部分の少なくとも一部を、さらに超音波はんだ付けにより接合することによって、気密性の向上を図ることが可能である。特にケースおよび/または封口体の材質がA5000系(Al−Mg合金)である場合には、その合金に含まれるMg等の添加物の影響により溶接が不安定となるため、超音波はんだを用いた接合方法が有効である。
本発明では、レーザー溶接した接合部分を全て、即ち、ケースの開口周縁全周を、超音波はんだ付けにより接合してもよいが、熱ストレスの少ないレーザー溶接で接合を行った後に、接合部の気密性確認試験を行い、気密不良が確認された箇所のみ超音波はんだで補填してもよい。
以下、本発明の電子部品の製造例を示して本発明を具体的に説明するが、本発明は、これに限定されるものではない。
In the second step (ultrasonic soldering step) in the present invention, it is possible to improve the airtightness by joining at least a part of the laser welded joining portion by ultrasonic soldering. In particular, when the material of the case and / or the sealing body is an A5000 series (Al-Mg alloy), welding becomes unstable due to the influence of additives such as Mg contained in the alloy. The joining method is effective.
In the present invention, the entire laser welded joint portion, that is, the entire circumference of the opening periphery of the case may be joined by ultrasonic soldering, but after joining by laser welding with less thermal stress, An airtightness confirmation test may be performed, and only portions where airtight defects are confirmed may be supplemented with ultrasonic solder.
Hereinafter, the present invention will be specifically described with reference to production examples of the electronic component of the present invention, but the present invention is not limited thereto.

〔本発明によるレーザー溶接+超音波はんだ封止を行った場合と、従来法によるレーザー溶接封止を行った場合の歩留り比較〕
電子部品であるアルミ電解コンデンサを一例に説明する。アルミ電解コンデンサ素子を収納するために一方向が開口した角形のケース(外形寸法:29mm×15mm×3mm)として、A3004材(Al−Mn合金)から成り、長辺側の厚みが0.175mm、短辺側の厚みが0.250mmのものを準備した。
上記ケースの開口を封止するための封口体としては、A1000系(A1100材、純アルミニウム)、A3000系(A3004材、Al−Mn合金)、A5000系(A5083材、Al−Mg合金)から成り、封口体のケースより外部に位置する外形寸法が14.95mm×2.95mmのものをそれぞれ準備した。
[Yield Comparison between Laser Welding + Ultrasonic Solder Sealing According to the Present Invention and Laser Welding Sealing Using Conventional Method]
An aluminum electrolytic capacitor, which is an electronic component, will be described as an example. As a rectangular case (outside dimension: 29 mm x 15 mm x 3 mm) opened in one direction to accommodate the aluminum electrolytic capacitor element, it is made of A3004 material (Al-Mn alloy) and has a long side thickness of 0.175 mm, A short side having a thickness of 0.250 mm was prepared.
The sealing body for sealing the opening of the case is made of A1000 series (A1100 material, pure aluminum), A3000 series (A3004 material, Al-Mn alloy), A5000 series (A5083 material, Al-Mg alloy). The outer dimensions of the outer body located outside the case of the sealing body were 14.95 mm × 2.95 mm.

1.本発明によるレーザー溶接+超音波はんだ封止による封止品の製造
上記ケースの開口に上記の各封口体を嵌め入れ、レーザー溶接による接合層の厚さが約0.400mm(ケース長辺側厚みに対して2.29倍、ケース短辺側厚みに対して1.60倍)となるように、ケースの開口周縁をレーザー出力:250W、溶接速度:120mm/秒、焦点距離:+0.5mmのレーザー溶接条件にて溶接し、封止した。次に、溶接部分をさらに、こて温度:350℃、振動数:60kHzの条件にて、Sn70〜80%、Zn3〜5%、Sb3〜5%、In15〜25%のはんだを用いて超音波はんだ付けで封止し、封止品(本発明品)を得た。本発明品の溶接部断面概略図を図3に示す。ケース2と封口体3の接合箇所にレーザー溶接による接合層4がケース2の厚みの1.25倍以上に形成され、接合層4の表面全体が超音波によるはんだ層5で覆われている。なお、点線はレーザー溶接前の状態を示している。
1. Manufacture of sealed products by laser welding and ultrasonic soldering according to the present invention Each of the sealing bodies is fitted into the opening of the case, and the thickness of the bonding layer by laser welding is about 0.400 mm (thickness on the long side of the case) The laser output is 250 W, the welding speed is 120 mm / second, and the focal length is +0.5 mm. Welded and sealed under laser welding conditions. Next, the welded portion is further subjected to ultrasonic using a solder of Sn 70 to 80%, Zn 3 to 5%, Sb 3 to 5%, In 15 to 25% under the conditions of a trowel temperature: 350 ° C. and a frequency: 60 kHz. Sealing was performed by soldering to obtain a sealed product (product of the present invention). FIG. 3 shows a schematic cross-sectional view of the welded part of the product of the present invention. A joining layer 4 by laser welding is formed at 1.25 times or more of the thickness of the case 2 at the joining portion of the case 2 and the sealing body 3, and the entire surface of the joining layer 4 is covered with the solder layer 5 by ultrasonic waves. In addition, the dotted line has shown the state before laser welding.

2.従来のレーザー溶接封止のみによる封止品の製造
上記1.と同条件でレーザー溶接のみ行って、封止品(従来品)を得た。
2. Manufacturing of sealed products using only conventional laser welding sealing Only the laser welding was performed under the same conditions as above to obtain a sealed product (conventional product).

3.気密性確認試験
上記で得られた従来品および本発明品をフロリナート(商標)中に120℃にて浸漬し、封止部からの気泡の発生の有無を1分間目視により観察し、気泡の発生のないものを「良品」、気泡の発生のあるものを「不良品」として評価した。
なお、上記の気密性確認試験は、封口体の材質(3種類)ごとに、それぞれ10個ずつ行った。
その結果、従来品(レーザー溶接封止のみによる封止品)についての歩留りが、A1000系の場合9/10個(90%)、A3000系の場合7/10個(70%)、A5000系の場合5/10個(50%)であったのに対し、本発明品(レーザー溶接+超音波はんだ封止による封止品)についての歩留りは、A1000系の場合10/10個(100%)、A3000系の場合10/10個(100%)、A5000系の場合10/10個(100%)であった。
3. Airtightness confirmation test The conventional product and the product of the present invention obtained above were immersed in Florinart (trademark) at 120 ° C, and the presence or absence of bubbles from the sealed portion was visually observed for 1 minute to generate bubbles. Those with no bubbles were evaluated as “good”, and those with bubbles were evaluated as “defective”.
In addition, said 10 airtightness confirmation tests were each performed for every material (3 types) of a sealing body.
As a result, the yield of the conventional product (sealed product only by laser welding sealing) is 9/10 (90%) for the A1000 series, 7/10 (70%) for the A3000 series, and the A5000 series. In the case of 5/10 pieces (50%), the yield of the product of the present invention (sealed product by laser welding + ultrasonic solder sealing) was 10/10 pieces (100%) in the case of A1000 series. In the case of the A3000 series, 10/10 pieces (100%), and in the case of the A5000 series, the number was 10/10 pieces (100%).

上記の歩留り比較試験から、本発明は、従来法における問題点を解消できるものであり、レーザー溶接と超音波はんだ封止の併用によって、ケースとハーメチックシールを有する封口体の材質が同じであっても異なっても、接合箇所を確実に気密封止することができ、製品の歩留り向上を実現できることが確認された。   From the above yield comparison test, the present invention can solve the problems in the conventional method, and the combination of laser welding and ultrasonic solder sealing makes the material of the sealing body having the case and the hermetic seal the same. However, it was confirmed that the joints could be reliably hermetically sealed and the product yield could be improved.

本発明の電子部品は、熱ストレスを押さえたレーザー溶接を行った後に超音波はんだ付けを行うことによって、レーザー溶接のみでは溶接が非常に困難であると言われていた薄板とA5000系の合金からなる封口体の溶接であっても、接合箇所を気密状態にて封止することができ、歩留り良く電子部品を製造するのに非常に有用である。   The electronic component of the present invention comprises a thin plate and an A5000 series alloy, which are said to be very difficult to weld by laser welding alone, by performing ultrasonic soldering after laser welding with suppressed thermal stress. Even when the sealing body is welded, the joint portion can be sealed in an airtight state, which is very useful for manufacturing an electronic component with a high yield.

また、本発明の実施例としてアルミ電解コンデンサを例示して説明したが、電気二重層コンデンサ、リチウムイオンキャパシタ、二次電池などにも利用することができる。   Moreover, although the aluminum electrolytic capacitor was illustrated and demonstrated as an Example of this invention, it can utilize also for an electrical double layer capacitor, a lithium ion capacitor, a secondary battery, etc.

1 素子
2 ケース
3 封口体
4 接合層(レーザー溶接による溶接部)
5 はんだ層
1 element 2 case 3 sealing body 4 bonding layer (welded part by laser welding)
5 Solder layer

Claims (6)

開口部を有する金属製ケースと、前記ケースの内部に収納された素子と、前記開口部を封口する金属製封口体からなる電子部品において、
前記封口体がハーメチックシールで封止された外部引出端子を有し、
前記封口体の一部が前記ケースに嵌め入れられるとともに、前記封口体と前記ケースの開口側先端とをレーザー溶接にて接合した接合層と、少なくとも前記接合層の表面に超音波はんだによるはんだ層を有することを特徴とする電子部品。
In an electronic component comprising a metal case having an opening, an element housed in the case, and a metal sealing body that seals the opening,
The sealing body has an external lead terminal sealed with a hermetic seal,
A part of the sealing body is fitted in the case, a bonding layer in which the sealing body and the opening-side end of the case are bonded by laser welding, and a solder layer made of ultrasonic solder at least on the surface of the bonding layer An electronic component comprising:
前記ケースおよび前記封口体の材質が、JIS規格A1000系の純アルミニウム、JIS規格A3000系のアルミニウム−マンガン系合金および、JIS規格A5000系のアルミニウム−マグネシウム系合金からなるグループより選ばれるものであることを特徴とする請求項1に記載の電子部品。   The material of the case and the sealing body is selected from the group consisting of JIS standard A1000 series pure aluminum, JIS standard A3000 series aluminum-manganese alloy, and JIS standard A5000 series aluminum-magnesium alloy. The electronic component according to claim 1. 前記接合層の厚さが、前記ケースの厚みの1.25倍以上であることを特徴とする請求項1または2に記載の電子部品。   The electronic component according to claim 1, wherein a thickness of the bonding layer is 1.25 times or more of a thickness of the case. 電子部品を製造するための方法であって、当該方法が、
素子が内部に収納された金属製ケースの開口周縁に、当該ケースの開口を封止可能な形状を有し、外部引出端子がハーメチックシールで封止された金属製封口体を嵌め入れ、前記ケースの開口周縁をレーザー溶接により接合する第1の工程、および、
前記第1の工程にてレーザー溶接した接合部分の少なくとも一部を、さらに超音波はんだ付けにより接合する第2の工程
を含むことを特徴とする電子部品の製造方法。
A method for manufacturing an electronic component, the method comprising:
A metal sealing body having a shape capable of sealing the opening of the case and having an external lead terminal sealed with a hermetic seal is fitted into the opening periphery of the metal case in which the element is housed. A first step of joining the peripheral edges of the openings by laser welding, and
A method for manufacturing an electronic component, comprising: a second step of joining at least a part of the joining portion laser-welded in the first step by ultrasonic soldering.
前記ケースおよび前記封口体の材質が、JIS規格A1000系の純アルミニウム、JIS規格A3000系のアルミニウム−マンガン系合金および、JIS規格A5000系のアルミニウム−マグネシウム系合金からなるグループより選ばれるものであることを特徴とする請求項4に記載の電子部品の製造方法。   The material of the case and the sealing body is selected from the group consisting of JIS standard A1000 series pure aluminum, JIS standard A3000 series aluminum-manganese alloy, and JIS standard A5000 series aluminum-magnesium alloy. The manufacturing method of the electronic component of Claim 4 characterized by these. 前記ケースの材質と前記封口体の材質が異なるものであることを特徴とする請求項4または5に記載の電子部品の製造方法。   6. The method of manufacturing an electronic component according to claim 4, wherein a material of the case and a material of the sealing body are different.
JP2017127211A 2017-06-29 2017-06-29 Electronic components and their manufacturing methods Active JP6767316B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2017127211A JP6767316B2 (en) 2017-06-29 2017-06-29 Electronic components and their manufacturing methods

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2017127211A JP6767316B2 (en) 2017-06-29 2017-06-29 Electronic components and their manufacturing methods

Publications (2)

Publication Number Publication Date
JP2019012723A true JP2019012723A (en) 2019-01-24
JP6767316B2 JP6767316B2 (en) 2020-10-14

Family

ID=65227931

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2017127211A Active JP6767316B2 (en) 2017-06-29 2017-06-29 Electronic components and their manufacturing methods

Country Status (1)

Country Link
JP (1) JP6767316B2 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61240569A (en) * 1985-04-18 1986-10-25 Matsushita Electric Ind Co Ltd Manufacture of sealed lead-acid battery
JPS63279135A (en) * 1987-05-12 1988-11-16 Furukawa Electric Co Ltd:The Pinhole checker
JP2004095321A (en) * 2002-08-30 2004-03-25 Matsushita Electric Ind Co Ltd Square battery
JP2016072175A (en) * 2014-10-01 2016-05-09 住友電気工業株式会社 Lead member and manufacturing method of lead member
WO2016195027A1 (en) * 2015-06-03 2016-12-08 エヌイーシー ショット コンポーネンツ株式会社 Airtight terminal, aluminum electrolytic capacitor and method for manufacturing aluminum electrolytic capacitor

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61240569A (en) * 1985-04-18 1986-10-25 Matsushita Electric Ind Co Ltd Manufacture of sealed lead-acid battery
JPS63279135A (en) * 1987-05-12 1988-11-16 Furukawa Electric Co Ltd:The Pinhole checker
JP2004095321A (en) * 2002-08-30 2004-03-25 Matsushita Electric Ind Co Ltd Square battery
JP2016072175A (en) * 2014-10-01 2016-05-09 住友電気工業株式会社 Lead member and manufacturing method of lead member
WO2016195027A1 (en) * 2015-06-03 2016-12-08 エヌイーシー ショット コンポーネンツ株式会社 Airtight terminal, aluminum electrolytic capacitor and method for manufacturing aluminum electrolytic capacitor

Also Published As

Publication number Publication date
JP6767316B2 (en) 2020-10-14

Similar Documents

Publication Publication Date Title
JP6605549B2 (en) Penetration
JP7009499B2 (en) A substrate for the penetration of a conductor, and a housing member of a housing comprising such a substrate, especially a battery housing.
JP5556364B2 (en) Metal lead and its manufacturing method
JP2012033339A (en) Large scale lithium ion battery for motor vehicle, dwelling house, and industrial apparatus
WO2014073665A1 (en) Cover material for hermitic sealing and package for containing electronic component
JP2009260023A (en) Electrochemical cell, manufacturing method thereof, and sealing member
JP2015032441A (en) Tab lead and nonaqueous electrolyte battery
TWI636527B (en) Cover material for airtight seal, manufacturing method of cover material for airtight seal, and packaging for storing electronic parts
JPH1186809A (en) Jointing method of container
JP6767316B2 (en) Electronic components and their manufacturing methods
JP2005190776A (en) Sealed type battery
JP5569261B2 (en) Lead member and lead member manufacturing method
TW575974B (en) Closed type battery and its manufacturing method
JP6405856B2 (en) Lead member and lead member manufacturing method
JP2005123060A (en) Manufacturing method of sealed battery
JP2008124163A (en) Airtight terminal, and its manufacturing method
JP6031958B2 (en) Sealed container and method for manufacturing sealed container
CN112714575B (en) Aluminum-silicon composite packaging cover plate and manufacturing method thereof
JP2010177016A (en) Seal terminal and battery
JPS6253949B2 (en)
JPH11267779A (en) Production of blind container
JP2010016759A (en) Air-tightly sealed electronic component
JPH02297955A (en) Airtight sealing structure
KR101714146B1 (en) Socket for aluminum wire and producing method thereof
JP2003257470A (en) Battery

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20191212

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20200907

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20200916

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20200917

R150 Certificate of patent or registration of utility model

Ref document number: 6767316

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250