JP2018509594A - ナフサ流の相対評価法 - Google Patents
ナフサ流の相対評価法 Download PDFInfo
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- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
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- G01—MEASURING; TESTING
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- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
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- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2823—Oils, i.e. hydrocarbon liquids raw oil, drilling fluid or polyphasic mixtures
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- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
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- G01N33/28—Oils, i.e. hydrocarbon liquids
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; viscous liquids; paints; inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2835—Oils, i.e. hydrocarbon liquids specific substances contained in the oil or fuel
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- G06Q30/00—Commerce
- G06Q30/02—Marketing; Price estimation or determination; Fundraising
- G06Q30/0283—Price estimation or determination
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/305—Octane number, e.g. motor octane number [MON], research octane number [RON]
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/308—Gravity, density, e.g. API
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/88—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86
- G01N2030/8809—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86 analysis specially adapted for the sample
- G01N2030/884—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86 analysis specially adapted for the sample organic compounds
- G01N2030/8854—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86 analysis specially adapted for the sample organic compounds involving hydrocarbons
Abstract
Description
本出願は、2015年1月5日に出願された米国特許仮出願第62/099,788号明細書の利益を主張するものであり、その開示が参照により本明細書に組み込まれる。
式中:
吸光度=所定の波数範囲、例えば、4,000cm−1〜12,821cm−1の範囲で検出されたピークの原油溶液の吸光度値。
パラフィン含有量=KPa+KPb*DEN+KPc*DEN2+KPd*DEN3+KPe*I+KPf*I2+KPg*I3+KPh*DEN*I (1b)
芳香族含有量=KAa+KAb*DEN+KAc*DEN2+KAd*DEN3+KAe*I+KAf*I2+KAg*I3+KAh*DEN*I (1c)
ナフテン含有量=100−パラフィン含有量−芳香族含有量 (1d)
式中;
式中、KPaからKPhおよびKAaからKAhは定数であり、
DEN=15℃での原油の密度、および
I=指数、例えば、式(1)において与えられるFT NIR指数、または原油サンプルの他の分析によって与えられる他の指数である。
供給品質=N+2A (2)
Y=KYa*(N+2A)2+KYb*(N+2A)+KYc*Rt2+KYd*Rt
+KYe (3)
式中、KYaからKYeは定数である。
未加工エタン収率、C2r=KC2ra*Y+KC2rb (5)
未加工プロパン収率、C3r=KC3ra*Y+KC3rb (6)
未加工ブタン収率、C4r=KC4ra*Y+KC4rb (7)
未加工ガソリン収率、Gr=KGra*Y+KGrb (8)
未加工水素収率、Hr=KHra*Y+KHrb*Rt+KHrc (9)
式中、KC1raからKC4rb、KGra、KGrbおよびKHRAからKHrcは定数である。
全未加工収率、Tr=C1r+C2r+C3r+C4r+Gr+Hr(10)
規格化メタン収率、C1n=(C1r*100)/Tr (11)
規格化エタン収率、C2n=(C2r*100)/Tr (12)
規格化プロパン収率、C3n=(C3r*100)/Tr (13)
規格化ブタン収率、C4n=(C4r*100)/Tr (14)
規格化ガソリン収率、Gn=(Gr*100)/Tr (15)
規格化水素収率、Hn=(Hr*100)/Tr (16)
メタンの価値、C1v=(C1n/100)*C1P
(式中、C1Pはメタンの価値である。) (17)
エタンの価値、C2v=(C2n/100)*C2P
(式中、C2Pはエタンの価値である。) (18)
プロパンの価値、C3v=(C3n/100)*C3P
(式中、C3Pはプロパンの価値である。) (19)
ブタンの価値、C4v=(C4n/100)*C4P
(式中、C4Pはブタンの価値である。) (20)
ガソリンの価値、Gv=(Gn/100)*GP
(式中、GPはガソリンの価値である。) (21)
水素の価値、Hv=(Hn/100)*HP
(式中、HPは水素の価値である。) (22)
ナフサ単価($/ton)、NPT=C1v+C2v+C3v+C4v+Gv+Hv
(23)
NPB=(NPT/密度)*159リットル/バレル (24)
供給品質=N+2A=14.98+2*8.05=31.08 (2)。
式(3):KYa=−0.01702;KYb=2.192;KYc
=−0.03333;KYd=5.531;およびKYe
=−206.63
式(4)〜(9):KC1ra=−0.12393;KC1rb=11.42;KC2ra=−0.17991;KC2rb=16.8;KC3ra=−0.25714;KC3rb=24.24286;KC4ra=−0.28705;KC4rb=27.27143;KGra=0.839255;KGrb=18.09532;KHra=0.0605;KHrb=0.1;およびKHrc=−12.145。
Y=KYa*(N+2A)2+KYb*(N+2A)+KYc*Rt2+KYd*Rt
+KYe (3)
Y=(−0.01702)*(31.08)2+2.192*31.08−0.03333*(98)2+5.531*98−206.63
Y=66.99.
C1r=KC1ra*Y+KC1rb=0.12393*66.99+11.42
=3.11 (4)
C2r=KC2ra*Y+KC2rb=−0.17991*66.99+16.8
=4.75 (5)
C3r=KC3ra*Y+KC3rb=−0.25714*66.99
+24.24286=7.02 (6)
C4r=KC4ra*Y+KC4rb=−0.28705*66.99
+27.27143=8.04 (7)
Gr=KGra*Y+KGrb=0.839255*66.99+18.09532
=74.32 (8)
Hr=KHra*Y+KHrb*Rt+KHrc=0.0605*66.99
+0.1*98−12.145=1.7 (9)
Tr =C1r+C2r+C3r+C4r+Gr+Hr (10)
=3.11+4.75+7.02+8.04+74.32+1.71
=98.95
C1n=(C1r*100)/Tr=(3.11*100)/98.94917
=3.14 (11)
C2n=(C2r*100)/Tr=(4.75*100)/98.94917
=4.80 (12)
C3n=(C3r*100)/Tr=(7.02*100)/98.94917
=7.09 (13)
C4n=(C4r*100)/Tr=(8.04*100)/98.94917
=8.13 (14)
Gn=(Gr*100)/Tr=(74.32*100)/98.94917
=75.11 (15)
Hn=(Hr*100)/Tr(1.71*100)/98.94917
=1.73 (16)
C1v=(3.14/100)*$152.44/ton=$4.80/ton
(17)
C2v=(4.80/100)*$149.81/ton=$7.19/ton
(18)
C3v=(7.09/100)*$343.71/ton=$24.37/ton
(19)
C4v=(8.13/100)*$499.03/ton=$40.57/ton
(20)
Gv=(75.11/100)*$601.63/ton=$451.88/to
(21)
Hv=(1.73/100)*$391.60/ton=$6.77/ton
(22)
NPT=4.80+7.19+24.37+40.57+451.88+6.77
=$535.58/ton (23)
NPB=($535.58/ton/750リットル/ton)*159リットル/
バレル=$113.54/バレル (24)
パラフィン含有量=KPa+KPb*DEN+KPc*DEN2+KPd*DEN3
+KPe*I+KPf*I2+KPg*I3+KPh*DEN*I
(1b)
芳香族含有量=KAa+KAb*DEN+KAc*DEN2+KAd*DEN3
+KAe*I+KAf*I2+KAg*I3+KAh*DEN*I
(1c)
ナフテン含有量=100−パラフィン含有量−芳香族含有量 (1d)
Claims (3)
- 原油サンプルから得られるナフササンプルに、前記原油サンプルの分析に基づいて値を与えるためのシステムであって:
計算モジュールおよび原油分析データを格納する不揮発性メモリデバイスと;
前記メモリに結合されているプロセッサと;
前記原油分析データの指数および前記原油サンプルの密度の関数として芳香族含有量およびナフテン含有量を計算し、かつ前記ナフササンプルに与える第1の計算モジュールと;
前記芳香族含有量およびナフテン含有量の関数として全製品収率を計算し、かつ与える第2の計算モジュールと;
前記与えられた全液体製品収率の関数として未加工製品収率を計算し、かつメタン、エタン、プロパン、ブタンおよびガソリンのそれぞれに与える第3の計算モジュールと;
前記与えられた全液体製品収率の関数として水素の未加工製品収率を計算し、かつ与える第4の計算モジュールと;および
水素、メタン、エタン、プロパン、ブタンおよびガソリンのそれぞれの前記未加工製品収率および各製品の単価の関数として値を計算し、かつ水素、メタン、エタン、プロパン、ブタンおよびガソリンのそれぞれに与える第5の計算モジュールと
を含むシステム。 - コンピュータを操作して、原油サンプルから得られるナフササンプルに、前記原油サンプルの分析に基づいて値を与えるための方法であって:
前記コンピュータに原油分析データを入力する工程と;
前記原油分析データの指数および前記原油サンプルの密度の関数として芳香族含有量およびナフテン含有量を計算し、かつ前記ナフササンプルに与える工程と;
前記芳香族含有量およびナフテン含有量の関数として全製品収率を計算し、かつ与える工程と;
前記与えられた全液体製品収率の関数として未加工製品収率を計算し、かつメタン、エタン、プロパン、ブタンおよびガソリンのそれぞれに与える工程と;
前記与えられた全液体製品収率の関数として水素の未加工製品収率を計算し、かつ与える工程と;および
水素、メタン、エタン、プロパン、ブタンおよびガソリンのそれぞれの前記未加工製品収率および各製品の単価の関数として値を計算し、かつ水素、メタン、エタン、プロパン、ブタンおよびガソリンのそれぞれに与える工程と
を含む方法。 - 前記原油分析データが、フーリエ変換近赤外分光法、フーリエ変換赤外分光法、フーリエ変換イオンサイクロトロン質量分析法、飛行時間型質量分析法、紫外可視分光法、レーザー誘起紫外分光法、核磁気分光法、蛍光分光法、ラマン分光法、ガスクロマトグラフィー、液体クロマトグラフィー、超臨界流体クロマトグラフィー、熱重量分析および示差走査熱量測定法からなる群から選択される分析手法から得られる請求項1または2に記載のシステムまたは方法。
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US201562099788P | 2015-01-05 | 2015-01-05 | |
US62/099,788 | 2015-01-05 | ||
PCT/US2016/012160 WO2016111997A1 (en) | 2015-01-05 | 2016-01-05 | Relative valuation method for naphtha streams |
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JP2018509594A true JP2018509594A (ja) | 2018-04-05 |
JP2018509594A5 JP2018509594A5 (ja) | 2019-05-30 |
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US (1) | US10845355B2 (ja) |
EP (1) | EP3243072A1 (ja) |
JP (1) | JP2018509594A (ja) |
KR (1) | KR20170118713A (ja) |
CN (1) | CN107250787B (ja) |
SA (1) | SA517381857B1 (ja) |
SG (1) | SG11201705473XA (ja) |
WO (1) | WO2016111997A1 (ja) |
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US10371633B2 (en) | 2017-10-30 | 2019-08-06 | Saudi Arabian Oil Company | Determining a specific gravity of a sample |
US11662288B2 (en) | 2020-09-24 | 2023-05-30 | Saudi Arabian Oil Company | Method for measuring API gravity of petroleum crude oils using angle-resolved fluorescence spectra |
US11320413B1 (en) | 2021-02-24 | 2022-05-03 | Saudi Arabian Oil Company | Characterization of crude oil by time of flight mass spectrometry |
TWI807566B (zh) * | 2021-12-30 | 2023-07-01 | 台灣化學纖維股份有限公司 | 輕油產品評估裝置、方法及其電腦程式產品 |
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KR20170118713A (ko) | 2017-10-25 |
WO2016111997A1 (en) | 2016-07-14 |
SA517381857B1 (ar) | 2021-04-11 |
CN107250787B (zh) | 2021-02-02 |
SG11201705473XA (en) | 2017-08-30 |
US20170370897A1 (en) | 2017-12-28 |
CN107250787A (zh) | 2017-10-13 |
US10845355B2 (en) | 2020-11-24 |
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