JP2018203759A - Composition containing heterocyclic compound - Google Patents

Abstract

To provide a composition having excellent pest control effect on harmful arthropod.SOLUTION: There is provided a composition containing a compound represented by the formula (I), where Q represents a substituent having a skeleton such as imidazolopyridine, triazolopyridine, T represents such as a C1-C10 chain hydrocarbon group having one or more halogen atom, Arepresents a nitrogen atom or the like, Arepresents a nitrogen atom or the like, Arepresents a nitrogen atoms or the like, and one or more kind of components selected from the group consisting of Group (a): a group consisting of insecticidal components, an acaricidal components, and a nematocidal components; Group (b): sterilization components; Group (c): a plant growth regulator; Group (d): phytotoxicity reducing agents; Group (e): synergist; Group (f): repellent components; Group (g): molluscicidal components; Group (h): insect pheromone; Group (i): herbicidal activity components; Group (j): microorganism materials.SELECTED DRAWING: None

Description

  The present invention relates to a composition containing a heterocyclic compound.

So far, various compounds have been studied and put into practical use for the purpose of controlling harmful arthropods.
Moreover, it is known that a certain compound has a pest control effect (for example, refer patent document 1).

International Publication No. 2016/121969

  An object of the present invention is to provide a composition having an excellent control effect against harmful arthropods.

The present invention is as follows.
[1] Formula (I):
[Where:
Q represents a group represented by the following formula Q1, a group represented by the following formula Q2, a group represented by the following formula Q3, or a group represented by the following formula Q4.
(Where
n represents 0, 1 or 2;
R ² represents a cyclopropyl group, a cyclopropylmethyl group, or a C1-C6 alkyl group optionally having one or more halogen atoms,
Z ¹ represents a nitrogen atom or CR ^3c ,
Z ² represents a nitrogen atom or CR ^3d ,
Z ³ represents a nitrogen atom or CR ^3e ,
Z ⁴ represents NR ³⁴ , CR ³⁶ R ³⁷ or C (O),
Z ⁵ represents NR ³⁵ , CR ³⁸ R ³⁹ or C (O),
R ^3a , R ^3b , R ^3c , R ^3d and R ^3e are each independently a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from group B, from group E C3-C7 cycloalkyl group optionally having one or more substituents selected, phenyl group optionally having one or more substituents selected from group H, one or more substitutions selected from group H 5- or 6-membered aromatic heterocyclic group optionally having a group, OR ¹² , NR ¹¹ R ¹² , NR ^11a R ^12a , NR ²⁹ NR ¹¹ R ¹² , NR ²⁹ OR ¹¹ , NR ¹¹ C (O) R ¹³ , NR ²⁹ NR ¹¹ C (O) R ¹³ , NR ¹¹ C (O) OR ¹⁴ , NR ²⁹ NR ¹¹ C (O) OR ¹⁴ , NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , NR ²⁹ NR ¹¹ C ( ^{O) NR 15 R 16, N} = CHNR 15 R 16, N = S (O) x R 15 R 16, C (O) OR 17, cyano group, nitro group, halogen Represents an atom or a hydrogen atom,
x represents 0 or 1;
R ³⁴ and R ³⁵ each independently have a C1-C6 chain hydrocarbon group which may have one or more substituents selected from group B, and one or more substituents selected from group C. An optionally substituted phenyl group, a 5- or 6-membered aromatic heterocyclic group optionally having one or more substituents selected from group C, and one or more substituents selected from group C; And represents a C3-C7 alicyclic hydrocarbon group, C (O) OR ^d , C (O) R ^d , C (O) NR ^e R ^f , S (O) ₂ R ⁱ , or a hydrogen atom,
R ³⁶ , R ³⁷ , R ³⁸ and R ³⁹ are each independently a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from group B, 1 selected from group C A phenyl group optionally having the above substituents, a C3-C7 alicyclic hydrocarbon group optionally having one or more substituents selected from group C, or a hydrogen atom;
R ^d represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a hydrogen atom,
R ^e and R ^f are each independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, and a C3-C7 alicyclic ring optionally having one or more halogen atoms. Represents a hydrocarbon group, or a hydrogen atom,
R ⁱ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms),
A ² represents a nitrogen atom or CR ^4a ,
A ³ represents a nitrogen atom or CR ^4b ,
A ⁴ represents a nitrogen atom or CR ^4c ,
R ^4a , R ^4b , and R ^4c are each independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a nitro group, OR ¹⁸ , NR ¹⁸ R ¹⁹ , and a cyano group. Represents a halogen atom or a hydrogen atom,
R ¹⁸ represents a C1-C6 chain hydrocarbon group which may have one or more halogen atoms,
R ¹⁹ represents a C1-C6 chain hydrocarbon group which may have one or more halogen atoms or a hydrogen atom,
T is a C1-C10 chain hydrocarbon group having one or more halogen atoms, (C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms, and (C1-C5 alkyl) having one or more halogen atoms. (Sulfanyl) C2-C5 alkyl group, (C1-C5 alkylsulfinyl) C2-C5 alkyl group having one or more halogen atoms, (C1-C5 alkylsulfonyl) C2-C5 alkyl group having one or more halogen atoms, group G 1 or more having a substituent (C3-C7 cycloalkyl) C1-C3 alkyl group, C3-C7 cycloalkyl group having one or more substituents selected from the group G to be more ^{selected, oR 1, S (O)} m _{^{R 1, OS (O) 2}} R 1, CH 2 OR 1, NR 1 R 24, C (O) R 1, C (O) NR 1 R 24, NR 24 C (O) R 1, N CR ¹ R ^30, a group represented by the following formula T-1, a group represented by the formula T-2, a group represented by the following formula T-3, a group represented by the following formula T-4, under Group represented by formula T-5, group represented by formula T-6 below, group represented by formula T-7 below, group represented by formula T-8 below, table represented by formula T-9 below A group represented by the following formula T-10, a group represented by the following formula T-11, or a group represented by the following formula T-12,
X ¹ represents a nitrogen atom or CR ^1a ,
X ² represents a nitrogen atom or CR ^1b ,
X ³ represents a nitrogen atom or CR ^1c ,
X ⁴ represents a nitrogen atom or CR ^1d ,
X ⁵ represents a nitrogen atom or CR ^1e ,
R ^1a , R ^1b , R ^1c , R ^1d , and R ^1e each independently have a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, and having one or more halogen atoms. An optionally substituted C3-C6 cycloalkyl group, a halogen atom, or a hydrogen atom;
Y ¹ represents NR ²⁵ , an oxygen atom or a sulfur atom,
Y ² represents a nitrogen atom or CR ²⁶ ,
Y ³ represents a nitrogen atom or CR ²⁷ ,
Y ⁴ represents a nitrogen atom or CR ²⁸ ;
R ²⁵ is a C1-C6 chain hydrocarbon group which may have one or more halogen atoms, a C1-C6 alkoxy group which may have one or more halogen atoms, and one or more halogen atoms. A C3-C7 cycloalkyl group optionally having one or more halogen atoms (C3-C7 cycloalkyl) a C1-C6 alkyl group, or a hydrogen atom,
R ²⁶ , R ²⁷ , and R ²⁸ are each independently a C1-C6 chain hydrocarbon group that may have one or more halogen atoms, and C3 that may have one or more halogen atoms. -C6 represents a cycloalkyl group, a halogen atom, or a hydrogen atom,
R ^1x is OR ⁷ , OS (O) ₂ R ⁷ , S (O) _m R ⁷ , NR ⁸ S (O) ₂ R ⁷ , a C1-C5 chain hydrocarbon group having one or more halogen atoms, cyano Represents a group, or a halogen atom,
R ^1y is OR ⁷ , OS (O) ₂ R ⁷ , S (O) _m R ⁷ , NR ⁸ S (O) ₂ R ⁷ , cyano group, C1-C5 chain hydrocarbon having one or more halogen atoms Represents a group, or a halogen atom,
R ^1ay and R ⁷ each independently represents a C1-C6 chain hydrocarbon group having one or more halogen atoms,
R ⁸ represents a C1-C6 chain hydrocarbon group which may have one or more halogen atoms, or a hydrogen atom,
m represents 0, 1, or 2;
R ¹ is a C1-C10 chain hydrocarbon group having one or more halogen atoms, (C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms, and one or more halogen atoms (C1-C5 Alkylsulfanyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfinyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfonyl) C2-C5 alkyl group, group A (C3-C7 cycloalkyl) C1-C3 alkyl group having one or more substituents selected from G, or a C3-C7 cycloalkyl group having one or more substituents selected from Group G;
R ¹¹ , R ¹⁷ , R ²⁴ , and R ²⁹ each independently represent a C1-C6 chain hydrocarbon group that may have one or more halogen atoms, or a hydrogen atom,
R ³⁰ represents a C1-C6 chain hydrocarbon group which may have one or more halogen atoms or a hydrogen atom,
R ¹² represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkyl group having one substituent selected from Group F, and one or more selected from Group H A phenyl group which may have a substituent, a 5- or 6-membered aromatic heterocyclic group which may have one or more substituents selected from group H, S (O) ₂ R ²³ , or a hydrogen atom; Represents
R ²³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a phenyl group optionally having one or more substituents selected from Group D;
R ^11a and R ^12a together with the nitrogen atom to which they are attached form a 3-7 membered non-aromatic heterocyclic group optionally having one or more substituents selected from group E;
R ¹³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, and one or more halogen atoms. (C3-C6 cycloalkyl) which may have C1-C3 alkyl group, phenyl group which may have one or more substituents selected from group D, one or more substituents selected from group D Represents a 5- or 6-membered aromatic heterocyclic group which may have a hydrogen atom, or
R ¹⁴ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, and one or more halogen atoms. (C3-C6 cycloalkyl) which may have (C3-C6 cycloalkyl) C1-C3 alkyl group, or phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group has one or more substituents selected from group D You may have. },
R ¹⁵ and R ¹⁶ each independently represent a C1-C6 alkyl group optionally having one or more halogen atoms.
Group B: C1-C6 alkoxy group optionally having one or more halogen atoms, C3-C6 alkenyloxy group optionally having one or more halogen atoms, having one or more halogen atoms A C3-C6 alkynyloxy group, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, one or more A group consisting of a C1-C6 alkylsulfonyl group optionally having a halogen atom, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom.
Group C: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, having one or more halogen atoms A group consisting of a C3-C6 alkenyloxy group which may have one, a C3-C6 alkynyloxy group which may have one or more halogen atoms, and a halogen atom.
Group D: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, hydroxy group, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogen atoms A C3-C6 alkenyloxy group that may have one or more, a C3-C6 alkynyloxy group that may have one or more halogen atoms, a sulfanyl group, or a C1-C6 that may have one or more halogen atoms. C6 alkylsulfanyl group, C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, amino group, NHR ²¹ , NR ^{21 R 22, C (O)} R 21, OC (O) R 21, C (O) oR 21, cyano group, the group {R ²¹ and R ²² consisting of nitro group, and halogen atoms are each independently Te represents one or more halogen atoms which may have a C1-C6 alkyl group}.
Group E: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, having one or more halogen atoms A group consisting of a C3-C6 alkenyloxy group which may have one or more, a C3-C6 alkynyloxy group which may have one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group.
Group F: C1-C6 alkoxy group optionally having one or more halogen atoms, phenyl group optionally having one or more substituents selected from Group D, one or more substitutions selected from Group D A 5- or 6-membered aromatic heterocyclic group which may have a group, a C3-C7 cycloalkyl group which may have one or more halogen atoms, and one or more substituents selected from group C A group consisting of a 3-7 membered non-aromatic heterocyclic group, an amino group, NHR ²¹ , NR ²¹ R ²² , and a cyano group, which may be
Group G: A group consisting of a C1-C6 alkyl group having at least one halogen atom and a halogen atom.
Group H: 1 or more halogen atoms optionally may C1-C6 alkyl group optionally ^{having, OR 10, NR 9 R 10} , C (O) R 10, C (O) NR 9 R 10, OC (O) R ⁹ , OC (O) OR ⁹ , NR ¹⁰ C (O) R ⁹ , NR ¹⁰ C (O) OR ⁹ , C (O) OR ¹⁰ , halogen atom, nitro group, cyano group, amino group, and 5 or 6 Group consisting of a membered aromatic heterocyclic group {R ⁹ is a C1-C6 alkyl group optionally having one or more halogen atoms or a C3-C6 cycloalkyl group optionally having one or more halogen atoms R ¹⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, or a hydrogen atom} . ]
(Hereinafter, the compound represented by the formula (I) is referred to as “the present compound”). And group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i) and group (j And a composition comprising one or more components selected from the group consisting of:
Group (a): a group consisting of an insecticidal active ingredient, an acaricidal active ingredient and a nematicidal active ingredient;
Group (b): bactericidal active ingredient;
Group (c): plant growth regulating component;
Group (d): phytotoxicity reducing component;
Group (e): synergist;
Group (f): repellent ingredients;
Group (g): molluscicidal components;
Group (h): insect pheromone;
Group (i): herbicidal active ingredient;
Group (j): Microbial material.
[2] A method for controlling harmful arthropods, which comprises applying an effective amount of the composition according to [1] to harmful arthropods, habitats, plants or soil of harmful arthropods.
[3] A seed or vegetative organ holding an effective amount of the composition according to [1].

  According to the present invention, harmful arthropods can be controlled.

The substituent in the present invention will be described.
“Halogen atom” represents a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom.
When the substituent has two or more halogen atoms, these halogen atoms may be the same or different.
In this specification, the expression “CX-CY” means that the number of carbon atoms is X to Y. For example, the notation “C1-C6” means 1 to 6 carbon atoms.
The “chain hydrocarbon group” represents an alkyl group, an alkenyl group or an alkynyl group.
Examples of the “alkyl group” include methyl group, ethyl group, propyl group, isopropyl group, 1,1-dimethylpropyl group, 1,2-dimethylpropyl group, 1-ethylpropyl group, butyl group, sec-butyl group, Examples include a tert-butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, and a decyl group.
Examples of the “alkenyl group” include a vinyl group, 1-propenyl group, 2-propenyl group, 1-methyl-1-propenyl group, 1-methyl-2-propenyl group, 1,2-dimethyl-1-propenyl group, Examples include 1-ethyl-2-propenyl group, 3-butenyl group, 4-pentenyl group, 5-hexenyl group, 6-heptenyl group, 7-octenyl group, 8-nonenyl group, and 9-decenyl group.
Examples of the “alkynyl group” include ethynyl group, 1-propynyl group, 2-propynyl group, 1-methyl-2-propynyl group, 1,1-dimethyl-2-propynyl group, 1-ethyl-2-propynyl group, Examples include 2-butynyl group, 4-pentynyl group, 5-hexynyl group, 6-heptynyl group, 7-octynyl group, 8-noninyl group, and 9-decynyl group.
Examples of the C1-C6 alkyl group having one or more halogen atoms include a trifluoromethyl group, a 2,2,2-trifluoroethyl group, a 2-bromo-1,1,2,2-tetrafluoroethyl group, Examples include 2,2,3,3-tetrafluoropropyl group, 1-methyl-2,2,3,3-tetrafluoropropyl group and perfluorohexyl group.
Examples of the C1-C5 alkyl group having 3 or more fluorine atoms include 2,2,2-trifluoroethyl group, 2,2,3,3,3-pentafluoropropyl group, 2,2,3,3. 4,4,4-heptafluoropropyl group, and perfluoropropyl group.

Examples of the “C3-C7 alicyclic hydrocarbon group” include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a cycloheptyl group.
Examples of the “cycloalkyl group” include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a cycloheptyl group.
Examples of the C3-C6 cycloalkyl group optionally having one or more halogen atoms include a 2,2-difluorocyclopropyl group, a 1- (2,2,2-trifluoroethyl) cyclopropyl group, and 4- (trifluoromethyl) cyclohexyl group is mentioned.

Examples of the “alkoxy group” include methoxy group, ethoxy group, propoxy group, butoxy group, pentoxy group and hexyloxy group.
The “C1-C6 alkoxy group optionally having one or more halogen atoms” refers to a group in which one or more hydrogen atoms of the C1-C6 alkoxy group are substituted with a halogen atom, for example, trifluoromethoxy Groups, difluoromethoxy groups, 2,2,2-trichloroethoxy, and 2,2,2-trifluoroethoxy.

An alkylsulfanyl group, an alkylsulfinyl group, and an alkylsulfonyl group represent, for example, an alkyl group having a moiety represented by S (O) n.
For example, examples of the alkylsulfanyl group in which n is 0 include a methylsulfanyl group, an ethylsulfanyl group, a propylsulfanyl group, and an isopropylsulfanyl group.
For example, examples of the alkylsulfinyl group in which n is 1 include a methylsulfinyl group, an ethylsulfinyl group, a propylsulfinyl group, and an isopropylsulfinyl group.
For example, examples of the alkylsulfonyl group in which n is 2 include a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, and an isopropylsulfonyl group.

“3-7-membered non-aromatic heterocyclic group” means an aziridine ring, azetidine ring, pyrrolidine ring, imidazoline ring, imidazolidine ring, piperidine ring, tetrahydropyrimidine ring, hexahydropyrimidine ring, piperazine ring, azepane ring, oxazolidine Ring, isoxazolidine ring, 1,3-oxazinane ring, morpholine ring, 1,4-oxazepane ring, thiazolidine ring, isothiazolidine ring, 1,3-thiazinane ring, thiomorpholine ring, or 1,4-thiazepane ring . Examples of the 3-7 membered non-aromatic heterocyclic group optionally having one or more substituents selected from group E include the groups shown below.

“(C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms” represents a group in which (C1-C5 alkoxy) and / or (C2-C5 alkyl) has one or more halogen atoms, For example, 2- (trifluoromethoxy) ethyl group, 2,2-difluoro-3-methoxypropyl group, 2,2-difluoro-3- (2,2,2-trifluoroethoxy) propyl group, and 3- ( 2-chloroethoxy) propyl group.
“(C1-C5 alkylsulfanyl) C2-C5 alkyl group having one or more halogen atoms” means a group in which (C1-C5 alkylsulfanyl) and / or (C2-C5 alkyl) has one or more halogen atoms. For example, a 2,2-difluoro-2- (trifluoromethylthio) ethyl group.
“(C1-C5 alkylsulfinyl) C2-C5 alkyl group having one or more halogen atoms” means a group in which (C1-C5 alkylsulfinyl) and / or (C2-C5 alkyl) has one or more halogen atoms. For example, 2,2-difluoro-2- (trifluoromethanesulfinyl) ethyl group.
“(C1-C5 alkylsulfonyl) C2-C5 alkyl group having one or more halogen atoms” means a group in which (C1-C5 alkylsulfonyl) and / or (C2-C5 alkyl) has one or more halogen atoms. For example, a 2,2-difluoro-2- (trifluoromethanesulfonyl) ethyl group.
“(C3-C7 cycloalkyl) C1-C3 alkyl group optionally having one or more halogen atoms” means that (C3-C7 cycloalkyl) and / or (C1-C3 alkyl) is one or more halogens Represents a group which may have an atom, for example, (2,2-difluorocyclopropyl) methyl group, 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, and 2- (2, 2-difluorocyclopropyl) -1,1,2,2-tetrafluoroethyl group.
"Phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may have one or more substituents selected from group D}" means, for example, a benzyl group, 2-fluorobenzyl Group, 4-chlorobenzyl group, 4- (trifluoromethyl) benzyl group, and 2- [4- (trifluoromethyl) phenyl] ethyl group.

The “5- or 6-membered aromatic heterocyclic group” means a 5-membered aromatic heterocyclic group or a 6-membered aromatic heterocyclic group, and the 5-membered aromatic heterocyclic group means a pyrrolyl group, a furyl group, a thienyl group, It represents a pyrazolyl group, an imidazolyl group, a triazolyl group, a tetrazolyl group, an oxazolyl group, an isoxazolyl group, a thiazolyl group, an isothiazolyl group, an oxadiazolyl group, or a thiadiazolyl group. As the 5-membered aromatic heterocyclic group, a pyrrolyl group, a pyrazolyl group, an imidazolyl group, a 1,2,4-triazolyl group, a 1,2,3-triazolyl group, or a tetrazolyl group is preferable. The 6-membered aromatic heterocyclic group represents a pyridyl group, a pyridazinyl group, a pyrimidinyl group, or a pyrazinyl group.
The “5- or 6-membered aromatic heterocyclic group” represents a 5-membered aromatic heterocyclic group or a 6-membered aromatic heterocyclic group.

  Next, the manufacturing method of this compound is demonstrated.

Manufacturing method 1
The present compound comprises a compound represented by formula (M-1) (hereinafter referred to as compound (M-1)) and a compound represented by formula (M-2) (hereinafter referred to as compound (M-2)). Can be produced by reacting in the presence of a metal catalyst.
[Wherein, X ^a represents a chlorine atom, a bromine atom or an iodine atom, and other symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers (hereinafter referred to as ethers) such as tetrahydrofuran (hereinafter referred to as THF), 1,4-dioxane, ethylene glycol dimethyl ether, methyl tert-butyl ether (hereinafter referred to as MTBE), and the like. Aprotic polar solvents such as aromatic hydrocarbons such as toluene and xylene (hereinafter referred to as aromatic hydrocarbons), N-methylpyrrolidone (hereinafter referred to as NMP), dimethyl sulfoxide (hereinafter referred to as DMSO), etc. (Hereinafter referred to as aprotic polar solvent), water and mixtures thereof.
Examples of the metal catalyst used in the reaction include tetrakis (triphenylphosphine) palladium (0), 1,1′-bis (diphenylphosphino) ferrocenepalladium (II) dichloride, tris (dibenzylideneacetone) dipalladium (0), Palladium catalysts such as palladium (II) acetate can be mentioned.
A ligand or a base may be added to the reaction as necessary.
Examples of the ligand used in the reaction include triphenylphosphine, xanthophos, 2,2′-bis (diphenylphosphino) -1,1′-binaphthyl, 1,1′-bis (diphenylphosphino) ferrocene, -Dicyclohexylphosphino-2 ', 4', 6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2 ', 6'-dimethoxybiphenyl, 1,2-bis (diphenylphosphino) ethane, 2,2'- Bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline.
Examples of the base used in the reaction include organic bases such as triethylamine, diisopropylethylamine, pyridine, 4- (dimethylamino) pyridine (hereinafter referred to as organic bases), alkali metal carbonates such as sodium carbonate and potassium carbonate (hereinafter referred to as organic bases). , Alkali metal carbonates), tripotassium phosphate and potassium fluoride.
In the reaction, with respect to 1 mol of the compound (M-1), the compound (M-2) is usually in a proportion of 1 to 10 mol, the metal catalyst is usually in a proportion of 0.01 to 0.5 mol, and the ligand is Usually, the base is used in a proportion of 0.01 to 1 mol and the base is usually used in a proportion of 0.1 to 5 mol.
The reaction temperature is usually in the range of -20 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, the compound can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Manufacturing method 2
A compound represented by formula (I-Q1a) (hereinafter referred to as compound (I-Q1a)) is a compound represented by formula (M-3) (hereinafter referred to as compound (M-3)), chloroacetaldehyde, Can be made to react.
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aprotic polar solvents, halogenated hydrocarbons such as dichloromethane and chloroform (hereinafter referred to as halogenated hydrocarbons), and nitriles such as acetonitrile (hereinafter referred to as nitriles). ), Alcohols such as methanol and ethanol (hereinafter referred to as alcohols), water, and mixtures thereof.
An acid or a base may be added to the reaction, and examples of the acid include hydrogen chloride, p-toluenesulfonic acid and 10-camphorsulfonic acid. Examples of the base include alkali metal carbonates and organic bases.
For the reaction, acid or base is usually used in a proportion of 0.1 to 10 mol, and chloroacetaldehyde is usually used in a proportion of 1 to 10 mol with respect to 1 mol of compound (M-3).
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
After completion of the reaction, compound (I-Q1a) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Production method 3
The compound represented by the formula (I-Q1b) (hereinafter referred to as the compound (I-Q1b)) is composed of the compound represented by the formula (M-4) (hereinafter referred to as the compound (M-4)) and the formula (R -1) (hereinafter referred to as compound (R-1)) can be reacted.
[ ^Wherein R ^3ca may have one or more substituents selected from group B and a C1-C6 chain hydrocarbon group ^optionally having one or more substituents selected from group B; C3-C7 cycloalkyl group, phenyl group optionally having one or more substituents selected from group H, 5- or 6-membered aromatic optionally having one or more substituents selected from group H It represents a heterocyclic group or a hydrogen atom, and other symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aprotic polar solvents, halogenated hydrocarbons, nitriles, alcohols, water, and mixtures thereof.
An acid or a base may be added to the reaction, and examples of the acid include hydrogen chloride, p-toluenesulfonic acid and 10-camphorsulfonic acid. Examples of the base include alkali metal carbonates and organic bases.
In the reaction, with respect to 1 mol of compound (M-4), the acid or base is usually used in a proportion of 0.1 to 10 mol, and compound (R-1) is usually used in the proportion of 1 to 10 mol. .
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
After completion of the reaction, compound (I-Q1b) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
Compound (R-1) is a commercially available compound, or can be produced using a known method.

Manufacturing method 4
A compound represented by formula (I-Q2a) (hereinafter referred to as compound (I-Q2a)) is a compound represented by formula (M-5) (hereinafter referred to as compound (M-5)) and 2-chloro. It can be produced by reacting with ethylamine.
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aprotic polar solvents, halogenated hydrocarbons, nitriles, alcohols, water, and mixtures thereof.
A base may be added to the reaction, and examples of the base include alkali metal carbonates, alkali metal hydrides such as sodium hydride (hereinafter referred to as alkali metal hydrides), and organic bases.
For the reaction, the base is usually used in a proportion of 1 to 10 mol, and 2-chloroethylamine is usually used in the proportion of 1 to 10 mol per 1 mol of the compound (M-5).
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
After completion of the reaction, compound (I-Q2a) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
Compound (M-5) can be produced, for example, according to the method described in International Publication No. 2016/121969.

Manufacturing method 5
A compound represented by formula (I-Q2b) (hereinafter referred to as compound (I-Q2b)) can be produced by reacting compound (M-4) with 1,1′-carbonyldiimidazole. .
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aprotic polar solvents, halogenated hydrocarbons, nitriles, alcohols, and mixtures thereof.
In the reaction, 1,1′-carbonyldiimidazole is usually used at a ratio of 1 to 10 mol with respect to 1 mol of the compound (M-4).
The reaction temperature is usually in the range of -20 to 120 ° C. The reaction time is usually in the range of 0.1 to 12 hours.
After completion of the reaction, compound (I-Q2b) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Reference manufacturing method 1
Compound (M-2) can be produced by reacting a compound represented by formula (M-7) with bis (pinacolato) diboron.
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out, for example, according to the method described in Example 127 of International Publication No. 2015/153720.

Reference production method 2
A compound represented by formula (M-7b) (hereinafter referred to as compound (M-7b)) or a compound represented by formula (M-7c) (hereinafter referred to as compound (M-7c)) is represented by formula (M -7a) (hereinafter referred to as compound (M-7a)) can be produced by oxidation.
[Wherein, Z ⁶ -Z ⁷ is a group represented by the following formula Q1-1, a group represented by the following formula Q2-1, a group represented by the following formula Q3-1, or the following formula Q4-1 The other symbols represent the same meaning as described above. ]
[Wherein the symbols have the same meaning as described above. ]
These reactions can be carried out according to the method described in Production Method 1 of International Publication No. 2013/018928.

Reference manufacturing method 3
Compound (M-7a) is a compound represented by formula (M-8) (hereinafter referred to as compound (M-8)) and a compound represented by formula (R-2) (hereinafter referred to as compound (R-2)). In the presence of a base.
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method described in Production Method 5 of International Publication No. 2013/018928.
Compound (R-2) can be a commercially available compound or can be produced using a known method.

Reference production method 4
A compound represented by formula (M-8-Q1a) (hereinafter referred to as compound (M-8-Q1a)) is a compound represented by formula (M-9) (hereinafter referred to as compound (M-9)). And sodium azide.
[Wherein, X ^b represents a fluorine atom or a chlorine atom, and other symbols have the same meaning as described above. ]
The reaction can be carried out according to the method described in Tetrahedron Letters, 2013, 54 (5), 414.
Compound (M-9) can be produced, for example, according to the method described in International Publication No. 2012/083224.

Reference production method 5
A compound represented by the formula (M-8-Q1b) (hereinafter referred to as compound (M-8-Q1b)) can be produced according to the following scheme.
[ ^Wherein , X ^c represents a chlorine atom or a bromine atom, and R ^3da represents a C1-C6 chain hydrocarbon group ^optionally having one or more substituents selected from group B, 1 selected from group E. A C3-C7 cycloalkyl group optionally having the above substituents, a phenyl group optionally having one or more substituents selected from group H, and one or more substituents selected from group H. Represents a 5- or 6-membered aromatic heterocyclic group which may be substituted, or a hydrogen atom, and other symbols have the same meaning as described above. ]

  This reference production method comprises the first step of producing a compound represented by the formula (M-10) (hereinafter referred to as compound (M-10)) from compound (M-9), and compound (M-10). A second step of producing the compound (M-8-Q1b) is included.

First, the first step will be described.
Compound (M-10) can be produced by reacting compound (M-9) with ammonia. The reaction can be carried out according to the method described in Production Example 8 (1) of International Publication No. 2015/002211.

Next, the second step will be described.
Compound (M-8-Q1b) can be produced by reacting compound (M-10) with a compound represented by formula (R-3) (hereinafter referred to as compound (R-3)). . The reaction can be carried out according to the method described in Production Method 2.
Compound (R-3) is a commercially available compound, or can be produced using a known method.

Reference manufacturing method 6
A compound represented by formula (M-8-Q1d) (hereinafter referred to as compound (M-8-Q1d)), a compound represented by formula (M-8-Q1e) (hereinafter referred to as compound (M-8-Q1e)) ), A compound represented by formula (M-8-Q1f) (hereinafter referred to as compound (M-8-Q1f)) and a compound represented by formula (M-8-Q1g) (hereinafter referred to as compound (M- 8-Q1g)) can be prepared according to the following scheme.
[ ^Wherein R ^3cb is OR ¹² , NR ¹¹ R ¹² , NR ^11a R ^12a , NR ²⁹ NR ¹¹ R ¹² , NR ²⁹ OR ¹¹ , NR ¹¹ C (O) R ¹³ , NR ²⁹ NR ¹¹ C (O) R ^{13 represents} NR ¹¹ C (O) OR ¹⁴ , NR ²⁹ NR ¹¹ C (O) OR ¹⁴ , NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , or NR ²⁹ NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , Other symbols represent the same meaning as described above. ]

  This reference production method includes the first step of producing compound (M-8-Q1d) and compound (M-8-Q1e) from compound (M-8-Q1c), and compound (M-8-Q1d) and A second step of producing compound (M-8-Q1f) and compound (M-8-Q1g) from compound (M-8-Q1e) is included.

First, the first step will be described.
Compound (M-8-Q1d) and compound (M-8-Q1e) can be produced by reacting compound (M-8-Q1c) with N-chlorosuccinimide.
The reaction can be carried out according to the method described in PREPARATIVE EXAMPLE 60 of International Publication No. 2004/026867.

Next, the second step will be described.
Compound (M-8-Q1f) is obtained by reacting compound (M-8-Q1d) with a compound represented by formula (R-4) (hereinafter referred to as compound (R-4)) in the presence of a base. Can be manufactured. Compound (M-8-Q1g) can be produced by reacting compound (M-8-Q1e) with compound (R-4) in the presence of a base.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aprotic polar solvents, halogenated hydrocarbons, nitriles, and mixtures thereof.
A base may be added to the reaction. Examples of the base include alkali metal carbonates, alkali metal hydrides such as sodium hydride, and organic bases.
In the reaction, with respect to 1 mol of compound (M-8-Q1d) or 1 mol of compound (M-8-Q1e), the base is usually used at a ratio of 1 to 10 mol, and compound (R-4) is usually used. Used in a proportion of 1 to 10 mol.
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
After completion of the reaction, post-treatment operations such as addition of water to the reaction mixture, extraction with an organic solvent, and drying and concentration of the organic layer are performed, whereby compound (M-8-Q1f) or compound (M-8- Q1g) can be obtained.
Compound (R-4) is a commercially available compound, or can be produced using a known method.

Reference manufacturing method 7
A compound represented by the formula (M-8-Q1h) (hereinafter referred to as compound (M-8-Q1h)) can be produced according to the following scheme.
[Wherein the symbols have the same meaning as described above. ]

  This reference production method comprises the first step of producing a compound represented by formula (M-11) from compound (M-9) (hereinafter referred to as compound (M-11)), and compound (M-11). A second step of producing the compound (M-8-Q1h) is included.

First, the first step will be described. Compound (M-11) can be produced by reacting compound (M-9) with hydrazine.
The reaction can be carried out according to the method described in Example 2 of International Publication No. 2013/074390.

  Next, the second step will be described. The reaction can be carried out according to the method described in Production Method 3.

The compound represented by the formula (M-8-Q1k) and the compound represented by the formula (M-8-Q1m) can be produced according to the following scheme.
[Wherein the symbols have the same meaning as described above. ]
These reactions can be carried out according to the method described in Reference Production Method 6.

Reference production method 8
A compound represented by formula (M-8-Q2a) (hereinafter referred to as compound (M-8-Q2a)) is a compound represented by compound (M-9) and formula (R-5) (hereinafter referred to as compound (M R-5)) can be reacted.
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method described in Production Method 4.
Compound (R-5) is a commercially available compound, or can be produced using a known method.

Reference manufacturing method 9
A compound represented by formula (M-8-Q2b) (hereinafter referred to as compound (M-8-Q2b)) is a compound represented by formula (M-10) (hereinafter referred to as compound (M-10)). And a compound represented by the formula (R-6) (hereinafter referred to as compound (R-6)).
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include aprotic polar solvents, halogenated hydrocarbons, nitriles, alcohols, and mixtures thereof.
A base may be added to the reaction, and examples of the base include alkali metal carbonates, alkali metal hydrides, and organic bases.
In the reaction, with respect to 1 mol of compound (M-10), the base is usually used at a ratio of 1 to 10 mol, and compound (R-6) is usually used at a ratio of 1 to 10 mol.
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
After completion of the reaction, the compound (M-8-Q2b) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
Compound (R-6) is a commercially available compound, or can be produced using a known method.

Reference production method 10
A compound represented by formula (M-8-Q2c) (hereinafter referred to as compound (M-8-Q2c)) is a compound represented by compound (M-10) and formula (R-7) (hereinafter referred to as compound (M R-7)) can be reacted with each other.
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include aprotic polar solvents, halogenated hydrocarbons, nitriles, alcohols, and mixtures thereof.
A base may be added to the reaction, and examples of the base include alkali metal carbonates, alkali metal hydrides, and organic bases.
In the reaction, with respect to 1 mol of compound (M-10), the base is usually used at a ratio of 1 to 10 mol, and compound (R-7) is usually used at a ratio of 1 to 10 mol.
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
After completion of the reaction, the compound (M-8-Q2c) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
Compound (R-7) is a commercially available compound, or can be produced using a known method.

Reference production method 11
A compound represented by formula (M-8-Q2e) (hereinafter referred to as compound (M-8-Q2e)) and a compound represented by formula (M-8-Q2f) (hereinafter referred to as compound (M-8-Q2f)) Can be prepared according to the following scheme.
[Wherein the symbols have the same meaning as described above. ]

  In this reference production method, the first step of producing compound (M-8-Q2e) from compound (M-11) and the step of producing compound (M-8-Q2f) from compound (M-8-Q2e) 2 steps are included.

First, the first step will be described.
Compound (M-8-Q2e) can be produced by reacting compound (M-11) with 1,1′-carbonyldiimidazole.
The reaction can be carried out according to the method described in Production Method 5.

Next, the second step will be described.
Compound (M-8-Q2f) is produced by reacting compound (M-8-Q2e) with a compound represented by formula (R-9) (hereinafter referred to as compound (R-9)). Can do.
The reaction is described in Bioorganic and Medicinal Chemistry Letters, 2015, 25 (23), 5524., International Publication No. It can implement according to the method of description.
Compound (R-9) is a commercially available compound, or can be produced using a known method.

Reference production method 12
Compound (M-3) can be produced by reacting compound (M-5) with ammonia.
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method for producing compound (M-10) from compound (M-9) described in Reference Production Method 5.

Reference production method 13
Compound (M-4) can be produced by reacting compound (M-5) with hydrazine.
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method described in Production Method 3 of International Publication No. 2015/002211.

Reference production method 14
The compound represented by formula (M-1a) (hereinafter referred to as compound (M-1a)) is composed of the compound represented by formula (M-20a) (hereinafter referred to as compound (M-20a)) and the formula (R −10) (hereinafter referred to as compound (R-10)) in the presence of a base.
[Wherein T ² is OR ¹ , NR ¹ R ²⁴ , a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, or formula T-8. The other symbols represent the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures thereof.
Examples of the base used in the reaction include alkali metal carbonates or alkali metal hydrides.
In the reaction, with respect to 1 mol of compound (M-20a), compound (R-10) is usually used at a ratio of 1 to 2 mol, and the base is usually used at a ratio of 1 to 10 mol.
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
After completion of the reaction, the compound (M-1a) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
Compound (R-10) and compound (M-20a) are commercially available compounds, or can be produced using known methods.

Reference production method 15
A compound represented by the formula (M-1b) (hereinafter referred to as a compound (M-1b)) is a compound represented by a formula (M-20b) (hereinafter referred to as a compound (M-20b)) and a compound represented by the formula (M-20b): It can be produced by reacting a compound represented by R-11) (hereinafter referred to as compound (R-11)).
[Wherein, T ³ is a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, or a formula T Represents a group represented by -9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12, and other symbols have the same meanings as described above. Represent. ]
The reaction was carried out according to the method described in Production Method 1, using Compound (M-20b) instead of Compound (M-1) and Compound (R-11) instead of Compound (M-2). can do.
Compound (R-11) and compound (M-20b) are commercially available compounds, or can be produced using known methods.

Reference production method 16
The compound represented by the formula (M-1c) (hereinafter referred to as the compound (M-1c)) is composed of the compound represented by the formula (M-20c) (hereinafter referred to as the compound (M-20c)) and the formula (R −12) (hereinafter, referred to as compound (R-12)) can be reacted.
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method described in Production Example 1 (1) of International Publication No. 2016/125621.
Compound (R-12) and compound (M-20c) are commercially available compounds, or can be produced using known methods.

Reference production method 17
The compound represented by the formula (M-1d) (hereinafter referred to as the present compound (M-1d)) is the compound (M-20b) and the compound represented by the formula (R-13) (hereinafter referred to as the compound (R-13). Can be produced by reacting in the presence of copper.
[Wherein T ⁴ has a C1-C10 chain hydrocarbon group having one or more halogen atoms, (C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms, and one or more halogen atoms ( (C1-C5 alkylsulfanyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfinyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfonyl) C2-C5 alkyl A group, a (C3-C7 cycloalkyl) C1-C3 alkyl group having one or more substituents selected from group G, or a C3-C7 cycloalkyl group having one or more substituents selected from group G; The symbol represents the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include aromatic hydrocarbons, aprotic polar solvents, and mixtures thereof.
In the reaction, with respect to 1 mol of compound (M-20b), compound (R-13) is usually used at a ratio of 1 to 10 mol, and copper is usually used at a ratio of 1 to 10 mol.
The reaction temperature is usually in the range of 40 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, the compound (M-1d) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
Compound (R-13) is a commercially available compound, or can be produced using a known method.

Reference production method 18
The compound represented by the formula (M-1e) (hereinafter referred to as the compound (M-1e)) is composed of the compound represented by the formula (M-20d) (hereinafter referred to as the compound (M-20d)) and the formula (R -14) (hereinafter referred to as compound (R-14)).
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method described in Production Example 6 (1) of International Publication No. 2014/021468.
Compound (M-20d) and compound (R-14) are commercially available compounds, or can be produced according to known methods.

Reference production method 19
The compound represented by the formula (M-1f) (hereinafter referred to as the compound (M-1f)) is composed of the compound (M-20b) and the compound represented by the formula (R-15) (hereinafter referred to as the compound (R-15)). Can be made to react in the presence of a base.
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method described in Synthesis, 2008, 3707.
Compound (R-15) is a commercially available compound, or can be produced according to a known method.

Reference production method 20
A compound represented by formula (M-1g) (hereinafter referred to as compound (M-1g)) is composed of a compound represented by formula (M-20e) (hereinafter referred to as compound (M-20e)) and a formula (R -16) (hereinafter referred to as compound (R-16)) can be produced by reacting in the presence of a condensing agent.
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method of Production Example 6 (1) described in International Publication No. 2014/021468.
Compound (M-20e) and compound (R-16) are commercially available compounds, or can be produced using known methods.

Reference manufacturing method 21
A compound represented by formula (M-1h) (hereinafter referred to as compound (M-1h)) is composed of a compound represented by formula (M-20f) (hereinafter referred to as compound (M-20f)) and a formula (R -17) (hereinafter referred to as compound (R-17)).
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aliphatic halogenated hydrocarbons, aromatic hydrocarbons, aprotic polar solvents, and mixtures thereof.
An acid may be added to the reaction as necessary, and examples of the acid include p-toluenesulfonic acid, 10-camphorsulfonic acid and the like.
In the reaction, with respect to 1 mol of compound (M-20f), compound (R-17) is usually used at a ratio of 1 to 10 mol, and acid is usually used at a ratio of 0.1 to 10 mol.
The reaction temperature is usually in the range of -20 ° C to 180 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, compound (M-1h) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
Compound (M-20f) and compound (R-17) are commercially available compounds, or can be produced using known methods.

Reference manufacturing method 22
A compound represented by formula (M-1i) (hereinafter referred to as compound (M-1i)) is a compound represented by formula (M-20g) (hereinafter referred to as compound (M-20g)) and a formula (R −18) (hereinafter, referred to as compound (R-18)) can be produced by reacting in the presence of a base.
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, and mixtures thereof.
Examples of the base used in the reaction include organic bases, alkali metal hydrides, and alkali metal carbonates.
In the reaction, with respect to 1 mol of the compound (M-20g), the compound (R-18) is usually used in a proportion of 1 to 10 mol, and the base is usually used in a proportion of 0.1 to 5 mol.
The reaction temperature is usually in the range of -20 ° C to 120 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, compound (M-1i) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
Compound (R-18) and compound (M-20g) are commercially available compounds, or can be produced according to known methods.

Reference production method 23
A compound represented by formula (M-1j) (hereinafter referred to as compound (M-1j)), a compound represented by formula (M-1k) (hereinafter referred to as compound (M-1k)), and a formula (M -1m) (hereinafter referred to as compound (M-1m)) can be produced according to the following method.
[Wherein the symbols have the same meaning as described above. ]

  This reference production method is a first step for producing a compound represented by the formula (M-21) from the compound (M-20b) (hereinafter referred to as the compound (M-21)), from the compound (M-21). A second step of producing a compound represented by (M-22) (hereinafter referred to as compound (M-22), a third step of producing compound (M-1j) from compound (M-22), and a compound ( 4th process which manufactures a compound (M-1k) and a compound (M-1m) from M-1j) is included.

  The first step will be described. Compound (M-21) can be produced by reacting compound (M-20b) with thiobenzoic acid in the presence of a copper catalyst and a base. The reaction can be carried out according to the method described in Production Example 24 (4) of International Publication No. 2013/018928.

  The second step will be described. Compound (M-22) can be produced by hydrolyzing compound (M-21). The reaction can be carried out according to the method described in Production Example 24 (5) of International Publication No. 2013/018928.

  The third step will be described. Compound (M-1j) can be produced by reacting compound (M-22) with compound (R-18) in the presence of a base. The reaction can be carried out according to the method described in Reference Production Method 22.

  The fourth step will be described. Compound (M-1k) and compound (M-1m) can be produced by oxidizing compound (M-1j). The reaction can be carried out according to the method described in Production Method 1 of International Publication No. 2013/018928.

Next, specific examples of this compound are shown below.
In the present specification, Me represents a methyl group, Et represents an ethyl group, Pr represents a propyl group, i-Pr represents an isopropyl group, c-Pr represents a cyclopropyl group, and c-Bu represents a cyclobutyl group. In the formula, Ph represents a phenyl group, Py2 represents a 2-pyridyl group, and Py3 represents a 3-pyridyl group. When c-Pr, Ph, Py2, Py3, and Py4 have a substituent, the substituent is indicated together with the substitution position before the symbol. For example, 4-CF ₃ -Py2 represents a 4- (trifluoromethyl) -2-pyridyl group, and 3,5- (CF ₃ ) ₂ -Ph represents a 3,5-bis (trifluoromethyl) phenyl group. .

Formula (L-1):
In which Z ¹ and Z ² are CH, R ^3b is a hydrogen atom, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter, (Referred to as compound group SX1).

In the compound represented by the formula (L-1), Z ¹ and Z ² are CH, R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6] A compound which is a substituent (hereinafter referred to as compound group SX2).
In the compound represented by the formula (L-1), Z ¹ is CH, Z ² is a nitrogen atom, R ^3b is a hydrogen atom, and T is described in [Table 1] to [Table 6]. A compound which is any one of the substituents (hereinafter referred to as compound group SX3).
In the compound represented by the formula (L-1), Z ¹ is CH, Z ² is a nitrogen atom, R ^3b is a trifluoromethyl group, and T is in [Table 1] to [Table 6]. A compound having any of the substituents described below (hereinafter referred to as compound group SX4).
In the compound represented by the formula (L-1), Z ¹ is a nitrogen atom, Z ² is CH, R ^3b is a hydrogen atom, and T is described in [Table 1] to [Table 6]. A compound which is any one of the substituents (hereinafter referred to as compound group SX5).
In the compound represented by the formula (L-1), Z ¹ is a nitrogen atom, Z ² is CH, R ^3b is a trifluoromethyl group, and T is defined in [Table 1] to [Table 6]. A compound having any one of the substituents described below (hereinafter referred to as compound group SX6).
In the compound represented by the formula (L-1), Z ¹ and Z ² are nitrogen atoms, R ^3b is a hydrogen atom, and T is any one of substitutions described in [Table 1] to [Table 6] A compound which is a group (hereinafter referred to as compound group SX7).
In the compound represented by the formula (L-1), Z ¹ and Z ² are nitrogen atoms, R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6]. (Hereinafter, referred to as compound group SX8).

Formula (L-2):
In which Z ¹ and Z ² are CH, R ^3b is a hydrogen atom, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter, (Referred to as compound group SX9).
In the compound represented by the formula (L-2), Z ¹ and Z ² are CH, R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6] A compound which is a substituent (hereinafter referred to as compound group SX10).
In the compound represented by the formula (L-2), Z ¹ is CH, Z ² is a nitrogen atom, R ^3b is a hydrogen atom, and T is described in [Table 1] to [Table 6]. A compound which is any one of the substituents (hereinafter referred to as compound group SX11).
In the compound represented by the formula (L-2), Z ¹ is CH, Z ² is a nitrogen atom, R ^3b is a trifluoromethyl group, and T is defined in [Table 1] to [Table 6]. A compound having any one of the substituents described below (hereinafter referred to as compound group SX12).
In the compound represented by the formula (L-2), Z ¹ is a nitrogen atom, Z ² is CH, R ^3b is a hydrogen atom, and T is described in [Table 1] to [Table 6]. A compound which is any one of the substituents (hereinafter referred to as compound group SX13).
In the compound represented by the formula (L-2), Z ¹ is a nitrogen atom, Z ² is CH, R ^3b is a trifluoromethyl group, and T is defined in [Table 1] to [Table 6]. A compound having any one of the substituents described below (hereinafter referred to as compound group SX14).
In the compound represented by the formula (L-2), Z ¹ and Z ² are nitrogen atoms, R ^3b is a hydrogen atom, and T is any of the substitutions described in [Table 1] to [Table 6] A compound as a group (hereinafter referred to as compound group SX15).
In the compound represented by the formula (L-2), Z ¹ and Z ² are nitrogen atoms, R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6]. (Hereinafter, referred to as compound group SX16).

Formula (L-3):
In which Z ¹ and Z ² are CH, R ^3b is a hydrogen atom, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter, (Referred to as compound group SX17).
In the compound represented by the formula (L-3), Z ¹ and Z ² are CH, R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6] A compound which is a substituent (hereinafter referred to as compound group SX18).
In the compound represented by the formula (L-3), Z ¹ is CH, Z ² is a nitrogen atom, R ^3b is a hydrogen atom, and T is described in [Table 1] to [Table 6]. A compound which is any one of the substituents (hereinafter referred to as compound group SX19).
In the compound represented by the formula (L-3), Z ¹ is CH, Z ² is a nitrogen atom, R ^3b is a trifluoromethyl group, and T is defined in [Table 1] to [Table 6]. A compound having any one of the substituents described below (hereinafter referred to as compound group SX20).
In the compound represented by the formula (L-3), Z ¹ is a nitrogen atom, Z ² is CH, R ^3b is a hydrogen atom, and T is described in [Table 1] to [Table 6]. A compound which is any one of the substituents (hereinafter referred to as compound group SX21).
In the compound represented by the formula (L-3), Z ¹ is a nitrogen atom, Z ² is CH, R ^3b is a trifluoromethyl group, and T is in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX22).
In the compound represented by the formula (L-3), Z ¹ and Z ² are nitrogen atoms, R ^3b is a hydrogen atom, and T is any of the substitutions described in [Table 1] to [Table 6] A compound as a group (hereinafter referred to as compound group SX23).
In the compound represented by the formula (L-3), Z ¹ and Z ² are nitrogen atoms, R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6]. (Hereinafter referred to as compound group SX24).

Formula (L-4):
In which Z ¹ and Z ² are CH, R ^3b is a hydrogen atom, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter, Compound group SX25).
In the compound represented by the formula (L-4), Z ¹ and Z ² are CH, R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6] A compound which is a substituent (hereinafter referred to as compound group SX26).
In the compound represented by the formula (L-4), Z ¹ is CH, Z ² is a nitrogen atom, R ^3b is a hydrogen atom, and T is described in [Table 1] to [Table 6]. A compound which is any one of the substituents (hereinafter referred to as compound group SX27).
In the compound represented by the formula (L-4), Z ¹ is CH, Z ² is a nitrogen atom, R ^3b is a trifluoromethyl group, and T is defined in [Table 1] to [Table 6]. A compound having any of the substituents described below (hereinafter referred to as compound group SX28).
In the compound represented by the formula (L-4), Z ¹ is a nitrogen atom, Z ² is CH, R ^3b is a hydrogen atom, and T is described in [Table 1] to [Table 6]. A compound which is any one of the substituents (hereinafter referred to as compound group SX29).
In the compound represented by the formula (L-4), Z ¹ is a nitrogen atom, Z ² is CH, R ^3b is a trifluoromethyl group, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX30).
In the compound represented by the formula (L-4), Z ¹ and Z ² are nitrogen atoms, R ^3b is a hydrogen atom, and T is any of the substitutions described in [Table 1] to [Table 6] A compound as a group (hereinafter referred to as compound group SX31).
In the compound represented by the formula (L-4), Z ¹ and Z ² are nitrogen atoms, R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6]. (Hereinafter, referred to as compound group SX32).

Formula (L-5):
In which Z ⁴ and Z ⁵ are CH ₂ , R ^3b is a hydrogen atom, and T is any one of the substituents described in [Table 1] to [Table 6] And referred to as Compound Group SX33).
In the compound represented by the formula (L-5), Z ⁴ and Z ⁵ are CH ₂ , R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6]. (Hereinafter, referred to as compound group SX34).
In the compound represented by the formula (L-5), Z ⁴ is CH ₂ , Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is [Table 1] to [Table 6]. Or a compound having any one of the substituents described below (hereinafter referred to as compound group SX35).
In the compound represented by the formula (L-5), Z ⁴ is CH ₂ , Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 1]. 6] (hereinafter, referred to as compound group SX36).
In the compound represented by the formula (L-5), Z ⁴ is C (O), Z ⁵ is CH ₂ , R ^3b is a hydrogen atom, and T is [Table 1] to [Table 6]. Or a compound having any one of the substituents described below (hereinafter referred to as compound group SX37).
In the compound represented by the formula (L-5), Z ⁴ is C (O), Z ⁵ is CH ₂ , R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 1]. 6] (hereinafter, referred to as compound group SX38).
In the compound represented by the formula (L-5), Z ⁴ is NH, Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX39).
In the compound represented by the formula (L-5), Z ⁴ is NH, Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is one of substituents as described in the following (it is hereafter described as compound group SX40).
In the compound represented by the formula (L-5), Z ⁴ is C (O), Z ⁵ is NH, R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX41).
In the compound represented by the formula (L-5), Z ⁴ is C (O), Z ⁵ is NH, R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is one of substituents as described in the following (it is hereafter described as compound group SX42).
In the compound represented by the formula (L-5), Z ⁴ is NMe, Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound which is any one of the substituents described below (hereinafter referred to as compound group SX43).
In the compound represented by the formula (L-5), Z ⁴ is NMe, Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX44).
In the compound represented by the formula (L-5), Z ⁴ is C (O), Z ⁵ is NMe, R ^3b is a hydrogen atom, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX45).
In the compound represented by the formula (L-5), Z ⁴ is C (O), Z ⁵ is NMe, R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX46).

Formula (L-6):
In which Z ⁴ and Z ⁵ are CH ₂ , R ^3b is a hydrogen atom, and T is any one of the substituents described in [Table 1] to [Table 6] And referred to as Compound Group SX47).
In the compound represented by the formula (L-6), Z ⁴ and Z ⁵ are CH ₂ , R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6]. (Hereinafter, referred to as compound group SX48).
In the compound represented by the formula (L-6), Z ⁴ is CH ₂ , Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is [Table 1] to [Table 6]. Or a compound having any one of the substituents described below (hereinafter referred to as compound group SX49).
In the compound represented by the formula (L-6), Z ⁴ is CH ₂ , Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 1]. 6] (hereinafter, referred to as compound group SX50).
In the compound represented by the formula (L-6), Z ⁴ is C (O), Z ⁵ is CH ₂ , R ^3b is a hydrogen atom, and T is [Table 1] to [Table 6]. Or a compound having any one of the substituents described below (hereinafter referred to as compound group SX51).
In the compound represented by the formula (L-6), Z ⁴ is C (O), Z ⁵ is CH ₂ , R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 1]. 6] (hereinafter referred to as compound group SX52).
In the compound represented by the formula (L-6), Z ⁴ is NH, Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is defined in [Table 1] to [Table 6]. A compound which is any one of the substituents described below (hereinafter referred to as compound group SX53).
In the compound represented by the formula (L-6), Z ⁴ is NH, Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is one of substituents as described in the following (it is hereafter described as the compound group SX54).
In the compound represented by the formula (L-6), Z ⁴ is C (O), Z ⁵ is NH, R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound having any one of the substituents described below (hereinafter referred to as compound group SX55).
In the compound represented by the formula (L-6), Z ⁴ is C (O), Z ⁵ is NH, R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX56).
In the compound represented by the formula (L-6), Z ⁴ is NMe, Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound having any of the substituents described below (hereinafter referred to as compound group SX57).
In the compound represented by the formula (L-6), Z ⁴ is NMe, Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is either substituent as described in (Hereinafter, it describes as the compound group SX58.).
In the compound represented by the formula (L-6), Z ⁴ is C (O), Z ⁵ is NMe, R ^3b is a hydrogen atom, and T is defined in [Table 1] to [Table 6]. A compound having any one of the substituents described below (hereinafter referred to as compound group SX59).
In the compound represented by the formula (L-6), Z ⁴ is C (O), Z ⁵ is NMe, R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX60).

Formula (L-7):
In which Z ⁴ and Z ⁵ are CH ₂ , R ^3b is a hydrogen atom, and T is any one of the substituents described in [Table 1] to [Table 6] And referred to as Compound Group SX61).
In the compound represented by the formula (L-7), Z ⁴ and Z ⁵ are CH ₂ , R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6]. (Hereinafter referred to as compound group SX62).
In the compound represented by the formula (L-7), Z ⁴ is CH ₂ , Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is [Table 1] to [Table 6]. Or a compound (hereinafter, referred to as compound group SX63).
In the compound represented by the formula (L-7), Z ⁴ is CH ₂ , Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 1]. 6] (hereinafter, referred to as compound group SX64).
In the compound represented by the formula (L-7), Z ⁴ is C (O), Z ⁵ is CH ₂ , R ^3b is a hydrogen atom, and T is [Table 1] to [Table 6]. Or a compound having any one of the substituents described below (hereinafter referred to as compound group SX65).
In the compound represented by the formula (L-7), Z ⁴ is C (O), Z ⁵ is CH ₂ , R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 1]. 6] (hereinafter referred to as compound group SX66).
In the compound represented by the formula (L-7), Z ⁴ is NH, Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound having any of the substituents described below (hereinafter referred to as compound group SX67).
In the compound represented by the formula (L-7), Z ⁴ is NH, Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX68).
In the compound represented by the formula (L-7), Z ⁴ is C (O), Z ⁵ is NH, R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound which is any one of the substituents described below (hereinafter referred to as compound group SX69).
In the compound represented by the formula (L-7), Z ⁴ is C (O), Z ⁵ is NH, R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX70).
In the compound represented by the formula (L-7), Z ⁴ is NMe, Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound having any one of the substituents described below (hereinafter referred to as compound group SX71).
In the compound represented by the formula (L-7), Z ⁴ is NMe, Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX72).
In the compound represented by the formula (L-7), Z ⁴ is C (O), Z ⁵ is NMe, R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound which is any one of the substituents described below (hereinafter referred to as compound group SX73).
In the compound represented by the formula (L-7), Z ⁴ is C (O), Z ⁵ is NMe, R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is either substituent as described in (Hereinafter, it describes as the compound group SX74.).

Formula (L-8):
In which Z ⁴ and Z ⁵ are CH ₂ , R ^3b is a hydrogen atom, and T is any one of the substituents described in [Table 1] to [Table 6] And referred to as Compound Group SX75).
In the compound represented by the formula (L-8), Z ⁴ and Z ⁵ are CH ₂ , R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6]. (Hereinafter, referred to as compound group SX76).
In the compound represented by the formula (L-8), Z ⁴ is CH ₂ , Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is [Table 1] to [Table 6]. Or a compound having any one of the substituents described below (hereinafter referred to as compound group SX77).
In the compound represented by the formula (L-8), Z ⁴ is CH ₂ , Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 1]. 6] (hereinafter referred to as compound group SX78).
In the compound represented by the formula (L-8), Z ⁴ is C (O), Z ⁵ is CH ₂ , R ^3b is a hydrogen atom, and T is [Table 1] to [Table 6]. Or a compound (hereinafter, referred to as compound group SX79).
In the compound represented by the formula (L-8), Z ⁴ is C (O), Z ⁵ is CH ₂ , R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 1]. 6] (hereinafter referred to as compound group SX80).
In the compound represented by the formula (L-8), Z ⁴ is NH, Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX81).
In the compound represented by the formula (L-8), Z ⁴ is NH, Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is a substituent in any one of description (henceforth the compound group SX82).
In the compound represented by the formula (L-8), Z ⁴ is C (O), Z ⁵ is NH, R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX83).
In the compound represented by the formula (L-8), Z ⁴ is C (O), Z ⁵ is NH, R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX84).
In the compound represented by the formula (L-8), Z ⁴ is NMe, Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX85).
In the compound represented by the formula (L-8), Z ⁴ is NMe, Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is either substituent as described in (Hereinafter, it describes as the compound group SX86.).
In the compound represented by the formula (L-8), Z ⁴ is C (O), Z ⁵ is NMe, R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX87).
In the compound represented by the formula (L-8), Z ⁴ is C (O), Z ⁵ is NMe, R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX88).

Formula (L-9):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX89).

In the compound represented by the formula (L-9), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any substituent described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX90).
In the compound represented by the formula (L-9), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX91).
In the compound represented by the formula (L-9), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX92).

Formula (L-10):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX93).
In the compound represented by the formula (L-10), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX94).
In the compound represented by the formula (L-10), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX95).
In the compound represented by the formula (L-10), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX96).

Formula (L-11):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX97).
In the compound represented by the formula (L-11), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX98).
In the compound represented by the formula (L-11), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX99).
In the compound represented by the formula (L-11), compounds in which Z ¹ and Z ² are nitrogen atoms and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX100).

Formula (L-12):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX101).
In the compound represented by the formula (L-12), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX102).
In the compound represented by the formula (L-12), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any substituent described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX103).
In the compound represented by the formula (L-12), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX104).

Formula (L-13):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX105).
In the compound represented by the formula (L-13), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any substituent described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX106).
In the compound represented by the formula (L-13), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX107).
In the compound represented by the formula (L-13), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX108).

Formula (L-14):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX109).
In the compound represented by the formula (L-14), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX110).
In the compound represented by the formula (L-14), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX111).
In the compound represented by the formula (L-14), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, Compound group SX112).

Formula (L-15):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX113).
In the compound represented by the formula (L-15), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX114).
In the compound represented by the formula (L-15), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX115).
In the compound represented by the formula (L-15), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX116).

Formula (L-16):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX117).
In the compound represented by the formula (L-16), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX118).
In the compound represented by the formula (L-16), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX119).
In the compound represented by the formula (L-16), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX120).

Formula (L-17):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX121).
In the compound represented by the formula (L-17), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any substituent described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX122).
In the compound represented by the formula (L-17), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX123).
In the compound represented by the formula (L-17), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX124).

Formula (L-18):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX125).
In the compound represented by the formula (L-18), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any substituent described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX126).
In the compound represented by the formula (L-18), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX127).
In the compound represented by the formula (L-18), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX128).

Formula (L-19):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX129).
In the compound represented by the formula (L-19), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX130).
In the compound represented by the formula (L-19), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX131).
In the compound represented by the formula (L-19), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX132).

Formula (L-20):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX133).
In the compound represented by the formula (L-20), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in Table 7 to Table 15. Compound (hereinafter referred to as Compound Group SX134).
In the compound represented by the formula (L-20), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX135).
In the compound represented by the formula (L-20), compounds in which Z ¹ and Z ² are nitrogen atoms and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX136).

Formula (L-21):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX137).
In the compound represented by the formula (L-21), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX138).
In the compound represented by the formula (L-21), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX139).
In the compound represented by the formula (L-21), compounds in which Z ¹ and Z ² are nitrogen atoms and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX140).

Formula (L-22):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX141).
In the compound represented by the formula (L-22), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX142).
In the compound represented by the formula (L-22), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX143).
In the compound represented by the formula (L-22), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX144).

Formula (L-23):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX145).
In the compound represented by the formula (L-23), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX146).
In the compound represented by the formula (L-23), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX147).
In the compound represented by the formula (L-23), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX148).

Formula (L-24):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX149).
In the compound represented by the formula (L-24), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX150).
In the compound represented by the formula (L-24), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX151).
In the compound represented by the formula (L-24), compounds in which Z ¹ and Z ² are nitrogen atoms and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX152).

Formula (L-25):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX153).
In the compound represented by the formula (L-25), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX154).
In the compound represented by the formula (L-25), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX155).
In the compound represented by the formula (L-25), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX156).

Formula (L-26):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX157).
In the compound represented by the formula (L-26), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX158).
In the compound represented by the formula (L-26), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX159).
In the compound represented by the formula (L-26), compounds in which Z ¹ and Z ² are nitrogen atoms and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX160).

Formula (L-27):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX161).
In the compound represented by the formula (L-27), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX162).
In the compound represented by the formula (L-27), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX163).
In the compound represented by the formula (L-27), compounds in which Z ¹ and Z ² are nitrogen atoms and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX164).

Formula (L-28):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX165).
In the compound represented by the formula (L-28), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX166).
In the compound represented by the formula (L-28), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX167).
In the compound represented by the formula (L-28), compounds in which Z ¹ and Z ² are nitrogen atoms and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX168).

Formula (L-29):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX169).
In the compound represented by the formula (L-29), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX170).
In the compound represented by the formula (L-29), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX171).
In the compound represented by the formula (L-29), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX172).

Formula (L-30):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX173).
In the compound represented by the formula (L-30), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX174).
In the compound represented by the formula (L-30), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX175).
In the compound represented by the formula (L-30), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX176).

Formula (L-31):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX177).
In the compound represented by the formula (L-31), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX178).
In the compound represented by the formula (L-31), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX179).
In the compound represented by the formula (L-31), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX180).

Formula (L-32):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX181).
In the compound represented by the formula (L-32), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX182).
In the compound represented by the formula (L-32), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX183).
In the compound represented by the formula (L-32), compounds in which Z ¹ and Z ² are nitrogen atoms, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX184).

Formula (L-33):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX185).
In the compound represented by the formula (L-33), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in Table 7 to Table 15. Compound (hereinafter referred to as compound group SX186).
In the compound represented by the formula (L-33), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX187).
In the compound represented by the formula (L-33), compounds in which Z ¹ and Z ² are nitrogen atoms and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX188).

Formula (L-34):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX189).
In the compound represented by the formula (L-34), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX190).
In the compound represented by the formula (L-34), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX191).
In the compound represented by the formula (L-34), compounds in which Z ¹ and Z ² are nitrogen atoms and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX192).

Formula (L-35):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX193).
In the compound represented by the formula (L-35), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any substituent described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX194).
In the compound represented by the formula (L-35), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as compound group SX195).
In the compound represented by the formula (L-35), compounds in which Z ¹ and Z ² are nitrogen atoms and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX196).

Formula (L-36):
In which Z ¹ and Z ² are CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX197).
In the compound represented by the formula (L-36), Z ¹ is CH, Z ² is a nitrogen atom, and R ^3b is any substituent described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX198).
In the compound represented by the formula (L-36), Z ¹ is a nitrogen atom, Z ² is CH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. Compound (hereinafter referred to as Compound Group SX199).
In the compound represented by the formula (L-36), compounds in which Z ¹ and Z ² are nitrogen atoms and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter, (Referred to as compound group SX200).

Formula (L-37):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX201). .
In the compound represented by the formula (L-37), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of the substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX202).
In the compound represented by the formula (L-37), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX203).
In the compound represented by the formula (L-37), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX204).
In the compound represented by the formula (L-37), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX205).
In the compound represented by the formula (L-37), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX206).
In the compound represented by the formula (L-37), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX207).

Formula (L-38):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX208). .
In the compound represented by the formula (L-38), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any substitution described in [Table 7] to [Table 15] A compound which is a group (hereinafter referred to as compound group SX209).
In the compound represented by the formula (L-38), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX210).
In the compound represented by the formula (L-38), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX211).
In the compound represented by the formula (L-38), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX212).
In the compound represented by the formula (L-38), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX213).
In the compound represented by the formula (L-38), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX214).

Formula (L-39):
In which Z ⁴ and Z ⁵ are CH ₂ , and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX215). .
In the compound represented by the formula (L-39), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX216).
In the compound represented by the formula (L-39), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX217).
In the compound represented by the formula (L-39), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX218).
In the compound represented by the formula (L-39), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX219).
In the compound represented by the formula (L-39), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX220).
In the compound represented by the formula (L-39), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX221).

Formula (L-40):
In which Z ⁴ and Z ⁵ are CH ₂ , and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX222). .
In the compound represented by the formula (L-40), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound which is a group (hereinafter referred to as compound group SX223).
In the compound represented by the formula (L-40), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX224).
In the compound represented by the formula (L-40), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX225).
In the compound represented by the formula (L-40), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX226).
In the compound represented by the formula (L-40), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX227).
In the compound represented by the formula (L-40), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX228).

Formula (L-41):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX229). .
In the compound represented by the formula (L-41), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX230).
In the compound represented by the formula (L-41), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX231).
In the compound represented by the formula (L-41), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX232).
In the compound represented by the formula (L-41), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX233).
In the compound represented by the formula (L-41), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX234).
In the compound represented by the formula (L-41), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX235).

Formula (L-42):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX236). .
In the compound represented by the formula (L-42), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX237).
In the compound represented by the formula (L-42), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX238).
In the compound represented by the formula (L-42), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX239).
In the compound represented by the formula (L-42), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX240).
In the compound represented by the formula (L-42), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX241).
In the compound represented by the formula (L-42), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX242).

Formula (L-43):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX243). .
In the compound represented by the formula (L-43), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX244).
In the compound represented by the formula (L-43), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX245).
In the compound represented by the formula (L-43), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX246).
In the compound represented by the formula (L-43), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX247).
In the compound represented by the formula (L-43), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX248).
In the compound represented by the formula (L-43), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX249).

Formula (L-44):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX250). .
In the compound represented by the formula (L-44), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX251).
In the compound represented by the formula (L-44), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX252).
In the compound represented by the formula (L-44), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX253).
In the compound represented by the formula (L-44), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX254).
In the compound represented by the formula (L-44), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX255).
In the compound represented by the formula (L-44), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX256).

Formula (L-45):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX257). .
In the compound represented by the formula (L-45), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX258).
In the compound represented by the formula (L-45), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX259).
In the compound represented by the formula (L-45), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX260).
In the compound represented by the formula (L-45), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX261).
In the compound represented by the formula (L-45), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX262).
In the compound represented by the formula (L-45), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX263).

Formula (L-46):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX264). .
In the compound represented by the formula (L-46), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX265).
In the compound represented by the formula (L-46), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX266).
In the compound represented by the formula (L-46), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX267).
In the compound represented by the formula (L-46), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX268).
In the compound represented by the formula (L-46), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX269).
In the compound represented by the formula (L-46), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX270).

Formula (L-47):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX271). .
In the compound represented by the formula (L-47), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX272).
In the compound represented by the formula (L-47), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX273).
In the compound represented by the formula (L-47), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX274).
In the compound represented by the formula (L-47), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX275).
In the compound represented by the formula (L-47), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX276).
In the compound represented by the formula (L-47), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX277).

Formula (L-48):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX278). .
In the compound represented by the formula (L-48), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as a compound group SX279).
In the compound represented by the formula (L-48), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX280).
In the compound represented by the formula (L-48), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX281).
In the compound represented by the formula (L-48), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX282).
In the compound represented by the formula (L-48), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX283).
In the compound represented by the formula (L-48), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX284).

Formula (L-49):
Wherein Z ⁴ and Z ⁵ are CH ₂ , and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX285). .
In the compound represented by the formula (L-49), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX286).
In the compound represented by the formula (L-49), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX287).
In the compound represented by the formula (L-49), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX288).
In the compound represented by the formula (L-49), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX289).
In the compound represented by the formula (L-49), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX290).
In the compound represented by the formula (L-49), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX291).

Formula (L-50):
In which Z ⁴ and Z ⁵ are CH ₂ , and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX292). .
In the compound represented by the formula (L-50), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX293).
In the compound represented by the formula (L-50), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX294).
In the compound represented by the formula (L-50), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX295).
In the compound represented by the formula (L-50), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX296).
In the compound represented by the formula (L-50), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX297).
In the compound represented by the formula (L-50), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX298).

Formula (L-51):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX299) .
In the compound represented by the formula (L-51), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound which is a group (hereinafter referred to as compound group SX300).
In the compound represented by the formula (L-51), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound which is a group (hereinafter referred to as compound group SX301).
In the compound represented by the formula (L-51), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX302).
In the compound represented by the formula (L-51), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX303).
In the compound represented by the formula (L-51), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX304).
In the compound represented by the formula (L-51), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX305).

Formula (L-52):
In which Z ⁴ and Z ⁵ are CH ₂ , and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX306). .
In the compound represented by the formula (L-52), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX307).
In the compound represented by the formula (L-52), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as a compound group SX308).
In the compound represented by the formula (L-52), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX309).
In the compound represented by the formula (L-52), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX310).
In the compound represented by the formula (L-52), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX311).
In the compound represented by the formula (L-52), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX312).

Formula (L-53):
In in the compound represented, a Z ⁴ and Z ⁵ is CH _2, R ^3b is, Table 7 ~ compound is any of the substituents described in Table 15] (hereinafter, referred to as compound group SX313) .
In the compound represented by the formula (L-53), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as a compound group SX314).
In the compound represented by the formula (L-53), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX315).
In the compound represented by the formula (L-53), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX316).
In the compound represented by the formula (L-53), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX317).
In the compound represented by the formula (L-53), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX318).
In the compound represented by the formula (L-53), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX319).

Formula (L-54):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX320). .
In the compound represented by the formula (L-54), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX321).
In the compound represented by the formula (L-54), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as a compound group SX322).
In the compound represented by the formula (L-54), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX323).
In the compound represented by the formula (L-54), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX324).
In the compound represented by the formula (L-54), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX325).
In the compound represented by the formula (L-54), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX326).

Formula (L-55):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX327). .
In the compound represented by the formula (L-55), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX328).
In the compound represented by the formula (L-55), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound which is a group (hereinafter referred to as compound group SX329).
In the compound represented by the formula (L-55), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX330).
In the compound represented by the formula (L-55), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX331).
In the compound represented by the formula (L-55), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX332).
In the compound represented by the formula (L-55), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX333).

Formula (L-56):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX334). .
In the compound represented by the formula (L-56), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX335).
In the compound represented by the formula (L-56), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX336).
In the compound represented by the formula (L-56), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX337).
In the compound represented by the formula (L-56), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX338).
In the compound represented by the formula (L-56), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX339).
In the compound represented by the formula (L-56), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX340).

Formula (L-57):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX341). .
In the compound represented by the formula (L-57), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any substitution described in [Table 7] to [Table 15] A compound which is a group (hereinafter referred to as compound group SX342).
In the compound represented by the formula (L-57), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX343).
In the compound represented by the formula (L-57), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX344).
In the compound represented by the formula (L-57), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX345).
In the compound represented by the formula (L-57), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX346).
In the compound represented by the formula (L-57), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX347).

Formula (L-58):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX348). .
In the compound represented by the formula (L-58), Z ⁴ is CH _2, Z ⁵ is C (O), R ^3b is a substituted either according to Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX349).
In the compound represented by the formula (L-58), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX350).
In the compound represented by the formula (L-58), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX351).
In the compound represented by the formula (L-58), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX352).
In the compound represented by the formula (L-58), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX353).
In the compound represented by the formula (L-58), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX354).

Formula (L-59):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX355). .
In the compound represented by the formula (L-59), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX356).
In the compound represented by the formula (L-59), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX357).
In the compound represented by the formula (L-59), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX358).
In the compound represented by the formula (L-59), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX359).
In the compound represented by the formula (L-59), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX360).
In the compound represented by the formula (L-59), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX361).

Formula (L-60):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX362). .
In the compound represented by the formula (L-60), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX363).
In the compound represented by the formula (L-60), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] Compound as a group (hereinafter referred to as Compound Group SX364).
In the compound represented by the formula (L-60), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX365).
In the compound represented by the formula (L-60), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX366).
In the compound represented by the formula (L-60), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX367).
In the compound represented by the formula (L-60), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX368).

Formula (L-61):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX369). .
In the compound represented by the formula (L-61), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any substitution described in [Table 7] to [Table 15] A compound which is a group (hereinafter referred to as compound group SX370).
In the compound represented by the formula (L-61), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX371).
In the compound represented by the formula (L-61), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX372).
In the compound represented by the formula (L-61), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX373).
In the compound represented by the formula (L-61), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX374).
In the compound represented by the formula (L-61), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX375).

Formula (L-62):
In which Z ⁴ and Z ⁵ are CH ₂ , and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX376). .
In the compound represented by the formula (L-62), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX377).
In the compound represented by the formula (L-62), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX378).
In the compound represented by the formula (L-62), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX379).
In the compound represented by the formula (L-62), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX380).
In the compound represented by the formula (L-62), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX381).
In the compound represented by the formula (L-62), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX382).

Formula (L-63):
In in the compound represented, a Z ⁴ and Z ⁵ is CH _2, R ^3b is, Table 7 ~ compound is any of the substituents described in Table 15] (hereinafter, referred to as compound group SX383) .
In the compound represented by the formula (L-63), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of the substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX384).
In the compound represented by the formula (L-63), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX385).
In the compound represented by the formula (L-63), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX386).
In the compound represented by the formula (L-63), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX387).
In the compound represented by the formula (L-63), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX388).
In the compound represented by the formula (L-63), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX389).

Formula (L-64):
In which Z ⁴ and Z ⁵ are CH ₂ and R ^3b is any one of the substituents described in [Table 7] to [Table 15] (hereinafter referred to as compound group SX390). .
In the compound represented by the formula (L-64), Z ⁴ is CH ₂ , Z ⁵ is C (O), and R ^3b is any one of substitutions described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX391).
In the compound represented by the formula (L-64), Z ⁴ is C (O), Z ⁵ is CH ₂ , and R ^3b is any substitution described in [Table 7] to [Table 15] A compound as a group (hereinafter referred to as compound group SX392).
In the compound represented by the formula (L-64), Z ⁴ is NH, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX393).
In the compound represented by the formula (L-64), Z ⁴ is C (O), Z ⁵ is NH, and R ^3b is any one of the substituents described in Table 7 to Table 15. (Hereinafter referred to as compound group SX394).
In the compound represented by the formula (L-64), Z ⁴ is NMe, Z ⁵ is C (O), and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX395).
In the compound represented by the formula (L-64), Z ⁴ is C (O), Z ⁵ is NMe, and R ^3b is any one of the substituents described in [Table 7] to [Table 15]. (Hereinafter referred to as compound group SX396).

Formula (L-65):
In which Z ² and Z ³ are CH, R ^3b is a hydrogen atom, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter, Compound group SX397).
In the compound represented by the formula (L-65), Z ² and Z ³ are CH, R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6] A compound which is a substituent (hereinafter referred to as compound group SX398).
In the compound represented by the formula (L-65), Z ² is CH, Z ³ is a nitrogen atom, R ^3b is a hydrogen atom, and T is described in [Table 1] to [Table 6]. A compound which is any one of the substituents (hereinafter referred to as compound group SX399).
In the compound represented by the formula (L-65), Z ² is CH, Z ³ is a nitrogen atom, R ^3b is a trifluoromethyl group, and T is defined in [Table 1] to [Table 6]. A compound which is any one of the substituents described below (hereinafter referred to as compound group SX400).
In the compound represented by the formula (L-65), Z ² is a nitrogen atom, Z ³ is CH, R ^3b is a hydrogen atom, and T is described in [Table 1] to [Table 6]. A compound which is any one of the substituents (hereinafter referred to as compound group SX401).
In the compound represented by the formula (L-65), Z ² is a nitrogen atom, Z ³ is CH, R ^3b is a trifluoromethyl group, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX402).
In the compound represented by the formula (L-65), Z ² and Z ³ are nitrogen atoms, R ^3b is a hydrogen atom, and T is any of the substitutions described in [Table 1] to [Table 6] A compound as a group (hereinafter referred to as compound group SX403).
In the compound represented by the formula (L-65), Z ² and Z ³ are nitrogen atoms, R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6]. (Hereinafter, referred to as compound group SX404).

Formula (L-66):
In which Z ⁴ and Z ⁵ are CH ₂ , R ^3b is a hydrogen atom, and T is any one of the substituents described in [Table 1] to [Table 6] And referred to as Compound Group SX405).
In the compound represented by the formula (L-66), Z ⁴ and Z ⁵ are CH ₂ , R ^3b is a trifluoromethyl group, and T is any one of [Table 1] to [Table 6]. (Hereinafter, referred to as compound group SX406).
In the compound represented by the formula (L-66), Z ⁴ is CH ₂ , Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is [Table 1] to [Table 6]. Or any one of the substituents described below (hereinafter referred to as compound group SX407).
In the compound represented by the formula (L-66), Z ⁴ is CH ₂ , Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 1]. 6] (hereinafter, referred to as a compound group SX408).
In the compound represented by the formula (L-66), Z ⁴ is C (O), Z ⁵ is CH ₂ , R ^3b is a hydrogen atom, and T is [Table 1] to [Table 6]. Or a compound having any one of the substituents described below (hereinafter referred to as compound group SX409).
In the compound represented by the formula (L-66), Z ⁴ is C (O), Z ⁵ is CH ₂ , R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 1]. 6] (hereinafter, referred to as a compound group SX410).
In the compound represented by the formula (L-66), Z ⁴ is NH, Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound which is any one of the substituents described below (hereinafter referred to as compound group SX411).
In the compound represented by the formula (L-66), Z ⁴ is NH, Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] A compound (hereinafter, referred to as compound group SX412).
In the compound represented by the formula (L-66), Z ⁴ is C (O), Z ⁵ is NH, R ^3b is a hydrogen atom, and T is in [Table 1] to [Table 6]. A compound which is any one of the substituents described below (hereinafter referred to as compound group SX413).
In the compound represented by the formula (L-66), Z ⁴ is C (O), Z ⁵ is NH, R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX414).
In the compound represented by the formula (L-66), Z ⁴ is NMe, Z ⁵ is C (O), R ^3b is a hydrogen atom, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX415).
In the compound represented by the formula (L-66), Z ⁴ is NMe, Z ⁵ is C (O), R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX416).
In the compound represented by the formula (L-66), Z ⁴ is C (O), Z ⁵ is NMe, R ^3b is a hydrogen atom, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX417).
In the compound represented by the formula (L-66), Z ⁴ is C (O), Z ⁵ is NMe, R ^3b is a trifluoromethyl group, and T is [Table 1] to [Table 6]. ] The compound which is any one of substituents as described in the following (hereinafter referred to as compound group SX418).

Formula (L-67):
Wherein ^{X X1} , Z ^X2 , and Z ^X3 are any combination described in [Table 16] and [Table 17] (hereinafter referred to as compound group SX419).

Formula (L-68):
Wherein ^{X X1} , Z ^X2 , and Z ^X3 are any combination described in [Table 16] and [Table 17] (hereinafter referred to as compound group SX420).

Formula (L-69):
Wherein ^{X X3} , Z ^X4 , and Z ^X5 are any combination described in [Table 18] (hereinafter referred to as compound group SX421).

Formula (L-70):
Wherein ^{X X3} , Z ^X4 , and Z ^X5 are any combination described in [Table 18] (hereinafter referred to as compound group SX422).

This compound comprises the following groups (a), (b), (c), (d), (e), (f), (g), (h), (i) and One or more components selected from the group consisting of group (j) (hereinafter referred to as this component) can be used in combination or in combination.
The mixed or combined means that the present compound and the present component are used simultaneously, separately or at intervals.
When using this compound and this component simultaneously, this compound and this component may be contained in the respectively separate formulation, and may be contained in one formulation.
One aspect of the present invention is that group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h) group (i) ) And one or more components selected from the group consisting of group (j) (that is, the present component), and a composition containing the present compound (hereinafter referred to as composition A).

  Group (a) includes acetylcholinesterase inhibitors (eg carbamate insecticides, organophosphorus insecticides), GABAergic chloride channel antagonists (eg phenylpyrazole insecticides), sodium channel modulators (eg pyrethroid insecticides) ), Nicotinic acetylcholine receptor antagonist modulators (eg neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamatergic chloride channel allosteric modulators (eg macrolide insecticides), juvenile hormone mimics , Multi-site inhibitor, chordal organ TRPV channel modulator, mite growth inhibitor, mitochondrial ATP biosynthesis enzyme inhibitor, oxidative phosphorylation uncoupler, nicotinic acetylcholine receptor Channel blocker (eg nereistoxin insecticide), chitin synthesis inhibitor, molting inhibitor, ecdysone receptor agonist, octopamine receptor agonist, inhibitor of mitochondrial electron transport complex I, II, III and IV, voltage dependent Group consisting of active sodium channel blocker, acetyl-CoA carboxylase inhibitor, ryanodine receptor modulator (eg diamide insecticide), stringed organ modulator, microbial insecticide, and other insecticidal, acaricidal and nematicidal active ingredients . These are described in the classification based on the mechanism of action of IRAC.

  Group (b) includes nucleic acid synthesis inhibitors (eg, phenylamide fungicides, acylamino acid fungicides), cell division and cytoskeleton inhibitors (eg, MBC fungicides), respiratory inhibitors (eg, QoI fungicides) , QiI fungicides), amino acid synthesis and protein synthesis inhibitors (eg, anilinopyridine fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (eg, triazoles) Bactericides), cell wall synthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multi-acting contact active bactericides, microbial bactericides, and other bactericidal active ingredients. These are described in the classification based on the mechanism of action of FRAC.

  Group (c) is a group of plant growth regulating components.

  Group (d) is a group of phytotoxicity reducing components.

  Group (e) is a group of synergists.

  Group (f) is a group of repellent components comprising bird repellent components, insect repellent components and animal repellent components.

  Group (g) is a group of molluscicidal components.

  Group (h) is a group of insect pheromones.

  Group (i) includes acetyl-CoA carboxylase (ACCase) inhibitor, acetolactate synthase (ALS) inhibitor, photosynthesis (photosystem II) inhibitor, photosystem I electron conversion agent, protoporphyrinogen oxidase (PPO) Inhibitor, phytoene desaturase system (PDS) inhibitor, 4-hydroxyphenylpyruvate dioxygenase (4-HPPD) inhibitor, carotenoid biosynthesis inhibitor, EPSP synthase inhibitor, glutamine synthetase inhibitor, dihydroptero Inacid (DHP) synthase inhibitor, microtubule polymerization inhibitor, mitosis / microtubule formation inhibitor, inhibitor of very long chain fatty acid (VLCFA), cellulose synthesis inhibitor, uncoupling agent, lipid synthesis inhibitor , An indole acetic acid-like active agent, an auxin transfer inhibitor, and other herbicidal active ingredients. These are described in the classification based on the mechanism of action of HRAC.

  Group (j) is a microorganism having a pest control effect (for example, insecticidal activity, acaricidal activity, nematicidal activity, bactericidal activity, herbicidal activity, etc.) or a plant growth regulating effect such as rhizobia or mycorrhizal fungi A group of materials.

Below, the example of the combination of this component and this compound is described. For example, alanycarb + SX means a combination of alanycarb and SX.
The abbreviation SX means any one of the present compounds selected from the compound groups SX1 to SX422. In addition, all of the components described below are known components, and can be obtained from commercially available preparations or produced by known methods. If this component is a microorganism, it can also be obtained from a fungus depository. The numbers in parentheses represent CAS RN (registered trademark).

Combination of this component of the above group (a) and this compound:
Abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acetoprole + SX, acrinathrin + SX, acinathyr + acynonapyr Afidopyropen + SX, afoxolaner + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha endosulfan (alpha) -endosulfan) + SX, aluminum phosphide + SX, amitraz + SX, azadirachtin + SX, azamethiphos + SX, azinphos-ethyl + SX, azinphos- methyl) + SX, azocyclotin + SX, Celastrus angulatus bark of bark of Celastrus angulatus + SX, bendiocarb + SX, benful Benfluthrin + SX, benfuracarb + SX, bensultap + SX, benzoximate + SX, benzpyrimoxan + SX, beta-cyfluthrin + SX , Beta-cypermethrin + SX, bifenazate + SX, bifenthrin + SX, bioallethrin + SX, bioresmethrin + SX, bistrifluron + SX , Borax + SX, boric acid + SX, broflanilide + SX, bromopropylate + SX, buprofezin + SX, butocarboxim + SX, Butoxycarboxim + SX, cadusafos + SX, calcium phosphide + SX, carbaryl + SX, carbofuran + SX, carbosulfan + SX, L-tap hydrochloride + SX, cartap + SX, chinomethionat + SX, chlorantraniliprole + SX, chlordane + SX, chlorethoxyfos + SX, chlorfenapyr (chlorfenapyr) + SX, chlorfenvinphos + SX, chlorfluazuron + SX, chlormephos + SX, chlorpicrin + SX, chlorpyrifos + SX, chlorpyrifos methyl ( chlorpyrifos-methyl) + SX, chromafenozide + SX, clofentezine + SX, clothianidin + SX, concanamycin A + SX, coumaphos + SX, cryolite ( cryolite) + SX, cyanophos + SX, cyanantaniprole + SX, cycloniliprole + SX, siku Cycloprothrin + SX, cycloxaprid + SX, cyenopyrafen + SX, cyflumetofen + SX, cyfluthrin + SX, cyhalodiamide + SX, cyhalothrin + cySX (cyhexatin) + SX, cypermethrin + SX, cyphenothrin + SX, cyromazine + SX, dazomet + SX, deltamethrin + SX, demeton-S-methyl (demeton) -S-methyl) + SX, diafenthiuron + SX, diazinon + SX, dichlorvos + SX, dicloromezotiaz, dicohol + SX, dicrotophos ) + SX, diflovidazin + SX, diflubenzuron + SX, dimefluthrin + SX, dimethoate + SX, dimethylvinphos (dime) thylvinphos + SX, dinotefuran + SX, disodium octaborate + SX, disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, doramectin + SX, dried leaves of Dryopteris filix-mas + SX, emamectin benzoate + SX, empenthrin + SX, endosulfan + SX, EPN (O-ethyl) O- (4-nitrophenyl) phenylphosphonothioate) + SX, epsilon-metofluthrin + SX, epsilon-momfluorothrin + SX, esfenvalerate + SX, ethiofencarb + SX, ethion + SX, ethiprole + SX, ethoprophos + SX, etofenprox + SX, etoxazole + SX, extract of Artemisia absinthium + SX , Ca ssia nigricans extract (extract of Cassia nigricans) + SX, extract of clitoria ternatea (extract of clitoria ternatea) + SX, extract of Symphytum officinale + SX, extract of origami (extracts or simulated blend of Chenopodium ambrosioides) + SX, extract of Tanacetum vulgare + SX, extract of Urtica dioica + SX, extract of Viscum album + SX, famphur + SX, Fenamiphos + SX, fenazaquin + SX, fenbutatin oxide + SX, fenitrothion + SX, fenobucarb + SX, fenoxycarb + SX, fenpropathrin ) + SX, fenpyroximate + SX, fenthion + SX, fenvalerate + SX, fipronil + SX, flometoq uin) + SX, flonicamid + SX, fluacrypyrim + SX, fluazaindolizine + SX, fluazuron + SX, flubendiamide + SX, flucycloxuron ) + SX, flucythrinate + SX, fluensulfone + SX, flufenprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin ( flumethrin) + SX, flupiradifuron + SX, fluprimin + SX, fluralaner + SX, flvalinate + SX, fluxametamide + SX, formetanate + SX, phosthiazet fosthiazate) + SX, furamethrin + SX, furathiocarb + SX, gamma-cyhalothrin + SX, GS-omega / kappa HXTX-H v1a peptide (GS-omega / kappa HXTX-Hv1a peptide) + SX, halfenprox + SX, halofenozide + SX, heptafluthrin + SX, heptenophos + SX, hexafull Hexaflumuron + SX, hexythiazox + SX, potassium salt of hop beta acid + SX, hydramethylnon + SX, hydroprene + SX, imicyafos ) + SX, imidacloprid + SX, imiprothrin + SX, indoxacarb + SX, isocycloseram + SX, isofenphos + SX, isoprocarb + SX, Isopropyl O- (methoxyaminothiophosphoryl) salicylate (isopropyl-O- (methoxyaminothiophosphoryl) salicylate) + SX, isoxathion + SX, ivermectin + SX, Cadethrin + SX, kappa-tefluthrin + SX, kappa-bifenthrin + SX, kinoprene + SX, lambda-cyhalothrin + SX, lenoremycin ) + SX, lepimectin + SX, lime sulfur + SX, lotilaner + SX, lufenuron + SX, machine oil + SX, malathion + SX, mecarbam + SX, meperfluthrin + SX, metaflumizone + SX, metam + SX, metamidophos + SX, methidathion + SX, methiocarb + SX , Metomyl + SX, metoprene + SX, methoxychlor + SX, methoxyfenozide + SX, methyl bromide + SX, mettofluthrin + SX, metolca rb) + SX, metoxadiazone + SX, mevinphos + SX, milbemectin + SX, milbemycin oxime + SX, momfluorothrin + SX, monocrotophos + SX, moxidectin + SX, nared + SX, neem oil + SX, nicotine + SX, nicotine-sulfate + SX, nitenpyram + SX, nobarulon (novaluron) + SX, noviflumuron + SX, oil of the seeds of Chenopodium anthelminticum + SX, omethoate + SX, oxamyl + SX, oxazosulfyl ) + SX, oxydemeton-methyl + SX, parathion + SX, parathion-methyl + SX, permethrin + SX, phenothrin + SX, phentoate (ph) enthoate) + SX, phorate + SX, phosalone + SX, phosmet + SX, phosphamidon + SX, phosphine + SX, phoxim + SX, pirimicarb ) + SX, pirimiphos-methyl + SX, prallethrin + SX, profenfos + SX, profluthrin + SX, propargite + SX, propetamphos + SX, propoxyl (SX) propoxur) + SX, propylene glycol alginate + SX, prothiofos + SX, pyflubumide + SX, pyrometrozine + SX, pyraclofos + SX, pyrethrins + SX, pyridaben + SX, pyridalalyl + SX, pyridaphenthion + SX, pyrifluquinazone + SX, pyrimidifen + S X, pyriminostrobin + SX, pyriprole + SX, pyriproxyfen + SX, quinalphos + SX, resmethrin + SX, rotenone + SX, ryanodine (ryanodine) + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate + SX, metaboric acid Sodium metaborate + SX, spinetoram + SX, spinosad + SX, spirodiclofen + SX, spiromesifen + SX, spiropidion + SX, spirotetramat (spirotetramat) + SX, sulfluramid + SX, sulfurotep + SX, sulfoxaflor + SX, sulfur + SX, sulfuryl fluoride + SX, tartar r emetic) + SX, tau-fluvalinate + SX, tebufenozide + SX, tebufenpyrad + SX, tebupirimfos + SX, teflubenzuron + SX, tefluthurine (SX)
fluthrin) + SX, temephos + SX, terbufos + SX, terpene constituents of the extract of chenopodium ambrosioides near ambrosioides, Brand name: Terpenoid blend QRD 460) + SX, tetrachrome Lantraniliprole + SX, tetrachlorvinphos + SX, tetradifon + SX, tetramethrin + SX, tetramethylfluthrin + SX, tetraniliprole + SX, theta-cypermethrin + SX, thiacloprid + SX, thiamethoxam + SX, thiocyclam + SX, thiodicarb + SX, thiofanox + SX , Thiometon + SX, thiosultap-disodium + SX, thiosultap-monosodi um) + SX, tioxazafen + SX, tolfenpyrad + SX, tralomethrin + SX, transfluthrin + SX, triazamate + SX, triazophos + SX, trichlorphos (trichlorfon) + SX, triflumezopyrim + SX, triflumuron + SX, trimethacarb + SX, tyclopyrazoflor + SX, vamidthioion + SX, wood Ingredients (wood extract of Quassia amara) + SX, XMC (3,5-dimethylphenyl N-methylcarbamate) + SX, xylylcarb + SX, zeta-cypermethrin + SX, zinc phosphide + SX, N- [3-Chloro-1- (pyridin-3-yl) -1H-pyrazol-4-yl] -N-ethyl-3- (3,3,3-trifluoropropanesulfinyl) Lopanamide (1477923-37-7) + SX, 4- [5- (3,5-dichlorophenyl) -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl] -2 -Methyl-N- (1-oxothietan-3-yl) benzamide (1241050-20-3) + SX, 3-methoxy-N- (5- {5- (trifluoromethyl) -5- [3- (tri Fluoromethyl) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} indan-1-yl) propanamide (1118626-57-5) + SX, N- [2-bromo-6-chloro -4- (1,1,1,2,3,3,3-heptafluoropropan-2-yl) phenyl] -3- {ethyl [(pyridin-4-yl) carbonyl] amino} -2-methoxybenzamide (1429513-53-0) + SX, N- [2-Bromo-6-chloro-4- (1,1, 1,2,3,3,3-heptafluoropropan-2-yl) phenyl] -3- [ethyl (4-cyanobenzoyl) amino] -2-methoxybenzamide (1609007-65-9) + SX, N- [2-Bromo-6-difluoromethoxy-4- (1,1,1,2,3,3,3-heptafluoropropan-2-yl) phenyl] -3- {methyl [(pyridin-4-yl) Carbonyl] amino} -2-methoxybenzamide (1630969-78-6) + SX, 1- {2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl) sulfinyl] phenyl} -3 -(Trifluoromethyl) -1H-1,2,4-triazol-5-amine (885026-50-6) + SX, BT crop protein Cry1Ab (BT crop protein Cry1Ab) + SX, BT crop protein Cry1Ac ( BT crop protein Cry1Ac) + SX, BT crop protein Cry1Fa (BT crop protei n Cry1Fa) + SX, BT crop protein Cry1A.105 (BT crop protein Cry1A.105) + SX, BT crop protein Cry2Ab (BT crop protein Cry2Ab) + SX, BT crop protein Vip3A (BT crop protein Vip3A) + SX, BT crop protein mCry3A (BT crop protein Cry3A) + SX, BT crop protein Cry3Ab (BT crop protein Cry3Ab) + SX, BT crop protein Cry3Bb + SX, BT crop protein Cry34Ab1 / Cry35Ab1 (BT crop protein Cry34Ab1 / Cry35Ab1) + SX.

Combination of this component of the above group (b) and this compound:
Acibenzolar-S-methyl + SX, aldimorph + SX, ametoctradin + SX, aminopyrifen + SX, amisulbrom + SX, anilazine + SX, Azaconazole + SX, azoxystrobin + SX, basic copper sulfate + SX, benalaxyl + SX, benalaxyl-M + SX, benodanil + SX, benomyl + SX, benthiavalicarb + SX, benthivalicarb-isopropyl + SX, benzovindiflupyr + SX, binapacryl + SX, Biphenyl + SX, bitertanol + SX, bixafen + SX, blasticidin-S + SX, Bordeaux mixture + SX, boscalid + SX, bromotalonyl ( b romothalonil) + SX, bromuconazole + SX, bupirimate + SX, captafol + SX, captan + SX, carbendazim + SX, carboxin + SX, carpropamid + SX, chinomethionat + SX, chitin + SX, chloroneb + SX, chlorothalonil + SX, chlozolinate + SX, collochlorin B (colltochlorin B) ) + SX, copper (II) acetate + SX, copper (II) hydroxide + SX, copper oxychloride + SX, copper sulfate (II) ) (copper (II) sulfate) + SX, coumoxystrobin + SX, cyazofamid + SX, cyflufenamid + SX, cymoxanil + SX, cyproconazole + SX , Cyprodinil + SX, Diclobentiazox ) + SX, dichlofluanid + SX, dilocymet + SX, diclomezine + SX, dicloran + SX, dietofencarb + SX, difenoconazole + SX, difenoconazole diflumetorim) + SX, dimethachlone + SX, dimethirimol + SX, dimethomorph + SX, dimoxystrobin + SX, diniconazole + SX, diiconazole-M + SX, dinocap + SX, dipotassium hydrogenphosphite + SX, dipymetitrone + SX, dithianon + SX, dodecylbenzenesulphonic dodecylbenzenesulphonic acid (dodecylbenzenesulphonic) acid bisethylenediamine copper (II) salt) + SX, dodemorph + SX, dodine + SX, edifenphos + SX, e Xenostrobin + SX, epoxiconazole + SX, etaconazole + SX, ethaboxam + SX, ethirimol + SX, etridiazole + SX, tea tree extract from Melaleuca alternifolia) + SX, extract of reedoutria sachalinensis + SX, extract from cotyledons of lupine plantlets ("BLAD") + SX, extract of garlic Allium sativum) + SX, extract of Equisetum arvense + SX, extract of Tropaeolum majus + SX, famoxadone + SX, fenamidone + SX, fenaminstrobin ) + SX, fenarimol + SX, fenbuconazole, fenfuram + SX, fenhexamid + SX, phenoxanyl ( fenoxanil) + SX, fenpiclonil + SX, fenpicoxamid + SX, fenpropidin + SX, fenpropimorph + SX, fenpyrazamine + SX, triphenyl acetate Fentin acetate + SX, fentin chloride + SX, fentin hydroxide + SX, ferbam + SX, ferimzone + SX, florylpicoxamide (florylpicoxamid) + SX, fluazinam + SX, fludioxonil + SX, flufenoxystrobin + SX, fluindapyr + SX, flumorph + SX, fluopicolide + SX , Fluopyram + SX, fluopimomide + SX, fluoroimide + SX, fluoxastrobin + SX, fluquinconazole + SX, Flusilazole + SX, flusulfamide + SX, flutianil + SX, flutolanil + SX, flutriafol + SX, fluxapyroxad + SX, folpet ) + SX, fosetyl + SX, fosetyl-aluminium + SX, fuberidazole + SX, furalaxyl + SX, furametpyr + SX, guazatine + SX, hexa Hexaconazole + SX, hymexazole + SX, imazalil + SX, imibenconazole + SX, iminoctadine + SX, iminoctadine triacetate + SX, inpyr Influrfluxam + SX, iodocarb + SX, ipconazole + SX, ipfentrifluconazole + SX, ipflufenoxy Ipflufenoquin + SX, iprobenfos + SX, iprodione + SX, iprovalicarb + SX, isofetamid + SX, isoflucypram + SX, isoprothiolane + SX , Isopyrazam + SX, Isotianil + SX, kasugamycin + SX, kresoxim-methyl + SX, laminarin + SX, oak leaves and bark of Quercus + SX, mancozeb + SX, mandestrobin + SX, mandipropamid + SX, maneb + SX, mefentrifluconazole + SX, mepanipyrim + SX, Mepronil + SX, meptyldinocap + SX, metalaxyl + SX, metalaxyl-M + SX, metconazole + SX, metas Methasulfocarb + SX, metiram + SX, metinominostrobin + SX, metrafenone + SX, methyltetraprole + SX, mineral oils + SX, microbutanyl ( myclobutanil) + SX, naftifine + SX, nuarimol + SX, octhilinone + SX, ofurace + SX, orysastrobin + SX, oxadixyl + SX, oxathiapi Oxathiapiprolin + SX, oxine-copper + SX, oxolinic acid + SX, oxpoconazole + SX, oxpoconazole fumarate + SX, oxycarboxin ( oxycarboxin) + SX, oxytetracycline + SX, pefurazoate + SX, penconazole + SX, pencycuron + SX, penflufen + SX, penthiopyrad + SX, phenamacril + SX, phosphorous acid + SX, phthalide + SX, picarbutrazox + SX, picoxystrobin ) + SX, piperalin + SX, polyoxins + SX, potassium hydrogencarbonate + SX, potassium dihydrogenphosphite + SX, probenazole + SX, prochloraz ( prochloraz) + SX, procymidone + SX, propamidine + SX, propamocarb + SX, propiconazole + SX, propineb + SX, proquinazid + SX, prothiocarb (prothiocarb) + SX, prothioconazole + SX, pydiflumetofen + SX, pyraclostrobin + SX, pyrametostrobin bin) + SX, pyraoxystrobin + SX, pyrapropoyne + SX, pyraziflumid + SX, pyrazophos + SX, pyribencarb + SX, pyributicarb + SX Pyridachlometyl + SX, pyrifenox + SX, pyrimethanil + SX, pyrimorph + SX, pyriophenone + SX, pyrisoxazole + SX, pyroquilon + SX, Quillaja extract + SX, quinconazole + SX, quinofumelin + SX, quinoxyfen + SX, quintozene + SX, Saponins of quinoa Chenopodium quinoa) + SX, sedaxane + SX, silthiofam + SX, simeconazole + SX, sodium hydrogencarbonate + SX, spi Roxamine + SX, streptomycin + SX, sulfur + SX, tebuconazole + SX, tebufloquin + SX, teclofthalam + SX, tecnazene + SX, terbinafine (terbinafine) + SX, tetraconazole + SX, thiabendazole + SX, thifluzamide + SX, thiophanate + SX, thiophanate-methyl + SX, thiram + SX, thymol + SX, tiadinil + SX, tolclofos-methyl + SX, tolfenpyrad + SX, tolprocarb + SX, tolylfluanid + SX, triazime (triadimefon) + SX, triadimenol + SX, triazoxide + SX, triclopyricarb + SX, tricyclazole (tric yclazole) + SX, triridemorph + SX, trifloxystrobin + SX, triflumizole + SX, triforine + SX, triticonazole + SX, validamycin ) + SX, valifenalate + SX, vinclozolin + SX, yellow mustard powder + SX, zinc thiazole + SX, zineb + SX, ziram + SX, zoxamide (zoxamide) + SX, 3- (difluoromethyl) -N-methoxy-1-methyl-N-[(1R) -1-methyl-2- (2,4,6-trichlorophenyl) ethyl] pyrazole-4- Carboxamide (1639015-48-7) + SX, 3- (difluoromethyl) -N-methoxy-1-methyl-N-[(1S) -1-methyl-2- (2,4,6-trichlorophenyl) ethyl ] -1H-pyrazole-4-ca Boxamide (1639015-49-8) + SX, 3- (Difluoromethyl) -1-methyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) pyrazole-4 Carboxamide (141573-94-6) + SX, 3- (difluoromethyl) -N-[(3R) -7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-indene-4- Yl] -1-methyl-1H-pyrazole-4-carboxamide (1513466-73-3) + SX, N ′-[4-({3-[(4-chlorophenyl) methyl] -1,2,4-thiadiazole -5-yl} oxy) -2,5-dimethylphenyl] -N-ethyl-N-methylmethanimidamide (1202781-91-6) + SX, 2- {3- [2- (1- {2- [3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidine-4 Yl) -1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -3-chlorophenyl methanesulfonate (1360819-11-9) + SX, 4- (2-Bromo-4-fluorophenyl) -N- (2-chloro-6-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX, 2- [ 6- (3-Fluoro-4-methoxyphenyl) -5-methylpyridin-2-yl] quinazoline (1257056-97-5) + SX, 5-fluoro-2-[(4-methylphenyl) methoxy] pyrimidine- 4-Amine (1174376-25-0) + SX, 5-Fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2 (1H) -one (1616664-98-2) + SX, N ′-(2,5-dimethyl-4-phenoxyphenyl) -N-ethyl-N-methylmethane Imidoamide (1052688-31-9) + SX, N ′-{4-[(4,5-dichlorothiazol-2-yl) oxy] -2,5-dimethylphenyl} -N-ethyl-N-methylmethaneimide Amide (929908-57-6) + SX, (2Z) -3-amino-2-cyano-3-phenyl acrylate (39491-78-6) + SX, N-[(2-chlorothiazole-5- Yl) methyl] -N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, α- [3- (4-chloro-2-fluorophenyl) -5- ( 2,4-difluorophenyl) -4-isoxazolyl] -3-pyridinemethanol (1229605-96-2) + SX, (αS)-[3- (4-chloro-2-fluorophenyl) -5- (2, 4-Difluorophenyl) -4-isoxazolyl] -3-pyridinemethanol (1229606-46-5) + SX, (αR)-[3 -(4-Chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -4-isoxazolyl] -3-pyridinemethanol (1229606-02-3) + SX, 2-{[3- (2 -Chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione (1342260-19-8) + SX, 2-{[(2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2 , 4-Triazole-3-thione (1638897-70-7) + SX, 2-{[(2S, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2- Yl] methyl} -2,4-dihydro-3H-1,2,4-triazol -3-thione (1638897-71-8) + SX, 2-{[(2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxilan-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione (1638897-72-9) + SX, 2-{[(2S, 3S) -3- (2-chlorophenyl) -2- (2,4-Difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione (1638897-73-0) + SX, 1-{[ 3- (2-Chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanate (1342260-26-7) + SX , 1-{[(2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) Xylan-2-yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanato (1638897-82-1) + SX, 1-{[(2S, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanato (1638897-84-3) + SX, 1-{[(2R , 3R) -3- (2-Chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanate (1638897-86- 5) + SX, 1-{[(2S, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4- Triazol-5-yl thiocyanato (1638897-89-8) + SX, 5- (4-chloro (Benzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentan-1-ol (1394057-11-4) + SX, (1R, 2S, 5S) -5- (4-Chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentan-1-ol (1801930-06-2) ) + SX, (1S, 2R, 5R) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentane- 1-ol (1801930-07-3) + SX, (1R, 2R, 5R) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4- Triazol-1-ylmethyl) cyclopentan-1-ol (1801919-53-8) + SX, (1S 2S, 5S) -5- (4-Chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentan-1-ol (1801919-54 -9) + SX, (1R, 2R, 5S) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclo Pentan-1-ol (1801919-55-0) + SX, (1S, 2S, 5R) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2, 4-Triazol-1-ylmethyl) cyclopentan-1-ol (1801919-56-1) + SX, (1R, 2S, 5R) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl- 1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentane-1 -Ol (1801919-57-2) + SX, (1S, 2R, 5S) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazole -1-ylmethyl) cyclopentan-1-ol (1801919-58-3) + SX, methyl = 3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2, , 4-Triazol-1-ylmethyl) cyclopentane-1-carboxylate (1791398-02-1) + SX, methyl = (1R, 2S, 3S) -3-[(4-chlorophenyl) methyl] -2-hydroxy -1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentane-1-carboxylate (2080743-90-2) + SX, methyl = (1S, 2R, 3R) -3 -[(4-Chlorophenyl) methyl] -2-hydroxy-1-methyl -2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentane-1-carboxylate (2080743-91-3) + SX, methyl = (1R, 2R, 3R) -3-[(4 -Chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentane-1-carboxylate (2080743-92-4) + SX, methyl = (1S, 2S, 3S) -3-[(4-Chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentane-1-carboxy Lat (2080743-93-5) + SX, methyl = (1R, 2R, 3S) -3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4 -Triazol-1-ylmethyl) cyclope Tan-1-carboxylate (2080743-94-6) + SX, methyl = (1S, 2S, 3R) -3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H- 1,2,4-triazol-1-ylmethyl) cyclopentane-1-carboxylate (2080743-95-7) + SX, methyl = (1R, 2S, 3R) -3-[(4-chlorophenyl) methyl]- 2-hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentane-1-carboxylate (2081061-22-3) + SX, methyl = (1S, 2R, 3S ) -3-[(4-Chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentane-1-carboxylate (2081061-23- 4) + SX, 2-chloromethyl-5- (4 -Fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentan-1-ol (1394057-13-6) + SX, (1R, 2S, 5S)- 2-Chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentan-1-ol (1801930-08-4) + SX , (1S, 2R, 5R) -2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentan-1-ol (1801930-09-5) + SX, (1R, 2R, 5R) -2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazole-1 -Ylmethyl) cyclopentan-1-ol (1638898-08-4) + SX, (1S, 2 , 5S) -2-Chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentan-1-ol (1638898-10- 8) + SX, (1R, 2R, 5S) -2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentane -1-ol (1638898-13-1) + SX, (1S, 2S, 5R) -2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2,4 -Triazol-1-ylmethyl) cyclopentan-1-ol (1638898-16-4) + SX, (1R, 2S, 5R) -2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1 -(1H-1,2,4-triazol-1-ylmethyl) cyclopenta -1-ol (1638898-20-0) + SX, (1S, 2R, 5S) -2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2,4 -Triazol-1-ylmethyl) cyclopentan-1-ol (1638898-24-4) + SX, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4- Triazol-1-yl) pent-3-in-2-ol + SX, (R) -2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazole -1-yl) pent-3-yn-2-ol (1801919-59-4) + SX, (R) -2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl]- 1- (1,2,4-Triazol-1-yl) propan-2-ol (1616236-94-2) + SX, 1- [4- (4-chloroph Enoxy) -2- (trifluoromethyl) phenyl] -1-cyclopropyl-2- (1,2,4-triazol-1-yl) ethanol + SX, (R) -1- [4- (4-chloro Phenoxy) -2- (trifluoromethyl) phenyl] -1-cyclopropyl-2- (1,2,4-triazol-1-yl) ethanol (1801919-60-7) + SX, (R) -2- [4- (4-Chlorophenoxy) -2- (trifluoromethyl) phenyl] -3-methyl-1- (1,2,4-triazol-1-yl) butan-2-ol (1801919-61-8 ) + SX, methyl = ({2-methyl-5- [1- (4-methoxy-2-methylphenyl) -1H-pyrazol-3-yl] phenyl} methyl) carbamate (1605879-98-8) + SX , 2- (difluoromethyl) -N- [1,1,3-trimethyl-2, - dihydro -1H- inden-4-yl] pyridine-3-carboxamide (1616239-21-4) + SX, 2- (difluoromethyl) -N - [(
3R) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] pyridine-3-carboxamide (1616239-33-8) + SX, 2- (difluoromethyl) -N- [ 3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl] pyridine-3-carboxamide (1847460-02-9) + SX, 2- (difluoromethyl) -N-[( 3R) -3-Ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl] pyridine-3-carboxamide (1952305-97-3) + SX, 2- (difluoromethyl) -N -[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl] pyridine-3-carboxamide (1847460-05-2) + SX, 2- (difluoromethyl) -N- [(3R) -3-propyl-1,1-dimethyl-2,3-dihydro- H-Inden-4-yl] pyridine-3-carboxamide (1952306-00-1) + SX, (2E, 3Z) -5-{[1- (4-chlorophenyl) -1H-pyrazol-3-yl] oxy } -2- (Methoxyimino) -N, 3-dimethylpent-3-enamide (1445331-27-0) + SX.

Combination of this component of the above group (c) and this compound:
1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 2,3,5-triiodobenzoic acid + SX , IAA ((1H-indol-3-yl) acetic acid) + SX, IBA (4- (1H-indol-3-yl) butyric acid) + SX, MCPA (2- (4-chloro-2-methylphenoxy) acetic acid) + SX, MCPB (4- (4-chloro-2-methylphenoxy) butyric acid) + SX, 4-CPA (4-chlorophenoxyacetic acid) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anthymidol + SX, butralin + SX, calcium carbonate (calcium carbonate) + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + S X, chlormequat-chloride + SX, chloropropham + SX, choline chloride + SX, cloprop + SX, cyanamide + SX, cyclanilide ) + SX, daminozide + SX, decan-1-ol + SX, dichlorprop + SX, dikegulac + SX, dimethipin + SX, diquat ( diquat) + SX, ethephon + SX, etychlozate + SX, flumetralin + SX, flurprimidol + SX, forchlorfenuron + SX, formononetin + SX , Gibberellin A + SX, Gibberellin A3 + SX, Inabenfide + SX, Kinetin + SX, lipochitooligosaccharide SP104 + SX, Maleic hydrazide + SX, Difluide (mefluidide) + SX, mepiquat-chloride + SX, oxidized glutathione + SX, pacrobutrazol + SX, pendimethalin + SX, prohexadione Calcium (prohexandione-calcium) + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, sintofen + SX, 1-sodium 1-naphthaleneacetate + SX , Sodium cyanate + SX, streptmycin + SX, thidiazuron + SX, triapenthenol + SX, tribufos + SX, trinexapac-ethyl + SX, uniconazole-P + SX, 2- (naphthalene-1-yl) acetamide + SX, [4-oxo-4- (2-phenylethyl) )amino Butyric acid + SX, 5- (trifluoromethyl) benzo [b] methyl thiophene-2-carboxylate + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl) amino] -1-propanol + SX , Strigolactone + SX, (1E) -1-[[1- [3,5-bis (trifluoromethyl) phenyl] -4-methyl-5-oxo-2H-pyrrole described in International Publication No.2018 / 145979 -2-yl] oxymethylene] -3,3a, 4,8b-tetrahydroindeno [2,1-b] pyrrol-2-one + SX, (2R) -1- [3 described in WO 2018/145979 , 5-bis (trifluoromethyl) phenyl] -4-methyl-2-[(E)-(2-oxo-4,8b-dihydro-3aH-indeno [2,1-b] furan-1-ylidene) methoxy] -2H-pyrrol-5-one + SX, (2S) -1- [3,5-bis (trifluoromethyl) phenyl] -4-methyl-2-[(E)-, as described in WO 2018/145979 (2-oxo-4,8b-dihydro-3aH-indeno [2,1-b] furan-1-ylidene) methoxy] -2H-pyrrol-5-one + SX.

Combination of this component of the above group (d) and this compound:
Allidochlor + SX, benoxacor + SX, cloquintocet + SX, cloquintocet-mexyl + SX, cyometrinil + SX, cyprosulfamide + SX, dichlormid + SX, dicyclonone + SX, dimepiperate + SX, disulfoton + SX, dymron + SX, fenchlorazole + SX, fenchlorazole Fenchlorazole-ethyl + SX, fenclorim + SX, flurazole + SX, furilazole + SX, flxofenim + SX, hexim + SX, isoxadifen + SX , Isoxadifen-ethyl + SX, mecoprop + SX, mefenpyr + SX, mefenpyr-ethyl + SX, mefenpyrdi Chill (mefenpyr-diethyl) + SX, mephenate + SX, meetcamifen + SX, oxabetrinil + SX, 1,8-naphthalic anhydride + SX, 1 , 8-octamethylenediamine + SX, AD-67 (4- (dichloroacetyl) -1-oxa-4-azaspiro [4.5] decane) + SX, CL-304415 (4-carboxy- 3,4-dihydro-2H-1-benzopyran-4-acetic acid) + SX, CSB (1-bromo-4-[(chloromethyl) sulfonyl] benzene) + SX, DKA-24 (2,2-dichloro-N -[2-oxo-2- (2-propenylamino) ethyl] -N- (2-propenyl) acetamide) + SX, MG191 (2- (dichloromethyl) -2-methyl-1,3-dioxolane) + SX, MG -838 (2-propenyl 1-oxa-4-azaspiro [4.5] decane-4-carbodithioate) + SX, PPG-1292 (2,2-dichloro-N- (1,3-dioxan-2-ylmethyl) -N -(2-propenyl) acetamide) + SX, R-28725 (3- (dichloroacetyl) -2,2-dimethyl-1,3-oxazolidine) + SX, R-29148 (3- (dichloroacetyl) -2,2, 5-trimethyl-1,3-oxazolidine) + SX, TI-35 (1- (dichloroacetyl) azepane) + SX.

Combination of this component of the above group (e) and this compound:
1-dodecyl-1H-imidazole + SX, N- (2-ethylhexyl) -8,9,10-trinorborn-5-ene-2,3-dicarboximide (N -(2-ethylhexyl) -8,9,10-trinorborn-5-ene-2,3-dicarboximide) + SX, bucarpolate + SX, N, N-dibutyl-4-chlorobenzenesulfonamide (N, N -dibutyl-4-chlorobenzenesulfonamide) + SX, dietholate + SX, diethylmaleate + SX, piperonyl butoxide + SX, piperonylcyclonene + SX, piperotal + SX, propyl isome + SX, safroxan + SX, sesamex + SX, sesamolin + SX, sulfoxide + SX, Verbutin + SX, DMC (1, 1-bis (4-chlorophenyl) ethanol) + SX, FDMC (1,1-bis (4-chlorophenyl) -2,2,2-trifluoroethanol) + SX, ETN (1,2- epoxy-1,2,3,4-tetrahydronaphthalene) + SX, ETP (1,1,1-trichloro-2,3-expoxypropane) + SX, PSCP (phenylsaligenin cyclic phosphate) + SX, TBPT (S, S, S -tributyl phosphorotrithioate) + SX, TPP (triphenyl phosphate) + SX.

Combination of this component of the above group (f) and this compound:
Anthraquinone + SX, chloralose + SX, acrep + SX, butopyronoxyl + SX, camphor + SX, d-camphor + SX, carboxide ) + SX, dibutyl phthalate + SX, deet + SX, dimethyl carbate + SX, dimethyl phthalate + SX, dibutyl succinate + SX , Dibutyl adipate + SX, ethohexadiol + SX, hexamid + SX, icaridin + SX, methoquin-butyl + SX, methyl neodecanamide (methylneodecanamide) + SX, 2- (octylthio) ethanol + SX, butoxypolypropylene glycol + SX, oxamate + SX, quwenzhi + SX, quyingding + SX, zengxiaon + SX, Les Rebemide + SX, copper naphthenate + SX, zinc naphthenate + SX.

Combination of this component of the above group (g) and this compound:
Bis (tributyltin) oxide + SX, allicin + SX, bromoacetamide + SX, cloethocarb + SX, copper sulfate + SX, fentin ) + SX, ferric phosphate + SX, metaldehyde + SX, niclosamide + SX, pentachlorophenol + SX, sodium pentachlorophenoxide + SX, tazimcarb + SX, tralopyril + SX, trifenmorph + SX.

Combination of this component of the above group (h) and this compound:
(E) -2-hexenal + SX, (E) -2-octadecenal + SX, (E) -4-tridecen-1-yl acetate + SX, (E) -5-decen-1-yl acetate + SX, (E) -5-decen-1-ol + SX, (E) -3,3-dimethylcyclohexylideneacetaldehyde + SX, (E) -7-dodecen-1-yl acetate + SX, (E) -8-dodecen-1 -yl acetate + SX, (E) -9-dodecen-1-yl acetate + SX, (E) -10-hexadecenal + SX, (E) -11-hexadecen-1-yl acetate + SX, (E)- 11-tetradecen-1-yl acetate + SX, (E) -11-tetradecen-1-ol + SX, (E) -4-tridecen-1-yl acetate + SX, (E) -6-methylhept-2- en-4-ol + SX, (Z) -2- (3,3-dimethylcyclohexylidene) ethanol + SX, (Z) -4-decen-1-yl acetate + SX, (Z) -4-tridecen-1- yl acetate + SX, (Z) -5-decen-1-yl acetate + SX, (Z) -5-decen-1-ol + SX, (Z) -7-tetradecenal + SX, (Z) -7- dodecen-1-yl acetate + SX, (Z) -8-dodecen-1-yl acetate + SX, (Z) -9-dodecen-1-yl acetate + SX, (Z) -8-dodecen-1-ol + SX, (Z) -9-hexadecenal + SX, (Z) -10-hexadecen-1-yl acetate + SX, (Z) -11-hexadecen-1-ol + SX, (Z) -11-hexadecenal + SX, (Z) -11-hexadecen-1-yl acetate + SX, (Z) -11-octadecenal + SX, (Z) -13-octadecenal + SX, (Z) -hexad ec-13-en-11-yn-1-yl acetate + SX, (Z) -13-octadecenal + SX, (Z) -icos-13-en-10-one + SX, (Z) -7-tetradecenal + SX, (Z) -tetradec-9-en-1-ol + SX, (Z) -9-tetradecen-1-yl acetate + SX, (Z) -11-tetradecen-1-yl acetate + SX, ( Z) -13-icosen-10-one + SX, (Z, E) -7,11-hexadecadien-1-yl acetate + SX, (Z, E) -9,12-tetradecadien-1-yl acetate + SX , (E, Z) -4,10-tetradecadien-1-yl acetate + SX, (E, E) -8,10-dodecadien-1-ol + SX, (E, E) -10,12-hexadecadienal + SX, (E, E) -9,11-tetradecadien-1-yl acetate + SX, (E, Z) -2,13-octadecadien-1-ol + SX, (E, Z) -3,13-octadecadien -1-ol + SX, (E, Z) -2,13-octadecadien-1-yl acetate + SX, (E, Z) -3,13-octadecadien-1-yl acetate + SX, (E, Z) -7,9-dodecadien-1-yl acetate + SX, (E, E) -7,9-dodecadien-1-yl acetate + SX, (Z, E) -9,12-tetradecadien-1-yl acetate + SX, (Z, E) -9,11-tetradecadien-1-yl acetate + SX, (Z, E) -7,11-hexadecadien-1-yl acetate + SX, (Z, Z) -3,13- octadecadien-1-ol + SX, (Z, Z) -4,7-decadien-1-yl acetate + SX, (Z, Z) -3,13-octadecadien-1-yl acetate + SX, (Z, Z ) -7,11-hexadecadien-1-yl acetat e + SX, (Z, Z, E) -7,11,13-hexadecatrienal + SX, (5R) -5-[(1Z) -1-decen-1-yl] dihydro-2 (3H) -furanone + SX, (2R, 5R) -ethyl-1,6-dioxaspiro [4,4] nonane + SX, (2R, 5S) -ethyl-1,6-dioxaspiro [4,4] nonane + SX, (4R, 8R ) -4,8-dimethyldecanal + SX, (4R, 8S) -4,8-dimethyldecanal + SX, 2,4-dimethyl-5-ethyl-6,8-dioxabicyclo [3,2,1] octane + SX, (-)-4-methyl-3-heptanol + SX, 1,7-dioxaspiro [5,5] undecane + SX, 3-carene + SX, 3-methylcyclohex-2-en-1-one + SX, 14- methyloctadec-1-ene + SX, 4-methylnonan-5-ol + SX, 4-methylnonan-5-one + SX, 4- (3-oxobutyl) phenyl acetate + SX, dodecyl acetate + SX, dodeca-8,10 -dien-1-yl acetate + SX, ethyl (2E, 4Z) -decadienoate + SX, ethyl 4-methyloctanoate + SX, methyl 2,6,10-trimethyldodecanoate + SX, tetradecan-1-ol + SX, tetradec-11 -en-1-ol + SX, tetradec-11-en-1-yl acetate + SX, tridec-4-en-1-yl acetate + SX, (3S, 6R) -3-methyl-6-isopropenyl-9 -decen-1-yl acetate + SX, (3S, 6S) -3-methyl-6-isopropenyl-9-decen-1-yl acetate + SX, alpha-multistriatin + SX, alpha-pinene + SX, endo-brevicomin + SX, exo-brevicomin + SX, camphene + SX, codlelure + SX, codlemone + SX, cuelure + SX, disparlure + SX, dominicalure + SX, eugenol + SX, farnesol + SX, ferrolure + SX, frontalin + SX, gossyplure + SX, grandlure + SX, grandlure I + SX, grandlure II + SX, grandlure III + SX, grandlure IV + SX, hexalure + SX, ipsdienol + SX, ipsenol + SX, japonilure + SX, lineatin + SX, litlue + SX, looplure + SX, medlure + SX, megatomoic acid + SX, methyl eugenol + SX, muscalure + SX, nerolidol + SX, orfralure + SX, oryctalure + SX, ostramone + SX, rhyncolure + SX, siglure + SX, sordidin + SX, sulcatol + SX, trimedlure + SX, trimedlure A + SX, trimedlure B1 + SX, trimedlure B2 + SX, trimedlure C + SX, trunc-call + SX, (E) -verbenol + SX, (Z) -verbenol + SX, trans-verbenol + SX, (S) -verbenone + SX.

Combination of this component of the above group (i) and this compound:
2,3,6-TBA (2,3,6-trichlorobenzoic acid) + SX, 2,3,6-TBA-dimethylammonium + SX, 2,3,6-TBA Lithium salt (2,3,6-TBA-lithium) + SX, 2,3,6-TBA potassium salt (2,3,6-TBA-potassium) + SX, 2,3,6-TBA sodium salt (2 , 3,6-TBA-sodium) + SX, 2,4-D + SX, 2,4-D choline salt (2,4-D choline salt) + SX, 2,4-D BAPMA salt (2,4 -DN, N-bis (3-aminopropyl) methylamine salt) + SX, 2,4-D 2-butoxypropyl + SX, 2,4-D 2-ethylhexyl (2 , 4-D-2-ethylhexyl) + SX, 2,4-D 3-butoxypropyl + SX, 2,4-D ammonium (2,4-D-ammonium) + SX, 2,4-D butotyl (2,4-D-butotyl) + SX, 2,4-D butyl (2,4-D-butyl) + SX, 2,4-D diethylammonium (2,4 -D-diethylammonium) + SX, 2,4-D dimethylammonium (2,4-D-dimethylammonium) + SX, 2,4-D diolamine salt (2,4-D-diolamine) + SX, 2,4 -D-decylammonium + SX, 2,4-D-ethyl + SX, 2,4-D hep Ruammonium (2,4-D-heptylammonium) + SX, 2,4-D Isobutyl (2,4-D-isobutyl) + SX, 2,4-D isooctyl (2,4-D-isooctyl) + SX, 2,4-D isopropyl (2,4-D-isopropyl) + SX, 2,4-D isopropylammonium (2,4-D-isopropylammonium) + SX, 2,4-D lithium salt (2,4-D -lithium) + SX, 2,4-D meptyl (2,4-D-mepty) + SX, 2,4-D methyl (2,4-D-methyl) + SX, 2,4-D octyl (2 , 4-D-octyl) + SX, 2,4-D pentyl (2,4-D-pentyl) + SX, 2,4-D propyl (2,4-D-propyl) + SX, 2,4- D sodium salt (2,4-D-sodium) + SX, 2,4-D tefryl (2,4-D-tefuryl) + SX, 2,4-D tetradecylammonium (2,4-D-tetradecylammonium) + SX, 2,4-D triethylammonium (2,4-D-triethylammonium) SX, 2,4-D tris (2-hydroxypropyl) ammonium + SX, 2,4-D trolamine salt (2,4-D-trolamine) + SX, 2,4-DB + SX, 2,4-DB choline salt (SX), SX, 2 , 4-DB BAPMA salt (2,4-DB N, N-bis (3-aminopropyl) methylamine salt) + SX, 2,4-DB butyl (2,4-DB-butyl) + SX, 2,4-DB dimethylammonium (2,4-DB-dimethylammonium) + SX, 2,4-DB isooctyl (2,4- DB-isoctyl) + SX, 2,4-DB potassium salt (2,4-DB-potassium) + SX, 2,4-DB sodium salt (2,4-DB-sodium) + SX, acetochlor + SX, acifluorfen + SX, acifluorfen-sodium + SX, aclonifen + SX, ACN (2-amino-3-chloronaphthalene-1,4-dione) + SX , Alachlor + SX, alloxydim + SX, ametryn + SX, amicarbazone + SX, amidosulfuron + SX, aminocyclopyrachlor + SX, amino Aminocyclopyrachlor-methyl + SX, Aminocyclopyrachlor-potassium + SX, Aminopyralid + SX, Aminopyralidocholine salt pyralid choline salt) + SX, aminopyralid-potassium + SX, aminopyralid-tris (2-hydroxypropyl) ammonium) + SX, amiprophos methyl -methyl) + SX, amitrole + SX, anilofos + SX, asuram + SX, atrazine + SX, azafenidin + SX, azimsulfuron + SX, befurbutamide (beflubutamid) + SX, benazolin-ethyl + SX, bencarbazone + SX, benfluralin + SX, benfuresate + SX, bensulfuron + SX, bensulfuron-methyl methyl) + SX, bensulide + SX, bentazon + SX, benthiocarb + SX, benzfendizone + SX, benzobicyc lon) + SX, benzofenap + SX, benzthiazuron + SX, bialafosbialaphos + SX, bicyclopyrone + SX, bifenox + SX, bispyribac + SX, Bispyribac-sodium + SX, bixlozone + SX, bromacil + SX, bromobutide + SX, bromofenoxim + SX, bromoxynil + SX, bromoxynil Octanoate + SX, butachlor + SX, butafenacil + SX, butamifos + SX, butroxydim + SX, butylate + SX, cafenstrole + SX, carbetamide + SX, carfentrazone + SX, carfentrazone-ethyl + SX, chlomethoxyfen + SX, Chloramben + SX, chloridazon + SX, chlorimuron + SX, chlorimuron-ethyl + SX, chlorobromuron + SX, chlorotoluron + SX, chloroxuron (chloroxuron) + SX, chlorpropham + SX, chlorsulfuron + SX, chlorthal-dimethyl + SX, chlorthiamid + SX, cinidon + SX, sinidone ethyl (cinidon-ethyl) + SX, cinmethylin + SX, cinosulfuron + SX, clethodim + SX, clodinahop + SX, clodinahop-propargyl + SX, clomazone ( clomazone) + SX, clomeprop + SX, clopyralid + SX, clopyralid choline salt + SX, clopyralid-methyl + SX, clopyralid-olamine + SX, clopyralid-potassium + SX, clopyralid-tris (2-hydroxypropyl) ammonium + SX, chloranthram ( cloransulam) + SX, cloransulam-methyl + SX, cumyluron + SX, cyanazine + SX, cycloate + SX, cyclopyranil + SX, cyclopyrimolate ( cyclopyrimorate) + SX, cyclosulfamuron + SX, cyclooxydim + SX, cyhalofop + SX, cyhalofop-butyl + SX, dalapon + SX, dazomet ( dazomet) + SX, desmedipham + SX, desmetryn + SX, di-allate + SX, dicamba + SX, dicamba choline salt + SX, dicamba BAPMA Salt (dicamba N, N-bis (3-aminopropyl) methylamine salt) + SX, dicamba-trolamine + SX, dicamba-diglycolamine + SX, dicamba dimethylammonium ( dicamba-dimethylammonium) + SX, dicamba-diolamine + SX, dicamba-isopropylammonium + SX, dicamba-methyl + SX, dicamba-olamine + SX, dicamba-potassium + SX, dicamba-sodium + SX, dichlobenil + SX, dichlorprop choline salt + SX, dichlorprop BAPMA salt (dichlorprop N, N-bis (3-aminopropyl) methylamine salt) + SX, dichlorprop-2-ethylhexyl + SX, dichlorprop-butotyl + SX, diclopropdimethylammonium Dichlorprop-dimethylammonium + SX, dichlorprop-ethylammonium + SX, dichlorprop-isoctyl + SX, dichlorprop-methyl + SX, dichlorprop-P P) + SX, dicloprop-P choline salt + SX, dicloprop-P BAPMA salt (dichlorprop-P N, N-bis (3-aminopropyl) methylamine salt) + SX, dicloprop-P 2- Ethylhexyl (dichlorprop-P-2-ethylhexyl) + SX, dichlorprop-P-dimethylammonium + SX, dichlorprop-potassium + SX, dichlorprop-sodium + SX, diclofop + SX, diclofop-methyl + SX, dicloslam + SX, difenoxuron + SX, difenzoquat + SX, diflufenica (diflufenican) + SX, diflufenzopyr + SX, diflufenzopyr-sodium + SX, dimefuron + SX, dimepiperate + SX, dimethachlor + SX , Dimethametryn + SX, dimethenamid + SX, dimethenamid-P + SX, dinitramine + SX, dinoseb + SX, dinoterb + SX, diphenamid (diphendamide) + SX, diquat-dibromide + SX, DSMA (disodium methylarsonate) + SX, dithiopyr + SX, diuron + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX , Esprocarb + SX, ethalluralin + SX, ethametsulfuron + SX, ethametsulfuron-methyl + SX, ethidimuron + SX, etofumesate + ethofumesate SX, Ethoxyfen-ethyl + SX, ethoxysulfuron + SX, etobenzanid + SX, fenoxaprop + SX, fenoxaprop-ethyl + SX, phenoxa Prop P (fenoxaprop-P) + SX, fenoxaprop-P-ethyl + SX, fenoxasulfone + SX, fenquinotrione + SX, fentrazamide + SX, Fenuron + SX, flamprop-M + SX, flazasulfuron + SX, florasulam + SX, florpyrauxifen + SX, florpyrauxifenbenzyl ( florpyrauxifen-benzyl) + SX, fluazifop-flux + SX, fluazifop-butyl + SX, fluazifop-P + SX, fluazifop-P-butyl + SX, Fluazolate + SX, flucarbazone + SX, flucarbazone-sodium + SX, flucetosulfuron + SX, flufenacet + SX, flufenpyr + SX, flufenpyr-ethyl + SX, flumetsulam + SX, flumetsulam + SX, flumiclorac + SX, flumiclorac-pentyl + SX, flumi Oxazine (flumioxazin) + SX, fluometuron + SX, fluoroglycofen-ethyl + SX, flupoxam + SX, flupropanate + SX, flupirsulfuron + SX , Flupirsulfuron-methyl-sodium + SX, flurenol + SX, fluridone + SX, flurochloridone ) + SX, fluroxypyr + SX, fluroxypyr-meptyl + SX, flurtamone + SX, fluthiacet + SX, fluthiaset methyl
-methyl) + SX, fomesafen + SX, fomesafen-sodium + SX, foramsulfuron + SX, fosamine + SX, glufosinate + SX, glufosinate ammonium Glufosinate-ammonium + SX, glufosinate-P + SX, glufosinate-P-ammonium + SX, glufosinate-P-sodium + SX, glyphosate SX + glyphosate choline salt + SX, glyphosate guanidine derivative salts + SX, glyphosate isopropylamine salt + SX, glyphosate BAPMA salt (glyphosate N, N-bis) (3-aminopropyl) methylamine salt) + SX, glyphosate-ammonium + SX, glyphosate-diammonium + SX, glyphos Potassium salt (glyphosate-potassium) + SX, glyphosate-sodium salt + SX, glyphosate-trimethylsulfonium + SX, halauxifen + SX, halauxifen-methyl ) + SX, halosafen + SX, halosulfuron + SX, halosulfuron-methyl + SX, halooxyfop + SX, halooxyfop-etotyl + SX, Haloxyfop-methyl + SX, Haloxyfop-P + SX, Haloxyfop-P-etotyl + SX, Haloxyfop-P-methyl + SX, Hexazinone ( hexazinone) + SX, imazamethabenz + SX, imazamethabenz-methyl + SX, imazamox + SX, imazamox-ammonium + SX, Imazapic + SX, imazapic-ammonium + SX, imazapyr + SX, imazapyr-isopropylammonium + SX, imazaquin + SX, imazapic Quinammonium salt (imazaquin-ammonium) + SX, imazethapyr + SX, imazethapyr-ammonium + SX, imazosulfuron + SX, indanofan + SX, indaziflam + indaziflam SX, iodosulfuron + SX, iodosulfuron-methyl-sodium + SX, iofensulfuron + SX, iofensulfuron-sodium + SX, ioxynil ) + SX, ioxynil-octanoate + SX, ipfencarbazone + SX, isoproturon + SX, Isouron + SX, isoxaben + SX, isoxachlortole + SX, isoxaflutole + SX, lactofen + SX, lenacil + SX, linuron ( linuron) + SX, maleic hydrazide + SX, MCPA choline salt + SX, MCPA BAPMA salt (MCPA N, N-bis (3-aminopropyl) methylamine salt) + SX, MCPA 2- Ethylhexyl (MCPA-2-ethylhexyl) + SX, MCPA-butotyl + SX, MCPA-butyl + SX, MCPA dimethylammonium + SX, MCPA diolamine salt (MCPA-diolamine) ) + SX, MCPA ethyl (MCPA-ethyl) + SX, MCPA-isobutyl + SX, MCPA isopropyl (MCPA-isopropyl) + SX, MCPA methyl (MCPA-methyl) ) + SX, MCPA allamine salt (MCPA-olamine) + SX, MCPA sodium salt (MCPA-sodium) + SX, MCPA-trolamine salt (MCPA-trolamine) + SX, M CPB (4- (4-chloro-2-methylphenoxy) butanoic acid) + SX, MCPB choline salt + SX, MCPB BAPMA salt (MCPB N, N-bis (3-aminopropyl) methylamine salt) + SX , MCPB-ethyl + SX, MCPB-methyl + SX, MCPB-sodium + SX, mecoprop choline salt + SX, mecoprop BAPMA salt (mecoprop N , N-bis (3-aminopropyl) methylamine salt) + SX, mecoprop-2-ethylhexyl + SX, mecoprop-dimethylammonium + SX, mecoprop-diolamine ) + SX, mecoprop-ethadyl + SX, mecoprop-isoctyl + SX, mecoprop-methyl + SX, mecoprop-potassium + SX , Mecoprop-sodium + SX, mecoprop-trolamine + SX, mecop P (mecoprop-P) + SX, mecoprop-P choline salt + SX, mecoprop-P-2-ethylhexyl + SX, mecoprop-P dimethylammonium (mecoprop-P -dimethylammonium) + SX, mecoprop-P-isobutyl + SX, mecoprop-P-potassium + SX, mefenacet + SX, mesosulfuron + SX, mesosulfuron methyl (mesosulfuron-methyl) + SX, mesotrione + SX, metam + SX, metamifop + SX, metamitron + SX, metazachlor + SX, metazosulfuron + SX , Methabenzthiazuron + SX, methiozolin + SX, methyldymron + SX, metobromuron + SX, metolachlor + SX, metosul am) + SX, metoxuron + SX, metribuzin + SX, metsulfuron + SX, metsulfuron-methyl + SX, molinate + SX, monolinuron + SX , Naproanilide + SX, napropamide + SX, napropamide-M + SX, naptalam + SX, neburon + SX, nicosulfuron + SX, norflurazon ) + SX, oleic acid + SX, orbencarb + SX, orthosulfamuron + SX, oryzalin + SX, oxadiargyl + SX, oxadiazon + SX , Oxasulfuron + SX, oxaziclomefone + SX, oxyfluorfen + SX, paraquat + SX, paraquat-dichloride + SX, Pebulate + SX, pelargonic acid + SX, pendimethalin + SX, penoxsulam + SX, pentanochlor + SX, pentoxazone + SX, petoxamide ( pethoxamid) + SX, phenisopham + SX, phenmedipham + SX, picloram, picolinafen + SX, picolinafen + SX, pinoxaden + SX , Piperophos + SX, pretilachlor + SX, primisulfuron + SX, primisulfuron-methyl + SX, prodiamine + SX, profluazol + SX, propoxydim + SX, prometon + SX, promethrin + SX, propachlor + SX, propanil + SX, propaxa hop (propa quizafop) + SX, propazine + SX, propham + SX, propisochlor + SX, propoxycarbazone + SX, propoxycarbazone-sodium + SX, Propyrisulfuron + SX, propyzamide + SX, prosulfocarb + SX, prosulfuron + SX, pyraclonil + SX, pyrasulfotole + SX, pyrazolynate ) + SX, pyrazosulfuron + SX, pyrazosulfuron-ethyl + SX, pyrrazoxyfen + SX, pyribenzoxim + SX, pyributicarb + SX, apyridolpy , Pyridate + SX, pyriftalide + SX, pyriminobac + SX, pyriminobac-methyl + SX, Pyrimisulfan + SX, pyrithiobac + SX, pyrithiobac-sodium + SX, pyroxasulfone + SX, pyroxsulam + SX, quinclorac + SX, quinmerac + SX, quizalofop-SX + SX, quizalofop-tefuryl + SX, quizalofop-P + SX, quizalofop-P-ethyl + SX, quizalofop-P-tefuryl + SX, rimsulfuron + SX, saflufenacil + SX, sethoxydim + SX , EPTC (S-ethyl N, N-dipropylcarbamothioate) + SX, siduron + SX, simazine + SX, simetryn + SX, S-metolachlor + SX, MSMA ( sodium hydrogen methylarsonate) + SX, sulcotrione (s ulcotrione) + SX, sulfentrazone + SX, sulfometuron + SX, sulfometuron-methyl + SX, sulfosulfuron + SX, swep + SX, TCA (2,2,2-trichloroacetic acid) + SX, tebutam + SX, tebuthiuron + SX, tefuryltrione + SX, tembotrione + SX, tepraloxydim + SX, terbacil + SX, terbumeton + SX, terbutryn + SX, terbutryn + SX, taxtomin A + SX, thenylchlor + SX, thiazopy ) + SX, thidiazimin + SX, thiencarbazone + SX, thiencarbazone-methyl + SX, thifensulfuron + SX, thifensulfuron-methyl + SX , Tiafenacil + SX, thiocarbazil + SX, tolpyralate + SX, topramezone + SX, tralkoxydim + SX, triafamone + SX, tri-allate + SX, triasulfuron + SX, triaziuram + SX, tribenuron + SX, tribenuron-methyl + SX, triclopyr + SX, triclopyrbutyl (SX) triclopyr-butotyl + SX, triclopyr-ethyl + SX, trilopyr-triethylammonium + SX, tridiphane + SX, trietazine + SX, trifloxysulfuron ) + SX, trifloxysulfuron-sodium + SX, trifludimoxazin + SX, trifluralin + SX, tri Triflusulfuron + SX, triflusulfuron-methyl + SX, tritosulfuron + SX, vernolate + SX, 2-[(2,4-dichlorophenyl) methyl]- 4,4-dimethyl-1,2-oxazolidin-3-one + SX, Ethyl [(3- {2-chlor
o-4-fluoro-5- [3-methyl-4- (trifluoromethyl) -2,6-dioxo-1,2,3,6-tetrahydropyrimidin-1-yl] phenoxy} pyridin-2-yl) oxy] acetate (353292-31-6) + SX.

Combination of this component of the above group (j) and this compound:
Abbreviata caucasica + SX, Aquaria spp. (Acuaria spp.) + SX, Agamermis decaudata + SX, Agrobacterium radiobacter K1026 (Agrobacterium radiobacter K1026) + SX, Agrobacterium・ Radobacter K84 strain (Agrobacterium radiobacter K84) + SX, Agrobacterium vitis VAR03-1 strain (Agrobacterium vitis VAR03-1) + SX, Allantonema spp. (Allantonema spp.) + SX, Alternaria destoluene 59 strain ( Alternaria destruens 59) + SX, Alternaria destruens + SX, Ampelomyces quisqualis AQ10 + SX, Amphimelmis spp. (Amphimermis spp.) + SX, Arsrobothris dactylides (SX) Arthrobotrys dactyloides) + SX, Arthrobotrys superba + SX, Aschersonia aleyrodes + SX, Pergillus flavus AF36 strain (Aspergillus flavus AF36) + SX, Aspergillus flavus NRRL21882 strain (Aspergillus flavus NRRL21882) + SX, Aureobasidium pullulans DSM14940 strain (Aureobasidium pullulans DSM14940) + SX, Aureobasidium puller 149 pullulans DSM14941) + SX, Azopirillum + SX, Azorhizobiuma caulinodans ZB-SK-5 + SX, Azotobacter chroococcum H23 (Azotobacter chroococcum H23) + SX Kum (Azotobacter chroocuccum) + SX, Azotobacter cyst + SX, Azotobacter vinelandii ATCC12837 (SX), SX, Azotobacter dar + acid Bacillus acidoterrestris + SX, Bacillus acidoterrestris Bacillus albolactis + SX, Bacillus alcalophilus + SX, Bacillus alvei + SX, Bacillus aminoglucosidicus + SX, Bacillus aminovorans + SX, Bacillus amyloliquefaciens AT332 (Bacillus amyloliquefaciens AT332) + SX, Bacillus amyloliquefaciens B3 + SX, Bacillus amyloliquefaciens D747 (Bacillus amyloliquefaciens D747) , Bacillus amyloliquefaciens DB101 + SX, Bacillus amyloliquefaciens DB102 + SX, Bacillus amyloliquefaciens FZB24 (Bacillus amyloliquefaciens FZB24) -Amiloliquefaciens FZB42 (Bacillus amyloliquefaciens FZB42) + SX, Bacil -Amiloliquefaciens GB03 (Bacillus amyloliquefaciens GB03) + SX, Bacillus amyloliquefaciens IN937a + SX, Bacillus amyloliquefaciens MBI600 (Bacillus amyloliquefaciens MBI600 + Bacillus amyloliquefaciens MBI600 + Bacillus amyloliquefaciens MBI600) Liquefaciens QST713 (Bacillus amyloliquefaciens QST713) + SX, Bacillus amyloliquefaciens isolate B246 (Bacillus amyloliquefaciens isolate B246) + SX, Bacillus amyloliquefaciens F727 (Bacillus amyloliquefaciens F727) + SX Amiloliquefaciens plantarum D747 strain (Bacillus amyloliquefaciens subsp. Plantarum D747) + SX, Bacillus amylolyticus + SX, Bacillus aneurinolyticus + SX, Bacillus agri ( Bacillus atro) + SX, Bacillus atrophaeus + SX, Bacillus・ Azotoformans + SX, Bacillus badius + SX, Bacillus cereus BP01 (Bacillus cereus BP01) + SX, Bacillus cereus CNCM 1-1562 (Bacillus cereus CNCM 1-1562) + SX, Bacillus chitinosporus AQ746 (Bacillus chitinosporus AQ746) + SX, Bacillus chitinosporus CM-1 (Bacillus chitinosporus CM-1) + SX, Bacillus circulans + SX, Bacillus coagulans TQ33 ( Bacillus coagulans TQ33) + SX, Bacillus fastidiosus + SX, Bacillus firmus GB-126 (Bacillus firmus GB-126) + SX, Bacillus firms I-1582 (Bacillus firmus I) -1582) + SX, Bacillus lacticola + SX, Bacillus lactimorbus + SX, Bacillus lactis + SX, Bacillus lautus + SX, Bacillus lacticus + SX Bacillus Lentimorbus + SX, Bacillus lentus + SX, Bacillus licheniformis HB-2 strain (Bacillus licheniformis HB-2) + SX, Bacillus licheniformis SB3086 strain (Bacillus licheniformis SB3086) + SX Bacillus maroccanus + SX, Bacillus medusa + SX, Bacillus megaterium YFM3.25 (Bacillus megaterium YFM3.25) + SX, Bacillus methylotrophicus BAC-9912 (Bacillus methylotrophicus BAC) -9912) + SX, Bacillus metiens + SX, Bacillus mojavensis SR11 + SX, Bacillus mycoides AQ726 + SX, Bacillus mycoides isolate J (Bacillus mycoides isopate J) + SX, Bacillus nematocida + SX, Bacillus nigrificans + SX, Bacillus digram (Bacillus nigrum) + SX, Bacillus popilliae + SX, Bacillus cyclosaccharolyticus + SX, Bacillus pumilus AQ717 strain (Bacillus pumilus AQ717) + SX, Bacillus pumilus BUF-33 Strains (Bacillus pumilus BUF-33) + SX, Bacillus pumilus GB34 (Bacillus pumilus GB34) + SX, Bacillus pumilus QST2808 (Bacillus pumilus QST2808) + SX, Bacillus siamensis + SX, Bacillus siamensis Simplex CGF2856 strain (Bacillus simplex CGF2856) + SX, Bacillus smithii + SX, Bacillus sp. AQ175 strain (Bacillus sp. AQ175) + SX, Bacillus sp. AQ177 strain (Bacillus sp. AQ177) + SX, Bacillus sp. AQ178 (Bacillus sp. AQ178) + SX, Bacillus sphaericus 2362 (Bacillus sphaericus 2362) + SX, Bacillus sphaericus ABTS1743 (Bacillus sphaericus ABTS1743) + SX, Bacillus sphaericus H5a5b lus sphaericus Serotype H5a5b) + SX, Bacillus subtilis AQ153 (Bacillus subtilis AQ153) + SX, Bacillus subtilis AQ743 (Bacillus subtilis AQ743) + SX, Bacillus subtilis D747 (Bacillus subtilis D747) + SX DB101 strain (Bacillus subtilis DB101) + SX, Bacillus subtilis FZB24 strain (Bacillus subtilis FZB24) + SX, Bacillus subtilis GB03 strain (Bacillus subtilis GB03) + SX, Bacillus subtilis HAI0404 strain (Bacillus subtilis HAI0404) + SX Subtilis IAB / BS03 (Bacillus subtilis IAB / BS03) + SX, Bacillus subtilis MBI600 (Bacillus subtilis MBI600) + SX, Bacillus subtilis QST30002 / AQ30002 (Bacillus subtilis QST30002 / AQ30002) + SX, Bacillus ST0004 / AQ30004 (Bacillus subtilis QST30004 / AQ30004) + SX, Bacillus subtilis QST713 (Bacillus subtilis QST713) + SX, Bacillus subtilis QST714 (Bacillus subtilis QST714) + S X, Bacillus subtilis var amylolique efaciens strain FZB24 (Bacillus subtilis var. Amyloliquefaciens FZB24) + SX, Bacillus subtilis strain Y1336 (Bacillus subtilis Y1336) + SX, Bacillus subtilis subsp. SX, Bacillus tequilensis NII-0943 (Bacillus tequilensis NII-0943) + SX, Bacillus thuringiensis AQ52 (Bacillus thuringiensis AQ52) + SX, Bacillus thuringiensis BD # 32 (Bacillus thuringiensis BD # 32) + SX , Bacillus thuringiensis CR-371 (Bacillus thuringiensis CR-371) + SX, Bacillus thuringiensis subsp. Aizawai ABTS-1857 + SX, Bacillus thuringiensis IZAWA Subspecies strain GC-91 (Bacillus thuringiensis subsp. Aizawai GC-91) + SX, Bacillus thuringiensis Aizawai subspecies Serotype H-7 (Bacillus thuringiensis subsp. Aizawai Serotype H-7) + SX, Bacillus thuringiensis subsp. Kurstaki ABTS351 (Bacillus thuringiensis subsp. Kurstaki ABTS351) + SX, Bacillus thuringiensis subsp. Kurstaki BMP123 + SX, Bacillus thuringiensis subsp. Kurstaki EG234 + SX, Bacillus thuringiensis subsp. Kurstaki EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki EG7841 Kristaki subspecies EVB113-19 strain (Bacillus thuringiensis subsp. Kurstaki EVB113-19) + SX, Bacillus thuringiensis subsp. Kurstaki F810 strain + SX, Bacillus thuringiensis subtilis subspecies HD -1 strain (Bacillus thuringiensis subsp. Kurstaki HD-1 strain) + SX, Bacillus thuringiensis・ Christaki subsp. Strain PB54 (Bacillus thuringiensis subsp. Kurstaki PB54) + SX, Bacillus thuringiensis subsp. Kurstaki SA-11 strain + SX, Bacillus thuringiensis subsp. Kurstaki subspecies SA-12 (Bacillus thuringiensis subsp. Kurstaki SA-12) + SX, Bacillus thuringiensis subsp. Morrisoni + SX, Bacillus thuringiensis tenebriosis subsp. NB176 (Bacillus thuringiensis subsp. Tenebriosis NB 176) + SX, Bacillus thuringiensis subsp. Thuringiensis subsp. Thuringiensis MPPL002 + SX, Bacillus thuringiensis subsp. Var. Colmeri + SX, Bacillus thuringiensis Thuringiensis Darmstadiensis variant 24-91 (Bacillus thuringiensis subsp.var.darmstadiensis 24-91) + SX, Bacillus thuringiensis subsp. Var.dendrolimus + SX, Bacillus thuringiensis subsp. Var. Galleriae + SX, Bacillus thuringiensis -Isla Elensis subsp. BMP144 strain (Bacillus thuringiensis subsp. Israelensis BMP144) + SX, Bacillus thuringiensis subsp. AM65-52 strain (Bacillus thuringiensis subsp. Israelensis AM65-52) + SX, Bacillus thuringiensis・ Japonensis variant buibui strain (Bacillus thuringiensis subsp. Var. Japonensis buibui) + SX, Bacillus thuringiensis subsp. Var.aegypti + SX, Bacillus thuringiensis 7216 var. + SX, Bacillus thuringiensis var. San diego M-7) + SX, Bacillus thuringiensis var.T36 + SX, Bacillus uniflagellate + SX, Bacillus uniflagellatus + SX, bacteria spp. bacteria spp.) + SX, bacteriophage of Clavibacter
michiganesis) + SX, Beauveria bassiana ANT-03 (Beauveria bassiana ANT-03) + SX, Beauveria bassiana ATCC74040 (Beauveria bassiana ATCC74040) + SX, Beauveria bassiana GHA (Beauveria bassiana GHA) + SX, Beauberia Vasiana PPRI 5339 (Beauveria bassiana PPRI 5339) + SX, Beauveria brongniartii + SX, Beddingia siridicola + SX, Bovienema spp. (Bovienema spp.) + SX, Brevibacil (Brevibacillus brevis 2904) + SX, Brevibacillus brevis SS86-3 (Brevibacillus brevis SS86-3) + SX, Brevibacillus brevis SS86-4 (Brevibacillus brevis SS86-4) + SX, Brevibacillus brevis SS86- 5 strains (Brevibacillus brevis SS86-5) + SX, Brevibacillus laterosporus ATCC64 (Brevibacillus laterosporus ATCC64) + SX, Brevibacillus laterosporus BPM3 (Brevibacillus laterospor) us BPM3) + SX, Brevibacillus laterosporus G4 (Brevibacillus laterosporus G4) + SX, Brevibacillus laterosporus NCIMB 41419 (Brevibacillus laterosporus NCIMB 41419) + SX, Brevibacillus laterosporus NRS11SX NRS1645 (Brevibacillus laterosporus NRS1645) + SX, Burkholderia cepacia type Wisconsin type J82 + SX, Burkholderia cepacia Wisconsin type M54 (Burkholderia cepacia type Wisconsin type Ms) Burkholderia cepacia + SX, Burkholderia gladii BA-7 + SX, Burkholderia rinojensis A396 + SX, Cameronia spp. Cameronia spp.) + SX, Canadian thistle fungus + S X, Candida oleophila O + SX, Candida saitoana + SX, Candida spp. + SX, Chaetomium cupreum + SX, Chitowoodiera・ Chitwoodiella ovofilamenta + SX, Chromobacterium subtsugae PRAA4-1T + SX, Cladosporium cladosporioides H39 + SX, Chronostachys・ Rosea (Clonostachys rosea) + SX, Conidiobolus obscurus (Conidiobolus obscurus) + SX, Coniothyrium minitans CGMCC8325 (Coniothyrium minitans CGMCC8325) + SX, Coniocilium minitans CON / M / 91-08 mini (Cons M / 91-08) + SX, Contortylenchus spp. + SX, Cryptococcus albidus + SX, Coricimermis spp. mermis spp.) + SX, Dactyllela ellipsospora + SX, Dectylaria thaumasia + SX, Delftia acidovorans RAY209 strain (Delftia acidovorans RAY209) + SX, dilopecuri ilo i Diplotriaena spp. + SX, Empidomermis spp. + SX, Entomophthora virulenta + SX, Erwinia carotobola subsp. ) + SX, Filipjevimermis leipsandra + SX, Fusarium oxysporum Fo47 + SX, Fusariumproliferatum + SX, Gastromermis spp. spp.) + SX, Gliocladium catenulatum J1446 + SX, gluconacetobacter diazotrophicus + SX, Gongylonema spp. + SX, Gynopoecilia pseudovipara + SX, Harpin protein + SX, hetero Heterorhabditis bacteriophora + SX, Heterorhabditis baujardi + SX, Heterorhabditis heliothidis + SX, Heterorhabditis indica, Heterorhabditis indica Heterorhabditis marelatus + SX, Heterorhabditis megidis + SX, Heterorhabditis zealandica + SX, Hexamermis spp. (Hexamermis spp.) + SX Hirsutella minnesotensis ) + SX, Hirsutella rsiliensis + SX, Hirsutella thompsonii + SX, Hydromermis spp. + SX, Isaria fumosorosea Mel + SX, Isaria fumosorosea spp. (Isomermis spp.) + SX, Lactobacillus acidophilus + SX, Lactobacillus brevis + SX, Lactobacillus plantarum + SX, Lactobacillus spp. (p.) + SX, Lagenidium giganteum + SX, Lecanicillium lecanii KV01 (Lecanicillium lecanii KV01) + Conidia (Lecanicillium lecanii conidia of strain DAOM198499) DA 1984 Conidia (Lecanicillium lecanii conidia of strain DAOM216596) + SX, Lecanicillium mass potassium Ve6 strain (Lec anicillium muscarium (formerly Verticillium lecanii) Ve6) + SX, Limomelmis spp. (Limnomermis spp.) + SX, Lysobacter antibioticus 13-1 (Lysobacter antibioticus 13-1) + SX, Rhizobacter enzymogenes C3 ( Lysobacter enzymogenes C3) + SX, Maupasina weissi + SX, Mermis nigrescens + SX, Mesomermis spp. + SX, Metarhizium anisopliae var.acridum variant (Metarhizium anisopliae var. Anisopliae var. Anisopliae BIPESCO 5 / F52) ) + SX, Metschnikowia dimerum + SX, Metnicovia Fructicola NRRLY-30752 (Metschn) ikowia fructicola NRRLY-30752) + SX, Microsphaeropsis ochracea + SX, Monacrosporium phymatopagum + SX, Mucor hiemalis + SX, Muskodor (SXbus 620) Muscodor albus 620) + SX, Muscodor albus QST 20799 (Muscodor albus QST 20799) + SX, Muscodor albus SA13 (Muscodor albus SA13) + SX, Muscodor roseus A3-5 (Muscodor roseus A3-5) + SX, Myrothecium verrucaria AARC-0255 + SX, Neomesomermis spp. + SX, Neoparasitylenchus rugulosi + SX, Nomura Air Lily CG128 rileyi CG128) + SX, Nomura Air Lily GU87401 (Nomuraea rileyi GU87401) + SX, Nomura Air Lily SA86101 (Nomuraea rileyi SA86101) + SX, Nomura Air Lily SR86151 (Nom) uraea rileyi SR86151) + SX, Nomura Air Lily VA9101 (Nomuraea rileyi VA9101) + SX, Nosema locustae + SX, Octomiomermis spp. Ophiostoma piliferum D97) + SX, Pekirmyces fumosoroseus Apopka 97 (now known as Isaria fumosorosea Apopka 97) (Paecilomyces fumosoroseus Apopka 97, now Isaria fumosorosea Apopka 97) + SX, Pekyromesus 251 Paecilomyces lilacinus 251) + SX, Pekylomyces tenuipes T1 (Paecilomyces tenuipes T1) + SX, Pekylomyces variotii Q-09 (Paecilomyces variotii Q-09) + SX, Paenibacillus alvey 2771 (Paenibacillus alSX) , Paenibacillus alvei 46C3 + SX, Paenibacillus alvei III2E + SX, Paenibacillus alvei 46C3 Rus Alvey III3DT-1A (Paenibacillus alvei III3DT-1A) + SX, Paenibacillus alvei T36 + SX, Paenibacillus macerans + SX, Paenibacillus polycila AC1 (AC-1) + SX, Paenibacillus polymyxa BS-0105 (Paenibacillus polymyxa BS-0105) + SX, Paenibacillus popilliae + SX, Pandora delphacis + SX, Pantoea agglomerans E325 ( Pantoea agglomerans E325) + SX, Pantoea vagans C9-1 (Pantoea vagans C9-1) + SX, Paracytaferenchus spp. (Parasitaphelenchus spp.) + SX, Parasitetorhabditis spp. (Parasitorhabditis spp.) + SX, Parasitylenchus spp. (Parasitylenchus spp.) + SX, Pasturia nishizawae Pn1 + SX, Pasturia penetran (Pasteuria penetran) s) + SX, Pasteuria ramose + SX, Pasturia usgae + SX, Pectobacterium carotovorum + SX, Penicillium biryii ATCC22348 (Penicillium bilaii ATSX22348 + ATCC22348) Penicillium citrinum VFI-51 (Penicillium citrinum VFI-51) + SX, Penicillium vermiculatum + SX, Perutilimermis culicis + SX, Pasturia thoynei + SX, Phasmarhabditis hermaphrodita + SX, Ferrebiopsis gigantea VRA1992 strain (phlebiopsis gigantea VRA1992) + SX, Physaloptera spp. (Physaloptera spp.) + SX, Phytopasora ) + SX, Pichia anomala WRL-076 (Pichia anomala WRL-076) + SX, Pichia guilermonde Z1 (pichi a guilliermondii Z1) + SX, Pichia guilliermondii Z8 + SX, Pochonia chlamydosporia isolate PC10 + SX, Pochonia chlamydosporia + SX, Pochonia chlamydosporia + SX, Pochonia chlamydosporia Protrellatus spp.) + SX, Pseudomonas aeruginosa PN1 (Pseudomonas aeruginosa PN1) + SX, Pseudomonas aeruginosa WS-1 (SX) + SX, Pseudomonas aureofaciens TX-1 (Pseudomonas aureofacienien) TX-1) + SX, Pseudomonas cepacia type Wisconsin J82 (Pseudomonas cepacia type Wisconsin M82) + SX, Pseudomonas chlorolafis 63-28 (Pseudomonas cepacia type Wisconsin M54) Pseudomonas chlororaphis 63-28) + SX, Pseudomonas chlororaphis MA342 + SX, Pseudomonas fu Luorescens 1629RS (pseudomonas fluorescens 1629RS) + SX, Pseudomonas fluorescens A506 (pseudomonas fluorescens A506) + SX, Pseudomonas fluorescens CL145A (pseudomonas fluorescens CL145A) + SX, Pseudomonas fluorescens fluorescens fluorescens fluorescens fluorescens fluorescens ) + SX, Pseudomonas fluoresce
Biover B XJ3 (Pseudomonas fluorescens biover B XJ3) + SX, Pseudomonas fluorescens biover B XS18 (Pseudomonas fluorescens biover B XS18) + SX, Pseudomonas fluorescens bioover A LRS12 (Pseudomonas fluorescens bios B) , Pseudomonas proradix + SX, Pseudomonas putida + SX, Pseudomonas reactans + SX, Pseudomonas resinovorans + SX, Pudomonas 804 rhodesiae HAI-0804) + SX, Pseudomonas sp. CAB-02 (Pseudomonas sp. CAB-02) + SX, Pseudomonas syringae 742RS (Pseudomonas syringae 742RS) + SX, Pseudomonas syringae MA-4 (Pseudomonas syringae MA) -4) + SX, Pseudozyma flocculosa PF-A22UL + SX, Ptereigo derma Titus spp. (Pterygodermatites spp.) + SX, Puccinia thelaspeos woad strain (puccinia thlaspeos woad) + SX, Purpureocillium lilacinum + SX, Pythium oligandrum DV74 strain (Pythium oligandrum DV74) , Pythium oligandrum M1 + SX, Rhodococcus globerulus AQ719 + SX, Romanomermis spp. + SX, Saccharomyces cerevisiae LASOe SX, Screotinia minor IMI34414 (sclerotinia minor IMI34414) + SX, Serratia entomophila + SX, Serratia marcescens 35 (Serratia marcescens 35) + SX, Serratia marcescens SRM (Serratia marcescens SRM) SX, Seuratum cadarachense + SX, Sinorhizobium meliloti + SX, Sfae Rurariopsis spp. (Sphaerulariopsis spp.) + SX, Spirura guianensis + SX, Sporothrix insectorum + SX, Steinernema bibionis + SX, Steinerma SX, Steinernema feltiae + SX, Steinernema glaseri + SX, Steinernema kraussei + SX, Steinernema riobrave (Steinernema riobrave) + SX, Steinernema riobrave SX, Steinernema scarabaei + SX, Steinernema siamkayai + SX, Steinernema spp. + SX, Strelkovimermis peters Reed DISKABIES RL-110T strain (Streptomyces acidiscabies RL-110T) + SX, Streptomyces candidus Y21007-2 (Streptomyces candidus Y21007-2) + SX, Streptomyces colombiensis + SX, Streptomyces・ Galbus QST6047 (Streptomyces galbus QST6047) + SX, Streptomyces goshikiensis + SX, Streptomyces griseoviridis K61 (Streptomyces griseoviridis K61) + SX, Streptomyces lavence lavesle SX, Streptomyces lydicus WYCD108US (Streptomyces lydicus WYCD108US) + SX, Streptomyces lydicus WYEC108 strain (Streptomyces lydicus WYEC108) + SX, Streptomyces prasinus + SX, Streptomyces lyscus Streptomyces rimosus) + SX, Streptomyces salaceticus (Streptomyces sa raceticus) + SX, Streptomyces sp. NRRL No. B-30145 (Streptomyces sp. NRRL No. B-30145) + SX, Streptomyces sp. WYE20 (Streptomyces sp. WYE20) + SX, Streptomyces sp. WYE 324 strain (Streptomyces sp. WYE 324) + SX, Streptomyces venezuelae + SX, Subaru spp. (Subulura spp.) + SX, Sulphuretylenchus elongatus + SX, Talaromyces flavus SAY-Y-94-01 (Talaromyces flavus SAY-Y-94-01) + SX, Talaromyces flavus V117b (Talaromyces flavus V117b) + SX, Tetrameres spp. (Tetrameres spp.) + SX , Thelohania solenopsis + SX, Thiobacillus spp. (Trichoderma aspe rellum ICC012) + SX, Trichoderma asperellum T25 + SX, Trichoderma asperellum T34 + SX, Trichoderma asperellum SKT-1 (Trichoderma asperellum SKT-1 + Trichoderma asperellum SKT-1)・ Aspererum TV1 strain (Trichoderma aperviride TV1) + SX, Trichoderma atroviride CNCM 1-1237 (Trichoderma atroviride LC52) + SX, Trichoderma atroviride LC52 206 IMI 206 (Trichoderma atroviride IMI 206040) + SX, Trichoderma atroviride SC1 + SX, Trichoderma atroviride SKT-1 (Trichoderma atroviride SKT-1) + SX, Trichoderma atroviride T11 + vi T11 SX, Trichoderma gamsii ICC080 (Trichoderma gamsii ICC080) + SX, Trichoderma harzianum 21 (Trichoderma harzian) um 21) + SX, Trichoderma harzianum DB 104 (Trichoderma harzianum DB 104) + SX, Trichoderma harzianum DSM 14944 (Trichoderma harzianum DSM 14944) + SX, Trichoderma harzianum ESALQ-1303 (Trichoderma harzianum ESALQ-1303) + SX, Trichoderma harzianum ESALQ-1306 (Trichoderma harzianum ESALQ-1306) + SX, Trichoderma harzianum IIHR-Th-2 (Trichoderma harzianum IIHR-Th-2) + SX, Trichoderma harzianum ITEM908 (Trichoderma harzianum ITRI908) SX, Trichoderma harzianum kd + SX, Trichoderma harzianum MO1 + SX, Trichoderma harzianum SF + Trichoderma harzianum SF + SX, Trichoderma har 22 harzianum T22) + SX, Trichoderma harzianum T39 (Trichoderma harzianum T39) + SX, Trichoderma harzianum T78 (Trichoderm a harzianum T78) + SX, Trichoderma harzianum TH35 + SX, Trichoderma harzianum rifai T39 + SX, Trichoderma koningder ligno (Trichoderma koningder) + SX, Trichoderma koningder SX + Trichoderma polysporum IMI206039 (Trichoderma polysporum IMI206039) + SX, Trichoderma stromaticum + SX, Trichoderma virens G-41 (G-41) 41) + SX, Trichoderma virens GL-21 (Trichoderma virens GL-21formaly Gliocladium virens GL-21) + SX, Trichoderma viride + SX, Tsukamurella paurometabola + SX Facoliza 94671 (Typhula phacorrhiza 94671) + SX, urocradium oudemansiii HRU3 (Ulocladium oudemansii HRU 3) + SX, Bailimorpha spp.Q-09 (Vairimorpha spp Q-09) + SX, Varioborax paradoxus GF4526 + SX, Verticillium alboatrum WCS850 (Verticillium alboatrum WCS850) + SX, Verticillium chlamydosporium + SX, Verticillium dahliae + SX, Verticillium lecani NCIM1312 (Verticillium lecani NCIM1312) + SX, Birgibacillus pantothenicus ATCC 14576 Virgibacillus pantothenticus ATCC14576) + SX, Birgibacillus pantothenticus DSM491 (Virgibacillus pantothenticus DSM491) + SX, Xanthomonas campestris pv poae + SX, Xanthomonas zestoss ) + SX, Xenorhabdus (Xenorhabdus) nematophila + SX, Zoophtora radicans + SX, Adoxophyes orana granulosis virus BV-0001 + SX, Agrotis segetum nuclear polyhedrosis virus (Agrotis segetum nuclear polyhedrosis) virus (NPV)) + SX, Anagraoha falcifera nuclear polyhedrosis virus (Anagraoha falcifera NPV) + SX, Anticarsia gemmatalis mNPV virus + SX, Autographa california nuclear polyhedrosis virus FV # 11 (Autographa californica mNPV FV # 11) + SX, Biston suppressaria nuclear polyhedrosis virus (Biston suppressaria NPV) + SX, Bombyx mori NPV polymorphism virus (Bombyx mori NPV) + SX, Cryptoflavia・ Cryptophlebia leucotreta GV + SX, Sidia pomonella granule disease virus V15 strain (Cydia pomonella GV V15) + SX, Sidia pomonella condyle Disease virus V22 strain (Cydia pomonella GV V22) + SX, Dendrolimus punctatus cypovirus + SX, Helicoberpa algera nuclear polyhedrosis virus BV-0003 (Helicoverpa armigera NPV BV-0003) + SX, Helicoverpa zea NPV) + SX, Leucoma salicis NPV + SX, Lymantria dispar NPV + SX, Mamestra・ Brass frog nuclear polyhedrosis virus (Mamestra brassicae NPV) + SX, Mamestra configurata nuclear polyhedrosis virus (Mamestra configurata NPV) + SX, Neodiprion abietis nuclear polyhedrosis virus (Neodiprion abietis NPV)) + SX , Neodiprion lecontei NPV) + SX, Neodiprion cellifer nuclear polyhedrosis Irs (Neodiprion sertifer NPV) + SX, Orgyia pseudotsugata NPV + SX, pepino mosaic virus CH2 isolate 1906 isolate + SX, Putrimaea opelcurella Granule disease virus (Phthorimaea operculella GV)) + SX, Pieris rapae GV) + SX, Prosia interpunctella granule virus (Plodia interpunctella GV) + SX, Plutella xylostella granule disease virus ( (Plutella xylostella GV)) + SX, Ppodella xylostella GV + SX, Spodoptera albula mNPV)) + SX, Spodoptera exempta mNPV) ) + SX, Spodoptera exigua mNPV BV-0004 + SX, Spodoptera frugiperta nucleus Spodoptera frugiperda mNPV + SX, Spodoptera littoralis mNPV + SX, Spodoptera litura NPV + SX, Tobacco mild green Tobacco mild tobamovirus U2 + SX, Zucchini Yellow Mosaik Virus weak strain + SX, Acaulospora spp. + SX,
Ambispora spp. + SX, Archaeospora spp. + SX, Claroideoglomus spp., Formerly Glomus spp. + SX, Claroideoglomus etunicatum Previously Glomus etunicatum) + SX, Claroideoglomus claroideum, formerly Glomus claroideum + SX, Diversispora spp. + SX, Entrophospora spp. + SX , Fanelliformis spp., Formerly Glomus spp. + SX, Faneliformis mosseae, formerly Glomus mosseae + SX, Geosiphon spp. + SX , Gigaspora spp. + SX, Gigaspora margarita + SX, Gigaspora rosea + SX, Glomus spp. + SX, Glomus aggregatum Glomus aggregatum) + SX, Glomus deserticola + SX, Glomus monosporum + SX, Pacispora spp. + SX, Paraglomus spp. + SX, Paraglomus spp. Brasilianum (formerly Glomus brasillianum) + SX, Racocetra spp. + SX, Rhizophagus spp., Formerly Glomus spp. + SX, Rhizophagus clarus, former Is Glomus clarum) + SX, Rhizophagus intraradices (formerly Glomus intraradices) + SX, Rhizophagus intraradisis RTI-801 strain + SX Rhizophagus irregularis (formerly Glomus intraradices, strain: DAOM 197198) + SX, Rhizophagus irregularis strain DAOM 197198 + SX, Scuterospora species (Scut ellospora spp.) + SX, Azorhizobium spp. + SX, Azorhizobium caulinodans + SX, Azospirillum amazonense + SX, Azospirillum spirsil -Brasilens XOH strain (Azospirillum brasilense strain XOH) + SX, Azospirillum brasilense strain Ab-V5 (Azospirillum brasilense strain Ab-V5) + SX, Azospirillum brasilense strain Ab-V6 (Azospirillum brasilense strain Ab-V6) + SX, Azospirillum caulinodans + SX, Azospirillum halopraeferens + SX, Azospirillum irakense + SX, Azospirillum lipoferum (Azospirillum lipoulinum) (Bradyrhizobium spp.) + SX, Bradyrizobium elkani (B radyrhizobium elkanii) + SX, Bradyrizobium elkanii strain SEMIA 587 (Bradyrhizobium elkanii strain SEMIA 587) + SX, Bradyrizobium elkanii strain SEMIA 5019 (Bradyrhizobium elkanii strain SEMIA 5019) + SX, Bradyzobium (Bradyrhizobium japonicum) + SX, Bradyrizobium japonicum strain TA-11 + SX, Bradyrizobium japonicum strain USDA 110 (Bradyrhizobium japonicum strain USDA 110) + SX, Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Bradyrhizobium sp. (Arachis) + SX, Bradyrizobium Genus (Bradyrhizobium sp. (Vigna)) + SX, Delftia acidovorans + SX, Delftia acidovorans RAY209 strain (Delftia acidovorans st rain RAY209) + SX, Metylobacterium spp. + SX, Mesorhizobium ciceri + SX, Mesorhizobium huakii + SX, Mesorhizobium rochi (SX) Mesorhizobium spp. + SX, Rhizobium etli + SX, Rhizobium galegae + SX, Rhizobium leguminosarum bv, Rhizobium leguminosarum bv, Rhizobium leguminosarum bv Rhizobium leguminosarum bv.Trifolii + SX, Rhizobium leguminosarum bv. Viciae + SX, Rhizobium trifolii + SX, Rhizobium Freddy (Sinorhizobium fredii) + SX, Sinorhizobium meliloti + SX.

  The mixing ratio of the present compound and this component is not particularly limited, but is 1000: 1 to 1: 1000, 500: 1 to 1: 500, 100: 1 to 1 by weight ratio (this compound: this component). 1: 100, 50: 1, 20: 1, 10: 1, 9: 1, 8: 1, 7: 1, 6: 1, 5: 1, 4: 1, 3: 1, 2: 1, 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8, 1: 9, 1:10, 1:20, 1:50, and the like.

  This compound can be used in combination with or in combination with chemical fertilizers (such as ammonium sulfate, phosphorous acid, ammonium nitrate, urea, ammonium chloride).

  The harmful arthropod control composition of the present invention contains the present compound or composition A and an inert carrier (hereinafter referred to as the present composition). In the composition of the present invention, the present compound or the composition A is usually mixed with an inert carrier such as a solid carrier, a liquid carrier, a gaseous carrier, etc., and a surfactant and other formulation adjuvants are added as necessary. Emulsions, oils, powders, granules, wettable powders, flowables, microcapsules, aerosols, smokers, poisonous baits, resin formulations, shampoos, pastes, foams, carbon dioxide formulations, It is formulated into tablets. These preparations may be used after being processed into mosquito coils, electric mosquito mats, liquid mosquito traps, fumigants, fumigants, sheet preparations, spot-on agents, or oral treatments. The composition of the present invention usually contains 0.0001 to 95% by weight of the present compound or composition A.

  Examples of the solid carrier include clays (kaolin clay, diatomaceous earth, bentonite, acid clay), dry silica, wet silica, talc, ceramic, and other inorganic minerals (sericite, quartz, sulfur, activated carbon, calcium carbonate, etc.), Fine powder and granular materials such as chemical fertilizers (ammonium sulfate, phosphorous acid, ammonium nitrate, urea, ammonium chloride, etc.), and synthetic resins (polyester resins such as polypropylene, polyacrylonitrile, polymethyl methacrylate, polyethylene terephthalate, nylon-6, And nylon resins such as nylon-11 and nylon-66, polyamide resins, polyvinyl chloride, polyvinylidene chloride, and vinyl chloride-propylene copolymers).

  Examples of the liquid carrier include water, alcohols (methanol, ethanol, isopropyl alcohol, butanol, hexanol, benzyl alcohol, ethylene glycol, propylene glycol, phenoxyethanol, etc.), ketones (acetone, methyl ethyl ketone, cyclohexanone, etc.), aromatic hydrocarbons (Toluene, xylene, ethylbenzene, dodecylbenzene, phenylxylylethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, kerosene, light oil, etc.), esters (ethyl acetate, butyl acetate, isopropyl myristate, Ethyl oleate, diisopropyl adipglycerate, diisobutyl adipate, propylene glycol monomethyl ether acetate, etc.), nitriles (acetonitrile, Sobutyronitrile, etc.), ethers (diisopropyl ether, 1,4-dioxane, 1,2-dimethoxyethane, diethylene glycol dimethyl ether, diethylene glycol monomethyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, 3-methoxy-3-methyl-1 -Butanol etc.), amides (DMF, dimethylacetamide etc.), sulfoxides (DMSO etc.), propylene carbonate and vegetable oils (soybean oil, cottonseed oil etc.).

  Examples of the gaseous carrier include fluorocarbon, butane gas, LPG (liquefied petroleum gas), dimethyl ether, and carbon dioxide gas.

  Examples of the surfactant include nonionic surfactants such as polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, and polyethylene glycol fatty acid ester, and anions such as alkyl sulfonate, alkyl benzene sulfonate, and alkyl sulfate. Surfactant is mentioned.

  Other formulation adjuvants include sticking agents, dispersants, colorants, antifreezes and stabilizers, such as casein, gelatin, sugars (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin Derivatives, bentonites, synthetic water-soluble polymers (polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylic acids, etc.), acidic isopropyl phosphate, 2,6-di-tert-butyl-4-methylphenol, BHA (2-tert-butyl- 4-methoxyphenol and a mixture of 3-tert-butyl-4-methoxyphenol).

Examples of the base material of the resin preparation include vinyl chloride polymers, polyurethanes, etc., and these base materials include phthalic acid esters (dimethyl phthalate, dioctyl phthalate, etc.) and adipic acid esters as necessary. Further, a plasticizer such as stearic acid may be added. The resin formulation is obtained by kneading the present compound in the base material using a normal kneading apparatus, and then molding by injection molding, extrusion molding, press molding, etc., and if necessary, further undergoes molding, cutting, etc. , Plate-like, film-like, tape-like, net-like, or string-like resin preparations. These resin preparations are processed, for example, as animal collars, animal ear tags, sheet preparations, attracting strings, or gardening supports.
Examples of the bait base include cereal flour, vegetable oil, sugar, crystalline cellulose and the like, and if necessary, antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid, and preservatives such as dehydroacetic acid. Additives for preventing accidental eating by children and pets such as pepper powder, cheese flavoring, onion flavoring, and pest-attracting flavoring such as peanut oil are added.

  Moreover, you may add a coloring agent to a formulation. Examples of the colorant include a red pigment, a blue pigment, a green pigment, and a yellow pigment. Specific examples include monazole red, cyanine green, Prussian blue, and brilliant blue.

  The method for controlling harmful arthropods according to the present invention comprises an effective amount of the present compound or the composition of the present invention directly on harmful arthropods and / or habitats of harmful arthropods (plants, plant cultivation carriers, households). , Etc., by applying to animal bodies. The habitat mentioned here includes not only the place where harmful arthropods live, but also the place where they are expected to live. The harmful arthropod control method of the present invention is usually used in the form of the composition of the present invention.

  The plant cultivation carrier is a plant support and may be any material on which the plant can grow. Examples thereof include soil, a seedling mat, and water. Specific materials for the soil and nursery mat include, for example, sand, pumice, vermiculite, diatomaceous earth, gel material, polymer material, rock wool, glass wool, wood chip, and bark.

  In the control method of the present invention, the treatment amount of the composition of the present invention is the type of plant to be treated, the type and frequency of harmful arthropods to be controlled, formulation form, treatment time, treatment method, treatment place, weather conditions, etc. For example, the following may be mentioned.

  When the composition of the present invention is used for the control of harmful arthropods in the agricultural field, the application amount is the type of plant to be applied, the type and frequency of occurrence of pests to be controlled, the form of preparation, the application period, the application method, the application Although it can vary widely depending on the location, weather conditions, etc., it is usually 1 to 10000 g per ha at the application rate of this compound, and usually 1 to 10,000 g per ha at any one application rate of this component. When the composition of the present invention is formulated into an emulsion, wettable powder, flowable agent, etc., it is usually added with water so that the active ingredient concentration of any one of the present compound and this component is 0.01 to 10,000 ppm. Diluted and applied, and granules, powders, etc. are usually applied as they are.

  These preparations and water dilutions of these preparations may be sprayed directly on harmful arthropods or plants such as crops to be protected from harmful arthropods, and harmful arthropods that inhabit the soil of cultivated land. You may treat to this soil in order to control.

  Moreover, it can also process by the method of wrapping the resin formulation processed into the sheet form or the string form around the crop, stretching over the crop vicinity, and laying on the stock soil.

  When the composition of the present invention is used for controlling harmful arthropods that live in the house, the amount applied is the amount of the compound per 1 m 2 of the treated area when treated on the surface, usually 0.01 to 1000 mg. Yes, when processing in a space, the amount of the present compound per 1 m 3 of the processing space is usually 0.01 to 500 mg. When the composition of the present invention is formulated into an emulsion, wettable powder, flowable, etc., it is usually diluted with water so that the active ingredient concentration is 0.1 to 10,000 ppm, and applied to oil, aerosol, Apply smoke smoke, poison bait, etc. as they are.

  When the composition of the present invention is used for controlling ectoparasites of domestic animals such as cattle, horses, pigs, sheep, goats and chickens, and small animals such as dogs, cats, rats and mice, it is applied to animals by methods known in veterinary medicine. Can be used. As a specific method of use, for the purpose of systemic suppression, for example, administration by tablet, feed mixing, suppository, injection (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.) is intended for non-systemic suppression. In this case, for example, an oil agent or an aqueous liquid is sprayed, a pour-on treatment or a spot-on treatment is performed, the animal is washed with a shampoo preparation, or a resin preparation is attached to the animal with a collar or ear tag. The amount of the present compound when administered to an animal body is usually in the range of 0.1 to 1000 mg per 1 kg body weight of the animal.

  In the present invention, the plant includes the whole plant and a specific part of the plant. Specific parts of plants include, for example, foliage, flowers, ears, fruits, trunks, branches, canopies, seeds, vegetative organs and seedlings.

  The vegetative reproductive organ means a plant root, stem, leaf or the like that has the ability to grow when the part is separated from the main body and placed in the soil. Examples of vegetative reproductive organs include tuberous root, creeping root, bulb, corm or solid bulb, tuber, rhizome, and stolon. , Rhizopholes, cane cuttings, propagules and vine cuttings. In addition, a toothpick is sometimes called a runner, and a basket is also called a pearl bud, and is divided into a granulation (broad bud) and a scale bud (bulbil). The vine means shoots (a general term for leaves and stems, shoot) such as sweet potatoes and yams. A bulb, a bulb, a tuber, a rhizome, a stem fragment, a root bearing body or a tuberous root is collectively called a bulb. For example, potato cultivation begins with planting tubers into soil, but the tubers used are commonly referred to as seed pods.

  Seedlings include seedlings and saplings.

  Examples of the treatment method of the composition of the present invention include foliage treatment, soil treatment, root treatment, shower treatment, smoke treatment, water surface treatment, and seed treatment.

Examples of the foliage treatment include a method in which the composition of the present invention is treated on the surfaces of foliage, tree trunks, fruits, flowers or ears.
Examples of the root treatment include a method of immersing the whole plant or the root in a chemical solution containing the composition of the present invention, and a method of attaching a solid preparation containing the composition of the present invention to the root of the plant.
Examples of soil treatment include soil spraying, soil mixing, and chemical irrigation into soil. In addition, examples of the place where soil treatment is performed include, for example, planting holes, rowing, near planting holes, near rowing, the entire cultivation area, plant land, inter-stock, under-trunk, main trunk, cultivation soil, nursery box, raising seedling. Examples include trays and nurseries. Examples of the treatment time include the sowing time before sowing, at the time of sowing, after sowing, the seedling raising period, before planting, at the time of planting, and after the planting. Moreover, in the said soil treatment, this invention composition may be processed to a plant simultaneously, and solid fertilizers, such as paste fertilizer containing this invention composition, may be applied to soil. Moreover, you may mix with an irrigation liquid, for example, the injection | pouring to irrigation equipments (irrigation tube, irrigation pipe, a sprinkler, etc.), the mixing to a streak water solution, mixing to a hydroponic liquid etc. are mentioned. In addition, the irrigation liquid and the active ingredient can be mixed in advance, and can be treated using an appropriate irrigation method such as the above irrigation method or other watering or watering.
As a root part process, the method of immersing the root part of a plant with the dilution liquid of this invention composition is mentioned, for example.
As a shower process, the method of showering the dilution liquid of this invention composition on the fruit after harvest is mentioned, for example.
The soot treatment includes, for example, a method in which the diluted solution of the composition of the present invention is made into a mist and scattered in the air and attached to the foliage and fruits of plants.
Such water surface treatment includes, for example, a method of spraying a chemical solution containing the composition of the present invention or a solid preparation containing the composition of the present invention onto a flooded paddy field.
Seed treatment includes, for example, treatment of the composition of the present invention to seeds or vegetative reproductive organs. Specifically, for example, the suspension of the composition of the present invention is atomized to form a seed surface or vegetative reproductive organ surface. Spraying treatment, smearing treatment in which the composition of the present invention is applied to seeds or vegetative organs, immersion treatment in which seeds are immersed in a chemical solution of the composition of the present invention for a certain period of time, seeds with a carrier containing the composition of the present invention Examples thereof include a method of coating a vegetative organ (for example, film coating treatment, pellet coating treatment, etc.). As the above-mentioned vegetative reproductive organs, seed pods are particularly mentioned.

  More specifically, the treatment method of the composition of the present invention includes planting treatment (planting hole spraying, planting hole treatment soil mixing), plant source processing (stock source spraying, strain source soil mixing, strain source irrigation, late seedling stage) Plant root treatment), grooving treatment (spreading grooving, mixing grooving soil), cropping treatment (spreading spraying, mixing of soil with soil, sprinkling with growing season), cropping treatment at sowing (spreading at the time of sowing) , Soil mixing at the time of sowing), whole surface treatment (spreading whole surface soil, whole surface soil mixing), side strip processing, water surface treatment (water surface application, water surface application after flooding), other soil spraying treatment (growth season foliar spray) , Under the crown or around the trunk, soil surface spray, soil surface mixing, sowing hole spray, buttocks land surface spray, inter-plant spray), other irrigation treatment (soil irrigation, seedling irrigation, chemical injection, local irrigation, Chemical solution drip irrigation, Chemigation), seedling box processing (nursing box spraying, seedling box irrigation, seedling box chemical solution Water), seedling tray treatment (nursing tray spraying, seedling tray irrigation, seedling tray irrigation, seedling tray submergence), seedling treatment (seedbed spraying, seedbed irrigation, water seedling seedling spraying, seedling soaking), bed soil mixing treatment (bed soil mixing, seeding) Pre-floor soil mixing, sowing before sowing, sowing after sowing, soaking, and other treatments (culture soil mixing, plowing, topsoil mixing, raindrop soil mixing, planting position treatment, granule inflorescence spraying, It may be called paste fertilizer admixture, hydroponic liquid admixture, hydroponic liquid mixture).

  When this compound is applied to seeds or vegetative reproductive organs, the application amount of this compound is usually 0.001 to 100 g, preferably 0.01 to 50, more preferably 0.1 per kg of seed or vegetative reproductive organs. -10 g. In addition, when this component is added to this compound and applied, the application amount per one component is usually 0.001 to 100 g, preferably 0.01 to 50, more preferably 1 kg per seed or vegetative organ. 0.1 to 10 g.

  The composition of the present invention can be used as a pest control agent for harmful arthropods in agricultural fields such as fields, paddy fields, orchards, and non-agricultural land such as lawns and forests.

Plants that can use the composition of the present invention include, for example, the following crops: corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugar cane, tobacco, Triticale, kidney bean, lentil, cowpea, mung bean, tunned bean, safflower bean, bamboo shoot, moss bean, tepary bean, broad bean, pea, chickpea, lentil, lupine, yellow bean, alfalfa, etc.
Vegetables: Solanum vegetables (eggplants, tomatoes, peppers, peppers, potatoes, bell peppers, etc.), cucumbers (cucumbers, pumpkins, zucchini, watermelons, melons, squash, etc.), cruciferous vegetables (radish, turnip, horseradish, Cole rabi, Chinese cabbage, cabbage, mustard, broccoli, cauliflower, etc.), Asteraceae vegetables (burdock, shungiku, artichoke, lettuce, etc.), lily family vegetables (leek, onion, garlic, asparagus), celery family vegetables (carrot, Parsley, celery, American scallop, etc.), red crustacean vegetables (spinach, chard, etc.), perilla vegetables (perilla, mint, basil, lavender, etc.), strawberry, sweet potato, yam, taro, etc., flower buds, houseplants,
Fruit trees; pears (apples, pears, Japanese pears, quince, quince, etc.), nuclear fruits (peaches, plums, nectarines, ume, sweet cherry, apricots, prunes, etc.), citrus (satsuma mandarin, orange, lemon, lime, grapefruit) ), Nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, banana, coffee, Date palm, coconut palm, etc.
Trees other than fruit trees: Cha, mulberry, flowering trees, street trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak, poplar, redwood, fu, sycamore, zelkova, black bean, peach tree, Tsuga, rat, pine, Spruce, yew), etc.
Shiva and pasture.

  The above-mentioned plant varieties are not particularly limited as long as they are generally cultivated varieties.

  The aforementioned plant may be a plant that can be produced by natural mating, a plant that can be generated by mutation, an F1 hybrid plant, or a transgenic plant (also referred to as a genetically modified plant). These plants generally have resistance to herbicides, accumulation of toxic substances against pests (also called pest resistance), suppression of susceptibility to diseases (also called disease resistance), increased yield potential, biological and abiotic It has properties such as improved resistance to stress factors, quality modification of products (for example, increase / decrease in content of components, change in composition, improvement in storage stability or processability).

  An F1 hybrid plant is a first-generation hybrid obtained by crossing two varieties of varieties, and is generally a plant having characteristics of hybrid strength having a trait superior to both of parents. Transgenic plants are introduced with foreign genes from other organisms such as microorganisms, and impart characteristics that cannot be easily obtained by cross breeding, mutagenesis, or natural recombination in the natural environment. Plant.

Examples of the technique for producing the above plant include conventional breeding techniques; gene recombination techniques; genome breeding techniques; new breeding techniques; genome editing techniques. The conventional breed improvement technique is a technique for obtaining a plant having desirable properties by mutation or crossing. Genetic recombination technology is a technology that gives a new property to an organism by removing the target gene (DNA) from a certain organism (for example, a microorganism) and introducing it into the genome of another target organism, or a plant. Antisense technology or RNA interference technology that confer new or improved properties by silencing other genes present. The genome breeding technique is a technique for improving the efficiency of breeding using genome information, and includes a DNA marker (also referred to as genome marker or gene marker) breeding technique and genomic selection. For example, DNA marker breeding is a method in which a progeny having a target useful trait gene is selected from a large number of mating progeny using a DNA marker, which is a DNA sequence that serves as a marker for the location of a specific useful trait gene on the genome is there. By analyzing the progeny of the mating plant using a DNA marker when it is a young plant, it has a feature that the time required for breeding can be effectively shortened.
Genomic selection is a technique that creates prediction formulas from previously obtained phenotypes and genome information, and predicts characteristics without evaluating phenotypes from prediction formulas and genome information, contributing to efficient breeding. It is possible technology. New breeding technology (new breeding technigues) is a general term for breeding (breeding) technology combining molecular biological techniques. For example, cisgenesis / intragenesis, oligonucleotide-directed mutagenesis, RNA-dependent DNA methylation, genome editing, grafting to GM rootstock or hogi, reverse breeding, agroinfiltration, seed production technology (Seed Production) Technology, SPT). The genome editing technique is a technique for converting genetic information in a sequence-specific manner, and can delete base sequences, replace amino acid sequences, introduce foreign genes, and the like. Examples of such tools include zinc finger nuclease (Zinc-Finger, ZFN), Talen (TALEN), Crisper Casnine (CRISPR / Cas9), and Crisper CP1 (CRISPER / Cpf1) that can sequence-specifically cleave DNA. And Meganuclease. In addition, there are sequence-specific genome modification techniques such as CAS9 nickase and Target-AID created by modifying the aforementioned tools.

  The above-mentioned plant is, for example, registered as a genetically modified crop in the electronic information site (http://www.isaaa.org/) of the INTERNATINAL SERVICE for the ACQUISITION of AGRI-BIOTECH APPLICATIONS, ISAAA. Plants listed in the database (GM APPROVAL DATABASE). More specifically, for example, herbicide-tolerant plants, pest-resistant plants, disease-resistant plants, product quality modification (for example, increase / decrease in content of components, change in composition, improvement in preservability or processability) And dwarf trait-modified plants, abiotic stress-tolerant plants, or plants with traits that are related to growth or yield.

Examples of plants given herbicide tolerance are listed below.
Mechanisms of resistance to herbicides, for example, reduce the affinity between herbicides and their targets; rapid metabolism of herbicides (such as degradation and modification) by the expression of enzymes that inactivate herbicides; Incorporation into plants; and inhibition of transfer of herbicides in plants.

Plants to which herbicide tolerance has been imparted by genetic recombination technology include, for example, protoporphyrinogen oxidase (hereinafter abbreviated as PPO) herbicides such as flumioxazin; 4-hydroxyphenylpyruvic acid such as isoxaflutol and mesotrione Dioxygenase (hereinafter abbreviated as HPPD) inhibitors; imidazolinone herbicides such as imazetapyr, acetolactate synthase (hereinafter abbreviated as ALS) inhibitors such as sulfonylurea herbicides such as thifensulfuronmethyl; glyphosate 5-enolpyruvylshikimate-3-phosphate synthase (hereinafter abbreviated as EPSPS) inhibitors; glutamine synthase inhibitors such as glufosinate; auxin-type herbicides such as 2,4-D and dicamba; There are plants with tolerance to oxynyl herbicides. Preferred herbicide-tolerant transgenic plants are grains such as wheat, barley, rye, oat, canola, sorghum, soybean, rice, rapeseed, sugar beet, sugar cane, grape, lentil, sunflower, alfalfa, pomegranate, nuclear fruit, Vegetables such as coffee, tea, strawberry, buckwheat, tomato, potato, cucumber, lettuce, more preferably grains such as wheat, barley, rye, oat, soybean, rice, vine, tomato, potato, pear is there.
The specific herbicide-tolerant plants are shown below.
Glyphosate herbicide-tolerant plants: Glyphosate-resistant EPSPS gene (CP4 epsps) derived from Agrobacterium tumefaciens strain CP4 and glyphosate N-acetyltransferase gene derived from Bacillus licheniformis by shuffling technology Glyphosate N-acetyltransferase gene with enhanced metabolic activity (gat4601 or gat4621), glyphosate oxidase gene (goxv247) from Ochrobacterum anthropi strain LBAA, or glyphosate resistance from maize (Zea mays) It can be obtained by introducing any one or more of EPSPS genes (mepsps or 2mepsps) having mutations. The main plants are, for example, alfalfa (Medicago sativa), Argentine canola (Brassica napus), cotton (Gossypium hirsutum L.), creeping bentgrass (Agrostis stolonifera), corn (Zea mays L.) polish canola (Brassica rapa), Examples include potato (Solanum tube HDDrosum L.), soybean (Glycine max L.), sugar beet (Beta vulgaris) and wheat (Triticum aestivum). Several glyphosate-tolerant plants are commercially available. For example, a genetically modified plant introduced with CP4 epsps is a trade name including “Roundup Ready (registered trademark)”, and a genetically modified plant introduced with gat4601 or gat4621 is “Optimum (registered trademark) GAT (trademark)”, “ Genetically modified plants into which mepsps or 2mepsps have been introduced are sold under the trade name "GlyTol (trademark)" under the trade name "Optimum (registered trademark) Gly canola". More specific glyphosate-tolerant plants include, for example, corn "Roundup Ready (trademark) Maize", "Roundup Ready (trademark) 2 Maize", "Agrisure (trademark) GT", "Agrisure (trademark) GT / CB / "LL", "Agrisure (TM) GT / RW", "Agrisure (TM) 3000GT", "YieldGard (TM) VT (TM) Rootworm (TM) RR2" and "YieldGard (TM) VT Triple"; Ready (TM) Soybean "and" Optimum GAT (TM) "; Cotton is" Roundup Ready (TM) Cotton "," Roundup Ready (TM) Flex Cotton "and" GlyTol (TM) "; Canola is" Roundup Ready (TM) " Canola "and" Optimum (R) Gly canola "; Alfalfa is" Roundup Ready (TM) Alfalfa "; Rice is" Roundup Ready Rice "; Sugarcane is" Roundup Ready (TM) sugarbeet "and" InVigor (TM) sugarbeet " Wheat (Triticum aestivum) under the trade name “Roundup Ready (trademark) wheat” It has been sold.
Glyphosate herbicide-tolerant plants: the gene for phosphinothricin N-acetyltransferase (PAT) from Streptomyces hygroscopicus (bar), Streptomyces bilidochrome One or more of PAT gene (pat) derived from Mogenes (Streptomyes viridochromogenes) or synthesized PAT gene (pat syn) derived from Streptomyces viridochromogenes Tu494 strain (Streptomyes viridochromogenes strain Tu494) It is obtained by introducing. Major plants include, for example, Argentine canola (Brassica napus), chicory (Cichorium intybus) cotton (Gossypium hirsutum L.), corn (Zea mays L.) polish canola (Brassica rapa), rice (Oryza sativa L.), soybean (Glycine max L.) and sugar beet (Beta vulgaris). Some glufosinate-tolerant plants are commercially available. For example, transgenic plants introduced with bar or pat are sold under trade names including “LibertyLink ™”, “InVigor ™”, or “WideStrike ™”. More specific glyphosate-tolerant plants include, for example, corn “Roundup Ready ™ 2”, “Liberty Link ™”, “Herculex ™ I”, “Herculex RW”, “Herculex XTRA ™”. , "Agrisure (trademark) GT / CB / LL", "Agrisure (trademark) CB / LL / RW" and "Bt10"; Cotton is "FiberMax (trademark) Liberty Link (trademark)"; Rice is "Liberty Link (trademark)" ) Rice ”; Canola is sold under the trade name“ inVigor ™ Canola ”; Soybean is sold under the trade name“ Liberty Link ™ Soybean ”;
Oxynyl herbicide (eg bromoxynil) resistant plant: obtained by introducing a nitrilase gene (bxn) derived from Klebsiella pneumoniae subsp. Ozaenae. Examples of main plants include Argentine canola (Brassica napus), cotton (Gossypium hirsutum L.), and tobacco (Nicotiana tabacum L.). Several oxynyl herbicide resistant plants are commercially available. For example, it is sold under the trade name including “Navigator (trademark)” or “BXN (trademark)”. More specific oxynyl herbicide-tolerant plants are sold, for example, under the brand name “BXN ™ Cotton” for cotton and “Navigator ™ Cotton” for Argentine canola.
ALS herbicide-tolerant plants: Carnation (Dianthus caryophyllus) introduced with ALS herbicide-tolerant ALS gene (surB) from tobacco (Nicotiana tabacum) as a selection marker, for example, "Moondust (trademark)", "Moonshadow (trademark)""," Moonshade (trademark) "," Moonlite (trademark) "," Moonaqua (trademark) "," Moonvista (trademark) "," Moonique (trademark) "," Moonpearl (trademark) "," Moonberry (trademark) " Or it is sold under the trade name "Moonvelvet (TM)". For example, flax (Linum usitatissumum L.) into which ALS herbicide-resistant ALS gene (als) derived from Arabidopsis thaliana has been introduced is sold under the trade name of “CDC Triffid Flax”. Maize (Zea mays L.) resistant to sulfonylurea and imidazolinone herbicides introduced with ALS herbicide-resistant ALS gene (zm-hra) derived from corn is, for example, “Optimum ™ GAT ™”. Are sold under the trade name " Soybean having resistance to an imidazolinone herbicide into which an ALS herbicide-tolerant ALS gene (csr1-2) derived from Arabidopsis thaliana has been introduced is sold under the trade name “Cultivance”, for example. Soybeans into which an ALS herbicide-tolerant ALS gene (gm-hra) derived from soybean (Glycine max) has been introduced are, for example, trademarks of “Treus (trademark)”, “Plenish (trademark)” and “Optimum GAT (trademark)”. It is sold by name. In addition, there is a cotton into which an ALS gene (S4-HrA) resistant to an ALS herbicide derived from tobacco (Nicotiana tabacum cv. Xanthi) is introduced.
HPPD herbicide resistant plant: obtained by introducing HPPD gene (avhppd-03) derived from oat (Avena sativa). For example, soybeans introduced with the PAT gene (pat) derived from Streptomyes viridochromogenes at the same time as the above genes are soybeans having resistance to mesotrione and glyphosate as “Herbicide-tolerant Soybean line” It is sold under the trade name.
2,4-D resistant plants: Maize introduced with an aryloxyalkanoate dioxygenase gene (aad-1) derived from Sphingobium herbicidovorans, for example, “Enlist ( (Trademark) It is sold under the brand name “Maize”. Soybeans and cotton introduced with the allyloxyalkanoate dioxygenase gene (aad-12) derived from Delftia acidovorans are known and sold under the trade name “Enlist ™ Soybean”, for example. ing.
Dicamba herbicide-tolerant plant: obtained by introducing a dicamba monooxygenase gene (dmo) derived from Stenotrophomonas maltophilia strain DI-6. Soybean and cotton into which the above gene has been introduced are known. A soybean (Glycine max L.) into which a glyphosate-resistant EPSPS gene (CP4 epsps) derived from Agrobacterium tumefaciens strain CP4 (Agrobacterium tumefaciens strain CP4) was introduced at the same time as the above gene is, for example, “Genuity (registered trademark) Roundup Ready (trademark) 2 Xtend (trademark) ".
Additional plants modified with respect to herbicides are widely known, e.g., alfalfa, apple, barley, eucalyptus, flax, grape, lentil, rapeseed, pea, potato, rice, sugar beet, sunflower, resistant to glyphosate Tobacco, tomato beetle and wheat (see, for example, US5188642, US4940835, US5633435, US5804425, US5627061); bean, cotton, soybean, pea, potato, sunflower, tomato, tobacco, corn, resistant to dicamba Sorghum and sugarcane (see, for example, WO2008 / 051633, US7105724, and US5670454); soybeans, sugar beets, potatoes, tomatoes, and tobacco that are resistant to glufosinate (see, for example, US6376754, US5646024, US5561236); 2,4-D Resistant cotton and peppers Apples, tomatoes, sunflowers, tobacco, potatoes, corn, cucumbers, wheat, soybeans, sorghum and millet (see, for example, US6153401, US6100446, WO2005 / 107437, US5608147 and US5670454); ALS-inhibiting herbicides (eg, sulfonylurea series) Canola, corn, millet, barley, cotton, mustard, lettuce, lentil, melon, millet, oats, nata, potatoes, rice, rye, sorghum with resistance to herbicides or imidazolinone herbicides) , Soybeans, sugar beets, sunflowers, tobacco, tomatoes and wheat (see for example US5013659, WO2006 / 060634, US4761373, US5304732, US6211438, US6211439 and US6222100), especially rice that is resistant to imidazolinone herbicides Specific to the acetohydroxyacid synthase gene Rice having mutations (eg, S653N, S654K, A122T, S653 (At) N, S654 (At) K, A122 (At) T) (see, eg, US2003 / 0217381, WO2005 / 020673); HPPD-inhibiting herbicides (eg, Isoxazole herbicides such as isoxaflutor; triketone herbicides such as sulcotrione and mesotrione; and pyrazole herbicides such as pyrazolinate), Rice, corn, tobacco, soybean, cotton, rapeseed, sugar beet, wheat and potato (see, for example, WO2004 / 055191, WO1996 / 38567, WO1997 / 049816 and US6791014); and wheat resistant to PPO-inhibiting herbicides , Soybean, cotton, sugar beet, rapeseed, rice, corn, sorghum, sugar cane and sugar beet (eg, US2002 / 0073443, US2008 / 0052798, Pest Management Science, 61, 2005, 277-285).

  As plants to which herbicide tolerance has been imparted by conventional breeding technology or genome breeding technology, for example, rice `` Clearfield Rice '', wheat `` tolerant to imidazolinone-based ALS-inhibiting herbicides such as imazetapyr and imazamox '' Clearfield Wheat ", sunflower" Clearfield Sunflower ", lentil" Clearfield lentils "and canola" Clearfield canola "(product of BASF); soybean" STS soybean "resistant to sulfonylurea ALS-inhibiting herbicides such as Thifensulfuron methyl; Corn “SR corn” (also known as “Poast Protected® corn”) that is resistant to acetyl-CoA carboxylase inhibitors such as trione oxime herbicides, aryloxyphenoxypropionic acid herbicides; Sunflower "Expre" resistant to sulfonylurea herbicides such as tribenuron ssSun® ”; rice“ Provisia® Rice ”resistant to acetyl CoA carboxylase inhibitors such as quizalofop; and canola“ Triazine Tolerant Canola ”resistant to photosystem II inhibitors.

  Canola "SU Canola (registered trademark)" with sulfonylurea herbicide tolerance using rapid cultivar development technology (Rapid Trait Development System, RTDS (registered trademark)) as a plant to which herbicide tolerance was imparted by genome editing technology Is mentioned. RTDS (registered trademark) corresponds to the introduction of oligonucleotide-directed mutagenesis in genome editing technology. Gene repair Oligonucleotide (GRON), that is, cleaving DNA in plants through DNA and RNA chimeric oligonucleotides It is a technology that can introduce mutations without any problems. Other examples include maize with reduced herbicide tolerance and phytic acid content by deleting the endogenous gene IPK1 using zinc finger nuclease (see, eg, Nature 459, 437-441 2009); Examples include rice that has been given herbicide tolerance using cast-nine (see, for example, Rice, 7, 5 2014).

  Examples of plants to which herbicide tolerance has been imparted by the new breeding technology include soybeans in which the properties possessed by GM rootstock are imparted to the hogi using a variety improvement technology using grafts. Specific examples include soybeans in which glyphosate tolerance is imparted to non-transgenic soybean spikelets using Roundup Ready (registered trademark) soybean having glyphosate tolerance as rootstocks (see Weed Technology 2013, 27, 412.). .

  Examples of plants imparted with pest resistance are listed below.

Plants that have been given resistance to lepidopteran pests by genetic engineering technology, for example, encode delta-endotoxin (δ-endotoxin), an insecticidal protein derived from the soil bacterium Bacillus thuringiensis (hereinafter abbreviated as Bt fungus). Maize (Zea mays L.), soybean (Glycine max L.), cotton (Gossypium hirsutum L.), rice (Oryza sativa L.), poplar (Populus sp.), Tomato (Lycopersicon esculentum) and Examples include eggplant (Solanum melongena). Examples of delta-endotoxins that impart resistance to lepidopteran pests include Cry1A, Cry1Ab, modified Cry1Ab (partially deleted Cry1Ab), Cry1Ac, Cry1Ab-Ac (a hybrid protein in which Cry1Ab and Cry1Ac are fused), Cry1C, Cry1F, Cry1Fa2 (modified cry1F), moCry1F (modified Cry1F), Cry1A. 105 (a hybrid protein in which Cry1Ab, Cry1Ac, and Cry1F are fused), Cry2Ab2, Cry2Ae, Cry9C, Vip3A, and Vip3Aa20.
Plants imparted with resistance to Coleoptera by genetic recombination techniques include, for example, corn and potato introduced with a gene encoding delta-endotoxin, an insecticidal protein derived from soil bacteria Bt. Examples of delta-endotoxins that confer resistance to Coleoptera include Cry3A, mCry3A (modified Cry3A), Cry3Bb1, Cry34Ab1, and Cry35Ab1.
Plants that have been given resistance to Diptera by genetic recombination technology, for example, maize (Cry3A and Cry1Ab-derived hybrid protein eCry3.1Ab fused with a synthetic gene encoding Cry3A and Cry1Ab derived from soil bacteria) And cotton (Gossypium hirsutum L.) introduced with a gene encoding a trypsin inhibitor CpTI derived from Zea mays L. and cowpea (Vigna unguiculata). Furthermore, there are poplars and the like into which a gene encoding API, which is a protease inhibitor protein A derived from squittaria sagittifolia, and exhibits resistance to a wide range of pests.
Insecticidal proteins that impart pest resistance to plants include hybrid proteins of the above insecticidal proteins, partially missing proteins, and modified proteins. The hybrid protein is produced by a combination of different domains of a plurality of insecticidal proteins, using genetic recombination techniques, Cry1Ab-Ac and Cry1A. 105 etc. are known. As a protein lacking a part, Cry1Ab and the like lacking a part of the amino acid sequence are known. Examples of the modified protein include proteins in which one or more amino acids of natural delta-endotoxin are substituted, and Cry1Fa2, moCry1F, mCry3A, and the like are known. The modified protein includes a case where a non-naturally occurring proteolytic enzyme recognition sequence is inserted into a toxin. For example, Cry3A055 (WO2003 / 018810 in which a cathepsin G-recognition sequence is inserted into a Cry3A toxin is used. Reference).
Cotton (event MON88702) introduced with modified BT protein Cry51Aa2 (Cry51Aa2.834_16) by gene recombination technology has been developed by Monsanto, and the genus lygus such as Lygus lineolaris and the hemipods such as aphids and Frankliniella Resistant to thrips such as genus species.
Other insecticidal proteins that impart pest resistance to plants by genetic recombination techniques include, for example, insecticidal proteins derived from Bacillus cereus or Bacillus popilliae; plant insecticidal proteins Vip1, Vip2 , Vip3 (as subclasses Vip3Aa to Vip3Aj, Vip3Ba, Vip3B and Vip3Ca are known, specifically, for example, Vip3Aa20 and Vip3Aa61 are known) and Vip4; Photolabdus luminescens (Photorhabdus luminescens), etc. Insecticidal proteins from nematode symbiotic bacteria (colonizing nematodes) such as Photorhabdus spp. Or Xenorhabdus nematophilus; scorpion toxin, spider toxin Toxins produced by animals including insect-specific neurotoxins such as bee toxins; Toxins produced by filamentous fungi such as Streptomycetes venom; plant lectins such as pea lectin, barley lectin, snowdrop lectin; agglutinin; trypsin inhibitor, serine protease inhibitor, patatin, cystatin, papain inhibitor, etc. Inhibitors: Ribosome inactivating proteins (RIP) such as ricin, corn-RIP, abrin, ruffin, saporin, bryodin; steroids such as 3-hydroxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, cholesterol oxidase Metabolic enzyme; ecdysone inhibitor; HMG-CoA-reductase; ion channel inhibitor such as sodium channel inhibitor and calcium channel inhibitor; juvenile hormone esterase; diuretic hormone Receptor; stilbene synthase; bicycloalkyl benzyl synthase; it includes and glucanase; chitinases.

In addition, plants that have been imparted with pest resistance by introducing one or more insecticidal protein genes are already known, and some plants are commercially available.
Examples of cotton imparted with insect resistance include `` Bollgard (trademark) cotton '', `` BXN (trademark) Plus Bollgard (trademark) Cotton '', `` BXN (trademark) Plus, which expresses the insecticidal protein Cry1Ac derived from Bt bacteria “Bollgard ™ Cotton”, “JK 1”, “Roundup Ready ™ Bollgard ™ Cotton” and “Ingard ™”; “Herculex (Cry1Fa2)” expressing the insecticidal protein modified Cry1F (Cry1Fa2) from Bt (Trademark) I "and" Herculex (trademark) CB ";" VIPCOT (trademark) Cotton "expressing the insecticidal protein Vip3A from Bt bacteria;" Bollgard II (trademark) "expressing the insecticidal proteins Cry1Ac and Cry2Ab from Bt bacteria ) cotton '', `` Roundup Ready (TM) Bollgard II (TM) Cotton '', `` Roundup Ready (TM) Flex (TM) Bollgard II (TM) Cotton '' and `` Fivermax (TM) Liberty Link (TM) Bollgard II (TM) Bollgard III (registered trademark) expressing the insecticidal proteins Cry1Ac, Cry2Ab and Vip3A derived from Bt bacteria "And" Bollgard (R) III x Roundup Ready (TM) Flex (TM) ";" VIPCOT (TM) Roundup Ready Flex (TM) Cotton "expressing the insecticidal proteins Vip3A and Cry1Ab from Bt; “VIPCOT® Cotton” expressing insecticidal proteins Vip3A and Cry1Ac derived from “WideStrike ™ Cotton” and “WideStrike ™ Roundup Ready (trademark) expressing insecticidal proteins Cry1Ac and Cry1F derived from Bt bacteria ”Cotton” and “Widestrike ™ Roundup Ready Flex ™ Cotton”; “TwinLink ™ Cotton” and “Glytol ™ x Twinlink ™” expressing the insecticidal proteins Cry1Ab and Cry2Ae from Bt bacteria "Widestrike (registered trademark) 3" and "Widestrike (trademark) x Roundup Ready Flex (trademark) x VIPCOT (trademark) Cotton" expressing insecticidal proteins Cry1Ac, Cry1F and Vip3A derived from Bt bacteria; Glytol (trademark) expressing the sex proteins Cry1Ab, Cry2Ae and Vip3A x Twinlink (TM) x VIPCOT (TM) Cotton "is commercially available.
Examples of corn imparted with insect resistance include `` YieldGard (registered trademark) Rootworm RW '', `` YieldGard (trademark) RW + RR '', `` YieldGard (trademark) VT (expressing Cry3Bb1 derived from Bt bacteria) Trademarks) Rootworm ™ RR2 ”and“ MaxGard ™ ”;“ YieldGard® VT Triple ”and“ YieldGard ™ Plus with RR ”expressing the insecticidal proteins Cry3Bb1 and Cry1Ab from Bt bacteria; Bt "Bt Xtra (trademark) Maize" expressing insecticidal protein Cry1Ac derived from bacteria; "YieldGard Plus (registered trademark)" expressing insecticidal proteins Cry1Ab and Cry3Bb1 derived from Bt; insecticidal protein Cry1Ab derived from Bt “Bt10”, “Liberty Link ™ Yieldgard ™ Maize”, “Agrisure ™ GT / CB / LL” and “YieldGard ™ CB + RR” expressed; insecticidal protein Cry1A. “YieldGard ™ VT Pro ™” and “Genuity® VT Double Pro ™” expressing 105 and Cry2Ab2; “Agrisure® RW” expressing the insecticidal protein mCry3A from Bt bacteria And “Agrisure ™ GT / RW”; “Starlink ™ Maize” expressing the insecticidal protein Cry9C from Bt bacteria; “YieldGard ™” expressing the insecticidal protein Cry1Ab from Bt bacteria; MaizeGard (TM), NaturGard KnockOut (TM), Maximizer (TM), Roundup Ready (TM) YieldGard (TM) maize, Agrisure (TM) CB / LL, and Mavera (TM) YieldGard (Trademark) Maize ”;“ Agrisure® 3122 ”expressing the insecticidal proteins Cry1Ab, Cry1F, modified Cry3A, Cyr34Ab1 and Cyr35Ab1 derived from Bt;“ Agrisure (registered trademark) expressing the insecticidal protein Vip3Aa20 derived from Bt ” Viptera ";" Agri "expressing the insecticidal proteins Vip3Aa20 and Cry1Ab from Bt bacteria sure (registered trademark) Viptera (registered trademark) 2100 ”and“ Agrisure (registered trademark) Viptera (registered trademark) 3110 ”; Bt-derived insecticidal proteins Vip3Aa20, Cry1Ab, and“ Agrisure (registered trademark) Viptera ( (Trademark) 3100 "," Agrisure (registered trademark) Viptera (trademark) 3111) "and" Agrisure (registered trademark) Viptera (trademark) 4 "; expressing the insecticidal proteins Vip3Aa20, Cry1Ab and modified Cry1F from Bt (Registered trademark) Viptera (trademark) 3220 ";" Agrisure (registered trademark) Duracade (trademark) "expressing insecticidal protein eCry3.1Ab (Cry3A-Cry1Ab chimeric protein) derived from Bt; insecticidal protein derived from Bt eCry3.1Ab (Cry3A-Cry1Ab chimeric protein), “Agrisure® Duracade ™ 5122” expressing modified Cry3A, Cry1Ab and modified Cry1F; insecticidal protein eCry3.1Ab (Cry3A-Cry1Ab Chimeric protein), modified Cry3A, modified Cry1Ab and Vip3A variants “Agrisure® Duracade ™ 5222”; “Herculex ™ RW” expressing the insecticidal proteins Cyr34Ab1 and Cyr35Ab1 from Bt; expressing the insecticidal proteins Cyr34Ab1, Cyr35Ab1 and Cry1F from Bt “Herculex XTRA ™”; an insecticidal protein Cry1A derived from Bt bacteria. 105, “Genuity® VT Triple Pro ™” expressing Cry2Ab2 and Cry3Bb1; insecticidal proteins Cry1F, Cry2Ab, Cyr34Ab1, Cyr35Ab1, Cry3Bb1 and Cry1A. “Genuity® SmartStax ™” expressing 105; insecticidal protein modified Cry1F, Cry2Ab and Cry1A. “Power Core ™” expressing 105; “Herculex XTRA ™ RR” expressing insecticidal protein modified Cry1F, Cyr34Ab1 and Cyr35Ab1 from Bt; insecticidal protein modified Cry1F, Cyr34Ab1, Cyr35Ab1 from Bt “Optimum® Intrasect Xtreme” expressing Cry1Ab and modified Cry3A; “Optimum® Intrasect XTRA” expressing insecticidal protein modified Cry1F, Cyr34Ab1, Cyr35Ab1 and Cry1Ab derived from Bt; “Optimum® TRIsect” expressing the insecticidal protein modified Cry1F and modified Cyr3A is commercially available.
Examples of other pest-resistant plants include potatoes expressing the insecticidal protein Cry3A derived from Bt bacteria `` Atlantic NewLeaf (trademark) potato '', `` NewLeaf (trademark) Russet Burbank potato '', `` Lugovskoi plus '', "Elizaveta plus", "Hi-Lite NewLeaf (TM) Y potato, Superior NewLeaf (TM) potato" and "Shepody NewLeaf (TM) Y potato"; rice expressing the insecticidal proteins Cry1Ab and Cry1Ac from Bt 63 ”and“ Huahui-1 ”; soybean“ Intacta ™ Roundup Ready ™ 2 Pro ”expressing the insecticidal protein Cry1Ac derived from Bt; eggplant“ BARI Bt expressing the insecticidal protein Cry1Ac derived from Bt "Begun-1, -2, -3 and -4" are commercially available.
Also, for example, corn “YieldGard corn rootworm”, “YieldGard VT”, “Herculex RW”, “Herculex Rootworm” and “Agrisure CRW” having resistance to corn rootworm; Corn “YieldGard corn” having resistance to corn borer borer "," YieldGard plus "," YieldGard VT Pro "," Agrisure CB / LL "," Agrisure 3000GT "," Hercules I "," Hercules II "," KnockOut "," NatureGard "and" StarLink "; Corn "Herculex I", "Herculex Xtra", "NewLeaf", "NewLeaf Y" and "NewLeaf Plus" resistant to cut worms, corn borers, black cut worms and fall army worms; against corn borers and corn root worms Resistant corn “YieldGard Plus”; resistant to fake American tobacco Tutton "Bollgard I" and "Bollgard II"; cotton "Bollgard II", "WideStrike (Wise Strike), fake American tobacco, cotton ball worm, fall army worm, beat army worm, cabbage looper, soybean looper and pink ball worm ”And“ VipCot ”; potatoes“ NewLeaf ”,“ NewLeaf Y ”and“ NewLeaf Plus ”having resistance to tobacco tin mega; eggplants“ Bt brinjal ”,“ Dumaguete ”having resistance to eggplant moth, fruit bowler and cotton ball worm "Long Purple" and "Mara" (see, for example, US5128130) are known.
Additional plants with insecticide resistance are generally known, e.g., corn borer resistant rice (see, e.g., Molecular Breeding, Vol. 18 (2006), No. 1), lepidopter resistant lettuce (e.g., US Pat. No. 5,349,124), and Lepidoptera (for example, Japanese pear moth, Ichimon disseri, rice mushroom, corn borer, rice case worm, and rice army worm) have resistance to rice (see, for example, WO2001 / 021821). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above publications.

  Plants to which pest resistance has been imparted by RNA interference technology include lepidopterous pests (eg, cut worms such as corn borers, corn ear worms, black cut worms, and fall army worms) and Coleoptera pests (corn root worms) Corn that is resistant to) is marketed or developed under the trade names "SmartStax (registered trademark)", "SmartStax (registered trademark) Pro" or "Genuity (registered trademark) SmartStax Pro".

  Examples of plants to which pest resistance has been imparted by conventional breeding techniques or genome breeding techniques include, for example, the aphid resistance gene “Rag1 (Resistance to Aphis glycines 1)” or “Rag2 (Resistance to Aphis glycines) 2) Soybeans resistant to soybean Aphis glycines carrying the gene (see J. Econ. Entomol., 2015, 108, 326.); Soybeans resistant to Heterodera glycines (Phytopathology) , 2016, 106, 1444.); Cotton resistant to Meloidogyne incognita (J. Nematol., 2009, 41, 140); Rice “Kanto BPH1” resistant to brown planthopper; An example is soybean “Fukuminori” which exhibits resistance.

  These pest-resistant plants are given resistance to any harmful insects (especially lepidopterous insects, Coleoptera insects, Diptera insects, Coleoptera insects), harmful spiders and harmful nematodes Has been. Plants imparted with pest resistance are preferably cereals (e.g. wheat, barley, rye, oats), corn, canola, sorghum, soybean, rice, rapeseed, sugar beet, sugar cane, grape, lentil, sunflower, alfalfa, Selected from berries, drupes, peanuts, coffee, tea, strawberries, turf, vegetables (e.g. tomatoes, potatoes, cucurbits and lettuce), more preferably soybeans, corn, tomatoes, rice and straw Selected from cereals (eg, wheat, barley, rye and oats), most preferably selected from soybeans, rice, corn and cereals (eg, wheat, barley, rye and oats).

  Examples of plants imparted with disease resistance are listed below.

Plants that have been rendered disease resistant by genetic engineering techniques, for example, express so-called `` pathogenicity related proteins '' (PRP, e.g. see EP0392225) or so-called `` antifungal proteins '' (AFP, e.g. see US6864068) Plant. Various antifungal proteins with activity against phytopathogenic fungi have been isolated from specific plant species and are common sense. Examples of such anti-pathogenic substances and plants capable of synthesizing such anti-pathogenic substances are known, for example, from EP0392225, WO1993 / 05153, WO1995 / 33818 and EP0353191. Plants that are resistant to fungicidal pathogens, viral pathogens and bacterial pathogens are created by introducing plant resistance genes. A number of resistance genes have been identified and isolated and used to improve plant resistance, such resistance genes include, for example, producing tobacco mosaic virus (TMV) resistant tobacco plants N genes introduced into TMV-sensitive tobacco lines (e.g. see US 5571706), Prf genes introduced into plants to obtain enhanced pathogenic resistance (e.g. see WO1998 / 02545), And the Rps2 gene from Arabidopsis thaliana used to create resistance to bacterial pathogens such as Pseudomonas syringae (see, eg, WO1995 / 028423). Plants showing a systemic acquired resistance response were obtained by introducing a nucleic acid molecule encoding the TIR domain of the N gene (see, eg, US 6630618). Further examples of known resistance genes include the Xa21 gene that has been introduced into many rice varieties (see, e.g., US5952485, US5977434, WO1999 / 009151, WO1996 / 022375), Rcg1 for resistance to colletotrichum. Genes (see, for example, US2006 / 225152), prp1 gene (see, for example, US5859332, WO2008 / 017706), ppv-cp gene that introduces resistance to plum poxvirus (see, for example, US PP15,154Ps), P1 Genes (e.g. see US5968828), genes such as Blb1, Blb2, Blb3, RB2 and Rpi-vnt1 to introduce resistance to potato phytophthora infestans (see e.g. US7148397), LRPKml gene (See, for example, WO1999 / 064600), P1 gene for potato virus Y resistance (see, for example, US5968828), HA5-1 gene (see, for example, US5877403 and US6046384), potato virus X (PVX), jas PIP gene for introducing broad resistance to viruses such as potato virus Y (PVY), potato cigar virus (PLRV) (see, for example, EP0707069), as well as Arabidopsis NI16 to obtain fungal resistance Genes, genes such as the ScaM4 gene and the ScaM5 gene (see, for example, US6706952 and EP1018553). In addition, bean golden mosaic virus (hereinafter referred to as BGMV) resistant beans are plants that have been given resistance by RNA interference technology and are double-stranded RNA genes of replication proteins. (sense and antisense ac1 gene) is introduced, and resistance to BGMV is exhibited by inhibiting the synthesis of BGMV replication protein. Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above publications.
Anti-pathogenic substances that can be expressed by such plants include, for example, ion channel blockers (sodium channel blockers, calcium channel blockers, etc.); viral KP1, KP4 and KP6 toxins; stilbene synthase; bibenzyl synthase Chitinase; glucanase; so-called “pathogenicity related proteins” (PRP; see eg EP0392225); anti-pathogenic substances produced by microorganisms (eg peptide antibiotics, heterocyclic antibiotics (eg WO1995 / 033818) And protein factors or polypeptide factors involved in plant pathogen defense (so-called “plant disease resistance genes” described in WO2003 / 000906)).
Anti-pathogenic substances produced by plants can protect plants from various pathogenic microorganisms such as fungi, viruses and bacteria. Useful plants of increasing interest in connection with the present invention are cereals (e.g. wheat, barley, rye and oats), soybeans, corn, rice, rapeseed, berries, nuts, peanuts, coffee, tea, strawberries Vines and vegetables (e.g. tomatoes, potatoes), cucurbits, papayas, melons, lentes and lettuce, more preferably soybeans, tomatoes, rice and cereals (e.g. wheat, barley, Rye and oats) and most preferably selected from soybeans, rice and cereals (eg wheat, barley, rye and oats).
Plants that are resistant to fungal pathogens are, for example, soybeans that are resistant to soybean rust fungi (Phakopsora pachyrhizi and Phakopsora meibomiae) (see, eg, WO2008 / 017706); against potato phytophthora infestans Resistant solanaceous plants such as cotton, tomatoes and potatoes (see, for example, US5859332, US7148397, EP1334979); maize resistant to the genus Colletotrichum such as Colletotrichum graminicola (eg, US2006 / Apples with resistance to venturia inaequalis (see eg WO1999 / 064600); Fusarium species (eg fusarium graminearum, fusarium sporotrichioides, fusarium lateritium, fusarium pseudograminearum, fusarium sambucinum, fusarium culmorum , Fusarium poae, fusarium acuminatum, fus plants with resistance to arium equiseti) (eg rice, wheat, barley, rye, corn, oats, potato, melon, soybean and sorghum) (see eg US6646184, EP1477557); There are plants such as corn, soybean, cereals (especially wheat, rye, barley, oats, rye, rice), tobacco, sorghum, sugar cane, potatoes (see, for example, US5859332, US5689046, US6706952, EP1018553 and US6020129).
Plants that are resistant to bacterial pathogens include, for example, rice that is resistant to xylella fastidiosa (see, eg, US6232528); rice, cotton, and soybean that are resistant to bacterial head blight Plants such as potato, sorghum, corn, wheat, barley, sugarcane, tomato and pepper (see, eg, WO2006 / 42145, US5952485, US5977434, WO1999 / 09151, WO1996 / 22375); resistance to pseudomonas syringae There are tomatoes that have sex (see, for example, Can. J. Plant Path., 1983, 5: 251-255).
Plants that are resistant to viral pathogens are, for example, nuclear fruits (eg, plums, almonds, apricots, cherries, peaches, nectarines) that are resistant to plum pox virus (eg, US PP15154Ps, EP0626449 Potato having resistance to potato virus Y (see, for example, US5968828); potato, tomato, cucumber and tomato spotted wilt virus Plants such as legumes (see, eg, EP0626449, US5973135); maize that is resistant to maize streak virus (see, eg, US6040496); papaya ring spot virus (papaya ring spot virus) Papaya resistant to) (see eg S5877403, US6046384); cucumber mosaic Cucurbitaceae (eg, cucumber, melon, watermelon and pumpkin) resistant to cucumber mosaic virus and solanaceous plants (eg, potato, tobacco, tomato, eggplant, paprika, capsicum and pepper) (eg, US6849780 Cucurbitae (eg cucumber, melon, watermelon and pumpkin) having resistance to watermelon mosaic virus 2 and zucchini yellow mosaic virus (see eg US6015942); potato Viruses such as potato virus resistant to potato leafroll virus (see, for example, US5576202); potato virus X (potato virus X), potato virus Y (potato virus Y)), potato leafroll virus Potatoes with broad resistance to (e.g. E P0707069); common bean that is resistant to Bean golden mosaic virus (see, for example, Mol Plant Microbe Interact. 2007 Jun; 20 (6): 717-26.).
There are plants that are resistant to antibiotics (eg, kanamycin, neomycin and ampicillin). The naturally occurring bacterial nptII gene expresses an enzyme that blocks the action of the antibiotics kanamycin and neomycin. The ampicillin resistance gene ampR (also known as blaTEM1) is derived from the bacterium Salmonella paratyphi and is used as a marker gene in the transformation of microorganisms and plants. ampR is involved in the synthesis of beta-lactamase, an enzyme that neutralizes the antibiotics of the penicillin group including ampicillin. Plants having resistance to antibiotics include, for example, potato, tomato, flax, canola, rapeseed, rape seed and corn (see, for example, Plant Cell Reports, 20, 2001, 610-615, Trends in Plant Science, 11, 2006, 317-319, Plant Molecular Biology, 37, 1998, 287-296, Mol Gen Genet., 257, 1998, 606-13. Plant Cell Reports, 6, 1987, 333-336, Federal Register (USA), 60, No. 113, 1995, 31139. Federal Register (USA), 67, No. 226, 2002, 70392, Federal Register (USA), 63, No. 88, 1998, 25194, Federal Register (USA), Volume 60, No.141, 1995, 37870, Canadian Food Inspection Agency, FD / OFB-095-264-A, October 1999, FD / OFB-099-127-A, see October 1999). Preferably, the plant is selected from soybeans, tomatoes and cereals (e.g. wheat, barley, rye and oats), most preferably selected from soybeans and cereals (e.g. wheat, barley, rye and oats). The
Available plants that have been given resistance to plant viral diseases are, for example, papaya “Rainbow”, “SunUp” and “Huanong No. 1” that have been given resistance to papaya ringspot virus. Potato “Innate® Hibernate”, “Innate® Glaciate” and “Innate® Acclimate” showing resistance to potato plagues (phytophthora infestans); Potato virus Y And / or there is a potato “Newleaf ™” that shows resistance to potato leaf curl virus (PLRV).

  Rice that has been given resistance to rice blast (Magnaporthe oryzae) as a plant that has been given resistance to disease by conventional breeding technology or genome breeding technology; resistance to Rhizoctonia solani Rice given resistance to red rust (Puccinia triticina); Wheat resistant to yellow rust (Puccinia striiformis f. Sp. Tritici); Black rust (Puccinia graminis f. sp. tritici) wheat; resistance to powdery mildew (Blumeria graminis f. sp. tritici); wheat resistance to leaf blight (Zymoseptoria tritici); Wheat with resistance to blight (Stagonospora nodorum); Wheat with resistance to Pyrenophora tritic-repentis; Powdery mildew (Blumeria graminis f. Sp. Barley with resistance against hordei; Barley with resistance against small morbidity (Puccnia hordei); Barley with resistance against Pyrenophora teres; against Rhynchosporium commune Barley with resistance; Barley with resistance to Ramularia collo-cygni; Corn with resistance to Anthracnose stalk rot; Gray leaf spot disease (Gray leaf) maize with resistance to spot); maize with resistance to Boss Bacterial Disease (Goss`s wilt); maize with resistance to Fusarium stalk rot; Asia Soybean with resistance to Asian soybean rust; Resistance to soybean phytophthora rot Soybean granted; Soybean granted resistance to sudden death syndrome; Pepper granted resistance to Phytophthora; Lettuce granted resistance to powdery mildew; Tomato with resistance to Bacterial wilt; Tomato with resistance to Geminivirus; Lettuce with resistance to Downy mildew; Clubroot Rapeseed, cabbage, Brussels sprouts, cauliflower, colored green (Borekale), cruciferous plants such as broccoli; rapeseed, cabbage, Brussels sprouts, cauliflower, imparted resistance to black leg, Cruciferous plants such as colored green (Borekale), broccoli; melon vine caused by Fusarium oxysporum f.sp. melonis Melon (for example, refer to WO2009 / 000736) imparted with resistance to split disease.

  As a plant to which disease resistance has been imparted by genome editing technology, the powdery mildew resistance gene (MILDEW RESISTACE LOCUS O, hereinafter abbreviated as MLO) is deleted using Talen and Crisper Cassine. Bread wheat that is resistant to this disease (see, for example, Nat. Biotech., 32,947-951 2014); powdery mildew by deleting the SlMLO1 gene, one of the MLOs, using Crisper Cassine Tomlo1 tomato (Tomelo, for example) that is resistant to Xanthomonas (see, for example, Scientific Reports 7, Article number: 482 2017); Xanthomonas oryzae that causes white leaf blight of rice by editing the OsSWEET14 gene in rice using talen oryzae pv. Oryzae) resistant rice (see Nat. Biotechnol. 30, 390-392 2012); modifying the OsERF922 gene in rice using crisper-cassine , Rice resistant to Magnaporthe oryzae that causes rice blast (PLoS ONE 11: e0154027. Doi: 10.1371 / journal.pone.0154027 2016); using recessive eIF4E ( Cucumber (Mol. PlantPathol. 17) resistant to cucumber vein yellow ingvirus (CVYV), zucchini yellow mosaic virus (ZYMV), and papaya ringspot virus-type W (PRSV-W) by disruption of eukaryotic translation initiation factor 4E) gene , 7 1140-1153 (see 2016); soybeans resistant to soybean stem blight caused by Phytophthora sojae by disruption of RXLR effector gene (Avr4 / 6) using Crisper Cassine (Mol Plant Pathol 17 (1 ) 127-139 2016)).

  Introduced Rvi6 (previously called HcrVf2) gene that is resistant to apple scab caused by Venturia inaequalis as a plant given disease resistance by new breeding technology An apple that is resistant to apple mold (see, for example, Plant Biotech. J., 12, 2-9, 2014); an example that gives HOKI the properties of GM rootstock, which is a variety improvement technology using grafts As a sweet cherry (Plant Biotech. J., 12, 1319-) whose nature has been transferred from a transgenic rootstock having resistance to infection to Prunus necrotic ringspot virus to a non-transgenic spikelet. 1328 2014)).

Examples of plants with modified product quality are listed below.
The product quality modification means the synthesis of the modified component or the increase or decrease in the synthesis amount of the component compared to the corresponding wild type plant. For example, there are modified plants with increased or decreased content of vitamins, amino acids, proteins and starches, various oils, and modified plants with decreased nicotine content.

  Plants whose product quality has been modified by genetic recombination technology include, for example, alfalfa-derived S-adenosyl-L-methionine: trans-caffeoyl CoA 3-methyltransferase (ccomt) gene duplexes involved in lignin production Alfalfa with a gene that generates RNA and reduced lignin content by RNA interference; Triacylglyceride containing lauric acid by introducing a 12: 0 ACP thioesterase gene from Umbellularia californica involved in fatty acid synthesis Canola with increased content "Laurical (trademark) Canola"; by introducing a partial gene (gm-fad2-1) of omega-6 desaturase derived from soybean, which is a desaturase of fatty acid, Soybean “Plenish ™” or “Treus ™” with increased oleic acid content; -Acyl-acyl carrier protein thioesterase gene (fatb1-A) double-stranded RNA and soybean-derived delta-12 desaturase gene (fad2-1A) double-stranded RNA Soybean "Vistive Gold (trademark)" in which saturated fatty acid content is reduced by introducing the gene; δ-6 desaturase gene (Pj. D6D) derived from primrose, and δ-12 desaturase gene (Nc. Fad3) derived from red bread mold Transgenic soybean in which stearidonic acid, which is one of ω3 fatty acids, was produced by introducing a heat-stable alpha-amylase gene (amy797E) of Thermococcales sp. Maize “Enogen (registered trademark)” with enhanced bioethanol production; Maize “Mavera ™ Maize” and “Mavera ™ YieldGard ™ Maize” enhanced lysine production by introducing a dihydrodipicolinate synthase gene (cordapA) from Corynebacterium glutamicum Potato "Amflora (trademark)" in which the amylose content in starch granules is decreased and the amylopectin content is increased by introducing the antisense gene gbss of starch-synthesizing enzyme derived from potato (granule-bound starch synthase enzame, GBSS) , “Starch Potato”; introduction of genes pPhL and pR1 that generate double-stranded RNA of transcription factors PhL and R1 that promote potato-derived starch degradation, and two genes Asn1 involved in inhibition of starch degradation and asparagine production. Suppression of asparagine synthesis by introducing asn1 gene that generates heavy chain RNA (carcinogenesis by heating) The purpose of this study was to suppress the accumulation of asparagine and reducing sugars involved in the production of acrylamide, the substance), and the potato that suppressed the formation of black spots by introducing the gene ppo5 that generates double-stranded RNA of the polyphenol oxidase gene Ppo5 derived from potato. Innate (registered trademark) Cultivate, Innate (registered trademark) Generate, Innate (registered trademark) Accelerate, Innate (registered trademark) Invigorate, Innate (registered trademark) Glaciate, Innate (registered trademark) Acclimate ”and“ Innate® Hibernate ”; tobacco with reduced nicotine content by introducing the antisense gene (NtQPT1) of the quinolinate phosphoribosyltransferase gene QpTase from Nicotiana tabacum; Narcissus Pseudonarcissus) phytoene synthase gene (psy) and carotenoid synthesis Golden rice that can produce rice containing vitamin A by producing β-carotene in endosperm tissue by introducing carotene desaturase gene (crt1) derived from soil bacteria (Erwinia uredovora) and expressing it specifically in endosperm There is rice (Golden rice). Other examples include potato and corn with modified amylopectin content (see, for example, US6784338, US2007 / 0261136, WO1997 / 04471); canola, corn, cotton, grape, cattail with modified oil content , Catalpa, rice, soybean, rapeseed, wheat, sunflower, bittern, safflower and vernonia plants (eg, US7294759, US7157621, US5850026, US6441278, US5723761, US6380462, US6365802, WO2001 / 079499, US2006 / 0075515 and US7294759); sunflower with increased fatty acid content (see eg US6084164); soybean with reduced allergen content (see eg US6864362); tobacco with reduced nicotine content (see eg US6864362) For example, see US2006 / 0185684, WO2005 / 000352 and WO2007 / 064636); canola and soybeans with increased lysine content (eg Bio / Tec hnology 13, 1995, 577-582); corn and soybean with modified methionine, leucine, isoleucine and / or valine composition (see eg US6946589, US6905877); soybean with increased sulfur amino acid content ( For example, see EP0929685, WO1997 / 041239); 3'-Phosphoadenosine-5'-phosphosulfate reductase derived from Escherichia coli is expressed specifically on the leaf surface Corn with increased methionine content (see PNAS, 2017, 114 (43), 11386.); increased content of free amino acids (eg asparagine, aspartic acid, serine, threonine, alanine, histidine and glutamic acid) Tomato (see for example US6727411); corn with increased amino acid content (see for example WO05 / 077117); potato, corn with modified starch content Rocci and rice (see eg WO1997 / 044471 and US7317146); tomatoes, corn, grapes, alfalfa, apples, legumes and peas with altered flavonoid content (eg see WO00 / 04175); containing phenolic compounds Corn, rice, sorghum, cotton and soybean with modified amounts (eg see US2008 / 0235829); tomatoes and canola with increased vitamin A content (eg see US6797498, US7348167); vitamin E content Increased tomato, canola, soybean, wheat, sunflower, rice, corn, barley and rye (see for example US7348167, WO2004 / 058934); alfalfa, apple, bean, corn, grape, tomato and flavonoid content modified There are peas (see eg WO00 / 04175). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above-mentioned publications. Preferably, the plant is selected from soybeans, canola, tomatoes, rice and cereals (eg wheat, barley, rye and oats), most preferably selected from soybeans, canola, rice and wheat, barley.

  Rapeseed “Nexera (registered trademark) Canola” that produces unsaturated omega-9 fatty acids as a plant whose quality of the product has been modified by conventional breeding technology or genome breeding technology; soybean with reduced allergen content “Yumeminori”; rice for the purpose of changing to a good taste, for example, rice “Yumepirika” with a reduced amylose content is commercially available. Citrus with modified fruit characteristics (eg, fruit weight, aroma, juiciness and sugar content) is known (see Scientific Reports 7, 4721 2017).

  Plants with altered plant nutrient utilization are, for example, plants with enhanced nitrogen or phosphorus assimilation or metabolism. Plants having enhanced nitrogen assimilation ability and nitrogen utilization ability by genetic recombination techniques include, for example, canola, corn, wheat, sunflower, rice, tobacco, soybean, cotton, alfalfa, tomato, wheat, potato, sugar beet, sugar cane and Selected from rapeseed (see, for example, WO1995 / 009911, WO1997 / 030163, US6084153, US5955651 and US6864405). Plants with improved phosphorus uptake by genetic engineering techniques include, for example, alfalfa, barley, canola, corn, cotton, tomato, rapeseed, rice, soybean, sugar beet, sugarcane, sunflower, wheat and potato (e.g., US7417181, (See US2005 / 0137386). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above-mentioned publications. Preferably, the plant is selected from soybeans, tomatoes and cereals (eg wheat, barley, rye and oats), most preferably selected from soybeans, rice, corn and wheat.

  Plants whose fertility traits and the like have been modified by genetic recombination techniques include plants that have been given male sterility and fertility recovery traits. For example, maize and chicory that have been given male sterility by expressing a ribonuclease gene (barnase) derived from Bacillus amyloliquefaciens in cocoon tapetum cells; a DNA adenine methylase gene (dam) derived from E. coli Maize that has been given male sterility by introducing corn-derived alpha-amylase gene (zm-aa1) that gives male sterility traits and ms45 protein gene (ms45) that gives maternal recovery traits Corn with controlled fertility traits; canola with fertility-recovering function expressed by expressing a ribonuclease inhibitor protein gene (barstar) from Bacillus in tapetum cells of pupae; bacillus giving male sterility traits Ribonuclease gene derived from fungi (b There is a canola whose fertility trait is controlled by expressing a ribonuclease-inhibiting protein gene (barstar) derived from Bacillus that gives arnase) and a fertility recovery trait. Other plants to which fertility traits have been imparted by genetic engineering techniques include tomato, rice, mustard, wheat, soybean and sunflower (e.g., US6720481, US6281348, US5659124, US6399856, US7345222, US7230168, US6072102, EP1135982, WO2001). / 092544 and WO1996 / 040949). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above-mentioned publications. Preferably the plant is selected from corn, canola, soybean, tomatoes and cereals (eg wheat), most preferably from corn, canola, soybean, rice, wheat.

  Plants with abiotic stress tolerance are drought, high salinity, high light intensity, high UV irradiation, chemical contamination (eg high heavy metal concentration), low or high temperature, limited nutrients (ie nitrogen, phosphorus) Plants exhibiting increased resistance to abiotic stress conditions such as supply and collective stress (see, for example, WO 2000/004173, WO2007 / 131699, CA2521729 and US2008 / 0229448).

  Plants imparted with abiotic stress tolerance by genetic engineering techniques include, for example, rice, corn, soybean, sugarcane, alfalfa, wheat, tomato, potato, barley, rapeseed, legume, oat, sorghum, and tolerant to drought. Cotton (see for example WO2005 / 048693, WO2008 / 002480 and WO 2007/030001); corn, soybean, wheat, cotton, rice, rapeseed and alfalfa (see for example US4731499 and WO2007 / 112122) resistant to low temperatures; Examples include rice, cotton, potato, soybean, wheat, barley, rye, sorghum, alfalfa, grape, tomato, sunflower and tobacco (see, for example, US7256326, US7034139, WO / 2001/030990) that are resistant to high salinity. There is also a corn “DroughtGard (registered trademark)” (Monsanto product) into which a cold shock protein gene cspB of Bacillus subtilis has been introduced.

  Plants that have been imparted with abiotic stress tolerance by conventional breeding technology or genome breeding technology are, for example, corn having drought tolerance (Agrisure Artesian (registered trademark)) and Optimum (registered trademark). (Trademark) "AQUAmax (registered trademark)" has been developed under the trade name.

  Plants to which other characteristics are imparted include plants with modified maturation characteristics. Examples of alteration of maturation characteristics include delayed ripening, delayed softening and early maturation. Maturation characteristics have been modified by gene recombination technology, and plants have improved shelf life by introducing, for example, the S-adenosylmethion hydrolase gene (sam-K) derived from E. coli bacteriophage T3 for ethylene production of the plant hormone Melon and tomato; a gene lacking a part of the ACC synthase gene derived from tomato involved in ethylene production of plant hormones; an ACC deaminase gene derived from Pseudomonas chlororaphis that degrades ethylene precursor ACC; cell wall Shelving by introducing one or more of a tomato-derived polygalacturonase gene double-stranded RNA or a tomato-derived ACC oxidase gene involved in ethylene production that degrades pectin Improved tomato; of polygalacturonase gene derived from tomato There are tomatoes shelf-life by introducing a gene pg for generating heavy chain RNA was improved "FLAVR SAVR (TM)". Other plants whose maturation characteristics have been modified by gene recombination technology include, for example, tomatoes, melons, raspberries, strawberries, muskmelons, peppers and papayas whose ripening has been delayed (e.g., US 5767376, US7084321, US6107548, US5981831). , WO1995 / 035387, US5952546, US5512466, WO1997 / 001952, WO1992 / 008798 and Plant Cell. 1989, 53-63. See Plant Molecular Biology, 50, 2002). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above-mentioned publications. Preferably, the plants are fruits (eg tomatoes, vines, melons, papayas, bananas, peppers, raspberries and strawberries); nuclear fruits (eg cherries, apricots and peaches); berries (eg apples and berries) Pear); and citrus fruits (e.g., citron, lime, orange, pomelo, grapefruit, and mandarin), more preferably selected from tomato, melon, papaya, vine, apple, banana, orange and strawberry; Most preferred are tomato, melon and papaya.

  Plants to which other quality modifications have been imparted by genetic recombination technology, for example, introduce endogenous phytin by introducing a 3-phytase gene (phyA) derived from Aspergillus niger, a plant phytic acid degrading enzyme. Canola “Phytaseed® Canola” with enhanced acid degradation; dihydrodoflavonol-4-reductase gene from Petunia hybrida, an enzyme that produces the blue pigment delphinidin and its derivatives, and petunia, pansy (Viola wittrockiana), salvia (Salvia splendens), or carnations “Moondust ™”, “Moonshadow (Moonshadow)”, in which the flower color is controlled to be blue by introducing a flavonoid-3 ′, 5′-hydroxylase gene derived from carnation. Trademark) "," Moonshade (trademark) "," Moonlite (trademark) "," Moonaqua (trade) ”,“ Moonvista ™ ”,“ Moonique ™ ”,“ Moonpearl ™ ”,“ Moonberry ™ ”and“ Moonvelvet ™ ”; enzymes that produce the blue pigment delphinidin and its derivatives A rose whose flower color is controlled to be blue by introducing an anthocyanin-5-acyltransferase gene derived from a certain Torenia sp. And a flavonoid-3,5′-hydroxylase gene derived from pansy; modified cedar pollen Rice that is immunotolerant and alleviates pollen allergy by introducing the antigen protein gene (7crp); maize that has enhanced the degradation of endogenous phytic acid by introducing the black mold 3-phytase gene (phyA); A product that produces high-quality fibers with improved fiber micronaire, increased fiber strength, length uniformity and color. Down (see, for example, WO1996 / 26639, US7329802, US6472588 and WO2001 / 17333) there is.

  Examples of plants whose traits relating to plant growth and yield have been modified include plants with enhanced growth ability. Plants whose growth and yield traits have been modified by genetic recombination technology have been enhanced by introducing a gene (bbx32) that encodes a transcription factor that regulates the diurnal properties of Arabidopsis thaliana. Soybeans with high yields can be expected; introduction of a transcription factor gene (athb17) belonging to the homeodomain derived from Arabidopsis thaliana-14 zippers (HD-Zip) family class II HD-Zip II) increases the ear weight. As a result, corn with high yields has been developed.

  As a plant whose quality has been altered by genome editing technology, the zinc finger nuclease is used to lack the IPK1 gene encoding inositol-1,3,4,5,6-pentakisphosphate 2-kinase, an enzyme for phytic acid biosynthesis. Corn with reduced phytic acid content, "ZFN-12 maize"; by using crisper casnaine, the gene encoding polyphenol oxidase is deleted and browning resistance is conferred. Mushrooms (see, for example, Nature., Vol 532, 21 APRIL 2016).

  Plants whose quality has been altered by the new breeding technology can be used, for example, by introducing low polyphenole oxidase (enzyme causing browning) production gene sequence GEN-03 isolated from apples into new apple varieties using cisgenesis. , An apple "Arctic (registered trademark)" that reduces polyphenole oxidase expression and does not turn brown; an example of giving sapling the properties of GM rootstock, a cultivar improvement technology using grafted tomato rootstock that has salt tolerance The tomato (Physiol Plantarum, 124, 465-475 2005) which gave salt tolerance to the tomato of a non-transgenic panicle using this is mentioned.

  In rice, genes showing resistance to a large number of diseases, pests and abiotic stress are known, and the production of resistant varieties into which these genes have been introduced is thriving. Examples of genes showing disease resistance in rice and resistance to abiotic stress include BPH1, BPH2, BPH3, BPH4, BPH5, BPH6, BPH7, BPH8, BPH9, BPH10, BPH11, BPH12, BPH13, BPH14, BPH15, BPH17 , BPH18, BPH19, BPH20, BPH21, BPH22, BPH23, BPH24, BPH25, BPH26, BPH27, BPH28, BPH29, BPH32, qBPH-12, qBPHR-1, qBPHR-3, qBPHR-8, qBPHR-5-1qBPHR-5 -2 green planthopper resistance genes such as qBPHR-11-1 and qBPHR-11-2; white-spotted plant resistance such as WBPH1, WBPH2, WBPH3, WBPH4, WBPH5, WBPH6, OVC, qOVA-5-2, qOVA1-3, and qOVA5-1 Sexual varieties: Qsbph2b, Qsbph3, Qsbph3b, Qsbph3c, Qsbph3d, Qsbph4, Qsbph8, Qsbph11, Qsbph11d, Qsbph11e, Qsbph11f, Qsbph11g, Qsbph12H, GL, GL , GLH9, GLH10, GLH11, GLH12, GLH13, GRH1, GRH2, GRH3, GRH4, GRH5, Zlh1, Zlh2, Zlh3, qGRH-4, qGRH-2, qGRH-5, qGRH-6, qGRH-11, qGRH- Leafhopper resistance genes such as 3; Nikamei resistance genes such as SB; Pii, PI65, PIZT, PI24, PI29, PI25, Pi-jnw1, PB1, PIQ6, PID3, PI67, PITQ5, PITP, PITQ6, PLM2, PISE3, IPI, PISE1, PI157, PIQ4, PI21, PIA, PIB, PIK, PIKUR1, PIKUR2, PI3, PIF, PIZH, PIR4, PIR7, PI30, PI, PIGD2, PIG, PIGD3, PIGD1, PIZ, PI (, PI18, PIM , PI17, PI20, PI1, PI19, PI5, PISH, PI10, PI9, PI21, PI22, PI44, PI22, PI13, PII, PIB1, PIQ1, PIQ2, PIQ3, PIIS1, PII2, PI62, PI12, IPI3, PI14, PI15 , PI16, PIT, PI11, PI6, PI23, PI14, PI11, PIIS2, PIB2, PI12, PI39, PI40, PITA, PIR2-3, PIR9-2, PIR12-2, PIRF2-1, qRBR-2, qRBR-3 , PI27, PI28, PI26, PIGM, PI47, PI48, PI7, PI56, PI49, PI34, PIKG, PI38, PI32, PI31, PI46, PIX, PIXY, Pita3, PI41, PI42, PI2, PI36, PI37, PIKH, PIKM , PIKP, PI35, PIZ5, PIB2, PI43, PI50, PI51, PID1, PIY1, PIY2, PI55-2, PICO39, PI55-1, PIBH8, PIR7A, PIR7B, PID2, PI3 3, qBFR4-1, qBFR4-2, qRBR-2, qRBR-3, qRBR-8, qRBR-1-1, qRBR-1-3, qRBR-7-1, qRBR-7-2, qRBR-9- 1, blast resistance genes such as qRBR-9-2, qRBR-9-3, qRBR-1-2, qRBR-1-4; stripe wilt resistance genes such as STVA, STVB, Stvb-i; XA21D, XA, XA40, XA NM, XA8, XA33, XA34, XA35, XA36, XA37, XA7, XA3, XA25, XA28, XA29, XA30, XA31, XA32, XA38, XA39, XA11, XA16, XA17, XA18, XA17, XA18 XB20, XA14, XA2, XA12, XA1, XA K, XA A, XA H, XA10, XA23, XA22, XA24, XA21, SERRT13, XA4, XA5, XA13, etc .; blight resistance genes such as qSB-3, qSB-7, qSB-11, qSB-9-1; sesame leaf resistance genes such as CE; yellow dwarf disease resistance genes such as YDV; Black line dwarf disease resistance gene; high temperature climbing resistance gene such as Amy1A, Amy1C, Amy3A, Amy3B; low amylose gene such as dul3, qAC9.3, rsr1, Wx, and Wx1-1; AP01, SCM2, Sd1, etc. Lodging resistance gene ; Ear germination resistance genes such as Sdr4; low temperature resistance genes such as CTB1, CTB2, qLTG3-1; drought resistance genes such as Dro1; DEP1, Cn1a, GPS, SPIKE, PTB1, TAWAWA1, WFP, IPA1, GS3, GS5, GS6 , GL3.1, GW2, GW8, qGL3, qSS7, qSW5, etc. related to the number of seeds or seed form; genes that regulate day length responsiveness such as Hd1, Ghd8, DTH8; Genes: Lipoxygenase-deficient genes (reducing old rice odor) such as LOX3; genes related to amylopectin chain length such as Alk are known. Rice varieties in which one or more of these genes are simultaneously incorporated have been developed or marketed.

  For the above-mentioned plants, genetic recombination technology, conventional breeding technology, genome breeding technology, new breeding technology or genome editing technology are used, and abiotic stress resistance, disease resistance, weeding as described above. By crossing two or more plants with similar or different properties, such as drug resistance, pest resistance, growth and yield traits, modification of nutrient utilization, product quality modification, fertility traits, etc. Plants to which two or more properties of the parent line are added are also included.

Commercial plants that have been tolerated by two or more herbicides are, for example, cotton “GlyTol ™ LibertyLink ™” and “GlyTol ™ LibertyLink ™” that are resistant to glyphosate and glufosinate; Corn “Roundup Ready ™ LibertyLink ™ Maize” with tolerance and glufosinate tolerance; Soybean “Enlist ™ Soybean” with glufosinate tolerance and 2,4-D tolerance; Soybean “Genuity with glyphosate tolerance and dicamba tolerance” (R) Roundup Ready (TM) 2 Xtend (TM); Glyphosate and ALS inhibitor resistant corn and soybean "OptimumGAT (TM)"; three herbicides: glyphosate, glufosinate and 2,4-D Transgenic soybeans that are resistant "Enlist E3 ™" and "Enlist ™ Roundup Ready 2 Yield ™"; glyphosa Corn “Enlist ™ Roundup Ready® Corn 2” that is resistant to herbicides, 2,4-D and allyloxyphenoxypropionic acid (FOPs); glyphosate, 2,4-D and allyloxyphenoxy Corn “Enlist ™ Roundup Ready® Corn 2” resistant to propionic acid (FOPs) herbicides; Cotton “Bollgard II® XtendFlex ™ Cotton resistant to dicamba, glyphosate and glufosinate "Enlist ™ Cotton", which is resistant to three glyphosate, glufosinate and 2,4-D herbicides; three herbicides, glyphosate, glufosinate and HPPD herbicides (eg, isoxaflutol) There is soybean "Liberty Link (registered trademark) GT27 (trademark)" which is resistant. In addition, cotton resistant to both glufosinate and 2,4-D; cotton resistant to both glufosinate and dicamba; corn resistant to both glyphosate and 2,4-D; glyphosate and HPPD herbicide Soybeans that are resistant to both; glyphosate, glufosinate, 2,4-D, corn resistant to allyloxyphenoxypropionic acid (FOPs) and cyclohexadione (DIMs) herbicides have also been developed.
Commercial plants conferred with herbicide resistance and pest resistance include, for example, corn “YieldGard Roundup Ready” and “YieldGard Roundup Ready 2” with glyphosate resistance and resistance to corn borer; glufosinate resistance and corn borer resistance Corn "Agrisure CB / LL" with glyphosate resistance; "Yield Gard VT Root worm / RR2" maize with glyphosate and corn rootworm resistance; Corn with glyphosate resistance and resistance to corn rootworm and corn borer “Yield Gard VT Triple”; corn “Herculex I” with glufosinate resistance and corn lepidopteran pest resistance (Cry1F) (eg, resistance to western bean cut worms, corn borers, black cut worms and fall army worms) Glyphoser Corn “YieldGard Corn Rootworm / Roundup Ready 2” with tolerance and corn rootworm resistance; glufosinate resistance and corn crustacean pest resistance (Cry3A) (eg Western corn rootworm, Northern corn rootworm and Mexican corn root) Maize "Agrisure GT / RW" with resistance to worms; resistance to glufosinate and corn crustacean pest resistance (Cry34 / 35Ab1) (eg resistance to western corn rootworm, northern corn rootworm and Mexican corn rootworm) "Herculex RW"; glyphosate resistance and corn rootworm resistance; "Yield Gard VT Root worm / RR2"; dicamba resistance, glyphosate resistance, glyphosate resistance and cotton lepidopterous insect resistance ( Example If there is a cotton "Bollgard 3 (R) XtendFlex (registered trademark)" having a bollworm acids and tobacco budworm, resistance to such armyworm acids).

  Commercial plants to which disease resistance and pest resistance have been imparted are, for example, potato “Hi-Lite NewLeaf (trademark) Y Potato, to which Potato virus Y resistance and pest resistance have been imparted. "NewLeaf (TM) Y Russet Burbank Potato" and "Shepody NewLeaf (TM) Y Potato"; Potato leafroll virus-resistant and pest-resistant potatoes "NewLeaf (TM) Plus Russet Burbank Potato ”.

  Commercial plants conferred with herbicide tolerance and product quality-modifying properties are, for example, canola “InVigor ™ Canola” imparted with glufosinate tolerance and fertility traits; glufosinate tolerance and fertility traits Maize “InVigor ™ Maize”; soybean “Vistive Gold ™” with modified glyphosate tolerance and oil content.

  Examples of commercial plants with more than two traits include glyphosate tolerance, glufosinate tolerance and lepidopteran insect resistance (Cry1F) (ie against Western bean cut worms, corn borers, black cut worms and fall army worms) Corn "Herculex I / Roundup Ready 2" with resistance); Corn "YieldGard Plus / Roundup Ready 2" with glyphosate resistance, corn rootworm resistance and corn borer resistance; Glyphosate resistance, glufosinate resistance and corn borer resistance Maize "Agrisure GT / CB / LL" with glufosinate resistance, Lepidoptera pest resistance (Cry1F) and Coleoptera pest resistance (Cry34 / 35Ab1) (ie Western bean cut worm, corn borer, black cut worm and fall army) Lepidoptera damage such as worms And corn "Herculex Xtra" with resistance to Coleoptera such as Western corn rootworm, Northern corn rootworm, Mexican corn rootworm, etc .; glufosinate resistance, corn borer resistance (Cry1Ab) and resistance to Coleoptera (Cry3A) ) (Ie resistance to Western corn rootworm, Northern corn rootworm and Mexican corn rootworm) “Agrisure CB / LL / RW”; glyphosate resistance, corn borer resistance (Cry1Ab) and Coleoptera pest resistance ( Cry3A) (ie resistance to Western corn rootworm, Northern corn rootworm and Mexican corn rootworm) “Agrisure ™ 3000GT”; resistant to glyphosate, corn rootworm and European corn borer Corn with high resistance and high lysine trait “Mavera high-value corn”; harms the ground such as European corn borer, Southwestern corn borer, corn ear worm, fall army worm, black cut worm and / or western bean worm Maize "Optimum (R) Leptra (TM)" with resistance to pests; glyphosate resistance, glyphosate resistance, frogeye leaf spot resistance, Sudden Death Syndrome resistance, soybean stem Resistance to southern stem canker, resistance to Phytophthora root rot, resistance to southern root-knot nematode, resistance to Sclerotinia white mold, brown defoliation of soybean (brown) Stem rot resistant, soy cyst nematode (soybea Soybean “Credenz® soybean” with improved resistance to n cyst nematode, improvement of iron deficiency chlorosis, and modification of chloride sensitivity; confer multiple herbicide resistance and pest resistance Cotton “Stoneville (registered trademark) Cotton” (ST5517GLTP, ST4848GLT, ST4949GLT, ST5020GLT, ST5115GLT, ST6182GLT, ST4747GLB2, ST4946GLB2, ST6448GLB2, ST6448GLB2 to cope with the occurrence of weeds and pests in the field in each region There are two varieties).

The plants that are commercially available or developed are listed below (A1 to A550). The parentheses mean [plant name, Event Name, Event code, trademark name (Tradename)]. NA means “no information” or “unavailable information”. Many of these plants are registered databases (GM APPROVAL DATABASE) in the electronic information site (http://www.isaaa.org/) of the INTERNATINAL SERVICE for the ACQUISITION of AGRI-BIOTECH APPLICATIONS, ISAAA. It is listed.
A1: [Alfalfa, J101, MON-00101-8, Roundup Ready (trademark) Alfalfa], A2: [Alfalfa, J101 x J163, MON-00101-8 x MON-00163-7, Roundup Ready (trademark) Alfalfa], A3: [Alfalfa, J163, MON-00163-7, Roundup Ready (TM) Alfalfa], A4: [Alfalfa, KK179, MON-00179-5, HarvXtra (TM)], A5: [Alfalfa, KK179 x J101, MON -00179-5 x MON-00101-8], A6: [Apple, GD743, OKA-NB001-8, Arctic (TM) "Golden Delicious" Apple], A7: [Apple, GS784, OKA-NB002-9, Arctic (Trademark)], A8: [apple, NF872, OKA-NB003-1, Arctic (trademark) Fuji Apple], A9: [Argentina canola, 23-18-17 (Event 18), CGN-89111-8, Laurical ( Trademark) Canola], A10: [Argentina Canola, 23-198 (Event 23), CGN-89465-2, Laurical (TM) Canola], A11: [Argentina Canola, 61061, DP-061061-7], A12: [ Argentina Canola, 73396, DP-073496-4, Optimum (Register Gly canola], A13: [Argentina canola, 73396 x RF3, DP-073496-4 x ACS-BN003-6, NA], A14: [Argentina canola, GT200 (RT200), MON-89249-2, Roundup Ready (Trademark) Canola], A15: [Argentina Canola, GT73 (RT73), MON-00073-7, Roundup Ready (Trademark) Canola], A16: [Argentina Canola, HCN10 (Topas 19/2), NA, Liberty Link ( Trademark) Independence (trademark)], A17: [Argentina canola, HCN28 (T45), ACS-BN008-2, InVigor (TM) Canola], A18: [Argentina canola, HCN28 x MON88302, ACS-BN008-2 x MON- 88302-9, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) Canola], A19: [Argentina Canola, HCN92 (Topas 19/2), ACS-BN007-1, Liberty Link (TM) Innovator (TM) )], A20: [Argentina canola, HCN92 x MON88302, ACS-BN007-1 x MON-88302-9, Liberty Link (TM) Innovator (TM) x TruFlex (TM) ) Roundup Ready (TM) Canola], A21: [Argentina Canola, MON88302, MON-88302-9, TruFlex (TM) Roundup Ready (TM) Canola], A22: [Argentina Canola, MON88302 x MS8 x RF3, MON- 88302-9 x ACS-BN005-8 x ACS-BN003-6, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) Canola], A23: [Argentina canola, MON88302 x RF3, MON-88302-9 x ACS-BN003-6, NA], A24: [Argentina canola, MPS961, NA, Phytaseed (TM) Canola], A25: [Argentina canola, MPS962, NA, Phytaseed (TM) Canola], A26: [Argentina canola, MPS963 , NA, Phytaseed (TM) Canola], A27: [Argentina Canola, MPS964, NA, Phytaseed (TM) Canola], A28: [Argentina Canola, MPS965, NA, Phytaseed (TM) Canola], A29: [Argentina Canola, MS1 (B91-4), ACS-BN004-7, InVigor ™ Canola], A30: [Al Nchin canola, MS1 x MON88302, ACS-BN004-7 x MON-88302-9, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) Canola], A31: [Argentina canola, MS1 x RF1 (PGS1), ACS-BN004-7 x ACS-BN001-4, InVigor ™ Canola], A32: [Argentina canola, MS1 x RF1 (PGS2), ACS-BN004-7 x ACS-BN002-5, InVigor ™ Canola] , A33: [Argentina canola, MS1 x RF3, ACS-BN004-7 x ACS-BN003-6, InVigor (TM) Canola], A34: [Argentina canola, MS8, ACS-BN005-8, InVigor (TM) Canola] , A35: [Argentina canola, MS8 x MON88302, ACS-BN005-8 x MON-88302-9, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) Canola], A36: [Argentina canola, MS8 x RF3 , ACS-BN005-8 x ACS-BN003-6, InVigor ™ Canola], A37: [Argentina canola, MS8 x RF3 x GT73 (RT73), ACS-BN005-8 x ACS-BN003-6 x MON-00073 -7, NA], A38: [A Zentin canola, OXY-235, ACS-BN011-5, Navigator ™ Canola], A39: [Argentina canola, PHY14, NA, NA], A40: [Argentina canola, PHY23, NA, NA], A41: [Argentina Canola, PHY35, NA, NA], A42: [Argentina canola, PHY36, NA, NA], A43: [Argentina canola, RF1 (B93-101), ACS-BN001-4, InVigor ™ Canola], A44: [Argentina canola, RF1 x MON88302, CS-BN001-4 x MON-88302-9, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) Canola], A45: [Argentina canola, RF2 (B94-2) , ACS-BN002-5, InVigor (TM) Canola], A46: [Argentina canola, RF2 x MON88302, ACS-BN002-5 x MON-88302-9, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) ) Canola], A47: [Argentina canola, RF3, ACS-BN003-6, InVigor (TM) Canola], A48: [beans, EMBRAPA5.1, EMB-PV051-1, NA], A 49: [Carnation, 11 (7442), FLO-07442-4, Moondust (trademark)], A50: [Carnation, 11363 (1363A), FLO-11363-1, Moonshadow (trademark)], A51: [Carnation, 1226A (11226), FLO-11226-8, Moonshade (trademark)], A52: [carnation, 123.2.2 (40619), FLO-40619-7, Moonshade (trademark)], A53: [carnation, 123.2.38 (40644) ), FLO-40644-4, Moonlite ™], A54: [Carnation, 123.8.12, FLO-40689-6, Moonaqua ™], A55: [Carnation, 123.8.8 (40685), FLO-40685 -1, Moonvista (trademark)], A56: [Carnation, 1351A (11351), FLO-11351-7, Moonshade (trademark)], A57: [Carnation, 1400A (11400), FLO-11400-2, Moonshade (trademark) )], A58: [Carnation, 15, FLO-00015-2, Moondust (TM)], A59: [Carnation, 16, FLO-00016-3, Moondust (TM)], A60: [Carnation, 19907, IFD- 19907-9, Moonique (trademark)], A61: [Car , 25947, IFD-25947-1, Moonpearl (trademark)], A62: [carnation, 25958, IFD-25958-3, Moonberry (trademark)], A63: [carnation, 26407, IFD-26407-2, Moonvelvet ( Trademark)], A64: [Carnation, 4, FLO-00004-9, Moondust (Trademark)], A65: [Carnation, 66, FLO-00066-8, NA] A66: [Carnation, 959A (11959), FLO- 11959-3, Moonshade (trademark)], A67: [Carnation, 988A (11988), FLO-11988-7, Moonshade (trademark)], A68: [Chicory, RM3-3, NA, SeedLink (trademark)], A69 : [Chicory, RM3-4, NA, SeedLink (trademark)], A70: [Chicory, RM3-6, NA, SeedLink (trademark)], A71: [Cotton, 19-51a, DD-01951A-7, NA] , A72: [Cotton, 281-24-236, DAS-24236-5, NA], A73: [Cotton, 281-24-236 x 3006-210-23 (MX B-13), DAS-24236-5 x DAS-21023-5, WideStrike ™ Cotton], A74: [Cotton, 281-24-236 x 3006-210-23 x COT102 x 81910, DAS-24236-5 x DAS-21023-5 x SYN-IR1 02-7 x DAS-81910-7, NA], A75: [Cotton, 3006-210-23, DAS-21023-5, NA], A76: [Cotton, 3006-210-23 x 281-24-236 x MON1445, DAS-21023-5 x DAS-24236-5 x MON-01445-2, WideStrike ™ RoundupReady ™ Cotton], A77: [Cotton, 3006-210-23 x 281-24-236 x MON88913, DAS-21023-5 x DAS-24236-5 x NAMON-88913-8, Widestrike (TM) RoundupReadyFlex (TM) Cotton], A78: [Cotton, 3006-210-23 x 281-24-236 x MON88913 x COT102, DAS-21023-5 x DAS-24236-5 x MON-88913-8 x SYN-IR102-7, Widestrike (TM) RoundupReadyFlex (TM) Cotton], A79: [Cotton, 31707, NA, BXN (TM) PlusBollgard ( Trademark) Cotton], A80: [Cotton, 31803, NA, BXN (TM) PlusBollgard (TM) Cotton], A81: [Cotton, 31807 x 31808, NA, NA], A82: [Cotton, 31807, NA, BXN ( Trademark) PlusBollgard (TM) Cotton], A83: [Cotton, 31808, NA, BXN (TM) PlusBollgard (TM) Cotton], A84: [Cotton, 42317, NA, BXN (TM) PlusBo llgard (trademark) Cotton], A85: [Cotton, 81910, DAS-81910-7, NA], A86: [Cotton, BNLA-601, NA, NA], A87: [Cotton, BXN10211 (10211), BXN-10211 -9, NA], A88: [Cotton, BXN10215 (10215), BXN-10215-4NA, BXN (trademark) Cotton], A89: [Cotton, BXN102 cotton 22 (10222), BXN-10222-2, BXN (trademark) ) Cotton], A90: [Cotton, BXN10224 (10224), BXN-10224-4NA, BXN (trademark) Cotton], A91: [Cotton, COT102 (IR102), SYN-IR102-7, VIPCOT (trademark) Cotton], A92: [Cotton, COT102 x COT67B, SYN-IR102-7NA x NASYN-IR67B-1, VIPCOT (trademark) Cotton], A93: [Cotton, COT102 x COT67B x MON88913, SYN-IR102-7NA x NASYN-IR67B-1NA x NAMON-88913-8, VIPCOT ™ RoundupReadyFle x ™ Cotton], A94: [Cotton, COT102 x MON15985, SYN-IR102-7NA x NAMON-15985-7, Bollgard ™ III], A95: [Cotton, COT102 x MON15985 x MON88913, SYN-IR102-7NA x NAMON-15985-7NA x NAMON-88913-8, Bollgard (R) III x Roun dupReady (TM) Flex (TM)], A96: [Cotton, COT102 x MON15985 x MON88913 x MON88701, SYN-IR102-7NA x NAMON-15985-7NA x NAMON-88913-8NA x NAMONNA88701-3, NA], A97 : [Cotton, COT67B (IR67B), SYN-IR67B-1, NA], A98: [Cotton, Event1, NA, JK1], A99: [Cotton, GFMCry1A, GTL-GFM311-7, NA], A100: [Cotton , GHB119, BCS-GH005-8, NA], A101: [Cotton, GHB614, BCS-GH002-5, GlyTol (trademark)], A102: [Cotton, GHB614 x LLCotton25, BCS-GH002-5NA x NAACS-GH001- 3, GlyTol (trademark) LibertyLink (trademark)], A103: [Cotton, GHB614 x LLCotton25 x MON15985, BCS-GH002-5NA x NAACS-GH001-3NA x NAMON-15985-7, NA], A104: [Cotton, GHB614 x MON15985, BCS-GH002-5NA x NAMON-15985, NA], A105: [Cotton, GHB614 x T304-40 x GHB119, BCS-GH002-5NA x NABCS-GH004-7NA x NABCS-GH005-8, Glytol (Trademark) ) X Twinlink (trademark)], A106: [Cotton, GHB614 x T304-40 x GHB119 x COT102, BCS-GH002-5NA x NABCS-GH004-7NA x NABCS- GH005-8NA x NASYN-IR102-7, Glytol (trademark) x Twinlink (trademark) x VIPCOT (trademark) Cotton], A107: [Cotton, GK12, NA, NA], A108: [Cotton, LLCotton25, ACS-GH001- 3NA, Fiberma x (trademark) LibertyLink (trademark)], A109: [Cotton, LLCotton25 x MON15985, ACS-GH001-3NA x NAMON-15985-7, Fiberma x (trademark) LibertyLink (trademark) BollgardII (trademark)], A110 : [Cotton, MLS9124, NA, NA], A111: [Cotton, MON1076, MON-89924-2, Bollgard (trademark) Cotton], A112: [Cotton, MON1445, MON-01445-2, RoundupReady (trademark) Cotton] A113: [Cotton, MON15985, MON-15985-7, BollgardII (trademark) Cotton], A114: [Cotton, MON15985 x MON1445, MON-15985-7NA x NAMON-01445-2, RoundupReady (trademark) BollgardII (trademark) Cotton], A115: [Cotton, MON1698, MON-89383-1, RoundupReady (trademark) Cotton], A116: [Cotton, MON531, MON-00531-6, Bollgard (trademark) Cotton, Ingard (trademark)], A117: [Cotton, MON531 x MON1445, MON-0531 -6NA x NAMON-01445-2, RoundupReady (TM) Bollgard (TM) Cotton], A118: [Cotton, MON757, MON-00757-7, Bollgard (TM) Cotton], A119: [Cotton, MON88701, MONNA88701-3 , NA], A120: [Cotton, MON88701 x MON88913, MONNA88701-3NA x NAMON-88913-8, NA], A121: [Cotton, MON88701 x MON88913 x MON15985, MONNA88701-3NA x NAMON-88913-8NA x NAMON-15985 -7, Bollgard II® XtendFlex ™ Cotton], A122: [Cotton, MON88913, MON-88913-8, RoundupReady ™ Flex ™ Cotton], A123: [Cotton, MON88913 x MON15985, MON -88913-8NA x NAMON-15985-7, RoundupReady (TM) Flex (TM) BollgardII (TM) Cotton], A124: [Cotton, NgweChi6Bt, NA, NgweChi6Bt], A125: [Cotton, SGK321, NA, NA], A126: [Cotton, T303-3, BCS-GH003-6, NA], A127: [Cotton, T304-40, BCS-GH004-7, NA], A128: [Cotton, T304-40 x GHB119, BCS-GH004 -7NA x NABCS-GH005-8, TwinLink ™ Cotton], A129: Over ping bentgrass, ASR368, SMG-36800-2,
NA], A130: [Eggles, BtBrinjalEventEE1, BtBrinjalEventEE1, BARIBtBegun-1, -2, -3and-4], A131: [eucalyptus, H421, H421, GMEucalyptus], A132: [Ama, FP967 (CDCTriffid), CDC-FL001 -2, CDCTriffidFlax], A133: [Lentil, RH44, RH44, Clearfield ™ lentil], A134: [Corn, 32138, DP-32138-132138, 2138SPTmaintainer], A135: [Corn, 3272, SYN-E3272- 5, Enogen (trademark)], A136: [corn, 3272 x Bt11, SYN-E3272-5 x SYN-BT011-1, NA], A137: [corn, 3272 x Bt11 x GA21, SYN-E3272-5 x SYN -BT011-1 x MON-00021-9, NA], A138: [Corn, 3272 x Bt11 x MIR604, SYN-E3272-5 x SYN-BT011-1 x SYN-IR604-5, NA], A139: [Corn , 3272 x BT11 x MIR604 x GA21, SYN-E3272-5 x SYN-BT011-1 x SYN-IR604-5 x MON-00021-9, NA], A140: [corn, 3272 x Bt11 x MIR604 x TC1507 x 5307 x GA21, SYN-E3272-5 x SYN-BT011-1 x SYN-IR604-5 x DAS-01507-1 x SYN-05307-1 x MON-00021-9, NA], A141: [ Corn, 3272 x GA21, SYN-E3272-5 x MON-00021-9, NA], A142: [Corn, 3272 x MIR604, SYN-E3272-5 x SYN-IR604-5, NA], A143: [Corn, 3272 x MIR604 x GA21, SYN-E3272-5 x SYN-IR604-5 x MON-00021-9, NA], A144: corn, 33121, DP-033121-3, NA], A145: [corn, 4114, DP -004114-3, NA], A146: [corn, 5307, SYN-05307-1, Agrisure® Duracade ™], A147: [corn, 5307 x GA21, SYN-05307-1 x MON-00021 -9, NA], A148: [Corn, 5307 x MIR604 x Bt11 x TC1507 x GA21, SYN-05307-1 x SYN-IR604-5 x SYN-BT011-1 x DAS-01507-1 x MON-00021-9 , Agrisure® Duracade ™ 5122], A149: [corn, 5307 x MIR604 x Bt11 x TC1507 x GA21 x MIR162, SYN-05307-1 x SYN-IR604-5 x SYN-BT011-1 x DAS- 01507-1 x MON-00021-9 x SYN-IR162-4, Agrisure (R) Duracade (TM) 5222], A150: [Corn, 59122, DAS-59122-7, Hercule x (Trademark) ) RW], A151: [corn, 59122 x DAS40278, DAS-59122-7 x DAS-40278-9, NA], A152: [corn, 59122 x GA21, DAS-59122-7 x MON-00021-9, NA ], A153: [Corn, 59122 x MIR604, DAS-59122-7 x SYN-IR604-5, NA], A154: [Corn, 59122 x MIR604 x GA21, DAS-59122-7 x SYN-IR604-5 x MON -00021-9, NA], A155: [corn, 59122 x MIR604 x TC1507, DAS-59122-7 x SYN-IR604-5 x DAS-01507-1, NA], A156: [corn, 59122 x MIR604 x TC1507 x GA21, DAS-59122-7 x SYN-IR604-5 x DAS-01507-1 x MON-00021-9, NA], A157: [Corn, 59122 x MON810, DAS-59122-7 x MON-00810-6 , NA], A158: [corn, 59122 x MON810 x MIR604, DAS-59122-7 x MON-00810-6 x SYN-IR604-5, NA], A159: [corn, 59122 x MON810 x NK603, DAS-59122 -7 x MON-00810-6 x MON-00603-6, NA], A160: [Corn, 59122 x MON810 x NK603 x MIR604, DAS-59122-7 x MON-00810-6 x MON-00603-6 x SYN -IR604-5, NA], A161: [G Sorghum, 59122 x MON88017, DAS-59122-7 x MON-88017-3, NA], A162: [Corn, 59122 x MON88017 x DAS40278, DAS-59122-7 x MON-88017-3 x DAS-40278-9, NA], A163: [corn, 59122 x NK603, DAS-59122-7 x MON-00603-6, Herculex ™ RWRoundupReady ™ 2], A164: [corn, 59122 x NK603 x MIR604, DAS-59122- 7 x MON-00603-6 x SYN-IR604-5, NA], A165: [corn, 59122 x TC1507 x GA21, DAS-59122-7 x DAS-01507-1 x MON-00021-9, NA], A166 : [Corn, 676, PH-000676-7, NA], A167: [Corn, 678, PH-000678-9, NA], A168: [Corn, 680, PH-000680-2, NA], A169: [ Corn, 98140, DP-098140-6, Optimum (TM) GAT (TM)], A170: [Maize, 98140 x 59122, DP-098140-6 x DAS-59122-7, NA], A171: [Corn, 98140 x TC1507, DP-098140-6 x DAS-01507-1, NA], A172: [Corn, 98140 x TC1507 x 59122, DP-098140-6 x DAS-01507-1 x DAS-59122- 7, NA], A173: [corn, Bt10, NA, Bt10], A174: [corn, Bt11 (X4334CBR, X4734CBR), SYN-BT011-1, Agrisure ™ CB / LL], A175: [corn , Bt11 x 5307, SYN-BT011-1 x SYN-05307-1, NA], A176: [Corn, Bt11 x 5307 x GA21, SYN-BT011-1 x SYN-05307-1 x MON-00021-9, NA ], A177: [Corn, Bt11 x 59122, SYN-BT011-1 x DAS-59122-7, NA], A178: [Corn, Bt11 x 59122 x GA21, SYN-BT011-1 x DAS-59122-7 x MON -00021-9, NA], A179: [corn, Bt11 x 59122 x MIR604, SYN-BT011-1 x DAS-59122-7 x SYN-IR604-5, NA], A180: [corn, Bt11 x 59122 x MIR604 x GA21, SYN-BT011-1 x DAS-59122-7 x SYN-IR604-5 x MON-00021-9, NA], A181: [Corn, Bt11 x 59122 x MIR604 x TC1507, SYN-BT011-1 x DAS -59122-7 x SYN-IR604-5 x DAS-01507-1, NA], A182: [Corn, BT11 x 59122 x MIR604 x TC1507 x GA21, SYN-BT011-1 x DAS-59122-7 x SYN-IR604 -5 x DAS-01507-1 x MON-00021-9, Agr isure® 3122], A183: [corn, Bt11 x 59122 x TC1507, SYN-BT011-1 x DAS-59122-7 x DAS-01507-1, NA], A184: [corn, Bt11 x 59122 x TC1507 x GA21, SYN-BT011-1 x DAS-59122-7 x DAS-01507-1 x MON-00021-9, NA], A185: [Corn, Bt11 x GA21, SYN-BT011-1 x MON-00021-9 , Agrisure ™ GT / CB / LL], A186: [corn, Bt11 x MIR162, SYN-BT011-1 x SYN-IR162-4, Agrisure® Viptera ™ 2100], A187: [corn, Bt11 x MIR162 x 5307, SYN-BT011-1 x SYN-IR162-4 x SYN-05307-1, NA], A188: [Corn, Bt11 x MIR162 x 5307 x GA21, SYN-BT011-1 x SYN-IR162- 4 x SYN-05307-1 x MON-00021-9, NA], A189: [Maize, Bt11 x MIR162 x GA21, SYN-BT011-1 x SYN-IR162-4 x MON-00021-9, Agrisure (registered trademark) ) Viptera (TM) 3110], A190: [corn, BT11 x MIR162 x MIR604, SYN-BT011-1 x SYN-IR162-4 x SYN-IR604-5, Agrisure (R) Viptera (TM) 3100], A191 : [Tow Rokosi, BT11 x MIR162 x MIR604 x 5307, SYN-BT011-1 x SYN-IR162-4 x SYN-IR604-5 x SYN-05307-1, NA], A192: [Corn, Bt11 x MIR162 x MIR604 x 5307 x GA21, SYN-BT011-1 x SYN-IR162-4 x SYN-IR604-5 x SYN-05307-1 x MON-00021-9, NA], A193: [corn, Bt11 x MIR162 x MIR604 x GA21, SYN- BT011-1 x SYN-IR162-4 x SYN-IR604-5 x MON-00021-9, Agrisure (R) Viptera (TM) 3111, Agrisure (R) Viptera (TM) 4], A194: [corn, Bt11 x MIR162 x MIR604 x MON89034 x 5307 x GA21, SYN-BT011-1 x SYN-IR162-4 x SYN-IR604-5 x MON-89034-3 x SYN-05307-1 x MON-00021-9, NA] , A195: [corn, BT11 x MIR162 x MIR604 x TC1507, SYN-BT011-1 x SYN-IR162-4 x SYN-IR604-5 x DAS-01507-1, NA], A196: [corn, BT11 x MIR162 x MIR604 x TC1507 x 5307, SYN-BT011-1 x SYN-IR162-4 x SYN-IR604-5 x DAS-01507-1 x SYN-05307-1, NA], A197: [Corn, Bt11 x MIR162 x MIR604 x TC1507 x GA21, SYN-BT011-1 x SYN-IR162-4 x SY N-IR604-5 x DAS-01507-1 x MON-00021-9, NA], A198: [Corn, Bt11 x MIR162 x MON89034, SYN-BT011-1 x SYN-IR162-4 x MON-89034-3, NA], A199: [corn, Bt11 x MIR162 x MON89034 x GA21, SYN-BT011-1 x SYN-IR162-4 x MON-89034-3 x MON-00021-9, NA], A200: [corn, Bt11 x MIR162 x TC1507, SYN-BT011-1 x SYN-IR162-4 x DAS-01507-1, NA], A201: [Corn, Bt11 x MIR162 x TC1507 x 5307, SYN-BT011-1 x SYN-IR162-4 x DAS-01507-1 x SYN-05307-1, NA], A202: [Corn, Bt11 x MIR162 x TC1507 x 5307 x GA21, SYN-BT011-1 x SYN-IR162-4 x DAS-01507-1 x SYN- 05307-1 x MON-00021-9, NA], A203: [Corn, Bt11 x MIR162 x TC1507 x GA21, SYN-BT011-1 x SYN-IR162-4 x DAS-01507-1 x MON-00021-9, Agrisure ™ Viptera3220], A204: [corn, Bt11 x MIR604, SYN-BT011-1 x SYN-IR604-5, Agrisure ™ CB / LL / RW], A205: [corn, Bt11 x MIR604 x 5307, SYN-BT011-1 x SYN-IR604-5 x SYN-05307-1, NA], A20 6: [Corn, Bt11 x MIR604 x 5307 x GA21, SYN-BT011-1 x SYN-IR604-5 x SYN-05307-1 x MON-00021-9, NA], A207: [Corn, BT11 x MIR604 x GA21 , SYN-BT011-1 x SYN-IR604-5 x MON-00021-9, Agrisure ™ 3000GT], A208: [corn, Bt11 x MIR604 x TC1507, SYN-BT011-1 x SYN-IR604-5 x DAS -01507-1, NA], A209: [Corn, Bt11 x MIR604 x TC1507 x 5307, SYN-BT011-1 x SYN-IR604-5 x DAS-01507-1 x SYN-05307-1, NA], A210: [Corn, Bt11 x MIR604 x TC1507 x GA21, SYN-BT011-1 x SYN-IR604-5 x DAS-01507-1 x MON-00021-9, NA], A211: [Corn, Bt11 x MON89034, SYN-BT011 -1 x MON-89034-3, NA], A212: [Corn, Bt11 x MON89034 x GA21, SYN-BT011-1 x MON-89034-3 x MON-00021-9, NA], A213: [Corn, Bt11 x TC1507, SYN-BT011-1 x DAS-01507-1, NA], A214: [Corn, Bt11 x TC1507 x 5307, SYN-BT011-1 x DAS-01507-1 x SYN-05307-1, NA], A215: [Corn, Bt11 x TC1507 x 5307 x GA21, SYN-BT011-1 x DAS-01507-1 x SYN-05307-1 x MON-00021-9, NA], A216: [Corn, Bt11 x TC1507 x GA21, SYN-BT011-1 x DAS-01507 -1 x MON-00021-9, NA], A217: [corn, Bt176 (176), SYN-EV176-9, NaturGardKnockOut (TM), Maximizer (TM)], A218: [corn, BVLA430101, NA, NA], A219: [corn, CBH-351, ACS-ZM004-3, Starlink ™ Maize], A220: [corn, DAS40278, DAS-40278-9, Enlist ™ Maize], A221: [corn, DAS40278 x NK603, DAS-40278-9 x MON-00603-6, NA], A222: [Maize, DBT418, DKB-89614-9, Bt X tra ™ Maize], A223: [Maize, DLL25 (B16) , DKB-89790-5, NA], A224: [corn, GA21, MON-00021-9, RoundupReady (TM) Maize, Agrisure (TM) GT], A225: [corn, GA21 x MON810, MON-00021-9 x MON-00810-6, RoundupReady (TM) YieldGard (TM) maize], A226: [corn, GA21 x T25, MON-00021-9 x ACS- ZM003-2, NA], A227: [corn, HCEM485, HCEM485, NA], A228: [corn, LY038, REN-00038-3, Mavera ™ Maize], A229: [corn, LY038 x MON810, REN- 00038-3 x MON-00810-6, Mavera ™ YieldGard ™ Maize], A230: [corn, MIR162, SYN-IR162-4, Agrisure ™ Viptera], A231: [corn, MIR162 x 5307, SYN-IR162-4 x SYN-05307-1, NA], A232: [Corn, MIR162 x 5307 x GA21, SYN-IR162-4 x SYN-05307-1 x MON-00021-9, NA], A233: [ Corn, MIR162 x GA21, SYN-IR162-4 x MON-00021-9, NA], A234: [corn, MIR162 x MIR604, SYN-IR162-4 x SYN-IR604-5, NA], A235: [corn, MIR162 x MIR604 x 5307, SYN-IR162-4 x SYN-IR604-5 x SYN-05307-1, NA], A236: [Corn, MIR162 x MIR604 x 5307 x GA21, SYN-IR162-4 x SYN-IR604- 5 x SYN-05307-1 x MON-00021-9, NA], A237: [Corn, MIR162 x MIR604 x GA21, SYN-IR162-4 x SYN-IR604-5 x MON-0002 1-9, NA], A238: [Corn, MIR162 x MIR604 x TC1507 x 5307, SYN-IR162-4 x SYN-IR604-5 x DAS-01507-1 x SYN-05307-1, NA], A239: [ Corn, MIR162 x MIR604 x TC1507 x 5307 x GA21, SYN-IR162-4 x SYN-IR604-5 x DAS-01507-1 x SYN-05307-1 x MON-00021-9, NA], A240: [corn, MIR162 x MIR604 x TC1507 x GA21, SYN-IR162-4 x SYN-IR604-5 x DAS-01507-1 x MON-00021-9, NA], A241: [Corn, MIR162 x MON89034, SYN-IR162-4 x MON-89034-3, NA], A242: [Corn, MIR162 x MON89034 x GA21, SYN-IR162-4 x MON-89034-3 x MON-00021-9, NA], A243: [Corn, MI
R162 x NK603, SYN-IR162-4 x MON-00603-6, NA], A244: [Maize, MIR162 x TC1507, SYN-IR162-4 x DAS-01507-1, NA], A245: [Corn, MIR162 x TC1507 x 5307, SYN-IR162-4 x DAS-01507-1 x SYN-05307-1, NA], A246: [Corn, MIR162 x TC1507 x 5307 x GA21, SYN-IR162-4 x DAS-01507-1 x SYN-05307-1 x MON-00021-9, NA], A247: [Corn, MIR162 x TC1507 x GA21, SYN-IR162-4 x DAS-01507-1 x MON-00021-9, NA], A248: [ Corn, MIR604, SYN-IR604-5, Agrisure ™ RW], A249: [Corn, MIR604 x 5307, SYN-IR604-5 x SYN-05307-1, NA], A250: [Corn, MIR604 x 5307 x GA21, SYN-IR604-5 x SYN-05307-1 x MON-00021-9, NA], A251: [Corn, MIR604 x GA21, SYN-IR604-5 x MON-00021-9, Agrisure ™ GT / RW], A252: [Maize, MIR604 x NK603, SYN-IR604-5 x MON-00603-6, NA], A253: [Corn, MIR604 x TC1507, SYN-IR604-5 x DAS-01507-1, Optimum ( TRIsect (registered trademark) )], A254: [Corn, MIR604 x TC1507 x 5307, SYN-IR604-5 x DAS-01507-1 x SYN-05307-1, NA], A255: [Corn, MIR604 x TC1507 x 5307 x GA21, SYN- IR604-5 x TC1507 x SYN-05307-1 x MON-00021-9, NA], A256: [Corn, MIR604 x TC1507 x GA21, SYN-IR604-5 x TC1507 x MON-00021-9, NA], A257 : [Corn, MON801 (MON80100), MON801, NA], A258: [Corn, MON802, MON-80200-7, NA], A259: [Corn, MON809, PH-MON-809-2, NA], A260: [Corn, MON810, MON-00810-6, YieldGard (TM), MaizeGard (TM)], A261: [Corn, MON810 x MIR162, MON-00810-6 x SYN-IR162-4, NA], A262: [Corn , MON810 x MIR162 x NK603, MON-00810-6 x SYN-IR162-4 x MON-00603-6, NA], A263: [corn, MON810 x MIR604, MON-00810-6 x SYN-IR604-5, NA ], A264: [corn, MON810 x MON88017, MON-00810-6 x MON-88017-3, YieldGard (TM) VTTriple], A265: [corn MON810 x NK603 x MIR604, MON-00810-6 x MON-00603-6 x SYN-IR604-5, NA], A266: [corn, MON832, NA, RoundupReady (TM) Maize], A267: [corn, MON863, MON-00863-5, YieldGard ™ Rootworm RW, MaxGard ™], A268: [corn, MON863 x MON810, MON-00863-5 x MON-00810-6, YieldGard ™ Plus], A269: [ Corn, MON863 x MON810 x NK603, MON-00603-6 x MON-00810-6 x MON-00863-5, YieldGard (TM) PluswithRR], A270: [Corn, MON863 x NK603, MON-00863-5 x MON- 00603-6, YieldGard ™ RW + RR], A271: [corn, MON87403, MON87403-1, NA], A272: [corn, MON87411, MON-87411-9, NA], A273: [corn, MON87419, MON87419-8, NA], A274: [corn, MON87427, MON-87427-7, RoundupReady (TM) Maize], A275: [corn, MON87427 x 59122, MON-87427-7 x DAS-59122-7, NA] , A276: [Corn, MON87427 x MON88017, MON-87427-7 x MO N-88017-3, NA], A277: [corn, MON87427 x MON88017 x 59122, MON-87427-7 x MON-88017-3 x DAS-59122-7, NA], A278: [corn, MON87427 x MON89034, MON-87427-7 x MON-89034-3, NA], A279: [Corn, MON87427 x MON89034 x 59122, MON-87427-7 x MON-89034-3 x DAS-59122-7, NA], A280: [ Corn, MON87427 x MON89034 x MON88017, MON-87427-7 x MON-89034-3 x MON-88017-3, NA], A281: [Corn, MON87427 x MON89034 x MON88017 x 59122, MON-87427-7 x MON- 89034-3 x MON-88017-3 x 59122, NA], A282: [corn, MON87427 x MON89034 x NK603, MON-87427-7 x MON-89034-3 x MON-00603-6, NA], A283: [ Corn, MON87427 x MON89034 x TC1507, MON-87427-7 x MON-89034-3 x DAS-01507-1, NA], A284: [Corn, MON87427 x MON89034 x TC1507 x 59122, MON-87427-7 x MON- 89034-3 x DAS-01507-1 x DAS-59122-7, NA], A285: [Corn, MON87427 x MON89034 x TC1507 x MON87411 x 59122, MON-87427-7 x MON-89034 -3 x DAS-01507-1 x MON-87411-9 x DAS-59122-7, NA], A286: [Corn, MON87427 x MON89034 x TC1507 x MON88017, MON-87427-7 x MON-89034-3 x DAS -01507-1 x MON-88017-3, NA], A287: [Corn, MON87427 x MON89034 x MIR162 x NK603, MON-87427-7 x MON-89034-3 x SYN-IR162-4 x MON-00603-6 , NA], A288: [corn, MON87427 x MON89034 x TC1507 x MON88017 x 59122, MON-87427-7 x MON-89034-3 x DAS-01507-1 x MON-88017-3 x DAS-59122-7, NA ], A289: [Corn, MON87427 x NK603, MON-87427-7 x MON-00603-6, NA], A290: [Corn, MON87427 x TC1507, MON-87427-7 x DAS-01507-1, NA], A291: [Corn, MON87427 x TC1507 x 59122, MON-87427-7 x DAS-01507-1 x DAS-59122-7, NA], A292: [Corn, MON87427 x TC1507 x MON88017, MON-87427-7 x DAS -01507-1 x MON-88017-3, NA], A293: [Corn, MON87427 x TC1507 x MON88017 x 59122, MON-87427-7 x DAS-01507-1 x MON-88017-3 x DAS-59122-7 , NA], A294: [Tomorrow MON87460, MON-87460-4, Genuity (registered trademark) DroughtGard (trademark)], A295: [corn, MON87460 x MON88017, MON-87460-4 x MON-88017-3, NA], A296: [corn, MON87460 x MON89034 x MON88017, MON-87460-4 x MON-89034-3 x MON-88017-3, NA], A297: [corn, MON87460 x MON89034 x NK603, MON-87460-4 x MON-89034-3 x MON-00603-6, NA], A298: [corn, MON87460 x NK603, MON-87460-4 x MON-00603-6, NA], A299: [corn, MON88017, MON-88017-3, YieldGard (trademark) VT ™ Rootworm ™ RR2], A300: [corn, MON88017 x DAS40278, MON-88017-3 x DAS-40278-9, NA], A301: [corn, MON89034, MON-89034-3, YieldGard ( Trademark) VTPro (trademark)], A302: [corn, MON89034 x 59122, MON-89034-3 x DAS-59122-7, NA], A303: [corn, MON89034 x 59122 x DAS40278, MON-89034-3 x DAS -59122-7 x DAS-40278-9, NA], A304: [corn, MON89034 x 59122 x MON88017, MON-89034-3 x DAS-59122-7 x MON-88017-3, NA], A305: [Corn, MON89034 x 59122 x MON88017 x DAS40278, MON-89034-3 x DAS-59122-7 x MON-88017- 3 x DAS-40278-9, NA], A306: [corn, MON89034 x DAS40278, MON-89034-3 x DAS-40278-9, NA], A307: [corn, MON89034 x MON87460, MON-89034-3 x MON-87460-4, NA], A308: [corn, MON89034 x MON88017, MON-89034-3 x MON-88017-3, Genuity (R) VTTriplePro (TM)], A309: [corn, MON89034 x MON88017 x DAS40278, MON-89034-3 x MON-88017-3 x DAS-40278-9, NA], A310: [Corn, MON89034 x NK603, MON-89034-3 x MON-00603-6, Genuity (R) VTDoublePro (Trademark)], A311: [corn, MON89034 x NK603 x DAS40278, MON-89034-3 x MON-00603-6 x DAS-40278-9, NA], A312: [corn, MON89034 x TC1507, MON-89034- 3 x DAS-01507-1, NA], A313: [corn, MON89034 x TC1507 x 59122, MON-89034-3 x DAS-01507-1 x DAS-59122-7, NA], A314: [corn, MON89034 x TC1507 x 59122 x DAS40278, MON-89034-3 x DAS-01507-1 x DAS-59122-7 x DAS-40278-9, NA], A315: [corn, MON89034 x TC1507 x DAS40278, MON-89034-3 x DAS-01507-1 x DAS-40278-9, NA], A316: [Corn, MON89034 x TC1507 x MON88017, MON-89034-3 x DAS-01507-1 x MON- 88017-3, NA], A317: [corn, MON89034 x TC1507 x MON88017 x 59122, MON-89034-3 x DAS-01507-1 x MON-88017-3 x DAS-59122-7, Genuity (R) SmartSta x (trademark)], A318: [corn, MON89034 x TC1507 x MON88017 x 59122 x DAS40278, MON-89034-3 x DAS-01507-1 x MON-88017-3 x DAS-59122-7 x DAS-40278-9 , NA], A319: [corn, MON89034 x TC1507 x MON88017 x DAS40278, MON-89034-3 x DAS-01507-1 x MON-88017-3 x DAS-59122-7 x DAS-40278-9, NA], A320: [Corn, MON89034 x TC1507 x NK603, MON-89034-3 x DAS-01507-1 x MON-00603-6, PowerCore (TM)], A321: [Corn, MON89034 x TC1507 x NK6 03 x DAS40278, MON-89034-3 x DAS-01507-1 x MON-00603-6 x DAS-40278-9, NA], A322: [Corn, MON89034 x TC1507 x NK603 x MIR162, MON-89034-3 x DAS-01507-1 x MON-00603-6 x SYN-IR162-4, NA], A323: [Corn, MON89034 x TC1507 x NK603 x MIR162 x DAS40278, MON-89034-3 x DAS-01507-1 x MON- 00603-6 x SYN-IR162-4 x DAS-40278-9, NA], A324: [corn, MON89034 x GA21, MON-89034-3 x MON-00021-9, NA], A325: [corn, MS3, ACS-ZM001-9, InVigor ™ Maize], A326: [corn, MS6, ACS-ZM005-4, InVigor ™ Maize], A327: [corn, MZHG0JG, SYN-000JG-2, NA], A328 : [Corn, MZIR098, SYN-00098-3, NA], A329: [Corn, NK603, MON-00603-6, RoundupReady (TM) 2Maize], A330: [Corn, NK603 x MON810 x 4114 x MIR604, MON- 00603-6 x MON-00810-6 x DP004114-3 x SYN-IR604-4, NA], A331: [Corn, NK603 x MON810, MON-00603-6 x MON-00810-6, YieldGard ( Standard) CB + RR], A332: [Corn, NK603 x T25, MON-00603-6 x ACS-ZM003-2, RoundupReady (TM) LibertyLink (TM) Maize], A333: [Corn, T14, ACS-ZM002- 1, LibertyLink (trademark) Maize], A334: [corn, T25, ACS-ZM003-2, LibertyLink (trademark) Maize], A335: [corn, T25 x MON810, ACS-ZM003-2 x MON-00810-6, LibertyLink (trademark) Yieldgard (trademark) Maize], A336: [corn, TC1507, DAS-01507-1, Hercule x (trademark) I, Herrcule x (trademark) CB], A337: [corn, TC1507 x 59122 x MON810 x MIR604 x NK603, DAS-01507-1 x DAS-59122-7 x MON-00810-6 x SYN-IR604-5 x MON-00603-6, Optimum (TM) Intrasect X treme], A338: [Corn, TC1507x MON810 x MIR604 x NK603, DAS-01507-1 x MON-00810-6 x SYN-IR604-5 x MON-00603-6, NA], A339: [corn, TC1507 x 5307, DAS-01507-1 x SYN- 05307-1, NA], A340: [corn, TC1507 x 5307 x GA21, DAS-01507-1 x SYN-05307-1 x MON-00021-9, NA], A341: [ Sorghum, TC1507 x 59122, DAS-01507-1 x DAS-59122-7, Hercule x X TRA (TM)], A342: [Corn, TC1507 x 59122 x DAS40278, DAS-01507-1 x DAS-59122-7 x DAS-40278-9, NA], A343: [corn, TC1507 x 59122 x MON810, DAS-01507-1 x DAS-59122-7 x MON-00810-6, Optimum (R) AcreMax (R) X tra], A344: [Corn, TC1507 x 59122 x MON810 x MIR604, DAS-01507-1 x DAS-59122-7 x MON-00810-6 x SYN-IR604-5, Optimum (R) AcreMax (R) ) X Treme], A345: [Corn, TC1507 x 59122 x MON810 x NK603, DAS-01507-1 x DAS-59122-7 x MON-00810-6 x MON-00603-6, Optimum (TM) Intrasect X TRA] , A346: [Corn, TC1507 x 59122 x MON88017, DAS-01507-1 x DAS-59122-7 x MON-88017-3, NA], A347: [Corn, TC1507 x 59122 x MON88017 x DAS40278, DAS-01507- 1 x DAS-59122-7 x MON-88017-3 x DAS-40278-9, NA], A348: [Corn, TC1507 x 59122 x NK603, DAS-01507-1 x DAS-59122-7 x M ON-00603-6, Hercule x X TRA ™ RR], A349: [corn, TC1507 x 59122 x NK603 x MIR604, DAS-01507-1 x DAS-59122-7 x MON-00603-6 x SYN-IR604 -5, NA], A350: [corn, TC1507 x DAS40278, DAS-01507-1 x DAS-40278-9, NA], A351: [corn, TC1507 x GA21, DAS-01507-1 x MON-00021-9 , NA], A352: [corn, TC1507 x MIR162 x NK603, DAS-01507-1 x SYN-IR162-4 x MON-00603-6, Optimum (R) Leptra (TM)], A353: [corn, TC1507 x MIR604 x NK603, DAS-01507-1 x SYN-IR604-5 x MON-00603-6, Optimum (TM) TRIsect], A354: [corn, TC1
507 x MON810, DAS-01507-1 x MON-00, NA], A355: [Corn, TC1507 x MON810 x MIR162, DAS-01507-1 x MON-00810-6 x SYN-IR162-4, NA], A356 : [Corn, TC1507 x MON810 x MIR604, DAS-01507-1 x MON-00810-6 x SYN-IR162-4 x MON-00603-6, NA], A357: [Corn, TC1507 x MON810 x MIR604, DAS-01507-1 x MON-00810-6 x SYN-IR604-5, NA], A358: [Corn, TC1507 x MON810 x NK603, DAS-01507-1 x MON-00810-6 x MON-00603-6, Optimum ™ Intrasect], A359: [corn, TC1507 x MON810 x NK603 x MIR604, DAS-01507-1 x MON-00810-6 x MON-00603-6 x SYN-IR604-5, NA], A360: [ Corn, TC1507 x MON88017, DAS-01507-1 x MON-88017-3, NA], A361: [Corn, TC1507 x MON88017 x DAS40278, DAS-01507-1 x MON-88017-3 x DAS-40278-9, NA], A362: [Corn, TC1507 x NK603, DAS-01507-1 x MON-00603-6, Hercule x (trademark) IRR], A363: [Corn, TC1507 x NK603 x DAS40278, DAS-01507-1 x MON -00 603-6 x DAS-40278-9, NA], A364: [Corn, TC6275, DAS-06275-8, NA], A365: [Corn, VCO-01981-5, VCO-01981-5, NA], A366 : [Corn, DK404SR, DK404SR, NA], A367: [Corn, EXP1910IT, EXP1910IT, NA], A368: [Melon, MelonA, NA, NA], A369: [Melon, MelonB, NA, NA], A370: [ Papaya, 55-1, CUH-CP551-8, Rainbow, SunUp], A371: [Papaya, 63-1, CUH-CP631-7, NA], A372: [Papaya, HuanongNo.1, NA, HuanongNo.1] , A373: [Papaya, X17-2, UFL-X17CP-6, NA], A374: [Petunia, Petunia-CHS, NA, NA], A375: [Plum, C-5, ARS-PLMC5-6, NA] , A376: [Polish canola, HCR-1, NA, NA], A377: [Polish canola, ZSR500, NA, Hysyn101RRRoundup-Ready (trademark)], A378: [Polish canola, ZSR502, NA, Hysyn101RRRoundup-Ready (trademark) ], A379: [Polish canola, ZSR503, NA, Hysyn101RRRoundup-Ready (trademark)], A380: [Poplar , Btpoplar, poplar12 (Populusnigra), NA, NA], A381: [Poplar, Hybridpoplarclone741, NA, NA], A382: [Potato, 1210amk, NA, Lugovskoiplus], A383: [Potato, 2904 / 1kgs, NA, Elizavetaplus] , A384: [potato, AM04-1020, BPS-A1020-5, StarchPotato], A385: [potato, ATBT04-27, NMK-89367-8, AtlanticNewLeaf ™ potato], A386: [potato, ATBT04-30, NMK-89613-2, AtlanticNewLeaf ™ potato], A387: [potato, ATBT04-31, NMK-89170-9, AtlanticNewLeaf ™ potato], A388: [potato, ATBT04-36, NMK-89279-1, AtlanticNewLeaf ™ potato], A389: [potato, ATBT04-6, NMK-89761-6, AtlanticNewLeaf ™ potato], A390: [potato, BT06, NMK-89812-3, NewLeaf ™ RussetBurbankpotato], A391 : [Potato, BT10, NMK-89175-5, NewLeaf (trademark) RussetBurbankpotato], A392: [potato, BT12, NMK-89601-8, NewLeaf (trademark) RussetBurbankpotato], A393: [jaugat Potato, BT16, NMK-89167-6, NewLeaf ™ RussetBurbankpotato], A394: [potato, BT17, NMK-89593-9, NewLeaf ™ RussetBurbankpotato], A395: [potato, BT18, NMK-89906-7, NewLeaf ™ RussetBurbankpotato], A396: [potato, BT23, NMK-89675-1, NewLeaf ™ RussetBurbankpotato], A397: [potato, E12, SPS-00E12-8, Innate® Cultivate], A398: [Potato, E24, SPS-00E24-2, NA], A399: [potato, EH92-527-1, BPS-25271EH92-527-1-9, Amflora (trademark)], A400: [potato, F10, SPS- 00F10-7, Innate (registered trademark) Generate], A401: [potato, F37, SPS-00F37-7, NA], A402: [potato, G11, SPS-00G11-9, NA], A403: [potato, H37 , SPS-00H37-9, NA], A404: [potato, H50, SPS-00H50-4, NA], A405: [potato, HLMT15-15, NA, Hi-LiteNewLeaf ™ Ypotato], A406: [potato , HLMT15-3, NA, Hi-LiteNewLeaf ™ Ypotato], A407: [ Potato, HLMT15-46, NA, Hi-LiteNewLeaf ™ Ypotato], A408: [potato, J3, SPS-000J3-4, Innate® Accelerate], A409: [potato, J55, SPS-00J55-2 , NA], A410: [potato, J78, SPS-00J78-7, NA], A411: [potato, RBMT15-101, NMK-89653-6, NewLeaf ™ YRussetBurbankpotato], A412: [potato, RBMT21-129 , NMK-89684-1, NewLeaf (TM) PlusRussetBurbankpotato], A413: [potato, RBMT21-152, NA, NewLeaf (TM) PlusRussetBurbankpotato], A414: [potato, RBMT21-350, NMK-89185-6, NewLeaf (trademark) ) PlusRussetBurbankpotato], A415: [potato, RBMT22-082, NMK-89896-6, NewLeaf (TM) PlusRussetBurbankpotato], A416: [potato, RBMT22-186, NA, NewLeaf (TM) PlusRussetBurbankpotato], A417: [potato, RBMT22 -238, NA, NewLeaf ™ PlusRussetBurbankpotato], A418: [potato, RBMT22-262, NA, NewLeaf ™ PlusRussetBurbankpotato], A419: [ Potato, SEMT15-02, NMK-89935-9, ShepodyNewLeaf (trademark) Ypotato], A420: [potato, SEMT15-07, NA, ShepodyNewLeaf (trademark) Ypotato], A421: [potato, SEMT15-15, NMK-89930- 4, ShepodyNewLeaf (trademark) Ypotato], A422: [potato, SPBT02-5, NMK-89576-1, SuperiorNewLeaf (trademark) potato], A423: [potato, SPBT02-7, NMK-89724-5, SuperiorNewLeaf (trademark) potato], A424: [potato, TIC-AR233-5, TIC-AR233-5, NA], A425: [potato, V11, SPS-00V11-6, Innate (registered trademark) Invigorate], A426: [potato, W8 , SPS-000W8-4, Innate (registered trademark) Glaciate], A427: [potato, X 17, SPS-00 X 17-5, Innate (registered trademark) Acclimate], A428: [potato, Y9, SPS-000Y9- 7, Innate (registered trademark) Hibernate], A429: [Rice, 7Crp # 10, NA, NA], A430: [Rice, GMShanyou63, NA, BTShanyou63], A431: [Rice, Huahui-1 / TT51-1, NA , Huahui-1], A432: [Rice, LLRICE06, ACS-OS001-4, LibertyLink (quotient ) Rice], A433: [Rice, LLRICE601, BCS-OS003-7, LibertyLink (trademark) rice], A434: [Rice, LLRICE62, ACS-OS002-5, LibertyLink (trademark) rice], A435: [Rice, Taromolaii + cry1Ab, NA, NA], A436: [Rice, CL121 x CL141 x CF X 51, CL121 x CL141 x CF X 51, Clearfield (R) Rice], A437: [Rice, IMINTA-1 x IMINTA-4, IMINTA -1 x IMINTA-4, Clearfield ™ Rice], A438: [Rice, PWC16, PWC16, NA], A439: [Rose, WKS82 / 130-4-1, IFD-52401-4, NA], A440: [Rose, WKS92 / 130-9-1, IFD-52901-9, NA], A441: [Soybean, 260-05 (G94-1, G94-19, G168), DD-026005-3, NA], A442 : [Soybean, A2704-12, ACS-GM005-3, LibertyLink (trademark) soybean], A443: [soybean, A2704-21, ACS-GM004-2, LibertyLink (trademark) soybean], A444: [soybean, A5547- 127, ACS-GM006-4, LibertyLink (trademark) soybean], A445: [soybean, A5547-35, ACS-GM008-6, LibertyLink (trademark) soybean], A446: [soybean, CV127, BPS-CV127-9, Cultivance], A447: [soybean, DAS44 406-6, DAS-44406-6, NA], A448: [soybean, DAS68416-4, DAS-68416-4, Enlist ™ Soybean], A449: [soybean, DAS68416-4 x MON89788, DAS-68416- 4 x MON-89788-1, NA], A450: [soybean, DAS81419, DAS-81419-2, NA], A451: [soybean, DAS81419 x DAS44406-6, DAS-81419-2 x DAS-44406-6, NA], A452: [soybean, DP305423, DP-305423-1, Treus (trademark) or Plenish (trademark)], A453: [soybean, DP305423 x GTS40-3-2, DP-305423-1 x MON-04032 -6, NA], A454: [soybean, DP356043, DP-356043-5, OptimumGAT (trademark)], A455: [soybean, FG72 (FG072-2, FG072-3), MST-FG072-3, NA], A456: [soybean, FG72 x A5547-127, MST-FG072-3 x ACS-GM006-4, Liberty Link (registered trademark) GT27 (trademark)], A457: [soybean, GTS40-3-2 (40-3- 2), MON-04032-6, RoundupReady (trademark) soybean], A458: [soybean, GU262, ACS-GM003-1, LibertyLink (trademark) soybean], A459: [soybean, IND-00410-5, IND-00410 -5, VerdecaHB4Soybean], A460: [soybean, MON87701, MON-87701-2, NA], A461: [soybean, MON87701 x MON89788, MON-87701-2 x MON-89788-1, Intacta ™ RoundupReady ™ 2Pro], A462: [soybean, MON87705, MON-87705-6, VistiveGold ™) , A463: [soybean, MON87705 x MON87708, MON-87705-6 x MON-87708-9, NA], A464: [soybean, MON87705 x MON87708 x MON89788, MON-87705-6 x MON-87708-9 x MON- 89788-1, NA], A465: soybean, MON87705 x MON89788, MON-87705-6 x MON-89788-1, NA], A466: [soybean, MON87708, MON-87708-9, Genuity® RoundupReady ( Trademark) 2 X tend (trademark)], A467: [soybean, MON87708 x MON89788, MON-87708-9 x MON-89788-1, Roundup Ready 2 X tend (registered trademark)], A468: [soybean, MON87712, MON -87712-4, NA], A469: [soybean, MON87751, MON-87751-7, NA], A470: [soybean, MON87751 x MON87701 x MON87708 x MON89788, MON-87751-7 x MON-87701-2 x MON87708 x MON89788, NA], A471: [soybean, MON87769, MON87769-7, NA], A472: [soybean, MON87769 x MON89788, MON-87769-7 x MON-89788-1 , NA], A473: [soybean, MON89788, MON-89788-1, Genuity® Roundup Ready 2 Yield ™], A474: [soybean, SYHT0H2, SYN-000H2-5, Herbicide-tolerant Soybeanline], A475 : [Soybean, W62, ACS-GM002-9, LibertyLink (trademark) soybean], A476: [soybean, W98, ACS-GM001-8, LibertyLink (trademark) soybean], A477: [soybean, OT96-15, OT96- 15, NA], A478: [Peppo pumpkin (Cucurbitapepo), CZW3, SEM-0CZW3-2, NA], A479: [Peppo pumpkin (Cucurbita pepo), ZW20, SEM-0ZW20-7, NA], A480: [sugar beet, GTSB77 (T9100152), SY-GTSB77-8, InVigor ™ sugarbeet], A481: [sugar beet, H7-1, KM-000H71-4, Roundup Ready ™ sugarbeet], A482: [sugar beet, T120-7, ACS -BV001-3, LibertyLink ™ sugarbeet], A483: [sugarcane, CTB141175 / 01-A, CTB141175 / 01-A, NA], A484: [sugarcane, NXI-1T, NXI-1T, NA], A485: [Sugarcane, NXI-4T, NXI-4T, NA], A486: [sugarcane, NXI-6T, NXI-6T, NA], A487: [sugar Wari, X81359, X81359, Clearfield ™ Sunflower], A488: [Sweet Pepper, PK-SP01, X81359, NA], A489: [Tobacco, C / F / 93 / 08-02, NA, NA], A490: [Tobacco, Vector21-41, NA, NA], A491: [Tomato, 1345-4, NA, NA], A492: [Tomato, 35-1-N, NA, NA], A493: [Tomato, 5345, NA , NA], A494: [Tomato, 8338, CGN-89322-3, NA], A495: [Tomato, B, SYN-0000B-6, NA], A496: [Tomato, Da, SYN-000DA-9, NA ], A497: [Tomato, DaDongNo9, NA, NA], A498: [Tomato, F (1401F, h38F, 11013F, 7913F), SYN-0000F-1, FLAVRSAVR (trademark)], A499: [Tomato, FLAVRSAVR, CGN -89564-2, FLAVRSAVR (trademark)], A500: [Tomato, HuafanNo1, NA, NA], A501: [Tomato, PK-TM8805R (8805R), NA, NA], A502: [Wheat, MON71800, MON-71800 -3, RoundupReady (TM) wheat], A503: [Wheat, AP205CL, AP205CL, Clearfield (TM) Wheat], A504: [Wheat, AP602CL, AP602CL, Clearfield (TM) Wheat], A505: [Wheat, BW25 5-2 x BW238-3, BW255-2 x BW238-3, Clearfield (TM) Wheat], A506: [Wheat, BW7, BW7, Clearfield (TM) Wheat], A507: [Wheat, Teal11A, Teal11A, Clearfield ( Trademark) Wheat], A508: [Wheat, SWP965001, SWP965001, NA], A509: [Corn, NA, NA, Agrisure Artesian (TM)], A510: [Corn, NA, NA, Optimum (R) AQUAmax (Registered Trademark) Trademark)], A511: [canola, NA, NA, SU canola (registered trademark)], A512: [canola, NA, NA, Nexera (registered trademark) Canola], A513: [soybean, NA, NA, STS soybean] , A514: “corn, NA, NA, SR corn”, A514: “sunflower, NA, NA, ExpressSun®”, A515: [rice, NA, NA, Golden rice], A516: [corn, NA, NA, Post Protected (registered trademark) corn], A517: [sunflower, NA, NA, ExpressSun (registered trademark)], A518: [Rice, NA, NA, Provisia (R) Rice], A519: [Canola, NA, NA, Triazinon Tolerant Canola], A520: [ Corn, NA, NA, SmartStax (TM) Pro], A521: [soybean, NA, NA, Cr
edenz (registered trademark) soybean], A522: [corn, TC1507 x 59122, DAS-01507-1 × DAS-59122-7, Optimum (registered trademark) AcreMax (registered trademark) 1], A523: [corn, 4114 x MON810 x MIR604, DP-004114-3 × MON-00810-6 × SYN-IR604-5, Qrome (trademark)], A524: [Cotton, NA, NA, Stoneville (registered trademark) Cotton ST5517GLTP], A525: [cotton, NA, NA, Stoneville (registered trademark) Cotton ST4848GLT], A526: [Cotton, NA, NA, Stoneville (registered trademark) Cotton ST4949GLT], A527: [Cotton, NA, NA, Stoneville (registered trademark) Cotton ST5020GLT], A528 : [Cotton, NA, NA, Stoneville (registered trademark) Cotton ST5115GLT], A529: [Cotton, NA, NA, Stoneville (registered trademark) Cotton ST6182GLT], A530: [Cotton, NA, NA, Stoneville (registered trademark) Cotton ST4747GLB2], A531: [Cotton, NA, NA, Stoneville (registered trademark) Cotton ST4946GLB2], A532: [Cotton, NA, NA, Stoneville (registered trademark) Cotton ST6448GLB2], A533: [soybean, NA, NA, Enlist E3 ( Mark)], A534: [soybean, NA, NA, Enlist (trademark) Roundup Ready 2 Yield (registered trademark)], A535: [corn, NA, NA, Enlist (trademark) Roundup Ready (registered trademark) Corn 2], A536: [Corn, NA, NA, Smartstax (registered trademark) Enlist (trademark)], A537: [Corn, NA, NA, Powercore (registered trademark) Enlist (trademark)], A538: [Cotton, NA, NA, Enlist (Cotton), A539: [Cotton, NA, NA, Bollgard 3 (registered trademark) XtendFlex (registered trademark)], A540: [Corn, NA, NA, SmartStax (registered trademark) RIB Complete (registered trademark) Corn ], A541: [corn, NA, NA, VT Double PRO (registered trademark) RIB Complete (registered trademark) Corn], A542: [corn, NA, NA, VT Double PRO (registered trademark) Corn], A543: [corn , NA, NA, Genuity (registered trademark) VT Triple PRO (registered trademark) RIB Complete Corn], A544: [corn, NA, NA, Trecepta (trademark) Corn], A545: [soybean, NA, NA, fukuminori], A546: [Soybean, NA, NA, Meminori], A547: [Corn, NA, NA, ZFN-12 maize], A548: [Rice, NA, NA, Yumepirika], A549: [Rice NA, NA, Kanto BPH1], A550: [Cotton, NA, MON88702, NA], A551: [soybean, DP305423 x MON87708, DP-305423-1 x MON-87708-9, NA], A552: [soybean, DP305423 x MON87708 x MON89788, DP-305423-1 x MON- 87708-9 x MON-89788-1, NA], A553: [soybean, DP305423 x MON89788, DP-305423-1 x MON-89788-1, NA], A554: [cotton, 3006-210-23 x 281- 24-236 x MON88913 x COT102 x 81910, DAS-21023-5 x DAS-24236-5 x MON-88913-8 x SYN-IR102-7], A555: [Cotton, GHB811, BCS-GH811-4, NA] .

  In the present invention, the composition of the present invention can be applied to the modified plants A1 to A555 or the cultivation carrier of the plant. When applying this invention composition to said plant, it is more preferable to apply to the seed or vegetative reproduction organ.

  When treating the composition of the present invention to seeds or vegetative reproductive organs, it is preferable to use a composition containing at least one bactericidal component selected from the group (b) among the compositions of the present invention. At this time, commercially treated seeds or vegetative organs may be used.

  When the composition of the present invention is treated on seeds or vegetative organs, manganese, copper, zinc or the like may be treated at the same time. The seed or vegetative reproductive organ treated with the composition of the present invention is sown or planted in a field by a usual method.

  The composition of the present invention can effectively control a wide range of subjects in a cereal field, a vegetable field, a flower field, an orchard, or a non-agricultural field where normal tillage cultivation or non-tillage cultivation is performed.

  When the composition of the present invention is applied to sugarcane, in sugarcane cultivation, a sugarcane stem fragment that has been cut so as to have one node may be used, and the size of the sugarcane stem fragment may be 2 cm. One having 15 to 15 cm, preferably 3 to 8 cm may be used. Sugarcane cultivation techniques using such stem fragments are known (WO09 / 000398, WO09 / 000399, WO09 / 000400, WO09 / 000401, WO09 / 000402) and are implemented under the trade name of Prene (registered trademark). The

  When the composition of the present invention is applied to rice, it may be applied to a nursery, may be applied to paddy fields, or may be applied to rice seeds. The above-mentioned nursery includes a nursery box or a rice seedling tray and a nursery.

  When the composition of the present invention is applied to a seedling box, the application time is not particularly limited as long as it is a seedling period from rice sowing to transplanting. The time when the composition of the present invention is treated in the seedling box at the time of sowing may be not only on the day of sowing but also on any day before or several days after sowing. The time when the composition of the present invention is treated into the nursery box at the time of transplantation may be not only the day of transplantation but also any day from several days before the day of transplantation. During the seedling raising period, the seedlings to be transplanted are either young seedlings (seedlings before and after the 2.5 leaf stage), medium seedlings (seedlings before and after the 3.5 leaf stage), or adult seedlings (seedlings before and after the 4.5 leaf stage) The composition of the present invention can be applied in any case, although it varies depending on the weather conditions and varies depending on weather conditions. Examples of the method for treating the seedling box with the composition of the present invention include a method of spraying a kneaded granule or a sand coating granule onto the seedling box, and a method of irrigating the seedling box with the solution of the composition of the present invention. . Further, the composition of the present invention can be treated on floor soil or covering soil, or can be mixed with floor soil or covering soil. In general, for example, a method for treating a pesticide during the seedling raising period. It is referred to as mixing with soil before sowing, pre-soiling treatment at sowing, post-soiling treatment at sowing, greening treatment, treatment on the day of transplantation, and simultaneous treatment of transplantation. The composition of the present invention may be processed into a seedling box by any of the above processing methods. The seedling culture medium is not particularly limited as long as it is a soil for rice seedlings, and a seedling mat other than soil may be used. The seedlings to which the composition of the present invention has been applied may be cultivated by pool seedlings.

  When applying this invention composition to a paddy field, you may use for the rice of transplant cultivation, and may be used for the rice of direct sowing cultivation. The method of applying to the paddy field is not particularly limited, for example, a method of applying the composition of the present invention to rice foliage, a method of applying to paddy soil, and a method of applying to the water surface of a flooded paddy field. Can be mentioned. Moreover, it can also be applied labor-saving with the supply of water by processing chemicals such as emulsion and flowable at the source of water flowing into paddy fields such as a water inlet and an irrigation device. The time to apply to the rice stem and leaves may be any time from seedling to harvest. Preparations to be used include preparations to be applied in the form of powders, fine granules, etc., and flowables, dry flowables, wettable powders, granular wettable powders, SE drugs, aqueous solvents, granular aqueous solvents, liquids, microscopic products. Examples include emmaffusion agents, EW agents, oil agents, surf agents, and emulsions. The spraying device may be any device that is normally used, and a hand-spreading device, a power spreader, a cruising player, a radio control helicopter, a manned helicopter, and the like can be used. In addition, the inventive composition may be sprayed by hand without using a spraying device.

  As a method for applying the composition of the present invention to paddy field soil, a method of treating the entire surface of paddy field soil (full surface treatment), a method of treating a groove provided when sowing rice (seeding groove treatment), and a rice seed immediately below Examples of the method include a method of processing to 0 to 10 centimeters, a method of processing in the form of streaks or dots in the vicinity of a rice strain or seed (side treatment).

  When applying this invention composition to paddy field soil, it can also apply simultaneously with agricultural materials, such as paste fertilizer and granular fertilizer, or it can mix and apply with these agricultural materials. The time of applying the composition of the present invention may be before sowing or before transplantation, may be simultaneously with sowing or transplanting, or may be immediately after sowing or immediately after transplanting.

  When applying simultaneously with sowing or transplanting, it may be applied using an attachment attached to the sowing or transplanting machine, or may be applied by other methods. Further, in the case of full surface treatment, it may be a period until water injection after sowing or transplanting, an intermediate drying period, or an intermittent irrigation period. When using the composition of the present invention, the soil surface of the paddy field may be dry, or the soil surface may be moist but free of flooding (water depth 0 cm). When it is applied to the surface of a flooded paddy field, it can be applied at any time from sowing or transplanting to harvesting, as long as the water depth is maintained by normal rice management.

  When using the composition of the present invention for direct sowing cultivation of rice, the rice seed is coated with a coating material such as iron powder (iron oxide powder, reduced iron powder, atomized iron powder, electrolytic iron powder, etc.), calcium peroxide, molybdenum, molybdenum compound, etc. It may be surface-treated. These coating materials can be used alone or in combination at any ratio. If necessary, auxiliary materials such as calcined gypsum and montmorillonite can be used for the purpose of increasing the amount or improving the fixation to rice seeds. An agent can be added. A mixture of calcium peroxide, calcined gypsum, and mineral powder is available as a commercial product, and examples thereof include Calper powder 16 (manufactured by Hodogaya UPL Co., Ltd.). Here, the rice seed means rice seed in a state before being sown in soil such as paddy field.

  When the composition of the present invention is treated with rice seeds, the rice seeds can be cultivated by direct sowing in dry fields, wet fields and paddy fields, or can be cultivated by sowing in a seedling box. Examples of the paddy field include paddy fields that are flooded or soiled. A paddy field in a flooded state refers to a paddy field that has been plowed, filled with water, shaved, etc., and further filled with water if necessary. The paddy field in the wet soil state is a paddy field in which the amount of water is maintained to the same level as the flooded state by performing a water-falling treatment or the like from the flooded state, and the soil surface is exposed. The composition of the present invention can be applied to rice seeds, rice seed before germination can be immersed in a solution containing the composition of the present invention, or the composition of the present invention can be applied to rice seeds after germination. The containing solution can also be sprayed. Moreover, in any treatment method, the composition of the present invention may contain one or more phytotoxicity reducing components selected from the group (d).

  The seeding machine used for rice seeding is not particularly limited as long as it is a seeding machine generally used for direct sowing cultivation of rice, such as paddy rice, upland rice, etc. For example, direct seeding machine for iron coating NDS-6 (Tetsu Maki-chan, KUBOTA Co., Ltd.), Iron coating direct sowing machine NDS-8 (Tetsu Maki-chan, Kubota Co., Ltd.), Iron coating direct sowing machine EP4-TC (Cute Tetsu Maki-chan, Kubota Co., Ltd.), Multi-purpose work machine RG6 (Manufactured by Yanmar Co., Ltd.), multipurpose working machine RG8 (manufactured by Yanmar Co., Ltd.), high-precision seeding machine PZV60 (manufactured by Iseki Agricultural Machinery Co., Ltd.) and high-precision seeding machine PZV80 (manufactured by Iseki Agricultural Machinery Co., Ltd.).

  It is preferable that iron or an oxide thereof (hereinafter referred to as iron and its oxide is referred to as “coating material A”) as a coating material to be processed on rice seeds is powdery. Examples of the powdery coating material A include reduced iron powder, atomized iron powder, electrolytic iron powder, and iron oxide powder, and these are available as commercial products. Moreover, these can also be used in mixture of 2 or more types. In the present invention, it is preferable to use reduced iron powder and / or iron oxide powder. The iron powder obtained by reducing iron oxide or iron salt with hydrogen or the like is reduced iron powder, and the iron powder obtained by jetting a high-pressure water jet of 8 to 20 MPa into the flow of molten iron is atomized iron powder or sulfuric acid. Iron powder obtained by depositing iron by electrolysis from a solution of iron or the like to obtain electrolytic iron flakes, pulverizing and annealing them with a rod mill or a vibration mill is called electrolytic iron powder. Iron oxide is an iron oxide having an oxidation number of II and / or III. The particle size of the coating material A used in the present invention is not particularly limited, but is preferably adjusted to a particle size of 10 to 100 μm. As the coating material A available as a commercial product, for example, DAE1K iron powder (DOWA (DOWA) IP (IP) Creation Co., Ltd.), DSP317 iron powder (DOWA (DOWA) IP (IP) Creation Co., Ltd.), Agricultural iron powder (manufactured by Daitetsu Kogyo Co., Ltd.), agricultural iron powder (manufactured by Tetsugen Co., Ltd.), and hematite (DOWA (DOWA) IP (IP) Creation Co., Ltd.).

When processing this invention composition to a rice seed, you may mix with calcined gypsum. For example, calcined gypsum may be used as an auxiliary agent when the composition of the present invention and the coating material A are processed into rice seeds. Such calcined gypsum may be powdered calcium sulfate 1/2 hydrate (CaSO ₄ .1 / 2H ₂ O), and such calcined gypsum is commercially available. For example, KTS-1 (Yoshino Gypsum Sales Co., Ltd.) and KTS-25 (Yoshino Gypsum Sales Co., Ltd.). Moreover, what mixed the coating | covering material A and calcined gypsum may be used, and such a mixture is available as a commercial item, for example, DAE1K mix (made by DOWA (Dowa) IP (IP) Creation Co., Ltd.) is mentioned.

  The rice seed dressing treatment using the coating material A can take various forms, but is generally a known method (“Iron-coated flooded direct sowing manual 2010”, independent method of rice seed dressing treatment using iron powder). This is carried out in the same manner as the National Agricultural Research Organization of Agriculture and Food Industry, March 2010, ISBN 978-4-903078-05-2). Specifically, dried rice seeds before germination are immersed in water (sometimes referred to as soaking), drained, and then dressed with the coating material A and calcined gypsum as necessary. To do. The order of the treatment of the covering material A and the calcined gypsum may be any first, and the mixture of the covering material A and the calcined gypsum may be treated simultaneously. After performing these treatments, if necessary, after finishing with powdered gypsum as a finish, it is usually placed on a flat surface on a flat surface and dried in the shade.

  The amount of coating material A to be used for rice seeds is usually 100 to 2000 grams for coating material A per 1000 grams of dry weight of rice seeds. Further, the amount of calcined gypsum in the case of powder coating with calcined gypsum is usually 5 to 100 g per 1000 g of dry weight of rice seeds. The amount of gypsum is usually 0 to 50 grams per 1000 grams of dry weight of rice seeds.

  As calcium peroxide, a calcium peroxide simple substance prepared in a powder having a particle size of 10 to 150 μm can be used. Can also be used. Such a calcium peroxide-containing composition is available as a commercial product, and examples thereof include Calper powder granules 16 (manufactured by Hodogaya UPL Co., Ltd.).

  The rice seed dressing treatment using calcium peroxide can take various forms, but generally, a method known as a rice seed dressing treatment using calcium peroxide (Japanese Patent Laid-Open No. 61-015805) and The same operation is performed. Specifically, the dried rice seeds before germination are immersed in water (sometimes referred to as soaking), drained, and then the rice seeds are dressed with a calcium peroxide powder or a calcium peroxide-containing composition. . After performing these treatments, it is usually dried by placing it on a basket or the like laid on a flat surface and drying it in the shade.

  The amount of calcium peroxide or a calcium peroxide-containing composition used for rice seeds is usually 100 to 1000 grams in terms of calcium peroxide alone relative to 1000 grams of dry weight of rice seeds.

  Examples of molybdenum and molybdenum compounds include molybdenum alone, molybdenum oxide, molybdic acid and its salt, molybdophosphoric acid and its salt, and molybdosilicic acid and its salt. Examples of the salt of molybdic acid include calcium molybdate, magnesium molybdate, ammonium molybdate, sodium molybdate, and potassium molybdate. Examples of molybdophosphate include ammonium molybdophosphate, sodium molybdophosphate, and potassium molybdophosphate. Such molybdenum and molybdenum compounds are commercially available, and examples thereof include molybdenum trioxide (Nippon Inorganic Chemical Industry Co., Ltd.).

  The treatment of rice seeds using molybdenum and molybdenum compounds can take various forms, but is usually carried out in the same manner as a known method for treating rice seeds using molybdenum and molybdenum compounds (WO 2011/093341). . Specifically, it is fixed to a rice seed surface using an adhesive such as polyvinyl alcohol, prepared in a solution and immersed in rice seed, and mixed with a coating material containing iron powder and / or calcium peroxide. For example, the operation of dressing rice seeds.

  In particular, “Bengara Molybdenum Coating” is known, which is a mixture of molybdenum compounds such as molybdenum trioxide, iron oxide powder (sometimes called Bengal flour) and water-resistant polyvinyl alcohol, and then treated on rice seeds (Yoshitaka Hara 2013. Improvement of Rice Seedling Establishment on Sulfate-Applied Submerged Soil by Seed Coating with Poorly Soluble Molybdenum Compounds. Plant Prod. Sci. 16 (3): 271-275), this method is also preferably performed in the present invention.

  The amount of molybdenum and molybdenum compound used for rice seeds is usually 0.01 to 10 mol in terms of molybdenum with respect to 1000 grams of dry weight of rice seeds.

Examples of the combination of the present compound or the composition of the present invention to be treated with rice seeds and a coating material include the following.
SX + iron oxide powder, SX + reduced iron powder, SX + iron oxide powder + reduced iron powder, SX + calcium peroxide, SX + molybdenum compound, SX + molybdenum compound + iron oxide powder, SX + molybdenum trioxide, SX + molybdenum trioxide + iron oxide powder, SX + iron oxide powder + calcined gypsum, SX + reduced iron powder + calcined gypsum, SX + iron oxide powder + reduced iron powder + calcined gypsum, SX + calcium peroxide + calcined gypsum, composition A + iron oxide powder, composition A + reduced iron powder, Composition A + iron oxide powder + reduced iron powder, composition A + calcium peroxide, composition A + molybdenum compound, composition A + molybdenum compound + iron oxide powder, composition A + molybdenum trioxide, composition A + molybdenum trioxide + iron oxide Powder, composition A + iron oxide powder + calcined gypsum, composition A + reduced iron powder + calcined gypsum, composition A + iron oxide powder + reduced iron powder + calcined gypsum, composition A + calcium peroxide + calcined gypsum.
Here, as the present component contained in the composition A, in particular, isothianyl, furametopyr, impylfluxam, ethaboxam, benomyl, oxolinic acid, clothianidin, fenitrothion, cartap hydrochloride, oxazosulfur, tetraniliprol, Lantraniliprole, cyantraniliprole, triflumezopyrim and ethiprole are preferred.

  The order of treatment of rice seeds in the above combination may be that the rice seed may be treated with the compound or the composition A and then the coating material may be treated, or the rice seed may be treated with the coating material and then the compound or composition. The product A may be treated, or the present compound or composition A and the coating material may be treated simultaneously. Here, when the composition A is treated, the order of treatment of the present compound and the present component and the coating material contained in the composition A may be the order of the present compound, the present component and the coating material, or the present compound, The order of the coating material and this component may be the order of this component, this compound and the coating material, the order of this component, the coating material and this compound, or the coating material. The order of this compound and this component may be sufficient, and the order of a coating | covering material, this component, and this compound may be sufficient. Or you may process this compound, this component, and a coating | covering material simultaneously to a rice seed.

  When the composition of the present invention is applied to rice, rice seed sprouting may be performed by immersing in water, or by immersing in water and holding in a wet state. The wet state means a state in which part or all of the surface of the rice seed after being immersed in water can be in contact with the outside air and can retain the moisture of the rice seed. For example, in the wet state, after the rice seed immersed in water is coated with a breathable material such as rice straw or cloth, water is sprayed on the coated material as necessary, or the rice seed is immersed in water. This is realized by storing rice seeds as they are in the net-like or bag-like material used in the process.

  When using this invention composition for rice, a fertilizer can also be used together. Examples of such fertilizers include Rakuichi (registered trademark, Sumitomo Chemical Co., Ltd.), Sumishort (registered trademark, Sumitomo Chemical Co., Ltd.) and Super SR Coat (registered trademark, Sumitomo Chemical Co., Ltd.). When using a fertilizer together, you may fertilize the whole rice cultivation soil before sowing, and you may fertilize the whole rice cultivation soil after sowing or in the growing season. Moreover, you may fertilize in the shape of a groove | channel along the row | line | column sowed at the time of sowing (it may also be called side stripe fertilization).

  When the composition of the present invention is applied to rice, sterilized seeds can be used to control seed infectious diseases and pests regardless of whether they are applied to seedlings, paddy fields or seeds. Specifically, groups (a) and groups of prochloraz, triflumizole, pefazoate, oxolinic acid, ipconazole, fludioxonil, kasugamycin-hydrochloride, cupric hydroxide, basic copper chloride, fenitrothion, cartap hydrochloride, etc. b) One or more insecticide and fungicide components selected from the above, or Trichoderma atroviride SKT-1 strain, Talalomyces flavus SAY-Y-94-01 strain, Pseudomonas sp. CAB-02 strain, Bacillus simplex CGF2856 Seeds that have been dipped, smeared or powdered with one or more components of the microbial material selected from the group (j) such as a strain can be used.

  Applying one or more kinds of cartap hydrochloride and metaaldehyde to paddy fields before rice seeding, paddy fields before rice transplanting, paddy fields after rice seeding, or paddy fields after rice transplantation will have the effect of scallop apple mussels and monoaragai Can be controlled. Moreover, weeds generated in paddy fields can be controlled by treating one or more herbicidal active ingredients selected from group (i). The time when the herbicidal active ingredient is applied is not particularly limited as long as the herbicidal active ingredient does not cause phytotoxicity to rice.

  One or more herbicidal active ingredients selected from the group (i) that can be used in paddy fields include, for example, azimusulfuron, bensulfuron methyl, chlorimuron ethyl, cyclosulfamuron, ethoxysulfuron, flucetosulfuron, halosulfuron methyl. , Imazosulfuron, orthosulfamlone, propyrisulfuron, pyrazosulfuronethyl, sinosulfuron, metsulfuronmethyl, metazosulfuron, beniocarb, molinate, esprocarb, pyributycarb, dimethylpiperate, swep, butachlor, pretilachlor, dimethrin, dimethrin, methylmethrin Propanil, mefenacet, flufenacet, chromeprop, naproanilide, bromobutide, dimelon, cumylron, etbenzani , Bentazone, Tridiphan, Carfentrazone ethyl, Fenchlorazole ethyl, Isoxadifen ethyl, Fentrazamide, Chromazone, Maleic acid hydrazide, Pyridate, Oxadichrome, cinmethyline, Benfrate, Oxadiazone, Oxadiargyl, Pentoxazone, Cihalohopbutyl Caffenstrol, ipfencarbazone, pyriminobacmethyl, bisbilivac sodium, pyrimisulphan, triamon, pyribenzoxime, pyriftalide, indhanophane, ACN, benzobicyclon, tefriltrione, mesotrione, phenquinotrione, dithiopyr, darapon, chlorthiamid , Penox slam, anilophos, benzulide, butamifos, phenoxasulfone, benzophenap Pyrazolinate, pyrazoxifene, imazametabenz, imazametabenzmethyl, imazamox, imazamox ammonium salt), imazapic, imazapic ammonium salt, imazapyr, imazaquin, imazetapill, pendimethalin, fenoxaprop ethyl, fenoxaprop P ethyl, metamihop, pyraclonyl, quinclolac, 2,4-D and its salt, MCP and its salt, MCPA and its salt, MCPB and its salt, piperophos, fluoxypyr, cyclopimolate, benzobicyclon, florpyraoxifene -Benzyl, Florpyroxifene and Taxumin A.

  Rice that can use the composition of the present invention refers to Oryza sativa, Oryza glaberima, which are cultivated species among annual plants of the genus Oryza, and hybrids thereof, and can be any of Japonica, Java, and Indica. Moreover, any of sticky rice, sticky rice, sake rice, and feed rice may be used. Rice varieties are not particularly limited, and may be varieties produced by crossing or varieties produced by gene recombination techniques, as exemplified by the plant varieties described above. When applied to cultivars imparted with herbicide resistance, pest resistance or disease resistance, a particularly labor-saving control method can be used. Moreover, the multiline which mixes and cultivates several varieties in which different resistance genes were integrated may be sufficient.

  The composition A containing one or more herbicidal active ingredients selected from the group (i) and one or more phytotoxicity reducing ingredients selected from the group (d) may contain all of the present ingredients in one preparation. It may be a separate formulation. Moreover, before and after planting seeds or plant reproductive organs treated with one or more phytotoxicity-reducing ingredients selected from group (d) in the cultivation area, the herbicidal active ingredient selected from group (i) is treated to the cultivated soil, etc. May be. Moreover, in that case, you may purchase and use the commercially available seed which processed 1 or more types of phytotoxicity reduction components chosen from group (d).

  When one or more herbicidal active ingredients selected from group (i) are treated before seed sowing or vegetative organ or seedling planting, the treatment time of the herbicidal active ingredient is 50 days before sowing or planting. To just before sowing or planting, preferably from 30 days before sowing or planting to just before sowing or planting, more preferably from 20 days before sowing or planting to just before sowing or planting, more preferably, Between 10 days before sowing or planting and immediately before sowing or planting.

  When one or more herbicidal active ingredients selected from group (i) are treated after seed sowing or after planting of vegetative reproductive organs or seedlings, the treatment time of the herbicidal active ingredient is preferably immediately after sowing or planting To 50 days after sowing or planting, more preferably, immediately after sowing or planting to 3 days after sowing or planting.

  Simultaneously with seed sowing or vegetative organ or seedling planting, one or more components selected from group (i) can be treated.

  In the case of treating one or more herbicidal active ingredients selected from the group (i) after sowing of soybean seeds, the treatment time of the herbicidal active ingredient is, for example, from before germination to flowering stage of soybean. Among the period from before the emergence of soybean to the flowering period, the period is preferably from the period before emergence of soybean to the period of 6 double leaves, and more preferably from the period before emergence of soybean to the period of 3 complex leaves.

  When one or more herbicidal active ingredients selected from the group (i) are treated after sowing of corn seeds, the treatment time of the herbicidal active ingredient is, for example, from before emergence to the 12th leaf stage, preferably from 8 before emergence. The period from the leaf stage to the 6th leaf stage is more preferable. In addition, the leaf age of corn is determined by the leaf color method (Leaf Collar Method).

  When one or more herbicidal active ingredients selected from the group (i) are treated before sowing of the cotton seed, the treatment time of the herbicidal active ingredient is from 50 days before sowing to immediately before sowing, preferably from 30 days before sowing. It is between just before sowing, more preferably from 20 days before sowing to just before sowing. When one or more herbicidal active ingredients selected from group (i) are treated after sowing of cotton seeds, the treatment time of the herbicidal active ingredient is from immediately after sowing to 70 days after sowing, preferably from 30 days after sowing. 50 days later, for example, from before cotton emergence to the flowering period, preferably from the beginning of treeization of cotton stem base to the period when the wooded part is 20 cm from the base.

  When one or more herbicidal active ingredients selected from the group (i) are treated before sugarcane planting, the treatment time of the herbicidal active ingredient is from 40 days before the planting date to immediately before, preferably 30 days of planting. It is between 20 days before and just before the date of planting, more preferably from the day before to just before. When one or more herbicidal active ingredients selected from the group (i) are treated after sugarcane planting, the treatment time of the herbicidal active ingredient is from immediately after planting to 40 days after planting, preferably immediately after planting, sowing or planting. It is between 20 days later, more preferably between immediately after planting and 10 days after planting.

  By applying the composition of the present invention, depending on the plant species or plant varieties, their growth location and growth conditions (soil, climate, growth season, nutrient), improvement of plant seedling establishment rate, improvement of plant growth, high temperature Or improved tolerance or tolerance to low temperature, improved tolerance to drought, overhumidity or salt contained in water or soil, improved flowering ability, improved ease of harvesting, accelerated maturation, increased yield, seed Or increase in fruit number, size or weight, increase plant height, increase plant weight, improve leaf green color, increase number of healthy leaves, increase leaf area, faster flowering, number of flowers or arrival Increased number of fruits, increased fruit set rate, improved quality and / or nutritional value of harvested product, increased sugar content in fruit, increased gluten strength, improved storage stability of harvested product And / or when workability can be improved That.

When the composition of the present invention is applied to a place where rice is nurtured, the application amount of the composition of the present invention is usually 5000 g or less, preferably 1000 g or less per sowing area (cultivated area) 10a. The total amount of the present compound or composition A contained in is usually 1000 g or less, preferably 500 g or less. Moreover, the total amount of the present compound or the composition A contained in the composition of the present invention per 1 m ^{2 of the} place where rice is nurtured is usually 0.05 to 1000 g, preferably 0.5 to 200 g.

  When the composition of the present invention is applied to a rice seedling box, the application amount of the composition of the present invention is the total amount of the present compound or composition A contained in the composition of the present invention. It is usually 0.1 to 35 g, preferably 0.2 to 20 g per about 30 cm).

  When the composition of the present invention is processed by seeds or vegetative reproductive officers, the application amount of the composition of the present invention is usually 0.001 to 100 g, preferably 0.02 to 50 g, per 1 kg of seed or vegetative reproductive organ. The total amount of the present compound or composition A contained in the composition is usually 0.000001 to 50 g, preferably 0.0001 to 30 g per kg of seeds or vegetative organs. Here, the weight of seeds or vegetative reproductive organs means the weight of seeds or vegetative reproductive organs before sowing or planting and before applying the composition of the present invention.

  When the composition of the present invention is processed into seeds or vegetative organs, an adjuvant may be mixed with the composition of the present invention as necessary. In addition, when applying the composition of the present invention, this compound and this component may be applied separately, before and after seeding seeds or vegetative reproductive organs to which either this compound or this component is attached to a cultivation carrier. The other may be applied to the cultivation carrier.

  The weight ratio between the application amount of the present compound and the application amount of this component in the composition A is the type of plant to be protected, the harmful arthropod to be controlled, the type and frequency of occurrence of phytopathogenic microorganisms or weeds, formulation Depending on the form, application time, application method, application location, weather conditions, etc., the weight ratio can be adjusted appropriately. For example, in the agricultural field, when applied to plants (especially, foliage, seeds, vegetative organs) or when applied to a cultivation carrier (especially soil) for cultivating plants, the following weight ratios can be mentioned.

With regard to the components contained in group (a), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (a)) = 1: 1000 to 1000: 1, preferably 100 : 1 to 1: 100, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5 : 1, 10: 1, 20: 1, 50: 1;
With regard to the components included in group (b), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (b)) = 1: 100 to 10,000: 1, preferably Is in the range of 1:10 to 1000: 1, more preferably in the range of 1: 1 to 100: 1, for example 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2. 1: 1, 2: 1, 3: 1, 5: 1, 10: 1, 20: 1, 50: 1, 100: 1, 200: 1, 300: 1, 400: 1, 500: 1;
With regard to the components included in group (c), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (c)) = 1: 1000 to 1000: 1, preferably 100: 1 to 1: 100, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5: 1, 10: 1, 20: 1, 50: 1;
With regard to the components contained in group (d), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (d)) = 1: 1000 to 1000: 1, preferably 100 : 1 to 1: 100, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5 : 1, 10: 1, 20: 1, 50: 1;
With regard to the components included in group (e), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (e)) = 1: 1000 to 10,000: 1, preferably Is in the range of 1: 100 to 100: 1, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1 5: 1, 10: 1, 20: 1, 50: 1;
With regard to the components included in group (f), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (f)) = 1: 1000 to 1000: 1, preferably 100 : 1 to 1: 100, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1 5: 1, 10: 1, 20: 1, 50: 1;
With regard to the components contained in group (g), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (g)) = 1: 1000 to 1000: 1, preferably 1 : 100 to 100: 1, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5 : 1, 10: 1, 20: 1, 50: 1;
With regard to the components included in group (h), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (h)) = 1: 1000 to 1000: 1, preferably 1 : 100 to 100: 1, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5 : 1, 10: 1, 20: 1, 50: 1;
With regard to the components included in group (i), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (i)) = 1: 1000 to 1000: 1, preferably 1 : 100 to 100: 1, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5 : 1, 10: 1, 20: 1, 50: 1.

The component selected from the group (j) is usually prepared by a culture method known in the art. For example, when the component selected from the group (j) is a bacterium or a fungus, it is prepared by a medium known in the art and a known fermentation method. In the case of virus or nematode, it is prepared by a culture method known in the art. When this component is a bacterium or a filamentous fungus, its preparation is 1 × 10 ⁴ to 1 × 10 ¹³ CFU (colony forming unit) per gram, preferably 1 × 10 ⁸ to 1 × 10 ¹² CFU. including. When this component is a virus, the preparation is 1 × 10 ⁴ to 1 × 10 ¹³ embedded bodies (sometimes referred to as occlurion bodies, sometimes referred to as Obs), preferably 1 × 10 ⁸ to 1 × Contains this component of 10 ¹² embedded bodies (sometimes referred to as occlurion bodies, sometimes referred to as Obs). When the component is a nematode, the preparation contains 1 × 10 ⁴ to 1 × 10 ¹³ individuals, preferably 1 × 10 ⁸ to 1 × 10 ¹² individuals of the component per gram.

  When the composition selected from the group (j) is contained in the composition of the present invention, (present compound): (one or more components selected from the group (j)) = 1: irrespective of the presence or absence of other components The range is 10,000 to 10,000: 1, preferably 1: 1000 to 1000: 1. For example, 1: 500, 1: 400, 1: 300, 1: 200, 1: 100, 1:50, 1:10, 1: 5, 1: 1, 5: 1, 10: 1, 20: 1, 50: 1, 100: 1, 200: 1, 300: 1, 400: 1, 500: 1. . The weight ratio of one or more components selected from group (j) means the total weight of the preparation of one or more components selected from group (j). For example, a weight ratio of 1: 500 means 500 parts by weight of a preparation of one or more components selected from group (j) per 1 part by weight of the compound.

  The composition of the present invention is effective against harmful arthropods such as harmful insects and harmful mites, harmful nematodes, and harmful molluscs. Examples of harmful arthropods, harmful nematodes, and harmful molluscs include the following.

  Hemiptera: Japanese green planthopper (Laodelphax striatellus), yellow planthopper (Nilaparvata lugens), white-tailed planthopper (Sogatella furcifera), corn planter (Peregrinus maidis), yellow-spotted plantfish (Javesella pellucida), blackfish planter Delphacidae; Nephotettix cincticeps, Nephotettix virescens, Nephotettix nigropictus, Recilia dorsalis, Eki ca , Cornleaf hopper (Dalbulus maidis), Cofana spectra, etc. (Cicadellidae); Mahanarva posticata, Mahanarva fimbriolata, etc. (Cercopidae); Mussels (Aphis fabae), soybean aphids (Aphis glycines), cotton aphids (Aphis gossypii), European apple aphids (Aphis pomi), snowy aphids (Aphis spiraecola), peach aphids (Myzus persicae), wheat worms hel cyra , Radish aphids (Brevicoryne brassicae), Rosy apple aphid (Dysaphis plantaginea), black radish aphids (Lipaphis erysimi), tulip beetle aphids (Macrosiphum euphorbiae), potato beetle aphids (Aulacorthum solani), aphids Aphids (Rhopalosiphum padi), corn aphids (Rhopalosiphum maidis), citrus aphids (Toxoptera citricida), peach beetle (Hyalopterus pruni), hyena aphids (Melanaphis sacc) hari), Tetraneura nigriabdominalis, Ceratovacuna lanigera, Eriosoma lanigerum, etc. Aphididae; Grape aphid, Pak phyllera Phylloxeridae such as phylloxera (Phylloxera notabilis), Southern pecan leaf phylloxera (Phylloxera russellae); Adelges tsugae; Adelges piceae; Scotinophara lurida, Malayan rice black bug (Scotinophara coarctata), Nezoara antennata, Eysarcoris aeneus, Eysarcoris ys Eysarcoris annamita, Halyomorpha halys, Southern stink bug (Nezara viridula), Brown stink bug (Euschistus heros), Red banded stink bug (Piezodorus guildinii), Oebalus pugnalac, ae ; Burrower brown bug (Scaptocoris castanea) and other horned bugs (Cydnidae); Crestus punctiger, Leptoglossus australis, etc. ) Etc. gaeidae); Trigonotylus caelestialium; Stenotus rubrovittatus; Stenodema calcarata; Lyario lineolaris; Triridae; Tobacco whitefly (Bemisia tabaci), citrus whitefly (Dialeurodes citri), citrus whitefly (Aleurocanthus spiniferus), scallop whitefly (Aleurocanthus camelliae), scorpionate (Pealius euryida) Abgrallaspis cyanophylli), Aonidiella aurantii, pear beetle (Diaspidiotus perniciosus), stag beetle (Pseudaulacaspis pentagona), worm (Unaspis yanonensis), fake Nonaspis citri, etc. (Diaspididae); Ruby beetle (Ceroplastes rubens), etc., Coccidae; Icerya purchasi, Family (Margarodidae); Phenacoccus solani, Phenacoccus solenopsis, Pterococcus kraunhiae, Pseudococcus comstocki, Cicumococcus trica Pseudococcus calceolariae), Pseudococcus longispinus, Tattlemy Lee bug (Brevennia rehi) and other species of Pseudococcidae; Diaphorina citri; rytreae), Pepylthia cactus (Ccopsylla pyricuga), Pear psylla (Cacopsylla pyricola), Pear uchlla (Ccopsylla pyricuga) marmorata), Stephanitis nashi, Stephanitis pyrioides, and other species (Tingidae); Cicadidae; Brazilian turtle (Triatoma infestans), Venezuelan turtle (Rhodonius prolixus), etc.

  Lepidoptera: Green squirrel (Chilo suppressalis), Darkheaded stem borer (Chilo polychrysus), White stem borer (Scirpophaga innotata), Scirpophaga incertulas, Rupela albina, Cnaphalocrocisas medinalis, Cnaphalocrocisas medinalis, Casino maiga (Marasmia exigua), cotton mackerel (Notarcha derogata), green magnolia (Ostrinia furnacalis), European corn borer (Ostrinia nubilalis), yellow-tailed mackerel (Hellula undalis), Monpetronomarelus (Principal), Herpetogramma luctuoseter Caseworms (Nymphula depunctalis), Sugarcane borer (Diatraea saccharalis), etc. (Crambidae); (Cadr a cautella, Pyralidae; Spodoptera litura, Spodoptera exigua, Mythimna separata, Mamestra brassicae, Srangia inferens Na aenescens, Spodoptera frugiperda, African white scallop (Spodoptera exempta), Agrotis ipsilon, Amantis uwaba (Autographa nigrisigna), Akinosawaba (Plusia festucae), Sorybean tricho (plus) spp. alis), Cotton leafworm (Alabama argillacea), Hop vine borer (Hydraecia immanis), etc. (Noctuidae); dimorpha, leguminivora glycinivorella, Matsumuraeses azukivora, Adoxophyes orana fasciata, Adoxophyes honmai, Homona magnanima, fumonaco (Cydia pomonella), Tetramoera schistaceana, Bean Shoot Borer (Epinotia aporema), Citrus fruit borer (Ecdytolopha aurantiana), Tortricidae; Caloptilia theivora; Hosoga ( Gracillariidae); Carposinidae such as Carposina sasakii; Caroffinidae such as Coffee Leaf miner (Leucoptera coffeella), Lyonetia clerkella; Lymantria spp., Euproctis pseudoconspersa, Euproctis spp. Lymantriidae, Plutellidae such as Plutella xylostella Lineatella, Helcystogramma triannulella, Cotton moth (Pectinophora gossypiella), Potato moth (Phthorimaea operculella), Tuta absoluta, etc. Telchin licus) Castniidae; Cossus insularis, etc. (Cossidae); Artemidae, such as Ascotis selenaria; Geometridae, etc .; masinissa, etc. (Stathmopodidae); Acherontia lachesis, etc., Sphingidae; ; Ceratoidaceae (Hesperiidae) such as Parnara guttata, Tinea translucens, Tineola bisselliella, etc. (Tinedae).

  Thysanoptera: Citrus thalis (Frankliniella occidentalis), Thrips palmi, Scirtothrips dorsalis, Thrips tabasa, Thrips tabasa, Thrips tabasa, Thrips tabasa , Thripidae, such as Echinothrips americanus;

  Diptera: Anthomyiidae such as Dela platura, Delia antiqua, Pegomya cunicularia; Udidiidae such as sugar beet root mygot Agromyza oryzae, tomato leaffly (Liriomyza sativae), bean leaffly (Liriomyza trifolii), leafhopper (Chromatomyia horticola) and other leafhoppers (Agromyzidae); Bactrocera cucurbitae), Bactrocera dorsalis, Salmonella (Bactrocera latifrons), Olive fruit fly (Bactrocera oleae), Quinland fruit fly (Bactrocera tryoni), Ceratitis capitamon (ha) Tephritidae such as Rhacochlaena japonica; Hydrellia griseola, Hydrellia philippina, Hydrellia sasakii, etc. Drosophila suzukii, etc. Drosophilidae; Megaselia spiracularis, etc. Phoridae; Clogmia albipunctata, etc. Psychodidae Sciaridae; Cecidomyiidae such as Mayetiola destructor and Orseolia oryzae; Diopsidae such as Diopsis macrophthalma; Common agula cranefly (Tipula ol eracea), European cranefly (Tipula paludosa), etc. (Tipulidae); Culex pipiens pallens, Culex tritaeniorhynchus, Culex pipiens f. ), Mosquito (Culex vishnui), Aedes albopictus, Aedes aegypti, Anopheles sinesis, Anopheles gambiae, Anopheleshen , Anopheles sundaicus, Anopheles arabiensis, Anopheles funestus, Anopheles darlingi, Anopheles farauti, Anopheles minimus and other mosquitoes (Culicidae); trigonus) etc. Tabaidae; Musca domestica, Muscina stabulans, Stomoxys calcitrans, Haematobia irritans, etc. Muscidae; Calliphoridae; (Chironomus plumosus), Chironomus yoshimatsui, Glyptotendipes tokunagai, and other Chironomidae, and Fannidae.

  Coleoptera: Western corn root worm (Diabrotica virgifera virgifera), Southern corn root worm (Diabrotica undecimpunctata howardi), Northern corn root worm (Diabrotica barberi), Mexican corn root worm (Diabrotica virgifera zeae), Banded Cucumber beetle balteata), Cucurbit Beetle (Diabrotica speciosa), bean leaf beetle (Cerotoma trifurcata), terrestrial beetle (Oulema melanopus), cucumber leaf beetle (Aulacophora femoralis), pheasant leaf beetle (Phyllotreta striolata), cabbage flea beifer (lebwest crifer beef) flea beetle (Phyllotreta pusilla), Cabbage stem flea beetle (Psylliodes chrysocephala), Colorado potato beetle (Leptinotarsa decemlineata), rice beetle (Oulema oryzae), grape corapis (Colaspis brunnea), corn flare beet (Chaetocnema pulicaria), sweet potato beetle (Chaetocnema confinis), potato flare beetle (Epitrix cucumeris), rice beetle (Dicladispa armigera), southern corn leaf beetle (Myochrous denticollis), quadricorn acc Chrysomelidae such as Epitrix hirtipennis; Carabidae such as Seedcorn beetle (Stenolophus lecontei), Slender seedcorn beetle (Clivina impressifrons); Anomala cuprea, Anomala Arubobo , Populus japonica, Heptophylla picea, European Chafer (Rhizotrogus majalis), Tomarus gibbosus, Holotrichia spp., Phyllophaga crhyophaaga ), D Scarabaeidae, such as the genus Diloboderus (Diloboderus spp.), such as iloboderus abderus; Araecerus coffeae, Cylas formicarius, Euspes postfasciayp (Sitophilus zeamais), weevil (Sitophilus oryzae), granary weevil (Sitophilus granarius), weevil (Echinocnemus squameus), rice weevil (Lissorhoptrus oryzophilus), white weevil (Rhabdothmusum weevil) Weevil (Sphenophorus venatus), Southern Corn Billbug (Sphenophorus callosus), Soybean stalk weevil (Sternechus subsignatus), Sugarcane weevil (Sphenophorus levis), Sabichoane weevil (Scepticus griseus) Scepticus uniformis, Brazilian weevil (Zabrotes subfasciatus), pine beetle (Tomicus piniperda), Coffee Berry Borer (Hypothenemus hampei), Aracanthus mourei and other Aracanthus spp. Curculionidae; Tribium castaneum, Tribolium confusum, Alphitobius diaperinus, etc. (Tenebrionidae); ; Lyctus brunneus, Rhizopertha dominica, and other species of Bostrychidae; Melanonotus okinawensis, Agriotes fuscicollis, Melanonotus legatus, Anchastus spp., Conoderus spp., Ctenicera sp, Ctenicera spp. Limonius spp., Aeolus genus (Aeolus spp.), Etc., Elateridae; Paederus fuscipes, etc. maculates), Dermestidae, such as Trogoderma granarium; Anobidae, such as Lasioderma serricorne; Stenobium paniceum; Department (Laemophloeidae ; Saw-tooth grain beetle (Oryzaephilus surinamensis) Hosohiratamushi family, etc. (Silvanidae).

  Orthoptera: Tolocama migratoria, Moroccan grasshopper (Dociostaurus maroccanus), Australian grasshopper (Chortoicetes terminifera), red locust (Nomadacris septemfasciata), Brown Locust (Locustana pardalina), Tree Locust (Locustana pardalina), Tree Locust (Locustana pardalina) Locust (Calliptamus italicus), Differential grasshopper (Melanoplus differentialis), Two striped grasshopper (Melanoplus bivittatus), Migratory grasshopper (Melanoplus sanguinipes), Red-Legged grasshopper (Melanoplus femurrubrum), Clearwinged grasshopper (Camnula pellucida) ), Yellow-winged locust (Gastrimargus musicus), Spur-throated locust (Austracris guttulosa), Cobainago (Oxya yezoensis), Scarlet moth (Oxya japonica), Thai winged locust (Patanga succincta), etc. ntalis), Gryllotalpidae; European crickets (Acheta domestica), crickets (Gryllidae) such as Teleogryllus emma;

  Hymenoptera: Tenthledinidae such as Athalia rosae, Athalia japonica; Tenthredinidae; Solenopsis geminata; Solenopsis spp. leaf-cutting ant (Atta capiguara) and other species of genus Atta spp., genus Acromyrmex spp., scorpion (Paraponera clavata), rugliari (Ochetellus glaber), common ant (Monomorium pharaonis), humiliate ant (Linepithema ile) ), Black ants (Formica fusca japonica), red ants (Pristomyrmex punctutus), giant ants (Pheidole noda), crested ants (Pheidole megacephala), black ants (Camponotus japonicus), red-tailed ants (Camponotus obscuripes), etc. (Pogonomyrmex occidentalis), etc. mex), genus Wasmania, such as Wasmania auropunctata, ant family (Formicidae), such as Anoplolepis gracilipes; Vespa mandarinia japonica, Vespa simillimais, Fabric Viuspa ), Vespa velutina, Polistes jokahamae, and other vespidae (Vespidae); Urocerus gigas, such as Siricidae, and Bethylidae.

  Cockroach (Blattodea): German cockroach (Blattellidae) such as German cockroach (Blattellidae); Black cockroach (Periplaneta fuliginosa), American cockroach (Periplaneta americana), Greater cockroach (Periplaneta brunnea), British cockroach ali (Blatta or cockroach ali) (Blattidae); Yamato termite (Reticulitermes speratus), termite (Coptotermes formosanus), American ant termite (Incisitermes minor), scallop termite (Cryptotermes domesticus), taiwan termite (Odontotermes formosanus), quasi termite (hunts termite) Glyptotermes satsumensis), Glyptotermes nakajimai, Caterpillars (Glyptotermes fuscus), Termites (Hodotermopsis sjostedti), Crested termites (Coptotermes guangzhouensis), Amamishiro Reticulitermes amamianus, Reticulitermes miyatakei, Remulitermes kanmonensis, Takashi termites (Nasutitermes takasagoensis), Nitto termites (Pericapritermes nitobei), Musi termites (Sino termites, Mumri termites) ).

  Flea eyes (Siphonaptera): Pulex genus such as human flea (Pulex irritans), Ctenocephalides felis such as cat flea (Ctenocephalides canis), Xenopsylla cheungs such as Xenopsylla cheopis, Genus Tunga, Echidnophaga gallinacea, etc., and Nosopsyllus genus, such as European rat minnow (Nosopsyllus fasciatus).

Psocodae: Pediculus genus such as head lice (Pediculus humanus capitis), Phtirus genus such as pheasants (Pthirus pubis), Haematopinus eurysternus, Haemalpinus eus such as Haematopinus suis Damalinia genus such as Damalinia bovis, bovine white lice (Linognathus vituli), sheep trunk parasitic white lice (Linognathus ovillus), etc. Menopon, Trimenopon spp., Trinoton spp., Trichodectes genus such as Trichodectes canis, Felicola genus such as cat lice (Felicola subrostratus), Bovicola genus such as Bovicola bovis, Menacanthus genus such as wolf lice (Menacanthus stramineus), Werneckiella spp., Lepikentron spp., Liposcelis subfuscas, Liposcelis bostrychophilus, Liposcelis simulans, Liposcelis divinatorcelis Liposcelididae, etc.
.

  Thysanura: Lepismatidae, such as Ctenoepisma villosa and Lepisma saccharina.

  Acari: Acrid: Tetranychus urticae, Tetranychus kanzawai, Mitranous spider mites (Tetranychus evansi), Citrus spider mites (Panonychus ulmi); ); Citrus ticks (Aculops pelekassi), Phyllocoptruta citri, Tomato rustic ticks (Aculops lycopersici), Chinese radish (Calacarus carinatus), Chinese radish (Acaphylla theavagrans), Mites Aculus schlechtendali, Aceria diospyri, Aceria tosichella, Sheevtchenkella sp., Etc., Eriophyidae; nicis, etc., Tenuipalpidae; Tuckerellidae; Ixodidae, for example Haemaphysalis longicornis, Haemaphysalis flava, Haemaphysali, etc. Dermacentor genus such as Dermacentor variabilis, Dermacentor taiwanicus, Dermacentor andersoni, Ixodes ovatus, Ixodes persulcatus, Western legged cap (Ixodes persulcatus) Ixodes pacificus, Ixodes genus such as Ixodes holocyclus, Amblyomma americanum, Amblyomma genus such as Ambryomma maculatum, Rhipicephalus (Boophil us) microplus), Boophilus genus such as Boophilus annulatus, Rhipicephalus sanguineus, Rhipicephalus appendiculatus and other Rhipicephalus genus; Tyrophagus putria Tyrophagus similis, Acaridae; Dermatophagoides farinae, Dermatophagoides pteronyssinus, Pyroglyphidae; Cheyletus eruditus, mite Clawlet ticks (Cheyletiella yasguri), etc. (Cheyletidae); Argas persicus (Argas persicus) genus, Ornithodorus hermsi, Ornithodorus turikata (Ornithodorus t uricata) and other genus Ornithodorus genus, scorpion genus Psoroptes ovis, psoroptes genus such as Psoroptes equi, Knemidocoptes mutans genus Knemidocoptes genus, Notoedres genus such as Notoedres muris, Sarcoptes genus such as Sarcoptes scabiei, Otodectes genus such as Octodectes cynotis, Listrophorus sp. ), Spider mites (Hypodectes spp.), Pterolichus spp., Cytodites spp., Laminosioptes spp., Dermanyssus genus such as Dermanyssus gallinae, Triys House dust mite (Ornithonyssus b genus Ornithonyssus such as acoti), Varroa such as Varroa jacobsoni, Cheletiella yasguri, Cheletiella blakei, Ornithocheyletia spp. Demodex genus such as Demodex canis, Caterpillar mite (Demodex cati), Myobia spp., Psorergates spp., Trombicula akamushi, Trombicula pallida, Trombicula scutellaris).

Araneae: Eutrichuridae such as Cheracanthium japonicum; Theridiidae such as Latrodectus hasseltii.
Polydesmida: Paradoxosomatidae, such as Oxidus gracilis and Nedyopus tambanus.
Isopoda: Armadillidiidae, such as Armadillidium vulgare.
Chiropoda: Scutigeridae, such as Thereuonema hilgendorfi; Scolopendridae, such as Scolopendra subspinipes;
Gastropoda: Limax marginatus, Limax flavus, and other scallops (Limacidae); Slug (Meghimatium bilineatum), etc. Ampullariidae; Austropeplea ollula, etc. (Lymnaeidae).

  Nematoda: Aphelenchoididae, such as Aphelenchoides besseyi; Pratylenchus coffeae, Pratylenchus brachyurus, Pratylenchus Rads, Pratylenchus negus Pratylenenchidae such as similis; Javaloid nematode (Meloidogyne javanica), Sweet potato nematode (Meloidogyne incognita), Kitane nematode (Meloidogyne hapla), soybean cyst nematode (Heterodera glycines), potato moth Heteroderidae such as Globodera pallida; Hoplolymidae such as Rotylenchulus reniformis; Nothotylenchus acris, Dityrenx gypsi Anguinidae such as itylenchus dipsaci; Tylenchulidae such as Tylenchulus semipenetrans; Longidoridae such as Xiphinema index; Trichodolae; Parasitaphelenchidae such as Bursaphelenchus xylophilus.

Within the above-mentioned harmful insects, harmful arthropods such as harmful mites, harmful molluscs, and harmful nematodes, variation within the species is not limited. In other words, harmful arthropods, harmful molluscs, and harmful nematodes that are less sensitive (also known as resistant) to certain insecticides, acaricides, molluscicides and nematicides It is. Examples of the insecticide, the acaricide, the molluscicide and the nematicide include group a1 to group a18.
Group a1: Acetylcholinesterase inhibitors alanycarb, aldicarb, bendiocarb, benfuracarb, butocarboxim, butoxycarboxim, carbaryl (NAC), Carbofuran, carbosulfan, ethiofencarb, fenobucarb (BPMC), formethanate, furathiocarb, isoprocarb (MIPC), methiocarb, methomyl , Metolcarb, oxamyl, pirimicarb, propoxur (PHC), thiodicarb, thiofanox, triazamate, trimeta Rumeth (trimethacarb), xylylcarb (acephate), azamethiphos (azamethiphos), azinphos-ethyl, azinphos-methyl, cadusafos, chlorethoxyfos, chlorvinbinphos ), Chlormephos, chlorpyrifos, chlorpyrifos-methyl, coumaphos, cyanophos (CYAP), demeton-S-methyl, diazinon, Dichlorvos (DDVP), dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, fanfhur, fenamifos (f) enamiphos, fenitrothion (MEP), fenthion (MPP), fosthiazate, heptenophos, imityaphos, isofenphos, isopropyl-O- (methoxyaminothiophosphoryl) salicylate (isopropyl) -O- (methoxyaminothiophosphoryl) salicylate), isoxathion, malathion, mecarbam, methamidophos, methidathion (DMTP), mevinphos, monocrotophos, nared : BRP), omethoate, oxydemeton-methyl, parathion, parathion-methyl, phentoate (PAP), phorate, phosalone, phoalone Met (phosmet: PMP), phosphamidon (phosphamidon), phoxim (pixim), pirimiphos-methyl, profenfos (profenofos), propetamphos (propetamphos), prothiofos (prothiofos), pyracrophos (pyraclofos), pyridafenthion (pyridaphenthion) (Quinalphos), sulfotep, tebupirimfos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon (DEP) and bamidthione A group consisting of (vamidothion).
Group a2: The group consisting of GABAergic chloride channel antagonist etiprole, fipronil and flufiprole.
Group a3: sodium channel modulators acrinathrin, allethrin, bifenthrin, kappa-bifenthrin, bioallethrin, bioresmethrin, cycloprothrin, cyfluthrin (Cyfluthrin), beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha cypermethrin (alpha- cypermethrin), beta-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, sigma-cypermethrin, cyphenothrin, deltamethrin thrin), empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, fluvalinate ( fluvalinate, tau-fluvalinate, halffenprox, heptafluthrin (heptafluthrin), imiprothrin, kadesthrin, meperfluthrin, monfluorothrin (momfluorothrin), permethrin permethrin), phenothrin, prallethrin, pyrethrin, resmethrin, silafluofen, tefluthrin, kappa-tefluthrin , Tetramethrin, tetramethylfluthrin, tralomethrin, transfluthrin, benfluthrin, flufenprox, flumethrin, furamethrin, methfluthrin The group consisting of metofluthrin), profluthrin and dimefluthrin.
Group a4: nicotinic acetylcholine receptor competitive modulators acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxurone, thiamethoxam , Sulfoxaflor, cycloxaprid, triflumezopyrim, dicloromezotiaz, and flupyrimine.
Group a5: Group consisting of nicotinic acetylcholine receptor allosteric modulators spinosad and spinetoram.
Group a6: glutamatergic chloride channel allosteric modulator abamectin, emamectin benzoate, lepimectin, milbemectin, dimadectin, doramectin, eprinomectin A group consisting of ivermectin, latidectin, selamectin, milbemycin D, moxidectin and nemadectin.
Group a7: The group consisting of juvenile hormones mimic hydroprene, kinoprene, metoprene, phenoxycarb and pyriproxyfen.
Group a8: A group consisting of the string organ TRPV channel modulators Pymetrozine and Pyrifluquinazon.
Group a9: Bacillus sphaericus, Bacillus thuringiensis strain BD # 32, Bacillus thuringiensis strain AQ52, Bacillus thuringiensis strain AQ52, Bacillus thuringiensis subsp. Aizawai strain ABTS-1857 (Bacillus thuringiensis subsp. Aizawai strain ABTS-1857), Bacillus thuringiensis subsp. Kurstaki strain HD-1), Bacillus thuringiensis subsp. Thuringiensis cristaki subsp. BMP123 strain (Bacillus thuringiensis subsp.kurstaki strain BMP123), Bacillus thuringiensis subsp. var. israelensis), Bacillus thuringiensis Aegypti (Bacillus thuringiensis var.aegypti), Bacillus thuringiensis var.colmeri, Bacillus thuringiensis var.darmstadiensis, Dendrolimus varieties (Bacillus thuringiensis var.dendrolimus), Bacillus thuringiensis galeria varieties (Bacillus thuringiensis var. Morrisoni), Bacillus thuringiensis var. San diego, Bacillus thuringiensis subsp. MPPL002 strain (Bacillus thuringiensis subsp. Thuringiensis strain MPPL0) 02), Bacillus thuringiensis 7216 variant (Bacillus thuringiensis var. 7216), Bacillus thuringiensis T36 variant (Bacillus thuringiensis var. T36), delta-endotoxins that confer resistance to lepidopteran insects (eg Cry1A, Cry1Ab , Modified Cry1Ab (partially deleted Cry1Ab), Cry1Ac, Cry1Ab-Ac (a hybrid protein fused with Cry1Ab and Cry1Ac), Cry1C, Cry1F, Cry1Fa2 (modified cry1F), moCry1F (modified Cry1F) , Cry1A. 105 (hybrid protein fused with Cry1Ab, Cry1Ac, Cry1F), Cry2Ab2, Cry2Ae, Cry9C, Vip3A, Vip3Aa20), and delta-endotoxins that confer resistance to Coleoptera (eg Cry3A, mCry3A (modified Cry3A)), Cry3Bb1, Cry34Ab1, Cry35Ab1).
Group a10: Group consisting of oxidative phosphorylation uncouplers chlorfenapyr and sulfluramid that disturb the proton gradient.
Group a11: Nicotinic acetylcholine receptor channel blocker bensultap, cartap, cartap hydrochloride, thiocyclam, thiosultap-disodium, and thiosultap monosodium salt ( thiosultap-monosodium).
Group a12: chitin biosynthesis inhibitors bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, The group consisting of lufenuron, novaluron, novifluururon, teflubenzuron, triflumuron and buprofezin.
Group a13: A group consisting of the molting inhibitor Cyromazine.
Group a14: A group consisting of molting hormone (ecdysone) receptor agonists chromafenozide, halofenozide, methoxyfenozide and tebufenozide.
Group a15: Group consisting of voltage-dependent sodium channel blockers indoxacarb and metaflumizone.
Group a16: the group consisting of the acetyl CoA carboxylase inhibitors spirodiclofen, spiromesifen and spirotetramat.
Group a17: Ryanodine receptor modulators chlorantraniliprole, cyantraniliprole, cycloniliprole, flubendiamide, tetraniliprole, cyhalodiamide and A group consisting of tetrachlorantraniliprole.
Group a18: A group consisting of flonicamid, a chordal organ modulator.

  Factors that decrease sensitivity include [1] decreased skin permeability, [2] enhanced metabolism, and [3] amino acid substitution of the target protein. The enhancement of metabolism in [2] means an increase in the activity of metabolic enzymes (also referred to as detoxification enzymes) such as cytochrome P450, carboxylesterase and glutathione S-transferase. In [3], the target protein may have one or more amino acid substitutions. Moreover, it may have one or more of [1] decreased skin permeability, [2] enhanced metabolism, and [3] amino acid substitution of the target protein as a factor of decreased sensitivity.

Examples of harmful arthropods, harmful molluscs, and harmful nematodes such as harmful insects and harmful mites that have decreased sensitivities include the following.
Hemiptera with reduced sensitivity to one or more compounds selected from group a2;
Hemiptera with reduced sensitivity to one or more compounds selected from group a4;
Hemiptera with reduced sensitivity to one or more compounds selected from group a8;
Hemiptera with reduced sensitivity to one or more compounds selected from group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a4;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a8;
One or more compounds selected from group a2, and hemiptera with reduced sensitivity to buprofezin belonging to group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a4 and one or more compounds selected from group a8;
One or more compounds selected from group a4, and Hemiptera with reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from group a8, and hemiptera with reduced sensitivity to buprofezin belonging to group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2, one or more compounds selected from group a4, and one or more compounds selected from group a8;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2, one or more compounds selected from group a4, and buprofezin belonging to group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2, one or more compounds selected from group a8, and buprofezin belonging to group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a4, one or more compounds selected from group a8, and buprofezin belonging to group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2, one or more compounds selected from group a4, one or more compounds selected from group a8, and buprofezin belonging to group a12;
A planthopper family with reduced sensitivity to one or more compounds selected from group a2;
A planthopper with reduced sensitivity to one or more compounds selected from group a4;
A planthopper family with reduced sensitivity to one or more compounds selected from group a8;
A planthopper family with reduced sensitivity to one or more compounds selected from group a12;
A planthopper family with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a4;
One or more compounds selected from group a2 and a planthopper family with reduced sensitivity to pymetrozine belonging to group a8;
One or more compounds selected from group a2, and a planthopper family with reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from group a4, and a planthopper family with reduced sensitivity to pymetrozine belonging to group a8;
One or more compounds selected from group a4, and a planthopper family with reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from group a2, one or more compounds selected from group a4, and a planthopper family with reduced sensitivity to pymetrozine belonging to group a8;
One or more compounds selected from group a2, one or more compounds selected from group a4, and a planthopper family with reduced sensitivity to buprofezin belonging to group a12;
A planthopper family with reduced sensitivity to one or more compounds selected from group a2, pymetrozine belonging to group a8, and buprofezin belonging to group a12;
A planthopper family with reduced sensitivity to one or more compounds selected from group a4, pymetrozine belonging to group a8, and buprofezin belonging to group a12;
One or more compounds selected from group a2, one or more compounds selected from group a4, pymetrozine belonging to group a8, and a planthopper family with reduced sensitivity to buprofezin belonging to group a12;
A brown planthopper, a brown planthopper, or a brown planthopper with reduced sensitivity to one or more compounds selected from group a2;
A brown planthopper, a brown planthopper, or a brown planthopper with reduced sensitivity to one or more compounds selected from group a4;
A brown planthopper, a brown planthopper, or a brown planthopper with reduced sensitivity to one or more compounds selected from group a8;
A brown planthopper, a brown planthopper, or a brown planthopper with reduced sensitivity to one or more compounds selected from group a12;
One or more compounds selected from group a2 and one or more compounds selected from group a4 and having reduced sensitivity to one or more compounds selected from group a4;
One or more compounds selected from group a2 and a brown planthopper, white-spotted planthopper, or brown planthopper with reduced sensitivity to pymetrozine belonging to group a8;
One or more compounds selected from group a2 and a brown planthopper, white-spotted planthopper, or brown planthopper with reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from the group a4, and a brown planthopper, sedge plant, or a planthopper with reduced sensitivity to pymetrozine belonging to the group a8;
One or more compounds selected from the group a4 and a brown planthopper, white-spotted planthopper, or a brown planthopper with reduced sensitivity to buprofezin belonging to the group a12;
One or more compounds selected from the group a2, one or more compounds selected from the group a4, and a brown planthopper, white-spotted planthopper, or a brown planthopper having reduced sensitivity to pymetrozine belonging to the group a8;
One or more compounds selected from group a2, one or more compounds selected from group a4, and a brown planthopper, white-spotted planthopper, or a brown planthopper having reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from group a2, pymetrozine belonging to group a8, and a brown planthopper, white-spotted planthopper, or a brown planthopper with reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from the group a4, pymetrozine belonging to the group a8, and a brown planthopper, white-spotted planthopper, or a brown planthopper with reduced sensitivity to the buprofezin belonging to the group a12;
One or more compounds selected from the group a2, one or more compounds selected from the group a4, pymetrozine belonging to the group a8, and a brown planthopper, white-spotted planthopper, or a brown planthopper with reduced sensitivity to the buprofezin belonging to the group a12;
Aphids with reduced sensitivity to one or more compounds selected from group a3;
Aphids with reduced sensitivity to one or more compounds selected from group a8;
Aphids with reduced sensitivity to one or more compounds selected from group a3 and one or more compounds selected from group a4;
Aphids with reduced sensitivity to one or more compounds selected from group a3 and one or more compounds selected from group a8;
Aphids with reduced sensitivity to one or more compounds selected from group a4 and one or more compounds selected from group a8;
Aphids with reduced sensitivity to one or more compounds selected from group a3, one or more compounds selected from group a4, and one or more compounds selected from group a8;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a3;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a4;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a8;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a3 and one or more compounds selected from group a4;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a3 and one or more compounds selected from group a8;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a4 and one or more compounds selected from group a8;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a3, one or more compounds selected from group a4, and one or more compounds selected from group a8;
Lepidoptera with reduced sensitivity to one or more compounds selected from group a14;
Lepidoptera with reduced sensitivity to one or more compounds selected from group a15;
Lepidoptera with reduced sensitivity to one or more compounds selected from group a17;
Lepidoptera with reduced sensitivity to one or more compounds selected from group a14 and one or more compounds selected from group a17;
Diamondback moth with reduced sensitivity to one or more compounds selected from group a15;
Diamondback moth with reduced sensitivity to one or more compounds selected from group a17;
Corn borers with reduced sensitivity to one or more compounds selected from group a14;
Corn borers with reduced sensitivity to one or more compounds selected from group a17;
One or more compounds selected from the group a14, and a Cobb rice moth having reduced sensitivity to one or more compounds selected from the group a17;
Chahamaki with reduced sensitivity to one or more compounds selected from group a14;
Chahamaki with reduced sensitivity to one or more compounds selected from group a17;
Chanococmon anemone with reduced sensitivity to one or more compounds selected from group a14;
Chanococmon anemone with reduced sensitivity to one or more compounds selected from group a17;
One or more compounds selected from group a14, and a chinook leaf beetle with reduced sensitivity to one or more compounds selected from group a17;
Coleoptera with reduced sensitivity to one or more compounds selected from group a2;
Coleoptera with reduced sensitivity to one or more compounds selected from group a3;
Coleoptera with reduced sensitivity to one or more compounds selected from group a4;
Coleoptera with reduced sensitivity to one or more compounds selected from group a9;
Coleoptera with reduced sensitivity to one or more compounds selected from group a17;
Coleoptera with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a4;
Chrysomelidae with reduced sensitivity to one or more compounds selected from group a2;
Chrysomelidae with reduced sensitivity to one or more compounds selected from group a3;
Chrysomelidae with reduced sensitivity to one or more compounds selected from group a4;
Chrysomelidae with reduced sensitivity to one or more compounds selected from group a9;
Chrysomelidae with reduced sensitivity to one or more compounds selected from group a17;
One or more compounds selected from group a2 and potato beetles with reduced sensitivity to one or more compounds selected from group a4;
Rice dwarf rice with reduced sensitivity to one or more compounds selected from group a2;
Rice dwarf rice with reduced sensitivity to one or more compounds selected from group a4;
Rice drab beetle with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a4;
The genus Diabrotica with reduced sensitivity to one or more compounds selected from group a2;
The genus Diabrotica with reduced sensitivity to one or more compounds selected from group a3;
The genus Diabrotica with reduced sensitivity to one or more compounds selected from group a4;
The genus Diabrotica with reduced sensitivity to one or more compounds selected from group a9;
The genus Diabrotica with reduced sensitivity to one or more compounds selected from group a17;
Diabrotica virgifera virgifera with reduced sensitivity to one or more compounds selected from group a2;
Diabrotica virgifera virgifera with reduced sensitivity to one or more compounds selected from group a3;
Diabrotica virgifera virgifera with reduced sensitivity to one or more compounds selected from group a4;
Diabrotica virgifera virgifera with reduced sensitivity to one or more compounds selected from group a9;
Diabrotica virgifera virgifera with reduced sensitivity to one or more compounds selected from group a17;
Diabrotica undecimpunctata howardi with reduced sensitivity to one or more compounds selected from group a2;
Diabrotica undecimpunctata howardi with reduced sensitivity to one or more compounds selected from group a3;
Diabrotica undecimpunctata howardi with reduced sensitivity to one or more compounds selected from group a4;
Diabrotica undecimpunctata howardi with reduced sensitivity to one or more compounds selected from group a9;
Diabrotica undecimpunctata howardi with reduced sensitivity to one or more compounds selected from group a17;
Diabrotica barberi with reduced sensitivity to one or more compounds selected from group a2;
Diabrotica barberi with reduced sensitivity to one or more compounds selected from group a3;
Diabrotica barberi with reduced sensitivity to one or more compounds selected from group a4;
Diabrotica barberi with reduced sensitivity to one or more compounds selected from group a9;
Diabrotica barberi with reduced sensitivity to one or more compounds selected from group a17;
Diabrotica speciosa with reduced sensitivity to one or more compounds selected from group a2;
Diabrotica speciosa with reduced sensitivity to one or more compounds selected from group a3;
Diabrotica speciosa with reduced sensitivity to one or more compounds selected from group a4;
Diabrotica speciosa with reduced sensitivity to one or more compounds selected from group a9;
Diabrotica speciosa with reduced sensitivity to one or more compounds selected from group a17;
Colorado potato beetle with reduced sensitivity to one or more compounds selected from group a2;
Colorado potato beetle with reduced sensitivity to one or more compounds selected from group a3;
Colorado potato beetle with reduced sensitivity to one or more compounds selected from group a4;
Colorado potato beetle with reduced sensitivity to one or more compounds selected from group a17;
Kissing beetle with reduced sensitivity to one or more compounds selected from group a3;
Susceptibility to one or more compounds selected from group a4;
Kissing beetle with reduced sensitivity to one or more compounds selected from group a17;
Phyllotreta cruciferae with reduced sensitivity to one or more compounds selected from group a3;
Phyllotreta cruciferae with reduced sensitivity to one or more compounds selected from group a4;
Phyllotreta cruciferae with reduced sensitivity to one or more compounds selected from group a17;
Phyllotreta pusilla with reduced sensitivity to one or more compounds selected from group a3;
Phyllotreta pusilla with reduced sensitivity to one or more compounds selected from group a4;
Phyllotreta pusilla with reduced sensitivity to one or more compounds selected from group a17;
Psylliodes chrysocephala with reduced sensitivity to one or more compounds selected from group a3;
Psylliodes chrysocephala with reduced sensitivity to one or more compounds selected from group a4;
Psylliodes chrysocephala with reduced sensitivity to one or more compounds selected from group a17;
Psylliodes punctulata with reduced sensitivity to one or more compounds selected from group a3;
Psylliodes punctulata with reduced sensitivity to one or more compounds selected from group a4;
Psylliodes punctulata with reduced sensitivity to one or more compounds selected from group a17;
Weevil with reduced sensitivity to one or more compounds selected from group a2;
Weevilaceae with reduced sensitivity to one or more compounds selected from group a4;
One or more compounds selected from group a2 and a weevil with reduced sensitivity to one or more compounds selected from group a4;
Rice weevil with reduced sensitivity to one or more compounds selected from group a2;
Rice weevil with reduced sensitivity to one or more compounds selected from group a4;
Rice weevil with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a4;
A click beetle with reduced sensitivity to one or more compounds selected from group a2;
The beetle with reduced sensitivity to one or more compounds selected from group a3;
A click beetle with reduced sensitivity to one or more compounds selected from group a4;
Okinawa Kanshakumetsuki with reduced sensitivity to one or more compounds selected from group a2;
Okinawa Kanshokumetsuki with reduced sensitivity to one or more compounds selected from Group a3;
Okinawa Kanshakumetsuki with reduced sensitivity to one or more compounds selected from Group a4;
Tobiiromubosokometsuki with reduced sensitivity to one or more compounds selected from group a2;
Tobiiromubosokometeki with reduced sensitivity to one or more compounds selected from group a3;
Tobiiromubosokometsuki with reduced sensitivity to one or more compounds selected from group a4;
A crispiness with reduced sensitivity to one or more compounds selected from group a2;
A crispiness with reduced sensitivity to one or more compounds selected from group a3;
A crispiness with reduced sensitivity to one or more compounds selected from group a4;
The genus Ashibetella with reduced sensitivity to one or more compounds selected from group a2;
The genus Ashibetella with reduced sensitivity to one or more compounds selected from group a3;
The genus Ashibetella with reduced sensitivity to one or more compounds selected from group a4;
Reduced susceptibility to one or more compounds selected from group a2;
Reduced susceptibility to one or more compounds selected from group a3;
Reduced susceptibility to one or more compounds selected from group a4;
Kutenisella sp. With reduced sensitivity to one or more compounds selected from group a2;
Kutenisella sp. With reduced sensitivity to one or more compounds selected from group a3;
Kutenisella sp. With reduced sensitivity to one or more compounds selected from group a4;
Limonius with reduced sensitivity to one or more compounds selected from group a2;
Limonius with reduced sensitivity to one or more compounds selected from group a3;
Limonius with reduced sensitivity to one or more compounds selected from group a4;
A genus Aeolus with reduced sensitivity to one or more compounds selected from group a2;
A genus Aeolus with reduced sensitivity to one or more compounds selected from group a3;
A genus Aeolus with reduced sensitivity to one or more compounds selected from group a4;

Examples of harmful arthropods, harmful molluscs, and harmful nematodes such as harmful insects and harmful mites that have been reduced in sensitivity by amino acid substitution at the target site include the following.
Cotton aphids with R81T amino acid substitution in the β subunit of the nicotinic acetylcholine receptor; Peach aphids with R81T amino acid substitution in the β subunit of the nicotinic acetylcholine receptor;
A diamondback moth with an amino acid substitution of G4946E at the ryanodine receptor;
A diamondback moth having an amino acid substitution of F1845Y or V1848I in the sodium channel;
Seduce plant having an A2'N amino acid substitution at the GABA receptor;

The compounds and compositions A can also be used to protect plants from plant diseases caused by insect-borne viruses or insect-borne bacteria.

Examples of such insect-borne viruses include the following.
Rice tungro spherical virus, Rice tungro bacilliform virus, Rice grassy stunt virus, Rice ragged stunt virus, Rice stripe virus ( Rice stripe virus, Rice black streaked dwarf virus, Southern rice black-streaked dwarf virus, Rice gall dwarf virus, Rice hoja blanca virus), rice yellow stunt virus, rice yellow mottle virus, rice dwarf virus, northern cereal mosaic virus, barley yellow dwarf virus, Barley mild mosaic virus, Barley yellow dwarf virus-PAV, Ruiki萎 RPS virus (Cereal yellow dwarf virus-RPS), wheat yellow leaves virus (Wheat yellow leaf virus), Oat sterile dwarf virus, Wheat streak mosaic virus,
Maize dwarf mosaic virus, Maize stripe virus, Maize chlorotic mottle virus, Maize chlorotic dwarf virus, Maize rayado fino virus, sugarcane mosaic virus, Fiji disease virus, Sugarcane yellow leaf virus Mosaic virus (Soybean mild mosaic virus), Cycas necrotic stunt, Soybean dwarf virus, Milk vetch dwarf virus, Soybean mosaic virus, Alfalfa Mosaic virus (Alfalfa mosaic virus), bean yellow mosaic virus, bean common mosaic virus, southern bean mosaic virus, peanut stunt virus, Sorama Wild bean wilt virus 1, Broad bean wilt virus 2, Broad bean necrosis virus, Broad bean yellow vein virus, Clover yellow vein virus, Peanut mottle virus, Tobacco streak virus, Bean pod mottle virus, Cowpea chlorotic mottle virus, Mung bean yellow mosaic virus, Soybean crinkle leaf virus,
Tomato chlorosis virus, Tomato spotted wilt virus, Tomato yellow leaf curl virus, Tomato aspermy virus, Tomato infectious Tomato infectious chlorosis virus, Potato leafroll virus, Potato virus Y, Melon yellow spot virus, Melon necrotic spot virus ), Watermelon mosaic virus, Cucumber mosaic virus, Zucchini yellow mosaic virus, Turnip mosaic virus, Turnip yellow mosaic virus ), Cauliflower mosaic virus Cauliflower mosaic virus, Lettuce mosaic virus, Celery mosaic virus, Beet mosaic virus, Cucurbit chlorotic yellows virus, Pepper reddening virus (Capsicum chlorosis virus), Beet pseudo yellows virus, Leak yellow stripe virus, Onion yellow dwarf virus, Sweet potato feathery mottle virus ), Sweet potato shukuyo mosaic virus, Strawberry mottle virus, Strawberry mild yellow edge virus, Strawberry pseudo mild yellow edge virus (Strawberry pseudo mild yellow edge virus) ), Ichi Strawberry crinkle virus, Strawberry vein banding virus, plum pox virus, Chrysanthemum stem necrosis virus, Impatiens necrosis virus (Impatiens) necrotic spot virus), Iris yellow spot virus, Lily mottle cirus, Lily symptomless virus, Tulip mosaic virus, etc.

Examples of insect-borne bacteria include the following.
Rice yellow dwarf phytoplasma (Candidatus Phytoplasma oryzae), Candidatus Phytoplasma asteris, Maize bushy stunt phytoplasma, citrus greening fungus Asian type (Candidatus Liberbacter asiaticus), citrus greening fungus African type (Candidatus Liberbacter african disease) Type (Candidatus Liberbacter americanus) etc.

  The present compound and the composition A also have a feeding damage suppressing effect, a repellent effect, an egg laying suppressing effect, an infertility effect, a next generation output suppressing effect, a mating behavior inhibitory effect, a molting inhibitory effect, and an emergence inhibitory effect. As a result, crops can be protected from damage by harmful arthropods such as harmful insects and harmful mites, harmful molluscs, and harmful nematodes.

  The composition of the present invention can also control plant diseases caused by phytopathogenic microorganisms such as fungi, bacteria, oomycetes, and fungi when a bactericidal active ingredient is included as this component. Examples of plant diseases include the following. In parentheses are the scientific names of the phytopathogenic microorganisms that cause each disease.

Rice blast (Magnaporthe grisea), sesame leaf blight (Cochliobolus miyabeanus), blight (Rhizoctonia solani), idiot seedling (Gibberella fujikuroi), yellow dwarf (Sclerophthora macrospora), wheat powdery mildew (Erysiphe) graminis), red mold (Fusarium graminearum, F. avenaceum, F. culmorum, Microdochium nivale), rust (Puccinia striiformis, P. graminis, P. recondita), red snow rot (Microdochium nivale, M.majus), Snow rot microbe nuclei (Typhula sp.), Naked smut (Ustilago tritici), black scab (Tilletia caries, T. controversa), eye spot (Pseudocercosporella herpotrichoides), leaf blight (Septoria tritici), blight Disease (Stagonospora nodorum), macular disease (Pyrenophora tritici-repentis), seedling blight (Rhizoctonia solani), bacterial blight (Gaeumannomyces graminis), barley powdery mildew (Erysiphe graminis), red mold ( Fusarium graminearu m, F. avenaceum, F. culmorum, Microdochium nivale), rust disease (Puccinia striiformis, P.graminis, P.hordei), naked smut (Ustilago nuda), cloud disease (Rhynchosporium secalis), reticular disease (Pyrenophora teres) ), Spot disease (Cochliobolus sativus), leafy leaf disease (Pyrenophora graminea), lambaria disease (Ramularia collo-cygni), Rhizoctonia solani (Rhizoctonia solani); corn rust (Puccinia sorghi), southern rust Diseases (Puccinia polysora), soot rot (Setosphaeria turcica), tropical rust (Physopella zeae), sesame leaf blight (Cochliobolus heterostrophus), anthracnose (Colletotrichum graminicola), gray leaf spot (Cercospora zeae-maydis) ), Brown spot (Kabatiella zeae), Faeosphaeria reef spot disease (Phaeosphaeria maydis), diplodia disease (Stenocarpella maydis, Stenocarpella macrospora), Stokelot disease (Fu) sarium graminearum, Fusarium verticilioides, Colletotrichum graminicola), smut (Ustilago maydis), cotton anthracnose (Colletotrichum gossypii), mildew (Ramularia areola), black spot (Alternaria macrospora, A. gossypii), Thielaviopsis Black root rot disease (Thielaviopsis basicola), coffee rust disease (Hemileia vastatrix), leaf spot disease (Cercospora coffeicola), rape mycorrhizal disease (Sclerotinia sclerotiorum), black spot disease (Alternaria brassicae), rot disease (Phoma) lingam), sugarcane rust (Puccinia melanocephela, Puccinia kuehnii), smut (Ustilago scitaminea), sunflower rust (Puccinia helianthi), downy mildew (Plasmopara halstedii), citrus black spot (Diaporthe disease) (Elsinoe fawcetti), fruit rot (Penicillium digitatum, P. italicum), plague (Phytophthora parasitica, Phytophthora citrophthora), apple monilia (Monilinia) mali), rot (Valsa ceratosperma), powdery mildew (Podosphaera leucotricha), spotted leaf disease (Alternaria alternata apple pathotype), black star disease (Venturia inaequalis), anthracnose (Glomerella cingulata), brown spot disease (Diplocarpon mali) , Ring-tooth disease (Botryosphaeria berengeriana), plague (Phytophtora cactorum), pear black spot disease (Venturia nashicola, V. pirina), black spot disease (Alternaria alternata Japanese pear pathotype), red star disease (Gymnosporangium haraeanum), peach ash star Disease (Monilinia fructicola), black scab (Cladosporium carpophilum), phomopsis sp. (Phomopsis sp.); Grape black rot (Elsinoe ampelina), late rot (Glomerella cingulata), powdery mildew (Uncinula necator), rust (Phakopsora ampelopsidis), Blacklot disease (Guignardia bidwellii), downy mildew (Plasmopara viticola), oyster anthracnose (Gloeosporium kaki), deciduous disease (Cercospora kaki, Mycosphaerella nawae) Colletotrichum lagenarium, powdery mildew (Sphaerotheca fuliginea), vine blight (Didymella bryoniae), brown spot (Corynespora cassiicola), vine split (Fusarium oxysporum), downy mildew (Pseudoperonospora cubensis) , Plague (Phytophthora sp.), Seedling blight (Pythium sp.), Tomato ring rot (Alternaria solani), leaf mold (Cladosporium fulvum), subtilis (Pseudocercospora fuligena), plague (Phytophthora infestans), Powdery mildew (Leveillula taurica), eggplant brown spot (Phomopsis vexans), powdery mildew (Erysiphe cichoracearum), cruciferous vegetable black spot (Alternaria japonica), white spot (Cercosporella brassicae), clubroot (Plasmodiophora) brassicae), downy mildew (Peronospora parasitica), spring onion rust (Puccinia allii), soybean purpura (Cercospora kikuchii), black scab (Elsinoe glycines), black spot (Diaporthe phaseolorum var. sojae), Disease (Phakopsora pachyrhizi), brown ring disease (Corynespora cassiicola), anthrax (Colletotrithum glycines, C. truncatum), leaf rot (Rhizoctonia solani), brown leaf disease (Septoria glycines), spot disease (Cercospora sojina), fungus Nuclear disease (Sclerotinia sclerotiorum), powdery mildew (Microsphaera diffusa), stem blight (Phytophthora sojae), downy mildew (Peronospora manshurica), sudden death (Fusarium virguliforme), kidney bean, Sclerotinia sclerotiorum, rust Disease (Uromyces appendiculatus), horn spot disease (Phaeoisariopsis griseola), anthracnose (Colletotrichum lindemthianum), groundnut black rot (Cercospora personata), brown spot disease (Cercospora arachidicola), white silkworm (Sclerotium rolfsii); Powdery mildew (Erysiphe pisi), potato summer plague (Alternaria solani), plague (Phytophthora infestans), scarlet rot (Phytophthora erythroseptica), powdery scab (Spongospora subterranea) n f. sp. subterranea), half body wilt (Verticillium albo-atrum, V. dahliae, V. nigrescens), strawberry powdery mildew (Sphaerotheca humuli), tea net blast (Exobasidium reticulatum), white scab (Elsinoe) leucospila), ring spot disease (Pestalotiopsis sp.), anthracnose (Colletotrichum theae-sinensis), cigarette scab (Alternaria longipes), anthracnose (Colletotrichum tabacum), downy mildew (Peronospora tabacina), plague (Phytophthora) nicotianae), brown spot of sugar beet (Cercospora beticola), leaf rot (Thanatephorus cucumeris), root rot (Thanatephorus cucumeris), black root (Aphanomyces cochlioides), black spot of rose (Diplocarpon rosae), powdery mildew (Sphaerotheca) pannosa), brown spot of chrysanthemum (Septoria chrysanthemi-indici), white rust (Puccinia horiana), leaf blight of onion (Botrytis cinerea, B. byssoidea, B. squamosa), gray rot (Botrytis alli), Bacterial rot (Bo) trytis squamosa), various crops of gray mold (Botrytis cinerea), mycorrhizal disease (Sclerotinia sclerotiorum), radish black spot (Alternaria brassicicola), buckwheat dollar spot (Sclerotinia homeocarpa), buckwheat brown patch disease and large Patch disease (Rhizoctonia solani), as well as banana sigatoka disease (Mycosphaerella fijiensis, Mycosphaerella musicola).
Seed disease or early growth of various crops caused by Aspergillus, Penicillium, Fusarium, Gibberella, Tricoderma, Thielaviopsis, Rhizopus, Mucor, Corticium, Phoma, Rhizoctonia, and Diplodia Disease. Viral diseases of various crops mediated by Polymixa genus or Olpidium genus.
Rice seed blight (Burkholderia plantarii), cucumber spotted bacterial disease (Pseudomonas syringae pv. Lachrymans), eggplant blight (Ralstonia solanacearum), citrus scab (Xanthomonas citiri), Chinese cabbage soft rot (Erwinia) carotovora) etc.

  For the above plant pathogenic microorganisms, the variation within the species is not particularly limited. That is, it includes those having reduced sensitivity (also referred to as resistance) to a specific fungicide. The decrease in sensitivity may be due to a mutation at the target site (point of action mutation) or may be due to a factor that is not a point of action mutation (non-point of action mutation). With regard to the action point mutation, a mutation in the nucleic acid sequence portion (open reading frame) corresponding to the amino acid sequence of the protein caused amino acid substitution in the target protein, deletion of the suppressor sequence in the promoter region, or enhancer Those in which the protein at the target site is overexpressed due to mutation such as amplification of the sequence or increase in the copy number of the gene are included. Non-acting point mutations include, for example, enhancement of the excretory function of discharging the bactericide that has flowed into the cell out of the cell by ABC transporter, MFS transporter, or the like. Moreover, detoxification by metabolism of a bactericide is also mentioned.

  Examples of the bactericides include nucleic acid synthesis inhibitors (for example, phenylamide bactericides, acylamino acid bactericides, DNA topoisomerase type II bactericides), mitosis and cell division inhibitors (for example, MBC bactericides). Agents, N-phenylcarbamate fungicides), respiratory inhibitors (eg QoI fungicides, QiI fungicides, SDHI fungicides), amino acid synthesis and protein synthesis inhibitors (eg anilinopyrimidine fungicides), signal transduction Inhibitors (eg phenylpyrrole fungicides, dicarboximide fungicides), lipid synthesis and cell membrane synthesis inhibitors (eg phosphorothiolate fungicides, dithiolane fungicides, aromatic hydrocarbon fungicides, heteroaromatics Family fungicides, carbamate fungicides), sterol biosynthesis inhibitors (eg triazole-based DMI fungicides) , Hydroxyanilide fungicides, aminopyrazolinone fungicides), cell wall synthesis inhibitors (eg, polyoxin fungicides, carboxylic acid amide fungicides), melanin synthesis inhibitors (eg, MBI-R fungicides, MBI) -D fungicide, MBI-P fungicide), and other fungicides (for example, cyanoacetamidooxime fungicides, phenylacetamide fungicides).

Examples of the amino acid substitution at the target site include the following.
Cytochrome b: G143A, F129L or G137R;
Cyp51 protein includes A311G, A379G, A381G, A410T, A61V, D107V, D134G, D282E, D411N, E297K, F120L, F219S, F449S, F489L, F495I, G138C / R / S, G312A, G412A, G432S, G434C, G448S, G434C, G448S / Δ, G462A, G464S, G484S, G510C, G54E / K / R / V / W, G54W, H147Y, H303Y, H399P, I145F, I330T, I381V / Δ, I471T, I475T, K142R, K143E, K147Q, K175N, K197N , L50S, L98H, M145L, M220K / I / T / V, M288L, N125I, N178S, N22D, N284H, N513K, P216L, P384S, P394L, Q141H, Q88H, R467K, S188N, S208T, S297T, S405F, S508T, S509T , S524T, S52T, S79T, T289A, T440A, T454P, T469S, V101F, V136A / C / G, V490L, Y121F, Y131F / H, Y132F / H / N, Y134F, Y134F, Y136F, Y137F, Y140F / H, Y145F Y431C, Y459C / D / N / S / P / Δ, Y461D, Y461D / H / S, Y463D / H / N, Y491H or Y68N;
β-tubulin: H6L / Y, Y50C / N / S, Q134K, A165V, E198A / D / G / K / L / Q / V, F200Y, M257L, F200Y, F167Y, Q73R or L240F;
SdhB: H277R / Y, P225H / F / L / T, N230I, H272L / R / V / Y, H278Y / R, H249L / N / Y, H273Y, N225I / T, T268I / A, I269V, H242R, H257L or T253I;
SdhC: H134R, P80H / L, A85V, S73P, T90I, I86F, N88S, H154Y / R, K49E, R64K, N75S, G79R, S135R, N87S, H153R, H146R, I29V, N33T, N34T, T79I / N, W80S, A84V, N86K / S / A, G90R, R151T / S, H152R, I161S, G169D or H151R;
SdhD: H133R, H132R, S89P, G109V, D124E / N, H134R, G138V, D145G, I50F, M114V or D129E;
OS-1 (Shk1): E753K, G420D, I365N / R / S, V368F, Q369H / P, N373S, T447S, F267L, L290S, T765R, Q777R, T489I, E599K or G736Y;
ERG27: S9G, F26S, P57A, T63I, G170R, V192I, L195F, N196T, A210G, I232M, P238S / Δ, P250S, P269L, P298Δ, V309M, A314V, S336C, V365A, E368D, N369D, E375K, A378T, L400F S, Y408S, F412I / S / V / C, A461S or R496T.

  Moreover, the following are mentioned as a phytopathogenic microorganism and its host plant in which the sensitivity with respect to the fungicide fell by overexpressing Cyp51 gene. Septoria tritici in wheat (reference: Pest Management Science. 2012. 68 (7) .1034-1040), Rhynchosporium secalis in barley (reference: Molecular Bilogy and Evolution. 2014. 31 (7) .1793-1802) Phakopsora pachyrhizi (reference: Pest Management Science. 2014. 70 (3) .378-388), apple Venturia inaequalis (reference: Phytopathology. 2016. 106 (6) .562-571), citrus penicillium digitatum (reference) Literature: Applied and Environmental Microbiology. 2000. 66 (8) .3421-3426).

  The phytopathogenic microorganism that can control the composition of the present invention may have a plurality of the above amino acid substitutions. In this case, the plurality of amino acid substitutions may be the same protein or different proteins. Moreover, you may have two or more non-action point mutations and action point mutations. For example, a phytopathogenic microorganism that causes amino acid substitutions of G143A, F129L and G137R in cytochrome b; a phytopathogenic microorganism having an amino acid substitution of G143A in cytochrome b and an amino acid substitution of A311G in Cyp51; G143A in cytochrome b; Phytopathogenic microorganisms with F129L amino acid substitution and Cyp51 with A311G amino acid substitution; cytochrome b with G143A and F129L amino acid substitutions and β-tubulin with H6L / Y amino acid substitutions Furthermore, phytopathogenic microorganisms in which the Cyp51 gene is overexpressed can be mentioned.

Examples of phytopathogenic microorganisms having an action point mutation include the following.
Alternaria alternata having an amino acid substitution of G143A in cytochrome b;
Alternaria arborescens having an amino acid substitution of G143A in cytochrome b;
Alternaria solani having an amino acid substitution of F129L in cytochrome b;
Alternaria tomato having an amino acid substitution of G143A in cytochrome b;
Botryotinia fuckeliana having an amino acid substitution of G143A in cytochrome b;
Glomerella graminicola having an amino acid substitution of G143A in cytochrome b;
Corynespora cassiicola having an amino acid substitution of G143A in cytochrome b;
Cercospora beticola having an amino acid substitution of G143A in cytochrome b;
Cercospora sojina having an amino acid substitution of G143A in cytochrome b;
Cladsporium carpophilum having an amino acid substitution of G143A in cytochrome b;
Colletotrichum graminicola having an amino acid substitution of G143A in cytochrome b;
Glomerella cingulata having an amino acid substitution of G143A in cytochrome b;
Blumeria graminis f. Sp. Hordei having an amino acid substitution of G143A in cytochrome b;
Blumeria graminis f. Sp. Tritici having an amino acid substitution of G143A in cytochrome b;
Parastagonospora nodorum having an amino acid substitution of G143A in cytochrome b;
Monographella nivalis having an amino acid substitution of G143A in cytochrome b;
Microdochium majus, nivale with an amino acid substitution of G143A in cytochrome b;
Mycosphaerella fijiensis having an amino acid substitution of G143A in cytochrome b;
Didymella rabiei having an amino acid substitution of G143A in cytochrome b;
Phakopsora pachyrhizi with an amino acid substitution of F129L in cytochrome b;
Plasmopara viticola having an amino acid substitution of F129L or G143A in cytochrome b;
Pleospora allii having an amino acid substitution of G143A in cytochrome b;
Podosphaera fusca having an amino acid substitution of G143A in cytochrome b;
Podosphaera xanthii having an amino acid substitution of G143A in cytochrome b;
Pseudoperonospora cubensis having an amino acid substitution of G143A in cytochrome b;
Magnaporthe oryzae having an amino acid substitution of F129L or G143A in cytochrome b;
Pyrenophora teres with F129L amino acid substitution in cytochrome b;
Pyrenophora tritici-repentis having an amino acid substitution of F129L, G137R or G143A in cytochrome b;
Pythium aphanidermatum having an amino acid substitution of F129L in cytochrome b;
Thanatephorus cucumeris having an amino acid substitution of F129L or G143A in cytochrome b;
Ramularia collo-cygni having an amino acid substitution of G143A in cytochrome b;
Rhynchosporium secalis with an amino acid substitution of G143A in cytochrome b;
Rhizoctonia solani having an amino acid substitution of F129L in cytochrome b;
Zymoseptoria tritici having amino acid substitution of F129L, G137R or G143A in cytochrome b;
Erysiphe necator having an amino acid substitution of G143A in cytochrome b;
Venturia inaequalis having an amino acid substitution of G143A in cytochrome b;
Ajellomyces capsulatus having an amino acid substitution of Y136F in Cyp51;
Aspergillus flavus having amino acid substitution of Y132N, K197N, D282E, M288L, T469S, H399P, D411N or T454P in Cyp51;
Cyp51 to N22D, S52T, G54E / K / R / V / W, Y68N, Q88H, L98H, V101F, Y121F, N125I, G138C / R / S, Q141H, H147Y, P216L, F219S, M220K / I / T / V, Aspergillus fumigatus having an amino acid substitution of T289A, S297T, P394L, Y431C, G432S, G434C, T440A, G448S, Y491H or F495I;
Aspergillus parasiticus having an amino acid substitution of G54W in Cyp51;
Cypida albicans having an amino acid substitution of A61V, Y132F / H, K143E, S405F, F449S, G464S, R467K or I471T in Cyp51;
Cercospora beticola having an amino acid substitution of E297K, I330T or P384S in Cyp51;
Blumeria graminis f. Sp. Hordei having an amino acid substitution of Y136F, K147Q or S509T in Cyp51;
Blumeria graminis f. Sp. Tritici having an amino acid substitution of C79 with S79T, Y136F, or K175N;
Filobaidiella neoformans having an amino acid substitution of Y145F or G484S in Cyp51;
Monilinia fructicola having an amino acid substitution of Y136F in Cyp51,
Mycosphaerella fijiensis having an amino acid substitution of Y136F, A313G, A381G, Y461D, G462A or Y463D / H / N in Cyp51;
Phakopsora pachyrhizi having an amino acid substitution of F120L, Y131F / H, K142R, I145F or I475T in Cyp51;
Puccinia triticina with Y134F amino acid substitution in Cyp51;
Pyrenophora teres with F489L amino acid substitution in Cyp51;
Pyrenopeziza brassicae having an amino acid substitution of S508T in Cyp51;
Saccharomyces cerevisiae having an amino acid substitution of Y140F / H in Cyp51;
Cyp51 to L50S, D107V, D134G, V136A / C / G, Y137F, M145L, N178S, S188N, S208T, N284H, H303Y, A311G, G312A, A379G, I381V / Δ, A410T, G412A, Y459C / D / N / S / Zymoseptoria tritici having an amino acid substitution of P / Δ, G460D / Δ, Y461D / H / S, V490L, G510C, N513K or S524T;
Erysiphe necator having an amino acid substitution of Y136F in Cyp51;
Emericella nidulans having an amino acid substitution of H6L / Y, Y50N / S, Q134K, A165V, E198D / K / Q, F200Y or M257L in β-tubulin;
Botryotinia fuckeliana having an amino acid substitution of E198A / G / K / V or F200Y in β-tubulin;
Cochliobolus heterostrophus having an amino acid substitution of F167Y in β-tubulin;
Cercospora beticola having an amino acid substitution of F167Y or E198A in β-tubulin;
Gibberella fujikuroi having an amino acid substitution of Y50N, E198V or F200Y in β-tubulin;
Gibberella zeae having an amino acid substitution of Y50C, Q73R, F167Y, E198K / L / Q or F200Y in β-tubulin;
Helminthosporium solani with an amino acid substitution of E198A / Q in β-tubulin;
Hypomyces odoratus having an amino acid substitution of Y50C in β-tubulin;
Parastagonospora nodorum with amino acid substitution of H6Y in β-tubulin;
Monilinia fructicola having an amino acid substitution of H6Y or E198A / K in β-tubulin;
Monilinia laxa having an amino acid substitution of L240F in β-tubulin;
Microdochium majus, nivale with an amino acid substitution of E198A in β-tubulin;
Mycosphaerella fijiensis with an amino acid substitution of E198A in β-tubulin;
Neurospora crassa having an amino acid substitution of F167Y or E198G in β-tubulin;
Penicillium aurantiogriseum having an amino acid substitution of E198A / K or F200Y in β-tubulin;
Penicillium expansum having an amino acid substitution of F167Y or E198A / K / V on β-tubulin;
Penicillium italicum having an amino acid substitution of E198K or F200Y in β-tubulin;
Pyrenopeziza brassicae with L240F amino acid substitution in β-tubulin;
Rhynchosporium secalis with an amino acid substitution of E198G / K or F200Y in β-tubulin;
Sclerotinia homoeocarpa with E198A / K amino acid substitution in β-tubulin;
Sclerotinia sclerotiorum having an amino acid substitution of E198A in β-tubulin;
Zymoseptoria tritici with an amino acid substitution of E198A / G in β-tubulin;
Venturia inaequalis having an amino acid substitution of E198A / K, F200Y or L240F in β-tubulin;
Alternaria alternata having an amino acid substitution of H277R / Y in SdhB;
Alternaria solani having an amino acid substitution of H277R / Y in SdhB,
Botryotinia fuckeliana having an amino acid substitution of P225H / F / L / T, N230I or H272L / R / V / Y in SdhB;
Corynespora cassiicola with H278Y / R amino acid substitution in SdhB;
Stagonosporopsis cucurbitacearum having an amino acid substitution of H277R / Y in SdhB;
Eurotium oryzae having an amino acid substitution of H249L / N / Y in SdhB;
Pyrenophora teres with H277Y amino acid substitution in SdhB;
Sclerotinia sclerotiorum having an amino acid substitution of H273Y in SdhB;
Zymoseptoria tritici having an amino acid substitution of N225I / T, H273Y, T268I / A or I269V in SdhB;
Erysiphe necator having an amino acid substitution of H242R in SdhB;
Ustilago maydis having an amino acid substitution of H257L in SdhB;
Venturia inaequalis with T253I amino acid substitution in SdhB;
Alternaria alternata having an amino acid substitution of H134R in SdhC;
Botryotinia fuckeliana with P80H / L or A85V amino acid substitution in SdhC;
Corynespora cassiicola having S73P amino acid substitution in SdhC;
Eurotium oryzae with T90I amino acid substitution in SdhC;
Phakopsora pachyrhizi having an amino acid substitution of I86F, N88S or H154Y / R in SdhC;
Pyrenophora teres having an amino acid substitution of K49E, R64K, N75S, G79R, H134R or S135R in SdhC;
Ramularia collo-cygni having an amino acid substitution of N87S, H146R or H153R in SdhC;
Sclerotinia sclerotiorum having an amino acid substitution of H146R in SdhC;
Zymoseptoria tritici having an amino acid substitution of I29V, N33T, N34T, T79I / N, W80S, A84V, N86K / S / A, G90R, R151T / S, H152R or I161S in SdhC;
Erysiphe necator having an amino acid substitution of G169D in SdhC;
Venturia inaequalis having an amino acid substitution of H151R in SdhC;
Alternaria alternata having an amino acid substitution of H133R in SdhD;
Alternaria solani having an amino acid substitution of H133R in SdhD;
Botryotinia fuckeliana with H132R amino acid substitution in SdhD;
Corynespora cassiicola having S89P or G109V amino acid substitution in SdhD;
Eurotium oryzae with D124E amino acid substitution in SdhD;
Pyrenophora teres having an amino acid substitution of D124E / N, H134R, G138V or D145G in SdhD;
Sclerotinia sclerotiorum having an amino acid substitution of H132R in SdhD;
Zymoseptoria tritici having an amino acid substitution of I50F, M114V or D129E in SdhD;
Phytophthora capsici with Q1077K or V1109L / M amino acid substitution in CesA3;
Phethophthora drechsleri with V1109L amino acid substitution in CesA3;
Phethophthora infestans having G1105A / V or V1109L amino acid substitution in CesA3;
Plasmopara viticola with G1105S / V amino acid substitution in CesA3;
Pseudoperonospora cubensis having an amino acid substitution of G1105V / W in CesA3;
Alternaria brassicicola with E753K amino acid substitution in OS-1 (Shk1);
Alternaria longipes with G420D amino acid substitution in OS-1 (Shk1);
Botryotinia fuckeliana having an amino acid substitution of I365N / R / S, V368F, Q369H / P, N373S or T447S in OS-1 (Shk1);
Pleospora allii having an amino acid substitution of F267L, L290S, T765R or Q777R in OS-1 (Shk1);
Sclerotinia sclerotiorum having an amino acid substitution of T489I, E599 K or G736Y in OS-1 (Shk1);
ERG27 to S9G, F26S, P57A, T63I, G170R, V192I, L195F, N196T, A210G, I232M, P238S / Δ, P250S, P269L, P298Δ, V309M, A314V, S336C, V365A, E368D, N369D, E375K, A378T, L400F Botryotinia fuckeliana having an amino acid substitution of S, Y408S, F412I / S / V / C, A461S or R496T.

  The composition of the present invention can also control weeds when a herbicidal active ingredient is included as this component. The weed in the present invention means a plant whose growth is not desirable in the place. Examples of weeds include the following.

Nettic Weed (Urticaceae): Urtica urens
Polygonaceae: Polygonum convolvulus, Polygonum lapathifolium, Polygonum pensylvanicum, Polygonum persicaria, Polygonum alist, Polygonum longisetum, Polygonum longisetum, Polygonum longisetum, , Polygonum cuspidatum, Ripex japonicus, Ragex crispus, Rumex obtusifolius, Sorrel (Rumex acetosa)
Physalis Weed (Portulacaceae): Physalis (Portulaca oleracea)
Caryophyllaceae: Stellaria media, Stellaria aquatica, Cerastium holosteoides, Cerastium glomeratum, Spergula arvensis, Mannema (Silene gallica)
Pomegranate Weed (Molluginaceae): Mollugo verticillata
Chiropodiaceae: Chenopodium album, Chenopodium ambrosioides, Kochia scoparia, Salalah kali, Atriplex spp.

Amaranthaceae: Amaranthus retroflexus, Amaranthus viridis, Amaranthus lividus, Amaranthus spinosus, Amaranthus hybridus, Amaranthus hybridus, Palm Amaranthus patulus, water hemp (Amaranthus tuberculatus = Amaranthus rudis = Amaranthus tamariscinus), American marsh (Amaranthus blitoides), Amaranthus deflexus, Amaranthus quatersis (Amaranthus quitentern), Algae phil ), Sanguinaria (Alternanthera tenella)
Poppyaceae: Papaver rhoeas, Papaver dubium, Argemone mexicana
Brassicaceae: Japanese radish (Raphanus raphanistrum), radish (Raphanus sativus), Noragarashi (Sinapis arvensis), Nazuna (Capsella bursa-pastoris), Brassica juncea, Brassica napus (Brassica napus), Brassica napus (Descurainia pinnata), Red-tailed burdock (Rorippa islandica), Red-tailed pebbles (Rorippa sylvestris), Gambina (Thlaspi arvense), Miyagashi (Myagrum rugosum), Laridium virginicum, mus or pus
Capparaceae: Cleome affinis

Legaceae weeds (Fabaceae): Aeschynomene indica, zigzag joint bech (Aeschynomene rudis), Sesbania exaltata, Ebusa (Cassia obtusifolia), Cassia occidentalis, Desmogi (Desmo) adscendens, Desmodium illinoense, White clover (Trifolium repens), Kudu (Pueraria lobata), Vicia angustifolia, Raccoon peas (Indigofera hirsuta), Indigofera truxensis (Indigofera) Vigna sinensis)
Oxalidaceae: Oxalis corniculata, Oxalis strica, Oxalis oxyptera
Geraniaceae: American caroline (Geranium carolinense), Dutch flower (Erodium cicutarium)
Euphorbiaceae: Euphorbia helioscopia, Euphorbia maculata, Euphorbia humistrata, Euphorbia esula, Euphorbia heterophyll, Euphorbia heterophyll (Acalypha australis), Tropic grotulos, Croton lobatus, Phyllanthus corcovadensis, Ricinus communis

Malvaceae: Abutilon theophrasti, Sika rhombiforia, Sida cordifolia, Sida spinosa, Sida glaziovii, Sida santaremnsis ), Ginseng (Hibiscus trionum), Carp (Anoda cristata), Carp (Malvastrum coromandelianum)
Onagraceae: Ludwigia epilobioides, Ludwigia octovalvis, Ludwigia decurre, Oenothera biennis, Oenothera laciniata
Aceraceae weed (Sterculiaceae): Waltheria indica
Violaceae: Makibasmille (Viola arvensis), Wild pansy (Viola tricolor)
Cucurbitaceae: Areciuri (Sicyos angulatus), wild cucumber (Echinocystis lobata), wild bitter gourd (Momordica charantia)
Lythraceae: Ammannia multiflora, Ammannia auriculata, Ammannia coccinea, Lythrum salicaria, Rotala indica
Elephantaceae (Elatinaceae): Elephant triandra, California water wort (Elatine californica)

Apiaceae: Seri (Oenanthe javanica), Nolanin (Daucus carota), Dungin (Conium maculatum)
Araliaceae: Hydrocotyle sibthorpioides, Brazilian Hydrocotyle ranunculoides
Ceratoophyllaceae: Matsumoto (Ceratophyllum demersum)
Cabombaceae: Cabomba caroliniana
Haloragaceae: Myrophyllum aquaticum, Fusamo (Myriophyllum verticillatum), Watermilfoil (Myriophyllum spicatum, Myriophyllum heterophyllum, etc.)
Sapindaceae: Cardiospermum halicacabum
Primulalaceae: Anagallis arvensis
Asperpiadaceae: Milkweed (Asclepias syriaca), Honey Vine Milkweed (Ampelamus albidus)
Rubiaceae: Catchweed Bed Straw (Galium aparine), Yamgra (Galium spurium var. Echinospermon), Spermacoce latifolia, Brazilian Brasiliensis, Wingdphalus buttonweed (Borreria alba)

Convolvulaceae: Japanese morning glory (Ipomoea nil), American morning glory (Ipomoea hederacea), Marva morning glory (Ipomoea purpurea), Malba American morning glory (Ipomoea hederacea var. , Ipomoea acuminata, Ipomoea hederifolia, Ipomoea coccinea, Ipomoea quamoclit, Ipomoea grandifolia (Ipomoea grandifolia ea) , Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis a cissoides), Okinawan morning glory (Jacquemontia tamnifolia)
Purple weed (Boraginaceae): Forget-me-not (Myosotis arvensis)
Lamiaceae: Laury purpureum, Lamium amplexicaule, Leonotis nepetaefolia, Hyptis suarolsis (Hyptis loventa), Hyptis lophanta

Solanaceae: Datura stramonium, Solanum nigrum, Solanum americanum, Solanum ptycanthum, Solanum sarrachoum Solanum strata , Goldfish (Solanum aculeatissimum), wild tomato (Solanum sisymbriifolium), varunabi (Solanum carolinense), physalis angulata, smooth ground cherry (Physalis subglabrata), osennari (Nicandra physaloides)
Scrophulariaceae: Veronica hederaefolia, Veronica persica, Veronica arvensis, Azena (Lindernia procumbens), American azena (Lindernia dubia), Alistia rot (Dopatrium junceum), Giant Abnomome (Gratiola japonica),
Plantaginaceae: Plantago asiatica, Plantago lanceolata, Plantago major, Callitriche palustris

  Asteraceae: Xanthium pensylvanicum, Xanthium occidentale, Xanthium italicum, wild sunflower (Helianthus annuus), chamomile (Matricaria chamomilla), dogwood forumata (Matricaria perumata) ), Otricha matricarioides, Artemisia princeps, Artemisia vulgaris, Chinese mugwort (Artemisia verlotorum), Solidago altissima, Solida altissima, Taraxacum officinga (Galinsoga parviflora), Sorgio vulgaris, Senecio brasiliensis, Senecio grisebachii, Conyza bonariensis, Giant cricket (C) onyza smatrensis), Conyza canadensis, Ragweed (Ambrosia artemisiaefolia), Ambrosia trifida, Bidens tripartita, Bidens pilosa, Bidens frondo (Bidens frondo) Spring thistle (Cirsium arvense), American thistle (Cirsium vulgare), Maria thistle (Silybum marianum), Musk thistle (Carduus nutans), Skeletia (Lactuca serriola), Nogeshi (Sonchus oleraceus), Onchose asper (Sonchus asper) Wedelia glauca, Perforate black foot (Melampodium perfoliatum), Emilia sonchifolia, Tagetes minuta, Blainvillea latifolia, Tridax procumbens, Yerba po Rosa (Porophyllum ruderale), Paraguay star bar (Acanthospermum australe), Bristol star bar (Acanthospermum hispidum), Cardiospermum halicacabum, Cuckoo thistle (Ageratum conyzoides), Common bone set (Eupatorium perta alba) , Dendborogiku (Erechtites hieracifolia), American Everlasting (Gamochaeta spicata), Vinelet Pichigusa (Gnaphalium spicatum), Jagelia Hitera (Jaegeria hirta), Sesame (Parthenium hysterophorus), Menamomi (Siegesbeckia or Seriskin serikins) Takasaburo (Eclipta prostrata), American Takasaburo (Eclipta alba), Tokinsou (Centipeda minima),

Osidaceae weeds (Alismataceae): Urikawa (Sagittaria pygmaea), Omodaka (Sagittaria trifolia), Omodaka (Sagittaria sagittifolia), Tilin Omodaka (Sagittaria montevidensis), Aginashi (Sagittaria aginashi), Tulum aquatica)
Limnocharitaceae: Limnocharis flava
Hydrocharitaceae: Frogbit (Limnobium spongia), Black spider (Hydrilla verticillata), Common water nymph (Najas guadalupensis)
Araceae: Button duckweed (Pistia stratiotes)
Duckweed (Lemnaceae): Lemna aoukikusa, Spirodela polyrhiza, Daphnia (Wolffia spp)
Potato getonaceae: Potato geton distinctus, pondweeds (Potamogeton crispus, Potamogeton illinoensis, Stuckenia pectinata, etc.)
Liliaceae: Wild Onion (Allium canadense), Wild Garlic (Allium vineale), Nobil (Allium macrostemon)
Weeping mallow weeds: water hyacinth (Eichhornia crassipes), American oak (Heteranthera limosa), Mizouroi (Monochoria korsakowii), oak (Monochoria vaginalis)
Commelinaceae: Commelina communis, Compositina bengharensis, Electday flower (Commelina erecta), Murdannia keisak

  Poaceae: Echinochloa crus-galli, Echinochloa oryzicola, Echinochloa crus-galli var formosensis, Late watergrass (Echinochloa oryzoides), Echiochloa colonies (Echinochloa colonies) Echinochloa crus-pavonis), Enocorogusa (Setaria viridis), Akinoenokorogusa (Setaria faberi), Echinocholo (Setaria glauca), American Enocorosa (Setaria geniculata), Meishiba (Digitaria ciliaris), Large Crabgrass (Digitaria sanguinalis) Digitaria horizontalis, Gibbon beetle (Digitaria insularis), Bark beetle (Eleusine indica), Sparrow anemone (Poa annua), Poa trivialis, Nagahagusa (Poa pratensis), Algae spp (Alospecurus aequus) opecurus myosuroides, Avena fatua, Sorghum halepense, Shatar cane (Sorghum vulgare), Agropyron repens, Ratium multiflorum, Lolium perenne, Boar, Lolium rigid Bromus catharticus, Bromus sterilis, Bromus japonicus, Bromus secalinus, Bromus tectorum, Hordeum jubatum, Adeilops lins, Aegilops lin Pepper (Phalaris minor), Silky bentgrass (Apera spica-venti), Prickly millet (Panicum dichotomiflorum), Texas panicum (Panicum texanum), Panaxcum (Panicum maximum), Meriken prickly millet (Brachiaria platyphylla), Rugegrass en (Brachiaria ruzi) , Alexandergrass (Brachiaria plantaginea), Surinamegrass (Brachiaria decumbens), Palisadegrass (Brachiaria brizantha), Colombiagrass (Brachiaria humidicola), Cinchrus echinatus, Cenchrus pauciflorus, Narcobienise (Eriochloatum) setosum), African Beard (Chloris gayana), Bearded Sheep (Chlorisvirgata), Elephrostis pilosa, Ruby Gaya (Rhynchelitrum repens), Tatsunosumaya (Dactyloctenium aegyptium), Ischaemum rugo (Ischaemum rugo) Oryza sativa), American spider (Paspalum notatum), coastal sand paspalm (Paspalum maritimum), Kyushu genus (Paspalum distichum), Kennyugrass (Pennisetum clandestinum), Hosobachikara Pennisetum setosum, Rottboellia cochinchinensis, Leptochloa chinensis, Leptochloa fascicularis, Leptochloa filiformis, Lepuscheria leuka, Leptochaia pug , Leersia oryzoides, Glyceria leptorrhiza, Glyceria acutiflora, Glyceria maxima, Agrostis gigantea, Agrostis glontea, Agrostis glontea , Eremochloa ophiuroides, Festuca arundinacea, Festuca rubra, Imperata cylindrica, Miscanthus sinensis, Switchgrass (Panicum virgatum), Bas (Zoysia japonica)

Cyperaceae: Cyperus microiria, Cyperus iria, Cyperus compressus, Cyperus difformis, Cyperus flaccidus, cyperus flaccidus, Cyperus flaccidus (Cyperus odoratus), Cyperus serotinus, Jasper (Cyperus rotundus), Yellow-headed geese (Cyperus esculentus), Kyllinga gracillima, Ida-kug (Kyllinga brevifolia), Hiderico acicularis), Kurowai (Eleocharis kuroguwai), firefly (Schoenoplectiella hotarui), firefly (Schoenoplectiella juncoides), Taiwan Yamai (Schoenoplectiella wallichii), Schoenoplectiella mucronatus, kangaret (Schoenoplectiella triangulatus), pulp (Schoenoplectiella nipponicus), Sankakui (Schoenoplectiella triqueter), Koukiyagara (Bolboschoenus koshevnikovii), Ukiyagara (Bolboschoenus fluviatilis)
Equisetaceae: Equisetum arvense, Equisetum palustre
Salviniaceae: Salvinia natans
Azollaceae: Azolla japonica, Azolla imbricata
Marsileaceae: Marsilea quadrifolia
Others: filamentous algae (Pithophora, Cladophora), mosses, moss, hornworts, cyanobacteria, ferns, perennial crops (fruits, stones, berries, nuts, citrus, hops, grapes, etc.) Sucker.

  About the above weeds, the variation | mutation in a seed | species is not specifically limited. In other words, those having reduced sensitivity to specific herbicides (also called resistance) are also included. The decrease in sensitivity may be due to a mutation at the target site (point of action mutation) or may be due to a factor that is not a point of action mutation (non-point of action mutation). As for the action point mutation, the amino acid substitution in the protein which is the target site due to the mutation of the nucleic acid sequence part (open reading frame) corresponding to the amino acid sequence of the protein, the deletion of the suppressor sequence in the promoter region, the enhancer sequence Those in which the protein at the target site is overexpressed due to mutation such as amplification of the gene or increase in the copy number of the gene. Non-acting point mutations include increased metabolism, malabsorption, migration failure, and out-of-system excretion. Factors that enhance metabolism include those in which the activity of metabolic enzymes such as cytochrome P450 monooxygenase, allyl acylamidase, esterase, and glutathione S-transferase is increased. The out-of-system discharge includes transport to the vacuole by ABC transporter.

Examples of the amino acid substitution at the target site include the following.
ALS: Ala122Thr, Ala122Val, Ala122Tyr, Pro197Ser, Pro197His, Pro197Thr, Pro197Arg, Pro197Leu, Pro197Gln, Pro197Ala, Pro197Ile, Ala205Val, Ala205Phe, Asp376Glu, Arg377His, Trp574Leu, Trp574Gly, Trp574Met, Ser653Thr, Ser653Thr, Ser653Asn, Ser635Ile, Gly654Glu or Gly645Asp;
ACCase: Ile1781Leu, Ile1781Val, Ile1781Thr, Trp1999Cys, Trp1999Leu, Ala2004Val, Trp2027Cys, Ile2041Asn, Ile2041Val, Asp2078Gly or Cys2088Arg;
PPX2: Gly210Δ, Arg98Leu, Arg98Met, Arg98Gly, Arg98His, Gly399Ala;
EPSP: Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu.

  The weeds that can be controlled by the composition of the present invention may have a plurality of the above amino acid substitutions. In this case, the plurality of amino acid substitutions may be the same protein or different proteins. Moreover, you may have two or more non-action point mutations and action point mutations.

Examples of weeds having an action point mutation include the following.
PPG2 has the amino acid substitution of Gly210Δ, Arg98Met, Arg98Gly or Gly399Ala;
Water hemp having an amino acid substitution of Gly210Δ, Arg98Met, Arg98Gly or Gly399Ala in PPX2;
Ragweed having an amino acid substitution of Arg98Leu in PPX2;
Botanus having an amino acid substitution of Arg98His in PPX2;
EPSHI has a cypress having an amino acid substitution of Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu;
EPSP, Baumgi with an amino acid substitution of Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu;
EPSP, Susukishieshiba having an amino acid substitution of Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu;
EPSP has a cypress having an amino acid substitution of Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu;
EPSP with Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu amino acid substitutions;

  The above-mentioned Daphnia magna, water hemp and ragweed are resistant to PPO inhibitors such as lactofen, fomesafen and flumioxazin.

Other weeds include the following.
An over-expressed EPSP gene results in reduced sensitivity to glyphosate.
Resistant wormwood, oleaginous, and retinoic with reduced sensitivity to glyphosate involving ABC transporters.

  In particular, the composition of the present invention can effectively control the above-mentioned giant moth, cypress, scallop, chickweed, oleix and tineo.

  In addition, the composition of the present invention can effectively control glyphosate-resistant cypress, sagebrush, scallop, squirrel, cybridae, and scallop that have an amino acid substitution of Thr102Ile and Pro106Ser in EPSP.

Hereinafter, although this invention is demonstrated in more detail by a manufacture example, a formulation example, a test example, etc., this invention is not limited only to these examples.
First, the manufacture example of this compound is shown.

Reference production example 1
6-chloro-3- (ethanesulfonyl) -5- (trifluoromethyl) -5 '-(2,2,3,3,3-pentafluoropropoxy) -2,2'-bipyridine 500 mg and 28% aqueous ammonia 3 mL of the mixture was stirred at 100 ° C. for 5 hours. Water was added to the obtained mixture at room temperature, and the mixture was extracted with ethyl acetate. The obtained organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography to obtain 401 mg of intermediate (1) represented by the following formula.
Intermediate (1)
¹ H-NMR (CDCl ₃ ) δ: 8.44 (1H, s), 8.35 (1H, s), 7.78 (1H, d), 7.39 (1H, d), 5.52 (2H, s), 4.53 (2H, t ), 3.79 (2H, q), 1.37 (3H, t).

Reference Production Example 2-1
6-chloro-3- (ethanesulfonyl) -5 ′-(2,2,3,3,3-pentafluoropropoxy) -2,2′-bipyridine 600 mg, hydrazine monohydrate 219 mg, diethylisopropylamine 180 mg and A mixture of 2 mL of THF was stirred at reflux for 10 hours. Water was added to the obtained mixture at room temperature, and the mixture was extracted with ethyl acetate. The obtained organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The obtained residue was recrystallized from ethyl acetate and hexane to obtain 465 mg of an intermediate (2) represented by the following formula.
Intermediate (2)
¹ H-NMR (CDCl ₃ ) δ: 8.34 (1H, d), 8.17 (1H, d), 7.70 (1H, d), 7.37 (1H, dd), 6.89 (1H, d), 6.40 (1H, s ), 4.52 (2H, t), 3.93 (2H, s), 3.66 (2H, q), 1.32 (3H, t).

Reference production example 2-2
The intermediate compounds produced according to the method described in Reference Production Example 2-1 and their physical properties are shown below.
Intermediate (3)
¹ H-NMR (CDCl ₃ ) δ: 8.40 (1H, s), 8.37 (1H, d), 7.82 (1H, d), 7.41 (1H, dd), 6.74 (1H, s), 4.55 (2H, t ), 4.19 (2H, d), 3.80 (2H, q), 1.37 (3H, t).

Production Example 1
A mixture of 185 mg of intermediate (2), 81 mg of 1,1′-carbonyldiimidazole and 2 mL of NMP was stirred at room temperature for 2 hours. Water was added to the obtained mixture at room temperature, and the mixture was extracted with ethyl acetate. The obtained organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography to obtain 171 mg of the present compound 1 represented by the following formula.
Compound 1
¹ H-NMR (CDCl ₃ ) δ: 10.17 (1H, s), 8.38 (1H, d), 7.59 (1H, d), 7.56 (1H, d), 7.36 (1H, dd), 7.22 (1H, d ), 4.55 (2H, t), 3.15 (2H, q), 1.28 (3H, t).

Production Example 2
The compounds produced according to the method described in Production Example 1 and their physical properties are shown below.
Compound 2
¹ H-NMR (CDCl ₃ ) δ: 10.59 (1H, s), 8.40 (1H, d), 7.95 (1H, s), 7.57 (1H, d), 7.38 (1H, dd), 4.57 (2H, t ), 3.22-3.17 (2H, m), 1.29 (3H, t).

Production Example 3
A mixture of intermediate (3) 247 mg, trimethyl orthoformate 5 mL and trifluoroacetic acid 57 μL was stirred at 110 ° C. for 3 hours. Water was added to the obtained mixture at room temperature, and the mixture was extracted with ethyl acetate. The obtained organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography (hexane: ethyl acetate = 1: 1) to obtain 249 mg of the present compound 3 represented by the following formula.
Compound 3
¹ H-NMR (CDCl ₃ ) δ: 8.59 (1H, dd), 8.49 (1H, s), 8.26 (1H, d), 7.76 (1H, dd), 7.56 (1H, dd), 4.63 (2H, t ), 3.23 (2H, q), 1.31 (3H, t).

Production Example 4
The compounds produced according to the method described in Production Example 3 and their physical properties are shown below.
Compound 4
¹ H-NMR (CDCl ₃ ) δ: 8.57 (1H, dd), 8.39 (1H, d), 7.98 (1H, dd), 7.90 (1H, d), 7.73 (1H, dd), 7.54 (1H, dd ), 4.62 (2H, td), 3.19 (2H, q), 1.28 (3H, t).

Production Example 5
A mixture of intermediate (1) 300 mg, 2-chloroethylamine hydrochloride 105 mg, diethylisopropylamine 310 μL and NMP 2 mL was stirred at 120 ° C. for 7 hours. Water was added to the obtained mixture at room temperature, and the mixture was extracted with ethyl acetate. The obtained organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography (hexane: ethyl acetate = 1: 1) to obtain 138 mg of the present compound 5 represented by the following formula.
Compound 5
¹ H-NMR (CDCl ₃ ) δ: 8.43 (1H, d), 7.74 (1H, d), 7.53 (1H, d), 7.41 (1H, dd), 4.54 (2H, t), 4.08-4.03 (2H , m), 3.61 (2H, d), 2.93 (2H, q), 1.25 (3H, t).

Production Example 6
A mixture of 300 mg of intermediate (1), 1.05 g of 2-chloroacetaldehyde and 2 mL of NMP was stirred at 120 ° C. for 7 hours. Water was added to the obtained mixture at room temperature, and the mixture was extracted with ethyl acetate. The obtained organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography (hexane: ethyl acetate = 2: 1) to obtain 200 mg of the present compound 6 represented by the following formula.
Compound 6
¹ H-NMR (CDCl ₃ ) δ: 8.56 (1H, d), 8.20 (1H, s), 7.84 (1H, d), 7.67 (1H, d), 7.53 (1H, dd), 7.20 (1H, d ), 4.61 (2H, t), 3.25-3.21 (2H, m), 1.29 (3H, t).

  Examples of the composition A include the following.

  In List 1, * represents any one of the present compounds 1-6. Moreover, the number described in [] of each component means the weight part of each component in the composition A.

[List 1]
1: * [2] + Spinetoram [0.5]
2: * [2] + clothianidin [1.5]
3: * [2] + Isotianil [2]
4: * [2] + Frametopil [4]
5: * [2] + Impilfluxam [2]
6: * [2] + Orissatrobin [7]
7: * [2] + spinetoram [0.5] + clothianidin [1.5]
8: * [2] + Spinetoram [0.5] + Isotianil [2]
9: * [2] + Spinetram [0.5] + Flametopill [4]
10: * [2] + Spinetrum [0.5] + Impylfluxam [2]
11: * [2] + Spinetram [0.5] + Orisatrobin [7]
12: * [2] + clothianidin [1.5] + isotianil [2]
13: * [2] + clothianidin [1.5] + furametopir [4]
14: * [2] + clothianidin [1.5] + impylfluxam [2]
15: * [2] + clothianidin [1.5] + orisatrobin [7]
16: * [2] + Isotianil [2] + Frametopyr [4]
17: * [2] + Isotianil [2] + Impylfluxam [2.5]
18: * [2] + spinetoram [0.5] + clothianidin [1.5] + isotianil [2]
19: * [2] + Spinetram [0.5] + Clothianidin [1.5] + Framethopill [4]
20: * [2] + spinetoram [0.5] + clothianidin [1.5] + impylufluxam [2] 21: * [2] + spinetoram [0.5] + isotianil + framtopyr [4]
22: * [2] + spinetoram [0.5] + isotianil [2] + impylfluxam [2]
23: * [2] + clothianidin [1.5] + isotianil [2] + furametopyr [4]
24: * [2] + clothianidin [1.5] + isotianil [2] + impylfluxam [2]
25: * [2] + spinetoram [0.5] + clothianidin [1.5] + isotianil [2] + furametopyr [4]
26: * [2] + spinetoram [0.5] + clothianidin [1.5] + isotianil [2] + impylfluxam [2]
27: * [0.1] + clothianidin [0.5]
28: * [0.1] + Fusaride [1.5]
29: * [0.1] + Validamycin A [0.3]
30: * [0.1] + clothianidin [0.5] + fusaride [1.5]
31: * [0.1] + clothianidin [0.5] + validamycin A [0.3]
32: * [0.1] + Fusaride [1.5] + Validamycin A [0.3]
33: * [0.1] + Ferimzone [2] + Fusaride [1.5]
34: * [0.1] + clothianidin [0.5] + ferrimzone [2] + fusaride [1.5]
35: * [0.1] + clothianidin [0.5] + fusaride [1.5] + validamycin A [0.3]
36: * [0.1] + Ferimzone [2] + Fusaride [1.5] + Validamycin A [0.3]
37: * [0.1] + clothianidin [0.5] + ferrimzone [2] + fusaride [1.5] + validamycin A [0.3]
38: * [5] + clothianidin [6.6]
39: * [5] + Fusaride [20]
40: * [5] + Validamycin A [5]
41: * [5] + clothianidin [6.6] + fusaride [20]
42: * [5] + clothianidin [6.6] + validamycin A [5]
43: * [5] + Fusaride [15] + Ferimzone [15]
44: * [5] + Fusaride [20] + Validamycin A [5]
45: * [5] + clothianidin [6.6] + fusaride [15] + ferrimzone [15]
46: * [5] + clothianidin [6.6] + fusaride [20] + validamycin A [5]
47: * [5] + clothianidin [6.6] + fusaride [15] + ferrimzone [15] + validamycin A [5]
48: * [5] + Azoxystrobin [8]
49: * [5] + clothianidin [6.6] + azoxystrobin [8]
50: * [10] + clothianidin [10]
51: * [10] + Cyantraniprolol [10]
52: * [10] + Bacillus films I-1582 strain [2]
53: * [10] + Pasteuria nisawae Pn1 strain [2]
54: * [10] + Abamectin [10]
55: * [10] + metconazole [2]
56: * [10] + Tebuconazole [2]
57: * [10] + Difenoconazole [2]
58: * [10] + Triticonazole [2]
59: * [10] + Fluquinconazole [2]
60: * [10] + Prothioconazole [2]
61: * [10] + Diniconazole [2]
62: * [10] + Diniconazole M [2]
63: * [10] + ipconazole [2]
64: * [10] + fludioxonil [2]
65: * [10] + Prochloraz [2]
66: * [10] + Chiuram [2]
67: * [10] + thiophanate methyl [10]
68: * [10] + Mandestrobin [2]
69: * [10] + Azoxystrobin [2]
70: * [10] + Fluoxastrobin + [2]
71: * [10] + Trifloxystrobin [2]
72: * [10] + pyraclostrobin [2]
73: * [10] + Torquelofosmethyl [2]
74: * [10] + Tifluzamide [2]
75: * [10] + Penflufen [2]
76: * [10] + Sedaxane [2]
77: * [10] + Floxapyroxide [2]
78: * [10] + full opiram [2]
79: * [10] + ethaboxam [2]
80: * [10] + Impylfluxam [2]
81: * [10] + Metalaxyl [2]
82: * [10] + Metalaxyl M [1]
83: * [10] + Fluopicolide [2]
84: * [10] + Oxathiapiproline [2]
85: * [10] + metconazole [2] + torquelofosmethyl [2] + ethaboxam [2]
86: * [10] + metconazole [2] + torquelofosmethyl [2] + metalaxyl [2]
87: * [10] + metconazole [2] + torquelofosmethyl [2] + metalaxyl M [1]
88: * [10] + metconazole [2] + torquelofos methyl [2] + fluopicolide [2]
89: * [10] + metconazole [2] + torquelofosmethyl [2] + oxathiapiproline [2]
90: * [10] + metconazole [2] + impylfluxam [2] + ethaboxam [2]
91: * [10] + metconazole [2] + impylfluxam [2] + metalaxyl [2]
92: * [10] + metconazole [2] + impylfluxam [2] + metalaxyl M [1]
93: * [10] + metconazole [2] + impylfluxam [2] + fluopicolide [2]
94: * [10] + metconazole [2] + impylfluxam [2] + oxathiapiproline [2]
95: * [10] + metconazole [2] + tifluzamide [2] + ethaboxam [2]
96: * [10] + metconazole [2] + tifluzamide [2] + metalaxyl [2]
97: * [10] + metconazole [2] + tifluzamide [2] + metalaxyl M [1]
98: * [10] + metconazole [2] + tifluzamide [2] + fluopicolide [2]
99: * [10] + metconazole [2] + tifluzamide [2] + oxathiapiproline [2]
100: * [10] + metconazole [2] + penflufen [2] + ethaboxam [2]
101: * [10] + metconazole [2] + penflufen [2] + metalaxyl [2]
102: * [10] + metconazole [2] + penflufen [2] + metalaxyl M [1]
103: * [10] + metconazole [2] + penflufen [2] + fluopicolide [2]
104: * [10] + metconazole [2] + penflufen [2] + oxathiapiproline [2]
105: * [10] + metconazole [2] + sedaxane [2] + ethaboxam [2]
106: * [10] + metconazole [2] + sedaxane [2] + metalaxyl [2]
107: * [10] + metconazole [2] + sedaxane [2] + metalaxyl M [1]
108: * [10] + metconazole [2] + sedaxane [2] + fluopicolide [2]
109: * [10] + metconazole [2] + sedaxane [2] + oxathiapiproline [2]
110: * [10] + metconazole [2] + floxapyroxad [2] + ethaboxam [2]
111: * [10] + metconazole [2] + floxapyroxad [2] + metalaxyl [2]
112: * [10] + metconazole [2] + floxapyroxad [2] + metalaxyl M [1]
113: * [10] + metconazole [2] + floxapyroxad [2] + fluopicolide [2]
114: * [10] + metconazole [2] + floxapyroxad [2] + oxathiapiproline [2]
115: * [10] + metconazole [2] + fluopyram [2] + ethaboxam [2]
116: * [10] + metconazole [2] + fluopyram [2] + metalaxyl [2]
117: * [10] + metconazole [2] + fluopyram [2] + metalaxyl M [1]
118: * [10] + metconazole [2] + fluopyram [2] + fluopicolide [2]
119: * [10] + metconazole [2] + fluopyram [2] + oxathiapiproline [2]
120: * [10] + metconazole [2] + fludioxonil [2] + ethaboxam [2]
121: * [10] + metconazole [2] + fludioxonil [2] + metalaxyl [2]
122: * [10] + metconazole [2] + fludioxonil [2] + metalaxyl M [1]
123: * [10] + metconazole [2] + fludioxonil [2] + fluopicolide [2]
124: * [10] + metconazole [2] + fludioxonyl [2] + oxathiapiproline [2]
125: * [10] + tebuconazole [2] + torquelofosmethyl [2] + ethaboxam [2]
126: * [10] + Tebuconazole [2] + Torquelofosmethyl [2] + Metalaxyl [2]
127: * [10] + Tebuconazole [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
128: * [10] + tebuconazole [2] + torquelofosmethyl [2] + fluopicolide [2]
129: * [10] + tebuconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
130: * [10] + Tebuconazole [2] + Impylfluxam [2] + Etaboxam [2]
131: * [10] + Tebuconazole [2] + Impylfluxam [2] + Metalaxyl [2]
132: * [10] + Tebuconazole [2] + Impylfluxam [2] + Metalaxyl M [1]
133: * [10] + Tebuconazole [2] + Impylfluxam [2] + Fluopicolide [2]
134: * [10] + Tebuconazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
135: * [10] + tebuconazole [2] + tifluzamide [2] + ethaboxam [2]
136: * [10] + Tebuconazole [2] + Tifluzamide [2] + Metalaxyl [2]
137: * [10] + Tebuconazole [2] + Thifluzamide [2] + Metalaxyl M [1]
138: * [10] + Tebuconazole [2] + Tifluzamide [2] + Fluopicolide [2]
139: * [10] + Tebuconazole [2] + Thifluzamide [2] + Oxathiapiproline [2]
140: * [10] + tebuconazole [2] + penflufen [2] + ethaboxam [2]
141: * [10] + Tebuconazole [2] + Penflufen [2] + Metalaxyl [2]
142: * [10] + Tebuconazole [2] + Penflufen [2] + Metalaxyl M [1]
143: * [10] + Tebuconazole [2] + Penflufen [2] + Fluopicolide [2]
144: * [10] + Tebuconazole [2] + Penflufen [2] + Oxathiapiproline [2]
145: * [10] + tebuconazole [2] + sedaxane [2] + ethaboxam [2]
146: * [10] + Tebuconazole [2] + Sedaxane [2] + Metalaxyl [2]
147: * [10] + tebuconazole [2] + sedaxane [2] + metalaxyl M [1]
148: * [10] + Tebuconazole [2] + Sedaxane [2] + Fluopicolide [2]
149: * [10] + tebuconazole [2] + sedaxane [2] + oxathiapiproline [2]
150: * [10] + tebuconazole [2] + floxapyroxad [2] + ethaboxam [2]
151: * [10] + Tebuconazole [2] + Floxapyroxad [2] + Metalaxyl [2]
152: * [10] + Tebuconazole [2] + Floxapyroxad [2] + Metalaxyl M [1]
153: * [10] + Tebuconazole [2] + Floxapyroxad [2] + Fluopicolide [2]
154: * [10] + Tebuconazole [2] + Floxapyroxad [2] + Oxathiapiproline [2]
155: * [10] + tebuconazole [2] + fluopyram [2] + ethaboxam [2]
156: * [10] + Tebuconazole [2] + Fluopyram [2] + Metalaxyl [2]
157: * [10] + Tebuconazole [2] + Fluopyram [2] + Metalaxyl M [1]
158: * [10] + Tebuconazole [2] + Fluopyram [2] + Fluopicolide [2]
159: * [10] + Tebuconazole [2] + Fluopyram [2] + Oxathiapiproline [2]
160: * [10] + tebuconazole [2] + fludioxonil [2] + ethaboxam [2]
161: * [10] + Tebuconazole [2] + Fludioxonyl [2] + Metalaxyl [2]
162: * [10] + Tebuconazole [2] + Fludioxonyl [2] + Metalaxyl M [1]
163: * [10] + Tebuconazole [2] + Fludioxonil [2] + Fluopicolide [2]
164: * [10] + Tebuconazole [2] + Fludioxonyl [2] + Oxathiapiproline [2]
165: * [10] + difenoconazole [2] + tolcrofosmethyl [2] + ethaboxam [2]
166: * [10] + difenoconazole [2] + tolcrofosmethyl [2] + metalaxyl [2]
167: * [10] + difenoconazole [2] + tolcrofosmethyl [2] + metalaxyl M [1]
168: * [10] + difenoconazole [2] + tolcrofosmethyl [2] + fluopicolide [2]
169: * [10] + difenoconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
170: * [10] + Difenoconazole [2] + Impylfluxam [2] + Etaboxam [2]
171: * [10] + Difenoconazole [2] + Impylfluxam [2] + Metalaxyl [2]
172: * [10] + Difenoconazole [2] + Impylfluxam [2] + Metalaxyl M [2]
173: * [10] + Difenoconazole [2] + Impylfluxam [2] + Fluopicolide [2]
174: * [10] + Difenoconazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
175: * [10] + difenoconazole [2] + tifluzamide [2] + ethaboxam [2]
176: * [10] + difenoconazole [2] + tifluzamide [2] + metalaxyl [2]
177: * [10] + difenoconazole [2] + tifluzamide [2] + metalaxyl M [1]
178: * [10] + difenoconazole [2] + tifluzamide [2] + fluopicolide [2]
179: * [10] + difenoconazole [2] + tifluzamide [2] + oxathiapiproline [2]
180: * [10] + difenoconazole [2] + penflufen [2] + ethaboxam [2]
181: * [10] + difenoconazole [2] + penflufen [2] + metalaxyl [2]
182: * [10] + difenoconazole [2] + penflufen [2] + metalaxyl M [1]
183: * [10] + difenoconazole [2] + penflufen [2] + fluopicolide [2]
184: * [10] + difenoconazole [2] + penflufen [2] + oxathiapiproline [2]
185: * [10] + difenoconazole [2] + sedaxan [2] + ethaboxam [2]
186: * [10] + difenoconazole [2] + sedaxan [2] + metalaxyl [2]
187: * [10] + difenoconazole [2] + sedaxan [2] + metalaxyl M [1]
188: * [10] + Difenoconazole [2] + Sedaxane [2] + Fluopicolide [2]
189: * [10] + difenoconazole [2] + cedaxane [2] + oxathiapiproline [2]
190: * [10] + difenoconazole [2] + floxapyroxad [2] + ethaboxam [2]
191: * [10] + difenoconazole [2] + floxapyroxad [2] + metalaxyl [2]
192: * [10] + difenoconazole [2] + floxapyradod [2] + metalaxyl M [1]
193: * [10] + difenoconazole [2] + floxapyroxad [2] + fluopicolide [2]
194: * [10] + difenoconazole [2] + floxapyroxad [2] + oxathiapiproline [2]
195: * [10] + difenoconazole [2] + fluopyram [2] + ethaboxam [2]
196: * [10] + difenoconazole [2] + fluopyram [2] + metalaxyl [2]
197: * [10] + difenoconazole [2] + fluopyram [2] + metalaxyl M
198: * [10] + difenoconazole [2] + fluopyram [2] + fluopicolide [2]
199: * [10] + difenoconazole [2] + fluopyram [2] + oxathiapiproline [2]
200: * [10] + difenoconazole [2] + fludioxonil [2] + ethaboxam [2]
201: * [10] + difenoconazole [2] + fludioxonil [2] + metalaxyl [2]
202: * [10] + difenoconazole [2] + fludioxonil [2] + metalaxyl M [1]
203: * [10] + difenoconazole [2] + fludioxonil [2] + fluopicolide [2]
204: * [10] + difenoconazole [2] + fludioxonyl [2] + oxathiapiproline [2]
205: * [10] + triticonazole [2] + tolcrofosmethyl [2] + ethaboxam [2]
206: * [10] + Triticonazole [2] + Torcrolophosmethyl [2] + Metalaxyl [2]
207: * [10] + Triticonazole [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
208: * [10] + triticonazole [2] + tolcrofosmethyl [2] + fluopicolide [2]
209: * [10] + triticonazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
210: * [10] + Triticonazole [2] + Impylfluxam [2] + Etaboxam [2]
211: * [10] + Triticonazole [2] + Impylfluxam [2] + Metalaxyl [2]
212: * [10] + Triticonazole [2] + Impylfluxam [2] + Metalaxyl M [1]
213: * [10] + Triticonazole [2] + Impylfluxam [2] + Fluopicolide [2]
214: * [10] + Triticonazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
215: * [10] + Triticonazole [2] + Tifluzamide [2] + Etaboxam [2]
216: * [10] + Triticonazole [2] + Thifluzamide [2] + Metalaxyl [2]
217: * [10] + Triticonazole [2] + Thifluzamide [2] + Metalaxyl M [1]
218: * [10] + Triticonazole [2] + Thifluzamide [2] + Fluopicolide [2]
219: * [10] + Triticonazole [2] + Thifluzamide [2] + Oxathiapiproline [2]
220: * [10] + triticonazole [2] + penflufen [2] + ethaboxam [2]
221: * [10] + Triticonazole [2] + Penflufen [2] + Metalaxyl [2]
222: * [10] + Triticonazole [2] + Penflufen [2] + Metalaxyl M [1]
223: * [10] + triticonazole [2] + penflufen [2] + fluopicolide [2]
224: * [10] + Triticonazole [2] + Penflufen [2] + Oxathiapiproline [2]
225: * [10] + Triticonazole [2] + Sedaxane [2] + Etaboxam [2]
226: * [10] + Triticonazole [2] + Sedaxane [2] + Metalaxyl [2]
227: * [10] + Triticonazole [2] + Sedaxane [2] + Metalaxyl M [1]
228: * [10] + Triticonazole [2] + Sedaxane [2] + Fluopicolide [2]
229: * [10] + Triticonazole [2] + Sedaxane [2] + Oxathiapiproline [2]
230: * [10] + Triticonazole [2] + Floxapyroxad [2] + Etaboxam [2]
231: * [10] + Triticonazole [2] + Floxapyroxad [2] + Metalaxyl [2]
232: * [10] + Triticonazole [2] + Floxapyroxad [2] + Metalaxyl M [1]
233: * [10] + Triticonazole [2] + Floxapyroxad [2] + Fluopicolide [2]
234: * [10] + Triticonazole [2] + Floxapyroxad [2] + Oxathiapiproline [2]
235: * [10] + triticonazole [2] + fluopyram [2] + ethaboxam [2]
236: * [10] + Triticonazole [2] + Fluopyram [2] + Metalaxyl [2]
237: * [10] + Triticonazole [2] + Fluopyram [2] + Metalaxyl M [1]
238: * [10] + Triticonazole [2] + Fluopyram [2] + Fluopicolide [2]
239: * [10] + Triticonazole [2] + Fluopyram [2] + Oxathiapiproline [2]
240: * [10] + triticonazole [2] + fludioxonil [2] + ethaboxam [2]
241: * [10] + Triticonazole [2] + Fludioxonyl [2] + Metalaxyl [2]
242: * [10] + Triticonazole [2] + Fludioxonyl [2] + Metalaxyl M [1]
243: * [10] + Triticonazole [2] + Fludioxonil [2] + Fluopicolide [2]
244: * [10] + Triticonazole [2] + Fludioxonyl [2] + Oxathiapiproline [2]
245: * [10] + Fluquinconazole [2] + Torquelofosmethyl [2] + Etaboxam [2]
246: * [10] + Fluquinconazole [2] + Torquelofosmethyl [2] + Metalaxyl
247: * [10] + Fluquinconazole [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
248: * [10] + fluquinconazole [2] + tolcrofosmethyl [2] + fluopicolide [2]
249: * [10] + fluquinconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
250: * [10] + Fluquinconazole [2] + Impylfluxam [2] + Etaboxam [2]
251: * [10] + Fluquinconazole [2] + Impylfluxam [2] + Metalaxyl [2]
252: * [10] + Fluquinconazole [2] + Impylfluxam [2] + Metalaxyl M [1]
253: * [10] + Fluquinconazole [2] + Impylfluxam [2] + Fluopicolide [2]
254: * [10] + Fluquinconazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
255: * [10] + fluquinconazole [2] + tifluzamide [2] + ethaboxam [2]
256: * [10] + fluquinconazole [2] + tifluzamide [2] + metalaxyl [2]
257: * [10] + Fluquinconazole [2] + Tifluzamide [2] + Metalaxyl M [1]
258: * [10] + Fluquinconazole [2] + Tifluzamide [2] + Fluopicolide [2]
259: * [10] + fluquinconazole [2] + tifluzamide [2] + oxathiapiproline [2]
260: * [10] + fluquinconazole [2] + penflufen [2] + ethaboxam [2]
261: * [10] + fluquinconazole [2] + penflufen [2] + metalaxyl [2]
262: * [10] + fluquinconazole [2] + penflufen [2] + metalaxyl M [1]
263: * [10] + fluquinconazole [2] + penflufen [2] + fluopicolide [2]
264: * [10] + fluquinconazole [2] + penflufen [2] + oxathiapiproline [2]
265: * [10] + Fluquinconazole [2] + Sedaxane [2] + Etaboxam [2]
266: * [10] + Fluquinconazole [2] + Sedaxane [2] + Metalaxyl [2]
267: * [10] + Fluquinconazole [2] + Sedaxane [2] + Metalaxyl M [1]
268: * [10] + fluquinconazole [2] + sedaxane [2] + fluopicolide [2]
269: * [10] + Fluquinconazole [2] + Sedaxane [2] + Oxathiapiproline [2]
270: * [10] + Fluquinconazole [2] + Floxapyroxad [2] + Etaboxam [2]
271: * [10] + Fluquinconazole [2] + Floxapyroxad [2] + Metalaxyl [2]
272: * [10] + Fluquinconazole [2] + Floxapyroxad [2] + Metalaxyl M [1]
273: * [10] + Fluquinconazole [2] + Floxapyroxad [2] + Fluopicolide [2]
274: * [10] + Fluquinconazole [2] + Floxapyroxad [2] + Oxathiapiproline [2]
275: * [10] + fluquinconazole [2] + fluopyram [2] + ethaboxam [2]
276: * [10] + fluquinconazole [2] + fluopyram [2] + metalaxyl [2]
277: * [10] + fluquinconazole [2] + fluopyram [2] + metalaxyl M [1]
278: * [10] + fluquinconazole [2] + fluopyram [2] + fluopicolide [2]
279: * [10] + fluquinconazole [2] + fluopyram [2] + oxathiapiproline [2]
280: * [10] + fluquinconazole [2] + fludioxonil [2] + ethaboxam [2]
281: * [10] + fluquinconazole [2] + fludioxonil [2] + metalaxyl [2]
282: * [10] + fluquinconazole [2] + fludioxonil [2] + metalaxyl M [1]
283: * [10] + fluquinconazole [2] + fludioxonil [2] + fluopicolide [2]
284: * [10] + fluquinconazole [2] + fludioxonil [2] + oxathiapiproline [2]
285: * [10] + prothioconazole [2] + tolcrofosmethyl [2] + ethaboxam [2]
286: * [10] + prothioconazole [2] + tolcrofosmethyl [2] + metalaxyl [2]
287: * [10] + prothioconazole [2] + tolcrofosmethyl [2] + metalaxyl M [1]
288: * [10] + Prothioconazole [2] + Torulofosmethyl [2] + Fluopicolide [2]
289: * [10] + prothioconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
290: * [10] + Prothioconazole [2] + Impylfluxam [2] + Etaboxam [2]
291: * [10] + Prothioconazole [2] + Impylfluxam [2] + Metalaxyl [2]
292: * [10] + Prothioconazole [2] + Impylfluxam [2] + Metalaxyl M [1]
293: * [10] + Prothioconazole [2] + Impylfluxam [2] + Fluopicolide [2]
294: * [10] + Prothioconazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
295: * [10] + prothioconazole [2] + tifluzamide [2] + ethaboxam [2]
296: * [10] + Prothioconazole [2] + Thifluzamide [2] + Metalaxyl [2]
297: * [10] + Prothioconazole [2] + Thifluzamide [2] + Metalaxyl M [1]
298: * [10] + Prothioconazole [2] + Thifluzamide [2] + Fluopicolide [2]
299: * [10] + Prothioconazole [2] + Thifluzamide [2] + Oxathiapiproline [2]
300: * [10] + prothioconazole [2] + penflufen [2] + ethaboxam [2]
301: * [10] + Prothioconazole [2] + Penflufen [2] + Metalaxyl [2]
302: * [10] + Prothioconazole [2] + Penflufen [2] + Metalaxyl M [1]
303: * [10] + prothioconazole [2] + penflufen [2] + fluopicolide [2]
304: * [10] + Prothioconazole [2] + Penflufen [2] + Oxathiapiproline [2]
305: * [10] + Prothioconazole [2] + Sedaxane [2] + Etaboxam [2]
306: * [10] + Prothioconazole [2] + Sedaxane [2] + Metalaxyl [2]
307: * [10] + Prothioconazole [2] + Sedaxane [2] + Metalaxyl M [1]
308: * [10] + Prothioconazole [2] + Sedaxane [2] + Fluopicolide [2]
309: * [10] + Prothioconazole [2] + Sedaxane [2] + Oxathiapiproline [2]
310: * [10] + prothioconazole [2] + floxapyradod [2] + ethaboxam [2]
311: * [10] + Prothioconazole [2] + Floxapyroxad [2] + Metalaxyl [2]
312: * [10] + Prothioconazole [2] + Floxapyroxad [2] + Metalaxyl M
313: * [10] + Prothioconazole [2] + Floxapyroxad [2] + Fluopicolide [2]
314: * [10] + Prothioconazole [2] + Floxapyroxad [2] + Oxathiapiproline [2]
315: * [10] + prothioconazole [2] + fluopyram [2] + ethaboxam [2]
316: * [10] + Prothioconazole [2] + Fluopyram [2] + Metalaxyl [2]
317: * [10] + Prothioconazole [2] + Fluopyram [2] + Metalaxyl M [1]
318: * [10] + Prothioconazole [2] + Fluopyram [2] + Fluopicolide [2]
319: * [10] + Prothioconazole [2] + Fluopyram [2] + Oxathiapiproline [2]
320: * [10] + prothioconazole [2] + fludioxonil [2] + ethaboxam [2]
321: * [10] + Prothioconazole [2] + Fludioxonyl [2] + Metalaxyl [2]
322: * [10] + prothioconazole [2] + fludioxonyl [2] + metalaxyl M [1]
323: * [10] + prothioconazole [2] + fludioxonil [2] + fluopicolide [2]
324: * [10] + Prothioconazole [2] + Fludioxonyl [2] + Oxathiapiproline [2]
325: * [10] + diniconazole [2] + tolcrofosmethyl [2] + ethaboxam [2]
326: * [10] + diniconazole [2] + tolcrofosmethyl [2] + metalaxyl [2]
327: * [10] + diniconazole [2] + tolcrofosmethyl [2] + metalaxyl M [1]
328: * [10] + diniconazole [2] + tolcrofosmethyl [2] + fluopicolide [2]
329: * [10] + diniconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
330: * [10] + Diniconazole [2] + Impylfluxam [2] + Etaboxam [2]
331: * [10] + Diniconazole [2] + Impylfluxam [2] + Metalaxyl [2]
332: * [10] + Diniconazole [2] + Impylfluxam [2] + Metalaxyl M [1]
333: * [10] + Diniconazole [2] + Impylfluxam [2] + Fluopicolide [2]
334: * [10] + Diniconazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
335: * [10] + diniconazole [2] + tifluzamide [2] + ethaboxam [2]
336: * [10] + Diniconazole [2] + Thifluzamide [2] + Metalaxyl [2]
337: * [10] + Diniconazole [2] + Thifluzamide [2] + Metalaxyl M
338: * [10] + Diniconazole [2] + Thifluzamide [2] + Fluopicolide [2]
339: * [10] + Diniconazole [2] + Thifluzamide [2] + Oxathiapiproline [2]
340: * [10] + diniconazole [2] + penflufen [2] + ethaboxam [2]
341: * [10] + Diniconazole [2] + Penflufen [2] + Metalaxyl [2]
342: * [10] + Diniconazole [2] + Penflufen [2] + Metalaxyl M
343: * [10] + diniconazole [2] + penflufen [2] + fluopicolide [2]
344: * [10] + diniconazole [2] + penflufen [2] + oxathiapiproline [2]
345: * [10] + Diniconazole [2] + Sedaxane [2] + Etaboxam [2]
346: * [10] + Diniconazole [2] + Sedaxane [2] + Metalaxyl [2]
347: * [10] + Diniconazole [2] + Sedaxane [2] + Metalaxyl M
348: * [10] + Diniconazole [2] + Sedaxane [2] + Fluopicolide [2]
349: * [10] + Diniconazole [2] + Sedaxane [2] + Oxathiapiproline [2]
350: * [10] + Diniconazole [2] + Floxapyroxad [2] + Etaboxam [2]
351: * [10] + Diniconazole [2] + Floxapyroxad [2] + Metalaxyl [2]
352: * [10] + Diniconazole [2] + Floxapyradod [2] + Metalaxyl M
353: * [10] + Diniconazole [2] + Floxapyroxide [2] + Fluopicolide [2]
354: * [10] + Diniconazole [2] + Floxapyroxad [2] + Oxathiapiproline [2]
355: * [10] + Diniconazole [2] + Fluopyram [2] + Etaboxam [2]
356: * [10] + Diniconazole [2] + Fluopyram [2] + Metalaxyl [2]
357: * [10] + Diniconazole [2] + Fluopyram [2] + Metalaxyl M [1]
358: * [10] + diniconazole [2] + fluopyram [2] + fluopicolide [2]
359: * [10] + diniconazole [2] + fluopyram [2] + oxathiapiproline [2]
360: * [10] + diniconazole [2] + fludioxonil [2] + ethaboxam [2]
361: * [10] + Diniconazole [2] + Fludioxonyl [2] + Metalaxyl [2]
362: * [10] + diniconazole [2] + fludioxonyl [2] + metalaxyl M
363: * [10] + diniconazole [2] + fludioxonil [2] + fluopicolide [2]
364: * [10] + Diniconazole [2] + Fludioxonyl [2] + Oxathiapiproline [2]
365: * [10] + Diniconazole M [2] + Torquelofosmethyl [2] + Etaboxam [2]
366: * [10] + Diniconazole M [2] + Torquelophosmethyl [2] + Metalaxyl [2]
367: * [10] + Diniconazole M [2] + Torquelophosmethyl [2] + Metalaxyl M [1]
368: * [10] + Diniconazole M [2] + Torquelofosmethyl [2] + Fluoropicolide [2]
369: * [10] + Diniconazole M [2] + Torquelophosmethyl [2] + Oxathiapiproline [2]
370: * [10] + Diniconazole M [2] + Impylfluxam [2] + Etaboxam [2]
371: * [10] + Diniconazole M [2] + Impylfluxam [2] + Metalaxyl [2]
372: * [10] + Diniconazole M [2] + Impylfluxam [2] + Metalaxyl M [1]
373: * [10] + Diniconazole M [2] + Impylfluxam [2] + Fluopicolide [2]
374: * [10] + Diniconazole M [2] + Impylfluxam [2] + Oxathiapiproline [2]
375: * [10] + Diniconazole M [2] + Tifluzamide [2] + Etaboxam [2]
376: * [10] + Diniconazole M [2] + Thifluzamide [2] + Metalaxyl [2]
377: * [10] + Diniconazole M [2] + Thifluzamide [2] + Metalaxyl M [1]
378: * [10] + Diniconazole M [2] + Thifluzamide [2] + Fluopicolide [2]
379: * [10] + Diniconazole M [2] + Thifluzamide [2] + Oxathiapiproline [2]
380: * [10] + Diniconazole M [2] + Penflufen [2] + Etaboxam [2]
381: * [10] + Diniconazole M [2] + Penflufen [2] + Metalaxyl [2]
382: * [10] + Diniconazole M [2] + Penflufen [2] + Metalaxyl M [1]
383: * [10] + Diniconazole M [2] + Penflufen [2] + Fluopicolide [2]
384: * [10] + Diniconazole M [2] + Penflufen [2] + Oxathiapiproline [2]
385: * [10] + Diniconazole M [2] + Sedaxane [2] + Etaboxam [2]
386: * [10] + Diniconazole M [2] + Sedaxane [2] + Metalaxyl [2]
387: * [10] + Diniconazole M [2] + Sedaxane [2] + Metalaxyl M [1]
388: * [10] + Diniconazole M [2] + Sedaxane [2] + Fluopicolide [2]
389: * [10] + Diniconazole M [2] + Sedaxane [2] + Oxathiapiproline [2]
390: * [10] + Diniconazole M [2] + Floxapyroxad [2] + Etaboxam [2]
391: * [10] + Diniconazole M [2] + Floxapyroxad [2] + Metalaxyl [2]
392: * [10] + Diniconazole M [2] + Floxapyroxad [2] + Metalaxyl M [1]
393: * [10] + Diniconazole M [2] + Floxapyroxad [2] + Fluopicolide [2]
394: * [10] + Diniconazole M [2] + Floxapyradod [2] + Oxathiapiproline [2]
395: * [10] + Diniconazole M [2] + Fluopyram [2] + Etaboxam [2]
396: * [10] + Diniconazole M [2] + Fluopyram [2] + Metalaxyl [2]
397: * [10] + Diniconazole M [2] + Fluopyram [2] + Metalaxyl M [1]
398: * [10] + Diniconazole M [2] + Fluopyram [2] + Fluopicolide [2]
399: * [10] + Diniconazole M [2] + Fluopyram [2] + Oxathiapiproline [2]
400: * [10] + Diniconazole M [2] + Fludioxonyl [2] + Etaboxam [2]
401: * [10] + Diniconazole M [2] + Fludioxonyl [2] + Metalaxyl [2]
402: * [10] + diniconazole M [2] + fludioxonyl [2] + metalaxyl M [1]
403: * [10] + Diniconazole M [2] + Fludioxonyl [2] + Fluopicolide [2]
404: * [10] + Diniconazole M [2] + Fludioxonyl [2] + Oxathiapiproline [2]
405: * [10] + ipconazole [2] + torquelofosmethyl [2] + ethaboxam [2]
406: * [10] + ipconazole [2] + torquelofosmethyl [2] + metalaxyl [2]
407: * [10] + ipconazole [2] + tolcrofosmethyl [2] + metalaxyl M [1]
408: * [10] + ipconazole [2] + torquelofosmethyl [2] + fluopicolide [2]
409: * [10] + ipconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
410: * [10] + ipconazole [2] + impylfluxam [2] + ethaboxam [2]
411: * [10] + ipconazole [2] + impylfluxam [2] + metalaxyl [2]
412: * [10] + ipconazole [2] + impylfluxam [2] + metalaxyl M [1]
413: * [10] + ipconazole [2] + impylfluxam [2] + fluopicolide [2]
414: * [10] + ipconazole [2] + impylfluxam [2] + oxathiapiproline [2]
415: * [10] + ipconazole [2] + tifluzamide [2] + ethaboxam [2]
416: * [10] + ipconazole [2] + tifluzamide [2] + metalaxyl [2]
417: * [10] + ipconazole [2] + tifluzamide [2] + metalaxyl M [1]
418: * [10] + ipconazole [2] + tifluzamide [2] + fluopicolide [2]
419: * [10] + ipconazole [2] + tifluzamide [2] + oxathiapiproline [2]
420: * [10] + ipconazole [2] + penflufen [2] + ethaboxam [2]
421: * [10] + ipconazole [2] + penflufen [2] + metalaxyl [2]
422: * [10] + ipconazole [2] + penflufen [2] + metalaxyl M [1]
423: * [10] + ipconazole [2] + penflufen [2] + fluopicolide [2]
424: * [10] + ipconazole [2] + penflufen [2] + oxathiapiproline [2]
425: * [10] + ipconazole [2] + sedaxane [2] + ethaboxam [2]
426: * [10] + ipconazole [2] + sedaxane [2] + metalaxyl [2]
427: * [10] + ipconazole [2] + sedaxane [2] + metalaxyl M [1]
428: * [10] + ipconazole [2] + sedaxane [2] + fluopicolide [2]
429: * [10] + ipconazole [2] + sedaxane [2] + oxathiapiproline [2]
430: * [10] + ipconazole [2] + floxapyroxad [2] + ethaboxam [2]
431: * [10] + ipconazole [2] + floxapyroxad [2] + metalaxyl [2]
432: * [10] + ipconazole [2] + floxapyroxad [2] + metalaxyl M [1]
433: * [10] + ipconazole [2] + floxapyroxad [2] + fluopicolide [2]
434: * [10] + ipconazole [2] + floxapyroxad [2] + oxathiapiproline [2]
435: * [10] + ipconazole [2] + fluopyram [2] + ethaboxam [2]
436: * [10] + ipconazole [2] + fluopyram [2] + metalaxyl [2]
437: * [10] + ipconazole [2] + fluopyram [2] + metalaxyl M [1]
438: * [10] + ipconazole [2] + fluopyram [2] + fluopicolide [2]
439: * [10] + ipconazole [2] + fluopyram [2] + oxathiapiproline [2]
440: * [10] + ipconazole [2] + fludioxonil [2] + ethaboxam [2]
441: * [10] + ipconazole [2] + fludioxonil [2] + metalaxyl [2]
442: * [10] + ipconazole [2] + fludioxonil [2] + metalaxyl M [1]
443: * [10] + ipconazole [2] + fludioxonil [2] + fluopicolide [2]
444: * [10] + ipconazole [2] + fludioxonil [2] + oxathiapiproline [2]
445: * [10] + fludioxonil [2] + tolcrofosmethyl [2] + ethaboxam [2]
446: * [10] + fludioxonil [2] + tolcrofosmethyl [2] + metalaxyl [2]
447: * [10] + fludioxonil [2] + tolcrofosmethyl [2] + metalaxyl M [1]
448: * [10] + fludioxonil [2] + tolcrofosmethyl [2] + fluopicolide [2]
449: * [10] + fludioxonil [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
450: * [10] + fludioxonil [2] + impylfluxam [2] + ethaboxam [2]
451: * [10] + fludioxonil [2] + impylfluxam [2] + metalaxyl [2]
452: * [10] + fludioxonil [2] + impylfluxam [2] + metalaxyl M [1]
453: * [10] + fludioxonil [2] + impylfluxam [2] + fluopicolide [2]
454: * [10] + fludioxonil [2] + impylfluxam [2] + oxathiapiproline [2]
455: * [10] + fludioxonil [2] + tifluzamide [2] + ethaboxam [2]
456: * [10] + fludioxonil [2] + tifluzamide [2] + metalaxyl [2]
457: * [10] + fludioxonil [2] + tifluzamide [2] + metalaxyl M [1]
458: * [10] + fludioxonil [2] + tifluzamide [2] + fluopicolide [2]
459: * [10] + fludioxonil [2] + tifluzamide [2] + oxathiapiproline [2]
460: * [10] + fludioxonil [2] + penflufen [2] + ethaboxam [2]
461: * [10] + fludioxonil [2] + penflufen [2] + metalaxyl [2]
462: * [10] + fludioxonil [2] + penflufen [2] + metalaxyl M [1]
463: * [10] + fludioxonil [2] + penflufen [2] + fluopicolide [2]
464: * [10] + fludioxonil [2] + penflufen [2] + oxathiapiproline [2]
465: * [10] + fludioxonil [2] + sedaxane [2] + ethaboxam [2]
466: * [10] + fludioxonil [2] + sedaxane [2] + metalaxyl [2]
467: * [10] + fludioxonyl [2] + sedaxan [2] + metalaxyl M [1]
468: * [10] + fludioxonil [2] + sedaxane [2] + fluopicolide [2]
469: * [10] + fludioxonil [2] + sedaxan [2] + oxathiapiproline [2]
470: * [10] + fludioxonil [2] + floxapyroxad [2] + ethaboxam [2]
471: * [10] + fludioxonil [2] + floxapyroxad [2] + metalaxyl [2]
472: * [10] + fludioxonil [2] + floxapyroxad [2] + metalaxyl M [1]
473: * [10] + fludioxonil [2] + floxapyroxad [2] + fluopicolide [2]
474: * [10] + fludioxonil [2] + floxapyradod [2] + oxathiapiproline [2]
475: * [10] + fludioxonil [2] + fluopyram [2] + ethaboxam [2]
476: * [10] + fludioxonil [2] + fluopyram [2] + metalaxyl [2]
477: * [10] + fludioxonil [2] + fluopyram [2] + metalaxyl M [1]
478: * [10] + fludioxonil [2] + fluopyram [2] + fluopicolide [2]
479: * [10] + fludioxonyl [2] + fluopyram [2] + oxathiapiproline [2]
480: * [10] + Prochloraz [2] + Torquelofosmethyl [2] + Etaboxam [2]
481: * [10] + Prochloraz [2] + Torcrolophosmethyl [2] + Metalaxyl [2]
482: * [10] + Prochloraz [2] + Torquelophosmethyl [2] + Metalaxyl M [1]
483: * [10] + Prochloraz [2] + Torquelofosmethyl [2] + Fluoropicolide [2]
484: * [10] + Prochloraz [2] + Torcrolophosmethyl [2] + Oxathiapiproline [2]
485: * [10] + Prochloraz [2] + Impylfluxam [2] + Etaboxam [2]
486: * [10] + Prochloraz [2] + Impylfluxam [2] + Metalaxyl [2]
487: * [10] + Prochloraz [2] + Impylfluxam [2] + Metalaxyl M [1]
488: * [10] + Prochloraz [2] + Impylfluxam [2] + Fluopicolide [2]
489: * [10] + Prochloraz [2] + Impylfluxam [2] + Oxathiapiproline [2]
490: * [10] + prochloraz [2] + tifluzamide [2] + ethaboxam [2]
491: * [10] + Prochloraz [2] + Tifluzamide [2] + Metalaxyl [2]
492: * [10] + Prochloraz [2] + Tifluzamide [2] + Metalaxyl M [1]
493: * [10] + Prochloraz [2] + Tifluzamide [2] + Fluopicolide [2]
494: * [10] + Prochloraz [2] + Tifluzamide [2] + Oxathiapiproline [2]
495: * [10] + Prochloraz [2] + Penflufen [2] + Etaboxam [2]
496: * [10] + Prochloraz [2] + Penflufen [2] + Metalaxyl [2]
497: * [10] + Prochloraz [2] + Penflufen [2] + Metalaxyl M [1]
498: * [10] + Prochloraz [2] + Penflufen [2] + Fluopicolide [2]
]
499: * [10] + Prochloraz [2] + Penflufen [2] + Oxathiapiproline [2]
500: * [10] + Prochloraz [2] + Sedaxane [2] + Etaboxam [2]
501: * [10] + Prochloraz [2] + Sedaxane + [2] Metalaxyl [2]
502: * [10] + Prochloraz [2] + Sedaxane [2] + Metalaxyl M [1]
503: * [10] + Prochloraz [2] + Sedaxane [2] + Fluopicolide [2]
504: * [10] + Prochloraz [2] + Sedaxane [2] + Oxathiapiproline [2]
505: * [10] + Prochloraz [2] + Floxapyroxad [2] + Etaboxam [2]
506: * [10] + Prochloraz [2] + Floxapyroxad [2] + Metalaxyl [2]
507: * [10] + Prochloraz [2] + Floxapyroxad [2] + Metalaxyl M [1]
508: * [10] + Prochloraz [2] + Floxapyroxad [2] + Fluopicolide [2]
509: * [10] + Prochloraz [2] + Floxapyroxad [2] + Oxathiapiproline [2]
510: * [10] + Prochloraz [2] + Fluopyram [2] + Etaboxam [2]
511: * [10] + Prochloraz [2] + Fluopyram [2] + Metalaxyl [2]
512: * [10] + Prochloraz [2] + Fluopyram [2] + Metalaxyl M [1]
513: * [10] + Prochloraz [2] + Fluopyram [2] + Fluopicolide [2]
514: * [10] + Prochloraz [2] + Fluopyram [2] + Oxathiapiproline [2]
515: * [10] + Prochloraz [2] + Fludioxonil [2] + Etaboxam [2]
516: * [10] + Prochloraz [2] + Fludioxonil [2] + Metalaxyl [2]
517: * [10] + Prochloraz [2] + Fludioxonil [2] + Metalaxyl M [1]
518: * [10] + Prochloraz [2] + Fludioxonil [2] + Fluopicolide [2]
519: * [10] + Prochloraz [2] + Fludioxonyl [2] + Oxathiapiproline [2]
520: * [10] + thiuram [2] + tolcrofosmethyl [2] + ethaboxam [2]
521: * [10] + thiuram [2] + tolcrofosmethyl [2] + metalaxyl [2]
522: * [10] + thiuram [2] + tolcrofosmethyl [2] + metalaxyl M [1]
523: * [10] + thiuram [2] + tolcrofosmethyl [2] + fluopicolide [2]
524: * [10] + thiuram [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
525: * [10] + Thiuram [2] + Impylfluxam [2] + Etaboxam [2]
526: * [10] + Thiuram [2] + Impylfluxam [2] + Metalaxyl [2]
527: * [10] + Thiuram [2] + Impylfluxam [2] + Metalaxyl M [1] [2]
528: * [10] + Thiuram [2] + Impylfluxam [2] + Fluopicolide [2]
529: * [10] + Thiuram [2] + Impylfluxam [2] + Oxathiapiproline [2]
530: * [10] + thiuram [2] + tifluzamide [2] + ethaboxam [2]
531: * [10] + thiuram [2] + tifluzamide [2] + metalaxyl [2]
532: * [10] + thiuram [2] + tifluzamide [2] + metalaxyl M [1] [1]
533: * [10] + thiuram [2] + tifluzamide [2] + fluopicolide [2]
534: * [10] + thiuram [2] + tifluzamide [2] + oxathiapiproline [2]
535: * [10] + thiuram [2] + penflufen [2] + ethaboxam [2]
536: * [10] + thiuram [2] + penflufen [2] + metalaxyl [2]
537: * [10] + thiuram [2] + penflufen [2] + metalaxyl M [1]
538: * [10] + Thiuram [2] + Penflufen [2] + Fluopicolide [2]
539: * [10] + thiuram [2] + penflufen [2] + oxathiapiproline [2]
540: * [10] + thiuram [2] + sedaxan [2] + ethaboxam [2]
541: * [10] + Thiuram [2] + Sedaxane [2] + Metalaxyl [2]
542: * [10] + thiuram [2] + sedaxan [2] + metalaxyl M [1]
543: * [10] + Thiuram [2] + Sedaxane [2] + Fluopicolide [2]
544: * [10] + thiuram [2] + sedaxane [2] + oxathiapiproline [2]
545: * [10] + thiuram [2] + floxapyradod [2] + ethaboxam [2]
546: * [10] + Thiuram [2] + Floxapyroxide [2] + Metalaxyl [2]
547: * [10] + Thiuram [2] + Floxapyradod [2] + Metalaxyl M [1]
548: * [10] + thiuram [2] + floxapyroxide [2] + fluopicolide [2]
549: * [10] + Thiuram [2] + Floxapyroxad [2] + Oxathiapiproline [2]
550: * [10] + thiuram [2] + fluopyram [2] + ethaboxam [2]
551: * [10] + thiuram [2] + fluopyram [2] + metalaxyl [2]
552: * [10] + thiuram [2] + fluopyram [2] + metalaxyl M [1]
553: * [10] + thiuram [2] + fluopyram [2] + fluopicolide [2]
554: * [10] + thiuram [2] + fluopyram [2] + oxathiapiproline [2]
555: * [10] + thiuram [2] + fludioxonil [2] + ethaboxam [2]
556: * [10] + thiuram [2] + fludioxonil [2] + metalaxyl [2]
557: * [10] + thiuram [2] + fludioxonil [2] + metalaxyl M [1]
558: * [10] + thiuram [2] + fludioxonil [2] + fluopicolide [2]
559: * [10] + thiuram [2] + fludioxonyl [2] + oxathiapiproline [2]
560: * [10] + thiophanate methyl [2] + tolcrofos methyl [2] + ethaboxam [2]
561: * [10] + thiophanate methyl [2] + tolcrofos methyl [2] + metalaxyl [2]
562: * [10] + thiophanate methyl [2] + tolcrofos methyl [2] + metalaxyl M [1]
563: * [10] + thiophanate methyl [2] + tolcrofos methyl [2] + fluopicolide [2]
564: * [10] + thiophanate methyl [2] + tolcrofos methyl [2] + oxathiapiproline [2]
565: * [10] + thiophanate methyl [2] + impylfluxam [2] + ethaboxam [2]
566: * [10] + Thiophanate methyl [2] + Impylfluxam [2] + Metalaxyl [2]
567: * [10] + thiophanate methyl [2] + impylfluxam [2] + metalaxyl M [1]
568: * [10] + thiophanate methyl [2] + impylfluxam [2] + fluopicolide [2]
569: * [10] + Thiophanate methyl [2] + Impylfluxam [2] + Oxathiapiproline [2]
570: * [10] + thiophanate methyl [2] + tifluzamide [2] + ethaboxam [2]
571: * [10] + thiophanate methyl [2] + tifluzamide [2] + metalaxyl [2]
572: * [10] + thiophanate methyl [2] + tifluzamide [2] + metalaxyl M [1]
573: * [10] + thiophanate methyl [2] + tifluzamide [2] + fluopicolide [2]
574: * [10] + thiophanate methyl [2] + tifluzamide [2] + oxathiapiproline [2]
575: * [10] + thiophanate methyl [2] + penflufen [2] + ethaboxam [2]
576: * [10] + thiophanate methyl [2] + penflufen [2] + metalaxyl [2]
577: * [10] + thiophanate methyl [2] + penflufen [2] + metalaxyl M [1]
578: * [10] + thiophanate methyl [2] + penflufen [2] + fluopicolide [2]
579: * [10] + thiophanate methyl [2] + penflufen [2] + oxathiapiproline [2]
580: * [10] + thiophanate methyl [2] + sedaxan [2] + ethaboxam [2]
581: * [10] + thiophanate methyl [2] + sedaxane [2] + metalaxyl [2]
582: * [10] + thiophanate methyl [2] + sedaxane [2] + metalaxyl M [1]
583: * [10] + thiophanate methyl [2] + sedaxane [2] + fluorpicolide [2]
584: * [10] + thiophanate methyl [2] + sedaxane [2] + oxathiapiproline [2]
585: * [10] + thiophanate methyl [2] + floxapyroxad [2] + ethaboxam [2]
586: * [10] + thiophanate methyl [2] + floxapyroxad [2] + metalaxyl [2]
587: * [10] + thiophanate methyl [2] + floxapyroxad [2] + metalaxyl M [1]
588: * [10] + thiophanate methyl [2] + floxapyroxad [2] + fluopicolide [2]
589: * [10] + thiophanate methyl [2] + floxapyroxad [2] + oxathiapiproline [2]
590: * [10] + thiophanate methyl [2] + fluopyram [2] + ethaboxam [2]
591: * [10] + thiophanate methyl [2] + fluopyram [2] + metalaxyl [2]
592: * [10] + thiophanate methyl [2] + fluopyram [2] + metalaxyl M [1]
593: * [10] + thiophanate methyl [2] + fluopyram [2] + fluopicolide [2]
594: * [10] + thiophanate methyl [2] + fluopyram [2] + oxathiapiproline [2]
595: * [10] + thiophanate methyl [2] + fludioxonil [2] + ethaboxam [2]
596: * [10] + thiophanate methyl [2] + fludioxonyl [2] + metalaxyl [2]
597: * [10] + thiophanate methyl [2] + fludioxonyl [2] + metalaxyl M [1]
598: * [10] + thiophanate methyl [2] + fludioxonyl [2] + fluopicolide [2]
599: * [10] + thiophanate methyl + fludioxonil + oxathiapiproline
600: * [10] + Mandestrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
601: * [10] + Mandestrobin [2] + Torquelofosmethyl [2] + Metalaxyl [2]
602: * [10] + Mandestrobin [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
603: * [10] + Mandestrobin [2] + Torquelofosmethyl [2] + Fluopicolide [2]
604: * [10] + Mandestrobin [2] + Torquelophosmethyl [2] + Oxathiapiproline [2]
605: * [10] + Mandestrobin [2] + Impylfluxam [2] + Etaboxam [2]
606: * [10] + Mandestrobin [2] + Impylfluxam [2] + Metalaxyl [2]
607: * [10] + Mandestrobin [2] + Impylfluxam [2] + Metalaxyl M [1]
608: * [10] + Mandestrobin [2] + Impylfluxam [2] + Fluopicolide [2]
609: * [10] + Mandestrobin [2] + Impylfluxam [2] + Oxathiapiproline [2]
610: * [10] + Mandestrobin [2] + Tifluzamide [2] + Etaboxam [2]
611: * [10] + Mandestrobin [2] + Thifluzamide [2] + Metalaxyl [2]
612: * [10] + Mandestrobin [2] + Thifluzamide [2] + Metalaxyl M [1]
613: * [10] + Mandestrobin [2] + Thifluzamide [2] + Fluopicolide [2]
614: * [10] + Mandestrobin [2] + Thifluzamide [2] + Oxathiapiproline [2]
615: * [10] + Mandestrobin [2] + Penflufen [2] + Etaboxam [2]
616: * [10] + Mandestrobin [2] + Penflufen [2] + Metalaxyl [2]
617: * [10] + Mandestrobin [2] + Penflufen [2] + Metalaxyl M [1]
618: * [10] + Mandestrobin [2] + Penflufen [2] + Fluopicolide [2]
619: * [10] + Mandestrobin [2] + Penflufen [2] + Oxathiapiproline [2]
620: * [10] + Mandestrobin [2] + Sedaxane [2] + Etaboxam [2]
621: * [10] + Mandestrobin [2] + Sedaxane [2] + Metalaxyl [2]
622: * [10] + Mandestrobin [2] + Sedaxane [2] + Metalaxyl M [1]
623: * [10] + Mandestrobin [2] + Sedaxane [2] + Fluopicolide [2]
624: * [10] + Mandestrobin [2] + Sedaxane [2] + Oxathiapiproline [2]
625: * [10] + Mandestrobin [2] + Floxapyroxad [2] + Etaboxam [2]
626: * [10] + Mandestrobin [2] + Floxapyroxad [2] + Metalaxyl [2]
627: * [10] + Mandestrobin [2] + Floxapyroxad [2] + Metalaxyl M [1]
628: * [10] + Mandestrobin [2] + Floxapyroxad [2] + Fluopicolide [2]
629: * [10] + Mandestrobin [2] + Floxapyroxad [2] + Oxathiapiproline [2]
630: * [10] + mandestrobin [2] + fluopyram [2] + ethaboxam [2]
631: * [10] + Mandestrobin [2] + Fluopyram [2] + Metalaxyl [2]
632: * [10] + Mandestrobin [2] + Fluopyram [2] + Metalaxyl M [1]
633: * [10] + Mandestrobin [2] + Fluopyram [2] + Fluopicolide [2]
634: * [10] + Mandestrobin [2] + Fluopyram [2] + Oxathiapiproline [2]
635: * [10] + mandestrobin [2] + fludioxonil [2] + ethaboxam [2]
636: * [10] + Mandestrobin [2] + Fludioxonil [2] + Metalaxyl [2]
637: * [10] + Mandestrobin [2] + Fludioxonil [2] + Metalaxyl M [1]
638: * [10] + Mandestrobin [2] + Fludioxonil [2] + Fluopicolide [2]
639: * [10] + Mandestrobin [2] + Fludioxonyl [2] + Oxathiapiproline [2]
640: * [10] + Azoxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
641: * [10] + Azoxystrobin [2] + Torquelophosmethyl [2] + Metalaxyl [2]
642: * [10] + Azoxystrobin [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
643: * [10] + Azoxystrobin [2] + Torquelofosmethyl [2] + Fluopicolide [2]
644: * [10] + azoxystrobin [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
645: * [10] + azoxystrobin [2] + impylfluxam [2] + ethaboxam [2]
646: * [10] + Azoxystrobin [2] + Impylfluxam [2] + Metalaxyl [2]
647: * [10] + Azoxystrobin [2] + Impylfluxam [2] + Metalaxyl M [1]
648: * [10] + Azoxystrobin [2] + Impylfluxam [2] + Fluopicolide [2]
649: * [10] + Azoxystrobin [2] + Impylfluxam [2] + Oxathiapiproline [2]
650: * [10] + azoxystrobin [2] + tifluzamide [2] + ethaboxam [2]
651: * [10] + Azoxystrobin [2] + Thifluzamide [2] + Metalaxyl [2]
652: * [10] + Azoxystrobin [2] + Thifluzamide [2] + Metalaxyl M [1]
653: * [10] + Azoxystrobin [2] + Thifluzamide [2] + Fluopicolide [2]
654: * [10] + Azoxystrobin [2] + Thifluzamide [2] + Oxathiapiproline [2]
655: * [10] + azoxystrobin [2] + penflufen [2] + ethaboxam [2]
656: * [10] + azoxystrobin [2] + penflufen [2] + metalaxyl [2]
657: * [10] + Azoxystrobin [2] + Penflufen [2] + Metalaxyl M [1]
658: * [10] + Azoxystrobin [2] + Penflufen [2] + Fluopicolide [2]
659: * [10] + azoxystrobin [2] + penflufen [2] + oxathiapiproline [2]
660: * [10] + azoxystrobin [2] + sedaxan [2] + ethaboxam [2]
661: * [10] + azoxystrobin [2] + sedaxan [2] + metalaxyl [2]
662: * [10] + Azoxystrobin [2] + Sedaxane [2] + Metalaxyl M [1]
663: * [10] + Azoxystrobin [2] + Sedaxane [2] + Fluopicolide [2]
664: * [10] + Azoxystrobin [2] + Sedaxane [2] + Oxathiapiproline [2]
665: * [10] + Azoxystrobin [2] + Floxapyroxad [2] + Etaboxam [2]
666: * [10] + Azoxystrobin [2] + Floxapyroxad [2] + Metalaxyl [2]
667: * [10] + Azoxystrobin [2] + Floxapyradod [2] + Metalaxyl M [1]
668: * [10] + Azoxystrobin [2] + Floxapyroxad [2] + Fluopicolide [2]
669: * [10] + Azoxystrobin [2] + Floxapyradod [2] + Oxathiapiproline [2]
670: * [10] + azoxystrobin [2] + fluopyram [2] + ethaboxam [2]
671: * [10] + Azoxystrobin [2] + Fluopyram [2] + Metalaxyl [2]
672: * [10] + Azoxystrobin [2] + Fluopyram [2] + Metalaxyl M [1]
673: * [10] + Azoxystrobin [2] + Fluopyram [2] + Fluopicolide [2]
674: * [10] + Azoxystrobin [2] + Fluopyram [2] + Oxathiapiproline [2]
675: * [10] + azoxystrobin [2] + fludioxonil [2] + ethaboxam [2]
676: * [10] + azoxystrobin [2] + fludioxonil [2] + metalaxyl [2]
677: * [10] + azoxystrobin [2] + fludioxonil [2] + metalaxyl M [1]
678: * [10] + azoxystrobin [2] + fludioxonil [2] + fluopicolide [2]
679: * [10] + Azoxystrobin [2] + Fludioxonyl [2] + Oxathiapiproline [2]
680: * [10] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
681: * [10] + Fluoxastrobin [2] + Torquelofosmethyl [2] + Metalaxyl [2]
682: * [10] + fluoxastrobin [2] + tolcrofosmethyl [2] + metalaxyl M [1]
683: * [10] + fluoxastrobin [2] + tolcrofosmethyl [2] + fluopicolide
684: * [10] + fluoxastrobin [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
685: * [10] + Fluoxastrobin [2] + Impylfluxam [2] + Etaboxam [2]
686: * [10] + Fluoxastrobin [2] + Impylfluxam [2] + Metalaxyl [2]
687: * [10] + Fluoxastrobin [2] + Impylfluxam [2] + Metalaxyl M [1]
688: * [10] + Fluoxastrobin [2] + Impylfluxam [2] + Fluopicolide [2]
689: * [10] + Fluoxastrobin [2] + Impylfluxam [2] + Oxathiapiproline [2]
690: * [10] + fluoxastrobin [2] + tifluzamide [2] + ethaboxam [2]
691: * [10] + Fluoxastrobin [2] + Thifluzamide [2] + Metalaxyl [2]
692: * [10] + Fluoxastrobin [2] + Thifluzamide [2] + Metalaxyl M [1]
693: * [10] + fluoxastrobin [2] + tifluzamide [2] + fluopicolide [2]
694: * [10] + Fluoxastrobin [2] + Thifluzamide [2] + Oxathiapiproline [2]
695: * [10] + fluoxastrobin [2] + penflufen [2] + ethaboxam [2]
696: * [10] + Fluoxastrobin [2] + Penflufen [2] + Metalaxyl [2]
697: * [10] + Fluoxastrobin [2] + Penflufen [2] + Metalaxyl M [1]
698: * [10] + Fluoxastrobin [2] + Penflufen [2] + Fluopicolide [2]
699: * [10] + Fluoxastrobin [2] + Penflufen [2] + Oxathiapiproline [2]
700: * [10] + Fluoxastrobin [2] + Sedaxane [2] + Etaboxam [2]
701: * [10] + Fluoxastrobin [2] + Sedaxane [2] + Metalaxyl [2]
702: * [10] + Fluoxastrobin [2] + Sedaxane [2] + Metalaxyl M [1]
703: * [10] + Fluoxastrobin [2] + Sedaxane [2] + Fluopicolide [2]
704: * [10] + Fluoxastrobin [2] + Sedaxane [2] + Oxathiapiproline [2]
705: * [10] + Fluoxastrobin [2] + Floxapyroxad [2] + Etaboxam [2]
706: * [10] + Fluoxastrobin [2] + Floxapyroxad [2] + Metalaxyl [2]
707: * [10] + Fluoxastrobin [2] + Floxapyroxad [2] + Metalaxyl M [1]
708: * [10] + Fluoxastrobin [2] + Floxapyroxad [2] + Fluopicolide [2]
709: * [10] + Fluoxastrobin [2] + Floxapyroxad [2] + Oxathiapiproline [2]
710: * [10] + fluoxastrobin [2] + fluopyram [2] + ethaboxam [2]
711: * [10] + fluoxastrobin [2] + fluopyram [2] + metalaxyl [2]
712: * [10] + Fluoxastrobin [2] + Fluopyram [2] + Metalaxyl M [1]
[2]
713: * [10] + Fluoxastrobin [2] + Fluopyram + Fluopicolide
[2]
714: * [10] + Fluoxastrobin [2] + Fluopyram [2] + Oxathiapiproline [2]
715: * [10] + fluoxastrobin [2] + fludioxonil [2] + ethaboxam [2]
716: * [10] + Fluoxastrobin [2] + Fludioxonil [2] + Metalaxyl [2]
717: * [10] + fluoxastrobin [2] + fludioxonil [2] + metalaxyl M [1]
718: * [10] + Fluoxastrobin [2] + Fludioxonil [2] + Fluopicolide [2]
719: * [10] + Fluoxastrobin [2] + Fludioxonyl [2] + Oxathiapiproline [2]
720: * [10] + Trifloxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
721: * [10] + Trifloxystrobin [2] + Torquelofosmethyl [2] + Metalaxyl [2]
722: * [10] + Trifloxystrobin [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
723: * [10] + Trifloxystrobin [2] + Torquelofosmethyl [2] + Fluopicolide [2]
724: * [10] + Trifloxystrobin [2] + Torquelophosmethyl [2] + Oxathiapiproline [2]
725: * [10] + Trifloxystrobin [2] + Impylfluxam [2] + Etaboxam [2]
726: * [10] + Trifloxystrobin [2] + Impylfluxam [2] + Metalaxyl [2]
727: * [10] + Trifloxystrobin [2] + Impylfluxam [2] + Metalaxyl M [1]
728: * [10] + Trifloxystrobin [2] + Impylfluxam [2] + Fluopicolide [2]
729: * [10] + Trifloxystrobin [2] + Impylfluxam [2] + Oxathiapiproline [2]
730: * [10] + Trifloxystrobin [2] + Tifluzamide [2] + Etaboxam [2]
731: * [10] + Trifloxystrobin [2] + Tifluzamide [2] + Metalaxyl [2]
732: * [10] + Trifloxystrobin [2] + Tifluzamide [2] + Metalaxyl M [1]
733: * [10] + trifloxystrobin [2] + tifluzamide [2] + fluopicolide [2]
734: * [10] + Trifloxystrobin [2] + Tifluzamide [2] + Oxathiapiproline [2]
735: * [10] + trifloxystrobin [2] + penflufen [2] + ethaboxam [2]
736: * [10] + Trifloxystrobin [2] + Penflufen [2] + Metalaxyl [2]
737: * [10] + Trifloxystrobin [2] + Penflufen [2] + Metalaxyl M [1]
738: * [10] + Trifloxystrobin [2] + Penflufen [2] + Fluopicolide [2]
739: * [10] + Trifloxystrobin [2] + Penflufen [2] + Oxathiapiproline [2]
740: * [10] + Trifloxystrobin [2] + Sedaxane [2] + Etaboxam [2]
741: * [10] + Trifloxystrobin [2] + Sedaxane [2] + Metalaxyl [2]
742: * [10] + Trifloxystrobin [2] + Sedaxane [2] + Metalaxyl M [1]
743: * [10] + Trifloxystrobin [2] + Sedaxane [2] + Fluopicolide [2]
744: * [10] + Trifloxystrobin [2] + Sedaxane [2] + Oxathiapiproline [2]
745: * [10] + Trifloxystrobin [2] + Floxapyroxad [2] + Etaboxam [2]
746: * [10] + Trifloxystrobin [2] + Floxapyroxad [2] + Metalaxyl [2]
747: * [10] + Trifloxystrobin [2] + Floxapyroxad [2] + Metalaxyl M [1]
748: * [10] + Trifloxystrobin [2] + Floxapyroxad [2] + Fluopicolide [2]
749: * [10] + Trifloxystrobin [2] + Floxapyroxad [2] + Oxathiapiproline [2]
750: * [10] + trifloxystrobin [2] + fluopyram [2] + ethaboxam [2]
751: * [10] + Trifloxystrobin [2] + Fluopyram [2] + Metalaxyl [2]
752: * [10] + Trifloxystrobin [2] + Fluopyram [2] + Metalaxyl M [1]
753: * [10] + Trifloxystrobin [2] + Fluopyram [2] + Fluopicolide [2]
754: * [10] + Trifloxystrobin [2] + Fluopyram [2] + Oxathiapiproline [2]
755: * [10] + trifloxystrobin [2] + fludioxonil [2] + ethaboxam [2]
756: * [10] + Trifloxystrobin [2] + Fludioxonil [2] + Metalaxyl [2]
757: * [10] + Trifloxystrobin [2] + Fludioxonil [2] + Metalaxyl M [1]
758: * [10] + Trifloxystrobin [2] + Fludioxonil [2] + Fluopicolide [2]
759: * [10] + Trifloxystrobin [2] + Fludioxonil [2] + Oxathiapiproline [2]
760: * [10] + pyraclostrobin [2] + torquelofosmethyl [2] + ethaboxam [2]
761: * [10] + pyraclostrobin [2] + torquelofosmethyl [2] + metalaxyl [2]
762: * [10] + pyraclostrobin [2] + tolcrofosmethyl [2] + metalaxyl M [1]
763: * [10] + pyraclostrobin [2] + torquelofosmethyl [2] + fluopicolide [2]
764: * [10] + pyraclostrobin [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
765: * [10] + pyraclostrobin [2] + impylfluxam [2] + ethaboxam [2]
766: * [10] + pyraclostrobin [2] + impylfluxam + [2] metalaxyl [2]
767: * [10] + Pyraclostrobin [2] + Impylfluxam + [2] Metalaxyl M [1]
768: * [10] + pyraclostrobin [2] + impylfluxam [2] + fluopicolide [2]
769: * [10] + pyraclostrobin [2] + impylfluxam [2] + oxathiapiproline [2]
770: * [10] + pyraclostrobin [2] + tifluzamide [2] + ethaboxam [2]
771: * [10] + pyraclostrobin [2] + tifluzamide [2] + metalaxyl [2]
772: * [10] + pyraclostrobin [2] + tifluzamide [2] + metalaxyl M [1]
773: * [10] + pyraclostrobin [2] + tifluzamide [2] + fluopicolide [2]
774: * [10] + pyraclostrobin [2] + tifluzamide [2] + oxathiapiproline [2]
775: * [10] + pyraclostrobin [2] + penflufen [2] + ethaboxam [2]
776: * [10] + pyraclostrobin [2] + penflufen [2] + metalaxyl [2]
777: * [10] + pyraclostrobin [2] + penflufen [2] + metalaxyl M [1]
778: * [10] + pyraclostrobin [2] + penflufen [2] + fluopicolide [2]
779: * [10] + pyraclostrobin [2] + penflufen [2] + oxathiapiproline [2]
780: * [10] + pyraclostrobin [2] + sedaxane [2] + ethaboxam [2]
781: * [10] + pyraclostrobin [2] + sedaxane [2] + metalaxyl [2]
782: * [10] + pyraclostrobin [2] + sedaxane [2] + metalaxyl M [1]
783: * [10] + pyraclostrobin [2] + sedaxane [2] + fluopicolide [2]
784: * [10] + pyraclostrobin [2] + sedaxane [2] + oxathiapiproline [2]
785: * [10] + pyraclostrobin [2] + floxapyroxad [2] + ethaboxam [2]
786: * [10] + pyraclostrobin [2] + floxapyroxad [2] + metalaxyl [2]
787: * [10] + pyraclostrobin [2] + floxapyroxad [2] + metalaxyl M [1]
788: * [10] + pyraclostrobin [2] + floxapyroxad [2] + fluopicolide [2]
789: * [10] + pyraclostrobin [2] + floxapyroxad [2] + oxathiapiproline [2]
790: * [10] + pyraclostrobin [2] + fluopyram [2] + ethaboxam [2]
791: * [10] + pyraclostrobin [2] + fluopyram [2] + metalaxyl [2]
792: * [10] + pyraclostrobin [2] + fluopyram [2] + metalaxyl M [1]
793: * [10] + pyraclostrobin [2] + fluopyram [2] + fluopicolide [2]
794: * [10] + pyraclostrobin [2] + fluopyram [2] + oxathiapiproline [2]
795: * [10] + pyraclostrobin [2] + fludioxonil + [2] ethaboxam [2]
796: * [10] + pyraclostrobin [2] + fludioxonil [2] + metalaxyl [2]
797: * [10] + pyraclostrobin [2] + fludioxonil [2] + metalaxyl M [1]
798: * [10] + pyraclostrobin [2] + fludioxonil [2] + fluopicolide [2]
799: * [10] + pyraclostrobin [2] + fludioxonil [2] + oxathiapiproline [2]
800: * [10] + metconazole [2] + mandestrobin [2] + torquelofosmethyl [2] + ethaboxam [2]
801: * [10] + metconazole [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
802: * [10] + metconazole [2] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
803: * [10] + metconazole [2] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
804: * [10] + metconazole [2] + pyraclostrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
805: * [10] + tebuconazole [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
806: * [10] + tebuconazole [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
807: * [10] + Tebuconazole [2] + Fluoxastrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
808: * [10] + tebuconazole [2] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
809: * [10] + tebuconazole + pyraclostrobin + tolcrofos methyl + ethaboxam
810: * [10] + difenoconazole [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
811: * [10] + difenoconazole [2] + azoxystrobin + [2] tolcrofosmethyl [2] + ethaboxam [2]
812: * [10] + difenoconazole [2] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
813: * [10] + difenoconazole [2] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
814: * [10] + difenoconazole [2] + pyraclostrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
815: * [10] + Triticonazole [2] + Mandestrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
816: * [10] + Triticonazole [2] + Azoxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
817: * [10] + Triticonazole + Fluoxastrobin + Torquelofos methyl + Etaboxam
818: * [10] + Triticonazole [2] + Trifloxystrobin [2] + Torcrolophosmethyl [2] + Etaboxam [2]
819: * [10] + Triticonazole [2] + Pyraclostrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
820: * [10] + fluquinconazole [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
821: * [10] + Fluquinconazole [2] + Azoxystrobin [2] + Torcrolophosmethyl [2] + Etaboxam [2]
822: * [10] + fluquinconazole [2] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
823: * [10] + Fluquinconazole [2] + Trifloxystrobin [2] + Torcrolophosmethyl [2] + Etaboxam [2]
824: * [10] + Fluquinconazole [2] + Pyraclostrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
825: * [10] + prothioconazole + mandestrobin + tolcrofos methyl + ethaboxam
826: * [10] + prothioconazole [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
827: * [10] + Prothioconazole [2] + Fluoxastrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
828: * [10] + prothioconazole + trifloxystrobin + tolcrofosmethyl + ethaboxam
829: * [10] + prothioconazole [2] + pyraclostrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
830: * [10] + Diniconazole [2] + Mandestrobin + [2] Torquelophosmethyl [2] + Etaboxam [2]
831: * [10] + Diniconazole [2] + Azoxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
832: * [10] + Diniconazole [2] + Fluoxastrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
833: * [10] + diniconazole [2] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
834: * [10] + diniconazole [2] + pyraclostrobin [2] + torquelofosmethyl [2] + ethaboxam [2]
835: * [10] + Diniconazole M [2] + Mandestrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
836: * [10] + Diniconazole M [2] + Azoxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
837: * [10] + Diniconazole M [2] + Fluoxastrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
838: * [10] + Diniconazole M [2] + Trifloxystrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
839: * [10] + Diniconazole M [2] + Pyraclostrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
840: * [10] + ipconazole [2] + mandestrobin [2] + torquelophosmethyl [2] + ethaboxam [2]
841: * [10] + ipconazole [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
842: * [10] + ipconazole [3] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
843: * [10] + ipconazole [3] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
844: * [10] + ipconazole [4] + pyraclostrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
845: * [10] + fludioxonil [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
846: * [10] + fludioxonil [2] + azoxystrobin [2] + torquelophosmethyl [2] + ethaboxam [2]
847: * [10] + fludioxonil [3] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
848: * [10] + fludioxonil [3] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
849: * [10] + fludioxonil [4] + pyraclostrobin [2] + torquelophosmethyl [2] + ethaboxam [2]
850: * [10] + Prochloraz [2] + Mandestrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
851: * [10] + Prochloraz [2] + Azoxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
852: * [10] + Prochloraz [3] + Fluoxastrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
853: * [10] + Prochloraz [3] + Trifloxystrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
854: * [10] + Prochloraz [4] + Pyraclostrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
855: * [10] + thiuram [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
856: * [10] + thiuram [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
857: * [10] + thiuram [3] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
858: * [10] + thiuram [3] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
859: * [10] + thiuram [4] + pyraclostrobin [2] + torquelofosmethyl [2] + ethaboxam [2]
860: * [10] + thiophanate methyl [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
861: * [10] + thiophanate methyl [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
865: * [10] + thiophanate methyl [3] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
863: * [10] + thiophanate methyl [3] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
864: * [10] + thiophanate methyl [4] + pyraclostrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]

Furthermore, the specific example of a composition A is shown below.
Composition A described in [Table A] is a composition composed of each component described in [Table A]. In [Table A], * described in the column for component 1 is the present compound. 1 represents any one of 1-6, and the number described in [] in the column of each component means the weight part of each component. Moreover, the composition A described in [Table A] is represented with the number described in [Table A], and for example, the composition 1 refers to the composition A described in number 1 of [Table A]. α1 means impylufluxam.

[Table A]

Continuation of [Table A]

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Compositions 841-1680
In each of the compositions 1 to 840 described in [Table A], a composition using 2 parts of tebuconazole instead of 2 parts of metconazole.

Composition 1681-2520
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of difenoconazole instead of 2 parts of metconazole.

Compositions 2521-360
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of triticonazole instead of 2 parts of metconazole.

Compositions 3361-4200
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of prothioconazole instead of 2 parts of metconazole.

Compositions 4201-5040
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of diniconazole instead of 2 parts of metconazole.

Compositions 5041-5880
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of diniconazole instead of 2 parts of metconazole.

Composition 5881-6720
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of ipconazole instead of 2 parts of metconazole.

Compositions 6721-7560
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of prochloraz instead of 2 parts of metconazole.

Compositions 7561-8400
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of fluquinconazole instead of 2 parts of metconazole.

Composition 8401-9240
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of triazimenol instead of 2 parts of metconazole.

Compositions A1-A9240
A composition obtained by adding 10 parts of clothianidin and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions B1-B9240
A composition obtained by further adding 10 parts clothianidin and 10 parts cyantraniliprole to each of the above compositions 1 to 9240.

Compositions C1-C9240
A composition obtained by adding 10 parts of clothianidin and 10 parts of fipronil to each of the above compositions 1 to 9240.

Compositions D1-D9240
A composition obtained by adding 10 parts of imidacloprid and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions E1-E9240
A composition obtained by further adding 10 parts of imidacloprid and 10 parts of cyantraniliprole to each of the above compositions 1 to 9240.

Compositions F1-F9240
A composition obtained by adding 10 parts of imidacloprid and 10 parts of fipronil to each of the above compositions 1 to 9240.

Compositions G1-G9240
A composition obtained by adding 10 parts of thiamethoxam and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions H1-H9240
A composition obtained by adding 10 parts of thiamethoxam and 10 parts of cyantraniliprol to each of the above compositions 1 to 9240.

Compositions I1-I9240
A composition obtained by adding 10 parts of thiamethoxam and 10 parts of fipronil to each of the above compositions 1 to 9240 (provided that the composition is 100 parts).

Compositions J1 to J9240
A composition obtained by adding 10 parts of thiacloprid and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions K1 to K9240
A composition obtained by further adding 10 parts of thiacloprid and 10 parts of cyantraniliprole to each of the above compositions 1 to 9240.

Compositions L1-L9240
A composition obtained by adding 10 parts of thiacloprid and 10 parts of fipronil to each of the above compositions 1 to 9240.

Compositions M1-M9240
A composition obtained by adding 10 parts of flupiradifuron and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions N1-N9240
A composition obtained by adding 10 parts of flupiradifuron and 10 parts of cyantraniliprol to each of the above compositions 1 to 9240.

Compositions O1-O9240
A composition obtained by further adding 10 parts of flupiradiflon and 10 parts of fipronil to each of the above compositions 1 to 9240.

Compositions P1-P9240
A composition obtained by adding 20 parts of clothianidin to each of the above compositions 1 to 9240.

Compositions Q1-Q9240
A composition obtained by adding 10 parts of flupirmine and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions R1-R9240
A composition in which 10 parts of flupyrimine and 10 parts of cyantraniliprole are further added to each of the above compositions 1 to 9240.

Compositions S1-S9240
A composition obtained by adding 10 parts of flupirmine and 10 parts of fipronil to each of the above compositions 1 to 9240.

Next, formulation examples are shown.
In addition, MX is composition 1-9240, composition A1-A9240, composition B1-B9240, composition C1-C9240, composition D1-D9240, composition E1-E9240, composition F1-F9240, composition G1. ~ G9240, Compositions H1 to H9240, Compositions I1 to I9240, Compositions J1 to J9240, Compositions K1 to K9240, Compositions L1 to L9240, Compositions M1 to M9240, Compositions N1 to N9240, Compositions O1 to O9240 , Compositions P1 to P9240, Compositions Q1 to Q9240, Compositions R1 to R9240, and Compositions S1 to S9240 means any one composition A.

Formulation Example 1
40 parts of any one of the present compounds 1 to 6, or 40 parts of MX, 35 parts of a mixture of white carbon and polyoxyethylene alkyl ether sulfate ammonium salt (weight ratio 1: 1) and 25 parts of water are added, Each formulation is obtained by mixing.

Formulation Example 2
40 parts of any one of the present compounds 1 to 6, or 40 parts of MX, 3 parts of calcium lignin sulfonate, 2 parts of sodium lauryl sulfate, and 55 parts of synthetic silicon hydroxide are added and mixed to prepare each preparation. obtain.

Formulation Example 3
40 parts of any one of the present compounds 1 to 6, or 40 parts of MX, add 15 parts of a mixture of white carbon and polyoxyethylene alkyl ether sulfate ammonium salt (weight ratio 1: 1) and 45 parts of water, Each formulation is obtained by mixing.

Formulation Example 4
20 parts of any one of these compounds 1 to 6, or 20 parts of MX, 35 parts of a mixture of white carbon and polyoxyethylene alkyl ether sulfate ammonium salt (weight ratio 1: 1), and water are mixed to make 100 parts in total. And each flowable preparation is obtained by mixing.

Formulation Example 5
20 parts of any one of the present compounds 1 to 6, or 20 parts of MX, 1.5 parts of sorbitan trioleate, and 28 parts of an aqueous solution containing 2 parts of polyvinyl alcohol are mixed and pulverized by a wet pulverization method. An aqueous solution containing 0.05 part of xanthan gum and 0.1 part of aluminum magnesium silicate is added to make the total amount 90 parts, and further 10 parts of propylene glycol is added and mixed to obtain each flowable preparation.

Formulation Example 6
By adding 20 parts of any one of the present compounds 1 to 6, or 20 parts of MX, 3 parts of calcium lignin sulfonate, 2 parts of sodium lauryl sulfate, and the rest of the synthetic silicon hydrated silicon to a total amount of 100 parts, and mixing. Obtain each wettable powder.

Formulation Example 7
Mix 3 parts of MX, 3 parts of MX, 1 part of synthetic silicon hydroxide fine powder, 2 parts of calcium lignin sulfonate, 30 parts of bentonite and the remainder of kaolin clay to make 100 parts in total. To do. Next, an appropriate amount of water is added to the mixture, and the mixture is further stirred, granulated with a granulator, and dried by ventilation to obtain granules.

Formulation Example 8
A powder is obtained by adding 0.5 part of any one of the present compounds 1 to 6, or 1 part of MX, 10 parts of talc, and the remainder of kaolin clay to a total amount of 100 parts and mixing.

  Next, application examples of the composition of the present invention to plant seeds will be shown.

Application example 1
Using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), 200 ml of any one of the formulations obtained by the method described in Formulation Example 1, 3, 4 or 5 is used for 100 kg of dried sorghum seeds. Each treated seed is obtained by smearing.

  Moreover, each treated seed is obtained by adding 180 grams of oxabetrinyl to 200 ml of any one of the formulations obtained by the method described in Formulation Example 1 or 3, and performing a smearing treatment in the same manner as described above.

Application example 2
Using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), 200 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 is added to 100 kg of dried sorghum seeds. Each treated seed is obtained by smearing.

  In addition, to 200 ml of any one of the formulations obtained by the method described in Formulation Examples 1, 3, 4 or 5, 40 grams of fluxofenim is added, and each treated seed is obtained by smearing in the same manner as described above. .

Application example 3
10 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 is added to 10 kg of dried corn seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH). Each treated seed is obtained by smearing. The corn may be a genetically modified corn containing a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application example 4
Using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH) 40 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 on 10 kg of dried corn seeds Each treated seed is obtained by smearing.

Application example 5
Apply 100 ml of any one of the preparations obtained by the method described in Preparation Example 1, 4 or 5 to 10 kg of dried corn seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH). Each treated seed is obtained by treatment.

Application Example 6
Each treated seed is obtained by subjecting 10 kg of dried corn seeds to 50 g of any one of the preparations obtained by the method described in Formulation Example 2 or 6.

Application example 7
Using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), 20 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 is added to 10 kg of dried soybean seeds. Each treated seed is obtained by smearing. The soybean may be a genetically modified soybean containing a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application example 8
100 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 is added to 10 kg of dried soybean seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH). Each treated seed is obtained by smearing.

Application example 9
Using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), 50 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 is added to 10 kg of dry cotton seeds. Each treated seed is obtained by smearing. The cotton may be a genetically modified cotton containing a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application Example 10
Using 10 ml of dried oilseed rape seeds, 50 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5, using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH). Each treated seed is obtained by smearing. The oilseed rape may be a genetically modified oilseed rape including a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application Example 11
10 kg of dried oilseed rape seeds, 10 ml of any one of the preparations obtained by the method described in Formulation Examples 1, 3, 4 or 5, using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH) Each treated seed is obtained by smearing.

Application Example 12
Using 10 kg of dried wheat seeds, 50 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH). Each treated seed is obtained by smearing.

Application Example 13
6 kg of any one of the flowable preparations prepared in Preparation Examples 1, 3, 4 and 5 is uniformly applied to 10 kg of potato seed meal to obtain each processed seed meal.

Application Example 14
10 kg of dried rice seed (dried rice cake) is put in a net bag and immersed in a 50-fold water dilution solution of Benrate (registered trademark) wettable powder (Benomil wettable powder, manufactured by Sumitomo Chemical Co., Ltd.) for 10 minutes, Immerse in water for 3 days. While draining rice seeds into a rotary pan-type rice seed coating machine and rotating, reduced iron powder 5 kg, calcined gypsum 600 g, and 100 g of any one of the formulations prepared in Formulation Examples 1, 3, 4 and 5 After adding 5 times water dilution liquid and dressing, 300g of calcined gypsum is further powdered. Thereafter, the rice seeds are taken out from the coating machine, dispersed on a vinyl sheet so as to have a thickness of 1 cm or less, and then allowed to stand and dried to obtain each treated seed.

Application Example 15
After putting 10 kg of dried rice seed (dried rice cake) in a net bag and immersing it in a 20-fold water dilution of Stana (registered trademark) wettable powder (oxolinic acid wettable powder, manufactured by Sumitomo Chemical Co., Ltd.) for 10 minutes, Immerse in tap water for 3 days. While draining rice seeds into a rotating pan-type rice seed coating machine and rotating, Culper (registered trademark) powder 16 (calcium peroxide powder, Hodogaya UPL Co., Ltd.) 20 kg and preparation example 2 100 g of the prepared preparation is added and dressed. Thereafter, the rice seeds are taken out from the coating machine, dispersed on a vinyl sheet so as to have a thickness of 1 cm or less, and then allowed to stand and dried to obtain each treated seed.

Application Example 16
10 kg of dried rice seeds (dry rice cake) is put in a net bag and sterilized by immersing in paddy SG aqueous solvent (Cartap hydrochloride aqueous solvent, manufactured by Sumitomo Chemical Co., Ltd.) in a 1500-fold aqueous diluted solution for 24 hours, and then tap water Soak for 3 days to germinate. While draining rice seeds into a rotary pan-type rice seed coating machine and rotating, an appropriate amount of Zojirushinol laundry paste (polyvinyl alcohol, Sanwa Yushi Kogyo Co., Ltd.) and molybdenum trioxide (Japan Inorganic Chemical Industry Co., Ltd.) 200 g; 100 g of 2 times water-diluted solution of any of the flowable preparations prepared in Preparation Examples 4 and 5 is added to treat the surface of rice seeds. Thereafter, the rice seeds are taken out from the coating machine, dispersed on a vinyl sheet so as to have a thickness of 1 cm or less, and then allowed to stand and dried to obtain each treated seed.

  Hereinafter, the effects of the present invention will be shown by test examples.

Test example 1
Treated corn seeds obtained by the method described in Application Example 3 are sown at 15 cm intervals to a depth of 5 cm using a seeder.
As a result, the corn treated with the present compounds 1 to 6 or MX can be confirmed to have an effect on harmful arthropods that injure the seedling blight fungi (Rhizotonia solani and Pythium spp.), Negusa nematode, and corn.

Test example 2
Treated soybean seeds obtained by the method described in Application Example 7 are sown and cultivated.
As a result, soybean treated with the present compounds 1 to 6 or MX has been confirmed to have an effect on Fusarium oxysporum, Rhizoctonia root rot, soybean cyst nematode, and harmful arthropods that harm soybean. it can.

Test example 3
Treated seeds of oilseed rape obtained by the method described in Application Example 10 are sown and cultivated.
As a result, soybeans treated with the present compounds 1 to 6 or MX can be confirmed to have an effect on harmful arthropods that harm Rhizotonia solani, Negusare nematode, and Brassica napus.

Test example 4
Rice seed pods obtained in Application Example 14 or 15 are sown in rice fields and cultivated.
As a result, rice treated with the present compounds 1 to 6 or MX can confirm the effects on rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper, corn borer, Futabikogaga, Nikameiga, and locust. Furthermore, the rice treated with the present compounds 1 to 6 or MX controls rice planthoppers and leafhoppers, thereby causing rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, The effects on rice stripe leaf blight, black stripe atrophy, rice southern black stripe atrophy, yellowing atrophy, rice yellow leaf disease, transition yellowing disease and rice atrophy disease can be confirmed.

Test Example 5
24 kg of rice seeds are packed in a cloth bag and immersed in water for 24 hours together with the bag. The soaked rice seeds are placed on the concrete ground together with the above bags and allowed to stand for 36 hours with appropriate watering so as not to dry. Rice seeds taken out from the cloth bag after standing still are spread on a sheet, and a water-diluted solution of the formulation obtained in Formulation Example 3 or Formulation Example 6 is sprayed here, and the mixture is thoroughly stirred on the sheet. After plowing, watering, shaving, etc. in advance, the rice seeds are sown by evenly spreading the rice seeds by hand evenly in a paddy field where the flooding depth is maintained at about 2 cm. Cultivate.
As a result, the rice treated with the present compounds 1 to 6 or MX can be confirmed to have effects on rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, white-bellied moth, Futabikogaiga, Nikamaiga and Itten-Ogaiga. The effect can also be confirmed against rice weevil, rice weevil, white planthopper, white-tailed planthopper, white-bellied planthopper, leafhopper, corn borer, butterfly moth, winged moth and itten potato, which have reduced sensitivity to one or more compounds selected from group a1 to group a18. In particular, the effect can be confirmed against rice weevil, rice rot beetle, rice planthopper, white-tailed planthopper, tiger leafhopper, and leafhopper with reduced sensitivity to one or more compounds selected from group d. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease, rice atrophy disease.

Test Example 6
After pruning, rice seeds obtained in any one of Application Examples 14 to 16 are sown in a dotted or streak-like manner in a paddy sowing machine in a paddy field that has been managed to fall for several days. At this time, the seeding amount per 10 ares is 4 kg in dry rice.
As a result, rice treated with the present compounds 1 to 6 or MX can be confirmed to have an effect on rice weevil, rice beetle, brown planthopper, white-spotted planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, leafhopper leafhopper, and leafhopper. Furthermore, the effect with respect to the one or more compounds selected from the group a1 to the group a18 can be confirmed for rice weevil, rice beetle, brown planthopper, white-spotted planthopper, brown-bellied planthopper, leafhopper leafhopper, leafhopper leafhopper, leafhopper leafhopper, leafhopper leafhopper, and leafhopper. In particular, the effect on the rice weevil, rice rot beetle, rice planthopper, white-tailed planthopper, tiger leafhopper, and leafhopper of the rice weevil, rice plant beetle, sensitivity to one or more compounds selected from group a4 can be confirmed.

Test Example 7
The corn seed obtained in Application Example 3 is sown at 15 cm intervals to a depth of 5 cm using a seeder and cultivated.
As a result, the corn treated with the present compounds 1 to 6 or MX has been confirmed to have an effect on larvae (generally referred to as wire worms) of the beetles belonging to the genus Diabrotica such as Western corn rootworm and the genus Agriotes and Melanotus. it can. The effect can also be confirmed against the larvae of the above-mentioned beetles that have decreased sensitivity to one or more compounds selected from group a1 to group a18.

Test Example 8
Soybean seeds obtained in Application Example 7 are sown and cultivated.
As a result, soybeans treated with the present compounds 1 to 6 or MX can be confirmed to be effective against the fly larvae. The effect can also be confirmed against the fly larvae having reduced sensitivity to one or more compounds selected from the group a1 to the group a18.

Test Example 9
The oilseed rape (Brassica napus) seed obtained in Application Example 10 is sown and cultivated.
As a result, the oilseed rape treated with the present compounds 1 to 6 or MX can confirm the effect on larvae of the beetle family. Moreover, an effect can be confirmed also to the larva of the beetle family in which the sensitivity with respect to 1 or more types of compounds chosen from the group a1-group a18 fell.

Test Example 10
Wheat seeds obtained in Application Example 12 are sown and cultivated.
As a result, the wheat treated with the present compounds 1 to 6 or MX can confirm the effect on the larvae of the beetles. The effect can also be confirmed against the larvae of the beetles that are less sensitive to one or more compounds selected from group a1 to group a18.

Test Example 11
The potato seed meal obtained in Application Example 13 is planted and cultivated in soil.
As a result, the potato treated with the present compounds 1 to 6 or MX can confirm the effect on larvae of the beetle family. Moreover, an effect can be confirmed also to the larva of the beetle family in which the sensitivity with respect to the 1 or more types of compound chosen from the group a1-group a18 fell.

Test Example 12
The granules obtained in Formulation Example 7 are mixed with soil, and sugarcane stem fragments are planted and cultivated there.
As a result, sugarcane treated with the present compounds 1 to 6 or MX can confirm the effect on the larvae of the beetles. Moreover, an effect can be confirmed also with respect to the larva of the beetle family in which the sensitivity with respect to 1 or more types of compounds chosen from the group a1-group a18 fell.

Test Example 13
The water-diluted solution of the flowable preparation obtained in Formulation Example 4 or 5 is sprayed before the covering soil and cultivated by covering the planting groove in which the sugarcane stem fragments are planted.
As a result, sugarcane treated with the present compounds 1 to 6 or MX can confirm the effect on the larvae of the beetles. Moreover, an effect can be confirmed also with respect to the larva of the beetle family in which the sensitivity with respect to 1 or more types of compounds chosen from the group a1-group a18 fell.

Test Example 14
During the seedling period immediately before transplanting from rice seeding, 50 g of the granule obtained in Formulation Example 7 is sprayed per seedling box (about 60 cm wide, about 30 cm long), covered with soil, and grown. The seed pods used are seed sterilized with a mixture of ipconazole and cupric hydroxide before sowing. Rice seedlings grown at the 2.5 leaf stage are transplanted and cultivated in paddy fields using a rice planting machine.
As a result, the rice treated with the present compounds 1 to 6 or MX can confirm the effects of rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, rice-bellied leafhopper, leafhopper leafworm, leafhopper, rice-nettle beetle and rice leafworm effect. In addition, against rice weevil, rice beetle, brown planthopper, white-throated planthopper, brown-bill beetle, leafhopper leafhopper, leafhopper leafhopper, rice-butterfly, rice-bellied moth, rice-bitter beetle, rice-bellied beetle and rice-butterfly The effect can be confirmed. In particular, the effect can be confirmed against rice weevil, rice squirrel, rice planthopper, white-tailed planthopper, rice planthopper, and leafhopper with reduced sensitivity to one or more compounds selected from group a4. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease, rice atrophy disease.

Test Example 15
During the seedling period immediately before transplanting from rice sowing, a solution obtained by diluting the flowable preparation obtained in Formulation Example 4 is irrigated to the rice seedlings grown at the 3.5 leaf stage using an irrigation apparatus. The rice seedlings are transplanted and cultivated in paddy fields using a rice planting machine.
As a result, the rice treated with the present compounds 1 to 6 or MX can confirm the effects of rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, rice-bellied leafhopper, leafhopper leafworm, leafhopper, rice-nettle beetle and rice leafworm effect. In addition, against rice weevil, rice beetle, brown planthopper, white-throated planthopper, brown-bill beetle, leafhopper leafhopper, leafhopper leafhopper, rice-butterfly, rice-bellied moth, rice-bitter beetle, rice-bellied beetle and rice-butterfly The effect can be confirmed. In particular, the effect can be confirmed against rice weevil, rice squirrel, rice planthopper, white-tailed planthopper, rice planthopper, and leafhopper with reduced sensitivity to one or more compounds selected from group a4. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease, rice atrophy disease.

Test Example 16
During the seedling period immediately before transplanting from rice seeding, 500 ml of a solution obtained by diluting the flowable preparation obtained in Formulation Example 5 is irrigated in a seedling box (about 60 cm wide, about 30 cm long). The rice seedlings are transplanted and cultivated in paddy fields using a rice planting machine.
As a result, the rice treated with the present compounds 1 to 6 or MX can confirm the effects of rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, rice-bellied leafhopper, leafhopper leafworm, leafhopper, rice-nettle beetle and rice leafworm effect. In addition, against rice weevil, rice beetle, brown planthopper, white-throated planthopper, brown-bill beetle, leafhopper leafhopper, leafhopper leafhopper, rice-butterfly, rice-bellied moth, rice-bitter beetle, rice-bellied beetle and rice-butterfly The effect can be confirmed. In particular, the effect can be confirmed against rice weevil, rice squirrel, rice planthopper, white-tailed planthopper, rice planthopper, and leafhopper with reduced sensitivity to one or more compounds selected from group a4. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease, rice atrophy disease.

Test Example 17
The present compounds 1 to 6 or MX are prepared according to the method described in Preparation Example 4. Similarly, triflumezopyrim, flupiradifurone or flupyrimine is prepared according to the method described in Preparation Example 4. Spreading agent (trade name: Cyndyne (registered trademark)) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume to obtain each dilution. Commercially available Admeier wettable powder (active ingredient: imidacloprid, manufactured by Bayer CropScience Co., Ltd.) and Actara granule wettable powder (active ingredient: thiamethoxam, manufactured by Syngenta Japan Co., Ltd.) with an active ingredient concentration of 0.05 ppm, Diluted with water containing 0.05% by volume of a spreading agent (trade name: Cyndyne (registered trademark)) to 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, Obtain a diluted solution. Cucumber seedlings planted in containers (second true leaf development stage) are susceptible lines (lines that have been bred in succession within the Institute for Health and Agriculture of Sumitomo Chemical Co., Ltd.) and reduced sensitivity lines (in Miyazaki Prefecture in 2016) After collection, inoculate 30 cotton aphids (including all growth stages) of a line that has been reared indefinitely. After 1 day, the diluted solution is sprayed on the seedlings at a rate of 10 mL / seedling. On the other hand, cucumbers are cultivated in the same manner as in the treated section except that the diluted solution containing the compound is not sprayed (this is referred to as “untreated section”). Six days after spraying, the number of live insects is observed, and the control value is determined by the formula 1).
Formula 1); control value (%) = {1− (Cb × Tai) / (Cai × Tb)} × 100
The characters in the formula have the following meanings.
Cb: number of test insects in the untreated group Cai: number of live insects at the time of investigation in the untreated group Tb: number of test insects in the treated group Tai: number of live insects at the time of survey in the treated group As a result, the nicotine of the group a4 It is confirmed that the treatment groups of triflumezopyrim, flupiradifuron, flupirimine, imidacloprid and thiamethoxam, which are competitive modulators of the sex acetylcholine receptor, are all less effective against the susceptible strain. This confirms that the sensitivity-reduced strain used in this study is a strain with reduced sensitivity to the nicotinic acetylcholine receptor competitive modulator. On the other hand, the treatment group of this compound 1-6 or MX can confirm the effect equivalent to it with respect to a sensitivity system | strain also with respect to a sensitivity reduction system | strain.

Test Example 18
The present compounds 1 to 6 or MX are prepared according to the method described in Preparation Example 4. Similarly, flupiradiflon and flupyrimine are each prepared according to the method described in Preparation Example 4. Spreading agent (trade name: Cyndyne (registered trademark)) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume. Commercially available Admeier wettable powder (active ingredient: imidacloprid, manufactured by Bayer CropScience Co., Ltd.), active ingredient concentration of 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and Dilute with water containing 0.05% by volume of a spreading agent (trade name: Cyndine (registered trademark)) to 200 ppm. The dilute solution is sprayed at a rate of 10 mL / seedling on rice (Oryza sativa) seedlings (2.5th leaf stage) planted in a container. Subsequently, susceptible planthopper (Sumitomo Chemical Co., Ltd. health farming and related business research line), and reduced sensitivity line planter (collected in Nagasaki Prefecture in 2016, then breeding indefinitely 20 strains of 3rd instar larvae are released. After 6 days, the number of surviving insects is examined, and the death rate is obtained by the formula 2). On the other hand, rice is cultivated in the same manner as in the treated area except that the diluted solution containing the compound is not sprayed (this is referred to as an untreated area).
Formula 2) Death rate (%) = {1−number of surviving insects / 20} × 100
As a result, it is confirmed that the treatment group of flupiradifuron, flupyrimine, and imidacloprid, which are the nicotinic acetylcholine receptor competitive modulators of the group a4, all have a lower effect on the sensitivity-reduced strain than the effect on the sensitive strain. This confirms that the sensitivity-reduced strain used in this study is a strain with reduced sensitivity to the nicotinic acetylcholine receptor competitive modulator. On the other hand, the treatment group of this compound 1-6 or MX can confirm the effect equivalent to it with respect to a sensitivity system | strain also with respect to a sensitivity reduction system | strain.

Test Example 19
The present compounds 1 to 6 or MX are prepared according to the method described in Preparation Example 4. Spreading agent (trade name: Cyndyne (registered trademark)) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume. Commercially available phoenix granule wettable powder (active ingredient: fulvendiamide, manufactured by Nippon Agricultural Chemicals Co., Ltd.), Prevason Flowable 5 (active ingredient: chlorantraniliprole, manufactured by Nissan Chemical Co., Ltd.) and Venevia OD (active ingredient: Cyantraniprolol (manufactured by Kumiai Chemical Industry Co., Ltd.) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume of the trade name: Cyndyne (registered trademark). The diluted solution is sprayed on a cabbage (Brassicae oleracea) seedling (third to fourth true leaf development stage) planted in a container at a rate of 20 mL / seedling. Later, the sensitive strain Koaga (Sumitomo Chemical Co., Ltd. Health Agriculture and Related Business Research Institute) and the sensitivity-reduced strain Koaga (collected in Kumamoto Prefecture in 2016 and then raised indefinitely 10 strains of 3rd instar larvae are released. After 5 days, the number of surviving insects is counted, and the mortality rate is obtained from Equation 3). On the other hand, cabbage is cultivated in the same manner as in the treated area except that the dilute solution containing the compound is not sprayed (this is defined as an untreated area).
Formula 3) Death rate% = (1−Number of surviving insects / 10) × 100
As a result, the treatment group of flubendiamide, chlorantraniliprole, and cyantraniliprolol, which are the ryanodine receptor modulators of the group a17, are all less effective against the sensitive line than the sensitive line. It is confirmed. From this, it is confirmed that the sensitivity-reduced strain used in this test is a strain with reduced sensitivity to the ryanodine receptor modulator. On the other hand, the treatment group of this compound 1-6 or MX can confirm the effect equivalent to it with respect to a sensitivity system | strain also with respect to a sensitivity reduction system | strain.

Test Example 20
The present compounds 1 to 6 or MX are prepared according to the method described in Preparation Example 4. Similarly, flupiradiflon and flupyrimine are each prepared according to the method described in Preparation Example 4. Spreading agent (trade name: Cyndyne (registered trademark)) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume. Commercially available Admeier granule wettable powder (active ingredient: imidacloprid, manufactured by Bayer CropScience), Trebon emulsion (active ingredient: etofenprox, manufactured by Mitsui Chemicals Agro Co., Ltd.), Prince flowable (active ingredient: fipronil, BASF Japan Co., Ltd.), Kirup Floable (active ingredient: Ethiprole, Bayer CropScience Co., Ltd.), and Uploadable (active ingredient: buprofezin, manufactured by Nippon Agricultural Chemicals Co., Ltd.) have an active ingredient concentration of 0.05 ppm and 0, respectively. It is diluted with water containing 0.05% by volume of a spreading agent (trade name: Cyndyne (registered trademark)) so as to be 2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm. The dilute solution is sprayed at a rate of 10 mL / seedling on rice (Oryza sativa) seedlings (2.5th leaf stage) planted in a container. Later, the susceptible strain Hime Tuna (Sumitomo Chemical Co., Ltd., Health Farming and Related Business Research Institute), and the reduced sensitivity strain Hime Tuna (collected in Nagasaki Prefecture in 2016, and then reared indefinitely) 20 strains of 3rd instar larvae are released. After 6 days, the number of surviving insects is examined, and the death rate is obtained by the formula 2). On the other hand, rice is cultivated in the same manner as in the treated area except that the diluted solution containing the compound is not sprayed (this is referred to as an untreated area).
Formula 2) Death rate (%) = {1−number of surviving insects / 20} × 100
As a result, flupirazifuron, flupyrimine and imidacloprid which are competitive modulators of the nicotinic acetylcholine receptor of the group a4, fipronil and etiprole which are GABAergic chloride channel blockers of the group a2, and etholine which is a sodium channel modulator of the group a3 It is confirmed that the treatment group of fenprox and buprofezin, which is the chitin biosynthesis inhibitor of the group a12, has a lower effect on the sensitivity-reduced line than the effect on the sensitive line. From this, it is confirmed that the sensitivity-reducing line used in this test is a line with reduced sensitivity to these compounds. On the other hand, the treatment group of this compound 1-6 or MX can confirm the effect equivalent to it with respect to a sensitivity system | strain also with respect to a sensitivity reduction system | strain.

Test Example 21
The present compounds 1 to 6 or MX are prepared according to the method described in Preparation Example 4. Spreading agent (trade name: Cyndyne (registered trademark)) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume. The commercially available Prince Flowable (active ingredient: fipronil, manufactured by BASF Japan Co., Ltd.) and Killup Flowable (active ingredient: Ethiprole, manufactured by Bayer Crop Science Co., Ltd.) have active ingredient concentrations of 0.05 ppm, 0.2 ppm, Dilute with water containing 0.05% by volume of a spreading agent (trade name: Cyndine®) to 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm. The diluted solution is sprayed at a rate of 10 mL / seedling on rice seedlings (2.5th leaf stage) planted in a container. Later, the susceptible line cedar (Shitomo Chemical Co., Ltd. health farming and related business research line), and the low sensitivity line cedar brown eel (collected in Nagasaki Prefecture in 2016, and then bred in succession) 20 strains of 3rd instar larvae are released. After 6 days, the number of surviving insects is examined, and the death rate is obtained by the formula 2). On the other hand, rice is cultivated in the same manner as in the treated area except that the diluted solution containing the compound is not sprayed (this is referred to as an untreated area).
Formula 2) Death rate (%) = {1−number of surviving insects / 20} × 100
As a result, it is confirmed that the treatment group of fipronil and etiprol, which are GABAergic chloride channel blockers of group a2, are less effective against the sensitivity-reduced strain than both. From this, it is confirmed that the sensitivity-reducing line used in this test is a line with reduced sensitivity to these compounds. On the other hand, the treatment group of this compound 1-6 or MX can confirm the effect equivalent to it with respect to a sensitivity system | strain also with respect to a sensitivity reduction system | strain.

Test Example 22
The present compounds 1 to 6 or MX are prepared according to the method described in Preparation Example 4.
Each of the above formulations is diluted 100 times with water. The diluted solution is irrigated with 500 ml in a cell-shaped seedling raising tray (about 60 cm wide, about 30 cm long) of cabbage one day before planting, planted in a field and cultivated.
As a result, the cabbage treated with the present compounds 1 to 6 or MX can be confirmed to have an effect on harmful insects belonging to the family Coniferaceae, Noctuidae, and Lepidoptera. The effect can also be confirmed against harmful insects belonging to the family Convolvulaceae, Noctuidae, and Lepidoptera, which have reduced sensitivities to one or more compounds selected from Group a1 to Group a18. In particular, the effect can be confirmed against the diamondback moth having reduced sensitivity to one or more compounds selected from the group a17.

Test Example 23
The present compounds 1 to 6 or MX are prepared according to the method described in Preparation Example 7. After carrying out the pricking, the above formulation was applied at a rate of 1 kg / 10a at a rate of 1 kg / 10a while sowing several rice seeds coated with iron oxide powder in a paddy seeder in a paddy field that was managed to fall for several days. Apply to a position of 1 cm depth. Then, rice is cultivated.
As a result, the rice treated with the present compounds 1 to 6 or MX can confirm the effects on rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, white-bellied leafhopper, leafhopper leafhopper, leafhopper leafworm, leafhopper, rice-nettle beetle. The effects of rice weevil, rice beetle, brown planthopper, white-tailed planthopper, brown-bill plant, leafhopper leafhopper, leafhopper leafhopper, leaf-butterfly, leaf-bucky beetle, rice-bitter beetle, rice-brush beetle and rice-butterfly I can confirm. In particular, the effect can be confirmed also for rice weevil, rice beetle, rice planthopper, white-tailed planthopper, rice planthopper, and leafhopper with reduced sensitivity to one or more compounds selected from group a4. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease and rice dwarf disease.

Test Example 24
The present compounds 1 to 6 or MX are prepared according to the method described in Preparation Example 7. After pruning, several rice seeds coated with Calper (registered trademark) granule 16 (calcium peroxide granule, Hodogaya UPL Co., Ltd.) were placed on a paddy field that had been managed for several days. While sowing the grains, the above-mentioned preparation is applied at a rate of 1 kg / 10a to a position 3 cm to the side of the sowing position and a depth of 3 cm. Then, rice is cultivated.
As a result, the rice treated with the present compounds 1 to 6 or MX can confirm the effects on rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, white-bellied leafhopper, leafhopper leafhopper, leafhopper leafworm, leafhopper, rice-nettle beetle. The effects of rice weevil, rice beetle, brown planthopper, white-tailed planthopper, brown-bill plant, leafhopper leafhopper, leafhopper leafhopper, leaf-butterfly, leaf-bucky beetle, rice-bitter beetle, rice-brush beetle and rice-butterfly I can confirm. In particular, the effect can be confirmed also for rice weevil, rice beetle, rice planthopper, white-tailed planthopper, rice planthopper, and leafhopper with reduced sensitivity to one or more compounds selected from group a4. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease and rice dwarf disease.

  According to the present invention, harmful arthropods can be controlled.

Claims (3)

Formula (I):
[Where:
Q represents a group represented by the following formula Q1, a group represented by the following formula Q2, a group represented by the following formula Q3, or a group represented by the following formula Q4.
(Where
n represents 0, 1 or 2;
R ² represents a cyclopropyl group, a cyclopropylmethyl group, or a C1-C6 alkyl group optionally having one or more halogen atoms,
Z ¹ represents a nitrogen atom or CR ^3c ,
Z ² represents a nitrogen atom or CR ^3d ,
Z ³ represents a nitrogen atom or CR ^3e ,
Z ⁴ represents NR ³⁴ , CR ³⁶ R ³⁷ or C (O),
Z ⁵ represents NR ³⁵ , CR ³⁸ R ³⁹ or C (O),
R ^3a , R ^3b , R ^3c , R ^3d and R ^3e are each independently a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from group B, from group E C3-C7 cycloalkyl group optionally having one or more substituents selected, phenyl group optionally having one or more substituents selected from group H, one or more substitutions selected from group H 5- or 6-membered aromatic heterocyclic group optionally having a group, OR ¹² , NR ¹¹ R ¹² , NR ^11a R ^12a , NR ²⁹ NR ¹¹ R ¹² , NR ²⁹ OR ¹¹ , NR ¹¹ C (O) R ¹³ , NR ²⁹ NR ¹¹ C (O) R ¹³ , NR ¹¹ C (O) OR ¹⁴ , NR ²⁹ NR ¹¹ C (O) OR ¹⁴ , NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , NR ²⁹ NR ¹¹ C ( ^{O) NR 15 R 16, N} = CHNR 15 R 16, N = S (O) x R 15 R 16, C (O) OR 17, cyano group, nitro group, halogen Represents an atom or a hydrogen atom,
x represents 0 or 1;
R ³⁴ and R ³⁵ each independently have a C1-C6 chain hydrocarbon group which may have one or more substituents selected from group B, and one or more substituents selected from group C. An optionally substituted phenyl group, a 5- or 6-membered aromatic heterocyclic group optionally having one or more substituents selected from group C, and one or more substituents selected from group C; And represents a C3-C7 alicyclic hydrocarbon group, C (O) OR ^d , C (O) R ^d , C (O) NR ^e R ^f , S (O) ₂ R ⁱ , or a hydrogen atom,
R ³⁶ , R ³⁷ , R ³⁸ and R ³⁹ are each independently a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from group B, 1 selected from group C A phenyl group optionally having the above substituents, a C3-C7 alicyclic hydrocarbon group optionally having one or more substituents selected from group C, or a hydrogen atom;
R ^d represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a hydrogen atom,
R ^e and R ^f are each independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, and a C3-C7 alicyclic ring optionally having one or more halogen atoms. Represents a hydrocarbon group, or a hydrogen atom,
R ⁱ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms),
A ² represents a nitrogen atom or CR ^4a ,
A ³ represents a nitrogen atom or CR ^4b ,
A ⁴ represents a nitrogen atom or CR ^4c ,
R ^4a , R ^4b , and R ^4c are each independently a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a nitro group, OR ¹⁸ , NR ¹⁸ R ¹⁹ , and a cyano group. Represents a halogen atom or a hydrogen atom,
R ¹⁸ represents a C1-C6 chain hydrocarbon group which may have one or more halogen atoms,
R ¹⁹ represents a C1-C6 chain hydrocarbon group which may have one or more halogen atoms or a hydrogen atom,
T is a C1-C10 chain hydrocarbon group having one or more halogen atoms, (C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms, and (C1-C5 alkyl) having one or more halogen atoms. (Sulfanyl) C2-C5 alkyl group, (C1-C5 alkylsulfinyl) C2-C5 alkyl group having one or more halogen atoms, (C1-C5 alkylsulfonyl) C2-C5 alkyl group having one or more halogen atoms, group G 1 or more having a substituent (C3-C7 cycloalkyl) C1-C3 alkyl group, C3-C7 cycloalkyl group having one or more substituents selected from the group G to be more ^{selected, oR 1, S (O)} m _{^{R 1, OS (O) 2}} R 1, CH 2 OR 1, NR 1 R 24, C (O) R 1, C (O) NR 1 R 24, NR 24 C (O) R 1, N CR ¹ R ^30, a group represented by the following formula T-1, a group represented by the formula T-2, a group represented by the following formula T-3, a group represented by the following formula T-4, under Group represented by formula T-5, group represented by formula T-6 below, group represented by formula T-7 below, group represented by formula T-8 below, table represented by formula T-9 below A group represented by the following formula T-10, a group represented by the following formula T-11, or a group represented by the following formula T-12,
X ¹ represents a nitrogen atom or CR ^1a ,
X ² represents a nitrogen atom or CR ^1b ,
X ³ represents a nitrogen atom or CR ^1c ,
X ⁴ represents a nitrogen atom or CR ^1d ,
X ⁵ represents a nitrogen atom or CR ^1e ,
R ^1a , R ^1b , R ^1c , R ^1d , and R ^1e each independently have a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, and having one or more halogen atoms. An optionally substituted C3-C6 cycloalkyl group, a halogen atom, or a hydrogen atom;
Y ¹ represents NR ²⁵ , an oxygen atom or a sulfur atom,
Y ² represents a nitrogen atom or CR ²⁶ ,
Y ³ represents a nitrogen atom or CR ²⁷ ,
Y ⁴ represents a nitrogen atom or CR ²⁸ ;
R ²⁵ is a C1-C6 chain hydrocarbon group which may have one or more halogen atoms, a C1-C6 alkoxy group which may have one or more halogen atoms, and one or more halogen atoms. A C3-C7 cycloalkyl group optionally having one or more halogen atoms (C3-C7 cycloalkyl) a C1-C6 alkyl group, or a hydrogen atom,
R ²⁶ , R ²⁷ , and R ²⁸ are each independently a C1-C6 chain hydrocarbon group that may have one or more halogen atoms, and C3 that may have one or more halogen atoms. -C6 represents a cycloalkyl group, a halogen atom, or a hydrogen atom,
R ^1x is OR ⁷ , OS (O) ₂ R ⁷ , S (O) _m R ⁷ , NR ⁸ S (O) ₂ R ⁷ , a C1-C5 chain hydrocarbon group having one or more halogen atoms, cyano Represents a group, or a halogen atom,
R ^1y is OR ⁷ , OS (O) ₂ R ⁷ , S (O) _m R ⁷ , NR ⁸ S (O) ₂ R ⁷ , cyano group, C1-C5 chain hydrocarbon having one or more halogen atoms Represents a group, or a halogen atom,
R ^1ay and R ⁷ each independently represents a C1-C6 chain hydrocarbon group having one or more halogen atoms,
R ⁸ represents a C1-C6 chain hydrocarbon group which may have one or more halogen atoms, or a hydrogen atom,
m represents 0, 1, or 2;
R ¹ is a C1-C10 chain hydrocarbon group having one or more halogen atoms, (C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms, and one or more halogen atoms (C1-C5 Alkylsulfanyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfinyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfonyl) C2-C5 alkyl group, group A (C3-C7 cycloalkyl) C1-C3 alkyl group having one or more substituents selected from G, or a C3-C7 cycloalkyl group having one or more substituents selected from Group G;
R ¹¹ , R ¹⁷ , R ²⁴ , and R ²⁹ each independently represent a C1-C6 chain hydrocarbon group that may have one or more halogen atoms, or a hydrogen atom,
R ³⁰ represents a C1-C6 chain hydrocarbon group which may have one or more halogen atoms or a hydrogen atom,
R ¹² represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkyl group having one substituent selected from Group F, and one or more selected from Group H A phenyl group which may have a substituent, a 5- or 6-membered aromatic heterocyclic group which may have one or more substituents selected from group H, S (O) ₂ R ²³ , or a hydrogen atom; Represents
R ²³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a phenyl group optionally having one or more substituents selected from Group D;
R ^11a and R ^12a together with the nitrogen atom to which they are attached form a 3-7 membered non-aromatic heterocyclic group optionally having one or more substituents selected from group E;
R ¹³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, and one or more halogen atoms. (C3-C6 cycloalkyl) which may have C1-C3 alkyl group, phenyl group which may have one or more substituents selected from group D, one or more substituents selected from group D Represents a 5- or 6-membered aromatic heterocyclic group which may have a hydrogen atom, or
R ¹⁴ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, and one or more halogen atoms. (C3-C6 cycloalkyl) which may have (C3-C6 cycloalkyl) C1-C3 alkyl group, or phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group has one or more substituents selected from group D You may have. },
R ¹⁵ and R ¹⁶ each independently represent a C1-C6 alkyl group optionally having one or more halogen atoms.
Group B: C1-C6 alkoxy group optionally having one or more halogen atoms, C3-C6 alkenyloxy group optionally having one or more halogen atoms, having one or more halogen atoms A C3-C6 alkynyloxy group, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, one or more A group consisting of a C1-C6 alkylsulfonyl group optionally having a halogen atom, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom.
Group C: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, having one or more halogen atoms A group consisting of a C3-C6 alkenyloxy group which may have one, a C3-C6 alkynyloxy group which may have one or more halogen atoms, and a halogen atom.
Group D: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, hydroxy group, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogen atoms A C3-C6 alkenyloxy group that may have one or more, a C3-C6 alkynyloxy group that may have one or more halogen atoms, a sulfanyl group, or a C1-C6 that may have one or more halogen atoms. C6 alkylsulfanyl group, C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, amino group, NHR ²¹ , NR ^{21 R 22, C (O)} R 21, OC (O) R 21, C (O) oR 21, cyano group, the group {R ²¹ and R ²² consisting of nitro group, and halogen atoms are each independently Te represents one or more halogen atoms which may have a C1-C6 alkyl group}.
Group E: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, having one or more halogen atoms A group consisting of a C3-C6 alkenyloxy group which may have one or more, a C3-C6 alkynyloxy group which may have one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group.
Group F: C1-C6 alkoxy group optionally having one or more halogen atoms, phenyl group optionally having one or more substituents selected from Group D, one or more substitutions selected from Group D A 5- or 6-membered aromatic heterocyclic group which may have a group, a C3-C7 cycloalkyl group which may have one or more halogen atoms, and one or more substituents selected from group C A group consisting of a 3-7 membered non-aromatic heterocyclic group, an amino group, NHR ²¹ , NR ²¹ R ²² , and a cyano group, which may be
Group G: A group consisting of a C1-C6 alkyl group having at least one halogen atom and a halogen atom.
Group H: 1 or more halogen atoms optionally may C1-C6 alkyl group optionally ^{having, OR 10, NR 9 R 10} , C (O) R 10, C (O) NR 9 R 10, OC (O) R ⁹ , OC (O) OR ⁹ , NR ¹⁰ C (O) R ⁹ , NR ¹⁰ C (O) OR ⁹ , C (O) OR ¹⁰ , halogen atom, nitro group, cyano group, amino group, and 5 or 6 Group consisting of a membered aromatic heterocyclic group {R ⁹ is a C1-C6 alkyl group optionally having one or more halogen atoms or a C3-C6 cycloalkyl group optionally having one or more halogen atoms R ¹⁰ represents a C1-C6 alkyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, or a hydrogen atom} . ]
And a group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i) And one or more components selected from the group consisting of group (j):
Group (a): a group consisting of an insecticidal active ingredient, an acaricidal active ingredient and a nematicidal active ingredient;
Group (b): bactericidal active ingredient;
Group (c): plant growth regulating component;
Group (d): phytotoxicity reducing component;
Group (e): synergist;
Group (f): repellent ingredients;
Group (g): molluscicidal components;
Group (h): insect pheromone;
Group (i): herbicidal active ingredient;
Group (j): Microbial material.   A method for controlling harmful arthropods, which comprises applying an effective amount of the composition according to claim 1 to harmful arthropods, habitats, plants or soil of harmful arthropods.   A seed or vegetative organ holding an effective amount of the composition of claim 1.