JP2018188462A - Composition containing heterocyclic compound - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a composition having excellent control effect on harmful arthropods.SOLUTION: The present invention relates to a composition containing a compound represented by formula (I) [where Ais a nitrogen atom or the like, n is 0 or the like, q is 0 or the like, G is a C3-C8 alicyclic hydrocarbon group that may have at least one substituent selected from a specific group, or the like, Ris a C1-C6 chain hydrocarbon group that may have at least one substituent selected from a specific group, or the like, Ais a nitrogen atom or the like, Ais a nitrogen atom or the like, Ais a nitrogen atom or the like, T is a C1-C10 chain hydrocarbon group having one or more halogen atoms, or the like, and Ris a cyclopropyl group or the like].SELECTED DRAWING: None

Description

  The present invention relates to a heterocyclic compound and a harmful arthropod control composition thereof.

So far, various compounds have been studied and put into practical use for the purpose of controlling harmful arthropods.
Moreover, it is known that a certain compound has a pest control effect (for example, refer patent document 1 and patent document 2).

International Publication No. 2016/052455 International Publication No. 2016/121969

  An object of the present invention is to provide a composition having an excellent control effect against harmful arthropods.

As a result of studying to find a composition having an excellent control effect against harmful arthropods, the present inventor has found that a compound represented by the following formula (I), a group (a), a group (b), a group ( c), group (d), group (e), group (f), group (g), group (h), one or more components selected from the group consisting of group (i) and group (j) It has been found that the composition has excellent control efficacy against harmful arthropods.
That is, the present invention is as follows.
[1] Formula (I):
[Where:
A ¹ represents a nitrogen atom or CR ^3b ,
n represents 0, 1 or 2;
q represents 0, 1, or 2;
G represents one or more substituents may be a C3-C8 alicyclic hydrocarbon group selected from the group E, or -L ¹ -G ^2,
L ¹ represents an oxygen atom or a sulfur atom,
G ² represents a 5- to 10-membered heterocyclic group which may have one or more substituents selected from group D;
R ^3a each independently has a C1-C6 chain hydrocarbon group which may have one or more substituents selected from group B, and one or more substituents selected from group E. A C3-C7 cycloalkyl group, a phenyl group optionally having one or more substituents selected from group H, a 5- or 6-membered optionally having one or more substituents selected from group H Aromatic heterocyclic group, OR ¹² , NR ¹¹ R ¹² , NR ^11a R ^12a , NR ²⁴ NR ¹¹ R ¹² , NR ²⁴ OR ¹¹ , NR ¹¹ C (O) R ¹³ , NR ²⁴ NR ¹¹ C (O) R ¹³ , NR ¹¹ C (O) OR ¹⁴ , NR ²⁴ NR ¹¹ C (O) OR ¹⁴ , NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , NR ²⁴ NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , N = CHNR ¹⁵ R ¹⁶ , N = S (O) _x R ¹⁵ R ¹⁶ , C (O) OR ¹⁷ , a cyano group, a nitro group, or a halogen atom,
R ^3b may have one or more substituents selected from group B and may have one or more substituents selected from group E; C3-C7 A cycloalkyl group, a phenyl group optionally having one or more substituents selected from group H, a 5- or 6-membered aromatic heterocyclic group optionally having one or more substituents selected from group H , OR ¹² , NR ¹¹ R ¹² , NR ^11a R ^12a , NR ²⁴ NR ¹¹ R ¹² , NR ²⁴ OR ¹¹ , NR ¹¹ C (O) R ¹³ , NR ²⁴ NR ¹¹ C (O) R ¹³ , NR ¹¹ C ( O) OR ¹⁴ , NR ²⁴ NR ¹¹ C (O) OR ¹⁴ , NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , NR ²⁴ NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , N = CHNR ¹⁵ R ¹⁶ , N = S (O) _x R ¹⁵ R ¹⁶ , C (O) OR ¹⁷ , a cyano group, a nitro group, a hydrogen atom or a halogen atom,
x represents 0 or 1;
A ² represents a nitrogen atom or CR ^4a ,
A ³ represents a nitrogen atom or CR ^4b ,
A ⁴ represents a nitrogen atom or CR ^4c ,
R ^4a , R ^4b and R ^4c are each independently a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a nitro group, OR ¹⁸ , NR ¹⁸ R ^19. Represents a cyano group or a halogen atom,
T is a C1-C10 chain hydrocarbon group having one or more halogen atoms, (C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms, and (C1-C5 alkyl) having one or more halogen atoms. (Sulfanyl) C2-C5 alkyl group, (C1-C5 alkylsulfinyl) C2-C5 alkyl group having one or more halogen atoms, (C1-C5 alkylsulfonyl) C2-C5 alkyl group having one or more halogen atoms, group G 1 or more having a substituent (C3-C7 cycloalkyl) C1-C3 alkyl group, C3-C7 cycloalkyl group having one or more substituents selected from the group G to be more ^{selected, oR 1, S (O)} m _{^{R 1, OS (O) 2}} R 1, CH 2 OR 1, NR 1 R 29, C (O) R 1, C (O) NR 1 R 29, NR 29 C (O) R 1, N CR ¹ R ^30, a group represented by the following formula T-1, a group represented by the formula T-2, a group represented by the following formula T-3, a group represented by the following formula T-4, the formula T-5 A group represented by the following formula T-6, a group represented by the following formula T-7, a group represented by the following formula T-8, a group represented by the following formula T-9, and the following formula T-10 Represents a group represented by the following formula T-11, or a group represented by the following formula T-12;
X ¹ represents a nitrogen atom or CR ^1a ,
X ² represents a nitrogen atom or CR ^1b ,
X ³ represents a nitrogen atom or CR ^1c ,
X ⁴ represents a nitrogen atom or CR ^1d ,
X ⁵ represents a nitrogen atom or CR ^1e ,
R ^1a , R ^1b , R ^1c , R ^1d and R ^1e are each independently a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, and one or more halogens. Represents a C3-C7 cycloalkyl group optionally having an atom, or a halogen atom;
R ^1x is OR ⁷ , OS (O) ₂ R ⁷ , S (O) _m R ⁷ , NR ¹ R ²⁹ , NR ⁸ S (O) ₂ R ⁷ , C1-C5 chain formula having one or more halogen atoms Represents a hydrocarbon group, a cyano group, or a halogen atom,
Y ¹ represents NR ²⁵ , an oxygen atom or a sulfur atom,
Y ² represents a nitrogen atom or CR ²⁶ ,
Y ³ represents a nitrogen atom or CR ²⁷ ,
Y ⁴ represents a nitrogen atom or CR ²⁸ ;
R ²⁵ is a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens. Represents a C3-C7 cycloalkyl group optionally having atoms, or a (C3-C7 cycloalkyl) C1-C6 alkyl group optionally having one or more halogen atoms,
R ²⁶ , R ²⁷ and R ²⁸ each independently have a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, and one or more halogen atoms. Represents a C3-C7 cycloalkyl group, or a halogen atom,
R ^1y is OR ⁷ , OS (O) ₂ R ⁷ , S (O) _m R ⁷ , NR ⁸ S (O) ₂ R ⁷ , cyano group, C1-C5 chain hydrocarbon having one or more halogen atoms Represents a group, or a halogen atom,
R ^1ay and R ⁷ each independently represents a C1-C6 chain hydrocarbon group having one or more halogen atoms,
R ⁸ represents a hydrogen atom or a C1-C6 chain hydrocarbon group which may have one or more halogen atoms,
m represents 0, 1, or 2;
R ¹ is a C1-C10 chain hydrocarbon group having one or more halogen atoms, (C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms, and one or more halogen atoms (C1-C5 Alkylsulfanyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfinyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfonyl) C2-C5 alkyl group, group A (C3-C7 cycloalkyl) C1-C3 alkyl group having one or more substituents selected from G, or a C3-C7 cycloalkyl group having one or more substituents selected from Group G;
R ² represents a cyclopropyl group, a cyclopropylmethyl group, or a C1-C6 alkyl group optionally having one or more halogen atoms,
R ¹¹ , R ¹⁷ , R ¹⁹ , R ²⁴ and R ²⁹ each independently represent a hydrogen atom or a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms,
R ³⁰ represents a hydrogen atom, a halogen atom, OR ³¹ , NR ³² R ³³ , or a C1-C6 chain hydrocarbon group which may have one or more halogen atoms,
R ¹⁸ and R ³¹ each independently represents a hydrogen atom or a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms,
R ³² and R ³³ each independently represent a hydrogen atom or a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms,
R ¹² is a hydrogen atom, S (O) ₂ R ²³ , a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a C1-C6 having one substituent selected from Group F. Represents a C6 alkyl group,
R ²³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a phenyl group optionally having one or more substituents selected from Group D;
R ^11a and R ^12a together with the nitrogen atom to which they are attached represent a 3-7 membered non-aromatic heterocyclic group optionally having one or more substituents selected from group E;
R ¹³ is a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, one or more A (C3-C7 cycloalkyl) C1-C3 alkyl group optionally having a halogen atom, a phenyl group optionally having one or more substituents selected from group D, or one or more selected from group D Represents a 5- or 6-membered aromatic heterocyclic group optionally having
R ¹⁴ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, and one or more halogen atoms. (C3-C7 cycloalkyl) which may have C1-C3 alkyl group, or phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group has one or more substituents selected from group D You may do it. },
R ¹⁵ and R ¹⁶ each independently represent a C1-C6 alkyl group optionally having one or more halogen atoms.
Group B: C1-C6 alkoxy group optionally having one or more halogen atoms, C3-C6 alkenyloxy group optionally having one or more halogen atoms, having one or more halogen atoms A C3-C6 alkynyloxy group, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, one or more A group consisting of a C1-C6 alkylsulfonyl group optionally having a halogen atom, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom.
Group D: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, hydroxy group, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogen atoms A C3-C6 alkenyloxy group that may have one or more, a C3-C6 alkynyloxy group that may have one or more halogen atoms, a sulfanyl group, or a C1-C6 that may have one or more halogen atoms. C6 alkylsulfanyl group, C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, amino group, NHR ²¹ , NR ^{21 R 22, C (O)} R 21, OC (O) R 21, C (O) oR 21, cyano group, the group {R ²¹ and R ²² consisting of nitro group, and halogen atoms are each independently Te represents one or more halogen atoms which may have a C1-C6 alkyl group. }.
Group E: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, having one or more halogen atoms C3-C6 alkenyloxy group which may have one, C3-C6 alkynyloxy group which may have one or more halogen atoms, amino group, NR ⁹ R ¹⁰ , C (O) R ¹⁰ , C (O) NR ⁹ R ¹⁰ , OC (O) R ⁹ , OC (O) OR ⁹ , NR ¹⁰ C (O) R ⁹ , NR ¹⁰ C (O) OR ⁹ , C (O) OR ¹⁰ , having one or more halogen atoms An optionally substituted C3-C7 cycloalkyl group, a phenyl group optionally having one or more substituents selected from group H, and optionally having one or more substituents selected from group H Or 6-membered aromatic heterocyclic group, halogen atom, oxo group, thioxo group, hydro Shi group, the group {R ⁹ consisting of a cyano group and a nitro group, is 1 or more may C1-C6 have a halogen atom an alkyl group or 1 or more halogen atoms have a C3-C7 Represents a cycloalkyl group, and R ¹⁰ represents a hydrogen atom, a C1-C6 alkyl group optionally having one or more halogen atoms, or a C3-C7 cycloalkyl group optionally having one or more halogen atoms. Represents. }.
Group F: C1-C6 alkoxy group which may have one or more halogen atoms, amino group, NHR ²¹ , NR ²¹ R ²² , cyano group, one or more substituents selected from group D A phenyl group, a 5- or 6-membered aromatic heterocyclic group optionally having one or more substituents selected from group D, and a C3-C7 cycloalkyl group optionally having one or more halogen atoms And a group consisting of a 3-7-membered non-aromatic heterocyclic group optionally having one or more substituents selected from group C {R ²¹ and R ²² are each independently one or more halogen atoms The C1-C6 alkyl group which may have is represented. }.
Group C: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, having one or more halogen atoms A group consisting of a C3-C6 alkenyloxy group which may have one, a C3-C6 alkynyloxy group which may have one or more halogen atoms, and a halogen atom.
Group G: A group consisting of a halogen atom and a C1-C6 haloalkyl group.
Group H: halogen atom, nitro group, cyano group, amino group, 5- or 6-membered aromatic heterocyclic group optionally having one or more halogen atoms, C1 optionally having one or more halogen atoms -C6 alkyl ^{group, OR 10, NR 9 R 10} , C (O) R 10, C (O) NR 9 R 10, OC (O) R 9, OC (O) OR 9, NR 10 C (O) R ⁹ , a group consisting of NR ¹⁰ C (O) OR ⁹ and C (O) OR ¹⁰ {R ⁹ represents a C1-C6 alkyl group optionally having one or more halogen atoms or one or more halogen atoms. Represents a C3-C7 cycloalkyl group which may have, and R ¹⁰ has a hydrogen atom, a C1-C6 alkyl group which may have one or more halogen atoms, or one or more halogen atoms. And may represent a C3-C7 cycloalkyl group. }. ]
(Hereinafter, the compound represented by the formula (I) is referred to as “the present compound”), a group (a), a group (b), a group (c), a group (d), a group (e), A harmful arthropod control composition comprising one or more components selected from the group consisting of group (f), group (g), group (h), group (i) and group (j):
Group (a): a group consisting of an insecticidal active ingredient, an acaricidal active ingredient and a nematicidal active ingredient;
Group (b): bactericidal active ingredient;
Group (c): plant growth regulating component;
Group (d): phytotoxicity reducing component;
Group (e): synergist;
Group (f): repellent ingredients;
Group (g): molluscicidal components;
Group (h): insect pheromone;
Group (i): herbicidal active ingredient;
Group (j): Microbial material.
[2] A method for controlling harmful arthropods, which comprises applying an effective amount of the composition according to [1] to harmful arthropods, habitats, plants or soil of harmful arthropods.
[3] A seed or vegetative organ holding an effective amount of the composition according to [1].

  According to the present invention, harmful arthropods can be controlled.

The substituent in the present invention will be described.
“Halogen atom” represents a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom.
When the substituent has two or more halogen atoms, these halogen atoms may be the same or different.
In this specification, the expression “CX-CY” means that the number of carbon atoms is X to Y. For example, the notation “C1-C6” means 1 to 6 carbon atoms.
The “chain hydrocarbon group” represents an alkyl group, an alkenyl group or an alkynyl group.
Examples of the “alkyl group” include methyl group, ethyl group, propyl group, isopropyl group, 1,1-dimethylpropyl group, 1,2-dimethylpropyl group, 1-ethylpropyl group, butyl group, sec-butyl group, Examples thereof include a tert-butyl group, a pentyl group, a hexyl group, and an octyl group.
Examples of the “alkenyl group” include a vinyl group, 1-propenyl group, 2-propenyl group, 1-methyl-1-propenyl group, 1-methyl-2-propenyl group, 1,2-dimethyl-1-propenyl group, Examples include 1-ethyl-2-propenyl group, 3-butenyl group, 4-pentenyl group, 5-hexenyl group, and 7-octenyl group.
Examples of the “alkynyl group” include ethynyl group, 1-propynyl group, 2-propynyl group, 1-methyl-2-propynyl group, 1,1-dimethyl-2-propynyl group, 1-ethyl-2-propynyl group, Examples include 2-butynyl group, 4-pentynyl group, 5-hexynyl group and 7-octynyl group.
Examples of the “C1-C6 haloalkyl group” include trifluoromethyl group, 2,2,2-trifluoroethyl group, 2-bromo-1,1,2,2-tetrafluoroethyl group, 2,2,3. , 3-tetrafluoropropyl group, 1-methyl-2,2,3,3-tetrafluoropropyl group and perfluorohexyl group.

Examples of the “C3-C8 alicyclic hydrocarbon group” include cyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, cyclooctyl group, cyclohexenyl group, cyclooctenyl group, bicyclo [2,2, 1] heptyl group and bicyclo [3,3,0] octyl group.
Examples of the “cycloalkyl group” include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a cycloheptyl group.

Examples of the “alkoxy group” include methoxy group, ethoxy group, propoxy group, butoxy group, pentoxy group and hexyloxy group.
The “C1-C6 alkoxy group optionally having one or more halogen atoms” refers to a group in which one or more hydrogen atoms of the C1-C6 alkoxy group are substituted with a halogen atom, for example, trifluoromethoxy Groups, difluoromethoxy groups, 2,2,2-trichloroethoxy, and 2,2,2-trifluoroethoxy.
The “C3-C6 alkenyloxy group optionally having one or more halogen atoms” represents a group in which one or more hydrogen atoms of the C3-C6 alkenyloxy group are substituted with halogen atoms. 1,3,3-trifluoro-1-propenyloxy group, 3,3,3-trichloro-1-propenyloxy group, and 2,3,3,3-tetrafluoro-1-propenyloxy group.
The “C3-C6 alkynyloxy group optionally having one or more halogen atoms” represents a group in which one or more hydrogen atoms of the C3-C6 alkynyloxy group is substituted with a halogen atom, for example, 3 , 3,3-trifluoro-1-propynyloxy group, and 3,3,3-trichloro-1-propynyloxy group.
An alkylsulfanyl group, an alkylsulfinyl group, and an alkylsulfonyl group represent an alkyl group having a moiety represented by S (O) z.
For example, examples of the alkylsulfanyl group in which z is 0 include a methylsulfanyl group, an ethylsulfanyl group, a propylsulfanyl group, and an isopropylsulfanyl group.
For example, examples of the alkylsulfinyl group in which z is 1 include a methylsulfinyl group, an ethylsulfinyl group, a propylsulfinyl group, and an isopropylsulfinyl group.
For example, examples of the alkylsulfonyl group in which z is 2 include a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, and an isopropylsulfonyl group.

“3-7 membered non-aromatic heterocyclic group” means an aziridine ring, azetidine ring, pyrrolidine ring, imidazoline ring, imidazolidine ring, piperidine ring, tetrahydropyrimidine ring, hexahydropyrimidine ring, piperazine ring, azepane ring, oxazolidine Ring, isoxazolidine ring, 1,3-oxazinane ring, morpholine ring, 1,4-oxazepane ring, thiazolidine ring, isothiazolidine ring, 1,3-thiazinane ring, thiomorpholine ring, or 1,4-thiazepane ring group Represents. Examples of the 3-7 membered non-aromatic heterocyclic group optionally having one or more substituents selected from group E include the groups shown below.

“(C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms” means that (C1-C5 alkoxy) and / or (C2-C5 alkyl) each independently have one or more halogen atoms. For example, 2- (trifluoromethoxy) ethyl group, 2,2-difluoro-3-methoxypropyl group, 2,2-difluoro-3- (2,2,2-trifluoroethoxy) propyl group, And 3- (2-chloroethoxy) propyl group.
“(C1-C5 alkylsulfanyl) C2-C5 alkyl group having one or more halogen atoms” means that (C1-C5 alkylsulfanyl) and / or (C2-C5 alkyl) are each independently one or more halogen atoms. For example, a 2,2-difluoro-2- (trifluoromethylthio) ethyl group may be mentioned.
"(C1-C5 alkylsulfinyl) C2-C5 alkyl group having one or more halogen atoms" means that (C1-C5 alkylsulfinyl) and / or (C2-C5 alkyl) are each independently one or more halogen atoms. For example, 2,2-difluoro-2- (trifluoromethanesulfinyl) ethyl group.
“(C1-C5 alkylsulfonyl) C2-C5 alkyl group having one or more halogen atoms” means that (C1-C5 alkylsulfonyl) and / or (C2-C5 alkyl) are each independently one or more halogen atoms. For example, a 2,2-difluoro-2- (trifluoromethanesulfonyl) ethyl group may be mentioned.
"(C3-C7 cycloalkyl) C1-C3 alkyl group optionally having one or more halogen atoms" means that (C3-C7 cycloalkyl) and / or (C1-C3 alkyl) are each independently Represents a group which may have one or more halogen atoms, for example, (2,2-difluorocyclopropyl) methyl group, 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, and 2 -(2,2-difluorocyclopropyl) -1,1,2,2-tetrafluoroethyl group is mentioned.
"(C3-C7 cycloalkyl) C1-C3 alkyl group having one or more substituents selected from group G" means that (C3-C7 cycloalkyl) and / or (C1-C3 alkyl) are each independently Represents a group having one or more substituents selected from Group G, for example, (2,2-difluorocyclopropyl) methyl group, [1- (trifluoromethyl) cyclopropyl] methyl group, [2- (trifluoro) Methyl) cyclopropyl] methyl group, 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, 2-cyclopropyl-3,3,3-trifluoropropyl group, and 1,1,2,2 -Tetrafluoro-2- [2- (trifluoromethyl) cyclopropyl] ethyl group.
Examples of the “C3-C7 cycloalkyl group having one or more substituents selected from group G” include a 2,2-difluorocyclopropyl group and a 1- (2,2,2-trifluoroethyl) cyclopropyl group. And 4- (trifluoromethyl) cyclohexyl group.
"Phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may have one or more substituents selected from group D}" means, for example, a benzyl group, 2-fluorobenzyl Group, 4-chlorobenzyl group, 4- (trifluoromethyl) benzyl group, and 2- [4- (trifluoromethyl) phenyl] ethyl group.
The “5- or 6-membered aromatic heterocyclic group” means a 5-membered aromatic heterocyclic group or a 6-membered aromatic heterocyclic group, and examples of the 5-membered aromatic heterocyclic group include a pyrrolyl group, a furyl group, It represents a thienyl group, a pyrazolyl group, an imidazolyl group, a triazolyl group, a tetrazolyl group, an oxazolyl group, an isoxazolyl group, a thiazolyl group, an isothiazolyl group, an oxadiazolyl group, or a thiadiazolyl group. As the 5-membered aromatic heterocyclic group, a 5-membered aromatic heterocyclic group having 1 to 4 nitrogen atoms, that is, pyrrolyl group, pyrazolyl group, imidazolyl group, 1,2,4-triazolyl group, 1,2,3 -A triazolyl group or a tetrazolyl group is preferable. The 6-membered aromatic heterocyclic group represents, for example, a pyridyl group, a pyridazinyl group, a pyrimidinyl group, or a pyrazinyl group.
The “5-10 membered heterocyclic group” represents an aromatic heterocyclic group or a non-aromatic cyclic group. Examples of aromatic heterocyclic groups include pyrrolyl, furyl, thienyl, pyrazolyl, imidazolyl, triazolyl, tetrazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridyl Group, pyridazinyl group, pyrimidinyl group, pyrazinyl group and quinolyl group. Examples of the non-aromatic ring group include pyrrolidinyl group, imidazolinyl group, imidazolidinyl group, piperidyl group, tetrahydropyrimidinyl group, hexahydropyrimidinyl group, piperazinyl group, azepanyl group, oxazolidinyl group, isoxazolidinyl group, 1,3 -Oxadinanyl group, morpholinyl group, 1,4-oxazepanyl group, thiazolidinyl group, isothiazolidinyl group, 1,3-thiadinanyl group, thiomorpholinyl group, and 1,4-thiazepanyl group.

  Next, the manufacturing method of this compound is demonstrated.

Manufacturing method 1
In this compound, the compound represented by formula (IA) is a compound represented by formula (M-1) (hereinafter referred to as compound (M-1)) and a compound represented by formula (R-1) (hereinafter referred to as “compound”). And compound (R-1).) In the presence of a metal catalyst.
[Wherein, G ¹ represents a C3-C8 alicyclic hydrocarbon group which may have one or more substituents selected from group E, and X ^a represents ^a chlorine atom, a bromine atom, an iodine atom, or Represents a trifluoromethanesulfonyloxy group, M represents a 9-borabicyclo [3.3.1] nonan-9-yl group, B (OH) ₂ , or BF ₃ K, and other symbols have the same meanings as described above. . ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers such as dimethoxyethane, 1,4-dioxane and tetrahydrofuran (hereinafter referred to as THF), aromatic hydrocarbons such as toluene and xylene, N, N-dimethylformamide ( Hereinafter, aprotic polar solvents such as DMF), N-methylpyrrolidone (hereinafter referred to as NMP), dimethyl sulfoxide (hereinafter referred to as DMSO), and mixtures thereof may be mentioned.
Examples of the metal catalyst used in the reaction include tetrakis (triphenylphosphine) palladium (0), [1,1′-bis (diphenylphosphino) ferrocene] palladium (II) dichloride, tris (dibenzylideneacetone) dipalladium (0 ), Palladium catalysts such as palladium (II) acetate (hereinafter referred to as palladium catalysts), and the like.
A ligand, a base, or an inorganic halide may be added to the reaction as necessary.
Examples of the ligand used in the reaction include triphenylphosphine, xanthophos, 2,2′-bis (diphenylphosphino) -1,1′-binaphthyl, 1,1′-bis (diphenylphosphino) ferrocene, 2- Phosphine ligands such as dicyclohexylphosphino-2 ′, 4 ′, 6′-triisopropylbiphenyl, 2-dicyclohexylphosphino-2 ′, 6′-dimethoxybiphenyl, 1,2-bis (diphenylphosphino) ethane (Hereinafter referred to as phosphine ligands).
Examples of the base used in the reaction include alkali metal hydrides such as sodium hydride (hereinafter referred to as alkali metal hydrides), alkali metal carbonates such as potassium carbonate (hereinafter referred to as alkali metal carbonates), And organic bases (hereinafter referred to as organic bases) such as triethylamine, diisopropylethylamine, pyridine, and 4- (dimethylamino) pyridine.
In the reaction, with respect to 1 mol of the compound (M-1), the compound (R-1) is usually in a proportion of 1 to 10 mol, the metal catalyst is usually in a proportion of 0.01 to 0.5 mol, and the ligand is Usually, the base is used in a proportion of 0.01 to 1 mol, and the base is usually used in a proportion of 0.1 to 5 mol.
The reaction temperature is usually in the range of -20 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
Compound (R-1) is a commercially available compound, or can be produced according to a known method.
After completion of the reaction, the compound can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Manufacturing method 2
In this compound, the compound represented by formula (IA) is a compound represented by formula (M-2) (hereinafter referred to as compound (M-2)) and a compound represented by formula (R-2) (hereinafter referred to as “compound”). And compound (R-2)) in the presence of a metal catalyst.
[Wherein the symbols have the same meaning as described above. ]
The compound represented by the formula (IA) is described in the production method 1, using the compound (R-2) instead of the compound (M-1) and the compound (M-2) instead of the compound (R-1). It can manufacture according to this method.
Compound (R-2) is a commercially available compound, or can be produced according to a known method.

Production method 3
In this compound, the compound represented by formula (Ib) (hereinafter referred to as compound (Ib)) and the compound represented by formula (Ic) (hereinafter referred to as compound (Ic)) are represented by formula (Ia). It can be produced by oxidizing the compound shown (hereinafter referred to as compound (Ia)).
[Wherein the symbols have the same meaning as described above. ]

First, a method for producing compound (Ib) from compound (Ia) will be described.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include halogenated hydrocarbons such as dichloromethane and chloroform (hereinafter referred to as halogenated hydrocarbons), nitriles such as acetonitrile (hereinafter referred to as nitriles), methanol, and ethanol. And the like (hereinafter referred to as alcohols), acetic acid, water, and mixtures thereof.
Examples of the oxidizing agent used in the reaction include sodium periodate, m-chloroperbenzoic acid (hereinafter referred to as mCPBA), and hydrogen peroxide. When hydrogen peroxide is used as the oxidizing agent, sodium carbonate or a catalyst may be added as necessary.
Examples of the catalyst used for the reaction include tungstic acid and sodium tungstate.
In the reaction, with respect to 1 mol of compound (Ia), the oxidizing agent is usually in a proportion of 1 to 1.2 mol, sodium carbonate is usually in a proportion of 0.01 to 1 mol, and the catalyst is usually in a proportion of 0.01 to 0.5. Used in molar proportions.
The reaction temperature is usually in the range of -20 to 80 ° C. The reaction time is usually in the range of 0.1 to 12 hours.
After completion of the reaction, water is added to the reaction mixture and extracted with an organic solvent, and the organic layer is extracted with an aqueous solution of a reducing agent (for example, sodium sulfite, sodium thiosulfate) and an aqueous solution of a base (for example, sodium bicarbonate) as necessary. Wash. Compound (Ib) can be obtained by drying and concentrating the organic layer.

Next, a method for producing compound (Ic) from compound (Ib) will be described.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include halogenated hydrocarbons, nitriles, alcohols, acetic acid, water, and mixtures thereof.
Examples of the oxidizing agent used in the reaction include mCPBA and hydrogen peroxide. When hydrogen peroxide is used as the oxidizing agent, sodium carbonate or a catalyst may be added as necessary.
Examples of the catalyst used in the reaction include sodium tungstate.
In the reaction, with respect to 1 mol of compound (Ib), the oxidizing agent is usually in a proportion of 1 to 2 mol, sodium carbonate is usually in a proportion of 0.01 to 1 mol, and the catalyst is usually in a proportion of 0.01 to 0.5 mol. Used in proportions.
The reaction temperature is usually in the range of -20 to 120 ° C. The reaction time is usually in the range of 0.1 to 12 hours.
After completion of the reaction, water is added to the reaction mixture and extracted with an organic solvent, and the organic layer is extracted with an aqueous solution of a reducing agent (for example, sodium sulfite, sodium thiosulfate) and an aqueous solution of a base (for example, sodium bicarbonate) as necessary. Wash. Compound (Ic) can be obtained by drying and concentrating the organic layer.

Compound (Ic) can be produced in a one-step reaction (one pot) by reacting compound (Ia) with an oxidizing agent.
The reaction is carried out according to the method for producing compound (Ic) from compound (Ib) using an oxidizing agent in a proportion of usually 2 to 5 mol per 1 mol of compound (Ia).

Manufacturing method 4
A compound represented by formula (Id) (hereinafter referred to as compound (Id)) can be produced according to the following scheme.
Wherein, when using methanol as a solvent, R ^v represents a methyl group, when ethanol is used as a solvent, R ^v represents an ethyl group, when using a propanol solvent, R ^v represents a propyl group, butanol when using a solvent, R ^v represents a butyl group, when using other solvents, R ^v represents a hydrogen atom. Any one of R ³⁴ , R ³⁵ , and R ³⁶ represents G, and the remainder each independently represents a hydrogen atom, a C1-C6 alkyl group optionally having one or more halogen atoms, group H Represents a phenyl group optionally having one or more substituents selected from the above, or a 5- or 6-membered aromatic heterocyclic group optionally having one or more substituents selected from group H; The symbol represents the same meaning as described above. ]

A compound represented by formula (M-3) (hereinafter referred to as compound (M-3)) and a compound represented by formula (R-3) (hereinafter referred to as compound (R-3)) are reacted. The compound represented by formula (M-24) (hereinafter referred to as compound (M-24)) and the compound represented by formula (M-25) (hereinafter referred to as compound (M-25)). ), Or the first step for producing a mixture thereof.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include aliphatic hydrocarbons such as methanol, ethanol, propanol, butanol, ethers, pentane, and hexane (hereinafter referred to as aliphatic hydrocarbons), aromatic hydrocarbons, chloroform. , Aliphatic halogenated hydrocarbons such as dichloromethane (hereinafter referred to as aliphatic halogenated hydrocarbons), esters such as ethyl acetate (hereinafter referred to as esters), nitriles, aprotic polar solvents , Nitrogen-containing aromatic compounds such as pyridine and 2,6-lutidine (hereinafter referred to as nitrogen-containing aromatic compounds) and mixtures thereof.
You may add an acid and a base to reaction as needed. Examples of the acid used in the reaction include carboxylic acids such as acetic acid, and sulfonic acids such as methanesulfonic acid and p-toluenesulfonic acid. Examples of the base include alkali metal carbonates, alkali metal hydrides, and organic bases. Is mentioned.
For the reaction, the compound (R-3) is usually in a proportion of 1 to 10 mol, the base is usually in a proportion of 0.1 to 10 mol, and the acid is usually in a proportion of 0.1 to 1 mol of the compound (M-3). Used in a proportion of 10 moles.
The reaction temperature is usually in the range of 0 to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
Compound (R-3) is a commercially available compound, or can be produced according to a known method.
After completion of the reaction, post-treatment operations such as addition of water to the reaction mixture, extraction with an organic solvent, and drying and concentration of the organic layer are performed, whereby compound (M-24), compound (M-25), or Mixtures of these can be obtained.

Subsequently, the second step of producing compound (Id) by reacting compound (M-24), compound (M-25), or a mixture thereof with an oxidizing agent will be described.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aliphatic hydrocarbons, aromatic hydrocarbons, aliphatic halogenated hydrocarbons, nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and these. A mixture is mentioned.
An example of the oxidizing agent used in the reaction is manganese dioxide.
Instead of reacting with the oxidizing agent, methanesulfonyl chloride and triethylamine may be mixed or sequentially reacted with the compound (M-24), the compound (M-25), or a mixture thereof.
Further, instead of reacting with an oxidizing agent, Pd—C and olefins such as vinyl acetate are mixed or sequentially reacted with the compound (M-24), the compound (M-25), or a mixture thereof. Also good.
For the reaction, the oxidizing agent is usually used in a proportion of 1 to 10 mol per 1 mol of the compound (M-24) and / or the compound (M-25).
In the reaction, when methanesulfonyl chloride and triethylamine are used in place of the oxidizing agent, 1 to 10 mol of methanesulfonyl chloride and 1 to 10 mol of triethylamine are usually used with respect to 1 mol of compound (M-24) or compound (M-25). Used in a proportion of 1 to 10 mol.
In the reaction, when Pd—C and olefins are used instead of the oxidizing agent, Pd—C is usually 0.001 to 1 mol with respect to 1 mol of the compound (M-24) or the compound (M-25), Olefins are usually used in a proportion of 1 to 10 mol.
The reaction temperature is usually in the range of 0 to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, the compound (Id) can be isolated by performing post-treatment operations such as addition of water to the reaction mixture, extraction with an organic solvent, and drying and concentration of the organic layer.

Manufacturing method 5
The compound represented by the formula (Ie) (hereinafter referred to as compound (Ie)) can be produced according to the method described below.
[Wherein, R ³⁷ represents a C1-C6 alkyl group, and other symbols have the same meaning as described above. ]

A compound represented by formula (M-4) (hereinafter referred to as compound (M-4)) and a compound represented by formula (R-4) (hereinafter referred to as compound (R-4)) are reacted. The first step is described.
Compound (R-4) can be produced according to the method described in International Publication No. 2009/054742.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aliphatic hydrocarbons, aromatic hydrocarbons, aliphatic halogenated hydrocarbons, alcohols, esters, nitriles, aprotic polar solvents, nitrogen-containing aromatics. Group compounds and mixtures thereof.
A base may be added to the reaction, and examples of the base include organic bases.
In the reaction, with respect to 1 mol of compound (M-4), compound (R-4) is usually used at a ratio of 1 to 10 mol, and the base is usually used at a ratio of 1 to 10 mol.
The reaction temperature is usually in the range of −50 to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, use the residue obtained by concentrating the reaction mixture as it is in the second step, or add water to the reaction mixture and then extract with an organic solvent, and dry and concentrate the organic layer. The residue obtained from the operation is used in the second step.

Subsequently, the second step of producing compound (Ie) by reacting the residue obtained in the first step with ammonia or a salt thereof will be described.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, nitriles, alcohols, aprotic polar solvents, nitrogen-containing aromatic compounds, water, and mixtures thereof.
Examples of ammonia or a salt thereof used for the reaction include an aqueous ammonia solution, an ammonia alcohol solution, ammonium carboxylates such as ammonium acetate, or ammonium halide salts such as ammonium chloride.
In the reaction, ammonia or a salt thereof is usually used at a ratio of 1 to 100 mol with respect to 1 mol of the compound (M-4).
The reaction temperature is usually in the range of 0 to 100 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, compound (Ie) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Manufacturing method 6
Compound (Id) can be produced by reacting compound (M-3) with a compound represented by formula (R-5) (hereinafter referred to as compound (R-5)).
[Wherein, R ³⁸ represents OR ³⁷ , a halogen atom, a C1-C3 alkylsulfonyloxy group optionally having one or more halogen atoms, or a p-toluenesulfonyloxy group; Represents the same meaning. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aliphatic hydrocarbons, aromatic hydrocarbons, aliphatic halogenated hydrocarbons, nitriles, alcohols, aprotic polar solvents, and nitrogen-containing aromatic compounds. And mixtures thereof.
In the reaction, compound (R-5) is usually used at a ratio of 1 to 10 mol per 1 mol of compound (M-3).
The reaction temperature is usually in the range of 0 to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
Compound (R-5) is a commercially available compound, or can be produced according to a known method.
After completion of the reaction, the compound (Id) can be isolated by performing post-treatment operations such as addition of water to the reaction mixture, extraction with an organic solvent, and drying and concentration of the organic layer.

Manufacturing method 7
Compound (Ia) is a compound represented by formula (M-9) (hereinafter referred to as compound (M-9)) and a compound represented by formula (R-6) (hereinafter referred to as compound (R-6)). Can be made to react in the presence of a base.
[Wherein, X ^b represents a fluorine atom or a chlorine atom, and other symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures thereof.
Examples of the base used in the reaction include alkali metal carbonates and alkali metal hydrides.
In the reaction, with respect to 1 mol of compound (M-9), compound (R-6) is usually used at a ratio of 1 to 10 mol, and the base is usually used at a ratio of 1 to 10 mol.
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
Compound (R-6) is a commercially available compound, or can be produced according to a known method.
After completion of the reaction, compound (Ia) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Manufacturing method 8
A compound represented by formula (If) (hereinafter referred to as compound (If)) can be produced according to the following scheme.
[Wherein, R ^xy represents a carboxy group or a trimethylsilyl group, and Q ^x represents a single bond, a C1-C5 alkylene group which may have one or more substituents selected from group E, or group E. Represents a C2-C5 alkenylene group optionally having one or more selected substituents, ^Xc represents a halogen atom, a trifluoromethanesulfonyloxy group, or a p-toluenesulfonyloxy group; Represents the same meaning. ]

First, a method for producing a compound represented by formula (M-23) (hereinafter referred to as compound (M-23)) will be described.
Compound (M-23) is obtained by reacting compound (M-1) with a compound represented by formula (R-16) (hereinafter referred to as compound (R-16)) in the presence of a metal catalyst. Can be manufactured.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures thereof.
Examples of the metal catalyst used in the reaction include palladium catalysts, nickel catalysts, and copper catalysts.
A ligand, a base, or an inorganic halide may be added to the reaction as necessary.
Examples of the ligand used in the reaction include phosphine ligands, 2,2′-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, and the like.
Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases.
Examples of the inorganic halide used in the reaction include metal fluorides such as potassium fluoride, cesium fluoride, and zinc fluoride, and alkali metal chlorides such as lithium chloride and sodium chloride.
In the reaction, with respect to 1 mol of compound (M-1), compound (R-16) is usually in a proportion of 1 to 10 mol, metal catalyst is usually in a proportion of 0.01 to 0.5 mol, and the ligand is Usually, a proportion of 0.01 to 1 mol, a proportion of base is usually 0.1 to 5 mol, and an inorganic halide is usually used in a proportion of 0.1 to 5 mol.
The reaction temperature is usually in the range of -20 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
Compound (R-16) is a commercially available compound, or can be produced according to a known method.
After completion of the reaction, the compound (M-23) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Next, the production method of compound (If) will be described.
Compound (If) is produced by reacting compound (M-23) with a compound represented by formula (R-18) (hereinafter referred to as compound (R-18)) in the presence of a base. be able to.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures thereof.
Examples of the base used in the reaction include alkali metal carbonates or alkali metal hydrides.
In the reaction, with respect to 1 mol of compound (M-23), compound (R-18) is usually used at a ratio of 1 to 2 mol, and the base is usually used at a ratio of 1 to 10 mol.
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
After completion of the reaction, compound (If) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
Compound (R-18) is a commercially available compound, or can be produced using a known method.

Compound (If) is obtained by reacting compound (M-1) with a compound represented by formula (R-17) (hereinafter referred to as compound (R-17)) in the presence of a metal catalyst. Can be manufactured.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures thereof.
Examples of the metal catalyst used in the reaction include palladium catalysts, nickel catalysts, and copper catalysts.
A ligand or a base may be added to the reaction as necessary.
Examples of the ligand used in the reaction include phosphine ligands, 2,2′-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, and the like.
Examples of the base used in the reaction include lithium bis (trimethylsilyl) amide, lithium diisopropylamide, alkali metal hydrides, alkali metal carbonates, and organic bases.
In the reaction, with respect to 1 mol of compound (M-1), compound (R-17) is usually in a proportion of 1 to 10 mol, metal catalyst is usually in a proportion of 0.01 to 0.5 mol, and the ligand is Usually, the base is used in a proportion of 0.01 to 1 mol, and the base is usually used in a proportion of 0.1 to 5 mol.
The reaction temperature is usually in the range of -20 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
Compound (R-17) is a commercially available compound, or can be produced according to a known method.
After completion of the reaction, compound (If) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Manufacturing method 9
A compound represented by formula (Ig) (hereinafter referred to as compound (Ig)) and a compound represented by formula (Ih) (hereinafter referred to as compound (Ih)) can be produced according to the following scheme. it can.
[Wherein the symbols have the same meaning as described above. ]

First, a method for producing compound (Ig) from compound (If) will be described.
Compound (Ig) can be produced by hydrolyzing compound (If) in the presence of a base or an acid.
The reaction is usually performed in a solvent. Examples of the solvent used for the reaction include aliphatic halogenated hydrocarbons, aromatic hydrocarbons, alcohols, acetic acid, water, and mixtures thereof.
Examples of the base used in the reaction include alkali metal hydroxides such as sodium hydroxide and lithium hydroxide.
Examples of the acid used for the reaction include mineral acids such as hydrochloric acid.
In the reaction, with respect to 1 mol of compound (If), when a base is used, the base is usually used in a proportion of 2 to 10 mol, and when an acid is used, the acid is usually used in a proportion of 0.1 to 10 mol. When using a mineral acid as an acid, a mineral acid can also be used as a solvent.
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, compound (Ig) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Next, the production method of compound (Ih) will be described.
Compound (Ih) can be produced by reacting compound (Ig) with a fluorinating agent.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include aliphatic halogenated hydrocarbons, aromatic hydrocarbons, and mixtures thereof.
Examples of the fluorinating agent used in the reaction include sulfur tetrafluoride, 4-tert-butyl-2,6-dimethylphenylsulfur trifluoride and the like.
Hydrofluoric acid or pyridinium poly (hydrogen fluoride) may be added to the reaction as necessary.
In the reaction, the proportion of the fluorinating agent is usually 3 to 10 moles relative to 1 mole of the compound (Ig). Used in a proportion of 0.5 mol.
The reaction temperature is usually in the range of -20 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, compound (Ih) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Manufacturing method 10
The compound represented by the formula (M-1b) (hereinafter referred to as the compound (M-1b)) and the compound represented by the formula (M-1c) (hereinafter referred to as the compound (M-1c)) have the formula It can be produced by oxidizing a compound represented by (M-1a) (hereinafter referred to as compound (M-1a)).
[Wherein the symbols have the same meaning as described above. ]
Compound (M-1b) and Compound (M-1c) can be produced according to the method described in Production Method 3, using Compound (M-1a) instead of Compound (Ia).

Manufacturing method 11
Compound (M-2) can be produced from compound (M-1).
[Wherein the symbols have the same meaning as described above. ]
The reaction is carried out according to the method described in Angew. Chem. Int. Ed., 2007, 5359. or Eur. J. Org. Chem., 2003, 4313.

Production method 12
Compound (M-3) can be produced by reacting compound (M-4) with ammonia or a salt thereof.
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, nitriles, alcohols, aprotic polar solvents, water, and mixtures thereof.
Examples of ammonia or a salt thereof used in the reaction include an aqueous ammonia solution, an ammonia alcohol solution, ammonium carboxylates such as ammonium acetate, or ammonium halide salts such as ammonium chloride.
In the reaction, ammonia or a salt thereof is usually used at a ratio of 1 to 100 mol with respect to 1 mol of the compound (M-4).
The reaction temperature is usually in the range of 0 ° C to 200 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
After completion of the reaction, the compound (M-3) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Production method 13
Compound (M-3) is a compound represented by formula (M-5) (hereinafter referred to as compound (M-5)) and a compound represented by formula (R-19) (hereinafter referred to as compound (R-19). Can be prepared by reacting in the presence of a base.
[Wherein the symbols have the same meaning as described above. ]
Compound (R-19) is a commercially available compound, or can be produced by the method described in Journal of Molecular Catalysis A: Chemical, 2011, 341 (1-2), 57.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include alcohols, ethers, aromatic hydrocarbons, aprotic polar solvents, and mixtures thereof.
Examples of the base used in the reaction include butyl lithium, sec-butyl lithium, tert-butyl lithium, lithium diisopropylamide, sodium bis (trimethylsilyl) amide, potassium bis (trimethylsilyl) amide, potassium tert-butoxide, sodium methoxide, sodium Examples include ethoxide and alkali metal hydrides.
In the reaction, with respect to 1 mol of compound (M-5), compound (R-19) is usually used at a ratio of 1 to 5 mol, and the base is usually used at a ratio of 1 to 5 mol. Preferably, the compound (R-19) is used in a proportion of 1.0 to 1.1 mol and the base is used in a proportion of 1 to 2 mol with respect to 1 mol of the compound (M-5).
The reaction temperature is usually in the range of -78 ° C to 100 ° C. The reaction time is usually in the range of 0.5 to 12 hours.
After completion of the reaction, the compound (M-3) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Manufacturing method 14
A compound represented by formula (M-5) (hereinafter referred to as compound (M-5)) is a compound represented by formula (M-6) (hereinafter referred to as compound (M-6)) and cyan. Can be produced by reacting the compound with a compound in the presence of a metal catalyst.
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures thereof.
Examples of the cyanide used in the reaction include sodium cyanide and zinc cyanide.
Examples of the metal catalyst used in the reaction include palladium catalysts, nickel catalysts, and copper catalysts.
A ligand may be added to the reaction as necessary.
Examples of the ligand used in the reaction include phosphine ligands, 2,2′-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, and the like.
In the reaction, relative to 1 mol of the compound (M-6), the cyanide is usually in a proportion of 1 to 10 mol, the metal catalyst is usually in a proportion of 0.01 to 0.5 mol, and the ligand is usually 0.01. Used in a proportion of ˜1 mol.
The reaction temperature is usually in the range of -20 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, the compound (M-5) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Production method 15
The compound represented by the formula (M-7) (hereinafter referred to as the compound (M-7)) is the compound (M-5) and the compound represented by the formula (R-22) (hereinafter referred to as the compound (R-22). In the presence of an acid.
[The symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, and mixtures thereof.
Examples of the acid used in the reaction include mineral acids such as hydrochloric acid and sulfuric acid, sulfonic acids such as p-toluenesulfonic acid, and Lewis acids such as aluminum chloride.
In the reaction, with respect to 1 mol of compound (M-5), compound (R-22) is usually used at a ratio of 1 to 100 mol, and acid is usually used at a ratio of 0.01 to 10 mol. Compound (R-22) can also be used as a solvent.
The reaction temperature is usually in the range of -20 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
Compound (R-22) is a commercially available compound, or can be produced according to a known method.
After completion of the reaction, the compound (M-7) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Production method 16
Compound (M-7) can be produced by reacting compound (M-6) with compound (R-22) in the presence of carbon monoxide and a metal catalyst.
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, and mixtures thereof.
Examples of the metal catalyst used in the reaction include palladium catalysts, nickel catalysts, and copper catalysts.
A ligand or a base may be added to the reaction as necessary.
Examples of the ligand used in the reaction include phosphine catalysts, 2,2′-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, and the like.
Examples of the base used in the reaction include alkali metal carboxylates such as sodium acetate and potassium acetate, alkali metal hydrides, alkali metal carbonates, and organic bases.
For the reaction, the proportion of carbon monoxide is 1 to 10,000 mol, the base is usually 1 to 10 mol, and the metal catalyst is usually 0.01 to 0.5 mol with respect to 1 mol of the compound (M-6). A ratio and a ligand are normally used in the ratio of 0.01-1 mol. The reaction can also be carried out in a carbon monoxide atmosphere.
The reaction temperature is usually in the range of -20 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, the compound (M-7) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Manufacturing method 17
Compound (M-4) can be produced by reacting compound (M-7) with compound (R-19) in the presence of a base.
[Wherein the symbols have the same meaning as described above. ]
Compound (M-4) can be produced according to the method described in Production Method 13, using Compound (M-7) instead of Compound (M-5).

Production method 18
A compound represented by compound (M-9A) (hereinafter referred to as compound (M-9A)) is a compound represented by formula (M-8) (hereinafter referred to as compound (M-8)) and a compound. It can manufacture by making (R-1) react.
[Wherein the symbols have the same meaning as described above. ]
Compound (M-9A) can be produced according to the method described in Production Method 1, using Compound (M-8) instead of Compound (M-1).

Production method 19
Compound (M-9A) can be produced by reacting a compound represented by formula (M-10) (hereinafter referred to as compound (M-10)) with compound (R-2).
[Wherein the symbols have the same meaning as described above. ]
Compound (M-9A) can be produced according to the method described in Production Method 2, using Compound (M-10) instead of Compound (M-2).

Manufacturing method 20
Compound (M-10) can be produced from compound (M-8).
[Wherein the symbols have the same meaning as described above. ]
Compound (M-10) can be produced according to the method described in Production Method 11, using Compound (M-8) instead of Compound (M-1).

Production method 21
Compound (M-1a) can be produced by reacting compound (M-8) with compound (R-6) in the presence of a base.
[Wherein the symbols have the same meaning as described above. ]
Compound (M-1a) can be produced according to the method described in Production Method 7, using Compound (M-8) instead of Compound (M-9).

Production method 22
A compound represented by formula (M-1d) (hereinafter referred to as compound (M-1d)) is a compound represented by formula (M-11) (hereinafter referred to as compound (M-11)); It can be produced by reacting phosphorus oxychloride or phosphorus oxybromide.
[Wherein, X ^d represents a chlorine atom or a bromine atom, and the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used for the reaction include aromatic hydrocarbons.
When using phosphorus oxychloride, phosphorus oxychloride can also be used as a solvent.
In the reaction, phosphorous oxychloride or phosphorous oxybromide is usually used at a ratio of 1 to 10 moles relative to 1 mole of the compound (M-11).
The reaction temperature is usually in the range of 0 ° C to 150 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
After completion of the reaction, the compound (M-1d) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Manufacturing method 23
Compound (M-11) can be produced by reacting a compound represented by formula (M-12) (hereinafter referred to as compound (M-12)) with an acid.
[Wherein R ^xx represents a methyl group or an ethyl group, and other symbols represent the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include aliphatic halogenated hydrocarbons, aromatic hydrocarbons, nitriles, alcohols, acetic acid, and mixtures thereof.
Examples of the acid used in the reaction include mineral acids such as hydrochloric acid, boron halides such as boron trichloride and boron tribromide, titanium (IV) chloride, and aluminum chloride.
In the reaction, the acid is usually used at a ratio of 0.1 to 10 mol with respect to 1 mol of the compound (M-12). When using a mineral acid as an acid, a mineral acid can also be used as a solvent.
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, the compound (M-11) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Production method 24
A compound represented by formula (M-12a) (hereinafter referred to as compound (M-12a)), a compound represented by formula (M-12b) (hereinafter referred to as compound (M-12b)), and a formula A compound represented by (M-12c) (hereinafter referred to as compound (M-12c)) can be produced according to the following scheme.
[Wherein the symbols have the same meaning as described above. ]

Compound (M-12a) is a method described in production method 7 using a compound represented by formula (M-13) (hereinafter referred to as compound (M-13)) instead of compound (M-9). It can be manufactured according to.
Compound (M-12b) and Compound (M-12c) can be produced according to the method described in Production Method 3, using Compound (M-12a) instead of Compound (Ia).

Production method 25
Compound (M-13) is obtained by reacting compound (M-6) with a compound represented by formula (M-15) (hereinafter referred to as compound (M-15)) in the presence of a metal catalyst. Can be manufactured.
[Wherein the symbols have the same meaning as described above. ]
Compound (M-13) is compound (M-1) used in place of compound (M-1), compound (R-1) is used in place of compound (M-15), and production method 1 is used. It can be produced according to the method.
Compound (M-15) is a commercially available compound, or can be produced according to a known method.

Manufacturing method 26
Compound (M-13) is a compound represented by formula (M-16) (hereinafter referred to as compound (M-16)) and a compound represented by formula (M-17) (hereinafter referred to as compound (M-17). In the presence of a metal catalyst.
[Wherein the symbols have the same meaning as described above. ]
Compound (M-13) is described in Production method 2, using compound (M-16) instead of compound (M-2), compound (M-17) instead of compound (R-2), and It can be produced according to the method.
Compound (M-16) and compound (M-17) are commercially available compounds, or can be produced according to known methods.

Manufacturing method 27
Compound (M-8) is obtained by reacting compound (M-6) with a compound represented by formula (M-18) (hereinafter referred to as compound (M-18)) in the presence of a metal catalyst. Can be manufactured.
[Wherein the symbols have the same meaning as described above. ]
Compound (M-8) is described in Production method 1, using compound (M-6) instead of compound (M-1), compound (M-18) instead of compound (R-1), and It can be produced according to the method.
Compound (M-18) is a commercially available compound, or can be produced according to a known method.

Production method 28
Compound (M-8) is obtained by reacting compound (M-16) with a compound represented by formula (M-19) (hereinafter referred to as compound (M-19)) in the presence of a metal catalyst. Can be manufactured.
[Wherein the symbols have the same meaning as described above. ]
Compound (M-8) is described in Production method 1, using compound (M-16) in place of compound (M-1) and using compound (M-19) in place of compound (R-1). It can be produced according to the method.
Compound (M-19) is a commercially available compound, or can be produced according to a known method.

Production method 29
The compound represented by formula (M-6a) (hereinafter referred to as compound (M-6a)) is composed of the compound represented by formula (M-20a) (hereinafter referred to as compound (M-20a)) and the formula ( It can be produced by reacting a compound represented by R-7) (hereinafter referred to as compound (R-7)) in the presence of a base.
[Wherein T ² is represented by OR ¹ , NR ¹ R ²⁹ , a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, or a formula T-8. Represents a group, and other symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures thereof.
Examples of the base used in the reaction include alkali metal carbonates or alkali metal hydrides.
In the reaction, with respect to 1 mol of compound (M-20a), compound (R-7) is usually used at a ratio of 1 to 2 mol, and the base is usually used at a ratio of 1 to 10 mol.
The reaction temperature is usually in the range of -20 ° C to 150 ° C. The reaction time is usually in the range of 0.5 to 24 hours.
After completion of the reaction, the compound (M-6a) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.
Compound (R-7) and compound (M-20a) are commercially available compounds, or can be produced using known methods.

Production method 30
The compound represented by the formula (M-6b) (hereinafter referred to as the compound (M-6b)) is composed of the compound represented by the formula (M-20b) (hereinafter referred to as the compound (M-20b)) and the formula It can be produced by reacting with a compound represented by (R-8) (hereinafter referred to as compound (R-8)).
[Wherein, T ³ represents a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, as described in the specification. Represents a group represented by the formula T-9, a group represented by the formula T-10, a group represented by the formula T-11, or a group represented by the formula T-12, and other symbols have the same meanings as described above. . ]
Compound (M-6b) is described in Production Method 1 using Compound (M-20b) instead of Compound (M-1) and Compound (M-8) instead of Compound (R-1). It can be produced according to the method.
Compound (R-8) and compound (M-20b) are commercially available compounds, or can be produced using known methods.

Production method 31
A compound represented by formula (M-6c) (hereinafter referred to as compound (M-6c)) is composed of a compound represented by formula (M-20c) (hereinafter referred to as compound (M-20c)), It can be produced by reacting a compound represented by (R-9) (hereinafter referred to as compound (R-9)).
[Wherein the symbols have the same meaning as described above. ]
The reaction is carried out according to the method described in International Publication No. 2016/121969.
Compound (R-9) and compound (M-20c) are commercially available compounds, or can be produced using known methods.

Production method 32
The compound represented by the formula (M-6d) (hereinafter referred to as the present compound (M-6d)) is composed of the compound (M-20b) and the compound represented by the formula (R-10) (hereinafter referred to as the compound (R— 10).) Can be reacted in the presence of copper.
[Wherein T ⁴ has a C1-C10 chain hydrocarbon group having one or more halogen atoms, (C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms, and one or more halogen atoms ( (C1-C5 alkylsulfanyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfinyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfonyl) C2-C5 alkyl A group, a (C3-C7 cycloalkyl) C1-C3 alkyl group having one or more substituents selected from group G, or a C3-C7 cycloalkyl group having one or more substituents selected from group G; The symbol represents the same meaning as described above. ]
Compound (R-10) is a commercially available compound, or can be produced according to a known method.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include aromatic hydrocarbons, aprotic polar solvents, and mixtures thereof.
In the reaction, with respect to 1 mol of the compound (M-20b), the compound (R-10) is usually used in a proportion of 1 to 10 mol, and the copper is usually used in a proportion of 1 to 10 mol.
The reaction temperature is usually in the range of 40 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, the compound (M-6d) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Production method 33
A compound represented by the formula (M-6e) (hereinafter referred to as a compound (M-6e)) is a compound represented by a formula (M-20d) (hereinafter referred to as a compound (M-20d)) and a formula. It can be produced by reacting a compound represented by (R-11) (hereinafter referred to as compound (R-11)) in the presence of a condensing agent.
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method described in International Publication No. 2014/021468.
Compound (R-11) is a commercially available compound, or can be produced according to a known method.

Manufacturing method 34
A compound represented by formula (M-6f) (hereinafter referred to as compound (M-6f)) is a compound represented by compound (M-20b) and a compound represented by formula (R-12) (hereinafter referred to as compound (R-12)). Can be prepared by reacting in the presence of a base.
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method described in Synthesis, 2008, 23, 3707.
Compound (R-12) is a commercially available compound, or can be produced according to a known method.

Production method 35
The compound represented by the formula (M-6g) (hereinafter referred to as the compound (M-6g)) and the compound represented by the formula (M-20e) (hereinafter referred to as the compound (M-20e)) and the formula It can be produced by reacting a compound represented by (R-13) (hereinafter referred to as compound (R-13)) in the presence of a condensing agent.
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method described in International Publication No. 2014/021468.
Compound (R-13) is a commercially available compound, or can be produced according to a known method.

Production method 36
A compound represented by formula (M-6h) (hereinafter referred to as compound (M-6h)) is a compound represented by formula (M-20f) (hereinafter referred to as compound (M-20f)) and a formula. It can be produced by reacting a compound represented by (R-14) (hereinafter referred to as compound (R-14)).
[Wherein the symbols have the same meaning as described above. ]
The reaction can be carried out according to the method described in Journal of Heterocyclic Chemistry, 2000, 1309.
Compound (R-14) is a commercially available compound, or can be produced according to a known method.

Production method 37
The compound represented by the formula (M-6i) (hereinafter referred to as the compound (M-6i)) and the compound represented by the formula (M-20g) (hereinafter referred to as the compound (M-20g)) and the formula It can manufacture by making the compound (henceforth a compound (R-15)) shown by (R-15) react in presence of a base.
[Wherein the symbols have the same meaning as described above. ]
Compound (R-15) and compound (M-20g) are commercially available compounds, or can be produced according to known methods.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, and mixtures thereof.
Examples of the base used in the reaction include organic bases, alkali metal hydrides, and alkali metal carbonates.
In the reaction, with respect to 1 mol of the compound (M-20g), the compound (R-15) is usually used in a proportion of 1 to 10 mol, and the base is usually used in a proportion of 0.1 to 5 mol.
The reaction temperature is usually in the range of -20 ° C to 120 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, the compound (M-6i) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Production method 38
A compound represented by formula (M-6j) (hereinafter referred to as compound (M-6j)), a compound represented by formula (M-6k) (hereinafter referred to as compound (M-6k)), and a formula A compound represented by (M-6m) (hereinafter referred to as compound (M-6m)) can be produced according to the following method.

[Wherein the symbols have the same meaning as described above. ]
First, a method for producing a compound represented by formula (M-21) (hereinafter referred to as compound (M-21)) will be described.
Compound (M-21) can be produced by reacting compound (M-20b) with thiobenzoic acid in the presence of a copper catalyst and a base.
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures thereof.
Examples of the copper catalyst used in the reaction include copper chloride, copper bromide, and copper iodide.
Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases.
A ligand may be added to the reaction as necessary.
Examples of the ligand used in the reaction include 2,2′-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, and the like.
In the reaction, thiobenzoic acid is usually used in a proportion of 1 to 10 mol, and a copper catalyst is usually used in a proportion of 0.01 to 0.5 mol, based on 1 mol of compound (M-20b). The ligand is usually used in a proportion of 0.01 to 1 mol, and the base is usually used in a proportion of 0.1 to 5 mol.
The reaction temperature is usually in the range of -20 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
After completion of the reaction, the compound (M-21) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Next, a method for producing a compound represented by formula (M-22) (hereinafter referred to as compound (M-22)) will be described.
Compound (M-22) can be produced, for example, according to the method described in International Publication No. 2011/068171 or the method described in Journal of Organic Chemistry, 1978, 43 (6), 1190-1192.

It continues and describes the manufacturing method of a compound (M-6j).
Compound (M-6j) can be produced according to the method described in Production Example 37, using compound (M-22) in place of compound (M-20g).

It continues and describes the manufacturing method of a compound (M-6k).
Compound (M-6k) can be produced according to the method described in Production Method 3, using Compound (M-6j) instead of Compound (Ia).

It continues and describes the manufacturing method of a compound (M-6m).
Compound (M-6m) can be produced according to the method described in Production Method 3, using Compound (M-6k) in place of Compound (Ib).

Manufacturing method 39
The compound represented by the formula (IB) (hereinafter referred to as the present compound B) is composed of the compound (M-1) and the compound represented by the formula (R-20) (hereinafter referred to as the compound (R-20)). Can be produced in the presence of a copper catalyst and a base.
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, and mixtures thereof.
Examples of the copper catalyst used in the reaction include copper (I) chloride, copper (I) bromide, and copper (I) iodide.
Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases.
A ligand may be added to the reaction as necessary.
Examples of the ligand used in the reaction include 2,2′-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, and the like.
In the reaction, the compound (R-20) is usually used in a proportion of 1 to 10 mol, and the copper catalyst is usually used in a proportion of 0.01 to 0.5 mol, relative to 1 mol of the compound (M-1). The ligand is usually used in a proportion of 0.01 to 1 mol, and the base is usually used in a proportion of 0.1 to 5 mol.
The reaction temperature is usually in the range of -20 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
Compound (R-20) is a commercially available compound, or can be produced according to a known method.
After completion of the reaction, this compound B can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Manufacturing method 40
This compound B is obtained by reacting compound (M-11) with a compound represented by formula (R-21) (hereinafter referred to as compound (R-21)) in the presence of a copper catalyst and a base. Can be manufactured.
[Wherein the symbols have the same meaning as described above. ]
The reaction is usually performed in a solvent. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aprotic polar solvents, and mixtures thereof.
Examples of the copper catalyst used in the reaction include copper (I) chloride, copper (I) bromide, and copper (I) iodide.
Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases.
A ligand may be added to the reaction as necessary.
Examples of the ligand used in the reaction include 2,2′-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, and the like.
In the reaction, the compound (R-21) is usually used in a proportion of 1 to 10 mol, and the copper catalyst is usually used in a proportion of 0.01 to 0.5 mol with respect to 1 mol of the compound (M-11). The ligand is usually used in a proportion of 0.01 to 1 mol, and the base is usually used in a proportion of 0.1 to 5 mol.
The reaction temperature is usually in the range of -20 ° C to 200 ° C. The reaction time is usually in the range of 0.1 to 24 hours.
Compound (R-21) is a commercially available compound, or can be produced according to a known method.
After completion of the reaction, the compound (IB) can be obtained by performing post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

Next, specific examples of this compound are shown below.
In the present specification, Me represents a methyl group, Et represents an ethyl group, Ph represents a phenyl group, Py2 represents a 2-pyridyl group, Py3 represents a 3-pyridyl group, and Py4 represents a 4-pyridyl group. . When Ph, Py2, Py3, and Py4 have a substituent, the substituent is indicated together with the substitution position before the symbol. For example, 4-CF ₃ -Py2 represents a 4- (trifluoromethyl) -2-pyridyl group, and 3,5- (CF ₃ ) ₂ -Ph represents a 3,5-bis (trifluoromethyl) phenyl group. .

Formula (L-1):
Wherein A ¹ is CH, G is a cyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter referred to as compound group). SX1).

In the formula (L-1), A ¹ is CH, G is a 1- (trifluoromethyl) cyclopropyl group, and T is any substituent described in Table 1 to Table 6. A compound (hereinafter referred to as compound group SX2).
In the formula (L-1), compounds wherein A ¹ is CH, G is a 1-cyanocyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (Hereinafter referred to as compound group SX3).
In Formula (L-1), A ¹ is CH, G is a 2,2-difluorocyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. Compound (hereinafter referred to as Compound Group SX4).
In the formula (L-1), A ¹ is CH, G is a 2- (4-fluorophenyl) cyclopropyl group, and T is any of the substitutions described in [Table 1] to [Table 6] A compound which is a group (hereinafter referred to as compound group SX5).
In formula (L-1), a compound wherein A ¹ is CH, G is a cyclobutyl group, and T is any substituent described in Table 1 to Table 6 (hereinafter referred to as compound) This is referred to as group SX6).
In the formula (L-1), compounds wherein A ¹ is CH, G is a 1-cyanocyclobutyl group, and T is any one of the substituents described in Table 1 to Table 6. (Hereinafter referred to as compound group SX7).
In the formula (L-1), compounds wherein A ¹ is CH, G is a cyclopentyl group, and T is any one of the substituents described in Table 1 to Table 6 (hereinafter, compounds (Indicated as group SX8).
In the formula (L-1), compounds wherein A ¹ is CH, G is a 1-cyanocyclopentyl group, and T is any one of the substituents described in Table 1 to Table 6. Hereinafter referred to as compound group SX9).
In the formula (L-1), a compound wherein A ¹ is CH, G is a cyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6 (hereinafter referred to as compound (Indicated as group SX10).
In the formula (L-1), compounds wherein A ¹ is CH, G is a 1-cyanocyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6. Hereinafter referred to as compound group SX11).
In the formula (L-1), A ¹ is CH, G is a 4,4-difluorocyclohexyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. Compound (hereinafter referred to as compound group SX12).
In formula (L-1), a compound wherein A ¹ is a nitrogen atom, G is a cyclopropyl group, and T is any one of the substituents described in Table 1 to Table 6 And referred to as Compound Group SX13).
In Formula (L-1), A ¹ is a nitrogen atom, G is a 1- (trifluoromethyl) cyclopropyl group, and T is any one of the substitutions described in [Table 1] to [Table 6] A compound which is a group (hereinafter referred to as compound group SX14).
In the formula (L-1), A ¹ is a nitrogen atom, G is a 1-cyanocyclopropyl group, and T is any substituent described in [Table 1] to [Table 6]. Compound (hereinafter referred to as compound group SX15).
In Formula (L-1), A ¹ is a nitrogen atom, G is a 2,2-difluorocyclopropyl group, and T is any of the substituents described in [Table 1] to [Table 6]. A certain compound (hereinafter referred to as compound group SX16).
In the formula (L-1), A ¹ is a nitrogen atom, G is a 2- (4-fluorophenyl) cyclopropyl group, and T is any one of [Table 1] to [Table 6] A compound which is a substituent (hereinafter referred to as compound group SX17).
In formula (L-1), a compound wherein A ¹ is a nitrogen atom, G is a cyclobutyl group, and T is any one of the substituents described in Table 1 to Table 6, (Referred to as compound group SX18).
In Formula (L-1), A ¹ is a nitrogen atom, G is a 1-cyanocyclobutyl group, and T is any substituent described in [Table 1] to [Table 6]. Compound (hereinafter referred to as compound group SX19).
In formula (L-1), a compound wherein A ¹ is a nitrogen atom, G is a cyclopentyl group, and T is any substituent described in Table 1 to Table 6 (hereinafter, (Referred to as compound group SX20).
In the formula (L-1), compounds wherein A ¹ is a nitrogen atom, G is a 1-cyanocyclopentyl group, and T is any substituent described in [Table 1] to [Table 6] (Hereinafter referred to as compound group SX21).
In formula (L-1), a compound wherein A ¹ is a nitrogen atom, G is a cyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6, (Referred to as compound group SX22).
In the formula (L-1), compounds wherein A ¹ is a nitrogen atom, G is a 1-cyanocyclohexyl group, and T is any substituent described in [Table 1] to [Table 6] (Hereinafter referred to as compound group SX23).
In the formula (L-1), A ¹ is a nitrogen atom, G is a 4,4-difluorocyclohexyl group, and T is any substituent described in [Table 1] to [Table 6]. Compound (hereinafter referred to as Compound Group SX24).

Formula (L-2):
Wherein A ¹ is CH, G is a cyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter referred to as compound group). SX25).
In Formula (L-2), A ¹ is CH, G is a 1- (trifluoromethyl) cyclopropyl group, and T is any one of the substituents described in Table 1 to Table 6. A compound (hereinafter referred to as compound group SX26).
In the formula (L-2), compounds wherein A ¹ is CH, G is a 1-cyanocyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (Hereinafter referred to as compound group SX27).
In Formula (L-2), A ¹ is CH, G is a 2,2-difluorocyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. Compound (hereinafter referred to as Compound Group SX28).
In the formula (L-2), A ¹ is CH, G is a 2- (4-fluorophenyl) cyclopropyl group, and T is any of the substitutions described in [Table 1] to [Table 6] A compound which is a group (hereinafter referred to as compound group SX29).
In formula (L-2), a compound wherein A ¹ is CH, G is a cyclobutyl group, and T is any one of the substituents described in Table 1 to Table 6 (hereinafter referred to as compound (Indicated as group SX30).
In the formula (L-2), compounds wherein A ¹ is CH, G is a 1-cyanocyclobutyl group, and T is any one of the substituents described in Table 1 to Table 6. (Hereinafter referred to as compound group SX31).
In the formula (L-2), a compound wherein A ¹ is CH, G is a cyclopentyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter referred to as “compound”) (Denoted as group SX32).
In the formula (L-2), compounds wherein A ¹ is CH, G is a 1-cyanocyclopentyl group, and T is any of the substituents described in Table 1 to Table 6. Hereinafter referred to as compound group SX33).
In the formula (L-2), a compound wherein A ¹ is CH, G is a cyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6 (hereinafter, compounds This is referred to as group SX34).
In the formula (L-2), compounds wherein A ¹ is CH, G is a 1-cyanocyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6. Hereinafter referred to as compound group SX35).
In the formula (L-2), A ¹ is CH, G is a 4,4-difluorocyclohexyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. Compound (hereinafter referred to as Compound Group SX36).
In the formula (L-2), a compound wherein A ¹ is a nitrogen atom, G is a cyclopropyl group, and T is any substituent described in Table 1 to Table 6 And referred to as Compound Group SX37).
In Formula (L-2), A ¹ is a nitrogen atom, G is a 1- (trifluoromethyl) cyclopropyl group, and T is any of the substitutions described in [Table 1] to [Table 6] A compound which is a group (hereinafter referred to as compound group SX38).
In Formula (L-2), A ¹ is a nitrogen atom, G is a 1-cyanocyclopropyl group, and T is any substituent described in [Table 1] to [Table 6]. Compound (hereinafter referred to as compound group SX39).
In Formula (L-2), A ¹ is a nitrogen atom, G is a 2,2-difluorocyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. A certain compound (hereinafter referred to as compound group SX40).
In Formula (L-2), A ¹ is a nitrogen atom, G is a 2- (4-fluorophenyl) cyclopropyl group, and T is any one of [Table 1] to [Table 6] A compound which is a substituent (hereinafter referred to as compound group SX41).
In the formula (L-2), a compound wherein A ¹ is a nitrogen atom, G is a cyclobutyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter, (Referred to as compound group SX42).
In Formula (L-2), A ¹ is a nitrogen atom, G is a 1-cyanocyclobutyl group, and T is any substituent described in [Table 1] to [Table 6]. Compound (hereinafter referred to as compound group SX43).
In the formula (L-2), a compound wherein A ¹ is a nitrogen atom, G is a cyclopentyl group, and T is any one of the substituents described in Table 1 to Table 6, (Referred to as compound group SX44).
In the formula (L-1), compounds wherein A ¹ is a nitrogen atom, G is a 1-cyanocyclopentyl group, and T is any substituent described in [Table 1] to [Table 6] (Hereinafter referred to as compound group SX45).
In formula (L-2), a compound wherein A ¹ is a nitrogen atom, G is a cyclohexyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter, (Referred to as compound group SX46).
In the formula (L-2), compounds wherein A ¹ is a nitrogen atom, G is a 1-cyanocyclohexyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (Hereinafter referred to as compound group SX47).
In the formula (L-2), A ¹ is a nitrogen atom, G is a 4,4-difluorocyclohexyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. Compound (hereinafter referred to as Compound Group SX48).

Formula (L-3):
Wherein A ¹ is CH, G is a cyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter referred to as compound group). SX49)
In the formula (L-3), A ¹ is CH, G is a 1- (trifluoromethyl) cyclopropyl group, and T is any one of the substituents described in Table 1 to Table 6. A compound (hereinafter referred to as compound group SX50).
In the formula (L-3), compounds wherein A ¹ is CH, G is a 1-cyanocyclopropyl group, and T is any substituent described in [Table 1] to [Table 6] (Hereinafter referred to as compound group SX51).
In Formula (L-3), A ¹ is CH, G is a 2,2-difluorocyclopropyl group, and T is any substituent described in [Table 1] to [Table 6]. Compound (hereinafter referred to as Compound Group SX52).
In Formula (L-3), A ¹ is CH, G is a 2- (4-fluorophenyl) cyclopropyl group, and T is any of the substitutions described in [Table 1] to [Table 6] A compound which is a group (hereinafter referred to as compound group SX53).
In the formula (L-3), a compound wherein A ¹ is CH, G is a cyclobutyl group, and T is any one of the substituents described in Table 1 to Table 6 (hereinafter, compounds This is referred to as group SX54).
In the formula (L-3), compounds wherein A ¹ is CH, G is a 1-cyanocyclobutyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (Hereinafter referred to as compound group SX55).
In the formula (L-3), a compound wherein A ¹ is CH, G is a cyclopentyl group, and T is any one of the substituents described in Table 1 to Table 6 (hereinafter referred to as compound (Referred to as group SX56).
In the formula (L-3), compounds wherein A ¹ is CH, G is a 1-cyanocyclopentyl group, and T is any one of the substituents described in Table 1 to Table 6. Hereinafter referred to as compound group SX57).
In the formula (L-3), a compound wherein A ¹ is CH, G is a cyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6 (hereinafter referred to as compound (Indicated as group SX58).
In the formula (L-3), compounds wherein A ¹ is CH, G is a 1-cyanocyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6. Hereinafter referred to as compound group SX59).
In Formula (L-3), A ¹ is CH, G is a 4,4-difluorocyclohexyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. Compound (hereinafter referred to as compound group SX60).
In formula (L-3), a compound wherein A ¹ is a nitrogen atom, G is a cyclopropyl group, and T is any one of the substituents described in Table 1 to Table 6 And referred to as Compound Group SX61).
In the formula (L-3), A ¹ is a nitrogen atom, G is a 1- (trifluoromethyl) cyclopropyl group, and T is any one of the substitutions described in [Table 1] to [Table 6] A compound which is a group (hereinafter referred to as compound group SX62).
In Formula (L-3), A ¹ is a nitrogen atom, G is a 1-cyanocyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. Compound (hereinafter referred to as Compound Group SX63).
In Formula (L-3), A ¹ is a nitrogen atom, G is a 2,2-difluorocyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. A certain compound (hereinafter referred to as compound group SX64).
In Formula (L-3), A ¹ is a nitrogen atom, G is a 2- (4-fluorophenyl) cyclopropyl group, and T is any one of [Table 1] to [Table 6] A compound which is a substituent (hereinafter referred to as compound group SX65).
In formula (L-3), a compound wherein A ¹ is a nitrogen atom, G is a cyclobutyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter, (Referred to as compound group SX66).
In Formula (L-3), A ¹ is a nitrogen atom, G is a 1-cyanocyclobutyl group, and T is any substituent described in [Table 1] to [Table 6]. Compound (hereinafter referred to as Compound Group SX67).
In formula (L-3), a compound wherein A ¹ is a nitrogen atom, G is a cyclopentyl group, and T is any one of the substituents described in Table 1 to Table 6, Compound group SX68).
In the formula (L-3), compounds wherein A ¹ is a nitrogen atom, G is a 1-cyanocyclopentyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (Hereinafter referred to as compound group SX69).
In formula (L-3), a compound wherein A ¹ is a nitrogen atom, G is a cyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6 (hereinafter, (Referred to as compound group SX70).
In the formula (L-3), compounds wherein A ¹ is a nitrogen atom, G is a 1-cyanocyclohexyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (Hereinafter referred to as compound group SX71).
In the formula (L-3), A ¹ is a nitrogen atom, G is a 4,4-difluorocyclohexyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. Compound (hereinafter referred to as Compound Group SX72).

Formula (L-4):
Wherein A ¹ is CH, G is a cyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter referred to as compound group). SX73).
In Formula (L-4), A ¹ is CH, G is a 1- (trifluoromethyl) cyclopropyl group, and T is any substituent described in Table 1 to Table 6. A compound (hereinafter referred to as compound group SX74).
In the formula (L-4), compounds wherein A ¹ is CH, G is a 1-cyanocyclopropyl group, and T is any one of the substituents described in Table 1 to Table 6. (Hereinafter referred to as compound group SX75).
In Formula (L-4), A ¹ is CH, G is a 2,2-difluorocyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. Compound (hereinafter referred to as Compound Group SX76).
In Formula (L-4), A ¹ is CH, G is a 2- (4-fluorophenyl) cyclopropyl group, and T is any one of the substitutions described in [Table 1] to [Table 6] A compound which is a group (hereinafter referred to as compound group SX77).
In formula (L-4), a compound wherein A ¹ is CH, G is a cyclobutyl group, and T is any one of the substituents described in Table 1 to Table 6 (hereinafter referred to as compound (Indicated as group SX78).
In the formula (L-4), compounds wherein A ¹ is CH, G is a 1-cyanocyclobutyl group, and T is any one of the substituents described in Table 1 to Table 6. (Hereinafter referred to as compound group SX79).
In the formula (L-4), a compound wherein A ¹ is CH, G is a cyclopentyl group, and T is any one of the substituents described in Table 1 to Table 6 (hereinafter referred to as compound (Indicated as group SX80).
In the formula (L-4), compounds wherein A ¹ is CH, G is a 1-cyanocyclopentyl group, and T is any one of the substituents described in Table 1 to Table 6. Hereinafter, this is referred to as compound group SX81).
In the formula (L-4), a compound wherein A ¹ is CH, G is a cyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6 (hereinafter referred to as compound This is referred to as group SX82).
In the formula (L-4), compounds wherein A ¹ is CH, G is a 1-cyanocyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6. Hereinafter referred to as compound group SX83).
In the formula (L-4), A ¹ is CH, G is a 4,4-difluorocyclohexyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. Compound (hereinafter referred to as compound group SX84).
In the formula (L-4), a compound wherein A ¹ is a nitrogen atom, G is a cyclopropyl group, and T is any one of the substituents described in Table 1 to Table 6 below And referred to as Compound Group SX85).
In Formula (L-4), A ¹ is a nitrogen atom, G is a 1- (trifluoromethyl) cyclopropyl group, and T is any one of the substitutions described in [Table 1] to [Table 6] A compound which is a group (hereinafter referred to as compound group SX86).
In Formula (L-4), A ¹ is a nitrogen atom, G is a 1-cyanocyclopropyl group, and T is any substituent described in [Table 1] to [Table 6]. Compound (hereinafter referred to as compound group SX87).
In Formula (L-4), A ¹ is a nitrogen atom, G is a 2,2-difluorocyclopropyl group, and T is any one of the substituents described in [Table 1] to [Table 6]. A certain compound (hereinafter referred to as compound group SX88).
In Formula (L-4), A ¹ is a nitrogen atom, G is a 2- (4-fluorophenyl) cyclopropyl group, and T is any one of [Table 1] to [Table 6] A compound which is a substituent (hereinafter referred to as compound group SX89).
In formula (L-4), a compound wherein A ¹ is a nitrogen atom, G is a cyclobutyl group, and T is any one of the substituents described in Table 1 to Table 6, (Referred to as compound group SX90).
In Formula (L-4), A ¹ is a nitrogen atom, G is a 1-cyanocyclobutyl group, and T is any substituent described in [Table 1] to [Table 6]. Compound (hereinafter referred to as Compound Group SX91).
In formula (L-4), a compound wherein A ¹ is a nitrogen atom, G is a cyclopentyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter, (Referred to as compound group SX92).
In the formula (L-4), compounds wherein A ¹ is a nitrogen atom, G is a 1-cyanocyclopentyl group, and T is any substituent described in [Table 1] to [Table 6] (Hereinafter referred to as compound group SX93).
In the formula (L-4), a compound wherein A ¹ is a nitrogen atom, G is a cyclohexyl group, and T is any one of the substituents described in [Table 1] to [Table 6] (hereinafter, (Referred to as compound group SX94).
In the formula (L-4), compounds wherein A ¹ is a nitrogen atom, G is a 1-cyanocyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6. (Hereinafter referred to as compound group SX95).
In Formula (L-4), A ¹ is a nitrogen atom, G is a 4,4-difluorocyclohexyl group, and T is any one of the substituents described in Table 1 to Table 6. Compound (hereinafter referred to as Compound Group SX96).

In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is Py ² , and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX97)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 3-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX98)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 4-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX99)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 5-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX100)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 6-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX101)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 3-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX102)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 4-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX103)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 5-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX104)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 6-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX105)
In formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 3-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX106)
In formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 4-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX107)
In formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 5-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX108)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 6-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. A compound having any one of the substituents described below (hereinafter referred to as compound group SX109)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 3-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX110)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 4-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX111)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 5-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX112)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 6-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX113)

In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is Py 3, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX114)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 2-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX115)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 4-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX116)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 5-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX117)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 6-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX118)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 2-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX119)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 4-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX120)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 5-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX121)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 6-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX122)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 2-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX123)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 4-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX124)
In formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 5-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX125)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 6-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX126)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 2-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX127)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 4-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX128)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 5-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX129)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 6-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX130)

In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is Py 4, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX131)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 3-Me-Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX132)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 2-Me-Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX133)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 3-Cl—Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX136)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 2-Cl—Py 4, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX137)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 3-CF ₃ —Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX140)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 2-CF ₃ —Py 4, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX141)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 3-OMe-Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX144)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 2-OMe-Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX145)

In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py ² , and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX148)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Me-Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX149)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX150)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX151)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX152)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX153)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX154)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX155)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX156)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX157),
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or any one of the substituents described below (hereinafter referred to as compound group SX158)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX159),
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX160),
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX161)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX162)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX163)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX164)

In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py 3, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX165)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Me-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX166)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Me-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX167)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Me-Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX168)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Me-Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX169)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX170)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. A compound having any one of the substituents described below (hereinafter referred to as compound group SX171)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX172)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. A compound having any one of the substituents described below (hereinafter referred to as compound group SX173)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX174),
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or any one of the substituents described below (hereinafter referred to as compound group SX175)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX176),
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX177),
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX178)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX179)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX180)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX181)

In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py 4, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX182)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Me-Py 4, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX183)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Me-Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX184)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Cl—Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX187)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Cl—Py 4, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX188)
Compound wherein G is —O—G ² , G ² is 3-CF ₃ —Py4, and T is any of the substituents described in [Table 1] to [Table 6] (hereinafter referred to as “compound”) (Indicated as group SX191)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-CF ₃ —Py 4, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX192),
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-OMe-Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX195)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-OMe-Py 4, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX196)

In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is Py ² , and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX199)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 3-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX200)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 4-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX201)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 5-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX202)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 6-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX203)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 3-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX204)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 4-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX205)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 5-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX206)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 6-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX207)
In formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 3-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX208)
In formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 4-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX209)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 5-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX210)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 6-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX211)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 3-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX212)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 4-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX213)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 5-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX214)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 6-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX215)

In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is Py 3, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX216)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 2-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX217)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 4-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX218)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 5-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX219)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 6-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX220)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 2-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX221)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 4-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX222)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 5-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX223)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 6-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX224)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 2-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX225)
In formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 4-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX226)
In formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 5-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX227)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 6-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX228)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 2-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX229)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 4-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX230)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 5-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX231)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 6-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX232)

In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is Py 4, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX233)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 3-Me-Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX234)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 2-Me-Py 4, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX235)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 3-Cl—Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX238)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 2-Cl—Py 4, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX239)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 3-CF ₃ —Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX242)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 2-CF ₃ —Py 4, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX243)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 3-OMe-Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX246)
In Formula (L-2), A ¹ is CH, G is —O—G ² , G ² is 2-OMe-Py 4, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX247)

In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py ² , and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX250)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX251)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX252)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX253)
In formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX254)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX255)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX256)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX257)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX258)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX259),
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX260),
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or any one of the substituents described below (hereinafter referred to as compound group SX261)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX262),
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX263)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX264)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX265)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX266)

In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py 3, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX267)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Me-Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX268)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Me-Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX269)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Me-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX270)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Me-Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX271)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX272)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX273)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX274)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX275)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX276),
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX277),
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX278), which is any of the substituents described in
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or any one of the substituents described below (hereinafter referred to as compound group SX279)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX280)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX281)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX282)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX283)

In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py 4, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX284)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Me-Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX285)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Me-Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX286)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Cl—Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX289)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Cl—Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX290)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-CF ₃ —Py 4, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX293),
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-CF ₃ —Py 4, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX294),
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-OMe-Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX297)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-OMe-Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX298)

In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is Py ² , and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX301)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 3-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX302)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 4-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX303)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 5-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX304)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 6-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX305)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 3-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX306)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 4-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX307)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 5-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX308)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 6-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX309)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 3-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX310)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 4-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX311)
In formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 5-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX312)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 6-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX313)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 3-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX314)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 4-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX315)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 5-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX316)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 6-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX3171)

In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is Py 3, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX318)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 2-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX318)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 4-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX319)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 5-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX320)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 6-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX321)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 2-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX322)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 4-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX323)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 5-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX324)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 6-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX325)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 2-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX326)
In formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 4-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX327)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 5-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX328)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 6-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX329)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 2-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX330)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 4-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX331)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 5-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX332)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 6-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX333)

In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is Py 4, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX334)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 3-Me-Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX335)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 2-Me-Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX336)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 3-Cl—Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX339)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 2-Cl—Py 4, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX340)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 3-CF ₃ —Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX343)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 2-CF ₃ —Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX344)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 3-OMe-Py 4, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX347)
In Formula (L-3), A ¹ is CH, G is —O—G ² , G ² is 2-OMe-Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX348)

In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py ² , and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX351)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX352)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Me-Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX353)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Me-Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX354)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX355)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX356)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX357)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX358)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX359)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX360), which is any of the substituents described in
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX361),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX362),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX363), which is any of the substituents described in
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX364)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX365)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX366)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX367)

In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py 3, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX368),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Me-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX369)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Me-Py 3, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX370)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Me-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX371)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Me-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX372)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX373)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX374)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. Compounds which are any of the substituents described below (hereinafter referred to as compound group SX375)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX376)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX377), which is any of the substituents described in
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX378),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or any one of the substituents described below (hereinafter referred to as compound group SX379)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX380),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX381)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX382)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX383)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX384)

In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py 4, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX385)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Me-Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX386)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Me-Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX387)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Cl—Py 4, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX390)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Cl—Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX391)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-CF ₃ —Py 4, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX394),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-CF ₃ —Py 4, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX395),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-OMe-Py 4, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX398)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-OMe-Py 4, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX399)

In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is Py ² , and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX402)
In formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 3-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX403)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 4-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX404)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 5-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX405)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 6-Me-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX406)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 3-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX407)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 4-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX408)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 5-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX409)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 6-Cl—Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX410)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 3-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX411)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 4-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX412)
In formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 5-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX413)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 6-CF ₃ —Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX414)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 3-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX415)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 4-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX416)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 5-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX417)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 6-OMe-Py 2, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX418)

In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is Py 3, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX419)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 2-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX420)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 4-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX421)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 5-Me-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX422)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 6-Me-Py 3, and T is described in [Table 1] to [Table 6]. A compound having any one of the substituents (hereinafter referred to as compound group SX423)
In the formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 2-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX424)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 4-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX425)
In the formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 5-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX426)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 6-Cl—Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX427)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 2-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX428)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 4-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX429)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 5-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX430)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 6-CF ₃ —Py ₃ , and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX431)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 2-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX432)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 4-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX433)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 5-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX434)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 6-OMe-Py 3, and T is described in [Table 1] to [Table 6]. Or any of the above-mentioned substituents (hereinafter referred to as compound group SX435)

In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is Py 4, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX436)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 3-Me-Py 4, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX437)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 2-Me-Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX438)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 3-Cl—Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX441)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 2-Cl—Py 4, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX442)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 3-CF ₃ —Py4, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX445)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 2-CF ₃ —Py4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX446)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 3-OMe-Py 4, and T is described in [Table 1] to [Table 6]. Or any one of the substituents (hereinafter referred to as compound group SX449)
In Formula (L-4), A ¹ is CH, G is —O—G ² , G ² is 2-OMe-Py 4, and T is described in [Table 1] to [Table 6]. Or any of the substituents (hereinafter referred to as compound group SX450)

In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py ² , and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX453),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX454)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX455)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX456)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Me-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX457)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX458)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX459)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX460)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Cl—Py 2, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX461)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX462),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX463),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX464),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-CF ₃ —Py 2, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX465),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX466)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX467)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX468)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-OMe-Py 2, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX469)

In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py 3, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX470)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Me-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX471)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Me-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX472)
In formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Me-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX473)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Me-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX474)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX475)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX476)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. Any of the substituents described above, a compound (hereinafter referred to as compound group SX477) /
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-Cl—Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX478)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX479), which is any of the substituents described in
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or any of the substituents described in the above (hereinafter referred to as compound group SX480)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or any one of the substituents described below (hereinafter referred to as compound group SX481)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-CF ₃ —Py ₃ , and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX482),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX483)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound having any one of the substituents described below (hereinafter referred to as compound group SX484)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX485)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6-OMe-Py 3, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX486)

In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is Py 4, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX487)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Me-Py 4, and T is defined in [Table 1] to [Table 6]. A compound that is any of the substituents described below (hereinafter referred to as compound group SX488)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Me-Py 4, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX489)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-Cl—Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX492)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-Cl—Py 4, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described below (hereinafter referred to as compound group SX493)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-CF ₃ —Py 4, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX496),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-CF ₃ —Py 4, and T is [Table 1] to [Table 6]. Or a compound (hereinafter referred to as compound group SX497),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3-OMe-Py 4, and T is defined in [Table 1] to [Table 6]. Any one of the substituents described above (hereinafter referred to as compound group SX500)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2-OMe-Py 4, and T is defined in [Table 1] to [Table 6]. A compound which is any of the substituents described below (hereinafter referred to as compound group SX501)

In the present specification, 1G to 39G represent the substituents described in [Table 7] to [Table 9].

In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 1 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX504)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 2G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX505)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 3G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX506)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 4G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX507)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 5G, and T is any one of [Table 1] to [Table 6] Compounds that are substituents (hereinafter referred to as compound group SX508)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 6G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX509)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 7 G, and T is any one of [Table 1] to [Table 6] A compound that is a substituent (hereinafter referred to as compound group SX510)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 8 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX511)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 9G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX512)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 10 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX513)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 11 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX514)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 12 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX515)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 13 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX516)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 14 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX517)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 15 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX518)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 16 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX519)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 17 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX520)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 18 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX521)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 19 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX522)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 20 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX523)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 21 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX524)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 22 G, and T is any one of [Table 1] to [Table 6] A compound which is a substituent (hereinafter referred to as compound group SX525)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 23 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX526)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 24 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX527)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 25 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX528)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 26 G, and T is any one of [Table 1] to [Table 6] Compounds that are substituents (hereinafter referred to as Compound Group SX529)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 27 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX530)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 28 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX531)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 29 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX532)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 30 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX533)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 31 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX534)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 32 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX535)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 33 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX536)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 34 G, and T is any one of [Table 1] to [Table 6] Compounds that are substituents (hereinafter referred to as compound group SX537)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 35 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX538)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 36 G, and T is any one of [Table 1] to [Table 6] Compounds that are substituents (hereinafter referred to as compound group SX539)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 37 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX540)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 38 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX541)
In Formula (L-1), A ¹ is CH, G is —O—G ² , G ² is 39 G, and T is any one of [Table 1] to [Table 6] Compound which is a substituent (hereinafter referred to as compound group SX542)

In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 1G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX543)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX544)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX545)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX546)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX547)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX548)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 7 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX549)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 8G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX550)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 9G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX551)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 10 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX552)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 11 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX553)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 12 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX554)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 13 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX555)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 14 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX556)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 15 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX557)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 16 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX558)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 17 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX559)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 18 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX560)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 19 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX561)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 20 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX562)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 21 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX563)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 22 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX564)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 23 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX565)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 24 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX566)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 25 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX567)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 26 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX568)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 27 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX569)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 28 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX570)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 29 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX571)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 30 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX572)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 31 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX573)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 32 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX574)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 33 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX575)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 34 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX576)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 35 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX577)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 36 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX578)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 37 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX579)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 38 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX580)
In Formula (L-1), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 39 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX581)

In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 1G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX582)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX583)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3G, and T is any one of [Table 1] to [Table 6]. A compound which is a substituent of (hereinafter referred to as compound group SX584)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX585)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX586)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX587)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 7G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX588)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 8G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX589)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 9G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX590)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 10 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX591)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 11 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX592)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 12 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX593)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 13 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX594)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 14 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX595)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 15 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX596)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 16 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX597)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 17 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX598),
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 18 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX599)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 19 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX600)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 20 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX601)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 21 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX602)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 22 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX603)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 23 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX604)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 24 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX605)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 25 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX606)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 26 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX607)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 27 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX608)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 28 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX609)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 29 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX610)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 30 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX611)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 31 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX612)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 32 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX613),
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 33 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX614)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 34 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX615)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 35 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX616)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 36 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX617)
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 37 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX618),
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 38 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX619),
In Formula (L-2), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 39 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX620)

In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 1G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX621)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX622),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX623)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX624)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX625)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX626),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 7 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX627)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 8G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX628)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 9G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX629)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 10 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX630)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 11 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX631)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 12 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX632),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 13 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX633)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 14 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX634)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 15 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX451)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 16 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX452)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 17 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX490)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 18 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX491)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 19 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX494)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 20 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX495)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 21 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX498)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 22 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX499)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 23 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX502)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 24 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX503)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 25 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX134)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 26 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group S135)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 27 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX138)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 28 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX139)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 29 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX142)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 30 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX143)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 31 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX146),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 32 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX147)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 33 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX185)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 34 G, and T is any one of [Table 1] to [Table 6]. A compound which is a substituent of (hereinafter referred to as compound group SX186)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 35 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX189),
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 36 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX190)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 37 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX193)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 38 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX194)
In Formula (L-3), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 39 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX197)

In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 1G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX198)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 2G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX236),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 3G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX237)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 4G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX240)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 5G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX241)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 6G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX244)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 7 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX245)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 8G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX248),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 9G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX249)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 10 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX287)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 11 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX288)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 12 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX291),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 13 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX292),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 14 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX295),
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 15 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX296)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 16 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX299)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 17 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX300)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 18 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX337)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 19 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX338)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 20 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX341)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 21 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX342)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 22 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX345)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 23 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX346)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 24 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX349)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 25 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX350)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 26 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX388)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 27 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX389)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 28 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX392)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 29 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX393)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 30 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX396)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 31 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX397)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 32 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX400)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 33 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX401)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 34 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX439)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 35 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX440)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 36 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX443)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 37 G, and T is any one of [Table 1] to [Table 6]. A compound that is a substituent of (hereinafter referred to as compound group SX444)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 38 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX447)
In Formula (L-4), A ¹ is a nitrogen atom, G is —O—G ² , G ² is 39 G, and T is any one of [Table 1] to [Table 6]. A compound (hereinafter referred to as compound group SX448)

This compound comprises the following groups (a), (b), (c), (d), (e), (f), (g), (h), (i) and One or more components selected from the group consisting of group (j) (hereinafter referred to as this component) can be used in combination or in combination.
The mixed or combined means that the present compound and the present component are used simultaneously, separately or at intervals.
When using this compound and this component simultaneously, this compound and this component may be contained in the respectively separate formulation, and may be contained in one formulation.
One aspect of the present invention is that group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h) group (i) ) And one or more components selected from the group consisting of group (j) (that is, the present component), and a composition containing the present compound (hereinafter referred to as composition A).

Group (a) includes acetylcholinesterase inhibitors (eg carbamate insecticides, organophosphorus insecticides), GABAergic chloride channel antagonists (eg phenylpyrazole insecticides), sodium channel modulators (eg pyrethroid insecticides) ), Nicotinic acetylcholine receptor antagonist modulators (eg, neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamatergic chloride channel allosteric modulators (eg, macrolide insecticides),
Juvenile hormone mimic, multi-site inhibitor, stringed organ TRPV channel modulator, mite growth inhibitor, mitochondrial ATP biosynthesis enzyme inhibitor, oxidative phosphorylation uncoupler, nicotinic acetylcholine receptor channel blocker (eg, nelice) Toxin insecticides), chitin synthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, inhibitors of mitochondrial electron transport complex I, II, III and IV, voltage-dependent sodium channel blockers, acetyl This group consists of CoA carboxylase inhibitors, ryanodine receptor modulators (eg, diamide insecticides), stringed organ modulators, microbial insecticides, and other insecticidal, acaricidal and nematicidal active ingredients. These are described in the classification based on the mechanism of action of IRAC.

  Group (b) includes nucleic acid synthesis inhibitors (eg, phenylamide fungicides, acylamino acid fungicides), cell division and cytoskeleton inhibitors (eg, MBC fungicides), respiratory inhibitors (eg, QoI fungicides) , QiI fungicides), amino acid synthesis and protein synthesis inhibitors (eg, anilinopyridine fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (eg, triazoles) Bactericides), cell wall synthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multi-acting contact active bactericides, microbial bactericides, and other bactericidal active ingredients. These are described in the classification based on the mechanism of action of FRAC.

  Group (c) is a group of plant growth regulating components.

  Group (d) is a group of phytotoxicity reducing components.

  Group (e) is a group of synergists.

  Group (f) is a group of repellent components comprising bird repellent components, insect repellent components and animal repellent components.

  Group (g) is a group of molluscicidal components.

  Group (h) is a group of insect pheromones.

  Group (i) includes acetyl-CoA carboxylase (ACCase) inhibitor, acetolactate synthase (ALS) inhibitor, photosynthesis (photosystem II) inhibitor, photosystem I electron conversion agent, protoporphyrinogen oxidase (PPO) Inhibitor, phytoene desaturase system (PDS) inhibitor, 4-hydroxyphenylpyruvate dioxygenase (4-HPPD) inhibitor, carotenoid biosynthesis inhibitor, EPSP synthase inhibitor, glutamine synthetase inhibitor, dihydroptero Inacid (DHP) synthase inhibitor, microtubule polymerization inhibitor, mitosis / microtubule formation inhibitor, inhibitor of very long chain fatty acid (VLCFA), cellulose synthesis inhibitor, uncoupling agent, lipid synthesis inhibitor , An indole acetic acid-like active agent, an auxin transfer inhibitor, and other herbicidal active ingredients. These are described in the classification based on the mechanism of action of HRAC.

  Group (j) is a microorganism having a pest control effect (for example, insecticidal activity, acaricidal activity, nematicidal activity, bactericidal activity, herbicidal activity, etc.) or a plant growth regulating effect such as rhizobia or mycorrhizal fungi A group of materials.

Below, the example of the combination of this component and this compound is described. For example, alanycarb + SX means a combination of alanycarb and SX.
The abbreviation for SX means any one of the present compounds selected from the compound groups SX1 to SX448. In addition, all of the components described below are known components, and can be obtained from commercially available preparations or produced by known methods. If this component is a microorganism, it can also be obtained from a fungus depository. The numbers in parentheses represent CAS RN (registered trademark).

Combination of this component of the above group (a) and this compound:
Abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acetoprole + SX, acrinathrin + SX, acinathyr + acynonapyr Afidopyropen + SX, afoxolaner + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha endosulfan (alpha) -endosulfan) + SX, aluminum phosphide + SX, amitraz + SX, azadirachtin + SX, azamethiphos + SX, azinphos-ethyl + SX, azinphos- methyl) + SX, azocyclotin + SX, Celastrus angulatus bark of bark of Celastrus angulatus + SX, bendiocarb + SX, benful Benfluthrin + SX, benfuracarb + SX, bensultap + SX, benzoximate + SX, benzpyrimoxan + SX, beta-cyfluthrin + SX , Beta-cypermethrin + SX, bifenazate + SX, bifenthrin + SX, bioallethrin + SX, bioresmethrin + SX, bistrifluron + SX , Borax + SX, boric acid + SX, broflanilide + SX, bromopropylate + SX, buprofezin + SX, butocarboxim + SX, Butoxycarboxim + SX, cadusafos + SX, calcium phosphide + SX, carbaryl + SX, carbofuran + SX, carbosulfan + SX, L-tap hydrochloride + SX, cartap + SX, chinomethionat + SX, chlorantraniliprole + SX, chlordane + SX, chlorethoxyfos + SX, chlorfenapyr (chlorfenapyr) + SX, chlorfenvinphos + SX, chlorfluazuron + SX, chlormephos + SX, chlorpicrin + SX, chlorpyrifos + SX, chlorpyrifos methyl ( chlorpyrifos-methyl) + SX, chromafenozide + SX, clofentezine + SX, clothianidin + SX, concanamycin A + SX, coumaphos + SX, cryolite ( cryolite) + SX, cyanophos + SX, cyanantaniprole + SX, cycloniliprole + SX, siku Cycloprothrin + SX, cycloxaprid + SX, cyenopyrafen + SX, cyflumetofen + SX, cyfluthrin + SX, cyhalodiamide + SX, cyhalothrin + cySX (cyhexatin) + SX, cypermethrin + SX, cyphenothrin + SX, cyromazine + SX, dazomet + SX, deltamethrin + SX, demeton-S-methyl (demeton) -S-methyl) + SX, diafenthiuron + SX, diazinon + SX, dichlorvos + SX, dicloromezotiaz, dicohol + SX, dicrotophos ) + SX, diflovidazin + SX, diflubenzuron + SX, dimefluthrin + SX, dimethoate + SX, dimethylvinphos (dime) thylvinphos + SX, dinotefuran + SX, disodium octaborate + SX, disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, doramectin + SX, dried leaves of Dryopteris filix-mas + SX, emamectin benzoate + SX, empenthrin + SX, endosulfan + SX, EPN (O-ethyl) O- (4-nitrophenyl) phenylphosphonothioate) + SX, epsilon-metofluthrin + SX, epsilon-momfluorothrin + SX, esfenvalerate + SX, ethiofencarb + SX, ethion + SX, ethiprole + SX, ethoprophos + SX, etofenprox + SX, etoxazole + SX, extract of Artemisia absinthium + SX , Ca ssia nigricans extract (extract of Cassia nigricans) + SX,
Extract of clitoria ternatea + SX, extract of Symphytum officinale + SX, extract or simulated blend of Chenopodium ambrosioides + SX, extract of Tanacetum vulgare ) + SX, extract of Urtica dioica + SX, extract of Viscum album + SX, famphur + SX, fenamiphos + SX, fenazaquin + SX , Fenbutatin oxide + SX, fenitrothion + SX, fenobucarb + SX, phenoxycarb + SX, fenpropathrin + SX, fenpyroximate + SX, fenthionate fenthion) + SX, fenvalerate + SX, fipronil + SX, flometoquin + SX, flonicamid + SX, fluar Lipiprim (fluacrypyrim) + SX, fluazaindolizine + SX, fluazuron + SX, flubendiamide + SX, flucycloxuron + SX, flucythrinate + SX , Fluensulfone + SX, flufenprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin + SX, flupyradifurone + SX, Flupyrimin + SX, fluralaner + SX, fluvalinate + SX, fluxametamide + SX, formetanate + SX, fosthiazate + SX, furamethrin + SX, furamethrin Furathiocarb + SX, gamma-cyhalothrin + SX, GS-omega / kappa HXTX-Hv1a peptide (GS-omega / kappa HXTX-Hv1a peptide) + SX, c Lufenprox + SX, halofenozide + SX, heptafluthrin + SX, heptenophos + SX, hexaflumuron + SX, hexythiazox + SX, hop beta Potassium salt of hop beta acid + SX, hydramethylnon + SX, hydroprene + SX, imiciafos + SX, imidacloprid + SX, imiprothrin + SX, indoxacarb + SX, isocycloseram + SX, isofenphos + SX, isoprocarb + SX, isopropyl O- (methoxyaminothiophosphoryl) salicylate (isopropyl-O- ( methoxyaminothiophosphoryl) salicylate) + SX, isoxathion + SX, ivermectin + SX, kadethrin + SX, kappa (kappa-tefluthrin) + SX, kappa-bifenthrin + SX, kinoprene + SX, lambda-cyhalothrin + SX, lenoremycin + SX, lepimectin + SX , Lime sulfur + SX, lotilaner + SX, lufenuron + SX, machine oil + SX, malathion + SX, mecarbam + SX, meperfluthrin (meperfluthrin) + SX, metaflumizone + SX, metam + SX, metamidophos + SX, methidathion + SX, methiocarb + SX, methomyl + SX, methoprene (SX) methoprene) + SX, methoxychlor + SX, methoxyfenozide + SX, methyl bromide + SX, metofluthrin + SX, metolcarb + SX, metoxadiazone + SX, Me Vinphos + SX, milbemectin + SX, milbemycin oxime + SX, momfluorothrin + SX, monocrotophos + SX, moxidectin + SX, nared ) + SX, neem oil + SX, nicotine + SX, nicotine-sulfate + SX, nitenpyram + SX, novaluron + SX, noviflumuron + SX , Oil of the seeds of Chenopodium anthelminticum + SX, omethoate + SX, oxamyl + SX, oxazosulfyl + SX, oxydemeton-methyl + SX, parathion + SX, parathion-methyl + SX, permethrin + SX, phenothrin + SX, phenthoate + SX, phorate + SX, hostal ( ph osalone) + SX, phosmet + SX, phosphamidon + SX,
Phosphine + SX, phoxim + SX, pirimicarb + SX, pirimiphos-methyl + SX, prallethrin + SX, profenfos + SX, profluthrin + SX , Propargite + SX, propetamphos + SX, propoxur + SX, propylene glycol alginate + SX, prothiofos + SX, pyflubumide + SX, pymetrozine ( pymetrozine + SX, pyraclofos + SX, pyrethrin (pyrethrins) + SX, pyridaben + SX, pyridaphenthion + SX, pyriflutinazone (pyrifluquin) ) + SX, pyriminostrobin + SX, pyriprole + SX, pyriproxyfen + SX, quinal Quinalphos + SX, resmethrin + SX, rotenone + SX, ryanodine + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate + SX, sodium metaborate + SX, spinetoram + SX, spinosad + SX, spirodiclofen + SX, spiromesifen + SX, spiropidion + SX, spirotetramat + SX, sulfluramid + SX, sulfotep + SX, sulfoxaflor + SX, sulfur (sulfur) + SX, sulfuryl fluoride + SX, tartar emetic + SX, tau-fluvalinate + SX, tebufenozide + SX, tebufenpyrad + SX, tebupirimfos + SX, teflubenzuron + SX, tefluthrin + SX, temephos + SX, terbufos + SX, terpene constituents of the extract of chenopodium ambrosioides near ambrosioides, Brand name: Terpenoid blend QRD 460) + SX, tetrachlorantraniliprole + SX, tetrachlorvinphos + SX, tetradifon + SX, tetramethrin + SX, tetramethylfluthrin + SX, tetraniliprole + SX, theta-cypermethrin + SX, thiacloprid + SX, thiamethoxam + SX, cyclam thioam ) + SX, thiodicarb + SX, thiofanox + SX, thiometon + SX, thiosulta Thiosultap-disodium + SX, thiosultap-monosodium + SX, tioxazafen + SX, tolfenpyrad + SX, tralomethrin + SX, transfluthrin ) + SX, triazamate + SX, triazophos + SX, trichlorfon + SX, triflumezopyrim + SX, triflumuron + SX, trimethacarb + SX, trimethacarb Tyclopyrazoflor + SX, vamidion + SX, wood extract of Quassia amara + SX, XMC (3,5-dimethylphenyl N-methylcarbamate) + SX, xylylcarb + SX , Zeta-cypermethrin + SX, zinc phosphide + SX, N- [3-chloro-1- (pyridin-3-yl) -1H-pyrazole- 4-yl] -N-ethyl-3- (3,3,3-trifluoropropanesulfinyl) propanamide (1477923-37-7) + SX, 4- [5- (3,5-dichlorophenyl) -5 (Trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl] -2-methyl-N- (1-oxothietan-3-yl) benzamide (1241050-20-3) + SX, 3 -Methoxy-N- (5- {5- (trifluoromethyl) -5- [3- (trifluoromethyl) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} indan-1- Yl) propanamide (1118626-57-5) + SX, N- [2-bromo-6-chloro-4- (1,1,1,2,3,3,3-heptafluoropropan-2-yl) Phenyl] -3- {ethyl [(pyridin-4-yl) carbonyl] amino} -2- Toxibenzamide (1429513-53-0) + SX, N- [2-Bromo-6-chloro-4- (1,1,1,2,3,3,3-heptafluoropropan-2-yl) phenyl] -3- [Ethyl (4-cyanobenzoyl) amino] -2-methoxybenzamide (1609007-65-9) + SX, N- [2-bromo-6-difluoromethoxy-4- (1,1,1,2) , 3,3,3-heptafluoropropan-2-yl) phenyl] -3- {methyl [(pyridin-4-yl) carbonyl] amino} -2-methoxybenzamide (1630969-78-6) + SX, 1 -{2-Fluoro-4-methyl-5-[(2,2,2-trifluoroethyl) sulfinyl] phenyl} -3- (trifluoromethyl) -1H-1,2,4-triazol-5-amine (885026-50-6) + SX, BT crop protein Cry1Ab + SX, BT crop protein Cry1Ac (BT crop protein Cry1Ac) + SX, BT crop protein Cry1Fa (BT crop protein Cry1A) + SX, BT crop protein Cry1A.105 + SX, BT crop Protein Cry2Ab (BT crop protein Cry2Ab) + SX, BT crop protein Vip3A (BT crop protein Cry3A) + SX, BT crop protein mCry3A (BT crop protein Cry3Ab) + SX, BT crop protein Cry3Ab (BT crop protein Cry3Ab) ) + SX, BT crop protein Cry3Bb + SX, BT crop protein Cry34Ab1 / Cry35Ab1 (BT crop protein Cry34Ab1 / Cry35Ab1) + SX.

Combination of this component of the above group (b) and this compound:
Acibenzolar-S-methyl + SX, aldimorph + SX, ametoctradin + SX, aminopyrifen + SX, amisulbrom + SX, anilazine + SX, Azaconazole + SX, azoxystrobin + SX, basic copper sulfate + SX, benalaxyl + SX, benalaxyl-M + SX, benodanil + SX, benomyl + SX, benthiavalicarb + SX, benthivalicarb-isopropyl + SX, benzovindiflupyr + SX, binapacryl + SX, Biphenyl + SX, bitertanol + SX, bixafen + SX, blasticidin-S + SX, Bordeaux mixture + SX, boscalid + SX, bromotalonyl ( b romothalonil) + SX, bromuconazole + SX, bupirimate + SX, captafol + SX, captan + SX, carbendazim + SX, carboxin + SX, carpropamid + SX, chinomethionat + SX, chitin + SX, chloroneb + SX, chlorothalonil + SX, chlozolinate + SX, collochlorin B (colltochlorin B) ) + SX, copper (II) acetate + SX, copper (II) hydroxide + SX, copper oxychloride + SX, copper sulfate (II) ) (copper (II) sulfate) + SX, coumoxystrobin + SX, cyazofamid + SX, cyflufenamid + SX, cymoxanil + SX, cyproconazole + SX , Cyprodinil + SX, Diclobentiazox ) + SX, dichlofluanid + SX, dilocymet + SX, diclomezine + SX, dicloran + SX, dietofencarb + SX, difenoconazole + SX, difenoconazole diflumetorim) + SX, dimethachlone + SX, dimethirimol + SX, dimethomorph + SX, dimoxystrobin + SX, diniconazole + SX, diiconazole-M + SX, dinocap + SX, dipotassium hydrogenphosphite + SX, dipymetitrone + SX, dithianon + SX, dodecylbenzenesulphonic dodecylbenzenesulphonic acid (dodecylbenzenesulphonic) acid bisethylenediamine copper (II) salt) + SX, dodemorph + SX, dodine + SX, edifenphos + SX, e Xenostrobin + SX, epoxiconazole + SX, etaconazole + SX, ethaboxam + SX, ethirimol + SX, etridiazole + SX, tea tree extract from Melaleuca alternifolia) + SX, extract of reedoutria sachalinensis + SX, extract from cotyledons of lupine plantlets ("BLAD") + SX, extract of garlic Allium sativum) + SX, extract of Equisetum arvense + SX, extract of Tropaeolum majus + SX, famoxadone + SX, fenamidone + SX, fenaminstrobin ) + SX, fenarimol + SX, fenbuconazole, fenfuram + SX, fenhexamid + SX, phenoxanyl ( fenoxanil) + SX, fenpiclonil + SX, fenpicoxamid + SX, fenpropidin + SX, fenpropimorph + SX, fenpyrazamine + SX, triphenyl acetate Fentin acetate + SX, fentin chloride + SX, fentin hydroxide + SX, ferbam + SX, ferimzone + SX, florylpicoxamide (florylpicoxamid) + SX, fluazinam + SX, fludioxonil + SX, flufenoxystrobin + SX, fluindapyr + SX, flumorph + SX, fluopicolide + SX , Fluopyram + SX, fluopimomide + SX, fluoroimide + SX, fluoxastrobin + SX, fluquinconazole + SX, Flusilazole + SX, flusulfamide + SX, flutianil + SX, flutolanil + SX, flutriafol + SX, fluxapyroxad + SX, folpet ) + SX, fosetyl + SX, fosetyl-aluminium + SX, fuberidazole + SX, furalaxyl + SX, furametpyr + SX, guazatine + SX, hexa Hexaconazole + SX, hymexazole + SX, imazalil + SX, imibenconazole + SX,
Iminoctadine + SX, iminoctadine triacetate + SX, inpyrfluxam + SX, iodocarb + SX, ipconazole + SX, ipfentrifluconazole + ipfentrifluconazole , Ipflufenoquin + SX, iprobenfos + SX, iprodione + SX, iprovalicarb + SX, isofetamid + SX, isoflucypram + SX, isoflucypram isoprothiolane) + SX, isopyrazam + SX, isotianil + SX, kasugamycin + SX, kresoxim-methyl + SX, laminarin + SX, oak leaves and bark bark of Quercus) + SX, mancozeb + SX, mandestrobin + SX, mandipropamid + SX, maneb + SX, mefentrifluconazole + SX, mepanipyrim + SX, mepronil + SX, meptyldinocap + SX, metalaxyl + SX, metalaxyl-M ) + SX, metconazole + SX, methasulfocarb + SX, metiram + SX, meteminostrobin + SX, metrafenone + SX, methyltetraprole + SX, machine oil + SX, myclobutanil + SX, naftifine + SX, nuarimol + SX, octhilinone + SX, ofurace + SX, orysastrobin + SX, oxadixyl + SX, oxathiapiprolin + SX, oxine-copper + SX, oxolinic acid + SX, oxpoconazole + SX, ox Oxpoconazole fumarate + SX, oxycarboxin + SX, oxytetracycline + SX, pefurazoate + SX, penconazole + SX, pencycuron + SX, Penflufen + SX, penthiopyrad + SX, phenamacril + SX, phosphoric acid + SX, phthalide + SX, picarbutrazox + SX, picoxy Stroxybin + SX, piperalin + SX, polyoxins + SX, potassium hydrogencarbonate + SX, potassium dihydrogenphosphite + SX, probenazole + SX, prochloraz + SX, procymidone + SX, propamidine + SX, propamocarb + SX, propiconazole (pro piconazole) + SX, propineb + SX, proquinazid + SX, prothiocarb + SX, prothioconazole + SX, pydiflumetofen + SX, pyraclostrobin ) + SX, pyrametostrobin + SX, pyraoxystrobin + SX, pyrapropoyne + SX, pyraziflumid + SX, pyrazophos + SX, pyribencarb + SX , Pyributicarb + SX, pyridachlometyl + SX, pyrifenox + SX, pyrimethanil + SX, pyrimorph + SX, pyriophenone + SX, pyroxoxole ) + SX, pyroquilon + SX, Quillaja extract + SX, quinconazole + SX, quinofumelin + S X, quinoxyfen + SX, quintozene + SX, saponins of chenopodium quinoa + SX, sedaxane + SX, silthiofam + SX, simeconazole + SX, carbonic acid Sodium hydrogencarbonate + SX, spiroxamine + SX, streptomycin + SX, sulfur + SX, tebuconazole + SX, tebufloquin + SX, teclofthalam + SX Tecnazene + SX, terbinafine + SX, tetraconazole + SX, thiabendazole + SX, thifluzamide + SX, thiophanate + SX, thiophanate methyl ) + SX, thiram + SX, thymol + SX, thiadinyl + SX, tolclofos-methyl + SX, tolphe Tolfenpyrad + SX, tolprocarb + SX, tolylfluanid + SX, triadimefon + SX, triadimenol + SX, triazoxide + SX, triclopyrib triclopyricarb) + SX, tricyclazole + SX, triridemorph + SX, trifloxystrobin + SX, triflumizole + SX, triforine + SX, triticonazole ) + SX, validamycin + SX, valifenalate + SX, vinclozolin + SX, yellow mustard powder + SX, zinc thiazole + SX, zineb + SX, ziram (ziram) + SX, zoxamide + SX,
3- (Difluoromethyl) -N-methoxy-1-methyl-N-[(1R) -1-methyl-2- (2,4,6-trichlorophenyl) ethyl] pyrazole-4-carboxamide (1639015-48- 7) + SX, 3- (Difluoromethyl) -N-methoxy-1-methyl-N-[(1S) -1-methyl-2- (2,4,6-trichlorophenyl) ethyl] -1H-pyrazole- 4-carboxamide (1639015-49-8) + SX, 3- (difluoromethyl) -1-methyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) pyrazole -4-carboxamide (141573-94-6) + SX, 3- (difluoromethyl) -N-[(3R) -7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-indene- 4-yl] -1-methyl-1H-pyrazole-4-ca Boxamide (1513466-73-3) + SX, N ′-[4-({3-[(4-chlorophenyl) methyl] -1,2,4-thiadiazol-5-yl} oxy) -2,5-dimethyl Phenyl] -N-ethyl-N-methylmethanimidamide (1202781-91-6) + SX, 2- {3- [2- (1- {2- [3,5-bis (difluoromethyl) -1H- Pyrazol-1-yl] acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -3-chlorophenyl = methanesulfonate (1360819-11-9) + SX, 4- (2-Bromo-4-fluorophenyl) -N- (2-chloro-6-fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine ( 1362477-26-6) + SX, 2- [6- (3-Fluoro-4-methoxyphenyl) -5-methyl Tylpyridin-2-yl] quinazoline (1257056-97-5) + SX, 5-fluoro-2-[(4-methylphenyl) methoxy] pyrimidin-4-amine (1174376-25-0) + SX, 5-fluoro -4-Imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2 (1H) -one (1616664-98-2) + SX, N '-(2,5-dimethyl-4-phenoxyphenyl ) -N-ethyl-N-methylmethanimidamide (1052688-31-9) + SX, N '-{4-[(4,5-dichlorothiazol-2-yl) oxy] -2,5-dimethylphenyl } -N-ethyl-N-methylmethanimidamide (929908-57-6) + SX, (2Z) ethyl 3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl) methyl] -N-ethyl-6-methoxy-3-nitropyridine-2 Amine (1446247-98-8) + SX, α- [3- (4-Chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -4-isoxazolyl] -3-pyridinemethanol (1229605- 96-2) + SX, (αS)-[3- (4-chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -4-isoxazolyl] -3-pyridinemethanol (1229606-46- 5) + SX, (αR)-[3- (4-Chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -4-isoxazolyl] -3-pyridinemethanol (1229606-02-3) + SX, 2-{[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole- 3-thione (1342260-19-8) + SX, 2-{[(2R, 3S) -3- (2- Chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione (1638897-70-7) + SX , 2-{[(2S, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2, 4-Triazole-3-thione (1638897-71-8) + SX, 2-{[(2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxilan-2-yl ] Methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione (1638897-72-9) + SX, 2-{[(2S, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4 Dihydro-3H-1,2,4-triazole-3-thione (1638897-73-0) + SX, 1-{[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2 -Yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanate (1342260-26-7) + SX, 1-{[(2R, 3S) -3- (2-chlorophenyl) -2- (2,4-Difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanate (1638897-82-1) + SX, 1-{[(2S, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanato (1638897-84-3) + SX, 1-{[(2R, 3R) -3- (2-chlorophenyl) -2- (2 4-Difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanato (1638897-86-5) + SX, 1-{[(2S, 3S) -3- (2-Chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanate (1638897-89-8) + SX, 5 -(4-Chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1394057-11-4) + SX, (1R, 2S, 5S) -5- (4-Chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1801930-06-2) + SX, (1S, 2R, 5R) -5- (4-chlorobenzyl) 2-chloro-2-methyl-1- (IH-1,2,4-triazol-1-ylmethyl) cyclopentanol (1801930-07-3) + SX,
(1R, 2R, 5R) -5- (4-Chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1801919-53 -8) + SX, (1S, 2S, 5S) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclo Pentanol (1801919-54-9) + SX, (1R, 2R, 5S) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazole -1-ylmethyl) cyclopentanol (1801919-55-0) + SX, (1S, 2S, 5R) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1 , 2,4-Triazol-1-ylmethyl) cyclopentanol (1801919-56-1) + SX, ( R, 2S, 5R) -5- (4-Chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1801919-57- 2) + SX, (1S, 2R, 5S) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopent Tanol (1801919-58-3) + SX, methyl = 3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclo Pentanecarboxylate (1791398-02-1) + SX, methyl = (1R, 2S, 3S) -3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2, , 4-Triazol-1-ylmethyl) cyclopentane Ruboxylate (2080743-90-2) + SX, methyl = (1S, 2R, 3R) -3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4 -Triazol-1-ylmethyl) cyclopentanecarboxylate (2080743-91-3) + SX, methyl = (1R, 2R, 3R) -3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl- 2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanecarboxylate (2080743-92-4) + SX, methyl = (1S, 2S, 3S) -3-[(4-chlorophenyl) methyl ] -2-Hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanecarboxylate (2080743-93-5) + SX, methyl = (1R, 2R, 3S) -3-[(4-chlorophenyl ) Methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanecarboxylate (2080743-94-6) + SX, methyl = (1S, 2S, 3R) -3-[(4-Chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanecarboxylate (2080743-95-7) + SX, methyl = (1R, 2S, 3R) -3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclo Pentanecarboxylate (2081061-22-3) + SX, methyl = (1S, 2R, 3S) -3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2, , 4-Triazole-1-y Methyl) cyclopentanecarboxylate (2081061-23-4) + SX, 2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) ) Cyclopentanol (1394057-13-6) + SX, (1R, 2S, 5S) -2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2,4) -Triazol-1-ylmethyl) cyclopentanol (1801930-08-4) + SX, (1S, 2R, 5R) -2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H -1,2,4-triazol-1-ylmethyl) cyclopentanol (1801930-09-5) + SX, (1R, 2R, 5R) -2-chloromethyl-5- (4-fluorobenzyl) -2- Methyl-1- (1H-1,2,4-triazol-1-ilme L) Cyclopentanol (1638898-08-4) + SX, (1S, 2S, 5S) -2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2, 4-Triazol-1-ylmethyl) cyclopentanol (1638898-10-8) + SX, (1R, 2R, 5S) -2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- ( 1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1638898-13-1) + SX, (1S, 2S, 5R) -2-chloromethyl-5- (4-fluorobenzyl) -2 -Methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1638898-16-4) + SX, (1R, 2S, 5R) -2-chloromethyl-5- (4 -Fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazole-1-y Rumethyl) cyclopentanol (1638898-20-0) + SX, (1S, 2R, 5S) -2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2, 4-triazol-1-ylmethyl) cyclopentanol (1638898-24-4) + SX,
2- [2-Chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) pent-3-yn-2-ol + SX, (R) -2 -[2-Chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) pent-3-yn-2-ol (1801919-59-4) + SX , (R) -2- [4- (4-Chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol (1616236- 94-2) + SX, 1- [4- (4-Chlorophenoxy) -2- (trifluoromethyl) phenyl] -1-cyclopropyl-2- (1,2,4-triazol-1-yl) ethanol + SX, (R) -1- [4- (4-chlorophenoxy) -2- (trifluoromethyl) pheny ] -1-cyclopropyl-2- (1,2,4-triazol-1-yl) ethanol (1801919-60-7) + SX, (R) -2- [4- (4-chlorophenoxy) -2 -(Trifluoromethyl) phenyl] -3-methyl-1- (1,2,4-triazol-1-yl) butan-2-ol (1801919-61-8) + SX, methyl = ({2-methyl -5- [1- (4-Methoxy-2-methylphenyl) -1H-pyrazol-3-yl] phenyl} methyl) carbamate (1605879-98-8) + SX, 2- (difluoromethyl) -N- [ 1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] pyridine-3-carboxamide (1616239-21-4) + SX, 2- (difluoromethyl) -N-[(3R) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] pyridine- Carboxamide (1616239-33-8) + SX, 2- (difluoromethyl) -N- [3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl] pyridine-3- Carboxamide (1847460-02-9) + SX, 2- (difluoromethyl) -N-[(3R) -3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl] pyridine -3-carboxamide (1952305-97-3) + SX, 2- (difluoromethyl) -N- [3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl] pyridine- 3-carboxamide (1847460-05-2) + SX, 2- (difluoromethyl) -N-[(3R) -3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl Pyridine-3-carboxamide (1952306-00-1) + SX, (2E, 3Z) -5 {[1- (4-Chlorophenyl) -1H-pyrazol-3-yl] oxy} -2- (methoxyimino) -N, 3-dimethylpent-3-enamide (1445331-27-0) + SX.

Combination of this component of the above group (c) and this compound:
1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 2,3,5-triiodobenzoic acid + SX , IAA ((1H-indol-3-yl) acetic acid) + SX, IBA (4- (1H-indol-3-yl) butyric acid) + SX, MCPA (2- (4-chloro-2-methylphenoxy) acetic acid) + SX, MCPB (4- (4-chloro-2-methylphenoxy) butyric acid) + SX, 4-CPA (4-chlorophenoxyacetic acid) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anthymidol + SX, butralin + SX, calcium carbonate (calcium carbonate) + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + S X, chlormequat-chloride + SX, chloropropham + SX, choline chloride + SX, cloprop + SX, cyanamide + SX, cyclanilide ) + SX, daminozide + SX, decan-1-ol + SX, dichlorprop + SX, dikegulac + SX, dimethipin + SX, diquat ( diquat) + SX, ethephon + SX, etychlozate + SX, flumetralin + SX, flurprimidol + SX, forchlorfenuron + SX, formononetin + SX , Gibberellin A + SX, Gibberellin A3 + SX, Inabenfide + SX, Kinetin + SX, lipochitooligosaccharide SP104 + SX, Maleic hydrazide + SX, Difluide (mefluidide) + SX, mepiquat-chloride + SX, oxidized glutathione + SX, pacrobutrazol + SX, pendimethalin + SX, prohexadione Calcium (prohexandione-calcium) + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, sintofen + SX, 1-sodium 1-naphthaleneacetate + SX , Sodium cyanate + SX, streptmycin + SX, thidiazuron + SX, triapenthenol + SX, tribufos + SX, trinexapac-ethyl + SX, uniconazole-P + SX, 2- (naphthalene-1-yl) acetamide + SX, [4-oxo-4- (2-phenylethyl) )amino Butyric acid + SX, 5- (trifluoromethyl) benzo [b] methyl thiophene-2-carboxylate + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl) amino] -1-propanol + SX .

Combination of this component of the above group (d) and this compound:
Allidochlor + SX, benoxacor + SX, cloquintocet + SX, cloquintocet-mexyl + SX, cyometrinil + SX, cyprosulfamide + SX, dichlormid + SX, dicyclonone + SX, dimepiperate + SX, disulfoton + SX, dymron + SX, fenchlorazole + SX, fenchlorazole Fenchlorazole-ethyl + SX, fenclorim + SX, flurazole + SX, furilazole + SX, flxofenim + SX, hexim + SX, isoxadifen + SX , Isoxadifen-ethyl + SX, mecoprop + SX, mefenpyr + SX, mefenpyr-ethyl + SX, mefenpyrdi Chill (mefenpyr-diethyl) + SX, mephenate + SX, meetcamifen + SX, oxabetrinil + SX, 1,8-naphthalic anhydride + SX, 1 , 8-octamethylenediamine + SX, AD-67 (4- (dichloroacetyl) -1-oxa-4-azaspiro [4.5] decane) + SX, CL-304415 (4-carboxy- 3,4-dihydro-2H-1-benzopyran-4-acetic acid) + SX, CSB (1-bromo-4-[(chloromethyl) sulfonyl] benzene) + SX, DKA-24 (2,2-dichloro-N -[2-oxo-2- (2-propenylamino) ethyl] -N- (2-propenyl) acetamide) + SX, MG191 (2- (dichloromethyl) -2-methyl-1,3-dioxolane) + SX, MG -838 (2-propenyl 1-oxa-4-azaspiro [4.5] decane-4-carbodithioate) + SX, PPG-1292 (2,2-dichloro-N- (1,3-dioxan-2-ylmethyl) -N -(2-propenyl) acetamide) + SX, R-28725 (3- (dichloroacetyl) -2,2-dimethyl-1,3-oxazolidine) + SX, R-29148 (3- (dichloroacetyl) -2,2, 5-trimethyl-1,3-oxazolidine) + SX, TI-35 (1- (dichloroacetyl) azepane) + SX.

Combination of this component of the above group (e) and this compound:
1-dodecyl-1H-imidazole + SX, N- (2-ethylhexyl) -8,9,10-trinorborn-5-ene-2,3-dicarboximide (N -(2-ethylhexyl) -8,9,10-trinorborn-5-ene-2,3-dicarboximide) + SX, bucarpolate + SX, N, N-dibutyl-4-chlorobenzenesulfonamide (N, N -dibutyl-4-chlorobenzenesulfonamide) + SX, dietholate + SX, diethylmaleate + SX, piperonyl butoxide + SX, piperonylcyclonene + SX, piperotal + SX, propyl isome + SX, safroxan + SX, sesamex + SX, sesamolin + SX, sulfoxide + SX, Verbutin + SX, DMC (1, 1-bis (4-chlorophenyl) ethanol) + SX, FDMC (1,1-bis (4-chlorophenyl) -2,2,2-trifluoroethanol) + SX, ETN (1,2- epoxy-1,2,3,4-tetrahydronaphthalene) + SX, ETP (1,1,1-trichloro-2,3-expoxypropane) + SX, PSCP (phenylsaligenin cyclic phosphate) + SX, TBPT (S, S, S -tributyl phosphorotrithioate) + SX, TPP (triphenyl phosphate) + SX.

Combination of this component of the above group (f) and this compound:
Anthraquinone + SX, chloralose + SX, acrep + SX, butopyronoxyl + SX, camphor + SX, d-camphor + SX, carboxide ) + SX, dibutyl phthalate + SX, deet + SX, dimethyl carbate + SX, dimethyl phthalate + SX, dibutyl succinate + SX , Dibutyl adipate + SX, ethohexadiol + SX, hexamid + SX, icaridin + SX, methoquin-butyl + SX, methyl neodecanamide (methylneodecanamide) + SX, 2- (octylthio) ethanol + SX, butoxypolypropylene glycol + SX, oxamate + SX, quwenzhi + SX, quyingding + SX, zengxiaon + SX, Les Rebemide + SX, copper naphthenate + SX, zinc naphthenate + SX.

Combination of this component of the above group (g) and this compound:
Bis (tributyltin) oxide + SX, allicin + SX, bromoacetamide + SX, cloethocarb + SX, copper sulfate + SX, fentin ) + SX, ferric phosphate + SX, metaldehyde + SX, niclosamide + SX, pentachlorophenol + SX, sodium pentachlorophenoxide + SX, tazimcarb + SX, tralopyril + SX, trifenmorph + SX.

Combination of this component of the above group (h) and this compound:
(E) -2-hexenal + SX, (E) -2-octadecenal + SX, (E) -4-tridecen-1-yl acetate + SX, (E) -5-decen-1-yl acetate + SX, (E) -5-decen-1-ol + SX, (E) -3,3-dimethylcyclohexylideneacetaldehyde + SX, (E) -7-dodecen-1-yl acetate + SX, (E) -8-dodecen-1 -yl acetate + SX, (E) -9-dodecen-1-yl acetate + SX, (E) -10-hexadecenal + SX, (E) -11-hexadecen-1-yl acetate + SX, (E)- 11-tetradecen-1-yl acetate + SX, (E) -11-tetradecen-1-ol + SX, (E) -4-tridecen-1-yl acetate + SX, (E) -6-methylhept-2- en-4-ol + SX, (Z) -2- (3,3-dimethylcyclohexylidene) ethanol + SX, (Z) -4-decen-1-yl acetate + SX, (Z) -4-tridecen-1- yl acetate + SX, (Z) -5-decen-1-yl acetate + SX, (Z) -5-decen-1-ol + SX, (Z) -7-tetradecenal + SX, (Z) -7- dodecen-1-yl acetate + SX, (Z) -8-dodecen-1-yl acetate + SX, (Z) -9-dodecen-1-yl acetate + SX, (Z) -8-dodecen-1-ol + SX, (Z) -9-hexadecenal + SX, (Z) -10-hexadecen-1-yl acetate + SX, (Z) -11-hexadecen-1-ol + SX, (Z) -11-hexadecenal + SX, (Z) -11-hexadecen-1-yl acetate + SX, (Z) -11-octadecenal + SX, (Z) -13-octadecenal + SX, (Z) -hexad ec-13-en-11-yn-1-yl acetate + SX, (Z) -13-octadecenal + SX, (Z) -icos-13-en-10-one + SX, (Z) -7-tetradecenal + SX, (Z) -tetradec-9-en-1-ol + SX, (Z) -9-tetradecen-1-yl acetate + SX, (Z) -11-tetradecen-1-yl acetate + SX, ( Z) -13-icosen-10-one + SX, (Z, E) -7,11-hexadecadien-1-yl acetate + SX, (Z, E) -9,12-tetradecadien-1-yl acetate + SX , (E, Z) -4,10-tetradecadien-1-yl acetate + SX, (E, E) -8,10-dodecadien-1-ol + SX, (E, E) -10,12-hexadecadienal + SX, (E, E) -9,11-tetradecadien-1-yl acetate + SX, (E, Z) -2,13-octadecadien-1-ol + SX, (E, Z) -3,13-octadecadien -1-ol + SX, (E, Z) -2,13-octadecadien-1-yl acetate + SX, (E, Z) -3,13-octadecadien-1-yl acetate + SX, (E, Z) -7,9-dodecadien-1-yl acetate + SX, (E, E) -7,9-dodecadien-1-yl acetate + SX, (Z, E) -9,12-tetradecadien-1-yl acetate + SX, (Z, E) -9,11-tetradecadien-1-yl acetate + SX, (Z, E) -7,11-hexadecadien-1-yl acetate + SX, (Z, Z) -3,13- octadecadien-1-ol + SX, (Z, Z) -4,7-decadien-1-yl acetate + SX, (Z, Z) -3,13-octadecadien-1-yl acetate + SX, (Z, Z ) -7,11-hexadecadien-1-yl acetat e + SX, (Z, Z, E) -7,11,13-hexadecatrienal + SX, (5R) -5-[(1Z) -1-decen-1-yl] dihydro-2 (3H) -furanone + SX, (2R, 5R) -ethyl-1,6-dioxaspiro [4,4] nonane + SX, (2R, 5S) -ethyl-1,6-dioxaspiro [4,4] nonane + SX, (4R, 8R ) -4,8-dimethyldecanal + SX, (4R, 8S) -4,8-dimethyldecanal + SX, 2,4-dimethyl-5-ethyl-6,8-dioxabicyclo [3,2,1] octane + SX, (-)-4-methyl-3-heptanol + SX, 1,7-dioxaspiro [5,5] undecane + SX, 3-carene + SX, 3-methylcyclohex-2-en-1-one + SX, 14- methyloctadec-1-ene + SX, 4-methylnonan-5-ol + SX, 4-methylnonan-5-one + SX, 4- (3-oxobutyl) phenyl acetate + SX, dodecyl acetate + SX, dodeca-8,10 -dien-1-yl acetate + SX, ethyl (2E, 4Z) -decadienoate + SX, ethyl 4-methyloctanoate + SX, methyl 2,6,10-trimethyldodecanoate + SX, tetradecan-1-ol + SX, tetradec-11 -en-1-ol + SX, tetradec-11-en-1-yl acetate + SX, tridec-4-en-1-yl acetate + SX, (3S, 6R) -3-methyl-6-isopropenyl-9 -decen-1-yl acetate + SX, (3S, 6S) -3-methyl-6-isopropenyl-9-decen-1-yl acetate + SX, alpha-multistriatin + SX, alpha-pinene + SX, endo-brevicomin + SX, exo-brevicomin + SX, camphene + SX, codlelure + SX, codlemone + SX, cuelure + SX, disparlure + SX, dominicalure + SX, eugenol + SX, farnesol + SX, ferrolure + SX, frontalin + SX, gossyplure + SX, grandlure + SX, grandlure I + SX, grandlure II + SX, grandlure III + SX, grandlure IV + SX, hexalure + SX, ipsdienol + SX, ipsenol + SX, japonilure + SX, lineatin + SX, litlue + SX, looplure + SX, medlure + SX, megatomoic acid + SX, methyl eugenol + SX, muscalure + SX, nerolidol + SX, orfralure + SX, oryctalure + SX, ostramone + SX, rhyncolure + SX, siglure + SX, sordidin + SX, sulcatol + SX, trimedlure + SX, trimedlure A + SX, trimedlure B1 + SX, trimedlure B2 + SX, trimedlure C + SX, trunc-call + SX, (E) -verbenol + SX, (Z) -verbenol + SX, trans-verbenol + SX, (S) -verbenone + SX.

Combination of this component of the above group (i) and this compound:
2,3,6-TBA (2,3,6-trichlorobenzoic acid) + SX, 2,3,6-TBA-dimethylammonium + SX, 2,3,6-TBA Lithium salt (2,3,6-TBA-lithium) + SX, 2,3,6-TBA potassium salt (2,3,6-TBA-potassium) + SX, 2,3,6-TBA sodium salt (2 , 3,6-TBA-sodium) + SX, 2,4-D + SX, 2,4-D choline salt (2,4-D choline salt) + SX, 2,4-D BAPMA salt (2,4 -DN, N-bis (3-aminopropyl) methylamine salt) + SX, 2,4-D 2-butoxypropyl + SX, 2,4-D 2-ethylhexyl (2 , 4-D-2-ethylhexyl) + SX, 2,4-D 3-butoxypropyl + SX, 2,4-D ammonium (2,4-D-ammonium) + SX, 2,4-D butotyl (2,4-D-butotyl) + SX, 2,4-D butyl (2,4-D-butyl) + SX, 2,4-D diethylammonium (2,4 -D-diethylammonium) + SX, 2,4-D dimethylammonium (2,4-D-dimethylammonium) + SX, 2,4-D diolamine salt (2,4-D-diolamine) + SX, 2,4 -D-decylammonium + SX, 2,4-D-ethyl + SX, 2,4-D hep Ruammonium (2,4-D-heptylammonium) + SX, 2,4-D Isobutyl (2,4-D-isobutyl) + SX, 2,4-D isooctyl (2,4-D-isooctyl) + SX, 2,4-D isopropyl (2,4-D-isopropyl) + SX, 2,4-D isopropylammonium (2,4-D-isopropylammonium) + SX, 2,4-D lithium salt (2,4-D -lithium) + SX, 2,4-D meptyl (2,4-D-mepty) + SX, 2,4-D methyl (2,4-D-methyl) + SX, 2,4-D octyl (2 , 4-D-octyl) + SX, 2,4-D pentyl (2,4-D-pentyl) + SX, 2,4-D propyl (2,4-D-propyl) + SX, 2,4- D sodium salt (2,4-D-sodium) + SX, 2,4-D tefryl (2,4-D-tefuryl) + SX, 2,4-D tetradecylammonium (2,4-D-tetradecylammonium) + SX, 2,4-D triethylammonium (2,4-D-triethylammonium) SX, 2,4-D tris (2-hydroxypropyl) ammonium + SX, 2,4-D trolamine salt (2,4-D-trolamine) + SX, 2,4-DB + SX, 2,4-DB choline salt (SX), SX, 2 , 4-DB BAPMA salt (2,4-DB N, N-bis (3-aminopropyl) methylamine salt) + SX, 2,4-DB butyl (2,4-DB-butyl) + SX, 2,4-DB dimethylammonium (2,4-DB-dimethylammonium) + SX, 2,4-DB isooctyl (2,4- DB-isoctyl) + SX, 2,4-DB potassium salt (2,4-DB-potassium) + SX, 2,4-DB sodium salt (2,4-DB-sodium) + SX, acetochlor + SX, acifluorfen + SX, acifluorfen-sodium + SX, aclonifen + SX, ACN (2-amino-3-chloronaphthalene-1,4-dione) + SX , Alachlor + SX, alloxydim + SX, ametryn + SX, amicarbazone + SX, amidosulfuron + SX, aminocyclopyrachlor + SX, amino Aminocyclopyrachlor-methyl + SX, Aminocyclopyrachlor-potassium + SX, Aminopyralid + SX, Aminopyralidocholine salt pyralid choline salt) + SX, aminopyralid-potassium + SX, aminopyralid-tris (2-hydroxypropyl) ammonium) + SX, amiprophos methyl -methyl) + SX, amitrole + SX, anilofos + SX, asuram + SX, atrazine + SX, azafenidin + SX, azimsulfuron + SX, befurbutamide (beflubutamid) + SX, benazolin-ethyl + SX, bencarbazone + SX, benfluralin + SX, benfuresate + SX, bensulfuron + SX, bensulfuron-methyl methyl) + SX, bensulide + SX, bentazon + SX, benthiocarb + SX, benzfendizone + SX, benzobicyc lon) + SX, benzofenap + SX, benzthiazuron + SX, bialafosbialaphos + SX, bicyclopyrone + SX, bifenox + SX, bispyribac + SX, Bispyribac-sodium + SX, bixlozone + SX, bromacil + SX, bromobutide + SX, bromofenoxim + SX, bromoxynil + SX, bromoxynil Octanoate + SX, butachlor + SX, butafenacil + SX, butamifos + SX, butroxydim + SX, butylate + SX, cafenstrole + SX, carbetamide + SX, carfentrazone + SX, carfentrazone-ethyl + SX, chlomethoxyfen + SX, Chloramben + SX, chloridazon + SX, chlorimuron + SX, chlorimuron-ethyl + SX, chlorobromuron + SX, chlorotoluron + SX, chloroxuron (chloroxuron) + SX, chlorpropham + SX, chlorsulfuron + SX, chlorthal-dimethyl + SX, chlorthiamid + SX, cinidon + SX, sinidone ethyl (cinidon-ethyl) + SX, cinmethylin + SX, cinosulfuron + SX, clethodim + SX, clodinahop + SX, clodinahop-propargyl + SX, clomazone ( clomazone) + SX, clomeprop + SX, clopyralid + SX, clopyralid choline salt + SX, clopyralid-methyl + SX, clopyralid-olamine + SX, clopyralid-potassium + SX, clopyralid-tris (2-hydroxypropyl) ammonium + SX, chloranthram ( cloransulam) + SX, cloransulam-methyl + SX, cumyluron + SX,
Cyanazine + SX, cycloate + SX, cyclopyranil + SX, cyclopyrimorate + SX, cyclosulfamuron + SX, cyclooxydim + SX, cihalohop ( cyhalofop) + SX, cyhalofop-butyl + SX, dalapon + SX, dazomet + SX, desmedipham + SX, desmetryn + SX, di-allate ) + SX, dicamba + SX, dicamba choline salt + SX, dicamba BAPMA salt (dicamba N, N-bis (3-aminopropyl) methylamine salt) + SX, dicamba-trolamine salt (dicamba- trolamine) + SX, dicamba-diglycolamine + SX, dicamba-dimethylammonium + SX, dicamba-diolamine + SX, dicamba-isopropylammonium (dicamba- isop ropylammonium) + SX, dicamba-methyl + SX, dicamba-olamine + SX, dicamba-potassium + SX, dicamba-sodium + SX, Dichlorpropnyl + SX, dichlorprop choline salt + SX, dichlorprop BAPMA salt (dichlorprop N, N-bis (3-aminopropyl) methylamine salt) + SX, dichlorprop 2-ethylhexyl (dichlorprop-2) -ethylhexyl) + SX, dichlorprop-butotyl + SX, dichlorprop-dimethylammonium + SX, dichlorprop-ethylammonium + SX, dichlorprop-isoctyl ) + SX, dichlorprop-methyl + SX, dichlorprop-P + SX, dichlorprop-P choline salt + SX, dicloprop-P BAPMA Salt (dichlorprop-P-2-dimethylhexyl) + SX, dichlorprop-P-2-ethylhexyl + SX, dichlorprop-P-dimethylammonium ) + SX, dichlorprop-potassium + SX, dichlorprop-sodium + SX, diclofop + SX, diclofop-methyl + SX, diclosram + SX, difenoxuron + SX, difenzoquat + SX, diflufenican + SX, diflufenzopyr + SX, diflufenzopyr-sodium + SX, dimeflon dimefuron) + SX, dimepiperate + SX, dimethachlor + SX, dimethametryn + SX, dimethenamid + SX, dimethenamid-P + SX, Nitramine + SX, dinosebu + SX, dinoterb + SX, diphenamid + SX, diquat-dibromide + SX, DSMA (disodium methylarsonate) + SX, dithiopyr ) + SX, diuron + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, esprocarb + SX, ethalluralin + SX, ethametsulfuron + SX , Ethametsulfuron-methyl + SX, ethidimuron + SX, ethofumesate + SX, ethoxyfen-ethyl + SX, ethoxysulfuron + SX, ettobenzanid ) + SX, fenoxaprop-P + ethyl, SX, phenoxaprop-ethyl + SX, fenoxaprop-P + SX, fenoxaprop-P-ethyl + SX, phenoxasul Fenoxasulfone + SX, fenquinotrione + SX, fentrazamide + SX, fenuron + SX, flamprop M (flamprop-M) + SX, flazasulfuron + SX, Florasulam + SX, florpyrauxifen + SX, florpyrauxifen-benzyl + SX, fluazifop + SX, fluazifop-butyl + SX, fluazifop P (fluazifop-P) + SX, fluazifop-P-butyl + SX, fluazolate + SX, flucarbazone + SX, flucarbazone-sodium + SX, full Flucetosulfuron + SX, flufenacet + SX, flufenpyr + SX, flufenpyr-ethyl + SX, flumetsulam + SX, flumetrasla Flumetsulam + SX, flumiclorac + SX, flumiclorac-pentyl + SX, flumioxazin + SX, fluometuron + SX, fluoroglycofen- ethyl) + SX, flupoxam + SX, flupropanate + SX, flupirsulfuron + SX, flupirsulfuron-methyl-sodium + SX, flurenol + SX, fluridone + SX, flurochloridone + SX, fluroxypyr + SX, fluroxypyr-meptyl + SX, flurtamone + SX, fluthiacet + SX, fluthiacet-methyl + SX,
Fomesafen + SX, fomesafen-sodium + SX, foramsulfuron + SX, fosamine + SX, glufosinate + SX, glufosinate-ammonium + SX, glufosinate-P + SX, glufosinate-P-ammonium + SX, glufosinate-P-sodium + SX, glyphosate + SX, glyphosate choline Salt (glyphosate choline salt) + SX, glyphosate guanidine derivative salts + SX, glyphosate isopropylamine salt + SX, glyphosate BAPMA salt (glyphosate N, N-bis (3-aminopropyl) methylamine salt) + SX, glyphosate-ammonium + SX, glyphosate-diammonium + SX, glyphosate potassium Glyphosate-potassium + SX, glyphosate-sodium + SX, glyphosate-trimethylsulfonium + SX, halauxifen + SX, halauxifen-methyl ) + SX, halosafen + SX, halosulfuron + SX, halosulfuron-methyl + SX, halooxyfop + SX, halooxyfop-etotyl + SX, Haloxyfop-methyl + SX, Haloxyfop-P + SX, Haloxyfop-P-etotyl + SX, Haloxyfop-P-methyl + SX, Hexazinone ( hexazinone) + SX, imazamethabenz + SX, imazamethabenz-methyl + SX, imazamox + SX, imazamox-ammonium + SX, imazamethabenz-methyl Imazapic + SX, imazapic-ammonium + SX, imazapyr + SX, imazapyr-isopropylammonium + SX, imazaquin + SX, imazaquin Quinammonium salt (imazaquin-ammonium) + SX, imazethapyr + SX, imazethapyr-ammonium + SX, imazosulfuron + SX, indanofan + SX, indaziflam + indaziflam SX, iodosulfuron + SX, iodosulfuron-methyl-sodium + SX, iofensulfuron + SX, iofensulfuron-sodium + SX, ioxynil ) + SX, ioxynil-octanoate + SX, ipfencarbazone + SX, isoproturon + SX, isouro (isouron) + SX, isoxaben + SX, isoxachlortole + SX, isoxaflutole + SX, lactofen + SX, lenacil + SX, linuron ) + SX, maleic hydrazide + SX, MCPA choline salt + SX, MCPA BAPMA salt (MCPA N, N-bis (3-aminopropyl) methylamine salt) + SX, MCPA 2-ethylhexyl (MCPA-2-ethylhexyl) + SX, MCPA-butotyl + SX, MCPA-butyl + SX, MCPA dimethylammonium + SX, MCPA diolamine salt (MCPA-diolamine) + SX, MCPA-ethyl + SX, MCPA-isobutyl + SX, MCPA-isopropyl + SX, MCPA-methyl + SX, MCPA allamine salt (MCPA-olamine) + SX, MCPA sodium salt (MCPA-sodium) + SX, MCPA-trolamine salt (MCPA-trolamine) + SX, MCPB (4- (4-chlor o-2-methylphenoxy) butanoic acid) + SX, MCPB choline salt (MCPB choline salt) + SX, MCPB BAPMA salt (MCPB N, N-bis (3-aminopropyl) methylamine salt) + SX, MCPB ethyl (MCPB-ethyl) ) + SX, MCPB methyl (MCPB-methyl) + SX, MCPB sodium salt (MCPB-sodium) + SX, mecoprop choline salt + SX, mecoprop BAPMA salt (mecoprop N, N-bis (3- aminopropyl) methylamine salt) + SX, mecoprop-2-dimethylhexyl + SX, mecoprop-dimethylammonium + SX, mecoprop-diolamine + SX, mecopropeta Jill (mecoprop-ethadyl) + SX, mecoprop-isoctyl + SX, mecoprop-methyl + SX, mecoprop-potassium + SX, mecoprop-sodium salt (mecoprop -sodium) + SX, mecoprop-trolamine salt + SX, mecoprop P (mecoprop-trolamine) prop-P) + SX, mecoprop-P choline salt + SX, mecoprop-P-2-ethylhexyl + SX, mecoprop-P-dimethylammonium + SX, mecoprop-P-isobutyl + SX, mecoprop-P-potassium + SX,
Mefenacet + SX, mesosulfuron + SX, mesosulfuron-methyl + SX, mesotrione + SX, metam + SX, metamifop + SX, metamitron + SX, metazachlor + SX, metazosulfuron + SX, methabenzthiazuron + SX, methiozolin + SX, methyldymron + SX, metobromuron + SX , Metolachlor + SX, metsusulam + SX, metoxuron + SX, metribuzin + SX, metsulfuron + SX, metsulfuron-methyl + SX, molinate molinate) + SX, monolinuron + SX, naproanilide + SX, napropamide + SX, napropamide-M + SX, naptara (naptalam) + SX, neburon + SX, nicosulfuron + SX, norflurazon + SX, oleic acid + SX, orbencarb + SX, orthosulfamuron ) + SX, oryzalin + SX, oxadiargyl + SX, oxadiazon + SX, oxasulfuron + SX, oxaziclomefone + SX, oxyfluorfen + SX, paracoat (paraquat) + SX, paraquat-dichloride + SX, pebulate + SX, pelargonic acid + SX, pendimethalin + SX, penoxsulam + SX, pentano Pentolechlor + SX, pentoxazone + SX, pethoxamid + SX, phenisopham + SX, phenmedipham + SX, picloram (piclor) am), Pyrocorinafen + SX, Picolinafen + SX, pinoxaden + SX, piperophos + SX, pretilachlor + SX, primisulfuron + SX , Primisulfuron-methyl + SX, prodiamine + SX, profluazol + SX, propoxydim + SX, prometon + SX, promethrin + SX, propachlor + SX, propanil + SX, propaquizafop + SX, propazine + SX, propham + SX, propisochlor + SX, propoxy Carbazone (propoxycarbazone) + SX, propoxycarbazone sodium salt (propoxycarbazone-sodium) + SX, propyrisulfuron + SX, propyzamide + SX, prosulfocarb + SX, Prosulfuron + SX, pyraclonil + SX, pyrasulfotole + SX, pyrazolynate + SX, pyrazosulfuron + SX, pyrazosulfuron-SX + SX, pyrazosulfuron + SX, pyrazosulfuron + SX, pyrazosulfuron + SX Pyrazoxyfen + SX, pyribenzoxim + SX, pyributicarb + SX, pyridafol + SX, pyridate + SX, pyrifalid + SX, pyrinobac Pyriminobac-methyl + SX, pyrimisulfan + SX, pyrithiobac + SX, pyrithiobac-sodium + SX, pyroxasulfone + SX, piroxislam (pyroxsulam) + SX, quinclorac + SX, quinmerac + SX, quizalofop + SX, quizalofop-e thyl) + SX, quizalofop-tefuryl + SX, quizalofop-P-ethyl + SX, quizalofop-P-tefuryl ) + SX, rimsulfuron + SX, saflufenacil + SX, sethoxydim + SX, EPTC (S-ethyl N, N-dipropylcarbamothioate) + SX, siduron + SX, simazine ) + SX, simetryn + SX, S-metolachlor + SX, MSMA (sodium hydrogen methylarsonate) + SX, sulcotrione + SX, sulfentrazone + SX, Sulfomethuron + SX, Sulfomethuron-methyl + SX, Sulfosulfuron + SX, Swep + SX, TCA (2,2,2-trichloroacetic acid) + SX, Tebutam (tebutam) + SX, tebuthiuron + SX, tefuryltrione + SX, Tembotrione + SX, tepraloxydim + SX, terbacil + SX, terbumeton + SX, terbuthylazine + SX, terbutryn + SX, tactmin A (th) + SX, thenylchlor + SX, thiazopyr + SX, thidiazimin + SX, thiencarbazone + SX, thiencarbazone-methyl + SX, thifensulfuron + SX, thifensulfuron-methyl + SX, tiafenacil + SX, tiocarbazil + SX, tolpyralate + SX, topramezone + SX, tralkoxydim + SX, tralkoxydim Triafamone + SX, tri-allate + SX, triasulfuron + SX, triaziflam + SX, tribenuron nuron) + SX, tribenuron-methyl + SX, triclopyr + SX, triclopyr-butotyl + SX, triclopyr-ethyl + SX, triclopyr Triethylammonium (triclopyr-triethylammonium) + SX, tridiphane + SX, trietazine + SX, trifloxysulfuron + SX, trifloxysulfuron-sodium + SX, trifludi Moxazine (trifludimoxazin) + SX, trifluralin + SX, triflusulfuron + SX, triflusulfuron-methyl + SX, tritosulfuron + SX, vernalate + SX, 2-[(2,4-dichlorophenyl) methyl] -4,4-dimethyl-1,2-oxazolidin-3-one + SX, Ethyl [(3- {2-chloro-4-fluoro-5- [3-methyl-4- (trifluoromethyl) -2,6-dioxo-1,2,3,6-tetrahydropyrimidin-1-yl] phenoxy} pyridin-2-yl) o xy] acetate (353292-31-6) + SX.

Combination of this component of the above group (j) and this compound:
Abbreviata caucasica + SX, Aquaria spp. (Acuaria spp.) + SX, Agamermis decaudata + SX, Agrobacterium radiobacter K1026 + SX, Agrobacterium radiobacter K Strain (Agrobacterium radiobacter K84) + SX, Agrobacterium vitis VAR03-1 strain (Agrobacterium vitis VAR03-1) + SX, Allantonema spp. (SX) + SX, Alternaria destruens 59 strain (Alternaria destruens 59) + SX, Alternaria・ Alternaria destruens + SX, Ampelomyces quisqualis AQ10 + SX, Amphimermis spp. + SX, Arthrobotrys dactyloides + SX, Arsrobolis Arthrobotrys superba) + SX, Achelsonia Leyrodes (Aschersonia aleyrodes) + SX, Aspergillus flavus AF36 strain (Aspergillus flavus AF36) + SX, Aspergillus flavus NRRL21882 strain (Aspergillus flavus NRRL21882) + SX, Aureobasidium pullulans DSM14940 strain (Aureobasidium pullulans) DSM14941 strain (Aureobasidium pullulans DSM14941) + SX, Azopirillum + SX, Azorhizobiuma caulinodans ZB-SK-5 + SX, Azotobacter chroococcum H23 (Azotobacter chroococcum) Azotobacter chroocuccum + SX, Azotobacter cyst + SX, Azotobacter vinelandii ATCC12837 + SX, Azotobacter + SX, Bacillus acidophilus acid caldarius) + SX, Bacillus acidoterrestris + SX, Bacillus albolactis + SX, Bacillus alcalophilus + SX, Bacillus alvei + SX, Bacillus aminoglucosidicus (Bacillus aminoglucosidicus) + SX, Bacillus aminovorans + SX, Bacillus amyloliquefaciens AT332 (Bacillus amyloliquefaciens AT332) + SX, Bacillus amyloliquefaciens B3 (Bacillus amyloliquefaciens B3) + SX, Bacillus amyloliquefaciens B3 ENS D747 strain (Bacillus amyloliquefaciens D747) + SX, Bacillus amyloliquefaciens DB101 strain (Bacillus amyloliquefaciens DB101) + SX, Bacillus amyloliquefaciens DB102 strain (Bacillus amyloliquefaciens DB102) + SX, Bacillus amyloliquefaciens FZB24 strain (Bacillus amyloliquefaciens FZB24) + SX, Bacillus amyloliquefaciens FZB42 strain (Bacillus amyloliquefaciens FZB42) + SX, Bacillus amyloliquefaciens GB03 strain (Bacillus amyloliquefaciens GB03) + SX, Bacillus amyloliquefaciens strain amyloliquefaciens IN937a) + SX, Bacillus amyloliquefaciens MBI600 strain (Bacillus amyloliquefaciens MBI600) + SX, Bacillus amyloliquefaciens QST713 strain (Bacillus amyloliquefaciens QST713) + SX, Bacillus amyloliquefaciens strain 246 isolate 246 B246) + SX, Bacillus amyloliquefaciens F727 strain (Bacillus amyloliquefaciens F727) + SX, Bacillus amylolyticus + SX,
Bacillus aneurinolyticus + SX, Bacillus agri + SX, Bacillus atrophaeus + SX, Bacillus azotoformans + SX, Bacillus badius + SX, Bacillus badius + SX Bacillus cereus BP01 strain (Bacillus cereus BP01) + SX, Bacillus cereus CNCM 1-1562 strain (Bacillus cereus CNCM 1-1562) + SX, Bacillus chitinosporus AQ746 strain (Bacillus chitinosporus AQ746) + SX, Bacillus chitinosporus CM-1 strain ( Bacillus chitinosporus CM-1) + SX, Bacillus circulans + SX, Bacillus coagulans TQ33 (Bacillus coagulans TQ33) + SX, Bacillus fastidiosus + SX, Bacillus films GB-126 (Bacillus firmus GB-126) + SX, Bacillus films I-1582 Bacillus firmus I-1582) + SX, Bacillus lacticola + SX, Bacillus lactimorbus + SX, Bacillus lactis + SX, Bacillus lautus + SX, Bacillus lentimorbus ) + SX, Bacillus lentus + SX, Bacillus licheniformis HB-2 (Bacillus licheniformis HB-2) + SX, Bacillus licheniformis SB3086 (Bacillus licheniformis SB3086) + SX, Bacillus marocus (Bacillus marocus)・ Medusa (Bacillus medusa) + SX, Bacillus megaterium YFM3.25 (Bacillus megaterium YFM3.25) + SX, Bacillus methylotrophicus BAC-9912 (Bacillus methylotrophicus BAC-9912) + SX, Bacillus metiens (SX) , Bacillus Mojabensis SR11 strain (Bacillu s mojavensis SR11) + SX, Bacillus mycoides AQ726 + SX, Bacillus mycoides isopate J + SX, Bacillus nematocida + SX, Bacillus nimato nigricans ANS + SX Bacillus nigrum + SX, Bacillus popilliae + SX, Bacillus psychrosaccharolyticus + SX, Bacillus pumilus AQ717 + SX, Bacillus pumilus BUF-33 Strain (Bacillus pumilus BUF-33) + SX, Bacillus pumilus GB34 strain (Bacillus pumilus GB34 strain) + SX, Bacillus pumilus QST2808 strain (Bacillus pumilus QST2808) + SX, Bacillus siamensis + SX, Bacillus 856 plex (CGF2 strain CGF2) Bacillus simplex CGF2856) + SX, Bacillus smithi Bacillus smithii) + SX, Bacillus sp. AQ175 strain (Bacillus sp. AQ175) + SX, Bacillus sp. AQ177 strain (Bacillus sp. AQ177) + SX, Bacillus sp. AQ178 strain (Bacillus sp. AQ178) + SX, Bacillus sp. Elixir strain 2362 ( Bacillus sphaericus 2362) + SX, Bacillus sphaericus ABTS1743 strain (Bacillus sphaericus ABTS1743) + SX, Bacillus sphaericus antigenic H5a5b strain (Bacillus sphaericus Serotype H5a5b) + SX, Bacillus subtilis AQ153 strain VS. (Bacillus subtilis AQ743) + SX, Bacillus subtilis D747 strain (Bacillus subtilis D747) + SX, Bacillus subtilis DB101 strain (Bacillus subtilis DB101) + SX, Bacillus subtilis FZB24 strain (Bacillus subtilis FZB24) + SX, Bacillus subtilis strain (Bacillus subtilis FZB24) subtilis GB03) + SX, Bacillus subtilis HAI0404 (Bacillus subtilis HAI0404) + SX, Bacillus Subtilis IAB / BS03 (Bacillus subtilis IAB / BS03) + SX, Bacillus subtilis MBI600 (Bacillus subtilis MBI600) + SX, Bacillus subtilis QST30002 / AQ30002 (Bacillus subtilis QST30002 / AQ30002) + SX, Bacillus subtilis Q0004 ST / 4 Bacillus subtilis QST30004 / AQ30004) + SX, Bacillus subtilis QST713 strain (Bacillus subtilis QST713) + SX, Bacillus subtilis QST714 strain (Bacillus subtilis QST714) + SX, Bacillus subtilis var amyloliquefaciens FZBtillo F. + SX, Bacillus subtilis Y1336 + SX, Bacillus subtillis subsp. Natto + SX, Bacillus tequilensis NII-0943 (Bacillus tequilensis NII-0943) + SX,
Bacillus thuringiensis AQ52 strain (Bacillus thuringiensis AQ52) + SX, Bacillus thuringiensis BD # 32 strain (Bacillus thuringiensis BD # 32) + SX, Bacillus thuringiensis CR-371 strain (Bacillus thuringiensis CR-371) + SX, Bacillus thuringiensis Aiswai subspecies ABTS-1857 (Bacillus thuringiensis subsp. Aizawai ABTS-1857) + SX, Bacillus thuringiensis subsp. Aizawai GC-91 + SX, Bacillus thuringiensis subsp. Aizawai subspecies Serotype H-7 (Bacillus thuringiensis subsp. Aizawai Serotype H-7) + SX, Bacillus thuringiensis subsp. Kurstaki ABTS351 + SX, Bacillus thuringiensis subsp. BMP123 (Bacillus thuringiensis subsp. Kurstaki BMP123) + SX, Bacillus thuringen S. Kristaki subsp. EG234 strain (Bacillus thuringiensis subsp. Kurstaki EG234) + SX, Bacillus thuringiensis subsp. Kurstaki EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki EG7841 strain (EVB113-19) Kurstaki EVB113-19) + SX, Bacillus thuringiensis subsp. Kurstaki F810 + SX, Bacillus thuringiensis subsp. Kurstaki HD-1 strain (Bacillus thuringiensis subsp. Kurstaki HD) -1) + SX, Bacillus thuringiensis subsp. Kurstaki PB54 + SX, Bacillus thuringiensis subsp. Kurstaki SA-11 + SX, Bacillus thuringiensis kristaki subspecies SA-12 strain (Bacillus thu ringiensis subsp. Kurstaki SA-12) + SX, Bacillus thuringiensis subsp. morrisoni + SX, Bacillus thuringiensis subsp. Tenebriosis NB 176 (SX 176) + SX, Bacillus thuringiensis Thuringiensis subsp. Thuringiensis subsp. Thuringiensis MPPL002 + SX, Bacillus thuringiensis subsp. Var. Colmeri + SX, Bacillus thuringiensis Darmstadiensis 24-91 (Bacillus thuringiensis subsp. Var. Darmstadiensis 24-91) + SX, Bacillus thuringiensis subsp. Var. Dendrolimus + SX, Bacillus thuringiensis subsp. Var. Galleriae + SX , Bacillus Thuringiensis israelensis subsp. BMP144 strain (Bacillus thuringiensis subsp. Israelensis BMP144) + SX, Bacillus thuringiensis subsp. Israelensis subsp. AM65-52 strain (Bacillus thuringiensis subsp. Israelensis AM65-52) + SX, Bacillus thuringiensis・ Japonensis variant buibui strain (Bacillus thuringiensis subsp. Var. Japonensis buibui) + SX, Bacillus thuringiensis subsp. Var. Bacillus thuringiensis var. Sandiego M-7 + SX, Bacillus thuringiensis var. T36 + SX, Bacillus uniflagellate + SX, Bacillus・ Sea urchin flagellasu (Bacillus un iflagellatus) + SX, bacteria spp. (bacteria spp.) + SX, bacteriophage of Clavibacter michiganesis + SX, Beauveria bassiana ANT-03 strain + SX, Boberia basiana ATCC74040 (Beauveria bassiana ATCC74040) + SX, Beauveria bassiana GHA + SX, Beauveria bassiana PPRI 5339 + SX, Beauveria brongniartii + ola, Bezier dic + SX, Bobienema spp. (Bovienema spp.) + SX, Brevibacillus brevis 2904 strain (Brevibacillus brevis 2904) + SX, Brevibacillus brevis SS86-3 strain (Brevibacillus brevis SS86-3) + SX, Brevibacillus brevis SS86-4 strain (Brevibacillus brevis SS86-4) + SX, Brevibacillus brevis S S86-5 strain (Brevibacillus brevis SS86-5) + SX, Brevibacillus laterosporus ATCC64 strain (Brevibacillus laterosporus ATCC64) + SX, Brevibacillus laterosporus BPM3 strain (Brevibacillus laterosporus BPM3) + SX, Brevibacillus laterosporus G4 strain, Brevibacillus laterosporus Glus strain・ Laterosporus NCIMB 41419 (Brevibacillus laterosporus NCIMB 41419) + SX, Brevibacillus laterosporus NRS1111 (Brevibacillus laterosporus NRS1111) + SX, Brevibacillus laterosporus NRS1645 (Brevibacillus laterosporus NRS1645) SX
Burkholderia cepacia type Wisconsin J82 + SX, Burkholderia cepacia type Wisconsin M54 + SX, Burkholderia cepacia + B Burkholderia gladii BA-7 + SX, Burkholderia rinojensis A396 + SX, Cameronia spp. (SX) + SX, Canadian thistle fungus + SX, Candida oleophila O + SX, Candida saitoana + SX, Candida spp. + SX, Chaetomium cupreum + SX, Chito Woodiera ovo Filamenta (Chitwoodiella ovofilamenta) + SX, Chromobacterium subtubae PRA A4-1T strain (Chromobacterium subtsugae PRAA4-1T) + SX, Cladosporium cladosporioides H39 + SX, Clonostachys rosea + SX, Conidiobolus obscurus + Conidiobolus SX Coniothyrium minitans CGMCC8325 + SX, Coniothyrium minitans CON / M / 91-08 + (Coniothyrium minitans CON / M / 91-08) + SX, Contortylenchus spp. + SX, Cryptocco・ Albidas (cryptococcus albidus) + SX, Colissimermis spp. (Culicimermis spp.) + SX, Dactyllela ellipsospora + SX, Dectilaria saumasia (Dectylaria thaumasia) + SX, Delphtia acid ran 209・ Dilophosphora alopecuri + SX, de Protria ena spp. (Diplotriaena spp.) + SX, Empidomermis spp. + SX, Entomophthora virulenta + SX, Erwinia carotobola subsp. Filipjevimermis leipsandra + SX, Fusarium oxysporum Fo47 + SX, Fusarium prasriferatum + SX, Gastromermis spp. + SX, Glyocladium Catenuratam J1446 strain (Gliocladium catenulatum J1446) + SX, gluconacetobacter diazotrophicus + SX, Gongylonema spp. + SX, Gynopoecilia pseudovipin (Hypoprotein) arpin protein + SX, Heterorhabditis bacteriophora + SX, Heterorhabditis baujardi + SX, Heterorhabditis heliothidis + SX, Heterorhabditis indica + Heterorhabditis indica + Heterorhabditis heliothidis + SX, Heterorhabditis heliothidis + SX Heterorhabditis marelatus + SX, Heterorhabditis megidis + SX, Heterorhabditis zealandica + SX, Hexamermis spp. + Ut, tens, nes ) + SX, Hirsutella rsiliensis + SX, Hirsutella thompsonii + SX, Hydromelmis spp. + SX, Isalia Fumo Sorocea (Isaria fumosorosea) + SX, Isomermis spp. (Isomermis spp.) + SX, Lactobacillus acidophilus + SX, Lactobacillus brevis + SX, Lactobacillus plantarum + pp, Lactobacillus plantarum + pp, Lactobacillus plantarum Lactobacillus spp. + SX, Lagenidium giganteum + SX, Lecanicillium lecanii KV01 (Lecanicillium lecanii KV01) + SX, Lecanicillium lecanii DA99198499 conidia (Lecanicillium lecanii con99) Conidia (Lecanicillium lecanii conidia of strain DAOM216596) + SX, Rimomermis spp. (Limnomermis spp.) + SX, Rhizobacter antibioticus 13-1 (Lysobacter antibioticus 13-1) + SX, Rhizobacter enzymogenes C3 (Lysobacter enzymogenes) C3) + S X, Maupasina weissi + SX, Mermis nigrescens + SX, Mesomermis spp. (Metarhizium anisopliae var. Acridum) + SX, Metarhizium flavoviride + SX, metschnikowia dimerum + SX, Methicobia fructicola NRRLY-30752 (Metschnikowia fructicola NRRLY-30752)
Microsphaeropsis ochracea + SX, Monacrosporium phymatopagum + SX, Mucor hiemalis + SX, Muscodor albus 620 + LS, Q (Muscodor albus QST 20799) + SX, Muscodor albus SA13 strain (Muscodor albus SA13) + SX, Muscodor roseus A3-5 strain (Muscodor roseus A3-5) + SX, Milotesium velcaria AARC-0255 strain (Myrothecium verrucaria AARC-0255) + SX, Neomesomermis spp. (Neomesomermis spp.) + SX, Neoparasitylenchus rugulosi + SX, Nomura Air Lily CG128 (Nomuraea rileyi CG128) + SX, Nomura Air Lily GU87401 (Nomuraea riley SX Lily SA86101 stock (Nomuraea rileyi SA86101) + SX, Nomura Air Lily SR86151 (Nomuraea rileyi SR86151) + SX, Nomura Air Riley VA9101 (Nomuraea rileyi VA9101) + SX, Nosema locustae + SX, Octtomyomermis spp. ) + SX, Pekiromyces fumosoroseus Apopka 97 (currently known as Isaria fumosorosea Apopka 97) (Paecilomyces fumosoroseus Apopka 97, now Isaria fumosorosea Apopka 97) + SX, Pakylomyces lilacinus 251 Paecilomyces tenuipes T1 + SX, Pequilomyces barriotti Q-09 (Paecilomyces variotii Q-09) + SX, Paenibacillus alvei 2771 (Paenibacillus alvei 2771) + SX, Paenibacillus alvei 46 46C3) + SX, Paenibacillus albeii III2E strain Paenibacillus alvei III2E) + SX, Paenibacillus alvei III3DT-1A strain (Paenibacillus alvei III3DT-1A) + SX, Paenibacillus alvei T36 strain (Paenibacillus alvei T36) + SX, Paenibacillus macerans-1 strain, Paenibacillus macerans-1 (Paenibacillus polymyxa AC-1) + SX, Paenibacillus polymyxa BS-0105 strain (Paenibacillus polymyxa BS-0105) + SX, Paenibacillus popilliae + SX, Pandora delphacis + SX, Pantoea agromer oe strain E325 agglomerans E325) + SX, Pantoea vagans C9-1 (Pantoea vagans C9-1) + SX, Paracyta Ferenchus spp. (Parasitaphelenchus spp.) + SX, Parasite Torhabditis spp. (SX) + SX, Parasite Lenks spp. (Parasitylenchus spp.) + SX, Pasteuria nisawae Pn1 strain Pasteuria nishizawae Pn1) + SX, Pasturia penetrans + SX, Pasteuria ramose + SX, Pasturia usgae + SX, Pectobacterium carotovorium + SX, 348 Penicillium bilaii ATCC22348) + SX, Penicillium citrinum VFI-51 strain (Penicillium citrinum VFI-51) + SX, Penicillium vermiculatum + SX, Perutilimermis culicis + SX, Pasteuria toinei Pasteuria thoynei + SX, Phasmarhabditis hermaphrodita + SX, Ferrebiopsis gigantea VRA1992 (phlebiopsis gigantea VRA1992) + SX, Physaloptera spp. (Physaloptera spp.) + SX, Phytopasola Palmi Phytophthora palmivora + SX, Pichia anomala WRL-076 (Pichia anomala WRL-076) + SX, Pichia guilliermondii Z1 + SX, Pichia guilliermondii Z8 (pichia guilliermondii Z8) + SX, Poconia Isolate PC10 strain (Pochonia chlamydosporia isolate PC10) + SX, Poconia chlamydosporia + SX, Protrellatus spp. + SX,
Pseudomonas aeruginosa PN1 + SX, Pseudomonas aeruginosa WS-1 (Pseudomonas aeruginosa WS-1) + SX, Pseudomonas aureofaciens TX-1 (Pseudomonas aureofaciens TX-1) + SX, Pseudomonas cepa Wisconsin type J82 strain (Pseudomonas cepacia type Wisconsin J82) + SX, Pseudomonas cepacia type Wisconsin type M54 strain (Pseudomonas cepacia type Wisconsin M54) + SX, Pseudomonas chlororaphis 63-28 strain (Pseudomonas chlororaphis 63-28) MA342 strain (Pseudomonas chlororaphis MA342) + SX, Pseudomonas fluorescens 1629RS strain (pseudomonas fluorescens 1629RS) + SX, Pseudomonas fluorescens A506 strain (pseudomonas fluorescens A506) + SX, Pseudomonas fluorescens CL145A strain escenona 145 Eggplant fluorescens G7090 (Pseudomonas fluorescens G7090) + SX, Pseudomonas fluorescens biover B XJ3 + SX, Pseudomonas fluorescens biover B XS18 (Pseudomonas fluorescens bioSX XS 18 Lessens biover A LRS12 strain (Pseudomonas fluorescens biover A LRS12) + SX, Pseudomonas proradix + SX, Pseudomonas putida + SX, Pseudomonas reactans + SX, Pseudomonas ovo Pseudomonas rhodesiae HAI-0804 + SX, Pseudomonas sp. CAB-02 (Pseudomonas sp. CAB-02) + SX, Pseudomonas syringae 742RS + SX, Pseudomonas schi Ngae MA-4 strain (Pseudomonas syringae MA-4) + SX, Pseudozyma flocculosa PF-A22UL + SX, Pterygodermatites spp. puccinia thlaspeos woad) + SX, Purpureocillium lilacinum + SX, Pythium oligandrum DV74 + SX, Rhodococcus globeberulus AQ719 strain (Rhodococcus globerulus AQ719) ) + SX, Saccharomyces cerevisiae LASO2 strain (saccharomyces cerevisiae LASO2) + SX, sclerotinia minor IMI34414 strain (sclerotinia minor IMI34414) + SX, Serratia entomophila + SX, Serratia marcesence 35 strain (Serratia marcen, 35 strains)・ Serratia marcescens SRM + SX, Seuratum cadarachense + SX, Sinorhizobium meliloti + SX, Sphaerulariopsis spp. + SX, Spirura guianensis (Spirura guianensis) + SX, Spirura guianensis + SX, Steinernema bibionis + SX, Steinernema carpocapsae + SX, Steinernema feltiae + SX, Steinernema glaseern + SX, Steinernema glaseri (Steinernema riobrave) + SX, Steinernema scapterisci + SX, Steinernema scarabaei + SX, Steinernema Siam Kayai (Steinernema siamkayai) + SX, Steinerne spp. (Steinernema spp.) + SX, Strelkovimermis peterseni + SX, Streptomyces acidiskabies RL-110T (Streptomyces acidiscabies RL-110T) + SX Candida Y21007-2 strain (Streptomyces candidus Y21007-2) + SX, Streptomyces colombiensis + SX, Streptomyces galbus QST6047 strain (Streptomyces galbus QST6047) + SX, Streptomyces goshikienshi (Streptomyces goki + SX, Streptomyces griseoviridis K61 + SX, Streptomyces lavendulae + SX, Streptomyces lydicus WYCD108US (Streptomyces lydicus WYCD108US) + SX, Streptomyces EC rep ces lydicus WYEC108) + SX, Streptomyces prasinus + SX, Streptomyces rimosus + SX, Streptomyces saraceticus + SX, Streptomyces sp.NRRL No.B-30145 Strain (Streptomyces sp. NRRL No. B-30145) + SX, Streptomyces sp. WYE20 strain (Streptomyces sp. WYE20) + SX, Streptomyces sp. WYE 324 strain (Streptomyces sp. WYE 324) + SX, Streptomyces sp. Venezuela (Streptomyces venezuelae) + SX,
Subaru spp. (Subulura spp.) + SX, Sulphuretylenchus elongatus + SX, Talaromyces flavus SAY-Y-94-01 (Talaromyces flavus SAY-Y-94-01) + SX, Talaromyces flavus V117b strain (Talaromyces flavus V117b) + SX, Tetrameres spp. (Tetrameres spp.) + SX, Terohania solenopsis + SX, Thiobacillus spp. + SX, Trichoderma album + SX JM41R (Trichoderma asperelloides JM41R) + SX, Trichoderma asperellum ICC012 (Trichoderma asperellum ICC012) + SX, Trichoderma asperellum T34 (Trichoderma asperellum T34) + SX, Trichoderma asperellum SKT-1per (SX)・ Atrobilide CNCM 1-1237 strain (Trichoderma atroviride CNCM 1-1237) + S X, Trichoderma atroviride LC52 + SX, Trichoderma atroviride SC1 + SX, Trichoderma atroviride SKT-1 + Trichoderma atroviride SKT-1 + SX, Trichoderma atroviride SKT-1 (Trichoderma atroviride SKT-1) ICC080) + SX, Trichoderma harzianum 21 strain (Trichoderma harzianum 21) + SX, Trichoderma harzianum DB 104 strain (Trichoderma harzianum DB 104) + SX, Trichoderma harzianum DSM 14944 strain (Trichoderma harzianum DSM 14944) + SX, Trichoderma harzian-1 Strain (Trichoderma harzianum ESALQ-1303) + SX, Trichoderma harzianum ESALQ-1306 strain (Trichoderma harzianum ESALQ-1306) + SX, Trichoderma harzianum IIHR-Th-2 strain (Trichoderma harzianum IIHR-Th-2) + SX, Trichoderma harzianum ITEM Strain (Trichoderma harzianum ITEM908) + SX, G Koderma harzianum kd strain (Trichoderma harzianum kd) + SX, Trichoderma harzianum MO1 strain (Trichoderma harzianum MO1) + SX, Trichoderma harzianum SF strain (Trichoderma harzianum SF) + SX, Trichoderma harzianum T22 strain (Trium S. Harjianum T39 (Trichoderma harzianum T39) + SX, Trichoderma harzianum T78 (Trichoderma harzianum T78) + SX, Trichoderma harzianum TH35 + SX, Trichoderma harzianum Riffy (Trichoderma harzian Trich, Trichorif 395) (Trichoderma koningii) + SX, Trichoderma lignorum + SX, Trichoderma polysporum IMI206039 strain (Trichoderma polysporum IMI206039) + SX, Trichoderma spp. (Trichoderma spp.) + SX, Trichoderma stromati Trichoderma stromaticum + SX, Trichoderma virens G-41 (Trichoderma virens GL-21, formaly Gliocladium virens GL-21) + SX, Trichoderma virens GL-21 Trichoderma viride + SX, Tsukamurella paurometabola + SX, Typhula phacorrhiza 94671 + SX, Uroladium oudemansii HRU3 + pp, airimorpha spp. -09) + SX, Variovorax paradoxus GF4526 + SX, Verticillium alboatrum WCS850 + Verticillium alboatrum WCS850 + SX, Verticillium chlamydosporium + SX, Verticillium・ Darie (Verticillium dahliae) + SX, Verticillium Recani NCIM1 312 strains (Verticillium lecani NCIM1312) + SX, Birgibacillus pantothenticus ATCC14576 strain (Virgibacillus pantothenticus ATCC14576) + SX, Birgibacillus pantothenticus DSM491 strain (Virgibacillus pantothenticus DSM491) + SX, Xanthomonas v pesto Xanthomonas campestris) + SX, Xenorhabdus luminescens + SX, Xenorhabdus nematophila + SX, Zoophtora radicans + SX, Adoxofis orulosis SX Agrotis segetum nuclear polyhedrosis virus (NPV) + SX, Anagraoha falcifera NPV + SX, anticalcia gema Squirrel nuclear polyhedrosis virus (Anticarsia gemmatalis mNPV) + SX, Autographa californica mNPV FV # 11 + SX, Biston suppressoraria nuclear polyhedrosis virus (Biston suppressaria NPV) + SX , Bombyx mori NPV + SX, Cryptophlebia leucotreta GV + SX, Sidia pomonella granule disease virus V15 (Cydia pomonella GV V15) + SX, Sidia Pomonella granule disease virus V22 strain (Cydia pomonella GV V22) + SX, Dendrolimus punctatus cypovirus + SX, Helicoberpa algera nuclear polyhedrosis virus BV-0003 (Helicoverpa armigera NPV BV-0003) + SX,
Helicoverpa zea NPV) + SX, Leucoma salicis NPV + SX, Lymantria dispar NPV + SX, Mamestra brassicae nucleus Polyhedral disease virus (Mamestra brassicae NPV) + SX, Mamestra configurata NPV + SX, Neodiprion abietis NPV) + SX, Neodiprion Recontain Nuclear polyhedrosis virus (Neodiprion lecontei NPV) + SX, Neodiprion sertifer NPV (Neodiprion sertifer NPV) + SX, Orgyia pseudotsugata NPV + SX, pepino mosaic・ Pepino mosaic virus CH2 isolate 1906 + SX, Putrimaea operculella granule disease virus (Phthorimaea operculella GV) + SX, Pieris rapae GV) + SX, Plodia interpunctella granule disease virus (Plodia interpunctella GV) + SX, Plutella xylostella granule disease Virus (Plutella xylostella GV)) + SX, Plutella xylostella GV + SX, Spodoptera albula mNPV) + SX, Spodoptera exempta mNPV)) + SX, Spodoptera frugiperda nuclear polyhedrosis virus (Spodoptera frugiperda mNPV) + SX, Spodoptera littoralis nuclear polyhedrosis virus (Spodoptera littoraliSX mVV BV-0004) , Spodoptera ritual nuclear polyhedrosis Virus (Spodoptera litura NPV) + SX, tobacco mild green tobamovirus U2 strain (Tobacco mild tobamovirus U2) + SX, Acaulospora spp. + SX, Ambispora spp. + SX, Archoseospora spp.) + SX, Claroideoglomus spp., formerly Glomus spp. Are Glomus claroideum) + SX, Diversispora spp. + SX, Entrophospora spp. + SX, Funeriformis spp., Formerly Glomus spp. + SX, Faneliformis mosseae (formerly Glomus mosseae) + SX, geo chiffon Species (Geosiphon spp.) + SX, Gigaspora spp. + SX, Gigaspora margarita + SX, Gigaspora rosea + SX, Glomus spp. + SX Glomus aggregatum + SX, Glomus deserticola + SX, Glomus monosporum + SX, Pacispora spp. + SX, Paraglomus spp. + SX, Paraglomus bramilia bra , Formerly Glomus brasillianum) + SX, Racocetra spp. + SX, Rhizophagus spp., Formerly Glomus spp.) + SX, Rhizophagus clarus, formerly Glomus clarum + SX, Rhizophagus intraradices (formerly Glomus intraradices) + SX, LA Zofagas intraradisis RTI-801 strain + SX, Rhizophagus irregularis (formerly Glomus intraradices, strain: DAOM 197198) + SX, Rhizophagus irregularis strain DAOM 197198 (Rhizophagus irregularis strain DAOM 197198) + SX, Scuterospora sp (Scutellospora spp.) + SX, Azorhizobium spp. + SX, Azorhizobium caulinodans + SX, Azospirillum amazonense + SX, Azospirillum brasilens X Strain (Azospirillum brasilense strain XOH) + SX, Azospirillum brasilense strain Ab-V5 (Azospirillum brasilense strain Ab-V5) + SX, Azospirillum brasilence strain Ab-V6 (Azospirillum brasilense strain Ab-V6) + SX, Azospirillum brasilense strain Ab-V5 Azospirillum caulinodans + SX, Azospirillum halopraeferens + SX, Azospirillum irakense + SX, Azospirillum lipoferum + SX, Bradirihibium zo + SX Bradyrhizobium elkanii strain + SX, Bradyrizobium elkanii strain SEMIA 587 (Bradyrhizobium elkanii strain SEMIA 587) + SX, Bradyrizobium elkanii strain SEMIA 5019 (Bradyrhizobium elkanii strain SEMIA 5019) + SX, SX bra Bradyrhizobium japonicum + SX, Bradyrizobium japonicum TA-11 (Bradyrhizobium japonicum strain TA-11) + SX, Bradyrhizobium japonicum USDA 110 (Bradyrhizobium japonicum strain USDA 110) + SX, Bradyrizobium Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Bradyrhizobium sp. (Arachis) + SX, Bradyrizobium sp (Vigna) + SX, Delftia acidovorans + SX, Delftia acidovorans RAY209 strain (Delftia acidovorans strain RAY209) + SX, Metylobacterium spp. + SX, MesorerizoSX + , Mesorhizobium huakii + SX, Mesorhizobium loti + SX, Mesorhizobium spp. + SX, Rhizobium etli + SX, Rhizobium eti .Faseori (Rhizob ium leguminosarum bv. Phaseoli) + SX, Rhizobium leguminosarum bv. Trifolii + SX, Rhizobium leguminosarum bv. Viciae + SX, trizorizo (Rhizobium tropici) + SX, Sinorhizobium fredii + SX, Sinorhizobium meliloti + SX.

  The mixing ratio of the present compound and this component is not particularly limited, but is 1000: 1 to 1: 1000, 500: 1 to 1: 500, 100: 1 to 1 by weight ratio (this compound: this component). 1: 100, 50: 1, 20: 1, 10: 1, 9: 1, 8: 1, 7: 1, 6: 1, 5: 1, 4: 1, 3: 1, 2: 1, 1: 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8, 1: 9, 1:10, 1:20, 1:50, and the like.

  This compound can be used in combination with or in combination with chemical fertilizers (such as ammonium sulfate, phosphorous acid, ammonium nitrate, urea, ammonium chloride).

  The harmful arthropod control composition of the present invention contains the present compound or composition A and an inert carrier (hereinafter referred to as the present composition). In the composition of the present invention, the present compound or the composition A is usually mixed with an inert carrier such as a solid carrier, a liquid carrier, a gaseous carrier, etc., and a surfactant and other formulation adjuvants are added as necessary. Emulsions, oils, powders, granules, wettable powders, flowables, microcapsules, aerosols, smokers, poisonous baits, resin formulations, shampoos, pastes, foams, carbon dioxide formulations, It is formulated into tablets. These preparations may be used after being processed into mosquito coils, electric mosquito mats, liquid mosquito traps, fumigants, fumigants, sheet preparations, spot-on agents, or oral treatments. The composition of the present invention usually contains 0.0001 to 95% by weight of the present compound or composition A.

  Examples of the solid carrier include clays (kaolin clay, diatomaceous earth, bentonite, acid clay), dry silica, wet silica, talc, ceramic, and other inorganic minerals (sericite, quartz, sulfur, activated carbon, calcium carbonate, etc.), Fine powder and granular materials such as chemical fertilizers (ammonium sulfate, phosphorous acid, ammonium nitrate, urea, ammonium chloride, etc.), and synthetic resins (polyester resins such as polypropylene, polyacrylonitrile, polymethyl methacrylate, polyethylene terephthalate, nylon-6, And nylon resins such as nylon-11 and nylon-66, polyamide resins, polyvinyl chloride, polyvinylidene chloride, and vinyl chloride-propylene copolymers).

  Examples of the liquid carrier include water, alcohols (methanol, ethanol, isopropyl alcohol, butanol, hexanol, benzyl alcohol, ethylene glycol, propylene glycol, phenoxyethanol, etc.), ketones (acetone, methyl ethyl ketone, cyclohexanone, etc.), aromatic hydrocarbons (Toluene, xylene, ethylbenzene, dodecylbenzene, phenylxylylethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, kerosene, light oil, etc.), esters (ethyl acetate, butyl acetate, isopropyl myristate, Ethyl oleate, diisopropyl adipglycerate, diisobutyl adipate, propylene glycol monomethyl ether acetate, etc.), nitriles (acetonitrile, Sobutyronitrile, etc.), ethers (diisopropyl ether, 1,4-dioxane, 1,2-dimethoxyethane, diethylene glycol dimethyl ether, diethylene glycol monomethyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, 3-methoxy-3-methyl-1 -Butanol etc.), amides (DMF, dimethylacetamide etc.), sulfoxides (DMSO etc.), propylene carbonate and vegetable oils (soybean oil, cottonseed oil etc.).

  Examples of the gaseous carrier include fluorocarbon, butane gas, LPG (liquefied petroleum gas), dimethyl ether, and carbon dioxide gas.

  Examples of the surfactant include nonionic surfactants such as polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, and polyethylene glycol fatty acid ester, and anions such as alkyl sulfonate, alkyl benzene sulfonate, and alkyl sulfate. Surfactant is mentioned.

  Other formulation adjuvants include sticking agents, dispersants, colorants, antifreezes and stabilizers, such as casein, gelatin, sugars (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin Derivatives, bentonites, synthetic water-soluble polymers (polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylic acids, etc.), acidic isopropyl phosphate, 2,6-di-tert-butyl-4-methylphenol, BHA (2-tert-butyl- 4-methoxyphenol and a mixture of 3-tert-butyl-4-methoxyphenol).

Examples of the base material of the resin preparation include vinyl chloride polymers, polyurethanes, etc., and these base materials include phthalic acid esters (dimethyl phthalate, dioctyl phthalate, etc.) and adipic acid esters as necessary. Further, a plasticizer such as stearic acid may be added. The resin formulation is obtained by kneading the present compound in the base material using a normal kneading apparatus, and then molding by injection molding, extrusion molding, press molding, etc., and if necessary, further undergoes molding, cutting, etc. , Plate-like, film-like, tape-like, net-like, or string-like resin preparations. These resin preparations are processed, for example, as animal collars, animal ear tags, sheet preparations, attracting strings, or gardening supports.
Examples of the bait base include cereal flour, vegetable oil, sugar, crystalline cellulose and the like, and if necessary, antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid, and preservatives such as dehydroacetic acid. Additives for preventing accidental eating by children and pets such as pepper powder, cheese flavoring, onion flavoring, and pest-attracting flavoring such as peanut oil are added.

  Moreover, you may add a coloring agent to a formulation. Examples of the colorant include a red pigment, a blue pigment, a green pigment, and a yellow pigment. Specific examples include monazole red, cyanine green, Prussian blue, and brilliant blue.

  The method for controlling harmful arthropods according to the present invention comprises an effective amount of the present compound or the composition of the present invention directly on harmful arthropods and / or habitats of harmful arthropods (plants, plant cultivation carriers, households). , Etc., by applying to animal bodies. The habitat mentioned here includes not only the place where harmful arthropods live, but also the place where they are expected to live. The harmful arthropod control method of the present invention is usually used in the form of the composition of the present invention.

  The plant cultivation carrier is a plant support and may be any material on which the plant can grow. Examples thereof include soil, a seedling mat, and water. Specific materials for the soil and nursery mat include, for example, sand, pumice, vermiculite, diatomaceous earth, gel material, polymer material, rock wool, glass wool, wood chip, and bark.

  In the control method of the present invention, the treatment amount of the composition of the present invention is the type of plant to be treated, the type and frequency of harmful arthropods to be controlled, formulation form, treatment time, treatment method, treatment place, weather conditions, etc. For example, the following may be mentioned.

  When the composition of the present invention is used for the control of harmful arthropods in the agricultural field, the application amount is the type of plant to be applied, the type and frequency of occurrence of pests to be controlled, the form of preparation, the application period, the application method, the application Although it can vary widely depending on the location, weather conditions, etc., it is usually 1 to 10000 g per ha at the application rate of this compound, and usually 1 to 10,000 g per ha at any one application rate of this component. When the composition of the present invention is formulated into an emulsion, wettable powder, flowable agent, etc., it is usually added with water so that the active ingredient concentration of any one of the present compound and this component is 0.01 to 10,000 ppm. Diluted and applied, and granules, powders, etc. are usually applied as they are.

  These preparations and water dilutions of these preparations may be sprayed directly on harmful arthropods or plants such as crops to be protected from harmful arthropods, and harmful arthropods that inhabit the soil of cultivated land. You may treat to this soil in order to control.

  Moreover, it can also process by the method of wrapping the resin formulation processed into the sheet form or the string form around the crop, stretching over the crop vicinity, and laying on the stock soil.

When the composition of the present invention is used for controlling harmful arthropods that inhabit a house, the application amount is the amount of the present compound per 1 m ² of treatment area when treated on the surface, usually 0.01 to 1000 mg. In the case of processing in a space, the amount of the present compound per 1 m ³ of the processing space is usually 0.01 to 500 mg. When the composition of the present invention is formulated into an emulsion, wettable powder, flowable, etc., it is usually diluted with water so that the active ingredient concentration is 0.1 to 10,000 ppm, and applied to oil, aerosol, Apply smoke smoke, poison bait, etc. as they are.

  When the composition of the present invention is used for controlling ectoparasites of domestic animals such as cattle, horses, pigs, sheep, goats and chickens, and small animals such as dogs, cats, rats and mice, it is applied to animals by methods known in veterinary medicine. Can be used. As a specific method of use, for the purpose of systemic suppression, for example, administration by tablet, feed mixing, suppository, injection (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.) is intended for non-systemic suppression. In this case, for example, an oil agent or an aqueous liquid is sprayed, a pour-on treatment or a spot-on treatment is performed, the animal is washed with a shampoo preparation, or a resin preparation is attached to the animal with a collar or ear tag. The amount of the present compound when administered to an animal body is usually in the range of 0.1 to 1000 mg per 1 kg body weight of the animal.

  In the present invention, the plant includes the whole plant and a specific part of the plant. Specific parts of plants include, for example, foliage, flowers, ears, fruits, trunks, branches, canopies, seeds, vegetative organs and seedlings.

  The vegetative reproductive organ means a plant root, stem, leaf or the like that has the ability to grow when the part is separated from the main body and placed in the soil. Examples of vegetative reproductive organs include tuberous root, creeping root, bulb, corm or solid bulb, tuber, rhizome, and stolon. , Rhizopholes, cane cuttings, propagules and vine cuttings. In addition, a toothpick is sometimes called a runner, and a basket is also called a pearl bud, and is divided into a granulation (broad bud) and a scale bud (bulbil). The vine means shoots (a general term for leaves and stems, shoot) such as sweet potatoes and yams. A bulb, a bulb, a tuber, a rhizome, a stem fragment, a root bearing body or a tuberous root is collectively called a bulb. For example, potato cultivation begins with planting tubers into soil, but the tubers used are commonly referred to as seed pods.

  Seedlings include seedlings and saplings.

  Examples of the treatment method of the composition of the present invention include foliage treatment, soil treatment, root treatment, shower treatment, smoke treatment, water surface treatment, and seed treatment.

Examples of the foliage treatment include a method in which the composition of the present invention is treated on the surfaces of foliage, tree trunks, fruits, flowers or ears.
Examples of the root treatment include a method of immersing the whole plant or the root in a chemical solution containing the composition of the present invention, and a method of attaching a solid preparation containing the composition of the present invention to the root of the plant.
Examples of soil treatment include soil spraying, soil mixing, and chemical irrigation into soil. In addition, examples of the place where soil treatment is performed include, for example, planting holes, rowing, near planting holes, near rowing, the entire cultivation area, plant land, inter-stock, under-trunk, main trunk, cultivation soil, nursery box, raising seedling. Examples include trays and nurseries. Examples of the treatment time include the sowing time before sowing, at the time of sowing, after sowing, the seedling raising period, before planting, at the time of planting, and after the planting. Moreover, in the said soil treatment, this invention composition may be processed to a plant simultaneously, and solid fertilizers, such as paste fertilizer containing this invention composition, may be applied to soil. Moreover, you may mix with an irrigation liquid, for example, the injection | pouring to irrigation equipments (irrigation tube, irrigation pipe, a sprinkler, etc.), the mixing to a streak water solution, mixing to a hydroponic liquid etc. are mentioned. In addition, the irrigation liquid and the active ingredient can be mixed in advance, and can be treated using an appropriate irrigation method such as the above irrigation method or other watering or watering.
As a root part process, the method of immersing the root part of a plant with the dilution liquid of this invention composition is mentioned, for example.
As a shower process, the method of showering the dilution liquid of this invention composition on the fruit after harvest is mentioned, for example.
The soot treatment includes, for example, a method in which the diluted solution of the composition of the present invention is made into a mist and scattered in the air and attached to the foliage and fruits of plants.
Such water surface treatment includes, for example, a method of spraying a chemical solution containing the composition of the present invention or a solid preparation containing the composition of the present invention onto a flooded paddy field.
Seed treatment includes, for example, treatment of the composition of the present invention to seeds or vegetative reproductive organs. Specifically, for example, the suspension of the composition of the present invention is atomized to form a seed surface or vegetative reproductive organ surface. Spraying treatment, smearing treatment in which the composition of the present invention is applied to seeds or vegetative organs, immersion treatment in which seeds are immersed in a chemical solution of the composition of the present invention for a certain period of time, seeds with a carrier containing the composition of the present invention Examples thereof include a method of coating a vegetative organ (for example, film coating treatment, pellet coating treatment, etc.). As the above-mentioned vegetative reproductive organs, seed pods are particularly mentioned.

  More specifically, the treatment method of the composition of the present invention includes planting treatment (planting hole spraying, planting hole treatment soil mixing), plant source processing (stock source spraying, strain source soil mixing, strain source irrigation, late seedling stage) Plant root treatment), grooving treatment (spreading grooving, mixing grooving soil), cropping treatment (spreading spraying, mixing of soil with soil, sprinkling with growing season), cropping treatment at sowing (spreading at the time of sowing) , Soil mixing at the time of sowing), whole surface treatment (spreading whole surface soil, whole surface soil mixing), side strip processing, water surface treatment (water surface application, water surface application after flooding), other soil spraying treatment (growth season foliar spray) , Under the crown or around the trunk, soil surface spray, soil surface mixing, sowing hole spray, buttocks land surface spray, inter-plant spray), other irrigation treatment (soil irrigation, seedling irrigation, chemical injection, local irrigation, Chemical solution drip irrigation, Chemigation), seedling box processing (nursing box spraying, seedling box irrigation, seedling box chemical solution Water), seedling tray treatment (nursing tray spraying, seedling tray irrigation, seedling tray irrigation, seedling tray submergence), seedling treatment (seedbed spraying, seedbed irrigation, water seedling seedling spraying, seedling soaking), bed soil mixing treatment (bed soil mixing, seeding) Pre-floor soil mixing, sowing before sowing, sowing after sowing, soaking, and other treatments (culture soil mixing, plowing, topsoil mixing, raindrop soil mixing, planting position treatment, granule inflorescence spraying, It may be called paste fertilizer admixture, hydroponic liquid admixture, hydroponic liquid mixture).

  When this compound is applied to seeds or vegetative reproductive organs, the application amount of this compound is usually 0.001 to 100 g, preferably 0.01 to 50, more preferably 0.1 per kg of seed or vegetative reproductive organs. -10 g. In addition, when this component is added to this compound and applied, the application amount per one component is usually 0.001 to 100 g, preferably 0.01 to 50, more preferably 1 kg per seed or vegetative organ. 0.1 to 10 g.

  The composition of the present invention can be used as a pest control agent for harmful arthropods in agricultural fields such as fields, paddy fields, orchards, and non-agricultural land such as lawns and forests.

Plants that can use the composition of the present invention include, for example, the following crops: corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugar cane, tobacco, Triticale, kidney bean, lentil, cowpea, mung bean, tunned bean, safflower bean, bamboo shoot, moss bean, tepary bean, broad bean, pea, chickpea, lentil, lupine, yellow bean, alfalfa, etc.
Vegetables: Solanum vegetables (eggplants, tomatoes, peppers, peppers, potatoes, bell peppers, etc.), cucumbers (cucumbers, pumpkins, zucchini, watermelons, melons, squash, etc.), cruciferous vegetables (radish, turnip, horseradish, Cole rabi, Chinese cabbage, cabbage, mustard, broccoli, cauliflower, etc.), Asteraceae vegetables (burdock, shungiku, artichoke, lettuce, etc.), lily family vegetables (leek, onion, garlic, asparagus), celery family vegetables (carrot, Parsley, celery, American scallop, etc.), red crustacean vegetables (spinach, chard, etc.), perilla vegetables (perilla, mint, basil, lavender, etc.), strawberry, sweet potato, yam, taro, etc., flower buds, houseplants,
Fruit trees; pears (apples, pears, Japanese pears, quince, quince, etc.), nuclear fruits (peaches, plums, nectarines, ume, sweet cherry, apricots, prunes, etc.), citrus (satsuma mandarin, orange, lemon, lime, grapefruit) ), Nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, banana, coffee, Date palm, coconut palm, etc.
Trees other than fruit trees: Cha, mulberry, flowering trees, street trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak, poplar, redwood, fu, sycamore, zelkova, black bean, peach tree, Tsuga, rat, pine, Spruce, yew), etc.
Shiva and pasture.

  The above-mentioned plant varieties are not particularly limited as long as they are generally cultivated varieties.

  The aforementioned plant may be a plant that can be produced by natural mating, a plant that can be generated by mutation, an F1 hybrid plant, or a transgenic plant (also referred to as a genetically modified plant). These plants generally have resistance to herbicides, accumulation of toxic substances against pests (also called pest resistance), suppression of susceptibility to diseases (also called disease resistance), increased yield potential, biological and abiotic stress factors It has characteristics such as improvement in resistance to quality, modification of product quality (for example, increase / decrease in content of components, change in composition, improvement in storage stability or processability).

  An F1 hybrid plant is a first-generation hybrid obtained by crossing two varieties of varieties, and is generally a plant having characteristics of hybrid strength having a trait superior to both of parents. Transgenic plants have the characteristics that foreign genes are introduced from other organisms such as microorganisms and cannot be easily obtained by cross breeding, mutagenesis or natural recombination in the natural environment. It is a plant.

Examples of the technique for producing the above plant include conventional breeding techniques; gene recombination techniques; genome breeding techniques; new breeding techniques; genome editing techniques. The conventional breed improvement technique is a technique for obtaining a plant having desirable properties by mutation or crossing. Genetic recombination technology is a technology that gives a new property to an organism by removing the target gene (DNA) from one organism (for example, a microorganism) and introducing it into the genome of another target organism. Antisense technology or RNA interference technology that confer new or improved properties by silencing other genes present. The genome breeding technique is a technique for improving the efficiency of breeding using genome information, and includes DNA marker (also referred to as genome marker or gene marker) breeding technique and genomic selection. For example, DNA marker breeding is a method in which a progeny having a target useful trait gene is selected from a large number of mating progeny using a DNA marker, which is a DNA sequence that serves as a marker for the location of a specific useful trait gene on the genome is there. By analyzing the progeny of the mating plant using a DNA marker when it is a young plant, it has a feature that the time required for breeding can be effectively shortened.
Genomic selection is a technique that creates prediction formulas from previously obtained phenotypes and genome information, and predicts characteristics without evaluating phenotypes from prediction formulas and genome information, contributing to efficient breeding. It is possible technology. New breeding technology (new breeding technigues) is a general term for breeding (breeding) technology combining molecular biological techniques. For example, cisgenesis / intragenesis, oligonucleotide-directed mutagenesis, RNA-dependent DNA methylation, genome editing, grafting to GM rootstock or hogi, reverse breeding, agroinfiltration, seed production technology (Seed Production) Technology, SPT). The genome editing technique is a technique for converting genetic information in a sequence-specific manner, and can delete base sequences, replace amino acid sequences, introduce foreign genes, and the like. For example, zinc finger nuclease (Zinc-Finger, ZFN), Talen (TALEN), Crisper Cassine (CRISPR / Cas9), Crisper CP1 (CRISPER / Cpf1) that can sequence-specific DNA cleavage There are sequence-specific genome modification technologies such as Meganuclease and CAS9 nickase and Target-AID, which are created by modifying the aforementioned tools.

  The above-mentioned plant can be registered, for example, in a genetically modified crop in an electronic information site (http://www.isaaa.org/) of the INTERNATINAL SERVICE for the ACQUISITION of AGRI-BIOTECH APPLICATIONS, ISAAA. Plants listed in the database (GM APPROVAL DATABASE). More specifically, herbicide-tolerant plants, pest-tolerant plants, disease-tolerant plants, quality modification of products (for example, increase / decrease in content of components, change in composition, improvement in preservability or processability) plants, fertile traits There are modified plants, abiotic stress-tolerant plants, or modified plants with traits for growth and yield.

Examples of plants given herbicide tolerance are listed below.
The mechanism of resistance to herbicides is the rapid metabolism (degradation, modification, etc.) of drugs by the expression of enzymes that inactivate drugs, which reduces the affinity between the drug and its target, or the incorporation of drugs into plants or It can be obtained by inhibiting migration in plants.

Plants to which herbicide tolerance has been imparted by genetic recombination technology include protoporphyrinogen oxidase (hereinafter abbreviated as PPO) herbicides such as flumioxazin, 4-hydroxyphenylpyruvate diacids such as isoxaflutol and mesotrione. 5 inhibitors such as oxygenase (hereinafter abbreviated as HPPD) inhibitors, imidazolinone herbicides containing imazetapyr and acetolactate synthase (hereinafter abbreviated as ALS) inhibitors such as sulfonylurea herbicides containing thifensulfuronmethyl -Enolpyruvylshikimate-3-phosphate synthase (hereinafter abbreviated as EPSP) inhibitors, glutamine synthetase inhibitors such as glufosinate, auxin-type herbicides such as 2,4-D and dicamba, and oxynyl containing bromoxynil Also included are plants to which resistance to herbicides has been conferred by genetic recombination techniques. Preferred herbicide-tolerant transgenic plants are grains such as wheat, barley, rye, oat, canola, sorghum, soybean, rice, rapeseed, sugar beet, sugar cane, grape, lentil, sunflower, alfalfa, pomegranate, nuclear fruit, Vegetables such as coffee, tea, strawberry, buckwheat, tomato, potato, cucumber, lettuce, more preferably grains such as wheat, barley, rye, oat, soybean, rice, vine, tomato, potato, pear is there.
The specific herbicide-tolerant plants are shown below.
Glyphosate herbicide-tolerant plants; glyphosate-resistant EPSPS gene (CP4 epsps) derived from Agrobacterium tumefaciens strain CP4, glyphosate metabolizing enzyme (glyphosate N-acetyl transferase) derived from Bacillus licheniformis Z) Glyphosate metabolizing enzyme gene (gat4601, gat4621), glyphosate metabolizing enzyme derived from Ochrobacterum anthropi strain LBAA (glyphosate oxidase gene, goxv247), It is obtained by introducing one or more EPSPS genes (mepsps, 2mepsps) having a glyphosate resistance mutation derived from maize. The main plants are alfalfa (Medicago sativa), Argentine canola (Brassica napus), cotton (Gossypium hirsutum L.), creeping bentgrass (Agrostis stolonifera), corn (Zea mays L.) polish canola (Brassica rapa), potato ( Solanum tube HDDrosum L.), soybean (Glycine max L.), sugar beet (Beta vulgaris), wheat (Triticum aestivum). Several glyphosate-tolerant transgenic plants are commercially available. For example, transgenic plants expressing glyphosate-resistant EPSPS derived from Agrobacterium are trade names including “Roundup Ready (registered trademark)”, and glyphosate-metabolizing enzyme derived from Bacillus bacteria whose metabolic activity has been enhanced by shuffling technology. Recombinant plants that express EPSPS with a glyphosate-resistant mutation derived from corn under the trade names of “Optimum (registered trademark) GAT (trademark)”, “Optimum (registered trademark) Gly canola”, etc. Is marketed under the trade name “GlyTol ™”.
Glyphosate herbicide-tolerant plants: Phosphinothricin N-acetyltransferase (PAT) gene (bar), Streptomyces hygroscopicus, a glufosinate metabolizing enzyme derived from Streptomyces hygroscopicus Phosphinothricin N-acetyltransferase (PAT) enzyme gene (pat), a glufosinate metabolizing enzyme derived from Nes (Streptomyes viridochromogenes), or synthesized from the Streptomyces viridochromogenes strain Tu494 (Streptomyes viridochromogenes strain Tu494) It is obtained by introducing one or more pat genes (pat syn). The main plants are Argentine canola (Brassica napus), chicory (Cichorium intybus) cotton (Gossypium hirsutum L.), maize (Zea mays L.) polish canola (Brassica rapa), rice (Oryza sativa L.), soybean (Glycine max L.) and sugar beet (Beta vulgaris). Several glufosinate-tolerant transgenic plants are commercially available. Glyphosate metabolizing enzyme (bar) derived from Streptomyces hygroscopicus and transgenic plants derived from Streptomyes viridochromogenes are "LibertyLink (trademark)", "InVigor (trademark)", "WideStrike ( Trademarks) ”are sold under the trade name. Oxynyl herbicide (eg, bromoxynil) resistant plant; Oxynyl herbicide introduced with nitrilase gene (bxn), a metabolic enzyme derived from Klebsiella pneumoniae subsp. Ozaenae For example, there are bromoxynil resistant transgenic plants. Major plants include Argentine canola (Brassica napus), cotton (Gossypium hirsutum L.), and tobacco (Nicotiana tabacum L.). , “Navigator ™ canola” or “BXN ™”. ALS herbicide-tolerant plants; carnation (Dianthus caryophyllus) “Moondust ™”, “Moonshadow ™”, “Moonshade” introduced with ALS herbicide-resistant ALS gene (surB) from tobacco (Nicotiana tabacum) as a selection marker (TM), Moonlite (TM), Moonaqua (TM), Moonvista (TM), Moonique (TM), Moonpearl (TM), Moonberry (TM), Moonvelvet ( Trademark); ALS (Linum usitatissumum L.) “CDC Triffid Flax” introduced with an ALS herbicide-resistant ALS gene (als) from Arabidopsis thaliana; ALS herbicide-resistant ALS gene (zm- hra) maize (Zea mays L.) “Optimum ™ GAT ™” resistant to sulfonylurea and imidazolinone herbicides introduced; Arabidopsis ALS herbicide-resistant ALS gene (csr1-2) Imidazolinone-based herbicide Tolerant soybean “Cultivance”; Soybean “Treus (trademark)”, “Plenish (trademark)” resistant to sulfonylurea herbicides introduced with ALS herbicide-resistant ALS gene (gm-hra) derived from soybean (Glycine max) ) ”And“ Optimum GAT ™ ”. In addition, there is a cotton into which an ALS gene (S4-HrA) resistant to an ALS herbicide derived from tobacco (Nicotiana tabacum cv. Xanthi) is introduced. HPPD herbicide-tolerant plants; resistant to homeotrione, a glufosinate metabolizing enzyme from HPPD gene (avhppd-03) and Streptomyes viridochromogenes resistant to mesotrione from Avena sativa Soybean introduced with the N-acetyltransferase (PAT) enzyme gene (pat) at the same time is sold under the trade name “Herbicide-tolerant Soybean line”.
2,4-D resistant plant; the 2,4-D metabolic enzyme, aryloxyalkanoate dioxygenase gene (aad-1) derived from Sphingobium herbicidovorans The introduced corn is sold under the trade name Enlist ™ Maize. There are soybeans and cotton introduced with the allyloxyalkanoate dioxygenase gene (aad-12), a 2,4-D metabolic enzyme derived from Delftia acidovorans. Trademark of “Enlist ™ Soybean” It is sold by name.
Dicamba resistant plants: soybean and cotton introduced with a dicamba monooxygenase gene (dmo), which is a dicamba metabolizing enzyme derived from Stenotrophomonas maltophilia strain DI-6. A soybean (Glycine max L.) into which a glyphosate-resistant EPSPS gene (CP4 epsps) derived from Agrobacterium tumefaciens strain CP4 (Agrobacterium tumefaciens strain CP4) was introduced at the same time as the above gene was "Genuity (R) Roundup Ready ( Trademark) 2 Xtend (TM) ".
Examples of commercially available transgenic plants with herbicide tolerance include corn that is resistant to glyphosate: Roundup Ready Corn, Roundup Ready 2, Agrisure GT, Agrisure GT / CB / LL "Agrisure GT / RW", "Agrisure 3000GT", "YieldGard VT Rootworm / RR2" and "YieldGard VT Triple"; soybeans "Roundup Ready Soybean" and "Optimum GAT" that are resistant to glyphosate; Resistant cotton "Roundup Ready Cootton", "Roundup Ready Flex"; glyphosate resistant canola "Roundup Ready Canola"; glyphosate resistant alfalfa "Roundup Ready Alfalfa", glyphosate resistant rice "Roundup Ready Rice"; Maize that is resistant to glufosinate, Roundup Ready 2, Liberty Link, Herculex 1, Herculex RW, Herculex X tra, “Agrisure GT / CB / LL”, “Agrisure CB / LL / RW” and “Bt10”; cotton “FiberMax Liberty Link” resistant to glufosinate; rice “Liberty Link Rice” resistant to glufosinate; Canola "in Vigor" resistant to glufosinate; Rice "Liberty Link Rice" (Bayer product) resistant to glufosinate; Cotton "BXN" resistant to bromoxynil; Canola "Navigator" resistant to bromoxynil, " Compass ";canola" InVigor "and with glufosinate tolerance. Additional plants modified with respect to herbicides are widely known, such as alfalfa, apple, barley, eucalyptus, flax, grape, lentil, rapeseed, pea, potato, rice, sugar beet, resistant to glyphosate, Sunflower, tobacco, tomato beetle and wheat (see for example US5188642, US4940835, US5633435, US5804425, US5627061); bean, cotton, soybean, pea, potato, sunflower, tomato, tobacco, corn resistant to dicamba , Sorghum and sugarcane (see eg WO2008051633, US7105724 and US5670454); soybean, sugar beet, potato, tomato and tobacco resistant to glufosinate (see eg US6376754, US5646024, US5561236); 2,4-D Cotton, pepper that is resistant to , Apple, tomato, sunflower, tobacco, potato, corn, cucumber, wheat, soybean, sorghum and millet (see, for example, US6153401, US6100446, WO2005107437, US5608147 and US5670454); attractor synthase (ALS) inhibitor herbicide (For example, canola, corn, millet, barley, cotton, mustard, lettuce, lentil, melon, millet, oat, nata, potato, rice having resistance to sulfonylurea herbicide and imidazolinone herbicide , Rye, sorghum, soybean, sugar beet, sunflower, tobacco, tomato and wheat (see, for example, US5013659, WO2006060634, US4761373, US5304732, US6211438, US6211439 and US6222100), especially rice that is resistant to imidazolinone herbicides Acetolactate synthesis gene (a Rice having a specific mutation (eg, S653N, S654K, A122T, S653 (At) N, S654 (At) K, A122 (At) T) in cetohydroxyacid synthase gene is known (eg, US 2003/0217381 , WO200520673); HPPD-inhibiting herbicides (eg, isoxazole herbicides such as isoxaflutole, triketone herbicides such as sulcotrione and mesotrione, pyrazole herbicides such as pyrazolinate, and degradation products of isoxaflutole Barley, sugarcane, rice, corn, tobacco, soybean, cotton, rapeseed, sugar beet, wheat and potato (see for example WO2004 / 055191, WO199638567, WO1997049816 and US6791014); protoporphyrinogen oxidase (PPO) Wheat, soybean, cotton, sugar beet, rapeseed, rice, corn resistant to inhibitory herbicides Stiffness, a sorghum, sugar cane and sugar beet (for example, US2002 / 0073443, US2008 / 0052798, Pest Management Science, 61, 2005, see 277-285).

  Plants to which herbicide tolerance has been imparted by conventional cultivar improvement technology or genome breeding technology include, for example, rice `` Clearfield Rice '', wheat `` tolerant to imidazolinone-based ALS-inhibiting herbicides such as imazetapil and imazamox '' Clearfield Wheat ", sunflower" Clearfield Sunflower ", lentil" Clearfield lentils "and canola" Clearfield canola "(BASF products); sulfonyl ALS-inhibiting herbicide-resistant soybeans such as Thifensulfuron methyl" STS soybean "; Trion oxime And cetoxydim-resistant corn "SR corn" and "Poast Protected (registered trademark) corn" resistant to acetyl-CoA carboxylase inhibitors such as aryloxyphenoxypropionic acid herbicides; resistant to sulfonylurea herbicides such as tribenuron Sunflower "ExpressSun (registered trademark)" There are rice “Provisia ™ Rice” resistant to acetyl-CoA carboxylase inhibitors such as Lohop; canola “Triazine Tolerant Canola” resistant to PSII inhibitors.

  Canola "SU Canola (registered trademark)" with sulfonylurea herbicide tolerance using rapid cultivar development technology (Rapid Trait Development System, RTDS (registered trademark)) as a plant that has been given herbicide tolerance by genome editing technology Is mentioned. RTDS (registered trademark) corresponds to the introduction of oligonucleotide-directed mutagenesis in genome editing technology. Gene repair Oligonucleotide (GRON), that is, cleaving DNA in plants through DNA and RNA chimeric oligonucleotides It is a technology that can introduce mutations without any problems. Also, maize with reduced herbicide tolerance and phytic acid content by deleting the endogenous gene IPK1 using zinc finger nuclease (see Nature 459, 437-441 2009); using Chrisper Cassine Examples of imparting herbicide tolerance to rice (see, for example, Rice, 7, 5 2014).

  As a plant to which herbicide tolerance has been imparted by a new breeding technique, soybeans in which the properties of a GM rootstock are imparted to hogi using a variety improvement technique using grafts can be mentioned. Specific examples include soybeans to which glyphosate tolerance is imparted to non-transgenic soybean spikelets using Roundup Ready (registered trademark) soybeans having glyphosate tolerance as rootstocks (see Weed Technology 27: 412-416 2013). .

  Examples of plants imparted with pest resistance are listed below.

Encodes delta-endotoxin (δ-endotoxin), an insecticidal protein derived from the soil bacterium Bacillus thuringiensis (hereinafter abbreviated as Bt), as an example of a plant that has been rendered resistant to lepidopteran pests by genetic engineering. Maize (Zea mays L.), soybean (Glycine max L.), cotton (Gossypium hirsutum L.), rice (Oryza sativa L.), poplar (Populus sp.), Tomato (Lycopersicon esculentum), eggplant There are plants such as (Solanum melongena). Cry1A, Cry1Ab, modified Cry1Ab (partially deleted Cry1Ab), Cry1Ac, Cry1Ab-Ac (a hybrid protein in which Cry1Ab and Cry1Ac are fused), Cry1C, Cry1F , Cry1Fa2 (modified cry1F), moCry1F (modified Cry1F), Cry1A. 105 (a hybrid protein in which Cry1Ab, Cry1Ac, and Cry1F are fused), Cry2Ab2, Cry2Ae, Cry9C, Vip3A, Vip3Aa20, and the like. Examples of plants that have been given resistance to Coleoptera by genetic recombination technologies include plants such as corn and potato that have been introduced with a gene encoding delta-endotoxin, an insecticidal protein derived from soil bacteria Bt. . Examples of delta-endotoxins that confer resistance to Coleoptera include Cry3A, mCry3A (modified Cry3A), Cry3Bb1, Cry34Ab1, and Cry35Ab1. As an example of a plant that has been given resistance to Diptera pests by gene recombination technology, gene recombination that has introduced a synthetic gene encoding hybrid protein eCry3.1Ab, which is a fusion of Cry3A and Cry1Ab derived from soil bacteria Bt There is a genetically modified cotton (Gossypium hirsutum L.) into which a gene encoding a trypsin inhibitor CpTI derived from maize (Zea mays L.) and cowpea (Vigna unguiculata) is introduced. Furthermore, there is a genetically modified poplar into which a gene encoding API, which is a protease inhibitor protein A derived from squittaria sagittifolia, and exhibits resistance to a wide range of pests.
Insecticidal proteins that impart pest resistance to plants include hybrid proteins of the above-mentioned insecticidal proteins, partially missing proteins, and modified proteins. The hybrid protein is produced by a combination of different domains of a plurality of insecticidal proteins using genetic recombination technology, and Cry1Ab-Ac and Cry1A. 105 etc. are known. As a protein lacking a part, Cry1Ab and the like lacking a part of the amino acid sequence are known. Examples of the modified protein include proteins in which one or more amino acids of the natural delta-endotoxin are substituted, and Cry1Fa2, moCry1F, mCry3A and the like are known. In addition, as in the case of Cry3A055 in which a cathepsin D-recognition sequence is inserted into Cry3A toxin (see WO2003 / 018810) and the like, it is preferable to recognize non-naturally occurring proteolytic enzymes. The sequence is inserted into the toxin.
Cotton (event MON88702) introduced with modified BT protein Cry51Aa2 (Cry51Aa2.834_16) by gene recombination technology has been developed by Monsanto, and the genus lygus such as Lygus lineolaris and the hemipods such as aphids and Frankliniella Resistant to thrips such as genus species.
In addition, insecticidal proteins derived from Bacillus cereus and Bacillus popilliae, and plant insecticidal proteins derived from Bt bacterium AB88 strains, which impart pest resistance to plants by genetic recombination technology Vip1, Vip2, Vip3, Vip3A, Photorhabdus spp. Such as Photorhabdus luminescens and Xenorhabdus nepophilus Xenorhabdus spp. Toxic bacteria (to colonize insects), toxins produced by animals including insect-specific neurotoxins such as scorpion toxins, spider toxins, bee toxins, fungal toxins such as Streptomycetes toxins, peas Lectins, barley lectins and snowdrop recties Plant lectins such as, agglutinin, trypsin inhibitor, serine protease inhibitor, protease inhibitor such as patatin, cystatin, papain inhibitor, ribosome inactive such as lysine, corn-RIP, abrin, ruffin, saporin, bryodin Ion channels such as phosphoprotein (RIP), 3-hydroxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, steroid metabolic enzymes such as cholesterol oxidase, ecdysone inhibitor, HMG-CoA-reductase, sodium channel or calcium channel inhibitor Inhibitors, juvenile hormone esterase, diuretic hormone receptor, stilbene synthase, bibenzyl synthase, chitinase, glucanase and the like.

In addition, plants that have been given pest resistance by introducing one or more insecticidal protein genes are already known, and some plants are commercially available. Examples of cotton imparted with pest resistance include “Bollgard ™ cotton”, “BXN ™ Plus Bollgard ™ Cotton”, “BXN ™ Plus Bollgard” that expresses the insecticidal protein Cry1Ac derived from Bt bacteria "Cotton", "JK 1", "Roundup Ready (TM) Bollgard (TM) Cotton" and "Ingard (TM)", Herculex (TM) expressing insecticidal protein modified Cry1F (Cry1Fa2) from Bt bacteria ”I” and “Herculex ™ CB”; “VIPCOT ™ Cotton” expressing the insecticidal protein Vip3A from Bt; “Bollgard II ™” expressing the insecticidal proteins Cry1Ac and Cry2Ab from Bt "cotton", "Roundup Ready (TM) Bollgard II (TM) Cotton", "Roundup Ready (TM) Flex (TM) Bollgard II (TM) Cotton" and "Fivermax (TM) Liberty Link (TM) Bollgard II (TM)"; Expresses insecticidal proteins Cry1Ac, Cry2Ab and Vip3A from Bt bacteria “Bollgard III (registered trademark)” and “Bollgard (registered trademark) III x Roundup Ready (trademark) Flex (trademark)”, “VIPCOT (trademark) Roundup Ready Flex (expressing the insecticidal proteins Vip3A and Cry1Ab derived from Bt bacteria” (Trademark) Cotton ”;“ VIPCOT (registered trademark) ”expressing insecticidal proteins Vip3A and Cry1Ac derived from Bt bacteria;“ WideStrike ™ Cotton ”,“ WideStrike (expressing Cry1Ac, Cry1F derived from Bt bacteria) (Trademark) Roundup Ready (trademark) Cotton "and" Widestrike (trademark) Roundup Ready Flex (trademark) Cotton ";" VIPCOT (trademark) Cotton "which expresses the insecticidal protein Vip3A derived from Bt bacteria; insecticidal protein derived from Bt bacteria “TwinLink ™ Cotton” and “Glytol ™ x Twinlink ™” expressing Cry1Ab and Cry2Ae; “Widestrike® 3” expressing the insecticidal proteins Cry1Ac, Cry1F and Vip3A from Bt and "Widestrike (TM) x Roundup Ready Flex (TM) x VIPCOT (TM) C “otton”; “Glytol ™ x Twinlink ™ x VIPCOT ™ Cotton” expressing the insecticidal proteins Cry1Ab, Cry2Ae and Vip3A from Bt bacteria.
Examples of pest-resistant corn include “YieldGard (registered trademark) Rootworm RW”, “YieldGard (registered trademark) RW + RR”, and “YieldGard (registered trademark) VT (trademark) that express the insecticidal protein Cry3Bb1 derived from Bt bacteria. ”Rootworm ™ RR2” and “MaxGard ™”; “YieldGard® VT Triple” and “YieldGard ™ Plus with RR” expressing the insecticidal proteins Cry3Bb1 and Cry1Ab from Bt; "Bt Xtra (trademark) Maize" expressing the insecticidal protein Cry1Ac derived from "YieldGard Plus (registered trademark)" expressing the insecticidal proteins Cry1Ab and Cry3Bb1 derived from Bt; expressing the insecticidal protein Cry1Ab derived from Bt “Bt10”, “Liberty Link ™ Yieldgard ™ Maize”, “Agrisure ™ GT / CB / LL” and “YieldGard ™ CB + RR”; insecticidal protein Cry1A from Bt. “YieldGard ™ VT Pro ™” and “Genuity ™ VT Double Pro ™” expressing 105 and Cry2Ab2; “Agrisure ™ RW” expressing the insecticidal protein mCry3A from Bt bacteria And “Agrisure ™ GT / RW”; “Starlink ™ Maize” expressing the insecticidal protein Cry9C from Bt bacteria; “YieldGard ™” expressing the insecticidal protein Cry1Ab from Bt bacteria; MaizeGard (TM), NaturGard KnockOut (TM), Maximizer (TM), Roundup Ready (TM) YieldGard (TM) maize, Agrisure (TM) CB / LL, and Mavera (TM) YieldGard (Trademark) Maize ”;“ Agrisure® 3122 ”expressing the insecticidal proteins Cry1Ab, Cry1F, modified Cry3A, Cyr34Ab1 and Cyr35Ab1 derived from Bt;“ Agrisure (registered) expressing the insecticidal protein Vip3Aa20 derived from Bt (Trademark) Viptera ";" Agri "expressing the insecticidal proteins Vip3Aa20 and Cry1Ab from Bt bacteria sure (registered trademark) Viptera (registered trademark) 2100 ”and“ Agrisure (registered trademark) Viptera (registered trademark) 3110 ”;“ Agrisure (registered trademark) Viptera ( (Trademark) 3100 "," Agrisure (registered trademark) Viptera (trademark) 3111) "and" Agrisure (registered trademark) Viptera (trademark) 4 ";" Agrisure ("Cry1Ab" expressing the insecticidal protein Vt3Aa20 and modified Cry1F derived from Bt (Registered trademark) Viptera (trademark) 3220 ";" Agrisure (registered trademark) Duracade (trademark) "expressing insecticidal protein eCry3.1Ab (chimeric protein of Cry3A-Cry1Ab) derived from Bt; insecticidal protein derived from Bt eCry3.1Ab (Cry3A-Cry1Ab chimeric protein), “Agrisure® Duracade ™ 5122” expressing modified Cry3A, Cry1Ab and modified Cry1F; insecticidal protein eCry3.1Ab (Cry3A-Cry1Ab Chimeric protein), modified Cry3A, modified Cry1Ab "Agrisure (R) Duracade (TM) 5222" expressing the Vip3A mutant and "Herculex (TM) RW" expressing Cyr34Ab1 and Cyr35Ab1 derived from Bt; insecticidal protein Cyr34Ab1, derived from Bt; “Herculex XTRA ™” expressing Cyr35Ab1 and Cry1F; the insecticidal protein Cry1A from Bt. 105, “Genuity® VT Triple Pro ™” expressing Cry2Ab2 and Cry3Bb1; insecticidal proteins Cry1F, Cry2Ab, Cyr34Ab1, Cyr35Ab1, Cry3Bb1 and Cry1A. “Genuity® SmartStax ™” expressing 105; insecticidal protein modified Cry1F, Cry2Ab and Cry1A. “Power Core ™” expressing 105; insecticidal protein modified Cry1F from Bt bacteria, “Herculex XTRA ™ RR” expressing Cyr34Ab1, Cyr35Ab1; insecticidal protein modified Cry1F, Cyr34Ab1, Cyr35Ab1 from Bt bacteria "Optimum (registered trademark) Intrasect Xtreme" expressing Cry1Ab and modified Cry3A; "Optimum (registered trademark) Intrasect XTRA" expressing insecticidal protein modified Cry1F, Cyr34Ab1, Cyr35Ab1, Cry1Ab derived from Bt; “Optimum® TRIsect” expressing the insecticidal protein modified Cry1F and modified Cyr3A is commercially available.
Examples of other pest-resistant plants include potatoes expressing the insecticidal protein Cry3A derived from Bt bacteria "Atlantic NewLeaf (trademark) potato", "NewLeaf (trademark) Russet Burbank potato", "Lugovskoi plus", " “Elizaveta plus”, “Hi-Lite NewLeaf ™ Y potato, Superior NewLeaf ™ potato” and “Shepody NewLeaf ™ Y potato”; rice expressing the insecticidal proteins Cry1Ab and Cry1Ac derived from Bt “hanyou 63 And “Huahui-1”; soybean “Intacta ™ Roundup Ready ™ 2 Pro” expressing the insecticidal protein Cry1Ac derived from Bt; eggplant “BARI Bt Begun expressing the insecticidal protein Cry1Ac derived from Bt -1, -2, -3 and -4 "are commercially available.
For example, corn “YieldGard corn rootworm” and “YieldGard VT”, “Herculex RW” and “Herculex Rootworm” and “Agrisure CRW” having resistance to corn rootworm; Corn “YieldGard corn borer” having resistance to corn borer "YieldGard plus" and "YieldGard VT Pro", "Agrisure CB / LL" and "Agrisure 3000GT""HerculesI" and "Hercules II", "KnockOut", "NatureGard" and "StarLink", Western bean cut worm, Corn Borer, Black Cut Worm and Fall Army Worm resistant corn "Herculex I" and "Herculex Xtra", "NewLeaf", "NewLeaf Y" and "NewLeaf Plus"; resistant to corn borer and corn root worm Maize “YieldGard Plus”; resistance to fake American tobacco Cotton "Bollgard I" and "Bollgard II" having the following properties: Fake American tobacco moth, cotton ball worm, fall army worm, beet army worm, cabbage looper, soybean looper and pink ball worm cotton "Bollgard II", " WideStrike ”and“ VipCot ”; Potatoes with resistance to tobacco tin mega“ NewLeaf ”,“ NewLeaf Y ”and“ NewLeaf Plus ”; Eggplants“ Bt brinjal ”,“ Dumaguete Long ”with resistance to eggplant moths, fruit borers and cotton ball worms Purple "," Mara "(see, for example, US5128130).
Additional plants with insecticide resistance are generally known, e.g., corn borer resistant rice (see, e.g., Molecular Breeding, 18 (2006), No. 1), lepidopterous resistant lettuce (e.g. US Pat. No. 5,349,124), and rice (eg, see WO2001021821) having resistance to Lepidoptera (for example, Pterodactyl, Ichimongiseseri, Rice-mushrooms, Ranunculus, Rice Case Worm, and Rice Army Worm). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above publications.

  Lepidopterous pests (for example, cut worms such as corn borers, corn ear worms, black cut worms, and fall army worms) and Coleoptera pests (corn root worms) that have been rendered pest resistant by RNA interference technology Corns that are resistant to corn are marketed or developed under the trade names of “SmartStax (registered trademark),“ SmartStax (registered trademark) Pro ”, and“ Genuity (registered trademark) SmartStax Pro ”.

  Plants to which pest resistance has been imparted by conventional breeding technology or genome breeding technology, for example, a Rag1 (Resistance Aphid Gene 1) gene or “Rag2 (Resistance to Aphis glycines 2)” gene that is an aphid resistance gene Soybeans with resistance to aphids with resistance to Aphis glycines (see J. Econ. Entomol., 2015, 108, 326.); resistance to Cysto nematode Soybeans: Cotton that is resistant to root knot nematode; Rice “Kanto BPH1” that is resistant to brown planthopper; Soybean “Fukuminori” that is resistant to Lotus moth.

  These pest-resistant plants are given resistance to any harmful insects (particularly lepidopterous insects, Coleoptera insects, Diptera), harmful spiders and harmful nematodes. Plants conferred with pest resistance are preferably cereals (eg, wheat, barley, rye, oats); corn, canola, sorghum, soybean, rice, rapeseed, sugar beet, sugar cane, grape, lentil, sunflower, alfalfa, seed Selected from fruits; nuclear fruits; peanuts; coffee; tea; strawberries; turf; (E.g. wheat, barley, rye and oats), most preferably selected from soybeans, rice, corn and cereals (e.g. wheat, barley, rye and oats).

  Examples of plants to which disease resistance is imparted are listed below.

Plants that have been rendered disease resistant by genetic engineering techniques, for example, express so-called "pathogenicity related proteins" (PRP, see eg EP0392225) or so-called "antifungal proteins" (AFP, see eg US6864068) It is a plant. Various antifungal proteins with activity against phytopathogenic fungi have been isolated from specific plant species and are common sense. Examples of such anti-pathogenic substances and plants from which such anti-pathogenic substances can be synthesized are known, for example, from EP0392225, WO1993 / 05153, WO1995 / 33818 and EP0353191. Plants that are resistant to fungicidal pathogens, viral pathogens and bacterial pathogens are created by introducing plant resistance genes. A number of resistance genes have been identified and isolated and used to improve plant resistance, such resistance genes include, for example, producing tobacco mosaic virus (TMV) resistant tobacco plants N genes introduced into TMV-sensitive tobacco lines (e.g. see US 5571706), Prf genes introduced into plants to obtain enhanced pathogenic resistance (e.g. see WO1998 / 02545), And the Rps2 gene from Arabidopsis thaliana that was used to create resistance to bacterial pathogens such as Pseudomonas syringae (see, eg, WO1995 / 28423). Plants showing a systemic acquired resistance response were obtained by introducing a nucleic acid molecule encoding the TIR domain of the N gene (see, eg, US6630618). Further examples of known resistance genes include the Xa21 gene that has been introduced into many rice varieties (see, e.g., US5952485, US5977434, WO1999 / 09151, WO1996 / 22375), Rcg1 for resistance to colletotrichum. Genes (see, for example, US2006 / 225152), prp1 gene (see, for example, US5859332, WO2008 / 017706), ppv-cp gene that introduces resistance to plum poxvirus (see, for example, US PP15,154Ps), P1 Genes (see, e.g., US5968828), genes such as Blb1, Blb2, Blb3, RB2 and Rpi-vnt1 for introducing resistance to potato blight in potato (phytophthora infestans) (e.g., US7148397 LRPKml gene (see, for example, WO1999 / 064600), P1 gene for potato virus Y resistance (see, for example, US5968828), HA5-1 gene (see, for example, US5877403 and US6046384) ), PIP genes for introducing broad resistance to viruses such as potato virus X (PVX), potato virus Y (PVY), potato cigar virus (PLRV), as well as fungal resistance Arabidopsis NI16 gene, ScaM4 gene and ScaM5 gene such as Arabidopsis to obtain (see for example US6706952 and EP1018553). Bean beans that are resistant to Bean golden mosaic virus (hereinafter referred to as BGMV) are plants that have been given resistance by RNA interference (hereinafter referred to as RNAi) technology, and are replication proteins. This gene is resistant to BGMV by introducing a double-stranded RNA gene (sense and antisense ac1 gene) and inhibiting the synthesis of BGMV replication protein. Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above publications.
Anti-pathogenic substances that can be expressed by such plants include, for example, ion channel blockers (such as sodium channel blockers and calcium channel blockers), such as viral KP1, KP4 or KP6 toxins; stilbene synthase; bibenzyl Synthase; chitinase; glucanase; so-called “pathogenicity related proteins” (PRP; see eg EP0392225); antipathogenic substances produced by microorganisms, eg peptide antibiotics or heterocyclic antibiotics (eg WO1995 / 33818) Or protein factors or polypeptide factors involved in plant pathogen defense (so-called “plant disease resistance genes” described in WO2003 / 000906).
Anti-pathogenic substances produced by plants can protect plants against various pathogens such as fungi, viruses and bacteria. Useful plants of increasing interest in connection with the present invention are cereal grains (e.g. wheat, barley, rye and oats), soybeans, corn, rice, rapeseed, berries, nuts, peanuts, coffee, tea, strawberries Vines and vegetables (eg tomatoes, potatoes), cucurbits, papayas, melons, lentes and lettuce, more preferably soybeans, tomatoes, rice and cereals (eg wheat, barley, Rye and oats) and most preferably selected from soybeans, rice and cereals (eg wheat, barley, rye and oats).
Plants that are resistant to fungal pathogens are, for example, soybeans that are resistant to Asian soybean rust (see, eg, WO2008 / 017706); potato plagues (phytophthora infestans) Resistant solanaceous plants such as cotton tomato potatoes (see for example US5859332, US7148397, EP1334979); maize resistant to the genus Colletotrichum such as Colletotrichum graminicola (see, for example, US2006 / 225152) Apples with resistance to apple black spot (Venturia inaequalis) (see eg WO1999 / 064600); Fusarium disease (eg fusarium graminearum, fusarium sporotrichioides) ), Fusarium Laterium (fusarium lateritium), Fusarium pseudograminearum, fusarium sambucinum, fusarium culmorum, fusarium poae, fusarium poae, fusarium acumatum inum Plants with resistance to fusarium equiseti, such as rice, wheat, barley, rye, corn, oats, potatoes, melons, soybeans and sorghum (see, for example, US6646184, EP1477557); In plants (such as US5859332, US5689046, US6706952, EP1018553 and US6020129) such as corn, soybeans, cereals with special properties (especially wheat, rye, barley, oats, rye, rice), tobacco, sorghum, sugarcane and potatoes is there.
Plants resistant to bacterial pathogens and plants covered by the present invention include, for example, rice having resistance to xylella fastidiosa (see, eg, US6232528); Resistant plants such as rice, cotton, soybean, potato, sorghum, corn, wheat, barley, sugarcane, tomato and pepper (see for example WO2006 / 42145, US5952485, US5977434, WO1999 / 09151, WO1996 / 22375); And tomatoes having resistance to pseudomonas syringae (see, for example, Can. J. Plant Path., 1983, 5: 251-255).
Plants that are resistant to viral pathogens include, for example, nuclear fruits (eg, plums, almonds, apricots, cherries, peaches, nectarines) that are resistant to plum poxviruses (PPV, eg, see US PP15154Ps, EP0626449); Potatoes that are resistant to virus Y (see, eg, US5968828); such as potatoes, tomatoes, cucumbers, and legumes that are resistant to tomato spotted wilt virus (see, eg, TSWV, eg, EP0626449, US5973135) Plants; maize resistant to corn streak virus (see eg US6040496); papaya resistant to papaya ringworm virus (PRSV eg eg S5877403, see US6046384); cucumber mosaic virus (CMV, (For example, see US6849780) Cucumber, melon, watermelon and pumpkin) and solanaceous plants (eg potato, tobacco, tomato, eggplant, paprika, pepper, and pepper); watermelon mosaic virus (WMV2, watermelon mosaic potyvirus 2) and zucchini yellow mosaic virus (ZYMV, zucchini yellow Cucurbitaceae plants resistant to (mosaic potyvirus) (eg cucumber, melon, watermelon and pumpkin) (see eg US6015942); Potatoes resistant to potato cigar virus (PLRV eg see US5576202); Potato virus X (PVX), potato virus Y (PVY), potato cigar virus (PLRV) and other potatoes with broad resistance to viruses (see eg EP0707069), Bean golden mosaic virus Resistant kidney beans (for example, , Mol Plant Microbe Interact 2007 Jun; 20 (6):.. 717-26 see) and the like.
There are plants that are resistant to antibiotics (eg, kanamycin, neomycin and ampicillin). The naturally occurring bacterial nptII gene expresses an enzyme that blocks the action of the antibiotics kanamycin and neomycin. The ampicillin resistance gene ampR (also known as blaTEM1) is derived from the bacterium Salmonella paratyphi and is used as a marker gene in microbial and plant transformation. ampR is involved in the synthesis of beta-lactamase, an enzyme that neutralizes the antibiotics of the penicillin group including ampicillin. Plants having resistance to antibiotics include, for example, potato, tomato, flax, canola, rapeseed, rape seed and corn (see, for example, Plant Cell Reports, 20, 2001, 610-615, Trends in Plant Science, 11, 2006, 317-319, Plant Molecular Biology, 37, 1998, 287-296, Mol Gen Genet., 257, 1998, 606-13. Plant Cell Reports, 6, 1987, 333-336, Federal Register (USA), 60, No. 113, 1995, 31139. Federal Register (USA), 67, No. 226, 2002, 70392, Federal Register (USA), 63, No. 88, 1998, 25194, Federal Register (USA), Volume 60, No.141, 1995, 37870, Canadian Food Inspection Agency, FD / OFB-095-264-A, October 1999, FD / OFB-099-127-A, see October 1999). Preferably, the plant is selected from soybeans, tomatoes and cereals (e.g. wheat, barley, rye and oats), most preferably selected from soybeans and cereals (e.g. wheat, barley, rye and oats). The
Available plants that have been given resistance to plant viral diseases are, for example, papaya “Rainbow”, “SunUp” and “Huanong No. 1” that have been given resistance to papaya ringspot virus. Potato “Innate® Hibernate”, “Innate® Glaciate” and “Innate® Acclimate” showing resistance to potato plagues (phytophthora infestans); Potato virus Y And / or products containing potato “Newleaf ™” that are resistant to potato cigar virus (PLRV).

  Rice that has been given resistance to rice blast (Magnaporthe oryzae) as a plant that has been given disease resistance by conventional cultivar improvement technology or genome breeding technology; rice that has been given resistance to Rhizoctonia solani ; Wheat imparted resistance to red rust (Puccinia triticina); Wheat imparted resistance to yellow rust (Puccinia striiformis f. Sp. Tritici); Resistant to black rust (Puccinia graminis f. Sp. Tritici) Wheat imparted; Wheat imparted resistance to powdery mildew (Blumeria graminis f. Sp. Tritici); Wheat imparted resistance to leaf blight (Zymoseptoria tritici); Resistant to blight (Stagonospora nodorum) Wheat imparted; Wheat imparted resistance to yellow spot disease (Pyrenophora tritic-repentis); Resistant to powdery mildew (Blumeria graminis f. Sp. Hordei) Barley; resistant to small morbidity (Puccnia hordei); barley imparted resistance to Pyrenophora teres; barley resistant to Rhynchosporium commune; lambaria disease Barley imparted resistance to (Ramularia collo-cygni); Corn imparted resistance to Anthracnose stalk rot; Corn imparted resistance to Gray leaf spot disease; Corn with resistance to Boss (Goss`s wilt); Corn with resistance to Fusarium stalk rot; Soybean with resistance to Asian soybean rust ; Soybeans tolerant to phytophthora rot; Sudden death s soybeans tolerant to yndrome; peppers tolerant to Phytophthora; lettuce tolerant to powdery mildew; tomatoes tolerant to bacterial wilt; geminivirus Tomatoes with resistance to (Geminivirus); Lettuce with resistance against downy mildew; Rapeseed, cabbage, Brussels sprouts, cauliflower, colored green (Borekale) with resistance against clubroot ), Cruciferous plants such as broccoli; cruciferous plants such as rapeseed, cabbage, brussels sprouts, cauliflower, colored green (Borekale), broccoli, etc. that have been given resistance to black leg; Fusarium oxysporum f.sp. melonis Melon imparted resistance to melon vine split disease caused by (for example, see WO2009 / 000736) And the like.

  As a plant to which disease resistance has been conferred by genome editing technology, the powdery mildew resistance gene (MILDEW RESISTACE LOCUS O, hereinafter abbreviated as MLO) is deleted using Talen and Crisper Cassine. Bread wheat that is resistant to the disease (see, for example, Nat. Biotech., 32,947-951 2014); by using Crisper Cassine to delete the SlMLO1 gene, one of the MLOs, Tolerant slmlo1 tomato (see, for example, Scientific Reports 7, Article number: 482 2017); Xanthomonas oryzae causing leaf blight of rice by editing the OsSWEET14 gene in rice using talen pv. Oryzae) resistant rice (see Nat. Biotechnol. 30, 390-392 2012); modifying the OsERF922 gene in rice using crisper-cassine , Rice resistant to Magnaporthe oryzae that causes rice blast (PLoS ONE 11: e0154027. Doi: 10.1371 / journal.pone.0154027 2016); using recessive eIF4E ( Cucumber (Mol. PlantPathol. 17) resistant to cucumber vein yellow ingvirus (CVYV), zucchini yellow mosaic virus (ZYMV), and papaya ringspot virus-type W (PRSV-W) by disruption of eukaryotic translation initiation factor 4E) gene , 7 1140-1153 (see 2016); soybeans resistant to soybean stem blight caused by Phytophthora sojae by disruption of RXLR effector gene (Avr4 / 6) using Crisper Cassine (Mol Plant Pathol 17 (1 ) 127-139 2016)).

  Rvi6 (previously called HcrVf2) gene that is resistant to apple scab caused by Venturia inaequalis was introduced using cisgenesis as a plant to which disease resistance was conferred by new breeding technology An apple that is resistant to apple mold (see, for example, Plant Biotech. J., 12, 2-9, 2014); As an example to give Hoki the properties of GM rootstock, which is a variety improvement technology using grafts A sweet cherry (Plant Biotech. J., 12, 1319-1328) whose nature has been transferred from a transgenic rootstock resistant to infection with Prunus necrotic ringspot virus to a non-transgenic spikelet. 2014)).

Examples of plants with modified product quality are listed below.
The product quality modification means the synthesis of the modified component or the increase or decrease in the synthesis amount of the component compared to the corresponding wild type plant. For example, there are modified plants with increased or decreased content of vitamins, amino acids, proteins and starches, various oils, and modified plants with decreased nicotine content.

  Plants whose product quality has been modified by genetic recombination technology include, for example, alfalfa-derived S-adenosyl-L-methionine: trans-caffeoyl CoA 3-methyltransferase (ccomt) gene duplexes involved in lignin production Alfalfa with a gene that generates RNA and reduced lignin content by RNA interference; Triacylglyceride containing lauric acid by introducing a 12: 0 ACP thioesterase gene from Umbellularia californica involved in fatty acid synthesis Canola with increased content "Laurical (trademark) Canola"; by introducing a partial gene (gm-fad2-1) of omega-6 desaturase derived from soybean, which is a desaturase of fatty acid, Soybean “Plenish ™” or “Treus ™” with increased oleic acid content; -Acyl-acyl carrier protein thioesterase gene (fatb1-A) double-stranded RNA and soybean-derived delta-12 desaturase gene (fad2-1A) double-stranded RNA Soybean "Vistive Gold (trademark)" in which saturated fatty acid content is reduced by introducing the gene; δ-6 desaturase gene (Pj. D6D) derived from primrose, and δ-12 desaturase gene (Nc. Fad3) derived from red bread mold Transgenic soybean in which stearidonic acid, which is one of ω3 fatty acids, was produced by introducing a heat-stable alpha-amylase gene (amy797E) of Thermococcales sp. Maize “Enogen (registered trademark)” with enhanced bioethanol production; Maize “Mavera ™ Maize”, “Mavera ™ YieldGard ™ Maize” enhanced lysine production by introducing a dihydrodipicolinate synthase gene (cordapA) from Corynebacterium glutamicum Potato "Amflora (trademark)" in which the amylose content in starch granules is reduced and the amylopectin content is increased by introducing the antisense gene gbss of starch-synthesizing enzyme derived from potato (granule-bound starch synthase enzame, GBSS) , “Starch Potato”; introduction of genes pPhL and pR1 that generate double-stranded RNA of transcription factors PhL and R1 that promote potato-derived starch degradation, and two genes Asn1 involved in inhibition of starch degradation and asparagine production. Suppression of asparagine synthesis by introducing asn1 gene that generates heavy chain RNA (carcinogenesis by heating) The purpose of this study was to suppress the accumulation of asparagine and reducing sugars involved in the production of acrylamide, the substance), and the potato that suppressed the formation of black spots by introducing the gene ppo5 that generates double-stranded RNA of the polyphenol oxidase gene Ppo5 derived from potato. Innate (registered trademark) Cultivate, Innate (registered trademark) Generate, Innate (registered trademark) Accelerate, Innate (registered trademark) Invigorate, Innate (registered trademark) Glaciate, Innate (registered trademark) Acclimate ”,“ Innate® Hibernate ”; tobacco with reduced nicotine content by introducing the antisense gene (NtQPT1) of the quinolinate phosphoribosyltransferase gene QpTase from tobacco (Nicotiana tabacum); Pseudonarcissus) phytoene synthase gene (psy) and carotenoid synthesis Golden rice that can produce rice containing vitamin A by producing beta-carotene in endosperm tissue by introducing carotene desaturase gene (crt1) derived from erwinia uredovora and expressing it specifically in endosperm There is rice (Golden rice). Other examples include potato and corn with modified amylopectin content (see, for example, US6784338, US20070261136, WO199704471); canola, corn, cotton, grape, cattail, catalpa with modified oil content ), Rice, soybean, rapeseed, wheat, sunflower, bittern, safflower and vernonia plants (eg, US7294759, US7157621, US5850026, US6441278, US5723761, US6380462, US6365802, US6974898, US2001 / 079499, US2006) Sunflower with increased fatty acid content (see eg US6084164); soybean with reduced allergen content (see eg US6864362); tobacco with reduced nicotine content (eg US2006 / 0185684, WO2005 / 000352 and WO2007 / 064636); canola and soybeans with increased lysine content (eg For example, see Bio / Technology 13, 1995, 577-582); Maize and soybean with modified methionine, leucine, isoleucine and valine compositions (see, eg, US6946589, US6905877); increased sulfur amino acid content Soybean (see, for example, EP0929685, WO199 / 7041239); 3'-Phosphoadenosine-5'-phospPNAShosulfate reductase from Escherichia coli is leaf-specific Corn with increased methionine content (see PNAS, 2017, 114 (43), 11386.); free amino acids (eg asparagine, aspartic acid, serine, threonine, alanine, histidine and glutamic acid) content Increased tomatoes (see eg US6727411); maize with increased amino acid content (eg see WO05 / 077117); modified starch content Potatoes, corn and rice (see for example WO1997 / 044471 and US7317146); tomatoes, corn, grapes, alfalfa, apples, legumes and peas with modified flavonoid content (see for example WO00 / 04175); phenolic Corn, rice, sorghum, cotton, soybean with modified compound content (eg see US2008 / 0235829); tomato, canola with increased vitamin A content (eg see US6797498, US7348167); vitamin E content Tomato, canola, soybean, wheat, sunflower, rice, corn, barley, rye (see eg US7348167, WO2004 / 058934); alfalfa, apple, bean, corn, grape, modified flavonoid content There are tomatoes and peas (for example, see WO00 / 04175). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above-mentioned publications. Preferably, the plant is selected from soybeans, canola, tomatoes, rice and cereals (eg wheat, barley, rye and oats), most preferably selected from soybeans, canola, rice and wheat, barley.

  Rapeseed “Nexera (registered trademark) Canola” that produces unsaturated omega-9 fatty acids as a plant whose quality of the product has been modified by conventional breeding technology or genome breeding technology; soybean with reduced allergen content “Yumeminori”; rice for the purpose of changing to a good taste, for example, rice “Yumepirika” with a reduced amylose content is commercially available. Citrus with modified fruit characteristics (such as fruit weight, fragrance, juiciness and sugar content) by genomic selection is also known (see Scientific Reports 7, 4721 2017).

  Plants with altered plant nutrient utilization are, for example, plants with enhanced nitrogen or phosphorus assimilation or metabolism. Plants with enhanced nitrogen assimilation and nitrogen utilization capacity by genetic engineering techniques include, for example, canola, corn, wheat, sunflower, rice, tobacco, soybean, cotton, alfalfa, tomato, wheat, potato, sugar beet, sugar cane and Selected from rapeseed (see, for example, WO1995 / 009911, WO1997 / 030163, US6084153, US5955651 and US6864405). Plants with improved phosphorus uptake by genetic engineering techniques are, for example, alfalfa, barley, canola, corn, cotton, tomato, rapeseed, rice, soybean, sugar beet, sugar cane, sunflower, wheat and potato (e.g., US7417181, (See US2005 / 0137386). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above-mentioned publications. Preferably, the plant is selected from soybeans, tomatoes and cereals (eg wheat, barley, rye and oats), most preferably selected from soybeans, rice, corn and wheat.

  Plants whose fertility traits and the like have been modified by genetic recombination techniques include plants that have been given male sterility and fertility recovery traits. For example, maize and chicory that have been given male sterility by expressing a ribonuclease gene (barnase) derived from Bacillus amyloliquefaciens in cocoon tapetum cells; a DNA adenine methylase gene (dam) derived from E. coli Maize that has been given male sterility by introducing corn-derived alpha-amylase gene (zm-aa1) that gives male sterility traits and ms45 protein gene (ms45) that gives maternal recovery traits Corn with controlled fertility traits; canola with fertility-recovering function expressed by expressing a ribonuclease inhibitor protein gene (barstar) from Bacillus in tapetum cells of pupae; bacillus giving male sterility traits Ribonuclease gene derived from fungi (b arnase) and canola in which the fertility trait is controlled by expressing a ribonuclease-inhibiting protein gene (barstar) derived from Bacillus that gives the fertility recovery trait. Other plants to which fertile traits have been imparted by genetic recombination techniques include tomato, rice, mustard, wheat, soybean, and sunflower (e.g., US6720481, US6281348, US5659124, US6399856, US7345222, US7230168, US6072102, EP1135982, WO2001). / 092544 and WO1996 / 040949). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above-mentioned publications. Preferably, the plant is selected from corn, canola, soybean, tomatoes and cereals (eg wheat), most preferably selected from corn, canola, soybean, rice, wheat.

  Plants with abiotic stress tolerance are drought, high salinity, high light intensity, high UV irradiation, chemical contamination (eg high heavy metal concentration), low or high temperature, limited nutrients (ie nitrogen, phosphorus) Plants exhibiting increased resistance to abiotic stress conditions such as supply and collective stress (see, for example, WO2000 / 004173, WO2007 / 131699, CA2521729 and US2008 / 0229448).

  Plants imparted with abiotic stress tolerance by genetic engineering techniques include, for example, rice, corn, soybean, sugarcane, alfalfa, wheat, tomato, potato, barley, rapeseed, legume, oats, sorghum, and tolerant to drought Cotton (see eg WO2005 / 048693, WO2008 / 002480 and WO2007 / 030001); corn, soybean, wheat, cotton, rice, rapeseed and alfalfa (see eg US4731499 and WO2007 / 112122) resistant to low temperatures; high Examples include rice, cotton, potato, soybean, wheat, barley, rye, sorghum, alfalfa, grape, tomato, sunflower and tobacco (see, for example, US7256326, US7034139, WO2001 / 030990) that are resistant to salt. There is also a corn “DroughtGard (registered trademark)” (Monsanto product) into which a cold shock protein gene cspB of Bacillus subtilis has been introduced.

  Plants that have been imparted with abiotic stress tolerance by conventional breeding technology or genome breeding technology, for example, corn having drought tolerance is "Agrisure Artesian (registered trademark)", "Optimum (registered trademark)" (Trademark) "AQUAmax (registered trademark)" has been developed under the trade name.

Plants to which other characteristics are imparted include plants with modified maturation characteristics. Modification of maturation characteristics includes, for example, delayed ripening, delayed softening and early maturation.
Plants whose maturation characteristics have been modified by genetic engineering techniques can be preserved, for example, by introducing the S-adenosylmethione hydrolase gene (sam-K) from E. coli bacteriophage T3 for the production of the plant hormone ethylene. Improved melons and tomatoes; genes lacking some of the ACC synthase genes from tomatoes involved in the production of plant hormone ethylene, ACC deaminase genes from Pseudomonas chlororaphis that degrade ethylene precursor ACC, cell walls A tomato with improved shelf life by introducing a tomato-derived polygalacturonase gene double-stranded RNA that degrades pectin of the tomato, or a tomato-derived ACC oxidase gene involved in the production of ethylene; tomato That produces double-stranded RNA of polygalacturonase gene There is a tomato with improved shelf-life by introducing the child pg "FLAVR SAVR (TM)". Other plants whose maturation characteristics have been modified by genetic recombination techniques include, for example, tomatoes, melons, raspberries, strawberries, muskmelons, peppers and papayas that have been ripened (e.g., US 5767376, US7084321, US6107548, US5981831). WO1995 / 035387, US 5952546, US 5512466, WO1997 / 001952, WO1992 / 008798, Plant Cell. 1989, 53-63. See Plant Molecular Biology, 50, 2002). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above-mentioned publications. Preferably, the plants are fruits (eg tomatoes, vines, melons, papayas, bananas, peppers, raspberries and strawberries); nuclear fruits (eg cherries, apricots and peaches); berries (eg apples and berries) Pear); and citrus fruits (eg, citron, lime, orange, pomelo, grapefruit, and mandarin), more preferably selected from tomato, melon, papaya, vine, apple, banana, orange and strawberry; Most preferred are tomato, melon and papaya.

  Plants to which other quality alterations have been imparted by gene recombination technology are introduced into the plant by introducing a 3-phytase gene (phyA) derived from Aspergillus niger, which is a plant phytic acid degrading enzyme. Canola with enhanced degradation “Phytaseed® Canola”; the dihydrodoflavonol-4-reductase gene from Petunia hybrida, an enzyme that produces the blue pigment delphinidin and its derivatives, and petunia, pansy (Viola wittrockiana) ), Salvia (Salvia splendens), or carnation “Moondust ™”, “Moonshadow ™” whose flower color was controlled to be blue by introducing a flavonoid-3 ′, 5′-hydroxylase gene derived from carnation, “Moonshade ™”, “Moonlite ™”, “Moonaqua ™”, “Moonv” ista ™, “Moonique ™”, “Moonpearl ™”, “Moonberry ™”, “Moonvelvet ™”; Torenia, an enzyme that produces the blue pigment delphinidin and its derivatives sp.) rose and blue rose color controlled by introducing pansy flavonoid-3,5′-hydroxylase gene; modified cedar pollen antigen protein gene (7crp) ) Transgenic rice with immune tolerance and hay fever mitigating effect; maize with enhanced degradation of endogenous phytic acid by introduction of black mold 3-phytase gene (phyA); fiber micronea Cotton that produces high quality fibers with improved fiber strength, length uniformity and color, etc. If, see WO1996 / 26639, US7329802, US6472588 and WO2001 / 17333) there is.

  Plants whose traits relating to plant growth and yield have been modified include plants with enhanced growth ability. Plants modified by gene recombination technology, for example, by introducing a gene (bbx32) that encodes a transcription factor that regulates diurnal properties derived from Arabidopsis thaliana, so that the growth of the plant is enhanced, and as a result, high yield can be expected ; Introduction of transcription factor gene (athb17) belonging to Arabidopsis homeodomain-leucine 14 zipper (HD-Zip) family class II HD-Zip II). Corn is being developed.

  As a plant whose quality has been altered by genome editing technology, the zinc finger nuclease is used to lack the IPK1 gene encoding inositol-1,3,4,5,6-pentakisphosphate 2-kinase, an enzyme for phytic acid biosynthesis. Deletion of the gene encoding polyphenol oxidase (abbreviated as PPO) by using corn "ZFN-12 maize" with reduced phytic acid content; Mushrooms to which browning resistance has been imparted (see, for example, Nature., Vol 532, 21 APRIL 2016).

  By introducing the low polyphenole oxidase (PPO, browning enzyme) production gene sequence GEN-03 isolated from apples using cis-genesis as a plant whose quality has been modified by new breeding technology. , An apple that has reduced PPO expression and does not turn brown "Arctic (registered trademark)"; An example in which salt tolerance is imparted to tomatoes using non-transgenic spikelets is described in Physiol Plantarum, 124, 465-475 2005).

  In rice, genes showing resistance to a large number of diseases, pests and abiotic stress are known, and the production of resistant varieties into which these genes have been introduced is thriving. Examples of genes showing disease resistance in rice and resistance to abiotic stress include BPH1, BPH2, BPH3, BPH4, BPH5, BPH6, BPH7, BPH8, BPH9, BPH10, BPH11, BPH12, BPH13, BPH14, BPH15, BPH17 , BPH18, BPH19, BPH20, BPH21, BPH22, BPH23, BPH24, BPH25, BPH26, BPH27, BPH28, BPH29, BPH32, qBPH-12, qBPHR-1, qBPHR-3, qBPHR-8, qBPHR-5-1qBPHR-5 -2 green planthopper resistance genes such as qBPHR-11-1, qBPHR-11-2; WBPH1, WBPH2, WBPH3, WBPH4, WBPH5, WBPH6, OVC, qOVA-5-2, qOVA1-3, qOVA5-1, etc. White-spotted plant resistant varieties: Qsbph2b, Qsbph3, Qsbph3b, Qsbph3c, Qsbph3d, Qsbph4, Qsbph8, Qsbph11, Qsbph11d, Qsbph11e, Qsbph11f, Qsbph11g, HGL, GL , GLH8, GLH9, GLH10, GLH11, GLH12, GLH13, GRH1, GRH2, GRH3, GRH4, GRH5, Zlh1, Zlh2, Zlh3, qGRH-4, qGRH-2, qGRH-5, qGRH-6, qGRH-11, Leafhopper resistance genes such as GRH-3; Nikamei resistance genes such as SB; Pii, PI65, PIZT, PI24, PI29, PI25, Pi-jnw1, PB1, PIQ6, PID3, PI67, PITQ5, PITP, PITQ6, PLM2 , PISE3, IPI, PISE1, PI157, PIQ4, PI21, PIA, PIB, PIK, PIKUR1, PIKUR2, PI3, PIF, PIZH, PIR4, PIR7, PI30, PI, PIGD2, PIG, PIGD3, PIGD1, PIZ, PI (, PI18, PIM, PI17, PI20, PI1, PI19, PI5, PISH, PI10, PI9, PI21, PI22, PI44, PI22, PI13, PII, PIB1, PIQ1, PIQ2, PIQ3, PIIS1, PII2, PI62, PI12, IPI3, PI14, PI15, PI16, PIT, PI11, PI6, PI23, PI14, PI11, PIIS2, PIB2, PI12, PI39, PI40, PITA, PIR2-3, PIR9-2, PIR12-2, PIRF2-1, qRBR-2, qRBR-3, PI27, PI28, PI26, PIGM, PI47, PI48, PI7, PI56, PI49, PI34, PIKG, PI38, PI32, PI31, PI46, PIX, PIXY, Pita3, PI41, PI42, PI2, PI36, PI37, PIKH, PIKM, PIKP, PI35, PIZ5, PIB2, PI43, PI50, PI51, PID1, PIY1, PIY2, PI55-2, PICO39, PI55-1, PIBH8, PIR7A, PIR7B, P ID2, PI33, qBFR4-1, qBFR4-2, qRBR-2, qRBR-3, qRBR-8, qRBR-1-1, qRBR-1-3, qRBR-7-1, qRBR-7-2, qRBR- 9-1, qRBR-9-2, qRBR-9-3, qRBR-1-2, qRBR-1-4, etc., blast resistance genes; STVA, STVB, Stvb-i, etc. Sex genes: XA21D, XA, XA40, XA NM, XA8, XA33, XA34, XA35, XA36, XA37, XA7, XA3, XA25, XA28, XA29, XA30, XA31, XA32, XA38, XA39, XA11, XA16, XA17 White leaf blight resistance genes such as XA18, XA19, XA20, XA14, XA2, XA12, XA1, XA K, XA A, XA H, XA10, XA23, XA22, XA24, XA21, SERRT13, XA4, XA5, XA13; -2, qSB-3, qSB-7, qSB-11, qSB-9-1 and other blight resistance genes; CE and other sesame leaf blight resistance genes; yellow dwarf disease resistance genes such as YDV; Black line dwarf disease resistance gene such as BSV; high temperature cram resistance gene such as Amy1A, Amy1C, Amy3A, Amy3B; low amylose gene such as dul3, qAC9.3, rsr1, Wx, Wx1-1; AP01, SCM2, Sd1 etc. Inferior genes; ear germination resistance genes such as Sdr4; low temperature resistance genes such as CTB1, CTB2, qLTG3-1; drought resistance genes such as Dro1; DEP1, Cn1a, GPS, SPIKE, PTB1, TAWAWA1, WFP, IPA1, GS3, GS5, GS6, GL3.1, GW2, GW8, qGL3, qSS7, qSW5 and other genes related to the number of seeds or seed form; Hd1, Ghd8, DTH8 and other genes regulating day length reactivity; FLO4, PDIL1, etc. endosperm Powdery genes; lipoxygenase-deficient genes (reducing old rice odor) such as LOX3; genes related to amylopectin chain length such as Alk are known. Rice varieties incorporating one or more of these genes simultaneously have been developed and marketed.

  For the above-mentioned plants, genetic recombination technology, conventional breeding technology, genome breeding technology, new breeding technology or genome editing technology, etc. are used, and abiotic stress resistance, disease resistance, herbicide as described above Resistance, pest resistance, growth and yield traits, modification of nutrient utilization, product quality modification, strains with two or more fertile traits, etc., and parent strains by crossing plants with similar or different properties A strain to which two or more kinds of properties possessed by is added is also included.

Commercial plants that have been rendered tolerant to two or more herbicides include, for example, cotton “GlyTol ™ LibertyLink ™”, “GlyTol ™ LibertyLink ™” resistant to glyphosate and glufosinate; Corn “Roundup Ready ™ LibertyLink ™ Maize” with tolerance and glufosinate tolerance; Soybean “Enlist ™ Soybean” with glufosinate tolerance and 2,4-D tolerance; Soybean “Genuity with glyphosate tolerance and dicamba tolerance” (R) Roundup Ready (TM) 2 Xtend (TM); Glyphosate and ALS inhibitor resistant corn and soybean "OptimumGAT (TM)"; three herbicides: glyphosate, glufosinate and 2,4-D Genetically modified soybean "Enlist E3 (TM)" and "Enlist (TM) Roundup Ready 2 Yield (R)" that are resistant; glyphosate Genetically modified maize “Enlist ™ Roundup Ready® Corn 2” resistant to 2,4-D and allyloxyphenoxypropionic acid (FOPs) herbicides; glyphosate, 2,4-D and allyloxy Genetically modified maize “Enlist ™ Roundup Ready® Corn 2” resistant to phenoxypropionic acid (FOPs) herbicides; genetically modified cotton “Bollgard II” resistant to dicamba, glyphosate and glufosinate There is a genetically modified cotton “Enlist ™ Cotton” that is resistant to three herbicides: glyphosate, glufosinate and 2,4-D. In addition, cotton resistant to glufosinate and 2,4-D, cotton resistant to both glufosinate and dicamba, corn resistant to both glyphosate and 2,4-D, resistant to both glyphosate and HPPD herbicides Genetically modified maize resistant to soybean, glyphosate, glufosinate 2,4-D, allyloxyphenoxypropionic acid (FOPs) herbicides, and cyclohexadione (DIMs) herbicides have also been developed.
Commercial plants that have been given herbicide and pest resistance include, for example, the corn “YieldGard Roundup Ready” and “YieldGard Roundup Ready 2” that have glyphosate resistance and resistance to corn borers; glufosinate resistance and corn borer resistance Maize “Agrisure CB / LL” with Glyphosate Resistance and Corn Root Worm Resistance “Yield Gard VT Root worm / RR2”; Corn with Yield Resistance and Resistance to Corn Root Worm and Corn Borer “Yield” Gard VT Triple ”; corn“ Herculex I ”with glufosinate resistance and maize Lepidopterous insect resistance (Cry1F) (eg, resistance to Western bean cut worm, corn borer, black cut worm and fall army worm); glyphosa Corn “YieldGard Corn Rootworm / Roundup Ready 2” with gut resistance and corn rootworm resistance; glufosinate resistance and corn crustacean pest resistance (Cry3A) (eg Western corn rootworm, Northern corn rootworm and Mexican corn) Maize "Agrisure GT / RW" with resistance to root worms; glufosinate resistance and corn crustacean pest resistance (Cry34 / 35Ab1) (eg against Western corn rootworm, Northern corn rootworm and Mexican corn rootworm) "Herculex RW" with glyphosate resistance and corn rootworm resistance; "Yield Gard VT Root worm / RR2"; dicamba resistance, glyphosate resistance, glyphosate resistance and cotton lepidopterous insect resistance (E.g., bollworm acids and tobacco budworm, resistance to such armyworm acids) is cotton "Bollgard 3 (R) XtendFlex (registered trademark)" with.

  Commercial plants to which disease resistance and pest resistance are imparted are, for example, Potato virus Y resistance and pest resistance potatoes “Hi-Lite NewLeaf ™ Y Potato”, “NewLeaf ™ ) “Y Russet Burbank Potato”, “Shepody NewLeaf ™ Y Potato”; Potato leaf roll virus resistance and pest resistance potato “NewLeaf ™ Plus Russet Burbank Potato” is there.

  Commercial plants conferred with herbicide tolerance and modified product quality, eg, canola “InVigor ™ Canola” conferred with glufosinate tolerance and fertility traits; glufosinate tolerance and fertility traits Maize “InVigor ™ Maize”; soybean “Vistive Gold ™” with modified glyphosate tolerance and oil content.

  Examples of commercial plants with more than two traits include glyphosate tolerance, glufosinate tolerance and lepidopteran insect resistance (Cry1F) (ie against Western bean cut worms, corn borers, black cut worms and fall army worms) Corn "Herculex I / Roundup Ready 2" with resistance); Glyphosate resistance, corn rootworm resistance and corn borer resistance "YieldGard Plus / Roundup Ready 2"; Glyphosate resistance, glufosinate resistance and corn borer resistance Corn "Agrisure GT / CB / LL" with glufosinate resistance, lepidopterous insect resistance (Cry1F) and Coleoptera insect resistance (Cry34 / 35Ab1) (ie Western bean cut worm, corn borer, black cut worm and fall army) Worm "Herculex Xtra" maize with resistance to Lepidoptera and Lepidoptera of Western corn rootworm, Northern corn rootworm, Mexican corn rootworm, etc .; glufosinate resistance, corn borer resistance (Cry1Ab) and Coleoptera Corn "Agrisure CB / LL / RW" with resistance (Cry3A) (ie resistance to Western corn rootworm, Northern corn rootworm and Mexican corn rootworm); glyphosate resistance + corn borer resistance (Cry1Ab) and Coleoptera Corn “Agrisure ™ 3000GT” with pest resistance (Cry3A) (ie resistance to Western corn rootworm, Northern corn rootworm and Mexican corn rootworm); glyphosate tolerance, corn rootworm and European Corn "Mavera high-value corn" with high resistance to corn borers and high lysine traits; European corn borers, Southwestern corn borers, corn ear worms, fall army worms, black cut worms, western bean worms, etc. Corn "Optimum (registered trademark) Leptra (trademark)", soybean frog eye leaf spot, sudden death syndrome (sudden death syndrome), soybean stem canker, soybean Resistant to Phytophthora root rot, southern root-knot nematode, soybean white silkworm (Sclerotinia white mold), soybean leaf rot (brown stem rot), soybean cyst nematode (soybean cyst nematode) Grant, and iron deficiency chlorosis (iron c Soybean "Credenz (registered trademark) soybean" with improved hlorosis and modified chloride sensitivity; Cotton "Stoneville (registered trademark) Cotton" with multiple herbicide and pest resistance There are nine varieties of ST5517GLTP, ST4848GLT, ST4949GLT, ST5020GLT, ST5115GLT, ST6182GLT, ST4747GLB2, ST4946GLB2, and ST6448GLB2 to cope with the occurrence of weeds and pests in the field in each region.

The plants that are commercially available or developed are listed below (A1 to A550). In parentheses, [plant name, Event Name, Event code, trade name] is described. NA means information for which no information is available or available. Many of these plants are registered databases (GM APPROVAL DATABASE) in the electronic information site (http://www.isaaa.org/) of the INTERNATINAL SERVICE for the ACQUISITION of AGRI-BIOTECH APPLICATIONS, ISAAA. It is listed.
A1: [Alfalfa, J101, MON-00101-8, Roundup Ready (trademark) Alfalfa], A2: [Alfalfa, J101 x J163, MON-00101-8 x MON-00163-7, Roundup Ready (trademark) Alfalfa], A3: [Alfalfa, J163, MON-00163-7, Roundup Ready (TM) Alfalfa], A4: [Alfalfa, KK179, MON-00179-5, HarvXtra (TM)], A5: [Alfalfa, KK179 x J101, MON -00179-5 x MON-00101-8], A6: [Apple, GD743, OKA-NB001-8, Arctic (TM) "Golden Delicious" Apple], A7: [Apple, GS784, OKA-NB002-9, Arctic (Trademark)], A8: [apple, NF872, OKA-NB003-1, Arctic (trademark) Fuji Apple], A9: [Argentina canola, 23-18-17 (Event 18), CGN-89111-8, Laurical ( Trademark) Canola], A10: [Argentina Canola, 23-198 (Event 23), CGN-89465-2, Laurical (TM) Canola], A11: [Argentina Canola, 61061, DP-061061-7], A12: [ Argentina Canola, 73396, DP-073496-4, Optimum (Register Gly canola], A13: [Argentina canola, 73396 x RF3, DP-073496-4 x ACS-BN003-6, NA], A14: [Argentina canola, GT200 (RT200), MON-89249-2, Roundup Ready (Trademark) Canola], A15: [Argentina Canola, GT73 (RT73), MON-00073-7, Roundup Ready (Trademark) Canola], A16: [Argentina Canola, HCN10 (Topas 19/2), NA, Liberty Link ( Trademark) Independence (trademark)], A17: [Argentina canola, HCN28 (T45), ACS-BN008-2, InVigor (TM) Canola], A18: [Argentina canola, HCN28 x MON88302, ACS-BN008-2 x MON- 88302-9, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) Canola], A19: [Argentina Canola, HCN92 (Topas 19/2), ACS-BN007-1, Liberty Link (TM) Innovator (TM) ], A20: [Argentina canola, HCN92 x MON88302, ACS-BN007-1 x MON-88302-9, Liberty Link (TM) Innovator (TM) x TruFlex (TM) Roundup Ready (TM) Canola], A21: [Argentina Canola, MON88302, MON-88302-9, TruFlex (TM) Roundup Ready (TM) Canola], A22: [Argentina Canola, MON88302 x MS8 x RF3, MON-88302- 9 x ACS-BN005-8 x ACS-BN003-6, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) Canola], A23: [Argentina canola, MON88302 x RF3, MON-88302-9 x ACS-BN003 -6, NA], A24: [Argentina canola, MPS961, NA, Phytaseed (TM) Canola], A25: [Argentina canola, MPS962, NA, Phytaseed (TM) Canola], A26: [Argentina canola, MPS963, NA, Phytaseed ™ Canola], A27: [Argentina Canola, MPS964, NA, Phytaseed ™ Canola], A28: [Argentina Canola, MPS965, NA, Phytaseed ™ Canola], A29: [Argentina Canola, MS1 (B91 -4), ACS-BN004-7, InVigor ™ Canola], A30: [Argenti Canola, MS1 x MON88302, ACS-BN004-7 x MON-88302-9, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) Canola], A31: [Argentina canola, MS1 x RF1 (PGS1), ACS -BN004-7 x ACS-BN001-4, InVigor ™ Canola], A32: [Argentina canola, MS1 x RF1 (PGS2), ACS-BN004-7 x ACS-BN002-5, InVigor ™ Canola], A33: [Argentina canola, MS1 x RF3, ACS-BN004-7 x ACS-BN003-6, InVigor (TM) Canola], A34: [Argentina canola, MS8, ACS-BN005-8, InVigor (TM) Canola], A35: [Argentina canola, MS8 x MON88302, ACS-BN005-8 x MON-88302-9, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) Canola], A36: [Argentina canola, MS8 x RF3, ACS -BN005-8 x ACS-BN003-6, InVigor ™ Canola], A37: [Argentina canola, MS8 x RF3 x GT73 (RT73), ACS-BN005-8 x ACS-BN003-6 x MON-00073-7 , NA], A38: [Argenti Canola, OXY-235, ACS-BN011-5, Navigator (TM) Canola], A39: [Argentina canola, PHY14, NA, NA], A40: [Argentina canola, PHY23, NA, NA], A41: [Argentina canola , PHY35, NA, NA], A42: [Argentina canola, PHY36, NA, NA], A43: [Argentina canola, RF1 (B93-101), ACS-BN001-4, InVigor ™ Canola], A44: [ Argentine canola, RF1 x MON88302, CS-BN001-4 x MON-88302-9, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) Canola], A45: [Argentina canola, RF2 (B94-2), ACS -BN002-5, InVigor (TM) Canola], A46: [Argentina canola, RF2 x MON88302, ACS-BN002-5 x MON-88302-9, InVigor (TM) x TruFlex (TM) Roundup Ready (TM) Canola] , A47: [Argentina canola, RF3, ACS-BN003-6, InVigor (trademark) Canola], A48: [bean, EMBRAPA5.1, EMB-PV051-1, NA], A49: [Carne Deployment, 11 (7442), FLO-07442-4, Moondust (TM)], A50: [Carnation, 11363 (1363A), FLO-11363-1, Moonshadow (TM)],
A51: [Carnation, 1226A (11226), FLO-11226-8, Moonshade (trademark)], A52: [Carnation, 123.2.2 (40619), FLO-40619-7, Moonshade (trademark)], A53: [Carnation , 123.2.38 (40644), FLO-40644-4, Moonlite (trademark)], A54: [carnation, 123.8.12, FLO-40689-6, Moonaqua (trademark)], A55: [carnation, 123.8.8 ( 40685), FLO-40685-1, Moonvista (trademark)], A56: [carnation, 1351A (11351), FLO-11351-7, Moonshade (trademark)], A57: [carnation, 1400A (11400), FLO-11400 -2, Moonshade (trademark)], A58: [Carnation, 15, FLO-00015-2, Moondust (trademark)], A59: [Carnation, 16, FLO-00016-3, Moondust (trademark)], A60: [ Carnation, 19907, IFD-19907-9, Moonique (trademark)], A61: [carnation, 25947, IFD-25947-1, Moonpearl (trademark)], A62: [carnation, 25958, IFD-25958-3, Moonberry ( Trademark)], A63: [Carnesi 26407, IFD-26407-2, Moonvelvet (trademark)], A64: [carnation, 4, FLO-00004-9, Moondust (trademark)], A65: [carnation, 66, FLO-00066-8, NA] A66: [Carnation, 959A (11959), FLO-11959-3, Moonshade (trademark)], A67: [Carnation, 988A (11988), FLO-11988-7, Moonshade (trademark)], A68: [Chicory, RM3 -3, NA, SeedLink (trademark)], A69: [Chicory, RM3-4, NA, SeedLink (trademark)], A70: [Chicory, RM3-6, NA, SeedLink (trademark)], A71: [Cotton 19-51a, DD-01951A-7, NA], A72: [Cotton, 281-24-236, DAS-24236-5, NA], A73: [Cotton, 281-24-236x3006-210-23 (MXB- 13), DAS-24236-5xDAS-21023-5, WideStrike ™ Cotton], A74: [Cotton, 281-24-236x3006-210-23xCOT102x81910, DAS-24236-5xDAS-21023-5xSYN-IR102-7xDAS-81910 -7, NA], A75: [Cotton, 3006-210-23, DAS-21023-5, NA], A76: [Cotton, 3006-210-23x281-24-236xMON1445, DAS-21023-5xDAS-24236-5xMON -01445-2, WideSt rike (TM) RoundupReady (TM) Cotton], A77: [Cotton, 3006-210-23x281-24-236xMON88913, DAS-21023-5NAxNADAS-24236-5NAxNAMON-88913-8, Widestrike (TM) RoundupReadyFlex (TM) Cotton] , A78: [Cotton, 3006-210-23x281-24-236xMON88913xCOT102, DAS-21023-5NAxNADAS-24236-5NAxNAMON-88913-8NAxNASYN-IR102-7, Widestrike (TM) RoundupReadyFlex (TM) Cotton], A79: [Cotton, 31707, NA, BXN (TM) PlusBollgard (TM) Cotton], A80: [Cotton, 31803, NA, BXN (TM) PlusBollgard (TM) Cotton], A81: [Cotton, 31807x31808, NA, NA], A82: [ Cotton, 31807, NA, BXN (TM) PlusBollgard (TM) Cotton], A83: [Cotton, 31808, NA, BXN (TM) PlusBollgard (TM) Cotton], A84: [Cotton, 42317, NA, BXN (TM) PlusBollgard ™ Cotton], A85: [Cotton, 81910, DAS-81910-7, NA], A86: [Cotton, BNLA-601, NA, NA], A87: [Cotton, BXN10211 (10211), BXN-10211 -9, NA], A88: , BXN10215 (10215), BXN-10215-4NA, BXN (trademark) Cotton], A89: [cotton, BXN102 cotton 22 (10222), BXN-10222-2, BXN (trademark) Cotton], A90: [cotton, BXN10224 (10224), BXN-10224-4NA, BXN (trademark) Cotton], A91: [Cotton, COT102 (IR102), SYN-IR102-7, VIPCOT (trademark) Cotton], A92: [Cotton, COT102xCOT67B, SYN- IR102-7NAxNASYN-IR67B-1, VIPCOT ™ Cotton], A93: [Cotton, COT102xCOT67BxMON88913, SYN-IR102-7NAxNASYN-IR67B-1NAxNAMON-88913-8, VIPCOT ™ RoundupReadyFlex ™ Cotton], A94: [ Cotton, COT102xMON15985, SYN-IR102-7NAxNAMON-15985-7, Bollgard (registered trademark) III], A95: [Cotton, COT102xMON15985xMON88913, SYN-IR102-7NAxNAMON-15985-7NAxNAMON-88913-8, Bollgard (registered trademark) IIIxRoundupReady ( Trademark) Flex (trademark)], A96: [Cotton, COT102xMON15985xMON88913xMON88701, SYN-IR102-7NAxNAMON-15985-7NAxNAMON-88913-8NAxNAMONNA88701-3, NA], A97: [Cotton, COT67B (IR67B), SYN-IR67B-1, NA], A 98: [Cotton, Event1, NA, JK1], A99: [Cotton, GFMCry1A, GTL-GFM311-7, NA], A100: [Cotton, GHB119, BCS-GH005-8, NA],
A101: [Cotton, GHB614, BCS-GH002-5, GlyTol (trademark)], A102: [Cotton, GHB614xLLCotton25, BCS-GH002-5NAxNAACS-GH001-3, GlyTol (trademark) LibertyLink (trademark)], A103: [Cotton , GHB614xLLCotton25xMON15985, BCS-GH002-5NAxNAACS-GH001-3NAxNAMON-15985-7, NA], A104: [Cotton, GHB614xMON15985, BCS-GH002-5NA × NAMON-15985, NA], A105: [Cotton, GHB614xT304-40xGHB119, BCS -GH002-5NAxNABCS-GH004-7NAxNABCS-GH005-8, Glytol (TM) xTwinlink (TM)], A106: [Cotton, GHB614xT304-40xGHB119xCOT102, BCS-GH002-5NAxNABCS-GH004-7NAxNABCS-GH005-8NAxNASYN-IR102-7 Glytol ™ xTwinlink ™ xVIPCOT ™ Cotton], A107: [Cotton, GK12, NA, NA], A108: [Cotton, LLCotton25, ACS-GH001-3NA, Fibermax ™ LibertyLink ™], A109: [Cotton, LLCotton25xMON15985, ACS-GH001-3NAxNAMON-15985-7, Fibermax (TM) LibertyLink (TM) BollgardII (TM)], A110: [Cotton, MLS9124, NA, NA], A111: [Co Ton, MON1076, MON-89924-2, Bollgard (trademark) Cotton], A112: [Cotton, MON1445, MON-01445-2, RoundupReady (trademark) Cotton], A113: [Cotton, MON15985, MON-15985-7, BollgardII ™ Cotton], A114: [Cotton, MON15985xMON1445, MON-15985-7NAxNAMON-01445-2, RoundupReady ™ BollgardII ™ Cotton], A115: [Cotton, MON1698, MON-89383-1, RoundupReady ( Trademark) Cotton], A116: [Cotton, MON531, MON-00531-6, Bollgard (trademark) Cotton, Ingard (trademark)], A117: [Cotton, MON531xMON1445, MON-0531-6NAxNAMON-01445-2, RoundupReady (trademark) ) Bollgard (TM) Cotton], A118: [Cotton, MON757, MON-00757-7, Bollgard (TM) Cotton], A119: [Cotton, MON88701, MONNA88701-3, NA], A120: [Cotton, MON88701xMON88913, MONNA88701 -3NAxNAMON-88913-8, NA], A121: [Cotton, MON88701xMON88913xMON15985, MONNA88701-3NAxNAMON-88913-8NAxNAMON-15985-7, Bollgard II (registered trademark) XtendFlex (trademark) Cotton], A122: [Cotton, MON88913, MON-88913-8, RoundupReady (TM) Flex (TM) Cotton], A123: [Cotton, MON88913xMON15985, MON-88913-8NAxNAMON-15985-7, RoundupReady (TM) Flex (TM) BollgardII (TM) ) Cotton], A124: [Cotton, NgweChi6Bt, NA, NgweChi6Bt], A125: [Cotton, SGK321, NA, NA], A126: [Cotton, T303-3, BCS-GH003-6, NA], A127: [Cotton , T304-40, BCS-GH004-7, NA], A128: [Cotton, T304-40xGHB119, BCS-GH004-7NAxNABCS-GH005-8, TwinLink (trademark) Cotton], A129: [Creeping bent glass, ASR368, SMG -36800-2, NA], A130: [Nasal, BtBrinjalEventEE1, BtBrinjalEventEE1, BARIBtBegun-1, -2, -3and-4], A131: [Eucali, H421, H421, GMEucalyptus], A132: [Ama, FP967 (CDCTriffid ), CDC-FL001-2, CDCTriffidFlax], A133: [Lentil, RH44, RH44, Clearfield ™ lentil], A134: [Corn, 32138, DP-32138-132138, 2138SPTmaintainer], A135: [Corn, 3272, SYN-E327 2-5, Enogen (TM)], A136: [Corn, 3272xBt11, SYN-E3272-5xSYN-BT011-1, NA], A137: [Corn, 3272xBt11xGA21, SYN-E3272-5xSYN-BT011-1xMON-00021-9 , NA], A138: [corn, 3272xBt11xMIR604, SYN-E3272-5xSYN-BT011-1xSYN-IR604-5, NA], A139: [corn, 3272xBT11xMIR604xGA21, SYN-E3272-5xSYN-BT011-1xSYN-IR604-5xMON-00021 -9, NA], A140: [corn, 3272xBt11xMIR604xTC1507x5307xGA21, SYN-E3272-5xSYN-BT011-1xSYN-IR604-5xDAS-01507-1xSYN-05307-1xMON-00021-9, NA], A141: [corn, 3272xGA21, SYN -E3272-5xMON-00021-9, NA], A142: [Corn, 3272xMIR604, SYN-E3272-5xSYN-IR604-5, NA], A143: [Corn, 3272xMIR604xGA21, SYN-E3272-5xSYN-IR604-5xMON-00021 -9, NA], A144: corn, 33121, DP-033121-3, NA], A145: [corn, 4114, DP-004114-3, NA], A146: [corn, 5307, SYN-05307-1, Agrisure (R) Duracade (R)], A147: [Tomato Rokosi, 5307xGA21, SYN-05307-1xMON-00021-9, NA], A148: [Corn, 5307xMIR604xBt11xTC1507xGA21, SYN-05307-1xSYN-IR604-5xSYN-BT011-1xDAS-01507-1xMON-00021-9, Agrisure (registered trademark) ) Duracade (TM) 5122], A149: [Corn, 5307xMIR604xBt11xTC1507xGA21xMIR162, SYN-05307-1xSYN-IR604-5xSYN-BT011-1xDAS-01507-1xMON-00021-9xSYN-IR162-4, Agrisure (R) Duracade (TM) 5222], A150: [corn, 59122, DAS-59122-7, Herculex ™ RW],
A151: [Corn, 59122xDAS40278, DAS-59122-7xDAS-40278-9, NA], A152: [Corn, 59122xGA21, DAS-59122-7xMON-00021-9, NA], A153: [Corn, 59122xMIR604, DAS-59122 -7xSYN-IR604-5, NA], A154: [corn, 59122xMIR604xGA21, DAS-59122-7xSYN-IR604-5xMON-00021-9, NA], A155: [corn, 59122xMIR604xTC1507, DAS-59122-7xSYN-IR604-5xDAS -01507-1, NA], A156: [corn, 59122xMIR604xTC1507xGA21, DAS-59122-7xSYN-IR604-5xDAS-01507-1xMON-00021-9, NA], A157: [corn, 59122xMON810, DAS-59122-7xMON-00810 -6, NA], A158: [corn, 59122xMON810xMIR604, DAS-59122-7xMON-00810-6xSYN-IR604-5, NA], A159: [corn, 59122xMON810xNK603, DAS-59122-7xMON-00810-6xMON-00603-6 , NA], A160: [corn, 59122xMON810xNK603xMIR604, DAS-59122-7xMON-00810-6xMON-00603-6xSYN-IR604-5, NA], A161: [corn, 59122xMON88017, DAS-59122-7xMON-88017-3, NA ], A162: [Tow Rokosi, 59122xMON88017xDAS40278, DAS-59122-7xMON-88017-3xDAS-40278-9, NA], A163: [corn, 59122xNK603, DAS-59122-7xMON-00603-6, Herculex ™ RWRoundupReady ™ 2], A164 : [Corn, 59122xNK603xMIR604, DAS-59122-7xMON-00603-6xSYN-IR604-5, NA], A165: [Corn, 59122xTC1507xGA21, DAS-59122-7xDAS-01507-1xMON-00021-9, NA], A166: [ Corn, 676, PH-000676-7, NA], A167: [corn, 678, PH-000678-9, NA], A168: [corn, 680, PH-000680-2, NA], A169: [corn, 98140, DP-098140-6, Optimum (TM) GAT (TM)], A170: [Corn, 98140x59122, DP-098140-6xDAS-59122-7, NA], A171: [Corn, 98140xTC1507, DP-098140-6xDAS -01507-1, NA], A172: [corn, 98140xTC1507x59122, DP-098140-6xDAS-01507-1xDAS-59122-7, NA], A173: [corn, Bt10, NA, Bt10], A174: [corn, Bt11 (X4334CBR, X4734CBR), SYN-BT011-1, A grisure (trademark) CB / LL], A175: [corn, Bt11x5307, SYN-BT011-1xSYN-05307-1, NA], A176: [corn, Bt11x5307xGA21, SYN-BT011-1xSYN-05307-1xMON-00021-9, NA], A177: [corn, Bt11x59122, SYN-BT011-1xDAS-59122-7, NA], A178: [corn, Bt11x59122xGA21, SYN-BT011-1xDAS-59122-7xMON-00021-9, NA], A179: [ Corn, Bt11x59122xMIR604, SYN-BT011-1xDAS-59122-7xSYN-IR604-5, NA], A180: [Corn, Bt11x59122xMIR604xGA21, SYN-BT011-1xDAS-59122-7xSYN-IR604-5xMON-00021-9, NA], A181 : [Corn, Bt11x59122xMIR604xTC1507, SYN-BT011-1xDAS-59122-7xSYN-IR604-5xDAS-01507-1, NA], A182: [Corn, BT11x59122xMIR604xTC1507xGA21, SYN-BT011-1xDAS-59122-7xSYN-IR604-5xDAS507 1xMON-00021-9, Agrisure® 3122], A183: [corn, Bt11x59122xTC1507, SYN-BT011-1xDAS-59122-7xDAS-01507-1, NA], A184: [corn, Bt11x59122xTC1507xGA21, SYN-BT011-1xDAS -59122-7xDAS-0 1507-1xMON-00021-9, NA], A185: [Maize, Bt11xGA21, SYN-BT011-1xMON-00021-9, Agrisure ™ GT / CB / LL], A186: [Corn, Bt11xMIR162, SYN-BT011- 1xSYN-IR162-4, Agrisure® Viptera ™ 2100], A187: [corn, Bt11xMIR162x5307, SYN-BT011-1xSYN-IR162-4xSYN-05307-1, NA], A188: [corn, Bt11xMIR162x5307xGA21, SYN -BT011-1xSYN-IR162-4xSYN-05307-1xMON-00021-9, NA], A189: [corn, Bt11xMIR162xGA21, SYN-BT011-1xSYN-IR162-4xMON-00021-9, Agrisure (R) Viptera (TM) 3110], A190: [corn, BT11xMIR162xMIR604, SYN-BT011-1xSYN-IR162-4xSYN-IR604-5, Agrisure® Viptera ™ 3100], A191: [corn, BT11xMIR162xMIR604x5307, SYN-BT011-1xSYN-IR162 -4xSYN-IR604-5xSYN-05307-1, NA], A192: [Maize, Bt11xMIR162xMIR604x5307xGA21, SYN-BT011-1xSYN-IR162-4xSYN-IR604-5xSYN-05307-1xMON-00021-9, NA], A193: [Corn , Bt11xMIR162xMIR60 4xGA21, SYN-BT011-1xSYN-IR162-4xSYN-IR604-5xMON-00021-9, Agrisure (R) Viptera (TM) 3111, Agrisure (R) Viptera (TM) 4], A194: [corn, Bt11xMIR162xMIR604xMON89034x5307xGA21, SYN-BT011-1xSYN-IR162-4xSYN-IR604-5xMON-89034-3xSYN-05307-1xMON-00021-9, NA], A195: [corn, BT11xMIR162xMIR604xTC1507, SYN-BT011-1xSYN-IR162-4xSYN-IR604-5xDAS- 01507-1, NA], A196: [corn, BT11xMIR162xMIR604xTC1507x5307, SYN-BT011-1xSYN-IR162-4xSYN-IR604-5xDAS-01507-1xSYN-05307-1, NA], A197: [corn, Bt11xMIR162xMIR604xTC1507xGA21, SYN-BT011- 1xSYN-IR162-4xSYN-IR604-5xDAS-01507-1xMON-00021-9, NA], A198: [corn, Bt11xMIR162xMON89034, SYN-BT011-1xSYN-IR162-4xMON-89034-3, NA], A199: [corn, Bt11xMIR162xMON89034xGA21, SYN-BT011-1xSYN-IR162-4xMON-89034-3xMON-00021-9, NA], A200: [corn, Bt11xMIR162xTC1507, SYN-BT011-1xSYN-IR162-4xDAS-01507-1, NA],
A201: [Corn, Bt11xMIR162xTC1507x5307, SYN-BT011-1xSYN-IR162-4xDAS-01507-1xSYN-05307-1, NA], A202: [Corn, Bt11xMIR162xTC1507x5307xGA21, SYN-BT011-1xSYN-IR162-4xDAS-01507-1xSYN-05 -1xMON-00021-9, NA], A203: [Maize, Bt11xMIR162xTC1507xGA21, SYN-BT011-1xSYN-IR162-4xDAS-01507-1xMON-00021-9, Agrisure ™ Viptera3220], A204: [Corn, Bt11xMIR604, SYN -BT011-1xSYN-IR604-5, Agrisure ™ CB / LL / RW], A205: [corn, Bt11xMIR604x5307, SYN-BT011-1xSYN-IR604-5xSYN-05307-1, NA], A206: [corn, Bt11xMIR604x5307xGA21 , SYN-BT011-1xSYN-IR604-5xSYN-05307-1xMON-00021-9, NA], A207: [corn, BT11xMIR604xGA21, SYN-BT011-1xSYN-IR604-5xMON-00021-9, Agrisure (TM) 3000GT], A208: [Corn, Bt11xMIR604xTC1507, SYN-BT011-1xSYN-IR604-5xDAS-01507-1, NA], A209: [Corn, Bt11xMIR604xTC1507x5307, SYN-BT011-1xSYN-IR604-5xDAS-01507-1xSYN-05307-1, NA ], A210 : [Corn, Bt11xMIR604xTC1507xGA21, SYN-BT011-1xSYN-IR604-5xDAS-01507-1xMON-00021-9, NA], A211: [Corn, Bt11xMON89034, SYN-BT011-1xMON-89034-3, NA], A212: [ Corn, Bt11xMON89034xGA21, SYN-BT011-1xMON-89034-3xMON-00021-9, NA], A213: [Corn, Bt11xTC1507, SYN-BT011-1xDAS-01507-1, NA], A214: [Corn, Bt11xTC1507x5307, SYN- BT011-1xDAS-01507-1xSYN-05307-1, NA], A215: [Maize, Bt11xTC1507x5307xGA21, SYN-BT011-1xDAS-01507-1xSYN-05307-1xMON-00021-9, NA], A216: [Corn, Bt11xTC1507xGA21, SYN-BT011-1xDAS-01507-1xMON-00021-9, NA], A217: [corn, Bt176 (176), SYN-EV176-9, NaturGardKnockOut ™, Maximizer ™], A218: [corn, BVLA430101 , NA, NA], A219: [corn, CBH-351, ACS-ZM004-3, Starlink ™ Maize], A220: [corn, DAS40278, DAS-40278-9, Enlist ™ Maize], A221: [Corn, DAS402 78xNK603, DAS-40278-9xMON-00603-6, NA], A222: [Maize, DBT418, DKB-89614-9, BtXtra ™ Maize], A223: [Corn, DLL25 (B16), DKB-89790-5 , NA], A224: [corn, GA21, MON-00021-9, RoundupReady (trademark) Maize, Agrisure (trademark) GT], A225: [corn, GA21xMON810, MON-00021-9xMON-00810-6, RoundupReady (trademark) ) YieldGard ™ maize], A226: [corn, GA21xT25, MON-00021-9xACS-ZM003-2, NA], A227: [corn, HCEM485, HCEM485, NA], A228: [corn, LY038, REN-00038 -3, Mavera ™ Maize], A229: [corn, LY038xMON810, REN-00038-3xMON-00810-6, Mavera ™ YieldGard ™ Maize], A230: [corn, MIR162, SYN-IR162-4 Agrisure ™ Viptera], A231: [corn, MIR162x5307, SYN-IR162-4xSYN-05307-1, NA], A232: [corn, MIR162x5307xGA21, SYN-IR162-4xSYN-05307-1xMON-00021-9, NA ], A233: [Corn, MIR 162xGA21, SYN-IR162-4xMON-00021-9, NA], A234: [Maize, MIR162xMIR604, SYN-IR162-4xSYN-IR604-5, NA], A235: [Corn, MIR162xMIR604x5307, SYN-IR162-4xSYN-IR604- 5xSYN-05307-1, NA], A236: [corn, MIR162xMIR604x5307xGA21, SYN-IR162-4xSYN-IR604-5xSYN-05307-1xMON-00021-9, NA], A237: [corn, MIR162xMIR604xGA21, SYN-IR162-4xSYN- IR604-5xMON-00021-9, NA], A238: [corn, MIR162xMIR604xTC1507x5307, SYN-IR162-4xSYN-IR604-5xDAS-01507-1xSYN-05307-1, NA], A239: [corn, MIR162xMIR604xTC1507x5307xGA21, SYN-IR162- 4xSYN-IR604-5xDAS-01507-1xSYN-05307-1xMON-00021-9, NA], A240: [Corn, MIR162xMIR604xTC1507xGA21, SYN-IR162-4xSYN-IR604-5xDAS-01507-1xMON-00021-9, NA], A241 : [Corn, MIR162xMON89034, SYN-IR162-4xMON-89034-3, NA], A242: [Corn, MIR162xMON89034xGA21, SYN-IR162-4xMON-89034-3xMON-00021-9, NA], A243: [Corn, MIR162xNK603, SYN-IR 162-4xMON-00603-6, NA], A244: [Corn, MIR162xTC1507, SYN-IR162-4xDAS-01507-1, NA], A245: [Corn, MIR162xTC1507x5307, SYN-IR162-4xDAS-01507-1xSYN-05307- 1, NA], A246: [corn, MIR162xTC1507x5307xGA21, SYN-IR162-4xDAS-01507-1xSYN-05307-1xMON-00021-9, NA], A247: [corn, MIR162xTC1507xGA21, SYN-IR162-4xDAS-01507-1xMON- 00021-9, NA], A248: [corn, MIR604, SYN-IR604-5, Agrisure ™ RW], A249: [corn, MIR604x5307, SYN-IR604-5xSYN-05307-1, NA], A250: [ Corn, MIR604x5307xGA21, SYN-IR604-5xSYN-05307-1xMON-00021-9, NA],
A251: [Corn, MIR604xGA21, SYN-IR604-5xMON-00021-9, Agrisure (trademark) GT / RW], A252: [Corn, MIR604xNK603, SYN-IR604-5xMON-00603-6, NA], A253: [Corn , MIR604xTC1507, SYN-IR604-5xDAS-01507-1, Optimum® TRIsect ™], A254: [corn, MIR604xTC1507x5307, SYN-IR604-5xDAS-01507-1xSYN-05307-1, NA], A255: [Corn, MIR604xTC1507x5307xGA21, SYN-IR604-5xTC1507xSYN-05307-1xMON-00021-9, NA], A256: [Corn, MIR604xTC1507xGA21, SYN-IR604-5xTC1507xMON-00021-9, NA], A257: [Corn, MON801 (MON80100 ), MON801, NA], A258: [corn, MON802, MON-80200-7, NA], A259: [corn, MON809, PH-MON-809-2, NA], A260: [corn, MON810, MON- 00810-6, YieldGard (trademark), MaizeGard (trademark)], A261: [corn, MON810xMIR162, MON-00810-6xSYN-IR162-4, NA], A262: [corn, MON810xMIR162xNK603, MON-00810-6xSYN-IR162- 4xM ON-00603-6, NA], A263: [corn, MON810xMIR604, MON-00810-6xSYN-IR604-5, NA], A264: [corn, MON810xMON88017, MON-00810-6xMON-88017-3, YieldGard (trademark) VTTriple], A265: [corn, MON810xNK603xMIR604, MON-00810-6xMON-00603-6xSYN-IR604-5, NA], A266: [corn, MON832, NA, RoundupReady (TM) Maize], A267: [corn, MON863, MON-00863-5, YieldGard (TM) RootwormRW, MaxGard (TM)], A268: [corn, MON863xMON810, MON-00863-5xMON-00810-6, YieldGard (TM) Plus], A269: [corn, MON863xMON810xNK603, MON -00603-6xMON-00810-6xMON-00863-5, YieldGard ™ PluswithRR], A270: [corn, MON863xNK603, MON-00863-5xMON-00603-6, YieldGard ™ RW + RR], A271: [corn , MON87403, MON87403-1, NA], A272: [corn, MON87411, MON-87411-9, NA], A273: [corn, MON87419, MON87419-8, NA], A274: [corn, MON 87427, MON-87427-7, RoundupReady ™ Maize], A275: [corn, MON87427x59122, MON-87427-7xDAS-59122-7, NA], A276: [corn, MON87427xMON88017, MON-87427-7xMON-88017- 3, NA], A277: [corn, MON87427xMON88017x59122, MON-87427-7xMON-88017-3xDAS-59122-7, NA], A278: [corn, MON87427xMON89034, MON-87427-7xMON-89034-3, NA], A279 : [Corn, MON87427xMON89034x59122, MON-87427-7xMON-89034-3xDAS-59122-7, NA], A280: [Corn, MON87427xMON89034xMON88017, MON-87427-7xMON-89034-3xMON-88017-3, NA], A281: [ Corn, MON87427xMON89034xMON88017x59122, MON-87427-7xMON-89034-3xMON-88017-3x59122, NA], A282: [corn, MON87427xMON89034xNK603, MON-87427-7xMON-89034-3xMON-00603-6, NA], A283: [corn, MON87427xMON89034xTC1507, MON-87427-7xMON-89034-3xDAS-01507-1, NA], A284: [Corn, MON87427xMON89034xTC1507x59122, MON-87427-7xMON-89034-3xDAS-0150 7-1xDAS-59122-7, NA], A285: [corn, MON87427xMON89034xTC1507xMON87411x59122, MON-87427-7xMON-89034-3xDAS-01507-1xMON-87411-9xDAS-59122-7, NA], A286: [corn, MON87427xMON89034xTC1507xMON88017, MON-87427-7xMON-89034-3xDAS-01507-1xMON-88017-3, NA], A287: [Corn, MON87427xMON89034xMIR162xNK603, MON-87427-7xMON-89034-3xSYN-IR162-4xMON-00603-6, NA], A288 : [Corn, MON87427xMON89034xTC1507xMON88017x59122, MON-87427-7xMON-89034-3xDAS-01507-1xMON-88017-3xDAS-59122-7, NA], A289: [Corn, MON87427xNK603, MON-87427-7xMON-00603-6, NA] , A290: [corn, MON87427xTC1507, MON-87427-7xDAS-01507-1, NA], A291: [corn, MON87427xTC1507x59122, MON-87427-7xDAS-01507-1xDAS-59122-7, NA], A292: [corn, MON87427xTC1507xMON88017, MON-87427-7xDAS-01507-1xMON-88017-3, NA], A293: [Corn, MON87427xTC1507xMON88017x59122, MON-87427-7xDAS-01507-1xMON-88017-3xDAS-591 22-7, NA], A294: [Corn, MON87460, MON-87460-4, Genuity (R) DroughtGard (TM)], A295: [Corn, MON87460xMON88017, MON-87460-4xMON-88017-3, NA] , A296: [corn, MON87460xMON89034xMON88017, MON-87460-4xMON-89034-3xMON-88017-3, NA], A297: [corn, MON87460xMON89034xNK603, MON-87460-4xMON-89034-3xMON-00603-6, NA], A298 : [Corn, MON87460xNK603, MON-87460-4xMON-00603-6, NA], A299: [Corn, MON88017, MON-88017-3, YieldGard (TM) VT (TM) Rootworm (TM) RR2], A300: [ Corn, MON88017xDAS40278, MON-88017-3xDAS-40278-9, NA],
A301: [corn, MON89034, MON-89034-3, YieldGard ™ VTPro ™], A302: [corn, MON89034x59122, MON-89034-3xDAS-59122-7, NA], A303: [corn, MON89034x59122xDAS40278, MON-89034-3xDAS-59122-7xDAS-40278-9, NA], A304: [Corn, MON89034x59122xMON88017, MON-89034-3xDAS-59122-7xMON-88017-3, NA], A305: [Corn, MON89034x59122xMON88017xDAS40278, MON- 89034-3xDAS-59122-7xMON-88017-3xDAS-40278-9, NA], A306: [Corn, MON89034xDAS40278, MON-89034-3xDAS-40278-9, NA], A307: [Corn, MON89034xMON87460, MON-89034- 3xMON-87460-4, NA], A308: [corn, MON89034xMON88017, MON-89034-3xMON-88017-3, Genuity (registered trademark) VTTriplePro (TM)], A309: [corn, MON89034xMON88017xDAS40278, MON-89034-3xMON- 88017-3xDAS-40278-9, NA], A310: [corn, MON89034xNK603, MON-89034-3xMON-00603-6, Genuity (R) VTDoublePro (TM)], A311 [Corn, MON89034xNK603xDAS40278, MON-89034-3xMON-00603-6xDAS-40278-9, NA], A312: [Corn, MON89034xTC1507, MON-89034-3xDAS-01507-1, NA], A313: [Corn, MON89034xTC1507x59122, MON -89034-3xDAS-01507-1xDAS-59122-7, NA], A314: [Corn, MON89034xTC1507x59122xDAS40278, MON-89034-3xDAS-01507-1xDAS-59122-7xDAS-40278-9, NA], A315: [Corn, MON89034xTC1507xDAS40278 , MON-89034-3xDAS-01507-1xDAS-40278-9, NA], A316: [corn, MON89034xTC1507xMON88017, MON-89034-3xDAS-01507-1xMON-88017-3, NA], A317: [corn, MON89034xTC1507xMON88017x59122, MON -89034-3xDAS-01507-1xMON-88017-3xDAS-59122-7, Genuity (R) SmartStax (TM)], A318: [Corn, MON89034xTC1507xMON88017x59122xDAS40278, MON-89034-3xDAS-01507-1xMON-88017-3xDAS-59122 -7xDAS-40278-9, NA], A319: [corn, MON89034xTC1507xMON88017xDAS40278, MON-89034-3xDAS-01507-1xMON-88017-3xDAS-59122-7xDA S-40278-9, NA], A320: [Corn, MON89034xTC1507xNK603, MON-89034-3xDAS-01507-1xMON-00603-6, PowerCore (TM)], A321: [Corn, MON89034xTC1507xNK603xDAS40278, MON-89034-3xDAS-01507 -1xMON-00603-6xDAS-40278-9, NA], A322: [Corn, MON89034xTC1507xNK603xMIR162, MON-89034-3xDAS-01507-1xMON-00603-6xSYN-IR162-4, NA], A323: [Corn, MON89034xTC1507xNK603xMIR162xDAS40278, MON -89034-3xDAS-01507-1xMON-00603-6xSYN-IR162-4xDAS-40278-9, NA], A324: [corn, MON89034xGA21, MON-89034-3xMON-00021-9, NA], A325: [corn, MS3 ACS-ZM001-9, InVigor ™ Maize], A326: [corn, MS6, ACS-ZM005-4, InVigor ™ Maize], A327: [corn, MZHG0JG, SYN-000JG-2, NA], A328: [Corn, MZIR098, SYN-00098-3, NA], A329: [Corn, NK603, MON-00603-6, RoundupReady (TM) 2Maize], A330: [Corn, NK603xMON810x4114xMIR604, MON-00603-6xM ON-00810-6xDP004114-3xSYN-IR604-4, NA], A331: [corn, NK603xMON810, MON-00603-6xMON-00810-6, YieldGard (trademark) CB + RR], A332: [corn, NK603xT25, MON- 00603-6xACS-ZM003-2, RoundupReady ™ LibertyLink ™ Maize], A333: [corn, T14, ACS-ZM002-1, LibertyLink ™ Maize], A334: [corn, T25, ACS-ZM003- 2, LibertyLink ™ Maize], A335: [corn, T25xMON810, ACS-ZM003-2xMON-00810-6, LibertyLink ™ Yieldgard ™ Maize], A336: [corn, TC1507, DAS-01507-1, Herculex (trademark) I, Herculex (trademark) CB], A337: [corn, TC1507 × 59122 × MON810 × MIR604xNK603, DAS-01507-1 × DAS-59122-7 × MON-00810-6 × SYN-IR604-5xMON- 00603-6, Optimum ™ IntrasectXtreme], A338: [corn, TC1507 × MON810 × MIR604 × NK603, DAS-01507-1 × MON-00810-6 × SYN-IR604-5 × MON-00603-6, NA] , A339: [Corn, TC1507x5307, DAS-01507-1xSYN-05307-1, NA], A340: [Corn, TC1507x5307xGA21, DAS-01507-1xSYN-05307-1xMON-00021-9, NA], A341: [Corn, TC1507x59122, DAS-01507-1xDAS-59122-7, HerculexXTRA ™], A342: [Corn, TC1507x59122xDAS40278, DAS-01507-1xDAS-59122-7xDAS-40278-9, NA], A343: [Corn, TC1507x59122xMON810, DAS-01507-1xDAS-59122-7xMON-00810-6, Optimum (R) AcreMax (R) Xtra], A344: [corn, TC1507x59122xMON810xMIR604, DAS-01507-1xDAS-59122-7xMON-00810-6xSYN-IR604-5, Optimum (R) AcreMax (R) XTreme], A345: [corn, TC1507x59122xMON810xNK603, DAS- 01507-1xDAS-59122-7xMON-00810-6xMON-00603-6, Optimum ™ IntrasectXTRA], A346: [Corn, TC1507x59122xMON88017, DAS-01507-1xDAS-59122-7xMON-88017-3, NA], A347: [ Corn, TC1507x59122xMON88017xDAS40278, DAS-01507-1xDAS-59122-7xMON-88017-3xDAS-40278-9, NA], A348: [Corn, TC1507x59122xNK603, DAS-01507-1xDAS -59122-7xMON-00603-6, HerculexXTRA ™ RR], A349: [corn, TC1507x59122xNK603xMIR604, DAS-01507-1xDAS-59122-7xMON-00603-6xSYN-IR604-5, NA], A350: [corn, TC1507xDAS40278 , DAS-01507-1xDAS-40278-9, NA],
A351: [Corn, TC1507xGA21, DAS-01507-1xMON-00021-9, NA], A352: [Corn, TC1507xMIR162xNK603, DAS-01507-1xSYN-IR162-4xMON-00603-6, Optimum (registered trademark) Leptra (trademark) ], A353: [corn, TC1507xMIR604xNK603, DAS-01507-1xSYN-IR604-5xMON-00603-6, Optimum (TM) TRIsect], A354: [corn, TC1507xMON810, DAS-01507-1xMON-00, NA], A355: [Corn, TC1507xMON810xMIR162, DAS-01507-1xMON-00810-6xSYN-IR162-4, NA], A356: [Corn, TC1507xMON810xMIR162xNK603, DAS-01507-1xMON-00810-6xSYN-IR162-4xMON-00603-6, NA], A357: [Corn, TC1507xMON810xMIR604, DAS-01507-1xMON-00810-6xSYN-IR604-5, NA], A358: [Corn, TC1507xMON810xNK603, DAS-01507-1xMON-00810-6xMON-00603-6, Optimum (TM) Intrasect ], A359: [Maize, TC1507xMON810xNK603xMIR604, DAS-01507-1xMON-00810-6xMON-00603-6xSYN-IR604-5, NA], A360: [Corn, TC1507xMON88017, DAS-01507-1xMON-88017- 3, NA], A361: [corn, TC1507xMON88017xDAS40278, DAS-01507-1xMON-88017-3xDAS-40278-9, NA], A362: [corn, TC1507xNK603, DAS-01507-1xMON-00603-6, Herculex (trademark) IRR], A363: [corn, TC1507xNK603xDAS40278, DAS-01507-1xMON-00603-6xDAS-40278-9, NA], A364: [corn, TC6275, DAS-06275-8, NA], A365: [corn, VCO- 01981-5, VCO-01981-5, NA], A366: [Corn, DK404SR, DK404SR, NA], A367: [Corn, EXP1910IT, EXP1910IT, NA], A368: [Melon, MelonA, NA, NA], A369 : [Melon, MelonB, NA, NA], A370: [Papaya, 55-1, CUH-CP551-8, Rainbow, SunUp], A371: [Papaya, 63-1, CUH-CP631-7, NA], A372 : [Papaya, HuanongNo.1, NA, HuanongNo.1], A373: [Papaya, X17-2, UFL-X17CP-6, NA], A374: [Petunia, Petunia-CHS, NA, NA], A375: [ Plum, C-5, ARS-PLMC5-6, NA], A376: [Polish canola, HCR-1, NA, NA], A377: [ Rich canola, ZSR500, NA, Hysyn101RRRoundup-Ready (trademark)], A378: [Polish canola, ZSR502, NA, Hysyn101RRRoundup-Ready (trademark)], A379: [Polish canola, ZSR503, NA, Hysyn101RRRoundup-Ready (trademark)] , A380: [Poplar, Btpoplar, poplar12 (Populusnigra), NA, NA], A381: [Poplar, Hybridpoplarclone741, NA, NA], A382: [Potato, 1210amk, NA, Lugovskoiplus], A383: [Potato, 2904 / 1kgs , NA, Elizavetaplus], A384: [potato, AM04-1020, BPS-A1020-5, StarchPotato], A385: [potato, ATBT04-27, NMK-89367-8, AtlanticNewLeaf (trademark) potato], A386: [potato ATBT04-30, NMK-89613-2, AtlanticNewLeaf ™ potato], A387: [potato, ATBT04-31, NMK-89170-9, AtlanticNewLeaf ™ potato], A388: [potato, ATBT04-36, NMK -89279-1, AtlanticNewLeaf ™ potato], A389: [potato, ATBT04-6, NMK-89761-6, AtlanticNewLeaf ™ potato], A390 : [Potato, BT06, NMK-89812-3, NewLeaf (trademark) RussetBurbankpotato], A391: [potato, BT10, NMK-89175-5, NewLeaf (trademark) RussetBurbankpotato], A392: [potato, BT12, NMK-89601- 8, NewLeaf ™ RussetBurbankpotato], A393: [potato, BT16, NMK-89167-6, NewLeaf ™ RussetBurbankpotato], A394: [potato, BT17, NMK-89593-9, NewLeaf ™ RussetBurbankpotato], A395 : [Potato, BT18, NMK-89906-7, NewLeaf (trademark) RussetBurbankpotato], A396: [potato, BT23, NMK-89675-1, NewLeaf (trademark) RussetBurbankpotato], A397: [potato, E12, SPS-00E12- 8, Innate (registered trademark) Cultivate], A398: [potato, E24, SPS-00E24-2, NA], A399: [potato, EH92-527-1, BPS-25271EH92-527-1-9, Amflora (trademark) )], A400: [potato, F10, SPS-00F10-7, Innate (registered trademark) Generate],
A401: [potato, F37, SPS-00F37-7, NA], A402: [potato, G11, SPS-00G11-9, NA], A403: [potato, H37, SPS-00H37-9, NA], A404: [Potato, H50, SPS-00H50-4, NA], A405: [potato, HLMT15-15, NA, Hi-LiteNewLeaf (trademark) Ypotato], A406: [potato, HLMT15-3, NA, Hi-LiteNewLeaf (trademark) ) Ypotato], A407: [potato, HLMT15-46, NA, Hi-Lite NewLeaf (trademark) Ypotato], A408: [potato, J3, SPS-000J3-4, Innate (registered trade mark) Accelerate], A409: [potato, J55, SPS-00J55-2, NA], A410: [potato, J78, SPS-00J78-7, NA], A411: [potato, RBMT15-101, NMK-89653-6, NewLeaf (TM) YRussetBurbankpotato], A412 : [Potato, RBMT21-129, NMK-89684-1, NewLeaf (TM) PlusRussetBurbankpotato], A413: [potato, RBMT21-152, NA, NewLeaf (TM) PlusRussetBurbankpotato], A414: [potato, RBMT21-350, NMK- 89185-6, NewLeaf ™ PlusRussetBurbankpotato] A415: [potato, RBMT22-082, NMK-89896-6, NewLeaf (TM) PlusRussetBurbankpotato], A416: [potato, RBMT22-186, NA, NewLeaf (TM) PlusRussetBurbankpotato], A417: [potato, RBMT22-238, NA NewLeaf (TM) PlusRussetBurbankpotato], A418: [potato, RBMT22-262, NA, NewLeaf (TM) PlusRussetBurbankpotato], A419: [potato, SEMT15-02, NMK-89935-9, ShepodyNewLeaf (TM) Ypotato], A420: [Potato, SEMT15-07, NA, ShepodyNewLeaf ™ Ypotato], A421: [potato, SEMT15-15, NMK-89930-4, ShepodyNewLeaf ™ Ypotato], A422: [potato, SPBT02-5, NMK-89576 -1, SuperiorNewLeaf ™ potato], A423: [potato, SPBT02-7, NMK-89724-5, SuperiorNewLeaf ™ potato], A424: [potato, TIC-AR233-5, TIC-AR233-5, NA ], A425: [potato, V11, SPS-00V11-6, Innate (registered trademark) Invigorate], A426: [potato, W8, SPS-000W8-4, Innate (registered trademark) Glac iate], A427: [potato, X17, SPS-00X17-5, Innate (registered trademark) Acclimate], A428: [potato, Y9, SPS-000Y9-7, Innate (registered trademark) Hibernate], A429: [rice, 7Crp # 10, NA, NA], A430: [Rice, GMShanyou63, NA, BTShanyou63], A431: [Rice, Huahui-1 / TT51-1, NA, Huahui-1], A432: [Rice, LLRICE06, ACS- OS001-4, LibertyLink (trademark) rice], A433: [Rice, LLRICE601, BCS-OS003-7, LibertyLink (trademark) rice], A434: [Rice, LLRICE62, ACS-OS002-5, LibertyLink (trademark) rice] , A435: [Rice, Tarommolaii + cry1Ab, NA, NA], A436: [Rice, CL121xCL141xCFX51, CL121xCL141xCFX51, Clearfield ™ Rice], A437: [Rice, IMINTA-1xIMINTA-4, IMINTA-1xIMINTA-4, Clearfield ( Trademark) Rice], A438: [Rice, PWC16, PWC16, NA], A439: [Rose, WKS82 / 130-4-1, IFD-52401-4, NA], A440: [Rose, WKS92 / 130-9- 1, IFD-52901-9, NA], A441: [soybean, 260-05 (G94-1, G94-19, G168), DD-026005-3, NA], A442: [soybean, A2704-12, ACS -GM0 05-3, LibertyLink (trademark) soybean], A443: [soybean, A2704-21, ACS-GM004-2, LibertyLink (trademark) soybean], A444: [soybean, A5547-127, ACS-GM006-4, LibertyLink ( (Trademark) soybean], A445: [soybean, A5547-35, ACS-GM008-6, LibertyLink (trademark) soybean], A446: [soybean, CV127, BPS-CV127-9, Cultivance], A447: [soybean, DAS44406- 6, DAS-44406-6, NA], A448: [soybean, DAS68416-4, DAS-68416-4, Enlist ™ Soybean], A449: [soybean, DAS68416-4xMON89788, DAS-68416-4xMON-89788- 1, NA], A450: [soybean, DAS81419, DAS-81419-2, NA],
A451: [soybean, DAS81419xDAS44406-6, DAS-81419-2xDAS-44406-6, NA], A452: [soybean, DP305423, DP-305423-1, Treus (trademark) or Plenish (trademark)], A453: [ Soybean, DP305423xGTS40-3-2, DP-305423-1xMON-04032-6, NA], A454: [Soybean, DP356043, DP-356043-5, OptimumGAT ™], A455: [Soybean, FG72 (FG072-2 , FG072-3), MST-FG072-3, NA], A456: [soybean, FG72xA5547-127, MST-FG072-3xACS-GM006-4, NA], A457: [soybean, GTS40-3-2 (40- 3-2), MON-04032-6, RoundupReady (trademark) soybean], A458: [soybean, GU262, ACS-GM003-1, LibertyLink (trademark) soybean], A459: [soybean, IND-00410-5, IND -00410-5, Verdeca HB4 Soybean], A460: [soybean, MON87701, MON-87701-2, NA], A461: [soybean, MON87701xMON89788, MON-87701-2xMON-89788-1, Intacta ™ RoundupReady ™ ) 2Pro], A462: [soybean, MON87705, MON-87705-6, Vistive Gold (trademark)], A463: [soybean, MON87705xMON87708, MON-87705-6xMON-87708-9, NA], A464: [soybean, MON 87705xMON87708xMON89788, MON-87705-6xMON-87708-9xMON-89788-1, NA], A465: soybean, MON87705xMON89788, MON-87705-6xMON-89788-1, NA], A466: [soybean, MON87708, MON-87708-9 Genuity (R) RoundupReady (TM) 2 Xtend (TM)], A467: [soybean, MON87708xMON89788, MON-87708-9xMON-89788-1, Roundup Ready 2 Xtend (R)], A468: [soybean, MON87712 , MON-87712-4, NA], A469: [soybean, MON87751, MON-87751-7, NA], A470: [soybean, MON87751xMON87701xMON87708xMON89788, MON-87751-7xMON-87701-2xMON87708xMON89788, NA], A471: [soybean , MON87769, MON87769-7, NA], A472: [soybean, MON87769xMON89788, MON-87769-7xMON-89788-1, NA], A473: [soybean, MON89788, MON-89788-1, Genuity (R) Roundup Ready 2 Yield ™], A474: [soybean, SYHT0H2, SYN-000H2-5, Herbicide-tolerantSoybeanline], A475: [soybean, W62, ACS-GM002-9, LibertyLink ™ soybean], A476: [soybean, W98, ACS-GM001-8, LibertyLink (Trademark) soybean], A477: [soybean, OT96-15, OT96-15, NA], A478: [Peppo pumpkin (Cucurbitapepo), CZW3, SEM-0CZW3-2, NA], A479: [Peppo pumpkin (Cucurbita pepo), ZW20, SEM -0ZW20-7, NA], A480: [sugar beet, GTSB77 (T9100152), SY-GTSB77-8, InVigor (trademark) sugarbeet], A481: [sugar beet, H7-1, KM-000H71-4, Roundup Ready (trademark) ) Sugarbeet], A482: [sugar beet, T120-7, ACS-BV001-3, LibertyLink (TM) sugarbeet], A483: [sugarcane, CTB141175 / 01-A, CTB141175 / 01-A, NA], A484: [sugarcane , NXI-1T, NXI-1T, NA], A485: [sugarcane, NXI-4T, NXI-4T, NA], A486: [sugarcane, NXI-6T, NXI-6T, NA], A487: [sunflower, X81359 , X81359, Clearfield ™ Sunflower], A488: [Sweet Pepper, PK-SP01, X81359, NA], A489: [Tobacco, C / F / 93 / 08-02, NA, NA], A490: [Tobacco, Vector21-41, NA, NA], A491: [Tomato, 1345-4, NA, NA], A492: [Tomato, 35-1-N, NA, NA], A493: [Tomato, 5345 , NA, NA], A494: [Tomato, 8338, CGN-89322-3, NA], A495: [Tomato, B, SYN-0000B-6, NA], A496: [Tomato, Da, SYN-000DA-9 , NA], A497: [Tomato, DaDongNo9, NA, NA], A498: [Tomato, F (1401F, h38F, 11013F, 7913F), SYN-0000F-1, FLAVRSAVR (trademark)], A499: [Tomato, FLAVRSAVR , CGN-89564-2, FLAVRSAVR (trademark)], A500: [Tomato, HuafanNo1, NA, NA],
A501: [Tomato, PK-TM8805R (8805R), NA, NA], A502: [Wheat, MON71800, MON-71800-3, RoundupReady (TM) wheat], A503: [Wheat, AP205CL, AP205CL, Clearfield (TM) Wheat], A504: [Wheat, AP602CL, AP602CL, Clearfield ™ Wheat], A505: [Wheat, BW255-2xBW238-3, BW255-2xBW238-3, Clearfield ™ Wheat], A506: [Wheat, BW7, BW7, Clearfield (TM) Wheat], A507: [Wheat, Teal11A, Teal11A, Clearfield (TM) Wheat], A508: [Wheat, SWP965001, SWP965001, NA], A509: [Corn, NA, NA, Agrisure Artesian (TM) )], A510: [corn, NA, NA, Optimum (registered trademark) AQUAmax (registered trademark)], A511: [canola, NA, NA, SU canola (registered trademark)], A512: [canola, NA, NA, Nexera (registered trademark) Canola], A513: [soybean, NA, NA, STS soybean], A514: "corn, NA, NA, SR corn", A514: "sunflower, NA, NA, ExpressSun (registered trademark)", A515: [Rice, NA NA, Golden rice], A516: [corn, NA, NA, Boost Protected (registered trademark) corn], A517: [sunflower, NA, NA, ExpressSun (registered trademark)], A518: [rice, NA, NA, Provisia (Trademark) Rice ”, A519: [Canola, NA, NA, Triazineon Tolerant Canola], A520: [Corn, NA, NA, SmartStax (registered trademark) Pro], A521: [Soybean, NA, NA, Credenz (registered trademark) ) soybean], A522: [corn, TC1507x59122, DAS-01507-1 × DAS-59122-7, Optimum® AcreMax® 1], A523: [corn, 4114xMON810xMIR604, DP-004114-3 × MON -00810-6 × SYN-IR604-5, Qrome (TM)], A524: [Cotton, NA, NA, Stoneville (R) Cotton ST5517GLTP], A525: [Cotton, NA, NA, Stoneville (R) Cotton ST4848GLT], A526: [Cotton, NA, NA, Stoneville (R) Cotton ST4949GLT], A527: [Cotton, NA, NA, Stoneville (R) Cotton ST5020GLT], A528: [Cotton, NA, NA, Stoneville ( Registered trademark) Cotton ST5115GLT], A529: [Cotton, NA, NA, Stoneville (R) Cotton ST6182GLT], A530: [Cotton, NA, NA, Stoneville (R) Cotton ST4747GLB2], A531: [Cotton, NA, NA, Stoneville (Registered trademark) Cotton ST4946GLB2], A532: [Cotton, NA, NA, Stoneville (registered trademark) Cotton ST6448GLB2], A533: [soybean, NA, NA, Enlist E3 (trademark)], A534: [soybean, NA, NA Enlist (R) Roundup Ready 2 Yield (R)], A535: [Corn, NA, NA, Enlist (R) Roundup Ready (R) Corn 2], A536: [Corn, NA, NA, Smartstax (R) (Trademark) Enlist (trademark)], A537: [corn, NA, NA, Powercore (registered trademark) Enlist (trademark)], A538: [cotton, NA, NA, Enlist (trademark) Cotton], A539: [cotton, NA, NA, Bollgard 3 (registered trademark) XtendFlex (registered trademark)], A540: [corn, NA, NA, SmartStax (registered trademark) RIB Complete (registered trademark) Corn], A541: [corn, NA, NA, VT Dou ble PRO (registered trademark) RIB Complete (registered trademark) Corn], A542: [corn, NA, NA, VT Double PRO (registered trademark) Corn], A543: [corn, NA, NA, Genuity (registered trademark) VT Triple PRO (registered trademark) RIB Complete Corn], A544: [corn, NA, NA, Trecepta (trademark) Corn], A545: [soybean, NA, NA, fukuminori], A546: [soybean, NA, NA, yumeminori] , A547: [Corn, NA, NA, ZFN-12 maize], A548: [Rice, NA, NA, Yumepirika], A549: [Rice, NA, NA, Kanto BPH1], A550: [Cotton, NA, MON88702, NA].

  When treating the composition of the present invention to seeds or vegetative reproductive organs, it is preferable to use a composition containing at least one bactericidal component selected from the group (b) among the compositions of the present invention. At this time, commercially treated seeds or vegetative organs may be purchased and used.

  When the composition of the present invention is treated on seeds or vegetative organs, manganese, copper, zinc, etc. may be treated at the same time. The seed or vegetative reproductive organ treated with the composition of the present invention is sown or planted in a field by a usual method.

  The composition of the present invention can effectively control a wide range of subjects in a cereal field, a vegetable field, a flower field, an orchard, or a non-agricultural land where normal tillage cultivation or non-tillage cultivation is performed.

  When the composition of the present invention is applied to sugarcane, in sugarcane cultivation, a sugarcane stem fragment that has been cut so as to have one node may be used, and the size of the sugarcane stem fragment may be 2 cm. One having 15 to 15 cm, preferably 3 to 8 cm may be used. Sugarcane cultivation techniques using such stem fragments are known (WO09 / 000398, WO09 / 000399, WO09 / 000400, WO09 / 000401, WO09 / 000402) and are implemented under the trade name of Prene (registered trademark). The

  When the composition of the present invention is applied to rice, it may be applied to a nursery, may be applied to paddy fields, or may be applied to rice seeds. The above-mentioned nursery includes a nursery box or a rice seedling tray and a nursery.

  When the composition of the present invention is applied to a seedling box, the application time is not particularly limited as long as it is a seedling period from rice sowing to transplanting. The time when the composition of the present invention is treated in the seedling box at the time of sowing may be not only on the day of sowing but also on any day before or several days after sowing. The time when the composition of the present invention is treated into the nursery box at the time of transplantation may be not only the day of transplantation but also any day from several days before the day of transplantation. During the seedling raising period, the seedlings to be transplanted are either young seedlings (seedlings before and after the 2.5 leaf stage), medium seedlings (seedlings before and after the 3.5 leaf stage), or adult seedlings (seedlings before and after the 4.5 leaf stage) The composition of the present invention can be applied in any case, although it varies depending on the weather conditions and varies depending on weather conditions. Examples of the method for treating the seedling box with the composition of the present invention include a method of spraying a kneaded granule or a sand coating granule onto the seedling box, and a method of irrigating the seedling box with the solution of the composition of the present invention. . Further, the composition of the present invention can be treated on floor soil or covering soil, or can be mixed with floor soil or covering soil. In general, for example, a method for treating a pesticide during the seedling raising period. It is referred to as mixing with soil before sowing, pre-soiling treatment at sowing, post-soiling treatment at sowing, greening treatment, treatment on the day of transplantation, and simultaneous treatment of transplantation. The composition of the present invention may be processed into a seedling box by any of the above processing methods. The seedling culture medium is not particularly limited as long as it is a soil for rice seedlings, and a seedling mat other than soil may be used. The seedlings to which the composition of the present invention has been applied may be cultivated by pool seedlings.

  When applying this invention composition to a paddy field, you may use for the rice of transplant cultivation, and may be used for the rice of direct sowing cultivation. Although the method applied to paddy fields is not particularly limited, examples thereof include a method of applying the composition of the present invention to rice foliage, a method of applying to paddy soil, and a method of applying to the surface of flooded paddy fields. It is done. Moreover, it can also be applied labor-saving with the supply of water by processing chemicals such as emulsion and flowable at the source of water flowing into paddy fields such as a water inlet and an irrigation device. The time to apply to the rice stem and leaves may be any time from seedling to harvest. Preparations to be used include preparations to be applied in the form of powders, fine granules, etc., and flowables, dry flowables, wettable powders, granular wettable powders, SE drugs, aqueous solvents, granular aqueous solvents, liquids, microscopic products. Examples include emmaffusion agents, EW agents, oil agents, surf agents, and emulsions. The spraying device may be any device that is normally used, and a hand-spreading device, a power spreader, a cruising player, a radio control helicopter, a manned helicopter, and the like can be used. In addition, the inventive composition may be sprayed by hand without using a spraying device.

  As a method for applying the composition of the present invention to paddy field soil, a method of treating the entire surface of paddy field soil (full surface treatment), a method of treating a groove provided when sowing rice (seeding groove treatment), and a rice seed immediately below Examples of the method include a method of processing to 0 to 10 centimeters, a method of processing in the form of streaks or dots in the vicinity of a rice strain or seed (side treatment).

  When the composition of the present invention is applied to paddy soil, it can be applied simultaneously with agricultural materials such as paste fertilizer or granular fertilizer, or mixed with these agricultural materials. The time of applying the composition of the present invention may be before sowing or before transplantation, may be simultaneously with sowing or transplanting, or may be immediately after sowing or immediately after transplanting.

  When applying simultaneously with sowing or transplanting, it may be applied using an attachment attached to the sowing or transplanting machine, or may be applied by other methods. Further, in the case of full surface treatment, it may be a period until water injection after sowing or transplanting, an intermediate drying period, or an intermittent irrigation period. When using the composition of the present invention, the soil surface of the paddy field may be dry, or the soil surface may be moist but free of flooding (water depth 0 cm). When it is applied to the surface of a flooded paddy field, it can be applied at any time from sowing or transplanting to harvesting, as long as the water depth is maintained by normal rice management.

  When the composition of the present invention is used for direct sowing cultivation of rice, rice seeds are covered with a coating material such as iron powder (iron oxide powder, reduced iron powder, atomized iron powder, electrolytic iron powder, etc.), calcium peroxide, molybdenum and molybdenum compounds. It may be surface-treated. These coating materials can be used alone or in combination at any ratio. If necessary, auxiliary materials such as calcined gypsum and montmorillonite can be used for the purpose of increasing the amount or improving the fixation to rice seeds. An agent can be added. A mixture of calcium peroxide, calcined gypsum, and mineral powder is available as a commercial product, and examples thereof include Calper powder 16 (manufactured by Hodogaya UPL Co., Ltd.). Here, the rice seed means rice seed in a state before being sown in soil such as paddy field.

  When the composition of the present invention is treated with rice seeds, the rice seeds can be cultivated by direct sowing in dry fields, wet fields and paddy fields, or can be cultivated by sowing in a seedling box. Examples of the paddy field include paddy fields that are flooded or soiled. The paddy field in the flooded state refers to a paddy field in a state where it is further filled with water if necessary after plowing, filling, and shaving. The paddy field in the wet soil state is a paddy field in which the amount of water is maintained to the same level as the flooded state by performing a water-falling treatment or the like from the flooded state, and the soil surface is exposed. The composition of the present invention can be applied to rice seeds, rice seed before germination can be immersed in a solution containing the composition of the present invention, or the composition of the present invention can be applied to rice seeds after germination. The containing solution can also be sprayed. Moreover, in any treatment method, the composition of the present invention may contain one or more phytotoxicity reducing components selected from the group (d).

  The seeding machine used for rice seeding is not particularly limited as long as it is a seeding machine generally used for direct sowing cultivation of rice, such as paddy rice, upland rice, etc. For example, direct seeding machine for iron coating NDS-6 (Tetsu Maki-chan, KUBOTA Co., Ltd.), Iron coating direct sowing machine NDS-8 (Tetsu Maki-chan, Kubota Co., Ltd.), Iron coating direct sowing machine EP4-TC (Cute Tetsu Maki-chan, Kubota Co., Ltd.), Multi-purpose work machine RG6 (Manufactured by Yanmar Co., Ltd.), multipurpose working machine RG8 (manufactured by Yanmar Co., Ltd.), high-precision seeding machine PZV60 (manufactured by Iseki Agricultural Machinery Co., Ltd.), and high-precision seeding machine PZV80 (manufactured by Iseki Agricultural Machinery Co., Ltd.).

  It is preferable that iron or an oxide thereof (hereinafter referred to as iron and its oxide is referred to as “coating material A”) as a coating material to be processed on rice seeds is powdery. Examples of the powdery coating material A include reduced iron powder, atomized iron powder, electrolytic iron powder, and iron oxide powder, and these are available as commercial products. Moreover, these can also be used in mixture of 2 or more types. In the present invention, it is preferable to use reduced iron powder and / or iron oxide powder. The iron powder obtained by reducing iron oxide or iron salt with hydrogen or the like is reduced iron powder, and the iron powder obtained by jetting a high-pressure water jet of 8 to 20 MPa into the flow of molten iron is atomized iron powder or sulfuric acid. Iron powder obtained by depositing iron by electrolysis from a solution of iron or the like to obtain electrolytic iron flakes, pulverizing and annealing them with a rod mill or a vibration mill is called electrolytic iron powder. Iron oxide is an iron oxide having an oxidation number of II and / or III. The particle size of the coating material A used in the present invention is not particularly limited, but is preferably adjusted to a particle size of 10 to 100 μm. As the coating material A available as a commercial product, for example, DAE1K iron powder (DOWA (DOWA) IP (IP) Creation Co., Ltd.), DSP317 iron powder (DOWA (DOWA) IP (IP) Creation Co., Ltd.), Agricultural iron powder (manufactured by Daitetsu Kogyo Co., Ltd.), agricultural iron powder (manufactured by Tetsugen Co., Ltd.), and hematite (DOWA (DOWA) IP (IP) Creation Co., Ltd.).

When processing this invention composition to a rice seed, you may mix with calcined gypsum. For example, calcined gypsum may be used as an auxiliary agent when the composition of the present invention and the coating material A are processed into rice seeds. Such calcined gypsum may be powdered calcium sulfate 1/2 hydrate (CaSO ₄ .1 / 2H ₂ O), and such calcined gypsum is commercially available. For example, KTS-1 (Yoshino Gypsum Sales Co., Ltd.) and KTS-25 (Yoshino Gypsum Sales Co., Ltd.). Moreover, what mixed the coating | covering material A and calcined gypsum may be sufficient, and such a mixture is available as a commercial item, for example, DAE1K mix (made by DOWA (Dowa) IP (IP) Creation Co., Ltd.) is mentioned.

  The rice seed dressing treatment using the coating material A can take various forms, but is generally a known method (“Iron-coated flooded direct sowing manual 2010”, independent method of rice seed dressing treatment using iron powder). This is carried out in the same manner as the National Agricultural Research Organization of Agriculture and Food Industry, March 2010, ISBN 978-4-903078-05-2). Specifically, dried rice seeds before germination are immersed in water (sometimes referred to as soaking), drained, and then dressed with the coating material A and calcined gypsum as necessary. To do. The order of the treatment of the covering material A and the calcined gypsum may be any first, and the mixture of the covering material A and the calcined gypsum may be treated simultaneously. After performing these treatments, if necessary, after finishing with powdered gypsum as a finish, it is usually placed on a flat surface on a flat surface and dried in the shade.

  The amount of coating material A to be used for rice seeds is usually 100 to 2000 grams for coating material A per 1000 grams of dry weight of rice seeds. Further, the amount of calcined gypsum in the case of powder coating with calcined gypsum is usually 5 to 100 g per 1000 g of dry weight of rice seeds. The amount of gypsum is usually 0 to 50 grams per 1000 grams of dry weight of rice seeds.

  As calcium peroxide, a calcium peroxide simple substance prepared in a powder having a particle size of 10 to 150 μm can be used. Can also be used. Such a calcium peroxide-containing composition is available as a commercial product, and examples thereof include Calper powder granules 16 (manufactured by Hodogaya UPL Co., Ltd.).

  The rice seed dressing treatment using calcium peroxide can take various forms, but generally, a method known as a rice seed dressing treatment using calcium peroxide (Japanese Patent Laid-Open No. 61-015805) and The same operation is performed. Specifically, the dried rice seeds before germination are immersed in water (sometimes referred to as soaking), drained, and then the rice seeds are dressed with a calcium peroxide powder or a calcium peroxide-containing composition. . After performing these treatments, it is usually dried by placing it on a basket or the like laid on a flat surface and drying it in the shade.

  The amount of calcium peroxide or a calcium peroxide-containing composition used for rice seeds is usually 100 to 1000 grams in terms of calcium peroxide alone relative to 1000 grams of dry weight of rice seeds.

  Examples of molybdenum and molybdenum compounds include molybdenum alone, molybdenum oxide, molybdic acid and its salt, molybdophosphoric acid and its salt, and molybdosilicic acid and its salt. Examples of the salt of molybdic acid include calcium molybdate, magnesium molybdate, ammonium molybdate, sodium molybdate, and potassium molybdate. Examples of molybdophosphate include ammonium molybdophosphate, sodium molybdophosphate, and potassium molybdophosphate. Such molybdenum and molybdenum compounds are commercially available, and examples thereof include molybdenum trioxide (Nippon Inorganic Chemical Industry Co., Ltd.).

  The treatment of rice seeds using molybdenum and molybdenum compounds can take various forms, but is usually carried out in the same manner as a known method for treating rice seeds using molybdenum and molybdenum compounds (WO 2011/093341). . Specifically, it is fixed to a rice seed surface using an adhesive such as polyvinyl alcohol, prepared in a solution and immersed in rice seed, and mixed with a coating material containing iron powder and / or calcium peroxide. For example, the operation of dressing rice seeds.

  In particular, “Bengara Molybdenum Coating” is known, which is a mixture of molybdenum compounds such as molybdenum trioxide, iron oxide powder (sometimes called Bengal flour) and water-resistant polyvinyl alcohol, and then treated on rice seeds (Yoshitaka Hara 2013. Improvement of Rice Seedling Establishment on Sulfate-Applied Submerged Soil by Seed Coating with Poorly Soluble Molybdenum Compounds. Plant Prod. Sci. 16 (3): 271-275), this method is also preferably performed in the present invention.

  The amount of molybdenum and molybdenum compound used for rice seeds is usually 0.01 to 10 mol in terms of molybdenum with respect to 1000 grams of dry weight of rice seeds.

Examples of the combination of the composition of the present invention to be treated with rice seeds and the coating material include the following.
SX + iron oxide powder, SX + reduced iron powder, SX + iron oxide powder + reduced iron powder, SX + calcium peroxide, SX + molybdenum compound, SX + molybdenum compound + iron oxide powder, SX + molybdenum trioxide, SX + molybdenum trioxide + iron oxide powder, SX + iron oxide powder + calcined gypsum, SX + reduced iron powder + calcined gypsum, SX + iron oxide powder + reduced iron powder + calcined gypsum, SX + calcium peroxide + calcined gypsum, composition A + iron oxide powder, composition A + reduced iron powder, Composition A + iron oxide powder + reduced iron powder, composition A + calcium peroxide, composition A + molybdenum compound, composition A + molybdenum compound + iron oxide powder, composition A + molybdenum trioxide, composition A + molybdenum trioxide + iron oxide Powder, composition A + iron oxide powder + calcined gypsum, composition A + reduced iron powder + calcined gypsum, composition A + iron oxide powder + reduced iron powder + calcined gypsum, composition A + calcium peroxide + calcined gypsum.
Here, as the present component contained in the composition A, in particular, isothianyl, furametopyr, impylfluxam, ethaboxam, benomyl, oxolinic acid, clothianidin, fenitrothion, cartap hydrochloride, oxazosulfur, tetraniliprol, Lantraniliprole, cyantraniliprole, triflumezopyrim and ethiprole are preferred.

  The order of treatment of rice seeds in the above combination may be that the rice seed may be treated with the compound or the composition A and then the coating material may be treated, or the rice seed may be treated with the coating material and then the compound or composition. The product A may be treated, or the present compound or composition A and the coating material may be treated simultaneously. Here, when the composition A is treated, the order of treatment of the present compound and the present component and the coating material contained in the composition A may be the order of the present compound, the present component and the coating material, or the present compound, The order of the coating material and this component may be the order of this component, this compound and the coating material, the order of this component, the coating material and this compound, or the coating material. The order of this compound and this component may be sufficient, and the order of a coating | covering material, this component, and this compound may be sufficient. Or you may process this compound, this component, and a coating | covering material simultaneously to a rice seed.

  When the composition of the present invention is applied to rice, rice seed sprouting may be performed by immersing in water, or by immersing in water and holding in a wet state. The wet state means a state in which part or all of the surface of the rice seed after being immersed in water can be in contact with the outside air and can retain the moisture of the rice seed. For example, in the wet state, after the rice seed immersed in water is coated with a breathable material such as rice straw or cloth, water is sprayed on the coated material as necessary, or the rice seed is immersed in water. This is realized by storing rice seeds as they are in the net-like or bag-like material used in the process.

  When using this invention composition for rice, a fertilizer can also be used together. Examples of such fertilizers include Rakuichi (registered trademark, Sumitomo Chemical Co., Ltd.), Sumishort (registered trademark, Sumitomo Chemical Co., Ltd.), and Super SR Coat (registered trademark, Sumitomo Chemical Co., Ltd.). When using a fertilizer together, you may fertilize the whole rice cultivation soil before sowing, and you may fertilize the whole rice cultivation soil after sowing or in the growing season. Moreover, you may fertilize in the shape of a groove | channel along the row | line | column sowed at the time of sowing (it may also be called side stripe fertilization).

  When the composition of the present invention is applied to rice, sterilized seeds can be used to control seed infectious diseases and pests regardless of whether they are applied to seedlings, paddy fields or seeds. Specifically, groups (a) and groups of prochloraz, triflumizole, pefrazate, oxolinic acid, ipconazole, fludioxonil, kasugamycin-hydrochloride, cupric hydroxide, basic copper chloride, fenitrothion, cartap hydrochloride ( b) One or more insecticide and fungicide components selected from the above, or Trichoderma atroviride SKT-1 strain, Talalomyces flavus SAY-Y-94-01 strain, Pseudomonas sp. CAB-02 strain, Bacillus simplex CGF2856 Seeds that have been dipped, smeared or powdered with one or more components of microbial material selected from group (j) such as a strain can be used.

  Applying one or more kinds of cartap hydrochloride and metaaldehyde to paddy fields before rice seeding, paddy fields before rice transplanting, paddy fields after rice seeding, or paddy fields after rice transplantation will have the effect of scallop apple mussels and monoaragai Can be controlled. Moreover, weeds generated in paddy fields can be controlled by treating one or more herbicidal active ingredients selected from group (i). The time when the herbicidal active ingredient is applied is not particularly limited as long as the herbicidal active ingredient does not cause phytotoxicity to rice.

  One or more herbicidal active ingredients selected from the group (i) that can be used in paddy fields include, for example, azimusulfuron, bensulfuron methyl, chlorimuron ethyl, cyclosulfamuron, ethoxysulfuron, flucetosulfuron, halosulfuron methyl. , Imazosulfuron, orthosulfamlone, propyrisulfuron, pyrazosulfuronethyl, sinosulfuron, metsulfuronmethyl, metazosulfuron, beniocarb, molinate, esprocarb, pyributycarb, dimethylpiperate, swep, butachlor, pretilachlor, dimethrin, dimethrin, methylmethrin Propanil, mefenacet, flufenacet, chromeprop, naproanilide, bromobutide, dimelon, cumylron, etbenzani , Bentazone, Tridiphan, Carfentrazone ethyl, Fenchlorazole ethyl, Isoxadifen ethyl, Fentrazamide, Chromazone, Maleic acid hydrazide, Pyridate, Oxadichrome, cinmethyline, Benfrate, Oxadiazone, Oxadiargyl, Pentoxazone, Cihalohopbutyl Caffenstrol, ipfencarbazone, pyriminobacmethyl, bisbilivac sodium, pyrimisulphan, triamon, pyribenzoxime, pyriftalide, indhanophane, ACN, benzobicyclon, tefriltrione, mesotrione, phenquinotrione, dithiopyr, darapon, chlorthiamid , Penox slam, anilophos, benzulide, butamifos, phenoxasulfone, benzophenap Pyrazolinate, pyrazoxifene, imazametabenz, imazametabenzmethyl, imazamox, imazamox ammonium salt), imazapic, imazapic ammonium salt, imazapyr, imazaquin, imazetapill, pendimethalin, fenoxaprop ethyl, fenoxaprop P ethyl, metamihop, pyraclonyl, quinclolac, 2,4-D and its salt, MCP and its salt, MCPA and its salt, MCPB and its salt, piperophos, fluoxypyr, cyclopimolate, benzobicyclon, florpyraoxifene -Benzyl, fluropyroxifene, taxolmin A, etc. are mentioned.

  Rice that can be used in the composition of the present invention refers to Oryza sativa, Oryza glaberima, which are cultivated species among annual plants of the genus Oryza, and hybrids thereof, and can be any of Japonica, Java, or Indica. Moreover, any of sticky rice, sticky rice, sake rice, and feed rice may be used. Rice varieties are not particularly limited, and may be varieties produced by crossing or varieties produced by gene recombination techniques, as exemplified by the plant varieties described above. When applied to cultivars that have been given resistance (also referred to as resistance) to herbicides, pests and diseases, it can be a particularly labor-saving control method. Moreover, the multiline which mixes and cultivates several varieties in which different resistance genes were integrated may be sufficient.

  The composition A containing one or more herbicidal active ingredients selected from the group (i) and one or more phytotoxicity reducing ingredients selected from the group (d) may contain all of the present ingredients in one preparation. It may be a separate formulation. Moreover, before and after planting seeds or plant reproductive organs treated with one or more phytotoxicity-reducing ingredients selected from group (d) in the cultivation area, the herbicidal active ingredient selected from group (i) is treated to the cultivated soil, etc. May be. Moreover, in that case, you may purchase and use the commercially available seed which processed 1 or more types of phytotoxicity reduction components chosen from group (d).

  When one or more herbicidal active ingredients selected from group (i) are treated before seed sowing or vegetative organ or seedling planting, the treatment time of the herbicidal active ingredient is 50 days before sowing or planting. To just before sowing or planting, preferably from 30 days before sowing or planting to just before sowing or planting, more preferably from 20 days before sowing or planting to just before sowing or planting, more preferably, Between 10 days before sowing or planting and immediately before sowing or planting.

  When one or more herbicidal active ingredients selected from group (i) are treated after seed sowing or after planting of vegetative reproductive organs or seedlings, the treatment time of the herbicidal active ingredient is preferably immediately after sowing or planting To 50 days after sowing or planting, more preferably, immediately after sowing or planting to 3 days after sowing or planting.

  Simultaneously with seed sowing or vegetative organ or seedling planting, one or more components selected from group (i) can be treated.

  In the case of treating one or more herbicidal active ingredients selected from the group (i) after sowing of soybean seeds, the treatment time of the herbicidal active ingredient is, for example, from before germination to flowering stage of soybean. Among the period from before the emergence of soybean to the flowering period, the period is preferably from the period before emergence of soybean to the period of 6 double leaves, and more preferably from the period before emergence of soybean to the period of 3 complex leaves.

  When one or more herbicidal active ingredients selected from the group (i) are treated after sowing of corn seeds, the treatment time of the herbicidal active ingredient is, for example, from before emergence to the 12th leaf stage, preferably from 8 before emergence. The period from the leaf stage to the 6th leaf stage is more preferable. In addition, the leaf age of corn is determined by the leaf color method (Leaf Collar Method).

  When one or more herbicidal active ingredients selected from the group (i) are treated before sowing of the cotton seed, the treatment time of the herbicidal active ingredient is from 50 days before sowing to immediately before sowing, preferably from 30 days before sowing. It is between just before sowing, more preferably from 20 days before sowing to just before sowing. When one or more herbicidal active ingredients selected from group (i) are treated after sowing of cotton seeds, the treatment time of the herbicidal active ingredient is from immediately after sowing to 70 days after sowing, preferably from 30 days after sowing. 50 days later, for example, from before cotton emergence to the flowering period, preferably from the beginning of treeization of cotton stem base to the period when the wooded part is 20 cm from the base.

  When one or more herbicidal active ingredients selected from the group (i) are treated before sugarcane planting, the treatment time of the herbicidal active ingredient is from 40 days before the planting date to immediately before, preferably 30 days of planting. It is between 20 days before and just before the date of planting, more preferably from the day before to just before. When one or more herbicidal active ingredients selected from the group (i) are treated after sugarcane planting, the treatment time of the herbicidal active ingredient is from immediately after planting to 40 days after planting, preferably immediately after planting, sowing or planting. It is between 20 days later, more preferably between immediately after planting and 10 days after planting.

  By applying the composition of the present invention, depending on the plant species or plant varieties, their growth location and growth conditions (soil, climate, growth season, nutrient), improvement of plant seedling establishment rate, improvement of plant growth, high temperature Or improved tolerance or tolerance to low temperature, improved tolerance to drought, overhumidity or salt contained in water or soil, improved flowering ability, improved ease of harvesting, accelerated maturation, increased yield, seed Or increase in fruit number, size or weight, increase plant height, increase plant weight, improve leaf green color, increase number of healthy leaves, increase leaf area, faster flowering, number of flowers or arrival Increased number of fruits, increased fruit set rate, improved quality and / or nutritional value of harvested product, increased sugar content in fruit, increased gluten strength, improved storage stability of harvested product And / or when workability can be improved That.

When the composition of the present invention is applied to a place where rice is nurtured, the application amount of the composition of the present invention is usually 5000 g or less, preferably 1000 g or less per sowing area (cultivated area) 10a. The total amount of the present compound or composition A contained in is usually 1000 g or less, preferably 500 g or less. Moreover, the total amount of the present compound or the composition A contained in the composition of the present invention per 1 m ^{2 of the} place where rice is nurtured is usually 0.05 to 1000 g, preferably 0.5 to 200 g.

  When the composition of the present invention is applied to a rice seedling box, the application amount of the composition of the present invention is the total amount of the present compound or composition A contained in the composition of the present invention. It is usually 0.1 to 35 g, preferably 0.2 to 20 g per about 30 cm).

  When the composition of the present invention is processed by seeds or vegetative reproductive officers, the application amount of the composition of the present invention is usually 0.001 to 100 g, preferably 0.02 to 50 g, per 1 kg of seed or vegetative reproductive organ. The total amount of the present compound or composition A contained in the composition is usually 0.000001 to 50 g, preferably 0.0001 to 30 g per kg of seeds or vegetative organs. Here, the weight of seeds or vegetative reproductive organs means the weight of seeds or vegetative reproductive organs before sowing or planting and before applying the composition of the present invention.

  When the composition of the present invention is processed into seeds or vegetative organs, an adjuvant may be mixed with the composition of the present invention as necessary. In addition, when applying the composition of the present invention, this compound and this component may be applied separately, before and after seeding seeds or vegetative reproductive organs to which either this compound or this component is attached to a cultivation carrier. The other may be applied to the cultivation carrier.

  The weight ratio between the application amount of the present compound and the application amount of this component in the composition A is the type of plant to be protected, the harmful arthropod to be controlled, the type and frequency of occurrence of phytopathogenic microorganisms or weeds, formulation Depending on the form, application time, application method, application location, weather conditions, etc., the weight ratio can be adjusted appropriately. For example, in the agricultural field, when applied to plants (especially, foliage, seeds, vegetative organs) or when applied to a cultivation carrier (especially soil) for cultivating plants, the following weight ratios can be mentioned.

With regard to the components contained in group (a), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (a)) = 1: 1000 to 1000: 1, preferably 100 : 1 to 1: 100, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5 : 1, 10: 1, 20: 1, 50: 1;
With regard to the components included in group (b), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (b)) = 1: 100 to 10,000: 1, preferably Is in the range of 1:10 to 1000: 1, more preferably in the range of 1: 1 to 100: 1, for example 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2. 1: 1, 2: 1, 3: 1, 5: 1, 10: 1, 20: 1, 50: 1, 100: 1, 200: 1, 300: 1, 400: 1, 500: 1;
With regard to the components included in group (c), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (c)) = 1: 1000 to 1000: 1, preferably 100: 1 to 1: 100, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5: 1, 10: 1, 20: 1, 50: 1;
With regard to the components contained in group (d), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (d)) = 1: 1000 to 1000: 1, preferably 100 : 1 to 1: 100, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5 : 1, 10: 1, 20: 1, 50: 1;
With regard to the components included in group (e), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (e)) = 1: 1000 to 10,000: 1, preferably Is in the range of 1: 100 to 100: 1, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1 5: 1, 10: 1, 20: 1, 50: 1;
With regard to the components included in group (f), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (f)) = 1: 1000 to 1000: 1, preferably 100 : 1 to 1: 100, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1 5: 1, 10: 1, 20: 1, 50: 1;
With regard to the components contained in group (g), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (g)) = 1: 1000 to 1000: 1, preferably 1 : 100 to 100: 1, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5 : 1, 10: 1, 20: 1, 50: 1;
With regard to the components included in group (h), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (h)) = 1: 1000 to 1000: 1, preferably 1 : 100 to 100: 1, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5 : 1, 10: 1, 20: 1, 50: 1;
With regard to the components included in group (i), regardless of the presence or absence of other components, (present compound): (one or more components selected from group (i)) = 1: 1000 to 1000: 1, preferably 1 : 100 to 100: 1, for example, 1:50, 1:20, 1:10, 1: 5, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 5 : 1, 10: 1, 20: 1, 50: 1;

The component selected from the group (j) is usually prepared by a culture method known in the art. For example, when the component selected from the group (j) is a bacterium or a fungus, it is prepared by a medium known in the art and a known fermentation method. In the case of virus or nematode, it is prepared by a culture method known in the art. When this component is a bacterium or a filamentous fungus, its preparation is 1 × 10 ⁴ to 1 × 10 ¹³ CFU (colony forming unit) per gram, preferably 1 × 10 ⁸ to 1 × 10 ¹² CFU. including. When this component is a virus, the preparation is 1 × 10 ⁴ to 1 × 10 ¹³ embedded bodies (sometimes referred to as occlurion bodies, sometimes referred to as Obs), preferably 1 × 10 ⁸ to 1 × Contains this component of 10 ¹² embedded bodies (sometimes referred to as occlurion bodies, sometimes referred to as Obs). When the component is a nematode, the preparation contains 1 × 10 ⁴ to 1 × 10 ¹³ individuals, preferably 1 × 10 ⁸ to 1 × 10 ¹² individuals of the component per gram.

  When the composition selected from the group (j) is contained in the composition of the present invention, (present compound): (one or more components selected from the group (j)) = 1: irrespective of the presence or absence of other components The range is 10,000 to 10,000: 1, preferably 1: 1000 to 1000: 1. For example, 1: 500, 1: 400, 1: 300, 1: 200, 1: 100, 1:50, 1:10, 1: 5, 1: 1, 5: 1, 10: 1, 20: 1, 50: 1, 100: 1, 200: 1, 300: 1, 400: 1, 500: 1. . The weight ratio of one or more components selected from group (j) means the total weight of the preparation of one or more components selected from group (j). For example, a weight ratio of 1: 500 means 500 parts by weight of a preparation of one or more components selected from group (j) per 1 part by weight of the compound.

  The composition of the present invention is effective against harmful arthropods such as harmful insects and harmful mites, harmful nematodes, and harmful molluscs. Examples of harmful arthropods, harmful nematodes, and harmful molluscs include the following.

  Hemiptera: Japanese green planthopper (Laodelphax striatellus), yellow planthopper (Nilaparvata lugens), white-tailed planthopper (Sogatella furcifera), corn planter (Peregrinus maidis), yellow-spotted plantfish (Javesella pellucida), blackfish planter Delphacidae; Nephotettix cincticeps, Nephotettix virescens, Nephotettix nigropictus, Recilia dorsalis, Eki ca , Cornleaf hopper (Dalbulus maidis), Cofana spectra, etc. (Cicadellidae); Mahanarva posticata, Mahanarva fimbriolata, etc. (Cercopidae); Mussels (Aphis fabae), soybean aphids (Aphis glycines), cotton aphids (Aphis gossypii), European apple aphids (Aphis pomi), snowy aphids (Aphis spiraecola), peach aphids (Myzus persicae), wheat worms hel cyra , Radish aphids (Brevicoryne brassicae), Rosy apple aphid (Dysaphis plantaginea), black radish aphids (Lipaphis erysimi), tulip beetle aphids (Macrosiphum euphorbiae), potato beetle aphids (Aulacorthum solani), aphids Aphids (Rhopalosiphum padi), corn aphids (Rhopalosiphum maidis), citrus aphids (Toxoptera citricida), peach beetle (Hyalopterus pruni), hyena aphids (Melanaphis sacc) hari), Tetraneura nigriabdominalis, Ceratovacuna lanigera, Eriosoma lanigerum, etc. Aphididae; Grape aphid, Pak phyllera Phylloxeridae such as phylloxera (Phylloxera notabilis), Southern pecan leaf phylloxera (Phylloxera russellae); Adelges tsugae; Adelges piceae; Scotinophara lurida, Malayan rice black bug (Scotinophara coarctata), Nezoara antennata, Eysarcoris aeneus, Eysarcoris ys Eysarcoris annamita, Halyomorpha halys, Southern stink bug (Nezara viridula), Brown stink bug (Euschistus heros), Red banded stink bug (Piezodorus guildinii), Oebalus pugnalac, ae ; Burrower brown bug (Scaptocoris castanea) and other horned bugs (Cydnidae); Crestus punctiger, Leptoglossus australis, etc. ) Etc. gaeidae); Trigonotylus caelestialium; Stenotus rubrovittatus; Stenodema calcarata; Lyario lineolaris; Triridae; Tobacco whitefly (Bemisia tabaci), citrus whitefly (Dialeurodes citri), citrus whitefly (Aleurocanthus spiniferus), scallop whitefly (Aleurocanthus camelliae), scorpionate (Pealius euryida) Abgrallaspis cyanophylli), Aonidiella aurantii, pear beetle (Diaspidiotus perniciosus), stag beetle (Pseudaulacaspis pentagona), worm (Unaspis yanonensis), fake Nonaspis citri, etc. (Diaspididae); Ruby beetle (Ceroplastes rubens), etc., Coccidae; Icerya purchasi, Family (Margarodidae); Phenacoccus solani, Phenacoccus solenopsis, Pterococcus kraunhiae, Pseudococcus comstocki, Cicumococcus trica Pseudococcus calceolariae), Pseudococcus longispinus, Tattlemy Lee bug (Brevennia rehi) and other species of Pseudococcidae; Diaphorina citri; rytreae), Pepylthia cactus (Ccopsylla pyricuga), Pear psylla (Cacopsylla pyricola), Pear uchlla (Ccopsylla pyricuga) marmorata), Stephanitis nashi, Stephanitis pyrioides, and other species (Tingidae); Cicadidae; Brazilian turtle (Triatoma infestans), Venezuelan turtle (Rhodonius prolixus), etc.

  Lepidoptera: Green squirrel (Chilo suppressalis), Darkheaded stem borer (Chilo polychrysus), White stem borer (Scirpophaga innotata), Scirpophaga incertulas, Rupela albina, Cnaphalocrocisas medinalis, Cnaphalocrocisas medinalis, Casino maiga (Marasmia exigua), cotton mackerel (Notarcha derogata), green magnolia (Ostrinia furnacalis), European corn borer (Ostrinia nubilalis), yellow-tailed mackerel (Hellula undalis), Monpetronomarelus (Principal), Herpetogramma luctuoseter Caseworms (Nymphula depunctalis), Sugarcane borer (Diatraea saccharalis), etc. (Crambidae); (Cadr a cautella, Pyralidae; Spodoptera litura, Spodoptera exigua, Mythimna separata, Mamestra brassicae, Srangia inferens Na aenescens, Spodoptera frugiperda, African white scallop (Spodoptera exempta), Agrotis ipsilon, Amantis uwaba (Autographa nigrisigna), Akinosawaba (Plusia festucae), Sorybean tricho (plus) spp. alis), Cotton leafworm (Alabama argillacea), Hop vine borer (Hydraecia immanis), etc. (Noctuidae); dimorpha, leguminivora glycinivorella, Matsumuraeses azukivora, Adoxophyes orana fasciata, Adoxophyes honmai, Homona magnanima, fumonaco (Cydia pomonella), Tetramoera schistaceana, Bean Shoot Borer (Epinotia aporema), Citrus fruit borer (Ecdytolopha aurantiana), Tortricidae; Caloptilia theivora; Hosoga ( Gracillariidae); Carposinidae such as Carposina sasakii; Caroffinidae such as Coffee Leaf miner (Leucoptera coffeella), Lyonetia clerkella; Lymantria spp., Euproctis pseudoconspersa, Euproctis spp. Lymantriidae, Plutellidae such as Plutella xylostella Lineatella, Helcystogramma triannulella, Cotton moth (Pectinophora gossypiella), Potato moth (Phthorimaea operculella), Tuta absoluta, etc. Telchin licus) Castniidae; Cossus insularis, etc. (Cossidae); Artemidae, such as Ascotis selenaria; Geometridae, etc .; masinissa, etc. (Stathmopodidae); Acherontia lachesis, etc., Sphingidae; ; Ceratoidaceae (Hesperiidae) such as Parnara guttata, Tinea translucens, Tineola bisselliella, etc. (Tinedae).

  Thysanoptera: Citrus thalis (Frankliniella occidentalis), Thrips palmi, Scirtothrips dorsalis, Thrips tabasa, Thrips tabasa, Thrips tabasa, Thrips tabasa , Thripidae, such as Echinothrips americanus;

  Diptera: Anthomyiidae such as Dela platura, Delia antiqua, Pegomya cunicularia; Udidiidae such as sugar beet root mygot Agromyza oryzae, tomato leaffly (Liriomyza sativae), bean leaffly (Liriomyza trifolii), leafhopper (Chromatomyia horticola) and other leafhoppers (Agromyzidae); Bactrocera cucurbitae), Bactrocera dorsalis, Salmonella (Bactrocera latifrons), Olive fruit fly (Bactrocera oleae), Quinland fruit fly (Bactrocera tryoni), Ceratitis capitamon (ha) Tephritidae such as Rhacochlaena japonica; Hydrellia griseola, Hydrellia philippina, Hydrellia sasakii, etc. Drosophila suzukii, etc. Drosophilidae; Megaselia spiracularis, etc. Phoridae; Clogmia albipunctata, etc. Psychodidae Sciaridae; Cecidomyiidae such as Mayetiola destructor and Orseolia oryzae; Diopsidae such as Diopsis macrophthalma; Common agula cranefly (Tipula ol eracea), European cranefly (Tipula paludosa), etc. (Tipulidae); Culex pipiens pallens, Culex tritaeniorhynchus, Culex pipiens f. ), Mosquito (Culex vishnui), Aedes albopictus, Aedes aegypti, Anopheles sinesis, Anopheles gambiae, Anopheleshen , Anopheles sundaicus, Anopheles arabiensis, Anopheles funestus, Anopheles darlingi, Anopheles farauti, Anopheles minimus and other mosquitoes (Culicidae); trigonus) etc. Tabaidae; Musca domestica, Muscina stabulans, Stomoxys calcitrans, Haematobia irritans, etc. Muscidae; Calliphoridae; (Chironomus plumosus), Chironomus yoshimatsui, Glyptotendipes tokunagai, and other Chironomidae, and Fannidae.

  Coleoptera: Western corn root worm (Diabrotica virgifera virgifera), Southern corn root worm (Diabrotica undecimpunctata howardi), Northern corn root worm (Diabrotica barberi), Mexican corn root worm (Diabrotica virgifera zeae), Banded Cucumber beetle balteata), Cucurbit Beetle (Diabrotica speciosa), bean leaf beetle (Cerotoma trifurcata), terrestrial beetle (Oulema melanopus), cucumber leaf beetle (Aulacophora femoralis), pheasant leaf beetle (Phyllotreta striolata), cabbage flea beifer (lebwest crifer beef) flea beetle (Phyllotreta pusilla), Cabbage stem flea beetle (Psylliodes chrysocephala), Colorado potato beetle (Leptinotarsa decemlineata), rice beetle (Oulema oryzae), grape corapis (Colaspis brunnea), corn flare beet (Chaetocnema pulicaria), sweet potato beetle (Chaetocnema confinis), potato flare beetle (Epitrix cucumeris), rice beetle (Dicladispa armigera), southern corn leaf beetle (Myochrous denticollis), quadricorn acc Chrysomelidae such as Epitrix hirtipennis; Carabidae such as Seedcorn beetle (Stenolophus lecontei), Slender seedcorn beetle (Clivina impressifrons); Anomala cuprea, Anomala Arubobo , Populus japonica, Heptophylla picea, European Chafer (Rhizotrogus majalis), Tomarus gibbosus, Holotrichia spp., Phyllophaga crhyophaaga ), D Scarabaeidae, such as the genus Diloboderus (Diloboderus spp.), such as iloboderus abderus; Araecerus coffeae, Cylas formicarius, Euspes postfasciayp (Sitophilus zeamais), weevil (Sitophilus oryzae), granary weevil (Sitophilus granarius), weevil (Echinocnemus squameus), rice weevil (Lissorhoptrus oryzophilus), white weevil (Rhabdothmusum weevil) Weevil (Sphenophorus venatus), Southern Corn Billbug (Sphenophorus callosus), Soybean stalk weevil (Sternechus subsignatus), Sugarcane weevil (Sphenophorus levis), Sabichoane weevil (Scepticus griseus) Scepticus uniformis, Brazilian weevil (Zabrotes subfasciatus), pine beetle (Tomicus piniperda), Coffee Berry Borer (Hypothenemus hampei), Aracanthus mourei and other Aracanthus spp. Curculionidae; Tribium castaneum, Tribolium confusum, Alphitobius diaperinus, etc. (Tenebrionidae); ; Lyctus brunneus, Rhizopertha dominica, and other species of Bostrychidae; Melanonotus okinawensis, Agriotes fuscicollis, Melanonotus legatus, Anchastus spp., Conoderus spp., Ctenicera sp, Ctenicera spp. Limonius spp., Aeolus genus (Aeolus spp.), Etc., Elateridae; Paederus fuscipes, etc. maculates), Dermestidae, such as Trogoderma granarium; Anobidae, such as Lasioderma serricorne; Stenobium paniceum; Department (Laemophloeidae ; Saw-tooth grain beetle (Oryzaephilus surinamensis) Hosohiratamushi family, etc. (Silvanidae).

  Orthoptera: Tolocama migratoria, Moroccan grasshopper (Dociostaurus maroccanus), Australian grasshopper (Chortoicetes terminifera), red locust (Nomadacris septemfasciata), Brown Locust (Locustana pardalina), Tree Locust (Locustana pardalina), Tree Locust (Locustana pardalina) Locust (Calliptamus italicus), Differential grasshopper (Melanoplus differentialis), Two striped grasshopper (Melanoplus bivittatus), Migratory grasshopper (Melanoplus sanguinipes), Red-Legged grasshopper (Melanoplus femurrubrum), Clearwinged grasshopper (Camnula pellucida) ), Yellow-winged locust (Gastrimargus musicus), Spur-throated locust (Austracris guttulosa), Cobainago (Oxya yezoensis), Scarlet moth (Oxya japonica), Thai winged locust (Patanga succincta), etc. ntalis), Gryllotalpidae; European crickets (Acheta domestica), crickets (Gryllidae) such as Teleogryllus emma;

  Hymenoptera: Tenthledinidae such as Athalia rosae, Athalia japonica; Tenthredinidae; Solenopsis geminata; Solenopsis spp. leaf-cutting ant (Atta capiguara) and other species of genus Atta spp., genus Acromyrmex spp., scorpion (Paraponera clavata), rugliari (Ochetellus glaber), common ant (Monomorium pharaonis), humiliate ant (Linepithema ile) ), Black ants (Formica fusca japonica), red ants (Pristomyrmex punctutus), giant ants (Pheidole noda), crested ants (Pheidole megacephala), black ants (Camponotus japonicus), red-tailed ants (Camponotus obscuripes), etc. (Pogonomyrmex occidentalis), etc. mex), genus Wasmania, such as Wasmania auropunctata, ant family (Formicidae), such as Anoplolepis gracilipes; Vespa mandarinia japonica, Vespa simillimais, Fabric Viuspa ), Vespa velutina, Polistes jokahamae, and other vespidae (Vespidae); Urocerus gigas, such as Siricidae, and Bethylidae.

  Cockroach (Blattodea): German cockroach (Blattellidae) such as German cockroach (Blattellidae); Black cockroach (Periplaneta fuliginosa), American cockroach (Periplaneta americana), Greater cockroach (Periplaneta brunnea), British cockroach ali (Blatta or cockroach ali) (Blattidae); Yamato termite (Reticulitermes speratus), termite (Coptotermes formosanus), American ant termite (Incisitermes minor), scallop termite (Cryptotermes domesticus), taiwan termite (Odontotermes formosanus), quasi termite (hunts termite) Glyptotermes satsumensis), Glyptotermes nakajimai, Caterpillars (Glyptotermes fuscus), Termites (Hodotermopsis sjostedti), Crested termites (Coptotermes guangzhouensis), Amamishiro Reticulitermes amamianus, Reticulitermes miyatakei, Remulitermes kanmonensis, Takashi termites (Nasutitermes takasagoensis), Nitto termites (Pericapritermes nitobei), Musi termites (Sino termites, Mumri termites) ).

  Flea eyes (Siphonaptera): Pulex genus such as human flea (Pulex irritans), Ctenocephalides felis such as cat flea (Ctenocephalides canis), Xenopsylla cheungs such as Xenopsylla cheopis, Genus Tunga, Echidnophaga gallinacea, etc., and Nosopsyllus genus, such as European rat minnow (Nosopsyllus fasciatus).

Psocodae: Pediculus genus such as head lice (Pediculus humanus capitis), Phtirus genus such as pheasants (Pthirus pubis), Haematopinus eurysternus, Haemalpinus eus such as Haematopinus suis Damalinia genus such as Damalinia bovis, bovine white lice (Linognathus vituli), sheep trunk parasitic white lice (Linognathus ovillus), etc. Menopon, Trimenopon spp., Trinoton spp., Trichodectes genus such as Trichodectes canis, Felicola genus such as cat lice (Felicola subrostratus), Bovicola genus such as Bovicola bovis, Menacanthus genus such as wolf lice (Menacanthus stramineus), Werneckiella spp., Lepikentron spp., Liposcelis subfuscas, Liposcelis bostrychophilus, Liposcelis simulans, Liposcelis divinatorcelis Liposcelididae, etc.
.

  Thysanura: Lepismatidae, such as Ctenoepisma villosa and Lepisma saccharina.

  Acari: Acrid: Tetranychus urticae, Tetranychus kanzawai, Mitranous spider mites (Tetranychus evansi), Citrus spider mites (Panonychus ulmi); ); Citrus ticks (Aculops pelekassi), Phyllocoptruta citri, Tomato rustic ticks (Aculops lycopersici), Chinese radish (Calacarus carinatus), Chinese radish (Acaphylla theavagrans), Mites Aculus schlechtendali, Aceria diospyri, Aceria tosichella, Sheevtchenkella sp., Etc., Eriophyidae; nicis, etc., Tenuipalpidae; Tuckerellidae; Ixodidae, for example Haemaphysalis longicornis, Haemaphysalis flava, Haemaphysali, etc. Dermacentor genus such as Dermacentor variabilis, Dermacentor taiwanicus, Dermacentor andersoni, Ixodes ovatus, Ixodes persulcatus, Western legged cap (Ixodes persulcatus) Ixodes pacificus, Ixodes genus such as Ixodes holocyclus, Amblyomma americanum, Amblyomma genus such as Ambryomma maculatum, Rhipicephalus (Boophil us) microplus), Boophilus genus such as Boophilus annulatus, Rhipicephalus sanguineus, Rhipicephalus appendiculatus and other Rhipicephalus genus; Tyrophagus putria Tyrophagus similis, Acaridae; Dermatophagoides farinae, Dermatophagoides pteronyssinus, Pyroglyphidae; Cheyletus eruditus, mite Clawlet ticks (Cheyletiella yasguri), etc. (Cheyletidae); Argas persicus (Argas persicus) genus, Ornithodorus hermsi, Ornithodorus turikata (Ornithodorus t uricata) and other genus Ornithodorus genus, scorpion genus Psoroptes ovis, psoroptes genus such as Psoroptes equi, Knemidocoptes mutans genus Knemidocoptes genus, Notoedres genus such as Notoedres muris, Sarcoptes genus such as Sarcoptes scabiei, Otodectes genus such as Octodectes cynotis, Listrophorus sp. ), Spider mites (Hypodectes spp.), Pterolichus spp., Cytodites spp., Laminosioptes spp., Dermanyssus genus such as Dermanyssus gallinae, Triys House dust mite (Ornithonyssus b genus Ornithonyssus such as acoti), Varroa such as Varroa jacobsoni, Cheletiella yasguri, Cheletiella blakei, Ornithocheyletia spp. Demodex genus such as Demodex canis, Caterpillar mite (Demodex cati), Myobia spp., Psorergates spp., Trombicula akamushi, Trombicula pallida, Trombicula scutellaris).

Araneae: Eutrichuridae such as Cheracanthium japonicum; Theridiidae such as Latrodectus hasseltii.
Polydesmida: Paradoxosomatidae, such as Oxidus gracilis and Nedyopus tambanus.
Isopoda: Armadillidiidae, such as Armadillidium vulgare.
Chiropoda: Scutigeridae, such as Thereuonema hilgendorfi; Scolopendridae, such as Scolopendra subspinipes;
Gastropoda: Limax marginatus, Limax flavus, and other scallops (Limacidae); Slug (Meghimatium bilineatum), etc. Ampullariidae; Austropeplea ollula, etc. (Lymnaeidae).

  Nematoda: Aphelenchoididae, such as Aphelenchoides besseyi; Pratylenchus coffeae, Pratylenchus brachyurus, Pratylenchus Rads, Pratylenchus negus Pratylenenchidae such as similis; Javaloid nematode (Meloidogyne javanica), Sweet potato nematode (Meloidogyne incognita), Kitane nematode (Meloidogyne hapla), soybean cyst nematode (Heterodera glycines), potato moth Heteroderidae such as Globodera pallida; Hoplolymidae such as Rotylenchulus reniformis; Nothotylenchus acris, Dityrenx gypsi Anguinidae such as itylenchus dipsaci; Tylenchulidae such as Tylenchulus semipenetrans; Longidoridae such as Xiphinema index; Trichodolae; Parasitaphelenchidae such as Bursaphelenchus xylophilus.

Within the above-mentioned harmful insects, harmful arthropods such as harmful mites, harmful molluscs, and harmful nematodes, variation within the species is not limited. In other words, harmful arthropods, harmful molluscs, and harmful nematodes that are less sensitive (also known as resistant) to certain insecticides, acaricides, molluscicides and nematicides It is. Examples of the insecticide, the acaricide, the molluscicide and the nematicide include group a1 to group a18.
Group a1: Acetylcholinesterase inhibitors alanycarb, aldicarb, bendiocarb, benfuracarb, butocarboxim, butoxycarboxim, carbaryl (NAC), Carbofuran, carbosulfan, ethiofencarb, fenobucarb (BPMC), formethanate, furathiocarb, isoprocarb (MIPC), methiocarb, methomyl , Metolcarb, oxamyl, pirimicarb, propoxur (PHC), thiodicarb, thiofanox, triazamate, trimeta Rumeth (trimethacarb), xylylcarb (acephate), azamethiphos (azamethiphos), azinphos-ethyl, azinphos-methyl, cadusafos, chlorethoxyfos, chlorvinbinphos ), Chlormephos, chlorpyrifos, chlorpyrifos-methyl, coumaphos, cyanophos (CYAP), demeton-S-methyl, diazinon, Dichlorvos (DDVP), dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, fanfhur, fenamifos (f) enamiphos, fenitrothion (MEP), fenthion (MPP), fosthiazate, heptenophos, imityaphos, isofenphos, isopropyl-O- (methoxyaminothiophosphoryl) salicylate (isopropyl) -O- (methoxyaminothiophosphoryl) salicylate), isoxathion, malathion, mecarbam, methamidophos, methidathion (DMTP), mevinphos, monocrotophos, nared : BRP), omethoate, oxydemeton-methyl, parathion, parathion-methyl, phentoate (PAP), phorate, phosalone, phoalone Met (phosmet: PMP), phosphamidon (phosphamidon), phoxim (pixim), pirimiphos-methyl, profenfos (profenofos), propetamphos (propetamphos), prothiofos (prothiofos), pyracrophos (pyraclofos), pyridafenthion (pyridaphenthion) (Quinalphos), sulfotep, tebupirimfos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon (DEP) and bamidthione A group consisting of (vamidothion).
Group a2: The group consisting of GABAergic chloride channel antagonist etiprole, fipronil and flufiprole.
Group a3: sodium channel modulators acrinathrin, allethrin, bifenthrin, kappa-bifenthrin, bioallethrin, bioresmethrin, cycloprothrin, cyfluthrin (Cyfluthrin), beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha cypermethrin (alpha- cypermethrin), beta-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, sigma-cypermethrin, cyphenothrin, deltamethrin thrin), empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, fluvalinate ( fluvalinate, tau-fluvalinate, halffenprox, heptafluthrin (heptafluthrin), imiprothrin, kadesthrin, meperfluthrin, monfluorothrin (momfluorothrin), permethrin permethrin), phenothrin, prallethrin, pyrethrin, resmethrin, silafluofen, tefluthrin, kappa-tefluthrin , Tetramethrin, tetramethylfluthrin, tralomethrin, transfluthrin, benfluthrin, flufenprox, flumethrin, furamethrin, methfluthrin The group consisting of metofluthrin), profluthrin and dimefluthrin.
Group a4: nicotinic acetylcholine receptor competitive modulators acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxurone, thiamethoxam , Sulfoxaflor, cycloxaprid, triflumezopyrim, dicloromezotiaz, and flupyrimine.
Group a5: Group consisting of nicotinic acetylcholine receptor allosteric modulators spinosad and spinetoram.
Group a6: glutamatergic chloride channel allosteric modulator abamectin, emamectin benzoate, lepimectin, milbemectin, dimadectin, doramectin, eprinomectin A group consisting of ivermectin, latidectin, selamectin, milbemycin D, moxidectin and nemadectin.
Group a7: The group consisting of juvenile hormones mimic hydroprene, kinoprene, metoprene, phenoxycarb and pyriproxyfen.
Group a8: A group consisting of the string organ TRPV channel modulators Pymetrozine and Pyrifluquinazon.
Group a9: Bacillus sphaericus, Bacillus thuringiensis strain BD # 32, Bacillus thuringiensis strain AQ52, Bacillus thuringiensis strain AQ52, Bacillus thuringiensis subsp. Aizawai strain ABTS-1857 (Bacillus thuringiensis subsp. Aizawai strain ABTS-1857), Bacillus thuringiensis subsp. Kurstaki strain HD-1), Bacillus thuringiensis subsp. Thuringiensis cristaki subsp. BMP123 strain (Bacillus thuringiensis subsp.kurstaki strain BMP123), Bacillus thuringiensis subsp. var. israelensis), Bacillus thuringiensis Aegypti (Bacillus thuringiensis var.aegypti), Bacillus thuringiensis var.colmeri, Bacillus thuringiensis var.darmstadiensis, Dendrolimus varieties (Bacillus thuringiensis var.dendrolimus), Bacillus thuringiensis galeria varieties (Bacillus thuringiensis var. Morrisoni), Bacillus thuringiensis var. San diego, Bacillus thuringiensis subsp. MPPL002 strain (Bacillus thuringiensis subsp. Thuringiensis strain MPPL0) 02), Bacillus thuringiensis 7216 variant (Bacillus thuringiensis var. 7216), Bacillus thuringiensis T36 variant (Bacillus thuringiensis var. T36), delta-endotoxins that confer resistance to lepidopteran insects (eg Cry1A, Cry1Ab , Modified Cry1Ab (partially deleted Cry1Ab), Cry1Ac, Cry1Ab-Ac (a hybrid protein fused with Cry1Ab and Cry1Ac), Cry1C, Cry1F, Cry1Fa2 (modified cry1F), moCry1F (modified Cry1F) , Cry1A. 105 (hybrid protein fused with Cry1Ab, Cry1Ac, Cry1F), Cry2Ab2, Cry2Ae, Cry9C, Vip3A, Vip3Aa20), and delta-endotoxins that confer resistance to Coleoptera (eg Cry3A, mCry3A (modified Cry3A)), Cry3Bb1, Cry34Ab1, Cry35Ab1).
Group a10: Group consisting of oxidative phosphorylation uncouplers chlorfenapyr and sulfluramid that disturb the proton gradient.
Group a11: Nicotinic acetylcholine receptor channel blocker bensultap, cartap, cartap hydrochloride, thiocyclam, thiosultap-disodium, and thiosultap monosodium salt ( thiosultap-monosodium).
Group a12: chitin biosynthesis inhibitors bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, The group consisting of lufenuron, novaluron, novifluururon, teflubenzuron, triflumuron and buprofezin.
Group a13: A group consisting of the molting inhibitor Cyromazine.
Group a14: A group consisting of molting hormone (ecdysone) receptor agonists chromafenozide, halofenozide, methoxyfenozide and tebufenozide.
Group a15: Group consisting of voltage-dependent sodium channel blockers indoxacarb and metaflumizone.
Group a16: the group consisting of the acetyl CoA carboxylase inhibitors spirodiclofen, spiromesifen and spirotetramat.
Group a17: Ryanodine receptor modulators chlorantraniliprole, cyantraniliprole, cycloniliprole, flubendiamide, tetraniliprole, cyhalodiamide and A group consisting of tetrachlorantraniliprole.
Group a18: A group consisting of flonicamid, a chordal organ modulator.

  Factors that decrease sensitivity include [1] decreased skin permeability, [2] enhanced metabolism, and [3] amino acid substitution of the target protein. The enhancement of metabolism in [2] means an increase in the activity of metabolic enzymes (also referred to as detoxification enzymes) such as cytochrome P450, carboxylesterase and glutathione S-transferase. In [3], the target protein may have one or more amino acid substitutions. Moreover, it may have one or more of [1] decreased skin permeability, [2] enhanced metabolism, and [3] amino acid substitution of the target protein as a factor of decreased sensitivity.

Examples of harmful arthropods, harmful molluscs, and harmful nematodes such as harmful insects and harmful mites that have decreased sensitivities include the following.
Hemiptera with reduced sensitivity to one or more compounds selected from group a2;
Hemiptera with reduced sensitivity to one or more compounds selected from group a4;
Hemiptera with reduced sensitivity to one or more compounds selected from group a8;
Hemiptera with reduced sensitivity to one or more compounds selected from group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a4;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a8;
One or more compounds selected from group a2, and hemiptera with reduced sensitivity to buprofezin belonging to group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a4 and one or more compounds selected from group a8;
One or more compounds selected from group a4, and Hemiptera with reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from group a8, and hemiptera with reduced sensitivity to buprofezin belonging to group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2, one or more compounds selected from group a4, and one or more compounds selected from group a8;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2, one or more compounds selected from group a4, and buprofezin belonging to group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2, one or more compounds selected from group a8, and buprofezin belonging to group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a4, one or more compounds selected from group a8, and buprofezin belonging to group a12;
Hemiptera with reduced sensitivity to one or more compounds selected from group a2, one or more compounds selected from group a4, one or more compounds selected from group a8, and buprofezin belonging to group a12;
A planthopper family with reduced sensitivity to one or more compounds selected from group a2;
A planthopper with reduced sensitivity to one or more compounds selected from group a4;
A planthopper family with reduced sensitivity to one or more compounds selected from group a8;
A planthopper family with reduced sensitivity to one or more compounds selected from group a12;
A planthopper family with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a4;
One or more compounds selected from group a2 and a planthopper family with reduced sensitivity to pymetrozine belonging to group a8;
One or more compounds selected from group a2, and a planthopper family with reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from group a4, and a planthopper family with reduced sensitivity to pymetrozine belonging to group a8;
One or more compounds selected from group a4, and a planthopper family with reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from group a2, one or more compounds selected from group a4, and a planthopper family with reduced sensitivity to pymetrozine belonging to group a8;
One or more compounds selected from group a2, one or more compounds selected from group a4, and a planthopper family with reduced sensitivity to buprofezin belonging to group a12;
A planthopper family with reduced sensitivity to one or more compounds selected from group a2, pymetrozine belonging to group a8, and buprofezin belonging to group a12;
A planthopper family with reduced sensitivity to one or more compounds selected from group a4, pymetrozine belonging to group a8, and buprofezin belonging to group a12;
One or more compounds selected from group a2, one or more compounds selected from group a4, pymetrozine belonging to group a8, and a planthopper family with reduced sensitivity to buprofezin belonging to group a12;
A brown planthopper, a brown planthopper, or a brown planthopper with reduced sensitivity to one or more compounds selected from group a2;
A brown planthopper, a brown planthopper, or a brown planthopper with reduced sensitivity to one or more compounds selected from group a4;
A brown planthopper, a brown planthopper, or a brown planthopper with reduced sensitivity to one or more compounds selected from group a8;
A brown planthopper, a brown planthopper, or a brown planthopper with reduced sensitivity to one or more compounds selected from group a12;
One or more compounds selected from group a2 and one or more compounds selected from group a4 and having reduced sensitivity to one or more compounds selected from group a4;
One or more compounds selected from group a2 and a brown planthopper, white-spotted planthopper, or brown planthopper with reduced sensitivity to pymetrozine belonging to group a8;
One or more compounds selected from group a2 and a brown planthopper, white-spotted planthopper, or brown planthopper with reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from the group a4, and a brown planthopper, sedge plant, or a planthopper with reduced sensitivity to pymetrozine belonging to the group a8;
One or more compounds selected from the group a4 and a brown planthopper, white-spotted planthopper, or a brown planthopper with reduced sensitivity to buprofezin belonging to the group a12;
One or more compounds selected from the group a2, one or more compounds selected from the group a4, and a brown planthopper, white-spotted planthopper, or a brown planthopper having reduced sensitivity to pymetrozine belonging to the group a8;
One or more compounds selected from group a2, one or more compounds selected from group a4, and a brown planthopper, white-spotted planthopper, or a brown planthopper having reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from group a2, pymetrozine belonging to group a8, and a brown planthopper, white-spotted planthopper, or a brown planthopper with reduced sensitivity to buprofezin belonging to group a12;
One or more compounds selected from the group a4, pymetrozine belonging to the group a8, and a brown planthopper, white-spotted planthopper, or a brown planthopper with reduced sensitivity to the buprofezin belonging to the group a12;
One or more compounds selected from the group a2, one or more compounds selected from the group a4, pymetrozine belonging to the group a8, and a brown planthopper, white-spotted planthopper, or a brown planthopper with reduced sensitivity to the buprofezin belonging to the group a12;
Aphids with reduced sensitivity to one or more compounds selected from group a3;
Aphids with reduced sensitivity to one or more compounds selected from group a8;
Aphids with reduced sensitivity to one or more compounds selected from group a3 and one or more compounds selected from group a4;
Aphids with reduced sensitivity to one or more compounds selected from group a3 and one or more compounds selected from group a8;
Aphids with reduced sensitivity to one or more compounds selected from group a4 and one or more compounds selected from group a8;
Aphids with reduced sensitivity to one or more compounds selected from group a3, one or more compounds selected from group a4, and one or more compounds selected from group a8;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a3;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a4;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a8;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a3 and one or more compounds selected from group a4;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a3 and one or more compounds selected from group a8;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a4 and one or more compounds selected from group a8;
Cotton aphids or peach aphids with reduced sensitivity to one or more compounds selected from group a3, one or more compounds selected from group a4, and one or more compounds selected from group a8;
Lepidoptera with reduced sensitivity to one or more compounds selected from group a14;
Lepidoptera with reduced sensitivity to one or more compounds selected from group a15;
Lepidoptera with reduced sensitivity to one or more compounds selected from group a17;
Lepidoptera with reduced sensitivity to one or more compounds selected from group a14 and one or more compounds selected from group a17;
Diamondback moth with reduced sensitivity to one or more compounds selected from group a15;
Diamondback moth with reduced sensitivity to one or more compounds selected from group a17;
Corn borers with reduced sensitivity to one or more compounds selected from group a14;
Corn borers with reduced sensitivity to one or more compounds selected from group a17;
One or more compounds selected from the group a14, and a Cobb rice moth having reduced sensitivity to one or more compounds selected from the group a17;
Chahamaki with reduced sensitivity to one or more compounds selected from group a14;
Chahamaki with reduced sensitivity to one or more compounds selected from group a17;
Chanococmon anemone with reduced sensitivity to one or more compounds selected from group a14;
Chanococmon anemone with reduced sensitivity to one or more compounds selected from group a17;
One or more compounds selected from group a14, and a chinook leaf beetle with reduced sensitivity to one or more compounds selected from group a17;
Coleoptera with reduced sensitivity to one or more compounds selected from group a2;
Coleoptera with reduced sensitivity to one or more compounds selected from group a3;
Coleoptera with reduced sensitivity to one or more compounds selected from group a4;
Coleoptera with reduced sensitivity to one or more compounds selected from group a9;
Coleoptera with reduced sensitivity to one or more compounds selected from group a17;
Coleoptera with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a4;
Chrysomelidae with reduced sensitivity to one or more compounds selected from group a2;
Chrysomelidae with reduced sensitivity to one or more compounds selected from group a3;
Chrysomelidae with reduced sensitivity to one or more compounds selected from group a4;
Chrysomelidae with reduced sensitivity to one or more compounds selected from group a9;
Chrysomelidae with reduced sensitivity to one or more compounds selected from group a17;
One or more compounds selected from group a2 and potato beetles with reduced sensitivity to one or more compounds selected from group a4;
Rice dwarf rice with reduced sensitivity to one or more compounds selected from group a2;
Rice dwarf rice with reduced sensitivity to one or more compounds selected from group a4;
Rice drab beetle with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a4;
The genus Diabrotica with reduced sensitivity to one or more compounds selected from group a2;
The genus Diabrotica with reduced sensitivity to one or more compounds selected from group a3;
The genus Diabrotica with reduced sensitivity to one or more compounds selected from group a4;
The genus Diabrotica with reduced sensitivity to one or more compounds selected from group a9;
The genus Diabrotica with reduced sensitivity to one or more compounds selected from group a17;
Diabrotica virgifera virgifera with reduced sensitivity to one or more compounds selected from group a2;
Diabrotica virgifera virgifera with reduced sensitivity to one or more compounds selected from group a3;
Diabrotica virgifera virgifera with reduced sensitivity to one or more compounds selected from group a4;
Diabrotica virgifera virgifera with reduced sensitivity to one or more compounds selected from group a9;
Diabrotica virgifera virgifera with reduced sensitivity to one or more compounds selected from group a17;
Diabrotica undecimpunctata howardi with reduced sensitivity to one or more compounds selected from group a2;
Diabrotica undecimpunctata howardi with reduced sensitivity to one or more compounds selected from group a3;
Diabrotica undecimpunctata howardi with reduced sensitivity to one or more compounds selected from group a4;
Diabrotica undecimpunctata howardi with reduced sensitivity to one or more compounds selected from group a9;
Diabrotica undecimpunctata howardi with reduced sensitivity to one or more compounds selected from group a17;
Diabrotica barberi with reduced sensitivity to one or more compounds selected from group a2;
Diabrotica barberi with reduced sensitivity to one or more compounds selected from group a3;
Diabrotica barberi with reduced sensitivity to one or more compounds selected from group a4;
Diabrotica barberi with reduced sensitivity to one or more compounds selected from group a9;
Diabrotica barberi with reduced sensitivity to one or more compounds selected from group a17;
Diabrotica speciosa with reduced sensitivity to one or more compounds selected from group a2;
Diabrotica speciosa with reduced sensitivity to one or more compounds selected from group a3;
Diabrotica speciosa with reduced sensitivity to one or more compounds selected from group a4;
Diabrotica speciosa with reduced sensitivity to one or more compounds selected from group a9;
Diabrotica speciosa with reduced sensitivity to one or more compounds selected from group a17;
Colorado potato beetle with reduced sensitivity to one or more compounds selected from group a2;
Colorado potato beetle with reduced sensitivity to one or more compounds selected from group a3;
Colorado potato beetle with reduced sensitivity to one or more compounds selected from group a4;
Colorado potato beetle with reduced sensitivity to one or more compounds selected from group a17;
Kissing beetle with reduced sensitivity to one or more compounds selected from group a3;
Susceptibility to one or more compounds selected from group a4;
Kissing beetle with reduced sensitivity to one or more compounds selected from group a17;
Phyllotreta cruciferae with reduced sensitivity to one or more compounds selected from group a3;
Phyllotreta cruciferae with reduced sensitivity to one or more compounds selected from group a4;
Phyllotreta cruciferae with reduced sensitivity to one or more compounds selected from group a17;
Phyllotreta pusilla with reduced sensitivity to one or more compounds selected from group a3;
Phyllotreta pusilla with reduced sensitivity to one or more compounds selected from group a4;
Phyllotreta pusilla with reduced sensitivity to one or more compounds selected from group a17;
Psylliodes chrysocephala with reduced sensitivity to one or more compounds selected from group a3;
Psylliodes chrysocephala with reduced sensitivity to one or more compounds selected from group a4;
Psylliodes chrysocephala with reduced sensitivity to one or more compounds selected from group a17;
Psylliodes punctulata with reduced sensitivity to one or more compounds selected from group a3;
Psylliodes punctulata with reduced sensitivity to one or more compounds selected from group a4;
Psylliodes punctulata with reduced sensitivity to one or more compounds selected from group a17;
Weevil with reduced sensitivity to one or more compounds selected from group a2;
Weevilaceae with reduced sensitivity to one or more compounds selected from group a4;
One or more compounds selected from group a2 and a weevil with reduced sensitivity to one or more compounds selected from group a4;
Rice weevil with reduced sensitivity to one or more compounds selected from group a2;
Rice weevil with reduced sensitivity to one or more compounds selected from group a4;
Rice weevil with reduced sensitivity to one or more compounds selected from group a2 and one or more compounds selected from group a4;
A click beetle with reduced sensitivity to one or more compounds selected from group a2;
The beetle with reduced sensitivity to one or more compounds selected from group a3;
A click beetle with reduced sensitivity to one or more compounds selected from group a4;
Okinawa Kanshakumetsuki with reduced sensitivity to one or more compounds selected from group a2;
Okinawa Kanshokumetsuki with reduced sensitivity to one or more compounds selected from Group a3;
Okinawa Kanshakumetsuki with reduced sensitivity to one or more compounds selected from Group a4;
Tobiiromubosokometsuki with reduced sensitivity to one or more compounds selected from group a2;
Tobiiromubosokometeki with reduced sensitivity to one or more compounds selected from group a3;
Tobiiromubosokometsuki with reduced sensitivity to one or more compounds selected from group a4;
A crispiness with reduced sensitivity to one or more compounds selected from group a2;
A crispiness with reduced sensitivity to one or more compounds selected from group a3;
A crispiness with reduced sensitivity to one or more compounds selected from group a4;
The genus Ashibetella with reduced sensitivity to one or more compounds selected from group a2;
The genus Ashibetella with reduced sensitivity to one or more compounds selected from group a3;
The genus Ashibetella with reduced sensitivity to one or more compounds selected from group a4;
Reduced susceptibility to one or more compounds selected from group a2;
Reduced susceptibility to one or more compounds selected from group a3;
Reduced susceptibility to one or more compounds selected from group a4;
Kutenisella sp. With reduced sensitivity to one or more compounds selected from group a2;
Kutenisella sp. With reduced sensitivity to one or more compounds selected from group a3;
Kutenisella sp. With reduced sensitivity to one or more compounds selected from group a4;
Limonius with reduced sensitivity to one or more compounds selected from group a2;
Limonius with reduced sensitivity to one or more compounds selected from group a3;
Limonius with reduced sensitivity to one or more compounds selected from group a4;
A genus Aeolus with reduced sensitivity to one or more compounds selected from group a2;
A genus Aeolus with reduced sensitivity to one or more compounds selected from group a3;
A genus Aeolus with reduced sensitivity to one or more compounds selected from group a4;

Examples of harmful arthropods, harmful molluscs, and harmful nematodes such as harmful insects and harmful mites that have been reduced in sensitivity by amino acid substitution at the target site include the following.
Cotton aphids with R81T amino acid substitution in the β subunit of the nicotinic acetylcholine receptor; Peach aphids with R81T amino acid substitution in the β subunit of the nicotinic acetylcholine receptor;
A diamondback moth with an amino acid substitution of G4946E at the ryanodine receptor;
A diamondback moth having an amino acid substitution of F1845Y or V1848I in the sodium channel;
Seduce plant having an A2'N amino acid substitution at the GABA receptor;

The compounds and compositions A can also be used to protect plants from plant diseases caused by insect-borne viruses or insect-borne bacteria.

Examples of such insect-borne viruses include the following.
Rice tungro spherical virus, Rice tungro bacilliform virus, Rice grassy stunt virus, Rice ragged stunt virus, Rice stripe virus ( Rice stripe virus, Rice black streaked dwarf virus, Southern rice black-streaked dwarf virus, Rice gall dwarf virus, Rice hoja blanca virus), rice yellow stunt virus, rice yellow mottle virus, rice dwarf virus, northern cereal mosaic virus, barley yellow dwarf virus, Barley mild mosaic virus, Barley yellow dwarf virus-PAV, Ruiki萎 RPS virus (Cereal yellow dwarf virus-RPS), wheat yellow leaves virus (Wheat yellow leaf virus), Oat sterile dwarf virus, Wheat streak mosaic virus,
Maize dwarf mosaic virus, Maize stripe virus, Maize chlorotic mottle virus, Maize chlorotic dwarf virus, Maize rayado fino virus, sugarcane mosaic virus, Fiji disease virus, Sugarcane yellow leaf virus Mosaic virus (Soybean mild mosaic virus), Cycas necrotic stunt, Soybean dwarf virus, Milk vetch dwarf virus, Soybean mosaic virus, Alfalfa Mosaic virus (Alfalfa mosaic virus), bean yellow mosaic virus, bean common mosaic virus, southern bean mosaic virus, peanut stunt virus, Sorama Wild bean wilt virus 1, Broad bean wilt virus 2, Broad bean necrosis virus, Broad bean yellow vein virus, Clover yellow vein virus, Peanut mottle virus, Tobacco streak virus, Bean pod mottle virus, Cowpea chlorotic mottle virus, Mung bean yellow mosaic virus, Soybean crinkle leaf virus,
Tomato chlorosis virus, Tomato spotted wilt virus, Tomato yellow leaf curl virus, Tomato aspermy virus, Tomato infectious Tomato infectious chlorosis virus, Potato leafroll virus, Potato virus Y, Melon yellow spot virus, Melon necrotic spot virus ), Watermelon mosaic virus, Cucumber mosaic virus, Zucchini yellow mosaic virus, Turnip mosaic virus, Turnip yellow mosaic virus ), Cauliflower mosaic virus Cauliflower mosaic virus, Lettuce mosaic virus, Celery mosaic virus, Beet mosaic virus, Cucurbit chlorotic yellows virus, Pepper reddening virus (Capsicum chlorosis virus), Beet pseudo yellows virus, Leak yellow stripe virus, Onion yellow dwarf virus, Sweet potato feathery mottle virus ), Sweet potato shukuyo mosaic virus, Strawberry mottle virus, Strawberry mild yellow edge virus, Strawberry pseudo mild yellow edge virus (Strawberry pseudo mild yellow edge virus) ), Ichi Strawberry crinkle virus, Strawberry vein banding virus, plum pox virus, Chrysanthemum stem necrosis virus, Impatiens necrosis virus (Impatiens) necrotic spot virus), Iris yellow spot virus, Lily mottle cirus, Lily symptomless virus, Tulip mosaic virus, etc.

Examples of insect-borne bacteria include the following.
Rice yellow dwarf phytoplasma (Candidatus Phytoplasma oryzae), Candidatus Phytoplasma asteris, Maize bushy stunt phytoplasma, citrus greening fungus Asian type (Candidatus Liberbacter asiaticus), citrus greening fungus African type (Candidatus Liberbacter african disease) Type (Candidatus Liberbacter americanus) etc.

  The present compound and the composition A also have a feeding damage suppressing effect, a repellent effect, an egg laying suppressing effect, an infertility effect, a next generation output suppressing effect, a mating behavior inhibitory effect, a molting inhibitory effect, and an emergence inhibitory effect. As a result, crops can be protected from damage by harmful arthropods such as harmful insects and harmful mites, harmful molluscs, and harmful nematodes.

  The composition of the present invention can also control plant diseases caused by phytopathogenic microorganisms such as fungi, bacteria, oomycetes, and fungi when a bactericidal active ingredient is included as this component. Examples of plant diseases include the following. In parentheses are the scientific names of the phytopathogenic microorganisms that cause each disease.

Rice blast (Magnaporthe grisea), sesame leaf blight (Cochliobolus miyabeanus), blight (Rhizoctonia solani), idiot seedling (Gibberella fujikuroi), yellow dwarf (Sclerophthora macrospora), wheat powdery mildew (Erysiphe) graminis), red mold (Fusarium graminearum, F. avenaceum, F. culmorum, Microdochium nivale), rust (Puccinia striiformis, P. graminis, P. recondita), red snow rot (Microdochium nivale, M.majus), Snow rot microbe nuclei (Typhula sp.), Naked smut (Ustilago tritici), black scab (Tilletia caries, T. controversa), eye spot (Pseudocercosporella herpotrichoides), leaf blight (Septoria tritici), blight Disease (Stagonospora nodorum), macular disease (Pyrenophora tritici-repentis), seedling blight (Rhizoctonia solani), bacterial blight (Gaeumannomyces graminis), barley powdery mildew (Erysiphe graminis), red mold ( Fusarium graminearu m, F. avenaceum, F. culmorum, Microdochium nivale), rust disease (Puccinia striiformis, P.graminis, P.hordei), naked smut (Ustilago nuda), cloud disease (Rhynchosporium secalis), reticular disease (Pyrenophora teres) ), Spot disease (Cochliobolus sativus), leafy leaf disease (Pyrenophora graminea), lambaria disease (Ramularia collo-cygni), Rhizoctonia solani (Rhizoctonia solani); corn rust (Puccinia sorghi), southern rust Diseases (Puccinia polysora), soot rot (Setosphaeria turcica), tropical rust (Physopella zeae), sesame leaf blight (Cochliobolus heterostrophus), anthracnose (Colletotrichum graminicola), gray leaf spot (Cercospora zeae-maydis) ), Brown spot (Kabatiella zeae), Faeosphaeria reef spot disease (Phaeosphaeria maydis), diplodia disease (Stenocarpella maydis, Stenocarpella macrospora), Stokelot disease (Fu) sarium graminearum, Fusarium verticilioides, Colletotrichum graminicola), smut (Ustilago maydis), cotton anthracnose (Colletotrichum gossypii), mildew (Ramularia areola), black spot (Alternaria macrospora, A. gossypii), Thielaviopsis Black root rot disease (Thielaviopsis basicola), coffee rust disease (Hemileia vastatrix), leaf spot disease (Cercospora coffeicola), rape mycorrhizal disease (Sclerotinia sclerotiorum), black spot disease (Alternaria brassicae), rot disease (Phoma) lingam), sugarcane rust (Puccinia melanocephela, Puccinia kuehnii), smut (Ustilago scitaminea), sunflower rust (Puccinia helianthi), downy mildew (Plasmopara halstedii), citrus black spot (Diaporthe disease) (Elsinoe fawcetti), fruit rot (Penicillium digitatum, P. italicum), plague (Phytophthora parasitica, Phytophthora citrophthora), apple monilia (Monilinia) mali), rot (Valsa ceratosperma), powdery mildew (Podosphaera leucotricha), spotted leaf disease (Alternaria alternata apple pathotype), black star disease (Venturia inaequalis), anthracnose (Glomerella cingulata), brown spot disease (Diplocarpon mali) , Ring-tooth disease (Botryosphaeria berengeriana), plague (Phytophtora cactorum), pear black spot disease (Venturia nashicola, V. pirina), black spot disease (Alternaria alternata Japanese pear pathotype), red star disease (Gymnosporangium haraeanum), peach ash star Disease (Monilinia fructicola), black scab (Cladosporium carpophilum), phomopsis sp. (Phomopsis sp.); Grape black rot (Elsinoe ampelina), late rot (Glomerella cingulata), powdery mildew (Uncinula necator), rust (Phakopsora ampelopsidis), Blacklot disease (Guignardia bidwellii), downy mildew (Plasmopara viticola), oyster anthracnose (Gloeosporium kaki), deciduous disease (Cercospora kaki, Mycosphaerella nawae) Colletotrichum lagenarium, powdery mildew (Sphaerotheca fuliginea), vine blight (Didymella bryoniae), brown spot (Corynespora cassiicola), vine split (Fusarium oxysporum), downy mildew (Pseudoperonospora cubensis) , Plague (Phytophthora sp.), Seedling blight (Pythium sp.), Tomato ring rot (Alternaria solani), leaf mold (Cladosporium fulvum), subtilis (Pseudocercospora fuligena), plague (Phytophthora infestans), Powdery mildew (Leveillula taurica), eggplant brown spot (Phomopsis vexans), powdery mildew (Erysiphe cichoracearum), cruciferous vegetable black spot (Alternaria japonica), white spot (Cercosporella brassicae), clubroot (Plasmodiophora) brassicae), downy mildew (Peronospora parasitica), spring onion rust (Puccinia allii), soybean purpura (Cercospora kikuchii), black scab (Elsinoe glycines), black spot (Diaporthe phaseolorum var. sojae), Disease (Phakopsora pachyrhizi), brown ring disease (Corynespora cassiicola), anthrax (Colletotrithum glycines, C. truncatum), leaf rot (Rhizoctonia solani), brown leaf disease (Septoria glycines), spot disease (Cercospora sojina), fungus Nuclear disease (Sclerotinia sclerotiorum), powdery mildew (Microsphaera diffusa), stem blight (Phytophthora sojae), downy mildew (Peronospora manshurica), sudden death (Fusarium virguliforme), kidney bean, Sclerotinia sclerotiorum, rust Disease (Uromyces appendiculatus), horn spot disease (Phaeoisariopsis griseola), anthracnose (Colletotrichum lindemthianum), groundnut black rot (Cercospora personata), brown spot disease (Cercospora arachidicola), white silkworm (Sclerotium rolfsii); Powdery mildew (Erysiphe pisi), potato summer plague (Alternaria solani), plague (Phytophthora infestans), scarlet rot (Phytophthora erythroseptica), powdery scab (Spongospora subterranea) n f. sp. subterranea), half body wilt (Verticillium albo-atrum, V. dahliae, V. nigrescens), strawberry powdery mildew (Sphaerotheca humuli), tea net blast (Exobasidium reticulatum), white scab (Elsinoe) leucospila), ring spot disease (Pestalotiopsis sp.), anthracnose (Colletotrichum theae-sinensis), cigarette scab (Alternaria longipes), anthracnose (Colletotrichum tabacum), downy mildew (Peronospora tabacina), plague (Phytophthora) nicotianae), brown spot of sugar beet (Cercospora beticola), leaf rot (Thanatephorus cucumeris), root rot (Thanatephorus cucumeris), black root (Aphanomyces cochlioides), black spot of rose (Diplocarpon rosae), powdery mildew (Sphaerotheca) pannosa), brown spot of chrysanthemum (Septoria chrysanthemi-indici), white rust (Puccinia horiana), leaf blight of onion (Botrytis cinerea, B. byssoidea, B. squamosa), gray rot (Botrytis alli), Bacterial rot (Bo) trytis squamosa), various crops of gray mold (Botrytis cinerea), mycorrhizal disease (Sclerotinia sclerotiorum), radish black spot (Alternaria brassicicola), buckwheat dollar spot (Sclerotinia homeocarpa), buckwheat brown patch disease and large Patch disease (Rhizoctonia solani), as well as banana sigatoka disease (Mycosphaerella fijiensis, Mycosphaerella musicola).
Seed disease or early growth of various crops caused by Aspergillus, Penicillium, Fusarium, Gibberella, Tricoderma, Thielaviopsis, Rhizopus, Mucor, Corticium, Phoma, Rhizoctonia, and Diplodia Disease. Viral diseases of various crops mediated by Polymixa genus or Olpidium genus.
Rice seed blight (Burkholderia plantarii), cucumber spotted bacterial disease (Pseudomonas syringae pv. Lachrymans), eggplant blight (Ralstonia solanacearum), citrus scab (Xanthomonas citiri), Chinese cabbage soft rot (Erwinia) carotovora) etc.

  For the above plant pathogenic microorganisms, the variation within the species is not particularly limited. That is, it includes those having reduced sensitivity (also referred to as resistance) to a specific fungicide. The decrease in sensitivity may be due to a mutation at the target site (point of action mutation) or may be due to a factor that is not a point of action mutation (non-point of action mutation). With regard to the action point mutation, a mutation in the nucleic acid sequence portion (open reading frame) corresponding to the amino acid sequence of the protein caused amino acid substitution in the target protein, deletion of the suppressor sequence in the promoter region, or enhancer Those in which the protein at the target site is overexpressed due to mutation such as amplification of the sequence or increase in the copy number of the gene are included. Non-acting point mutations include, for example, enhancement of the excretory function of discharging the bactericide that has flowed into the cell out of the cell by ABC transporter, MFS transporter, or the like. Moreover, detoxification by metabolism of a bactericide is also mentioned.

  Examples of the bactericides include nucleic acid synthesis inhibitors (for example, phenylamide bactericides, acylamino acid bactericides, DNA topoisomerase type II bactericides), mitosis and cell division inhibitors (for example, MBC bactericides). Agents, N-phenylcarbamate fungicides), respiratory inhibitors (eg QoI fungicides, QiI fungicides, SDHI fungicides), amino acid synthesis and protein synthesis inhibitors (eg anilinopyrimidine fungicides), signal transduction Inhibitors (eg phenylpyrrole fungicides, dicarboximide fungicides), lipid synthesis and cell membrane synthesis inhibitors (eg phosphorothiolate fungicides, dithiolane fungicides, aromatic hydrocarbon fungicides, heteroaromatics Family fungicides, carbamate fungicides), sterol biosynthesis inhibitors (eg triazole-based DMI fungicides) , Hydroxyanilide fungicides, aminopyrazolinone fungicides), cell wall synthesis inhibitors (eg, polyoxin fungicides, carboxylic acid amide fungicides), melanin synthesis inhibitors (eg, MBI-R fungicides, MBI) -D fungicide, MBI-P fungicide), and other fungicides (for example, cyanoacetamidooxime fungicides, phenylacetamide fungicides).

Examples of the amino acid substitution at the target site include the following.
Cytochrome b: G143A, F129L or G137R;
Cyp51 protein includes A311G, A379G, A381G, A410T, A61V, D107V, D134G, D282E, D411N, E297K, F120L, F219S, F449S, F489L, F495I, G138C / R / S, G312A, G412A, G432S, G434C, G448S, G434C, G448S / Δ, G462A, G464S, G484S, G510C, G54E / K / R / V / W, G54W, H147Y, H303Y, H399P, I145F, I330T, I381V / Δ, I471T, I475T, K142R, K143E, K147Q, K175N, K197N , L50S, L98H, M145L, M220K / I / T / V, M288L, N125I, N178S, N22D, N284H, N513K, P216L, P384S, P394L, Q141H, Q88H, R467K, S188N, S208T, S297T, S405F, S508T, S509T , S524T, S52T, S79T, T289A, T440A, T454P, T469S, V101F, V136A / C / G, V490L, Y121F, Y131F / H, Y132F / H / N, Y134F, Y134F, Y136F, Y137F, Y140F / H, Y145F Y431C, Y459C / D / N / S / P / Δ, Y461D, Y461D / H / S, Y463D / H / N, Y491H or Y68N;
β-tubulin: H6L / Y, Y50C / N / S, Q134K, A165V, E198A / D / G / K / L / Q / V, F200Y, M257L, F200Y, F167Y, Q73R or L240F;
SdhB: H277R / Y, P225H / F / L / T, N230I, H272L / R / V / Y, H278Y / R, H249L / N / Y, H273Y, N225I / T, T268I / A, I269V, H242R, H257L or T253I;
SdhC: H134R, P80H / L, A85V, S73P, T90I, I86F, N88S, H154Y / R, K49E, R64K, N75S, G79R, S135R, N87S, H153R, H146R, I29V, N33T, N34T, T79I / N, W80S, A84V, N86K / S / A, G90R, R151T / S, H152R, I161S, G169D or H151R;
SdhD: H133R, H132R, S89P, G109V, D124E / N, H134R, G138V, D145G, I50F, M114V or D129E;
OS-1 (Shk1): E753K, G420D, I365N / R / S, V368F, Q369H / P, N373S, T447S, F267L, L290S, T765R, Q777R, T489I, E599K or G736Y;
ERG27: S9G, F26S, P57A, T63I, G170R, V192I, L195F, N196T, A210G, I232M, P238S / Δ, P250S, P269L, P298Δ, V309M, A314V, S336C, V365A, E368D, N369D, E375K, A378T, L400F S, Y408S, F412I / S / V / C, A461S or R496T.

  Moreover, the following are mentioned as a phytopathogenic microorganism and its host plant in which the sensitivity with respect to the fungicide fell by overexpressing Cyp51 gene. Septoria tritici in wheat (reference: Pest Management Science. 2012. 68 (7) .1034-1040), Rhynchosporium secalis in barley (reference: Molecular Bilogy and Evolution. 2014. 31 (7) .1793-1802) Phakopsora pachyrhizi (reference: Pest Management Science. 2014. 70 (3) .378-388), apple Venturia inaequalis (reference: Phytopathology. 2016. 106 (6) .562-571), citrus penicillium digitatum (reference) Literature: Applied and Environmental Microbiology. 2000. 66 (8) .3421-3426).

  The phytopathogenic microorganism that can control the composition of the present invention may have a plurality of the above amino acid substitutions. In this case, the plurality of amino acid substitutions may be the same protein or different proteins. Moreover, you may have two or more non-action point mutations and action point mutations. For example, a phytopathogenic microorganism that causes amino acid substitutions of G143A, F129L and G137R in cytochrome b; a phytopathogenic microorganism having an amino acid substitution of G143A in cytochrome b and an amino acid substitution of A311G in Cyp51; G143A in cytochrome b; Phytopathogenic microorganisms with F129L amino acid substitution and Cyp51 with A311G amino acid substitution; cytochrome b with G143A and F129L amino acid substitutions and β-tubulin with H6L / Y amino acid substitutions Furthermore, phytopathogenic microorganisms overexpressing the Cyp51 gene.

Examples of phytopathogenic microorganisms having an action point mutation include the following.
Alternaria alternata having an amino acid substitution of G143A in cytochrome b;
Alternaria arborescens having an amino acid substitution of G143A in cytochrome b;
Alternaria solani having an amino acid substitution of F129L in cytochrome b;
Alternaria tomato having an amino acid substitution of G143A in cytochrome b;
Botryotinia fuckeliana having an amino acid substitution of G143A in cytochrome b;
Glomerella graminicola having an amino acid substitution of G143A in cytochrome b;
Corynespora cassiicola having an amino acid substitution of G143A in cytochrome b;
Cercospora beticola having an amino acid substitution of G143A in cytochrome b;
Cercospora sojina having an amino acid substitution of G143A in cytochrome b;
Cladsporium carpophilum having an amino acid substitution of G143A in cytochrome b;
Colletotrichum graminicola having an amino acid substitution of G143A in cytochrome b;
Glomerella cingulata having an amino acid substitution of G143A in cytochrome b;
Blumeria graminis f. Sp. Hordei having an amino acid substitution of G143A in cytochrome b;
Blumeria graminis f. Sp. Tritici having an amino acid substitution of G143A in cytochrome b;
Parastagonospora nodorum having an amino acid substitution of G143A in cytochrome b;
Monographella nivalis having an amino acid substitution of G143A in cytochrome b;
Microdochium majus, nivale with an amino acid substitution of G143A in cytochrome b;
Mycosphaerella fijiensis having an amino acid substitution of G143A in cytochrome b;
Didymella rabiei having an amino acid substitution of G143A in cytochrome b;
Phakopsora pachyrhizi with an amino acid substitution of F129L in cytochrome b;
Plasmopara viticola having an amino acid substitution of F129L or G143A in cytochrome b;
Pleospora allii having an amino acid substitution of G143A in cytochrome b;
Podosphaera fusca having an amino acid substitution of G143A in cytochrome b;
Podosphaera xanthii having an amino acid substitution of G143A in cytochrome b;
Pseudoperonospora cubensis having an amino acid substitution of G143A in cytochrome b;
Magnaporthe oryzae having an amino acid substitution of F129L or G143A in cytochrome b;
Pyrenophora teres with F129L amino acid substitution in cytochrome b;
Pyrenophora tritici-repentis having an amino acid substitution of F129L, G137R or G143A in cytochrome b;
Pythium aphanidermatum having an amino acid substitution of F129L in cytochrome b;
Thanatephorus cucumeris having an amino acid substitution of F129L or G143A in cytochrome b;
Ramularia collo-cygni having an amino acid substitution of G143A in cytochrome b;
Rhynchosporium secalis with an amino acid substitution of G143A in cytochrome b;
Rhizoctonia solani having an amino acid substitution of F129L in cytochrome b;
Zymoseptoria tritici having amino acid substitution of F129L, G137R or G143A in cytochrome b;
Erysiphe necator having an amino acid substitution of G143A in cytochrome b;
Venturia inaequalis having an amino acid substitution of G143A in cytochrome b;
Ajellomyces capsulatus having an amino acid substitution of Y136F in Cyp51;
Aspergillus flavus having amino acid substitution of Y132N, K197N, D282E, M288L, T469S, H399P, D411N or T454P in Cyp51;
Cyp51 to N22D, S52T, G54E / K / R / V / W, Y68N, Q88H, L98H, V101F, Y121F, N125I, G138C / R / S, Q141H, H147Y, P216L, F219S, M220K / I / T / V, Aspergillus fumigatus having an amino acid substitution of T289A, S297T, P394L, Y431C, G432S, G434C, T440A, G448S, Y491H or F495I;
Aspergillus parasiticus having an amino acid substitution of G54W in Cyp51;
Cypida albicans having an amino acid substitution of A61V, Y132F / H, K143E, S405F, F449S, G464S, R467K or I471T in Cyp51;
Cercospora beticola having an amino acid substitution of E297K, I330T or P384S in Cyp51;
Blumeria graminis f. Sp. Hordei having an amino acid substitution of Y136F, K147Q or S509T in Cyp51;
Blumeria graminis f. Sp. Tritici having an amino acid substitution of C79 with S79T, Y136F, or K175N;
Filobaidiella neoformans having an amino acid substitution of Y145F or G484S in Cyp51;
Monilinia fructicola having an amino acid substitution of Y136F in Cyp51,
Mycosphaerella fijiensis having an amino acid substitution of Y136F, A313G, A381G, Y461D, G462A or Y463D / H / N in Cyp51;
Phakopsora pachyrhizi having an amino acid substitution of F120L, Y131F / H, K142R, I145F or I475T in Cyp51;
Puccinia triticina with Y134F amino acid substitution in Cyp51;
Pyrenophora teres with F489L amino acid substitution in Cyp51;
Pyrenopeziza brassicae having an amino acid substitution of S508T in Cyp51;
Saccharomyces cerevisiae having an amino acid substitution of Y140F / H in Cyp51;
Cyp51 to L50S, D107V, D134G, V136A / C / G, Y137F, M145L, N178S, S188N, S208T, N284H, H303Y, A311G, G312A, A379G, I381V / Δ, A410T, G412A, Y459C / D / N / S / Zymoseptoria tritici having an amino acid substitution of P / Δ, G460D / Δ, Y461D / H / S, V490L, G510C, N513K or S524T;
Erysiphe necator having an amino acid substitution of Y136F in Cyp51;
Emericella nidulans having an amino acid substitution of H6L / Y, Y50N / S, Q134K, A165V, E198D / K / Q, F200Y or M257L in β-tubulin;
Botryotinia fuckeliana having an amino acid substitution of E198A / G / K / V or F200Y in β-tubulin;
Cochliobolus heterostrophus having an amino acid substitution of F167Y in β-tubulin;
Cercospora beticola having an amino acid substitution of F167Y or E198A in β-tubulin;
Gibberella fujikuroi having an amino acid substitution of Y50N, E198V or F200Y in β-tubulin;
Gibberella zeae having an amino acid substitution of Y50C, Q73R, F167Y, E198K / L / Q or F200Y in β-tubulin;
Helminthosporium solani with an amino acid substitution of E198A / Q in β-tubulin;
Hypomyces odoratus having an amino acid substitution of Y50C in β-tubulin;
Parastagonospora nodorum with amino acid substitution of H6Y in β-tubulin;
Monilinia fructicola having an amino acid substitution of H6Y or E198A / K in β-tubulin;
Monilinia laxa having an amino acid substitution of L240F in β-tubulin;
Microdochium majus, nivale with an amino acid substitution of E198A in β-tubulin;
Mycosphaerella fijiensis with an amino acid substitution of E198A in β-tubulin;
Neurospora crassa having an amino acid substitution of F167Y or E198G in β-tubulin;
Penicillium aurantiogriseum having an amino acid substitution of E198A / K or F200Y in β-tubulin;
Penicillium expansum having an amino acid substitution of F167Y or E198A / K / V on β-tubulin;
Penicillium italicum having an amino acid substitution of E198K or F200Y in β-tubulin;
Pyrenopeziza brassicae with L240F amino acid substitution in β-tubulin;
Rhynchosporium secalis with an amino acid substitution of E198G / K or F200Y in β-tubulin;
Sclerotinia homoeocarpa with E198A / K amino acid substitution in β-tubulin;
Sclerotinia sclerotiorum having an amino acid substitution of E198A in β-tubulin;
Zymoseptoria tritici with an amino acid substitution of E198A / G in β-tubulin;
Venturia inaequalis having an amino acid substitution of E198A / K, F200Y or L240F in β-tubulin;
Alternaria alternata having an amino acid substitution of H277R / Y in SdhB;
Alternaria solani having an amino acid substitution of H277R / Y in SdhB,
Botryotinia fuckeliana having an amino acid substitution of P225H / F / L / T, N230I or H272L / R / V / Y in SdhB;
Corynespora cassiicola with H278Y / R amino acid substitution in SdhB;
Stagonosporopsis cucurbitacearum having an amino acid substitution of H277R / Y in SdhB;
Eurotium oryzae having an amino acid substitution of H249L / N / Y in SdhB;
Pyrenophora teres with H277Y amino acid substitution in SdhB;
Sclerotinia sclerotiorum having an amino acid substitution of H273Y in SdhB;
Zymoseptoria tritici having an amino acid substitution of N225I / T, H273Y, T268I / A or I269V in SdhB;
Erysiphe necator having an amino acid substitution of H242R in SdhB;
Ustilago maydis having an amino acid substitution of H257L in SdhB;
Venturia inaequalis with T253I amino acid substitution in SdhB;
Alternaria alternata having an amino acid substitution of H134R in SdhC;
Botryotinia fuckeliana with P80H / L or A85V amino acid substitution in SdhC;
Corynespora cassiicola having S73P amino acid substitution in SdhC;
Eurotium oryzae with T90I amino acid substitution in SdhC;
Phakopsora pachyrhizi having an amino acid substitution of I86F, N88S or H154Y / R in SdhC;
Pyrenophora teres having an amino acid substitution of K49E, R64K, N75S, G79R, H134R or S135R in SdhC;
Ramularia collo-cygni having an amino acid substitution of N87S, H146R or H153R in SdhC;
Sclerotinia sclerotiorum having an amino acid substitution of H146R in SdhC;
Zymoseptoria tritici having an amino acid substitution of I29V, N33T, N34T, T79I / N, W80S, A84V, N86K / S / A, G90R, R151T / S, H152R or I161S in SdhC;
Erysiphe necator having an amino acid substitution of G169D in SdhC;
Venturia inaequalis having an amino acid substitution of H151R in SdhC;
Alternaria alternata having an amino acid substitution of H133R in SdhD;
Alternaria solani having an amino acid substitution of H133R in SdhD;
Botryotinia fuckeliana with H132R amino acid substitution in SdhD;
Corynespora cassiicola having S89P or G109V amino acid substitution in SdhD;
Eurotium oryzae with D124E amino acid substitution in SdhD;
Pyrenophora teres having an amino acid substitution of D124E / N, H134R, G138V or D145G in SdhD;
Sclerotinia sclerotiorum having an amino acid substitution of H132R in SdhD;
Zymoseptoria tritici having an amino acid substitution of I50F, M114V or D129E in SdhD;
Phytophthora capsici with Q1077K or V1109L / M amino acid substitution in CesA3;
Phethophthora drechsleri with V1109L amino acid substitution in CesA3;
Phethophthora infestans having G1105A / V or V1109L amino acid substitution in CesA3;
Plasmopara viticola with G1105S / V amino acid substitution in CesA3;
Pseudoperonospora cubensis having an amino acid substitution of G1105V / W in CesA3;
Alternaria brassicicola with E753K amino acid substitution in OS-1 (Shk1);
Alternaria longipes with G420D amino acid substitution in OS-1 (Shk1);
Botryotinia fuckeliana having an amino acid substitution of I365N / R / S, V368F, Q369H / P, N373S or T447S in OS-1 (Shk1);
Pleospora allii having an amino acid substitution of F267L, L290S, T765R or Q777R in OS-1 (Shk1);
Sclerotinia sclerotiorum having an amino acid substitution of T489I, E599 K or G736Y in OS-1 (Shk1);
ERG27 to S9G, F26S, P57A, T63I, G170R, V192I, L195F, N196T, A210G, I232M, P238S / Δ, P250S, P269L, P298Δ, V309M, A314V, S336C, V365A, E368D, N369D, E375K, A378T, L400F Botryotinia fuckeliana having an amino acid substitution of S, Y408S, F412I / S / V / C, A461S or R496T.

  The composition of the present invention can also control weeds when a herbicidal active ingredient is included as this component. The weed in the present invention means a plant whose growth is not desirable in the place. Examples of weeds include the following.

Nettic Weed (Urticaceae): Urtica urens
Polygonaceae: Polygonum convolvulus, Polygonum lapathifolium, Polygonum pensylvanicum, Polygonum persicaria, Polygonum alist, Polygonum longisetum, Polygonum longisetum, Polygonum longisetum, , Polygonum cuspidatum, Ripex japonicus, Ragex crispus, Rumex obtusifolius, Sorrel (Rumex acetosa)
Physalis Weed (Portulacaceae): Physalis (Portulaca oleracea)
Caryophyllaceae: Stellaria media, Stellaria aquatica, Cerastium holosteoides, Cerastium glomeratum, Spergula arvensis, Mannema (Silene gallica)
Pomegranate Weed (Molluginaceae): Mollugo verticillata
Chiropodiaceae: Chenopodium album, Chenopodium ambrosioides, Kochia scoparia, Salalah kali, Atriplex spp.

Amaranthaceae: Amaranthus retroflexus, Amaranthus viridis, Amaranthus lividus, Amaranthus spinosus, Amaranthus hybridus, Amaranthus hybridus, Palm Amaranthus patulus, water hemp (Amaranthus tuberculatus = Amaranthus rudis = Amaranthus tamariscinus), American marsh (Amaranthus blitoides), Amaranthus deflexus, Amaranthus quatersis (Amaranthus quitentern), Algae phil ), Sanguinaria (Alternanthera tenella)
Poppyaceae: Papaver rhoeas, Papaver dubium, Argemone mexicana
Brassicaceae: Japanese radish (Raphanus raphanistrum), radish (Raphanus sativus), Noragarashi (Sinapis arvensis), Nazuna (Capsella bursa-pastoris), Brassica juncea, Brassica napus (Brassica napus), Brassica napus (Descurainia pinnata), Red-tailed burdock (Rorippa islandica), Red-tailed pebbles (Rorippa sylvestris), Gambina (Thlaspi arvense), Miyagashi (Myagrum rugosum), Laridium virginicum, mus or pus
Capparaceae: Cleome affinis

Legaceae weeds (Fabaceae): Aeschynomene indica, zigzag joint bech (Aeschynomene rudis), Sesbania exaltata, Ebusa (Cassia obtusifolia), Cassia occidentalis, Desmogi (Desmo) adscendens, Desmodium illinoense, White clover (Trifolium repens), Kudu (Pueraria lobata), Vicia angustifolia, Raccoon peas (Indigofera hirsuta), Indigofera truxensis (Indigofera) Vigna sinensis)
Oxalidaceae: Oxalis corniculata, Oxalis strica, Oxalis oxyptera
Geraniaceae: American caroline (Geranium carolinense), Dutch flower (Erodium cicutarium)
Euphorbiaceae: Euphorbia helioscopia, Euphorbia maculata, Euphorbia humistrata, Euphorbia esula, Euphorbia heterophyll, Euphorbia heterophyll (Acalypha australis), Tropic grotulos, Croton lobatus, Phyllanthus corcovadensis, Ricinus communis

Malvaceae: Abutilon theophrasti, Sika rhombiforia, Sida cordifolia, Sida spinosa, Sida glaziovii, Sida santaremnsis ), Ginseng (Hibiscus trionum), Carp (Anoda cristata), Carp (Malvastrum coromandelianum)
Onagraceae: Ludwigia epilobioides, Ludwigia octovalvis, Ludwigia decurre, Oenothera biennis, Oenothera laciniata
Aceraceae weed (Sterculiaceae): Waltheria indica
Violaceae: Makibasmille (Viola arvensis), Wild pansy (Viola tricolor)
Cucurbitaceae: Areciuri (Sicyos angulatus), wild cucumber (Echinocystis lobata), wild bitter gourd (Momordica charantia)
Lythraceae: Ammannia multiflora, Ammannia auriculata, Ammannia coccinea, Lythrum salicaria, Rotala indica
Elephantaceae (Elatinaceae): Elephant triandra, California water wort (Elatine californica)

Apiaceae: Seri (Oenanthe javanica), Nolanin (Daucus carota), Dungin (Conium maculatum)
Araliaceae: Hydrocotyle sibthorpioides, Brazilian Hydrocotyle ranunculoides
Ceratoophyllaceae: Matsumoto (Ceratophyllum demersum)
Cabombaceae: Cabomba caroliniana
Haloragaceae: Myrophyllum aquaticum, Fusamo (Myriophyllum verticillatum), Watermilfoil (Myriophyllum spicatum, Myriophyllum heterophyllum, etc.)
Sapindaceae: Cardiospermum halicacabum
Primulalaceae: Anagallis arvensis
Asperpiadaceae: Milkweed (Asclepias syriaca), Honey Vine Milkweed (Ampelamus albidus)
Rubiaceae: Catchweed Bed Straw (Galium aparine), Yamgra (Galium spurium var. Echinospermon), Spermacoce latifolia, Brazilian Brasiliensis, Wingdphalus buttonweed (Borreria alba)

Convolvulaceae: Japanese morning glory (Ipomoea nil), American morning glory (Ipomoea hederacea), Marva morning glory (Ipomoea purpurea), Malba American morning glory (Ipomoea hederacea var. , Ipomoea acuminata, Ipomoea hederifolia, Ipomoea coccinea, Ipomoea quamoclit, Ipomoea grandifolia (Ipomoea grandifolia ea) , Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis, Convolvulus arvensis a cissoides), Okinawan morning glory (Jacquemontia tamnifolia)
Purple weed (Boraginaceae): Forget-me-not (Myosotis arvensis)
Lamiaceae: Laury purpureum, Lamium amplexicaule, Leonotis nepetaefolia, Hyptis suarolsis (Hyptis loventa), Hyptis lophanta

Solanaceae: Datura stramonium, Solanum nigrum, Solanum americanum, Solanum ptycanthum, Solanum sarrachoum Solanum strata , Goldfish (Solanum aculeatissimum), wild tomato (Solanum sisymbriifolium), varunabi (Solanum carolinense), physalis angulata, smooth ground cherry (Physalis subglabrata), osennari (Nicandra physaloides)
Scrophulariaceae: Veronica hederaefolia, Veronica persica, Veronica arvensis, Azena (Lindernia procumbens), American azena (Lindernia dubia), Alistia rot (Dopatrium junceum), Giant Abnomome (Gratiola japonica),
Plantaginaceae: Plantago asiatica, Plantago lanceolata, Plantago major, Callitriche palustris

  Asteraceae: Xanthium pensylvanicum, Xanthium occidentale, Xanthium italicum, wild sunflower (Helianthus annuus), chamomile (Matricaria chamomilla), dogwood forumata (Matricaria perumata) ), Otricha matricarioides, Artemisia princeps, Artemisia vulgaris, Chinese mugwort (Artemisia verlotorum), Solidago altissima, Solida altissima, Taraxacum officinga (Galinsoga parviflora), Sorgio vulgaris, Senecio brasiliensis, Senecio grisebachii, Conyza bonariensis, Giant cricket (C) onyza smatrensis), Conyza canadensis, Ragweed (Ambrosia artemisiaefolia), Ambrosia trifida, Bidens tripartita, Bidens pilosa, Bidens frondo (Bidens frondo) Spring thistle (Cirsium arvense), American thistle (Cirsium vulgare), Maria thistle (Silybum marianum), Musk thistle (Carduus nutans), Skeletia (Lactuca serriola), Nogeshi (Sonchus oleraceus), Onchose asper (Sonchus asper) Wedelia glauca, Perforate black foot (Melampodium perfoliatum), Emilia sonchifolia, Tagetes minuta, Blainvillea latifolia, Tridax procumbens, Yerba po Rosa (Porophyllum ruderale), Paraguay star bar (Acanthospermum australe), Bristol star bar (Acanthospermum hispidum), Cardiospermum halicacabum, Cuckoo thistle (Ageratum conyzoides), Common bone set (Eupatorium perta alba) , Dendborogiku (Erechtites hieracifolia), American Everlasting (Gamochaeta spicata), Vinelet Pichigusa (Gnaphalium spicatum), Jagelia Hitera (Jaegeria hirta), Sesame (Parthenium hysterophorus), Menamomi (Siegesbeckia or Seriskin serikins) Takasaburo (Eclipta prostrata), American Takasaburo (Eclipta alba), Tokinsou (Centipeda minima),

Osidaceae weeds (Alismataceae): Urikawa (Sagittaria pygmaea), Omodaka (Sagittaria trifolia), Omodaka (Sagittaria sagittifolia), Tilin Omodaka (Sagittaria montevidensis), Aginashi (Sagittaria aginashi), Tulum aquatica)
Limnocharitaceae: Limnocharis flava
Hydrocharitaceae: Frogbit (Limnobium spongia), Black spider (Hydrilla verticillata), Common water nymph (Najas guadalupensis)
Araceae: Button duckweed (Pistia stratiotes)
Duckweed (Lemnaceae): Lemna aoukikusa, Spirodela polyrhiza, Daphnia (Wolffia spp)
Potato getonaceae: Potato geton distinctus, pondweeds (Potamogeton crispus, Potamogeton illinoensis, Stuckenia pectinata, etc.)
Liliaceae: Wild Onion (Allium canadense), Wild Garlic (Allium vineale), Nobil (Allium macrostemon)
Weeping mallow weeds: water hyacinth (Eichhornia crassipes), American oak (Heteranthera limosa), Mizouroi (Monochoria korsakowii), oak (Monochoria vaginalis)
Commelinaceae: Commelina communis, Compositina bengharensis, Electday flower (Commelina erecta), Murdannia keisak

  Poaceae: Echinochloa crus-galli, Echinochloa oryzicola, Echinochloa crus-galli var formosensis, Late watergrass (Echinochloa oryzoides), Echiochloa colonies (Echinochloa colonies) Echinochloa crus-pavonis), Enocorogusa (Setaria viridis), Akinoenokorogusa (Setaria faberi), Echinocholo (Setaria glauca), American Enocorosa (Setaria geniculata), Meishiba (Digitaria ciliaris), Large Crabgrass (Digitaria sanguinalis) Digitaria horizontalis, Gibbon beetle (Digitaria insularis), Bark beetle (Eleusine indica), Sparrow anemone (Poa annua), Poa trivialis, Nagahagusa (Poa pratensis), Algae spp (Alospecurus aequus) opecurus myosuroides, Avena fatua, Sorghum halepense, Shatar cane (Sorghum vulgare), Agropyron repens, Ratium multiflorum, Lolium perenne, Boar, Lolium rigid Bromus catharticus, Bromus sterilis, Bromus japonicus, Bromus secalinus, Bromus tectorum, Hordeum jubatum, Adeilops lins, Aegilops lin Pepper (Phalaris minor), Silky bentgrass (Apera spica-venti), Prickly millet (Panicum dichotomiflorum), Texas panicum (Panicum texanum), Panaxcum (Panicum maximum), Meriken prickly millet (Brachiaria platyphylla), Rugegrass en (Brachiaria ruzi) , Alexandergrass (Brachiaria plantaginea), Surinamegrass (Brachiaria decumbens), Palisadegrass (Brachiaria brizantha), Colombiagrass (Brachiaria humidicola), Cinchrus echinatus, Cenchrus pauciflorus, Narcobienise (Eriochloatum) setosum), African Beard (Chloris gayana), Bearded Sheep (Chlorisvirgata), Elephrostis pilosa, Ruby Gaya (Rhynchelitrum repens), Tatsunosumaya (Dactyloctenium aegyptium), Ischaemum rugo (Ischaemum rugo) Oryza sativa), American spider (Paspalum notatum), coastal sand paspalm (Paspalum maritimum), Kyushu genus (Paspalum distichum), Kennyugrass (Pennisetum clandestinum), Hosobachikara Pennisetum setosum, Rottboellia cochinchinensis, Leptochloa chinensis, Leptochloa fascicularis, Leptochloa filiformis, Lepuscheria leuka, Leptochaia pug , Leersia oryzoides, Glyceria leptorrhiza, Glyceria acutiflora, Glyceria maxima, Agrostis gigantea, Agrostis glontea, Agrostis glontea , Eremochloa ophiuroides, Festuca arundinacea, Festuca rubra, Imperata cylindrica, Miscanthus sinensis, Switchgrass (Panicum virgatum), Bas (Zoysia japonica)

Cyperaceae: Cyperus microiria, Cyperus iria, Cyperus compressus, Cyperus difformis, Cyperus flaccidus, cyperus flaccidus, Cyperus flaccidus (Cyperus odoratus), Cyperus serotinus, Jasper (Cyperus rotundus), Yellow-headed geese (Cyperus esculentus), Kyllinga gracillima, Ida-kug (Kyllinga brevifolia), Hiderico acicularis), Kurowai (Eleocharis kuroguwai), firefly (Schoenoplectiella hotarui), firefly (Schoenoplectiella juncoides), Taiwan Yamai (Schoenoplectiella wallichii), Schoenoplectiella mucronatus, kangaret (Schoenoplectiella triangulatus), pulp (Schoenoplectiella nipponicus), Sankakui (Schoenoplectiella triqueter), Koukiyagara (Bolboschoenus koshevnikovii), Ukiyagara (Bolboschoenus fluviatilis)
Equisetaceae: Equisetum arvense, Equisetum palustre
Salviniaceae: Salvinia natans
Azollaceae: Azolla japonica, Azolla imbricata
Marsileaceae: Marsilea quadrifolia
Others: filamentous algae (Pithophora, Cladophora), mosses, moss, hornworts, cyanobacteria, ferns, perennial crops (fruits, stones, berries, nuts, citrus, hops, grapes, etc.) Sucker.

  About the above weeds, the variation | mutation in a seed | species is not specifically limited. In other words, those having reduced sensitivity to specific herbicides (also called resistance) are also included. The decrease in sensitivity may be due to a mutation at the target site (point of action mutation) or may be due to a factor that is not a point of action mutation (non-point of action mutation). As for the action point mutation, the amino acid substitution in the protein which is the target site due to the mutation of the nucleic acid sequence part (open reading frame) corresponding to the amino acid sequence of the protein, the deletion of the suppressor sequence in the promoter region, the enhancer sequence Those in which the protein at the target site is overexpressed due to mutation such as amplification of the gene or increase in the copy number of the gene. Non-acting point mutations include increased metabolism, malabsorption, migration failure, and out-of-system excretion. Factors that enhance metabolism include those in which the activity of metabolic enzymes such as cytochrome P450 monooxygenase, allyl acylamidase, esterase, and glutathione S-transferase is increased. The out-of-system discharge includes transport to the vacuole by ABC transporter.

Examples of the amino acid substitution at the target site include the following.
ALS: Ala122Thr, Ala122Val, Ala122Tyr, Pro197Ser, Pro197His, Pro197Thr, Pro197Arg, Pro197Leu, Pro197Gln, Pro197Ala, Pro197Ile, Ala205Val, Ala205Phe, Asp376Glu, Arg377His, Trp574Leu, Trp574Gly, Trp574Met, Ser653Thr, Ser653Thr, Ser653Asn, Ser635Ile, Gly654Glu or Gly645Asp;
ACCase: Ile1781Leu, Ile1781Val, Ile1781Thr, Trp1999Cys, Trp1999Leu, Ala2004Val, Trp2027Cys, Ile2041Asn, Ile2041Val, Asp2078Gly or Cys2088Arg;
PPX2: Gly210Δ, Arg98Leu, Arg98Met, Arg98Gly, Arg98His, Gly399Ala;
EPSP: Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu.

  The weeds that can be controlled by the composition of the present invention may have a plurality of the above amino acid substitutions. In this case, the plurality of amino acid substitutions may be the same protein or different proteins. Moreover, you may have two or more non-action point mutations and action point mutations.

Examples of weeds having an action point mutation include the following.
PPG2 has the amino acid substitution of Gly210Δ, Arg98Met, Arg98Gly or Gly399Ala;
Water hemp having an amino acid substitution of Gly210Δ, Arg98Met, Arg98Gly or Gly399Ala in PPX2;
Ragweed having an amino acid substitution of Arg98Leu in PPX2;
Botanus having an amino acid substitution of Arg98His in PPX2;
EPSHI has a cypress having an amino acid substitution of Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu;
EPSP, Baumgi with an amino acid substitution of Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu;
EPSP, Susukishieshiba having an amino acid substitution of Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu;
EPSP has a cypress having an amino acid substitution of Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu;
EPSP with Thr102Ile, Pro106Ser, Pro106Ala or Pro106Leu amino acid substitutions;

  The above-mentioned Daphnia magna, water hemp and ragweed are resistant to PPO inhibitors such as lactofen, fomesafen and flumioxazin.

Other weeds include the following.
An over-expressed EPSP gene results in reduced sensitivity to glyphosate.
Resistant wormwood, oleaginous, and retinoic with reduced sensitivity to glyphosate involving ABC transporters.

  In particular, the composition of the present invention can be effectively controlled against the above-mentioned Daphnia mellitus, Hydrangea, Bakigi, Himemukashimugigi, Giant Olechinogi and Alechinogi.

  Further, the composition of the present invention can effectively control glyphosate-resistant cypress, sagebrush, scallop, squirrel, cybridae, and scallop that have an amino acid substitution of Thr102Ile and Pro106Ser in EPSP.

Hereinafter, although this invention is demonstrated in more detail by a manufacture example, a formulation example, a test example, etc., this invention is not limited only to these examples.
First, the manufacture example of this compound is shown.

Production Example 1
Intermediate 1 of the following formula was produced according to the method described in Synthetic Communications, 2011, 41, 1852-1857. Using Compound 94 described in International Publication No. 2016/121969.
Intermediate 1
¹ H-NMR (CDCl ₃ ) δ: 8.44 (1H, d), 7.99 (1H, d), 7.84 (1H, d), 7.42 (1H, dd), 6.58 (1H, d), 4.56 (2H, t ), 3.34 (2H, q), 1.29 (3H, t).

Production Example 2
A mixture of Intermediate 1 (30 g), acetic acid 60 mL, and N-bromosuccinimide 14 g was stirred at 70 ° C. for 3 hours. To the obtained mixture, 20 mL of 12N aqueous sodium hydroxide solution and 20 mL of saturated aqueous sodium hydrogen sulfite solution were sequentially added. The precipitated solid was filtered, and the obtained solid was washed with water and dried under reduced pressure to obtain 35 g of intermediate 2 represented by the following formula.
Intermediate 2
¹ H-NMR (CDCl ₃ ) δ: 8.46 (1H, d), 8.40 (1H, s), 8.01 (1H, d), 7.42 (1H, dd), 4.56 (2H, dd), 3.33-3.23 (2H , br m), 1.29 (3H, t).

Production Example 3
A mixture of 35 g of Intermediate 2 and 60 mL of phosphorus oxychloride was stirred at 100 ° C. for 9 hours. The obtained mixture was concentrated under reduced pressure, saturated aqueous sodium hydrogen carbonate solution was added to the obtained residue, and the mixture was extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to obtain 35 g of a crude product of Intermediate 3 represented by the following formula.
Intermediate 3
¹ H-NMR (CDCl ₃ ) δ: 8.68 (1H, s), 8.37 (1H, d), 7.93 (1H, d), 7.42 (1H, dd), 4.54 (2H, t), 3.96 (2H, q ), 1.41 (3H, t).

Production Example 4
A mixture of 35 g of the intermediate 3 crude product obtained in Production Example 3, 17.5 g of hydrazine monohydrate, 25 mL of diisopropylethylamine, and 300 mL of THF was stirred at 50 ° C. for 8 hours. The resulting mixture was concentrated under reduced pressure. Water was added to the obtained residue, and the mixture was extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to obtain 33 g of a crude product of intermediate 4 represented by the following formula.
Intermediate 4
¹ H-NMR (CDCl ₃ ) δ: 8.34 (1H, d), 8.34 (1H, s), 7.78 (1H, d), 7.39 (2H, dd), 6.77 (1H, s), 4.57-4.51 (2H m), 3.76 (2H, q), 1.36 (3H, t).

Production Example 5
A mixture of 33 g of the intermediate 4 crude product obtained in Production Example 4, 17 g of p-toluenesulfonic acid chloride, 7.0 mL of pyridine, and 300 mL of acetonitrile was stirred at room temperature for 12 hours. The obtained mixture was concentrated, and 72 mL of ethylene glycol was added to the obtained residue. To this mixture, 40 mL of 8N aqueous sodium hydroxide solution was added and stirred at 80 ° C. for 10 hours. The resulting mixture was extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography to obtain 16 g of Intermediate 5 represented by the following formula.
Intermediate 5
¹ H-NMR (CDCl ₃ ) δ: 8.90 (1H, d), 8.62 (1H, d), 8.37 (1H, d), 7.88 (1H, d), 7.42 (1H, dd), 4.54 (2H, t ), 3.94 (2H, q), 1.40 (3H, t).

Production Example 6
300 mg of Intermediate 5, 160 mg of cyclopropylboronic acid, 550 mg of tripotassium phosphate n-hydrate, 23 mg of [1,1′-bis (diphenylphosphino) ferrocene] dichloropalladium (II), 0.3 mL of water, and A mixture of 3 mL of 1,2-dimethoxyethane was stirred at 100 ° C. for 5 hours. Water was added to the obtained mixture, and the mixture was extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography to obtain 230 mg of the present compound 1 represented by the following formula.
Compound 1
¹ H-NMR (CDCl ₃ ) δ: 8.63 (1H, d), 8.35 (1H, d), 8.05 (1H, d), 7.81 (1H, d), 7.40 (1H, dd), 4.53 (2H, t ), 3.86 (2H, q), 2.10-2.01 (1H, m), 1.36 (3H, t), 1.21-1.14 (2H, m), 0.90-0.85 (2H, m).

Production Example 7-1
To a mixture of 5.16 g of magnesium chloride, 9.15 g of triethylamine, and 24 g of THF, 8.15 g of 1- (ethanesulfonyl) propan-2-one was added at room temperature and stirred for 1 hour. To this mixture, a mixture of 8.0 g of 5-chloropyrazine-2-carbonyl chloride and 8 g of THF was added dropwise over 30 minutes, and the mixture was stirred at room temperature for 3 hours. To this mixture was added 25 g of 13% hydrochloric acid, and the mixture was further stirred for 17 hours. The obtained mixture was extracted with 40 g of toluene, and the organic layer was washed with water and concentrated under reduced pressure. The obtained residue was recrystallized with 8 g of toluene to obtain 9.16 g of intermediate 6 represented by the following formula.
Intermediate 6
¹ H-NMR (CDCl ₃ ) δ: 9.08 (1H, d), 8.70 (1H, d), 4.89 (2H, s), 3.29 (2H, q), 1.48 (3H, t)

Production Example 7-2
The compounds produced according to the method described in Production Example 7-1 and their physical properties are shown below.
Intermediate 7
¹ H-NMR (CDCl ₃ ) δ: 8.90 (1H, d), 8.40 (1H, d), 4.95 (2H, td), 4.88 (2H, s), 3.29 (2H, q), 1.47 (3H, t ).

Production Example 8-1
A mixture of 2.2 g of intermediate 6, 3.4 g of ammonium acetate, and 10 g of methanol was stirred at 70 ° C. for 3 hours. The mixture was cooled to room temperature, water was added, and the mixture was extracted with ethyl acetate. The obtained organic layer was washed with water, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to obtain 1.6 g of intermediate 8 represented by the following formula.
Intermediate 8
¹ H-NMR (DMSO-d6) δ: 9.05 (1H, d), 8.89 (1H, d), 7.01 (2H, br), 5.67 (1H, s), 3.09 (2H, q), 1.23 (3H, t)

Production Example 8-2
The compounds produced according to the method described in Production Example 8-1 and their physical properties are shown below.
Intermediate 9
¹ H-NMR (CDCl ₃ ) δ: 8.52 (1H, d), 8.35 (1H, d), 6.68 (2H, s), 5.34 (1H, s), 4.91 (2H, td), 3.11 (2H, q ), 1.41 (3H, t).

Production Example 9
A mixture of 500 mg of Intermediate 9, 110 mg of sodium hydride (60%, oil), 2-chloro-1,3-bis (dimethylamino) trimethinium hexafluorophosphate, 760 mg, and 3 mL of DMF was stirred at 60 ° C. for 2 hours. Water was added to the obtained mixture, and the mixture was extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography, so as to obtain 260 mg of intermediate 10 represented by the following formula.
Intermediate 10
¹ H-NMR (CDCl ₃ ) δ: 8.84 (1H, d), 8.66 (1H, d), 8.49 (1H, d), 8.33 (1H, d), 4.91 (2H, td), 3.87 (2H, q ), 1.41 (3H, t).

Production Example 10
250 mg of intermediate 10, cyclopropylboronic acid 400 mg, [1,1′-bis (diphenylphosphino) ferrocene] dichloropalladium (II) dichloromethane adduct 21 mg, tripotassium phosphate n-hydrate 670 mg, butyl bis (1 -Adamantyl) A mixture of 21 mg of phosphine, 2.7 mL of 1,2-dimethoxyethane, and 0.3 mL of water was stirred at 100 ° C for 8 hours. The obtained mixture was concentrated under reduced pressure, and the obtained residue was subjected to silica gel chromatography to obtain 40 mg of the present compound 2 represented by the following formula.
Compound 2
¹ H-NMR (CDCl ₃ ) δ: 8.66 (1H, d), 8.60 (1H, d), 8.31 (1H, d), 8.06 (1H, d), 4.90 (2H, t), 3.80 (2H, q ), 2.12-2.01 (1H, m), 1.37 (3H, t), 1.23-1.17 (2H, m), 0.92-0.87 (2H, m).

Production Example 11
9.02 g of 5-bromo-3-chloropyridine-2-carboxylic acid, 9.10 g of 1-ethyl-3- (3-dimethylaminopropyl) carbodiimide hydrochloride, 4.11 g of N, O-dimethylhydroxylamine hydrochloride, To a mixture of 0.93 g of 4- (dimethylamino) pyridine and 100 mL of chloroform, 10.6 mL of triethylamine was added dropwise under ice cooling. After warming to room temperature and stirring for 16 hours, a saturated aqueous sodium hydrogen carbonate solution was added, and the mixture was extracted with chloroform. The obtained organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The obtained residue was subjected to column chromatography to obtain 9.11 g of intermediate 11 represented by the following formula.
Intermediate 11
¹ H-NMR (CDCl ₃ ) δ: 8.57 (1H, d), 7.94 (1H, d), 3.57 (3H, s), 3.40 (3H, s).

Production Example 12
To a mixture of 193 mg of sodium hydride (oil, 60%) and 12 mL of THF, 0.35 mL of ethanethiol was added dropwise under ice cooling, and then a solution of 1 g of intermediate 11 and 3 mL of THF was added dropwise. The mixture was stirred for 1 hour under ice cooling and then stirred overnight at room temperature. Water was added to the obtained mixture, and the mixture was extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate. The obtained organic layer was concentrated under reduced pressure, and the obtained residue was subjected to column chromatography to obtain 0.76 g of intermediate 12 represented by the following formula.
Intermediate 12
¹ H-NMR (CDCl ₃ ) δ: 8.47 (1H, d), 7.84 (1H, d), 3.57 (3H, s), 3.39 (3H, d), 2.96 (2H, q), 1.32 (3H, t ).

Production Example 13
To a mixture of 6.41 g of the intermediate 12 and 100 mL of THF, 9.1 mL of 3M methylmagnesium bromide diethyl ether solution was added dropwise under ice cooling, and the mixture was stirred at room temperature for 1 hour. Saturated aqueous ammonium chloride solution was added to the resulting mixture under ice cooling, and the mixture was extracted with ethyl acetate. The obtained organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to obtain 5.48 g of intermediate 13 represented by the following formula.
Intermediate 13
¹ H-NMR (CDCl ₃ ) δ: 8.41 (1H, d), 7.77 (1H, d), 2.90 (2H, q), 2.68 (3H, s), 1.41 (3H, t).

Production Example 14
To a mixture of 4.89 g of intermediate 13, 3.46 g of glyoxylic acid monohydrate and 40 mL of methanol, 38 mL of 2N aqueous sodium hydroxide solution was added dropwise under ice cooling, and the mixture was stirred at room temperature for 4 hours. The mixture was ice-cooled, and 10 mL of concentrated hydrochloric acid and 4 mL of hydrazine monohydrate were sequentially added. The resulting mixture was stirred at 90 ° C. for 23 hours. The resulting mixture was allowed to cool to room temperature, saturated aqueous ammonium chloride solution was added, and the mixture was extracted with chloroform. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography, and 2.29 g of intermediate 14 represented by the following formula was obtained.
Intermediate 14
¹ H-NMR (CDCl ₃ ) δ: 11.18 (1H, brs), 8.44 (1H, d), 8.13 (1H, d), 7.77 (1H, dd), 7.05 (1H, d), 2.94 (2H, q ), 1.38 (3H, t).

Production Example 15
To a mixture of 6.90 g of intermediate 14 and 40 mL of acetonitrile, 1.5 mL of phosphoryl chloride was added at room temperature and stirred for 2 hours under reflux. The resulting mixture was allowed to cool to room temperature, then added dropwise to saturated multilayer water, and extracted with ethyl acetate. The obtained organic layer was washed successively with water and saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography to obtain 3.98 g of intermediate 15 represented by the following formula.
Intermediate 15
¹ H-NMR (CDCl ₃ ) δ: 8.49 (1H, d), 8.27 (1H, d), 7.87 (1H, d), 7.63 (1H, d), 2.95 (2H, q), 1.37 (3H, t ).

Production Example 16
A mixture of 1.1 g of Intermediate 15, 0.5 mL of 2,2,3,3,3-pentafluoro-1-propanol, 1.6 g of cesium carbonate and 11 mL of DMF was stirred at 60 ° C. for 3 hours. The resulting mixture was allowed to cool to room temperature, water was added, and the mixture was extracted with methyl t-butyl ether. The obtained organic layer was washed successively with water and saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography to obtain 1.5 g of intermediate 16 represented by the following formula.
Intermediate 16
¹ H-NMR (CDCl ₃ ) δ: 8.48 (1H, d), 8.32 (1H, d), 7.85 (1H, d), 7.24 (1H, d), 5.12 (2H, t), 2.96 (2H, q ), 1.38 (3H, t).

Production Example 17
To a mixture of 1.5 g of intermediate 16 and 60 mL of chloroform, 1.8 g of 75% mCPBA was added under ice cooling, and the mixture was stirred for 7 hours. A saturated aqueous sodium hydrogen carbonate solution was added to the obtained mixture, and the mixture was extracted with chloroform. The obtained organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to obtain 1.7 g of intermediate 17 represented by the following formula.
Intermediate 17
¹ H-NMR (CDCl ₃ ) δ: 8.96 (1H, d), 8.66 (1H, d), 7.94 (1H, d), 7.28 (1H, d), 5.08 (2H, t,), 3.91 (2H, q), 1.43 (3H, t).

Production Example 18
A mixture of 1.5 g of intermediate 17, 1.2 g of bis (pinacolato) diboron, 0.12 g of [1,1′-bis (diphenylphosphino) ferrocene] palladium (II) dichloride, 0.95 g of potassium acetate and 11 mL of DMSO. The mixture was stirred at 90 ° C. for 3 hours under a nitrogen atmosphere. Water was added to the obtained mixture at room temperature, and the mixture was extracted with chloroform. The obtained organic layer was washed with saturated brine, dried over anhydrous magnesium sulfate, and concentrated under reduced pressure to obtain 1.2 g of intermediate 18 represented by the following formula.
Intermediate 18
¹ H-NMR (CDCl ₃ ) δ: 9.18 (1H, d), 8.85 (1H, d), 7.95 (1H, d), 7.29 (1H, d), 5.08 (2H, t), 3.85 (2H, q ), 1.42 (3H, t), 1.39 (12H, s).

Production Example 19
A mixture of 1.1 g of intermediate 18, 1.3 g of sodium acetate, 8 mL of THF, 1.2 mL of 30% hydrogen peroxide and 4 mL of water was stirred at 0 ° C. for 4 hours. To the resulting mixture, 20 mL of saturated sodium thiosulfate was added and stirred for 1 hour. Saturated aqueous sodium hydrogen carbonate solution was added to the obtained mixture at room temperature, and the mixture was extracted with chloroform. The obtained organic layer was washed with saturated brine, dried over anhydrous magnesium sulfate, and concentrated under reduced pressure. The obtained residue was subjected to silica gel chromatography, so as to obtain 0.85 g of intermediate 19 represented by the following formula.
Intermediate 19
¹ H-NMR (CDCl ₃ ) δ: 8.51 (1H, d), 7.98 (1H, d), 7.89 (1H, d), 7.26 (1H, d), 5.07 (2H, t), 3.88 (2H, q ), 3.80-3.77 (1H, m), 1.39 (3H, t).

Production Example 20
A mixture of 0.20 g of intermediate 19, 0.12 g of 2-iodopyridine, 0.018 g of copper (I) iodide, 0.03 g of 1-butylimidazole, 0.13 g of potassium carbonate and 2.5 mL of toluene was refluxed. Stir for hours. The resulting mixture was allowed to cool to room temperature, filtered through Celite (registered trademark), and the filtrate was concentrated. The obtained residue was subjected to silica gel chromatography to obtain 0.17 g of the present compound 3 represented by the following formula.
Compound 3
¹ H-NMR (CDCl ₃ ) δ: 8.81 (1H, d), 8.35 (1H, d), 8.19-8.18 (1H, m), 7.95 (1H, d), 7.85-7.79 (1H, m), 7.28 (1H, d), 7.16-7.10 (2H, m), 5.08 (2H, t), 3.91 (2H, q), 1.42 (3H, t).

Production Example 21
The compounds produced according to the method described in Production Example 16 and their physical properties are shown below.
Intermediate 20
¹ H-NMR (CDCl ₃ ) δ: 8.48 (1H, d), 8.31 (1H, d), 7.85 (1H, d), 7.21 (1H, d), 6.11-5.97 (1H, m), 5.05 (2H , tt), 2.96 (2H, q), 1.38 (3H, t).

Production Example 22
The compounds produced according to the method described in Production Example 17 and their physical properties are shown below.
Intermediate 21
¹ H-NMR (CDCl ₃ ) δ: 8.96 (1H, d), 8.66 (1H, d), 7.93 (1H, d), 7.26 (1H, d), 6.18-5.91 (1H, m), 5.01 (2H , t), 3.91 (2H, q), 1.43 (3H, t).

Production Example 23
The compounds produced according to the method described in Production Example 18 and their physical properties are shown below.
Intermediate 22
¹ H-NMR (CDCl ₃ ) δ: 9.17 (1H, d), 8.85 (1H, d), 7.94 (1H, d), 7.25 (1H, d), 6.09-5.99 (1H, m), 5.01 (2H , t), 3.85 (2H, q), 1.42 (3H, t), 1.39 (12H, s).

Production Example 24
The compounds produced according to the method described in Production Example 19 and their physical properties are shown below.
Intermediate 23
¹ H-NMR (CDCl ₃ ) δ: 8.51 (1H, d), 7.99 (1H, d), 7.88 (1H, d), 7.23 (1H, d), 6.09-5.99 (1H, m), 4.99 (2H , t), 3.87 (2H, q), 2.11 (1H, br s), 1.39 (3H, t).

Production Example 25
The compounds produced according to the method described in Production Example 20 and their physical properties are shown below.

Compound 6
¹ H-NMR (CDCl ₃ ) δ: 8.81 (1H, d), 8.35 (1H, d), 8.19-8.18 (1H, m), 7.94 (1H, d), 7.83-7.81 (1H, m), 7.24 (1H, d), 7.16-7.10 (2H, m), 6.10-6.00 (1H, m), 5.04-4.97 (2H, m), 3.91 (2H, q), 1.42 (3H, t).

Compound 4
¹ H-NMR (CDCl ₃ ) δ: 8.80 (1H, d), 8.65 (1H, d), 8.33-8.33 (2H, m), 8.18-8.17 (1H, m), 7.82-7.80 (1H, m) , 7.15-7.10 (2H, m), 4.91 (2H, t), 3.86 (2H, q), 1.40 (3H, t).

Compound 5
¹ H-NMR (CDCl ₃ ) δ: 8.76 (1H, d), 8.37-8.36 (1H, m), 8.31 (1H, d), 8.17-8.16 (1H, m), 7.87 (1H, dd), 7.81 -7.79 (1H, m), 7.42 (1H, dd), 7.12-7.09 (2H, m), 4.54 (2H, t), 3.92 (2H, q), 1.40 (3H, t).

Production Example 26
A mixture of 324 mg of 2- (benzyloxy) -2-propenal and 248 mg of intermediate 8 and 10 mL of ethanol was heated and stirred at 90 ° C. for 12 hours. The obtained mixture was concentrated, a mixture of 229 mg of methanesulfonyl chloride, 405 mg of triethylamine, and 10 mL of chlorobenzene was added, and the mixture was heated to 100 ° C. and stirred for 24 hours. The resulting mixture was concentrated under reduced pressure and purified by silica gel column chromatography to obtain intermediate 24 represented by the following formula.
Intermediate 24
¹ H-NMR (CDCl ₃ ) δ: 8.84 (1H, d), 8.63 (1H, d), 8.55 (1H, d), 8.03 (1H, d), 7.48-7.30 (5H, m), 5.27 (2H , s), 3.84-3.77 (2H, m), 1.32 (3H, t).

Production Example 27
A mixture of 2.0 g of Intermediate 24, 2,2,3,3,3-hexafluoro-1-propanol 0.61 mL, cesium carbonate 2.0 g, and DMF 20 mL was stirred at 40 ° C. for 3 hours. The reaction mixture was added to 1N hydrochloric acid and extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel chromatography to obtain 1.9 g of 1.9 g of intermediate 25.
Intermediate 25
¹ H-NMR (CDCl ₃ ) δ: 8.61 (1H, d), 8.58 (1H, d), 8.30 (1H, d), 8.03 (1H, d), 7.48-7.36 (5H, m), 5.26 (2H , s), 4.89 (2H, t), 3.80 (2H, q), 1.31 (3H, t).

Production Example 28
A mixture of 1.9 g of the intermediate 25 crude product obtained in Production Example 27 and 4 mL of 25% hydrobromic acetic acid solution was stirred at 70 ° C. for 2 hours. Water was added to the obtained mixture, and the mixture was extracted with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel chromatography to obtain 1.0 g of intermediate 26 represented by the following formula.
Intermediate 26
¹ H-NMR (CDCl ₃ ) δ: 8.59 (1H, d), 8.53 (1H, d), 8.30 (1H, d), 7.99 (1H, d), 4.90 (2H, dd), 3.85 (2H, q ), 1.39 (3H, t).

Production Example 29
Intermediate 28 is obtained according to the method described in Production Example 26 using Intermediate 27 instead of Intermediate 8.

Intermediate 27
¹ H-NMR (CDCl ₃ ) δ: 8.37 (1H, d), 7.69 (1H, d), 7.34 (1H, dd), 6.79 (2H, s), 5.28 (1H, s), 4.54 (2H, t ), 3.10 (2H, q), 1.40 (3H, t).

Intermediate 28
¹ H-NMR (CDCl ₃ ) δ: 8.59 (1H, d), 8.33-8.33 (1H, m), 8.03 (1H, d), 7.80-7.78 (1H, m), 7.47-7.38 (6H, m) , 5.25 (2H, s), 4.52 (2H, t), 3.86 (2H, q), 1.32 (3H, t).

Production Example 30
The compounds produced according to the method described in Production Example 27 and their physical properties are shown below.
Intermediate 29
¹ H-NMR (CDCl ₃ ) δ: 8.42 (1H, d), 8.34 (1H, d), 7.92 (1H, d), 7.77 (1H, d), 7.39 (1H, dd), 4.52 (2H, t ), 3.83 (2H, q), 1.36 (3H, t).

Production Example 31
200 mg of Intermediate 17, 134 mg of cyclopropylboronic acid and 331 mg of tripotassium phosphate were dissolved in 1.3 mL of toluene / 0.13 mL of water, and [1,1′-bis (diphenylphosphino) ferrocene] palladium (II) dichloride under a nitrogen atmosphere. 20 mg was added and stirred at 100 ° C. for 5 hours. The resulting mixture was allowed to cool to room temperature and extracted with ethyl acetate. The obtained organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to obtain 190 mg of Compound 7 represented by the following formula.
Compound 7
¹ H-NMR (CDCl ₃ ) δ: 8.67 (1H, d), 8.07 (1H, d), 7.90 (1H, d), 7.26 (1H, d), 5.07 (2H, t), 3.85 (2H, q ), 2.10-2.06 (1H, m), 1.39 (3H, t), 1.25-1.20 (2H, m), 0.93-0.90 (2H, m).

  Examples of the composition A include the following.

In List 1, * represents any one of the present compounds 1-7. Moreover, the number described in [] of each component means the weight part of each component in the composition A.
[List 1]
1: * [2] + Spinetoram [0.5]
2: * [2] + clothianidin [1.5]
3: * [2] + Isotianil [2]
4: * [2] + Frametopil [4]
5: * [2] + Impilfluxam [2]
6: * [2] + Orissatrobin [7]
7: * [2] + spinetoram [0.5] + clothianidin [1.5]
8: * [2] + Spinetoram [0.5] + Isotianil [2]
9: * [2] + Spinetram [0.5] + Flametopill [4]
10: * [2] + Spinetrum [0.5] + Impylfluxam [2]
11: * [2] + Spinetram [0.5] + Orisatrobin [7]
12: * [2] + clothianidin [1.5] + isotianil [2]
13: * [2] + clothianidin [1.5] + furametopir [4]
14: * [2] + clothianidin [1.5] + impylfluxam [2]
15: * [2] + clothianidin [1.5] + orisatrobin [7]
16: * [2] + Isotianil [2] + Frametopyr [4]
17: * [2] + Isotianil [2] + Impylfluxam [2.5]
18: * [2] + spinetoram [0.5] + clothianidin [1.5] + isotianil [2]
19: * [2] + Spinetram [0.5] + Clothianidin [1.5] + Framethopill [4]
20: * [2] + spinetoram [0.5] + clothianidin [1.5] + impylufluxam [2] 21: * [2] + spinetoram [0.5] + isotianil + framtopyr [4]
22: * [2] + spinetoram [0.5] + isotianil [2] + impylfluxam [2]
23: * [2] + clothianidin [1.5] + isotianil [2] + furametopyr [4]
24: * [2] + clothianidin [1.5] + isotianil [2] + impylfluxam [2]
25: * [2] + spinetoram [0.5] + clothianidin [1.5] + isotianil [2] + furametopyr [4]
26: * [2] + spinetoram [0.5] + clothianidin [1.5] + isotianil [2] + impylfluxam [2]
27: * [0.1] + clothianidin [0.5]
28: * [0.1] + Fusaride [1.5]
29: * [0.1] + Validamycin A [0.3]
30: * [0.1] + clothianidin [0.5] + fusaride [1.5]
31: * [0.1] + clothianidin [0.5] + validamycin A [0.3]
32: * [0.1] + Fusaride [1.5] + Validamycin A [0.3]
33: * [0.1] + Ferimzone [2] + Fusaride [1.5]
34: * [0.1] + clothianidin [0.5] + ferrimzone [2] + fusaride [1.5]
35: * [0.1] + clothianidin [0.5] + fusaride [1.5] + validamycin A [0.3]
36: * [0.1] + Ferimzone [2] + Fusaride [1.5] + Validamycin A [0.3]
37: * [0.1] + clothianidin [0.5] + ferrimzone [2] + fusaride [1.5] + validamycin A [0.3]
38: * [5] + clothianidin [6.6]
39: * [5] + Fusaride [20]
40: * [5] + Validamycin A [5]
41: * [5] + clothianidin [6.6] + fusaride [20]
42: * [5] + clothianidin [6.6] + validamycin A [5]
43: * [5] + Fusaride [15] + Ferimzone [15]
44: * [5] + Fusaride [20] + Validamycin A [5]
45: * [5] + clothianidin [6.6] + fusaride [15] + ferrimzone [15]
46: * [5] + clothianidin [6.6] + fusaride [20] + validamycin A [5]
47: * [5] + clothianidin [6.6] + fusaride [15] + ferrimzone [15] + validamycin A [5]
48: * [5] + Azoxystrobin [8]
49: * [5] + clothianidin [6.6] + azoxystrobin [8]
50: * [10] + clothianidin [10]
51: * [10] + Cyantraniprolol [10]
52: * [10] + Bacillus films I-1582 strain [2]
53: * [10] + Pasteuria nisawae Pn1 strain [2]
54: * [10] + Abamectin [10]
55: * [10] + metconazole [2]
56: * [10] + Tebuconazole [2]
57: * [10] + Difenoconazole [2]
58: * [10] + Triticonazole [2]
59: * [10] + Fluquinconazole [2]
60: * [10] + Prothioconazole [2]
61: * [10] + Diniconazole [2]
62: * [10] + Diniconazole M [2]
63: * [10] + ipconazole [2]
64: * [10] + fludioxonil [2]
65: * [10] + Prochloraz [2]
66: * [10] + Chiuram [2]
67: * [10] + thiophanate methyl [10]
68: * [10] + Mandestrobin [2]
69: * [10] + Azoxystrobin [2]
70: * [10] + Fluoxastrobin + [2]
71: * [10] + Trifloxystrobin [2]
72: * [10] + pyraclostrobin [2]
73: * [10] + Torquelofosmethyl [2]
74: * [10] + Tifluzamide [2]
75: * [10] + Penflufen [2]
76: * [10] + Sedaxane [2]
77: * [10] + Floxapyroxide [2]
78: * [10] + full opiram [2]
79: * [10] + ethaboxam [2]
80: * [10] + Impylfluxam [2]
81: * [10] + Metalaxyl [2]
82: * [10] + Metalaxyl M [1]
83: * [10] + Fluopicolide [2]
84: * [10] + Oxathiapiproline [2]
85: * [10] + metconazole [2] + torquelofosmethyl [2] + ethaboxam [2]
86: * [10] + metconazole [2] + torquelofosmethyl [2] + metalaxyl [2]
87: * [10] + metconazole [2] + torquelofosmethyl [2] + metalaxyl M [1]
88: * [10] + metconazole [2] + torquelofos methyl [2] + fluopicolide [2]
89: * [10] + metconazole [2] + torquelofosmethyl [2] + oxathiapiproline [2]
90: * [10] + metconazole [2] + impylfluxam [2] + ethaboxam [2]
91: * [10] + metconazole [2] + impylfluxam [2] + metalaxyl [2]
92: * [10] + metconazole [2] + impylfluxam [2] + metalaxyl M [1]
93: * [10] + metconazole [2] + impylfluxam [2] + fluopicolide [2]
94: * [10] + metconazole [2] + impylfluxam [2] + oxathiapiproline [2]
95: * [10] + metconazole [2] + tifluzamide [2] + ethaboxam [2]
96: * [10] + metconazole [2] + tifluzamide [2] + metalaxyl [2]
97: * [10] + metconazole [2] + tifluzamide [2] + metalaxyl M [1]
98: * [10] + metconazole [2] + tifluzamide [2] + fluopicolide [2]
99: * [10] + metconazole [2] + tifluzamide [2] + oxathiapiproline [2]
100: * [10] + metconazole [2] + penflufen [2] + ethaboxam [2]
101: * [10] + metconazole [2] + penflufen [2] + metalaxyl [2]
102: * [10] + metconazole [2] + penflufen [2] + metalaxyl M [1]
103: * [10] + metconazole [2] + penflufen [2] + fluopicolide [2]
104: * [10] + metconazole [2] + penflufen [2] + oxathiapiproline [2]
105: * [10] + metconazole [2] + sedaxane [2] + ethaboxam [2]
106: * [10] + metconazole [2] + sedaxane [2] + metalaxyl [2]
107: * [10] + metconazole [2] + sedaxane [2] + metalaxyl M [1]
108: * [10] + metconazole [2] + sedaxane [2] + fluopicolide [2]
109: * [10] + metconazole [2] + sedaxane [2] + oxathiapiproline [2]
110: * [10] + metconazole [2] + floxapyroxad [2] + ethaboxam [2]
111: * [10] + metconazole [2] + floxapyroxad [2] + metalaxyl [2]
112: * [10] + metconazole [2] + floxapyroxad [2] + metalaxyl M [1]
113: * [10] + metconazole [2] + floxapyroxad [2] + fluopicolide [2]
114: * [10] + metconazole [2] + floxapyroxad [2] + oxathiapiproline [2]
115: * [10] + metconazole [2] + fluopyram [2] + ethaboxam [2]
116: * [10] + metconazole [2] + fluopyram [2] + metalaxyl [2]
117: * [10] + metconazole [2] + fluopyram [2] + metalaxyl M [1]
118: * [10] + metconazole [2] + fluopyram [2] + fluopicolide [2]
119: * [10] + metconazole [2] + fluopyram [2] + oxathiapiproline [2]
120: * [10] + metconazole [2] + fludioxonil [2] + ethaboxam [2]
121: * [10] + metconazole [2] + fludioxonil [2] + metalaxyl [2]
122: * [10] + metconazole [2] + fludioxonil [2] + metalaxyl M [1]
123: * [10] + metconazole [2] + fludioxonil [2] + fluopicolide [2]
124: * [10] + metconazole [2] + fludioxonyl [2] + oxathiapiproline [2]
125: * [10] + tebuconazole [2] + torquelofosmethyl [2] + ethaboxam [2]
126: * [10] + Tebuconazole [2] + Torquelofosmethyl [2] + Metalaxyl [2]
127: * [10] + Tebuconazole [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
128: * [10] + tebuconazole [2] + torquelofosmethyl [2] + fluopicolide [2]
129: * [10] + tebuconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
130: * [10] + Tebuconazole [2] + Impylfluxam [2] + Etaboxam [2]
131: * [10] + Tebuconazole [2] + Impylfluxam [2] + Metalaxyl [2]
132: * [10] + Tebuconazole [2] + Impylfluxam [2] + Metalaxyl M [1]
133: * [10] + Tebuconazole [2] + Impylfluxam [2] + Fluopicolide [2]
134: * [10] + Tebuconazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
135: * [10] + tebuconazole [2] + tifluzamide [2] + ethaboxam [2]
136: * [10] + Tebuconazole [2] + Tifluzamide [2] + Metalaxyl [2]
137: * [10] + Tebuconazole [2] + Thifluzamide [2] + Metalaxyl M [1]
138: * [10] + Tebuconazole [2] + Tifluzamide [2] + Fluopicolide [2]
139: * [10] + Tebuconazole [2] + Thifluzamide [2] + Oxathiapiproline [2]
140: * [10] + tebuconazole [2] + penflufen [2] + ethaboxam [2]
141: * [10] + Tebuconazole [2] + Penflufen [2] + Metalaxyl [2]
142: * [10] + Tebuconazole [2] + Penflufen [2] + Metalaxyl M [1]
143: * [10] + Tebuconazole [2] + Penflufen [2] + Fluopicolide [2]
144: * [10] + Tebuconazole [2] + Penflufen [2] + Oxathiapiproline [2]
145: * [10] + tebuconazole [2] + sedaxane [2] + ethaboxam [2]
146: * [10] + Tebuconazole [2] + Sedaxane [2] + Metalaxyl [2]
147: * [10] + tebuconazole [2] + sedaxane [2] + metalaxyl M [1]
148: * [10] + Tebuconazole [2] + Sedaxane [2] + Fluopicolide [2]
149: * [10] + tebuconazole [2] + sedaxane [2] + oxathiapiproline [2]
150: * [10] + tebuconazole [2] + floxapyroxad [2] + ethaboxam [2]
151: * [10] + Tebuconazole [2] + Floxapyroxad [2] + Metalaxyl [2]
152: * [10] + Tebuconazole [2] + Floxapyroxad [2] + Metalaxyl M [1]
153: * [10] + Tebuconazole [2] + Floxapyroxad [2] + Fluopicolide [2]
154: * [10] + Tebuconazole [2] + Floxapyroxad [2] + Oxathiapiproline [2]
155: * [10] + tebuconazole [2] + fluopyram [2] + ethaboxam [2]
156: * [10] + Tebuconazole [2] + Fluopyram [2] + Metalaxyl [2]
157: * [10] + Tebuconazole [2] + Fluopyram [2] + Metalaxyl M [1]
158: * [10] + Tebuconazole [2] + Fluopyram [2] + Fluopicolide [2]
159: * [10] + Tebuconazole [2] + Fluopyram [2] + Oxathiapiproline [2]
160: * [10] + tebuconazole [2] + fludioxonil [2] + ethaboxam [2]
161: * [10] + Tebuconazole [2] + Fludioxonyl [2] + Metalaxyl [2]
162: * [10] + Tebuconazole [2] + Fludioxonyl [2] + Metalaxyl M [1]
163: * [10] + Tebuconazole [2] + Fludioxonil [2] + Fluopicolide [2]
164: * [10] + Tebuconazole [2] + Fludioxonyl [2] + Oxathiapiproline [2]
165: * [10] + difenoconazole [2] + tolcrofosmethyl [2] + ethaboxam [2]
166: * [10] + difenoconazole [2] + tolcrofosmethyl [2] + metalaxyl [2]
167: * [10] + difenoconazole [2] + tolcrofosmethyl [2] + metalaxyl M [1]
168: * [10] + difenoconazole [2] + tolcrofosmethyl [2] + fluopicolide [2]
169: * [10] + difenoconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
170: * [10] + Difenoconazole [2] + Impylfluxam [2] + Etaboxam [2]
171: * [10] + Difenoconazole [2] + Impylfluxam [2] + Metalaxyl [2]
172: * [10] + Difenoconazole [2] + Impylfluxam [2] + Metalaxyl M [2]
173: + * [10] + difenoconazole [2] + impylfluxam [2] + fluopicolide [2]
174: * [10] + Difenoconazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
175: * [10] + difenoconazole [2] + tifluzamide [2] + ethaboxam [2]
176: * [10] + difenoconazole [2] + tifluzamide [2] + metalaxyl [2]
177: * [10] + difenoconazole [2] + tifluzamide [2] + metalaxyl M [1]
178: * [10] + difenoconazole [2] + tifluzamide [2] + fluopicolide [2]
179: * [10] + difenoconazole [2] + tifluzamide [2] + oxathiapiproline [2]
180: * [10] + difenoconazole [2] + penflufen [2] + ethaboxam [2]
181: * [10] + difenoconazole [2] + penflufen [2] + metalaxyl [2]
182: * [10] + difenoconazole [2] + penflufen [2] + metalaxyl M [1]
183: * [10] + difenoconazole [2] + penflufen [2] + fluopicolide [2]
184: * [10] + difenoconazole [2] + penflufen [2] + oxathiapiproline [2]
185: * [10] + difenoconazole [2] + sedaxan [2] + ethaboxam [2]
186: * [10] + difenoconazole [2] + sedaxan [2] + metalaxyl [2]
187: * [10] + difenoconazole [2] + sedaxan [2] + metalaxyl M [1]
188: * [10] + Difenoconazole [2] + Sedaxane [2] + Fluopicolide [2]
189: * [10] + difenoconazole [2] + cedaxane [2] + oxathiapiproline [2]
190: * [10] + difenoconazole [2] + floxapyroxad [2] + ethaboxam [2]
191: * [10] + difenoconazole [2] + floxapyroxad [2] + metalaxyl [2]
192: * [10] + difenoconazole [2] + floxapyradod [2] + metalaxyl M [1]
193: * [10] + difenoconazole [2] + floxapyroxad [2] + fluopicolide [2]
194: * [10] + difenoconazole [2] + floxapyroxad [2] + oxathiapiproline [2]
195: * [10] + difenoconazole [2] + fluopyram [2] + ethaboxam [2]
196: * [10] + difenoconazole [2] + fluopyram [2] + metalaxyl [2]
197: * [10] + difenoconazole [2] + fluopyram [2] + metalaxyl M
198: * [10] + difenoconazole [2] + fluopyram [2] + fluopicolide [2]
199: * [10] + difenoconazole [2] + fluopyram [2] + oxathiapiproline [2]
200: * [10] + difenoconazole [2] + fludioxonil [2] + ethaboxam [2]
201: * [10] + difenoconazole [2] + fludioxonil [2] + metalaxyl [2]
202: * [10] + difenoconazole [2] + fludioxonil [2] + metalaxyl M [1]
203: * [10] + difenoconazole [2] + fludioxonil [2] + fluopicolide [2]
204: * [10] + difenoconazole [2] + fludioxonyl [2] + oxathiapiproline [2]
205: * [10] + triticonazole [2] + tolcrofosmethyl [2] + ethaboxam [2]
206: * [10] + Triticonazole [2] + Torcrolophosmethyl [2] + Metalaxyl [2]
207: * [10] + Triticonazole [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
208: * [10] + triticonazole [2] + tolcrofosmethyl [2] + fluopicolide [2]
209: * [10] + triticonazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
210: * [10] + Triticonazole [2] + Impylfluxam [2] + Etaboxam [2]
211: * [10] + Triticonazole [2] + Impylfluxam [2] + Metalaxyl [2]
212: * [10] + Triticonazole [2] + Impylfluxam [2] + Metalaxyl M [1]
213: * [10] + Triticonazole [2] + Impylfluxam [2] + Fluopicolide [2]
214: * [10] + Triticonazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
215: * [10] + Triticonazole [2] + Tifluzamide [2] + Etaboxam [2]
216: * [10] + Triticonazole [2] + Thifluzamide [2] + Metalaxyl [2]
217: * [10] + Triticonazole [2] + Thifluzamide [2] + Metalaxyl M [1]
218: * [10] + Triticonazole [2] + Thifluzamide [2] + Fluopicolide [2]
219: * [10] + Triticonazole [2] + Thifluzamide [2] + Oxathiapiproline [2]
220: * [10] + triticonazole [2] + penflufen [2] + ethaboxam [2]
221: * [10] + Triticonazole [2] + Penflufen [2] + Metalaxyl [2]
222: * [10] + Triticonazole [2] + Penflufen [2] + Metalaxyl M [1]
223: * [10] + triticonazole [2] + penflufen [2] + fluopicolide [2]
224: * [10] + Triticonazole [2] + Penflufen [2] + Oxathiapiproline [2]
225: * [10] + Triticonazole [2] + Sedaxane [2] + Etaboxam [2]
226: * [10] + Triticonazole [2] + Sedaxane [2] + Metalaxyl [2]
227: * [10] + Triticonazole [2] + Sedaxane [2] + Metalaxyl M [1]
228: * [10] + Triticonazole [2] + Sedaxane [2] + Fluopicolide [2]
229: * [10] + Triticonazole [2] + Sedaxane [2] + Oxathiapiproline [2]
230: * [10] + Triticonazole [2] + Floxapyroxad [2] + Etaboxam [2]
231: * [10] + Triticonazole [2] + Floxapyroxad [2] + Metalaxyl [2]
232: * [10] + Triticonazole [2] + Floxapyroxad [2] + Metalaxyl M [1]
233: * [10] + Triticonazole [2] + Floxapyroxad [2] + Fluopicolide [2]
234: * [10] + Triticonazole [2] + Floxapyroxad [2] + Oxathiapiproline [2]
235: * [10] + triticonazole [2] + fluopyram [2] + ethaboxam [2]
236: * [10] + Triticonazole [2] + Fluopyram [2] + Metalaxyl [2]
237: * [10] + Triticonazole [2] + Fluopyram [2] + Metalaxyl M [1]
238: * [10] + Triticonazole [2] + Fluopyram [2] + Fluopicolide [2]
239: * [10] + Triticonazole [2] + Fluopyram [2] + Oxathiapiproline [2]
240: * [10] + triticonazole [2] + fludioxonil [2] + ethaboxam [2]
241: * [10] + Triticonazole [2] + Fludioxonyl [2] + Metalaxyl [2]
242: * [10] + Triticonazole [2] + Fludioxonyl [2] + Metalaxyl M [1]
243: * [10] + Triticonazole [2] + Fludioxonil [2] + Fluopicolide [2]
244: * [10] + Triticonazole [2] + Fludioxonyl [2] + Oxathiapiproline [2]
245: * [10] + Fluquinconazole [2] + Torquelofosmethyl [2] + Etaboxam [2]
246: * [10] + Fluquinconazole [2] + Torquelofosmethyl [2] + Metalaxyl
247: * [10] + Fluquinconazole [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
248: * [10] + fluquinconazole [2] + tolcrofosmethyl [2] + fluopicolide [2]
249: * [10] + fluquinconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
250: * [10] + Fluquinconazole [2] + Impylfluxam [2] + Etaboxam [2]
251: * [10] + Fluquinconazole [2] + Impylfluxam [2] + Metalaxyl [2]
252: * [10] + Fluquinconazole [2] + Impylfluxam [2] + Metalaxyl M [1]
253: * [10] + Fluquinconazole [2] + Impylfluxam [2] + Fluopicolide [2]
254: * [10] + Fluquinconazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
255: * [10] + fluquinconazole [2] + tifluzamide [2] + ethaboxam [2]
256: * [10] + fluquinconazole [2] + tifluzamide [2] + metalaxyl [2]
257: * [10] + Fluquinconazole [2] + Tifluzamide [2] + Metalaxyl M [1]
258: * [10] + Fluquinconazole [2] + Tifluzamide [2] + Fluopicolide [2]
259: * [10] + fluquinconazole [2] + tifluzamide [2] + oxathiapiproline [2]
260: * [10] + fluquinconazole [2] + penflufen [2] + ethaboxam [2]
261: * [10] + fluquinconazole [2] + penflufen [2] + metalaxyl [2]
262: * [10] + fluquinconazole [2] + penflufen [2] + metalaxyl M [1]
263: * [10] + fluquinconazole [2] + penflufen [2] + fluopicolide [2]
264: * [10] + fluquinconazole [2] + penflufen [2] + oxathiapiproline [2]
265: * [10] + Fluquinconazole [2] + Sedaxane [2] + Etaboxam [2]
266: * [10] + Fluquinconazole [2] + Sedaxane [2] + Metalaxyl [2]
267: * [10] + Fluquinconazole [2] + Sedaxane [2] + Metalaxyl M [1]
268: * [10] + fluquinconazole [2] + sedaxane [2] + fluopicolide [2]
269: * [10] + Fluquinconazole [2] + Sedaxane [2] + Oxathiapiproline [2]
270: * [10] + Fluquinconazole [2] + Floxapyroxad [2] + Etaboxam [2]
271: * [10] + Fluquinconazole [2] + Floxapyroxad [2] + Metalaxyl [2]
272: * [10] + Fluquinconazole [2] + Floxapyroxad [2] + Metalaxyl M [1]
273: * [10] + Fluquinconazole [2] + Floxapyroxad [2] + Fluopicolide [2]
274: * [10] + Fluquinconazole [2] + Floxapyroxad [2] + Oxathiapiproline [2]
275: * [10] + fluquinconazole [2] + fluopyram [2] + ethaboxam [2]
276: * [10] + fluquinconazole [2] + fluopyram [2] + metalaxyl [2]
277: * [10] + fluquinconazole [2] + fluopyram [2] + metalaxyl M [1]
278: * [10] + fluquinconazole [2] + fluopyram [2] + fluopicolide [2]
279: * [10] + fluquinconazole [2] + fluopyram [2] + oxathiapiproline [2]
280: * [10] + fluquinconazole [2] + fludioxonil [2] + ethaboxam [2]
281: * [10] + fluquinconazole [2] + fludioxonil [2] + metalaxyl [2]
282: * [10] + fluquinconazole [2] + fludioxonil [2] + metalaxyl M [1]
283: * [10] + fluquinconazole [2] + fludioxonil [2] + fluopicolide [2]
284: * [10] + fluquinconazole [2] + fludioxonil [2] + oxathiapiproline [2]
285: * [10] + prothioconazole [2] + tolcrofosmethyl [2] + ethaboxam [2]
286: * [10] + prothioconazole [2] + tolcrofosmethyl [2] + metalaxyl [2]
287: * [10] + prothioconazole [2] + tolcrofosmethyl [2] + metalaxyl M [1]
288: * [10] + Prothioconazole [2] + Torulofosmethyl [2] + Fluopicolide [2]
289: * [10] + prothioconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
290: * [10] + Prothioconazole [2] + Impylfluxam [2] + Etaboxam [2]
291: * [10] + Prothioconazole [2] + Impylfluxam [2] + Metalaxyl [2]
292: * [10] + Prothioconazole [2] + Impylfluxam [2] + Metalaxyl M [1]
293: * [10] + Prothioconazole [2] + Impylfluxam [2] + Fluopicolide [2]
294: * [10] + Prothioconazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
295: * [10] + prothioconazole [2] + tifluzamide [2] + ethaboxam [2]
296: * [10] + Prothioconazole [2] + Thifluzamide [2] + Metalaxyl [2]
297: * [10] + Prothioconazole [2] + Thifluzamide [2] + Metalaxyl M [1]
298: * [10] + Prothioconazole [2] + Thifluzamide [2] + Fluopicolide [2]
299: * [10] + Prothioconazole [2] + Thifluzamide [2] + Oxathiapiproline [2]
300: * [10] + prothioconazole [2] + penflufen [2] + ethaboxam [2]
301: * [10] + Prothioconazole [2] + Penflufen [2] + Metalaxyl [2]
302: * [10] + Prothioconazole [2] + Penflufen [2] + Metalaxyl M [1]
303: * [10] + prothioconazole [2] + penflufen [2] + fluopicolide [2]
304: * [10] + Prothioconazole [2] + Penflufen [2] + Oxathiapiproline [2]
305: * [10] + Prothioconazole [2] + Sedaxane [2] + Etaboxam [2]
306: * [10] + Prothioconazole [2] + Sedaxane [2] + Metalaxyl [2]
307: * [10] + Prothioconazole [2] + Sedaxane [2] + Metalaxyl M [1]
308: * [10] + Prothioconazole [2] + Sedaxane [2] + Fluopicolide [2]
309: * [10] + Prothioconazole [2] + Sedaxane [2] + Oxathiapiproline [2]
310: * [10] + prothioconazole [2] + floxapyradod [2] + ethaboxam [2]
311: * [10] + Prothioconazole [2] + Floxapyroxad [2] + Metalaxyl [2]
312: * [10] + Prothioconazole [2] + Floxapyroxad [2] + Metalaxyl M
313: * [10] + Prothioconazole [2] + Floxapyroxad [2] + Fluopicolide [2]
314: * [10] + Prothioconazole [2] + Floxapyroxad [2] + Oxathiapiproline [2]
315: * [10] + prothioconazole [2] + fluopyram [2] + ethaboxam [2]
316: * [10] + Prothioconazole [2] + Fluopyram [2] + Metalaxyl [2]
317: * [10] + Prothioconazole [2] + Fluopyram [2] + Metalaxyl M [1]
318: * [10] + Prothioconazole [2] + Fluopyram [2] + Fluopicolide [2]
319: * [10] + Prothioconazole [2] + Fluopyram [2] + Oxathiapiproline [2]
320: * [10] + prothioconazole [2] + fludioxonil [2] + ethaboxam [2]
321: * [10] + Prothioconazole [2] + Fludioxonyl [2] + Metalaxyl [2]
322: * [10] + prothioconazole [2] + fludioxonyl [2] + metalaxyl M [1]
323: * [10] + prothioconazole [2] + fludioxonil [2] + fluopicolide [2]
324: * [10] + Prothioconazole [2] + Fludioxonyl [2] + Oxathiapiproline [2]
325: * [10] + diniconazole [2] + tolcrofosmethyl [2] + ethaboxam [2]
326: * [10] + diniconazole [2] + tolcrofosmethyl [2] + metalaxyl [2]
327: * [10] + diniconazole [2] + tolcrofosmethyl [2] + metalaxyl M [1]
328: * [10] + diniconazole [2] + tolcrofosmethyl [2] + fluopicolide [2]
329: * [10] + diniconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
330: * [10] + Diniconazole [2] + Impylfluxam [2] + Etaboxam [2]
331: * [10] + Diniconazole [2] + Impylfluxam [2] + Metalaxyl [2]
332: * [10] + Diniconazole [2] + Impylfluxam [2] + Metalaxyl M [1]
333: * [10] + Diniconazole [2] + Impylfluxam [2] + Fluopicolide [2]
334: * [10] + Diniconazole [2] + Impylfluxam [2] + Oxathiapiproline [2]
335: * [10] + diniconazole [2] + tifluzamide [2] + ethaboxam [2]
336: * [10] + Diniconazole [2] + Thifluzamide [2] + Metalaxyl [2]
337: * [10] + Diniconazole [2] + Thifluzamide [2] + Metalaxyl M
338: * [10] + Diniconazole [2] + Thifluzamide [2] + Fluopicolide [2]
339: * [10] + Diniconazole [2] + Thifluzamide [2] + Oxathiapiproline [2]
340: * [10] + diniconazole [2] + penflufen [2] + ethaboxam [2]
341: * [10] + Diniconazole [2] + Penflufen [2] + Metalaxyl [2]
342: * [10] + Diniconazole [2] + Penflufen [2] + Metalaxyl M
343: * [10] + diniconazole [2] + penflufen [2] + fluopicolide [2]
344: * [10] + diniconazole [2] + penflufen [2] + oxathiapiproline [2]
345: * [10] + Diniconazole [2] + Sedaxane [2] + Etaboxam [2]
346: * [10] + Diniconazole [2] + Sedaxane [2] + Metalaxyl [2]
347: * [10] + Diniconazole [2] + Sedaxane [2] + Metalaxyl M
348: * [10] + Diniconazole [2] + Sedaxane [2] + Fluopicolide [2]
349: * [10] + Diniconazole [2] + Sedaxane [2] + Oxathiapiproline [2]
350: * [10] + Diniconazole [2] + Floxapyroxad [2] + Etaboxam [2]
351: * [10] + Diniconazole [2] + Floxapyroxad [2] + Metalaxyl [2]
352: * [10] + Diniconazole [2] + Floxapyradod [2] + Metalaxyl M
353: * [10] + Diniconazole [2] + Floxapyroxide [2] + Fluopicolide [2]
354: * [10] + Diniconazole [2] + Floxapyroxad [2] + Oxathiapiproline [2]
355: * [10] + Diniconazole [2] + Fluopyram [2] + Etaboxam [2]
356: * [10] + Diniconazole [2] + Fluopyram [2] + Metalaxyl [2]
357: * [10] + Diniconazole [2] + Fluopyram [2] + Metalaxyl M [1]
358: * [10] + diniconazole [2] + fluopyram [2] + fluopicolide [2]
359: * [10] + diniconazole [2] + fluopyram [2] + oxathiapiproline [2]
360: * [10] + diniconazole [2] + fludioxonil [2] + ethaboxam [2]
361: * [10] + Diniconazole [2] + Fludioxonyl [2] + Metalaxyl [2]
362: * [10] + diniconazole [2] + fludioxonyl [2] + metalaxyl M
363: * [10] + diniconazole [2] + fludioxonil [2] + fluopicolide [2]
364: * [10] + Diniconazole [2] + Fludioxonyl [2] + Oxathiapiproline [2]
365: * [10] + Diniconazole M [2] + Torquelofosmethyl [2] + Etaboxam [2]
366: * [10] + Diniconazole M [2] + Torquelophosmethyl [2] + Metalaxyl [2]
367: * [10] + Diniconazole M [2] + Torquelophosmethyl [2] + Metalaxyl M [1]
368: * [10] + Diniconazole M [2] + Torquelofosmethyl [2] + Fluoropicolide [2]
369: * [10] + Diniconazole M [2] + Torquelophosmethyl [2] + Oxathiapiproline [2]
370: * [10] + Diniconazole M [2] + Impylfluxam [2] + Etaboxam [2]
371: * [10] + Diniconazole M [2] + Impylfluxam [2] + Metalaxyl [2]
372: * [10] + Diniconazole M [2] + Impylfluxam [2] + Metalaxyl M [1]
373: * [10] + Diniconazole M [2] + Impylfluxam [2] + Fluopicolide [2]
374: * [10] + Diniconazole M [2] + Impylfluxam [2] + Oxathiapiproline [2]
375: * [10] + Diniconazole M [2] + Tifluzamide [2] + Etaboxam [2]
376: * [10] + Diniconazole M [2] + Thifluzamide [2] + Metalaxyl [2]
377: * [10] + Diniconazole M [2] + Thifluzamide [2] + Metalaxyl M [1]
378: * [10] + Diniconazole M [2] + Thifluzamide [2] + Fluopicolide [2]
379: * [10] + Diniconazole M [2] + Thifluzamide [2] + Oxathiapiproline [2]
380: * [10] + Diniconazole M [2] + Penflufen [2] + Etaboxam [2]
381: * [10] + Diniconazole M [2] + Penflufen [2] + Metalaxyl [2]
382: * [10] + Diniconazole M [2] + Penflufen [2] + Metalaxyl M [1]
383: * [10] + Diniconazole M [2] + Penflufen [2] + Fluopicolide [2]
384: * [10] + Diniconazole M [2] + Penflufen [2] + Oxathiapiproline [2]
385: * [10] + Diniconazole M [2] + Sedaxane [2] + Etaboxam [2]
386: * [10] + Diniconazole M [2] + Sedaxane [2] + Metalaxyl [2]
387: * [10] + Diniconazole M [2] + Sedaxane [2] + Metalaxyl M [1]
388: * [10] + Diniconazole M [2] + Sedaxane [2] + Fluopicolide [2]
389: * [10] + Diniconazole M [2] + Sedaxane [2] + Oxathiapiproline [2]
390: * [10] + Diniconazole M [2] + Floxapyroxad [2] + Etaboxam [2]
391: * [10] + Diniconazole M [2] + Floxapyroxad [2] + Metalaxyl [2]
392: * [10] + Diniconazole M [2] + Floxapyroxad [2] + Metalaxyl M [1]
393: * [10] + Diniconazole M [2] + Floxapyroxad [2] + Fluopicolide [2]
394: * [10] + Diniconazole M [2] + Floxapyradod [2] + Oxathiapiproline [2]
395: * [10] + Diniconazole M [2] + Fluopyram [2] + Etaboxam [2]
396: * [10] + Diniconazole M [2] + Fluopyram [2] + Metalaxyl [2]
397: * [10] + Diniconazole M [2] + Fluopyram [2] + Metalaxyl M [1]
398: * [10] + Diniconazole M [2] + Fluopyram [2] + Fluopicolide [2]
399: * [10] + Diniconazole M [2] + Fluopyram [2] + Oxathiapiproline [2]
400: * [10] + Diniconazole M [2] + Fludioxonyl [2] + Etaboxam [2]
401: * [10] + Diniconazole M [2] + Fludioxonyl [2] + Metalaxyl [2]
402: * [10] + diniconazole M [2] + fludioxonyl [2] + metalaxyl M [1]
403: * [10] + Diniconazole M [2] + Fludioxonyl [2] + Fluopicolide [2]
404: * [10] + Diniconazole M [2] + Fludioxonyl [2] + Oxathiapiproline [2]
405: * [10] + ipconazole [2] + torquelofosmethyl [2] + ethaboxam [2]
406: * [10] + ipconazole [2] + torquelofosmethyl [2] + metalaxyl [2]
407: * [10] + ipconazole [2] + tolcrofosmethyl [2] + metalaxyl M [1]
408: * [10] + ipconazole [2] + torquelofosmethyl [2] + fluopicolide [2]
409: * [10] + ipconazole [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
410: * [10] + ipconazole [2] + impylfluxam [2] + ethaboxam [2]
411: * [10] + ipconazole [2] + impylfluxam [2] + metalaxyl [2]
412: * [10] + ipconazole [2] + impylfluxam [2] + metalaxyl M [1]
413: * [10] + ipconazole [2] + impylfluxam [2] + fluopicolide [2]
414: * [10] + ipconazole [2] + impylfluxam [2] + oxathiapiproline [2]
415: * [10] + ipconazole [2] + tifluzamide [2] + ethaboxam [2]
416: * [10] + ipconazole [2] + tifluzamide [2] + metalaxyl [2]
417: * [10] + ipconazole [2] + tifluzamide [2] + metalaxyl M [1]
418: * [10] + ipconazole [2] + tifluzamide [2] + fluopicolide [2]
419: * [10] + ipconazole [2] + tifluzamide [2] + oxathiapiproline [2]
420: * [10] + ipconazole [2] + penflufen [2] + ethaboxam [2]
421: * [10] + ipconazole [2] + penflufen [2] + metalaxyl [2]
422: * [10] + ipconazole [2] + penflufen [2] + metalaxyl M [1]
423: * [10] + ipconazole [2] + penflufen [2] + fluopicolide [2]
424: * [10] + ipconazole [2] + penflufen [2] + oxathiapiproline [2]
425: * [10] + ipconazole [2] + sedaxane [2] + ethaboxam [2]
426: * [10] + ipconazole [2] + sedaxane [2] + metalaxyl [2]
427: * [10] + ipconazole [2] + sedaxane [2] + metalaxyl M [1]
428: * [10] + ipconazole [2] + sedaxane [2] + fluopicolide [2]
429: * [10] + ipconazole [2] + sedaxane [2] + oxathiapiproline [2]
430: * [10] + ipconazole [2] + floxapyroxad [2] + ethaboxam [2]
431: * [10] + ipconazole [2] + floxapyroxad [2] + metalaxyl [2]
432: * [10] + ipconazole [2] + floxapyroxad [2] + metalaxyl M [1]
433: * [10] + ipconazole [2] + floxapyroxad [2] + fluopicolide [2]
434: * [10] + ipconazole [2] + floxapyroxad [2] + oxathiapiproline [2]
435: * [10] + ipconazole [2] + fluopyram [2] + ethaboxam [2]
436: * [10] + ipconazole [2] + fluopyram [2] + metalaxyl [2]
437: * [10] + ipconazole [2] + fluopyram [2] + metalaxyl M [1]
438: * [10] + ipconazole [2] + fluopyram [2] + fluopicolide [2]
439: * [10] + ipconazole [2] + fluopyram [2] + oxathiapiproline [2]
440: * [10] + ipconazole [2] + fludioxonil [2] + ethaboxam [2]
441: * [10] + ipconazole [2] + fludioxonil [2] + metalaxyl [2]
442: * [10] + ipconazole [2] + fludioxonil [2] + metalaxyl M [1]
443: * [10] + ipconazole [2] + fludioxonil [2] + fluopicolide [2]
444: * [10] + ipconazole [2] + fludioxonil [2] + oxathiapiproline [2]
445: * [10] + fludioxonil [2] + tolcrofosmethyl [2] + ethaboxam [2]
446: * [10] + fludioxonil [2] + tolcrofosmethyl [2] + metalaxyl [2]
447: * [10] + fludioxonil [2] + tolcrofosmethyl [2] + metalaxyl M [1]
448: * [10] + fludioxonil [2] + tolcrofosmethyl [2] + fluopicolide [2]
449: * [10] + fludioxonil [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
450: * [10] + fludioxonil [2] + impylfluxam [2] + ethaboxam [2]
451: * [10] + fludioxonil [2] + impylfluxam [2] + metalaxyl [2]
452: * [10] + fludioxonil [2] + impylfluxam [2] + metalaxyl M [1]
453: * [10] + fludioxonil [2] + impylfluxam [2] + fluopicolide [2]
454: * [10] + fludioxonil [2] + impylfluxam [2] + oxathiapiproline [2]
455: * [10] + fludioxonil [2] + tifluzamide [2] + ethaboxam [2]
456: * [10] + fludioxonil [2] + tifluzamide [2] + metalaxyl [2]
457: * [10] + fludioxonil [2] + tifluzamide [2] + metalaxyl M [1]
458: * [10] + fludioxonil [2] + tifluzamide [2] + fluopicolide [2]
459: * [10] + fludioxonil [2] + tifluzamide [2] + oxathiapiproline [2]
460: * [10] + fludioxonil [2] + penflufen [2] + ethaboxam [2]
461: * [10] + fludioxonil [2] + penflufen [2] + metalaxyl [2]
462: * [10] + fludioxonil [2] + penflufen [2] + metalaxyl M [1]
463: * [10] + fludioxonil [2] + penflufen [2] + fluopicolide [2]
464: * [10] + fludioxonil [2] + penflufen [2] + oxathiapiproline [2]
465: * [10] + fludioxonil [2] + sedaxane [2] + ethaboxam [2]
466: * [10] + fludioxonil [2] + sedaxane [2] + metalaxyl [2]
467: * [10] + fludioxonyl [2] + sedaxan [2] + metalaxyl M [1]
468: * [10] + fludioxonil [2] + sedaxane [2] + fluopicolide [2]
469: * [10] + fludioxonil [2] + sedaxan [2] + oxathiapiproline [2]
470: * [10] + fludioxonil [2] + floxapyroxad [2] + ethaboxam [2]
471: * [10] + fludioxonil [2] + floxapyroxad [2] + metalaxyl [2]
472: * [10] + fludioxonil [2] + floxapyroxad [2] + metalaxyl M [1]
473: * [10] + fludioxonil [2] + floxapyroxad [2] + fluopicolide [2]
474: * [10] + fludioxonil [2] + floxapyradod [2] + oxathiapiproline [2]
475: * [10] + fludioxonil [2] + fluopyram [2] + ethaboxam [2]
476: * [10] + fludioxonil [2] + fluopyram [2] + metalaxyl [2]
477: * [10] + fludioxonil [2] + fluopyram [2] + metalaxyl M [1]
478: * [10] + fludioxonil [2] + fluopyram [2] + fluopicolide [2]
479: * [10] + fludioxonyl [2] + fluopyram [2] + oxathiapiproline [2]
480: * [10] + Prochloraz [2] + Torquelofosmethyl [2] + Etaboxam [2]
481: * [10] + Prochloraz [2] + Torcrolophosmethyl [2] + Metalaxyl [2]
482: * [10] + Prochloraz [2] + Torquelophosmethyl [2] + Metalaxyl M [1]
483: * [10] + Prochloraz [2] + Torquelofosmethyl [2] + Fluoropicolide [2]
484: * [10] + Prochloraz [2] + Torcrolophosmethyl [2] + Oxathiapiproline [2]
485: * [10] + Prochloraz [2] + Impylfluxam [2] + Etaboxam [2]
486: * [10] + Prochloraz [2] + Impylfluxam [2] + Metalaxyl [2]
487: * [10] + Prochloraz [2] + Impylfluxam [2] + Metalaxyl M [1]
488: * [10] + Prochloraz [2] + Impylfluxam [2] + Fluopicolide [2]
489: * [10] + Prochloraz [2] + Impylfluxam [2] + Oxathiapiproline [2]
490: * [10] + prochloraz [2] + tifluzamide [2] + ethaboxam [2]
491: * [10] + Prochloraz [2] + Tifluzamide [2] + Metalaxyl [2]
492: * [10] + Prochloraz [2] + Tifluzamide [2] + Metalaxyl M [1]
493: * [10] + Prochloraz [2] + Tifluzamide [2] + Fluopicolide [2]
494: * [10] + Prochloraz [2] + Tifluzamide [2] + Oxathiapiproline [2]
495: * [10] + Prochloraz [2] + Penflufen [2] + Etaboxam [2]
496: * [10] + Prochloraz [2] + Penflufen [2] + Metalaxyl [2]
497: * [10] + Prochloraz [2] + Penflufen [2] + Metalaxyl M [1]
498: * [10] + Prochloraz [2] + Penflufen [2] + Fluopicolide [2]
]
499: * [10] + Prochloraz [2] + Penflufen [2] + Oxathiapiproline [2]
500: * [10] + Prochloraz [2] + Sedaxane [2] + Etaboxam [2]
501: * [10] + Prochloraz [2] + Sedaxane + [2] Metalaxyl [2]
502: * [10] + Prochloraz [2] + Sedaxane [2] + Metalaxyl M [1]
503: * [10] + Prochloraz [2] + Sedaxane [2] + Fluopicolide [2]
504: * [10] + Prochloraz [2] + Sedaxane [2] + Oxathiapiproline [2]
505: * [10] + Prochloraz [2] + Floxapyroxad [2] + Etaboxam [2]
506: * [10] + Prochloraz [2] + Floxapyroxad [2] + Metalaxyl [2]
507: * [10] + Prochloraz [2] + Floxapyroxad [2] + Metalaxyl M [1]
508: * [10] + Prochloraz [2] + Floxapyroxad [2] + Fluopicolide [2]
509: * [10] + Prochloraz [2] + Floxapyroxad [2] + Oxathiapiproline [2]
510: * [10] + Prochloraz [2] + Fluopyram [2] + Etaboxam [2]
511: * [10] + Prochloraz [2] + Fluopyram [2] + Metalaxyl [2]
512: * [10] + Prochloraz [2] + Fluopyram [2] + Metalaxyl M [1]
513: * [10] + Prochloraz [2] + Fluopyram [2] + Fluopicolide [2]
514: * [10] + Prochloraz [2] + Fluopyram [2] + Oxathiapiproline [2]
515: * [10] + Prochloraz [2] + Fludioxonil [2] + Etaboxam [2]
516: * [10] + Prochloraz [2] + Fludioxonil [2] + Metalaxyl [2]
517: * [10] + Prochloraz [2] + Fludioxonil [2] + Metalaxyl M [1]
518: * [10] + Prochloraz [2] + Fludioxonil [2] + Fluopicolide [2]
519: * [10] + Prochloraz [2] + Fludioxonyl [2] + Oxathiapiproline [2]
520: * [10] + thiuram [2] + tolcrofosmethyl [2] + ethaboxam [2]
521: * [10] + thiuram [2] + tolcrofosmethyl [2] + metalaxyl [2]
522: * [10] + thiuram [2] + tolcrofosmethyl [2] + metalaxyl M [1]
523: * [10] + thiuram [2] + tolcrofosmethyl [2] + fluopicolide [2]
524: * [10] + thiuram [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
525: * [10] + Thiuram [2] + Impylfluxam [2] + Etaboxam [2]
526: * [10] + Thiuram [2] + Impylfluxam [2] + Metalaxyl [2]
527: * [10] + Thiuram [2] + Impylfluxam [2] + Metalaxyl M [1] [2]
528: * [10] + Thiuram [2] + Impylfluxam [2] + Fluopicolide [2]
529: * [10] + Thiuram [2] + Impylfluxam [2] + Oxathiapiproline [2]
530: * [10] + thiuram [2] + tifluzamide [2] + ethaboxam [2]
531: * [10] + thiuram [2] + tifluzamide [2] + metalaxyl [2]
532: * [10] + thiuram [2] + tifluzamide [2] + metalaxyl M [1] [1]
533: * [10] + thiuram [2] + tifluzamide [2] + fluopicolide [2]
534: * [10] + thiuram [2] + tifluzamide [2] + oxathiapiproline [2]
535: * [10] + thiuram [2] + penflufen [2] + ethaboxam [2]
536: * [10] + thiuram [2] + penflufen [2] + metalaxyl [2]
537: * [10] + thiuram [2] + penflufen [2] + metalaxyl M [1]
538: * [10] + Thiuram [2] + Penflufen [2] + Fluopicolide [2]
539: * [10] + thiuram [2] + penflufen [2] + oxathiapiproline [2]
540: * [10] + thiuram [2] + sedaxan [2] + ethaboxam [2]
541: * [10] + Thiuram [2] + Sedaxane [2] + Metalaxyl [2]
542: * [10] + thiuram [2] + sedaxan [2] + metalaxyl M [1]
543: * [10] + Thiuram [2] + Sedaxane [2] + Fluopicolide [2]
544: * [10] + thiuram [2] + sedaxane [2] + oxathiapiproline [2]
545: * [10] + thiuram [2] + floxapyradod [2] + ethaboxam [2]
546: * [10] + Thiuram [2] + Floxapyroxide [2] + Metalaxyl [2]
547: * [10] + Thiuram [2] + Floxapyradod [2] + Metalaxyl M [1]
548: * [10] + thiuram [2] + floxapyroxide [2] + fluopicolide [2]
549: * [10] + Thiuram [2] + Floxapyroxad [2] + Oxathiapiproline [2]
550: * [10] + thiuram [2] + fluopyram [2] + ethaboxam [2]
551: * [10] + thiuram [2] + fluopyram [2] + metalaxyl [2]
552: * [10] + thiuram [2] + fluopyram [2] + metalaxyl M [1]
553: * [10] + thiuram [2] + fluopyram [2] + fluopicolide [2]
554: * [10] + thiuram [2] + fluopyram [2] + oxathiapiproline [2]
555: * [10] + thiuram [2] + fludioxonil [2] + ethaboxam [2]
556: * [10] + thiuram [2] + fludioxonil [2] + metalaxyl [2]
557: * [10] + thiuram [2] + fludioxonil [2] + metalaxyl M [1]
558: * [10] + thiuram [2] + fludioxonil [2] + fluopicolide [2]
559: * [10] + thiuram [2] + fludioxonyl [2] + oxathiapiproline [2]
560: * [10] + thiophanate methyl [2] + tolcrofos methyl [2] + ethaboxam [2]
561: * [10] + thiophanate methyl [2] + tolcrofos methyl [2] + metalaxyl [2]
562: * [10] + thiophanate methyl [2] + tolcrofos methyl [2] + metalaxyl M [1]
563: * [10] + thiophanate methyl [2] + tolcrofos methyl [2] + fluopicolide [2]
564: * [10] + thiophanate methyl [2] + tolcrofos methyl [2] + oxathiapiproline [2]
565: * [10] + thiophanate methyl [2] + impylfluxam [2] + ethaboxam [2]
566: * [10] + Thiophanate methyl [2] + Impylfluxam [2] + Metalaxyl [2]
567: * [10] + thiophanate methyl [2] + impylfluxam [2] + metalaxyl M [1]
568: * [10] + thiophanate methyl [2] + impylfluxam [2] + fluopicolide [2]
569: * [10] + Thiophanate methyl [2] + Impylfluxam [2] + Oxathiapiproline [2]
570: * [10] + thiophanate methyl [2] + tifluzamide [2] + ethaboxam [2]
571: * [10] + thiophanate methyl [2] + tifluzamide [2] + metalaxyl [2]
572: * [10] + thiophanate methyl [2] + tifluzamide [2] + metalaxyl M [1]
573: * [10] + thiophanate methyl [2] + tifluzamide [2] + fluopicolide [2]
574: * [10] + thiophanate methyl [2] + tifluzamide [2] + oxathiapiproline [2]
575: * [10] + thiophanate methyl [2] + penflufen [2] + ethaboxam [2]
576: * [10] + thiophanate methyl [2] + penflufen [2] + metalaxyl [2]
577: * [10] + thiophanate methyl [2] + penflufen [2] + metalaxyl M [1]
578: * [10] + thiophanate methyl [2] + penflufen [2] + fluopicolide [2]
579: * [10] + thiophanate methyl [2] + penflufen [2] + oxathiapiproline [2]
580: * [10] + thiophanate methyl [2] + sedaxan [2] + ethaboxam [2]
581: * [10] + thiophanate methyl [2] + sedaxane [2] + metalaxyl [2]
582: * [10] + thiophanate methyl [2] + sedaxane [2] + metalaxyl M [1]
583: * [10] + thiophanate methyl [2] + sedaxane [2] + fluorpicolide [2]
584: * [10] + thiophanate methyl [2] + sedaxane [2] + oxathiapiproline [2]
585: * [10] + thiophanate methyl [2] + floxapyroxad [2] + ethaboxam [2]
586: * [10] + thiophanate methyl [2] + floxapyroxad [2] + metalaxyl [2]
587: * [10] + thiophanate methyl [2] + floxapyroxad [2] + metalaxyl M [1]
588: * [10] + thiophanate methyl [2] + floxapyroxad [2] + fluopicolide [2]
589: * [10] + thiophanate methyl [2] + floxapyroxad [2] + oxathiapiproline [2]
590: * [10] + thiophanate methyl [2] + fluopyram [2] + ethaboxam [2]
591: * [10] + thiophanate methyl [2] + fluopyram [2] + metalaxyl [2]
592: * [10] + thiophanate methyl [2] + fluopyram [2] + metalaxyl M [1]
593: * [10] + thiophanate methyl [2] + fluopyram [2] + fluopicolide [2]
594: * [10] + thiophanate methyl [2] + fluopyram [2] + oxathiapiproline [2]
595: * [10] + thiophanate methyl [2] + fludioxonil [2] + ethaboxam [2]
596: * [10] + thiophanate methyl [2] + fludioxonyl [2] + metalaxyl [2]
597: * [10] + thiophanate methyl [2] + fludioxonyl [2] + metalaxyl M [1]
598: * [10] + thiophanate methyl [2] + fludioxonyl [2] + fluopicolide [2]
599: * [10] + thiophanate methyl + fludioxonil + oxathiapiproline
600: * [10] + Mandestrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
601: * [10] + Mandestrobin [2] + Torquelofosmethyl [2] + Metalaxyl [2]
602: * [10] + Mandestrobin [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
603: * [10] + Mandestrobin [2] + Torquelofosmethyl [2] + Fluopicolide [2]
604: * [10] + Mandestrobin [2] + Torquelophosmethyl [2] + Oxathiapiproline [2]
605: * [10] + Mandestrobin [2] + Impylfluxam [2] + Etaboxam [2]
606: * [10] + Mandestrobin [2] + Impylfluxam [2] + Metalaxyl [2]
607: * [10] + Mandestrobin [2] + Impylfluxam [2] + Metalaxyl M [1]
608: * [10] + Mandestrobin [2] + Impylfluxam [2] + Fluopicolide [2]
609: * [10] + Mandestrobin [2] + Impylfluxam [2] + Oxathiapiproline [2]
610: * [10] + Mandestrobin [2] + Tifluzamide [2] + Etaboxam [2]
611: * [10] + Mandestrobin [2] + Thifluzamide [2] + Metalaxyl [2]
612: * [10] + Mandestrobin [2] + Thifluzamide [2] + Metalaxyl M [1]
613: * [10] + Mandestrobin [2] + Thifluzamide [2] + Fluopicolide [2]
614: * [10] + Mandestrobin [2] + Thifluzamide [2] + Oxathiapiproline [2]
615: * [10] + Mandestrobin [2] + Penflufen [2] + Etaboxam [2]
616: * [10] + Mandestrobin [2] + Penflufen [2] + Metalaxyl [2]
617: * [10] + Mandestrobin [2] + Penflufen [2] + Metalaxyl M [1]
618: * [10] + Mandestrobin [2] + Penflufen [2] + Fluopicolide [2]
619: * [10] + Mandestrobin [2] + Penflufen [2] + Oxathiapiproline [2]
620: * [10] + Mandestrobin [2] + Sedaxane [2] + Etaboxam [2]
621: * [10] + Mandestrobin [2] + Sedaxane [2] + Metalaxyl [2]
622: * [10] + Mandestrobin [2] + Sedaxane [2] + Metalaxyl M [1]
623: * [10] + Mandestrobin [2] + Sedaxane [2] + Fluopicolide [2]
624: * [10] + Mandestrobin [2] + Sedaxane [2] + Oxathiapiproline [2]
625: * [10] + Mandestrobin [2] + Floxapyroxad [2] + Etaboxam [2]
626: * [10] + Mandestrobin [2] + Floxapyroxad [2] + Metalaxyl [2]
627: * [10] + Mandestrobin [2] + Floxapyroxad [2] + Metalaxyl M [1]
628: * [10] + Mandestrobin [2] + Floxapyroxad [2] + Fluopicolide [2]
629: * [10] + Mandestrobin [2] + Floxapyroxad [2] + Oxathiapiproline [2]
630: * [10] + mandestrobin [2] + fluopyram [2] + ethaboxam [2]
631: * [10] + Mandestrobin [2] + Fluopyram [2] + Metalaxyl [2]
632: * [10] + Mandestrobin [2] + Fluopyram [2] + Metalaxyl M [1]
633: * [10] + Mandestrobin [2] + Fluopyram [2] + Fluopicolide [2]
634: * [10] + Mandestrobin [2] + Fluopyram [2] + Oxathiapiproline [2]
635: * [10] + mandestrobin [2] + fludioxonil [2] + ethaboxam [2]
636: * [10] + Mandestrobin [2] + Fludioxonil [2] + Metalaxyl [2]
637: * [10] + Mandestrobin [2] + Fludioxonil [2] + Metalaxyl M [1]
638: * [10] + Mandestrobin [2] + Fludioxonil [2] + Fluopicolide [2]
639: * [10] + Mandestrobin [2] + Fludioxonyl [2] + Oxathiapiproline [2]
640: * [10] + Azoxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
641: * [10] + Azoxystrobin [2] + Torquelophosmethyl [2] + Metalaxyl [2]
642: * [10] + Azoxystrobin [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
643: * [10] + Azoxystrobin [2] + Torquelofosmethyl [2] + Fluopicolide [2]
644: * [10] + azoxystrobin [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
645: * [10] + azoxystrobin [2] + impylfluxam [2] + ethaboxam [2]
646: * [10] + Azoxystrobin [2] + Impylfluxam [2] + Metalaxyl [2]
647: * [10] + Azoxystrobin [2] + Impylfluxam [2] + Metalaxyl M [1]
648: * [10] + Azoxystrobin [2] + Impylfluxam [2] + Fluopicolide [2]
649: * [10] + Azoxystrobin [2] + Impylfluxam [2] + Oxathiapiproline [2]
650: * [10] + azoxystrobin [2] + tifluzamide [2] + ethaboxam [2]
651: * [10] + Azoxystrobin [2] + Thifluzamide [2] + Metalaxyl [2]
652: * [10] + Azoxystrobin [2] + Thifluzamide [2] + Metalaxyl M [1]
653: * [10] + Azoxystrobin [2] + Thifluzamide [2] + Fluopicolide [2]
654: * [10] + Azoxystrobin [2] + Thifluzamide [2] + Oxathiapiproline [2]
655: * [10] + azoxystrobin [2] + penflufen [2] + ethaboxam [2]
656: * [10] + azoxystrobin [2] + penflufen [2] + metalaxyl [2]
657: * [10] + Azoxystrobin [2] + Penflufen [2] + Metalaxyl M [1]
658: * [10] + Azoxystrobin [2] + Penflufen [2] + Fluopicolide [2]
659: * [10] + azoxystrobin [2] + penflufen [2] + oxathiapiproline [2]
660: * [10] + azoxystrobin [2] + sedaxan [2] + ethaboxam [2]
661: * [10] + azoxystrobin [2] + sedaxan [2] + metalaxyl [2]
662: * [10] + Azoxystrobin [2] + Sedaxane [2] + Metalaxyl M [1]
663: * [10] + Azoxystrobin [2] + Sedaxane [2] + Fluopicolide [2]
664: * [10] + Azoxystrobin [2] + Sedaxane [2] + Oxathiapiproline [2]
665: * [10] + Azoxystrobin [2] + Floxapyroxad [2] + Etaboxam [2]
666: * [10] + Azoxystrobin [2] + Floxapyroxad [2] + Metalaxyl [2]
667: * [10] + Azoxystrobin [2] + Floxapyradod [2] + Metalaxyl M [1]
668: * [10] + Azoxystrobin [2] + Floxapyroxad [2] + Fluopicolide [2]
669: * [10] + Azoxystrobin [2] + Floxapyradod [2] + Oxathiapiproline [2]
670: * [10] + azoxystrobin [2] + fluopyram [2] + ethaboxam [2]
671: * [10] + Azoxystrobin [2] + Fluopyram [2] + Metalaxyl [2]
672: * [10] + Azoxystrobin [2] + Fluopyram [2] + Metalaxyl M [1]
673: * [10] + Azoxystrobin [2] + Fluopyram [2] + Fluopicolide [2]
674: * [10] + Azoxystrobin [2] + Fluopyram [2] + Oxathiapiproline [2]
675: * [10] + azoxystrobin [2] + fludioxonil [2] + ethaboxam [2]
676: * [10] + azoxystrobin [2] + fludioxonil [2] + metalaxyl [2]
677: * [10] + azoxystrobin [2] + fludioxonil [2] + metalaxyl M [1]
678: * [10] + azoxystrobin [2] + fludioxonil [2] + fluopicolide [2]
679: * [10] + Azoxystrobin [2] + Fludioxonyl [2] + Oxathiapiproline [2]
680: * [10] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
681: * [10] + Fluoxastrobin [2] + Torquelofosmethyl [2] + Metalaxyl [2]
682: * [10] + fluoxastrobin [2] + tolcrofosmethyl [2] + metalaxyl M [1]
683: * [10] + fluoxastrobin [2] + tolcrofosmethyl [2] + fluopicolide
684: * [10] + fluoxastrobin [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
685: * [10] + Fluoxastrobin [2] + Impylfluxam [2] + Etaboxam [2]
686: * [10] + Fluoxastrobin [2] + Impylfluxam [2] + Metalaxyl [2]
687: * [10] + Fluoxastrobin [2] + Impylfluxam [2] + Metalaxyl M [1]
688: * [10] + Fluoxastrobin [2] + Impylfluxam [2] + Fluopicolide [2]
689: * [10] + Fluoxastrobin [2] + Impylfluxam [2] + Oxathiapiproline [2]
690: * [10] + fluoxastrobin [2] + tifluzamide [2] + ethaboxam [2]
691: * [10] + Fluoxastrobin [2] + Thifluzamide [2] + Metalaxyl [2]
692: * [10] + Fluoxastrobin [2] + Thifluzamide [2] + Metalaxyl M [1]
693: * [10] + fluoxastrobin [2] + tifluzamide [2] + fluopicolide [2]
694: * [10] + Fluoxastrobin [2] + Thifluzamide [2] + Oxathiapiproline [2]
695: * [10] + fluoxastrobin [2] + penflufen [2] + ethaboxam [2]
696: * [10] + Fluoxastrobin [2] + Penflufen [2] + Metalaxyl [2]
697: * [10] + Fluoxastrobin [2] + Penflufen [2] + Metalaxyl M [1]
698: * [10] + Fluoxastrobin [2] + Penflufen [2] + Fluopicolide [2]
699: * [10] + Fluoxastrobin [2] + Penflufen [2] + Oxathiapiproline [2]
700: * [10] + Fluoxastrobin [2] + Sedaxane [2] + Etaboxam [2]
701: * [10] + Fluoxastrobin [2] + Sedaxane [2] + Metalaxyl [2]
702: * [10] + Fluoxastrobin [2] + Sedaxane [2] + Metalaxyl M [1]
703: * [10] + Fluoxastrobin [2] + Sedaxane [2] + Fluopicolide [2]
704: * [10] + Fluoxastrobin [2] + Sedaxane [2] + Oxathiapiproline [2]
705: * [10] + Fluoxastrobin [2] + Floxapyroxad [2] + Etaboxam [2]
706: * [10] + Fluoxastrobin [2] + Floxapyroxad [2] + Metalaxyl [2]
707: * [10] + Fluoxastrobin [2] + Floxapyroxad [2] + Metalaxyl M [1]
708: * [10] + Fluoxastrobin [2] + Floxapyroxad [2] + Fluopicolide [2]
709: * [10] + Fluoxastrobin [2] + Floxapyroxad [2] + Oxathiapiproline [2]
710: * [10] + fluoxastrobin [2] + fluopyram [2] + ethaboxam [2]
711: * [10] + fluoxastrobin [2] + fluopyram [2] + metalaxyl [2]
712: * [10] + Fluoxastrobin [2] + Fluopyram [2] + Metalaxyl M [1]
[2]
713: * [10] + Fluoxastrobin [2] + Fluopyram + Fluopicolide
[2]
714: * [10] + Fluoxastrobin [2] + Fluopyram [2] + Oxathiapiproline [2]
715: * [10] + fluoxastrobin [2] + fludioxonil [2] + ethaboxam [2]
716: * [10] + Fluoxastrobin [2] + Fludioxonil [2] + Metalaxyl [2]
717: * [10] + fluoxastrobin [2] + fludioxonil [2] + metalaxyl M [1]
718: * [10] + Fluoxastrobin [2] + Fludioxonil [2] + Fluopicolide [2]
719: * [10] + Fluoxastrobin [2] + Fludioxonyl [2] + Oxathiapiproline [2]
720: * [10] + Trifloxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
721: * [10] + Trifloxystrobin [2] + Torquelofosmethyl [2] + Metalaxyl [2]
722: * [10] + Trifloxystrobin [2] + Torquelofosmethyl [2] + Metalaxyl M [1]
723: * [10] + Trifloxystrobin [2] + Torquelofosmethyl [2] + Fluopicolide [2]
724: * [10] + Trifloxystrobin [2] + Torquelophosmethyl [2] + Oxathiapiproline [2]
725: * [10] + Trifloxystrobin [2] + Impylfluxam [2] + Etaboxam [2]
726: * [10] + Trifloxystrobin [2] + Impylfluxam [2] + Metalaxyl [2]
727: * [10] + Trifloxystrobin [2] + Impylfluxam [2] + Metalaxyl M [1]
728: * [10] + Trifloxystrobin [2] + Impylfluxam [2] + Fluopicolide [2]
729: * [10] + Trifloxystrobin [2] + Impylfluxam [2] + Oxathiapiproline [2]
730: * [10] + Trifloxystrobin [2] + Tifluzamide [2] + Etaboxam [2]
731: * [10] + Trifloxystrobin [2] + Tifluzamide [2] + Metalaxyl [2]
732: * [10] + Trifloxystrobin [2] + Tifluzamide [2] + Metalaxyl M [1]
733: * [10] + trifloxystrobin [2] + tifluzamide [2] + fluopicolide [2]
734: * [10] + Trifloxystrobin [2] + Tifluzamide [2] + Oxathiapiproline [2]
735: * [10] + trifloxystrobin [2] + penflufen [2] + ethaboxam [2]
736: * [10] + Trifloxystrobin [2] + Penflufen [2] + Metalaxyl [2]
737: * [10] + Trifloxystrobin [2] + Penflufen [2] + Metalaxyl M [1]
738: * [10] + Trifloxystrobin [2] + Penflufen [2] + Fluopicolide [2]
739: * [10] + Trifloxystrobin [2] + Penflufen [2] + Oxathiapiproline [2]
740: * [10] + Trifloxystrobin [2] + Sedaxane [2] + Etaboxam [2]
741: * [10] + Trifloxystrobin [2] + Sedaxane [2] + Metalaxyl [2]
742: * [10] + Trifloxystrobin [2] + Sedaxane [2] + Metalaxyl M [1]
743: * [10] + Trifloxystrobin [2] + Sedaxane [2] + Fluopicolide [2]
744: * [10] + Trifloxystrobin [2] + Sedaxane [2] + Oxathiapiproline [2]
745: * [10] + Trifloxystrobin [2] + Floxapyroxad [2] + Etaboxam [2]
746: * [10] + Trifloxystrobin [2] + Floxapyroxad [2] + Metalaxyl [2]
747: * [10] + Trifloxystrobin [2] + Floxapyroxad [2] + Metalaxyl M [1]
748: * [10] + Trifloxystrobin [2] + Floxapyroxad [2] + Fluopicolide [2]
749: * [10] + Trifloxystrobin [2] + Floxapyroxad [2] + Oxathiapiproline [2]
750: * [10] + trifloxystrobin [2] + fluopyram [2] + ethaboxam [2]
751: * [10] + Trifloxystrobin [2] + Fluopyram [2] + Metalaxyl [2]
752: * [10] + Trifloxystrobin [2] + Fluopyram [2] + Metalaxyl M [1]
753: * [10] + Trifloxystrobin [2] + Fluopyram [2] + Fluopicolide [2]
754: * [10] + Trifloxystrobin [2] + Fluopyram [2] + Oxathiapiproline [2]
755: * [10] + trifloxystrobin [2] + fludioxonil [2] + ethaboxam [2]
756: * [10] + Trifloxystrobin [2] + Fludioxonil [2] + Metalaxyl [2]
757: * [10] + Trifloxystrobin [2] + Fludioxonil [2] + Metalaxyl M [1]
758: * [10] + Trifloxystrobin [2] + Fludioxonil [2] + Fluopicolide [2]
759: * [10] + Trifloxystrobin [2] + Fludioxonil [2] + Oxathiapiproline [2]
760: * [10] + pyraclostrobin [2] + torquelofosmethyl [2] + ethaboxam [2]
761: * [10] + pyraclostrobin [2] + torquelofosmethyl [2] + metalaxyl [2]
762: * [10] + pyraclostrobin [2] + tolcrofosmethyl [2] + metalaxyl M [1]
763: * [10] + pyraclostrobin [2] + torquelofosmethyl [2] + fluopicolide [2]
764: * [10] + pyraclostrobin [2] + tolcrofosmethyl [2] + oxathiapiproline [2]
765: * [10] + pyraclostrobin [2] + impylfluxam [2] + ethaboxam [2]
766: * [10] + pyraclostrobin [2] + impylfluxam + [2] metalaxyl [2]
767: * [10] + Pyraclostrobin [2] + Impylfluxam + [2] Metalaxyl M [1]
768: * [10] + pyraclostrobin [2] + impylfluxam [2] + fluopicolide [2]
769: * [10] + pyraclostrobin [2] + impylfluxam [2] + oxathiapiproline [2]
770: * [10] + pyraclostrobin [2] + tifluzamide [2] + ethaboxam [2]
771: * [10] + pyraclostrobin [2] + tifluzamide [2] + metalaxyl [2]
772: * [10] + pyraclostrobin [2] + tifluzamide [2] + metalaxyl M [1]
773: * [10] + pyraclostrobin [2] + tifluzamide [2] + fluopicolide [2]
774: * [10] + pyraclostrobin [2] + tifluzamide [2] + oxathiapiproline [2]
775: * [10] + pyraclostrobin [2] + penflufen [2] + ethaboxam [2]
776: * [10] + pyraclostrobin [2] + penflufen [2] + metalaxyl [2]
777: * [10] + pyraclostrobin [2] + penflufen [2] + metalaxyl M [1]
778: * [10] + pyraclostrobin [2] + penflufen [2] + fluopicolide [2]
779: * [10] + pyraclostrobin [2] + penflufen [2] + oxathiapiproline [2]
780: * [10] + pyraclostrobin [2] + sedaxane [2] + ethaboxam [2]
781: * [10] + pyraclostrobin [2] + sedaxane [2] + metalaxyl [2]
782: * [10] + pyraclostrobin [2] + sedaxane [2] + metalaxyl M [1]
783: * [10] + pyraclostrobin [2] + sedaxane [2] + fluopicolide [2]
784: * [10] + pyraclostrobin [2] + sedaxane [2] + oxathiapiproline [2]
785: * [10] + pyraclostrobin [2] + floxapyroxad [2] + ethaboxam [2]
786: * [10] + pyraclostrobin [2] + floxapyroxad [2] + metalaxyl [2]
787: * [10] + pyraclostrobin [2] + floxapyroxad [2] + metalaxyl M [1]
788: * [10] + pyraclostrobin [2] + floxapyroxad [2] + fluopicolide [2]
789: * [10] + pyraclostrobin [2] + floxapyroxad [2] + oxathiapiproline [2]
790: * [10] + pyraclostrobin [2] + fluopyram [2] + ethaboxam [2]
791: * [10] + pyraclostrobin [2] + fluopyram [2] + metalaxyl [2]
792: * [10] + pyraclostrobin [2] + fluopyram [2] + metalaxyl M [1]
793: * [10] + pyraclostrobin [2] + fluopyram [2] + fluopicolide [2]
794: * [10] + pyraclostrobin [2] + fluopyram [2] + oxathiapiproline [2]
795: * [10] + pyraclostrobin [2] + fludioxonil + [2] ethaboxam [2]
796: * [10] + pyraclostrobin [2] + fludioxonil [2] + metalaxyl [2]
797: * [10] + pyraclostrobin [2] + fludioxonil [2] + metalaxyl M [1]
798: * [10] + pyraclostrobin [2] + fludioxonil [2] + fluopicolide [2]
799: * [10] + pyraclostrobin [2] + fludioxonil [2] + oxathiapiproline [2]
800: * [10] + metconazole [2] + mandestrobin [2] + torquelofosmethyl [2] + ethaboxam [2]
801: * [10] + metconazole [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
802: * [10] + metconazole [2] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
803: * [10] + metconazole [2] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
804: * [10] + metconazole [2] + pyraclostrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
805: * [10] + tebuconazole [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
806: * [10] + tebuconazole [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
807: * [10] + Tebuconazole [2] + Fluoxastrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
808: * [10] + tebuconazole [2] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
809: * [10] + tebuconazole + pyraclostrobin + tolcrofos methyl + ethaboxam
810: * [10] + difenoconazole [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
811: * [10] + difenoconazole [2] + azoxystrobin + [2] tolcrofosmethyl [2] + ethaboxam [2]
812: * [10] + difenoconazole [2] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
813: * [10] + difenoconazole [2] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
814: * [10] + difenoconazole [2] + pyraclostrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
815: * [10] + Triticonazole [2] + Mandestrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
816: * [10] + Triticonazole [2] + Azoxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
817: * [10] + Triticonazole + Fluoxastrobin + Torquelofos methyl + Etaboxam
818: * [10] + Triticonazole [2] + Trifloxystrobin [2] + Torcrolophosmethyl [2] + Etaboxam [2]
819: * [10] + Triticonazole [2] + Pyraclostrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
820: * [10] + fluquinconazole [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
821: * [10] + Fluquinconazole [2] + Azoxystrobin [2] + Torcrolophosmethyl [2] + Etaboxam [2]
822: * [10] + fluquinconazole [2] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
823: * [10] + Fluquinconazole [2] + Trifloxystrobin [2] + Torcrolophosmethyl [2] + Etaboxam [2]
824: * [10] + Fluquinconazole [2] + Pyraclostrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
825: * [10] + prothioconazole + mandestrobin + tolcrofos methyl + ethaboxam
826: * [10] + prothioconazole [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
827: * [10] + Prothioconazole [2] + Fluoxastrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
828: * [10] + prothioconazole + trifloxystrobin + tolcrofosmethyl + ethaboxam
829: * [10] + prothioconazole [2] + pyraclostrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
830: * [10] + Diniconazole [2] + Mandestrobin + [2] Torquelophosmethyl [2] + Etaboxam [2]
831: * [10] + Diniconazole [2] + Azoxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
832: * [10] + Diniconazole [2] + Fluoxastrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
833: * [10] + diniconazole [2] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
834: * [10] + diniconazole [2] + pyraclostrobin [2] + torquelofosmethyl [2] + ethaboxam [2]
835: * [10] + Diniconazole M [2] + Mandestrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
836: * [10] + Diniconazole M [2] + Azoxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
837: * [10] + Diniconazole M [2] + Fluoxastrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
838: * [10] + Diniconazole M [2] + Trifloxystrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
839: * [10] + Diniconazole M [2] + Pyraclostrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
840: * [10] + ipconazole [2] + mandestrobin [2] + torquelophosmethyl [2] + ethaboxam [2]
841: * [10] + ipconazole [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
842: * [10] + ipconazole [3] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
843: * [10] + ipconazole [3] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
844: * [10] + ipconazole [4] + pyraclostrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
845: * [10] + fludioxonil [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
846: * [10] + fludioxonil [2] + azoxystrobin [2] + torquelophosmethyl [2] + ethaboxam [2]
847: * [10] + fludioxonil [3] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
848: * [10] + fludioxonil [3] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
849: * [10] + fludioxonil [4] + pyraclostrobin [2] + torquelophosmethyl [2] + ethaboxam [2]
850: * [10] + Prochloraz [2] + Mandestrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
851: * [10] + Prochloraz [2] + Azoxystrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
852: * [10] + Prochloraz [3] + Fluoxastrobin [2] + Torquelofosmethyl [2] + Etaboxam [2]
853: * [10] + Prochloraz [3] + Trifloxystrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
854: * [10] + Prochloraz [4] + Pyraclostrobin [2] + Torcrolofosmethyl [2] + Etaboxam [2]
855: * [10] + thiuram [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
856: * [10] + thiuram [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
857: * [10] + thiuram [3] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
858: * [10] + thiuram [3] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
859: * [10] + thiuram [4] + pyraclostrobin [2] + torquelofosmethyl [2] + ethaboxam [2]
860: * [10] + thiophanate methyl [2] + mandestrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
861: * [10] + thiophanate methyl [2] + azoxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
865: * [10] + thiophanate methyl [3] + fluoxastrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
863: * [10] + thiophanate methyl [3] + trifloxystrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]
864: * [10] + thiophanate methyl [4] + pyraclostrobin [2] + tolcrofosmethyl [2] + ethaboxam [2]

Furthermore, the specific example of a composition A is shown below.
Composition A described in [Table A] is a composition composed of each component described in [Table A]. In [Table A], * described in the column for component 1 is the present compound. 1 represents any one of 1-7, and the number described in [] in the column of each component means the weight part of each component. Moreover, the composition A described in [Table A] is represented with the number described in [Table A], and for example, the composition 1 refers to the composition A described in number 1 of [Table A]. α1 means impylufluxam.

[Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Continuation of [Table A]

Compositions 841-1680
In each of the compositions 1 to 840 described in [Table A], a composition using 2 parts of tebuconazole instead of 2 parts of metconazole.

Composition 1681-2520
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of difenoconazole instead of 2 parts of metconazole.

Compositions 2521-360
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of triticonazole instead of 2 parts of metconazole.

Compositions 3361-4200
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of prothioconazole instead of 2 parts of metconazole.

Compositions 4201-5040
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of diniconazole instead of 2 parts of metconazole.

Compositions 5041-5880
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of diniconazole instead of 2 parts of metconazole.

Composition 5881-6720
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of ipconazole instead of 2 parts of metconazole.

Compositions 6721-7560
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of prochloraz instead of 2 parts of metconazole.

Compositions 7561-8400
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of fluquinconazole instead of 2 parts of metconazole.

Composition 8401-9240
In each of Compositions 1 to 840 described in [Table A], a composition using 2 parts of triazimenol instead of 2 parts of metconazole.

Compositions A1-A9240
A composition obtained by adding 10 parts of clothianidin and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions B1-B9240
A composition obtained by further adding 10 parts clothianidin and 10 parts cyantraniliprole to each of the above compositions 1 to 9240.

Compositions C1-C9240
A composition obtained by adding 10 parts of clothianidin and 10 parts of fipronil to each of the above compositions 1 to 9240.

Compositions D1-D9240
A composition obtained by adding 10 parts of imidacloprid and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions E1-E9240
A composition obtained by further adding 10 parts of imidacloprid and 10 parts of cyantraniliprole to each of the above compositions 1 to 9240.

Compositions F1-F9240
A composition obtained by adding 10 parts of imidacloprid and 10 parts of fipronil to each of the above compositions 1 to 9240.

Compositions G1-G9240
A composition obtained by adding 10 parts of thiamethoxam and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions H1-H9240
A composition obtained by adding 10 parts of thiamethoxam and 10 parts of cyantraniliprol to each of the above compositions 1 to 9240.

Compositions I1-I9240
A composition obtained by adding 10 parts of thiamethoxam and 10 parts of fipronil to each of the above compositions 1 to 9240 (provided that the composition is 100 parts).

Compositions J1 to J9240
A composition obtained by adding 10 parts of thiacloprid and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions K1 to K9240
A composition obtained by further adding 10 parts of thiacloprid and 10 parts of cyantraniliprole to each of the above compositions 1 to 9240.

Compositions L1-L9240
A composition obtained by adding 10 parts of thiacloprid and 10 parts of fipronil to each of the above compositions 1 to 9240.

Compositions M1-M9240
A composition obtained by adding 10 parts of flupiradifuron and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions N1-N9240
A composition obtained by adding 10 parts of flupiradifuron and 10 parts of cyantraniliprol to each of the above compositions 1 to 9240.

Compositions O1-O9240
A composition obtained by further adding 10 parts of flupiradiflon and 10 parts of fipronil to each of the above compositions 1 to 9240.

Compositions P1-P9240
A composition obtained by adding 20 parts of clothianidin to each of the above compositions 1 to 9240.

Compositions Q1-Q9240
A composition obtained by adding 10 parts of flupirmine and 10 parts of chlorantraniliprol to each of the above compositions 1 to 9240.

Compositions R1-R9240
A composition in which 10 parts of flupyrimine and 10 parts of cyantraniliprole are further added to each of the above compositions 1 to 9240.

Compositions S1-S9240
A composition obtained by adding 10 parts of flupirmine and 10 parts of fipronil to each of the above compositions 1 to 9240.

Next, formulation examples are shown.
In addition, MX is composition 1-9240, composition A1-A9240, composition B1-B9240, composition C1-C9240, composition D1-D9240, composition E1-E9240, composition F1-F9240, composition G1. ~ G9240, Compositions H1 to H9240, Compositions I1 to I9240, Compositions J1 to J9240, Compositions K1 to K9240, Compositions L1 to L9240, Compositions M1 to M9240, Compositions N1 to N9240, Compositions O1 to O9240 , Compositions P1 to P9240, Compositions Q1 to Q9240, Compositions R1 to R9240, and Compositions S1 to S9240 means any one composition A.

Formulation Example 1
40 parts of any one of the present compounds 1 to 7, or 40 parts of MX, 35 parts of a mixture of white carbon and polyoxyethylene alkyl ether sulfate ammonium salt (weight ratio 1: 1) and 25 parts of water are added, Each formulation is obtained by mixing.

Formulation Example 2
40 parts of any one of the present compounds 1 to 7, or 40 parts of MX, 3 parts of calcium lignin sulfonate, 2 parts of sodium lauryl sulfate, and 55 parts of synthetic silicon hydroxide are added and mixed to prepare each preparation. obtain.

Formulation Example 3
40 parts of any one of the present compounds 1 to 7, or 40 parts of MX, 15 parts of a mixture of white carbon and polyoxyethylene alkyl ether sulfate ammonium salt (weight ratio 1: 1) and 45 parts of water are added, Each formulation is obtained by mixing.

Formulation Example 4
20 parts of any one of the present compounds 1 to 7, or 20 parts of MX, 35 parts of a mixture of white carbon and polyoxyethylene alkyl ether sulfate ammonium salt (weight ratio 1: 1), and water are mixed to make 100 parts in total. And each flowable preparation is obtained by mixing.

Formulation Example 5
20 parts of any one of the present compounds 1 to 7, or 20 parts of MX, 1.5 parts of sorbitan trioleate, and 28 parts of an aqueous solution containing 2 parts of polyvinyl alcohol are mixed and pulverized by a wet pulverization method. An aqueous solution containing 0.05 part of xanthan gum and 0.1 part of aluminum magnesium silicate is added to make the total amount 90 parts, and further 10 parts of propylene glycol is added and mixed to obtain each flowable preparation.

Formulation Example 6
By adding 20 parts of any one of the present compounds 1 to 7, or 20 parts of MX, 3 parts of calcium lignin sulfonate, 2 parts of sodium lauryl sulfate, and the rest of the synthetic hydrous hydroxide to 100 parts, Obtain each wettable powder.

Formulation Example 7
3 parts of any one of these compounds 1 to 7, or 3 parts of MX, 1 part of synthetic hydrous silicon oxide fine powder, 2 parts of calcium lignin sulfonate, 30 parts of bentonite and the remainder of kaolin clay are added to make a total of 100 parts. To do. Next, an appropriate amount of water is added to the mixture, and the mixture is further stirred, granulated with a granulator, and dried by ventilation to obtain granules.

Formulation Example 8
A powder is obtained by mixing 0.5 part of any one of the present compounds 1 to 7, or 1 part of MX, 10 parts of talc and the remainder of kaolin clay to make a total amount of 100 parts and mixing.

  Next, application examples of the composition of the present invention to plant seeds will be shown.

Application example 1
Using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), 200 ml of any one of the formulations obtained by the method described in Formulation Example 1, 3, 4 or 5 is used for 100 kg of dried sorghum seeds. Each treated seed is obtained by smearing.

  Moreover, each treated seed is obtained by adding 180 grams of oxabetrinyl to 200 ml of any one of the formulations obtained by the method described in Formulation Example 1 or 3, and performing a smearing treatment in the same manner as described above.

Application example 2
Using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), 200 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 is added to 100 kg of dried sorghum seeds. Each treated seed is obtained by smearing.

  In addition, to 200 ml of any one of the formulations obtained by the method described in Formulation Examples 1, 3, 4 or 5, 40 grams of fluxofenim is added, and each treated seed is obtained by smearing in the same manner as described above. .

Application example 3
10 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 is added to 10 kg of dried corn seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH). Each treated seed is obtained by smearing. The corn may be a genetically modified corn containing a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application example 4
Using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH) 40 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 on 10 kg of dried corn seeds Each treated seed is obtained by smearing.

Application example 5
Apply 100 ml of any one of the preparations obtained by the method described in Preparation Example 1, 4 or 5 to 10 kg of dried corn seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH). Each treated seed is obtained by treatment.

Application Example 6
Each treated seed is obtained by subjecting 10 kg of dried corn seeds to 50 g of any one of the preparations obtained by the method described in Formulation Example 2 or 6.

Application example 7
Using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), 20 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 is added to 10 kg of dried soybean seeds. Each treated seed is obtained by smearing. The soybean may be a genetically modified soybean containing a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application example 8
100 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 is added to 10 kg of dried soybean seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH). Each treated seed is obtained by smearing.

Application example 9
Using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), 50 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 is added to 10 kg of dry cotton seeds. Each treated seed is obtained by smearing. The cotton may be a genetically modified cotton containing a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application Example 10
Using 10 ml of dried oilseed rape seeds, 50 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5, using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH). Each treated seed is obtained by smearing. The oilseed rape may be a genetically modified oilseed rape including a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application Example 11
10 kg of dried oilseed rape seeds, 10 ml of any one of the preparations obtained by the method described in Formulation Examples 1, 3, 4 or 5, using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH) Each treated seed is obtained by smearing.

Application Example 12
Using 10 kg of dried wheat seeds, 50 ml of any one of the preparations obtained by the method described in Preparation Examples 1, 3, 4 or 5 using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH). Each treated seed is obtained by smearing.

Application Example 13
6 kg of any one of the flowable preparations prepared in Preparation Examples 1, 3, 4 and 5 is uniformly applied to 10 kg of potato seed meal to obtain each processed seed meal.

Application Example 14
10 kg of dried rice seed (dried rice cake) is put in a net bag and immersed in a 50-fold water dilution solution of Benrate (registered trademark) wettable powder (Benomil wettable powder, manufactured by Sumitomo Chemical Co., Ltd.) for 10 minutes, Immerse in water for 3 days. While draining rice seeds into a rotary pan-type rice seed coating machine and rotating, reduced iron powder 5 kg, calcined gypsum 600 g, and 100 g of any one of the formulations prepared in Formulation Examples 1, 3, 4 and 5 After adding 5 times water dilution liquid and dressing, 300g of calcined gypsum is further powdered. Thereafter, the rice seeds are taken out from the coating machine, dispersed on a vinyl sheet so as to have a thickness of 1 cm or less, and then allowed to stand and dried to obtain each treated seed.

Application Example 15
After putting 10 kg of dried rice seed (dried rice cake) in a net bag and immersing it in a 20-fold water dilution of Stana (registered trademark) wettable powder (oxolinic acid wettable powder, manufactured by Sumitomo Chemical Co., Ltd.) for 10 minutes, Immerse in tap water for 3 days. While draining rice seeds into a rotating pan-type rice seed coating machine and rotating, Culper (registered trademark) powder 16 (calcium peroxide powder, Hodogaya UPL Co., Ltd.) 20 kg and preparation example 2 Add 100 g of the prepared formulation and dress. Thereafter, the rice seeds are taken out from the coating machine, dispersed on a vinyl sheet so as to have a thickness of 1 cm or less, and then allowed to stand and dried to obtain each treated seed.

Application Example 16
10 kg of dried rice seeds (dry rice cake) is put in a net bag and sterilized by immersing in paddy SG aqueous solvent (Cartap hydrochloride aqueous solvent, manufactured by Sumitomo Chemical Co., Ltd.) in a 1500-fold aqueous diluted solution for 24 hours, and then tap water Soak for 3 days to germinate. While draining rice seeds into a rotary pan-type rice seed coating machine and rotating, an appropriate amount of Zojirushinol laundry paste (polyvinyl alcohol, Sanwa Yushi Kogyo Co., Ltd.) and molybdenum trioxide (Japan Inorganic Chemical Industry Co., Ltd.) 200 g; 100 g of 2 times water-diluted solution of any of the flowable preparations prepared in Preparation Examples 4 and 5 is added to treat the surface of rice seeds. Thereafter, the rice seeds are taken out from the coating machine, dispersed on a vinyl sheet so as to have a thickness of 1 cm or less, and then allowed to stand and dried to obtain each treated seed.

  Hereinafter, the effects of the present invention will be shown by test examples.

Test example 1
Treated corn seeds obtained by the method described in Application Example 3 are sown at 15 cm intervals to a depth of 5 cm using a seeder.
As a result, the corn treated with the present compounds 1 to 7 or MX can be confirmed to have an effect on harmful arthropods that harm the seedling blight fungi (Rhizotonia solani, Pythium spp.), Negusa nematode, and corn.

Test example 2
Treated soybean seeds obtained by the method described in Application Example 7 are sown and cultivated.
As a result, soybean treated with the present compounds 1 to 7 or MX has been confirmed to have an effect on Fusarium oxysporum, Rhizoctonia root rot, soybean cyst nematode, and harmful arthropods that harm soybean. it can.

Test example 3
Treated seeds of oilseed rape obtained by the method described in Application Example 10 are sown and cultivated.
As a result, soybeans treated with the present compounds 1 to 7 or MX can be confirmed to have an effect on harmful arthropods that harm Rhizotonia solani, Negusale nematodes, and Brassica napus.

Test example 4
Rice seed pods obtained in Application Example 14 or 15 are sown in rice fields and cultivated.
As a result, the rice treated with the present compounds 1 to 7 or MX can confirm the effects on rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, white-bellied moth, Futobikogaiga, Nikaameiga, locust. Furthermore, rice treated with the present compounds 1 to 7 or MX is controlled by controlling planthoppers and leafhoppers, thereby causing rice dwarf disease mediated by these insects, tundra disease, rice grassy stunt disease, rice rugid stunt disease, The effects on rice stripe leaf blight, black stripe atrophy, rice southern black stripe atrophy, yellowing atrophy, rice yellow leaf disease, transition yellowing disease and rice atrophy disease can be confirmed.

Test Example 5
24 kg of rice seeds are packed in a cloth bag and immersed in water for 24 hours together with the bag. The soaked rice seeds are placed on the concrete ground together with the above bags and allowed to stand for 36 hours with appropriate watering so as not to dry. Rice seeds taken out from the cloth bag after standing still are spread on a sheet, and a water-diluted solution of the formulation obtained in Formulation Example 3 or Formulation Example 6 is sprayed here, and the mixture is thoroughly stirred on the sheet. After plowing, watering, shaving, etc. in advance, the rice seeds are sown by evenly spreading the rice seeds by hand evenly in a paddy field where the flooding depth is maintained at about 2 cm. Cultivate.
As a result, the rice treated with the present compounds 1 to 7 or MX can be confirmed to have an effect on rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, white-bellied moth, Futabikogaiga, Nikamaiga and Itten-Ogaiga. The effect can also be confirmed against rice weevil, rice weevil, white planthopper, white-tailed planthopper, white-bellied planthopper, leafhopper, corn borer, butterfly moth, winged moth and itten potato, which have reduced sensitivity to one or more compounds selected from group a1 to group a18. In particular, the effect can be confirmed against rice weevil, rice rot beetle, rice planthopper, white-tailed planthopper, tiger leafhopper, and leafhopper with reduced sensitivity to one or more compounds selected from group d. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease, rice atrophy disease.

Test Example 6
After pruning, rice seeds obtained in any one of Application Examples 14 to 16 are sown in a dotted or streak-like manner in a paddy sowing machine in a paddy field that has been managed to fall for several days. At this time, the seeding amount per 10 ares is 4 kg in dry rice.
As a result, the rice treated with the present compounds 1 to 7 or MX can be confirmed to have an effect on rice weevil, rice beetle, brown planthopper, white-spotted planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, leafhopper leafhopper, and leafhopper. Furthermore, the effect with respect to the one or more compounds selected from the group a1 to the group a18 can be confirmed for rice weevil, rice beetle, brown planthopper, white-spotted planthopper, brown-bellied planthopper, leafhopper leafhopper, leafhopper leafhopper, leafhopper leafhopper, leafhopper leafhopper, and leafhopper. In particular, the effect on the rice weevil, rice rot beetle, rice planthopper, white-tailed planthopper, tiger leafhopper, and leafhopper of the rice weevil, rice plant beetle, sensitivity to one or more compounds selected from group a4 can be confirmed.

Test Example 7
The corn seed obtained in Application Example 3 is sown at 15 cm intervals to a depth of 5 cm using a seeder and cultivated.
As a result, the corn treated with the present compounds 1 to 7 or MX has been confirmed to have an effect on the larvae (generally called wire worms) of the beetles belonging to the genus Diabrotica such as Western corn rootworm and the genus Agriotes and Melanotus. it can. The effect can also be confirmed against the larvae of the above-mentioned beetles whose sensitivity to one or more drugs selected from group a1 to group a18 is reduced.

Test Example 8
Soybean seeds obtained in Application Example 7 are sown and cultivated.
As a result, soybeans treated with the present compounds 1 to 7 or MX can be confirmed to be effective against the fly larvae. The effect can also be confirmed against the fly larvae having reduced sensitivity to one or more compounds selected from the group a1 to the group a18.

Test Example 9
The oilseed rape (Brassica napus) seed obtained in Application Example 10 is sown and cultivated.
As a result, the oilseed rape treated with the present compounds 1 to 7 or MX can confirm the effect on larvae of the beetle family. Moreover, an effect can be confirmed also to the larva of the beetle family in which the sensitivity with respect to 1 or more types of compounds chosen from the group a1-group a18 fell.

Test Example 10
Wheat seeds obtained in Application Example 12 are sown and cultivated.
As a result, the wheat treated with the present compounds 1 to 7 or MX can confirm the effect on the larvae of the beetles. The effect can also be confirmed against the larvae of the beetles that are less sensitive to one or more compounds selected from group a1 to group a18.

Test Example 11
The potato seed meal obtained in Application Example 13 is planted and cultivated in soil.
As a result, the potato treated with the present compounds 1 to 7 or MX can confirm the effect on larvae of the beetle family. Moreover, an effect can be confirmed also to the larva of the beetle family in which the sensitivity with respect to the 1 or more types of compound chosen from the group a1-group a18 fell.

Test Example 12
The granules obtained in Formulation Example 7 are mixed with soil, and sugarcane stem fragments are planted and cultivated there.
As a result, sugarcane treated with the present compounds 1 to 7 or MX can confirm the effect on the larvae of the beetles. Moreover, an effect can be confirmed also with respect to the larva of the beetle family in which the sensitivity with respect to 1 or more types of compounds chosen from the group a1-group a18 fell.

Test Example 13
The water-diluted solution of the flowable preparation obtained in Formulation Example 4 or 5 is sprayed before the covering soil and cultivated by covering the planting groove in which the sugarcane stem fragments are planted.
As a result, sugarcane treated with the present compounds 1 to 7 or MX can confirm the effect on the larvae of the beetles. Moreover, an effect can be confirmed also with respect to the larva of the beetle family in which the sensitivity with respect to 1 or more types of compounds chosen from the group a1-group a18 fell.

Test Example 14
During the seedling period immediately before transplanting from rice seeding, 50 g of the granule obtained in Formulation Example 7 is sprayed per seedling box (about 60 cm wide, about 30 cm long), covered with soil, and grown. The seed pods used are seed sterilized with a mixture of ipconazole and cupric hydroxide before sowing. Rice seedlings grown at the 2.5 leaf stage are transplanted and cultivated in paddy fields using a rice planting machine.
As a result, the rice treated with the present compounds 1 to 7 and MX is capable of confirming the effects of rice weevil, rice dwarf beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, white-bellied leafhopper, leafhopper leafhopper, leafhopper leafworm, rice leafworm, rice leafworm and rice leafworm effect. In addition, against rice weevil, rice beetle, brown planthopper, white-throated planthopper, brown-bill beetle, leafhopper leafhopper, leafhopper leafhopper, rice-butterfly, rice-bellied moth, rice-bitter beetle, rice-bellied beetle and rice-butterfly The effect can be confirmed. In particular, the effect can be confirmed against rice weevil, rice squirrel, rice planthopper, white-tailed planthopper, rice planthopper, and leafhopper with reduced sensitivity to one or more compounds selected from group a4. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease, rice atrophy disease.

Test Example 15
During the seedling period immediately before transplanting from rice sowing, a solution obtained by diluting the flowable preparation obtained in Formulation Example 4 is irrigated to the rice seedlings grown at the 3.5 leaf stage using an irrigation apparatus. The rice seedlings are transplanted and cultivated in paddy fields using a rice planting machine.
As a result, the rice treated with the present compounds 1 to 7 or MX can confirm the effects of rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, white-bellied leafhopper, leafhopper leafhopper, leafhopper leafworm, rice leafworm, rice leaf beetle and rice leafworm effect. In addition, against rice weevil, rice beetle, brown planthopper, white-throated planthopper, brown-bill beetle, leafhopper leafhopper, leafhopper leafhopper, rice-butterfly, rice-bellied moth, rice-bitter beetle, rice-bellied beetle and rice-butterfly The effect can be confirmed. In particular, the effect can be confirmed against rice weevil, rice squirrel, rice planthopper, white-tailed planthopper, rice planthopper, and leafhopper with reduced sensitivity to one or more compounds selected from group a4. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease, rice atrophy disease.

Test Example 16
During the seedling period immediately before transplanting from rice seeding, 500 ml of a solution obtained by diluting the flowable preparation obtained in Formulation Example 5 is irrigated in a seedling box (about 60 cm wide, about 30 cm long). The rice seedlings are transplanted and cultivated in paddy fields using a rice planting machine.
As a result, the rice treated with the present compounds 1 to 7 or MX can confirm the effects of rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, white-bellied leafhopper, leafhopper leafhopper, leafhopper leafworm, rice leafworm, rice leaf beetle and rice leafworm effect. In addition, against rice weevil, rice beetle, brown planthopper, white-throated planthopper, brown-bill beetle, leafhopper leafhopper, leafhopper leafhopper, rice-butterfly, rice-bellied moth, rice-bitter beetle, rice-bellied beetle and rice-butterfly The effect can be confirmed. In particular, the effect can be confirmed against rice weevil, rice squirrel, rice planthopper, white-tailed planthopper, rice planthopper, and leafhopper with reduced sensitivity to one or more compounds selected from group a4. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease, rice atrophy disease.

Test Example 17
The present compounds 1 to 7 or MX are prepared according to the method described in Preparation Example 4. Similarly, triflumezopyrim, flupiradifurone or flupyrimine is prepared according to the method described in Preparation Example 4. Spreading agent (trade name: Cyndyne (registered trademark)) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume to obtain each dilution. Commercially available Admeier wettable powder (active ingredient: imidacloprid, manufactured by Bayer CropScience Co., Ltd.) and Actara granule wettable powder (active ingredient: thiamethoxam, manufactured by Syngenta Japan Co., Ltd.) with an active ingredient concentration of 0.05 ppm, Diluted with water containing 0.05% by volume of a spreading agent (trade name: Cyndyne (registered trademark)) to 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, Obtain a diluted solution. Cucumber seedlings planted in containers (second true leaf development stage) are susceptible lines (lines that have been bred in succession within the Institute for Health and Agriculture of Sumitomo Chemical Co., Ltd.) and reduced sensitivity lines (in Miyazaki Prefecture in 2016) After collection, inoculate 30 cotton aphids (including all growth stages) of a line that has been reared indefinitely. After 1 day, the diluted solution is sprayed on the seedlings at a rate of 10 mL / seedling. On the other hand, cucumbers are cultivated in the same manner as in the treated section except that the diluted solution containing the compound is not sprayed (this is referred to as “untreated section”). Six days after spraying, the number of live insects is observed, and the control value is determined by the formula 1).
Formula 1); control value (%) = {1− (Cb × Tai) / (Cai × Tb)} × 100
The characters in the formula have the following meanings.
Cb: number of test insects in the untreated group Cai: number of live insects at the time of investigation in the untreated group Tb: number of test insects in the treated group Tai: number of live insects at the time of survey in the treated group As a result, the nicotine of the group a4 It is confirmed that the treatment groups of triflumezopyrim, flupiradifuron, flupirimine, imidacloprid and thiamethoxam, which are competitive modulators of the sex acetylcholine receptor, are all less effective against the susceptible strain. This confirms that the sensitivity-reduced strain used in this study is a strain with reduced sensitivity to the nicotinic acetylcholine receptor competitive modulator. On the other hand, the treatment group of this compound 1-7 or MX can confirm the effect equivalent to it with respect to a sensitivity system | strain also with respect to a sensitivity reduction system | strain.

Test Example 18
The present compounds 1 to 7 or MX are prepared according to the method described in Preparation Example 4. Similarly, flupiradiflon and flupyrimine are each prepared according to the method described in Preparation Example 4. Spreading agent (trade name: Cyndyne (registered trademark)) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume. Commercially available Admeier wettable powder (active ingredient: imidacloprid, manufactured by Bayer CropScience Co., Ltd.), active ingredient concentration of 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and Dilute with water containing 0.05% by volume of a spreading agent (trade name: Cyndine (registered trademark)) to 200 ppm. The dilute solution is sprayed at a rate of 10 mL / seedling on rice (Oryza sativa) seedlings (2.5th leaf stage) planted in a container. Subsequently, susceptible planthopper (Sumitomo Chemical Co., Ltd. health farming and related business research line), and reduced sensitivity line planter (collected in Nagasaki Prefecture in 2016, then breeding indefinitely 20 strains of 3rd instar larvae are released. After 6 days, the number of surviving insects is examined, and the death rate is obtained by the formula 2). On the other hand, rice is cultivated in the same manner as in the treated area except that the diluted solution containing the compound is not sprayed (this is referred to as an untreated area).
Formula 2) Death rate (%) = {1−number of surviving insects / 20} × 100
As a result, it is confirmed that the treatment group of flupiradifuron, flupyrimine, and imidacloprid, which are the nicotinic acetylcholine receptor competitive modulators of the group a4, all have a lower effect on the sensitivity-reduced strain than the effect on the sensitive strain. This confirms that the sensitivity-reduced strain used in this study is a strain with reduced sensitivity to the nicotinic acetylcholine receptor competitive modulator. On the other hand, the treatment group of this compound 1-7 or MX can confirm the effect equivalent to it with respect to a sensitivity system | strain also with respect to a sensitivity reduction system | strain.

Test Example 19
The present compounds 1 to 7 or MX are prepared according to the method described in Preparation Example 4. Spreading agent (trade name: Cyndyne (registered trademark)) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume. Commercially available phoenix granule wettable powder (active ingredient: fulvendiamide, manufactured by Nippon Agricultural Chemicals Co., Ltd.), Prevason Flowable 5 (active ingredient: chlorantraniliprole, manufactured by Nissan Chemical Co., Ltd.) and Venevia OD (active ingredient: Cyantraniprolol (manufactured by Kumiai Chemical Industry Co., Ltd.) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume of the trade name: Cyndyne (registered trademark). The diluted solution is sprayed on a cabbage (Brassicae oleracea) seedling (third to fourth true leaf development stage) planted in a container at a rate of 20 mL / seedling. Later, the sensitive strain Koaga (Sumitomo Chemical Co., Ltd. Health Agriculture and Related Business Research Institute) and the sensitivity-reduced strain Koaga (collected in Kumamoto Prefecture in 2016 and then raised indefinitely 10 strains of 3rd instar larvae are released. After 5 days, the number of surviving insects is counted, and the mortality rate is obtained from Equation 3). On the other hand, cabbage is cultivated in the same manner as in the treated area except that the dilute solution containing the compound is not sprayed (this is defined as an untreated area).
Formula 3) Death rate% = (1−Number of surviving insects / 10) × 100
As a result, the treatment group of flubendiamide, chlorantraniliprole, and cyantraniliprolol, which are the ryanodine receptor modulators of the group a17, are all less effective against the sensitive line than the sensitive line. It is confirmed. From this, it is confirmed that the sensitivity-reduced strain used in this test is a strain with reduced sensitivity to the ryanodine receptor modulator. On the other hand, the treatment group of this compound 1-7 or MX can confirm the effect equivalent to it with respect to a sensitivity system | strain also with respect to a sensitivity reduction system | strain.

Test Example 20
The present compounds 1 to 7 or MX are prepared according to the method described in Preparation Example 4. Similarly, flupiradiflon and flupyrimine are each prepared according to the method described in Preparation Example 4. Spreading agent (trade name: Cyndyne (registered trademark)) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume. Commercially available Admeier granule wettable powder (active ingredient: imidacloprid, manufactured by Bayer CropScience), Trebon emulsion (active ingredient: etofenprox, manufactured by Mitsui Chemicals Agro Co., Ltd.), Prince flowable (active ingredient: fipronil, BASF Japan Co., Ltd.), Kirup Floable (active ingredient: Ethiprole, Bayer CropScience Co., Ltd.), and Uploadable (active ingredient: buprofezin, manufactured by Nippon Agricultural Chemicals Co., Ltd.) have an active ingredient concentration of 0.05 ppm and 0, respectively. It is diluted with water containing 0.05% by volume of a spreading agent (trade name: Cyndyne (registered trademark)) so as to be 2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm. The dilute solution is sprayed at a rate of 10 mL / seedling on rice (Oryza sativa) seedlings (2.5th leaf stage) planted in a container. Later, the susceptible strain Hime Tuna (Sumitomo Chemical Co., Ltd., Health Farming and Related Business Research Institute), and the reduced sensitivity strain Hime Tuna (collected in Nagasaki Prefecture in 2016, and then reared indefinitely) 20 strains of 3rd instar larvae are released. After 6 days, the number of surviving insects is examined, and the death rate is obtained by the formula 2). On the other hand, rice is cultivated in the same manner as in the treated area except that the diluted solution containing the compound is not sprayed (this is referred to as an untreated area).
Formula 2) Death rate (%) = {1−number of surviving insects / 20} × 100
As a result, flupirazifuron, flupyrimine and imidacloprid which are competitive modulators of the nicotinic acetylcholine receptor of the group a4, fipronil and etiprole which are GABAergic chloride channel blockers of the group a2, and etholine which is a sodium channel modulator of the group a3 It is confirmed that the treatment group of fenprox and buprofezin, which is the chitin biosynthesis inhibitor of the group a12, has a lower effect on the sensitivity-reduced line than the effect on the sensitive line. From this, it is confirmed that the sensitivity-reducing line used in this test is a line with reduced sensitivity to these compounds. On the other hand, the treatment group of this compound 1-7 or MX can confirm the effect equivalent to it with respect to a sensitivity system | strain also with respect to a sensitivity reduction system | strain.

Test Example 21
The present compounds 1 to 7 or MX are prepared according to the method described in Preparation Example 4. Spreading agent (trade name: Cyndyne (registered trademark)) so that the active ingredient concentration is 0.05 ppm, 0.2 ppm, 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm, respectively. Dilute with water containing 0.05% by volume. The commercially available Prince Flowable (active ingredient: fipronil, manufactured by BASF Japan Co., Ltd.) and Killup Flowable (active ingredient: Ethiprole, manufactured by Bayer Crop Science Co., Ltd.) have active ingredient concentrations of 0.05 ppm, 0.2 ppm, Dilute with water containing 0.05% by volume of a spreading agent (trade name: Cyndine®) to 0.8 ppm, 3.1 ppm, 12.5 ppm, 50 ppm and 200 ppm. The diluted solution is sprayed at a rate of 10 mL / seedling on rice seedlings (2.5th leaf stage) planted in a container. Later, susceptible line cedar (Strains that have been bred in Sumitomo Chemical Co., Ltd.) 20 strains of 3rd instar larvae are released. After 6 days, the number of surviving insects is examined, and the death rate is obtained by the formula 2). On the other hand, rice is cultivated in the same manner as in the treated area except that the diluted solution containing the compound is not sprayed (this is referred to as an untreated area).
Formula 2) Death rate (%) = {1−number of surviving insects / 20} × 100
As a result, it is confirmed that the treatment group of fipronil and etiprol, which are GABAergic chloride channel blockers of group a2, are less effective against the sensitivity-reduced strain than both. From this, it is confirmed that the sensitivity-reducing line used in this test is a line with reduced sensitivity to these compounds. On the other hand, the treatment group of this compound 1-7 or MX can confirm the effect equivalent to it with respect to a sensitivity system | strain also with respect to a sensitivity reduction system | strain.

Test Example 22
The present compounds 1 to 7 or MX are prepared according to the method described in Preparation Example 4.
Each of the above formulations is diluted 100 times with water. The diluted solution is irrigated with 500 ml in a cell-shaped seedling raising tray (about 60 cm wide, about 30 cm long) of cabbage one day before planting, planted in a field and cultivated.
As a result, the cabbage treated with the present compounds 1 to 7 or MX can be confirmed to have an effect on harmful insects belonging to the family Coniferaceae, Noctuidae and Whiteflies. The effect can also be confirmed against harmful insects belonging to the family Convolvulaceae, Noctuidae, and Lepidoptera, which have reduced sensitivities to one or more compounds selected from Group a1 to Group a18. In particular, the effect can be confirmed against the diamondback moth having reduced sensitivity to one or more compounds selected from the group a17.

Test Example 23
The present compounds 1 to 7 or MX are prepared according to the method described in Preparation Example 7. After carrying out the pricking, the above formulation was applied at a rate of 1 kg / 10a at a rate of 1 kg / 10a while sowing several rice seeds coated with iron oxide powder in a paddy seeder in a paddy field that was managed to fall for several days. Apply to a position of 1 cm depth. Then, rice is cultivated.
As a result, the rice treated with the present compounds 1 to 7 or MX can confirm the effects on rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, rice-bellied leafhopper, leafhopper leafworm, leafhopper, rice-nettle beetle and rice leafworm effect. The effects of rice weevil, rice beetle, brown planthopper, white-tailed planthopper, brown-bill plant, leafhopper leafhopper, leafhopper leafhopper, leaf-butterfly, leaf-bucky beetle, rice-bitter beetle, rice-brush beetle and rice-butterfly I can confirm. In particular, the effect can be confirmed also for rice weevil, rice beetle, rice planthopper, white-tailed planthopper, rice planthopper, and leafhopper with reduced sensitivity to one or more compounds selected from group a4. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease and rice dwarf disease.

Test Example 24
The present compounds 1 to 7 or MX are prepared according to the method described in Preparation Example 7. After pruning, several rice seeds coated with Calper (registered trademark) granule 16 (calcium peroxide granule, Hodogaya UPL Co., Ltd.) were placed on a paddy field that had been managed for several days. While sowing the grains, the above-mentioned preparation is applied at a rate of 1 kg / 10a to a position 3 cm to the side of the sowing position and a depth of 3 cm. Then, rice is cultivated.
As a result, the rice treated with the present compounds 1 to 7 or MX can confirm the effects on rice weevil, rice beetle, brown planthopper, white-tailed planthopper, Japanese brown planthopper, leafhopper leafhopper, leafhopper leafhopper, rice-bellied leafhopper, leafhopper leafworm, leafhopper, rice-nettle beetle and rice leafworm effect. The effects of rice weevil, rice beetle, brown planthopper, white-tailed planthopper, brown-bill plant, leafhopper leafhopper, leafhopper leafhopper, leaf-butterfly, leaf-bucky beetle, rice-bitter beetle, rice-brush beetle and rice-butterfly I can confirm. In particular, the effect can be confirmed also for rice weevil, rice beetle, rice planthopper, white-tailed planthopper, rice planthopper, and leafhopper with reduced sensitivity to one or more compounds selected from group a4. In addition, by controlling harmful insects belonging to the planthopper family and leafhopper family, these insect-borne rice dwarf disease, tundra disease, rice grassy stunt disease, rice rugid stunt disease, rice stripe leaf blight, black stripe atrophy Rice can be protected from diseases, rice southern black stripe atrophy, yellow dwarf disease, rice yellow leaf disease, transition yellowing disease and rice dwarf disease.

  According to the present invention, harmful arthropods can be controlled.

Claims (3)

Formula (I):
[Where:
A ¹ represents a nitrogen atom or CR ^3b ,
n represents 0, 1 or 2;
q represents 0, 1, or 2;
G represents one or more substituents may be a C3-C8 alicyclic hydrocarbon group selected from the group E, or -L ¹ -G ^2,
L ¹ represents an oxygen atom or a sulfur atom,
G ² represents a 5- to 10-membered heterocyclic group which may have one or more substituents selected from group D;
R ^3a each independently has a C1-C6 chain hydrocarbon group which may have one or more substituents selected from group B, and one or more substituents selected from group E. A C3-C7 cycloalkyl group, a phenyl group optionally having one or more substituents selected from group H, a 5- or 6-membered optionally having one or more substituents selected from group H Aromatic heterocyclic group, OR ¹² , NR ¹¹ R ¹² , NR ^11a R ^12a , NR ²⁴ NR ¹¹ R ¹² , NR ²⁴ OR ¹¹ , NR ¹¹ C (O) R ¹³ , NR ²⁴ NR ¹¹ C (O) R ¹³ , NR ¹¹ C (O) OR ¹⁴ , NR ²⁴ NR ¹¹ C (O) OR ¹⁴ , NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , NR ²⁴ NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , N = CHNR ¹⁵ R ¹⁶ , N = S (O) _x R ¹⁵ R ¹⁶ , C (O) OR ¹⁷ , a cyano group, a nitro group, or a halogen atom,
R ^3b may have one or more substituents selected from group B and may have one or more substituents selected from group E; C3-C7 A cycloalkyl group, a phenyl group optionally having one or more substituents selected from group H, a 5- or 6-membered aromatic heterocyclic group optionally having one or more substituents selected from group H , OR ¹² , NR ¹¹ R ¹² , NR ^11a R ^12a , NR ²⁴ NR ¹¹ R ¹² , NR ²⁴ OR ¹¹ , NR ¹¹ C (O) R ¹³ , NR ²⁴ NR ¹¹ C (O) R ¹³ , NR ¹¹ C ( O) OR ¹⁴ , NR ²⁴ NR ¹¹ C (O) OR ¹⁴ , NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , NR ²⁴ NR ¹¹ C (O) NR ¹⁵ R ¹⁶ , N = CHNR ¹⁵ R ¹⁶ , N = S (O) _x R ¹⁵ R ¹⁶ , C (O) OR ¹⁷ , a cyano group, a nitro group, a hydrogen atom or a halogen atom,
x represents 0 or 1;
A ² represents a nitrogen atom or CR ^4a ,
A ³ represents a nitrogen atom or CR ^4b ,
A ⁴ represents a nitrogen atom or CR ^4c ,
R ^4a , R ^4b and R ^4c are each independently a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a nitro group, OR ¹⁸ , NR ¹⁸ R ^19. Represents a cyano group or a halogen atom,
T is a C1-C10 chain hydrocarbon group having one or more halogen atoms, (C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms, and (C1-C5 alkyl) having one or more halogen atoms. (Sulfanyl) C2-C5 alkyl group, (C1-C5 alkylsulfinyl) C2-C5 alkyl group having one or more halogen atoms, (C1-C5 alkylsulfonyl) C2-C5 alkyl group having one or more halogen atoms, group G 1 or more having a substituent (C3-C7 cycloalkyl) C1-C3 alkyl group, C3-C7 cycloalkyl group having one or more substituents selected from the group G to be more ^{selected, oR 1, S (O)} m _{^{R 1, OS (O) 2}} R 1, CH 2 OR 1, NR 1 R 29, C (O) R 1, C (O) NR 1 R 29, NR 29 C (O) R 1, N CR ¹ R ^30, a group represented by the following formula T-1, a group represented by the formula T-2, a group represented by the following formula T-3, a group represented by the following formula T-4, the formula T-5 A group represented by the following formula T-6, a group represented by the following formula T-7, a group represented by the following formula T-8, a group represented by the following formula T-9, and the following formula T-10 Represents a group represented by the following formula T-11, or a group represented by the following formula T-12;
X ¹ represents a nitrogen atom or CR ^1a ,
X ² represents a nitrogen atom or CR ^1b ,
X ³ represents a nitrogen atom or CR ^1c ,
X ⁴ represents a nitrogen atom or CR ^1d ,
X ⁵ represents a nitrogen atom or CR ^1e ,
R ^1a , R ^1b , R ^1c , R ^1d and R ^1e are each independently a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, and one or more halogens. Represents a C3-C7 cycloalkyl group optionally having an atom, or a halogen atom;
R ^1x is OR ⁷ , OS (O) ₂ R ⁷ , S (O) _m R ⁷ , NR ¹ R ²⁹ , NR ⁸ S (O) ₂ R ⁷ , C1-C5 chain formula having one or more halogen atoms Represents a hydrocarbon group, a cyano group, or a halogen atom,
Y ¹ represents NR ²⁵ , an oxygen atom or a sulfur atom,
Y ² represents a nitrogen atom or CR ²⁶ ,
Y ³ represents a nitrogen atom or CR ²⁷ ,
Y ⁴ represents a nitrogen atom or CR ²⁸ ;
R ²⁵ is a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens. Represents a C3-C7 cycloalkyl group optionally having atoms, or a (C3-C7 cycloalkyl) C1-C6 alkyl group optionally having one or more halogen atoms,
R ²⁶ , R ²⁷ and R ²⁸ each independently have a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, and one or more halogen atoms. Represents a C3-C7 cycloalkyl group, or a halogen atom,
R ^1y is OR ⁷ , OS (O) ₂ R ⁷ , S (O) _m R ⁷ , NR ⁸ S (O) ₂ R ⁷ , cyano group, C1-C5 chain hydrocarbon having one or more halogen atoms Represents a group, or a halogen atom,
R ^1ay and R ⁷ each independently represents a C1-C6 chain hydrocarbon group having one or more halogen atoms,
R ⁸ represents a hydrogen atom or a C1-C6 chain hydrocarbon group which may have one or more halogen atoms,
m represents 0, 1, or 2;
R ¹ is a C1-C10 chain hydrocarbon group having one or more halogen atoms, (C1-C5 alkoxy) C2-C5 alkyl group having one or more halogen atoms, and one or more halogen atoms (C1-C5 Alkylsulfanyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfinyl) C2-C5 alkyl group, one or more halogen atoms (C1-C5 alkylsulfonyl) C2-C5 alkyl group, group A (C3-C7 cycloalkyl) C1-C3 alkyl group having one or more substituents selected from G, or a C3-C7 cycloalkyl group having one or more substituents selected from Group G;
R ² represents a cyclopropyl group, a cyclopropylmethyl group, or a C1-C6 alkyl group optionally having one or more halogen atoms,
R ¹¹ , R ¹⁷ , R ¹⁹ , R ²⁴ and R ²⁹ each independently represent a hydrogen atom or a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms,
R ³⁰ represents a hydrogen atom, a halogen atom, OR ³¹ , NR ³² R ³³ , or a C1-C6 chain hydrocarbon group which may have one or more halogen atoms,
R ¹⁸ and R ³¹ each independently represents a hydrogen atom or a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms,
R ³² and R ³³ each independently represent a hydrogen atom or a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms,
R ¹² is a hydrogen atom, S (O) ₂ R ²³ , a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a C1-C6 having one substituent selected from Group F. Represents a C6 alkyl group,
R ²³ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a phenyl group optionally having one or more substituents selected from Group D;
R ^11a and R ^12a together with the nitrogen atom to which they are attached represent a 3-7 membered non-aromatic heterocyclic group optionally having one or more substituents selected from group E;
R ¹³ is a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, one or more A (C3-C7 cycloalkyl) C1-C3 alkyl group optionally having a halogen atom, a phenyl group optionally having one or more substituents selected from group D, or one or more selected from group D Represents a 5- or 6-membered aromatic heterocyclic group optionally having
R ¹⁴ represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, and one or more halogen atoms. (C3-C7 cycloalkyl) which may have C1-C3 alkyl group, or phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group has one or more substituents selected from group D You may do it. },
R ¹⁵ and R ¹⁶ each independently represent a C1-C6 alkyl group optionally having one or more halogen atoms.
Group B: C1-C6 alkoxy group optionally having one or more halogen atoms, C3-C6 alkenyloxy group optionally having one or more halogen atoms, having one or more halogen atoms A C3-C6 alkynyloxy group, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, one or more A group consisting of a C1-C6 alkylsulfonyl group optionally having a halogen atom, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom.
Group D: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, hydroxy group, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogen atoms A C3-C6 alkenyloxy group that may have one or more, a C3-C6 alkynyloxy group that may have one or more halogen atoms, a sulfanyl group, or a C1-C6 that may have one or more halogen atoms. C6 alkylsulfanyl group, C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, amino group, NHR ²¹ , NR ^{21 R 22, C (O)} R 21, OC (O) R 21, C (O) oR 21, cyano group, the group {R ²¹ and R ²² consisting of nitro group, and halogen atoms are each independently Te represents one or more halogen atoms which may have a C1-C6 alkyl group. }.
Group E: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, having one or more halogen atoms C3-C6 alkenyloxy group which may have one, C3-C6 alkynyloxy group which may have one or more halogen atoms, amino group, NR ⁹ R ¹⁰ , C (O) R ¹⁰ , C (O) NR ⁹ R ¹⁰ , OC (O) R ⁹ , OC (O) OR ⁹ , NR ¹⁰ C (O) R ⁹ , NR ¹⁰ C (O) OR ⁹ , C (O) OR ¹⁰ , having one or more halogen atoms An optionally substituted C3-C7 cycloalkyl group, a phenyl group optionally having one or more substituents selected from group H, and optionally having one or more substituents selected from group H Or 6-membered aromatic heterocyclic group, halogen atom, oxo group, thioxo group, hydro Shi group, the group {R ⁹ consisting of a cyano group and a nitro group, is 1 or more may C1-C6 have a halogen atom an alkyl group or 1 or more halogen atoms have a C3-C7 Represents a cycloalkyl group, and R ¹⁰ represents a hydrogen atom, a C1-C6 alkyl group optionally having one or more halogen atoms, or a C3-C7 cycloalkyl group optionally having one or more halogen atoms. Represents. }.
Group F: C1-C6 alkoxy group which may have one or more halogen atoms, amino group, NHR ²¹ , NR ²¹ R ²² , cyano group, one or more substituents selected from group D A phenyl group, a 5- or 6-membered aromatic heterocyclic group optionally having one or more substituents selected from group D, and a C3-C7 cycloalkyl group optionally having one or more halogen atoms And a group consisting of a 3-7-membered non-aromatic heterocyclic group optionally having one or more substituents selected from group C {R ²¹ and R ²² are each independently one or more halogen atoms The C1-C6 alkyl group which may have is represented. }.
Group C: C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, having one or more halogen atoms A group consisting of a C3-C6 alkenyloxy group which may have one, a C3-C6 alkynyloxy group which may have one or more halogen atoms, and a halogen atom.
Group G: A group consisting of a halogen atom and a C1-C6 haloalkyl group.
Group H: halogen atom, nitro group, cyano group, amino group, 5- or 6-membered aromatic heterocyclic group optionally having one or more halogen atoms, C1 optionally having one or more halogen atoms -C6 alkyl ^{group, OR 10, NR 9 R 10} , C (O) R 10, C (O) NR 9 R 10, OC (O) R 9, OC (O) OR 9, NR 10 C (O) R ⁹ , a group consisting of NR ¹⁰ C (O) OR ⁹ and C (O) OR ¹⁰ {R ⁹ represents a C1-C6 alkyl group optionally having one or more halogen atoms or one or more halogen atoms. Represents a C3-C7 cycloalkyl group which may have, and R ¹⁰ has a hydrogen atom, a C1-C6 alkyl group which may have one or more halogen atoms, or one or more halogen atoms. And may represent a C3-C7 cycloalkyl group. }. ]
And a group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i) And one or more components selected from the group consisting of group (j):
Group (a): a group consisting of an insecticidal active ingredient, an acaricidal active ingredient and a nematicidal active ingredient;
Group (b): bactericidal active ingredient;
Group (c): plant growth regulating component;
Group (d): phytotoxicity reducing component;
Group (e): synergist;
Group (f): repellent ingredients;
Group (g): molluscicidal components;
Group (h): insect pheromone;
Group (i): herbicidal active ingredient;
Group (j): Microbial material.   A method for controlling harmful arthropods, which comprises applying an effective amount of the composition according to claim 1 to harmful arthropods, habitats, plants or soil of harmful arthropods.   A seed or vegetative organ holding an effective amount of the composition of claim 1.