JP2018177652A - Hair cleansing composition for use by filling up in foam discharge container - Google Patents
Hair cleansing composition for use by filling up in foam discharge container Download PDFInfo
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- JP2018177652A JP2018177652A JP2017074581A JP2017074581A JP2018177652A JP 2018177652 A JP2018177652 A JP 2018177652A JP 2017074581 A JP2017074581 A JP 2017074581A JP 2017074581 A JP2017074581 A JP 2017074581A JP 2018177652 A JP2018177652 A JP 2018177652A
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- Prior art keywords
- hair
- cleansing composition
- mass
- hair cleansing
- component
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Abstract
Description
本発明は、泡吐出容器に充填して用いる毛髪洗浄剤組成物およびそれを用いた毛髪の洗浄方法に関する。 The present invention relates to a hair cleansing composition to be used by filling in a foam discharge container and a method for washing hair using the same.
近年、泡吐出容器に充填された洗浄剤が開発されている。泡吐出容器に充填して用いられる洗浄剤に関する技術として、特許文献１に記載のものがある。 In recent years, detergents filled in foam discharge containers have been developed. As a technique regarding the washing | cleaning agent used by being filled with a foam discharge container, there exists a thing of patent document 1. As shown in FIG.
特許文献１（特開２０１３−１５５１４３号公報）には、特定のアミドアミン型両性界面活性剤および特定のカチオン化セルロースを含有する泡吐出容器用頭髪洗浄剤組成物が記載されている。同文献によれば、かかる構成により、低温においても目詰まり無く、クリーミーな泡を吐出でき、かつ、髪への十分なリンスイン効果を有する泡吐出容器用頭髪洗浄剤を提供することができるとされている。 Patent Document 1 (Japanese Patent Application Laid-Open No. 2013-155143) describes a hair cleaner composition for a foam discharge container, which contains a specific amidoamine type amphoteric surfactant and a specific cationized cellulose. According to this document, it is considered that such a configuration can provide a hair cleaner for a foam discharge container which can discharge creamy foam without clogging even at low temperatures and has a sufficient rinse-in effect on the hair. ing.
ここで、一般的な泡吐出容器用頭髪洗浄剤中ではアニオン性界面活性剤とカチオン化ポリマーとを併用すると、吐出時の泡質低下や低温時（−５℃）における組成物の保存安定性の悪化が生じることがあった。また、先行文献１に示すような泡吐出容器用頭髪洗浄剤組成物では洗髪時（皮脂存在下で）の泡量および泡質が低下してしまうことがあった。 Here, when an anionic surfactant and a cationized polymer are used in combination in a general foam cleaner for foam discharge containers, the foam quality declines at the time of discharge and the storage stability of the composition at a low temperature (-5 ° C.) In some cases, deterioration of In addition, in the case of the hair cleansing composition for a foam discharge container as shown in the prior art 1, the foam amount and the foam quality may be lowered during hair washing (in the presence of sebum).
そこで、本発明は、良質な泡の吐出性や低温時（−５℃）の保存安定性といった基本性能は担保しつつ、洗髪時（皮脂存在下で）の泡量および泡質が良好であり、更に毛髪すすぎ時の滑らかさに優れる、泡吐出容器に充填して用いる毛髪洗浄剤組成物を提供することを課題とする。 Therefore, the present invention secures basic performance such as good foam dischargeability and storage stability at low temperature (−5 ° C.), while the foam volume and foam quality are good during hair washing (in the presence of sebum). Furthermore, it is an object of the present invention to provide a hair cleansing composition which is used by filling in a foam discharge container and having excellent smoothness at the time of hair rinse.
本発明者の検討の結果、驚くべきことに、毛髪洗浄剤組成物中にアニオン性界面活性剤およびカチオン化ポリマーに加えて、ポリオキシプロピレンポリグリセリルエーテルを併用することで、上記課題を解決し得ることを見出した。 As a result of the present inventor's investigation, surprisingly, the above-mentioned problems can be solved by using polyoxypropylene polyglyceryl ether in combination with the anionic surfactant and the cationized polymer in the hair cleansing composition. I found out.
本発明は、以下の成分（Ａ）〜（Ｃ）を含み、泡吐出容器に充填して用いる毛髪洗浄剤組成物を提供するものである。
（Ａ）アニオン性界面活性剤を含む界面活性剤
（Ｂ）カチオン化ポリマー
（Ｃ）ポリオキシプロピレンポリグリセリルエーテル
The present invention provides a hair cleansing composition containing the following components (A) to (C) and used by filling in a foam discharge container.
(A) Surfactant (B) containing an anionic surfactant (B) cationized polymer (C) polyoxypropylene polyglyceryl ether
また、本発明は、上記本発明における毛髪洗浄剤組成物を前記泡吐出容器から吐出して毛髪に適用し、洗い流すことを含む、毛髪の洗浄方法を提供するものである。 The present invention also provides a method for washing hair, which comprises the steps of: discharging the hair cleansing composition according to the present invention from the foam discharge container, applying the composition to the hair, and washing the hair.
本発明によれば、良質な泡を吐出でき、低温時（−５℃）でも保存安定性が高く、洗髪時（皮脂存在下で）の泡量および泡質が良好であり、更に毛髪すすぎ時の滑らかさに優れる、泡吐出容器に充填して用いる毛髪洗浄剤組成物を提供することができる。 According to the present invention, high-quality foam can be discharged, storage stability is high even at low temperature (-5 ° C), foam volume and foam quality are good during hair-washing (in the presence of sebum), and also during hair rinse It is possible to provide a hair cleansing composition that is used by filling in a foam discharge container and having excellent smoothness.
以下、本発明の実施の形態について、具体例を挙げて説明する。なお、各成分はいずれも単独でまたは２種以上を組み合わせて用いることができる。 Hereinafter, embodiments of the present invention will be described by way of specific examples. In addition, each component can be used individually or in combination of 2 or more types.
本実施形態における毛髪洗浄剤組成物は、上述した成分（Ａ）〜（Ｃ）を含む組成物である。また、本実施形態における毛髪洗浄剤組成物は、泡吐出容器に充填して用いるものである。以下、各成分について説明する。 The hair cleansing composition in the present embodiment is a composition containing the components (A) to (C) described above. In addition, the hair cleanser composition in the present embodiment is used by filling in a foam discharge container. Each component will be described below.
（成分（Ａ））
成分（Ａ）は少なくとも１種のアニオン性界面活性剤を含む界面活性剤である。界面活性剤の具体例として、アニオン性界面活性剤、カチオン性界面活性剤、ノニオン性界面活性剤、両性界面活性剤等が挙げられる。これらは単独で用いても２種類以上併用してもよい。
(Component (A))
Component (A) is a surfactant comprising at least one anionic surfactant. Specific examples of the surfactant include anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants and the like. These may be used alone or in combination of two or more.
毛髪洗浄剤組成物中の成分（Ａ）の界面活性剤の総含有量は、組成物の低温保存安定性（−５℃）および吐出時の泡質を向上させる観点、洗髪時の良好な泡立ち（泡量）を付与する観点ならびにすすぎ時の毛髪への滑らかさ付与の観点から、毛髪洗浄剤組成物全体に対して例えば５質量％以上であり、好ましくは６質量％以上、より好ましくは７質量％以上、さらに好ましくは８質量％以上、さらにより好ましくは９質量％以上、殊更好ましくは１１質量％以上であり、また、例えば２０質量％以下であり、好ましくは１７質量％以下、より好ましくは１５質量％以下である。 The total content of the surfactant of the component (A) in the hair cleansing composition improves the low-temperature storage stability (-5.degree. C.) of the composition and the foam quality at the time of discharge, From the viewpoint of imparting (foam amount) and the viewpoint of imparting smoothness to hair at the time of rinsing, it is, for example, 5% by mass or more, preferably 6% by mass or more, more preferably 7% by mass with respect to the entire hair cleansing composition. % By mass, more preferably 8% by mass, still more preferably 9% by mass, particularly preferably 11% by mass, and for example, 20% by mass or less, preferably 17% by mass or less, more preferably Is 15% by mass or less.
（アニオン性界面活性剤）
アニオン性界面活性剤は、毛髪洗浄剤組成物に用いられるものであればよく、その具体例として、アルキル硫酸塩、アルケニル硫酸塩、ポリオキシアルキレンアルキルエーテル硫酸塩、ポリオキシアルキレンアルケニルエーテル硫酸塩等の硫酸塩型アニオン性界面活性剤；スルホコハク酸アルキルエステル塩、ポリオキシアルキレンスルホコハク酸アルキルエステル塩、アルカンスルホン酸塩等のスルホン酸型アニオン性界面活性剤；高級脂肪酸塩、ポリオキシアルキレンアルキルエーテルカルボン酸またはその塩等のカルボン酸型アニオン性界面活性剤が挙げられる。これらは単独で用いても２種類以上併用してもよい。
(Anionic surfactant)
The anionic surfactant may be any one as long as it is used in a hair cleansing composition, and specific examples thereof include alkyl sulfates, alkenyl sulfates, polyoxyalkylene alkyl ether sulfates, polyoxyalkylene alkenyl ether sulfates, etc. Sulfate type anionic surfactants; Sulfonic acid alkyl ester salts, polyoxyalkylene sulfosuccinic acid alkyl ester salts, sulfonic acid type anionic surfactants such as alkane sulfonates; Higher fatty acid salts, polyoxyalkylene alkyl ether carboxylic acids And carboxylic acid type anionic surfactants such as acids or salts thereof. These may be used alone or in combination of two or more.
中でも、ポリオキシアルキレンアルキルエーテル硫酸塩、ポリオキシアルキレンアルケニルエーテル硫酸塩、アルキル硫酸塩、アルケニル硫酸塩が好ましく、中でも、ポリオキシアルキレンアルキルエーテル硫酸塩としては、下記一般式（１）で表されるポリオキシエチレンアルキルエーテル硫酸塩が好ましい。 Among them, polyoxyalkylene alkyl ether sulfates, polyoxyalkylene alkenyl ether sulfates, alkyl sulfates and alkenyl sulfates are preferable, and among them, polyoxyalkylene alkyl ether sulfates are represented by the following general formula (1) Polyoxyethylene alkyl ether sulfates are preferred.
Ｒ1Ｏ（ＣＨ2ＣＨ2Ｏ）aＳＯ3Ｍ （１）
〔上記一般式（１）中、Ｒ1は炭素数８以上１８以下の直鎖または分岐鎖のアルキル基またはアルケニル基を示し、Ｍはアルカリ金属、アルカリ土類金属、アンモニウム、アルカノールアミンまたは塩基性アミノ酸を示し、ａはエチレンオキシドの平均付加モル数であり、質量平均で０．５以上５以下の数を示す。〕
R 1 O (CH 2 CH 2 O) a SO 3 M (1)
[In the general formula (1), R 1 represents a linear or branched alkyl or alkenyl group having 8 to 18 carbon atoms, and M represents an alkali metal, an alkaline earth metal, ammonium, an alkanolamine or a basic group An amino acid is shown, a is an average added mole number of ethylene oxide, and shows a number of 0.5 or more and 5 or less by mass average. ]
これらの中でも、すばやい泡立ちと良好な泡の感触を両立する観点から、一般式（１）中のＲ1が炭素数１２以上１４以下の直鎖のアルキル基であるものが好ましい。また、エチレンオキシド（ＥＯ）の平均付加モル数ａは、０．９以上４以下であるのが好ましく、１以上３以下であるのがより好ましい。さらに、Ｍがアンモニウムまたはナトリウムであるポリオキシエチレンアルキルエーテル硫酸塩が好ましく、ラウレス硫酸アンモニウム、ラウレス硫酸ナトリウムがより好ましい。 Among these, from the viewpoint of achieving both quick bubbling and good foam feeling, it is preferable that R 1 in the general formula (1) is a linear alkyl group having 12 to 14 carbon atoms. The average addition mole number a of ethylene oxide (EO) is preferably 0.9 or more and 4 or less, and more preferably 1 or more and 3 or less. Furthermore, polyoxyethylene alkyl ether sulfates in which M is ammonium or sodium are preferable, and ammonium laureth sulfate and sodium laureth sulfate are more preferable.
また、アニオン性界面活性剤がカルボン酸型アニオン性界面活性剤を含むとき、カルボン酸型アニオン性界面活性剤は、好ましくはポリオキシアルキレンアルキルエーテルカルボン酸塩であり、より好ましくは下記一般式（３）で表されるポリオキシエチレンアルキルエーテルである。 When the anionic surfactant contains a carboxylic acid type anionic surfactant, the carboxylic acid type anionic surfactant is preferably a polyoxyalkylene alkyl ether carboxylate, more preferably the following general formula ( It is a polyoxyethylene alkyl ether represented by 3).
Ｒ3Ｏ−（ＣＨ2−ＣＨ2Ｏ）s−ＣＨ2ＣＯＯＸ （３）
〔上記一般式（３）中、Ｒ3は炭素数１０以上１８以下の直鎖または分岐鎖のアルキル基またはアルケニル基を示し、Ｘはアルカリ金属、アルカリ土類金属、アンモニウム、アルカノールアミンまたは塩基性アミノ酸由来のカチオンを示し、ｓはエチレンオキシドの平均付加モル数であり、質量平均で０．５以上１５以下の数を示す。〕
R 3 O- (CH 2 -CH 2 O) s -CH 2 COOX (3)
[In the above general formula (3), R 3 represents a linear or branched alkyl or alkenyl group having 10 to 18 carbon atoms, and X represents an alkali metal, an alkaline earth metal, ammonium, an alkanolamine or a basic group The cation derived from an amino acid is shown, s is the average added mole number of ethylene oxide, and shows the number of 0.5 or more and 15 or less by mass average. ]
これらの中でも、洗浄時の泡立ちを豊かにする観点から、一般式（３）中のＲ3が炭素数１２以上１６以下の直鎖のアルキル基であるものが好ましい。また、エチレンオキシド（ＥＯ）の平均付加モル数ｓは、１以上６以下であるのが好ましい。さらに、Ｘがアンモニウムまたはナトリウムであるポリオキシエチレンアルキルエーテルカルボン酸塩が好ましく、ラウレスカルボン酸アンモニウム、ラウレスカルボン酸ナトリウムがより好ましい。
また、アニオン性界面活性剤が、ポリオキシアルキレンアルキルエーテルカルボン酸塩と前述のポリオキシエチレンアルキルエーテル硫酸塩とを含むことも好ましい。
Among these, from the viewpoint of enriching foaming at the time of washing, it is preferable that R 3 in the general formula (3) is a linear alkyl group having 12 to 16 carbon atoms. Further, the average addition mole number s of ethylene oxide (EO) is preferably 1 or more and 6 or less. Furthermore, polyoxyethylene alkyl ether carboxylates in which X is ammonium or sodium are preferable, and ammonium laureth carboxylate and sodium laureth carboxylate are more preferable.
It is also preferred that the anionic surfactant comprises a polyoxyalkylene alkyl ether carboxylate and the aforementioned polyoxyethylene alkyl ether sulfate.
毛髪洗浄剤組成物中のアニオン性界面活性剤の含有量は、泡立ちをさらにより向上させる観点から、毛髪洗浄剤組成物全体に対して、好ましくは５質量％以上であり、より好ましくは６質量％以上、さらにより好ましくは７質量％以上、殊更好ましくは８質量％以上である。また、泡切れの向上およびすすぎ時の毛髪のきしみを抑制する観点から、毛髪洗浄剤組成物全体に対するアニオン性界面活性剤の含有量は、好ましくは２０質量％以下であり、より好ましくは１７質量％以下、さらに好ましくは１５質量％以下、さらにより好ましくは１３質量％以下、殊更好ましくは１２質量％以下である。 The content of the anionic surfactant in the hair cleanser composition is preferably 5% by mass or more, more preferably 6% by mass, based on the whole hair cleanser composition, from the viewpoint of further improving foaming. % Or more, further more preferably 7% by mass or more, particularly preferably 8% by mass or more. Moreover, from the viewpoint of improving the foam break and suppressing the texture of the hair at the time of rinsing, the content of the anionic surfactant with respect to the entire hair cleansing composition is preferably 20% by mass or less, more preferably 17%. % Or less, more preferably 15% by mass or less, even more preferably 13% by mass or less, particularly preferably 12% by mass or less.
また、毛髪洗浄剤組成物中の成分（Ａ）の含有量に対するアニオン性界面活性剤の含有量の質量割合（（アニオン性界面活性剤）／（Ａ））は、組成物の低温保存安定性（−５℃）および吐出時の泡質を向上させる観点、洗髪時の良好な泡立ち（泡量）を付与する観点ならびにすすぎ時の毛髪への滑らかさ付与の観点から、好ましくは０．２５以上であり、より好ましくは０．３０以上、さらに好ましくは０．５以上であり、また、好ましくは１．０以下であり、より好ましくは０．８５以下、さらに好ましくは０．７５以下である。 In addition, the mass ratio of the content of the anionic surfactant to the content of the component (A) in the hair cleansing composition ((anionic surfactant) / (A)) is the low-temperature storage stability of the composition (−5 ° C.) and a viewpoint of improving foam quality at the time of discharge, a viewpoint of imparting good lathering (foam amount) at the time of hair washing, and a viewpoint of imparting smoothness to hair at the time of rinsing More preferably, it is 0.30 or more, more preferably 0.5 or more, preferably 1.0 or less, more preferably 0.85 or less, and still more preferably 0.75 or less.
（カチオン性界面活性剤）
カチオン性界面活性剤は、毛髪洗浄剤組成物に用いられるものであればよく、その具体例として、第３級アミン化合物またはその塩および第４級アンモニウム塩が挙げられる。より具体的には、特開２０１７−１９７４８号公報に記載のカチオン性界面活性剤を用いることができる。これらは単独で用いても２種類以上併用してもよい。
(Cationic surfactant)
The cationic surfactant may be any one as long as it is used in a hair cleansing composition, and specific examples thereof include tertiary amine compounds or salts thereof and quaternary ammonium salts. More specifically, the cationic surfactant described in JP-A-2017-19748 can be used. These may be used alone or in combination of two or more.
毛髪洗浄剤組成物中のカチオン性界面活性剤の含有量は、すすぎ時の毛髪のきしみを抑制する観点から、毛髪洗浄剤組成物全体に対して好ましくは０．０５質量％以上であり、より好ましくは０．１０質量％以上、さらに好ましくは０．２質量％以上、さらにより好ましくは０．３質量％以上であり、また、好ましくは２質量％以下であり、より好ましくは１．０質量％以下、さらに好ましくは０．７質量％以下である。 The content of the cationic surfactant in the hair cleansing composition is preferably 0.05% by mass or more with respect to the entire hair cleansing composition, from the viewpoint of suppressing hair blemishes during rinsing. The content is preferably 0.10% by mass or more, more preferably 0.2% by mass or more, still more preferably 0.3% by mass or more, preferably 2% by mass or less, more preferably 1.0% by mass % Or less, more preferably 0.7% by mass or less.
（ノニオン性界面活性剤）
成分（Ａ）は、組成物の低温保存安定性（−５℃）および吐出時の泡質をさらに向上させる観点、洗髪時の良好な泡立ち（泡量）を付与する観点ならびにすすぎ時の毛髪への滑らかさ付与の観点から、好ましくはノニオン性界面活性剤を更に含む。
ノニオン性界面活性剤は、毛髪洗浄剤組成物に用いられるものであればよく、その具体例として、アルキルポリグリコシド；ポリオキシエチレンラウリルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンイソステアリルエーテル、ポリプロピレングリコールカプリリルエーテル等のポリオキシアルキレンアルキルエーテル；ポリオキシエチレン硬化ヒマシ油；グリセリン脂肪酸エステル；ソルビタン脂肪酸エステル；ポリオキシアルキレンソルビトール脂肪酸エステル；ポリエチレングリコール脂肪酸エステル等の（ポリ）エチレングリコール脂肪酸エステル；ポリオキシアルキレン脂肪酸エステル；ポリオキシエチレンソルビタン脂肪酸エステル等のポリオキシアルキレンソルビタン脂肪酸エステル；２−エチルヘキシルグリセリルエーテル、イソデシルグリセリルエーテル等のモノアルキルグリセリルエーテル；モノアルケニルグリセリルエーテル；ヤシ油脂肪酸モノエタノールアミド、ヤシ油脂肪酸Ｎ−メチルモノエタノールアミド等の脂肪酸モノアルカノールアミド等が挙げられる。ノニオン性界面活性剤におけるアルキル基は直鎖であってもよいし分岐であってもよい。これらは単独で用いても２種類以上併用してもよい。
(Nonionic surfactant)
Component (A) is a viewpoint of further improving the low temperature storage stability (-5 ° C.) of the composition and foam quality at the time of discharge, a viewpoint of imparting a good foaming (foam amount) at the time of hair washing, and Preferably, a nonionic surfactant is further included from the viewpoint of imparting smoothness.
The nonionic surfactant may be any one as long as it is used in a hair detergent composition, and specific examples thereof include alkyl polyglycosides; polyoxyethylene lauryl ether, polyoxyethylene stearyl ether, polyoxyethylene isostearyl ether, polypropylene Polyoxyalkylene alkyl ethers such as glycol caprylyl ether; polyoxyethylene hydrogenated castor oil; glycerin fatty acid ester; sorbitan fatty acid ester; polyoxyalkylene sorbitol fatty acid ester; (poly) ethylene glycol fatty acid ester such as polyethylene glycol fatty acid ester; Alkylene fatty acid ester; polyoxyalkylene sorbitan fatty acid ester such as polyoxyethylene sorbitan fatty acid ester; 2-ethyl ether Sill glyceryl ether, monoalkyl glyceryl ethers such as isodecyl glyceryl ether; monoalkenyl glyceryl ether; coconut oil fatty acid monoethanolamide, fatty acid monoalkanolamides, such as coconut oil fatty acid N- methyl monoethanolamide, and the like. The alkyl group in the nonionic surfactant may be linear or branched. These may be used alone or in combination of two or more.
これらの中でも下記の一般式（２）で表される化合物を含む化合物を含むノニオン性界面活性剤が、良好な泡立ちを得る観点から好ましい。
Ｒ2−Ｏ−（ＣＨ2ＣＨ2−Ｏ）n−Ｈ （２）
〔上記一般式（２）中、Ｒ2は炭素数１２〜２４の直鎖または分岐のアルキル基またはアルケニル基を示し、ｎは１〜５０の数を示す。〕
これらの中でも、すばやい泡立ちと良好な泡の感触を両立する観点から、一般式（２）中のＲ2が炭素数１２以上２０以下の直鎖のアルキル基であるものが好ましい。また、エチレンオキシドの平均付加モル数ｎは、１以上２５以下であるのが好ましい。
Among these, nonionic surfactants containing a compound containing a compound represented by the following general formula (2) are preferable from the viewpoint of obtaining good foaming.
R 2 -O- (CH 2 CH 2 -O) n -H (2)
[In the above general formula (2), R 2 represents a linear or branched alkyl or alkenyl group having 12 to 24 carbon atoms, and n represents a number of 1 to 50]. ]
Among these, from the viewpoint of achieving both quick bubbling and good foam feeling, it is preferable that R 2 in the general formula (2) is a linear alkyl group having 12 to 20 carbon atoms. The average added mole number n of ethylene oxide is preferably 1 or more and 25 or less.
毛髪洗浄剤組成物中のノニオン性界面活性剤の含有量は、組成物の低温保存安定性（−５℃）および吐出時の泡質を向上させる観点、洗髪時の良好な泡立ち（泡量）を付与する観点ならびにすすぎ時の毛髪への滑らかさ付与の観点から、毛髪洗浄剤組成物全体に対して好ましくは０．１質量％以上であり、より好ましくは０．５質量％以上、さらに好ましくは１．０質量％以上であり、また、好ましくは１０質量％以下であり、より好ましくは７質量％以下、さらに好ましくは５質量％以下である。 The content of the nonionic surfactant in the hair cleanser composition is the viewpoint of improving the low-temperature storage stability (-5 ° C.) of the composition and the foam quality at the time of discharge, good lathering during shampooing (foam amount) Preferably, it is 0.1% by mass or more, more preferably 0.5% by mass or more, more preferably from the viewpoint of imparting the oil and imparting smoothness to the hair when rinsing. Is 1.0% by mass or more, preferably 10% by mass or less, more preferably 7% by mass or less, and still more preferably 5% by mass or less.
（両性界面活性剤）
両性界面活性剤は、毛髪洗浄剤組成物に用いられるものであればよく、ベタイン型界面活性剤、アミノ酸型界面活性剤、イミダゾリン型界面活性剤、アミノキサイド型界面活性剤等が挙げられる。これらは単独で用いても２種類以上併用してもよい。
このうち、ベタイン型界面活性剤の具体例として、アルキルカルボベタイン等のカルボベタイン型界面活性剤；アルキルスルホベタイン、ラウリルヒドロキシスルタイン等のアルキルヒドロキシスルホベタイン、アルキルアミドヒドロキシスルホベタイン等のスルホベタイン型界面活性剤；アルキルアミドアミン型ベタイン；アルキルイミダゾリン型ベタイン等が挙げられる。
このうち、泡質と洗い上がりの使用感の点から、両性界面活性剤は、好ましくは炭素数８〜１８のアルキル基を有するアルキルアミドプロピルベタインまたはアルキルヒドロキシスルホベタインであり、より好ましくはアルキルヒドロキシスルホベタインであり、さらに好ましくはヤシ油脂肪酸ヒドロキシスルホベタイン、ラウリルヒドロキシスルホベタイン、ミリスチルヒドロキシスルホベタインからなる群から選択される１種以上であり、さらにより好ましくはラウリルヒドロキシスルホベタインである。
また、炭素数８〜１４のアルキル基を有するアルキルアミドプロピルベタインは、好ましくはラウラミドプロピルベタインである。
(Ampholytic surfactant)
The amphoteric surfactant may be any one as long as it is used in a hair cleansing composition, and examples thereof include betaine type surfactants, amino acid type surfactants, imidazoline type surfactants, aminoxide type surfactants and the like. These may be used alone or in combination of two or more.
Among them, specific examples of betaine-type surfactants include carbobetaine-type surfactants such as alkylcarbobetaines; alkylsulfobetaines such as alkylsulfobetaines and laurylhydroxysultanes; sulfobetaine-types such as alkylamidohydroxysulfobetaines and the like Surfactants; alkylamidoamine type betaines; alkyl imidazoline type betaines and the like.
Among them, the amphoteric surfactant is preferably alkylamidopropyl betaine or alkylhydroxysulfobetaine having an alkyl group having 8 to 18 carbon atoms, from the viewpoint of foam quality and sense of use after washing, and more preferably alkylhydroxyl. It is a sulfobetaine, more preferably one or more selected from the group consisting of coconut oil fatty acid hydroxysulfobetaine, lauryl hydroxysulfobetaine and myristyl hydroxysulfobetaine, and still more preferably lauryl hydroxysulfobetaine.
The alkylamidopropyl betaine having an alkyl group having 8 to 14 carbon atoms is preferably lauramidopropyl betaine.
毛髪洗浄剤組成物全体に対する両性界面活性剤の含有量は、泡立ちを向上させる観点およびすすぎ時の毛髪のきしみを抑制する観点から、好ましくは０．１質量％以上であり、より好ましくは０．２質量％以上、さらに好ましくは０．５質量％以上であり、また、好ましくは１０質量％以下であり、より好ましくは５質量％以下、さらに好ましくは４質量％以下、さらに好ましくは３質量％以下、さらに好ましくは２質量％以下である。 The content of the amphoteric surfactant with respect to the entire hair cleansing composition is preferably 0.1% by mass or more, more preferably 0.% from the viewpoint of improving lathering and suppressing hair texture at the time of rinsing. It is 2% by mass or more, more preferably 0.5% by mass or more, preferably 10% by mass or less, more preferably 5% by mass or less, still more preferably 4% by mass or less, still more preferably 3% by mass The content is more preferably 2% by mass or less.
（成分（Ｂ））
成分（Ｂ）は、カチオン化ポリマーである。カチオン化ポリマーの具体例として、カチオン化グァーガム（例えば、ソルベイ社製のジャガーＣ１４、ジャガーＣ１７やジャガーＥｘｃｅｌ）、カチオン化タラガム（例えば、東邦化学社製のカチナールＣＴＲ−１００）、カチオン化ローカストビーンガム（ローカストビーンヒドロキシプロピルトリモニウムクロリド；例えば、東邦化学社製のカチナールＣＬＢ−１００）、カチオン化フェヌグリークガム（例えば、東邦化学社製のカチナールＣＦ−１００）等のカチオン化ガラクトマンナンのほか、カチオン化キサンタンガム、カチオン化セルロース（例えばポリクオタニウム−１０；例えば、花王社製のポイズＣ−６０Ｈ、ポイズＣ−８０Ｍ、ポイズＣ−１５０Ｌ）、カチオン化デンプン、ジアリルジメチル四級アンモニウム塩のホモポリマー（ポリクオタニウム−６；例えば、ルーブリゾール社製のマーコート１００）、ジアリルジメチル四級アンモニウム塩／アクリルアミド共重合物（ポリクオタニウム−７；例えば、ルーブリゾール社製のマーコート５５０、マーコート７４０、マーコート２２００）、ジアリルジメチル四級アンモニウム塩／アクリル酸共重合物（ポリクオタニウム−２２；例えば、ルーブリゾール社製のマーコート２８０）、Ｎ，Ｎ−ジメチルアミノエチルメタクリル酸ジエチル硫酸塩・Ｎ，Ｎ−ジメチルアクリルアミド・ジメタクリル酸ポリエチレングリコール共重合体（ポリクオタニウム−５２；例えば、花王社製のソフケアＫＧ−１０１Ｅ、ソフケアＫＧ−３０１Ｗ）、四級化ポリビニルピロリドン誘導体、ポリグリコールポリアミン縮合物、ビニルイミダゾリウムトリクロライド／ビニルピロリドン共重合体、ヒドロキシエチルセルロース／ジメチルジアリルアンモニウムクロライド共重合体（ポリクオタニウム−４；例えば、アクゾノーベル社製のセルコートＬ２００）、ビニルピロリドン／四級化ジメチルアミノエチルメタクリレート共重合体（ポリクオタニウム−１１；例えば、アシュランド社製のガフカット７５５）、ポリビニルピロリドン／アルキルアミノアクリレート共重合体、ポリビニルピロリドン／アルキルアミノアクリレート／ビニルカプロラクタム共重合体（例えば、アシュランド社製のコポリマー８４５、９３７、９５８）、ビニルピロリドン／メタクリルアミドプロピル塩化トリメチルアンモニウム共重合体（アシュランド社製のガフカットＨＳ−１００）、アルキルアクリルアミド／アクリレート／アルキルアミノアルキルアクリルアミド／ポリエチレングリコールメタクリレート共重合体、アジピン酸／ジメチルアミノヒドロキシプロピルエチレントリアミン共重合体（米国サンドス社製カルタレチン）、特開昭５３−１３９７３４号公報、特開昭６０−３６４０７号公報に記載されているカチオン化ポリマー等が挙げられる。
(Component (B))
Component (B) is a cationized polymer. Specific examples of the cationized polymer include cationized guar gum (eg, Solvay Jaguar C14, Jaguar C17 and Jaguar Excel), cationized cod gum (eg, Toho Chemical Inc. Catal CTR-100), cationized locust bean gum In addition to cationized galactomannans such as (Locust bean hydroxypropyltrimonium chloride; for example, Catalun CLB-100 made by Toho Chemical Co., Ltd.), cationized fenugreek gum (for example, Cathinal CF-100 made by Toho Chemical Co., Ltd.) Xanthan gum, cationized cellulose (for example, polyquaternium-10; for example, Kao Poise C-60H, Poise C-80M, Poise C-150L), cationized starch, diallyl dimethyl quaternary ammonium salt Polymer (polyquaternium-6; for example, mer coat 100 manufactured by Lubrizol), diallyldimethyl quaternary ammonium salt / acrylamide copolymer (polyquaternium-7; for example, mer coat 550, mer coat 740, mer coat 2200, for example, made by Lubrisol) Diallyldimethyl quaternary ammonium salt / acrylic acid copolymer (polyquaternium-22; for example, Mercot 280 manufactured by Lubrizol Corporation), N, N-dimethylaminoethyl methacrylate diethyl sulfate, N, N-dimethylacrylamide, dimethacrylic Acid polyethylene glycol copolymer (polyquaternium-52; for example, Sofcare KG-101E, Sofcare KG-301W manufactured by Kao Corporation), quaternized polyvinylpyrrolidone derivative, polyglycol polyamine condensation , Vinyl imidazolium trichloride / vinyl pyrrolidone copolymer, hydroxyethyl cellulose / dimethyldiallyl ammonium chloride copolymer (polyquaternium-4; eg, Celcoat L200 manufactured by Akzo Nobel Co., Ltd.), vinyl pyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer Polymer (Polyquaternium-11; for example, Gaffcut 755 manufactured by Ashland Co., Ltd.), polyvinylpyrrolidone / alkylaminoacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer (eg, Copolymer 845 manufactured by Ashland Co., Ltd.) , 937, 958), vinylpyrrolidone / methacrylamidopropyl trimethyl ammonium chloride copolymer (Gafcut HS-10 manufactured by Ashland Co., Ltd.) 0), alkyl acrylamide / acrylate / alkyl amino alkyl acrylamide / polyethylene glycol methacrylate copolymer, adipic acid / dimethylaminohydroxypropyl ethylene triamine copolymer (cartaretin manufactured by US Sandos Co., Ltd.), JP-A-53-139734, especially The cationized polymer etc. which are described in Unexamined-Japanese-Patent No. 60-36407 are mentioned.
中でも、洗髪時の良好な泡立ち（泡量）および良好な泡質を付与する観点ならびにすすぎ時の毛髪への滑らかさ付与の観点から、成分（Ｂ）が、カチオン化ガラクトマンナン、カチオン化デンプン、ポリクオタニウム−６、ポリクオタニウム−７、ポリクオタニウム−１０、ポリクオタニウム−２２およびポリクオタニウム−５２からなる群より選択される１種以上であることが好ましい。更に、成分（Ｂ）は、カチオン化ガラクトマンナン、ポリクオタニウム−６、ポリクオタニウム−７、ポリクオタニウム−１０およびポリクオタニウム−２２からなる群より選択される少なくとも１種であることがより好ましい。これら成分（Ｂ）は、いずれかを単独でまたは２種以上を組み合わせて使用することができる。 Above all, the component (B) is a cationized galactomannan, a cationized starch, from the viewpoint of giving a good lathering (foaming amount) and a good lather quality at the time of shampooing and giving a smoothness to the hair at the time of rinsing. It is preferable that it is 1 or more types selected from the group which consists of polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-22, and polyquaternium-52. Furthermore, component (B) is more preferably at least one selected from the group consisting of cationized galactomannan, polyquaternium-6, polyquaternium-7, polyquaternium-10 and polyquaternium-22. These components (B) can be used singly or in combination of two or more.
毛髪洗浄剤組成物全体に対する成分（Ｂ）の含有量は、洗髪時の良好な泡質を付与する観点およびすすぎ時の毛髪への滑らかさ付与の観点から、好ましくは０．０１質量％以上であり、より好ましくは０．０１５質量％以上、さらに好ましくは０．０３質量％以上、さらに好ましくは０．０５質量％以上であり、また、吐出時の泡質を向上させる観点から、好ましくは１．０質量％以下であり、より好ましくは０．８質量％以下、さらに好ましくは０．７質量％以下、さらに好ましくは０．５質量％以下、さらに好ましくは０．３０質量％以下、さらに好ましくは０．２５質量％以下である。 The content of the component (B) with respect to the entire hair cleansing composition is preferably 0.01% by mass or more from the viewpoint of imparting a good foam during hair washing and from the viewpoint of imparting smoothness to hair during rinsing. It is more preferably 0.015% by mass or more, still more preferably 0.03% by mass or more, still more preferably 0.05% by mass or more, and preferably 1 from the viewpoint of improving the foam quality at the time of discharge. .0 mass% or less, more preferably 0.8 mass% or less, still more preferably 0.7 mass% or less, still more preferably 0.5 mass% or less, still more preferably 0.30 mass% or less, more preferably Is not more than 0.25% by mass.
（成分（Ｃ））
成分（Ｃ）は、ポリオキシプロピレンポリグリセリルエーテルであり、ここでは、２分子以上のグリセリンと２分子以上のプロピレンオキシドとの縮合物を示し、更には、２分子以上のグリセリンが縮合したポリグリセリンと、２分子以上のプロピレンオキシドの縮合物である。
(Component (C))
The component (C) is a polyoxypropylene polyglyceryl ether, and here shows a condensate of 2 or more molecules of glycerin and 2 or more molecules of propylene oxide, and further, polyglycerin in which 2 or more molecules of glycerin are condensed and And a condensate of two or more molecules of propylene oxide.
成分（Ｃ）中のグリセリンの重合度は、毛髪洗浄剤組成物の粘度を低下させる観点および洗髪時の良好な泡質を得る観点、すすぎ時の毛髪のきしみ感を抑制する観点から、２以上であり、好ましくは２以上１０以下、より好ましくは２以上５以下、さらに好ましくは２以上３以下、さらにより好ましくは２である。 The polymerization degree of glycerin in the component (C) is at least 2 from the viewpoint of lowering the viscosity of the hair cleansing composition, from the viewpoint of obtaining good foam quality at the time of hair washing, and from the viewpoint of suppressing the feeling of hair squeezing at the time of rinsing It is preferably 2 or more and 10 or less, more preferably 2 or more and 5 or less, further preferably 2 or more and 3 or less, and still more preferably 2.
また、成分（Ｃ）におけるプロピレンオキシドの付加モル数は、洗髪時の良好な泡質の付与およびすすぎ時の髪のきしみの抑制の観点から、好ましくは３以上であり、より好ましくは５以上、さらに好ましくは７以上、さらにより好ましくは９以上であり、また、好ましくは２４以下であり、より好ましくは２０以下、さらに好ましくは１５以下、さらにより好ましくは１４以下である。同様の観点から、成分（Ｃ）におけるプロピレングリコールの付加モル数は、好ましくは３以上２４以下であり、より好ましくは３以上２０以下、さらに好ましくは５以上１５以下、さらにより好ましくは７以上１４以下、殊更好ましくは９以上１４以下である。 In addition, the number of moles of propylene oxide added in component (C) is preferably 3 or more, more preferably 5 or more, from the viewpoint of imparting good foam quality at the time of shampooing and suppressing hair squeaking at the time of rinsing. More preferably, it is 7 or more, further more preferably 9 or more, and preferably 24 or less, more preferably 20 or less, still more preferably 15 or less, still more preferably 14 or less. From the same viewpoint, the addition mole number of propylene glycol in the component (C) is preferably 3 or more and 24 or less, more preferably 3 or more and 20 or less, still more preferably 5 or more and 15 or less, still more preferably 7 or more and 14 or more. Particularly preferably 9 or more and 14 or less.
成分（Ｃ）として用いることができる市販品の例として、日油社製のポリオキシプロピレンジグリセリルエーテルであるユニルーブ ＤＧＰ−７００（ＰＰＧ−９ジグリセリル）、ユニルーブ ＤＧＰ−７００Ｆ（ＰＰＧ−９ジグリセリル）、ユニルーブ ＤＧＰ−９５０（ＰＰＧ−１４ジグリセリル）；阪本薬品工業社製のポリオキシプロピレンジグリセリルエーテルであるＳＹ−ＤＰ９（ＰＰＧ−９ジグリセリル）、ＳＹ−ＤＰ１４（ＰＰＧ−１４ポリグリセリル−２エーテル）、ＳＹ−ＤＰ１４Ｔ（ＰＰＧ−１４ポリグリセリル−２エーテル）；ならびに阪本薬品工業社製のポリオキシプロピレンポリグリセリルエーテルであるＳＣ−Ｐ７５０（ＰＯＰ（９）ポリグリセリルエーテル）、ＳＣ−Ｐ１０００（ＰＯＰ（１４）ポリグリセリルエーテル）、ＳＣ−Ｐ１６００（ＰＯＰ（２４）ポリグリセリルエーテル）が挙げられる。これらは単独で用いても２種類以上併用してもよい。 As an example of the commercial item which can be used as component (C), Unilobe DGP-700 (PPG-9 diglyceryl) which is a polyoxypropylene diglyceryl ether manufactured by NOF Corporation, Unilobe DGP-700F (PPG-9 diglyceryl) Unilobe DGP-950 (PPG-14 diglyceryl); SY-DP9 (PPG-9 diglyceryl) which is a polyoxypropylene diglyceryl ether manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. SY-DP14 (PPG-14 polyglyceryl-2 ether) And SY-DP 14 T (PPG-14 polyglyceryl-2 ether); and SC-P 750 (POP (9) polyglyceryl ether) which is a polyoxypropylene polyglyceryl ether manufactured by Sakamoto Yakuhin Kogyo Co., SC-P 1000 (POP (14) polyglycerin). Ether), SC-P1600 (POP (24) polyglyceryl ether) and the like. These may be used alone or in combination of two or more.
毛髪洗浄剤組成物中の成分（Ｃ）の含有量は、成分（Ｂ）の種類ならびに含有量等を踏まえて決めることができるが、洗髪時の良好な泡立ち（泡量）および良好な泡質を付与する観点ならびにすすぎ時の毛髪への滑らかさ付与の観点から、例えば０．０１質量％以上であり、好ましくは０．０２５質量％以上、より好ましくは０．０５質量％以上、さらに好ましくは０．０７５質量％以上、さらにより好ましくは０．１０質量％以上、さらにより好ましくは０．２質量％以上であり、また、例えば１０質量％以下であり、好ましくは５質量％以下、より好ましくは４質量％以下、さらに好ましくは３質量％以下、さらにより好ましくは２質量％以下、さらにより好ましくは１．０質量％以下、さらにより好ましくは０．７５質量％以下、さらにより好ましくは０．５質量％以下、さらにより好ましくは０．３質量％以下である。 The content of the component (C) in the hair cleanser composition can be determined based on the type and content of the component (B), etc., but good lathering (foaming amount) and good lather quality at the time of hair washing From the viewpoint of imparting saturability and the provision of smoothness to the hair during rinsing, it is, for example, 0.01 mass% or more, preferably 0.025 mass% or more, more preferably 0.05 mass% or more, still more preferably It is 0.075% by mass or more, further more preferably 0.10% by mass or more, still more preferably 0.2% by mass or more, and for example, 10% by mass or less, preferably 5% by mass or less, more preferably Is 4% by mass or less, more preferably 3% by mass or less, still more preferably 2% by mass or less, still more preferably 1.0% by mass or less, still more preferably 0.75% by mass or less More preferably 0.5 mass% or less, still more preferably not more than 0.3 mass%.
また、毛髪洗浄剤組成物中の成分（Ｂ）の含有量に対する成分（Ｃ）の含有量の質量割合（（Ｃ）／（Ｂ））は、組成物の吐出時の泡質を向上させる観点、洗髪時の良好な泡立ち（泡量）を付与する観点およびすすぎ時の毛髪への滑らかさ付与の観点から、例えば０．１以上であり、好ましくは０．２以上、より好ましくは０．５以上、さらに好ましくは０．７５以上、さらにより好ましくは１．０以上、さらにより好ましくは１．５以上であり、また、好ましくは２０以下であり、より好ましくは１５以下、さらに好ましくは１２以下、さらにより好ましくは８以下、さらにより好ましくは６以下、さらにより好ましくは５以下、さらにより好ましくは４以下、さらにより好ましくは３以下である。 Moreover, the mass ratio ((C) / (B)) of the content of the component (C) to the content of the component (B) in the hair cleansing composition is a viewpoint of improving the foam quality at the time of discharge of the composition And from the viewpoint of imparting good lathering (foaming amount) at the time of hair washing and from the viewpoint of imparting smoothness to hair at the time of rinsing, for example, 0.1 or more, preferably 0.2 or more, more preferably 0.5 Or more, more preferably 0.75 or more, still more preferably 1.0 or more, still more preferably 1.5 or more, preferably 20 or less, more preferably 15 or less, still more preferably 12 or less , Still more preferably 8 or less, still more preferably 6 or less, still more preferably 5 or less, still more preferably 4 or less, still more preferably 3 or less.
次に、毛髪洗浄剤組成物のｐＨについて説明する。
本実施形態において、毛髪洗浄剤組成物を水で２０倍に希釈したときの２５℃におけるｐＨは、毛髪洗浄剤組成物の保存安定性の観点ならびに洗髪時の泡立ちや汚れ落ち性能を向上させる観点から、上記ｐＨは例えば７．０以下、好ましくは６．５以下、より好ましくは６以下である。また、同様の観点から、上記ｐＨが、好ましくは２．５以上であり、より好ましくは３．０以上であり、さらに好ましくは３．５以上である。
Next, the pH of the hair cleansing composition will be described.
In the present embodiment, the pH at 25 ° C. when the hair cleansing composition is diluted 20 times with water is from the viewpoint of storage stability of the hair cleansing composition and from the viewpoint of improving the lathering and stain release performance during hair washing. Therefore, the pH is, for example, 7.0 or less, preferably 6.5 or less, and more preferably 6 or less. Moreover, from the same viewpoint, the pH is preferably 2.5 or more, more preferably 3.0 or more, and still more preferably 3.5 or more.
また、本実施形態における毛髪洗浄剤組成物は好ましくは液状の組成物である。このとき、毛髪洗浄剤組成物の５℃における粘度は、前述の成分（Ａ）、（Ｂ）、（Ｃ）の量ならびに比率、ならびに用いる泡吐出容器の構造や機構にもよるが、毛髪へ塗布しやすい泡質とする観点から、好ましくは１ｍＰａ・ｓ以上であり、より好ましくは２ｍＰａ・ｓ以上、さらに好ましくは３ｍＰａ・ｓ以上であり、また、ノンガス型の泡吐出容器に充填して用いられる際の吐出性を向上させる観点から、好ましくは３００ｍＰａ・ｓ以下であり、より好ましくは２５０ｍＰａ・ｓ以下、さらに好ましくは２００ｍＰａ・ｓ以下である。 Moreover, the hair cleansing composition in the present embodiment is preferably a liquid composition. At this time, the viscosity at 5 ° C. of the hair cleansing composition depends on the amount and ratio of the above-mentioned components (A), (B) and (C), and the structure and mechanism of the foam discharge container used. It is preferably 1 mPa · s or more, more preferably 2 mPa · s or more, still more preferably 3 mPa · s or more, from the viewpoint of making it easy to apply foam, and it is used by filling in a non-gas type foam discharge container The viscosity is preferably 300 mPa · s or less, more preferably 250 mPa · s or less, and still more preferably 200 mPa · s or less from the viewpoint of improving the dischargeability at the time of
ここで、毛髪洗浄剤組成物の粘度は、ブルックフィールド型粘度計（東機産業社製、ＴＶ−１０）により測定される。 Here, the viscosity of the hair cleansing composition is measured by a Brookfield viscometer (TV-10, manufactured by Toki Sangyo Co., Ltd.).
本実施形態における毛髪洗浄剤組成物は、前述した成分（Ａ）〜（Ｃ）以外の成分を含んでもよい。 The hair cleansing composition in the present embodiment may contain components other than the components (A) to (C) described above.
（成分（Ｄ））
毛髪洗浄剤組成物は、更に成分（Ｄ）としてポリプロピレングリコール（ＰＰＧ）を含有し得る。成分（Ｄ）は、ここでは、３分子以上のプロピレングリコールの重合体を示す。
成分（Ｄ）におけるプロピレングリコールの重合度は、洗髪時の良好な泡立ち（泡量）および良好な泡質を付与する観点ならびにすすぎ時の毛髪への滑らかさ付与の観点から、３以上であり、好ましくは５以上、さらに好ましくは７以上であり、また、好ましくは３０以下であり、より好ましくは２６以下、さらに好ましくは２０以下、さらにより好ましくは１７以下である。また、同様の観点から、プロピレングリコールの重合度は好ましくは３以上３０以下であり、より好ましくは重合度が５以上２６以下、さらに好ましくは重合度が７以上２０以下、さらにより好ましくは重合度が７以上１７以下である。
(Component (D))
The hair wash composition may further contain polypropylene glycol (PPG) as component (D). Component (D) here represents a polymer of three or more molecules of propylene glycol.
The degree of polymerization of propylene glycol in the component (D) is 3 or more, from the viewpoint of imparting good lathering (foaming amount) and good lather quality upon hair washing and from the viewpoint of imparting smoothness to hair upon rinsing, Preferably, it is 5 or more, more preferably 7 or more, and preferably 30 or less, more preferably 26 or less, still more preferably 20 or less, and still more preferably 17 or less. From the same point of view, the polymerization degree of propylene glycol is preferably 3 or more and 30 or less, more preferably 5 or more and 26 or less, still more preferably 7 or more and 20 or less, still more preferably the polymerization degree Is 7 or more and 17 or less.
成分（Ｄ）のポリプロピレングリコールの具体例として、ＰＰＧ−３、ＰＰＧ−７、ＰＰＧ−９、ＰＰＧ−１７およびＰＰＧ−６１が挙げられる。これらは単独で用いても２種類以上併用してもよい。 PPG-3, PPG-7, PPG-9, PPG-17 and PPG-61 are mentioned as a specific example of the polypropylene glycol of component (D). These may be used alone or in combination of two or more.
毛髪洗浄剤組成物中の成分（Ｄ）の含有量は、成分（Ａ）の種類および含有量等を踏まえて決めることができるが、洗髪時の良好な泡立ち（泡量）および良好な泡質を付与する観点ならびにすすぎ時の毛髪への滑らかさ付与の観点から、例えば０．０１質量％以上であり、好ましくは０．０２５質量％以上、より好ましくは０．０５質量％以上、さらに好ましくは０．０７５質量％以上、さらにより好ましくは０．１０質量％以上であり、また、例えば５質量％以下であり、好ましくは４質量％以下、より好ましくは３質量％以下、さらに好ましくは２質量％以下、さらにより好ましくは１質量％以下である。 The content of the component (D) in the hair cleanser composition can be determined based on the type and content of the component (A), etc., but good lathering (foaming amount) and good lather quality during hair washing From the viewpoint of imparting saturability and the provision of smoothness to the hair during rinsing, it is, for example, 0.01 mass% or more, preferably 0.025 mass% or more, more preferably 0.05 mass% or more, still more preferably It is 0.075% by mass or more, further more preferably 0.10% by mass or more, and for example, 5% by mass or less, preferably 4% by mass or less, more preferably 3% by mass or less, more preferably 2% by mass % Or less, and even more preferably 1% by mass or less.
本実施形態における毛髪洗浄剤組成物は、さらに水を含んでもよい。水としては、イオン交換水や蒸留水等を用いることができる。
毛髪洗浄剤組成物中の水の含有量は、例えば毛髪洗浄剤中の水以外の成分を除いた残部とすることができる。また、水の含有量は、毛髪洗浄剤組成物全体に対し、５０質量％以上が好ましく、６０質量％以上がより好ましい。また９５質量％以下が好ましく、９２質量％以下がより好ましい。
The hair cleansing composition in the present embodiment may further contain water. As water, ion exchange water, distilled water or the like can be used.
The content of water in the hair cleansing composition can be, for example, the balance excluding components other than water in the hair cleansing agent. Moreover, 50 mass% or more is preferable with respect to the whole hair washing agent composition, and, as for content of water, 60 mass% or more is more preferable. Moreover, 95 mass% or less is preferable, and 92 mass% or less is more preferable.
また、本実施形態において、毛髪洗浄剤組成物は、上記成分（Ｃ）および（Ｄ）以外の多価アルコールをさらに含んでもよい。 In the embodiment, the hair cleansing composition may further contain polyhydric alcohols other than the components (C) and (D).
また、本実施形態における毛髪洗浄剤組成物には、ｐＨ調整剤を配合してもよい。ｐＨ調整剤の具体例として、乳酸、リンゴ酸、クエン酸、コハク酸等の有機カルボン酸が挙げられる。また、他のｐＨ調整剤として、これら有機酸と合わせて、水酸化ナトリウム、水酸化カリウム、塩化アンモニウム等の塩基を用いてもよい。 Moreover, you may mix | blend a pH adjuster with the hair cleansing composition in this embodiment. Specific examples of pH adjusters include organic carboxylic acids such as lactic acid, malic acid, citric acid and succinic acid. Moreover, you may use bases, such as sodium hydroxide, potassium hydroxide, ammonium chloride, combining with these organic acids as another pH adjuster.
また、本実施形態における毛髪洗浄剤組成物には、洗浄性能の向上、乾燥後の毛髪の仕上がりの向上等について所望の効果を得るために、さらに、油剤を含有させてもよく、油剤の具体例として、ラウリン酸等の脂肪酸、シリコーン類が挙げられる。 In addition, the hair cleanser composition according to the present embodiment may further contain an oil agent in order to obtain a desired effect on the improvement of the cleaning performance, the improvement of the finish of the hair after drying, etc. Specific examples of the oil agent Examples include fatty acids such as lauric acid, silicones.
本実施形態の毛髪洗浄剤組成物においては、上記成分のほか、通常の毛髪洗浄剤組成物に用いられる成分を所望の効果に応じて適宜配合できる。このような任意成分としては、例えば、エタノール等の炭素数１〜６のアルコール；抗フケ剤；ビタミン剤；殺菌剤；グリチルリチン酸ジカリウム等のグリチルリチン酸およびその塩、グリチルレチン酸およびその塩等の抗炎症剤；安息香酸およびその塩等の防腐剤；キレート剤；ソルビトール、パンテノール等の保湿剤；染料、顔料等の着色剤；ユーカリの極性溶媒抽出物等のユーカリエキス、コンキオリンまたはその加水分解物、蜂蜜、ローヤルゼリー、シルクから得られる蛋白質またはその加水分解物、マメ科植物の種子から得られる蛋白含有抽出物、オタネニンジン抽出物、米胚芽抽出物、ヒバマタ抽出物、アロエ抽出物、ハス抽出物、ザクロ抽出物、ノバラ抽出物、カモミラ抽出物、カンゾウ抽出物、月桃葉抽出物、クロレラ抽出物等のエキス類；酸化チタン等のパール化剤；香料；紫外線吸収剤；酸化防止剤；シアバター；ローズ水；ヒマワリ油；オレンジ油；ユーカリ油等が挙げられる。 In the hair cleansing composition of the present embodiment, in addition to the above-mentioned components, components used in a general hair cleansing composition can be appropriately blended according to the desired effect. Such optional components include, for example, alcohols having 1 to 6 carbon atoms such as ethanol; antidandruff agents; vitamin agents; bactericides; glycyrrhizinic acid such as dipotassium glycyrrhizinate and salts thereof, glycyrrhetinic acid and salts thereof and the like Inflammatory agents; Preservatives such as benzoic acid and its salts; chelating agents; moisturizing agents such as sorbitol and panthenol; coloring agents such as dyes and pigments; Eucalyptus extract such as Eucalyptus polar solvent extract; conquiolin or its hydrolysates , Honey, royal jelly, protein obtained from silk or its hydrolyzate, protein-containing extract obtained from the seeds of leguminous plants, ginseng extract, rice germ extract, himata extract, aloe extract, lotus extract, Pomegranate extract, Novara extract, Kamomila extract, licorice extract, Lunar peach leaf extract, Chlorella extract Extracts, and the like; pearlescent agent such as titanium oxide; perfumes; ultraviolet absorbers, antioxidants, shea butter; rose water; sunflower oil; orange oil; eucalyptus oil and the like.
次に、本実施形態における毛髪洗浄剤組成物の製造方法を説明する。
本実施形態の毛髪洗浄剤組成物は、例えば、成分（Ａ）〜（Ｃ）および適宜他の成分を所定の順序で混合することで製造される。さらに具体的には、水を含む毛髪洗浄剤組成物は、成分（Ａ）〜（Ｃ）および適宜他の成分を所定の順序で混合して水に溶解または分散することで製造される。
具体的には、５０〜１００℃程度に加熱した水に、成分（Ａ）および（Ｂ）を加え撹拌し均一にした後、冷却しながら成分（Ｃ）および適宜その他の成分を加え撹拌し均一にして、室温まで冷却することにより得ることができる。
Next, a method of producing the hair cleanser composition in the present embodiment will be described.
The hair cleansing composition of the present embodiment is produced, for example, by mixing the components (A) to (C) and optionally other components in a predetermined order. More specifically, a hair cleansing composition containing water is produced by mixing the components (A) to (C) and other components as needed in a predetermined order and dissolving or dispersing in water.
Specifically, components (A) and (B) are added to water heated to about 50 to 100 ° C. and stirred to be uniform, then component (C) and other components are appropriately added while cooling, and stirring is uniform Can be obtained by cooling to room temperature.
得られた毛髪洗浄剤組成物は、泡吐出容器に充填されて、より好ましくはノンガス型の泡吐出容器に充填されて用いられる。
ノンガス型の泡吐出容器としては、空気と混合して泡として吐出できるものであればいずれのものでも用いることができるが、例えば、ポンプヘッドを押すことで、空気室のシリンダーと液体洗浄剤組成物のシリンダーが加圧されて、空気と液体洗浄剤組成物とが混合されて泡状となって吐出するポンプフォーマー容器や、押圧変形可能な容器の胴体部分を押すことで、容器が変形して吐出するスクイズフォーマー容器が挙げられ、これらの容器の毛髪洗浄剤組成物の吐出流路にメッシュ等の多孔質膜フィルターが設けられていることが好ましい。
ノンガス型の泡吐出容器の具体例として、吉野工業所社製、大和製罐社製のフォーマー容器が挙げられる。また、特開平７−３１５４６３号公報、特開平８−２３０９６１号公報、特開２００５−１９３９７２号公報等に記載された泡吐出容器を使用することもできる。
The obtained hair cleansing composition is filled in a foam discharge container, and more preferably used in a non-gas type foam discharge container.
Although any non-gas type foam discharge container can be used as long as it can be mixed with air and discharged as foam, for example, the cylinder of the air chamber and the liquid cleaning agent composition by pushing the pump head The cylinder of the object is pressurized, the air and the liquid detergent composition are mixed, and the container is deformed by pressing the body portion of the pump former container that discharges in foam form or the container that can be pressed and deformed. It is preferable that porous film filters, such as a mesh, are provided in the discharge flow path of the hair-cleansing composition of these containers.
As a specific example of the non-gas type foam discharge container, there is a former container manufactured by Yoshino Kogyosho Co., Ltd., manufactured by Yamato Co., Ltd. Moreover, the foam | form discharge container described in Unexamined-Japanese-Patent No. 7-315463, Unexamined-Japanese-Patent No. 8-230961, Unexamined-Japanese-Patent No. 2005-193972 etc. can also be used.
また、本実施形態における毛髪洗浄剤組成物を用いた毛髪の洗浄方法は、例えば、毛髪洗浄剤組成物を毛髪に適用し、洗い流すことを含む。また、本実施形態における毛髪洗浄剤組成物を用いた毛髪の洗浄方法は、好ましくは、毛髪洗浄剤組成物を泡吐出容器から吐出して毛髪に適用し、洗い流すことを含み、より好ましくは、泡吐出容器からから吐出した毛髪洗浄剤組成物を毛髪に適用し、適用した毛髪洗浄剤組成物を泡立てた後、洗い流すことを含む。毛髪洗浄剤組成物を泡状にして毛髪に塗布することにより、塗布時に毛髪全体に広げやすく、毛髪になじませ易くすることができる。 In addition, the method of washing the hair using the hair cleansing composition according to the present embodiment includes, for example, applying the hair cleansing composition to the hair and washing it out. In addition, the method for washing hair using the hair cleansing composition according to the present embodiment preferably includes discharging the hair cleansing composition from a foam discharge container, applying it to the hair, and washing away, more preferably, Applying the hair cleansing composition discharged from the foam dispensing container to the hair and frothing the applied hair cleansing composition prior to washing away. By applying a foam to the hair cleansing composition and applying it to the hair, it can be easily spread over the hair at the time of application and can be easily applied to the hair.
本実施形態における毛髪洗浄剤組成物では、特定の成分（Ａ）〜（Ｃ）が組み合わせて用いられているため、良質な泡を吐出でき、低温時の保存安定性に優れるとともに、洗髪時（皮脂存在下で）の泡量および泡質が良好であり、更に毛髪すすぎ時に優れた滑らかさを得ることができる。
さらに具体的には、泡の吐出性に優れ、寒冷地域の冬場浴室の環境として想定される−５℃程度の低温下においても保存安定性が高い毛髪洗浄剤組成物を得ることができる。また、吐出した泡の外観に優れる毛髪洗浄剤組成物が得られ、例えば吐出した泡をきめ細かく一様に均質なものとすることができる。
また、本実施形態における毛髪洗浄剤組成物は、上述した良質の泡の吐出性や低温時（−５℃）の保存安定性といった基本性能を担保しつつ、容器から吐出した泡の頭髪上での泡立ちに優れた毛髪洗浄剤組成物を得ることができるため、例えば、洗髪時に使用者が好ましい清浄感や、皮脂汚れの洗浄効果に優れるという実感を得ることも可能となる。
In the hair cleansing composition according to the present embodiment, since specific components (A) to (C) are used in combination, good quality foam can be discharged, and the storage stability at low temperature is excellent, and In the presence of sebum, the foam volume and foam quality are good, and moreover, excellent smoothness can be obtained when rinsing the hair.
More specifically, it is possible to obtain a hair cleansing composition which is excellent in foam dischargeability and high in storage stability even under a low temperature of about -5 ° C assumed as a winter bathing environment in a cold region. In addition, a hair cleansing composition excellent in the appearance of the discharged foam can be obtained, and, for example, the discharged foam can be finely and uniformly homogenized.
In addition, the hair cleansing composition according to the present embodiment has the basic performance such as the above-described high-quality foam dischargeability and storage stability at low temperature (−5 ° C.) while ensuring the basic performance on foam hair discharged from the container. Since a hair cleansing composition excellent in lathering can be obtained, it is also possible to obtain, for example, a feeling that the user feels preferable to feel clean when washing hair and is excellent in the cleaning effect of sebum dirt.
以上、本発明の実施形態について述べたが、これらは本発明の例示であり、上記以外の様々な構成を採用することもできる。 As mentioned above, although embodiment of this invention was described, these are the illustrations of this invention, and various structures other than the above can also be employ | adopted.
（実施例１〜１１、比較例１〜２）
表１に示す組成の毛髪洗浄剤組成物を調製し、以下の方法に従って評価した。評価方法および評価基準を以下に示す。
(Examples 1 to 11, Comparative Examples 1 to 2)
A hair cleansing composition having the composition shown in Table 1 was prepared and evaluated according to the following method. The evaluation method and evaluation criteria are shown below.
（ポンプフォーマーから吐出の際の泡質：５℃）
得られた各例の毛髪洗浄剤組成物を、ポンプヘッドを押すことで泡を吐出するポンプフォーマー容器（吉野工業所社製、泡吐出流路に設けた多孔質膜フィルターのメッシュサイズ；＃２００、メッシュ枚数；２枚、１プッシュあたりの液吐出量；約１ｇ、１プッシュあたりの空気吐出量（泡吐出量）；約１３ｃｍ3、容器の容積；約３００ｍＬ）に約１００ｍＬ充填・密閉し、５℃の定温恒温室にて２４時間以上静置した。その後、該容器を水平な台上に置き、ポンプヘッドを鉛直に最後まで押し下げて泡を吐出する操作を行った。該操作により吐出した４プッシュ分の泡の状態を、専門パネラー１名にて以下の３段階の基準で目視評価した。
Ａ：泡のキメが揃っている
Ｂ：概ね泡のキメが揃っている
Ｃ：泡のキメが揃っていない
評価結果を表１中、「吐出時の泡質」の項に示す。
(Bubble quality at the time of discharge from the pump former: 5 ° C)
A pump former container (a mesh size of a porous membrane filter provided in a foam discharge flow path, manufactured by Yoshino Kogyosho Co., Ltd., which discharges foam by pushing the pump head with the obtained hair washing composition of each example; # 200, number of meshes: 2 pieces, liquid discharge amount per push; about 1 g, air discharge amount per push (foam discharge amount); about 13 cm 3 , container volume: about 300 mL) filled and sealed In the constant temperature and constant temperature room of 5 ° C., it was left to stand for 24 hours or more. Thereafter, the container was placed on a horizontal table, and the pump head was pushed down vertically to the end to discharge bubbles. The state of the foam for 4 push discharged by this operation was visually evaluated by one expert panelist based on the following three levels of criteria.
A: The texture of the foam is uniform B: The texture of the foam is generally uniform C: The texture of the foam is not uniform The evaluation results are shown in Table 1 under the heading "foam quality at discharge".
（低温（−５℃）の保存安定性）
得られた各例の毛髪洗浄剤組成物を、１１０ｍＬガラス瓶に約１００ｍＬ充填・密閉し、−５℃の定温恒温室にて３日間静置し、外観を目視にて観察した。
Ａ：透明
Ｂ：白濁
Ｃ：析出、分離または沈殿が認められる
(Low temperature (-5 ° C) storage stability)
About 100 mL of the hair cleansing composition obtained in each example was filled and sealed in a 110 mL glass bottle, and allowed to stand in a constant temperature and constant temperature room at -5 ° C for 3 days, and the appearance was visually observed.
A: Transparent B: White turbidity C: Precipitation, separation or precipitation is observed
（モデル皮脂存在下での洗髪時の泡立ち）
長さ３０ｃｍ、幅６ｃｍ、重さ２０ｇの日本人女性毛髪束を４０℃の温水で充分にすすいだ後、０．０２ｇのモデル皮脂（組成については後述する。）を毛髪束上に塗布し、１．０ｇの毛髪洗浄剤組成物を上記泡吐出容器より吐出して毛髪に均一に塗布し、約３０秒間、毛髪同士を軽く擦り合せるように泡立てた。その際の泡立ちの良さ（泡量）を、専門パネラー１名にて以下の５段階基準で官能評価した。
５：とても泡立ちが良い
４：泡立ちが良い
３：やや泡立ちが良い
２：やや泡立ちが悪い
１：泡立ちが悪い
(Bubbling during shampooing in the presence of model sebum)
After thoroughly rinsing a 30 cm long, 6 cm wide, 20 g weight Japanese female hair bundle with warm water at 40 ° C., apply 0.02 g model sebum (the composition will be described later) on the hair bundle, 1.0 g of the hair cleansing composition was discharged from the foam discharge container and uniformly applied to the hair, and was bubbled so as to lightly rub the hair for about 30 seconds. The goodness of foaming (the amount of foam) at that time was sensory-evaluated by one expert panelist based on the following five steps.
5: very good foaming 4: good foaming 3: slightly foamy 2: slightly foamy 1: poor foaming
＜モデル皮脂組成＞
成分 配合
パルミチン酸 ３６．８質量部
オレイン酸 １８．８質量部
スクアレン ８ 質量部
ミリスチン酸ミリスチル １４ 質量部
綿実油 ７．２質量部
コレステロール １２ 質量部
コレステロールエステル ４ 質量部
合計 １００．８質量部
<Model sebum composition>
Component Blended palmitic acid 36.8 parts by mass Oleic acid 18.8 parts by mass squalene 8 parts by mass myristyl myristate 14 parts by mass cottonseed oil 7.2 parts by mass cholesterol 12 parts by mass cholesterol ester 4 parts by mass 100.8 parts by mass
（モデル皮脂存在下での洗髪時の泡質）
長さ３０ｃｍ、幅６ｃｍ、重さ２０ｇの日本人女性毛髪束を４０℃の温水で充分にすすいだ後、０．０２ｇの上記モデル皮脂を毛髪束上に塗布し、１．０ｇの毛髪洗浄剤組成物を上記泡吐出容器より吐出して塗布し、約３０秒間、毛髪同士を軽く擦り合せるように泡立てた。その際の泡質を専門パネラー１名にて、以下の５段階基準で官能評価した。
５：きめ細かくとても良質である
４：きめ細かく良質である
３：ややきめ細かくやや良質である
２：やや粗くあまり良質でない
１：粗く良質でない
(Bubble quality during hair washing in the presence of model sebum)
After thoroughly rinsing a 30 cm long, 6 cm wide, 20 g Japanese female hair tress with warm water at 40 ° C., 0.02 g of the above model sebum is applied onto the hair tress and 1.0 g of a hair cleansing agent The composition was discharged from the foam discharge container and applied, and was bubbled so as to slightly rub the hairs for about 30 seconds. The foam quality at that time was sensory-evaluated by one expert panelist on the basis of the following five steps.
5: fine and very good quality 4: fine and good quality 3: slightly fine and somewhat good 2: slightly rough and not very good 1: rough and not good
（すすぎ時の毛髪の滑らかさ）
長さ３０ｃｍ、幅６ｃｍ、重さ２０ｇの日本人女性毛髪束を４０℃の温水で充分にすすいだ後、１．０ｇの毛髪洗浄剤組成物を上記泡吐出容器より吐出して塗布し、約３０秒間、毛髪同士を軽く擦り合せるように泡立てた。その後、４０℃の温水ですすぎながら、すすぎ時の毛髪の滑らかさを、専門パネラー１名にて以下の５段階基準で官能評価した。
５：滑らかさがとても良好である
４：やや滑らかさが良好である
３：滑らかさがやや良好である
２：滑らかさがあまり良好でない
１：滑らかさが良好でない
(Smoothness of hair when rinsing)
A Japanese female hair bundle of 30 cm in length, 6 cm in width and 20 g in weight is sufficiently rinsed with warm water at 40 ° C., and then 1.0 g of a hair cleansing composition is discharged from the foam discharge container and applied. The hair was bubbled so as to gently rub the hairs for 30 seconds. Thereafter, while being rinsed with warm water at 40 ° C., the smoothness of the hair at the time of rinsing was organoleptically evaluated by one expert panelist on the basis of the following five levels.
5: the smoothness is very good 4: the smoothness is good 3: the smoothness is good 2: the smoothness is not good 1: the smoothness is not good
表１中の各例で用いた成分の詳細を以下に示す。
＊１ ポリクオタニウム−１０：ポイズＣ−８０Ｍ（花王社製）
＊２ カチオン化グァーガム：Ｊａｇｕａｒ Ｅｘｃｅｌ（ソルベイ社製）
＊３ ポリクオタニウム−７：Ｍｅｒｑｕａｔ−７４０（ルーブリゾール社製）
＊４ ＰＰＧ−９ジグリセリル：ＳＹ−ＤＰ９（阪本薬品工業社製）
＊５ ＰＰＧ−７：アデカカーポール ＤＬ−３０（ＡＤＥＫＡ社製）
The detail of the component used by each example in Table 1 is shown below.
* 1 Polyquaternium-10: Poise C-80M (manufactured by Kao Corporation)
* 2 Cationized guar gum: Jaguar Excel (made by Solvay)
* 3 Polyquaternium-7: Merquat-740 (manufactured by Lubrisol Corporation)
* 4 PPG-9 diglyceryl: SY-DP9 (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.)
* 5 PPG-7: Adeka car pole DL-30 (made by Adeka company)
表１より、各実施例で得られた毛髪洗浄剤組成物は、ポンプフォーマーから吐出した際の泡質および低温下（−５℃）での保存安定性について好ましいものであった。そして、各実施例で得られた毛髪洗浄剤組成物は、洗髪時の泡量および泡質、ならびに、すすぎ時の毛髪の滑らかさの各効果のバランスの点で、各比較例のものよりも優れていた。 From Table 1, the hair cleansing composition obtained in each Example was preferable for foam quality when discharged from a pump former and storage stability at low temperature (-5 ° C.). And, the hair cleansing composition obtained in each example is superior to that of each comparative example in terms of the balance of each effect of foam amount and foam quality at the time of hair washing and smoothness of hair at the time of rinsing. It was excellent.
（処方例１〜７）
毛髪洗浄剤組成物の処方例を表２に示す。
(Prescription Examples 1 to 7)
Formulation examples of the hair cleansing composition are shown in Table 2.
表２中の各例で用いた成分のうち、表１について前述した成分以外の成分の詳細を以下に示す。
＊６ ＰＰＧ−１４ジグリセリル：ＳＹ−ＤＰ１４（阪本薬品工業社製）
Among the components used in each example in Table 2, the details of the components other than the components described above for Table 1 are shown below.
* 6 PPG-14 diglyceryl: SY-DP14 (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.)
Claims (12)
（Ａ）アニオン性界面活性剤を含む界面活性剤
（Ｂ）カチオン化ポリマー
（Ｃ）ポリオキシプロピレンポリグリセリルエーテル Hair washing composition containing the following components (A)-(C), and filling a foam discharge container and using it.
(A) Surfactant (B) containing an anionic surfactant (B) cationized polymer (C) polyoxypropylene polyglyceryl ether
Ｒ2−Ｏ−（ＣＨ2ＣＨ2−Ｏ）n−Ｈ （２）
〔上記一般式（２）中、Ｒ2は炭素数１２〜２４の直鎖または分岐のアルキル基またはアルケニル基を示し、ｎは１〜５０の数を示す。〕 The hair cleansing composition according to claim 9, wherein the nonionic surfactant comprises a compound represented by the following general formula (2).
R 2 -O- (CH 2 CH 2 -O) n -H (2)
[In the above general formula (2), R 2 represents a linear or branched alkyl or alkenyl group having 12 to 24 carbon atoms, and n represents a number of 1 to 50]. ]
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| WO2021116986A1 (en) | 2019-12-12 | 2021-06-17 | 日商花王股份有限公司 | Hair cleanser composition, kit and method for hair cleaning |
| WO2022014487A1 (en) | 2020-07-16 | 2022-01-20 | 株式会社Adeka | Method for improving effervescence and foam quality of cleaning agent composition, and method for cleaning skin or hair |
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