JP2018158904A - Shampoo cosmetics - Google Patents
Shampoo cosmetics Download PDFInfo
- Publication number
- JP2018158904A JP2018158904A JP2017056930A JP2017056930A JP2018158904A JP 2018158904 A JP2018158904 A JP 2018158904A JP 2017056930 A JP2017056930 A JP 2017056930A JP 2017056930 A JP2017056930 A JP 2017056930A JP 2018158904 A JP2018158904 A JP 2018158904A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- weight
- component
- cosmetic
- washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 42
- 239000002453 shampoo Substances 0.000 title abstract description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 18
- 229930195729 fatty acid Natural products 0.000 claims abstract description 18
- 239000000194 fatty acid Substances 0.000 claims abstract description 18
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 17
- -1 polyoxyethylene Polymers 0.000 claims abstract description 16
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 15
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229940117986 sulfobetaine Drugs 0.000 claims abstract description 13
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 10
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001913 cellulose Substances 0.000 claims abstract description 6
- 229920002678 cellulose Polymers 0.000 claims abstract description 6
- 229960003080 taurine Drugs 0.000 claims abstract description 4
- 238000005406 washing Methods 0.000 claims description 51
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 claims description 18
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid ester group Chemical group C(CCCCCCCCCCC)(=O)O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 12
- 229940074052 glyceryl isostearate Drugs 0.000 claims description 9
- 239000003240 coconut oil Substances 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- 239000005639 Lauric acid Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 abstract description 20
- 239000006260 foam Substances 0.000 abstract description 20
- 238000011156 evaluation Methods 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 3
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- OVBJJZOQPCKUOR-UHFFFAOYSA-L EDTA disodium salt dihydrate Chemical compound O.O.[Na+].[Na+].[O-]C(=O)C[NH+](CC([O-])=O)CC[NH+](CC([O-])=O)CC([O-])=O OVBJJZOQPCKUOR-UHFFFAOYSA-L 0.000 description 2
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 2
- GWVPJQDUGPKIOI-UQKRIMTDSA-N [Na].CCCCCCCCCCCC(=O)CN[C@@H](C)C(O)=O Chemical compound [Na].CCCCCCCCCCCC(=O)CN[C@@H](C)C(O)=O GWVPJQDUGPKIOI-UQKRIMTDSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- DJXPNUIRGNRCPQ-UHFFFAOYSA-N 2-[2,3-bis[2-(16-methylheptadecanoyloxy)ethoxy]propoxy]ethyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCCOCC(COCCOC(=O)CCCCCCCCCCCCCCC(C)C)OCCOC(=O)CCCCCCCCCCCCCCC(C)C DJXPNUIRGNRCPQ-UHFFFAOYSA-N 0.000 description 1
- VGVRWTPKKMTCFK-UHFFFAOYSA-N 2-[hexadecanoyl(methyl)amino]ethanesulfonic acid Chemical class CCCCCCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O VGVRWTPKKMTCFK-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- CMPDPBDUZTUXAD-UHFFFAOYSA-N [3-hydroxy-2-(16-methylheptadecanoyloxy)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCCCCCC(C)C CMPDPBDUZTUXAD-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- AMFZXVSYJYDGJD-UHFFFAOYSA-M ethyl-dimethyl-(3-methyl-2-oxobut-3-enyl)azanium;chloride Chemical compound [Cl-].CC[N+](C)(C)CC(=O)C(C)=C AMFZXVSYJYDGJD-UHFFFAOYSA-M 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229940096994 peg-10 glyceryl stearate Drugs 0.000 description 1
- 229940016593 peg-20 glyceryl isostearate Drugs 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940098385 triisostearin Drugs 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本願発明は、洗髪用化粧料に関し、更に詳細には泡質が良く、洗い流し時の指通り性が良好で、濡れた状態の毛髪にハリコシ感を与え、かつ乾燥後の毛髪にもハリコシ感を与えると共にボリューム感も付与することができる洗髪用化粧料に関する。 The present invention relates to a cosmetic for washing hair, and more particularly, has good foam quality, good fingering properties when washed off, gives a harsh feel to wet hair, and also feels harshness on dried hair. The present invention relates to a hair-washing cosmetic that can give a volume feeling as well as giving.
毛髪は、加齢に伴い細くなりハリコシ感が低下する傾向がある。細くハリコシ感が低下した毛髪は、洗髪・乾燥後に頭頂部の毛髪のボリューム感が低下してしまい、望むスタイリングへのセットのしやすさを低下させたり、見た目の印象を低下させてしまい、非常に大きな悩みの一つとなっている。 The hair tends to become thinner with age, and the harshness tends to decrease. The hair that is thin and has a reduced feeling of elasticity will have a reduced volume of hair on the top of the head after washing and drying, which may reduce the ease of setting to the desired styling and the impression of appearance. It is one of the big troubles.
この悩みを解決するために、洗髪用化粧料においても毛髪にハリコシを与える技術やボリューム感を向上させる技術が種々検討されてきた。
例えば、アニオン性界面活性剤とカチオン性ポリマーとコラーゲンとポリシロキサンを含有する洗髪用化粧料（特許文献１）が提案されている。
In order to solve this problem, various techniques have been studied for applying harshness to hair and improving the volume feeling in cosmetics for washing hair.
For example, a hair washing cosmetic (Patent Document 1) containing an anionic surfactant, a cationic polymer, collagen, and polysiloxane has been proposed.
また、Ｎ−混合脂肪酸（Ｃ１２、Ｃ１４）アシル−Ｌ−アスパラギン酸ナトリウム液からなるアニオン性界面活性剤と両性界面活性剤と非イオン界面活性剤とアクリル酸類高分子を含有する洗髪用化粧料（特許文献２）や、非石鹸系アニオンと両性界面活性剤とカチオン化キトサンを含有した洗髪用化粧料（特許文献３）も提案されている。 Further, a cosmetic for hair washing containing an anionic surfactant comprising an N-mixed fatty acid (C12, C14) acyl-L-aspartate solution, an amphoteric surfactant, a nonionic surfactant and an acrylic polymer ( Patent Document 2) and cosmetics for hair washing (Patent Document 3) containing non-soap anions, amphoteric surfactants and cationized chitosan have also been proposed.
しかしながら、これらの洗髪用化粧料は、泡質と洗い流し時の指通り性、濡れた状態の毛髪のハリコシ感、乾燥後の毛髪のハリコシ感とボリューム感のすべてを満足できるものではなかった。 However, these hair-washing cosmetics cannot satisfy all of the foam quality, the finger-wiping property at the time of washing, the harshness of wet hair, the harshness and volume of hair after drying.
本願発明の目的は、泡質が良く洗い流し時の指通り性が良好で、濡れた状態で毛髪にハリコシ感を与え、かつ乾燥後の毛髪にもハリコシ感を与えると共にボリューム感も付与することができる洗髪用化粧料を提供することである。 The object of the present invention is that the foam quality is good and the finger-free property when washed off is good, the hair feels firm when wet, and the hair after drying also feels firm and feels volume. It is to provide a cosmetic for hair washing that can be performed.
かかる事情に鑑み、本願発明者は鋭意研究の結果、（Ａ）Ｎ−アシルメチルタウリン型アニオン性界面活性剤、（Ｂ）アルキルアミドスルホベタイン型両性界面活性剤、（Ｃ）カチオン化セルロース、（Ｄ）ポリクオタニウム−４８、及び（Ｅ）ポリオキシエチレン脂肪酸グリセリルを含有する洗髪用化粧料が、洗髪時の泡質と指通り性がよく、濡れた状態で毛髪にハリコシ感を与え、かつ洗髪乾燥後の毛髪にもハリコシ感を与えると共にボリューム感も付与することができる優れた洗髪用化粧料であることを見出し、本願発明を完成させた。 In view of such circumstances, the inventor of the present application, as a result of earnest research, (A) N-acylmethyltaurine type anionic surfactant, (B) alkylamide sulfobetaine type amphoteric surfactant, (C) cationized cellulose, ( D) Polyquaternium-48 and (E) Hair-washing cosmetics containing polyoxyethylene fatty acid glyceryl have good foam quality and fingering properties at the time of shampooing, give the hair a harsh feel in the wet state, and dry the shampoo The present invention was completed by discovering that it is an excellent hair-washing cosmetic that can give a sense of volume and also a sense of volume to the later hair.
また、本願発明は、前記成分（Ａ）Ｎ−アシルメチルタウリン型アニオン性界面活性剤の含有量が２〜１５重量％であり、（Ｂ）アルキルアミドスルホベタイン型両性界面活性剤の含有量が０．５〜１０重量％であり、かつ（Ｄ）ポリクオタニウム−４８の含有量が０．０５〜４重量％であることを特徴とする洗髪用化粧料を提供する。 In the present invention, the content of the component (A) N-acylmethyltaurine type anionic surfactant is 2 to 15% by weight, and (B) the content of the alkylamide sulfobetaine type amphoteric surfactant is Provided is a cosmetic for washing hair, which is 0.5 to 10% by weight and (D) the content of polyquaternium-48 is 0.05 to 4% by weight.
また、本願発明は、前記成分（Ｅ）ポリオキシエチレン脂肪酸グリセリルが０．０５〜２重量％であることを特徴とする洗髪用化粧料を提供する。 Moreover, this invention provides the cosmetics for hair washing characterized by the said component (E) polyoxyethylene fatty acid glyceryl being 0.05 to 2 weight%.
また、本願発明は、前記成分（Ａ）Ｎ−アシルメチルタウリン型アニオン性界面活性剤の含有量がアニオン性界面活性剤全体の５０重量％以上であり、かつ（Ｂ）アルキルアミドスルホベタイン型両性界面活性剤の含有量が両性界面活性剤全体の５０重量％以上であることを特徴とする洗髪用化粧料を提供する。 In the present invention, the content of the component (A) N-acylmethyltaurine type anionic surfactant is 50% by weight or more of the whole anionic surfactant, and (B) the alkylamide sulfobetaine type amphoteric Provided is a cosmetic for washing hair, wherein the content of the surfactant is 50% by weight or more of the total amount of the amphoteric surfactant.
また、本願発明は、前記成分（Ａ）Ｎ−アシルメチルタウリン型アニオン性界面活性剤がＮ−ヤシ油脂肪酸メチルタウリン塩であり、かつ（Ｂ）アルキルアミドスルホベタイン型両性界面活性剤がラウリン酸アミドプロピルスルホベタインであることを特徴とする洗髪用化粧料を提供する。 In the present invention, the component (A) N-acylmethyltaurine type anionic surfactant is N-coconut oil fatty acid methyltaurine salt, and (B) the alkylamide sulfobetaine type amphoteric surfactant is lauric acid. Provided is a hair washing cosmetic characterized by being amidopropylsulfobetaine.
また、本願発明は、前記成分（Ｅ）ポリオキシエチレン脂肪酸グリセリルがイソステアリン酸ＰＥＧ−８グリセリルであることを特徴とする洗髪用化粧料を提供する。 Moreover, this invention provides the cosmetics for hair washing characterized by the said component (E) polyoxyethylene fatty acid glyceryl being PEG-8 glyceryl isostearate.
本願発明の洗髪用化粧料は、泡質が良く洗い流し時の指通り性が良好で、濡れた状態で毛髪にハリコシ感を与え、かつ乾燥後の毛髪にもハリコシ感を与えると共にボリューム感も付与することができる優れたものである。 The cosmetic for hair washing of the present invention has good foam quality and good finger-wiping property, gives the hair a firm feeling when wet, and also gives a sense of volume to the hair after drying. It is an excellent thing that can be done.
本願発明に用いる成分（Ａ）Ｎ−アシルメチルタウリン型アニオン性界面活性剤としては、Ｎ−ヤシ油脂肪酸メチルタウリン塩、Ｎ−ラウロイルメチルタウリン塩、Ｎ−ミリストイルメチルタウリン塩、Ｎ−ステアロイルメチルタウリン塩、Ｎ−パルミトイルメチルタウリン塩等が挙げられ、これらの塩としてはナトリウム塩、カリウム塩、トリエタノールアミン塩等が挙げられる。これらのＮ−アシルメチルタウリン型アニオン性界面活性剤は、１種又は２種以上を組み合わせて用いることができる。これらの中でも、洗髪用化粧料の泡立ち及び泡質を良好にし得る点から、Ｎ−ヤシ油脂肪酸メチルタウリンナトリウムが好ましい。 Component (A) N-acylmethyl taurine type anionic surfactant used in the present invention includes N-coconut oil fatty acid methyl taurine salt, N-lauroyl methyl taurine salt, N-myristoyl methyl taurine salt, N-stearoyl methyl taurine Salts, N-palmitoylmethyl taurine salts, and the like. Examples of these salts include sodium salts, potassium salts, and triethanolamine salts. These N-acylmethyl taurine type anionic surfactants can be used alone or in combination of two or more. Among these, N-coconut oil fatty acid methyl taurine sodium is preferable because it can improve the foaming and foam quality of the hair-washing cosmetic.
成分（Ａ）の含有量は、好ましくは洗髪用化粧料全体に対して２〜１５重量％、特に好ましくは３〜１５重量％である。２重量％より少ないと、泡質が不十分の場合があり、また１５重量％を越えると、使用感が悪くなる場合がある。 Content of a component (A) becomes like this. Preferably it is 2 to 15 weight% with respect to the whole cosmetics for hair washing, Most preferably, it is 3 to 15 weight%. If it is less than 2% by weight, the foam quality may be insufficient, and if it exceeds 15% by weight, the feeling of use may be deteriorated.
本願発明に用いる成分（Ｂ）アルキルアミドスルホベタイン型両性界面活性剤としては、ラウリン酸アミドプロピルヒドロキシスルホベタイン、ミリスチン酸アミドプロピルヒドロキシスルホベタイン、ヤシ油脂肪酸アミドプロピルヒドロキシスルホベタイン、エルカ酸アミドプロピルヒドロキシスルホベタイン等が挙げられる。これらのアルキルアミドスルホベタイン型両性界面活性剤は、１種又は２種以上を組み合わせて用いることができる。これらの中でも、ラウリン酸アミドプロピルヒドロキシスルホベタインが好ましい。 Examples of the component (B) alkylamide sulfobetaine type amphoteric surfactant used in the present invention include lauric acid amidopropyl hydroxysulfobetaine, myristic acid amidopropyl hydroxysulfobetaine, coconut oil fatty acid amidopropyl hydroxysulfobetaine, erucic acid amidopropyl hydroxy Examples include sulfobetaine. These alkylamide sulfobetaine type amphoteric surfactants can be used alone or in combination of two or more. Among these, lauric acid amidopropyl hydroxysulfobetaine is preferable.
成分（Ｂ）の含有量は特に限定されるものではないが、好ましくは洗髪用化粧料全体に対して０．５〜１０重量％、特に好ましくは２〜１０重量％である。０．５重量％より少ないと、ハリコシ感が低下する場合があり、また１０重量％を越えると、使用感が悪くなる場合がある。 Although content of a component (B) is not specifically limited, Preferably it is 0.5 to 10 weight% with respect to the whole cosmetics for hair washing, Most preferably, it is 2 to 10 weight%. If the amount is less than 0.5% by weight, the harshness may be lowered, and if it exceeds 10% by weight, the feeling in use may be deteriorated.
成分（Ａ）及び成分（Ｂ）の含有量の割合は特に限定されるものではないが、好ましくは成分（Ａ）は洗髪用化粧料が含有するアニオン性界面活性剤全体の５０重量％以上であり、成分（Ｂ）は洗髪用化粧料が含有する両性界面活性剤全体の５０重量％以上である。 The proportion of the content of component (A) and component (B) is not particularly limited, but preferably component (A) is 50% by weight or more of the total anionic surfactant contained in the hair-washing cosmetic. Yes, component (B) is 50% by weight or more of the total ampholytic surfactant contained in the hair-washing cosmetic.
本願発明に用いる成分（Ｃ）カチオン化セルロースとしては、市販品を用いることが可能であり、例えばアクゾノーベル社製のＣＥＬＱＵＡＴ ＳＣ−２３０Ｍ（平均分子量：１７０万）、ライオン社製のレオガードＭＧＰ（平均分子量：１６５万）、レオガードＭＬＰ（平均分子量１３０万）、東邦化学工業社製のカチナールＨＣ−２００（平均分子量：１３０万）、カチナールＬＣ−２００（平均分子量：１２５万）が挙げられる。 As the component (C) cationized cellulose used in the present invention, commercially available products can be used. For example, CELQUAT SC-230M (average molecular weight: 1.7 million) manufactured by Akzo Nobel, Leogard MGP (average) manufactured by Lion Molecular weight: 1.65 million), Leogard MLP (average molecular weight: 1.3 million), Kachinal HC-200 (average molecular weight: 1.3 million) manufactured by Toho Chemical Industry Co., Ltd., and kachinal LC-200 (average molecular weight: 1.25 million).
成分（Ｃ）の含有量は特に限定されるものではないが、好ましくは洗髪用化粧料全体に対して０．１〜１重量％、特に好ましくは０．３〜１重量％である。０．１重量％より少ないと洗い流し時の指通りが悪くなる場合があり、また１重量％を越えると、洗髪後にごわつき感が生じる場合がある。 Although content of a component (C) is not specifically limited, Preferably it is 0.1 to 1 weight% with respect to the whole cosmetics for hair washing, Most preferably, it is 0.3 to 1 weight%. If the amount is less than 0.1% by weight, the finger passage at the time of washing may be deteriorated, and if it exceeds 1% by weight, a feeling of stiffness may occur after washing.
本願発明に用いる成分（Ｄ）ポリクオタニウム−４８は、メタクリロイルエチルジメチルベタイン・塩化メタクリロイルエチルトリメチルアンモニウム・メタクリル酸２−ヒドロキシエチル共重合体であり、市販品を用いることが可能である。市販品としては、例えば互応化学工業社製のプラスサイズＬ−４５０、プラスサイズＬ−４５０Ｗが挙げられる。 Component (D) polyquaternium-48 used in the present invention is a methacryloylethyldimethylbetaine / methacryloylethyltrimethylammonium chloride / 2-hydroxyethyl methacrylate copolymer, and a commercially available product can be used. Commercially available products include, for example, Plus Size L-450 and Plus Size L-450W manufactured by Kyoyo Chemical Industry Co., Ltd.
成分（Ｄ）の含有量は特に限定されるものではないが、好ましくは洗髪用化粧料全体に対して０．０５〜４重量％、特に好ましくは０．１〜２重量％である。０．０５重量％より少ないと、効果が得られない場合があり、また４重量％を越えると、ごわつきなど使用感が悪くなる場合がある。 Although content of a component (D) is not specifically limited, Preferably it is 0.05 to 4 weight% with respect to the whole cosmetics for hair washing, Most preferably, it is 0.1 to 2 weight%. If the amount is less than 0.05% by weight, the effect may not be obtained. If the amount exceeds 4% by weight, the feeling of use such as wobbling may be deteriorated.
本願発明に用いる成分（Ｅ）ポリオキシエチレン脂肪酸グリセリルは、親水基としてポリオキシエチレングリセリンの縮合物、親油基として脂肪酸を持つ非イオン性界面活性剤である（以下ＰＥＧはポリオキシエチレンを意味する）。ポリオキシエチレン脂肪酸グリセリルの具体例としては、例えば、イソステアリン酸ＰＥＧ−５グリセリル、イソステアリン酸ＰＥＧ−８グリセリル、イソステアリン酸ＰＥＧ−１０グリセリル、イソステアリン酸ＰＥＧ−１５グリセリル、イソステアリン酸ＰＥＧ−２０グリセリル、トリイソステアリン酸ＰＥＧ−1０グリセリル、トリイソステアリン酸ＰＥＧ−２０グリセリル、トリイソステアリン酸ＰＥＧ−３０グリセリル、トリイソステアリン酸ＰＥＧ−４０グリセリル、ジイソステアリン酸ＰＥＧ−２０グリセリル、ステアリン酸ＰＥＧ−１０グリセリル、トリステアリン酸ＰＥＧ−２０グリセリル、（カプリル／カプリン酸）ＰＥＧ−８グリセリルなどを例示することができる。これらの中でも、イソステアリン酸ＰＥＧ−８グリセリルが好ましい。 Component (E) polyoxyethylene fatty acid glyceryl used in the present invention is a nonionic surfactant having a polyoxyethylene glycerin condensate as a hydrophilic group and a fatty acid as a lipophilic group (hereinafter PEG means polyoxyethylene) To do). Specific examples of the polyoxyethylene fatty acid glyceryl include, for example, PEG-5 glyceryl isostearate, PEG-8 glyceryl isostearate, PEG-10 glyceryl isostearate, PEG-15 glyceryl isostearate, PEG-20 glyceryl isostearate, and triisostearin. PEG-10 glyceryl acid, PEG-20 glyceryl triisostearate, PEG-30 glyceryl triisostearate, PEG-40 glyceryl triisostearate, PEG-20 glyceryl diisostearate, PEG-10 glyceryl stearate, PEG-20 tristearate Examples thereof include glyceryl and (capryl / capric acid) PEG-8 glyceryl. Among these, PEG-8 glyceryl isostearate is preferable.
成分（Ｅ）の含有量は特に限定されるものではないが、好ましくは洗髪用化粧料全体に対して０．０５〜２重量％、特に好ましくは０．１〜２重量％である。０．０５重量％より少ないと、ボリュ−ム感及びハリコシ感が不十分な場合があり、また２重量％を越えると、泡質が悪くなる場合がある。 Although content of a component (E) is not specifically limited, Preferably it is 0.05 to 2 weight% with respect to the whole cosmetics for hair washing, Most preferably, it is 0.1 to 2 weight%. If it is less than 0.05% by weight, the volume feeling and the firmness may be insufficient, and if it exceeds 2% by weight, the foam quality may be deteriorated.
本願発明の洗髪用化粧料には、目的の効果が損なわれない範囲で上記成分以外に、通常の洗髪用化粧料に用いられる任意の成分を含有することができる。例えば、油剤、上記以外の界面活性剤、パ−ル剤、ｐＨ調製剤、保湿剤、防腐剤、増粘剤、紫外線吸収剤、フケ防止剤、キレ−ト剤、抗酸化剤、コンディショニング剤、着色剤、着香剤、抗炎症剤等が挙げられる。ただし、これら例示に限定されるものでない。 The cosmetics for hair washing of the present invention can contain any components used in ordinary cosmetics for washing hair, in addition to the above components, as long as the intended effects are not impaired. For example, oil agents, surfactants other than those mentioned above, pill agents, pH adjusters, humectants, preservatives, thickeners, UV absorbers, anti-dandruff agents, chelating agents, antioxidants, conditioning agents, Coloring agents, flavoring agents, anti-inflammatory agents and the like can be mentioned. However, it is not limited to these examples.
本願発明の洗髪用化粧料は、上記の各成分を、溶媒である精製水に溶解または分散することで調製することができる。すなわち、上記成分（Ａ）〜（Ｅ）、上記任意成分、及び精製水（残量）を混合して得ることができる。 The hair-washing cosmetic of the present invention can be prepared by dissolving or dispersing each of the above components in purified water as a solvent. That is, it can be obtained by mixing the components (A) to (E), the optional component, and purified water (remaining amount).
次に、実施例を挙げて、本願発明をより詳細に説明する。ただし、本願発明はこれらにより限定されるものではない。なお、含有量は重量％であり、含有成分の純分を示す。 Next, an Example is given and this invention is demonstrated in detail. However, this invention is not limited by these. In addition, content is weight% and shows the pure part of a containing component.
表１〜４に示した組成に従い、実施例１〜３５及び比較例１〜９の各洗髪用化粧料を、溶媒である水に溶解または分散することで調製し、得られた洗髪用化粧料について下記方法に従って評価した。 According to the compositions shown in Tables 1 to 4, the hair washing cosmetics of Examples 1 to 35 and Comparative Examples 1 to 9 were prepared by dissolving or dispersing them in water as a solvent. Was evaluated according to the following method.
（評価方法）
専門パネル１０名により、各洗髪用化粧料を使用してもらい、（１）洗髪中の泡質、（２）洗い流し時の指通り、（３）濡れた状態のハリコシ感、（４）乾燥後のハリコシ感、（５）乾燥後のボリュ−ム感について評価を行った。尚、評価基準は以下のとおりである。
（１）洗髪中の泡質
（評価基準）
◎：泡質が良いと評価した人が８人以上。
○：泡質が良いと評価した人が６人以上、８人未満。
△：泡質が良いと評価した人が４人以上、６人未満。
×：泡質が良いと評価した人が、４人未満。
（２）洗い流し時の指通り
（評価基準）
◎：洗い流し時に指通りが良いと評価した人が８人以上。
○：洗い流し時に指通りが良いと評価した人が６人以上、８人未満。
△：洗い流し時に指通りが良いと評価した人が４人以上、６人未満。
×：洗い流し時に指通りが良いと評価した人が、４人未満。
（３）濡れた状態のハリコシ感
（評価基準）
◎：濡れた状態の毛髪にハリコシ感があると評価した人が８人以上。
○：濡れた状態の毛髪にハリコシ感があると評価した人が６人以上、８人未満。
△：濡れた状態の毛髪にハリコシ感があると評価した人が４人以上、６人未満。
×：濡れた状態の毛髪にハリコシ感があると評価した人が、４人未満。
（４）乾燥後のハリコシ感
（評価基準）
◎：乾燥後の毛髪にハリコシ感があると評価した人が８人以上。
○：乾燥後の毛髪にハリコシ感があると評価した人が６人以上、８人未満。
△：乾燥後の毛髪にハリコシ感があると評価した人が４人以上、６人未満。
×：乾燥後の毛髪にハリコシ感があると評価した人が、４人未満。
（５）乾燥後のボリュ−ム感
（評価基準）
◎：乾燥後の毛髪に十分なボリュ−ム感があると評価した人が８人以上。
○：乾燥後の毛髪に十分なボリュ−ム感があると評価した人が６人以上、８人未満。
△：乾燥後の毛髪に十分なボリュ−ム感があると評価した人が４人以上、６人未満。
×：乾燥後の毛髪に十分なボリュ−ム感があると評価した人が、４人未満。
(Evaluation method)
10 professional panelists use each hair-washing cosmetics, (1) Foam quality during hair washing, (2) Follow the fingers when washing, (3) Harshness feeling in the wet state, (4) After drying (5) Volume feeling after drying was evaluated. The evaluation criteria are as follows.
(1) Foam quality during hair washing (evaluation criteria)
A: Eight or more people evaluated that the foam quality was good.
○: There are 6 or more and less than 8 people who evaluate that the foam quality is good.
Δ: There are 4 or more and less than 6 people who evaluate that the foam quality is good.
X: Less than 4 people evaluated that the foam quality was good.
(2) Follow your finger when washing off (evaluation criteria)
A: Eight or more people evaluated that the finger was good when washed off.
○: 6 or more people and less than 8 people evaluated that the fingering was good when washing.
Δ: There are 4 or more and less than 6 people who evaluated good fingering when washing.
×: Less than 4 people evaluated that the finger was good when washed off.
(3) Harshness feeling in the wet state (evaluation criteria)
A: Eight or more people evaluated that the wet hair had a harsh feeling.
○: There are 6 or more and less than 8 people who evaluate that the wet hair has a feeling of elasticity.
Δ: 4 or more and less than 6 people evaluated that the hair in a wet state had a sense of elasticity.
X: Less than four people evaluated that the wet hair had a harsh feeling.
(4) Harshness after drying (evaluation criteria)
A: Eight or more people evaluated that the hair after drying had a feeling of elasticity.
○: 6 or more and less than 8 people evaluated that the hair after drying had a feeling of elasticity.
Δ: 4 or more and less than 6 people evaluated that the hair after drying had a feeling of elasticity.
X: Less than 4 people evaluated that the hair after drying had a feeling of elasticity.
(5) Volume feeling after drying (evaluation criteria)
A: Eight or more people evaluated that the hair after drying had a sufficient volume feeling.
○: 6 or more and less than 8 people evaluated that the hair after drying had a sufficient volume feeling.
Δ: 4 or more and less than 6 people evaluated that the hair after drying had a sufficient volume feeling.
X: Less than 4 people evaluated that the hair after drying had a sufficient volume feeling.
＊２ プラスサイズ Ｌ−４５０Ｗ（互応化学工業社製、ポリマー含有量４０重量％）
* 2 Plus size L-450W (manufactured by Kyoyo Chemical Co., Ltd., polymer content 40% by weight)
＊４ モイストコートＰＸ（片倉チッカリン社製 ポリマー含有量２重量％）
＊５ ＭＥＲＱＵＡＴ ５５０（日本ルーブリゾール社製 ポリマー含有量９重量％）
＊６ プラスサイズ Ｌ−４４０（互応化学工業社製、ポリマー含有量３０重量％）
* 4 Moist coat PX (polymer content 2% by weight, manufactured by Katakura Chikkarin)
* 5 MERQUAT 550 (Nippon Lubrizol polymer content 9% by weight)
* 6 Plus size L-440 (manufactured by Kyoyo Chemical Co., Ltd., polymer content 30% by weight)
上記表１〜４において示した実施例１〜３５の本願発明の洗髪用化粧料を使用した場合、洗髪中の泡質が良好で、洗い流し時に指通りがよく、濡れた状態での毛髪にハリコシ感があり、乾燥後の毛髪に良好なハリコシ感とボリュ−ム感があるという結果が得られた。 When the hair-washing cosmetics of the present invention of Examples 1 to 35 shown in Tables 1 to 4 above are used, the foam quality during washing is good, the finger is good when washed off, and the hair is wet. As a result, the hair after drying had good tension and volume feeling.
一方、上記表４において、成分（Ａ）を他のアニオン性界面活性剤に置き換えた場合（比較例１及び２）、成分（Ｂ）を他の両性界面活性剤に置き換えた場合（比較例３）洗髪中の泡質やハリコシ感やボリューム感が悪くなった。
成分（Ｃ）を他のカチオン化高分子に置き換えた場合（比較例４及び５）、洗髪中の泡質や洗い流し時の指通りが悪くなった。
成分（Ｄ）を他の成分に置き換えた場合（比較例６及び７）、ハリコシ感とボリュ−ム感が悪くなった。
成分（Ｅ）を他の成分に置き換えた場合（比較例８及び９）、ボリュ−ム感が悪くなった。
On the other hand, in Table 4 above, when component (A) is replaced with another anionic surfactant (Comparative Examples 1 and 2), when component (B) is replaced with another amphoteric surfactant (Comparative Example 3). ) The foam quality, harshness and volume during hair washing deteriorated.
When component (C) was replaced with another cationized polymer (Comparative Examples 4 and 5), the foam quality during shampooing and fingering during scouring deteriorated.
When component (D) was replaced with other components (Comparative Examples 6 and 7), the harshness and volume feeling deteriorated.
When component (E) was replaced with other components (Comparative Examples 8 and 9), the volume feeling deteriorated.
（実施例３６）
（成分） （重量％）
１．Ｎ−ヤシ油脂肪酸メチルタウリンナトリウム ７．０
２．Ｎ−ラウロイルメチルアラニンナトリウム ３．０
３．ラウリン酸アミドプロピルヒドロキシスルホベタイン ７．０
４．カチオン化セルロ−ス（＊７） ０．５
５．ポリクオタニウム−４８（＊２） １．０
６．イソステアリン酸ＰＥＧ−８グリセリル ０．５
７．ジラウロイルグルタミン酸リシンナトリウム ０．０５
８．エデト酸二ナトリウム二水塩 ０．１
９．クエン酸 適量
１０．安息香酸ナトリウム ０．２
１１．香料 ０．５
１２．精製水 残余
＊７ ＣＥＬＱＵＡＴ ＳＣ−２３０Ｍ（アクゾノーベル社製）
（調製方法）
実施例１〜３５と同様の方法で調製した。
ｐＨ＝５．８
(Example 36)
(Ingredient) (wt%)
1. N-coconut oil fatty acid methyl taurine sodium 7.0
2. N-lauroylmethylalanine sodium 3.0
3. Lauric acid amidopropyl hydroxysulfobetaine 7.0
4). Cationized cellulose (* 7) 0.5
5. Polyquaternium-48 (* 2) 1.0
6). PEG-8 glyceryl isostearate 0.5
7). Dilauroyl glutamate lysine sodium 0.05
8). Edetate disodium dihydrate 0.1
9. Citric acid appropriate amount10. Sodium benzoate 0.2
11. Fragrance 0.5
12 Purified water residue * 7 CELQUAT SC-230M (manufactured by Akzo Nobel)
(Preparation method)
Prepared in the same manner as in Examples 1-35.
pH = 5.8
（実施例３７）
（成分） （重量％）
１．Ｎ−ヤシ油脂肪酸メチルタウリンナトリウム １０．０
２．Ｎ−ラウロイルメチルアラニンナトリウム ２．０
３．ラウリン酸アミドプロピルヒドロキシスルホベタイン ５．０
４．カチオン化セルロ−ス（＊７） ０．３
５．ポリクオタニウム−４８（＊８） ２．０
６．ポリオキシエチレンジオレイン酸メチルグルコシド（１２０Ｅ．Ｏ．） １．２
７．イソステアリン酸ＰＥＧ−８グリセリル ０．１
８．ジステアリン酸ポリエチレングリコ−ル（１） ２．０
９．エデト酸二ナトリウム二水塩 ０．１
１０．クエン酸 適量
１１．安息香酸ナトリウム ０．１
１２．香料 ０．４
１３．精製水 残余
＊８ プラスサイズ Ｌ−４５０（互応化学工業社製、ポリマー含有量４０重量％）
（調製方法）
実施例１〜３５と同様の方法で調製した。
ｐＨ＝５．０
(Example 37)
(Ingredient) (wt%)
1. N-coconut oil fatty acid methyl taurine sodium 10.0
2. N-lauroylmethylalanine sodium 2.0
3. Lauric acid amidopropyl hydroxysulfobetaine 5.0
4). Cationized cellulose (* 7) 0.3
5. Polyquaternium-48 (* 8) 2.0
6). Polyoxyethylene dioleic acid methyl glucoside (120 EO) 1.2
7). PEG-8 glyceryl isostearate 0.1
8). Polyethylene glycol distearate (1) 2.0
9. Edetate disodium dihydrate 0.1
10. Citric acid appropriate amount11. Sodium benzoate 0.1
12 Fragrance 0.4
13. Purified water residue * 8 Plus size L-450 (manufactured by Kyoyo Chemical Co., Ltd., polymer content 40% by weight)
(Preparation method)
Prepared in the same manner as in Examples 1-35.
pH = 5.0
実施例３６及び３７に示す洗髪用化粧料を評価したところ、泡質が良く、洗い流し時の指通り性が良好で、濡れた状態で毛髪にハリコシ感を与え、かつ乾燥後の毛髪にもハリコシ感を与えると共にボリュ−ム感も付与することができるものであった。 The cosmetics for hair washing shown in Examples 36 and 37 were evaluated. As a result, the foam quality was good, the finger-wiping property was good when washed off, the hair was harsh, and the hair after drying was also harsh. A feeling of volume can be imparted as well as feeling.
本願発明によれば、泡質が良く洗い流し時の指通り性が良好で、濡れた状態で毛髪にハリコシ感を与え、かつ乾燥後の毛髪にもハリコシ感を与えると共にボリュ−ム感も付与することができる洗髪用化粧料を提供できる。
According to the invention of the present application, the foam quality is good, the fingering property at the time of rinsing is good, the hair feels firm when wet, and the hair after drying also feels firm and feels volume. It is possible to provide a cosmetic for washing hair.
Claims (6)
（Ａ）Ｎ−アシルメチルタウリン型アニオン性界面活性剤
（Ｂ）アルキルアミドスルホベタイン型両性界面活性剤
（Ｃ）カチオン化セルロ−ス
（Ｄ）ポリクオタニウム−４８
（Ｅ）ポリオキシエチレン脂肪酸グリセリル
を含有することを特徴とする洗髪用化粧料。 The following components (A) to (E);
(A) N-acylmethyltaurine type anionic surfactant (B) alkylamide sulfobetaine type amphoteric surfactant (C) cationized cellulose (D) polyquaternium-48
(E) A hair-washing cosmetic comprising polyoxyethylene fatty acid glyceryl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017056930A JP6861956B2 (en) | 2017-03-23 | 2017-03-23 | Shampoo cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017056930A JP6861956B2 (en) | 2017-03-23 | 2017-03-23 | Shampoo cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2018158904A true JP2018158904A (en) | 2018-10-11 |
| JP6861956B2 JP6861956B2 (en) | 2021-04-21 |
Family
ID=63795890
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017056930A Active JP6861956B2 (en) | 2017-03-23 | 2017-03-23 | Shampoo cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6861956B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2021063015A (en) * | 2019-10-10 | 2021-04-22 | 日油株式会社 | Hair washing composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006282565A (en) * | 2005-03-31 | 2006-10-19 | Kose Corp | Shampoo composition |
| JP2011001374A (en) * | 2003-05-07 | 2011-01-06 | Ajinomoto Co Inc | Cleaning composition |
| JP2013133302A (en) * | 2011-12-27 | 2013-07-08 | Nof Corp | Detergent composition for skin |
-
2017
- 2017-03-23 JP JP2017056930A patent/JP6861956B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011001374A (en) * | 2003-05-07 | 2011-01-06 | Ajinomoto Co Inc | Cleaning composition |
| JP2006282565A (en) * | 2005-03-31 | 2006-10-19 | Kose Corp | Shampoo composition |
| JP2013133302A (en) * | 2011-12-27 | 2013-07-08 | Nof Corp | Detergent composition for skin |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2021063015A (en) * | 2019-10-10 | 2021-04-22 | 日油株式会社 | Hair washing composition |
| JP7205727B2 (en) | 2019-10-10 | 2023-01-17 | 日油株式会社 | Hair cleanser composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6861956B2 (en) | 2021-04-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2005068051A (en) | Cleaning preparation | |
| JP5575453B2 (en) | Hair treatment agent | |
| JP6861956B2 (en) | Shampoo cosmetics | |
| JP3807842B2 (en) | Shampoo composition | |
| JP7309190B2 (en) | hair cleanser | |
| JP3417893B2 (en) | Detergent composition | |
| JP2008115107A (en) | Aqueous hair-cleansing agent | |
| JP6884613B2 (en) | Cosmetics | |
| JP6220157B2 (en) | Rinse-type hair treatment composition | |
| JP2016069361A (en) | Hair cosmetics | |
| JP5570239B2 (en) | Gel-like skin cleansing composition | |
| JP6611440B2 (en) | Aqueous hair cleanser | |
| JP2006045183A (en) | Hair cosmetic | |
| JP3403367B2 (en) | Cleaning composition | |
| JP2017128513A (en) | Hair Cosmetics | |
| JP6616644B2 (en) | Hair washing cosmetics | |
| JP6295871B2 (en) | Shampoo composition | |
| JP5814164B2 (en) | Scalp treatment agent and treatment method using the treatment agent | |
| JP2021038162A (en) | Hair washing agent, hair cosmetic set, treatment method of shampoo/treatment, and treatment method of acid/heat treatment | |
| JP6856237B2 (en) | Hair treatment agent | |
| JP7181574B2 (en) | Hair cleansing composition | |
| JP6930253B2 (en) | Hair cleanser composition | |
| JP2010037484A (en) | Cleansing composition | |
| JP6782976B2 (en) | Hair styling cosmetics | |
| JP2005306788A (en) | Cleaning agent composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20200110 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20200909 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20201006 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20201202 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20210309 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20210319 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6861956 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |