JP2018126724A - Fluorine coating method - Google Patents

Fluorine coating method Download PDF

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JP2018126724A
JP2018126724A JP2017023693A JP2017023693A JP2018126724A JP 2018126724 A JP2018126724 A JP 2018126724A JP 2017023693 A JP2017023693 A JP 2017023693A JP 2017023693 A JP2017023693 A JP 2017023693A JP 2018126724 A JP2018126724 A JP 2018126724A
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acrylic resin
paint
coating
sealer
fluororesin
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一広 亀井
Kazuhiro Kamei
一広 亀井
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BOSS CO Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a method for improvement of adhesion when a fluorine resin-based paint is used for finish coating.SOLUTION: According to this coating method, a surface 1A of a base material 1 is previously treated and is coated with a water-based primer (main component: epoxy modified acrylic resin emulsion or the like) or a solvent-based primer (main component: epoxy modified acrylic resin system or the like) by a roller, a brush, an air spray and so on thereby forming an undercoat layer 2, and thereafter, an aqueous acrylic resin-based paint is diluted with an aqueous sealer which contains one of an acrylic resin-based emulsion, an epoxy resin-based emulsion, and an acrylic resin varnish as a main component, and is coated onto the undercoat layer 2 by the roller or the like thereby performing intermediate coating, and then, is dried during 20 to 24 hours thereby forming an intermediate coat layer 3. Finally, an aqueous fluorine resin-based paint is diluted with fresh water and is stirred, and then, is coated onto the intermediate coat layer 3 by the roller or the like thereby performing finish coating to form a top coat layer 4.SELECTED DRAWING: Figure 1

Description

本発明はフッ素塗装工法に係り、とくに基材の上にフッ素樹脂塗料を塗布する場合に好適なフッ素塗装工法に関する。   The present invention relates to a fluorine coating method, and more particularly to a fluorine coating method suitable for applying a fluorine resin paint on a substrate.

建築物のモルタル壁、コンクリート壁、ALCパネル、サイディング、タイル、鋼材や、橋梁等の鉄骨構造物等の表面は、日射や風雨などによる割れ、酸化、錆び等の劣化を抑えるため塗装処理を施して保護している。塗装後も日射や風雨などにより塗膜が劣化するため、5年乃至10年程度の間隔で定期的に補修塗装が施されている。塗装材料には化学的成分の異なる種々のタイプがあるが、中でもフッ素樹脂系塗料が耐候性に優れており、高価であるものの次第に普及し始めている。
ところで、塗装品質は塗膜と基材側との密着性(塗着性)が重要であるが、評価に長年月を要することから、上塗りにフッ素樹脂系塗料を用いる場合の下塗りに適した塗装材料の研究が進んでおらず、施主側が指定した種類の下塗り材を機械的に塗っているのが現状ある。
Surfaces of building mortar walls, concrete walls, ALC panels, siding, tiles, steel, and steel structures such as bridges are painted to prevent cracking, oxidization, rust, etc. caused by solar radiation, wind and rain, etc. And protect. Even after painting, the coating film deteriorates due to solar radiation, wind and rain, etc., so that repair painting is regularly applied at intervals of about 5 to 10 years. There are various types of coating materials having different chemical components. Among them, fluororesin-based paints are excellent in weather resistance and are gradually becoming widespread although they are expensive.
By the way, although the adhesion (coating property) between the coating film and the substrate side is important for the coating quality, it takes many years to evaluate, so the coating is suitable for undercoating when a fluororesin paint is used for the top coating. There is currently no progress in research on materials, and there is currently a mechanical application of the type of primer specified by the owner.

本発明は上記した従来技術の問題に鑑みなされたもので、上塗りにフッ素樹脂系塗料を用いる場合の密着性を高めることのできるフッ素塗装工法を提供することを、その目的とする。   The present invention has been made in view of the above-described problems of the prior art, and an object of the present invention is to provide a fluorine coating method capable of improving the adhesion when a fluororesin-based paint is used for overcoating.

請求項1記載の発明では、塗装対象の基材にフッ素樹脂系塗料を上塗り塗装するに際し、フッ素樹脂系塗料の下側に水性シーラーで希釈した水性アクリル樹脂系塗料を塗布しておくようにしたこと、を特徴としている。
請求項2記載の発明では、塗装対象の基材に下塗りと中塗りをしたあと、フッ素樹脂系塗料を上塗り塗装する塗装方法において、中塗りを、水性シーラーで希釈した水性アクリル樹脂系塗料を塗布することにより行うようにしたこと、を特徴としている。
請求項3記載の発明では、水性シーラーは、合成樹脂シーラーであること、
を特徴としている。
請求項4記載の発明では、水性シーラーは、アクリル樹脂系エマルジョン、エポキシ樹脂系エマルジョン、アクリル樹脂ワニスの内の1つが主成分であること、を特徴としている。
In the first aspect of the invention, when the fluororesin-based paint is overcoated on the substrate to be coated, an aqueous acrylic resin-based paint diluted with an aqueous sealer is applied below the fluororesin-based paint. It is characterized by that.
In the invention according to claim 2, in the coating method in which the base material to be coated is undercoated and intermediately coated and then overcoated with a fluororesin-based coating, the intermediate coating is applied with an aqueous acrylic resin-based coating diluted with an aqueous sealer. It is characterized by having done by doing.
In the invention according to claim 3, the aqueous sealer is a synthetic resin sealer,
It is characterized by.
The invention according to claim 4 is characterized in that the aqueous sealer is mainly composed of one of an acrylic resin emulsion, an epoxy resin emulsion and an acrylic resin varnish.

本発明によれば、水性シーラーで希釈した水性アクリル樹脂系塗料の塗膜が基材側とフッ素樹脂系塗料の塗膜を強固に密着させるので、フッ素樹脂系塗料のもつ優れた耐候性を長期にわたり維持させることができる。また、上塗りしたフッ素樹脂系塗料が基材に吸い込まれて膜厚が薄くなるのを防止することができる。   According to the present invention, the water-based acrylic resin-based paint film diluted with the water-based sealer firmly adheres the base material side to the fluororesin-based paint film, so that the excellent weather resistance of the fluororesin-based paint can be maintained for a long time. Can be maintained over time. Further, it is possible to prevent the overcoated fluororesin-based paint from being sucked into the base material and thinning the film.

本発明の一実施例に係るフッ素塗装工法の説明図である(実施例1)。It is explanatory drawing of the fluorine coating construction method which concerns on one Example of this invention (Example 1).

以下、本発明の最良の形態を実施例に基づき説明する。   Hereinafter, the best mode of the present invention will be described based on examples.

図1は本発明の一実施例に係るフッ素塗装工法の説明図である。
この実施例では、基材に下塗りと中塗りをしたのち、フッ素樹脂系塗料で上塗り塗装する場合を例に挙げる。
図1(1)乃至(4)において、1は塗装対象の基材であり、建築物、鉄骨構造物のモルタル壁、コンクリート壁、ALCパネル、サイディング、タイル、鋼材などである。
予め塗装準備として、基材1の表面1Aのゴミ、ヨゴレ、セメント粉末等の付着物をワイヤーブラシ、サンドペーパー、ウエスなどで除去、乾燥し下地処理をしておく(図1(1)参照)。
まず水性プライマー(例えば、菊水化学工業株式会社(登録商標)製キクスイ(登録商標)プライマースーパーE:主成分はエポキシ変性アクリル樹脂エマルジョン)を清水で希釈して基材1の表面1Aにローラ、刷毛、エアスプレー等で塗布するか、または溶剤系プライマー(例えば、菊水化学工業株式会社製キクスイプライマーSS:主成分はエポキシ変性アクリル樹脂系)を塗料用シンナーで希釈して基材1の表面1Aにローラ等で塗布し、下塗りを行い、20乃至24時間程度乾燥させて下塗り層2を形成する(図1(2)参照)。下塗りは、次に述べる中塗り層(符号3参照)と基材1との密着性を高めるために行われる。
FIG. 1 is an explanatory view of a fluorine coating method according to an embodiment of the present invention.
In this embodiment, a case where an undercoat and an intermediate coat are applied to a substrate and then an overcoat is applied with a fluororesin-based paint is taken as an example.
1 (1) to (4), reference numeral 1 denotes a base material to be painted, such as a building, a mortar wall of a steel structure, a concrete wall, an ALC panel, a siding, a tile, or a steel material.
As preparation for coating, deposits such as dust, dirt and cement powder on the surface 1A of the substrate 1 are removed with a wire brush, sandpaper, waste cloth, etc., dried, and then subjected to a ground treatment (see FIG. 1 (1)). .
First, an aqueous primer (for example, Kikusui (Registered Trademark) Primer Super E manufactured by Kikusui Chemical Co., Ltd., the main component is an epoxy-modified acrylic resin emulsion) is diluted with clean water, and a roller or brush is applied to the surface 1A of the substrate 1. Apply with air spray, etc., or dilute a solvent-based primer (for example, Kikusui Primer SS manufactured by Kikusui Chemical Co., Ltd., the main component is an epoxy-modified acrylic resin) with paint thinner to make the surface 1A of the substrate 1 It is applied with a roller or the like, undercoated, and dried for about 20 to 24 hours to form an undercoat layer 2 (see FIG. 1 (2)). The undercoating is performed to improve the adhesion between the intermediate coating layer (see reference numeral 3) described below and the substrate 1.

次に、水性アクリル樹脂系塗料(例えば、日本特殊塗料株式会社(登録商標)製シルビア(登録商標)WA−100、関西ペイント株式会社(登録商標)製アスカII)を合成樹脂系の水性シーラーで希釈して下塗り層2の上にローラ、刷毛、エアスプレー等で塗布して中塗りを行い、20乃至24時間程度乾燥させて中塗り層3を形成する(図1(3)参照)。この際、水性アクリル樹脂系塗料の主剤16kgに対し、水性シーラー1乃至1.5リットルの割合で希釈し、6乃至8分間程度攪拌する。   Next, water-based acrylic resin-based paint (for example, Silvia (registered trademark) WA-100 manufactured by Nippon Special Paint Co., Ltd., Asuka II manufactured by Kansai Paint Co., Ltd. (registered trademark)) is a synthetic resin-based aqueous sealer. It is diluted and applied onto the undercoat layer 2 with a roller, brush, air spray, or the like to make an intermediate coat, and dried for about 20 to 24 hours to form the intermediate coat layer 3 (see FIG. 1 (3)). In this case, 16 kg of the main component of the aqueous acrylic resin-based paint is diluted at a ratio of 1 to 1.5 liters of aqueous sealer and stirred for about 6 to 8 minutes.

水性シーラーには、アクリル樹脂系エマルジョン、エポキシ樹脂系エマルジョン、アクリル樹脂ワニスなどの1つを主成分とする合成樹脂シーラー(JIS
K 5663)を用いることができる。具体例を挙げると、関西ペイント株式会社製エコカチオンシーラー(主成分:カチオン性アクリルシリコン樹脂エマルジョン)、菊水化学工業株式会社製プライマースーパーE(主成分:エポキシ変性アクリル樹脂エマルジョン)、大日本塗料株式会社(登録商標)製水性マイティーシーラーマルチ(主成分:特殊変性アクリル樹脂ワニス)があり、他にも株式会社アサヒペン製水性シーラー、ニッペホームプロダクツ株式会社製水性浸透シーラや、特殊ウレタン変性アクリル樹脂エマルジョンを主成分とする合成樹脂シーラーなどを用いることができる。
For water-based sealers, synthetic resin sealers (JIS) with one of acrylic resin emulsion, epoxy resin emulsion, acrylic resin varnish, etc. as the main component
K 5663) can be used. Specific examples include Eco-cation sealer (main component: cationic acrylic silicone resin emulsion) manufactured by Kansai Paint Co., Ltd., Primer Super E (main component: epoxy-modified acrylic resin emulsion) manufactured by Kikusui Chemical Co., Ltd., Dainippon Paint Co., Ltd. There is a company (registered trademark) water-based mighty sealer multi (main component: specially modified acrylic resin varnish), other water-based sealers manufactured by Asahi Pen Co., Ltd. A synthetic resin sealer containing as a main component can be used.

ここで、水性アクリル樹脂系塗料は、通常、清水で希釈して使用するが、本願発明者は、清水に代えて水性シーラーで希釈することにより、上塗りに用いるフッ素樹脂系塗料の塗膜と基材側との密着度が著しく向上することを見出した。また、フッ素樹脂系塗料の塗膜が基材に吸い込まれるのを抑制し、塗装後の膜厚減少を防止できることを見出した。   Here, the water-based acrylic resin-based paint is usually used after being diluted with clean water. However, the present inventor has diluted the coating with the coating film of the fluororesin-based paint used for the top coating by diluting with an aqueous sealer instead of fresh water. It has been found that the degree of adhesion with the material side is remarkably improved. Moreover, it discovered that the coating film of a fluororesin-type coating material was suppressed inhaling into a base material, and the film thickness reduction after coating could be prevented.

最後に、水性フッ素樹脂系塗料(例えば、菊水化学工業株式会社製キーズ(登録商標)水系フッ素エース)を主剤15kgに対し、清水0乃至1.5リットルの割合で希釈し、6乃至8分間程度攪拌したのち、中塗り層3の上に、ローラ、刷毛、エアスプレー等で塗布して上塗りを行い、上塗り層4を形成する。または、溶剤系フッ素樹脂系塗料(例えば、菊水化学工業株式会社製キーズスーパーパワーフッ素)を主剤13.5kg、硬化剤1.5kgに対し、塗料用シンナーを0.8乃至1.6ットルの割合で希釈し、6乃至8分間程度攪拌したのち、中塗り層3の上にローラ等で塗布して上塗りを行い、上塗り層4を形成する。   Finally, a water-based fluororesin-based paint (for example, Keys (registered trademark) water-based fluorine ace manufactured by Kikusui Chemical Co., Ltd.) is diluted at a ratio of 0 to 1.5 liters of fresh water with respect to 15 kg of the main ingredient, and is about 6 to 8 minutes. After stirring, the overcoat layer 4 is formed on the intermediate coat layer 3 by applying it with a roller, a brush, an air spray, or the like. Alternatively, a solvent-based fluororesin-based paint (for example, Keys Super Power Fluorine, manufactured by Kikusui Chemical Co., Ltd.) is used at a ratio of 0.8 to 1.6 torr of paint thinner with respect to 13.5 kg of the main agent and 1.5 kg of the curing agent. Then, the mixture is stirred for about 6 to 8 minutes, and then applied onto the intermediate coating layer 3 with a roller or the like for overcoating to form the overcoating layer 4.

この実施例によれば、被塗装対象であるモルタル壁、コンクリート壁、ALCパネル、サイディング、タイル、鋼材などの基材1に、下から順に下塗り層2と中塗り層3を形成したあと、フッ素樹脂系塗料を上塗りするフッ素塗装工法を行なうに際し、フッ素樹脂系塗料の下の中塗り層2を、水性アクリル樹脂系塗料を清水でなく水性シーラーで希釈して塗布することで形成することにより、水性アクリル樹脂系塗料の塗膜が基材1の側と上塗りしたフッ素樹脂系塗料による塗膜を強固に密着させることができ、フッ素樹脂系塗料のもつ優れた耐候性を長期にわたり維持させることができる。また、また基材1と上塗りしたフッ素樹脂系塗料の間に、水性シーラーで希釈した水性アクリル樹脂系塗料の塗膜が介在することにより、フッ素樹脂系塗料が基材1に吸い込まれて膜厚が薄くなるのを確実に防止することができる。   According to this embodiment, after forming an undercoat layer 2 and an intermediate coat layer 3 in order from the bottom on a base material 1 such as a mortar wall, concrete wall, ALC panel, siding, tile, steel material to be coated, fluorine By forming the intermediate coating layer 2 under the fluororesin-based paint by diluting the water-based acrylic resin-based paint with an aqueous sealer instead of fresh water when performing the fluorine coating method for overcoating the resin-based paint, The coating film of the water-based acrylic resin-based paint can firmly adhere the coating film of the fluororesin-based paint overcoated with the substrate 1 side, and can maintain the excellent weather resistance of the fluororesin-based paint over a long period of time. it can. In addition, a coating film of an aqueous acrylic resin paint diluted with an aqueous sealer is interposed between the base material 1 and the overcoated fluororesin paint, so that the fluororesin paint is sucked into the base material 1 and has a film thickness. Can be reliably prevented.

なお、上記した実施例では、下塗りをプライマーで行う場合を例に挙げて説明したが、シーラーを下塗りしたり、微弾性塗料を下塗りするようにしても良い。
また、フッ素樹脂系塗料にも日本特殊塗料株式会社製シルビアWF−400など各種の塗料を用いることができる。
In the above-described embodiments, the case where the primer is applied with a primer has been described as an example. However, a sealer may be undercoated or a slightly elastic paint may be undercoated.
Various paints such as Silvia WF-400 manufactured by Nippon Special Paint Co., Ltd. can also be used for the fluororesin paint.

本発明は、建築物、鉄骨構造物のモルタル壁、コンクリート壁、ALCパネル、サイディング、タイル、鋼材などを被塗装対象基材としてフッ素樹脂系塗料で塗装する場合に適用可能である。   INDUSTRIAL APPLICABILITY The present invention is applicable when a building, a mortar wall of a steel structure, a concrete wall, an ALC panel, a siding, a tile, a steel material, etc. are coated with a fluororesin-based paint as a substrate to be coated.

1 基材
2 下塗り層
3 中塗り層
4 上塗り層
DESCRIPTION OF SYMBOLS 1 Base material 2 Undercoat layer 3 Middle coat layer 4 Topcoat layer

Claims (4)

塗装対象の基材にフッ素樹脂系塗料を上塗り塗装するに際し、
フッ素樹脂系塗料の下側に水性シーラーで希釈した水性アクリル樹脂系塗料を下塗りしておくようにしたこと、
を特徴とするフッ素塗装工法。
When overcoating a fluororesin paint on the substrate to be painted,
Underlying water-based acrylic resin-based paint diluted with water-based sealer under the fluororesin-based paint,
Fluorine painting method characterized by
塗装対象の基材に下塗りと中塗りをしたあと、フッ素樹脂系塗料を上塗り塗装する塗装方法において、
中塗りを、水性シーラーで希釈した水性アクリル樹脂系塗料を塗布することにより行うようにしたこと、
を特徴とするフッ素塗装工法。
In the coating method, after applying the undercoat and intermediate coat to the base material to be painted, overcoating the fluororesin paint,
The intermediate coating was performed by applying a water-based acrylic resin paint diluted with a water-based sealer,
Fluorine painting method characterized by
水性シーラーは、合成樹脂シーラであること、
を特徴とする請求項1または2記載のフッ素塗装工法。
The aqueous sealer is a synthetic resin sealer,
The fluorine coating method according to claim 1 or 2, wherein:
水性シーラーは、アクリル樹脂系エマルジョン、エポキシ樹脂系エマルジョン、アクリル樹脂ワニスの内の1つが主成分であること、
を特徴とする請求項3記載のフッ素塗装工法。
The aqueous sealer is mainly composed of one of acrylic resin emulsion, epoxy resin emulsion and acrylic resin varnish.
The fluorine coating method according to claim 3.
JP2017023693A 2017-02-12 2017-02-12 Fluorine coating method Pending JP2018126724A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001207652A (en) * 2000-01-21 2001-08-03 Nippon Paint Co Ltd Method of repairing exterior-wall coating
JP2001239517A (en) * 2000-03-01 2001-09-04 Kansai Paint Co Ltd Method for producing inorganic material
JP2004196914A (en) * 2002-12-17 2004-07-15 Chugoku Marine Paints Ltd Aqueous sealer composition for inorganic base material, and method for preparing surface of inorganic base material using the same
JP2009149767A (en) * 2007-12-20 2009-07-09 Ohbayashi Corp Substrate preparation material and method for coating finishing of cement-based substrate
JP2013006932A (en) * 2011-06-23 2013-01-10 Henkel Japan Ltd Resin composition for sealer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001207652A (en) * 2000-01-21 2001-08-03 Nippon Paint Co Ltd Method of repairing exterior-wall coating
JP2001239517A (en) * 2000-03-01 2001-09-04 Kansai Paint Co Ltd Method for producing inorganic material
JP2004196914A (en) * 2002-12-17 2004-07-15 Chugoku Marine Paints Ltd Aqueous sealer composition for inorganic base material, and method for preparing surface of inorganic base material using the same
JP2009149767A (en) * 2007-12-20 2009-07-09 Ohbayashi Corp Substrate preparation material and method for coating finishing of cement-based substrate
JP2013006932A (en) * 2011-06-23 2013-01-10 Henkel Japan Ltd Resin composition for sealer

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