JP4897259B2 - Anticorrosion coating method for power transmission towers - Google Patents

Anticorrosion coating method for power transmission towers

Info

Publication number
JP4897259B2
JP4897259B2 JP2005253083A JP2005253083A JP4897259B2 JP 4897259 B2 JP4897259 B2 JP 4897259B2 JP 2005253083 A JP2005253083 A JP 2005253083A JP 2005253083 A JP2005253083 A JP 2005253083A JP 4897259 B2 JP4897259 B2 JP 4897259B2
Authority
JP
Japan
Prior art keywords
coating
paint
resin
anticorrosion
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2005253083A
Other languages
Japanese (ja)
Other versions
JP2007061760A (en
Inventor
浩平 諫山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHUDEN-KOGYOU CO., LTD.
Original Assignee
CHUDEN-KOGYOU CO., LTD.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHUDEN-KOGYOU CO., LTD. filed Critical CHUDEN-KOGYOU CO., LTD.
Priority to JP2005253083A priority Critical patent/JP4897259B2/en
Publication of JP2007061760A publication Critical patent/JP2007061760A/en
Application granted granted Critical
Publication of JP4897259B2 publication Critical patent/JP4897259B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Application Of Or Painting With Fluid Materials (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Description

本発明は、送電鉄塔を構成する鋼材の防食塗装方法に関する。   The present invention relates to an anticorrosion coating method for steel materials constituting a power transmission tower.

送電鉄塔は、風雨に晒され錆の発生しやすい苛酷な環境に設置されることが多いため、これを構成する鋼材には溶融亜鉛メッキ鋼材などが用いられるが、時間経過に伴い鋼材の防錆処理面に錆が発現してくる。そのため、所定の期間経過後に送電鉄塔を構成する鋼材の表面に防食塗装が施される。しかし、その後の時間経過により、上塗り塗膜の劣化によるチョーキングや表面のワレが生じ、さらには鋼材表面で発現した錆が当該塗膜表面に浮き出たり、塗膜内への水分の浸透により鋼材との界面で亜鉛が溶出し、塗膜の剥離や浮きなどが生じる。また、上記の錆や表面のワレに至らない場合でも、塗膜表面の色相の変化(色あせ)による美観の低下、環境調和の欠如、航空色のような機能色の低下などが生じた場合、強く塗り替えが要請されることがある。従って、このような事情のもと、所定の塗装周期ごと定期的に防食塗装(塗り替え塗装)を繰り返す必要がある。この塗り替え塗装は、経済性を考慮すると、発錆寸前に行うのが好ましい。   Since power transmission towers are often installed in harsh environments where they are exposed to wind and rain and are prone to rust, hot-dip galvanized steel is used as the steel that constitutes them. Rust appears on the treated surface. Therefore, anti-corrosion coating is applied to the surface of the steel material constituting the power transmission tower after a predetermined period. However, over time, choking due to deterioration of the top coat film and cracking of the surface occur, and furthermore, rust that appears on the surface of the steel material floats on the surface of the paint film, or moisture penetrates into the paint film and the steel material. Zinc elutes at the interface, and peeling or floating of the coating film occurs. In addition, even if the above rust and cracking of the surface do not occur, if the appearance of the coating surface changes in color (fading), the aesthetics deteriorate, lack of environmental harmony, functional color such as aerial colors, etc. Strong repainting may be required. Therefore, under such circumstances, it is necessary to periodically repeat the anticorrosion coating (repainting) every predetermined coating cycle. This repainting is preferably performed just before rusting in consideration of economy.

この現場での防食塗装作業は、作業中の感電事故などを防止するため、防食塗装を施そ
うとする送電鉄塔が支持する架空送電線を停電して行わなければならない。この送電線の停電は、通常、当該送電線路の供給電力を他の送電線路に振り分けることにより行われる。しかし、上記他の送電線路でトラブルが発生した場合、電力の供給支障が生じ、その結果需要地が停電する可能性がある。このリスクを極力低減するために、送電線路を長時間停電させることができないという事情がある。従って、この防食塗装作業は短時間で完了させる必要があり、通常、作業期間は1日以内とされている。
In order to prevent an electric shock accident during the work, the anti-corrosion coating work at this site must be performed by powering off the overhead transmission line supported by the transmission tower to which the anti-corrosion coating is to be applied. This power failure of the power transmission line is usually performed by distributing the power supplied to the power transmission line to another power transmission line. However, when trouble occurs in the other power transmission lines, there is a possibility that power supply will be hindered, resulting in a power outage in the demand area. In order to reduce this risk as much as possible, there is a circumstance that the power transmission line cannot be interrupted for a long time. Therefore, it is necessary to complete this anticorrosion painting work in a short time, and the work period is usually within one day.

防食塗装は、長期防食性を確保するために、通常、下塗りおよび上塗り、または下塗り、中塗りおよび上塗りのように重ね塗りによって行われる。上記のような限られた時間で塗料を重ね塗りして防食塗装を行うためには、塗料に優れた速乾性が必要とされる。このような速乾性の要求を満たす塗料の種類は限られており、従来、変性ビニル樹脂系塗料や油性ペイントなどが用いられてきた。例えば、変性ビニル樹脂系塗料は、下塗りおよび上塗りの双方に使用されており、アルミニウムペイントやアクリル変性アルキッド樹脂系塗料では、あらかじめ素地に速乾性ジンククロメートプライマーなどが塗布され、該プライマーが乾燥した後の塗膜面にアルミニウムペイントやアルキッド樹脂系塗料が上塗りされるのが一般的であった。しかし、上記の変性ビニル樹脂系塗料や油性ペイントは、長期防食性や耐候性については十分とはいえず、比較的短時間で防食塗装(塗り替え)工事を行う必要があった。しかも、送電停止時間に制約があることから、毎回の塗り替え工事において同種の防食塗料を重ね塗りする方法をとらざるを得ず、結果として塗り替え周期の長期化を図ることができないという問題があった。   In order to ensure long-term anticorrosion, the anticorrosion coating is usually performed by overcoating such as undercoating and overcoating, or undercoating, intermediate coating and overcoating. In order to perform anti-corrosion coating by repeatedly applying the paint in the limited time as described above, the paint needs to have excellent quick drying properties. There are limited types of paints that satisfy such requirements for quick drying, and conventionally, modified vinyl resin-based paints, oil-based paints, and the like have been used. For example, modified vinyl resin-based paints are used for both undercoating and overcoating. In aluminum paints and acrylic-modified alkyd resin-based paints, a quick-drying zinc chromate primer is applied to the substrate in advance, and the primer is dried. In general, an aluminum paint or an alkyd resin-based paint is overcoated on the coating surface. However, the modified vinyl resin-based paints and oil paints are not sufficient for long-term corrosion resistance and weather resistance, and it is necessary to perform anticorrosion coating (repainting) work in a relatively short time. Moreover, because there is a restriction on the power transmission stop time, there is a problem that the method of repeatedly applying the same type of anticorrosive paint in each repainting work has to be taken, and as a result, the repainting cycle cannot be prolonged. .

一方、塗膜の長期防食性や耐候性に優れた塗料としては、エポキシ樹脂系塗料、ウレタン樹脂系塗料、フッ素樹脂系塗料などが挙げられる。ウレタン樹脂系塗料やフッ素樹脂系塗料は、通常、中塗り用や上塗り用として使用され、そのためにエポキシ樹脂系塗料を用いて下塗りを行い、当該塗料の塗膜を形成しておく必要がある。しかし、エポキシ樹脂系塗料は、上記のような利点はあるものの、乾燥性に難点がある。例えば、気温20℃の環境下で塗装を行った場合、当該塗膜面に重ね塗りが可能となるまでのインタバルは、通常18時間程度を要し、さらに気温の低下する冬場などではこのインタバルがさらに長期化する。したがって、このエポキシ樹脂系塗料を送電鉄塔鋼材の下塗りに使用しようとすると、必然的に送電停止時間を長くせざるを得ず、作業員の待機時間も長くなるという問題とともに、これらの塗料を使用するのが困難であるという問題もあった。   On the other hand, examples of the paint excellent in long-term corrosion resistance and weather resistance of the coating film include epoxy resin-based paints, urethane resin-based paints, and fluororesin-based paints. Urethane resin-based paints and fluororesin-based paints are usually used for intermediate coating and top coating, and for that purpose, it is necessary to undercoat using an epoxy resin-based coating to form a coating film of the coating. However, the epoxy resin-based paint has the above-mentioned advantages but has a difficulty in drying. For example, when coating is performed in an environment where the temperature is 20 ° C., the interval until the coating surface can be overcoated usually takes about 18 hours. Prolonged further. Therefore, if you try to use this epoxy resin-based paint for the undercoating of transmission tower steel, you must inevitably lengthen the power transmission stop time and use these paints with the problem that the waiting time for workers will also be longer. There was also a problem that it was difficult to do.

また、エポキシ樹脂系塗料は、通常、使用に際して混合して塗装に用いる2液型であり、一般に塗料の可使時間が短く、これらの混合比が変わったり、硬化促進剤を用いることにより、更に可使時間が短くなる可能性がある。したがって、塗料使用量が増加し、塗装コストおよび輸送費が増大するといった問題があった。さらに、エポキシ樹脂系塗料は、キシレン、トルエンなどの芳香族系のほか、メチルイソブチルケトン(MIBK)などケトン系、ブタノールなどのアルコール系、酢酸ブチルなどのエステル系、カルビトールなどのエーテル系などの官能基を有し溶解力の大きい有機溶剤を含有するため、ビニル樹脂系やアルミニウム系の旧塗膜への付着性に難点がある。
特開2001−40280号公報
In addition, the epoxy resin-based paint is usually a two-component type which is mixed for use and used for coating. Generally, the usable time of the paint is short, the mixing ratio thereof is changed, or by using a curing accelerator, The pot life may be shortened. Therefore, there has been a problem that the amount of paint used increases and the coating cost and transportation cost increase. Furthermore, epoxy resin paints include aromatics such as xylene and toluene, ketones such as methyl isobutyl ketone (MIBK), alcohols such as butanol, esters such as butyl acetate, and ethers such as carbitol. Since it contains an organic solvent having a functional group and high dissolving power, there is a difficulty in adhesion to vinyl resin-based and aluminum-based old coating films.
Japanese Patent Laid-Open No. 2001-40280

本発明は、かかる事情に鑑み、約12時間で少なくとも2回の重ね塗りを行う防食塗装作業を完了させ、しかも長期防食性や耐候性に優れた塗膜を得ることができ、その結果防食塗装の周期を長くすることができる防食塗装方法を提供することを目的とする。
In view of such circumstances, the present invention can complete an anti-corrosion coating operation in which at least two recoating operations are performed in about 12 hours, and can obtain a coating film excellent in long-term anti-corrosion properties and weather resistance. It aims at providing the anticorrosion coating method which can lengthen the period of this.

本発明者は、上記目的のもと、鋭意検討を重ねた結果、エポキシ樹脂系塗料と比較しても同等程度の長期防食性や耐候性を有する特定の湿気硬化型樹脂塗料が、従来のビニル樹脂系塗料やアルミニウムペイントなどの塗膜にも付着可能であるとの知見を得、本発明を完成した。   Based on the above objectives, the present inventor has conducted extensive studies, and as a result, a specific moisture-curable resin paint having a long-term corrosion resistance and weather resistance comparable to that of an epoxy resin paint is a conventional vinyl resin. The present invention was completed by obtaining the knowledge that it can be attached to a coating film such as a resin paint or aluminum paint.

上記目的は、本発明によれば、鋼材塗装面の素地調整を行い、この素地調整面に、環境温度条件に応じて半硬化乾燥時間を約4時間以内に調整した湿気硬化型樹脂塗料を下塗りした後、当該半硬化乾燥状態に達したところで該下塗り塗膜面に防食塗料を重ね塗りすることを特徴とする送電鉄塔の防食塗装方法によって達成される。
According to the present invention, the object of the present invention is to adjust the substrate surface of the steel coating surface, and undercoat the substrate adjustment surface with a moisture curable resin paint whose semi-curing drying time is adjusted within about 4 hours according to the environmental temperature conditions. Then, when the semi-cured and dried state is reached, the anti-corrosion paint is overcoated on the surface of the undercoat coating film.

上記鋼材塗装面は、変性ビニル樹脂系塗料またはアルミニウムペイント塗膜面であり、これらの旧塗膜面に本発明の防食塗装方法をより好適に使用できる。   The steel material coating surface is a modified vinyl resin paint or aluminum paint coating surface, and the anticorrosion coating method of the present invention can be more suitably used for these old coating surfaces.

本発明によれば、送電鉄塔の防食塗装において、その下塗り用塗料として速乾性を有する特定の湿気硬化型樹脂塗料をさらに環境温度条件に応じて半硬化乾燥時間を約4時間以内に調整して塗装することとしたので、短時間のうちに硬化した下塗り塗膜面に更に中塗り塗装や上塗り塗装が可能となる。これにより、ロス時間を低減でき、塗装コストの低減が図れる。また、中塗り塗料や上塗り塗料にも長期防食性や耐候性に優れた塗料を使用でき、このような優れた性能を備えた塗膜を積層できるので、防食塗装の周期を長くすることができる。その結果、長期的スパンで見た場合、塗り替え塗装工事に係る材料などの輸送コストや送電停止回数の低減が図られる。
According to the present invention, in the anticorrosion coating of a power transmission tower, a specific moisture-curing resin paint having a quick drying property is further adjusted as an undercoating paint by adjusting the semi-curing drying time within about 4 hours according to the environmental temperature conditions. Since the coating is performed, the intermediate coating or the top coating can be further applied to the surface of the undercoat film that has been cured in a short time. Thereby, loss time can be reduced and the coating cost can be reduced. In addition, coatings with excellent long-term corrosion resistance and weather resistance can be used for intermediate coatings and top coatings, and coatings with such excellent performance can be laminated, so the cycle of anticorrosion coating can be extended. . As a result, when viewed from a long-term span, it is possible to reduce the transportation cost of materials and the like related to repainting work and the number of power transmission interruptions.

本発明の防食塗装方法は、発錆により劣化した鋼材の防食塗装面に素地調整を行い、当該素地調整面に湿気硬化型樹脂塗料による下塗り塗膜を形成した後、その上に少なくとも1回防食塗料を用いて重ね塗り塗装を行うものである。以下、本発明の防食塗装方法についてより詳細に説明する。   The anticorrosion coating method of the present invention is to prepare a base on the anticorrosion coating surface of a steel material deteriorated by rusting, and after forming an undercoat film with a moisture-curable resin paint on the base adjustment surface, at least once anticorrosion Overpainting is performed using paint. Hereinafter, the anticorrosion coating method of the present invention will be described in more detail.

送電鉄塔を構成する鋼材としては、通常、炭素鋼などの表面に防錆処理を施した山形鋼などが使用されるが、本発明においては鋼材の種類や形状について特に限定されない。例えば、鋼材の種類としては、炭素鋼、各種合金鋼、ステンレス鋼などが挙げられ、形状としては、丸鋼、山形鋼、平形鋼、みぞ形鋼、I形鋼、H形鋼などのほか、鋼管などが挙げられる。   As the steel material constituting the power transmission tower, angle steel having a rust-proofing treatment on the surface thereof such as carbon steel is usually used, but in the present invention, the type and shape of the steel material are not particularly limited. For example, the types of steel materials include carbon steel, various alloy steels, stainless steel, etc. The shapes include round steel, angle steel, flat steel, groove steel, I-shaped steel, H-shaped steel, etc. Examples include steel pipes.

上記鋼材は、その表面に防食塗装がすでに施されていてもよく、上記のように防錆処理が施されたものであってもよいが、本発明においては、前者の防食塗装がすでに少なくとも1回施された鋼材を対象とする。送電鉄塔の場合、この防食塗装は、通常、ビニル樹脂系塗料や油性ペイントが複数回重ね塗りされたものである。   The steel material may have already been subjected to anticorrosion coating on the surface thereof, or may have been subjected to rust prevention treatment as described above. However, in the present invention, the former anticorrosion coating is already at least 1 Targeted steel materials that have been recirculated. In the case of a power transmission tower, this anticorrosion coating is usually one in which a vinyl resin paint or an oil paint is applied multiple times.

このような鋼材塗装面について、塗装面の浮き錆や塗膜の劣化した部分と活膜部分(塗膜の劣化していない部分)とに分けて素地調整を行う。素地調整は、旧塗膜上に新たに施工される防食塗膜との付着性を向上させることを目的とするものである。   For such a steel material coated surface, the substrate is adjusted by dividing it into a floating rust on the painted surface and a part where the coating film is deteriorated and an active film part (a part where the coating film is not deteriorated). The substrate adjustment is intended to improve the adhesion with the anticorrosion coating newly constructed on the old coating.

旧塗膜の劣化部分については、上記浮き錆や旧塗膜の劣化の程度などに応じて、例えばケレン処理やブラスト処理などの公知の方法を適宜用い、塗装面の浮き錆や劣化した旧塗膜などを除去する。ケレン処理は、ウエス、電動ディスクサンダー、ワイヤーブラシ、スクレーパー、サンドペーパーなどを使用し、上記の錆部分や劣化した塗膜を除去する方法であり、ブラスト処理は、さらに発錆などが著しい場合に、小粒径の吹き付け(研磨)材を圧縮空気で吹き付けることで塗装面の錆や劣化した塗膜を除去する方法である。   For the deteriorated part of the old paint film, depending on the degree of floating rust or deterioration of the old paint film, for example, a known method such as keren treatment or blast treatment is used as appropriate. Remove the film. Keren treatment is a method of removing the rusted part and deteriorated coating film using waste cloth, electric disk sander, wire brush, scraper, sandpaper, etc. This is a method of removing rust and a deteriorated coating film on a painted surface by spraying a spraying (polishing) material having a small particle diameter with compressed air.

また、活膜部分については、当該部分にこびりついた塵芥、油分や塩分などをワイヤブラシ、スクレーパー、サンドペーパーなどで目粗しした後、ウエスなどを用いて除去する。塵芥などが強固に活膜面に付着している場合には、電動ディスクサンダーなどを用いて目粗ししてもよい。   In addition, the dust, oil, salt, etc. stuck to the active film portion is coarsened with a wire brush, scraper, sandpaper, etc., and then removed using a waste or the like. When dust or the like is firmly attached to the active film surface, it may be roughened using an electric disk sander or the like.

このように鋼材の旧塗装面に素地調整を施した後、湿気硬化型樹脂塗料を用いて下塗りを行う。この湿気硬化型樹脂塗料としては、ポリウレタン樹脂系、エポキシ樹脂−ケチミン硬化系、アルキルシリケート樹脂系、アルキルアルコキシシラン樹脂系などが挙げられる。本発明においては、これらのうち湿気硬化型ポリウレタン樹脂塗料を用いるのが好ましく、更に1液型のものを使用するのがより好ましい。これらの湿気硬化型樹脂塗料は、公知の種々の製法によって製造されたものが好適に使用できる。   In this way, after adjusting the surface of the old painted surface of the steel material, undercoating is performed using a moisture curable resin paint. Examples of the moisture curable resin coating include polyurethane resin, epoxy resin-ketimine curing, alkyl silicate resin, and alkyl alkoxysilane resin. In the present invention, it is preferable to use a moisture-curable polyurethane resin coating, and it is more preferable to use a one-pack type. As these moisture curable resin coatings, those produced by various known production methods can be suitably used.

上記の1液型湿気硬化型ポリウレタン(MCU)樹脂塗料は、ポリオールとポリイソシアネートとを反応させてすべての水酸基をウレタン結合させて得られるイソシアネート基(−NCO基)を残留させた樹脂を主剤として含む。ポリイソシアネートは3官能基以上で、架橋間の重量平均分子量が500〜1500(Mw)であることが好ましい。この樹脂にイソシアネートとの反応性がなく、含水性および吸湿性のない体質顔料や着色顔料を添加して、上記塗料が製造される。上記体質顔料としては、タルク、炭酸カルシウム、硫酸バリウム、マイカ状酸化鉄などが挙げられる。また、着色顔料としては、酸化チタン、ベンガラ、カーボンブラック、フタロシアニンブルーなどが挙げられる。これらの顔料は、上記樹脂に単独で配合してもよく、2種以上を組み合わせて配合することもできる。このような1液型湿気硬化型ポリウレタン(MCU)樹脂塗料としては、例えば、パイネ#8010S(商品名、中電工業社製)やVグラン(商品名、大日本塗料社製)などが挙げられる。   The above one-component moisture curable polyurethane (MCU) resin coating is mainly composed of a resin in which an isocyanate group (-NCO group) obtained by reacting a polyol and a polyisocyanate to urethane-bond all hydroxyl groups is left. Including. The polyisocyanate preferably has three or more functional groups and a weight average molecular weight between crosslinks of 500 to 1500 (Mw). The paint is produced by adding extender pigments and coloring pigments which are not reactive with isocyanate and have no water content and moisture absorption. Examples of the extender pigment include talc, calcium carbonate, barium sulfate, and mica-like iron oxide. Examples of the color pigment include titanium oxide, bengara, carbon black, and phthalocyanine blue. These pigments may be blended alone or in combination of two or more in the above resin. Examples of such one-component moisture-curable polyurethane (MCU) resin paints include Paine # 8010S (trade name, manufactured by Chuden Kogyo Co., Ltd.) and V Gran (trade name, manufactured by Dainippon Paint Co., Ltd.). .

上記湿気硬化型ポリウレタン樹脂系塗料の硬化反応は、当該塗料中に主剤として含まれる湿気硬化型ポリウレタン樹脂の開環重合反応を利用したものであり、湿気などの環境中の水分と反応して硬化する。その硬化反応は、次のように概説できる。上記樹脂は、末端に反応基としてイソシアネート基を有しており、この反応基が空気中の湿気や素地調整面上の水分と反応してカルバミン酸が生成される。このカルバミン酸は非常に活性が強く分解してアミンと二酸化炭素が生成される。生成されたアミンは、周囲に存在する湿気硬化型ポリウレタン樹脂のイソシアネート基と反応し、ウレア結合によって3次元の網目構造を有する強靭な硬化物(塗膜)が生成される。この硬化反応機構を以下に示す。   The curing reaction of the moisture-curable polyurethane resin-based paint is based on the ring-opening polymerization reaction of the moisture-curable polyurethane resin contained as a main agent in the paint, and is cured by reacting with moisture in the environment such as moisture. To do. The curing reaction can be outlined as follows. The above-mentioned resin has an isocyanate group as a reactive group at the terminal, and this reactive group reacts with moisture in the air or moisture on the substrate adjustment surface to generate carbamic acid. This carbamic acid is very active and decomposes to produce amine and carbon dioxide. The produced amine reacts with the isocyanate groups of the moisture-curing polyurethane resin present in the surroundings, and a tough cured product (coating film) having a three-dimensional network structure is produced by urea bonding. This curing reaction mechanism is shown below.

Figure 0004897259
Figure 0004897259

この湿気硬化型樹脂塗料は、半硬化乾燥時間にて20℃環境下で4時間、指触乾燥時間で2時間程度のものを好適に使用できる。この乾燥時間は、上記温度よりも低温になれば長期化し、高温になれば、短くなる傾向を示すのが一般的である。例えば−5℃といった極低温の環境下で、この乾燥時間を短縮させたい場合には、所定の硬化促進剤を使用することもできる。この硬化促進剤としては、トリエチレンジアミン10重量部と上記高沸点有機溶剤90重量部との混合液などが挙げられ、その添加量は塗料全量に対して約1〜3重量%とするのがよい。   As this moisture curable resin coating material, a semi-curing drying time of about 4 hours under a 20 ° C. environment and a touch drying time of about 2 hours can be suitably used. In general, the drying time tends to be longer when the temperature is lower than the above temperature and shorter when the temperature is higher. For example, when it is desired to shorten the drying time in an extremely low temperature environment such as −5 ° C., a predetermined curing accelerator can be used. Examples of the curing accelerator include a mixed solution of 10 parts by weight of triethylenediamine and 90 parts by weight of the high boiling point organic solvent, and the addition amount is preferably about 1 to 3% by weight with respect to the total amount of the paint. .

また、この塗料には、消泡剤溶液を添加することもできるs。このような消泡剤溶液としてはシリコン系消泡剤などが挙げられる。具体的には、シリコンYSA6402(商品名、東芝シリコン社製)やシリコンKF69(商品名、信越化学社製)などが好適に使用できる。これらは、通常、後述の高沸点有機溶剤などで100倍に希釈して塗料組成物中に添加される。   Also, an antifoam solution can be added to the paint. Examples of such an antifoaming agent solution include a silicon-based antifoaming agent. Specifically, silicon YSA6402 (trade name, manufactured by Toshiba Silicon Corporation), silicon KF69 (trade name, manufactured by Shin-Etsu Chemical Co., Ltd.), or the like can be suitably used. These are usually diluted 100 times with a high-boiling organic solvent described later and added to the coating composition.

この湿気硬化型樹脂塗料は、そのまま塗装に供してもよく、希釈して粘度調整を行った上で塗装に供してもよい。後者の場合、希釈剤としては炭化水素系有機溶剤を好適に使用できる。このうち芳香族炭化水素系有機溶剤が好ましく、さらに高沸点のものがより好ましい。ここで、「高沸点」芳香族炭化水素系有機溶剤とは、蒸留範囲が160〜180℃であり、重質の芳香族化合物を95容量%以上含有し、日本塗料工業会規格JPIA−4に相当するものをいうものとする。このような高沸点芳香族炭化水素系溶剤としては、ソルベッソ100級スワゾール1000(商品名、丸善石油化学社製)、日石ハイゾール100(商品名、新日本石油化学社製)、イプゾール100(商品名、出光興産社製)などが挙げられる。上記溶剤の添加量は、目標とする粘度にもよるが、希釈後の塗料の全量に対して、5〜30重量%程度に設定できる。 This moisture curable resin coating material may be used for coating as it is, or may be used for coating after dilution and viscosity adjustment. In the latter case, a hydrocarbon-based organic solvent can be suitably used as the diluent. Of these, aromatic hydrocarbon organic solvents are preferable, and those having a high boiling point are more preferable. Here, the “high boiling point” aromatic hydrocarbon-based organic solvent has a distillation range of 160 to 180 ° C., contains 95% by volume or more of a heavy aromatic compound, and complies with Japan Paint Industry Association Standard JPIA-4. The equivalent shall be said. Examples of such high-boiling aromatic hydrocarbon solvents include Solvesso 100-grade Swazol 1000 (trade name, manufactured by Maruzen Petrochemical Co., Ltd.), Nisseki Hysol 100 (trade name, manufactured by Shin Nippon Petrochemical Co., Ltd.), Ipsol 100 (product) Name, manufactured by Idemitsu Kosan Co., Ltd.). Although the amount of the solvent added depends on the target viscosity, it can be set to about 5 to 30% by weight with respect to the total amount of the paint after dilution.

この塗料の素地調整面への塗布に当たっては、公知の塗装方法を用いることができる。このような公知の塗装方法としては、エアレススプレー塗装、刷毛塗り塗装、ローラー塗装などが挙げられる。その標準塗布量は、通常、エアレススプレー塗装の場合、0.19kg/m程度とされ、刷毛塗り塗装の場合、0.15kg/m程度とされる。また、塗膜厚は、その乾燥塗膜厚にて、20〜80μm、好ましくは30〜70μm、より好ましくは40〜60μmとなるようにするのがよい。この塗膜厚は、厚ければ厚いほど塗膜の耐久性が向上するが、上記範囲未満では、塗膜の耐久性に問題があり、上記範囲を超えた場合、塗膜の乾燥時間が長くなり、好ましくない。特に、エアレススプレー塗装の場合、80μm以上の塗膜厚をえることができるが、ウレタン反応によるガスの発生により塗膜表面にピンホールが生じ、塗膜外観が劣ることになり、好ましくない。 A known coating method can be used for applying the paint to the substrate adjustment surface. Examples of such known coating methods include airless spray coating, brush coating, and roller coating. The standard coating amount is usually about 0.19 kg / m 2 in the case of airless spray coating, and about 0.15 kg / m 2 in the case of brush coating. Moreover, it is good to make it a coating film thickness be 20-80 micrometers by the dry coating film thickness, Preferably it is 30-70 micrometers, More preferably, it is 40-60 micrometers. The thicker the coating, the better the durability of the coating. However, if the thickness is less than the above range, there is a problem with the durability of the coating. It is not preferable. In particular, in the case of airless spray coating, a coating thickness of 80 μm or more can be obtained. However, the generation of gas due to the urethane reaction causes pinholes on the coating surface, resulting in poor coating appearance.

環境中の温度の影響が少なく、特に秋口から冬場に行われることが多い送電鉄塔の防食塗装作業では、この湿気硬化型ポリウレタン樹脂系塗料を好適に使用できる。また、このように1液型の塗料を使用することで、2液型塗料の場合のような混合比により可使時間が制限されることがない。また、この塗料は、塗り下地選択性が小さく、どのような下地にも塗装が可能であるという利点がある。   This moisture-curable polyurethane resin-based paint can be suitably used in anticorrosion coating work for power transmission towers, which is less affected by temperature in the environment and is often performed from autumn to winter. In addition, by using the one-component paint in this way, the pot life is not limited by the mixing ratio as in the case of the two-component paint. In addition, this paint has an advantage that the coating base selectivity is small and any base can be applied.

上記湿気硬化型樹脂塗料の塗膜が半硬化乾燥状態になった後、この塗膜面に少なくとも1回防食塗料を塗装する。この防食塗料としては、公知の中塗り塗料および上塗り塗料を使用でき、従って上記塗膜面にはさらに1回もしくは2回、またはそれ以上防食塗料を重ね塗りできるが、好ましくは上記塗膜面に直接(すなわち1回)耐候性上塗り塗料を用いるのがよい。耐候性上塗り塗料としては、フッ素樹脂系塗料、塩化ゴム系上塗り塗料、ポリウレタン樹脂系上塗り塗料、アクリル系上塗り塗料、シリコンアルキッド系上塗り塗料、シリコンアクリル系上塗り塗料などが挙げられ、これらの群から適宜選択して塗装に使用できる。   After the coating film of the moisture curable resin coating is in a semi-cured and dried state, the anticorrosion coating is applied to the coating surface at least once. As the anticorrosion paint, known intermediate paints and topcoat paints can be used. Therefore, the above-mentioned coating surface can be further coated once or twice or more times, but preferably on the above-mentioned coating surface. A direct (i.e. once) weather resistant top coat may be used. Examples of the weather-resistant top coating include fluororesin-based coatings, chlorinated rubber-based top coatings, polyurethane resin-based top coatings, acrylic top coatings, silicon alkyd top coatings, and silicone acrylic top coatings. Can be selected and used for painting.

尚、本発明の防食塗装方法は、上記送電鉄塔に対してのみならず、例えば橋梁や海洋構造物等の鉄骨構造物に対しても実施できるとともに、製造直後の亜鉛処理鋼材表面に直接実施できることはいうまでもない。   The anticorrosion coating method of the present invention can be applied not only to the power transmission tower, but also to a steel structure such as a bridge or an offshore structure, and can be directly applied to the surface of a zinc-treated steel immediately after production. Needless to say.

以下、実施例及び比較例を参照して本発明をさらに詳細に説明する。なお、下記の例中、「部」は特に断りのない限り重量基準である。また、使用した塗料は下記のとおりであり、各種物性の評価方法についても下記の評価方法に従った。
[使用した塗料]
以下に示す下塗り塗料および上塗り塗料を試験に供した。
(1)湿気硬化型ポリウレタン樹脂系塗料
Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples. In the following examples, “parts” are based on weight unless otherwise specified. Moreover, the used coating materials are as follows, and the following evaluation methods were also used for the evaluation methods of various physical properties.
[Used paint]
The following undercoat and topcoat were used for the test.
(1) Moisture curable polyurethane resin paint

Figure 0004897259
Figure 0004897259

(2)変性ビニル樹脂系塗料 (2) Modified vinyl resin paint

Figure 0004897259
Figure 0004897259

(2)速乾性ジンククロメートプライマー (2) Quick-drying zinc chromate primer

Figure 0004897259
Figure 0004897259

(3)アクリルアルキッド樹脂系塗料 (3) Acrylic alkyd resin paint

Figure 0004897259
Figure 0004897259

(4)アルミニウムペイント
JIS K5492相当品
(5)塩化ゴム系上塗り塗料
JIS K5639「上塗り塗料」相当品
(6)ポリウレタン樹脂系上塗り塗料
JIS K5657「上塗り塗料」相当品
(7)フッ素樹脂系上塗り塗料
JIS K5659「上塗り塗料」相当品
(4) Aluminum paint
JIS K5492 equivalent (5) Chlorinated rubber base coating
Equivalent to JIS K5639 “Topcoat” (6) Polyurethane resin-based topcoat
JIS K5657 “Topcoat” equivalent (7) Fluororesin-based topcoat
JIS K5659 “Topcoat” equivalent

(8)変性エポキシ樹脂系塗料 (8) Modified epoxy resin paint

Figure 0004897259
Figure 0004897259

[評価方法]
(1)膜厚測定
膜厚計(型式SME−2、電磁誘導式、サンコウ電子研究所製)を用いて塗膜の膜厚を測定した。
[Evaluation methods]
(1) Film thickness measurement The film thickness of the coating film was measured using a film thickness meter (model SME-2, electromagnetic induction type, manufactured by Sanko Electronics Laboratory).

(2)塗装作業性
JIS K 5600 1−1。刷毛塗りK 5600 1−5に準拠。
(2) Paint workability JIS K 5600 1-1. Conforms to brush coating K 5600 1-5.

(3)低温性
−5℃、相対湿度50%の環境下で下塗り塗料を刷毛塗りしてから、所定の時間で上塗りが可能か否かで評価した。
○:下塗り塗装後、8時間以内で上塗りが可能である
△:やや塗りにくいが、8時間以内で上塗りが可能である
×:8時間を越えて放置しても、上塗りを行えない
(3) Low temperature property Evaluation was made based on whether or not overcoating can be performed in a predetermined time after applying the undercoat paint in an environment of -5 ° C and 50% relative humidity.
○: Topcoat can be applied within 8 hours after undercoating △: Slightly difficult to apply, but overcoating is possible within 8 hours ×: Cannot be overcoated even if left for more than 8 hours

(4)高湿下
常温(23℃)、相対湿度99%の環境下で塗装した場合に、塗膜に異常が生じるか否かで評価した。
○:塗膜に変化が見られず、乾燥が良好である。
△:つや引け(つやがなくなり、白っぽく見える)が認められる程度で、乾燥は良好である。
×:塗膜の白化が認められ、成膜性が認められない。
(4) Under high humidity Evaluation was made based on whether or not an abnormality occurred in the coating film when coated in an environment of normal temperature (23 ° C.) and relative humidity of 99%.
○: No change is observed in the coating film, and the drying is good.
(Triangle | delta): Drying is favorable to such an extent that glossiness (glossiness is lost and it looks whitish) is recognized.
X: Whitening of the coating film is recognized and film forming property is not recognized.

(5)乾燥性
常温(23℃)環境下で、所定の時間内に上塗りが可能な否かで評価した。
○:乾燥が早く、4時間以内で上塗りが可能である
△:乾燥はやや劣るが、4時間以内で上塗りが可能である
×:乾燥が遅く、1日で上塗りできない
(5) Dryability Evaluation was made based on whether or not overcoating was possible within a predetermined time in a normal temperature (23 ° C.) environment.
○: Drying is fast and overcoating is possible within 4 hours. Δ: Drying is slightly inferior, but overcoating is possible within 4 hours. X: Drying is slow and cannot be overcoated in 1 day.

(6)付着性
塗膜面に2液型エポキシ樹脂系接着剤(TE2220(商品名)、東レファインケミカル社製)を持ちいて治具を接着して固定し、所定の時間放置した後、接着性試験機ADHESION TESTER(ELECOMETER社製)を用いて付着性の評価を行った。
(6) Adhesion Hold a two-pack type epoxy resin adhesive (TE2220 (trade name), manufactured by Toray Fine Chemical Co., Ltd.) on the coating surface and fix the jig. Adhesion was evaluated using a testing machine ADHESION TESTER (manufactured by ELECOMTER).

(7)促進耐候性
JIS K5600−7−7(キセノンランプ法)に従い、キセノンランプ光を1000時間照射し、塗膜照射面の耐候性を塗膜の外観および塗膜の付着性によって評価した。
塗膜の外観は、目視にて判定した。
○:ワレ、剥離、膨れなどの塗膜異常が認められず、光沢の低下および錆の発生が少な

△:外観の変化は少ないが、光沢の変化が認められる
×:ワレ、剥離、膨れが多く、錆の発生が認められる
また、塗膜の付着性は、その付着状態を観察することで以下のように判定した。
○:層間剥離が認められず、付着状態が良好である
△:部分的に層間剥離が認められる
×:全面に層間剥離が認められる
(7) Accelerated weather resistance According to JIS K5600-7-7 (xenon lamp method), xenon lamp light was irradiated for 1000 hours, and the weather resistance of the irradiated surface of the coating film was evaluated by the appearance of the coating film and the adhesion of the coating film.
The appearance of the coating film was determined visually.
○: No coating film abnormality such as cracking, peeling, swelling, etc. was observed, and gloss reduction and rust generation were small.
△: Little change in appearance, but change in gloss is observed. ×: Many cracks, peeling, and swelling are observed, and rust is observed. Judged as follows.
○: No delamination is observed, and the adhesion state is good. Δ: Partial delamination is observed. ×: Delamination is observed on the entire surface.

(8)塩水噴霧性
JIS K5600−7−1に準拠し、1000時間塩水を噴霧した後、塗膜塩水噴霧面の耐塩水噴霧性を塗膜の外観および塗膜の付着性によって評価した。評価基準は、上記(7)と同様である。
(8) Salt sprayability After spraying salt water for 1000 hours in accordance with JIS K5600-7-1, the salt spray resistance of the coating film salt spray surface was evaluated by the appearance of the coating film and the adhesion of the coating film. The evaluation criteria are the same as (7) above.

(9)耐湿性
JIS K5600−7−2(連続結露法)に準拠し、500時間稼動させた後、上記(7)と同様の方法で塗膜供試面の耐湿性を塗膜の外観および塗膜の付着性で評価した。評価基準は、上記(7)と同様である。
(9) Moisture resistance After operating for 500 hours in accordance with JIS K5600-7-2 (continuous condensation method), the moisture resistance of the coating film test surface was evaluated by the same method as in (7) above. The evaluation was based on the adhesion of the coating film. The evaluation criteria are the same as (7) above.

[旧塗膜の調製方法]
溶融亜鉛メッキ鋼板に表6「旧塗膜」欄に記載の塗装を施した。同表において、「変性ビニル樹脂系」とは、下塗り、上塗りとも変性ビニル樹脂系塗料(いずれも塗膜厚30μm)を塗布したものであり、「アルミニウム系」とは、下塗りとして速乾性ジンククロメープライマー(塗膜厚25μm)を塗布した上で、上塗りとしてアルミニウムペイント(塗膜厚15μm)を塗布したものである。また、「アクリルアルキッド樹脂系」とは、下塗りとして速乾性ジンククロメープライマー(塗膜厚25μm)を塗布した上で、上塗りとしてアクリル変性アルキッド樹脂系塗料(塗膜厚30μm)を塗布したものであり、「溶融亜鉛メッキ」とは、溶融亜鉛メッキ鋼板をそのまま用いたものである。
[Preparation method of old paint film]
The hot-dip galvanized steel sheet was coated as described in Table 6 “Old paint film”. In the table, the "modified vinyl resin", undercoating, overcoating with modified vinyl resin paint is obtained by applying the (both film thickness 30 [mu] m), the term "aluminum-based", quick-drying Jinkukurome DOO as a primer A primer (with a coating thickness of 25 μm) is applied, and then an aluminum paint (with a coating thickness of 15 μm) is applied as an overcoat. In addition, the "acrylic alkyd resin system", after applying a fast drying Jinkukurome preparative primer (coating thickness 25 [mu] m) as a primer, which was coated with acrylic-modified alkyd resin paint (film thickness 30 [mu] m) as a top coat “Hot galvanized” is a galvanized steel sheet used as it is.

上記のようにして得られた鋼板上の塗膜に対してキセノンランプの照射下に2000時間放置し、塗膜表面を劣化させた後、さらに屋外に1年間暴露する。暴露後の塗膜を実暴露5年間とみなし、旧塗膜として試験に供した。なお、キセノンランプによる耐候性試験は、JIS K5600−7−7に準拠した。   The coating film on the steel sheet obtained as described above is left for 2000 hours under irradiation of a xenon lamp to deteriorate the coating film surface, and then exposed to the outdoors for one year. The coating after the exposure was regarded as an actual exposure for 5 years, and was used for the test as an old coating. The weather resistance test with a xenon lamp was based on JIS K5600-7-7.

実施例1
変性ビニル樹脂系の旧塗膜が形成された溶融亜鉛メッキ鋼板の該旧塗膜面に素地調整を行い、表面を清浄にした後、下塗りとして湿気硬化型ポリウレタン樹脂系塗料を塗膜厚50μmとなるように塗付し、半硬化乾燥状態に至ったところで上塗りとして塩化ゴム系上塗り塗料を塗膜厚30μmとなるように塗付して試験体を得た。
Example 1
The surface of the old coating film of the hot-dip galvanized steel sheet on which a modified vinyl resin-based old coating film is formed is prepared, and after the surface is cleaned, a moisture-curable polyurethane resin-based coating is used as the undercoat with a coating thickness of 50 μm. When a semi- cured and dried state was reached, a chlorinated rubber-based top coating was applied as a top coat to a coating thickness of 30 μm to obtain a test specimen.

実施例2
アルミニウム系の旧塗膜が形成された溶融亜鉛メッキ鋼板の該旧塗膜面に素地調整を行い、表面を清浄にした後、下塗りとして湿気硬化型ポリウレタン樹脂系塗料を塗膜厚50μmとなるように塗付し、半硬化乾燥状態に至ったところで上塗りとして塩化ゴム系上塗り塗料を塗膜厚30μmとなるように塗付して試験体を得た。
Example 2
After the surface of the hot-dip galvanized steel sheet on which the aluminum-based old coating film has been formed is adjusted and the surface is cleaned, a moisture-curable polyurethane resin-based paint is applied to the coating thickness of 50 μm as the undercoat. When a semi- cured and dried state was reached, a chlorinated rubber-based top coating was applied as a top coat to a coating thickness of 30 μm to obtain a test specimen.

実施例3
アクリルアルキッド樹脂系の旧塗膜が形成された溶融亜鉛メッキ鋼板の該旧塗膜面に素地調整を行い、表面を清浄にした後、下塗りとして湿気硬化型ポリウレタン樹脂系塗料を塗膜厚50μmとなるように塗付し、半硬化乾燥状態に至ったところで上塗りとして塩化ゴム系上塗り塗料を塗膜厚30μmとなるように塗付して試験体を得た。
Example 3
After the surface of the hot-dip galvanized steel sheet on which the acrylic alkyd resin-based old coating film has been formed is prepared and the surface is cleaned, a moisture-curable polyurethane resin-based coating is used as the undercoat with a coating thickness of 50 μm. When a semi- cured and dried state was reached, a chlorinated rubber-based top coating was applied as a top coat to a coating thickness of 30 μm to obtain a test specimen.

参考例1〜3
溶融亜鉛メッキ鋼板の表面に直接、実施例1〜3の下塗りおよび上塗りを同様の塗膜厚になるように塗布してそれぞれの試験体を得た。
Reference Examples 1-3
Each test specimen was obtained by directly applying the undercoat and topcoat of Examples 1 to 3 to the same coating thickness on the surface of the hot-dip galvanized steel sheet.

比較例1〜3
従来の塗り替え塗装方法と同様、変性ビニル樹脂系、アルミニウム系およびアクリルアルキッド樹脂系の各旧塗膜面に、
(1)下塗り、上塗りとも同種の変性ビニル樹脂系塗料(塗膜厚はいずれも30μm)
(2)下塗り速乾性ジンククロメープライマー(塗膜厚25μm)、上塗りアルミニウムペイント(塗膜厚15μm)
(3)下塗り速乾性ジンククロメープライマー(塗膜厚25μm)、上塗りアクリル変性アルキッド樹脂系塗料(塗膜厚30μm)
をそれぞれ塗り重ね、比較例1〜3の試験体を得た。
Comparative Examples 1-3
In the same way as the conventional repainting method, on each old paint film surface of modified vinyl resin system, aluminum system and acrylic alkyd resin system,
(1) Modified vinyl resin-based paint of the same type for both undercoat and topcoat (both film thickness is 30 μm)
(2) Undercoat fast drying Jinkukurome preparative primer (coating thickness 25 [mu] m), overcoated aluminum paint (film thickness 15 [mu] m)
(3) an undercoat fast drying Jinkukurome preparative primer (coating thickness 25 [mu] m), topcoat acrylic-modified alkyd resin paint (film thickness 30 [mu] m)
The test bodies of Comparative Examples 1 to 3 were obtained.

比較例4〜6
比較例1〜3において、それぞれの旧塗膜の上に塗装される下塗り塗料を変性エポキシ樹脂系塗料に変更するとともに、上塗り塗料をそれぞれ塩化ゴム系、ウレタン系およびフッ素系に変更して、比較例4〜6の試験体を得た。これらの下塗り塗料および上塗り塗料の塗膜厚は、いずれも30μmとした。
Comparative Examples 4-6
In Comparative Examples 1 to 3, the undercoat paint applied on each old paint film was changed to a modified epoxy resin paint, and the top coat was changed to a chlorinated rubber system, a urethane system, and a fluorine system, respectively. Test bodies of Examples 4 to 6 were obtained. The coating thicknesses of these undercoat and topcoat were both 30 μm.

これらの評価結果を表1に示す。   These evaluation results are shown in Table 1.

Figure 0004897259
Figure 0004897259

表6から明らかなとおり、実施例1〜3の塗り替え塗料の塗膜は、塗装作業性、塗膜性能ともに優れることが示された。
これに対し、比較例1〜3の場合、塗装作業性(低温性および高湿下)および塗膜性能の外観は概ね劣り、下塗りとしてジンククロメートプライマーを用いた場合、塗膜性能、特に付着性も劣ることが示された。また、比較例4〜6の場合、塗膜性能は概ね良好であるが、塗装作業性(乾燥性)に劣り、塗装作業に長時間を要することが示された。
As is clear from Table 6, it was shown that the coating films of the repaints of Examples 1 to 3 were excellent in both the coating workability and the coating film performance.
On the other hand, in the case of Comparative Examples 1 to 3, the appearance of the coating workability (low temperature and high humidity) and the coating film performance are generally inferior, and when the zinc chromate primer is used as the undercoat, the coating film performance, particularly adhesion Was also shown to be inferior. Moreover, in the case of Comparative Examples 4-6, although the coating-film performance is generally favorable, it was shown that it is inferior to coating workability (drying property), and a long time is required for the coating work.

上記の結果を踏まえ、実際に防食塗装作業に要する時間および塗膜状態を調べるために、すでに変性ビニル樹脂系塗料による防食塗装が施されてから7年を経過した送電鉄塔について、その鋼材塗装面全面に以下のように素地調整を行った後、実施例4、5、および比較例7に示す防食塗装を行った。   Based on the above results, in order to investigate the actual time required for the anticorrosion coating and the state of the coating film, the steel coating surface of the transmission tower, which has passed seven years after the anticorrosion coating with the modified vinyl resin paint, has already been applied. After the substrate was adjusted on the entire surface as follows, the anticorrosion coating shown in Examples 4 and 5 and Comparative Example 7 was performed.

実施例4
塵芥、油脂などによる汚れをウエス、マジクロン(登録商標、三共理化学社製)などを用いて除去し、素地調整を行った。その素地調整面に、下塗りとして上記表1に示す組成の湿気硬化型ポリウレタン樹脂系塗料を膜厚が50μmとなるように刷毛塗りを行い、4時間乾燥させた。その後、上塗りとしてポリウレタン樹脂系上塗り塗料を所定の希釈率にて希釈したものを膜厚が30μmとなるように刷毛塗りを行った。その結果、塗装後の塗膜状態は良好であり、送電停止時間12時間で塗り替え塗装を完了することができた。
Example 4
Dirt, oil, and the like were removed using waste cloth, Magiclon (registered trademark, manufactured by Sankyo Rikagaku Co., Ltd.), etc., and the substrate was adjusted. The substrate-adjusted surface was brush-coated with a moisture-curable polyurethane resin paint having the composition shown in Table 1 as an undercoat so as to have a film thickness of 50 μm and dried for 4 hours. Thereafter, a polyurethane resin-based topcoat paint diluted as a topcoat at a predetermined dilution rate was applied with a brush so that the film thickness was 30 μm. As a result, the state of the coated film after coating was good, and the repainting could be completed within 12 hours of power transmission stop time.

実施例5
前回の防食塗装から7年経過した同様の送電鉄塔について、冬季に防食塗装を施した。この防食塗装に際しては、下塗り塗料である湿気硬化型ポリウレタン樹脂系塗料100重量部に対して、硬化促進剤を2部添加した以外は、実施例1と同様の方法とした。
その結果、実施例4と同様の結果が得られた。
Example 5
Corrosion-proof coating was applied in winter on a similar power transmission tower that had passed seven years since the last anti-corrosion coating. The anticorrosion coating was performed in the same manner as in Example 1 except that 2 parts of a curing accelerator was added to 100 parts by weight of a moisture-curable polyurethane resin-based paint that was an undercoat paint.
As a result, the same result as in Example 4 was obtained.

比較例7
同様に7年経過した送電鉄塔について、その鋼材塗装面に上記表5に示す変性エポキシ樹脂系塗料を塗膜厚が30μmとなるように刷毛塗りを行い、下塗りを行った。その後、ポリウレタン樹脂系上塗り塗料を刷毛塗りできるようになるまでの乾燥時間として18時間を要した。その結果、塗り替え塗装工事は2日間におよび、送電停止時間として2日を要した。
Comparative Example 7
Similarly, about the power transmission tower which passed for 7 years, the steel material coating surface was brush-coated with the modified epoxy resin-based paint shown in Table 5 so that the coating thickness was 30 μm, and then the primer was applied. Then, 18 hours were required as drying time until it became possible to brush-apply the polyurethane resin-type top coat. As a result, the repainting work took 2 days, and 2 days were required as the power transmission stoppage time.

また、実施例4および5から明らかなように、実際に送電鉄塔の鋼材塗装面に本発明の防食塗装方法を使用した場合、下塗りおよび上塗りの2回塗りの作業を12時間で完了させることができたのに対して、比較例7では塗装作業が2日に及び、停電時間は2日を要した。これらの結果からも、本発明の防食塗装方法を使用することで、短時間での重ね塗りが可能となることが明らかである。   Further, as is clear from Examples 4 and 5, when the anticorrosion coating method of the present invention is actually used on the steel coating surface of the transmission tower, the two times of the undercoating and topcoating operations can be completed in 12 hours. In contrast, in Comparative Example 7, the painting work took 2 days, and the power outage time took 2 days. Also from these results, it is clear that overcoating can be performed in a short time by using the anticorrosion coating method of the present invention.

本発明の防食塗装方法は、上記のとおり、時間的な制約によって従来塗り替え周期を長くすることができなかった送電鉄塔の塗り替え工事に好適である。

As described above, the anticorrosion coating method of the present invention is suitable for the repainting work of the transmission tower, which has not been able to make the repainting cycle longer due to time restrictions.

Claims (6)

鋼材塗装面の素地調整を行い、この素地調整面に、半硬化乾燥時間を環境温度条件に応じて約4時間以内に調整した湿気硬化型樹脂塗料を下塗りした後、当該半硬化乾燥状態に達したところで該下塗り塗膜面に防食塗料を重ね塗りすることを特徴とする送電鉄塔の防食塗装方法。 After adjusting the surface of the steel coated surface, and undercoating the moisture-curing resin coating with the semi-curing drying time adjusted within about 4 hours according to the environmental temperature conditions on this surface-adjusting surface, the semi -cured dry state is reached. Then, an anticorrosion coating method for a power transmission tower, characterized in that an anticorrosion coating is repeatedly applied to the surface of the undercoat. 前記湿気硬化型樹脂塗料は、ポリウレタン樹脂系である請求項1に記載の防食塗装方法。   The anti-corrosion coating method according to claim 1, wherein the moisture curable resin paint is a polyurethane resin system. 前記湿気硬化型樹脂塗料は、1液型塗料である請求項1または2に記載の防食塗装方法。   The anti-corrosion coating method according to claim 1, wherein the moisture curable resin coating is a one-component coating. 前記防食塗料は、耐候性上塗り塗料である請求項1〜3のいずれか1項に記載の防食塗装方法。   The anticorrosion coating method according to any one of claims 1 to 3, wherein the anticorrosion coating is a weather-resistant top coating. 前記耐候性上塗り塗料は、ポリウレタン樹脂系上塗り塗料、フッ素樹脂系上塗り塗料、塩化ゴム系上塗り塗料、アクリル系上塗り塗料、シリコンアルキッド系上塗り塗料またはシリコンアクリル系上塗り塗料である請求項4に記載の送電鉄塔の防食塗装方法。   The power transmission according to claim 4, wherein the weather-resistant top coating is a polyurethane resin-based top coating, a fluororesin-based top coating, a chlorinated rubber-based top coating, an acrylic top coating, a silicon alkyd top coating, or a silicon acrylic top coating. Anti-corrosion painting method for steel towers. 前記鋼材塗装面は、変性ビニル樹脂系塗料またはアルミニウムペイント塗膜の表面である請求項1〜5のいずれか1項に記載の防食塗装方法。   The anticorrosion coating method according to any one of claims 1 to 5, wherein the steel material coating surface is a surface of a modified vinyl resin-based paint or an aluminum paint coating film.
JP2005253083A 2005-09-01 2005-09-01 Anticorrosion coating method for power transmission towers Active JP4897259B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005253083A JP4897259B2 (en) 2005-09-01 2005-09-01 Anticorrosion coating method for power transmission towers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005253083A JP4897259B2 (en) 2005-09-01 2005-09-01 Anticorrosion coating method for power transmission towers

Publications (2)

Publication Number Publication Date
JP2007061760A JP2007061760A (en) 2007-03-15
JP4897259B2 true JP4897259B2 (en) 2012-03-14

Family

ID=37924586

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005253083A Active JP4897259B2 (en) 2005-09-01 2005-09-01 Anticorrosion coating method for power transmission towers

Country Status (1)

Country Link
JP (1) JP4897259B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017124391A (en) * 2016-01-08 2017-07-20 株式会社横河ブリッジ Coating-recoating method of steel member

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5705174B2 (en) * 2012-06-26 2015-04-22 オリジン電気株式会社 Rust prevention method for inner surface of circular steel pipe
WO2015145584A1 (en) * 2014-03-25 2015-10-01 中国電力株式会社 Transmission tower coating paint and transmission tower coating method
JP6092464B2 (en) * 2014-03-25 2017-03-08 中国電力株式会社 How to paint a transmission tower
JP6427624B1 (en) * 2017-05-16 2018-11-21 阿南電機株式会社 Repair method of steel structure
CN110330873B (en) * 2019-07-12 2021-04-23 广西民族大学 Preparation method of alkyd resin anticorrosive enamel with high pitting potential

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2743220B2 (en) * 1991-04-22 1998-04-22 新日本製鐵株式会社 Polyurethane heavy duty anti-corrosion coated steel
JPH0631243A (en) * 1992-07-17 1994-02-08 Nippon Paint Co Ltd Corrosion-proof paint film formation
JPH10157004A (en) * 1996-09-30 1998-06-16 William J Brinton Anticorrosive film, composite material, and coating method
JPH10298485A (en) * 1997-04-24 1998-11-10 Asahi Glass Co Ltd Coated article and repair coating method
JP2004148163A (en) * 2002-10-29 2004-05-27 Mitsui Kinzoku Toryo Kagaku Kk Method of repair-painting steel material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017124391A (en) * 2016-01-08 2017-07-20 株式会社横河ブリッジ Coating-recoating method of steel member

Also Published As

Publication number Publication date
JP2007061760A (en) 2007-03-15

Similar Documents

Publication Publication Date Title
JP4897259B2 (en) Anticorrosion coating method for power transmission towers
WO2007023934A1 (en) Anticorrosion coating method for zinc-plated steel structure
JPH10157004A (en) Anticorrosive film, composite material, and coating method
WO2017085970A1 (en) Anticorrosion paint composition and method for forming dried coating film
JP7457846B2 (en) Coated plated steel plate
JP2002167548A (en) Epoxy coating material composition and corrosionproof coating method and coated product
JP4764616B2 (en) Repair painting method of old paint film
JP5945201B2 (en) Rust prevention coating method, new installation method and renovation method of parking facilities
JP6606112B2 (en) Film formation method
JP4220110B2 (en) Corrosion protection for weathering steel
JP2002035686A (en) Method for preventing rusting of weatherable steel
JP3260097B2 (en) Anticorrosion coating and anticorrosion coating method
US20080241399A1 (en) Method of coating and coated sheet piling sections
JP3219028U (en) Laminated structure of repair and refurbishment treatment layers by coating on exterior materials of building structures
JPS58137471A (en) Method of finishing repairing coating on old paint film
JP4263348B2 (en) Corrosion protection for weathering steel
JPH11228909A (en) Antifouling coating film, method for forming same, and structure coated with same
JPH078905A (en) Corrosion-proof coating method
JP3130225B2 (en) Method of forming silicone coating
CN212610385U (en) General type anticorrosion coating structure
JP2000063741A (en) Quick-drying rust-preventive coating material
JP4450587B2 (en) How to paint metal surfaces
JP2002035685A (en) Method for preventing rusting of weatherable steel
JP5652989B2 (en) Repair method of old paint film
JPS6237067B2 (en)

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20080819

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20101125

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20101221

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110218

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20111213

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20111222

R150 Certificate of patent or registration of utility model

Ref document number: 4897259

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150106

Year of fee payment: 3

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250