JP2017207981A - See-through electrode, touch panel and display device with touch position detection function - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a see-through electrode that can achieve higher resistance to scratches and dents and sufficiently thinned lead wires, a touch panel, and a display device with a touch position detection function.SOLUTION: A see-through electrode 31 includes: a substrate film 32 including a transparent substrate 33 and acrylic resin layers 34a, 34b disposed on a surface of the transparent substrate; and a plurality of conductive patterns 41 disposed on the substrate film. The conductive pattern is constituted by lead wires 51 having light-shielding property and arranged into a mesh pattern to form an opening among the lead wires. The acrylic resin layer includes first acrylic resin layers 34a1, 34b1 and second acrylic resin layers 34a2, 34b2 disposed between the first acrylic resin layer and the transparent substrate. First fine particles P having a particle size larger than the thickness of the first acrylic resin layer are added to the first acrylic resin layer.SELECTED DRAWING: Figure 4

Description

  The present invention relates to a transparent electrode. The present invention also relates to a touch panel provided with a transparent electrode. The present invention also relates to a display device with a touch position detection function obtained by combining a touch panel and a display device.

  Today, touch panel devices are widely used as input means. The touch panel device includes a touch panel, a control circuit that detects a contact position on the touch panel, wiring, and an FPC (flexible printed circuit board). In many cases, the touch panel device is used together with the display device as an input means for various devices including a display device such as a liquid crystal display or an organic EL display (for example, a ticket vending machine, an ATM device, a mobile phone, a game machine). It has been. In such a device, the touch panel is arranged on the display surface of the display device, thereby enabling extremely direct input to the display device, particularly the position coordinates of the display image and information associated with the position coordinates. Input is possible. The area of the touch panel that faces the display area of the display device is transparent, and this area of the touch panel constitutes an active area that can detect the contact position (or approach position).

  As a touch panel, a projected capacitive coupling type touch panel is known. In a capacitively coupled touch panel, a parasitic capacitance is newly generated when an external conductor (typically a finger) whose position is to be detected contacts (or approaches) the touch panel via a dielectric. The position of the external conductor on the touch panel is detected on the basis of the change in capacitance caused by the parasitic capacitance. Such a projected capacitively coupled touch panel includes, for example, a transparent electrode including a transparent base material such as PET and a plurality of conductive patterns provided on the transparent base material. The conductive pattern is made of, for example, a transparent conductive material made of ITO (indium tin oxide) having translucency and conductivity.

  In addition, in order to reduce the electrical resistance value of the conductive pattern and thereby improve the detection accuracy of the touch position, a metal material such as silver or copper having higher conductivity than the transparent conductive material is used as a material constituting the conductive pattern. It has been proposed to use (see, for example, Patent Document 1). However, since these metal materials are opaque, when the conductive pattern is made of a metal material, the conductive pattern has an opening for transmitting the image light from the display device at an appropriate ratio. For example, the conductive pattern is composed of conductive wires arranged in a mesh shape.

  By the way, metal materials, such as copper, show a metallic luster, while having high electroconductivity. For this reason, when an untreated metal material is used as a conducting wire, the visibility of the image light from the display device is hindered by the metallic luster of the conducting wire. In particular, copper exhibits a reddish color peculiar to copper, so that it is more conspicuous than other metal materials such as silver, and this hinders the visibility of image light from the display device. In order to reduce such metallic luster peculiar to copper, for example, in the above-mentioned Patent Document 1, it is proposed to reduce the metallic luster of the conductive wire by providing a low reflective layer made of copper nitride on the surface of the metal layer. Has been.

JP 2013-169712 A

  As a method of manufacturing a flexible wiring board such as a flexible board, the above-mentioned low-reflection layer or metal layer is formed on a long resin base material that is supplied and conveyed by a roll-to-roll method. A method of manufacturing a long wiring board and winding the wiring board into a roll is conceivable. Here, the “roll-to-roll method” means that a long belt-like flexible substrate is unwound and conveyed from a take-up (roll), supplied, subjected to predetermined processing, and then taken up ( A processing method of winding into a roll) form.

  In such a roll-to-roll system, an acrylic resin layer is formed as a hard coat layer on the surface in order to improve the slipperiness between the guide roller and the base material and to prevent the wiring board from being scratched. Substrate film is used. The acrylic resin is typically a cured product of an ultraviolet curable acrylic resin. Friction between the base film and the guide roller is reduced by adding fine particles as a filler (filler) into the acrylic resin to form minute irregularities on the film surface.

  By the way, the inventors of the present invention have made extensive studies for producing a thin conducting wire having an average line width of 2 μm, and have obtained the following knowledge. That is, if the surface roughness of the film surface is large, the resist pattern located on the convex part of the surface is easily damaged by friction with the guide roller, and the etching liquid penetrates from the scratch when etching the metal layer, so that the conductor pattern May be eroded and, if it is significant, the conductor may be broken. Therefore, in order to realize sufficient thinning of the conducting wire, it is necessary to reduce the surface roughness of the film surface.

  On the other hand, in order to reduce the surface roughness of the film surface, if the particle size of the fine particles added to the acrylic resin is reduced, the thickness of the acrylic resin layer (that is, the thickness of the acrylic resin layer not containing the fine particles) ) Becomes thin, the physical strength of the acrylic resin layer is lowered, and appearance defects due to scratches and dents are likely to occur.

  The present invention has been made in consideration of such points. An object of the present invention is to provide a transparent electrode, a touch panel, and a display device with a touch position detection function capable of achieving both scratch resistance / high dent resistance and sufficient thinning of a conductive wire.

The transparent electrode according to the present invention comprises:
A substrate film comprising a transparent substrate and an acrylic resin layer provided on the surface of the transparent substrate;
A plurality of conductive patterns provided on the base film;
With
The conductive pattern is a conductive wire having a light shielding property, and includes conductive wires arranged in a mesh shape so that an opening is formed between the conductive wires,
The acrylic resin layer includes a first acrylic resin layer, and a second acrylic resin layer provided between the first acrylic resin layer and the transparent substrate,
First fine particles having a particle size larger than the thickness of the first acrylic resin layer are added to the first acrylic resin layer.

In the transparent electrode according to the present invention, the total volume of the raised portions included in the region of 543 μm □ on the surface of the acrylic resin layer is 6.0 × 10 ¹¹ nm ³ or more and 4.0 × 10 ¹² nm ³ or less. There may be.

  In the transparent electrode according to the present invention, the arithmetic average roughness Ra of the surface of the acrylic resin layer may be 3 nm or more and 25 nm or less.

  In the transparent electrode according to the present invention, the acrylic hardness of the acrylic resin layer may be H or higher.

  In the transparent electrode according to the present invention, second fine particles may be added to the second acrylic resin layer.

  In the transparent electrode according to the present invention, the second fine particles may have a particle size smaller than the thickness of the second acrylic resin layer.

  In the transparent electrode according to the present invention, the second fine particles may have a particle size of 50% or less of the thickness of the first acrylic resin layer.

  The touch panel according to the present invention includes any of the above-described transparent electrodes according to the present invention.

A display device according to the present invention comprises:
A display device;
A touch panel according to the present invention described above, disposed on the display surface of the display device;
Is provided.

  According to the present invention, it is possible to achieve both the scratch resistance and the high dent resistance and the sufficient thinning of the conductive wire.

FIG. 1 is a plan view showing a transparent electrode in the first embodiment of the present invention. 2A is an enlarged plan view showing a conductive pattern in a portion surrounded by an alternate long and short dash line denoted by reference numeral II in FIG. FIG. 2B is an enlarged plan view showing a modification of the conductive pattern. FIG. 3 is a cross-sectional view showing a case where the transparent electrode is cut along line III-III in FIG. 2A. FIG. 4 is an enlarged cross-sectional view of the transparent substrate and the conductor shown in FIG. FIG. 5A is a diagram for explaining a method of manufacturing a transparent electrode. FIG. 5B is a diagram for explaining a method of manufacturing a transparent electrode. FIG. 5C is a diagram for explaining a method of manufacturing a transparent electrode. FIG. 5D is a diagram for explaining a method of manufacturing the transparent electrode. FIG. 5E is a diagram for explaining a method of manufacturing a transparent electrode. FIG. 6 is a development view showing a display device with a touch position detection function in the third embodiment of the present invention. FIG. 7 is a plan view showing a touch panel in the display device with a touch position detection function of FIG. FIG. 8 is an enlarged plan view showing a conductive pattern in a portion surrounded by a one-dot chain line denoted by reference numeral VIII in FIG. 9 is a cross-sectional view showing a case where the touch panel is cut along the line IX-IX in FIG. 10 is an enlarged cross-sectional view of a part of the touch panel shown in FIG. FIG. 11 is a cross-sectional view showing a modification of the touch panel according to the second embodiment of the present invention. FIG. 12 is a cross-sectional view showing a modification of the touch panel according to the second embodiment of the present invention. FIG. 13 is a diagram showing a modification of the cross-sectional shape of the conductive wire arranged on the display device side. FIG. 14 is a cross-sectional view showing a transparent electrode according to the third embodiment of the present invention. FIG. 15 is an enlarged cross-sectional view of a part of the transparent electrode shown in FIG. FIG. 16 is a diagram for explaining “the thickness of the acrylic resin layer” and “the volume of the raised portion”.

  Embodiments of the present invention will be described below in detail with reference to the accompanying drawings. Note that, in the drawings attached to the present specification, for the sake of easy understanding of the drawings, the scale and the vertical / horizontal dimension ratio are appropriately changed and exaggerated from those of the actual ones.

<First Embodiment>
Hereinafter, the first embodiment of the present invention will be described with reference to FIGS.

  First, with reference to FIG. 1, the transparent electrode 31 in this Embodiment is demonstrated. FIG. 1 is a plan view showing the transparent electrode 31 when viewed from the observer side.

  Here, an example in which the transparent electrode 31 is configured for a projection-type capacitively coupled touch panel will be described. Note that the “capacitive coupling” method is also referred to as “capacitance” method, “capacitance coupling” method, or the like in the technical field of the touch panel. It is treated as a term synonymous with the “capacitive coupling” method. A typical capacitive coupling type touch panel has a conductive pattern, and when an external conductor (typically a human finger) approaches the touch panel, the electrical conductivity of the external conductor and the touch panel is reduced. A capacitor (capacitance) is formed between these patterns. Based on the change in the electrical state accompanying the formation of the capacitor, the position coordinates of the position where the external conductor is approaching on the touch panel are specified.

  As shown in FIG. 1, the transparent electrode 31 includes a base film 32 and a plurality of conductive patterns 41 provided on the base film 32. As shown in FIG. 1, each conductive pattern 41 has a rectangular outline shape, and the long side of the rectangle extends in a strip shape in the vertical direction of FIG. The plurality of conductive patterns 41 are arranged at a constant arrangement pitch in a direction orthogonal to the direction in which each conductive pattern 41 extends. The arrangement pitch of the conductive patterns 41 is determined according to the resolution required for the detection of the touch position, and is several mm, for example.

  As shown in FIG. 1, the base film 32 of the transparent electrode 31 includes a rectangular active area Aa1 corresponding to a region where the touch position can be detected, and a rectangular frame-shaped inactive located around the active area Aa1. Area Aa2. The active area Aa1 and the inactive area Aa2 are respectively divided in accordance with the active area and the inactive area of the display device of the display device with a touch position detection function 10 described later. In the present invention, “touch” of the touch panel means non-contact with a distance of several mm or less, except when the tip of a writing instrument such as a human finger or pencil directly contacts the touch panel or the transparent electrode. It also includes the case of close approach.

  The conductive pattern 41 described above is disposed in the active area Aa1. Further, in the inactive area Aa2, a plurality of frame wirings 43 electrically connected to the respective conductive patterns 41 and a plurality of frame wirings arranged near the outer edge of the base film 32 and electrically connected to each frame wiring 43 are provided. Terminal portion 44.

  The frame wiring 43 and the terminal portion 44 connected to the conductive pattern 41 are provided for extracting a signal from the conductive pattern 41 to the outside of the transparent electrode 31. As long as signals can be appropriately transmitted, the specific configurations of the frame wiring 43 and the terminal portion 44 are not particularly limited. For example, the frame wiring 43 and the terminal portion 44 may be formed simultaneously with the conductive wire 51 with the same layer configuration as the conductive wire 51 described later.

  Next, the pattern shape of the conductive pattern 41 will be described with reference to FIG. 2A. 2A is a plan view showing a conductive pattern 41 in a portion surrounded by a one-dot chain line denoted by reference numeral II in FIG. As shown in FIG. 2A, the conductive pattern 41 is a conductive wire 51 having light shielding properties and electrical conductivity, and is composed of conductive wires 51 arranged in a mesh shape so that openings 51a are formed between the conductive wires 51. Has been.

  The ratio of the area occupied by the opening 51a (hereinafter referred to as the aperture ratio) in the total area of the conductive pattern 41 is sufficiently high, so that the image light from the display device can be transmitted through the transparent electrode 31 with an appropriate transmittance. As long as it can pass through the active area Aa1, the size and shape of the conducting wire 51 are not particularly limited. For example, in the example shown in FIG. 2A, the conductive pattern 41 is configured by arranging conductive wires 51 formed in a rectangular shape along a predetermined direction. The aperture ratio is appropriately set according to the characteristics of the image light emitted from the display device.

  The line width of the conducting wire 51 is set according to the required aperture ratio, the invisibility of the conductive pattern, etc. For example, the line width of the conducting wire 51 is in the range of 1 μm to 5 μm, more preferably in the range of 1 μm to 3 μm. More preferably, the average is set to 2 μm. The arrangement pitch P1 of the conductive wires 51 extending in parallel with each other is also set according to the required aperture ratio. As a result, the influence of the conductive wire 51 on the image visually recognized by the observer can be reduced to a negligible level, that is, sufficient invisibility can be obtained.

  Although FIG. 2A shows an example in which the conductive pattern 41 is configured by arranging the conductive wires 51 whose opening portions are formed in a rectangular shape along a predetermined direction, the present invention is not limited thereto. . For example, as illustrated in FIG. 2B, the conductive pattern 41 may be configured by arranging the conductive wires 51 whose opening portions are formed in a rhombus shape along a predetermined direction. In this embodiment, as shown in FIGS. 2A and 2B, the number of openings 51a of the conductive pattern 41 is two in the direction orthogonal to the extending direction of the conductive pattern 41 (the left-right direction in the figure). However, the number of arrangements in the present invention is not limited to two, and the number is arranged as appropriate according to the resolution of detecting the position of the touch panel, the sensitivity, the invisibility of the conductive pattern, and the like.

  Next, the layer configuration of the transparent electrode 31 will be described with reference to FIGS. 3 and 4. 3 is a cross-sectional view showing a case where the transparent electrode 31 is cut along the line III in FIG. 2A. FIG. 4 is an enlarged cross-sectional view showing the base film 32 and the conductive wire 51 shown in FIG. is there.

  As shown in FIG. 3, the transparent electrode 31 includes a transparent base film 32 and a conductive pattern 41 including a conductive wire 51 provided on the surface of the base film 32. In the present specification, “transparent” means that the light transmittance is sufficiently high and the other side can be seen through. Specifically, for example, the visible light transmittance is 50% or more, more preferably 80% or more, and still more preferably 90% or more. Moreover, it is preferable that the base film 32 has a small haze. Specifically, for example, the haze is 1% or less, more preferably 0.5% or less. The total light transmittance is measured according to JIS K7361-1: 1997, and the haze is measured according to JIS K7105.

  The base film 32 is for supporting patterns and wiring such as the conductive pattern 41 and the frame wiring 43 described above. As shown in FIG. 4, the base film 32 includes a transparent base material 33 that can transmit image light from the display device, and an acrylic resin provided between the transparent base material 33 and the conductive wire 51 of the conductive pattern 41. And a layer 34a. The base film 32 may further include an acrylic resin layer 34 b provided on the side of the transparent base material 33 opposite to the side facing the conductive wire 51.

  As a material constituting the transparent base material 33, a material having transparency and flexibility is used, and for example, a synthetic resin (plastic) is used. Examples of synthetic resins include polyester resins such as polyethylene terephthalate (PET) and polyethylene naphthalate (PEN), polyolefin resins such as polypropylene (PP) and cycloolefin polymer (COP), polycarbonate (PC) resin, and triacetyl cellulose. A resin having flexibility and transparency such as a cellulose resin such as (TAC) is used. The thickness of the base film is about 50 μm to 200 μm.

  The acrylic resin layers 34a and 34b have a function of improving the scratch resistance against scratches that may be caused by friction with the guide roller when the transparent electrode 31 is manufactured by the roll-to-roll method, This is a layer provided to realize a function of adjusting optical characteristics such as transmittance and reflectance.

  One acrylic resin layer 34 a includes a first acrylic resin layer 34 a 1 and a second acrylic resin layer 34 a 2 provided between the first acrylic resin layer 34 a and the transparent substrate 33. . Similarly, the other acrylic resin layer 34b includes a first acrylic resin layer 34b1, and a second acrylic resin layer 34b2 provided between the first acrylic resin layer 34b and the transparent substrate 33. Contains.

  As a material constituting the acrylic resin layers 34a and 34b, an acrylic resin is used. As the acrylic resin, those having sufficient scratch resistance and transparency are preferable. Typical examples of satisfying these conditions include ionizing radiation type acrylic resins that cure by a crosslinking reaction or a polymerization reaction by ionizing radiation irradiation. It is done. As such an ionizing radiation curable acrylic resin, a (meth) acrylate prepolymer or a (meth) acrylate monomer having a polymerizable functional group such as a (meth) acryloyl group or a (meth) acryloyloxy group in the molecule is used. It is done. Examples of the (meth) acrylate prepolymer include prepolymers such as urethane (meth) acrylate, epoxy (meth) acrylate, and polyester (meth) acrylate. Examples of the (meth) acrylate monomer include ethylene glycol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, trimethylolpropane tri (meth) acrylate, and dipentaerythritol hexa (meth) methacrylate. Examples include a polymer. (Here, “(meth) acryloyl group”, “(meth) acrylate” and the like mean “acryloyl group or methacryloyl group” and “acrylate or methacrylate”, respectively). These prepolymers and monomers are Depending on the required performance such as scratch resistance, flexibility, coating suitability, etc., one or more of the above prepolymers may be mixed as appropriate, and the above monomers may be used alone or in combination of two or more. Alternatively, one or more of the above prepolymers and one or more of the above monomers may be mixed and used. As the ionizing radiation, electromagnetic waves such as ultraviolet rays, visible rays, and X-rays, and charged particle beams such as electron beams and alpha rays can be used. When ultraviolet rays or visible rays are used as the ionizing radiation, 0.1 parts by mass to 5 parts by mass of a photoinitiator such as a benzotriazole compound or a benzophenone compound with respect to 100 parts by mass of the prepolymer and the monomer. Add about 1 part. In this embodiment, a cured product of an ultraviolet curable acrylic resin composition comprising an acrylate prepolymer, an acrylate monomer, and a benzotriazole photoinitiator is used.

  In the acrylic resin of the first acrylic resin layers 34a1 and 34b1, first fine particles having a particle size larger than the thickness T1 (see FIG. 16) of the first acrylic resin layers 34a1 and 34b1 as fillers (fillers). P is added. Examples of the first fine particles P include inorganic particles made of silica (silicon oxide), alumina (aluminum oxide), calcium carbonate, barium sulfate, and the like, and organic substances such as acrylic resin, urethane resin, silicon resin, fluorine resin, and melamine resin. What consists of particle | grains can be used. Use of styrene-acrylic resin organic particles is more preferable because the haze can be reduced by combining the refractive indexes of the first fine particles P and the acrylic resin.

  When the base film is fed by the roll-to-roll method, the base film sticks to the guide roller if there is not enough slip between the base film and the guide roller, which causes wrinkles on the base film. Sometimes. In the present embodiment, the first fine particles P having a particle size larger than the thickness T1 of the first acrylic resin layers 34a1 and 34b1 are added to the first acrylic resin layers 34a1 and 34b1 of the base film 32. Yes. Since the first fine particles P have a particle size larger than the thickness T1 of the first acrylic resin layers 34a1 and 34b1, as shown in FIG. 16, the tops thereof are the first acrylic resin layers 34a1, It protrudes from the surface of 34b1. Thereby, a minute unevenness | corrugation can be formed in the surface of the base film 32, and sufficient slipperiness can be provided between the base film 32 and a guide roller. Therefore, it is possible to effectively prevent the base film 32 from sticking to the guide roller and causing the base film 32 to be wrinkled.

The arithmetic average roughness Ra of the surfaces of the acrylic resin layers 34a and 34b is preferably 3 nm or more and 25 nm or less. Moreover, it is preferable that the sum total of the volume of the protruding part contained in the region of 543 μm □ on the surface of the acrylic resin layers 34a and 34b is 6.0 × 10 ¹¹ nm ³ or more and 4.0 × 10 ¹² nm ³ or less. . In this case, sufficient slipperiness can be ensured between the base film 32 and the guide roller, and generation of wrinkles due to heat in the shape of the base film can be suppressed. In the present specification, the “volume of the raised portion” refers to the area of the acrylic resin layers 34a and 34b among the surfaces of the acrylic resin layers 34a and 34b, as shown in the region highlighted in diagonal lines in FIG. This refers to the volume of the portion raised above the height defined by the thickness T (that is, the thickness of the region not including the fine particles P in the acrylic resin layers 34a and 34b).

  By the way, as mentioned in the column of the problem to be solved by the invention, when the surface roughness of the base film 32 is large, the resist pattern located on the convex portion of the surface is easily damaged by friction with the guide roller, When the etching solution permeates from the scratch during etching, the pattern of the conductive wire 51 is eroded, and in a significant case, the conductive wire 51 may be disconnected.

As a result of intensive studies in consideration of such problems, the present inventors have found that when the arithmetic average roughness Ra of the surface of the base film 32 is 3 nm or more and 25 nm or less, for example, the average line width is 2 μm. It was confirmed that a thin wire could be produced stably. In addition, even when the total volume of the raised portions included in the region of 543 μm □ on the surface of the base film 32 is 6.0 × 10 ¹¹ nm ³ or more and 4.0 × 10 ¹² nm ³ or less, it is thinned. It was confirmed that the lead wires could be manufactured stably. In addition, arithmetic mean roughness Ra is based on the prescription | regulation of JISB0601: 2013. The total sum of the volumes of the raised portions included in the arithmetic average roughness Ra and the region of 543 μm □ can be measured using, for example, a scanning white interferometer manufactured by Zygo Corporation.

  The surface properties of the acrylic resin layers 34a and 34b described above can be realized by adjusting the particle size and addition amount of the fine particles P added as fillers in the acrylic resins of the first acrylic resin layers 34a1 and 34b1. For example, the particle size of the fine particles P can be about 0.5 μm to 1.3 μm. In this case, the thickness T1 of the first acrylic resin layers 34a1 and 34b1 can be about 0.3 μm to 1 μm in the dry and cured state. The addition amount of the fine particles P can be about 0.1% by mass to 30% by mass in the acrylic resin layer composition.

  Here, as a comparative example, a case where the second acrylic resin layers 34a2 and 34b2 are not provided between the first acrylic resin layers 34a1 and 34b1 and the transparent base material 33 is considered. In this case, the thickness of the acrylic resin layers 34a and 34b is very thin because the thickness T1 of the first acrylic resin layers 34a1 and 34b1 is only about 0.3 μm to 1 μm. The strength is not sufficient, and an appearance defect due to scratches or dents due to friction with the guide roller tends to occur. Here, a method of increasing the thickness T of the acrylic resin layers 34a and 34b by increasing the particle size of the fine particles P contained in the first acrylic resin layers 34a1 and 34b1 is also conceivable. Since the surface roughness of the system resin layers 34a and 34b is also increased, it is impossible to realize sufficient thinning of the conducting wire 51.

  On the other hand, in the present embodiment, since the second acrylic resin layers 34a2 and 34b2 are provided between the first acrylic resin layers 34a1 and 34b1 and the transparent substrate 33, the second acrylic resin layers 34a2 and 34a2 are provided. By adjusting the thickness of 34b2, the thickness T of the acrylic resin layers 34a and 34b is desired to realize sufficient physical strength while maintaining minute irregularities on the surfaces of the acrylic resin layers 34a and 34b. The thickness can be set. Thereby, generation | occurrence | production of the appearance defect by an abrasion and a dent can be suppressed effectively.

  Note that second fine particles may be added to the second acrylic resin layers 34a2 and 34b2. Examples of the second fine particles include inorganic particles made of silica (silicon oxide), alumina (aluminum oxide), calcium carbonate, barium sulfate, etc., organic substances such as acrylic resin, urethane resin, silicon resin, fluorine resin, and melamine resin. What consists of particle | grains can be used. It is more preferable to use organic particles of styrene acrylic resin because the haze can be reduced by matching the refractive indexes of the second fine particles P and the acrylic resin. Further, the first fine particles P and the second fine particles may be fine particles of the same material or may be fine particles of different materials.

  As described above, when the second fine particles are added to the second acrylic resin layers 34a2 and 34b2, minute irregularities are formed on the surfaces of the second acrylic resin layers 34a2 and 34b2 due to the presence of the second fine particles. Can be formed. Thereby, after forming the second acrylic resin layers 34a2 and 34b2 on the transparent base material 33 and before forming the first acrylic resin layers 34a1 and 34b1, the transparent base material 33 and the second acrylic resin layer 34a2 are formed. , 34b2 is also wound up in a roll shape, the friction between the second acrylic resin layers 34a2, 34b2 and the guide roller is caused by minute irregularities on the surfaces of the second acrylic resin layers 34a2, 34b2. Can be reduced. Therefore, it is effective that wrinkles are generated in the transparent base material 33 and the second acrylic resin layers 34a2 and 34b2 due to friction between the transparent base material 33 and the second acrylic resin layers 34a2 and 34b2 and the guide roller. Can be suppressed.

  The second fine particles preferably have a particle size smaller than the thickness T2 (see FIG. 16) of the second acrylic resin layers 34a2 and 34b2. Furthermore, the second fine particles preferably have a particle size of 50% or less of the thickness T1 of the first acrylic resin layers 34a1 and 34b1. According to the second acrylic resin layers 34a2 and 34b2 to which the second fine particles having such a particle size are added, the second acrylic resin layers 34a2 and 34b2 are caused by the unevenness on the surfaces of the second acrylic resin layers 34a2 and 34b2. It is possible to prevent the irregularities (surface roughness) on the surfaces of the first acrylic resin layers 34a1 and 34b1 formed on the layers 34a2 and 34b2 from becoming too large. Therefore, the conducting wire 51 can be effectively thinned.

  Moreover, it is preferable that the pencil hardness of the surface of acrylic resin layer 34a, 34b is H or more. Here, the pencil hardness is measured in accordance with JIS K5600-5-4-1: 1999 (load 1000 g, speed 1 mm / s).

Further, for example, the Martens hardness measured by pushing a Vickers indenter into the surfaces of the acrylic resin layers 34a and 34b is preferably 175 N / mm ² or more when the maximum pushing amount of the Vickers indenter is 1 μm. . The Martens hardness can be measured using, for example, a microhardness tester (PICODERTOR (registered trademark) HM500, ISO145777-1) manufactured by Fisher Instruments Co., Ltd.

  When the acrylic resin layers 34a and 34b have such hardness, it is possible to suppress the generation of scratches or dents on the surfaces of the acrylic resin layers 34a and 34b. In particular, when the transparent electrode 31 is manufactured by the roll-to-roll method, scratches or dents are generated on the surfaces of the acrylic resin layers 34a and 34b due to contact with a guide roller or the like provided in the middle of conveyance. Can be suppressed. Thereby, it is possible to effectively prevent the appearance defects caused by scratches or dents that may occur on the surfaces of the acrylic resin layers 34a and 34b. Therefore, it is possible to ensure good transparency through the transparent electrode 31 having the acrylic resin layers 34a and 34b.

  Of the acrylic resin layers 34a and 34b, the acrylic resin layer located on the observer side of the transparent base material 33 is referred to as an “observer side acrylic resin layer”, and the acrylic resin layer located on the opposite side. This may be referred to as “display device side acrylic resin layer”. As will be described later, the conducting wire 51 may be positioned on the viewer side of the base film 32 or may be positioned on the display device side of the base film 32. Therefore, the acrylic resin layer 34a may be an “observer side acrylic resin layer” and the acrylic resin layer 34b may be a “display device side acrylic resin layer”, or the acrylic resin layer 34b may be an “observer”. In some cases, the acrylic resin layer 34 a becomes a “display side acrylic resin layer”.

  Next, the layer structure of the conducting wire 51 will be described. As shown in FIG. 4, the conducting wire 51 includes a conducting wire forming layer 52 having a low reflection layer 54, a main body layer 53, and a low reflection layer 55 arranged in this order from the base film 32 side.

  The main body layer 53 is a layer for mainly realizing electrical conductivity in the conductive wire 51. The main body layer 53 in the present invention is configured to have a thickness of, for example, 0.2 μm or less, more specifically, in a range of 0.02 μm to 0.2 μm. Thereby, it can suppress that the thickness of the conducting wire 51 whole becomes large, and it can suppress that external light and video light are reflected in the side surface of the conducting wire 51 by this. For this reason, the visibility in the display device to which the transparent electrode 31 is attached can be sufficiently ensured.

On the other hand, reducing the thickness of the main body layer 53 can lead to an increase in the electrical resistance value of the conducting wire 51. Here, in the present embodiment, a metal material having a specific resistance equal to or lower than a desired value is used as a material constituting the main body layer 53. For example, the specific resistance is 4.0 × 10 ⁻⁶ (Ωm). The following metal materials are used. Thereby, the electrical resistance value of the conducting wire 51 can be made sufficiently low. For example, the sheet resistance value of the main body layer 53 can be set to 0.3Ω / □ or less. In the present invention, for example, gold, silver, copper, platinum, aluminum, or the like, as a metal material having a specific resistance of 4.0 × 10 ⁻⁶ (Ωm) or less for constituting the main body layer 53, A material (metal simple substance, metal alloy, etc.) containing 90% by weight or more of a metal such as tin can be used. In the present embodiment, a material containing 99.9% by weight of copper can be used.

  By the way, metal materials, such as copper, show a metallic luster, while having high electroconductivity. For this reason, when an untreated metal material is used as the conducting wire 51, the visibility of the image light from the display device is hindered by the metallic luster of the conducting wire. In particular, copper exhibits a reddish color peculiar to copper, so that it is more conspicuous than other metal materials such as silver, and this hinders the visibility of image light from the display device.

  In order to relieve such a metallic luster peculiar to copper, thin low reflection layers 54 and 55 in which the metallic luster is suppressed as compared with the main body layer 53 are provided on both surfaces of the main body layer 53. Hereinafter, the low reflection layers 54 and 55 will be described.

  The low reflection layers 54 and 55 are layers made of copper nitride. Copper nitride may further contain oxygen atoms. As the copper nitride, for example, a copper compound containing 5 to 25 atomic% of nitrogen, 5 to 25 atomic% of oxygen, and 50 to 90 atomic% of copper may be used. In the low reflection layer 54 configured using such copper nitride, the metallic luster is reduced compared to the metallic luster in the main body layer 53, and in particular, the reddish color peculiar to copper is present. In particular, the reddish color peculiar to copper is reduced. For this reason, it can suppress that the visibility of an image | video falls by the reflected light from the conducting wire 51. FIG.

  The low reflection layers 54 and 55 have a smaller thickness than the main body layer 53. Specifically, the thicknesses of the low reflection layers 54 and 55 are in the range of 10 nm to 60 nm. It is possible to suppress an increase in the thickness of the entire conductive wire 51, and thereby it is possible to suppress external light and video light from being reflected on the side surface of the conductive wire 51.

  Moreover, the reflectance of the light in the conducting wire 51 can also be lowered by setting the thickness of the low reflection layers 54 and 55 within the range of 10 nm to 60 nm. Examples of this reason include, but are not limited to, thin film interference that occurs in the low reflection layers 54 and 55. The thin film interference is a phenomenon in which light reflected on one surface of the low reflection layers 54 and 55 interferes with light reflected on the other surface of the low reflection layers 54 and 55. By setting the thicknesses of the low reflection layers 54 and 55 within the above-mentioned range of 10 to 60 nm, thin film interference occurs so as to weaken the reflected light, and this reduces the light reflectance of the conducting wire 51. Can be considered.

  A method for forming the thin low-reflection layers 54 and 55 as described above is not particularly limited, and a known thin film forming method such as a sputtering method, a vacuum evaporation method, a CVD method, an ion plating method, or an electron beam method is used. Can be used. For example, when a sputtering method is used, a desired composition is obtained by applying discharge power to a target made of copper while supplying both nitrogen gas or nitrogen gas and oxygen gas controlled to a predetermined flow rate in a vacuum atmosphere. It is possible to obtain a layer made of the above-mentioned copper nitride having

  Next, a method for manufacturing the transparent electrode 31 having the above configuration will be described with reference to FIGS. 5A to 5E.

  First, as shown in FIG. 5A, a base film 32 is prepared. As described above, the base film 32 includes the transparent base material 33 and the acrylic resin layers 34a and 34b provided on both sides of the transparent base material 33, respectively. The one acrylic resin layer 34 a includes a first acrylic resin layer 34 a 1 and a second acrylic resin layer 34 a 2 provided between the first acrylic resin layer 34 a and the transparent substrate 33. It is out. Similarly, the other acrylic resin layer 34b includes a first acrylic resin layer 34b1, and a second acrylic resin layer 34b2 provided between the first acrylic resin layer 34b and the transparent substrate 33. Contains. In addition, first fine particles P are added to the first acrylic resin layers 34a1 and 34b1 as fillers (fillers).

  An example of a method for producing the substrate film 32 will be described. First, a long transparent substrate 33 is prepared, and second acrylic resin layers 34a2 and 34b2 are formed on both sides of the transparent substrate 33, and the first Acrylic resin layers 34a1 and 34b1 are formed in this order.

  For example, the second acrylic resin layers 34a2 and 34b2 can be formed by coating a coating liquid containing an acrylic resin on the transparent substrate 33 using a coater. Note that second fine particles may be added to the second acrylic resin layers 34a2 and 34b2. Next, a coating liquid containing an acrylic resin to which the first fine particles P are added as a filler is coated on the cured second acrylic resin layers 34a2 and 34b2 using a coater, whereby the first acrylic resin is coated. Layers 34a1 and 34b1 can be formed. Here, the particle diameter of the first fine particles P added to the first acrylic resin layers 34a1 and 34b1 is larger than the thickness T1 of the first acrylic resin layers 34a1 and 34b1 in the dry-cured state. As a coater for forming the second acrylic resin layers 34a2 and 34b2 and the first acrylic resin layers 34a1 and 34b1, it is preferable that the flatness of the acrylic resin layers 34a and 34b can be sufficiently secured. For example, a gravure coater is used. The coating liquid for forming the second acrylic resin layers 34a2 and 34b2 and the coating liquid for forming the first acrylic resin layers 34a1 and 34b1 have flatness of the acrylic resin layers 34a and 34b. A leveling agent for increasing the viscosity may be included. Thereby, for example, it is possible to suppress the occurrence of defects such as pinholes when the conductive wire 51 layer is formed on the acrylic resin layer 34a.

  When the base film is fed by the roll-to-roll method, the base film sticks to the guide roller if there is not enough slip between the base film and the guide roller, which causes wrinkles on the base film. Sometimes. In the present embodiment, the first fine particles P having a particle size larger than the thickness T1 of the first acrylic resin layers 34a1 and 34b1 are added to the first acrylic resin layers 34a1 and 34b1 of the base film 32. Yes. Since the first fine particles P have a particle size larger than the thickness T1 of the first acrylic resin layers 34a1 and 34b1, as shown in FIG. 16, the tops thereof are the first acrylic resin layers 34a1, It protrudes from the surface of 34b1. Thereby, a minute unevenness | corrugation can be formed in the surface of the base film 32, and sufficient slipperiness can be provided between the base film 32 and a guide roller. Therefore, it is possible to effectively prevent the base film 32 from sticking to the guide roller and causing the base film 32 to be wrinkled.

  Furthermore, if the acrylic resin layers 34a and 34b are thin and have insufficient physical strength, there is a possibility that appearance defects due to scratches or dents due to friction with the guide roller may occur. On the other hand, in this embodiment, since the acrylic resin layers 34a and 34b include the first acrylic resin layers 34a1 and 34b1 and the second acrylic resin layers 34a2 and 34b2, the second acrylic resin layer 34a2 By adjusting the thickness of 34b2, the thickness of the acrylic resin layers 34a and 34b is set to a desired thickness that achieves sufficient physical strength while maintaining the surface roughness of the acrylic resin layers 34a and 34b. Can be controlled. Thereby, it can suppress effectively that the appearance defect by an abrasion or a dent occurs during conveyance of substrate film 32.

  Further, when the surface roughness of the base film 32 is small, the base film 32 is likely to stick to the guide roller in a vacuum atmosphere, and sufficient slipperiness cannot be obtained between the base film 32 and the guide roller. Therefore, wrinkles due to heat may occur in the shape of the base film 32. On the other hand, in this embodiment, since the arithmetic average roughness Ra of the surface of the base film 32 is 3 nm or more and 25 nm or less, sufficient slipperiness can be achieved between the base film 32 and the guide roller. Moreover, it can suppress that the wrinkle by a heat | fever generate | occur | produces in the shape of the base film 32. FIG.

  After preparing the base film 32, as shown to FIG. 5B, the low reflection layer 54 is formed on the acrylic resin layer 34a. The low reflective layer 54 is formed by sputtering a copper target using, for example, an AC discharge with a frequency of 30 kHz to 2 MHz (hereinafter, also referred to as an AC discharge with a specific frequency or an AC discharge) in an atmosphere containing nitrogen gas. Can be formed. A copper target may be sputtered using both AC discharge and DC discharge (hereinafter also abbreviated as DC discharge) having a frequency of 30 kHz to 2 MHz. In addition to nitrogen gas, oxygen gas may be further introduced.

  Next, as shown in FIG. 5B, the main body layer 53 is formed on the low reflection layer 54. Then, the low reflection layer 55 is formed on the main body layer 53. As a method for forming the main body layer 53 and the low reflection layer 54, as described above, a thin film forming method such as a sputtering method can be used.

  In this way, a laminate 60 (also referred to as a blank) as a base material for producing the transparent electrode 31 is obtained. The laminate 60 includes a base film 32 and a conductive wire forming layer 52 provided on the base film 32. The conducting wire forming layer 52 includes a low reflection layer 54, a main body layer 53, and a low reflection layer 55 arranged in this order from the base film 32 side.

  After preparing the laminated body 60, as shown in FIG. 5C, a photosensitive resist layer 71 is formed in a predetermined pattern on the conductive wire forming layer 52. The photosensitive resist layer 71 has photosensitivity to light in a specific wavelength range, for example, ultraviolet rays. The type of the photosensitive resist layer 71 is not particularly limited. For example, a photodissolvable photosensitive resist layer may be used, or a photocurable photosensitive resist layer may be used. Here, an example in which a photodissolvable photosensitive resist layer is used will be described.

  The photosensitive resist layer 71 is formed in a pattern corresponding to the pattern of the conductive wire 51. The photosensitive resist layer 71 is, for example, by first coating a photosensitive resist material on the surface of the laminate 60 using a coater, and then exposing and developing the photosensitive resist material in a predetermined pattern. A photosensitive resist layer 71 having a predetermined pattern shape is formed.

  Next, as shown in FIG. 5D, the low reflection layer 55, the main body layer 53, and the low reflection layer 54 are etched using the photosensitive resist layer 71 as a mask. As described above, all of the low reflection layer 55, the main body layer 53, and the low reflection layer 54 are configured to include copper. For this reason, the low reflection layer 55, the main body layer 53, and the low reflection layer 54 can be etched simultaneously using an etching solution capable of dissolving copper. As the etching solution, for example, phosphonitrate is used.

  Here, when the surface roughness of the base film 32 is large, the resist pattern located on the convex portion of the surface is easily damaged by friction with the guide roller, and the etching solution penetrates from the scratch during etching, so that the conductor 51 If the pattern is eroded and is noticeable, the conductor 51 may be broken. On the other hand, in this embodiment, since the arithmetic average roughness Ra of the surface of the base film 32 is 3 nm or more and 25 nm or less, the resist pattern is less likely to be scratched by friction with the guide roller, and etching soaks from the scratch. It can be suppressed that the pattern of the conducting wire 51 is eroded by the liquid. As a result, for example, it is possible to stably manufacture the conductive wire 51 that is thinned to an average line width of 2 μm.

  Next, the photosensitive resist layer 71 remaining on the main body layer 55 is washed with a chemical solution for dissolving and removing the photosensitive resist layer 71 and subjected to film removal. Thereby, as shown in FIG. 5E, the photosensitive resist layer 71 can be removed. In this way, the conductive wire forming layer 52 having the low reflective layer 55, the main body layer 53, and the low reflective layer 54 is patterned, and the transparent electrode 31 including the conductive wire 51 configured therefrom can be obtained.

  Here, according to the present embodiment, as described above, the conductive wire 51 includes the main body layer 53 containing 90% by weight or more of copper, and the low reflection layer 54 made of copper nitride provided on the surface of the main body layer 53. And. For this reason, the low reflection layer 54 can suppress reddish light from reaching the observer due to the metallic luster of copper. Moreover, since both the main body layer 53 and the low reflection layers 54 and 55 contain copper, when producing the transparent electrode 31 from the laminated body 60, by using an etching solution capable of selectively dissolving copper. The conductor layer 51 can be formed by simultaneously etching the main body layer 53 and the low reflection layers 54 and 55 of the laminate 60. For this reason, the man-hour required in order to produce the transparent electrode 31 can be made small.

<Second Embodiment>
Next, a second embodiment of the present invention will be described with reference to FIGS. In the present embodiment, a display device with a touch position detection function obtained by combining a touch panel including the above-described transparent electrode 31 and a display device will be described. In the present embodiment, the same parts as those in the above-described embodiments are denoted by the same reference numerals, and detailed description thereof is omitted. In addition, when it is clear that the operational effects obtained in each embodiment can be obtained also in this embodiment, the description thereof may be omitted.

  FIG. 6 is a development view showing the display device 10 with a touch position detection function. As shown in FIG. 6, the display device 10 with a touch position detection function is configured by combining a touch panel 30 and a display device 15 such as a liquid crystal display or an organic EL display.

  The illustrated display device 15 is configured as a flat panel display. The display device 15 includes a display panel 16 having a display surface 16 a and a display control unit (not shown) connected to the display panel 16. The display panel 16 includes an active area A1 that can display an image, and an inactive area (also referred to as a frame area) A2 that is disposed outside the active area A1 so as to surround the active area A1. . The display control unit processes information regarding the video to be displayed, and drives the display panel 16 based on the video information. The display panel 16 displays a predetermined image on the display surface 16a based on a control signal from the display control unit. That is, the display device 15 plays a role as an output device that outputs information such as characters and drawings as video.

  As shown in FIG. 6, a protective plate 12 having translucency may be further provided on the viewer side of the touch panel 30, that is, the side opposite to the display device 15. For example, the protective plate 12 is bonded to the surface of the touch panel 30 on the viewer side with an adhesive layer or the like. The protective plate 12 is for preventing damage to the pattern of the touch panel 30 and the display device 15 due to contact with an external conductor such as a finger, and is also referred to as a so-called front plate.

  As shown in FIG. 6, the touch panel 30 is bonded to the display surface 16 a of the display device 15 via, for example, an adhesive layer (not shown). The touch panel 30 is configured by combining two transparent electrodes 31. In FIG. 6, the see-through electrode arranged on the observer side is represented by reference numeral 31 </ b> A, and the see-through electrode arranged on the display device side from the see-through electrode 31 </ b> A is represented by reference numeral 31 </ b> B. In the following description, the transparent electrode labeled 31A is also referred to as a first transparent electrode 31A, and the transparent electrode labeled 31B is also referred to as a second transparent electrode 31B.

  FIG. 7 is a plan view showing the touch panel 30 when viewed from the observer side. In FIG. 7, the constituent elements of the first transparent electrode 31A are represented by solid lines, and the constituent elements of the second transparent electrode 31B are represented by dotted lines.

  As shown in FIG. 7, each of the first transparent electrode 31A and the second transparent electrode 31B includes a plurality of conductive patterns 41 extending in a predetermined direction. Here, the first transparent electrode 31A and the second transparent electrode 31B are arranged so that the respective conductive patterns 41 extend in directions intersecting each other. For example, the first transparent electrode 31A is arranged such that the conductive pattern 41 extends along the first direction D1. On the other hand, the 2nd transparent electrode 31B is arrange | positioned so that the conductive pattern 41 may extend along the 2nd direction D2 orthogonal to the 1st direction D1.

  FIG. 8 is an enlarged plan view showing the conductive pattern 41 in a portion surrounded by a one-dot chain line denoted by reference numeral VIII in FIG. As shown in FIG. 8, the conductive pattern 41 of the first transparent electrode 31A and the conductive pattern 41 of the second transparent electrode 31B are each composed of a conductive wire 51 arranged in a mesh shape.

  FIG. 9 is a cross-sectional view showing a case where the touch panel 30 is cut along the line IX-IX in FIG. As shown in FIG. 9, the touch panel 30 has the first perspective view so that both the lead wire 51 of the first transparent electrode 31 </ b> A and the lead wire 51 of the second transparent electrode 31 </ b> B are located on the display device side of the base film 32. 31A and the second transparent electrode 31B are combined. Note that an adhesive layer 38 or the like may be interposed between the first transparent electrode 31A and the second transparent electrode 31B.

  10 is an enlarged cross-sectional view of a part of the touch panel 30 shown in FIG. As shown in FIG. 10, both the conductive wire 51 of the first transparent electrode 31 </ b> A and the conductive wire 51 of the second transparent electrode 31 </ b> B include the above-described conductive wire forming layer 52. Here, as shown in FIG. 10, the conductive wire forming layer 52 includes a main body layer 53, a low reflection layer 54 provided on the observer side of the main body layer 53, and a low reflection provided on the display device side of the main body layer 53. Layer 55.

  Since the low reflection layer 54 is provided on the viewer side of the main body layer 53, it is possible to prevent external light incident on the touch panel 30 from the viewer side from being reflected by the conductive wire 51 and returning to the viewer side. it can. Thereby, it can suppress that the conducting wire 51 is visually recognized by an observer, and this can suppress that the visibility of the image from the display device 15 is hindered by the conducting wire 51. Further, since the low reflection layer 55 is provided on the display device side of the main body layer 53, the image light from the display device 15 incident on the touch panel 30 is reflected by the conductive wire 51 and returns to the display device 15 side, and then the display is performed. It can be suppressed that the light is reflected again by the components of the device 15 and reaches the observer as noise light.

  Further, as described above, the main body layer 53 of the conductive wire forming layer 52 is configured to have a thickness of 0.2 μm or less. In the present embodiment, it is 0.1 μm. For this reason, it can suppress that the light which injected into the touch panel 30 along the direction inclined from the normal line direction of the base film 32 is reflected by the side surface of the conducting wire formation layer 52. Thereby, it can suppress that the side of the conducting wire 51 is visually recognized by an observer, and that the video light from the display device is hindered by the side of the conducting wire 51. Accordingly, the visibility of the video can be improved.

  Various changes can be made to the above-described embodiment. Hereinafter, modified examples will be described with reference to the drawings. In the following description and the drawings used in the following description, the same reference numerals as those used for the corresponding parts in the above embodiment are used for the parts that can be configured in the same manner as the above embodiment. The duplicated explanation is omitted. In addition, when it is clear that the operational effects obtained in the above-described embodiment can be obtained in the modified example, the description thereof may be omitted.

  FIG. 9 shows an example in which both the conductive wire 51 of the first transparent electrode 31 </ b> A and the conductive wire 51 of the second transparent electrode 31 </ b> B are located on the display device side of the base film 32. There is no. For example, as shown in FIG. 11, the conducting wire 51 of the first transparent electrode 31A is located on the viewer side of the base film 32, while the conducting wire 51 of the second transparent electrode 31B is an indication of the base film 32. It may be located on the device side.

  As shown in FIG. 12, the conductive wire 51 of the first transparent electrode 31 </ b> A is located on the display device side of the base film 32, while the conductive wire 51 of the second transparent electrode 31 </ b> B is an observation of the base film 32. It may be located on the person side.

  Next, a preferable example of the cross-sectional shape of the conducting wire 51 when the conducting wire 51 is provided on the display device side of the base film 32 will be described with reference to FIG.

  As shown in FIG. 13, the conductive wire forming layer 52 of the conductive wire 51 has a tapered shape that tapers toward the display device 15. In this case, the external light L incident on the touch panel 30 along the direction inclined from the normal direction of the base film 32 is not incident on the side surface of the conductor 51 due to the tapered shape of the conductor formation layer 52. You can escape to the side. For this reason, it can further suppress that external light is reflected by the conducting wire 51 and returns to the observer side.

  Although the specific taper shape of the conducting wire formation layer 52 is appropriately set according to the assumed degree of inclination of external light, for example, the normal direction of the base film 32 and the side surface of the conducting wire 51 are formed. The angle is in the range of 10 ° to 30 °.

<Third Embodiment>
Next, a third embodiment of the present invention will be described with reference to FIGS. In the present embodiment, an example in which the conductive wires 51 are provided on both sides of the base film 32 will be described. In the present embodiment, the same parts as those in the above-described embodiments are denoted by the same reference numerals, and detailed description thereof is omitted. In addition, when it is clear that the operational effects obtained in each embodiment can be obtained also in this embodiment, the description thereof may be omitted.

  As shown in FIG. 14, the transparent electrode 31 includes a base film 32, a conductor 51 provided on the viewer-side surface (first surface) 32 a of the base film 32, and a display of the base film 32. And a conductor 51 provided on the device side surface (second surface) 32b. The conductive pattern 41 made of the conductive wire 51 on the first surface 32a side and the conductive pattern 41 made of the conductive wire 51 on the second surface 32b side are provided so as to cross each other. For example, in the figure, the conductive pattern 41 on the first surface 32a extends in a direction orthogonal to the paper surface, and the conductive pattern 41 on the second surface 32b extends in a direction parallel to the paper surface. For this reason, according to the present embodiment, the touch panel 30 can be configured by the single transparent electrode 31.

  FIG. 15 is an enlarged cross-sectional view of a part of the transparent electrode 31 shown in FIG. As shown in FIG. 15, the conductive wires 51 provided on the first surface 32 a and the second surface 32 b of the base film 32 each include the above-described conductive wire forming layer 52. For this reason, it can suppress that the external light which injected into the touch panel 30 from the observer side is reflected by the conducting wire 51, and returns to the observer side. Thereby, it can suppress that the conducting wire 51 is visually recognized by an observer, and this can suppress that the visibility of the image from the display device 15 is hindered by the conducting wire 51.

  In each of the embodiments described above, the use of the transparent electrode 31 has been described using the touch position detection electrode of the touch panel as an example. However, the use of the transparent electrode 31 of the present invention is not limited to this. In addition to touch position detection electrodes, transparent electrodes of EL (electroluminescence) image display devices, screens of various image display devices, windows of buildings, transparent electromagnetic shielding materials to be mounted on vehicle windows, windows of buildings, It can also be used for applications such as a transparent heating electrode mounted on a vehicle window or the like for defrosting or defogging.

  In addition, although the some modification with respect to this Embodiment mentioned above has been demonstrated, naturally, it can also apply combining a some modification suitably.

  EXAMPLES Next, although an Example demonstrates this invention further more concretely, this invention is not limited to description of a following example, unless the summary is exceeded.

  As shown in FIG. 4, samples (samples 1 and 2) of a laminate including a base film 32 and a conductive wire forming layer 52 provided on the base film 32 were prepared. The conducting wire forming layer 52 includes a low reflection layer 54, a main body layer 53, and a low reflection layer 55 arranged in this order from the base film 32 side. The conductive wire forming layer 52 was etched so that the average line width was 2 μm, and the pattern of the conductive wire 51 was produced. As a material constituting the transparent substrate 33 of the substrate film 32, a biaxially stretched PET film having a thickness of 100 μm was used. Materials constituting the acrylic resin layers 34a and 34b of the base film 32 include ultraviolet light from a monomer having an acryloyl group in the molecule, a prepolymer having an acryloyl group in the molecule, and a benzotriazole photoinitiator. A curable acrylic resin obtained by crosslinking and curing by ultraviolet irradiation was used. As a material constituting the main body layer 53, copper having a purity (copper content) of 99.9% by mass was used. As a material constituting the low reflection layers 54 and 55, a copper compound made of copper nitride was used.

  Moreover, the comparison samples 1-4 which do not have a 2nd acrylic resin layer were prepared for the comparison. Each sample was prepared under the same conditions except that the first fine particles P added as a filler in the acrylic resin of the acrylic resin layers 34a and 34b, the particle diameter thereof, and the thickness of the acrylic resin layers 34a and 34b were changed. It was done.

Next, the surface characteristics of the acrylic resin layers 34a and 34b in each sample were measured using a scanning white interferometer NewView (registered trademark) 7300 (manufactured by Zygo Corporation). Specific measurement conditions are as follows.
・ × 10x lens ・ 543μm □ area field of view specification ・ “Removed” setting: Cylinder
・ "Trimmed" setting: Zero

  The Martens hardness in each sample was measured using a micro hardness tester (PICODERTOR (registered trademark) HM500, ISO145777-1) manufactured by Fisher Instruments Co., Ltd. Table 1 shows Martens hardness when the maximum pushing amount of the Vickers indenter is 1 μm. Furthermore, the pencil hardness in each sample was measured using a hand-held pencil scratch hardness tester NO553.9-S manufactured by Yasuda Seiki Seisakusho, in accordance with JIS K5600-5-4-1: 1999, with a load of 750 g and a speed of 0.5 mm / s, the measurement length was 10 mm, and the scratch angle was 45 degrees. Moreover, it was judged visually whether the film shape of each sample was favorable. Here, the case where there was no wrinkle in each sample was determined to be good (◯), and the case where wrinkle was present was determined to be defective (x).

  Moreover, the total light transmittance and haze value were measured as an optical characteristic of each sample. The measurement light L was incident on each sample from the conductive wire forming layer 52 side. As a measuring instrument, a haze / transmittance meter HR-100 (manufactured by Murakami Color Research Laboratory Co., Ltd.) was used.

  Table 1 summarizes the production conditions, surface characteristics, hardness, film shape, and optical characteristics of each sample.

  In Table 1, Ra represents the arithmetic average roughness, and Vol Up represents the sum total of the volumes of the raised portions included in the 543 μm square region of the surface of the base film 32.

  As shown in Table 1, the sample 1 and the sample 2 having the second acrylic resin layer did not visually check for wrinkles and had a good film shape. Ra and Vol Up representing surface characteristics, and Martens hardness and pencil hardness representing hardness both have good values and provide sufficient slipping between the base film and the guide roller. However, it was confirmed that it was possible to suppress the generation of scratches and dents on the surface of the acrylic resin layer. Further, the total light transmittance and haze value representing the optical characteristics were also good values. That is, it was confirmed that even when the second acrylic resin layer was provided, the optical characteristics were not impaired, and the optical characteristics were sufficient as a transparent electrode. Furthermore, in Sample 1 and Sample 2, no disconnection of the conductive wire occurred, and the yield rate as a transparent electrode was good.

In Comparative Sample 1 having no second acrylic resin layer, wrinkles were visually observed, and it was confirmed that it was not suitable as a transparent electrode. Moreover, it was confirmed that Ra is smaller than 3 nm and Vol Up is smaller than 6.0 × 10 ¹¹ nm ³ . Thereby, in the comparison sample 1, in comparison with the sample 1 and the sample 2, the slipperiness between the base film and the guide roller may be inferior.

In Comparative Sample 2 having no second acrylic resin layer, although wrinkles were not visually observed, it was confirmed that Ra was larger than 25 nm and Vol Up was larger than 4.0 × 10 ¹² nm ³ . Thereby, in the comparative sample 2, in comparison with the sample 1 and the sample 2, there is a possibility that the resist pattern positioned on the convex portion on the surface during manufacture is easily damaged by friction with the guide roller. When the resist pattern is scratched, the etching solution penetrates from the scratch when the metal layer is etched, eroding the pattern of the conductor, and in a significant case, the conductor may be disconnected. Moreover, in the comparative sample 2, it was confirmed that the Martens hardness is smaller than 175 N / mm ² and the pencil hardness is smaller than H. Thereby, in the comparative sample 2, in comparison with the sample 1 and the sample 2, there is a possibility that the surface of the acrylic resin layer is likely to be scratched or dented due to contact with a guide roller or the like provided in the middle of conveyance. is there. If scratches or dents are generated on the surface of the acrylic resin layer, a poor appearance of the transparent electrode may occur, and the transparency through the transparent electrode may be reduced.

In Comparative Sample 3 and Sample 4 having no second acrylic resin layer, although wrinkles were not visually observed, it was confirmed that Martens hardness was smaller than 175 N / mm ² and pencil hardness was smaller than H. Thereby, in the comparative sample 2, in comparison with the sample 1 and the sample 2, there is a possibility that the surface of the acrylic resin layer is likely to be scratched or dented due to contact with a guide roller or the like provided in the middle of conveyance. is there. If scratches or dents are generated on the surface of the acrylic resin layer, a poor appearance of the transparent electrode may occur, and the transparency through the transparent electrode may be reduced.

DESCRIPTION OF SYMBOLS 10 Display device with a touch position detection function 12 Protection plate 15 Display device 16 Display panel 30 Touch panel 31 Transparent electrode 32 Base film 33 Transparent base material 34a, 34b Acrylic resin layer 34a1, 34b1 First acrylic resin layer 34a2, 34b2 Second acrylic resin layer 38 Adhesive layer 41 Conductive pattern 43 Frame wiring 44 Terminal portion 51 Conductive wire 52 Conductive wire forming layer 53 Main body layer 54 Low reflective layer 55 Low reflective layer 60 Laminate 71 Photosensitive resist layer P First fine particle

Claims (9)

A substrate film comprising a transparent substrate and an acrylic resin layer provided on the surface of the transparent substrate;
A plurality of conductive patterns provided on the base film;
With
The conductive pattern is a conductive wire having a light shielding property, and includes conductive wires arranged in a mesh shape so that an opening is formed between the conductive wires,
The acrylic resin layer includes a first acrylic resin layer, and a second acrylic resin layer provided between the first acrylic resin layer and the transparent substrate,
The transparent electrode, wherein the first acrylic resin layer is added with first fine particles having a particle diameter larger than the thickness of the first acrylic resin layer. The sum total of the volume of the protruding part contained in the region of 543 μm □ on the surface of the acrylic resin layer is 6.0 × 10 ¹¹ nm ³ or more and 4.0 × 10 ¹² nm ³ or less. Transparent electrode.   The transparent electrode according to claim 1 or 2, wherein an arithmetic average roughness Ra of the surface of the acrylic resin layer is 3 nm or more and 25 nm or less.   The see-through electrode in any one of Claims 1-3 whose pencil hardness of the surface of the said acrylic resin layer is H or more.   The transparent electrode according to claim 1, wherein second fine particles are added to the second acrylic resin layer.   The transparent electrode according to claim 5, wherein the second fine particles have a particle size smaller than a thickness of the second acrylic resin layer.   The transparent electrode according to claim 5 or 6, wherein the second fine particles have a particle size of 50% or less of the thickness of the first acrylic resin layer.   A touch panel comprising the transparent electrode according to claim 1. A display device;
The touch panel according to claim 8, which is disposed on a display surface of the display device;
A display device with a touch position detection function.

Images