JP2017179670A - Treatment agent composition for fiber product - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a treatment agent composition for fiber product having suppressed generation of amine odor due to exposure of ultraviolet or the like.SOLUTION: There is provided a treatment agent composition for fiber product containing following (A) to (C) components. (A) a compound represented by the formula I, (B) at least one kind of compound selected from a group consisting of an amine compound having 1 to 3 hydrocarbon group which may be parted by an ester group (-COO-) and/or an amide group (-NHCO-) and has 10 to 26 carbon atoms, a salt thereof and a quaternary product thereof and (C) a compound having an amino group, a quaternary ammonium group, an amide bond or an imide bond (excluding the B component).SELECTED DRAWING: None

Description

  The present invention relates to a treatment composition for textile products. Specifically, the present invention relates to a treatment composition for textile products in which generation of amine odor due to exposure to ultraviolet rays or the like is suppressed.

Nitrogen-containing compounds such as compounds having an amino group, quaternary ammonium group, amide bond or imide bond, which can be blended in the treatment composition for textile products, are the components themselves, their decomposition products, and low molecular weight components remaining. Therefore, amine odor may be generated when stored. Until now, by performing clothing treatment on such nitrogen-containing compounds (Patent Document 1) and masking amine odor by using specific fragrances (Patent Documents 2 and 3), the amine odor is suppressed. Has been tried. However, the amine odor suppression effect by these techniques was not satisfactory.
Patent Document 4 discloses an aryl-acrylate ester useful as a precursor such as flavor. However, Patent Document 4 does not disclose or suggest that the aryl-acrylic acid ester can suppress the generation of amine odor.

Japanese Unexamined Patent Publication No. 7-277948 Japanese Patent Laid-Open No. 2003-49195 JP 11-510541 A JP 2000-63328 A

  So far, a technology has been found that can sufficiently suppress the generation of amine odor derived from a compound having an amino group, a quaternary ammonium group, an amide bond or an imide bond, which can be incorporated into a treating agent composition for textile products. Was not.

As a result of intensive studies to solve the above problems, the present inventors have added a specific structure to the fiber product treating agent composition containing a compound having an amino group, a quaternary ammonium group, an amide bond or an imide bond. It has been found that, by blending the fragrance precursor having, the generation of amine odor due to exposure to ultraviolet rays or the like can be suppressed, and the present invention has been completed.
The present invention has been completed based on such novel findings.

（式中、
Ａはベンゼン環又はナフタレン環であり；
Ｒ¹は、飽和若しくは不飽和で、直鎖若しくは分岐鎖の脂環式又は芳香族Ｃ₁₀−Ｃ₃₀炭化水素残基；１個以上のＯ及び／又はＣ（Ｏ）基及び／又はアルコキシ基を含有する、飽和若しくは不飽和で、直鎖若しくは分岐鎖の脂環式又は芳香族Ｃ₁₀−Ｃ₃₀炭化水素残基；又は−Ｓｉ（Ｃ₁−Ｃ₆アルキル）₃であるか；又はＲ¹は、ノニルアルコール、３，５，５−トリメチルーヘキサノール、シス−６−ノネノール、２，６−ノナジエン−１−オール、２−フェニルプロパノール、３−フェニルプロパノール、２−（２−メチルフェニル）−エタノール、シンナミルアルコール、エチルバニリン、４−イソプロピル−シクロヘキサノール、３，３，５−トリメチル−シクロヘキサノール、２−シクロヘキシル−プロパノール、及び２，６−ジメチル−ヘプタン−２−オールから選ばれるアルコールＲ¹ＯＨの残基であり；
２−又は３−位置におけるＲ²は、水素又はメチル基であり；
Ｒ³とＲ⁴は、水素、直鎖若しくは分岐鎖Ｃ₁−Ｃ₆アルキル若しくはＣ₁−Ｃ₆アルコキシ残基、Ｎ及び／又はＯ原子を含有する五員複素環残基、又はＣ₁−Ｃ₆脂肪族及び／又は芳香族置換基によって置換された五員複素環残基、−ＯＨ、−ＮＯ₂、−ＮＨ₂、−Ｎ（Ｃ₁−Ｃ₆アルキル）₂、−Ｎ（ヒドロキシＣ₁−Ｃ₆アルキル）₂、−ＮＨＣＯ₂ＣＨ₃又は−ＮＨ（複素環）であり；
Ｒ²、Ｒ³及びＲ⁴は、同じ又は異なる基であり；
Ｘは、−ＯＨ、―ＮＨＲ₆又は−ＯＳｉ（Ｃ₁−Ｃ₆アルキル）₃を表し、Ｒ₆は水素、飽和若しくは不飽和で、直鎖若しくは分岐鎖のＣ₁−Ｃ₂₀炭化水素又は任意に置換される芳香族若しくは複素環残基であり；
アクリル系二重結合はＥ立体配置である）、
（Ｂ）エステル基（−ＣＯＯ−）及び／又はアミド基（−ＮＨＣＯ−）で分断されていてもよい、炭素数１０〜２６の炭化水素基を分子内に１〜３個有するアミン化合物、その塩及びその４級化物からなる群から選ばれる少なくとも１種の化合物、及び
（Ｃ）アミノ基、第四級アンモニウム基、アミド結合又はイミド結合を有する化合物（Ｂ成分を除く）。 In one embodiment of the present invention, there is provided a treating composition for textiles containing the following components (A) to (C).
(A) Compound represented by Formula I

(Where
A is a benzene ring or a naphthalene ring;
R ¹ is a saturated or unsaturated, linear or branched alicyclic or aromatic C ₁₀ -C ₃₀ hydrocarbon residue; one or more O and / or C (O) groups and / or alkoxy groups A saturated or unsaturated, linear or branched alicyclic or aromatic C ₁₀ -C ₃₀ hydrocarbon residue; or —Si (C ₁ -C ₆ alkyl) ₃ ; or R ¹ is nonyl alcohol, 3,5,5-trimethyl-hexanol, cis-6-nonenol, 2,6-nonadien-1-ol, 2-phenylpropanol, 3-phenylpropanol, 2- (2-methylphenyl) Ethanol, cinnamyl alcohol, ethyl vanillin, 4-isopropyl-cyclohexanol, 3,3,5-trimethyl-cyclohexanol, 2-cyclohexyl-propanol, and 2,6-dimethyl The residue of an alcohol R ¹ OH selected from lu-heptan-2-ol;
R ² in the 2- or 3-position is hydrogen or a methyl group;
R ³ and R ⁴ are hydrogen, a linear or branched C ₁ -C ₆ alkyl or C ₁ -C ₆ alkoxy residue, a 5-membered heterocyclic residue containing N and / or O atoms, or C _1- 5-membered heterocyclic residues substituted by C ₆ aliphatic and / or aromatic substituents, —OH, —NO ₂ , —NH ₂ , —N (C ₁ -C ₆ alkyl) ₂ , —N (hydroxyC ₁ -C ₆ alkyl) _2, be a -NHCO ₂ CH ₃ or -NH (heterocycle);
R ² , R ³ and R ⁴ are the same or different groups;
X represents —OH, —NHR ₆ or —OSi (C ₁ -C ₆ alkyl) ₃ , R ₆ is hydrogen, saturated or unsaturated, linear or branched C ₁ -C ₂₀ hydrocarbon or any An aromatic or heterocyclic residue substituted with
The acrylic double bond is in the E configuration),
(B) an amine compound having 1 to 3 hydrocarbon groups having 10 to 26 carbon atoms in the molecule, which may be separated by an ester group (—COO—) and / or an amide group (—NHCO—), At least one compound selected from the group consisting of a salt and a quaternized product thereof, and (C) a compound having an amino group, a quaternary ammonium group, an amide bond or an imide bond (excluding component B).

  According to one embodiment of the present invention, it is possible to provide a treating agent composition for textiles in which generation of an amine odor due to exposure to ultraviolet rays or the like is suppressed.

（式中、
Ａはベンゼン環又はナフタレン環であり；
Ｒ¹は、飽和若しくは不飽和で、直鎖若しくは分岐鎖の脂環式又は芳香族Ｃ₁₀−Ｃ₃₀炭化水素残基；１個以上のＯ及び／又はＣ（Ｏ）基／又はアルコキシ基を含有する、飽和若しくは不飽和で、直鎖若しくは分岐鎖の脂環式又は芳香族Ｃ₁₀−Ｃ₃₀炭化水素残基；又は−Ｓｉ（Ｃ₁−Ｃ₆アルキル）₃であるか；又はＲ¹は、ノニルアルコール、３，５，５−トリメチルーヘキサノール、シス−６−ノネノール、２，６−ノナジエン−１−オール、２−フェニルプロパノール、３−フェニルプロパノール、２−（２−メチルフェニル）−エタノール、シンナミルアルコール、エチルバニリン、４−イソプロピル−シクロヘキサノール、３，３，５−トリメチル−シクロヘキサノール、２−シクロヘキシル−プロパノール、及び２，６−ジメチル−ヘプタン−２−オールから選ばれるアルコールＲ¹ＯＨの残基であり；
２−又は３−位置におけるＲ²は、水素又はメチル基であり；
Ｒ³とＲ⁴は、水素、直鎖若しくは分岐鎖Ｃ₁−Ｃ₆アルキル若しくはＣ₁−Ｃ₆アルコキシ残基、Ｎ及び／又はＯ原子を含有する五員複素環残基、又はＣ₁−Ｃ₆脂肪族及び／又は芳香族置換基によって置換された五員複素環残基、−ＯＨ、−ＮＯ₂、−ＮＨ₂、−Ｎ（Ｃ₁−Ｃ₆アルキル）₂、−Ｎ（ヒドロキシＣ₁−Ｃ₆アルキル）₂、−ＮＨＣＯ₂ＣＨ₃又は−ＮＨ（複素環）であり；
Ｒ²、Ｒ³及びＲ⁴は、同じ又は異なる基であり；
Ｘは、−ＯＨ、−ＮＨＲ₆又は−ＯＳｉ（Ｃ₁−Ｃ₆アルキル）₃を表し、Ｒ₆は水素、飽和若しくは不飽和で、直鎖若しくは分岐鎖のＣ₁−Ｃ₂₀炭化水素又は任意に置換される芳香族若しくは複素環残基であり、
アクリル系二重結合はＥ立体配置である。） [(A) component]
Component (A) is a compound represented by Formula I.

(Where
A is a benzene ring or a naphthalene ring;
R ¹ is a saturated or unsaturated, linear or branched alicyclic or aromatic C ₁₀ -C ₃₀ hydrocarbon residue; one or more O and / or C (O) groups / or alkoxy groups. Containing saturated or unsaturated, linear or branched alicyclic or aromatic C ₁₀ -C ₃₀ hydrocarbon residues; or —Si (C ₁ -C ₆ alkyl) ₃ ; or R ¹ Is nonyl alcohol, 3,5,5-trimethyl-hexanol, cis-6-nonenol, 2,6-nonadien-1-ol, 2-phenylpropanol, 3-phenylpropanol, 2- (2-methylphenyl)- Ethanol, cinnamyl alcohol, ethyl vanillin, 4-isopropyl-cyclohexanol, 3,3,5-trimethyl-cyclohexanol, 2-cyclohexyl-propanol, and 2,6-dimethyl- The residue of an alcohol R ¹ OH selected from heptan-2-ol;
R ² in the 2- or 3-position is hydrogen or a methyl group;
R ³ and R ⁴ are hydrogen, a linear or branched C ₁ -C ₆ alkyl or C ₁ -C ₆ alkoxy residue, a 5-membered heterocyclic residue containing N and / or O atoms, or C _1- 5-membered heterocyclic residues substituted by C ₆ aliphatic and / or aromatic substituents, —OH, —NO ₂ , —NH ₂ , —N (C ₁ -C ₆ alkyl) ₂ , —N (hydroxyC ₁ -C ₆ alkyl) _2, be a -NHCO ₂ CH ₃ or -NH (heterocycle);
R ² , R ³ and R ⁴ are the same or different groups;
X represents —OH, —NHR ₆ or —OSi (C ₁ -C ₆ alkyl) ₃ , R ₆ is hydrogen, saturated or unsaturated, linear or branched C ₁ -C ₂₀ hydrocarbon or any An aromatic or heterocyclic residue substituted with
Acrylic double bonds are in the E configuration. )

In R ^1, "a saturated or unsaturated, linear or alicyclic or aromatic C ₁₀ -C ₃₀ branched chain hydrocarbon residue" refers to one of the R ¹ groups, alicyclic portion of the chain and aromatic It means that it can contain both the chain of the family moiety. For example, such R ¹ includes a residue of a predetermined alcohol R ¹ OH, a substrate in the enol form of a predetermined aldehyde R ¹ HO, or a substrate in the enol form of a predetermined ketone R ¹ O.
Specifically, R ¹ is 3,5,5-trimethyl-hexanol, cis-6-nonenol, 2,6-nonadien-1-ol, 2-phenyl-propanol, 3-phenyl-propanol, 2- ( 2-methylphenyl) -ethanol, cinnamyl alcohol, 4-isopropyl-cyclohexanol, 3,3,5-trimethyl-cyclohexanol, 2-cyclohexyl-propanol, 2,6-dimethyl-heptan-2-ol, ethyl vanillin Decyl alcohol, undecyl alcohol, lauryl alcohol, myristyl alcohol, 3,4,5,6,6-pentamethylheptan-2-ol, citronellol, geraniol, 2,5,7-trimethyl-octane-3-ol, 2-cis-3,7-dimethyl-2,6-octadiene-1 , 6-ethyl-3-methyl-5-octen-1-ol, 3,7-dimethyl-oct-3,6-dienol, 3,7-dimethyloctanol, 7-methoxy-3,7-dimethyl- Octan-2-ol, 5-ethyl-2-nonanol, 6,8-dimethyl-2-nonanol, 2,2,8-trimethyl-7 (8) -nonen-3-ol, 4-methyl-3-decene -5-ol, 9-decen-1-ol, 2-methyl-undecanol, 10-undecen-1-ol, 2-methyl-3-phenyl-3-propenol, 4-phenyl-2-butanol, 2-methyl -5-phenyl-pentanol, 2-methyl-4-phenyl-pentanol, 3-methyl-5-phenyl-pentanol, 4- (1-methylethyl) -benzene-methanol, 4- (4-hydroxyphenyl) -butan-2-ol, 4- (1-methylethyl) -2-hydroxy-1-methylbenzene, eugenol, isoeugenol, thymol, decahydro-2-naphthalenol, borneol, cedrenol, farnesol, Fenkyl alcohol, menthol, 3,7,11-trimethyl-2,6,10-dodecatrien-1-ol, α-ionol, tetrahydroionol, 2- (1,1-dimethylethyl) cyclohexanol, 3- (1,1-dimethylethyl) cyclohexanol, 4- (1,1-dimethylethyl) cyclohexanol, 6,6-dimethyl-bicyclo [3.3.1] hept-2-ene-2-ethanol, 6, 6-dimethyl-bicyclo [3.1.1] hept-2-ene-methanol, p Maintenance-8-en-3-ol, 2,4,6-trimethyl-3-cyclohexenyl-methanol, 4- (1-methylethyl) -cyclohexyl-methanol, 4- (1,1-dimethylethyl) -cyclo Hexanol, 2- (1,1-dimethylethyl) -cyclohexanol, 2,2,6-trimethyl-α-propyl-cyclohexanepropanol, 5- (2,2,3-trimethyl-3-cyclopentenyl) -3- Methylpentan-2-ol, 3-methyl-5- (2,2,3-trimethylcyclopent-3-enyl) pent-4-en-2-ol, 2-ethyl-4 (2,2,3- Trimethylcyclopent-3-enyl) but-2-en-1-ol, 4- (5,5,6-trimethylbicyclo [2.2.1] hept-2-yl) -cyclohexano 2- (2-methylpropyl) -4-hydroxy-4-methyl-tetrahydropyran, 2- (1,1-dimethylethyl) -4-methyl-cyclohexanol, 1- (2-tert-butyl-cyclohexyl) Oxy) -2-butanol, 1- (4-isopropyl-cyclohexyl) -ethanol, 2,6-dimethyl-oct-7-en-2-ol, 3,7-dimethyl-octa-1,6-diene-3 -Ol, amyl alcohol, hexyl alcohol, 2-hexyl alcohol, heptyl alcohol, octyl alcohol, nonyl alcohol, 3-methyl-but-2-en-1-ol, 3-methyl-1-pentanol, cis-3 -Hexenol, cis-4-hexenol, benzyl alcohol, 1-phenylethanol, 2-phenyl- Ethanol, 2-phenoxy - ethanol, 2-methoxy-4-methyl - phenol, 4-methyl - phenol, anisyl alcohol, p- tolyl alcohol, residue of an alcohol R ¹ OH selected from the group consisting of vanillin and ethyl vanillin It can be.
Specifically, R ¹ is 2,6,10-trimethylundec-9-enal, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2. -Naphthalene, tridecanal, 2- [4- (1-methylethyl) phenyl] -ethanal, 4-carboxaldehyde-1,3,5-trimethyl-cyclohex-1-ene, 1-carboxaldehyde-4- ( 4-hydroxy-4-methylpentyl) -cyclohex-3-ene, 2,6-dimethyl-hept-5-enal, decanal, dec-9-enal, dec-4-enal, 2-methyldecanal, Undece-10-enal, undecanal, dodecanal, 2-methyl-undecanal, tridecanal, undece-9-enal, 3,7-dimethyl-octanal, di Drofarnesal, 7-hydroxy-3,7-dimethyl-octanal, 2,6-dimethyl-oct-5-enal, 2- [4- (1-methylethyl) phenyl] -ethanal, 3- (3- Isopropyl-phenyl) -butanal, 2- (3,7-dimethyloct-6-enoxy) -ethanal, 1-carboxaldehyde-4- (4-methyl-3-pentenyl) -cyclohex-3-ene, longiformaldehyde 2-methyl-4- (2,6,6-trimethylcyclohex-2-en-1-yl) -butanal, 2-methyl-3- (4-tert-butylphenyl) -propanal, 4- ( 1,1-dimethyl-ethyl) -benzene-propanal, 2- [4- (1-methyl-ethyl) -phenyl] -propanal, α-methyl-1,3- Nzodioxol-5-propanal, 3,7-dimethyl-oct-6-enal, 2-methyl-3- (4-isopropylphenyl) -propionaldehyde, 4- (4-hydroxy-4-methyl-pentyl) -cyclohexe -3-ene-1-carboxaldehyde, α-methyl-1,3-benzodioxole-5-propanal, 1-carboxaldehyde-4- (1,1-dimethylethyl) -cyclohexane, 4- (octahydro -4,7-methano-5H-indene-5-ylidene) -butanal, [(3,7-dimethyl-6-octenyl) -oxy] -acetaldehyde, 2-4-dimethyl-cyclohex-3-ene-1- Carboxaldehyde, 1-carboxaldehyde-2,4-dimethyl-cyclohex-3-ene, heptaner R, octanal, nonanal, 3,5,5-trimethylhexanal, 2-phenyl-propanal, 4-methyl-phenyl-acetaldehyde and 2,3,5,5-tetramethyl-hexanal aldehyde R It can be the enol form of ¹ HO.

Specifically, R ¹ is 2-heptyl-cyclopentanone, 2,2,6,10-tetramethyltricyclo- [5.4.0.0 (6,10)]-undecane-4. -One, benzylacetone, carvone, 1,2,3,5,6,7-hexahydro-1,1,2,3,3-pentamethyl-4H-inden-4-one, dimethyloctenone, 2- (butane -2-yl) -cyclohexanone, 2-hexyl-cyclopent-2-en-1-one, 2- (1-methylethyl) -5-methyl-cyclohexanone, 2- (2-methylethyl) -5-methyl- Cyclohexanone, 3-methyl-cyclopentadecanone, 4-tert-pentyl-cyclohexanone, 3-oxo-2-pentyl-cyclopentaneacetic acid methyl ester, 1- (1,2,3,4,5, 7,8 octahydro -2,3,8,8- tetramethyl-2-naphthalenyl) - ethanone and 3-methyl-5-propyl - cyclohex-2-en-1-ketone selected from the group consisting of on-R It can be the enol form of ¹ O.

R ¹ is preferably dessey 9-enyl, ethyl, 2-ethyl-4- (2,2,3-trimethyl-cyclopent-3-enyl) -but-2-enyl, 3-methyl-5- Phenyl-pentyl, 3- (3-isopropyl-phenyl) -but-1-enyl, 1-ethoxy-3- (3-isopropyl-phenyl) -butyl, 3- (4-tert-butyl-phenyl) -1 -Ethoxy-propyl, methyl, 3,7-dimethyl-oct-6-enyl, or phenethyl. More preferred are dessey 9-enyl, ethyl, 3,7-dimethyl-oct-6-enyl, and phenethyl.
R ³ and R ⁴ are preferably independently hydrogen, linear or branched C ₁ -C ₆ alkyl or C ₁ -C ₆ alkoxy residues, hydrogen or linear or branched C ₁ -C _6. More preferably, it is alkyl. R ³ and R ⁴ are independently more preferably hydrogen or linear or branched C ₁ -C ₄ alkyl, and even more preferably hydrogen or linear or branched C ₁ -C ₃ alkyl. Particularly preferred is hydrogen, methyl or ethyl, and most preferred is hydrogen.

The compound represented by the above formula I can be produced by using a known standard method as described in JP-A-2000-63328. For example, (E) -3- (2-hydroxy-phenyl) -2-methyl-acrylic acid ethyl ester, which is a compound represented by the above formula I, can be produced according to the following procedure.
To a solution of 75.0 g (carbethoxyethylidene) triphenylphosphorane in 350 ml toluene, 23.2 g salicylaldehyde is added dropwise at 20 ° C. while cooling in an ice bath. After stirring for 90 minutes at room temperature, the reaction mixture is diluted with toluene and washed with water until neutral. The organic phase was dried, filtered and evaporated to dryness. The resulting yellow oil is purified by chromatography to give 35.5 g of a colorless solid ((E) -3- (2-hydroxy-phenyl) -2-methyl-acrylic acid ethyl ester).
Although the compounding quantity of (A) component is not specifically limited, Preferably it is 0.0001 mass% or more with respect to the total mass of the processing agent composition for textiles, More preferably, it is 0.002-1 mass%, More preferably, it is 0. 0.01 to 0.1% by mass. When the blending amount of component (A) is 0.0001% by mass or more, an effect of suppressing generation of amine odor due to exposure to ultraviolet rays or the like can be expected. (A) The change of the quality of the fragrance of a product can be suppressed as the compounding quantity of a component is 1 mass% or less.

[Component (B)]
(B) component is mix | blended in order to provide the effect (namely, the original function of the processing agent for textile products) which gives a textile product the softness | flexibility (texture) to the textile agent processing agent composition.
The component (B) is “an amine having 1 to 3 hydrocarbon groups of 10 to 26 carbon atoms which may be separated by an ester group (—COO—) and / or an amide group (—NHCO—) in the molecule. A cationic surfactant which is “at least one compound selected from the group consisting of compounds, salts thereof and quaternized compounds thereof”.
17-26 are preferable and 18-24 are more preferable, as for carbon number of a C10-C26 hydrocarbon group (henceforth a "long-chain hydrocarbon group" in this specification). When the number of carbon atoms is 10 or more, the flexibility-imparting effect is good, and when it is 26 or less, the handling property of the treating agent composition for textiles is good.
The long chain hydrocarbon group may be saturated or unsaturated. When the long chain hydrocarbon group is unsaturated, the position of the double bond may be anywhere, but when there is one double bond, the position of the double bond is the long chain carbonization. It is preferably at the center of the hydrogen group or around the center.
The long chain hydrocarbon group may be a chain hydrocarbon group or a hydrocarbon group containing a ring in the structure, and is preferably a chain hydrocarbon group. The chain hydrocarbon group may be linear or branched. As the chain hydrocarbon group, an alkyl group or an alkenyl group is preferable, and an alkyl group is more preferable.

The long chain hydrocarbon group may be separated by an ester group (—COO—) and / or an amide group (—NHCO—). That is, the long-chain hydrocarbon group has at least one kind of splitting group selected from the group consisting of an ester group and an amide group in the carbon chain, and the carbon chain is split by the splitting group. May be. Having the splitting group is preferable from the viewpoint of improving biodegradability.
When it has this dividing group, the number of the dividing groups which one long-chain hydrocarbon group has may be one, or may be two or more. That is, the long chain hydrocarbon group may be divided at one place by a dividing group, or may be divided at two or more places. When having two or more splitting groups, each splitting group may be the same or different.
In addition, when a long chain hydrocarbon group has a splitting group in the carbon chain, the carbon atom which a splitting group shall count to the carbon number of a long chain hydrocarbon group.
The long-chain hydrocarbon group is usually an unhydrogenated fatty acid derived from beef tallow, which is used industrially, a fatty acid obtained by hydrogenation or partial hydrogenation of an unsaturated part, palm-derived palm oil, oil palm-derived It is introduced by using a hydrogenated fatty acid or fatty acid ester, or a fatty acid or fatty acid ester obtained by hydrogenation or partial hydrogenation of an unsaturated portion.
“Amine compounds having 1 to 3 hydrocarbon groups of 10 to 26 carbon atoms separated by an ester group (—COO—) or an amide group (—NHCO—) in the molecule (hereinafter referred to as“ The number of long-chain hydrocarbon groups in “sometimes referred to as“ amine compound ”” is 1 to 3. Preferably 2 (secondary amine compound) or 3 (tertiary amine compound), more preferably 3.

（式中、Ｒ^1a〜Ｒ^3aはそれぞれ独立に、炭素数１０〜２６の炭化水素基、−ＣＨ₂ＣＨ（Ｙ）ＯＣＯＲ^4a（Ｙは水素原子又はＣＨ₃であり、Ｒ^4aは炭素数７〜２１の炭化水素基である）、−（ＣＨ₂）_nＮＨＣＯＲ⁵（ｎは２又は３であり、Ｒ⁵は炭素数７〜２１の炭化水素基である）、水素原子、炭素数１〜４のアルキル基、−ＣＨ₂ＣＨ（Ｙ）ＯＨ（Ｙは水素原子又はＣＨ₃である）、又は、−（ＣＨ₂）_nＮＨ₂（ｎは２又は３である）であり、
Ｒ^1a〜Ｒ^3aのうちの少なくとも１つは、炭素数１０〜２６の炭化水素基、−ＣＨ₂ＣＨ（Ｙ）ＯＣＯＲ^4a及び／又は−（ＣＨ₂）_nＮＨＣＯＲ⁵である。） As an amine compound, the compound represented by the following general formula (B1) is mentioned.

(Wherein R ^{1a to} R ^3a are each independently a hydrocarbon group having 10 to 26 carbon atoms, —CH ₂ CH (Y) OCOR ^4a (Y is a hydrogen atom or CH ₃ , and R ^4a is 7 carbon atoms) to 21 hydrocarbon group is _{a), - (CH 2) n} NHCOR 5 (n is 2 or 3, R ⁵ is a hydrocarbon group having 7 to 21 carbon atoms), a hydrogen atom, 1 to carbon atoms 4 alkyl groups, —CH ₂ CH (Y) OH (Y is a hydrogen atom or CH ₃ ), or — (CH ₂ ) _n NH ₂ (n is 2 or 3);
At least one of R ^{1a to} R ^3a is a hydrocarbon group having 10 to 26 carbon atoms, —CH ₂ CH (Y) OCOR ^4a and / or — (CH ₂ ) _n NHCOR ⁵ . )

In the general formula (B1), the carbon number of the hydrocarbon group having 10 to 26 carbon atoms in R ^1a to R ^3a is preferably 17 to 26, 19 to 24 is more preferable. The hydrocarbon group may be saturated or unsaturated. The hydrocarbon group is preferably an alkyl group or an alkenyl group.
In the group “—CH ₂ CH (Y) OCOR ^4a ” in formula (B1), Y is preferably a hydrogen atom. R ^4a is a hydrocarbon group having 7 to 21 carbon atoms, preferably a hydrocarbon group having 15 to 19 carbon atoms. When the compound represented by the general formula (B1) R ^4a there are a plurality, R ^4a of the plurality of may be the same as each other, may be different.
Hydrocarbon group R ⁴ is a residue obtained by removing a carboxy group from a fatty acid having 8 to 22 carbon atoms (R ^4a COOH) (fatty acid residue), fatty acids as the under R ^4a (R ^4a COOH) is Saturated fatty acids or unsaturated fatty acids may be used, and straight-chain fatty acids or branched fatty acids may be used. Of these, saturated or unsaturated linear fatty acids are preferred. In order to impart good water absorption to the soft-treated garment, the saturated / unsaturated ratio (mass ratio) of the fatty acid that is the basis of R ^4a is preferably 90/10 to 0/100, and 90/10 to 40 / 60, more preferably 90/10 to 70/30.
When R ^4a is an unsaturated fatty acid residue, a cis isomer and a trans isomer are present, and the mass ratio of the cis isomer / trans isomer is preferably 40/60 to 100/0, and 70/30 to 90/10. Particularly preferred.

Specific examples of fatty acids used as R ^4a include stearic acid, palmitic acid, myristic acid, lauric acid, oleic acid, elaidic acid, linoleic acid, partially hydrogenated palm oil fatty acid (iodine value 10 to 60), Examples include partially hydrogenated beef tallow fatty acid (iodine value 10 to 60). Among them, a fatty acid prepared by combining two or more selected from stearic acid, palmitic acid, myristic acid, oleic acid, elaidic acid, and linoleic acid in predetermined amounts to satisfy the following conditions (a) to (c) It is preferable to use a composition.
(A) The ratio (mass ratio) of saturated fatty acid / unsaturated fatty acid is 90/10 to 0/100, more preferably 90/10 to 40/60, and particularly preferably 90/10 to 70/30.
(B) The ratio (mass ratio) of cis isomer / trans isomer is 40/60 to 100/0, more preferably 70/30 to 90/10.
(C) The fatty acid having 18 carbon atoms is 60 mass% or more, preferably 80 mass% or more, the fatty acid having 20 carbon atoms is less than 2 mass%, and the fatty acid having 21 to 22 carbon atoms is less than 1 mass%. .

In the group “— (CH ₂ ) _n NHCOR ⁵ ” in the general formula (B1), n is 2 or 3, and n is preferably 3.
R ⁵ is a hydrocarbon group having 7 to 21 carbon atoms, preferably a hydrocarbon group having 15 to 19 carbon atoms. When the compound represented by the general formula (B1) R ⁵ there are a plurality, may be R ⁵ of said plurality of mutually identical, may be different.
Specific examples of R ⁵ include the same as R ^4a .

In General Formula (B1), at least one of R ^{1a to} R ^3a is a long-chain hydrocarbon group (a hydrocarbon group having 10 to 26 carbon atoms, —CH ₂ CH (Y) OCOR ^4a and / or — (CH _{2) n} NHCOR ^5). Of R ^{1a to} R ^3a , two are preferably long-chain hydrocarbon groups.
When one or two of R ^{1a to} R ^3a are long-chain hydrocarbon groups, the remaining two or one are a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, —CH ₂ CH (Y). OH (Y is a hydrogen atom or CH ₃ ), or — (CH ₂ ) _n NH ₂ (n is 2 or 3), an alkyl group having 1 to 4 carbon atoms, —CH ₂ CH (Y) OH, or - (CH ₂₎ is preferably _n NH _2. Here, as a C1-C4 alkyl group, a methyl group or an ethyl group is preferable, and a methyl group is especially preferable. Y in —CH ₂ CH (Y) OH is the same as Y in —CH ₂ CH (Y) OCOR ^4a . _{N in} — (CH ₂ ) _n NH ₂ is the same as n in — (CH ₂ ) _n NHCOR ⁵ .

〔（Ｂ１−１）式中、Ｒ⁷及びＲ⁸はそれぞれ独立に、炭素数１０〜２６の炭化水素基である。（Ｂ１−２）〜（Ｂ１−８）の各式中、Ｒ⁹及びＲ¹⁰はそれぞれ独立に、炭素数７〜２１の炭化水素基である。〕 Preferable examples of the compound represented by the general formula (B1) include tertiary amine compounds represented by the following general formulas (B1-1) to (B1-8).

[In the formula (B1-1), R ⁷ and R ⁸ are each independently a hydrocarbon group having 10 to 26 carbon atoms. In the formulas (B1-2) to (B1-8), R ⁹ and R ¹⁰ are each independently a hydrocarbon group having 7 to 21 carbon atoms. ]

Examples of the hydrocarbon group for R ⁷ and R ⁸ include the same hydrocarbon groups as those having 10 to 26 carbon atoms for R ^{1a to} R ^3a in the general formula (B1).
Examples of the hydrocarbon group having 7 to 21 carbon atoms in R ⁹ and R ¹⁰ include those similar to the hydrocarbon group having 7 to 21 carbon atoms in R ^4a of the general formula (B1). 15 to 17 alkyl groups and alkenyl groups. Incidentally, when the R ⁹ there are a plurality in the formula, R ⁹ of the plurality of it may be the same as each other, may be different.

The component (B) of the present invention may be a salt of an amine compound. As the salt, a salt of a tertiary amine compound is preferable.
The salt of an amine compound can be obtained by neutralizing the amine compound with an acid. The acid used for neutralization of the amine compound may be an organic acid or an inorganic acid, and examples thereof include hydrochloric acid, sulfuric acid, and methyl sulfuric acid. Neutralization of the amine compound can be performed by a known method.
The component (B) may be a quaternized amine compound. As the quaternized product, a quaternized product of a tertiary amine compound is preferable.
A quaternized product of an amine compound is obtained by reacting the amine compound with a quaternizing agent. Examples of the quaternizing agent used for quaternizing the amine compound include alkyl halides such as methyl chloride and dialkyl sulfuric acids such as dimethyl sulfate. When these quaternizing agents are reacted with an amine compound, the alkyl group of the quaternizing agent is introduced into the nitrogen atom of the amine compound, and a salt of a quaternary ammonium ion and a halogen ion or a monoalkyl sulfate ion is formed. . The alkyl group introduced by the quaternizing agent is preferably an alkyl group having 1 to 4 carbon atoms, more preferably a methyl group or an ethyl group, and particularly preferably a methyl group. The quaternization of the amine compound can be performed by a known method.

As the compounds represented by the general formulas (B1) and (B1-1) to (B1-8), salts thereof and quaternized products thereof, commercially available products may be used, or those prepared by known methods may be used. May be.
For example, a compound represented by the general formula (B1-2) (hereinafter referred to as “compound (B1-2)”) and a compound represented by the general formula (B1-3) (hereinafter referred to as “compound (B1-3)”). composition comprising) that has a general formula (B1) of the column the fatty acid composition described in the R ^4a, or fatty acid methyl ester composition of the fatty acid is replaced with the methyl esters of the fatty acids in the fatty acid composition, methyl It can be synthesized by a condensation reaction with diethanolamine. At that time, from the viewpoint of improving flexibility, the abundance ratio represented by “compound (B1-2) / compound (B1-3)” is 99/1 to 50/50 in mass ratio. It is preferable to synthesize.
Furthermore, when the quaternized product is used, it is more preferable to use dimethyl sulfate as a quaternizing agent. At that time, from the viewpoint of imparting flexibility, the abundance ratio represented by “a quaternized compound (B1-2) / a quaternized compound (B1-3)” is 99/1 to 50/50 in mass ratio. It is preferable to synthesize so that

A compound represented by the general formula (B1-4) (hereinafter referred to as “compound (B1-4)”) and a compound represented by the general formula (B1-5) (hereinafter referred to as “compound (B1-5)”). And a compound represented by the general formula (B1-6) (hereinafter referred to as “compound (B1-6)”) is a fatty acid composition described in the R ⁴ column of the general formula (B1) or It can be synthesized by a condensation reaction between a fatty acid methyl ester composition and triethanolamine. In that case, the content ratio of each component with respect to the total mass of the compounds (B1-4), (B1-5) and (B1-6) is such that the compound (B1-4) is 1 to 60 from the viewpoint of imparting flexibility. Preferably, the compound (B1-5) is 5 to 98% by mass, the compound (B1-6) is 0.1 to 40% by mass, the compound (B1-4) is 30 to 60% by mass, the compound More preferably, (B1-5) is 10 to 55% by mass and compound (B1-6) is 5 to 35% by mass.
In addition, when using the quaternized product, it is more preferable to use dimethyl sulfate as a quaternizing agent in that the quaternization reaction proceeds sufficiently. The abundance ratio of each quaternized compound (B1-4), (B1-5) and (B1-6) is a mass ratio from the viewpoint of imparting flexibility, and the quaternized compound (B1-4) is 1 It is preferable that the quaternized product of compound (B1-5) is 5 to 98% by mass, the quaternized product of compound (B1-6) is 0.1 to 40% by mass, and the compound (B1- The quaternized product of 4) is 30 to 60% by mass, the quaternized product of compound (B1-5) is 10 to 55% by mass, and the quaternized product of compound (B1-6) is 5 to 35% by mass. More preferred.
In addition, when quaternizing the compounds (B1-4), (B1-5) and (B1-6), esteramine which is not quaternized generally remains after the quaternization reaction. At that time, the ratio of “quaternized product / non-quaternized ester amine” is preferably in the range of a mass ratio of 70/30 to 99/1.

A compound represented by the general formula (B1-7) (hereinafter referred to as “compound (B1-7)”) and a compound represented by the general formula (B1-8) (hereinafter referred to as “compound (B1-8)”) From the fatty acid composition described in the R ⁴ column of the general formula (B1) and the adduct of N-methylethanolamine and acrylonitrile, J. Org. Org. Chem. , 26, 3409 (1960), by a condensation reaction with N- (2-hydroxyethyl) -N-methyl-1,3-propylenediamine synthesized by a known method. In that case, it is preferable to synthesize | combine so that the abundance ratio represented by "compound (B1-7) / compound (B1-8)" may become 99/1-50/50 by mass ratio.
When the quaternized product is used, it is preferable to use methyl chloride as the quaternizing agent, which is represented by “a quaternized compound (B1-7) / a quaternized compound (B1-8)”. It is preferable to synthesize so that the existing ratio is 99/1 to 50/50 by mass ratio.

As the component (B),
At least one selected from the group consisting of the compound represented by the general formula (B1), a salt thereof, and a quaternized product thereof is preferable.
More preferably, at least one selected from the group consisting of the compounds represented by the general formulas (B1-1) to (B1-8), a salt thereof, and a quaternized product thereof,
More preferred is at least one selected from the group consisting of the compounds represented by formulas (B1-4) to (B1-6), salts thereof and quaternized products thereof.
In particular, a quaternized product of the compound represented by the general formula (B1-4), a quaternized product of the compound represented by (B1-5), and a quaternized product of the compound represented by (B1-6). It is preferable to use together.

As the component (B), one type of amine compound, a salt thereof or a quaternized product thereof may be used alone, or a mixture of two or more types, for example, general formulas (B1-4) to (B1-6) You may use as a mixture of the compound represented.
(B) Although the compounding quantity of a component is not specifically limited as long as it is the quantity which can achieve a compounding objective, Preferably it is 5-50 mass% with respect to the total mass of the processing agent composition for textiles, More preferably, 8-30. It is 10 mass%, More preferably, it is 10-20 mass%.

[Component (C)]
The component (C) is a compound having an amino group, a quaternary ammonium group, an amide bond or an imide bond other than the component (B). Such a compound decomposes to produce a substance that emits an amine odor, or itself emits an amine odor.
(C) A component may be used individually by 1 type and may be used as a mixture (composition) which consists of 2 or more types.
In the textile product treating agent composition of the present invention, the component (C) is blended for the purpose of imparting flexibility, deodorization / deodorization, antibacterial effect and the like to the fiber. Examples of the component (C) include amine odor substances used or generated during synthesis, and substances that emit amine odor substances by decomposition. In general, the problem of amine odor of a compound having an amino group, a quaternary ammonium group, an amide bond or an imide bond is remarkable at a high pH, but (based on a biodegradable cationic surfactant as a main base material) ) Even under low pH conditions as in softener compositions, amine odor can be generated due to long-term storage and the influence of ultraviolet rays.
The component (C) may have only one type of amino group, quaternary ammonium group, amide bond or imide bond, or may have two or more types.

As the compound having a quaternary ammonium group, at least one of the substituents on the nitrogen atom is an alkyl group having 2 or more carbon atoms and generates an amine in the presence of an alkaline substance or in an alkaline environment Is mentioned. Specific examples thereof include cationic polymers such as cationized cellulose, cationized guar gum, cationized dextran, alkylammonium salt homopolymers or copolymers of the monomers and other monomers.
Specifically, homopolymers of alkylammonium salts or copolymers of the monomers and other monomers include dimethyldiallylammonium chloride polymers such as MERQUAT100 (Nalco), and chlorides such as MERQUAT550 (Nalco). Examples thereof include dimethyldiallylammonium / acrylamide copolymer, dimethyldiallylammonium chloride / acrylic acid copolymer such as MERQUAT280 (Nalco).

（式中、Ｒ_aは炭素数７〜２１の炭化水素基を示し、Ｒ_b及びＲ_cは水素原子、低級アルキル基又は-(CH2CH2O)n-H（ｎは１〜１０の数を示す）を示す）
で表わされる化合物が挙げられ、該アミドはアルカリ条件下で、例えば、求核攻撃を経る加水分解により、アミンを生ずる。その具体例としては、モノ又はジエタノール脂肪酸アミド、モノイソプロパノールアミド等のアルカノールアミド等が挙げられる。 Examples of the compound having an amide bond include

(In the formula, R _a represents a hydrocarbon group having 7 to 21 carbon atoms, and R _b and R _c represent a hydrogen atom, a lower alkyl group, or — (CH 2 CH 2 O) nH (n represents a number of 1 to 10). )
Wherein the amide generates an amine under alkaline conditions, for example, by hydrolysis via a nucleophilic attack. Specific examples thereof include alkanolamides such as mono- or diethanol fatty acid amide and monoisopropanolamide.

（式中、Ｒは、それぞれ独立して、―Ｈ、―ＯＨ、−ＣＨ₃及び−Ｓｉ（ＣＨ₃）₃からなる群より選ばれ、Ｘは、―（ＣＨ₂）_a―ＮＨ₂、または、―（ＣＨ₂）_a―ＮＨ（ＣＨ₂）_bＮＨ₂であり（aは０〜３の整数であり、bは１〜３の整数である）、ｎは１〜１０，０００であり、ｍは１〜１０００である。）
で表される、側鎖Xにアミノ基を導入してなる化合物である。 Examples of the compound having an amino group include amino-modified silicone, ethanolamine, imidazolinium compound, betaine-type amphoteric compound, and sarcosinate.
In the softener composition, it is preferable to blend an amino-modified silicone for improving the flexibility of the textile product, a betaine-type amphoteric compound for deodorizing and deodorizing effects, and an imidazolium compound for imparting antibacterial properties.
Amino-modified silicone is a compound formed by introducing amino groups into both ends or side chains of a dimethyl silicone skeleton.
A preferred amino-modified silicone has the following general formula (C1):

Wherein R is independently selected from the group consisting of —H, —OH, —CH ₃ and —Si (CH ₃ ) ₃ , and X is — (CH ₂ ) _a —NH ₂ , or , — (CH ₂ ) _a —NH (CH ₂ ) _b NH ₂ (a is an integer of 0 to 3, b is an integer of 1 to 3), n is 1 to 10,000, m is 1-1000.)
And a compound formed by introducing an amino group into the side chain X.

Amino-modified silicones are preferably, 100～20000Mm kinematic viscosity at 25 ° C. ² / s, more preferably 500~10000mm ² / s. When the kinematic viscosity at 25 ° C. is in the range of 100 to 20000 mm ² / s, a high texture-imparting effect is obtained, and the manufacturability and handleability of the textile product treating agent composition are facilitated. The kinematic viscosity can be measured with an Ostwald viscometer.
The amino-modified silicone preferably has an amino equivalent of 400 to 8000 g / mol, more preferably 500 to 5000 g / mol, and still more preferably 1200 to 4000 g / mol. When the amino equivalent is in the range of 400 to 8000 g / mol, a sufficient blending effect can be obtained. The amino equivalent can be determined by dividing the weight average molecular weight of the amino-modified silicone by the number of nitrogen atoms contained in the amino-modified silicone. The number of nitrogen atoms can be determined by elemental analysis.
The amino-modified silicone may be in the form of oil (silicone oil), or may be in the form of an emulsion (silicone emulsion) emulsified by using a nonionic surfactant or a cationic surfactant as an emulsifier. It is preferably in the form of a silicone emulsion.
A commercially available amino-modified silicone can be used.
Examples of the silicone oil include those sold under the trade names: SF-8417, BY16-849, BY16-892, FZ-3785 or BY16-890 from Toray Dow Corning Co., Ltd., and Shin-Etsu Chemical Co., Ltd. Product names: KF-864, KF-860, KF-880, KF-8004, KF-8002, KF-867 or KF-869, KF-861, KF-8610, and the like.

Although the compounding quantity of (C) component is not specifically limited, Preferably it is 0.01-35 mass% with respect to the total mass of the processing agent composition for textiles, More preferably, it is 0.05-20 mass%, Most preferably It is 0.05-10 mass%. The preferred blending amount of the component (C) varies depending on the blending purpose and effect of the compound to be blended, but when the component (C) is an amino-modified silicone, the total amount of the fiber product treating agent composition (softener composition) is about 0.1-10 mass% is preferable. When the component (C) is an amino-modified silicone, more preferably 0.5 to 5% by mass, particularly preferably 1 to 3% by mass is present in the fiber product treatment composition (softener composition). Is preferred. When the blending amount of the amino-modified silicone is 0.1% by mass or more, the effect of improving the flexibility of the fiber product is appropriately obtained, and when the blending amount of the amino-modified silicone is 10% by mass or less, the treating agent for the textile product. Yellowing and raw material costs during storage of the composition (softener composition) can be suppressed.
The mass ratio of the component (C) to the component (A) ((C) / (A)) is preferably 2 to 3000, more preferably 10 to 1000, and still more preferably 20 to 250. When (C) / (A) is larger than 3000, the fragrance deterioration after storage becomes large and it becomes easy to feel a bad odor.

[(D) component]
The processing agent composition for textiles of this invention may contain a nonionic surfactant as (D) component.
As the nonionic surfactant, for example, those derived from polyhydric alcohols, higher alcohols, higher amines or higher fatty acids can be used.
The carbon chain portion of the nonionic surfactant may be branched or linear, and may be unsaturated. There may also be a distribution in the carbon chain. The carbon chain may be a short chain or a long chain, but preferably has 6 to 20 carbon atoms, more preferably 8 to 18 carbon atoms. When the carbon chain is a straight chain, those having 6 to 14 carbon atoms are preferred, more preferably 8 to 12, and most preferably 8 to 10. When the carbon chain is a branched chain, those having 6 to 18 carbon atoms are preferred, more preferably 9 to 18, and most preferably 13.
As the raw material, Exxal Chemical Exal, BASF LUTENSOL Series, Kyowa Hakko Kogyo Oxocol, Hoechst AG Genapol Series, Shell DOBANOL Series, and the like can be used. In particular, in the case of an alkylene oxide adduct of alcohol, a primary alcohol or a secondary alcohol can be used, but the use of a primary alcohol provides better dispersibility of the composition. The alcohol having 13 carbon atoms is produced, for example, using dodecene as a raw material, but the starting material may be butylene or propylene.
When the carbon chain of the nonionic surfactant contains an unsaturated group, the number of carbon atoms is particularly preferably 18, and the stereoisomeric structure of the unsaturated group may be a cis isomer or a trans isomer. Although a mixture may be sufficient, it is particularly preferable that the ratio of cis form / trans form is 25/75 to 100/0 (mass ratio).
When the nonionic surfactant includes an alkylene oxide, the alkylene oxide is preferably ethylene oxide (EO), but may be one obtained by adding propylene oxide (PO) or butylene oxide (BO) together with ethylene oxide. The average added mole number of EO is preferably 10 to 100 mol, more preferably 20 to 80 mol, and particularly preferably 40 to 70 mol. Moreover, 1-5 are suitable as an average addition mole number of PO or BO added with EO, More preferably, it is 1-3 mol. At this time, PO or BO may be added after adding EO, or EO may be added after adding PO or BO.

More specifically, for example, average EO9PO1 adduct of nonyl alcohol, average EO 40 mol adduct of primary isononyl alcohol, average EO 20 mol adduct of primary isodecyl alcohol, average EO 20 mol adduct of lauryl alcohol, primary isohexa Average EO 60 mol adduct of decyl alcohol, Average EO 60 mol adduct of primary isotridecyl alcohol, Average EO 50 mol adduct of tridecyl alcohol, Average EO 60 adduct of tallow alkyl amine, Average EO 60 adduct of tallow alkyl amine, Oleyl amine Average EO50 adduct, and lauric acid average EO20 mol adduct. Emulex series made by Nippon Emulsion, Emalmine series made by Sanyo Kasei, TDA series made by Lion Chemical, Esomin series, Softanol series made by Nippon Shokubai, LUTESOL series made by BASF, etc. can be used.
Although the compounding quantity of (D) component is not specifically limited, Preferably it is 0-10 mass% with respect to the total mass of the processing agent composition for textiles, More preferably, it is 0.1-8 mass%, More preferably, it is 0.8. 5 to 5% by mass. When a nonionic surfactant is blended, the emulsion dispersion stability of the oil-soluble component in the emulsion and the freeze-recovery stability of the emulsion are improved. When the blending amount of the nonionic surfactant is 10% by mass or less, an increase in the viscosity of the fiber product treating agent composition can be suppressed and the usability can be improved.

[(E) component]
In the fiber composition treating agent composition of the present invention, inorganic or organic water-soluble salts can be used for the purpose of controlling the viscosity. Specifically, calcium chloride, magnesium chloride, sodium chloride, sodium p-toluenesulfonate, and the like can be used, among which calcium chloride and magnesium chloride are preferable. These water-soluble salts can be blended in the fiber product treating agent composition in an amount of about 0 to 1% by mass, and may be blended in any step of the textile product treating agent composition production.

[(F) component]
In the treatment composition for textile products of the present invention, a preservative can be used to enhance the antiseptic and sterilizing power and maintain the antiseptic property during long-term storage.
Specific examples include isothiazolone-based organic sulfur compounds, benzisothiazolone-based organic sulfur compounds, benzoic acids, 2-bromo-2-nitro-1,3-propanediol, and the like.
Examples of isothiazolone organic sulfur compounds include 5-chloro-2-methyl-4-isothiazoline-3-one, 2-n-butyl-3-isothiazolone, 2-benzyl-3-isothiazolone, 2-phenyl-3-isothiazolone. 2-methyl-4,5-dichloroisothiazolone, 5-chloro-2-methyl-3-isothiazolone, 2-methyl-4-isothiazolin-3-one, or a mixture thereof. Among them, 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one are preferable, and 5-chloro-2-methyl-4-isothiazolin-3-one and 2- A mixture of methyl-4-isothiazolin-3-one is more preferred, and a mixture of about 77% by weight of the former and about 23% by weight of the latter is particularly preferred.
Examples of benzisothiazolone-based organic sulfur compounds include 1,2-benzisothiazoline-3-one, 2-methyl-4,5-trimethylene-4-isothiazolin-3-one, and dithio-2,2-bis ( Benzmethylamide) or a mixture thereof. Among these, 1,2-benzisothiazolin-3-one is particularly preferable.
Examples of benzoic acids include benzoic acid or a salt thereof, parahydroxybenzoic acid or a salt thereof, methyl paraoxybenzoate, ethyl paraoxybenzoate, propyl paraoxybenzoate, butyl paraoxybenzoate, benzyl paraoxybenzoate, and the like.
It is preferable that the compounding quantity of antiseptic | preservative in the processing agent composition for textiles of this invention is 0.0001-1 mass% with respect to the total amount of the processing agent composition for textiles. When the blending amount of the preservative is less than the lower limit, it is difficult to obtain the effect of adding the preservative, and when it exceeds the upper limit, the storage stability may be lowered.

[(G) component]
The processing agent composition for textiles of the present invention may contain ambroxane (AMBROXANE) as the component (G).
(G) The compounding quantity of a component becomes like this. Preferably it is 0.1-5000 ppm with respect to the total amount of the processing agent composition for textiles, More preferably, it is 0.1-1000 ppm, More preferably, it is 0.1-500 ppm.
The mass ratio (G) / (A) of the component (G) to the component (A) is preferably 0.01 to 60, more preferably 0.01 to 10, and further preferably 0.1 to 8. . When (G) / (A) is greater than 60, the odor quality change before and after storage increases, and when (G) / (A) is 0.01 or more, the amine odor suppression effect is more favorable. can get.

[(H) component]
The processing agent composition for textiles of the present invention may contain phenylethyl alcohol (PHENYL ETHYL ALCOHOL) as the component (H).
The amount of component (H) is preferably 0.1 to 5000 ppm, more preferably 0.1 to 1000 ppm, and still more preferably 0.1 to 500 ppm, based on the total amount of the treating agent composition for textile products.
The mass ratio of component (H) to component (A) ((H) / (A)) is preferably 0.01 to 60, more preferably 0.01 to 10, and still more preferably 0.1 to 8. . When (H) / (A) is greater than 60, the odor quality change before and after storage increases, and when (H) / (A) is 0.01 or more, the amine odor suppression effect is more favorable. can get.

[(I) component]
The processing agent composition for textiles of the present invention may contain a fragrance composition as the component (I). The perfume ingredients in the perfume composition are not particularly limited, but the list of perfume raw materials used can be found in various documents such as “Perfume and Flavor Chemicals”, Vol. Iand II, Steffen Arctander, Allured Pub. Co. (1994) and "Synthetic fragrance chemistry and commercial knowledge", Motoichi Into, Chemical Industry Daily (1996) and "Perfume and Flavor Materials of Natural Origin", Stephen Arctander, Allred Pub. Co. (1994) and "Encyclopedia of Scents", edited by Japan Fragrance Association, Asakura Shoten (1989) and "Performer Material Performance V.3.3", Boelens Aroma Chemical Information Service (1996) and "Flower oil". , Danute Lajaujis Anonis, Allured Pub. Co. (1993).
In addition to the component (G), the component (H), and the component (I), a capsule fragrance can be blended in the treatment composition for textile products of the present invention.

[Other optional ingredients]
The processing agent composition for textiles of the present invention may contain the following components in addition to the above components (A) to (I) as necessary, within a range not impairing the effects of the present invention. Good.
<Dye and / or pigment>
A dye and / or a pigment can be blended for the purpose of improving the appearance of the treating composition for textile products. Preferably, it is one or more of red and yellow water-soluble dyes selected from acidic dyes, and specific examples include acid yellow and acid red.
Specific examples of the dyes that can be added are described in the Dye Handbook (edited by the Society of Synthetic Organic Chemistry, published on July 20, 1970, Maruzen Co., Ltd.).
From the viewpoint of the storage stability of the fiber composition treating agent composition of the present invention and the dyeing property to fibers, the composition has at least one functional group selected from a hydroxyl group, a sulfonic acid group, an amino group, and an amide group in the molecule. An acid dye is preferable, and the amount thereof is preferably 1 to 50 ppm, more preferably 1 to 30 ppm, based on the entire composition.

<Water>
The treatment composition for textiles of the present invention is preferably an aqueous composition and preferably contains water.
As water, any of tap water, ion exchange water, pure water, distilled water, and the like can be used. Of these, ion-exchanged water is preferred.
Water is preferably blended in the fiber composition treating agent composition of the present invention in an amount of 50% by mass or more, more preferably 60% by mass or more. When the water content is equal to or higher than the lower limit, handling properties are good.

<Ultraviolet absorber>
In the treatment composition for textiles of the present invention, an ultraviolet absorber can be blended. An ultraviolet absorber is a chemical | medical agent with the effect which protects an ultraviolet-ray, it is a component which absorbs an ultraviolet-ray, converts into infrared rays, visible light, etc., and discharge | releases.
Examples of the ultraviolet absorber include aminobenzoic acid derivatives such as p-aminobenzoic acid, ethyl p-aminobenzoate, glyceryl p-aminobenzoate, and amyl p-dimethylaminobenzoate; ethylene glycol salicylate, dipropylene glycol salicylate , Salicylic acid derivatives such as octyl salicylate, myristyl salicylate; methyl diisopropylcinnamate, ethyl p-methoxycinnamate, isopropyl p-methoxycinnamate, p-methoxycinnamate-2-ethylhexyl, p-methoxycinnamic acid Cinnamic acid derivatives such as butyl; benzophenone derivatives such as 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and 2,2′-dihydroxy-4-methoxybenzophenone; urocanic acid, Ouro Examples include azole compounds such as ethyl kanate; 4-t-butyl-4′-methoxybenzoylmethane.

<Antimicrobial agent>
An antibacterial agent can be mix | blended in the processing agent composition for textiles of this invention. The antibacterial agent is a component having an effect of suppressing the growth of bacteria on the fiber and further suppressing the generation of an unpleasant odor derived from the degradation product of the microorganism.
Antibacterial agents include, for example, cationic fungicides such as quaternary ammonium salts (benzalkonium chloride, didecyldimethylammonium chloride), diclosan, triclosan, bis- (2-pyridylthio-1-oxide) zinc, polyhexa Examples include methylene biguanidine hydrochloride, 8-oxyquinoline, polylysine and the like.

<Others>
In addition to the above-mentioned compounds, antioxidants, reducing agents, emulsions such as polystyrene emulsion, opaque agents, function improvers for improving the stability of aroma and color tone in the treatment composition for textile products of the present invention. As deodorant base material, shrinkage prevention agent, washing wrinkle prevention agent, shape retention agent, drape retention retention agent, ironability improvement agent, oxygen bleach prevention agent, whitening agent, whitening agent, fabric softening clay, antistatic Agents, dye transfer inhibitors such as polyvinylpyrrolidone, polymer dispersants, soil release agents, scum dispersants, 4,4-bis (2-sulfostyryl) biphenyl disodium (Cino Pearl CBS-X manufactured by Ciba Specialty Chemicals), etc. Cellulase, amylase, fluorescent whitening agent, dye fixing agent, anti-fading agent such as 1,4-bis (3-aminopropyl) piperazine, stain remover, fiber surface modifier Enzymes such as rotase, lipase, and keratinase, foam suppressors, silk protein powders that can impart silk texture and functions such as moisture absorption and release, surface modification products thereof, emulsified dispersions, specifically K-50, K-30, K-10, A-705, S-702, L-710, FP series (Idemitsu Petrochemical), hydrolyzed silk solution (upper hair), Silken G Solvel S (Ichimaru Falcos), alkylene terephthalate and / or Alternatively, a nonionic polymer compound composed of an alkylene isophthalate unit and a polyoxyalkylene unit, for example, an antifouling agent such as FR627 manufactured by Kyoyo Chemical Industry, SRC-1 manufactured by Clariant Japan, and the like can be blended.

[PH]
The pH of the fiber product treating agent composition of the present invention is not particularly limited, but the pH is 1 to 6 for the purpose of suppressing hydrolysis of the ester group contained in the molecule of the component (A) accompanying storage aging. It is preferable to adjust to the range, and it is more preferable that the range is 2 to 4. For pH adjustment, hydrochloric acid, sulfuric acid, phosphoric acid, alkyl sulfuric acid, benzoic acid, p-toluenesulfonic acid, citric acid, malic acid, succinic acid, lactic acid, glycolic acid, hydroxyethanediphosphonic acid, phytic acid, ethylenediaminetetraacetic acid, PH adjustment of short chain amine compounds such as triethanolamine, diethanolamine, dimethylamine, N-methylethanolamine, N-methyldiethanolamine, alkali metal hydroxides such as sodium hydroxide, alkali metal carbonates, and alkali metal silicates An agent can be used.

[viscosity]
The viscosity of the fiber product treating agent composition of the present invention is not particularly limited, but is preferably less than 1000 mPa · s (B-type viscometer, manufactured by TOKIMEC, 25 ° C., the same applies hereinafter). Considering the increase in viscosity due to storage aging, the viscosity immediately after production is more preferably less than 800 mPa · s, and further preferably less than 500 mPa · s. When it is in such a range, the usability such as handling property at the time of loading into the washing machine is good.

[Production method]
The treatment composition for textile products of the present invention can be produced by a known method, for example, a method similar to the production method of a conventional treatment composition for textile products using a cationic surfactant as a main agent.
When the textile product treating agent composition of the present invention is a softener composition, its preparation method is not particularly limited, and a known method, for example, a conventional softener composition using a cationic surfactant as a main agent is used. It can be manufactured by the same method as the manufacturing method.
For example, an emulsion obtained by mixing an oil phase containing (A) component, (B) component and (C) component and an aqueous phase containing (F) component under a temperature condition higher than the melting point of (B) component. And then, if necessary, can be produced by adding and mixing other components to the obtained emulsion. Component (C) may be added after mixing the oil phase and the aqueous phase to obtain an emulsion.

[Use / How to use]
Although the use of the treatment composition for textile products of the present invention is not particularly limited, it can be applied to a cleaning composition, a bleaching composition, a softener composition, a spray-type fiber treatment agent, and the like. Among them, it is preferable to apply as a softener composition. The method for treating a fiber product with the fiber product treatment composition of the present invention is not particularly limited, and conventionally known detergents, finishes (softeners, softeners, It can be carried out in the same manner as a paste-type fiber treatment agent and the like.
The textile product that can be treated with the treating composition for textile products of the present invention is not particularly limited, and examples thereof include clothing, curtains, sofas, carpets, towels, handkerchiefs, sheets, and macula covers. The material may also be natural fibers such as cotton, silk, and wool, or chemical fibers such as polyester.
When the treatment composition for textiles of the present invention is a liquid softener composition, the treatment method for textiles such as clothing is not particularly limited, and can be treated in the same manner as conventionally known softeners. For example, in the rinsing stage of washing, the composition of the present invention is dissolved in water for treatment, or the composition of the present invention is dissolved in water using a container such as a tub, and further garments are added to the immersion treatment. In this case, it is used after diluting to an appropriate concentration. In that case, the bath ratio (weight ratio of the treatment liquid to the textile product) is preferably 3 to 100 times, particularly preferably 5 to 50 times. Specifically, when the flexible treatment is performed, the concentration of the component (B) is preferably used in an amount that is 0.01 ppm to 1000 ppm, more preferably 0.1 ppm to 300 ppm, with respect to the total amount of water used. Used in such an amount.

  EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited to this. In the examples, the component blending amounts are all expressed by mass% (in terms of pure content, unless otherwise specified).

[(A) component]
The following A-1 and A-17 were synthesized and used according to the description in JP-A-2000-63328.
A-1: (E) -3- (2-hydroxyphenyl) -acrylic acid dessey 9-enyl ester (compound described in paragraph No. 0040 of JP-A-2000-63328)

A-2: (E) -3- (2-hydroxy-5-methyl-phenyl) -acrylic acid ethyl ester (compound described in paragraph No. 0038 of JP-A-2000-63328)

A-3: (E) -3- (2-hydroxy-phenyl) -acrylic acid 2-ethyl-4- (2,2,3-trimethyl-cyclopent-3-enyl) -but-2-enyl Esters (compounds described in paragraph No. 0041 of JP-A-2000-63328)

A-4: (E) -3- (2-hydroxy-5-methyl-phenyl) -acrylic acid 2-ethyl-4- (2,2,3-trimethyl-cyclopent-3-enyl) -bute 2-enyl ester (compound described in paragraph No. 0042 of JP-A-2000-63328)

A-5: (E) -3- (2-hydroxy-5-methyl-phenyl) -acrylic acid 3-methyl-5-phenyl-pentyl ester (compound described in paragraph No. 0043 of JP-A-2000-63328)

A-6: (E) -3- (4-diethylamino-2-hydroxy-phenyl) -but-2-enoic acid dec-9-enyl ester (described in paragraph No. 0044 of JP-A-2000-63328) Compound)

A-7: (E) -3- (4-diethylamino-2-hydroxy-phenyl) -but-2-enoic acid 3-methyl-5-phenyl-pentyl ester (paragraph number 0045 of JP-A-2000-63328) Compounds described in)

A-8: (E) -3- [2- (tert-butyl-dimethyl-silanioloxy) -phenyl] -acrylic acid tert-butyl-dimethyl-silyl ester (described in paragraph No. 0046 of JP-A-2000-63328) Compound)

A-9: (E) -3- (2-hydroxy-phenyl) -acrylic acid 3- (3-isopropyl-phenyl) -but-1-enyl ester (described in paragraph No. 0048 of JP-A-2000-63328) Compound)

A-10: (E) -3- (2-hydroxy-phenyl) -acrylic acid 1-ethoxy-3- (3-isopropyl-phenyl) -butyl ester (described in paragraph No. 0051 of JP-A-2000-63328) Compound)

A-11: (E) -3- (2-hydroxy-phenyl) -acrylic acid 3- (4-tert-butyl-phenyl) -1-ethoxy-propyl ester (see paragraph No. 0052 of JP-A-2000-63328) Described compounds)

A-12: (E) -3- (2-hydroxy-phenyl) -2-methyl-acrylic acid ethyl ester (compound described in paragraph No. 0030 of JP-A-2000-63328)

A-13: (E) -3- (2-hydroxy-phenyl) -2-methyl-acrylic acid methyl ester (compound described in paragraph 0031 of JP-A-2000-63328)

A-14: (E) -3- (2-hydroxy-phenyl) -2-methyl-acrylic acid ethyl ester (compound described in paragraph No. 0032 of JP-A-2000-63328)

A-15: (E) -3- (2-hydroxy-phenyl) -2-methyl-acrylic acid 3,7-dimethyl-oct-6-enyl ester (described in paragraph No. 0034 of JP-A-2000-63328) Compound)

A-16: (E) -3- (2-hydroxy-phenyl) -2-methyl-acrylic acid phenethyl ester (compound described in paragraph No. 0035 of JP-A-2000-63328)

A-17: 3- (4-diethylamino-2-hydroxy-phenyl) -but-2-enoic acid ethyl ester (compound described in paragraph No. 0036 of JP-A-2000-63328)

[Component (B)]
The following B-1 to B-3 were used.
B-1: Cationic surfactant (compound described in Example 4 of JP2003-12471) B-1 is represented by the general formulas (B1-4), (B1-5) and (B1-6) And a compound obtained by quaternizing a compound (wherein R ⁹ is an alkyl group or alkenyl group having 15 to 17 carbon atoms) with dimethyl sulfate.

B-2: cationic surfactant (manufactured by Stepan, trade name: Stepantex SE-88)
B-2 is a compound represented by the general formulas (B1-4), (B1-5) and (B1-6) (in each formula, R ⁹ is an alkyl or alkenyl group having 15 to 17 carbon atoms). ) Is quaternized with dimethyl sulfate.

-B-3: Cationic surfactant (made by Tonan Gosei Co., Ltd., trade name: HITEX RO16E)
B-3 is a compound represented by the general formulas (B1-4), (B1-5) and (B1-6) (in each formula, R ⁹ is an alkyl group or alkenyl group having 15 to 17 carbon atoms). ) Is quaternized with dimethyl sulfate.

[Component (C)]
The following C-1 to C-6 were used.
C-1: X52-8369 (manufactured by Shin-Etsu Chemical) amino-modified silicone C-2: KF-864 (manufactured by Shin-Etsu Chemical) amino-modified silicone C-3: KF-869 (manufactured by Shin-Etsu Chemical) amino-modified Silicone C-4: SM8904 (manufactured by Toray Dow Corning) Amino-modified silicone C-5: MERQUAT100 (manufactured by Nalco) polydimethyldiallylammonium chloride C-6: Lipomin APA168-65E (manufactured by Toho Chemical) Stearic acid Dimethylaminopropylamide ethanol

[(D) component]
The following D-1 to D-6 were used.
D-1: EO 60 mol adduct of isotridecyl alcohol (TA600-75, manufactured by Lion Chemical Co.)
D-2: polyoxyethylene lauryl ether EO 40 mol (TA400-75, manufactured by Lion Chemical Co.)
D-3: 60 mol of polyoxyethylene isotridecyl ether EO (exoxide 13 manufactured by Exxon Mobil Co., 60 mol of ethylene oxide (EO) added)

[(E) component]
The following E-1 was used.
E-1: Calcium chloride (Wako Pure Chemical Industries, Ltd.)

[(F) component]
The following F-1 was used.
F-1: isothiazolone solution (Caisson CG / ICP, manufactured by Rohm & Haas)

[(G) component] to [(I) component]
The following G-1, H-1, and I-1 were used.
G-1: Ambroxan H-1 Phenyl ethyl alcohol I-1 Fragrance composition described in Table 1 below

[Method for preparing treatment composition for textile products]
Using a glass container having an inner diameter of 100 mm and a height of 150 mm and a stirrer (Agitator SJ type, manufactured by Shimadzu Corporation), the blending amounts of the respective components are adjusted as described in Examples and Comparative Examples shown in Tables 2 to 4 below. A liquid softener composition was prepared by the following procedure.
-Example using (C-1), (C-4), (C-5) component (A) component, (B) component, (D) component, (G) component, (H) component, (I) ) Ingredients were mixed and stirred to obtain an oil phase mixture. On the other hand, the component (F) was dissolved in ion-exchange water for balance to obtain an aqueous phase mixture. Here, the balance of the ion-exchange water for balance is the balance obtained by subtracting the total amount of the oil phase mixture, the component (E), the component (C-1), the component (C-4), and the component (C-5) from 980 g. It corresponds to.
Next, the oil phase mixture heated above the melting point of the component (B) is placed in a glass container and stirred, and the aqueous phase mixture heated above the melting point of the component (B) is added in two portions. And stirred. Here, the split ratio of the aqueous phase mixture was 30:70 (mass ratio), and the stirring was performed at a rotational speed of 1,500 rpm for 3 minutes after the first aqueous phase mixture addition and for 2 minutes after the second aqueous phase mixture addition. It was. Thereafter, component (E) and then component (C) were added. The component (E) was dissolved in ion-exchanged water before addition and used as a 30% wt aqueous solution. If necessary, hydrochloric acid (reagent 1 mol / L, Kanto Chemical) or sodium hydroxide (reagent 1 mol / L, Kanto Chemical) is added in an appropriate amount to adjust the pH to 3, and the total mass is further adjusted to 1,000 g. Ion exchange water was added so that the desired softener composition was obtained.

-Example using (C-2), (C-3), (C-4) component (A) component, (B) component, (C) component, (D) component, (G) component, (H ) Component and (I) component were mixed and stirred to obtain an oil phase mixture. On the other hand, the component (F) was dissolved in ion-exchange water for balance to obtain an aqueous phase mixture. Here, the mass of the ion-exchange water for balance is equivalent to the remainder obtained by subtracting the total amount of the oil phase mixture and the component (E) from 980 g.
Next, the oil phase mixture heated above the melting point of the component (B) is placed in a glass container and stirred, and the aqueous phase mixture heated above the melting point of the component (B) is added in two portions. And stirred. Here, the split ratio of the aqueous phase mixture was 30:70 (mass ratio), and the stirring was performed at a rotational speed of 1,500 rpm for 3 minutes after the first aqueous phase mixture addition and for 2 minutes after the second aqueous phase mixture addition. It was. Thereafter, the component (E) was added. The component (E) was dissolved in ion-exchanged water before addition and used as a 30% wt aqueous solution. If necessary, hydrochloric acid (reagent 1 mol / L, Kanto Chemical) or sodium hydroxide (reagent 1 mol / L, Kanto Chemical) is added in an appropriate amount to adjust the pH to 3, so that the total mass becomes 1,000 g. Ion-exchanged water was added to the desired softener composition. Each liquid softening agent composition obtained had a viscosity (B-type viscometer) at 25 ° C. of 10 to 250 mPa · s.
The numerical value of each component of (A)-(I) in the Example and the comparative example shown by the following Tables 2-4 is the compounding quantity (mass%) with respect to the total mass of a liquid softening agent composition.
In addition, “C / A” in Examples and Comparative Examples shown in Tables 2 to 4 below indicates a ratio of “mass of (C) component” to “mass of (A) component”. The same applies to “G / A” and “H / A”.

[Evaluation method]
80 mL of the fiber composition treating agent composition prepared as described above was put in a PE container, wrapped in aluminum foil in triplicate, and then left outdoors or in a dark 25 ° C. thermostatic bath for 2 weeks. The outdoor UV integrated amount was 20MJ.
<Aroma evaluation of sun exposure products>
As described above, the fragrance of the treatment composition for textile products stored outdoors is evaluated by the following evaluation criteria by 5 panelists using a 25 ° C. storage sample as a reference product. Judged by. In the value of the product, △ or more was regarded as acceptable. The results are shown in Tables 2 to 4 below.
<Evaluation criteria>
1 point: No odor, no change compared to the control 2 points: No odor, no change, slightly different from the control 3 points: No odor, no change, 4 changes: odor There is a great change compared to the control <Criteria>
A: Less than 1 to 1.5 ○: Less than 1.5 to 2.5 Δ: Less than 2.5 to 3.5 x: 3.5 to 4

Claims (1)

Textile treatment composition containing the following components (A) to (C):
(A) Compound represented by Formula I

(Where
A is a benzene ring or a naphthalene ring;
R ¹ is a saturated or unsaturated, linear or branched alicyclic or aromatic C ₁₀ -C ₃₀ hydrocarbon residue; one or more O and / or C (O) groups and / or alkoxy groups A saturated or unsaturated, linear or branched alicyclic or aromatic C ₁₀ -C ₃₀ hydrocarbon residue; or —Si (C ₁ -C ₆ alkyl) ₃ ; or R ¹ is nonyl alcohol, 3,5,5-trimethyl-hexanol, cis-6-nonenol, 2,6-nonadien-1-ol, 2-phenylpropanol, 3-phenylpropanol, 2- (2-methylphenyl) Ethanol, cinnamyl alcohol, ethyl vanillin, 4-isopropyl-cyclohexanol, 3,3,5-trimethyl-cyclohexanol, 2-cyclohexyl-propanol, and 2,6-dimethyl The residue of an alcohol R ¹ OH selected from lu-heptan-2-ol;
R ² in the 2- or 3-position is hydrogen or a methyl group;
R ³ and R ⁴ are hydrogen, a linear or branched C ₁ -C ₆ alkyl or C ₁ -C ₆ alkoxy residue, a 5-membered heterocyclic residue containing N and / or O atoms, or C _1- 5-membered heterocyclic residues substituted by C ₆ aliphatic and / or aromatic substituents, —OH, —NO ₂ , —NH ₂ , —N (C ₁ -C ₆ alkyl) ₂ , —N (hydroxyC ₁ -C ₆ alkyl) _2, be a -NHCO ₂ CH ₃ or -NH (heterocycle);
R ² , R ³ and R ⁴ are the same or different groups;
X represents —OH, —NHR ₆ or —OSi (C ₁ -C ₆ alkyl) ₃ , R ₆ is hydrogen, saturated or unsaturated, linear or branched C ₁ -C ₂₀ hydrocarbon or any An aromatic or heterocyclic residue substituted with
The acrylic double bond is in the E configuration),
(B) an amine compound having 1 to 3 hydrocarbon groups having 10 to 26 carbon atoms in the molecule, which may be separated by an ester group (—COO—) and / or an amide group (—NHCO—), At least one compound selected from the group consisting of a salt and a quaternized product thereof, and (C) a compound having an amino group, a quaternary ammonium group, an amide bond or an imide bond (excluding component B).