JP2017144714A - Easily peelable laminate - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a package having an easily peelable layer having such advantages as to be obtained at low cost.SOLUTION: There is provided an easily peelable laminate 10a which has a first substrate layer 2 and an easily peelable layer 4 existing on the first substrate layer 2, where the easily peelable layer 4 is an amorphous polyester layer having a glass transition temperature of 25°C or lower, the first substrate layer 2 is a resin layer or a metal layer made of a single layer or a laminate having at least a resin layer or a metal layer, and the resin layer or the metal layer comes in contact with the easily peelable layer 4.SELECTED DRAWING: Figure 1

Description

  The present invention relates to an easily peelable laminate.

  As a package body such as a lid member and a bag body, a package body including at least two layers of an outer layer and an inner layer that is detachably stacked on the outer layer is used. In this laminate, usually, by providing an easily peelable layer at the interface between the outer layer and the inner layer, these are easily peeled off, and by peeling at least a part (peeling portion) of the outer layer, The inner layer can be exposed. Various configurations have been disclosed as materials constituting the easily peelable layer.

  Patent Document 1 discloses the use of a mixed resin layer formed of a mixed resin in which a polyolefin and a cyclic olefin copolymer are blended at a predetermined ratio as one aspect of the easily peelable layer. In Patent Document 1, the interface between the mixed resin layer and the polyester film layer laminated in contact with the mixed resin layer is a release surface.

  In patent document 2, as one aspect | mode of an easily peelable layer, using a peeling varnish layer between the sealing varnish layer and a polyethylene layer is disclosed. In Patent Document 2, the interface between the release varnish layer and the polyethylene layer is the release surface.

JP 2007-320580 A JP 2012-05640 A

  When the easily peelable layer of Patent Document 1 is used, it is necessary to increase the layer thickness to about 20 μm, which increases the cost. Moreover, in order to keep the peel strength with high accuracy, it is necessary to precisely adjust the kneading conditions and the extrusion conditions.

  Moreover, when using the easily peelable layer of Patent Document 2, the peelable varnish layer itself, which is an easily peelable layer, has no adhesiveness and it is necessary to provide a separate adhesive layer, and the adhesive strength is adjusted by the application pattern of the peelable varnish. In this method, easy peeling is realized. However, since the cost of the adhesive layer and the cost of the coating process are large in this method, the cost of the package increases as a result.

  Further, depending on the use of the package, it may be necessary to be able to reseal (reseal) after the outer layer is peeled off.

  Furthermore, when the package is used for food and drink, depending on the location where the outer layer is peeled off, the food and drink may adhere to the location, or the user may directly attach the mouth to the location. There is also a need to consider the hygiene of the materials used in the process.

  Therefore, there is a need to provide a package having an easily peelable layer having advantages such as being obtained at low cost.

As a result of intensive studies, the present inventors have found that the above problems can be solved by the following means, and have completed the present invention. That is, the present invention is as follows:
<1> An easy peelable laminate comprising a first base material layer and an easy peelable layer present on the first base material layer,
The easily peelable layer is a layer of amorphous polyester having a glass transition temperature of 25 ° C. or lower.
Easy peelable laminate.
<2> The second base material layer further including a second base material layer that is present on the side where the first base material layer is not present of the easily peelable layer. Is a resin layer or metal layer that is a single layer, or a laminate having at least a resin layer or a metal layer, and the resin layer or the metal layer is in contact with the easily peelable layer,
The easily peelable laminate according to <1> above.
<3> The easily peelable laminate is cut into a rectangle of 25 mm × 150 mm, and the second base material layer is peeled from the first base material layer to the long side direction at 300 mm / min from the first base material layer. The easy peeling according to the above <2>, wherein the average peeling strength at a peeling length of 10 to 30 mm is 0.3 N / 25 mm to 4.5 N / 25 mm when peeled by 180 ° under the condition of a length of 35 mm Laminate.
<4> The easily peelable laminate according to any one of <1> to <3>, wherein the easily peelable layer is present in an amount of 4.0 g / m ² or less.
<5> The easily peelable laminate according to any one of <1> to <4>, wherein the amorphous polyester has a glass transition temperature of −50 ° C. or higher.
<6> The above <1> to <5>, wherein the amorphous polyester has a number average molecular weight of 100,000 or less as measured by gel permeation chromatography with a tetrahydrofuran solvent and polystyrene standard. The easily peelable laminate according to any one of the items.
<7> The above <1> to <6>, wherein the first and / or second base material layer further includes a sealant layer as a layer not in contact with the easily peelable layer of the outermost layer. The easily peelable laminate according to any one of the items.
<8> The easily peelable laminate according to any one of <2> to <7>, wherein the first and / or second base material layer has a half cut line.
<9> The second base material layer further present on the side where the first base material layer is not present of the easily peelable layer,
The second base material layer is a single layer resin layer or metal layer, or a laminate having at least a resin layer or metal layer, and the resin layer or metal layer is the easily peelable layer. In contact with
A peeling tab for peeling the second base material layer from the easy peeling layer; and the second base material layer and the easy peeling layer of the peeling tab. Having a release agent layer in at least a part of the area between,
The easily peelable laminate according to any one of <1> to <8> above.
<10> The second easily peelable layer is further provided with a second base material layer that is present on the side where the first base material layer is not present,
The second base material layer is a single layer resin layer or metal layer, or a laminate having at least a resin layer or metal layer, and the resin layer or metal layer is the easily peelable layer. In contact with
From the easily peelable layer, it has a peeling tab for peeling the second base material layer,
The peeling tab and the other part of the easily peelable laminate are delimited by a half-cut line for peeling trigger that is engraved from the first base material layer side or the second base material layer side. And has a release agent layer between the second base material layer and the easily peelable layer so as to surround the half-cut line for peeling trigger,
The easily peelable laminate according to any one of <1> to <8> above.
<11> A lid material having the easily peelable laminate according to any one of the above items <1> to <10>.
<12> A lid for instant food,
It further comprises a second base material layer present on the side where the first base material layer is not present of the easily peelable layer,
The second base material layer is a single layer resin layer or metal layer, or a laminate having at least a resin layer or metal layer, and the resin layer or metal layer is the easily peelable layer. In contact with
One of the first and second base material layers is an inner layer, and the other is an outer layer,
The inner layer has an opening inner layer half cut line that exists so as to define a partial region of the inner layer, and a part of the inner layer when the outer layer is peeled from the inner layer The region is separated from the outer layer together with other parts of the inner layer, and an opening is formed in the inner layer.
The lid material according to <11> above.
<13> A packaging bag having the easily peelable laminate according to any one of <1> to <10> above.
<14> A packaging bag containing contents,
The easily peelable layer further comprises a second base material layer present on the side where the first base material layer does not exist, and the second base material layer is a single layer. It is a laminate having at least a resin layer or a metal layer, or a resin layer or a metal layer, and the resin layer or the metal layer is in contact with the easily peelable layer,
One of the first and second base material layers is an inner layer, and the other is an outer layer,
The inner layer has an opening inner layer half cut line that exists so as to define a partial region of the inner layer, and a part of the inner layer when the outer layer is peeled from the inner layer The region is separated from the outer layer together with other parts of the inner layer, and an opening is formed in the inner layer.
The packaging bag as described in <13> above.
<15> Applying a solution of amorphous polyester to the first base material layer, and drying the solution of amorphous polyester to form an easily peelable layer,
Including
The amorphous polyester has a glass transition temperature of 25 ° C. or less,
Manufacturing method of easily peelable laminate.
<16> The method according to <15>, further comprising pressing the second base material layer on the easily peelable layer.
<17> The method according to <16>, further comprising applying a release agent to the second base material layer.

  ADVANTAGE OF THE INVENTION According to this invention, the package which has an easily peelable layer which has advantages, such as being obtained at low cost, can be provided.

FIG. 1 is a diagram showing a layer structure of an easily peelable laminate according to the present invention. FIG. 2 is an explanatory view of 180 ° peeling. FIG. 3 is a diagram showing a layer structure of the easily peelable laminate of the present invention having a peeling tab and a release agent layer. FIG. 4 is a diagram showing a layer configuration of the easily peelable laminate of the present invention having a peeling tab, a release agent layer, and a half-cut line for peeling trigger. FIG. 5 is a diagram illustrating an example of a release agent layer formation region. FIG. 6 is a top view and a side sectional view of an embodiment of the lid member of the present invention. Fig.6 (a) is a top view of the cover material of this invention, FIG.6 (b) is side surface sectional drawing when the 1st base material layer of the cover material of this invention is peeled. 7 is a top view and a side cross-sectional view of another embodiment of the lid of FIG. Fig.7 (a) is a top view of the cover material of this invention, FIG.7 (b) is side surface sectional drawing when the 1st base material layer of the cover material of this invention is peeled. FIG. 8 is a top view and a side sectional view of another embodiment of the lid member of the present invention. Fig.8 (a) is a top view of the cover material of this invention, FIG.8 (b) is side surface sectional drawing when the 1st base material layer of the cover material of this invention is peeled. 9 is a top view and a side cross-sectional view of another embodiment of the lid of FIG. Fig.9 (a) is a top view of the lid | cover material of this invention, FIG.9 (b) is side surface sectional drawing when the 1st base material layer of the lid | cover material of this invention is peeled. FIG. 10 is a view showing an embodiment of the packaging bag of the present invention. 10 (a) is a side sectional view of one embodiment of the packaging bag of the present invention, and FIG. 10 (b) is a top view of one embodiment of the packaging bag of the present invention, FIG. 10 (c). These are side surface sectional views when the 1st base material layer is peeled of one embodiment of the packaging bag of the present invention. FIG. 11 is a diagram showing another embodiment of the packaging bag of FIG. 11 (a) is a side sectional view of one embodiment of the packaging bag of the present invention, and FIG. 11 (b) is a top view of one embodiment of the packaging bag of the present invention, FIG. 11 (c). These are side surface sectional views when the 1st base material layer is peeled of one embodiment of the packaging bag of the present invention. FIG. 12 is a view showing another embodiment of the packaging bag of the present invention. Fig. 12 (a) is a side cross-sectional view of another embodiment of the packaging bag of the present invention, and Fig. 12 (b) is a top view of another embodiment of the packaging bag of the present invention. c) It is side surface sectional drawing when the 1st base material layer is peeled of another embodiment of the packaging bag of this invention. FIG. 13 is a view showing another embodiment of the packaging bag of FIG. 13 (a) is a side cross-sectional view of another embodiment of the packaging bag of the present invention, FIG. 13 (b) is a top view of another embodiment of the packaging bag of the present invention, and FIG. c) It is side surface sectional drawing when the 1st base material layer is peeled of another embodiment of the packaging bag of this invention. FIG. 14 is a view showing a further embodiment of the packaging bag of the present invention. 14 (a) is a cross-sectional view of a further embodiment of the packaging bag of the present invention, taken along line XX ′ of FIG. 14 (b), and FIG. 14 (b) is a further illustration of the packaging bag of the present invention. 14 (c) is a cross-sectional view of a further embodiment of the packaging bag of the present invention, taken along line YY ′ of FIG. 14 (b), and FIG. 14 (d). These are sectional drawings in line YY 'of Drawing 14 (b) when the 1st substrate layer is exfoliated of the further embodiment of the packaging bag of the present invention. FIG. 15 is a diagram showing another embodiment of the packaging bag of FIG. Fig. 15 (a) is a cross-sectional view of a further embodiment of the packaging bag of the present invention, taken along line XX 'of Fig. 15 (b), and Fig. 15 (b) is a further illustration of the packaging bag of the present invention. 15 (c) is a cross-sectional view of a further embodiment of the packaging bag of the present invention, taken along line YY ′ of FIG. 15 (b), and FIG. 15 (d). These are sectional drawings in line YY 'of Drawing 15 (b) when the 1st substrate layer is exfoliated of the further embodiment of the packaging bag of the present invention. FIG. 16 is a diagram showing an embodiment of a method for producing an easily peelable laminate according to the present invention.

<Easily peelable laminate>
As shown to Fig.1 (a), the easily peelable laminated body (10a) of this invention exists easily on the 1st base material layer (2) and the 1st base material layer (2). A peelable layer (4) is provided. This easily peelable layer is a layer of amorphous polyester having a glass transition temperature of 25 ° C. or lower.

  The first base material layer can be a resin layer or a metal layer that is a single layer, or a laminate having at least a resin layer or a metal layer. In particular, the layer in contact with the easily peelable layer of the first base material layer can be a resin layer or a metal layer.

  In the case where the amorphous polyester layer having a glass transition temperature of 25 ° C. or less is used as an easily peelable layer, the present inventors have a thin film thickness, particularly when this is pressure-bonded to a resin layer or a metal layer. It was found that moderately easy peelability can be realized, and as a result, the cost of the package can be reduced. Although not wishing to be bound by theory, it is believed that this is due to the high affinity between the amorphous polyester and the resin and metal. In addition, since the amorphous polyester has an extremely low elution to food and drink, the easily peelable laminate of the present invention is particularly useful when used for a food and drink package.

  In particular, in one embodiment of the present invention, the easily peelable laminate is cut into rectangles of 25 mm × 150 mm, the second base material layer is cut from the first base material layer to the long side direction from the short side, The average peel strength at a peel length of 10 to 30 mm when peeled by 180 ° under the conditions of 300 mm / min and peel length of 35 mm can be 0.3 N / 25 mm to 4.5 N / 25 mm.

  More specifically, first, the easily peelable laminate is cut into 25 mm × 150 mm rectangular samples, and the second base material layer is peeled 35 mm from the short side to the long side. Next, as shown in FIG. 2, the first base material layer (2) side and the second base material layer (6) side of the peeled portion are paired with a pair of gripping tools (14a) facing each other of the measuring machine. 14b), and peeled 180 ° from the short side to the long side in the direction of 300 mm / min and peel length of 35 mm, and the average peel strength at a peel length of 10 to 30 mm is determined. The measurement of this peeling and average peeling strength can be performed using, for example, a strograph VES1D manufactured by Toyo Seiki Seisakusho.

  Furthermore, the present inventors use an amorphous polyester layer having a glass transition temperature of 25 ° C. or lower as an easily peelable layer, and a surface to be adhered to the easily peelable layer is a resin layer or a metal layer. As a result, it was found that after the first base material layer was peeled from the second base material layer, it was possible to reseal without causing stickiness of the peeled surface and then pressing them again.

  In particular, in one embodiment of the present invention, the first base layer and the second base layer are re-sealed by reciprocating once with a 2 kg roller with respect to the adherend surface having a width of 25 mm. Average peel strength at a peel length of 10 to 30 mm when the second base material layer is peeled from the material layer by 180 ° from the short side to the long side at 300 mm / min and a peel length of 35 mm Can be 0.05 N / 25 mm to 1.50 N / 25 mm.

  In one embodiment of the present invention, as shown in FIG. 1 (b), the easily peelable laminate (10b) of the present invention is the first base layer (2) of the easily peelable layer (4). There may be further provided a second base material layer (6) that is present on the side where is not present.

  The second base material layer is a single layer resin layer or metal layer, or a laminate having at least the resin layer or metal layer. In any case, the layer in contact with the easily peelable layer of the second base material layer is a resin layer or a metal layer.

  Further, the first and / or second base material layer may further include an optional sealant layer as a layer not in contact with the easily peelable layer of the outermost layer.

  In one embodiment of the present invention, the first and / or second base material layer may have a half cut line.

  In one embodiment of the present invention, as shown in FIGS. 3 (a) and 3 (b), the easily peelable laminate (10c) of the present invention comprises a second substrate from the easily peelable layer (4). Between the second substrate layer (6) and the easily peelable layer (4) of the peeling tab (16), which has a peeling tab (16) for peeling the layer (6) The release agent layer (8) may be provided in at least a part of the region.

  According to this embodiment, a region where the easily peelable layer and the second base material layer are not bonded is formed as a peeling tab, and this is used as a trigger for peeling from the easily peelable layer to the second peelable layer. The base material layer can be easily peeled off.

  Moreover, in one embodiment of this invention, as shown to Fig.4 (a)-(c), the easily peelable laminated body (10d) of this invention is 2nd from an easily peelable layer (4). It has a peeling tab (16) for peeling the substrate layer (6), and the peeling tab (16) and the other part of the easily peelable laminate (10d) are the first substrate. It is demarcated by the half-cut line (6c) for peeling trigger engraved from the layer side or the second substrate layer side, and as shown in FIGS. 4 (a) and (b), for peeling trigger A release agent layer (8) is provided in at least a part of the region between the second base material layer (6) and the easily peelable layer (4) so as to surround the half-cut line (6c). It may be.

  In this embodiment, the easily peelable layer and the second base material layer are bonded to each other at the tip of the peeling tab, but there is a release agent layer in the area around the half cut line for peeling trigger. Therefore, the peeling strength in this region is low, and therefore, when the peeling operation is performed, the second base material layer can be easily peeled off from the easily peelable layer triggered by the half cut line for peeling trigger.

  In the embodiment having the release agent layer (8), the release agent layer (8) may be laminated so as to fill the application region as shown in FIG. 5 (a). ), A pattern including a region where a release agent is not applied may be laminated. According to the embodiment shown in FIGS. 5B and 5C, the peel strength can be locally reduced, whereby the second base material layer can be easily peeled from the easily peelable layer.

  In the embodiment shown in FIGS. 5B and 5C, the lamination density of the release agent layer can be 10% or more, 20% or more, 30% or more, and 100% depending on the desired adhesive strength. Hereinafter, it may be 90% or less, or 80% or less. Here, the “lamination density” of the release agent layer is referred to in unit% as the ratio of the area where the release agent is applied per unit area.

  Below, each component of this invention is demonstrated.

<First base material layer>
A 1st base material layer is a layer which exists on an easily peelable layer. In particular, the first base material layer can be a single layer resin layer or metal layer, or a laminate having at least a resin layer or metal layer. In particular, the layer in contact with the easily peelable layer of the first base material layer can be a resin layer or a metal layer.

  When the first base material layer is a laminate, the first base material layer may have an optional sealant layer and other layers as a layer not in contact with the easily peelable layer.

(Resin layer)
As the resin layer, a commercially available film or an extruded resin can be used as appropriate.

  For example, as a film, polyethylene terephthalate film (PET), low density polyethylene film (LDPE), medium density polyethylene film (MDPE), high density polyethylene film (HDPE), linear low density polyethylene film (LLDPE), polypropylene film ( PP), nylon film (Ny) and the like may be used alone or in combination.

  Extrusion resins include low density polyethylene (LDPE), medium density polyethylene (MDPE), high density polyethylene (HDPE), linear low density polyethylene (LLDPE), ethylene methacrylic acid copolymer (EMAA), ethylene acrylic acid copolymer A combination (EAA) or the like may be used alone or in combination.

  Further, the resin layer may include other layers such as an adhesive layer, an inorganic vapor deposition layer, and a barrier coat layer.

(Metal layer)
As a metal layer, alloy foils, such as metal foil, such as aluminum foil, copper foil, and titanium foil, aluminum alloy foil, and stainless steel foil, can be used, for example.

(Sealant layer)
A sealant layer is a layer for heat-sealing an easily peelable laminated body to other structures, such as a container. In particular, in the first base material layer and the second base material layer of the present invention, the outermost layer is a layer that is not in contact with the easily peelable layer.

  The material of the heat seal layer is selected depending on the material to be sealed. For example, LDPE, LLDPE, PP, ethylene-methacrylic acid copolymer (EMAA), ethylene-acrylic acid copolymer (EAA), ionomer resin, ethylene-acetic acid Resins such as vinyl copolymers may be used. These resins may be in the form of, for example, a stretched or non-stretched film, a melted resin for extrusion lamination, and a paint for hot melt.

  Moreover, as a sealant layer, you may use the commercially available easy peel resin and easy peel sealant film which are not comprised with these resin.

(Other layers)
Examples of other layers include a paper layer, an adhesive layer, and a printing layer. The lamination of the other layers can be performed, for example, by extrusion lamination such as sand lamination or back lamination, or dry lamination.

  As the paper layer, coated paper, art paper or the like can be used.

  As the adhesive layer, for example, a dry laminate adhesive, an anchor coat adhesive, a hot melt adhesive, a water-soluble adhesive, an emulsion adhesive, a non-solvent laminate adhesive, a thermoplastic resin for extrusion lamination, etc. should be used. Can do.

  The print layer may be, for example, a print layer showing character information, a mark print layer, a light-shielding print layer, a pattern print, a photo print layer, or the like. The printing layer can be formed by gravure printing, flexographic printing, or the like.

<Easily peelable layer>
The easily peelable layer is a layer of amorphous polyester having a glass transition temperature of 25 ° C. or lower.

The easily peelable layer is preferably present in an amount of 4.0 g / m ² or less from the viewpoint of realizing good peelability and good resealability. This amount, 3.8 g / ^{m 2} or less, or 3.5 g / ^{m 2} can be less, also 0.1 g / ^{m 2} or more, 0.3 g / ^{m 2} or more, or 0.5 g / ^{m 2} That can be the end.

(Amorphous polyester)
Amorphous polyester has a glass transition temperature of 25 ° C. or less. The glass transition temperature can be 25 ° C. or lower, 22 ° C. or lower, or 20 ° C. or lower, and can be −50 ° C. or higher, −40 ° C. or higher, −30 ° C. or higher, or −20 ° C. or higher. . Within the above range, it is possible to ensure easy peeling and resealability with no practical problems, but from the viewpoint of not causing peeling (pulse peeling) accompanied by abnormal noise or catching, that is, from the viewpoint of causing smooth peeling Therefore, the glass transition temperature is preferably 15 ° C. or lower, 10 ° C. or lower, or 5 ° C. or lower.

  Here, “amorphous” in the present invention does not have a clear melting peak when the temperature is increased from −100 ° C. to 300 ° C. at a rate of 20 ° C./min using a differential scanning calorimeter (DSC). Means that.

  Further, the glass transition temperature (Tg) in the present specification is obtained by heat flux differential scanning calorimetry (heat flux DSC) under a temperature rising condition at a heating rate of 10 ° C./min in accordance with JIS K7121 (1987). In addition, the glass transition temperature (° C.) of the intermediate point is used, and “when measuring the glass transition temperature after performing a certain heat treatment” of JIS K7121 is adopted for adjusting the state of the test piece.

  The number average molecular weight of the amorphous polyester is preferably 100000 or less, 90000 or less, 80000 or less, 70000 or less, 60000 or less, or 50000 or less from the viewpoint of preventing stickiness of the easily peelable layer after peeling. It is preferable from a viewpoint of ensuring moderate peeling strength that it is 5000 or more, 6000 or more, 7000 or more, 8000 or more, 9000 or more, or 10,000 or more.

  Here, the number average molecular weight in the present specification means the number average molecular weight measured by gel permeation chromatography using a tetrahydrofuran solvent and a polystyrene standard.

  Such an amorphous polyester is an amorphous polyester containing 50 mol% of a dicarboxylic acid component and 50 mol% of a glycol component, which is 30 mol% or more of terephthalic acid and 25 mol% or more of ethylene. Amorphous polyester containing glycol and other dicarboxylic acid component and / or other glycol component of 5 to 45 mol% can be used.

  Other dicarboxylic acid components include isophthalic acid, orthophthalic acid, 1,5-naphthalic acid, 2,6-naphthalic acid, 4,4′-diphenyldicarboxylic acid, 2,2′-diphenyldicarboxylic acid, 4,4 ′. Aromatic dibasic acids such as diphenyl ether dicarboxylic acid, adipic acid, azelaic acid, sebacic acid, 1,4-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,2-cyclohexanedicarboxylic acid, 4-methyl-1 , 2-cyclohexanedicarboxylic acid, dimer acid, and other aliphatic and alicyclic dicarboxylic acids.

  Other diol components include propylene glycol, 1,3-propanediol, 2-methyl-1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, , 5-pentanediol, 1,6-hexanediol, 3-methyl-1,5-pentanediol, neopentyl glycol, diethylene glycol, dipropylene glycol, 2,2,4-trimethyl-1,3-pentanediol, cyclohexane Dimethanol, neopentyl hydroxypivalate, 1,9-nonanediol, 2-methyloctanediol, 1,10-dodecanediol, 2-butyl-2-ethyl-1,3-propanediol, tricyclodecane dimethanol Etc.

<Second base material layer>
A 2nd base material layer is a layer which exists in the side in which the 1st base material layer does not exist on an easily peelable layer. The second base material layer is a single layer resin layer or metal layer, or a laminate having at least the resin layer or metal layer. In any case, the layer in contact with the easily peelable layer of the second base material layer is a resin layer or a metal layer. The second base material layer may be the same as or different from the first base material layer.

  As the resin layer, metal layer, and optional sealant layer and other layers, those mentioned for the first substrate layer can be used.

<Half cut line>
The half cut line is a cut formed at a depth less than the thickness of the easily peelable laminate from the surface of the easily peelable laminate.

  For example, the half cut line can be formed by putting a cutting machine such as a cutter on the surface of the easily peelable laminate. Moreover, a half cut line can be formed in the 1st base material layer side and / or the 2nd base material layer side.

  For example, the half cut line on the first substrate side is engraved from the surface of the first substrate layer of the easily peelable laminate to a depth penetrating at least a part or all of the first substrate layer. Yes.

  The half cut line on the first base material layer side is engraved at a depth penetrating at least part or all of the first base material layer in the thickness direction of the first base material layer of the easily peelable laminate. Has been. Therefore, the depth of the first base material layer half cut line is substantially equal to the thickness of the first base material layer of the easily peelable laminate.

  For example, the half cut line on the first base material layer side can be formed from the surface of the first base material layer to a depth reaching the easily peelable layer. In this case, the second base material layer can be peeled off at the interface between the first base material layer and the easily peelable layer. Moreover, the half cut line by the side of the 1st base material layer can be formed until it penetrates an easily peelable layer from the surface of the 1st base material layer. In this case, the second base material layer can be peeled off at the interface between the second base material layer and the easily peelable layer.

  Hereinafter, in the lid material or the packaging bag having the easily peelable laminate, various aspects of the half cut line in the case where one of the first and second lid materials is used as the inner layer and the other is used as the outer layer. explain.

{Inner layer half cut line for opening}
The opening inner layer half-cut line exists so as to define a partial region of the inner layer. When the outer layer is peeled from the inner layer, this part of the region is separated from the other part of the inner layer together with the outer layer, and an opening is formed in the inner layer.

  This partial area may be a closed area or an unclosed area. Examples of the closed region include an annular shape, a polygonal shape, and a rounded polygonal shape.

{Half cut line for triggering peeling}
The half cut line for peeling trigger is a half cut line used as an element for peeling the other base material layer from one base material layer, particularly as an element for peeling the outer layer from the inner layer, that is, as a peeling trigger. In particular, when the peeling tab and other regions of the packaging laminate are defined by the peeling trigger half-cut line, the peeling trigger half-cut line exists so as to cross the side of the peeling tab. Also good.

{Outer layer half cut line}
The outer layer half-cut line is a half-cut line for defining a separation scheduled portion.

<Peeling tab>
The peeling tab is a peeling tab for peeling between the easily peelable layer and the second base material layer.

  The peeling tab and the other area of the packaging laminate may be defined by an area where the release agent layer is laminated or a half-cut line for peeling trigger.

  For example, the peeling tab may have a form in which a part of the easily peelable laminate protrudes.

<Release layer>
The release agent layer is present in at least a part of the release tab between the second base material layer and the easily peelable layer, or surrounds the release trigger half-cut line. It is an optional layer that can be present between the two substrate layers and the easily peelable layer. Due to the presence of the release agent layer, the peel strength between the easily peelable layer and the second base material layer can be reduced.

  Moreover, the release agent layer may partially exist between the second base material layer and the easily peelable layer. More specifically, the release agent layer may exist as a pattern including a region between which the release agent is not applied.

  As the release agent layer, nitrocellulose resin, urethane resin, silicone resin, silicone oil, aminoalkyd resin, polyamide resin, polyester resin, aqueous varnish, oily varnish, UV curable varnish, etc., or a mixture thereof It may be.

  The release agent layer is more preferably a mixture of at least one of the resins listed above and a wax. The wax content in the mixture may be about 20% or more, or about 30% or more, and about 85% or less, or about 80% or less, based on the weight of the mixture. .

<Cover>
The lid material of the present invention has the above easily peelable laminate.

  The lid | cover material of this invention can be used as a lid | cover material for instant foods. That is, the lid for instant food further comprises the second base material layer that is present on the side of the easily peelable layer where the first base material layer is not present, One of the first and second base material layers is an inner layer, the other is an outer layer, and the inner layer has an inner half-cut line for opening that exists so as to define a partial region of the inner layer. When the outer layer is peeled from the inner layer, a part of the inner layer is separated from the other part of the inner layer together with the outer layer, and an opening is formed in the inner layer. Furthermore, in one embodiment of the lid member, the inner layer and the outer layer can be resealed by returning the peeled portion to the state before peeling and pressing it.

  Examples of the instant food include foods that are assumed to be poured after the lid is opened and then discharged to perform processing such as cooking, such as instant noodles.

  One embodiment of the lid member of the present invention will be described with reference to FIG. In this lid member, the first base material layer is an outer layer, and the second base material layer is an inner layer. Fig.6 (a) is a top view of the cover material of this invention, FIG.6 (b) is side surface sectional drawing when the outer layer of the cover material of this invention is peeled.

  In one embodiment of the lid member of the present invention, the part to be peeled (42) is a part of the first base material layer (2) as the outer layer of the lid member (40a) as shown in FIG. Only the outer layer half cut line (2a) is inserted into the outer layer side from the outer layer side. When hot water is put into the instant noodle container (20), the lid (40a) is peeled off about half from the container (20) by using the opening tab (44). Moreover, when throwing away hot water from a container (20) after progress for a fixed time, the peeling scheduled part (42) is peeled from the inner layer half cut line (6c) for peeling trigger, and the opening (6b) is exposed. The opening (6b) is formed by inserting an opening inner layer half-cut line (6a) from the inner layer side. Before the peeling scheduled portion (42) is peeled off, the second base material layer ( 6), but when the part to be peeled (42) is peeled off, the half-cut part is removed along with the part to be peeled and exposed.

  In another embodiment of the lid member, as shown in FIG. 7A, the release agent layer (8) may be present so as to surround the release trigger inner layer half cut line (6c). . This release agent layer (8) may exist between the easily peelable layer (4) and the second base material layer (6) as shown in FIG. 7B, for example.

  Another embodiment of the lid of the present invention will be described with reference to FIG. In this lid member, the first base material layer is an outer layer, and the second base material layer is an inner layer. Fig.8 (a) is a top view of the cover material of this invention, FIG.8 (b) is side surface sectional drawing when the outer layer of the cover material of this invention is peeled.

  In another embodiment of the lid member of the present invention, as shown in FIG. 8, the lid member (50a) includes a peeling tab (56) and an opening tab (54). In addition, the lid member (50a) has an opening inner layer half cut line (6a) engraved in a region inside the flange portion of the container (20). When hot water is put into the container (20), the peeling tab (56) is picked, and the first base material layer that is the outer layer of the lid (50a) is removed from the peeling trigger inner layer half-cut line (6c). Remove about 3/4 from the container (20) to expose the opening (6b). This opening (6b) is formed by inserting an inner layer half cut line (6a) for opening from the inner layer side. Before the first substrate layer is peeled off, a second substrate layer ( 6), but when the first base material layer is peeled off, the half-cut portion is removed along with the first base material layer and is exposed.

  Furthermore, when the contents are steamed for a certain period of time after the hot water supply, it is possible to reseal by returning the first base material layer peeled about 3/4.

  And when eating after steaming the contents, the second base material layer (6) is peeled from the container (20) by picking the opening tab (54) and peeling the entire lid from the container. can do.

  In another embodiment of the lid member, as shown in FIG. 9A, the release agent layer (8) may be present so as to surround the release trigger inner layer half cut line (6c). . This release agent layer (8) may exist between the easily peelable layer (4) and the second base material layer (6) as shown in FIG. 9 (b), for example.

《Packaging bag》
The packaging bag of this invention has said easily peelable laminated body.

  The packaging bag of the present invention can be used as a packaging bag containing contents. That is, the packaging bag containing the contents further includes the second base material layer that is present on the side of the easily peelable layer where the first base material layer is not present. And one of the second base material layers is an inner layer, the other is an outer layer, and the inner layer has an inner layer half-cut line for opening that exists so as to define a partial region of the inner layer. When the outer layer is peeled from the inner layer, a part of the inner layer is separated from the other part of the inner layer together with the outer layer, and an opening is formed in the inner layer. Furthermore, in one embodiment of this packaging bag, the inner layer and the outer layer can be resealed by returning the peeled portion to the state before peeling and pressing it.

  The content may be, for example, a solid, a gel, or the like, and may be, for example, an article such as a chemical, a cosmetic, a detergent, a fragrance, a pharmaceutical, or a wet tissue.

  One embodiment of the packaging bag of the present invention will be described with reference to FIG. Fig. 10 (a) is a side sectional view of one embodiment of the packaging bag of the present invention, and Fig. 10 (b) is a top view of one embodiment of the packaging bag of the present invention, Fig. 5 (c). These are side surface sectional views when the 1st base material layer is peeled of one embodiment of the packaging bag of the present invention.

  In the packaging bag (100a) shown in FIGS. 10 (a) and 10 (b), the two second base material layers (6) face each other and are heat-sealed at the peripheral seal portion (102). A main body is comprised, and the opening-and-closing part (104) on a packaging bag main body is comprised by the 1st base material layer (2) and the easily peelable layer (4). And in the area | region with which an opening-and-closing part (104) and a packaging bag main body overlap, the half cut line (6a) is engraved from the packaging bag main body side. When the opening / closing part of the packaging bag is turned up, the half-cut portion is removed along with the opening / closing part, and an opening (6b) is formed.

  In another embodiment of the packaging bag, as shown in FIG. 11B, a release agent layer (8) may be present in a region corresponding to the opening / closing part (104). This release agent layer (8) may exist between the easily peelable layer (4) and the second base material layer (6) as shown in FIG. 11 (a), for example.

  Another embodiment of the packaging bag of the present invention will be described with reference to FIG. Fig. 12 (a) is a side cross-sectional view of another embodiment of the packaging bag of the present invention, and Fig. 12 (b) is a top view of another embodiment of the packaging bag of the present invention. c) It is side surface sectional drawing when the 1st base material layer is peeled of another embodiment of the packaging bag of this invention.

  In the packaging bag (200a) shown to Fig.12 (a) and (b), the surface of a bottom face side sheet, a 1st base material layer (2), an easily peelable layer (4), a 2nd base material layer The second base material layer (6) of the upper surface side sheets laminated in the order of (6) face each other, and the periphery of the sheet is sealed by the side edge seal portion (202a) and the edge seal portion (202b). The main body of the packaging bag (200a) is configured, and one end seal portion (202b) is formed on the inner side of the bag with respect to the end edge of the sheet so that it extends outside the end seal portion (202b). The extended portion (204) is provided.

  And the inner layer half cut line (6c) for peeling trigger which penetrates the 2nd base material layer of the top sheet between extension part (204) and edge seal part (202b) is formed, The opening inner layer half-cut line (6a) passing through the second base material layer of the top sheet inside the packaging bag surrounded by the edge seal part (202b) and the side edge seal part (202a) is It is formed so as to form a closed region.

  When the extension part (204) of the packaging bag is picked and the top sheet is turned up, the half-cut part is removed along with the opening / closing part, and an opening (6b) is formed.

  Moreover, it becomes possible to reseal by returning the peeled first base material layer (2).

  In another embodiment of this packaging bag, as shown in FIG. 13 (b), the release agent layer (8) may be present so as to surround the release trigger inner layer half cut line (6c). . This release agent layer (8) may exist between the easily peelable layer (4) and the second base material layer (6) as shown in FIG. 13 (a), for example.

  The packaging bag of this invention has said easily peelable laminated body. A further embodiment of the packaging bag of the present invention will be described with reference to FIG. 14 (a) is a cross-sectional view of a further embodiment of the packaging bag of the present invention, taken along line XX ′ of FIG. 14 (b), and FIG. 14 (b) is a further illustration of the packaging bag of the present invention. 14 (c) is a cross-sectional view of a further embodiment of the packaging bag of the present invention, taken along line YY ′ of FIG. 14 (b), and FIG. 14 (d). These are sectional drawings in line YY 'of Drawing 14 (b) when the 1st substrate layer is exfoliated of the further embodiment of the packaging bag of the present invention.

  In the packaging bag (250a) shown to Fig.14 (a)-(d), it laminated | stacked in order of the 1st base material layer (2), the easily peelable layer (4), and the 2nd base material layer (6). The easily peelable laminate is formed into a cylindrical shape with the second base material layer (6) on the inside, heat-sealed with the back seal portion (252), and then the end of the back seal portion (252) is in the center. This is a pillow bag (250a) sealed with edge seal portions (254a, 254b).

  In this pillow bag, as shown to Fig.14 (a), an easily peelable layer (4) is provided from the 1st base material layer (2) side of a bag top surface side without a back seal part (252). The outer half-cut line (2a) that penetrates is engraved so as to form a U-shape with the right side opened, for example, as viewed from the top of the bag, so as to form an unclosed region, Furthermore, an inner half-cut line (6a) for opening reaching the easily peelable layer (4) from the second base material layer (6) side is closed inside the region formed in the U-shape. It is formed so as to form a defined region.

  Then, when the peeling tab (256) which is a U-shaped closing part (left side part) is picked and the sheet is turned up, the half-cut part is removed along with the opening and closing part, and the opening (6b ) Is formed.

  Moreover, it becomes possible to reseal by returning the peeled first base material layer.

  In another embodiment of the packaging bag, as shown in FIG. 15B, a release agent layer (8) may be present around the release tab (256). This release agent layer (8) may exist between the easily peelable layer (4) and the second base material layer (6) as shown in FIG. 15 (c), for example.

  Each structure in said lid | cover material and a packaging bag can be combined suitably as needed.

<< Method for Producing Easy-Release Laminate >>
The method of the present invention for producing an easily peelable laminate includes an amorphous polyester solution coating step, a drying step, and an optional lamination step and a release agent coating step. In the following, referring to FIG. 16, one embodiment of the method of the present invention will be described.

<Amorphous polyester solution application process>
The amorphous polyester solution application step means applying an amorphous polyester solution to the first base material layer.

  In one embodiment, as shown in FIG. 16, in the amorphous polyester solution application step (310), the first base material layer is transferred from the feed roll (312) to the amorphous polyester solution application part (314). It can be done by moving. This application may be performed using, for example, a gravure roll.

  As the amorphous polyester solution, the amorphous polyester mentioned for the easily peelable layer can be dissolved in a solvent component and used.

  As the solvent component, ethyl acetate, methyl ethyl ketone, toluene, isopropyl alcohol, ethanol, methanol or the like can be used alone or in combination.

  The concentration of the amorphous polyester in the solution of the amorphous polyester at the time of application can be 5% by mass, 7% by mass or 10% by mass, and 40% by mass or less, 30% by mass or less. Or 20% by mass or less.

The solution of the amorphous polyester by coating, remaining after evaporation of the solvent component in the following drying step, the amount of amorphous polyester, 4.0 g / ^{m 2} or less, 3.8 g / ^{m 2} or less, Alternatively, it can be 3.5 g / m ² or less, and can be 0.1 g / m ² or more, 0.3 g / m ² or more, or 0.5 g / m ² or more. This amount can be adjusted by adjusting the concentration of the amorphous polyester in the solution of the amorphous polyester and the coating amount of the solution of the amorphous polyester.

<Drying process>
A drying process means drying the solution of an amorphous polyester and forming an easily peelable layer.

  As shown in FIG. 16, the drying step (320) can be performed using, for example, a drying facility (322).

  Examples of the drying equipment include a dryer.

<Lamination process>
A lamination process means making a 2nd base material layer press-fit and laminate | stack on an easily peelable layer.

  As shown in FIG. 16, in the laminating step (330), for example, the second base material layer (6) is moved from the feed roll (332) so as to overlap with the easily peelable laminate (10a), and is crimped. Can be performed.

<Release application process>
The release agent application step means applying a release agent to the second base material layer. This application may be performed by gravure printing, for example. As the release agent, the release agents mentioned for the release agent layer can be used.

  The present invention will be specifically described with reference to Examples and Comparative Examples, but the present invention is not limited to these.

[Evaluation of easy peelable laminate]
<Production of laminate>
<Examples 1-1 to 1-5>
Amorphous polyester A (Byron (trademark) 55SS, Toyobo Co., Ltd., Tg: −15 ° C.) dissolved in a solvent was diluted with ethyl acetate so that the amorphous polyester content was 15% by mass, A solution of amorphous polyester was prepared. Next, on a polyethylene terephthalate (PET) film (“PET1”, PETB, Unitika Co., Ltd., thickness: 12 μm) as a first base material layer, a solid with an amount of 0.4 g / m ² using a bar coater. A solution of amorphous polyester was applied so as to remain, and dried to drive off the solvent, and an easily peelable layer was prepared. Next, a polyethylene terephthalate (PET) film (“PET2”, E5100, Toyobo Co., Ltd., thickness: 12 μm) as the second base material layer is pressure-bonded onto the easily peelable layer, and the easy of Example 1-1 A peelable laminate was produced.

Next, after applying the amorphous polyester solution and removing the solvent, the solid content including the amorphous polyester is 1.0 g / m ² , 1.8 g / m ² , 2.2 g / m ² , and 3. Except having changed into 0.2 g / m < ² >, it carried out similarly to the easily peelable laminated body of Example 1-1, and produced the easily peelable laminated body of Examples 1-2 to 1-5.

<Examples 2-1 to 2-5>
After using amorphous polyester B (Byron (trademark) 50AS, Toyobo Co., Ltd., Tg: 4 ° C.) as the amorphous polyester dissolved in the solvent, the amorphous polyester solution was applied and the solvent was blown off. The solid content amount of amorphous polyester was changed to 0.6 g / m ² , 1.0 g / m ² , 1.4 g / m ² , 2.1 g / m ² , and 2.9 g / m ^2. Except for the easily peelable laminates of Example 1-1, the easily peelable laminates of Examples 2-1 to 2-5 were produced.

<Examples 3-1 to 3-5>
Using amorphous polyester C (Byron (trademark) GK-33AS, Toyobo Co., Ltd., Tg: 16 ° C.) as an amorphous polyester dissolved in a solvent, a solution of amorphous polyester is applied, and the solvent is removed. The solid content including the amorphous polyester after the change was changed to 0.7 g / m ² , 1.1 g / m ² , 1.5 g / m ² , 2.1 g / m ² , and 3.2 g / m ² . Except this, the easily peelable laminate of Examples 3-1 to 3-5 was produced in the same manner as the easily peelable laminate of Example 1-1.

<Comparative Examples 1-1 to 1-5>
After using amorphous polyester D (Byron (trademark) 20SS, Toyobo Co., Ltd., Tg: 47 ° C.) as the amorphous polyester dissolved in the solvent, the amorphous polyester solution was applied and the solvent was blown off. The amount of solid content including amorphous polyester was changed to 0.6 g / m ² , 0.8 g / m ² , 1.4 g / m ² , 2.0 g / m ² , and 2.7 g / m ^2. Except for the easily peelable laminates of Example 1-1, the easily peelable laminates of Comparative Examples 1-1 to 1-5 were produced.

<Comparative Examples 2-1 to 2-5>
Using amorphous polyester E (Byron (trademark) GK-88ME, Toyobo Co., Ltd., Tg: 84 ° C.) as an amorphous polyester dissolved in a solvent, a solution of amorphous polyester is applied, and the solvent is removed. The amount of solid content including the amorphous polyester was changed to 0.5 g / m ² , 1.2 g / m ² , 1.7 g / m ² , 2.3 g / m ² , and 3.3 g / m ² . Except for the above, in the same manner as the easily peelable laminate of Example 1-1, easy peelable laminates of Comparative Examples 2-1 to 2-5 were produced.

<Examples 4-1 to 4-5>
Using amorphous polyester F (Eritel (trademark) UE-3223-30EA, Unitika Ltd., Tg: 4 ° C.) as an amorphous polyester dissolved in a solvent, a solution of amorphous polyester was applied, and the solvent The solid content including the amorphous polyester after flying off is 0.6 g / m ² , 1.0 g / m ² , 1.3 g / m ² , 1.8 g / m ² , and 2.9 g / m ² . Except having changed, it carried out similarly to the easily peelable laminated body of Example 1-1, and produced the easily peelable laminated body of Examples 4-1 to 4-5.

<Examples 5-1 to 5-5>
Using amorphous polyester G (Eritel (trademark) XP-0109-30EA, Unitika Ltd., Tg: 2 ° C.) as the amorphous polyester dissolved in the solvent, a solution of amorphous polyester was applied, and the solvent The solid content amount including the amorphous polyester after flying off is 0.5 g / m ² , 0.8 g / m ² , 1.4 g / m ² , 2.1 g / m ² , and 2.8 g / m ² . Except having changed, it carried out similarly to the easily peelable laminated body of Example 1-1, and produced the easily peelable laminated body of Examples 5-1 to 5-5.

<Comparative Examples 3-1 to 3-3>
Instead of the amorphous polyester solution, an aqueous one-component acrylic pressure-sensitive adhesive was used, and the solid content after applying the pressure-sensitive adhesive and removing the solvent was 1.0 g / m ² , 1.9 g / m ² , and except that the 2.7 g / ^{m 2,} in the same manner as in the easily peelable laminate of example 1-1 was fabricated easily peelable laminate of Comparative example 3-1 to 3-3.

<Comparative Examples 4-1 to 4-5>
Instead of the amorphous polyester solution, a solvent-based two-component acrylic pressure-sensitive adhesive is used, and the solid content after applying the pressure-sensitive adhesive and removing the solvent is 0.5 g / m ² and 1.1 g / m ^2. , 1.4 g / m ² , 2.1 g / m ² , and 3.0 g / m ^2, and in the same manner as the easily peelable laminate of Example 1-1, Comparative Example 4-1 A 4-5 easily peelable laminate was produced.

<Comparative Examples 5-1 to 5-5>
Instead of the amorphous polyester solution, a two-pack type aliphatic ester adhesive is used, the solid content after applying the adhesive and removing the solvent is 0.5 g / m ² and 0.9 g / m ^2. , 1.3 g / m ² , 2.0 g / m ² , and 2.9 g / m ^2, and in the same manner as the easily peelable laminate of Example 1-1, Comparative Example 5-1 5-5 easily peelable laminates were prepared.

<Comparative Examples 6-1 to 6-5>
Instead of the amorphous polyester solution, the main component of the two-pack type aliphatic ester adhesive is used, and the solid content after applying the main component and removing the solvent is 0.6 g / m ² and 0.9 g / m. ² , 1.8 g / m ² , 2.1 g / m ² , and 2.7 g / m ² except that the peelable laminate of Example 1-1 was used, and Comparative Example 6-1 ˜6-5 easy peelable laminates were prepared.

<Examples 6-1 to 6-5>
Nylon (Ny) film (Emblem (trademark) ON, Unitika Ltd., thickness: 15 μm) was used as the second base material layer, the amorphous polyester solution was applied, and the amorphous after the solvent was blown off Except for changing the solid content containing the reactive polyester to 0.5 g / m ² , 0.8 g / m ² , 1.7 g / m ² , 2.0 g / m ² , and 3.1 g / m ² In the same manner as the easily peelable laminate of Example 1-1, easily peelable laminates of Examples 6-1 to 6-5 were produced.

<Examples 7-1 to 7-5>
As the first and second base material layers, Ny film (Emblem (trademark) ON, Unitika Co., Ltd., thickness: 15 μm) was used to apply the amorphous polyester solution, and the amorphous after the solvent was blown off Except that the amount of solid content containing the reactive polyester was changed to 0.4 g / m ² , 0.8 g / m ² , 1.5 g / m ² , 1.9 g / m ² , and 3.2 g / m ² The easily peelable laminates of Examples 7-1 to 7-5 were produced in the same manner as the easily peelable laminate of Example 1-1.

<Examples 8-1 to 8-5>
As the second base material layer, a polyethylene (PE) film (H-500S, Aicello Co., Ltd., thickness: 15 μm) is used. Example 1 with the exception that the solids content containing was changed to 0.6 g / m ² , 0.9 g / m ² , 1.4 g / m ² , 2.2 g / m ² , and 2.8 g / m ^2. The easily peelable laminate of Examples 8-1 to 8-5 was produced in the same manner as the easily peelable laminate of No.-1.

<Examples 9-1 to 9-5>
As a second base material layer, a soft aluminum (Al) foil (thickness: 6.5 μm) and a PET film (CB901, KOLON, thickness: 8 μm) are used as a two-pack type aliphatic ester adhesive (Takelac). A-525S / Takenate A-50, Mitsui Chemicals Co., Ltd.) is used so that the aluminum foil and the easily peelable layer are in contact with each other, a solution of amorphous polyester is applied, and the solvent is removed. The amount of solid content including the amorphous polyester was changed to 0.6 g / m ² , 0.8 g / m ² , 1.6 g / m ² , 2.1 g / m ² , and 3.1 g / m ² . Except this, the easily peelable laminates of Examples 9-1 to 9-5 were produced in the same manner as the easily peelable laminate of Example 1-1.

<Comparative Example 7>
An easily peelable resin obtained by kneading 95% by mass of low density polyethylene (Petrocene 226, Tosoh Corporation) and 5% by mass of a cyclic olefin copolymer (Apel 6013B, Mitsui Chemicals, Inc.) instead of the amorphous polyester solution. The PET film (PETB, Unitika Ltd., thickness: 12 μm) as the first substrate layer and the PET film (E5100, Toyobo Co., Ltd., thickness: 12 μm) as the second substrate layer In the meantime, this easily peelable resin was extruded and sand-laminated to prepare an easily peelable laminate of Comparative Example 7.

<Examples 10-1 to 10-3>
A release agent (Polycoat P-91, DIC Graphics) is applied to a polyethylene terephthalate (PET) film (“PET2”, E5100, Toyobo Co., Ltd., thickness: 12 μm) as a second base material layer, with a lamination density of 40. The easy-peelable laminate of Example 10-1 was applied in the same manner as Example 1-2 except that the side coated with gravure printing was applied and the release agent-coated side was pressure-bonded onto the easy-peelable layer. Produced.

  Except having changed the lamination | stacking density of the releasing agent layer into 60% and 80%, it carried out similarly to Example 10-1, and produced the easily peelable laminated body of Example 10-2 and 10-3.

<Evaluation>
<Evaluation of easy peelability>
Each produced easily peelable laminated body was cut into a rectangular sample of 25 mm × 150 mm, and the second base material layer was peeled 35 mm from the short side to the long side. Next, the first base material layer side and the second base material layer side of the peeled portion are respectively sandwiched by a pair of grips facing each other of a measuring machine (Strograph VES1D, Toyo Seiki Seisakusho Co., Ltd.) A 180 ° peel test was conducted by peeling 180 ° under conditions of a test speed of 300 mm / min and a peel length of 35 mm, and an average peel strength at a peel length of 10 to 30 mm was determined.

<Evaluation of resealability>
The peeled first base material layer and the second base material layer of the sample after the 180 ° peel test were overlapped and reciprocated once with a 2 kg roller to bond the peel interface. And about this sample, the 180 degree peeling test was done like the above.

  Next, the pasting and peeling were repeated three times, the peeled first base material layer and the second base material layer were overlapped and reciprocated once with a 2 kg roller, and the peeling interface was stuck together. And about this sample, the 180 degree peeling test was done like the above.

  Moreover, the test which changed the load applied with a rotating roll to 4 kg was similarly performed.

  The results are shown in Tables 1-5.

  Regarding easy peelability, from Tables 1 to 4, the easy peelable laminates of the examples using an amorphous polyester layer having a glass transition temperature of 25 ° C. or lower as the easy peelable layer are the conventional easy peelable properties. It will be understood that, as with the easily peelable laminate of Comparative Example 7 using a resin, it has good easy peelability. Moreover, the easily peelable laminated body of the Example using the resin film or metal foil other than PET film as an adhesion surface with an easily peelable layer is also the easily peelable laminated body of Examples 1-1 to 5-5. It will be understood that it also has good easy peelability.

  Moreover, regarding resealability, from Tables 1 to 4, the easily peelable laminates of Examples using an amorphous polyester layer having a glass transition temperature of 25 ° C. or less as the easily peelable layer cause stickiness. It will be understood that it has good resealability without any problems.

  Furthermore, from Table 5, by laminating the release agent layer, the values of the initial strength and reseal strength can be reduced, and as the lamination density of the release agent layer increases, these values become smaller. I understand.

[Evaluation of lid materials]
<Production of cover material>
<Example 11>
The following materials were prepared:
Coated paper (basis weight: 80 g / m ² ): Ryuo Coat, Daio Paper Co., Ltd. PET (thickness: 12 μm): E5100, Toyobo Co., Ltd. Release agent layer: Polycoat P-91, DIC Graphics Corporation Easy release layer: Byron (trademark) 55SS, Toyobo Co., Ltd. PET (thickness: 8 μm): CB901, KOLON Corp. Aluminum foil (thickness: 6.5 μm): soft aluminum Dry laminate adhesive: Takelac A-620 / Takenate A-65, Mitsui Chemical Co., Ltd. Sealant layer: CMPS ™ VN503, Mitsui DuPont Polychemical

The laminate obtained in this example was paper (basis weight: 80 g / m ² ) // PET (12) / release agent layer / easy peelable layer (1.0 g) / PET (8 μm) // AL (6 0.5 μm) / sealant (20 μm) (where “//” represents a dry laminate adhesive).

1. Using a dry laminator, the amount of dry laminate adhesive applied was set to a dry weight of 2.5 g / m ² or more, and the paper and PET film “E5100” were combined with the dry laminate adhesive “Takelac A-620 / Takenate A-65”. To obtain a member a (paper (basis weight: 80 g / m ² ) // PET (12 μm)) as a second base material layer. Furthermore, the release agent “Polycoat P-91” was applied to the PET-side tab formation planned portion of the member a.
2. Using a dry laminator, the amount of dry laminate adhesive applied was set at a dry weight of 2.5 g / m ² or more, and an aluminum foil and a PET film “CB901” were used. The dry laminate adhesive “Takelac A-620 / Takenate A- 65 ”to obtain a member b (PET (8 μm) // AL (6.5 μm)) as a first base material layer.
3. Amorphous polyester “Byron (trademark) 55SS” as an easily peelable layer dissolved in a solvent was diluted with ethyl acetate so that the amorphous polyester content was 15% by mass. A solution was made. Using a dry laminator, the coating amount was set to a dry weight of 1.5 g / m ² or less, this amorphous polyester solution was applied to the PET film “CB901” side of the member b, and the member a The PET film “E5100” side of the film was pressure-bonded to obtain a laminated film c.
4). Using an extrusion laminator, the film thickness was set to 20 μm, and “CMPS ™ VN503” as a sealant layer was extruded to the aluminum foil side of the member c to obtain a laminated film d.
5. An inner layer half cut for opening and an inner layer half cut for peeling trigger were engraved at a depth from the sealant layer of the laminated film d to the easily peelable layer with a rotary die cutter, and the lid outer peripheral edge was fully cut to obtain a lid material. .

<Example 12>
A lid material of Example 12 was produced in the same manner as Example 11 except that the release agent was not applied. The laminate obtained in this example was paper (basis weight: 80 g / m ² ) // PET (12) / easy peelable layer (1.0 g / m ² ) / PET (8 μm) // AL (6. 5 μm) / sealant (20 μm) (where “//” represents a dry laminate adhesive).

  On the flange part of a polystyrene container (square shape, short side length 171 mm, long side length 233 mm, height 57 mm, flange width 7 mm, pouring amount 820 ml), the lid materials of Examples 11 and 12 were 120 ° C., 65 kg, Heat sealing was performed for 0.7 seconds. Ten containers in which the lid materials of Example 11 and Comparative Example 8 were heat-sealed were similarly prepared and evaluated.

<Evaluation>
The heat-sealed lid was opened by hand, and the peeled state was visually observed. When peeling occurs at the interface between the easy-peeling layer and PET and an opening appears, peeling does not occur at the interface between the easy-peeling layer and PET, and peeling occurs at the interface between the sealant layer and the flange portion of the container X.

  The results are shown in Table 6.

  From Table 6, the lid material of Example 11 having a release agent layer was peeled well at the interface between the easily peelable layer and PET, compared to the lid material of Example 12 having no release agent layer. Can understand.

  In Example 12, the reason why the peelable layer and PET did not peel well was that they were exposed to high temperature and high pressure by heat sealing, and that the high temperature and high pressure were concentrated in a narrow region. This is considered due to the increase in peel strength. However, in view of the results of Examples 10-1 to 10-3, it can be naturally understood that this peel strength can be reduced by adjusting the lamination density and laminating the release agent layer.

2 First base material layer 2a Outer layer half cut line 4 Easy peelable layer 6 Second base material layer 6a Opening inner layer half cut line 6b Opening 6c Peeling trigger (inner layer) half cut line 8 Release agent layer 10a, 10b 10c, 10d Easy peelable laminate 14a, 14b Grasping tool 20 Container 40a, 40b, 50a, 50b Lid material 42 Planned peeling part 44, 54 Opening tab 16, 46, 56, 256 Stripping tab 100a, 100b, 200a , 200 b, 250 a, 250 b Packaging bag 102, 202 Peripheral seal portion 104 Tear guide portion 104 a Scheduled tear line 202 a Side edge seal portion 202 b, 254 a, 254 b Edge seal portion 204 Extension portion 252 Back seal portion 300 Easy peelable laminate Manufacturing method 310 coating process 312, 332 delivery roll 314 Amorphous polyester solution application section 320 Drying process 322 Drying equipment 330 Lamination process 334 Winding roll

Claims (17)

An easily peelable laminate comprising a first substrate layer and an easily peelable layer present on the first substrate layer,
The easily peelable layer is a layer of amorphous polyester having a glass transition temperature of 25 ° C. or lower.
Easy peelable laminate. The easily peelable layer further comprises a second base material layer present on the side where the first base material layer does not exist, and the second base material layer is a single layer. It is a laminate having at least a resin layer or a metal layer, or a resin layer or a metal layer, and the resin layer or the metal layer is in contact with the easily peelable layer,
The easily peelable laminate according to claim 1.   The easily peelable laminate is cut into a rectangle of 25 mm × 150 mm, and the second base material layer is separated from the first base material layer to the long side direction by 300 mm / min, and the peel length is 35 mm. The easily peelable laminate according to claim 2, wherein the average peel strength at a peel length of 10 to 30 mm when peeled by 180 ° under the conditions is 0.3 N / 25 mm to 4.5 N / 25 mm. The easily peelable laminate according to any one of claims 1 to 3, wherein the easily peelable layer is present in an amount of 4.0 g / m ² or less.   The easily peelable laminate according to any one of claims 1 to 4, wherein the amorphous polyester has a glass transition temperature of -50 ° C or higher.   The number average molecular weight of the amorphous polyester measured by gel permeation chromatography with a tetrahydrofuran solvent and polystyrene standard of the amorphous polyester is 100,000 or less, according to any one of claims 1 to 5. The easily peelable laminate described.   The said 1st and / or 2nd base material layer is further equipped with the sealant layer as a layer which is not in contact with the said easily peelable layer among outermost layers. The easily peelable laminate described.   The easily peelable laminate according to any one of claims 2 to 7, wherein the first and / or second base material layer has a half cut line. The second peelable layer is further provided with a second base material layer present on the side where the first base material layer is not present,
The second base material layer is a single layer resin layer or metal layer, or a laminate having at least a resin layer or metal layer, and the resin layer or metal layer is the easily peelable layer. In contact with
A peeling tab for peeling the second base material layer from the easy peeling layer; and the second base material layer and the easy peeling layer of the peeling tab. Having a release agent layer in at least a part of the area between,
The easily peelable laminated body as described in any one of Claims 1-8. The second peelable layer is further provided with a second base material layer present on the side where the first base material layer is not present,
The second base material layer is a single layer resin layer or metal layer, or a laminate having at least a resin layer or metal layer, and the resin layer or metal layer is the easily peelable layer. In contact with
From the easily peelable layer, it has a peeling tab for peeling the second base material layer,
The peeling tab and the other part of the easily peelable laminate are defined by a half-cut line for peeling trigger that is engraved from the first base material layer side or the second base material layer side. And has a release agent layer between the second base material layer and the easily peelable layer so as to surround the half-cut line for peeling trigger,
The easily peelable laminated body as described in any one of Claims 1-8.   The lid | cover material which has an easily peelable laminated body as described in any one of Claims 1-10. A lid for instant food,
The second peelable layer is further provided with a second base material layer present on the side where the first base material layer is not present,
The second base material layer is a single layer resin layer or metal layer, or a laminate having at least a resin layer or metal layer, and the resin layer or metal layer is the easily peelable layer. In contact with
One of the first and second base material layers is an inner layer, and the other is an outer layer,
The inner layer has an opening inner layer half cut line that exists so as to delimit a part of the inner layer, and when the outer layer is peeled off from the inner layer, a part of the inner layer Are separated from the outer layer together with other parts of the inner layer to form an opening in the inner layer.
The lid | cover material of Claim 11.   The packaging bag which has the easily peelable laminated body as described in any one of Claims 1-10. A packaging bag containing the contents,
The easily peelable layer further comprises a second base material layer present on the side where the first base material layer does not exist, and the second base material layer is a single layer. It is a laminate having at least a resin layer or a metal layer, or a resin layer or a metal layer, and the resin layer or the metal layer is in contact with the easily peelable layer,
One of the first and second base material layers is an inner layer, and the other is an outer layer,
The inner layer has an opening inner layer half cut line that exists so as to delimit a part of the inner layer, and when the outer layer is peeled off from the inner layer, a part of the inner layer Are separated from the outer layer together with other parts of the inner layer to form an opening in the inner layer.
The packaging bag according to claim 13. Applying a solution of amorphous polyester to the first base material layer, and drying the solution of amorphous polyester to form an easily peelable layer;
Including
The amorphous polyester has a glass transition temperature of 25 ° C. or less,
Manufacturing method of easily peelable laminate.   The method according to claim 15, further comprising press-bonding a second base material layer to the easily peelable layer.   The method of claim 16, further comprising applying a release agent to the second substrate layer.

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