JP2017131176A - Novel milk flavor promoter - Google Patents

Novel milk flavor promoter Download PDF

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JP2017131176A
JP2017131176A JP2016015408A JP2016015408A JP2017131176A JP 2017131176 A JP2017131176 A JP 2017131176A JP 2016015408 A JP2016015408 A JP 2016015408A JP 2016015408 A JP2016015408 A JP 2016015408A JP 2017131176 A JP2017131176 A JP 2017131176A
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bread
confectionery
milk flavor
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JP6694283B2 (en
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典子 和田濱
Noriko Wadahama
典子 和田濱
敏弘 藤本
Toshihiro Fujimoto
敏弘 藤本
健 杉瀬
Takeshi Sugise
健 杉瀬
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Kaneka Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a milk flavor promoter capable of adding good milk flavor to bread, confectionery or the like.SOLUTION: A milk flavor promoter for bread and confectionery contains mixed heated article of plant derived extract and saccharides of 40 to 100 wt.% and has dry weight ratio of the plant derived extract/the saccharides of 99/1 to 1/99, solid fraction amount of total of the plant derived extract and the saccharides of 40 to 80 wt.% based on the whole mixed heated article, the content of 2-acethyl furan of 0.003 to 7 ppm, the content of 5-methyl furfural of 0.001 to 2 ppm, the content of furfural of 0.04 to 15 ppm, the content of 3-methyl butanal of 0.001 to 10 ppm, the content of acetic acid of 0 to 2 ppm, the content of dimethyl disulfide of 0 to 0.5 ppm and the content of 1-butanol of 0 to 0.8 ppm based on whole milk flavor promoter.SELECTED DRAWING: None

Description

本発明は、パン、菓子等に対して、良好な乳風味を付与することができる乳風味増強剤、該乳風味増強剤を含む乳化油脂組成物、及び該風味増強剤や該乳化油脂組成物を含むパン、又は菓子に関する。   The present invention relates to a milk flavor enhancer capable of imparting a good milk flavor to bread, confectionery, etc., an emulsified oil / fat composition containing the milk flavor enhancer, and the flavor enhancer and the emulsified oil / fat composition. Relates to bread or confectionery.

近年、日本国内においてはバターの供給が逼迫しており、家庭用は勿論のこと、業務用においても入手が困難な状況である。そのため、パン・菓子業界や加工食品業界などにおいては、バターの代替品として、マーガリンの需要が伸びている。しかしながら、マーガリンは主に植物性油脂を使用するため、健康面や価格面で優れているものの、バターに感じられる乳風味が不足している。このため、フレーバーを添加して香り付けすることが一般的であるが、香りが不自然であったり、後味の広がりに欠けたり、加熱後の風味持続が劣るなどの問題がある。   In recent years, the supply of butter has been tight in Japan, and it is difficult to obtain it for business use as well as home use. Therefore, in the bread and confectionery industry and the processed food industry, the demand for margarine is growing as a substitute for butter. However, since margarine mainly uses vegetable oils and fats, it is excellent in terms of health and price, but lacks the milk flavor felt in butter. For this reason, it is common to add flavor and scent, but there are problems such as unnatural scent, lack of aftertaste, and poor flavor persistence after heating.

特許文献1では、自然な風味と味の厚みを食品に付与することを目的とした食品用風味改良剤として、麦由来原料を加熱処理して得られ、フルフラール、2−アセチルフラン及びフルフリルアルコールの合計含有量が100ppm以上、且つ5−メチルフルフラール含有量が20ppm以下である食品用風味改良剤が開示されている。しかし、この風味改良剤をマーガリンに添加した場合、麦由来原料の加熱処理によって生成した多量の3−メチルブタナールのために麦芽臭が強く感じられ、乳風味が損なわれる場合がある。   In patent document 1, it is obtained by heat-treating the wheat origin raw material as a food flavor improving agent for the purpose of imparting a natural flavor and taste thickness to food, and furfural, 2-acetylfuran and furfuryl alcohol. A flavor improver for foods having a total content of 100 ppm or more and a 5-methylfurfural content of 20 ppm or less is disclosed. However, when this flavor improving agent is added to margarine, the malt odor is strongly felt due to the large amount of 3-methylbutanal produced by the heat treatment of the wheat-derived raw material, and the milk flavor may be impaired.

特許文献2では、乳製品等に添加してコク、甘み、濃厚感、脂肪感、乳感(ミルク感)を増強させる調味料として、果汁と酵母エキスを混合加熱した調味料が開示されている。しかし、酵母エキスにはシステインが比較的多く含まれているため、加熱により多量のジメチルジスルフィドが生成して、乳風味としては好ましくない硫黄臭が乳製品に付与される欠点があった。   Patent Document 2 discloses a seasoning in which fruit juice and yeast extract are mixed and heated as a seasoning that is added to dairy products and the like to enhance richness, sweetness, richness, fatness, and milkiness (milkiness). . However, since yeast extract contains a relatively large amount of cysteine, there is a drawback that a large amount of dimethyl disulfide is generated by heating and a sulfur odor unfavorable for milk flavor is imparted to dairy products.

特開2015−53886号公報Japanese Patent Laying-Open No. 2015-53886 特開2006−61066号公報JP 2006-61066 A

本発明の目的は、パン、菓子等に対して、良好な乳風味を付与することができる乳風味増強剤、該乳風味増強剤を含む乳化油脂組成物、及び該風味増強剤や該乳化油脂組成物を含むパン、又は菓子を提供することである。   An object of the present invention is to provide a milk flavor enhancer capable of imparting a good milk flavor to bread, confectionery, etc., an emulsified oil / fat composition containing the milk flavor enhancer, and the flavor enhancer or the emulsified oil / fat. It is to provide a bread or confectionery containing the composition.

本発明者らは上記課題を解決するために鋭意研究を重ねた結果、特定の条件を満足する、植物由来エキスと糖類の混合加熱物を用いることで、パン、菓子等に対して良好な乳風味を付与できることを見出し、本発明を完成するに至った。   As a result of intensive research to solve the above-mentioned problems, the present inventors have used milk mixed with a plant-derived extract and a saccharide satisfying specific conditions, so that a good milk for bread, confectionery, etc. It discovered that a flavor could be provided and came to complete this invention.

第一の本発明は、パン・菓子用乳風味増強剤であって、
前記乳風味増強剤は、植物由来エキスと糖類との混合加熱物を40〜100重量%含有し、
前記植物由来エキス/前記糖類の乾燥重量比は、99/1〜1/99であり、
前記植物由来エキスと前記糖類の合計の固形分量は、前記混合加熱物の全体に対し40〜80重量%であり、
前記乳風味増強剤の全体に対し、2−アセチルフランの含有量は0.003〜7ppm、5−メチルフルフラールの含有量は0.001〜2ppm、フルフラールの含有量は0.04〜15ppm、3−メチルブタナールの含有量は0.001〜10ppm、酢酸の含有量は0〜2ppm、ジメチルジスルフィドの含有量は0〜0.5ppm、及び、1−ブタノールの含有量は0〜0.8ppmである、パン・菓子用乳風味増強剤に関する。
The first aspect of the present invention is a milk flavor enhancer for bread and confectionery,
The milk flavor enhancer contains 40 to 100% by weight of a mixed and heated product of a plant-derived extract and a saccharide,
The dry weight ratio of the plant-derived extract / the saccharide is 99/1 to 1/99,
The total solid content of the plant-derived extract and the saccharide is 40 to 80% by weight based on the whole of the mixed heated product,
The content of 2-acetylfuran is 0.003 to 7 ppm, the content of 5-methylfurfural is 0.001 to 2 ppm, and the content of furfural is 0.04 to 15 ppm with respect to the whole milk flavor enhancer. -The content of methylbutanal is 0.001-10 ppm, the content of acetic acid is 0-2 ppm, the content of dimethyl disulfide is 0-0.5 ppm, and the content of 1-butanol is 0-0.8 ppm. It relates to a milk flavor enhancer for bread and confectionery.

好ましくは、前記乳風味増強剤の全体に対する2−アセチルフラン、5−メチルフルフラール、フルフラール及び3−メチルブタナールの合計量(A)と、酢酸、ジメチルジスルフィド及び1−ブタノールの合計量(B)の重量比((B)/(A)×100)が0〜25%である。   Preferably, the total amount of 2-acetylfuran, 5-methylfurfural, furfural and 3-methylbutanal (A) and the total amount of acetic acid, dimethyl disulfide and 1-butanol (B) with respect to the whole of the milk flavor enhancer The weight ratio ((B) / (A) × 100) is 0 to 25%.

好ましくは、前記乳風味増強剤の全体に対する2−アセチルフラン、5−メチルフルフラール、フルフラール及び3−メチルブタナールの合計量(A)が0.05〜25ppmである。   Preferably, the total amount (A) of 2-acetylfuran, 5-methylfurfural, furfural and 3-methylbutanal with respect to the whole of the milk flavor enhancer is 0.05 to 25 ppm.

好ましくは、前記植物由来エキスが、昆布由来エキス、穀物由来エキス、及び穀物発酵物由来エキスからなる群より選ばれる少なくとも1種である。   Preferably, the plant-derived extract is at least one selected from the group consisting of a kelp-derived extract, a cereal-derived extract, and a fermented cereal-derived extract.

好ましくは、前記糖類が、アラビノース、ラクトース、キシロース、グルコース、フルクトース、スクロース、及びマルトースからなる群より選ばれる少なくとも1種である。   Preferably, the saccharide is at least one selected from the group consisting of arabinose, lactose, xylose, glucose, fructose, sucrose, and maltose.

好ましくは、前記乳風味増強剤は、更に、昆布由来エキス、チキン由来エキス、穀物由来エキス、及び穀物発酵物由来エキスからなる群より選ばれる少なくとも1種のエキスの非加熱物を含有する。   Preferably, the milk flavor enhancer further contains a non-heated product of at least one extract selected from the group consisting of a kelp-derived extract, a chicken-derived extract, a cereal-derived extract, and a cereal-fermented product-derived extract.

第二の本発明は、油中水型乳化油脂組成物の全体に対して、前記パン・菓子用乳風味増強剤0.015〜5重量%(乾燥重量)、及び、乳固形分0.1〜70重量%(乾燥重量)を含有するパン・菓子練り込み用油中水型乳化油脂組成物に関する。   2nd this invention is 0.015-5 weight% (dry weight) of the said milk flavor enhancer for bread | bakery and confectionery with respect to the whole water-in-oil type emulsified oil-fat composition, and milk solid content 0.1. The present invention relates to a water-in-oil emulsified oil / fat composition for kneading bread and confectionery, containing ~ 70% by weight (dry weight).

第三の本発明は、水中油型乳化油脂組成物の全体に対して、前記パン・菓子用乳風味増強剤0.015〜5重量%(乾燥重量)、及び、乳固形分0.1〜70重量%(乾燥重量)を含有するパン・菓子練り込み用水中油型乳化油脂組成物に関する。   3rd this invention is 0.015-5 weight% (dry weight) of the said milk flavor enhancer for bread | bakery and confectionery with respect to the whole oil-in-water-type emulsified oil-fat composition, and milk solid content 0.1. The present invention relates to an oil-in-water emulsified oil / fat composition for kneading bread and confectionery containing 70% by weight (dry weight).

第四の本発明は、穀粉100重量部に対して、前記パン・菓子用乳風味増強剤0.0001〜3重量部(乾燥重量)、及び、乳固形分0.005〜50重量部(乾燥重量)を含有するパン生地に関する。   4th this invention is 0.0001-3 weight part (dry weight) and said milk solid content 0.005-50 weight part (dry) with respect to 100 weight part of flour. Weight).

好ましくは、前記乳固形分の少なくとも一部が、乳固形分のリパーゼ処理物であり、前記リパーゼ処理物の全体に対して、乳脂肪10〜99.8重量%、乳蛋白質0.1〜50重量%、及び水分0.1〜70重量%を含有する。   Preferably, at least a part of the milk solid is a lipase-treated product of milk solid, and 10 to 99.8% by weight of milk fat and 0.1 to 50 of milk protein with respect to the whole lipase-treated product. % By weight and 0.1 to 70% by weight of water.

好ましくは、前記パン・菓子用乳風味増強剤と前記リパーゼ処理物の含有量比が99/1〜15/85(乾燥重量比)である。   Preferably, the content ratio of the milk flavor enhancer for bread / confectionery and the lipase-treated product is 99/1 to 15/85 (dry weight ratio).

第五の本発明は、前記パン生地が加熱調理されたパンに関する。   The fifth aspect of the present invention relates to a bread in which the bread dough is cooked.

第六の本発明は、穀粉100重量部に対して、前記パン・菓子用乳風味増強剤0.001〜10重量部(乾燥重量)、及び、乳固形分0.005〜120重量部(乾燥重量)を含有する菓子生地に関する。   The sixth present invention relates to 0.001 to 10 parts by weight (dry weight) of milk flavor enhancer for bread and confectionery and 0.005 to 120 parts by weight of milk solids (dry) with respect to 100 parts by weight of flour. Weight).

好ましくは、前記乳固形分の少なくとも一部が、乳固形分のリパーゼ処理物であり、前記リパーゼ処理物の全体に対して、乳脂肪10〜99.8重量%、乳蛋白質0.1〜50重量%、及び水分0.1〜70重量%を含有する。   Preferably, at least a part of the milk solid is a lipase-treated product of milk solid, and 10 to 99.8% by weight of milk fat and 0.1 to 50 of milk protein with respect to the whole lipase-treated product. % By weight and 0.1 to 70% by weight of water.

好ましくは、前記パン・菓子用乳風味増強剤と前記リパーゼ処理物の含有量比が99/1〜15/85(乾燥重量比)である。   Preferably, the content ratio of the milk flavor enhancer for bread / confectionery and the lipase-treated product is 99/1 to 15/85 (dry weight ratio).

第七の本発明は、前記菓子生地が加熱調理された菓子に関する。   The seventh aspect of the present invention relates to a confectionery in which the confectionery dough is cooked.

第八の本発明は、植物由来エキスと糖類との混合物であって、前記植物由来エキス/前記糖類の乾燥重量比が99/1〜1/99で、固形分量が40〜80重量%である混合物を、品温が75℃になるまで加熱した後、最高到達品温が110〜160℃の範囲内になるように前記混合物を1〜100℃/分の平均昇温速度で加熱し、前記最高到達品温を0.1秒〜5時間保持した後、品温が75℃になるまで前記混合物を5〜200℃/分の平均降温速度で冷却することで混合加熱物を得る工程を含む、当該混合加熱物を含有するパン・菓子用乳風味増強剤の製造方法に関する。   The eighth aspect of the present invention is a mixture of a plant-derived extract and a saccharide, wherein the dry weight ratio of the plant-derived extract / the saccharide is 99/1 to 1/99, and the solid content is 40 to 80% by weight. After the mixture is heated until the product temperature reaches 75 ° C., the mixture is heated at an average temperature increase rate of 1 to 100 ° C./min so that the highest achieved product temperature is in the range of 110 to 160 ° C. The method includes a step of obtaining a mixed heated product by holding the maximum attained product temperature for 0.1 seconds to 5 hours and then cooling the mixture at an average temperature decreasing rate of 5 to 200 ° C./min until the product temperature reaches 75 ° C. The present invention also relates to a method for producing a milk flavor enhancer for bread and confectionery containing the mixed heated product.

本発明に従えば、パン、菓子等に対して、乳脂肪感、乳の甘み、濃厚な乳感、コクといった乳風味を付与することができる乳風味増強剤、該乳風味増強剤を含む乳化油脂組成物、及び該風味増強剤や該乳化油脂組成物を含むパン、又は菓子を提供することができる。   According to the present invention, a milk flavor enhancer capable of imparting a milk flavor such as milk fat feeling, milk sweetness, rich milk feeling and richness to bread, confectionery, etc., and emulsification containing the milk flavor enhancer An oil / fat composition, and a bread or confectionery containing the flavor enhancer or the emulsified oil / fat composition can be provided.

本発明の乳風味増強剤を製造する際に使用可能な二重筒加熱装置の一実施形態の概略を示し、(a)は側断面図、(b)は図1(a)におけるI−I線断面図である。BRIEF DESCRIPTION OF THE DRAWINGS The outline of one Embodiment of the double cylinder heating apparatus which can be used when manufacturing the milk flavor enhancer of this invention is shown, (a) is a sectional side view, (b) is II in Fig.1 (a). It is line sectional drawing.

以下、本発明につき、さらに詳細に説明する。本発明の乳風味増強剤は、植物由来エキスと糖類の混合加熱物を特定量含有するものである。   Hereinafter, the present invention will be described in more detail. The milk flavor enhancer of the present invention contains a specific amount of a mixed heated product of plant-derived extract and sugar.

前記植物由来エキスは、葉、根、茎、皮、果実、種等の植物原料を熱水やアルコール等で抽出した抽出物、前記植物原料を発酵させたり酵素や酸で分解してから熱水やアルコール等で抽出した抽出物、更にはこれら抽出物を濃縮した濃縮液、前記抽出物または前記濃縮液を乾燥して得られた粉末等をいう。具体的には、昆布エキス等の各種海藻エキス、小麦エキス等の各種穀物エキス、白菜エキス等の各種野菜エキス、シイタケエキス等の各種キノコエキス、さらには前記植物原料を酵素や酸で分解した物、前記植物原料にアルコールや塩を加え、麹や酵母、乳酸菌で発酵熟成した調味料などが例示できる。調味料としては、より具体的な例としてみりん等の米系調味料、醤油や味噌等の大豆系又は麦系調味料などが挙げられる。   The plant-derived extract is an extract obtained by extracting plant materials such as leaves, roots, stems, skins, fruits, seeds, etc. with hot water or alcohol, etc. Or an extract extracted with alcohol or the like, a concentrated solution obtained by concentrating these extracts, a powder obtained by drying the extract or the concentrated solution, and the like. Specifically, various seaweed extracts such as kelp extract, various grain extracts such as wheat extract, various vegetable extracts such as Chinese cabbage extract, various mushroom extracts such as shiitake extract, and further products obtained by decomposing the above plant materials with enzymes and acids Examples include seasonings obtained by adding alcohol or salt to the plant raw material and fermenting and ripening with koji, yeast, or lactic acid bacteria. More specific examples of the seasoning include rice-based seasonings such as mirin, soy-based or wheat-based seasonings such as soy sauce and miso.

本発明においては、植物由来エキスとして、昆布由来エキス、穀物由来エキス、及び穀物発酵物由来エキスからなる群より選ばれる少なくとも1種を使用することが好ましく、大豆タンパク分解物、小麦発酵物、酒粕、米発酵物、昆布エキス、米糠発酵物がより好ましく、酒粕、米発酵物、昆布エキス、米糠発酵物が更に好ましく、米発酵物、昆布エキス、米糠発酵物が特に好ましい。   In the present invention, as the plant-derived extract, it is preferable to use at least one selected from the group consisting of a kelp-derived extract, a cereal-derived extract, and a fermented cereal-derived extract. Fermented rice, kelp extract, fermented rice bran are more preferable, sake lees, fermented rice, kelp extract, fermented rice bran are more preferable, fermented rice, kelp extract, fermented rice bran are particularly preferable.

前記糖類は、単糖又は二糖を言い、アラビノース、ラクトース、キシロース、グルコース、フルクトース、スクロース、マルトースなどが例示でき、これらの群より選ばれる少なくとも1種を使用することが好ましく、ラクトース、キシロース、グルコース、フルクトース、スクロース、マルトースがより好ましく、グルコース、フルクトース、マルトースが更に好ましい。   The saccharide refers to a monosaccharide or a disaccharide, and can be exemplified by arabinose, lactose, xylose, glucose, fructose, sucrose, maltose, etc., preferably at least one selected from these groups, lactose, xylose, Glucose, fructose, sucrose, and maltose are more preferable, and glucose, fructose, and maltose are more preferable.

前記植物由来エキス/糖類の混合比(乾燥重量比)は99/1〜1/99が好ましく、80/20〜1/99がより好ましく、60/40〜1/99が更に好ましく、40/60〜10/90が特に好ましい。混合比が99/1より大きい、或いは混合比が1/99より小さいと、目的とする乳風味増強効果が得られない場合がある。   The mixing ratio (dry weight ratio) of the plant-derived extract / saccharide is preferably 99/1 to 1/99, more preferably 80/20 to 1/99, still more preferably 60/40 to 1/99, and 40/60. Is particularly preferred. If the mixing ratio is greater than 99/1 or the mixing ratio is less than 1/99, the intended milk flavor enhancement effect may not be obtained.

前記植物由来エキスと糖類の合計の固形分量(乾燥重量)は、前記混合加熱物の全体に対し40〜80重量%が好ましく、50〜80重量%がより好ましい。固形分量が40重量%より少ないと、香気成分が発現しにくく、乳風味増強効果が得られない場合がある。また、80重量%より大きいと混合加熱物の粘度が高く、コゲが発生しやすくなったり、製造時にポンプ移送する場合は負荷や時間がかかったりするため、生産効率が落ちる場合がある。   The total solid content (dry weight) of the plant-derived extract and saccharide is preferably 40 to 80% by weight, and more preferably 50 to 80% by weight, based on the whole mixed and heated product. When the solid content is less than 40% by weight, the aroma component is hardly expressed and the milk flavor enhancing effect may not be obtained. On the other hand, if it is larger than 80% by weight, the viscosity of the mixed and heated product is high, so that kogation is likely to occur, and when pumped during production, load and time are required, which may reduce production efficiency.

本発明の乳風味増強剤は、植物由来エキスと糖類との混合加熱物を含有するものであるが、乳風味増強剤の全体に対する前記混合加熱物の含有割合は40〜100重量%である。この含有割合は40〜80重量%がより好ましく、40〜70重量%が更に好ましく、40〜60重量%が特に好ましい。前記混合加熱物の含有割合が40重量%より少ないと、目的とする乳風味増強効果が得られない場合がある。また、この範囲内では、後述する2−アセチルフラン、5−メチルフルフラール、フルフラール、3−メチルブタナール、酢酸、ジメチルジスルフィド及び1−ブタノールの含有量を特定範囲に収めることが容易になる。   The milk flavor enhancer of the present invention contains a mixed heat product of a plant-derived extract and a saccharide, and the content ratio of the mixed heat product with respect to the whole milk flavor enhancer is 40 to 100% by weight. The content is more preferably 40 to 80% by weight, still more preferably 40 to 70% by weight, and particularly preferably 40 to 60% by weight. When the content of the mixed heated product is less than 40% by weight, the intended milk flavor enhancing effect may not be obtained. Also, within this range, it becomes easy to keep the contents of 2-acetylfuran, 5-methylfurfural, furfural, 3-methylbutanal, acetic acid, dimethyl disulfide and 1-butanol, which will be described later, within a specific range.

本発明の乳風味増強剤は、前記混合加熱物のみから構成されるものであってもよいが、前記混合加熱物に加えて、昆布由来エキス、チキン由来エキス、穀物由来エキス及び穀物発酵物由来エキスからなる群から選ばれる少なくとも1種のエキスの非加熱物を含有することが好ましい。該非加熱物の含有量は、本発明の乳風味増強剤の全体に対し0.1〜40重量%が好ましく、5〜20重量%がより好ましい。以上の範囲内にあると、エキスの非加熱物の添加によって、より優れた乳風味増強効果を達成することができる。   The milk flavor enhancer of the present invention may be composed only of the mixed and heated product, but in addition to the mixed and heated product, it is derived from kelp-derived extract, chicken-derived extract, cereal-derived extract, and cereal-derived fermented product. It is preferable to contain a non-heated product of at least one extract selected from the group consisting of extracts. The content of the non-heated product is preferably 0.1 to 40% by weight, more preferably 5 to 20% by weight, based on the whole milk flavor enhancer of the present invention. When it is within the above range, a more excellent milk flavor enhancing effect can be achieved by adding the non-heated extract.

本発明の乳風味増強剤は、前記混合加熱物及び前記エキスの非加熱物以外にも、必要に応じて、目的とする風味を損なわない範囲で、前記以外の糖類、油脂類、塩類、乳成分、酵母エキス、或いは甘味料、着色料、保存料、増粘剤、酸化防止剤、漂白剤、香料、酸味料、調味料、乳化剤、pH調整剤、苦味料及び酵素等の食品添加物などを添加することもできる。   The milk flavor enhancer of the present invention is not limited to the above-mentioned mixed heated product and non-heated product of the extract, as long as it does not impair the desired flavor, other sugars, fats, salts, milk Ingredients, yeast extract, or sweeteners, colorants, preservatives, thickeners, antioxidants, bleaches, flavors, acidulants, seasonings, emulsifiers, pH adjusters, bitterings, food additives such as enzymes, etc. Can also be added.

前記以外の糖類としては、例えばオリゴ糖、及びその液糖類、コーンシロップ等の分解糖化液糖類、ソルビトールやエリスリトール等の糖アルコール及びその液糖類等が挙げられる。   Examples of saccharides other than the above include oligosaccharides, liquid saccharides thereof, decomposed saccharified liquid saccharides such as corn syrup, sugar alcohols such as sorbitol and erythritol, and liquid saccharides thereof.

前記油脂類としては、例えば、パーム油、パーム核油、ヤシ油、サフラワー油、向日葵油、綿実油、菜種油、コーン油、大豆油、米糠油、オリーブ油、カカオ脂、シア脂等の植物油脂や、魚油、牛脂、乳脂、豚脂等の動物油脂、また、これらの油脂をエステル交換したものや、硬化、分別したもの等が挙げられる。   Examples of the fats and oils include vegetable oils such as palm oil, palm kernel oil, coconut oil, safflower oil, sunflower oil, cottonseed oil, rapeseed oil, corn oil, soybean oil, rice bran oil, olive oil, cocoa butter, and shea fat. Animal oils such as fish oil, beef tallow, milk fat, pork fat, and the like, and those obtained by transesterifying these oils and fats, cured and fractionated, and the like.

前記乳成分としては、バター、乳脂肪、牛乳、クリーム、脱脂乳、バターミルク、脱脂粉乳、全脂粉乳、バターミルクパウダー、ホエー蛋白質、カゼイン蛋白質、乳清ミネラル、加糖練乳、無糖練乳、チーズ、発酵乳等が挙げられる。   Examples of the milk component include butter, milk fat, milk, cream, skim milk, butter milk, skim milk powder, whole milk powder, butter milk powder, whey protein, casein protein, whey mineral, sweetened condensed milk, sugar-free condensed milk, cheese And fermented milk.

前記酵母エキスとしては、ビール酵母、パン酵母、乳酵母、トルラ酵母などから抽出されたエキス等が挙げられる。   Examples of the yeast extract include extracts extracted from beer yeast, baker's yeast, milk yeast, torula yeast, and the like.

前記調味料としては、アミノ酸、核酸、有機酸、無機塩等が挙げられる。   Examples of the seasoning include amino acids, nucleic acids, organic acids, and inorganic salts.

本発明における混合加熱物においては、乳風味増強効果を発揮するため、2−アセチルフラン、5−メチルフルフラール、フルフラール、3−メチルブタナール、酢酸、ジメチルジスルフィド、及び1−ブタノールそれぞれの含有量が特定範囲内にある。   In the mixed heated product in the present invention, in order to exert a milk flavor enhancing effect, the contents of 2-acetylfuran, 5-methylfurfural, furfural, 3-methylbutanal, acetic acid, dimethyl disulfide, and 1-butanol are included. Within a specific range.

前記2−アセチルフランの含有量は、前記乳風味増強剤の全体に対し0.003〜7ppmであることが好ましく、0.005〜0.5ppmであることがより好ましい。0.003ppmより少ない、或いは7ppmより多いと目的とする乳風味増強効果が得られない場合がある。   The content of 2-acetylfuran is preferably 0.003 to 7 ppm, and more preferably 0.005 to 0.5 ppm, based on the whole milk flavor enhancer. If it is less than 0.003 ppm or more than 7 ppm, the intended milk flavor enhancement effect may not be obtained.

前記5−メチルフルフラールの含有量は、前記乳風味増強剤の全体に対し0.001〜2ppmであることが好ましく、0.005〜0.2ppmであることがより好ましい。0.001ppmより少ない、或いは2ppmより多いと目的とする乳風味増強効果が得られない場合がある。   The 5-methylfurfural content is preferably 0.001 to 2 ppm, more preferably 0.005 to 0.2 ppm, based on the whole milk flavor enhancer. If it is less than 0.001 ppm or more than 2 ppm, the intended milk flavor enhancement effect may not be obtained.

前記フルフラールの含有量は、前記乳風味増強剤の全体に対し0.04〜15ppmであることが好ましく、0.08〜2ppmであることがより好ましい。0.04ppmより少ない、或いは15ppmより多いと目的とする乳風味増強効果が得られない場合がある。   The content of the furfural is preferably 0.04 to 15 ppm, and more preferably 0.08 to 2 ppm, based on the whole milk flavor enhancer. If it is less than 0.04 ppm or more than 15 ppm, the intended milk flavor enhancing effect may not be obtained.

前記3−メチルブタナールの含有量は、前記乳風味増強剤の全体に対し0.001〜10ppmであることが好ましく、0.01〜5ppmであることがより好ましい。0.001ppmより少ないと目的とする乳風味増強効果が得られない場合があり、10ppmより多いと麦芽臭が強く感じられ、好ましい乳風味が損なわれる場合がある。   The content of 3-methylbutanal is preferably 0.001 to 10 ppm, and more preferably 0.01 to 5 ppm, based on the whole milk flavor enhancer. If the amount is less than 0.001 ppm, the intended milk flavor enhancing effect may not be obtained. If the amount is more than 10 ppm, malt odor may be felt strongly, and the preferred milk flavor may be impaired.

前記酢酸の含有量は少ない程好ましく、前記乳風味増強剤の全体に対し0〜2ppmであることが好ましく、0〜0.2ppmであることがより好ましく、0ppmであることが更に好ましい。2ppmより多いと酸臭が強く感じられて、目的とする乳風味増強効果が得られない場合がある。   The content of acetic acid is preferably as low as possible, preferably 0 to 2 ppm, more preferably 0 to 0.2 ppm, and still more preferably 0 ppm with respect to the whole milk flavor enhancer. If it exceeds 2 ppm, the acid odor is felt strongly, and the intended milk flavor enhancement effect may not be obtained.

前記ジメチルジスルフィドの含有量は少ない程好ましく、前記乳風味増強剤の全体に対し0〜0.5ppmであることが好ましく、0〜0.2ppmであることがより好ましく、0ppmであることが更に好ましい。0.5ppmより多いと硫黄臭が強く感じられ、乳風味として好ましくない風味が付与される場合がある。   The content of the dimethyl disulfide is preferably as low as possible, preferably 0 to 0.5 ppm, more preferably 0 to 0.2 ppm, and still more preferably 0 ppm with respect to the whole milk flavor enhancer. . If it exceeds 0.5 ppm, the sulfur odor is strongly felt, and an unfavorable flavor may be imparted as a milk flavor.

前記1−ブタノールの含有量は少ない程好ましく、前記乳風味増強剤の全体に対し0〜0.8ppmであることが好ましく、0〜0.2ppmであることがより好ましく、0ppmであることが更に好ましい。0.8ppmより多いと酸化臭が強く感じられ、目的とする乳風味増強効果が得られない場合がある。   The content of the 1-butanol is preferably as small as possible, preferably 0 to 0.8 ppm, more preferably 0 to 0.2 ppm, and further preferably 0 ppm with respect to the whole milk flavor enhancer. preferable. If it exceeds 0.8 ppm, the odor of oxidation is felt strongly, and the intended milk flavor enhancement effect may not be obtained.

また、本発明の乳風味増強剤の全体に対する2−アセチルフラン、5−メチルフルフラール、フルフラール及び3−メチルブタナールの合計量(A)は、0.05〜25ppmが好ましく、0.1〜20ppmがより好ましく、0.1〜5ppmが更に好ましい。以上の範囲内にあると、より優れた乳風味増強効果を得ることができる。   Moreover, 0.05-25 ppm is preferable and, as for the total amount (A) of 2-acetyl furan, 5-methylfurfural, furfural and 3-methylbutanal with respect to the whole milk | flavor flavor enhancer of this invention, 0.1-20 ppm Is more preferable, and 0.1 to 5 ppm is still more preferable. Within the above range, a more excellent milk flavor enhancing effect can be obtained.

さらに、本発明の乳風味増強剤の全体に対する2−アセチルフラン、5−メチルフルフラール、フルフラール及び3−メチルブタナールの合計量(A)と、同乳風味増強剤の全体に対する酢酸、ジメチルジスルフィド及び1−ブタノールの合計量(B)の重量比((B)/(A)×100)は小さい程好ましく、具体的には0〜25%が好ましく、0〜18%がより好ましい。以上の範囲内にあると、乳風味以外の風味が感じられることが少なく、より優れた乳風味増強効果を得ることができる。   Furthermore, the total amount (A) of 2-acetylfuran, 5-methylfurfural, furfural and 3-methylbutanal based on the whole milk flavor enhancer of the present invention, and acetic acid, dimethyl disulfide and The weight ratio ((B) / (A) × 100) of the total amount (B) of 1-butanol is preferably as small as possible, specifically 0 to 25% is preferable, and 0 to 18% is more preferable. Within the above range, flavors other than the milk flavor are rarely felt, and a more excellent milk flavor enhancing effect can be obtained.

本発明の乳風味増強剤全体中の2−アセチルフラン、5−メチルフルフラール、フルフラール、3−メチルブタナール、酢酸、ジメチルジスルフィド及び1−ブタノールの含有量は、ガスクロマトグラフ質量分析法によって測定できる。具体的な測定条件は以下の通りである。   The content of 2-acetylfuran, 5-methylfurfural, furfural, 3-methylbutanal, acetic acid, dimethyl disulfide, and 1-butanol in the whole milk flavor enhancer of the present invention can be measured by gas chromatography mass spectrometry. Specific measurement conditions are as follows.

(測定手順)
乳風味増強剤10gに蒸留水10gを加え、さらにテトラデカンの濃度が1ppmになるように添加し、よく攪拌したものをフラスコに投入して、下記の吸着条件に基づきTenax TAに乳風味増強剤のヘッドスペースガスの吸着を行なう。ヘッドスペースガスを吸着したTenax TAをインジェクション装置(GERSTEL社製、「TDS」)にセットし、下記の条件に基づきガスクロマトグラフ分析を行う。
(Measurement procedure)
Add 10 g of distilled water to 10 g of milk flavor enhancer, add so that the concentration of tetradecane is 1 ppm, add well-stirred into the flask, and add Tenax TA to the milk flavor enhancer based on the following adsorption conditions. Adsorb headspace gas. Tenax TA adsorbing headspace gas is set in an injection device (“TDS” manufactured by GERSTEL), and gas chromatographic analysis is performed based on the following conditions.

(Tenax TAチューブへのヘッドスペースガス吸着条件)
トラップ管:Tenax TA(GERSTEL社製)
乳風味増強剤の品温:40℃
内部標準:テトラデカン1ppm(和光純薬工業株式会社製、「203−10702」)
キャリアーガス:窒素
キャリアーガス流量:毎分100mL
吸着時間:1時間
水抜きガス:窒素
水抜きガス流量:毎分150mLで15分間
(ガスクロマトグラフ条件)
ガスクロマトグラフ装置:Agilent Technologies社製 6890N
分析手段:昇温分析法
カラム:HP−INNOWAX
カラムサイズ:60m×0.25mm
キャリアーガス:ヘリウム
検出器(MS):Agilent Technologies社製 5973inert
イニシャル温度:40℃
イニシャル温度保持時間:2分間
昇温スピード:100℃まで毎分3℃、その後240℃まで毎分5℃
最終温度:240℃
最終温度保持時間:30分間
キャリアーガス:ヘリウム 206kPa
キャリアーガス流量:2.1ml/min
MS(検出器条件):イオン源温度 230℃、四重極温度 150℃
(インジェクション条件)
インジェクション装置:GERSTEL社製、「TDS」
Cold trap material:シリカキャピラリー
Sample Tube Material: Tenax TA
(TDS条件)
イニシャル温度:20℃
イニシャル温度保持時間:1分間
昇温スピード:毎分60℃
最終温度240℃
最終温度保持時間:5分間
(CIS条件)
イニシャル温度:−100℃
イニシャル温度保持時間:0.2分間
昇温スピード:毎分12℃
最終温度:240℃
最終温度保持時間:10分間
本発明の乳風味増強剤を製造する方法の一例を以下に説明する。
(Head space gas adsorption condition to Tenax TA tube)
Trap tube: Tenax TA (manufactured by GERSTEL)
Product temperature of milk flavor enhancer: 40 ° C
Internal standard: Tetradecane 1 ppm (manufactured by Wako Pure Chemical Industries, “203-10702”)
Carrier gas: Nitrogen Carrier gas flow rate: 100 mL per minute
Adsorption time: 1 hour Degassing gas: Nitrogen Degassing gas flow rate: 150 mL / min for 15 minutes (gas chromatographic conditions)
Gas chromatograph: 6890N manufactured by Agilent Technologies
Analysis method: Temperature rising analysis method Column: HP-INNOWAX
Column size: 60m x 0.25mm
Carrier gas: Helium Detector (MS): 5973inert manufactured by Agilent Technologies
Initial temperature: 40 ° C
Initial temperature holding time: 2 minutes Heating speed: 3 ° C / min up to 100 ° C, then 5 ° C / min up to 240 ° C
Final temperature: 240 ° C
Final temperature holding time: 30 minutes Carrier gas: Helium 206 kPa
Carrier gas flow rate: 2.1ml / min
MS (detector conditions): ion source temperature 230 ° C, quadrupole temperature 150 ° C
(Injection conditions)
Injection device: “TDS” manufactured by GERSTEL
Cold trap material: Silica capillary
Sample Tube Material: Tenax TA
(TDS condition)
Initial temperature: 20 ° C
Initial temperature holding time: 1 minute Heating speed: 60 ° C per minute
Final temperature 240 ° C
Final temperature holding time: 5 minutes (CIS conditions)
Initial temperature: -100 ° C
Initial temperature holding time: 0.2 minutes Temperature rising speed: 12 ° C per minute
Final temperature: 240 ° C
Final temperature holding time: 10 minutes An example of the method for producing the milk flavor enhancer of the present invention will be described below.

まず、前記植物由来エキスと前記糖類との原料混合物を加熱して前記混合加熱物を製造する。その際、該原料混合物が流動されながら均一に加熱されることが好ましい。前記植物由来エキスと前記糖類との原料混合物の全体に対する植物由来エキスと糖類の合計の含有量(乾燥重量)は、40〜80重量%が好ましく、50〜80重量%がより好ましい。合計含有量が40重量%より少ないと、香気成分が発現しにくく、目的とする乳風味増強効果を得ることができない場合があり、80重量%より多いと原料混合物中の固形分の割合が相対的に多くなり、混合加熱物の粘度が高くなるため、固形分が加熱によって焦げ付き、焦げた風味が生成される場合がある。   First, the raw material mixture of the plant-derived extract and the saccharide is heated to produce the mixed and heated product. At that time, it is preferable that the raw material mixture is heated uniformly while flowing. The total content (dry weight) of the plant-derived extract and the saccharide with respect to the whole raw material mixture of the plant-derived extract and the saccharide is preferably 40 to 80% by weight, and more preferably 50 to 80% by weight. If the total content is less than 40% by weight, the aroma components are hardly expressed and the intended milk flavor enhancement effect may not be obtained. If the total content is more than 80% by weight, the ratio of the solid content in the raw material mixture is relative. Therefore, the viscosity of the mixed and heated product increases, so that the solid content may be burnt by heating and a burnt flavor may be generated.

均一な加熱処理を施す手段としては特に限定されないが、仕込み量が10kg以下のような少量の場合、撹拌効率さえよければ、焦げを生じないように注意して加熱すればよく、例えばポータブルリアクターのような装置を使用できる。   There is no particular limitation on the means for performing the uniform heat treatment, but in the case of a small amount such as 10 kg or less, as long as the stirring efficiency is sufficient, it may be heated carefully so as not to cause scorching. Such devices can be used.

しかし、仕込み量が10kgを超えるような大量になる場合、均一な加熱処理を施す手段としては、前記原料混合物を加熱装置の加熱容器内に導入し、該容器に設けた加熱面に強制的に接触させ、略均一な厚さの薄い膜状に拡げた状態で該加熱面に沿って流動させながら、所定の品温に到達するまで加熱処理できる装置を使用することが好ましい。そのような装置としては、従来公知のものを用いることができる。   However, when the amount charged exceeds 10 kg, as a means for performing uniform heat treatment, the raw material mixture is introduced into the heating container of the heating device and forcedly applied to the heating surface provided in the container. It is preferable to use a device that can be heat-treated until it reaches a predetermined product temperature while being brought into contact with each other and flowing along the heating surface in a state of being spread into a thin film having a substantially uniform thickness. A conventionally well-known apparatus can be used as such an apparatus.

このような加熱装置の例として、例えば図1に示すような二重筒加熱装置10を挙げることができる。図1(a)は、二重筒加熱装置10の側断面図、図1(b)は、図1(a)におけるI―I線断面図である。この二重筒加熱装置10は、それぞれ加熱用のジャケットを有する内筒12および外筒13の内外二本の円筒から加熱容器11を構成し、内筒12の外壁面12aと外筒13の内壁面13aとの二つの壁面間に、被加熱処理物である原料混合物の流路となる円筒状の間隙14を形成するとともに、間隙14に連通して、原料混合物の供給口14aと、加熱容器11内で加熱された原料混合物の排出口14bとが、それぞれ設けられている。この二重筒加熱装置10では、内筒12と外筒13とを相対的に回転させてもよい。その場合は、内筒12または外筒13の一方のみを回転させて他方は固定しておいても良いし、内筒12、外筒13の両方を互いに反対方向に回転させても良い。   As an example of such a heating device, for example, a double cylinder heating device 10 as shown in FIG. 1 can be mentioned. FIG. 1A is a side sectional view of the double cylinder heating device 10, and FIG. 1B is a sectional view taken along line II in FIG. 1A. This double cylinder heating device 10 comprises a heating container 11 composed of two cylinders, an inner cylinder 12 and an outer cylinder 13 each having a heating jacket, and the inner wall 12a of the inner cylinder 12 and the inner cylinder 13 Between the two wall surfaces of the wall surface 13a, a cylindrical gap 14 serving as a flow path for the raw material mixture, which is the object to be heated, is formed, and communicated with the gap 14 to supply the raw material mixture supply port 14a and the heating container 11 is provided with a discharge port 14b for the raw material mixture heated inside. In the double cylinder heating device 10, the inner cylinder 12 and the outer cylinder 13 may be relatively rotated. In that case, only one of the inner cylinder 12 or the outer cylinder 13 may be rotated and the other may be fixed, or both the inner cylinder 12 and the outer cylinder 13 may be rotated in directions opposite to each other.

また、加熱については、内筒12、外筒13の両方に加熱ジャケットを設けた両面加熱式でも良いし、いずれか一方のみに加熱ジャケットを設けて片面加熱としても良い。この二重筒加熱装置10では、内筒12および外筒13の内外二本の円筒のいずれか一方のジャケットまたは両方のジャケットに蒸気を導入し、供給口14aから加熱容器11内にポンプなどを用いて原料混合物を圧入すると、原料混合物は内筒12および/または外筒13からの加熱を受けながら、内筒12と外筒13との間の間隙14内を薄膜状となって排出口14bに向かって流動し、排出される。この時、内外二本の円筒12、13を相対的に回転させると、加熱容器11内に導入された原料混合物は、相対的に回転する内筒12と外筒13との間の間隙14内を、内筒12の外壁面と外筒13の内壁面との相対的移動方向(回転方向)に対して直交する方向(回転軸方向)に流動し、排出口14bから排出される。この装置では、内筒12の外径寸法と外筒13の内径寸法により間隙14の幅dを調整し、加熱容器11の間隙14内を流動する原料混合物の膜厚を調整することができる。また、加熱具合は、内筒12及び/または外筒13のジャケットに導入する蒸気圧と、前記膜厚(間隙14の幅d)に加えて、加熱容器11への原料混合物の単位時間当たりの圧入量(流量)で調整できる。   As for the heating, a double-sided heating type in which a heating jacket is provided in both the inner cylinder 12 and the outer cylinder 13 may be used, or a heating jacket may be provided in only one of them to perform single-sided heating. In this double cylinder heating device 10, steam is introduced into one or both of the inner cylinder 12 and the outer cylinder 13 of the outer cylinder 13, and a pump or the like is introduced into the heating container 11 from the supply port 14 a. When the raw material mixture is press-fitted using the raw material mixture, the raw material mixture is heated from the inner cylinder 12 and / or the outer cylinder 13, and the gap 14 between the inner cylinder 12 and the outer cylinder 13 is formed into a thin film to form a discharge port 14b. To flow toward and discharged. At this time, when the two inner and outer cylinders 12 and 13 are relatively rotated, the raw material mixture introduced into the heating container 11 is in the gap 14 between the inner cylinder 12 and the outer cylinder 13 that rotate relatively. Flows in a direction (rotational axis direction) perpendicular to the relative movement direction (rotation direction) between the outer wall surface of the inner cylinder 12 and the inner wall surface of the outer cylinder 13, and is discharged from the discharge port 14b. In this apparatus, the width d of the gap 14 can be adjusted by the outer diameter dimension of the inner cylinder 12 and the inner diameter dimension of the outer cylinder 13, and the film thickness of the raw material mixture flowing in the gap 14 of the heating container 11 can be adjusted. In addition to the vapor pressure introduced into the jacket of the inner cylinder 12 and / or the outer cylinder 13 and the film thickness (width d of the gap 14), the heating condition is determined per unit time of the raw material mixture into the heating container 11. Can be adjusted by press-fitting amount (flow rate).

更に、複数の二重筒加熱装置10を連設する、または二重筒加熱装置10の排出口14bから排出された原料混合物を再度供給口14aに圧入することを繰り返して循環させることにより、原料混合物が目的とする特定量の2−アセチルフラン、5−メチルフルフラール、フルフラール、3−メチルブタナール、酢酸、ジメチルジスルフィド及び1−ブタノールを生成する加工状態になるまで、加熱処理を繰り返し行うこともできる。   Furthermore, by continuously circulating a plurality of double tube heating devices 10 or by repeatedly press-fitting the raw material mixture discharged from the discharge port 14b of the double tube heating device 10 into the supply port 14a, The heat treatment may be repeated until the mixture is processed to produce a specific amount of 2-acetylfuran, 5-methylfurfural, furfural, 3-methylbutanal, acetic acid, dimethyl disulfide and 1-butanol. it can.

加熱面に沿って薄膜状に流動する原料混合物の膜厚は、使用する加熱装置の構造にもより特に限定されないが、通常は0.5〜125mmの範囲内が好ましい。前記膜厚が厚すぎると、薄膜状で流動する原料混合物の内部まで均一に加熱ができず、加熱面から遠いところではメイラード反応が進行しにくくなるため品質にムラが生じ、2−アセチルフラン、5−メチルフルフラール、フルフラール及び3−メチルブタナールが所定の含有量にならず、目的とする乳風味増強効果を得ることができない場合がある。また、膜厚が薄すぎると、過熱により焦げ付き等が発生し、得られる乳風味増強剤の品質が低下する場合がある。原料混合物に対する加熱制御の容易さを考慮すると、前記膜厚は1mm〜30mmがより好ましく、2mm〜10mmが更に好ましい。   The film thickness of the raw material mixture that flows in a thin film along the heating surface is not particularly limited by the structure of the heating device to be used, but is usually preferably in the range of 0.5 to 125 mm. If the film thickness is too thick, it cannot be uniformly heated to the inside of the raw material mixture that flows in a thin film state, and the Maillard reaction is difficult to proceed at a distance from the heating surface, resulting in unevenness in quality, 2-acetylfuran, 5-methylfurfural, furfural and 3-methylbutanal may not have a predetermined content, and the intended milk flavor enhancing effect may not be obtained. On the other hand, if the film thickness is too thin, scorching or the like may occur due to overheating, and the quality of the obtained milk flavor enhancer may deteriorate. Considering easiness of heating control for the raw material mixture, the film thickness is more preferably 1 mm to 30 mm, further preferably 2 mm to 10 mm.

原料混合物を加熱する際の加熱温度は、最高到達品温が110〜160℃の範囲内になるように加熱することが好ましく、130〜160℃がより好ましく、140〜160℃が更に好ましい。加熱温度が110℃未満では2−アセチルフラン、5−メチルフルフラール、フルフラール及び3−メチルブタナールが所定の含有量にならず、目的とする乳風味増強効果を得ることができない場合がある。また、160℃を超えると、過熱により焦げ付き等が発生したり、酢酸や1−ブタノールの含有量が多くなり、風味が悪化する場合がある。   The heating temperature for heating the raw material mixture is preferably such that the highest product temperature is in the range of 110 to 160 ° C, more preferably 130 to 160 ° C, and still more preferably 140 to 160 ° C. When the heating temperature is less than 110 ° C., 2-acetylfuran, 5-methylfurfural, furfural and 3-methylbutanal do not have a predetermined content, and the intended milk flavor enhancing effect may not be obtained. On the other hand, when the temperature exceeds 160 ° C., scorching or the like may occur due to overheating, or the content of acetic acid or 1-butanol may increase and the flavor may deteriorate.

原料混合物を加熱する際の加熱時間は、上記最高到達品温に達温後、0.1秒〜5時間保持することが好ましく、1〜30分間保持することがより好ましい。加熱保持時間が0.1秒間よりも短いと2−アセチルフラン、5−メチルフルフラール、フルフラール及び3−メチルブタナールの含有量が少なく、目的とする乳風味増強剤を得ることができない場合がある。また、5時間を超えると、過熱により焦げ付き等が発生したり、風味が悪化する場合がある。   The heating time for heating the raw material mixture is preferably maintained for 0.1 second to 5 hours, more preferably 1 to 30 minutes after reaching the maximum product temperature. If the heat holding time is shorter than 0.1 seconds, the content of 2-acetylfuran, 5-methylfurfural, furfural and 3-methylbutanal is small, and the intended milk flavor enhancer may not be obtained. . Moreover, when it exceeds 5 hours, a burning etc. may generate | occur | produce by overheating, or flavor may deteriorate.

原料混合物の品温が75℃から上記最高到達品温に到達するまでの平均昇温速度は1〜100℃/分が好ましく、3〜50℃/分がより好ましく、3〜30℃/分が更に好ましい。平均昇温速度が1℃/分より遅いと過熱により焦げ付き等が発生したり、風味が悪化する場合があり、100℃/分より早いと均質に加熱できずに品質にムラが生じ、目的とする乳風味増強効果が得られない場合がある。   The average rate of temperature increase until the product temperature of the raw material mixture reaches the maximum product temperature from 75 ° C is preferably 1 to 100 ° C / min, more preferably 3 to 50 ° C / min, and 3 to 30 ° C / min. Further preferred. If the average rate of temperature rise is slower than 1 ° C / min, it may cause scorching due to overheating or the flavor may deteriorate. If it is faster than 100 ° C / min, it will not be able to heat homogeneously, resulting in uneven quality. The effect of enhancing milk flavor may not be obtained.

また、上記最高到達品温に到達後、所定の時間保持した後、品温が75℃に到達するまでの平均降温速度は、5〜200℃/分が好ましく、10〜150℃/分がより好ましく、30〜100℃/分が更に好ましい。平均降温速度が5℃/分より遅いと所定の温度に達するまで加熱反応が継続して起こり、過反応により酢酸や1−ブタノールが多く生成してしまい、風味が悪化する場合があり、200℃/分より早いと工業的に生産するのが困難になる場合がある。   In addition, the average temperature decreasing rate until the product temperature reaches 75 ° C. after being held for a predetermined time after reaching the maximum product temperature is preferably 5 to 200 ° C./min, more preferably 10 to 150 ° C./min. Preferably, 30-100 degreeC / min is still more preferable. If the average temperature-decreasing rate is slower than 5 ° C / min, the heating reaction continues until a predetermined temperature is reached, and a large amount of acetic acid or 1-butanol is produced due to overreaction, which may deteriorate the flavor. If it is faster than / min, it may be difficult to produce industrially.

以上のようにして製造した混合加熱物を、そのまま本発明の乳風味増強剤としてもよいし、混合加熱物に、上述したような他の成分を添加し、常法により混合して本発明の乳風味増強剤を製造することもできる。   The mixed heated product produced as described above may be used as it is as the milk flavor enhancer of the present invention, or other components as described above are added to the mixed heated product and mixed by a conventional method. Milk flavor enhancers can also be produced.

本発明の乳風味増強剤はパン・菓子用乳風味増強剤であり、パン生地もしくは菓子生地に配合して使用するか、または、パン・菓子練り込み用油中水型乳化油脂組成物もしくはパン・菓子練り込み用水中油型乳化油脂組成物に配合して、これら組成物をパン生地もしくは菓子生地に練り込むために使用することができる。なお、本願における「練り込み用」には通常の練り込み用途に加えて、折り込み用途も含むものとする。   The milk flavor enhancer of the present invention is a milk flavor enhancer for bread and confectionery, and is used by blending with bread dough or confectionery dough, or a water-in-oil emulsified fat composition or bread It can mix | blend with the oil-in-water type emulsified oil-fat composition for confectionery kneading | mixing, and can use these compositions for kneading | mixing to bread dough or confectionery dough. Note that “for kneading” in the present application includes not only a normal kneading use but also a folding use.

本発明のパンは、穀粉、本発明の乳風味増強剤、乳固形分、油脂、パン酵母及び水分をそれぞれ特定量配合した原材料を混捏して作製したパン生地を加熱調理して得られるものを言い、例えば、食パン、あんパンやクリームパンの菓子パン、ロールパン、フランスパン等の堅焼きパン、デニッシュペストリー、クロワッサン、デニッシュブレッド等の層状膨化パン、バラエティブレッド、サンドイッチ等の調理パン、蒸しパン、またはそれらの二次加工品、或いはレンジ調理を必要とするもの等が挙げられる。   The bread of the present invention refers to a product obtained by heating and cooking bread dough prepared by mixing raw materials containing specific amounts of flour, milk flavor enhancer of the present invention, milk solids, fats and oils, baker's yeast and water, respectively. Baked bread such as bread, bun, cream bread, roll bread, French bread, etc., layered bread such as Danish pastries, croissants, Danish bread, cooking bread such as variety red, sandwich, steamed bread, or those Secondary processed products, or those requiring range cooking.

前記穀粉は、食用であれば特に限定はないが、例えば、小麦、米、とうもろこし、馬鈴薯、タピオカ、甘藷など、或いはそれらを由来とする澱粉及びその加工澱粉が例示でき、それらの群より選ばれる少なくとも1種を使用することができる。そして、該穀粉中には、小麦粉を80重量%以上含有することが好ましい。前記小麦粉は、例えば、強力粉、中力粉、薄力粉等が挙げられ、それらの群より選ばれる少なくとも1種を使用することができるが、蛋白質含量の多い強力粉を使用することが望ましく、強力粉の含量は前記小麦粉中、50〜100重量%が好ましく、60〜100重量%がより好ましく、70〜100重量%が更に好ましい。   The flour is not particularly limited as long as it is edible, and examples thereof include wheat, rice, corn, potato, tapioca, sweet potato, etc., or starch derived therefrom and processed starch thereof, and are selected from these groups At least one can be used. And it is preferable to contain 80 weight% or more of wheat flour in this flour. Examples of the flour include strong flour, medium flour, and weak flour, and at least one selected from the group can be used, but it is desirable to use strong flour with a high protein content, Is preferably 50 to 100% by weight, more preferably 60 to 100% by weight, and still more preferably 70 to 100% by weight in the flour.

本発明において、パン生地中の乳風味増強剤の含有量は、良好な乳風味増強効果を達成するために、前記穀粉100重量部に対して、乾燥重量で0.0001〜3重量部が好ましく、0.001〜1重量部がより好ましく、0.005〜0.1重量部が更に好ましい。   In the present invention, the content of the milk flavor enhancer in the bread dough is preferably 0.0001 to 3 parts by weight in dry weight with respect to 100 parts by weight of the flour in order to achieve a good milk flavor enhancing effect, 0.001-1 weight part is more preferable and 0.005-0.1 weight part is still more preferable.

前記乳固形分としては、例えば、バター、乳脂肪、牛乳、クリーム、脱脂乳、バターミルク、脱脂粉乳、全脂粉乳、バターミルクパウダー、ホエー蛋白質、カゼイン蛋白質、乳清ミネラル、加糖練乳、無糖練乳、チーズ等やこれら乳固形分のリパーゼ処理物が挙げられる。前記乳固形分の含有量は、パン生地中の穀粉100重量部に対して、乾燥重量で0.005〜50重量部が好ましく、0.01〜35重量部がより好ましく、0.05〜10重量部が更に好ましく、0.5〜5重量部が特に好ましい。乳固形分の含有量が0.005重量部以上であると、より好ましい乳風味を達成することができる。また、含有量が多すぎるとコストがかかりすぎる場合がある。   Examples of the milk solids include butter, milk fat, milk, cream, skim milk, butter milk, skim milk powder, whole milk powder, butter milk powder, whey protein, casein protein, whey mineral, sweetened condensed milk, and sugar-free milk Examples include condensed milk, cheese and lipase-treated products of these milk solids. The content of the milk solid content is preferably 0.005 to 50 parts by weight, more preferably 0.01 to 35 parts by weight, and more preferably 0.05 to 10 parts by weight with respect to 100 parts by weight of flour in the dough. Part is more preferable, and 0.5 to 5 parts by weight is particularly preferable. More preferable milk flavor can be achieved as content of milk solids is 0.005 weight part or more. Moreover, when there is too much content, it may cost too much.

また、前記乳固形分の少なくとも一部に、乳固形分のリパーゼ処理物を配合することが好ましい。前記乳固形分のリパーゼ処理物は、乳脂肪、乳蛋白質及び水を主成分とする混合物のリパーゼ処理物を言う。   Moreover, it is preferable to mix | blend the lipase processed material of milk solid content with at least one part of the said milk solid content. The lipase-treated product of milk solids refers to a lipase-treated product of a mixture mainly composed of milk fat, milk protein and water.

前記リパーゼ処理物中の乳脂肪は、生クリームやバターなどから水相部分を除去して得られるものを意味し、前記リパーゼ処理物全体中10〜99.8重量%が好ましく、20〜80重量%がより好ましく、30〜70重量%がより好ましく、40〜60重量%が更に好ましい。含有量が10重量%より少ないとより好ましい乳風味増強効果が得られない場合があり、99.8重量%より多いと脂肪分解臭が強く、逆に乳風味増強効果が低減する場合がある。   The milk fat in the lipase-treated product means one obtained by removing the aqueous phase from fresh cream or butter, and preferably 10 to 99.8% by weight in the whole lipase-treated product. % Is more preferable, 30 to 70% by weight is more preferable, and 40 to 60% by weight is still more preferable. When the content is less than 10% by weight, a more preferable milk flavor enhancing effect may not be obtained. When the content is more than 99.8% by weight, the lipolytic odor is strong, and on the contrary, the milk flavor enhancing effect may be reduced.

前記リパーゼ処理物中の乳蛋白質は、生乳に含まれる蛋白質を意味し、カゼイン、β−ラクトグロブリン、α−ラクトアルブミン、ラクトフェリン、血清アルブミン及び免疫グロブリンなどが挙げられ、前記リパーゼ処理物全体中0.1〜50重量%が好ましく、0.1〜30重量%がより好ましく、0.1〜10重量%がより好ましく、0.1〜3重量%が更に好ましい。含有量が0.1重量%より少ないとより好ましい乳風味増強効果が得られない場合があり、50重量%より多いと逆に乳風味増強効果が低減する場合がある。   The milk protein in the lipase-treated product means a protein contained in raw milk, and examples thereof include casein, β-lactoglobulin, α-lactalbumin, lactoferrin, serum albumin, and immunoglobulin. 0.1 to 50% by weight is preferable, 0.1 to 30% by weight is more preferable, 0.1 to 10% by weight is more preferable, and 0.1 to 3% by weight is still more preferable. When the content is less than 0.1% by weight, a more preferable milk flavor enhancing effect may not be obtained. When the content is more than 50% by weight, the milk flavor enhancing effect may be reduced.

前記リパーゼ処理物中の水分量は、前記リパーゼ処理物全体中0.1〜70重量%が好ましく、0.1〜40重量%がより好ましく、0.1〜30重量%がより好ましく、0.1〜20重量%が更に好ましい。含有量が0.1重量%より少ないとより好ましい乳風味増強効果が得られない場合があり、70重量%より多いと逆に乳風味増強効果が低減する場合がある。   The water content in the lipase-treated product is preferably from 0.1 to 70% by weight, more preferably from 0.1 to 40% by weight, more preferably from 0.1 to 30% by weight, based on the whole lipase-treated product. 1 to 20% by weight is more preferable. When the content is less than 0.1% by weight, a more preferable milk flavor enhancing effect may not be obtained, and when it is more than 70% by weight, the milk flavor enhancing effect may be reduced.

前記リパーゼ処理物で使用するリパーゼは、脂質を構成するエステル結合を加水分解する酵素のことを言い、例えば、Aspergillus niger、Candida rugosa、Candida lipolytica、Rhizopus oryzae、Penicillium camembertii、Penicillium roqueforti、Mucor javanicusなどの微生物由来の酵素や、子牛舌下腺、膵臓からの抽出物などが例示できる。   The lipase used in the lipase-treated product refers to an enzyme that hydrolyzes an ester bond that constitutes a lipid.For example, Aspergillus niger, Candida rugosa, Candida lipolytica, Rhizopus oryzae, Penicillium camembertii, Penicillium roqueforti, Mucor javanicus Examples include microorganism-derived enzymes, calf sublingual glands, and pancreas extracts.

前記リパーゼ処理物は、以下に例示する製造方法により得ることができる。即ち、融解した前記乳脂肪に、前記乳蛋白質及び水を混合して、前記リパーゼの至適温度±20℃に温調した混合物100重量部に対して、前記リパーゼを0.0001〜5重量部添加し、攪拌しながら1〜300時間保持して処理することで得られる。処理の度合いは、リパーゼによる油脂の分解度で、2〜90%が好ましく、5〜50%がより好ましい。油脂の分解度が2%より小さいと、本発明の乳風味増強効果が劣る場合があり、また90%より大きいと異味が付与される場合がある。なお、油脂の分解度とは〔{(酸価)/(けん化価)}×100〕によって求められる値を言う。前記リパーゼ処理物は、市販で入手できるものとして、「CFI740」(The TATUA Co-operative Dairy Company製)、「バターフレーバーBF−S」(森永乳業(株)社製)、「BUTTER BUDS HIGH CONCENTRATE UNCOLORED」(ButterBuds Inc.製)、「バタロンパウダー」(横山香料(株)社製)などが例示でき、これらを適宜使用することができる。   The lipase-treated product can be obtained by the production method exemplified below. That is, 0.0001 to 5 parts by weight of the lipase is mixed with 100 parts by weight of the mixture obtained by mixing the milk protein and water with the melted milk fat and adjusting the temperature to the optimum temperature of the lipase ± 20 ° C. It is obtained by adding and holding for 1 to 300 hours while stirring. The degree of treatment is the degree of degradation of fats and oils by lipase, preferably 2 to 90%, more preferably 5 to 50%. If the degree of degradation of fats and oils is less than 2%, the milk flavor enhancing effect of the present invention may be inferior, and if it is greater than 90%, a taste may be imparted. In addition, the decomposition degree of fats and oils means the value calculated | required by [{(acid value) / (saponification value)} * 100]. As the lipase-treated product, “CFI740” (manufactured by The TATUA Co-operative Dairy Company), “butter flavor BF-S” (manufactured by Morinaga Milk Industry Co., Ltd.), “BUTTER BUDS HIGH CONCENTRATE UNCOLORED” "(ButterBuds Inc.)", "Batalon powder" (Yokoyama Fragrance Co., Ltd.) and the like can be used as appropriate.

前記リパーゼ処理物の含量は、前記乳固形分中、0.1〜100重量%が好ましく、0.1〜60重量%がより好ましく、0.1〜40重量%が更に好ましい。0.1重量%より少ないとより好ましい乳風味増強効果が得られない場合がある。   The content of the lipase-treated product is preferably 0.1 to 100% by weight, more preferably 0.1 to 60% by weight, and still more preferably 0.1 to 40% by weight in the milk solid content. If it is less than 0.1% by weight, a more preferable milk flavor enhancing effect may not be obtained.

また、前記パン生地中、本発明の乳風味増強剤/前記リパーゼ処理物の含有量比は、99/1〜15/85(乾燥重量比)が好ましく、99/1〜30/70(乾燥重量比)がより好ましく、99/1〜40/60(乾燥重量比)が更に好ましい。含有量比が99/1より大きい、或いは15/85より小さいとより好ましい乳風味増強効果が得られない場合がある。   In the bread dough, the content ratio of the milk flavor enhancer of the present invention / the lipase-treated product is preferably 99/1 to 15/85 (dry weight ratio), and 99/1 to 30/70 (dry weight ratio). ) Is more preferable, and 99/1 to 40/60 (dry weight ratio) is still more preferable. If the content ratio is larger than 99/1 or smaller than 15/85, a more preferable milk flavor enhancing effect may not be obtained.

前記油脂は、従来マーガリンやショートニング等に使用されるいかなる油脂を使用してもよく、例えば、パーム油、パーム核油、ヤシ油、サフラワー油、向日葵油、綿実油、菜種油、コーン油、大豆油、米糠油、オリーブ油、カカオ脂、シア脂等の植物油脂や、魚油、牛脂、乳脂、豚脂等の動物油脂、また、これらの油脂をエステル交換したものや、硬化、分別したもの等が挙げられる。   The fats and oils may be any fats and oils conventionally used for margarine, shortening, etc., for example, palm oil, palm kernel oil, palm oil, safflower oil, sunflower oil, cottonseed oil, rapeseed oil, corn oil, soybean oil , Vegetable oils such as rice bran oil, olive oil, cacao butter, shea butter, animal oils such as fish oil, beef tallow, milk fat, pork tallow, and those obtained by transesterification, hardening, and fractionation of these oils It is done.

前記パン生地中の油脂の含有量は、練り込み用途として使用する場合、前記穀粉100重量部に対して、2〜40重量部が好ましく、5〜40重量部がより好ましく、8〜30重量部が更に好ましい。含有量が2重量部より少ないと、生地の伸展性が低下したり、出来たパンが硬くなる場合があり、40重量部を超えると、生地作製時にダレが生じたり、焼成後のパンから油のしみ出しが見られたり、食感が悪い場合がある。また前記油脂の含有量は、折り込み用途として使用する場合、前記穀粉100重量部に対して、30〜100重量部が好ましく、30〜80重量部がより好ましく、40〜60重量部が更に好ましい。含有量が30重量部より少ないと、生地の伸展性が低下したり、出来たパンのボリュームが小さかったり、食感が悪い場合があり、100重量部を超えると、生地作製時にダレが生じたり、焼成後のパンから油のしみ出しが見られたり、食感が悪い場合がある。   When used as a kneading application, the content of fats and oils in the bread dough is preferably 2 to 40 parts by weight, more preferably 5 to 40 parts by weight, and 8 to 30 parts by weight with respect to 100 parts by weight of the flour. Further preferred. If the content is less than 2 parts by weight, the extensibility of the dough may be reduced or the resulting bread may be hardened. If the content exceeds 40 parts by weight, sagging may occur during preparation of the dough, or oil from the baked bread Exudation may be seen or texture may be bad. Moreover, 30-100 weight part is preferable with respect to 100 weight part of said flours, when content of the said fats and oils is used as a folding use, 30-80 weight part is more preferable, and 40-60 weight part is still more preferable. If the content is less than 30 parts by weight, the extensibility of the dough may decrease, the volume of the resulting bread may be small, or the texture may be poor, and if it exceeds 100 parts by weight, sagging may occur during the preparation of the dough In some cases, oil oozes out from the baked bread or has a bad texture.

前記パン生地に使用するパン酵母は、糖を資化して炭酸ガスおよびアルコールを生成し、有機酸および香気成分をも生成する微生物をいい、例えば、サッカロミセス・セレビシエなど、通常製パンに使用する酵母等を用いることができる。前記パン酵母の添加量は、穀粉100重量部に対して、乾燥重量換算で0.2〜2.0重量部が好ましく、0.4〜1.5重量部がより好ましい。添加量が0.2重量部より少ないと、発酵に時間がかかり生産効率が悪い場合がある。また2.0重量部より多いと、パン酵母自体の好ましくない風味が付与される場合がある。   The baker's yeast used for the bread dough refers to a microorganism that assimilate sugars to produce carbon dioxide and alcohol, and also produces organic acids and aroma components, such as Saccharomyces cerevisiae, yeast used for normal bread production, etc. Can be used. The addition amount of the baker's yeast is preferably 0.2 to 2.0 parts by weight, more preferably 0.4 to 1.5 parts by weight in terms of dry weight with respect to 100 parts by weight of flour. If the amount added is less than 0.2 parts by weight, fermentation may take time and production efficiency may be poor. Moreover, when more than 2.0 weight part, the unpleasant flavor of baker's yeast itself may be provided.

前記パン生地への水の添加量は、前記穀粉100重量に対して25〜60重量部が好ましく、30〜50重量部がより好ましい。添加量が25重量部より少ないと、出来たパンの食感がぱさつく場合があり、60重量部より多いと、焼成前の生地がべたついたり、混捏時間が長くなる場合がある。   The amount of water added to the bread dough is preferably 25 to 60 parts by weight and more preferably 30 to 50 parts by weight with respect to 100 parts by weight of the flour. If the amount added is less than 25 parts by weight, the texture of the resulting bread may become crispy, and if it exceeds 60 parts by weight, the dough before baking may become sticky or the kneading time may become longer.

本発明のパン生地には、前記以外の原料として、糖類、食塩、アミラーゼなどの酵素類、卵、増粘多糖類及び乳化剤などの材料を配合することができる。   In the bread dough of the present invention, materials other than the above, such as sugars, salt, enzymes such as amylase, eggs, thickening polysaccharides and emulsifiers can be blended.

本発明のパンの製造方法は、常法に従えば良いが、以下に例示する。パンは、前記穀粉と、本発明の乳風味増強剤、乳固形分、油脂、パン酵母、水及び必要に応じてその他の卵、糖類などを原料とし、ノータイム法、ストレート法、中種法、冷蔵中種法、冷凍生地製法など一般的な製パン工程を通じてパン生地を調製した後、該生地を加熱調理することで、容易に乳脂肪感、乳の甘味、濃厚な乳感とコク等の乳風味を有するパンを得ることができる。   Although the bread manufacturing method of this invention should just follow a conventional method, it illustrates below. Bread is made from the above flour and the milk flavor enhancer of the present invention, milk solids, fats and oils, baker's yeast, water and other eggs, sugars as necessary, no time method, straight method, medium seed method, After preparing bread dough through a general bread making process such as refrigerated middle seed method, frozen dough manufacturing method, etc., the dough is cooked and cooked easily, milk fat feeling, milk sweetness, rich milk feeling and rich milk etc. A bread having a flavor can be obtained.

本発明の菓子は、穀粉、本発明の乳風味増強剤、乳固形分及び油脂をそれぞれ特定量配合した原材料を混捏して作製した菓子生地を加熱調理して得られるものを言い、例えば、例えば、クッキー、ビスケット、クラッカー、プレッツェル、バターケーキ、スポンジケーキ、パイ等が挙げられる。   The confectionery of the present invention refers to a product obtained by heating and cooking a confectionery dough prepared by mixing raw materials containing specific amounts of flour, the milk flavor enhancer of the present invention, milk solids and fats, for example, , Cookies, biscuits, crackers, pretzels, butter cakes, sponge cakes, pies and the like.

前記菓子生地中の穀粉は、前記パンで使用する穀粉と同様の物であり、該穀粉中には、同様に小麦粉を80重量%以上含有することが好ましい。そして前記小麦粉は、例えば、強力粉、中力粉、薄力粉等が挙げられ、それらの群より選ばれる少なくとも1種を使用することができるが、パンとは異なり蛋白質含量の少ない薄力粉を使用することが望ましく、薄力粉の含量は前記小麦粉中、50〜100重量%が好ましく、60〜100重量%がより好ましく、70〜100重量%が更に好ましい。   The flour in the confectionery dough is the same as the flour used in the bread, and the flour preferably contains 80% by weight or more of wheat flour. The wheat flour includes, for example, strong flour, medium flour, thin flour, etc., and at least one selected from these groups can be used, but unlike bread, it is possible to use weak flour with a low protein content. Desirably, the flour content is preferably 50 to 100% by weight, more preferably 60 to 100% by weight, and still more preferably 70 to 100% by weight in the flour.

本発明において、菓子生地中の乳風味増強剤の含有量は、良好な乳風味増強効果を達成するために、前記穀粉100重量部に対して、乾燥重量で0.001〜10重量部が好ましく、0.005〜1重量部がより好ましく、0.008〜0.8重量部が更に好ましい。   In the present invention, the content of the milk flavor enhancer in the confectionery dough is preferably 0.001 to 10 parts by weight in dry weight with respect to 100 parts by weight of the flour in order to achieve a good milk flavor enhancing effect. 0.005 to 1 part by weight is more preferable, and 0.008 to 0.8 part by weight is still more preferable.

前記菓子生地中の乳固形分は、前記パンで使用する乳固形分と同様の物であり、その含有量は、菓子生地中の穀粉100重量部に対して、乾燥重量で0.005〜120重量部が好ましく、0.01〜100重量部がより好ましく、0.1〜80重量部が更に好ましく、1〜50重量部が特に好ましい。乳固形分の含有量が0.005重量部以上であると、より好ましい乳風味を達成することができる。また、含有量が多すぎるとコストがかかりすぎる場合がある。   The milk solid content in the confectionery dough is the same as the milk solid content used in the bread, and the content thereof is 0.005 to 120 by dry weight with respect to 100 parts by weight of flour in the confectionery dough. Parts by weight are preferred, 0.01-100 parts by weight are more preferred, 0.1-80 parts by weight are still more preferred, and 1-50 parts by weight are particularly preferred. More preferable milk flavor can be achieved as content of milk solids is 0.005 weight part or more. Moreover, when there is too much content, it may cost too much.

また、前記乳固形分の少なくとも一部として、前記乳固形分のリパーゼ処理物を配合することが好ましい。前記乳固形分のリパーゼ処理物は、前記パンで使用した乳固形分のリパーゼ処理物と同様の物であり、前記リパーゼ処理物の含量は、前記乳固形分中0.1〜100重量%が好ましく、0.1〜60重量%がより好ましく、0.1〜40重量%が更に好ましい。0.1重量%より少ないとより好ましい乳風味増強効果が得られない場合がある。   Moreover, it is preferable to mix | blend the lipase processed material of the said milk solid content as at least one part of the said milk solid content. The lipase-treated product of milk solids is the same product as the lipase-treated product of milk solids used in the bread, and the content of the lipase-treated product is 0.1 to 100% by weight in the milk solids. Preferably, 0.1 to 60% by weight is more preferable, and 0.1 to 40% by weight is still more preferable. If it is less than 0.1% by weight, a more preferable milk flavor enhancing effect may not be obtained.

また、前記菓子生地中、本発明の乳風味増強剤と前記リパーゼ処理物の含有量比は、99/1〜15/85(乾燥重量比)が好ましく、99/1〜30/70(乾燥重量比)がより好ましく、99/1〜40/60(乾燥重量比)が更に好ましい。含有量比が99/1より大きい、或いは15/85より小さいとより好ましい乳風味増強効果が得られない場合がある。   In the confectionery dough, the content ratio of the milk flavor enhancer of the present invention to the lipase-treated product is preferably 99/1 to 15/85 (dry weight ratio), and 99/1 to 30/70 (dry weight). Ratio) is more preferable, and 99/1 to 40/60 (dry weight ratio) is still more preferable. If the content ratio is larger than 99/1 or smaller than 15/85, a more preferable milk flavor enhancing effect may not be obtained.

前記菓子生地中の油脂は、前記パンで使用する油脂と同様であり、その含有量は、練り込み用途として使用する場合、前記穀粉100重量部に対して、15〜200重量部が好ましく、25〜150重量部がより好ましく、35〜100重量部が更に好ましい。含有量が15重量部より少ないと、生地の伸展性が低下したり、出来た菓子が硬くなる場合があり、200重量部を超えると、生地作製時にダレが生じたり、焼成後の菓子から油のしみ出しが見られたり、食感が悪い場合がある。また前記油脂の含有量は、折り込み用途として使用する場合、前記穀粉100重量部に対して、30〜150重量部が好ましく、40〜100重量部がより好ましく、50〜100重量部が更に好ましい。含有量が30重量部より少ないと、生地の伸展性が低下したり、出来た菓子のボリュームが小さかったり、食感が悪い場合があり、150重量部を超えると、生地作製時にダレが生じたり、焼成後の菓子から油のしみ出しが見られたり、食感が悪い場合がある。   The fats and oils in the confectionery dough are the same as the fats and oils used in the bread, and the content is preferably 15 to 200 parts by weight with respect to 100 parts by weight of the flour when used for kneading, 25 -150 weight part is more preferable, and 35-100 weight part is still more preferable. If the content is less than 15 parts by weight, the extensibility of the dough may be reduced or the resulting confectionery may become hard. If the content exceeds 200 parts by weight, sagging may occur during preparation of the dough, or oil from the baked confectionery Exudation may be seen or texture may be bad. Moreover, 30-150 weight part is preferable with respect to 100 weight part of said flours, when content of the said fats and oils is used for a folding use, 40-100 weight part is more preferable, and 50-100 weight part is still more preferable. If the content is less than 30 parts by weight, the extensibility of the dough may decrease, the volume of the resulting confectionery may be small, or the texture may be poor, and if it exceeds 150 parts by weight, sagging may occur during the preparation of the dough In some cases, the baked confectionery seeps oil, and the texture is poor.

本発明の菓子生地には、前記以外の原料として、糖類、卵、増粘多糖類、アミラーゼなどの酵素類、乳化剤及び水などの材料を配合することができる。   In the confectionery dough of the present invention, materials such as sugars, eggs, thickening polysaccharides, enzymes such as amylase, emulsifiers and water can be blended as raw materials other than those described above.

本発明の菓子の製造方法は、常法に従えば良いが、以下に例示する。菓子は、前記穀粉と、本発明の乳風味増強剤、乳固形分、油脂及び必要に応じてその他の卵、糖類などを原料とし、オールインミックス法、後粉法、シュガーバッター法、フラワーバッター法等、公知の方法に準じて菓子生地を調製した後、該生地を加熱調理することで、容易に乳脂肪感、乳の甘味、濃厚な乳感とコク等の乳風味を有する菓子を得ることができる。   Although the manufacturing method of the confectionery of this invention should just follow a conventional method, it illustrates below. The confectionery uses the above-mentioned flour, the milk flavor enhancer of the present invention, milk solids, fats and oils and other eggs and sugars as necessary, and the all-in-mix method, the post-powder method, the sugar batter method, the flower batter After preparing the confectionery dough according to a known method such as a method, the dough is heated and cooked to easily obtain a confectionery having milk fat feeling, milk sweetness, rich milk feeling and rich milk taste such as richness be able to.

本発明の乳風味増強剤に乳固形分、油脂、及び水等を配合して、本発明の油中水型乳化油脂組成物、又は水中油型乳化油脂組成物を製造することができる。本発明の油中水型乳化油脂組成物、又は水中油型乳化油脂組成物はパン・菓子練り込み用の組成物であり、前記パン生地および菓子生地を作製するに際しては、本発明の乳風味増強剤に替えて、このような油中水型乳化油脂組成物又は水中油型乳化油脂組成物を配合することもできる。また、パン生地又は菓子生地には、該油中水型乳化油脂組成物又は水中油型乳化油脂組成物に加えて、本発明の乳風味増強剤、油脂、乳固形分などを配合しても良い。さらに、本発明の油中水型乳化油脂組成物又は水中油型乳化油脂組成物には、前記記載の原材料の他に、必要に応じて、糖類、食塩、乳化剤、増粘剤、香料、酸化剤及び各種酵素などを配合することもできる。   Milk solid content, fats and oils, water, etc. are mix | blended with the milk flavor enhancer of this invention, and the water-in-oil type emulsified fat composition of this invention or the oil-in-water type emulsified fat composition can be manufactured. The water-in-oil emulsified oil or fat composition of the present invention or the oil-in-water emulsified oil and fat composition is a composition for kneading bread and confectionery, and in producing the bread dough and confectionery dough, the milk flavor enhancement of the present invention It can replace with an agent and can mix | blend such a water-in-oil emulsified fat composition or an oil-in-water emulsified fat composition. In addition to the water-in-oil emulsified oil composition or oil-in-water emulsified oil composition, the bread dough or confectionery dough may be blended with the milk flavor enhancer of the present invention, fats and oils, milk solids, and the like. . Furthermore, in the water-in-oil emulsified oil or fat composition or the oil-in-water emulsified oil and fat composition of the present invention, in addition to the raw materials described above, sugars, salt, emulsifiers, thickeners, fragrances, oxidizers, as necessary Agents and various enzymes can also be added.

前記油中水型乳化油脂組成物は、油脂を含有する油相部と、前記乳風味増強剤、前記乳固形分及び水分を含有する水相部からなる。   The water-in-oil emulsified oil / fat composition comprises an oil phase part containing oil and fat, and an aqueous phase part containing the milk flavor enhancer, the milk solid content and water.

前記油中水型乳化油脂組成物中の油脂の種類は、前記パンや菓子中の油脂と同様であり、その含有量は、前記油中水型乳化油脂組成物中40〜97重量%が好ましく、50〜95重量%がより好ましく、60〜85重量%が更に好ましい。含有量が40重量%より少ないと、パン生地又は菓子生地に油中水型乳化油脂組成物を練り込むための好ましい物性を得ることができない場合がある。また含有量が97重量%を超えると、好ましい風味を付与するに十分な水溶性風味素材を添加することができない場合がある。   The types of fats and oils in the water-in-oil emulsified fat composition are the same as those in the bread and confectionery, and the content is preferably 40 to 97% by weight in the water-in-oil emulsified fat composition. 50 to 95% by weight is more preferable, and 60 to 85% by weight is still more preferable. When the content is less than 40% by weight, it may not be possible to obtain preferable physical properties for kneading the water-in-oil emulsified fat composition into bread dough or confectionery dough. Moreover, when content exceeds 97 weight%, water-soluble flavor raw material sufficient to provide a preferable flavor may not be added.

前記油中水型乳化油脂組成物中の乳風味増強剤の含有量は、良好な乳風味増強効果を達成するために、前記油中水型乳化油脂組成物中、乾燥重量で0.015〜5重量%が好ましく、0.03〜3重量%がより好ましく、0.1〜1重量%が更に好ましい。   The content of the milk flavor enhancer in the water-in-oil emulsified fat composition is 0.015 by dry weight in the water-in-oil emulsified fat composition in order to achieve a good milk flavor enhancing effect. 5 weight% is preferable, 0.03 to 3 weight% is more preferable, and 0.1 to 1 weight% is still more preferable.

前記油中水型乳化油脂組成物中の乳固形分は、前記パンや菓子中の乳固形分と同様の物であり、その含有量は、前記油中水型乳化油脂組成物全体中、乾燥重量で0.1〜70重量%が好ましく、0.5〜50重量%がより好ましく、1〜30重量%が更に好ましい。乳固形分の含有量が0.1重量%以上であると、より好ましい乳風味を達成することができる。また、含有量が多すぎるとコストがかかりすぎる場合がある。なお、乳脂肪は乳固形分と油脂のいずれにも該当するため、前記油中水型乳化油脂組成物に乳脂肪を配合する場合には、上述した乳固形分の含量及び油脂の含有量のいずれを算出する際にも、乳脂肪の含有量を考慮するものとする。   The milk solid content in the water-in-oil emulsified oil / fat composition is the same as the milk solid content in the bread or confectionery, and the content thereof is dried in the whole water-in-oil emulsified oil / fat composition. 0.1 to 70% by weight is preferred, 0.5 to 50% by weight is more preferred, and 1 to 30% by weight is even more preferred. When the milk solid content is 0.1% by weight or more, a more preferable milk flavor can be achieved. Moreover, when there is too much content, it may cost too much. In addition, since milk fat corresponds to both milk solid content and fats and oils, when mix | blending milk fat with the said water-in-oil type emulsified fat composition, content of the above-mentioned milk solid content and fat content In calculating any of them, the content of milk fat is considered.

前記水の含有量は、前記油中水型乳化油脂組成物中、2〜55重量%が好ましく、3〜40重量%がより好ましく、4〜30重量%が更に好ましい。含有量が2重量%より少ないと前記乳風味増強剤や乳固形分を溶解できず生産が困難となる場合があり、55重量%より多いと乳化が不安定になって、製造時に離水し安定的に生産することが困難となる場合がある。   The water content is preferably 2 to 55% by weight, more preferably 3 to 40% by weight, and still more preferably 4 to 30% by weight in the water-in-oil emulsified oil / fat composition. If the content is less than 2% by weight, the milk flavor enhancer and the milk solids may not be dissolved and production may be difficult. If the content is more than 55% by weight, the emulsification becomes unstable and the water is stable during production. Production may be difficult.

本発明の油中水型乳化油脂組成物の製造方法は、通常の油中水型油脂組成物と同様の方法で実施すれば良いが、以下に例示する。まず、50〜80℃に加温融解した油脂に油溶性原料を混合して油相部を得る。一方、50〜70℃の温水に、前記乳風味増強剤、乳固形分などの水系原料を攪拌溶解して水相部を得る。前記油相部に前記水相部を添加し、予備乳化した乳化液を、急冷捏和装置にて捏和して、本発明の油中水型乳化油脂組成物を得る。   Although the manufacturing method of the water-in-oil type emulsified oil-fat composition of this invention may be implemented by the method similar to a normal water-in-oil type oil-fat composition, it illustrates below. First, an oil-soluble raw material is mixed with fats and oils heated and melted at 50 to 80 ° C. to obtain an oil phase part. On the other hand, a water phase part is obtained by stirring and dissolving aqueous raw materials such as the milk flavor enhancer and milk solids in hot water of 50 to 70 ° C. The water phase part is added to the oil phase part, and the pre-emulsified emulsion is kneaded with a quenching kneader to obtain the water-in-oil emulsified fat composition of the present invention.

前記水中油型乳化油脂組成物は、油脂を含有する油相部と、前記乳風味増強剤、前記乳固形分及び水分を含有する水相部からなる。   The oil-in-water emulsified oil / fat composition comprises an oil phase part containing oil and fat, and an aqueous phase part containing the milk flavor enhancer, the milk solids and water.

前記水中油型乳化油脂組成物中の油脂の種類は、前記パンや菓子中の油脂と同様であり、その含有量は、前記水中型油乳化油脂組成物中5〜60重量%が好ましく、10〜50重量%がより好ましく、15〜45重量%が更に好ましい。含有量が5重量%より少ないと、目的とする乳風味増強効果が十分に得られない場合がある。また含有量が60重量%を超えると、パン生地又は菓子生地に水中油型乳化油脂組成物を練り込むための好ましい物性を得ることができない場合がある。   The types of fats and oils in the oil-in-water emulsified oil and fat composition are the same as those in the bread and confectionery, and the content is preferably 5 to 60% by weight in the water-in-oil emulsified oil and fat composition. -50 wt% is more preferable, and 15-45 wt% is still more preferable. If the content is less than 5% by weight, the intended milk flavor enhancement effect may not be sufficiently obtained. Moreover, when content exceeds 60 weight%, the preferable physical property for kneading an oil-in-water-type emulsified fat composition to bread dough or confectionery dough may not be obtained.

前記水中油型乳化油脂組成物中の乳風味増強剤の含有量は、良好な乳風味増強効果を達成するために、前記水中油型乳化油脂組成物中、乾燥重量で0.015〜5重量%が好ましく、0.03〜3重量%がより好ましく、0.1〜1重量%が更に好ましい。   The content of the milk flavor enhancer in the oil-in-water emulsified oil / fat composition is 0.015 to 5% by dry weight in the oil-in-water emulsified oil / fat composition in order to achieve a good milk flavor enhancing effect. % Is preferred, 0.03 to 3% by weight is more preferred, and 0.1 to 1% by weight is even more preferred.

前記水中油型乳化油脂組成物中の乳固形分は、前記パンや菓子中の乳固形分と同様の物であり、その含有量は、前記水中油型乳化油脂組成物全体中、乾燥重量で0.1〜70重量%が好ましく、0.5〜50重量%がより好ましく、1〜30重量%が更に好ましい。乳固形分の含有量が0.1重量%以上であると、より好ましい乳風味を達成することができる。また、含有量が多すぎるとコストがかかりすぎる場合がある。なお、乳脂肪は乳固形分と油脂のいずれにも該当するため、前記水中油型乳化油脂組成物に乳脂肪を配合する場合には、上述した乳固形分の含量及び油脂の含有量のいずれを算出する際にも、乳脂肪の含有量を考慮するものとする。   The milk solid content in the oil-in-water emulsified oil / fat composition is the same as the milk solid content in the bread and confectionery, and its content is the dry weight in the whole oil-in-water emulsified oil / fat composition. 0.1 to 70 weight% is preferable, 0.5 to 50 weight% is more preferable, and 1 to 30 weight% is still more preferable. When the milk solid content is 0.1% by weight or more, a more preferable milk flavor can be achieved. Moreover, when there is too much content, it may cost too much. In addition, since milk fat corresponds to both milk solid content and fats and oils, when milk fat is blended with the oil-in-water emulsified oil and fat composition, any of the above-described milk solid content and fat content is required. When calculating the value, the content of milk fat is taken into consideration.

前記水の含有量は、前記水中油型乳化油脂組成物全体中40〜90重量%が好ましく、45〜85重量%がより好ましく、50〜80重量%が更に好ましい。含有量が40重量%より少ないと、パン生地又は菓子生地に水中油型乳化油脂組成物を練り込むための好ましい物性を得ることができない場合があり、90重量%より多いと目的とする乳風味増強効果が十分に得られない場合がある。   The water content is preferably 40 to 90% by weight, more preferably 45 to 85% by weight, and still more preferably 50 to 80% by weight in the entire oil-in-water emulsified oil / fat composition. If the content is less than 40% by weight, it may not be possible to obtain desirable physical properties for kneading the oil-in-water emulsified oil / fat composition in bread dough or confectionery dough, and if it is more than 90% by weight, the intended milk flavor enhancement The effect may not be sufficiently obtained.

本発明の水中油型乳化油脂組成物の製造方法は、常法に従えば良いが、以下に例示する。まず、油脂、乳化剤等の油系原料を混合して50〜80℃に加温溶解した油相部と、前記乳風味増強剤、水溶性乳化剤や蛋白質などの水系原料を50〜70℃の温水に攪拌溶解した水相部とを予備乳化し、その後、均質化、殺菌、均質化、冷却などの通常行われる各処理を行うことにより、本発明の水中油型乳化油脂組成物を得ることができる。前記均質化処理は、通常行われる方法であれば何れでも良く、高圧ホモジナイザーの使用が一般的である。   Although the manufacturing method of the oil-in-water type emulsion oil-fat composition of this invention should just follow a conventional method, it illustrates below. First, an oily phase part obtained by mixing oil-based raw materials such as fats and fats and emulsifiers and heating and dissolving at 50 to 80 ° C, and water-based raw materials such as the milk flavor enhancer, water-soluble emulsifier and protein are heated at 50 to 70 ° C. It is possible to obtain the oil-in-water type emulsified oil / fat composition of the present invention by pre-emulsifying the water phase part stirred and dissolved in the aqueous solution, and then performing usual treatments such as homogenization, sterilization, homogenization, and cooling. it can. The homogenization treatment may be any method that is usually performed, and a high-pressure homogenizer is generally used.

以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。   EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to these examples. In the examples, “parts” and “%” are based on weight.

<パン、菓子、マーガリン及び水中油型乳化油脂組成物の官能評価方法>
実施例及び比較例で作製したパン、菓子、マーガリン及び水中油型乳化油脂組成物を、熟練した10名のパネラーに食べて評価してもらい、それらの平均点を評価値とした。その際の評価基準は、以下の通りである。
<Sensory evaluation method for bread, confectionery, margarine and oil-in-water emulsified oil / fat composition>
The bread, confectionery, margarine and oil-in-water emulsified oil / fat composition prepared in Examples and Comparative Examples were evaluated by 10 experienced panelists, and their average score was taken as the evaluation value. The evaluation criteria at that time are as follows.

(乳脂肪感)
5点:バターや生クリームを食べた時に感じる、濃厚な乳脂肪の風味が非常に強く、大変好ましい。
(Milk fat feeling)
5 points: The rich milk fat flavor felt when eating butter and fresh cream is very strong and very preferable.

4点:バターや生クリームを食べた時に感じる、濃厚な乳脂肪の風味が強く、好ましい。   4 points: The rich milk fat flavor felt when eating butter or fresh cream is preferable.

3点:バターや生クリームを食べた時に感じる、濃厚な乳脂肪の風味がやや強く、やや好ましい。   3 points: The flavor of rich milk fat felt when eating butter or fresh cream is somewhat strong and slightly preferred.

2点:バターや生クリームを食べた時に感じる、濃厚な乳脂肪の風味が弱く、物足りない。   2 points: The flavor of rich milk fat felt when eating butter and fresh cream is weak and unsatisfactory.

1点:バターや生クリームを食べた時に感じる、濃厚な乳脂肪の風味が感じられない。   1 point: The rich flavor of milk fat felt when eating butter or fresh cream is not felt.

(乳の甘み)
5点:温めたミルクを飲んだ時に感じる、甘い風味が非常に強く、大変好ましい。
(Sweetness of milk)
5 points: The sweet flavor that is felt when drinking warm milk is very strong and very preferable.

4点:温めたミルクを飲んだ時に感じる、甘い風味が強く、好ましい。   4 points: The sweet flavor that is felt when drinking warm milk is strong and preferable.

3点:温めたミルクを飲んだ時に感じる、甘い風味がやや強く、やや好ましい。   3 points: The sweet flavor felt when drinking warm milk is slightly strong and slightly preferred.

2点:温めたミルクを飲んだ時に感じる、甘い風味が弱く、物足りない。   2 points: The sweet flavor that is felt when drinking warm milk is weak and unsatisfactory.

1点:温めたミルクを飲んだ時に感じる、甘い風味が感じられない。   1 point: The sweet flavor that is felt when drinking warm milk is not felt.

(乳感)
5点:ミルクを飲んだ時に感じる、乳の風味が非常に強く、大変好ましい。
(Milk feeling)
5 points: The flavor of milk felt when drinking milk is very strong and very preferable.

4点:ミルクを飲んだ時に感じる、乳の風味が強く、好ましい。   4 points: The flavor of milk felt when drinking milk is strong and preferable.

3点:ミルクを飲んだ時に感じる、乳の風味がやや強く、やや好ましい。   3 points: The flavor of milk felt when drinking milk is somewhat strong and slightly preferred.

2点:ミルクを飲んだ時に感じる、乳の風味が弱く、物足りない。   2 points: The taste of milk is weak and unsatisfactory when you drink milk.

1点:ミルクを飲んだ時に感じる、乳の風味が感じられない。   1 point: The flavor of milk that is felt when drinking milk is not felt.

(コク)
5点:バターや生クリームを食べた時に感じる、風味の複雑さ、まとまり、後味の好ましい風味が非常に強く、大変好ましい。
(Body)
5 points: Flavor complexity, unity, and favorable aftertaste that are felt when eating butter and fresh cream are very strong and very preferable.

4点:バターや生クリームを食べた時に感じる、風味の複雑さ、まとまり、後味の好ましい風味が強く、好ましい。   4 points: Complexity of flavor felt when eating butter and fresh cream, unity, and favorable aftertaste flavor are strong and preferable.

3点:バターや生クリームを食べた時に感じる、風味の複雑さ、まとまり、後味の好ましい風味がやや強く、やや好ましい。   3 points: Flavor complexity, unity, and favorable aftertaste that are felt when eating butter and fresh cream are slightly strong and slightly preferable.

2点:バターや生クリームを食べた時に感じる、風味の複雑さ、まとまり、後味の好ましい風味が弱く、物足りない。   2 points: Flavor complexity, unity, and favorable aftertaste are weak and unsatisfactory when eating butter or fresh cream.

1点:バターや生クリームを食べた時に感じる、風味の複雑さ、まとまり、後味の好ましい風味が感じられない。   1 point: Complexity of flavors felt when eating butter and fresh cream, unity, and favorable aftertaste flavors are not felt.

<総合評価>
パン、菓子、マーガリン及び水中油型乳化油脂組成物の官能評価(乳脂肪感、乳の甘み、乳感、コク)の各評価結果を基に、総合評価を行った。その際の評価基準は以下の通りである。
<Comprehensive evaluation>
Based on the evaluation results of sensory evaluation (milk fat feeling, milk sweetness, milk feeling, richness) of bread, confectionery, margarine and oil-in-water emulsified oil and fat composition, comprehensive evaluation was performed. The evaluation criteria at that time are as follows.

5点:パン、菓子、マーガリン又は水中油型乳化油脂組成物の乳脂肪感、乳の甘み、乳感、コクの評価が全て4.5点以上。   5 points: Bread, confectionery, margarine or oil-in-water emulsified oil / fat composition has a milk fat feeling, milk sweetness, milk feeling, and richness all evaluated at 4.5 points or more.

4点:パン、菓子、マーガリン又は水中油型乳化油脂組成物の乳脂肪感、乳の甘み、乳感、コクの評価で4点未満がなく、且つ1つ以上が4点以上4.5点未満。   4 points: There are no less than 4 points in the evaluation of milk fat feeling, sweetness of milk, milk feeling, richness of bread, confectionery, margarine or oil-in-water emulsified oil and fat composition, and one or more is 4 points or more 4.5 points Less than.

3点:パン、菓子、マーガリン又は水中油型乳化油脂組成物の乳脂肪感、乳の甘み、乳感、コクの評価で3点未満がなく、且つ1つ以上が3点以上4点未満。   3 points: There are no less than 3 points in the evaluation of milk fat feeling, sweetness of milk, milk feeling, richness of bread, confectionery, margarine or oil-in-water emulsified oil and fat composition, and one or more is 3 points or more and less than 4 points.

2点:パン、菓子、マーガリン又は水中油型乳化油脂組成物の乳脂肪感、乳の甘み、乳感、コクの評価で1.5点未満がなく、且つ1つ以上が1.5点以上3点未満。   2 points: No more than 1.5 points in the evaluation of milk fat feeling, milk sweetness, milk feeling, richness of bread, confectionery, margarine or oil-in-water emulsified oil and fat composition, and one or more is 1.5 points or more Less than 3 points.

1点:パン、菓子、マーガリン又は水中油型乳化油脂組成物の乳脂肪感、乳の甘み、乳感、コクの評価で1つ以上が1.5点未満。   1 point: One or more is less than 1.5 in the evaluation of milk fat feeling, sweetness of milk, milk feeling and richness of bread, confectionery, margarine or oil-in-water emulsified oil and fat composition.

なお、実施例及び比較例で使用した原料は、以下の通りである。
1−A)三菱商事フードテック(株)製「コンブエキスB5」(固形分量:52重量%)
1−B)MCフーズスペシャリティー(株)製「ハイクックこんぶエキスパウダーM−3」(固形分量:97.6重量%)
2)三菱商事フードテック(株)製「バイオコンクS」(固形分量:23重量%)
3)ユニテックフーズ(株)製「UMAMIエンハンサー」(固形分量:83重量%)
4)MCフーズスペシャリティー(株)製「さかしお10号」(固形分量:44重量%)
5)MCフーズスペシャリティー(株)製「WA−3」(固形分量:99重量%)
6)キッコーマン(株)製「小麦発酵調味料」(固形分量:99重量%)
7)大日本明治製糖(株)製「ラクトベースLB−BT」(固形分量:95重量%)
8)昭和産業(株)製「ニューフラクトR−30」(固形分量:75重量%(内訳:グルコース30重量%、フルクトース45重量%))
9)ピュアモルト社製「CB30」(固形分量:65重量%)
10)日研フード(株)製「チキンミートペースト」(固形分量:47重量%)
11)(株)カネカ製「エステル交換油脂」(パーム油:80重量%とパーム核油:20重量%の化学エステル交換油脂)
12)(株)カネカ製「精製ナタネ油」
13)よつ葉乳業(株)製「無塩バター」(よつ葉バター(食塩不使用)を溶解し、遠心分離して水相部を除去したもの)
14)よつ葉乳業(株)製「脱脂粉乳」(乳固形分:97重量%)
15)The TATUA Co-operative Dairy Company製「CFI740」(乳脂肪:42.0重量%、乳蛋白質:1.9重量%、水分53.1重量%)
16)ADM製「YelkinTS」
17)阪本薬品工業(株)製「SYグリスターMS−5S」
18)日清製粉(株)製「カメリア」
19)(株)カネカ製「カネカイーストDR」
20)東洋精糖(株)製「上白糖」
21)キューピータマゴ(株)製「液全卵(殺菌)」
22)日清製粉(株)製「バイオレット」
23)公益財団法人塩事業センター製「精製塩」
24)奥野製薬工業(株)社製「ベーキングパウダー」
25)(株)トクヤマ製「重曹」
(実施例1)乳風味増強剤の作製
表1に示す配合に従い、密閉式加熱処理装置(耐圧硝子工業(株)製、ポータブルリアクター「TPR1−VS2−500」、以下の表1〜4の中では「PR」と表記)を用いて、混合加熱物を作製した。ポータブルリアクターは、加熱処理前にその中へ約60℃の温水200gを投入し、150℃まで加熱後、温水を容器外に取り出す操作を行うことで、容器を十分に温めた状態で使用した。昆布エキス、異性化液糖及び水を混合し、75℃に温調して、混合液を調製した。この混合液400gを、前記密閉式加熱処理装置に投入し、1000rpmで攪拌しながら、密閉状態で品温が75℃から140℃になるまで平均昇温速度5.1℃/分で加熱した。140℃に達温後、4分間ホールドし、製品出口コックを開放し、加熱処理混合物をステンレスビーカーに受け、直ちに氷水を入れたボールにステンレスビーカーを浸けて、ゴムベラで撹拌しながら、品温が140℃から75℃になるまで平均降温速度64.2℃/分で冷却し、混合加熱物を得た。これを実施例1の乳風味増強剤とした。
In addition, the raw material used by the Example and the comparative example is as follows.
1-A) “Comb Extract B5” manufactured by Mitsubishi Corporation Foodtech Co., Ltd. (solid content: 52% by weight)
1-B) “High Cook Konbu Extract Powder M-3” manufactured by MC Foods Specialty Co., Ltd. (solid content: 97.6% by weight)
2) “Bioconk S” manufactured by Mitsubishi Corporation Foodtech Co., Ltd. (solid content: 23% by weight)
3) “UMAMI Enhancer” manufactured by Unitech Foods Co., Ltd. (solid content: 83% by weight)
4) “Sakashio No. 10” manufactured by MC Foods Specialty Co., Ltd. (solid content: 44% by weight)
5) “WA-3” (solid content: 99% by weight) manufactured by MC Foods Specialty Co., Ltd.
6) “Wheat Fermented Seasoning” manufactured by Kikkoman Corporation (solid content: 99% by weight)
7) “Lact Base LB-BT” manufactured by Dainippon Meiji Sugar Co., Ltd. (solid content: 95% by weight)
8) “New Fract R-30” manufactured by Showa Sangyo Co., Ltd. (solid content: 75% by weight (breakdown: glucose 30% by weight, fructose 45% by weight))
9) “CB30” manufactured by Pure Malt (solid content: 65% by weight)
10) “Chicken meat paste” manufactured by Nikken Foods Co., Ltd. (solid content: 47% by weight)
11) "Transesterified oil" manufactured by Kaneka Corporation (palm oil: 80% by weight and palm kernel oil: 20% by weight chemical transesterified oil)
12) "Refined rapeseed oil" manufactured by Kaneka Corporation
13) “Unsalted butter” manufactured by Yotsuba Dairy Co., Ltd. (Yotsuba butter (without salt) dissolved and centrifuged to remove the aqueous phase)
14) “Skim milk powder” manufactured by Yotsuba Milk Industry Co., Ltd. (milk solid content: 97% by weight)
15) “CFI740” manufactured by The TATUA Co-operative Dairy Company (milk fat: 42.0% by weight, milk protein: 1.9% by weight, moisture 53.1% by weight)
16) ADM “YelkinTS”
17) "SY Glister MS-5S" manufactured by Sakamoto Pharmaceutical Co., Ltd.
18) “Camellia” manufactured by Nisshin Seifun Co., Ltd.
19) "Kaneka East DR" manufactured by Kaneka Corporation
20) “Kami white sugar” manufactured by Toyo Seika Co., Ltd.
21) “Liquid whole egg (sterilized)” manufactured by Kewpie Egg Co., Ltd.
22) Nisshin Flour Milling “Violet”
23) “Purified salt” manufactured by the Salt Business Center
24) "Baking powder" manufactured by Okuno Pharmaceutical Co., Ltd.
25) "Baking soda" made by Tokuyama Corporation
Example 1 Production of Milk Flavor Enhancer According to the formulation shown in Table 1, a closed heat treatment apparatus (manufactured by Pressure Glass Industrial Co., Ltd., portable reactor “TPR1-VS2-500”, in the following Tables 1-4 Then, a mixed heating product was prepared using “PR”. The portable reactor was used in a state where the container was sufficiently warmed by adding 200 g of hot water of about 60 ° C. into the pre-heat treatment, heating it to 150 ° C., and removing the hot water from the container. A kelp extract, isomerized sugar and water were mixed and temperature-controlled at 75 ° C. to prepare a mixed solution. 400 g of this mixed solution was put into the above-described sealed heat treatment apparatus and heated at an average temperature increase rate of 5.1 ° C./min until the product temperature was changed from 75 ° C. to 140 ° C. in a sealed state while stirring at 1000 rpm. After reaching 140 ° C, hold for 4 minutes, open the product outlet cock, receive the heat-treated mixture in a stainless steel beaker, immediately immerse the stainless steel beaker in a bowl containing ice water, and stir with a rubber spatula. The mixture was cooled at an average temperature decrease rate of 64.2 ° C./min from 140 ° C. to 75 ° C. to obtain a mixed heated product. This was used as the milk flavor enhancer of Example 1.

Figure 2017131176
Figure 2017131176

(実施例2〜6、比較例1)乳風味増強剤の作製
表1に示す配合に従い、昆布エキスを他の植物由来エキス又は酵母エキスに替え、エキスと糖類の合計の固形分量が実施例1と同じ54.4重量%に近付くように水の添加量を調整した以外は、実施例1と同様にして、乳風味増強剤を得た。
(Examples 2-6, Comparative Example 1) Production of Milk Flavor Enhancer According to the formulation shown in Table 1, the kelp extract was replaced with another plant-derived extract or yeast extract, and the total solid content of the extract and saccharide was Example 1. A milk flavor enhancer was obtained in the same manner as in Example 1, except that the amount of water added was adjusted to approach 54.4% by weight.

(実施例7,8、比較例2)乳風味増強剤の作製
表2に示す配合に従い、植物由来エキスと糖類の乾燥重量比は実施例1と同じ(17/83)で、植物由来エキスと糖類の合計の固形分量が変わるように、昆布エキスと異性化液糖の添加量を変えて、水の添加量を調整した以外は、実施例1と同様にして乳風味増強剤を得た。
(Examples 7 and 8, Comparative Example 2) Production of Milk Flavor Enhancer According to the formulation shown in Table 2, the dry weight ratio of the plant-derived extract and saccharide was the same as in Example 1 (17/83), and the plant-derived extract and A milk flavor enhancer was obtained in the same manner as in Example 1 except that the addition amount of kelp extract and isomerized liquid sugar was changed to adjust the addition amount of water so that the total solid content of the saccharide was changed.

Figure 2017131176
Figure 2017131176

(実施例9,10、比較例3,4)乳風味増強剤の作製
表2に示す配合に従い、植物由来エキスと糖類の合計の固形分量は実施例1と同じ54.4重量%近くで、植物由来エキスと糖類の乾燥重量比が変わるように、昆布エキスと異性化液糖の添加量を変えて、水の添加量を調整した以外は、実施例1と同様にして乳風味増強剤を得た。
(Examples 9 and 10, Comparative Examples 3 and 4) Production of Milk Flavor Enhancer According to the formulation shown in Table 2, the total solid content of the plant-derived extract and the saccharide was close to 54.4% by weight as in Example 1, A milk flavor enhancer was prepared in the same manner as in Example 1 except that the amount of kelp extract and isomerized liquid sugar was changed and the amount of water was adjusted so that the dry weight ratio between the plant-derived extract and the sugar was changed. Obtained.

(実施例11,12、比較例5,6)乳風味増強剤の作製
表3に示す配合に従い、混合加熱物の配合(原材料)は同じで、最高到達品温及び最高到達品温での保持時間を変えた以外は、実施例8と同様にして乳風味増強剤を得た。
(Examples 11 and 12, Comparative Examples 5 and 6) Production of Milk Flavor Enhancer According to the composition shown in Table 3, the composition (raw material) of the mixed heated product is the same, and is maintained at the maximum product temperature and the maximum product temperature. A milk flavor enhancer was obtained in the same manner as in Example 8 except that the time was changed.

Figure 2017131176
Figure 2017131176

(比較例7)乳風味増強剤の作製(特許文献1の実施例1に準拠)
表3に示す配合に従い、昆布エキスと異性化液糖の替わりに、麦芽エキスを使用し、最高到達品温を150℃及び最高到達品温での保持時間を0.1秒に変えた以外は、実施例8と同様にして乳風味増強剤を得た。
(Comparative Example 7) Preparation of milk flavor enhancer (based on Example 1 of Patent Document 1)
According to the composition shown in Table 3, instead of kelp extract and isomerized liquid sugar, malt extract was used, except that the maximum temperature reached 150 ° C and the retention time at the maximum temperature reached 0.1 seconds. In the same manner as in Example 8, a milk flavor enhancer was obtained.

(実施例13)乳風味増強剤の作製
表3に示す配合に従い、図1の二重筒加熱装置を用いて混合加熱物を作製した。昆布エキス、米糠発酵物及び異性化液糖を混合した後、60℃に温調して、混合液を調製した。この混合液80kgを、二重筒加熱装置に圧入させ、品温が75℃から155℃になるまで平均昇温速度14.5℃/分で連続的に加熱処理を行い加熱した。155℃に達温後、2.7分間ホールドし、平均降温速度62.6℃/分で、75℃まで冷却して、乳風味増強剤を得た。
Example 13 Production of Milk Flavor Enhancer According to the formulation shown in Table 3, a mixed heated product was produced using the double cylinder heating device of FIG. After mixing the kelp extract, the rice bran fermented product, and the isomerized liquid sugar, the temperature was adjusted to 60 ° C. to prepare a mixed solution. 80 kg of this mixed solution was press-fitted into a double cylinder heating apparatus, and was heated by continuous heat treatment at an average temperature increase rate of 14.5 ° C./min until the product temperature was changed from 75 ° C. to 155 ° C. After reaching 155 ° C., the mixture was held for 2.7 minutes and cooled to 75 ° C. at an average temperature drop rate of 62.6 ° C./min to obtain a milk flavor enhancer.

(実施例14)乳風味増強剤の作製
表3に示す配合に従い、昆布エキスの種類と量を変え、昆布エキス、米糠発酵物及び異性化液糖を混合し、最高到達品温を155℃、最高到達品温での保持時間を3分間に変えた以外は、実施例8と同様にして乳風味増強剤を得た。
(Example 14) Preparation of milk flavor enhancer According to the formulation shown in Table 3, the type and amount of kelp extract was changed, kelp extract, rice bran fermented product and isomerized liquid sugar were mixed, and the maximum reached product temperature was 155 ° C, A milk flavor enhancer was obtained in the same manner as in Example 8 except that the retention time at the highest product temperature was changed to 3 minutes.

(実施例15〜17)乳風味増強剤(非加熱物との混合)の作製
表4に示す配合に従い、実施例1で得た混合加熱物と、非加熱物のエキス(昆布エキス(実施例15)、チキンエキス(実施例16)、米糠発酵物(実施例17))、異性化液糖及び必要に応じて水を混合して、実施例1の混合加熱物を70重量%含む乳風味増強剤を得た。
(Examples 15 to 17) Preparation of milk flavor enhancer (mixed with non-heated product) According to the formulation shown in Table 4, the mixed heated product obtained in Example 1 and an extract of non-heated product (kombu extract (Example) 15), milk extract (Example 16), fermented rice bran (Example 17)), isomerized liquid sugar and water as required, and milk flavor containing 70% by weight of the mixed heated product of Example 1 An enhancer was obtained.

Figure 2017131176
Figure 2017131176

(実施例18)油中水型乳化油脂組成物(マーガリン)の作製
表5に示す配合に従い、油中水型乳化油脂組成物を作製した。即ち、エステル交換油脂、精製ナタネ油を70℃に加温・融解して油相部を調製した。次に、60℃の温水に乳風味増強剤(実施例1)及び脱脂粉乳を撹拌混合して水相部を調製した。油相部に水相部を徐々に添加し、その後約60℃に温調し、プロペラミキサーにて攪拌混合し乳化液にした。その後、急冷捏和装置にて捏和して、出口温度を15℃としてマーガリンを排出して得た。得られたマーガリンの官能評価結果を表5に示した。
(Example 18) Preparation of water-in-oil emulsified oil / fat composition (margarine) According to the formulation shown in Table 5, a water-in-oil emulsified oil / fat composition was prepared. That is, the oil phase part was prepared by heating and melting the transesterified oil and fat and refined rapeseed oil at 70 ° C. Next, a milk phase enhancer (Example 1) and skim milk powder were stirred and mixed in 60 ° C. warm water to prepare an aqueous phase part. The aqueous phase portion was gradually added to the oil phase portion, then the temperature was adjusted to about 60 ° C., and the mixture was stirred and mixed with a propeller mixer to obtain an emulsion. Then, it knead | mixed with the rapid cooling kneading apparatus, the exit temperature was 15 degreeC, and it obtained by discharging | emitting margarine. The sensory evaluation results of the obtained margarine are shown in Table 5.

Figure 2017131176
Figure 2017131176

(参考例1)油中水型乳化油脂組成物(マーガリン)の作製
表5に示す配合に従い、乳風味増強剤を添加せずに、水で全体量を調整した以外は、実施例18と同様にしてマーガリンを得た。
(Reference Example 1) Production of water-in-oil emulsified oil / fat composition (margarine) According to the formulation shown in Table 5, the same as in Example 18 except that the total amount was adjusted with water without adding a milk flavor enhancer. To get margarine.

(実施例19)油中水型乳化油脂組成物(マーガリン)の作製
表5に示す配合に従い、エステル交換油脂と精製ナタネ油の混合比率はほぼ同じで、合計の配合量を10重量部減らした替わりに乳脂肪を添加した以外は、実施例18と同様にしてマーガリンを得た。得られたマーガリンの官能評価結果を表5に示した。
(Example 19) Preparation of water-in-oil emulsified oil / fat composition (margarine) According to the composition shown in Table 5, the mixing ratio of the transesterified oil and refined rapeseed oil was almost the same, and the total compounded amount was reduced by 10 parts by weight. Margarine was obtained in the same manner as in Example 18 except that milk fat was added instead. The sensory evaluation results of the obtained margarine are shown in Table 5.

(実施例20〜22)油中水型乳化油脂組成物(マーガリン)の作製
表5に示す配合に従い、脱脂粉乳の替わりにクリームのリパーゼ処理物を異なる量で配合し、水で全体量を調整した以外は、実施例19と同様にしてマーガリンを得た。得られたマーガリンの官能評価結果を表5に示した。
(Examples 20 to 22) Preparation of water-in-oil emulsified oil / fat composition (margarine) In accordance with the formulation shown in Table 5, a lipase-treated product of cream is blended in a different amount instead of skim milk powder, and the total amount is adjusted with water. A margarine was obtained in the same manner as in Example 19 except that. The sensory evaluation results of the obtained margarine are shown in Table 5.

(比較例8)油中水型乳化油脂組成物(マーガリン)の作製
表5に示す配合に従い、脱脂粉乳を配合せず、水で全体量を調整した以外は、実施例18と同様にして、マーガリンを得た。得られたマーガリンの官能評価結果を表5に示した。
(Comparative Example 8) Preparation of water-in-oil emulsified oil / fat composition (margarine) According to the formulation shown in Table 5, except that skim milk powder was not blended and the total amount was adjusted with water, the same as in Example 18, I got margarine. The sensory evaluation results of the obtained margarine are shown in Table 5.

(比較例9)油中水型乳化油脂組成物(マーガリン)の作製
表5に示す配合に従い、実施例1の乳風味増強剤に替えて比較例3の乳風味増強剤を添加した以外は、実施例22と同様にしてマーガリンを得た。得られたマーガリンの官能評価結果を表5に示した。
(Comparative Example 9) Preparation of water-in-oil emulsified oil and fat composition (margarine) According to the formulation shown in Table 5, except that the milk flavor enhancer of Comparative Example 3 was added instead of the milk flavor enhancer of Example 1, Margarine was obtained in the same manner as in Example 22. The sensory evaluation results of the obtained margarine are shown in Table 5.

実施例1の乳風味増強剤を使用したマーガリン(実施例18)はバターの乳脂肪感、乳の甘み、濃厚な乳感とコクが感じられ、更に実施例18の油脂の一部を乳脂肪に変更したマーガリン(実施例19)はより好ましい乳風味が感じられ良好な評価であった。また、実施例19における脱脂粉乳をクリームのリパーゼ処理物に変更したマーガリン(実施例20〜22)は、乳風味が一段と向上し、非常に良好な評価結果であった。一方、乳固形分を配合しなかったマーガリン(比較例8)は、乳風味が感じられなかった。また、糖類を含まず植物由来エキスのみを加熱して得られた比較例3の乳風味増強剤を使用したマーガリン(比較例9)は、乳風味がもの足りなかった。   The margarine (Example 18) using the milk flavor enhancer of Example 1 has butter milk fat feeling, milk sweetness, rich milk feeling and richness, and a part of the fat and oil of Example 18 is milk fat. The margarine (Example 19) changed to was a favorable evaluation because a more preferable milk flavor was felt. Moreover, the margarine (Examples 20-22) which changed the skim milk powder in Example 19 into the lipase processed product of cream improved the milk flavor further, and was a very favorable evaluation result. On the other hand, margarine (Comparative Example 8) that did not contain milk solids did not feel milk flavor. In addition, margarine (Comparative Example 9) using the milk flavor enhancer of Comparative Example 3 obtained by heating only the plant-derived extract without saccharides was insufficient in milk flavor.

(実施例23)水中油型乳化油脂組成物の作製
表6に示す配合に従い、水中油型乳化油脂組成物を作製した。即ち、精製ナタネ油に、レシチンを添加し、65℃で溶解して油相部を作製した。また、乳風味増強剤(実施例1)、脱脂粉乳、クリームのリパーゼ処理物及びポリグリセリン脂肪酸エステルを60℃の水に溶解して水相部を作製した。上記水相部に油相部を加えて混合した後20分間予備乳化し、その後、高圧ホモジナイザーを用いて4MPaの圧力で処理した後に、UHT殺菌機を用いて142℃で4秒間殺菌処理した。その後、再び高圧ホモジナイザーを用いて6MPaの圧力で処理し、その後、冷却機で5℃まで冷却したものを容器に充填し、水中油型乳化油脂組成物を得た。得られた水中油型乳化油脂組成物の官能評価結果を表6に示した。
(Example 23) Preparation of oil-in-water emulsified oil / fat composition According to the formulation shown in Table 6, an oil-in-water emulsified oil / fat composition was prepared. That is, lecithin was added to refined rapeseed oil and dissolved at 65 ° C. to prepare an oil phase part. Further, a milk phase enhancer (Example 1), skim milk powder, a lipase-treated product of cream and a polyglycerin fatty acid ester were dissolved in water at 60 ° C. to prepare an aqueous phase part. The oil phase part was added to the water phase part and mixed, and then pre-emulsified for 20 minutes, and then treated at a pressure of 4 MPa using a high-pressure homogenizer and then sterilized at 142 ° C. for 4 seconds using a UHT sterilizer. Then, it processed at the pressure of 6 Mpa again using the high pressure homogenizer, Then, what was cooled to 5 degreeC with the cooler was filled into the container, and the oil-in-water type emulsified oil-fat composition was obtained. The sensory evaluation results of the obtained oil-in-water emulsified oil / fat composition are shown in Table 6.

Figure 2017131176
Figure 2017131176

その結果、実施例23の水中油型乳化油脂組成物は、乳脂肪感、乳の甘み、濃厚な乳感及びコクがバランス良く感じられ良好な評価であった。   As a result, the oil-in-water emulsified oil / fat composition of Example 23 was well evaluated with a good balance of milk fat feeling, milk sweetness, rich milk feeling and richness.

(実施例24)ロールパンの作製
表7に示す配合に従い、ロールパンを作製した。即ち、強力粉、イースト、上白糖、全卵、水をミキサーボウルに投入し、縦型ミキサー(関東混合機工業(株)製「カントーミキサー」)にフックを取り付け、低速で3分間、高速で3分間混捏して生地を得た。得られた生地を28℃の恒温槽にて2時間30分間発酵し、中種生地を得た。続いて、強力粉、薄力粉、上白糖、食塩、脱脂粉乳、水と中種生地をミキサーボウルに投入し、縦型ミキサーで低速で2分間、高速で5分間混捏した。さらに参考例1のマーガリンと実施例1の乳風味増強剤をミキサーボウルに投入し、低速で2分間、高速で5分間混捏した。得られた生地を28℃の恒温槽にて、60分間フロアータイムをとった後、60gずつの生地に分割した。分割後、28℃で20分間のベンチタイムをとり、モルダー((株)フジサワ製「FM−31Z」)にて生地を伸ばした後、カールして展圧し、棒状の成型物を得た。この成型物を天板の上に置き、温度:38℃、湿度:75%で60分間最終発酵を行った。最終発酵後、200℃のオーブンで9分間焼成し、ロールパンを得た。得られたロールパンの官能評価結果を表7に示した。
(Example 24) Production of roll bread According to the formulation shown in Table 7, roll bread was produced. That is, strong powder, yeast, white sucrose, whole egg, and water are put into a mixer bowl, and a hook is attached to a vertical mixer (“Canto Mixer” manufactured by Kanto Blender Kogyo Co., Ltd.). The dough was obtained by chaos for a minute. The obtained dough was fermented in a constant temperature bath at 28 ° C. for 2 hours and 30 minutes to obtain a medium seed dough. Subsequently, strong powder, thin powder, super white sugar, salt, skim milk powder, water and medium dough were put into a mixer bowl, and kneaded in a vertical mixer at low speed for 2 minutes and at high speed for 5 minutes. Furthermore, the margarine of Reference Example 1 and the milk flavor enhancer of Example 1 were put into a mixer bowl and kneaded for 2 minutes at low speed and for 5 minutes at high speed. The obtained dough was taken in a constant temperature bath at 28 ° C. for 60 minutes and then divided into 60 g pieces. After the splitting, a bench time of 20 minutes was taken at 28 ° C., and the dough was stretched with a molder (“FM-31Z” manufactured by Fujisawa Co., Ltd.), then curled and spread to obtain a rod-shaped molded product. This molded product was placed on a top plate and subjected to final fermentation at a temperature of 38 ° C. and a humidity of 75% for 60 minutes. After final fermentation, it was baked for 9 minutes in an oven at 200 ° C. to obtain a roll. Table 7 shows the sensory evaluation results of the obtained bread roll.

Figure 2017131176
Figure 2017131176

(比較例10)ロールパンの作製
表7に示す配合に従い、乳風味増強剤を添加しなった以外は、実施例24と同様にして、ロールパンを得た。得られたロールパンの官能評価結果を表7に示した。
(Comparative Example 10) Production of Roll Bread A roll bread was obtained in the same manner as in Example 24 except that the milk flavor enhancer was not added according to the formulation shown in Table 7. Table 7 shows the sensory evaluation results of the obtained bread roll.

(実施例25)ロールパンの作製
表7に示す配合に従い、クリームのリパーゼ処理物を添加し、水で全体量を調整した以外は、実施例24と同様にして、ロールパンを得た。得られたロールパンの官能評価結果を表7に示した。
(Example 25) Production of roll bread A roll bread was obtained in the same manner as in Example 24 except that a lipase-treated product of cream was added and the total amount was adjusted with water according to the formulation shown in Table 7. Table 7 shows the sensory evaluation results of the obtained bread roll.

(実施例26)ロールパンの作製
表7に示す配合に従い、乳風味増強剤の添加量を増加し、水で全体量を調整した以外は、実施例25と同様にして、ロールパンを得た。得られたロールパンの官能評価結果を表7に示した。
(Example 26) Production of roll bread According to the formulation shown in Table 7, a roll bread was obtained in the same manner as in Example 25 except that the addition amount of the milk flavor enhancer was increased and the total amount was adjusted with water. Table 7 shows the sensory evaluation results of the obtained bread roll.

(実施例27,28)ロールパンの作製
表7に示す配合に従い、実施例1の乳風味増強剤と参考例1のマーガリンに替えて、乳風味増強剤とクリームのリパーゼ処理物を配合した実施例20又は21のマーガリンを添加した以外は、実施例24と同様にして、ロールパンを得た。得られたロールパンの官能評価結果を表7に示した。
(Examples 27 and 28) Preparation of rolls Examples in which milk flavor enhancers and cream lipase-treated products were blended in place of the milk flavor enhancer of Example 1 and margarine of Reference Example 1 according to the formulation shown in Table 7 A roll bread was obtained in the same manner as in Example 24 except that 20 or 21 margarine was added. Table 7 shows the sensory evaluation results of the obtained bread roll.

(実施例29)ロールパンの作製
表7に示す配合に従い、実施例1の乳風味増強剤0.015重量部の代わりに、乳風味増強剤とクリームのリパーゼ処理物を配合した実施例23の水中油型乳化油脂組成物10重量部を用い、参考例1のマーガリンの添加量を12.5重量部に変更し、水で全体量を調整した以外は、実施例24と同様にして、ロールパンを得た。得られたロールパンの官能評価結果を表7に示した。
(Example 29) Production of rolls In accordance with the formulation shown in Table 7, in place of 0.015 parts by weight of the milk flavor enhancer of Example 1, a milk flavor enhancer and a lipase-treated product of cream were blended in the water of Example 23 A roll bread was prepared in the same manner as in Example 24 except that 10 parts by weight of the oil-type emulsified oil and fat composition was used, the amount of margarine added in Reference Example 1 was changed to 12.5 parts by weight, and the total amount was adjusted with water. Obtained. Table 7 shows the sensory evaluation results of the obtained bread roll.

実施例1の乳風味増強剤を使用したロールパン(実施例24)は、良好な乳風味が感じられたが、乳風味増強剤を使用しなった比較例10のロールパンは乳風味が弱かった。また、実施例24の配合にクリームのリパーゼ処理物を添加したロールパン(実施例25,26)は乳風味が増強され、乳風味増強剤とクリームのリパーゼ処理物を配合した実施例20又は21のマーガリンを添加したロールパン(実施例27,28)は乳風味が強く感じられ良好な評価結果であった。   The roll (Example 24) using the milk flavor enhancer of Example 1 felt a good milk flavor, but the roll of Comparative Example 10 using no milk flavor enhancer had a weak milk flavor. In addition, the rolls (Examples 25 and 26) in which the cream lipase-treated product was added to the formulation of Example 24 had enhanced milk flavor, and the milk flavour enhancer and the cream lipase-treated product of Example 20 or 21 were blended. The rolls to which margarine was added (Examples 27 and 28) felt a strong milk flavor and were good evaluation results.

更に、乳風味増強剤とクリームのリパーゼ処理物を配合した水中油型乳化油脂組成物を使用したロールパン(実施例29)は、乳風味が強く感じられた。   Furthermore, the roll bread (Example 29) using the oil-in-water emulsified oil and fat composition containing the milk flavor enhancer and the cream lipase-treated product felt a strong milk flavor.

(実施例30〜34、比較例11)ロールパンの作製
表8に示す配合に従い、実施例1の乳風味増強剤の代わりに、実施例2〜6又は比較例1の乳風味増強剤を使用した以外は、実施例25と同様にして、ロールパンを得た。得られたロールパンの官能評価結果を表8に示した。
(Examples 30 to 34, Comparative Example 11) Production of Roll Bread According to the formulation shown in Table 8, instead of the milk flavor enhancer of Example 1, the milk flavor enhancer of Examples 2 to 6 or Comparative Example 1 was used. Except for this, a roll was obtained in the same manner as in Example 25. Table 8 shows the sensory evaluation results of the obtained bread roll.

Figure 2017131176
Figure 2017131176

表8から明らかなように、種々の植物由来エキスを原料とした実施例1〜6の乳風味増強剤を添加したロールパン(実施例25〜34)は何れも乳風味が強く感じられ良好な評価結果であったが、植物由来エキスではなく酵母エキスを原料とした比較例1の乳風味増強剤を添加したロールパン(比較例11)は、硫黄臭が感じられ乳風味としては好ましくなかった。   As is apparent from Table 8, roll breads (Examples 25 to 34) to which the milk flavor enhancers of Examples 1 to 6 using various plant-derived extracts were added as raw materials all felt a strong milk flavor and were evaluated well. Although it was a result, the roll bread (comparative example 11) which added the milk flavor enhancer of the comparative example 1 which used the yeast extract instead of the plant-derived extract as a raw material felt a sulfur smell, and was not preferable as a milk flavor.

(実施例35〜38、比較例12〜14)ロールパンの作製
表9に示す配合に従い、実施例1の乳風味増強剤の代わりに、実施例7〜10又は比較例2〜4の乳風味増強剤を使用した以外は、実施例25と同様にして、ロールパンを得た。得られたロールパンの官能評価結果を表9に示した。
(Examples 35 to 38, Comparative Examples 12 to 14) Production of roll bread According to the formulation shown in Table 9, instead of the milk flavor enhancer of Example 1, Examples 7 to 10 or Comparative Examples 2 to 4 were enhanced. A roll bread was obtained in the same manner as in Example 25 except that the agent was used. Table 9 shows the sensory evaluation results of the obtained bread roll.

Figure 2017131176
Figure 2017131176

表9から明らかなように、植物由来エキスと糖類の合計の固形分量が40.8〜69.7%である実施例7〜9の乳風味増強剤を添加したロールパン(実施例35〜37)は、何れも乳風味が感じられ、特に固形分量が69.7%の乳風味増強剤を添加したロールパン(実施例36)が良好な評価結果であった。一方、固形分濃度が27.2%である比較例2の乳風味増強剤を使用したロールパン(比較例12)は、乳風味が弱くもの足りなかった。   As is clear from Table 9, rolls to which the milk flavor enhancers of Examples 7 to 9 in which the total solid content of the plant-derived extract and saccharide is 40.8 to 69.7% were added (Examples 35 to 37). In any case, a roll (Example 36) to which a milk flavor enhancer having a solid content of 69.7% was added was a good evaluation result. On the other hand, the roll (Comparative Example 12) using the milk flavor enhancer of Comparative Example 2 having a solid content concentration of 27.2% had a weak milk flavor and was insufficient.

また、植物由来エキス/糖類の乾燥重量比が75/25である実施例10の乳風味増強剤を使用したロールパン(実施例38)は、乳風味が感じられたものの、乾燥重量比が100/0や0.01/99.99である比較例3又は4の乳風味増強剤を使用したロールパン(比較例13,14)はどちらも乳風味が弱かった。   In addition, the bread roll (Example 38) using the milk flavor enhancer of Example 10 in which the dry weight ratio of the plant-derived extract / saccharide is 75/25, although the milk flavor was felt, the dry weight ratio was 100 / The rolls (Comparative Examples 13 and 14) using the milk flavor enhancer of Comparative Example 3 or 4 which was 0 or 0.01 / 99.99 had weak milk flavor.

(実施例39〜42、比較例15〜17)ロールパンの作製
表10に示す配合に従い、実施例8の乳風味増強剤の代わりに、実施例11〜14又は比較例5〜7の乳風味増強剤を使用した以外は、実施例36と同様にして、ロールパンを得た。得られたロールパンの官能評価結果を表10に示した。
(Examples 39-42, Comparative Examples 15-17) Production of Roll Bread According to the formulation shown in Table 10, instead of the milk flavor enhancer of Example 8, Examples 11-14 or Milk Flavor Enhancement of Comparative Examples 5-7 A roll bread was obtained in the same manner as in Example 36 except that the agent was used. Table 10 shows the sensory evaluation results of the obtained bread roll.

Figure 2017131176
Figure 2017131176

表10から明らかなように、最高到達品温又は最高到達品温での保持時間が異なっていても各化合物の含量が本発明の要件を満足する実施例8、11、12の乳風味増強剤を使用したロールパン(実施例36,39,40)は何れも乳風味が感じられたが、5−メチルフルフラールの含量が本発明の要件を満足しない比較例5、又は、酢酸及び1−ブタノールの含量が本発明の要件を満足しない比較例6の乳風味増強剤を使用したロールパン(比較例15,16)は乳風味が弱くもの足りなかった。   As is apparent from Table 10, the milk flavor enhancers of Examples 8, 11, and 12 in which the content of each compound satisfies the requirements of the present invention even when the maximum product temperature or the retention time at the maximum product temperature is different. Each of the bread rolls (Examples 36, 39, and 40) using the scent had a milky taste, but the content of 5-methylfurfural did not satisfy the requirements of the present invention, or Comparative Example 5 or acetic acid and 1-butanol. The rolls (Comparative Examples 15 and 16) using the milk flavor enhancer of Comparative Example 6 whose content does not satisfy the requirements of the present invention were insufficient due to weak milk flavor.

また、二重筒加熱装置を用いて作製した実施例13の乳風味増強剤を使用したロールパン(実施例41)も、良好な乳風味を有していた。一方、麦芽エキスを原材料とし糖類を使用していない比較例7の乳風味増強剤を使用したロールパン(比較例17)は、麦芽臭が感じられ乳風味が損なわれていた。植物由来エキスとして異なる種類の昆布エキスと米糠発酵物を併用して製造した実施例14の乳風味増強剤を使用したロールパン(実施例42)は、植物由来エキスとして昆布エキスのみを使用して製造した実施例8の乳風味増強剤を使用したロールパン(実施例36)よりも更に乳風味が強く感じられ、最も好ましい評価結果であった。   Moreover, the roll (Example 41) which used the milk flavor enhancer of Example 13 produced using the double cylinder heating apparatus also had favorable milk flavor. On the other hand, in the roll bread (Comparative Example 17) using the milk flavor enhancer of Comparative Example 7 using malt extract as a raw material and not using sugar, malt odor was felt and the milk flavor was impaired. A roll (Example 42) using the milk flavor enhancer of Example 14 produced by using a combination of different types of kelp extract and fermented rice bran as a plant-derived extract is produced using only the kelp extract as the plant-derived extract. The milk flavor was felt even stronger than the roll (Example 36) using the milk flavor enhancer of Example 8, which was the most preferable evaluation result.

(実施例43〜45)ロールパンの作製
表11に示す配合に従い、実施例1の乳風味増強剤の代わりに、実施例1の混合加熱物にエキスの非加熱物及び異性化液糖を混合して作製した実施例15〜17の乳風味増強剤を使用した以外は、実施例25と同様にして、ロールパンを得た。得られたロールパンの官能評価結果を表11に示した。
(Examples 43 to 45) Production of roll bread According to the composition shown in Table 11, instead of the milk flavor enhancer of Example 1, the non-heated extract and isomerized liquid sugar of the extract were mixed with the mixed heated product of Example 1. A roll bread was obtained in the same manner as in Example 25 except that the milk flavor enhancers of Examples 15 to 17 prepared in the above were used. Table 11 shows the sensory evaluation results of the obtained bread roll.

Figure 2017131176
Figure 2017131176

表11から明らかなように、実施例1の混合加熱物にエキスの非加熱物及び異性化液糖を混合して作製した実施例15〜17の乳風味増強剤を添加したロールパン(実施例43〜45)は、何れも実施例1の乳風味増強剤を添加したロールパン(実施例25)よりも乳風味が強く感じられ良好な評価結果であった。   As is clear from Table 11, the bread roll (Example 43) to which the milk flavor enhancer of Examples 15 to 17 prepared by mixing the non-heated extract and isomerized liquid sugar with the mixed and heated product of Example 1 was added. -45) were both good evaluation results in which the milk flavor was felt stronger than the roll (Example 25) to which the milk flavor enhancer of Example 1 was added.

(実施例46)パウンドケーキの作製
表12に示す配合に従いパウンドケーキを作製した。即ち、実施例18のマーガリン、上白糖をミキサーボウルに投入し、縦型ミキサー(HOBART社製「ミキサーN50」)にヒーターを取り付け、低速で2分間、中速で2分間混合した。次いで、全卵を、低速で混合しながら流し入れ、低速で1分30秒間、中速で1分30秒間混合した。最後に薄力粉とベーキングパウダーを投入し、低速で30秒間、中速で10秒間混合し、比重0.88g/ccのパウンドケーキ生地を得た。得られたパウンドケーキ生地を型に370g流し込み、180℃の固定窯で45分間焼成してパウンドケーキを得た。得られたパウンドケーキについて官能評価を行い、結果を表12に示した。
(Example 46) Preparation of a pound cake A pound cake was prepared according to the formulation shown in Table 12. That is, margarine and white sugar of Example 18 were put into a mixer bowl, a heater was attached to a vertical mixer (“Mixer N50” manufactured by HOBART), and mixed at low speed for 2 minutes and at medium speed for 2 minutes. The whole egg was then poured while mixing at low speed and mixed for 1 minute 30 seconds at low speed and 1 minute 30 seconds at medium speed. Finally, the flour and baking powder were added and mixed for 30 seconds at low speed and for 10 seconds at medium speed to obtain a pound cake dough having a specific gravity of 0.88 g / cc. 370 g of the obtained pound cake dough was poured into a mold and baked in a fixed kiln at 180 ° C. for 45 minutes to obtain a pound cake. Sensory evaluation was performed on the obtained pound cake, and the results are shown in Table 12.

Figure 2017131176
Figure 2017131176

(実施例47,48、比較例18〜20)パウンドケーキの作製
表12に示す配合に従い、実施例18のマーガリンの替わりに、実施例19若しくは22、参考例1、又は比較例8若しくは9のマーガリンを使用した以外は実施例46と同様にして、パウンドケーキを得た。得られたパウンドケーキの官能評価結果を表12に示した。
(Examples 47 and 48, Comparative Examples 18 to 20) Preparation of Pound Cake According to the formulation shown in Table 12, instead of margarine of Example 18, Example 19 or 22, Reference Example 1, or Comparative Example 8 or 9 A pound cake was obtained in the same manner as in Example 46 except that margarine was used. Table 12 shows the sensory evaluation results of the obtained pound cake.

(比較例21)パウンドケーキの作製
表12に示す配合に従い、実施例18のマーガリンの替わりに、参考例1のマーガリン、実施例1の乳風味増強剤及びクリームのリパーゼ処理物を使用した以外は実施例46と同様にして、パウンドケーキを得た。得られたパウンドケーキの官能評価結果を表12に示した。
(Comparative Example 21) Preparation of pound cake According to the formulation shown in Table 12, instead of the margarine of Example 18, the margarine of Reference Example 1, the milk flavor enhancer of Example 1 and the lipase-treated product of cream were used. A pound cake was obtained in the same manner as in Example 46. Table 12 shows the sensory evaluation results of the obtained pound cake.

表12から明らかなように、実施例1の乳風味増強剤と脱脂粉乳を配合した実施例18のマーガリンを使用したパウンドケーキ(実施例46)は、乳風味が感じられたが、参考例1または比較例8若しくは9のマーガリンを使用したパウンドケーキ(比較例18〜20)は、乳風味が弱くもの足りなかった。また、実施例18のマーガリンの油脂を、エステル交換油脂と精製ナタネ油の混合比率はほぼ同じで、合計の添加量を10重量部減らして替わりに乳脂肪を添加した実施例19のマーガリンを使用したパウンドケーキ(実施例47)は乳風味が強く良好な風味であった。更に、脱脂粉乳の替わりにクリームのリパーゼ処理物を配合した実施例22のマーガリンを使用したパウンドケーキ(実施例48)は、乳風味が極めて強く感じられた。一方、実施例1の乳風味増強剤の添加量が少ないパウンドケーキ(比較例21)は、乳風味のコクが不足してもの足りなかった。   As is apparent from Table 12, the pound cake (Example 46) using the margarine of Example 18 containing the milk flavor enhancer of Example 1 and skim milk powder felt a milk flavor, but Reference Example 1 Or the pound cake (comparative examples 18-20) using the margarine of the comparative example 8 or 9 had weak milk flavor, and was not enough. Further, the margarine fat of Example 18 is the same as the mixing ratio of the transesterified fat and refined rapeseed oil, and the total amount added is reduced by 10 parts by weight. Instead, the margarine of Example 19 is used instead of milk fat. The pound cake (Example 47) had a strong milk flavor and a good flavor. Furthermore, the pound cake using the margarine of Example 22 (Example 48) in which a lipase-treated product of cream was blended instead of skim milk powder felt a very strong milk flavor. On the other hand, the pound cake (Comparative Example 21) with a small amount of addition of the milk flavor enhancer of Example 1 was insufficient even if the milk flavor was insufficient.

10 二重筒加熱装置
11 加熱容器
12 内筒
12a 外壁面
13 外筒
13a 内壁面
14 間隙
14a 供給口
14b 排出口
DESCRIPTION OF SYMBOLS 10 Double cylinder heating apparatus 11 Heating container 12 Inner cylinder 12a Outer wall surface 13 Outer cylinder 13a Inner wall surface 14 Gap 14a Supply port 14b Discharge port

Claims (17)

パン・菓子用乳風味増強剤であって、
前記乳風味増強剤は、植物由来エキスと糖類との混合加熱物を40〜100重量%含有し、
前記植物由来エキス/前記糖類の乾燥重量比は、99/1〜1/99であり、
前記植物由来エキスと前記糖類の合計の固形分量は、前記混合加熱物の全体に対し40〜80重量%であり、
前記乳風味増強剤の全体に対し、2−アセチルフランの含有量は0.003〜7ppm、5−メチルフルフラールの含有量は0.001〜2ppm、フルフラールの含有量は0.04〜15ppm、3−メチルブタナールの含有量は0.001〜10ppm、酢酸の含有量は0〜2ppm、ジメチルジスルフィドの含有量は0〜0.5ppm、及び、1−ブタノールの含有量は0〜0.8ppmである、パン・菓子用乳風味増強剤。
A milk flavor enhancer for bread and confectionery,
The milk flavor enhancer contains 40 to 100% by weight of a mixed and heated product of a plant-derived extract and a saccharide,
The dry weight ratio of the plant-derived extract / the saccharide is 99/1 to 1/99,
The total solid content of the plant-derived extract and the saccharide is 40 to 80% by weight based on the whole of the mixed heated product,
The content of 2-acetylfuran is 0.003 to 7 ppm, the content of 5-methylfurfural is 0.001 to 2 ppm, and the content of furfural is 0.04 to 15 ppm with respect to the whole milk flavor enhancer. -The content of methylbutanal is 0.001-10 ppm, the content of acetic acid is 0-2 ppm, the content of dimethyl disulfide is 0-0.5 ppm, and the content of 1-butanol is 0-0.8 ppm. A milk flavor enhancer for bread and confectionery.
前記乳風味増強剤の全体に対する2−アセチルフラン、5−メチルフルフラール、フルフラール及び3−メチルブタナールの合計量(A)と、酢酸、ジメチルジスルフィド及び1−ブタノールの合計量(B)の重量比((B)/(A)×100)が0〜25%である、請求項1に記載のパン・菓子用乳風味増強剤。   Weight ratio of the total amount (A) of 2-acetylfuran, 5-methylfurfural, furfural and 3-methylbutanal to the total amount of the milk flavor enhancer and the total amount (B) of acetic acid, dimethyl disulfide and 1-butanol The milk flavor enhancer for bread and confectionery according to claim 1, wherein ((B) / (A) × 100) is 0 to 25%. 前記乳風味増強剤の全体に対する2−アセチルフラン、5−メチルフルフラール、フルフラール及び3−メチルブタナールの合計量(A)が0.05〜25ppmである、請求項1又は2に記載のパン・菓子用乳風味増強剤。   The bread * of Claim 1 or 2 whose total amount (A) of 2-acetylfuran, 5-methylfurfural, furfural and 3-methylbutanal with respect to the said whole milk flavor enhancer is 0.05-25 ppm. Milk flavor enhancer for confectionery. 前記植物由来エキスが、昆布由来エキス、穀物由来エキス、及び穀物発酵物由来エキスからなる群より選ばれる少なくとも1種である、請求項1〜3の何れかに記載のパン・菓子用乳風味増強剤。   The milk flavor enhancement for bread and confectionery according to any one of claims 1 to 3, wherein the plant-derived extract is at least one selected from the group consisting of a kelp-derived extract, a cereal-derived extract, and a fermented cereal-derived extract. Agent. 前記糖類が、アラビノース、ラクトース、キシロース、グルコース、フルクトース、スクロース、及びマルトースからなる群より選ばれる少なくとも1種である、請求項1〜4の何れかに記載のパン・菓子用乳風味増強剤。   The milk flavor enhancer for bread and confectionery according to any one of claims 1 to 4, wherein the saccharide is at least one selected from the group consisting of arabinose, lactose, xylose, glucose, fructose, sucrose, and maltose. 更に、昆布由来エキス、チキン由来エキス、穀物由来エキス、及び穀物発酵物由来エキスからなる群より選ばれる少なくとも1種のエキスの非加熱物を含有する、請求項1〜5の何れかに記載のパン・菓子用乳風味増強剤。   Furthermore, the non-heated thing of at least 1 sort (s) of extract chosen from the group which consists of a kombu origin extract, a chicken origin extract, a grain origin extract, and a grain fermented product origin extract is described in any one of Claims 1-5. Milk flavor enhancer for bread and confectionery. 油中水型乳化油脂組成物の全体に対して、請求項1〜6の何れかに記載のパン・菓子用乳風味増強剤0.015〜5重量%(乾燥重量)、及び、乳固形分0.1〜70重量%(乾燥重量)を含有するパン・菓子練り込み用油中水型乳化油脂組成物。   The milk flavor enhancer 0.015 to 5% by weight (dry weight) for bread and confectionery according to any one of claims 1 to 6, and the milk solid content, based on the whole water-in-oil emulsified oil and fat composition A water-in-oil emulsified oil / fat composition for kneading bread and confectionery containing 0.1 to 70% by weight (dry weight). 水中油型乳化油脂組成物の全体に対して、請求項1〜6の何れかに記載のパン・菓子用乳風味増強剤0.015〜5重量%(乾燥重量)、及び、乳固形分0.1〜70重量%(乾燥重量)を含有するパン・菓子練り込み用水中油型乳化油脂組成物。   The milk flavor enhancer 0.015 to 5% by weight (dry weight) for bread and confectionery according to any one of claims 1 to 6 and a milk solid content of 0 to the entire oil-in-water emulsified oil / fat composition An oil-in-water emulsified oil / fat composition for kneading bread and confectionery containing 1 to 70% by weight (dry weight). 穀粉100重量部に対して、請求項1〜6の何れかに記載のパン・菓子用乳風味増強剤0.0001〜3重量部(乾燥重量)、及び、乳固形分0.005〜50重量部(乾燥重量)を含有するパン生地。   The milk flavor enhancer 0.0001-3 parts by weight (dry weight) for bread and confectionery according to any one of claims 1 to 6 and 100-5 parts by weight of milk solids relative to 100 parts by weight of flour Bread dough containing parts (dry weight). 前記乳固形分の少なくとも一部が、乳固形分のリパーゼ処理物であり、前記リパーゼ処理物の全体に対して、乳脂肪10〜99.8重量%、乳蛋白質0.1〜50重量%、及び水分0.1〜70重量%を含有する、請求項9に記載のパン生地。   At least a part of the milk solids is a lipase-treated product of milk solids, 10 to 99.8% by weight of milk fat, 0.1 to 50% by weight of milk protein, based on the whole lipase-treated product, The bread dough according to claim 9, further comprising 0.1 to 70% by weight of water. 前記パン・菓子用乳風味増強剤と前記リパーゼ処理物の含有量比が99/1〜15/85(乾燥重量比)である、請求項10に記載のパン生地。   The bread dough according to claim 10, wherein a content ratio of the milk flavor enhancer for bread / confectionery and the lipase-treated product is 99/1 to 15/85 (dry weight ratio). 請求項9〜11の何れかに記載のパン生地が加熱調理されたパン。   Bread in which the bread dough according to any one of claims 9 to 11 is cooked. 穀粉100重量部に対して、請求項1〜6の何れかに記載のパン・菓子用乳風味増強剤0.001〜10重量部(乾燥重量)、及び、乳固形分0.005〜120重量部(乾燥重量)を含有する菓子生地。   The milk flavor enhancer 0.001 to 10 parts by weight (dry weight) for bread and confectionery according to any one of claims 1 to 6 and a milk solid content of 0.005 to 120 parts by weight with respect to 100 parts by weight of flour. Confectionery dough containing parts (dry weight). 前記乳固形分の少なくとも一部が、乳固形分のリパーゼ処理物であり、前記リパーゼ処理物の全体に対して、乳脂肪10〜99.8重量%、乳蛋白質0.1〜50重量%、及び水分0.1〜70重量%を含有する、請求項13に記載の菓子生地。   At least a part of the milk solids is a lipase-treated product of milk solids, 10 to 99.8% by weight of milk fat, 0.1 to 50% by weight of milk protein, based on the whole lipase-treated product, The confectionery dough according to claim 13, further comprising 0.1 to 70% by weight of water. 前記パン・菓子用乳風味増強剤と前記リパーゼ処理物の含有量比が99/1〜15/85(乾燥重量比)である、請求項14に記載の菓子生地。   The confectionery dough according to claim 14, wherein a content ratio of the milk flavor enhancer for bread / confectionery and the lipase-treated product is 99/1 to 15/85 (dry weight ratio). 請求項13〜15の何れかに記載の菓子生地が加熱調理された菓子。   The confectionery by which the confectionery material in any one of Claims 13-15 was cooked. 植物由来エキスと糖類との混合物であって、前記植物由来エキス/前記糖類の乾燥重量比が99/1〜1/99で、固形分量が40〜80重量%である混合物を、品温が75℃になるまで加熱した後、最高到達品温が110〜160℃の範囲内になるように前記混合物を1〜100℃/分の平均昇温速度で加熱し、前記最高到達品温を0.1秒〜5時間保持した後、品温が75℃になるまで前記混合物を5〜200℃/分の平均降温速度で冷却することで混合加熱物を得る工程を含む、当該混合加熱物を含有するパン・菓子用乳風味増強剤の製造方法。
A mixture of a plant-derived extract and a saccharide, wherein a dry weight ratio of the plant-derived extract / the saccharide is 99/1 to 1/99 and a solid content is 40 to 80% by weight. After heating to 0 ° C., the mixture is heated at an average rate of temperature increase of 1 to 100 ° C./min so that the maximum product temperature is in the range of 110 to 160 ° C. After holding for 1 second to 5 hours, including the mixed heated product, including the step of obtaining the mixed heated product by cooling the mixture at an average temperature decrease rate of 5 to 200 ° C./min until the product temperature reaches 75 ° C. Of a milk flavor enhancer for bread and confectionery.
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019097525A (en) * 2017-12-07 2019-06-24 オリエンタル酵母工業株式会社 Manufacturing method of fermentation flavor solution, and manufacturing method of foods
CN112021546A (en) * 2020-09-04 2020-12-04 恒枫食品科技有限公司 Preparation method of almond-flavored essence
WO2021177115A1 (en) * 2020-03-02 2021-09-10 ミヨシ油脂株式会社 Emulsified fat composition
KR102584894B1 (en) * 2022-10-19 2023-10-05 정승민 Method for producing water for dough containing cabbage extract and water for dough manufactured by the same
KR102593102B1 (en) * 2023-03-24 2023-10-30 정승민 Bread manufacturing method using cabbage fermented liquid and bread manufactured thereby
KR102603513B1 (en) * 2023-03-24 2023-11-21 정승민 Manufacturing method of Scone with excellent Sensory characteristics
KR102644071B1 (en) * 2023-03-24 2024-03-08 정승민 Method for manufacturing baguette bread using cabbage fermented liquid and baguette bread manufactured thereby

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4701335A (en) * 1984-08-24 1987-10-20 Lever Brothers Company Butter-like concentrate
JPS6439927A (en) * 1987-08-07 1989-02-10 Fuji Oil Co Ltd Bread making property improving material and method
JPH02215334A (en) * 1989-02-16 1990-08-28 Kanegafuchi Chem Ind Co Ltd Production of breads and cakes using fermented milk
JP2001292696A (en) * 2000-04-12 2001-10-23 Asahi Denka Kogyo Kk Oil-in-water type emulsion composition and emulsified plastic fat composition using the same
WO2005120254A1 (en) * 2004-06-07 2005-12-22 Fuji Oil Company, Limited Fermented flavoring material
JP2013153742A (en) * 2012-01-06 2013-08-15 Kaneka Corp Saltiness enhancing agent
JP2015053886A (en) * 2013-09-11 2015-03-23 株式会社カネカ Food flavor modifier
JP2015053880A (en) * 2013-09-11 2015-03-23 株式会社カネカ Milk flavor taste material
JP2015104345A (en) * 2013-11-29 2015-06-08 株式会社Adeka Water-in-oil type emulsified fat composition having plasticity

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4701335A (en) * 1984-08-24 1987-10-20 Lever Brothers Company Butter-like concentrate
JPS6439927A (en) * 1987-08-07 1989-02-10 Fuji Oil Co Ltd Bread making property improving material and method
JPH02215334A (en) * 1989-02-16 1990-08-28 Kanegafuchi Chem Ind Co Ltd Production of breads and cakes using fermented milk
JP2001292696A (en) * 2000-04-12 2001-10-23 Asahi Denka Kogyo Kk Oil-in-water type emulsion composition and emulsified plastic fat composition using the same
WO2005120254A1 (en) * 2004-06-07 2005-12-22 Fuji Oil Company, Limited Fermented flavoring material
JP2013153742A (en) * 2012-01-06 2013-08-15 Kaneka Corp Saltiness enhancing agent
JP2015053886A (en) * 2013-09-11 2015-03-23 株式会社カネカ Food flavor modifier
JP2015053880A (en) * 2013-09-11 2015-03-23 株式会社カネカ Milk flavor taste material
JP2015104345A (en) * 2013-11-29 2015-06-08 株式会社Adeka Water-in-oil type emulsified fat composition having plasticity

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019097525A (en) * 2017-12-07 2019-06-24 オリエンタル酵母工業株式会社 Manufacturing method of fermentation flavor solution, and manufacturing method of foods
WO2021177115A1 (en) * 2020-03-02 2021-09-10 ミヨシ油脂株式会社 Emulsified fat composition
CN112021546A (en) * 2020-09-04 2020-12-04 恒枫食品科技有限公司 Preparation method of almond-flavored essence
CN112021546B (en) * 2020-09-04 2022-07-01 恒枫食品科技有限公司 Preparation method of almond-flavored essence
KR102584894B1 (en) * 2022-10-19 2023-10-05 정승민 Method for producing water for dough containing cabbage extract and water for dough manufactured by the same
KR102593102B1 (en) * 2023-03-24 2023-10-30 정승민 Bread manufacturing method using cabbage fermented liquid and bread manufactured thereby
KR102603513B1 (en) * 2023-03-24 2023-11-21 정승민 Manufacturing method of Scone with excellent Sensory characteristics
KR102644071B1 (en) * 2023-03-24 2024-03-08 정승민 Method for manufacturing baguette bread using cabbage fermented liquid and baguette bread manufactured thereby

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