JP2017095412A - Aerosol composition for insect pest control, aerosol for insect pest control and pest control method - Google Patents
Aerosol composition for insect pest control, aerosol for insect pest control and pest control method Download PDFInfo
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本発明は、害虫防除用エアゾール組成物、害虫防除用エアゾール、並びに、害虫の防除方法に関する。本発明は、屋内において飛翔害虫等の害虫を防除するのに有用なものである。 The present invention relates to a pest control aerosol composition, a pest control aerosol, and a pest control method. The present invention is useful for controlling pests such as flying pests indoors.
殺虫用エアゾールを用いて害虫を防除する方法として、害虫へ直接、害虫の生息場所や侵入場所に噴射する方法がある。また、大気中や室内空間中に向けて噴射（噴霧）する方法も知られている。 As a method for controlling insect pests using an insecticidal aerosol, there is a method in which the insect pests are sprayed directly on the place of infestation or invasion. In addition, a method for spraying (spraying) air in the atmosphere or indoor space is also known.
殺虫用エアゾールの殺虫成分として様々なピレスロイド系化合物が知られているが、いずれの化合物も含有量を少なくしても防除効果が高く、かつ防除効果を発揮した後は、殺虫成分が消滅する、もしくはほとんど残留しないような低残留性ものが求められている。 Various pyrethroid compounds are known as insecticidal components of insecticidal aerosols, but even if the content of any compound is reduced, the controlling effect is high, and after exhibiting the controlling effect, the insecticidal component disappears, Alternatively, a low-residue material that hardly remains is demanded.
本発明の目的は、屋内において飛翔害虫等を一定時間低薬量で防除でき、且つ低残留性の害虫防除用エアゾール組成物、害虫防除用エアゾール及び防除方法に関するものである。 An object of the present invention relates to a pest control aerosol composition, a pest control aerosol, and a control method that can control flying pests and the like indoors at a low dose for a certain period of time.
本発明者は上記課題を解決するために鋭意種々の研究を行った結果、特定の範囲にある殺虫成分、溶剤、噴射剤を組み合わせることにより、本発明を完成させたものである。すなわち本発明は、
（１）殺虫成分としてプロフルトリンを０．００５〜０.５重量％、溶剤として炭素数が２〜３の低級アルコールを０.５〜５重量％、及び液化石油ガス又はジメチルエーテルを主成分とし且つ噴射剤を９４．５〜９９．４９５重量％含有することを特徴とする害虫防除用エアゾール組成物。
（２）（１）に記載の害虫防除用エアゾール組成物がエアゾール容器に充填されてなる害虫防除用エアゾール。
（３）前記害虫防除用エアゾールの噴霧粒子の平均粒子径が１０μｍ未満となるような全量噴霧用エアゾールバルブを備え、１回の噴霧操作で全量の害虫防除用エアゾール組成物を噴霧できるものであり、噴霧量が１ｍ３当たり１〜１０ｍＬになるようにし、且つ噴霧してから２４時間後に処理された空間の床面におけるプロフルトリンの残留量が０．０１ｍｇ／ｍ２以下となることを特徴とする害虫防除用エアゾール。
（４）（１）に記載の害虫防除用エアゾール組成物もしくは（２）又は（３）に記載の害虫防除用エアゾールを屋内に噴霧することにより、害虫を防除することを特徴とする害虫の防除方法。
（５）前記害虫は、飛翔害虫であることを特徴とする害虫の防除方法。
As a result of diligent researches to solve the above problems, the present inventor has completed the present invention by combining insecticide components, solvents, and propellants in a specific range. That is, the present invention
(1) 0.005-0.5% by weight of profluthrin as an insecticidal component, 0.5-5% by weight of a lower alcohol having 2 to 3 carbon atoms as a solvent, and liquefied petroleum gas or dimethyl ether as a main component and injection An aerosol composition for controlling pests, comprising 94.5 to 99.495% by weight of an agent.
(2) An aerosol for controlling pests, wherein the aerosol composition for controlling insects according to (1) is filled in an aerosol container.
(3) A pest control aerosol valve is provided so that the average particle size of the spray particles of the pest control aerosol is less than 10 μm, and the pest control aerosol composition can be sprayed in a single spray operation. The spray amount is 1 to 10 mL per 1 m 3 , and the residual amount of profluthrin on the floor surface of the space treated 24 hours after spraying is 0.01 mg / m 2 or less. Aerosol for pest control.
(4) A pest control characterized by controlling pests by spraying the pest control aerosol composition according to (1) or the pest control aerosol according to (2) or (3) indoors Method.
(5) The pest control method, wherein the pest is a flying pest.
本発明を用いることにより、屋内において飛翔害虫等を一定時間防除でき、且つ低残留性の害虫防除をすることができる。 By using the present invention, it is possible to control flying pests and the like indoors for a certain period of time and to control pests with low persistence.
本発明の殺虫成分としてはプロフルトリンを０．００５〜０.５重量含有することが好ましい。 The insecticidal component of the present invention preferably contains 0.005 to 0.5 weight of profluthrin.
本発明の溶剤としては、炭素数が２〜３の低級アルコール、特にエタノールやイソプロパノールが好ましい。本発明の溶剤の含量は０.５〜５重量％が好ましい。また、溶剤は１種類のみを用いてもよく、２種類以上を併用してもよい。 The solvent of the present invention is preferably a lower alcohol having 2 to 3 carbon atoms, particularly ethanol or isopropanol. The content of the solvent of the present invention is preferably 0.5 to 5% by weight. Moreover, only 1 type may be used for a solvent and it may use 2 or more types together.
本発明の噴射剤は、液化石油ガス（ＬＰＧ）、ジメチルエーテル（ＤＭＥ）、ＨＦＯ−１２３４Ｚｅ、窒素ガス、炭酸ガス、亜酸化窒素、圧縮空気等の圧縮ガスがあげられ、そのうちの一種または二種以上を適宜用いることができるが、ＬＰＧ又はＤＭＥを主成分とするものが好ましい。噴射剤の含量は９４．５〜９９．４９５重量％の範囲内が好ましい。 Examples of the propellant of the present invention include liquefied petroleum gas (LPG), dimethyl ether (DME), HFO-1234Ze, compressed gas such as nitrogen gas, carbon dioxide gas, nitrous oxide, and compressed air, one or more of them. Can be used as appropriate, but those containing LPG or DME as the main component are preferred. The propellant content is preferably in the range of 94.5 to 99.495% by weight.
本発明の害虫防除用エアゾール組成物は、基本的には殺虫成分、炭素数が２〜３の低級アルコール及び噴射剤により構成されるが、本発明の効果を損なわない範囲で他の成分を適宜含有していてもよい。例えば、当該他の成分として、前記殺虫成分以外の合成品あるいは天然由来の殺虫成分、防除剤、香料、殺虫成分溶解助剤、などを含有させてもよい。 The aerosol composition for controlling pests of the present invention is basically composed of an insecticidal component, a lower alcohol having 2 to 3 carbon atoms, and a propellant, but other components are appropriately added within a range not impairing the effects of the present invention. You may contain. For example, as the other components, synthetic products other than the insecticidal components or naturally derived insecticidal components, control agents, fragrances, insecticidal component dissolution aids, and the like may be contained.
本発明の害虫防除用エアゾールは、本発明の害虫防除用エアゾール組成物がエアゾール容器に充填されてなるものである。エアゾール容器としては特に限定はなく、例えば、耐圧容器、エアゾールバルブ、アクチュエーター等を備えた公知のエアゾール容器を用いることができる。 The aerosol for pest control of the present invention is obtained by filling the aerosol container with the aerosol composition for pest control of the present invention. There is no limitation in particular as an aerosol container, For example, the well-known aerosol container provided with a pressure | voltage resistant container, an aerosol valve, an actuator, etc. can be used.
本発明のエアゾールの仕様は、１回の噴霧操作で全量の害虫防除用エアゾール組成物を噴霧できる構成を有する。１回の噴霧量としては、１ｍ３当たり１〜１０ｍＬとなるようにすることが好ましい。具体例としては、噴射剤としてジメチルエーテルを採用し、２５℃におけるエアゾール容器内圧を約０．２〜０．６ＭＰａ（ゲージ圧）とし、５０〜１５０ｍ３の屋内に対してエアゾール内容量を３００ｍＬとした全量噴霧用エアゾールバルブを装着する。噴霧粒子の平均粒子径は１０μｍ未満となるようにし、且つ噴霧してから２４時間後に処理された空間の床面における害虫防除成分の残留量を０．０１ｍｇ／ｍ２以下となるようにすることが好ましい。 The specification of the aerosol of the present invention has a configuration in which the entire amount of the pest control aerosol composition can be sprayed by a single spraying operation. The amount of spraying at one time is preferably 1 to 10 mL per 1 m 3 . As a specific example, dimethyl ether is employed as a propellant, the inner pressure of the aerosol container at 25 ° C. is set to about 0.2 to 0.6 MPa (gauge pressure), and the inner volume of the aerosol is set to 300 mL with respect to a room of 50 to 150 m 3 . Equipped with an aerosol valve for full spray The average particle size of the spray particles should be less than 10 μm, and the residual amount of the pest control component on the floor surface of the treated space 24 hours after spraying should be 0.01 mg / m 2 or less. Is preferred.
本発明の防除対象となる害虫類としては、以下のものが挙げられる。アカイエカ等のイエカ類、ヒトスジシマカ等のヤブカ類、ユスリカ類、イエバエ等のイエバエ類、クロバエ類、ニクバエ類、ヒメイエバエ等のハナバエ類、ミバエ類、ショウジョウバエ類、クロバネキノコバエ類、ノミバエ類、ケバエ類、タマバエ類、チョウバエ類、ノシメマダラメイガ等のメイガ類、アブ類、ブユ類、サシバエ類、ヌカカ類、カメムシ類等が挙げられる。この中でも特に屋内の飛翔害虫に対する防除効果が高い。 Examples of the pests to be controlled according to the present invention include the following. House mosquitoes such as Culex mosquitoes, japonicas such as Aedes albopictus, chironomids, house flies such as house flies, fly flies, sand flies, fly flies such as flies, fruit flies, fruit flies, leaf flies, flies, flies, Examples include Japanese medusa such as bat flies, butterflies, and mosquitoes, horse mackerel, flyfish, sand flies, nukaka, stink bugs, and the like. Among them, the effect of controlling indoor flying pests is particularly high.
以下に、実施例をもって本発明をさらに具体的に説明するが、本発明はこの実施例に限定されるものではない。 Hereinafter, the present invention will be described more specifically with reference to examples, but the present invention is not limited to these examples.
（実施例１）
プロフルトリン０．１ｇ、エタノール１．７ｇをエアゾール缶に入れ、 全量噴霧エアゾールバルブを装着後、ジメチルエーテル１９６．８ｇを充填した。内圧は０．５２ＭＰａ（ゲージ圧、２５℃）であった。これにより、プロフルトリンを０．０５重量％、炭素数が２〜３の低級アルコールを０．８６重量％、及びジメチルエーテルを９９．０９重量％含有する害虫防除用エアゾールを得た。当該害虫防除用エアゾールを噴霧した時の噴霧粒子の平均粒子径は３．８０μｍであった。
Example 1
0.1 g of profluthrin and 1.7 g of ethanol were put into an aerosol can, and after a full-amount aerosol valve was mounted, 196.8 g of dimethyl ether was charged. The internal pressure was 0.52 MPa (gauge pressure, 25 ° C.). As a result, a pest control aerosol containing 0.05% by weight of profluthrin, 0.86% by weight of a lower alcohol having 2 to 3 carbon atoms, and 99.09% by weight of dimethyl ether was obtained. The average particle diameter of the spray particles when the pest control aerosol was sprayed was 3.80 μm.
（実施例２，３、比較例１〜３）
実施例１と同様に、表１に示す配合、平均粒子径となる実施例２及び３、比較例１〜３の害虫防除用エアゾールを得た。
(Examples 2 and 3, Comparative Examples 1 to 3)
Similarly to Example 1, the aerosols for pest control according to Examples 2 and 3 and Comparative Examples 1 to 3 having the composition and average particle diameter shown in Table 1 were obtained.
（試験例１）
閉めきった約９３ｍ３の試験室の４隅の床上１ｍの位置に供試虫としてキイロショウジョウバエ約３０頭を入れた直径５ｃｍの金属製ケージを設置した。実施例１〜３、比較例１〜３のエアゾールを用いて、該試験室の床面中央から上方に向けて全量噴霧した。噴霧処理４時間後に供試虫を回収し、別容器に移して水と餌を与え、別室にて保管した。噴霧開始から２４時間後に供試虫の生死を調査して死虫率を求めた。結果は以下の基準で示した。◎：平均死虫率９０〜１００％、○：平均死虫率７５〜８９％、△：平均死虫率５０〜７４％、×：平均死虫率５０％未満。
(Test Example 1)
A metal cage having a diameter of 5 cm containing about 30 Drosophila melanogaster was placed as a test insect at a position 1 m above the floor at the four corners of a closed test room of about 93 m 3 . Using the aerosols of Examples 1 to 3 and Comparative Examples 1 to 3, the entire amount was sprayed upward from the center of the floor surface of the test chamber. The test insects were collected 4 hours after the spray treatment, transferred to another container, fed with water and food, and stored in a separate room. 24 hours after the start of spraying, the life and death of the test insects were investigated to determine the death rate. The results are shown in the following criteria. A: Average mortality 90 to 100%, ◯: Average mortality 75 to 89%, Δ: Average mortality 50 to 74%, X: Average mortality 50% or less.
（試験例２〜４）
試験例１と同じ試験装置、試験条件、試験方法で供試虫をオオチョウバエ１０頭（試験例２）、アカイエカ１０頭（試験例３）、ノシメマダラメイガ１０頭（試験例４）に替えて実施した。
(Test Examples 2 to 4)
Using the same test equipment, test conditions, and test methods as in Test Example 1, the test insects were replaced with 10 giant fly flies (Test Example 2), 10 squid (Test Example 3), and 10 scallops (Test Example 4). Carried out.
試験例１〜４の結果を表２に示す。 The results of Test Examples 1 to 4 are shown in Table 2.
（試験例５）
約９３ｍ３の試験室の床面中央から水平方向に２ｍの位置に１０ｃｍ×１０ｃｍのステンレス板を設置した。該ステンレス板は４方向に計４枚設置した。該試験室の床面中央に設置した実施例１〜３、比較例１〜３のエアゾールを全量噴霧して室内を密閉した。噴霧処理２４時間後に該ステンレス板を全て回収し、付着したプロフルトリンをアセトニトリルで抽出してガスクロマトグラフィーにより分析した。
(Test Example 5)
A stainless steel plate of 10 cm × 10 cm was installed at a position 2 m horizontally from the center of the floor surface of the test room of about 93 m 3 . A total of four stainless steel plates were installed in four directions. The aerosols of Examples 1 to 3 and Comparative Examples 1 to 3 installed in the center of the floor of the test chamber were all sprayed to seal the room. All of the stainless steel plate was recovered 24 hours after the spray treatment, and the attached profluthrin was extracted with acetonitrile and analyzed by gas chromatography.
試験例５の結果を表３に示す。 The results of Test Example 5 are shown in Table 3.
本発明は、害虫防除、特に屋内の飛翔害虫に対する防除を目的に使用することができる。
INDUSTRIAL APPLICABILITY The present invention can be used for controlling insect pests, particularly for controlling indoor flying insect pests.
Claims (5)
The pest control method according to claim 4, wherein the pest is a flying pest.
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| JP2000095617A (en) * | 1998-09-28 | 2000-04-04 | Fumakilla Ltd | Insecticidal aerosol composition |
| JP2002193718A (en) * | 2000-12-27 | 2002-07-10 | Sumitomo Chem Co Ltd | Insecticidal composition |
| JP2003081721A (en) * | 2001-09-14 | 2003-03-19 | Sumitomo Chem Co Ltd | Method for controlling flying insect pest in room |
| WO2007129818A1 (en) * | 2006-05-04 | 2007-11-15 | Industry Academic Cooperation Foundation, Chungbuk National University | Mosquitoes aerosol insecticide using setting polymer |
| JP2014019674A (en) * | 2012-07-20 | 2014-02-03 | Dainippon Jochugiku Co Ltd | Flying insect pest control method |
| JP2014031342A (en) * | 2012-08-03 | 2014-02-20 | Fumakilla Ltd | Insecticidal aerosol composition |
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000095617A (en) * | 1998-09-28 | 2000-04-04 | Fumakilla Ltd | Insecticidal aerosol composition |
| JP2002193718A (en) * | 2000-12-27 | 2002-07-10 | Sumitomo Chem Co Ltd | Insecticidal composition |
| JP2003081721A (en) * | 2001-09-14 | 2003-03-19 | Sumitomo Chem Co Ltd | Method for controlling flying insect pest in room |
| WO2007129818A1 (en) * | 2006-05-04 | 2007-11-15 | Industry Academic Cooperation Foundation, Chungbuk National University | Mosquitoes aerosol insecticide using setting polymer |
| JP2014019674A (en) * | 2012-07-20 | 2014-02-03 | Dainippon Jochugiku Co Ltd | Flying insect pest control method |
| JP2014031342A (en) * | 2012-08-03 | 2014-02-20 | Fumakilla Ltd | Insecticidal aerosol composition |
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