JP2017061736A - Electrolytic device for partial anode oxidation treatment and treatment method using the same - Google Patents
Electrolytic device for partial anode oxidation treatment and treatment method using the same Download PDFInfo
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- JP2017061736A JP2017061736A JP2015188881A JP2015188881A JP2017061736A JP 2017061736 A JP2017061736 A JP 2017061736A JP 2015188881 A JP2015188881 A JP 2015188881A JP 2015188881 A JP2015188881 A JP 2015188881A JP 2017061736 A JP2017061736 A JP 2017061736A
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- 238000000034 method Methods 0.000 title claims abstract description 8
- 230000003647 oxidation Effects 0.000 title abstract description 5
- 238000007254 oxidation reaction Methods 0.000 title abstract description 5
- 230000002093 peripheral effect Effects 0.000 claims abstract description 40
- 238000007599 discharging Methods 0.000 claims abstract description 4
- 239000008151 electrolyte solution Substances 0.000 claims description 22
- 238000007743 anodising Methods 0.000 claims description 11
- 239000010407 anodic oxide Substances 0.000 claims description 7
- 238000003672 processing method Methods 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 abstract description 4
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 238000005868 electrolysis reaction Methods 0.000 description 6
- 229910000838 Al alloy Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004512 die casting Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
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- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
Abstract
Description
本発明は、アルミニウム合金等を素材としたワークに部分的に陽極酸化皮膜を形成するための電解装置及びそれを用いた部分陽極酸化処理方法に関する。 The present invention relates to an electrolysis apparatus for partially forming an anodized film on a workpiece made of an aluminum alloy or the like, and a partial anodizing method using the same.
アルミニウム及びその合金を用いた各種素形材(以下ワークという。)を電解液に浸漬し、このワークを陽極として対極にカーボン,鉛,ステンレス等の陰極を配設し、電解処理するとワークの表面に陽極酸化皮膜が形成される。
この陽極酸化皮膜は緻密で硬いことから、耐食性向上、耐摩耗性向上等を目的に行われている。
車両の駆動部品、機関部品として、アルミニウム合金のダイカスト鋳造品、低圧鋳造品等が用いられている。
この種の駆動部品、機関部品の中には、回転体として使用され、回転面に耐摩耗性等が部分的に要求される場合がある。
従って、このような製品の場合に製品全体の表面に陽極酸化皮膜を形成する必要がなく、従来のようにワーク全体を電解液に浸漬して陽極酸化処理するのはエネルギー的にもムダが多い。
また、アルミニウム合金の鋳造品は電解時に電流密度を高くして高速処理化を図らんとすると、電解ヤケが発生しやすく均一な皮膜も得られ難い課題もあった。
Various shaped materials using aluminum and its alloys (hereinafter referred to as workpieces) are immersed in an electrolyte, and a cathode of carbon, lead, stainless steel, etc. is disposed on the counter electrode as the anode, and the surface of the workpiece is subjected to electrolytic treatment. An anodized film is formed on the surface.
Since this anodized film is dense and hard, it is carried out for the purpose of improving corrosion resistance and wear resistance.
Aluminum alloy die castings, low pressure castings, and the like are used as vehicle drive parts and engine parts.
Some of these types of drive parts and engine parts are used as a rotating body, and the rotating surface may partially require wear resistance or the like.
Accordingly, in the case of such a product, it is not necessary to form an anodic oxide film on the entire surface of the product, and it is wasteful in terms of energy to anodic oxidation by immersing the entire work piece in an electrolytic solution as in the past. .
In addition, when an aluminum alloy cast product is used to increase the current density during electrolysis and to achieve high-speed processing, there has been a problem that an electrolytic burn is likely to occur and a uniform film is difficult to obtain.
従来から例えば、特許文献1〜4に開示するように部分的に陽極酸化処理する技術が各種提案されている。
しかし、いずれの技術もワークにリング状の部分陽極酸化皮膜を形成するのに適したものではない。
Conventionally, for example, as disclosed in
However, none of these techniques is suitable for forming a ring-shaped partial anodic oxide film on a workpiece.
本発明は、ワークにリング状の陽極酸化皮膜を部分的に形成するのに適した電解装置及びそれを用いた処理方法の提供を目的とする。 An object of the present invention is to provide an electrolytic apparatus suitable for partially forming a ring-shaped anodized film on a workpiece and a treatment method using the same.
本発明に係る部分陽極酸化処理用電解装置は、ワークにリング状の部分陽極酸化皮膜を形成するための電解装置であって、円筒状の内周壁と、当該内周壁の外側に所定の間隔を設けて形成した円筒状の外周壁と、当該内周壁と外周壁との一方の端部側を端部壁で塞いだ電解槽を備え、前記内周壁と外周壁との間の他方側の開口部を塞ぐようにワークをセットするものであり、前記外周壁は接線方向から内部に電解液を供給する供給部と、接線方向に内部から外部に向けて電解液を排出する排出部を有することを特徴とする。
このようにすると一方の端部側が塞がれ、内周壁と外周壁との間に形成された電解槽の開口部をワークで塞ぐようにセットし、接線方向から電解液を供給すると、ドーナツ状の電解槽に沿って電解液が渦を巻くように旋回しながら排出部から排出され、必要に応じて温調し循環される。
これにより、ワークの表面で発生したガスや熱が電解液の流れに沿って効率よく除かれるので高電流密度による高速処理化もしやすい。
本明細書では、内周壁と外周壁との間に電解液が充填される電解槽の構造を説明するために、一方の端部側の壁を便宜上、端部壁と表現したものであって、限らずしも内・外周壁の端部に限定するものではない。
An electrolytic apparatus for partial anodizing treatment according to the present invention is an electrolytic apparatus for forming a ring-shaped partial anodized film on a workpiece, and has a predetermined interval between a cylindrical inner peripheral wall and an outer side of the inner peripheral wall. A cylindrical outer peripheral wall provided and an electrolytic cell in which one end side of the inner peripheral wall and the outer peripheral wall is closed with an end wall, and an opening on the other side between the inner peripheral wall and the outer peripheral wall The outer peripheral wall has a supply part for supplying the electrolyte solution from the tangential direction to the inside and a discharge part for discharging the electrolyte solution from the inside to the outside in the tangential direction. It is characterized by.
In this way, one end side is closed, and the electrolytic cell opening formed between the inner peripheral wall and the outer peripheral wall is set so as to be closed with a workpiece, and the electrolyte is supplied from the tangential direction. The electrolytic solution is discharged from the discharge portion while swirling along the electrolytic cell, and the temperature is adjusted and circulated as necessary.
As a result, the gas and heat generated on the surface of the workpiece are efficiently removed along the flow of the electrolytic solution, so that high-speed processing with a high current density is easy.
In this specification, in order to explain the structure of the electrolytic cell in which the electrolytic solution is filled between the inner peripheral wall and the outer peripheral wall, one end side wall is expressed as an end wall for convenience. However, the present invention is not limited to the end portions of the inner and outer peripheral walls.
本発明にて、前記電解槽は内部に配設した陰極を有し、前記電解液の供給部と排出部とは陰極側と陽極となるワーク側とに位置を相対的にずらして配設してあるのが好ましい。
これにより、電解液の旋回流が安定する。
In the present invention, the electrolytic cell has a cathode disposed therein, and the electrolytic solution supply unit and the discharge unit are disposed with their positions relatively shifted from the cathode side and the workpiece side serving as the anode. Preferably it is.
Thereby, the swirl | vortex flow of electrolyte solution is stabilized.
本発明は、請求項1又は2記載の部分陽極酸化処理用電解装置を用いた処理方法であって、ワークは円盤部と、当該円盤部から突設した凸部を有し、前記ワークの凸部を前記内周壁の内側に挿入し、前記ワークの円盤部で前記電解槽の開口部を塞ぐようにシールセット配置し、前記円盤部にリング状の部分陽極酸化皮膜を形成することを特徴とする。
このようにすると、回転体の必要な表面にリング状の陽極酸化皮膜を効率的に形成することができる。
The present invention is a processing method using the electrolytic apparatus for partial anodizing treatment according to
If it does in this way, a ring-shaped anodic oxide film can be efficiently formed in the required surface of a rotating body.
本発明に係る電解装置を用いるとワークの表面にリング状の陽極酸化皮膜を形成することができるので、回転体等のワークの必要な表面に陽極酸化膜による耐摩耗性を付加することができる。
また、陽極酸化処理の高速化が可能で、それによる皮膜の硬質化を図り、耐摩耗性がさらに向上する。
When the electrolytic apparatus according to the present invention is used, a ring-shaped anodic oxide film can be formed on the surface of the work, so that the wear resistance by the anodic oxide film can be added to the necessary surface of the work such as a rotating body. .
In addition, it is possible to increase the speed of the anodizing treatment, thereby making the film harder and further improving the wear resistance.
本発明に係る電解装置及びそれを用いた処理方法例を以下、図面に基づいて説明する。 An example of an electrolytic apparatus according to the present invention and a treatment method using the same will be described below with reference to the drawings.
本発明における陽極酸化処理の対象とするのに適したワークの形状例を図1(d)と
図5に示す。
例えば対象製品は、車両向の回転部品となるワークが例として挙げられ、ワーク1は円盤部1aと円筒状の凸部1bを有する。
このような部品は例えばダイカスト用アルミニウム合金JIS ADC12等を用いてダイカスト鋳造される。
電解槽10は図1,2に示すように、円筒状の内周壁12と同心円状の外周壁11の一方の端部側を端部壁13に塞いだ開口部から見た平面視で略ドーナッツ状の槽構造になっている。
図2では上部側に陰極20が配設され、外部に陰極導線部20aが設けられている。
外周壁11は、接線方向に内部に電解液を供給するための供給部14と、供給された電解液が接線方向に排出するための排出部15を有する。
従って、平面視では図2(a)に示すようにパイプ状の供給部14、排出部15が外周壁の接線方向に溶接等により接続されている。
また、電解液の供給部14と排出部15とは、側面図に示すように上下方向に相互にずらして配置してあり、本実施例ではワーク側よりに供給部14を配置し、端部壁側に排出部15を配置した例になっている。
FIG. 1D and FIG. 5 show examples of the shape of a workpiece suitable for the object of anodizing treatment in the present invention.
For example, the target product is a workpiece that is a rotating component for a vehicle, and the
Such a part is die-cast using, for example, an aluminum alloy for die casting JIS ADC12.
As shown in FIGS. 1 and 2, the
In FIG. 2, a
The outer
Therefore, in plan view, as shown in FIG. 2A, the pipe-
The electrolyte
ワーク1を図1(b)に示すように凸部1bが内周壁12の内側に挿通されるようにセットすると、図3(a)に断面図を示すようにワーク1の円盤部1aの表面で電解槽の開口部を塞ぐ。
ワーク1と電解槽の間をOリング等のシール部材11a,12aにてシールする。
例えば、ワークを下側に配置し、電解槽とワークとを相互に押圧セットすることでシールされる。
この状態で図3(b)に示すように、供給部14から電解液Sを供給すると図4(b)に模式図を示すように電解液Sは矢印に示すように旋回し、ワークの表面から上方に流れ、排出部15から排出される。
この状態でワーク1を陽極として、陰極との間に直流等の電圧を印加することでワークの表面に陽極酸化皮膜が形成される。
その状態を図1(d),図5(d)にAとして示す。
When the
The
For example, the work is placed on the lower side, and the electrolytic cell and the work are pressed and set to each other for sealing.
In this state, as shown in FIG. 3B, when the electrolytic solution S is supplied from the
In this state, an anodic oxide film is formed on the surface of the workpiece by applying a voltage such as a direct current between the
This state is shown as A in FIGS. 1 (d) and 5 (d).
次に電解処理した実施例を説明する。
外径約100mm、凸部の外径約45mmのワークに幅約15mmのリング状の陽極酸化皮膜Aを形成した。
電解槽の内周壁の外径は約50mm、外周壁の内径は約80mmとなる。
電解液としてはアルミニウム合金の陽極酸化に用いられる公知の各種電解液を用いることができ、本実験では200g/lの硫酸水溶液を用いた。
液温10℃,流量15リットル/分,電圧30Vとし、20分間電解処理した。
なお、電圧計、制御系は公知のものを用い、図示を省略した。
その結果、膜厚約8μmの陽極酸化皮膜が形成され、摩耗試験の結果、約10,000サイクルの摩耗試験で耐摩耗性基準を充分にクリアーした。
ADC12材からなるダイカスト製品は鋳造性に優れるものの、一般的には陽極酸化処理が難しいとされている材料であるが、本発明に係る電解装置を用いると、均一に陽極酸化処理できた。
また、電解条件も直流のみならず交流等の組み合せでもよく、必要に応じて電解液は冷却装置を経由してポンプ循環させることで電解液の温調を図ることができる。
Next, an example of electrolytic treatment will be described.
A ring-shaped anodized film A having a width of about 15 mm was formed on a workpiece having an outer diameter of about 100 mm and a convex portion having an outer diameter of about 45 mm.
The outer diameter of the inner peripheral wall of the electrolytic cell is about 50 mm, and the inner diameter of the outer peripheral wall is about 80 mm.
As the electrolytic solution, various known electrolytic solutions used for anodic oxidation of aluminum alloys can be used. In this experiment, 200 g / l sulfuric acid aqueous solution was used.
Electrolytic treatment was performed at a liquid temperature of 10 ° C., a flow rate of 15 liters / minute, and a voltage of 30 V for 20 minutes.
In addition, a voltmeter and a control system used a well-known thing, and illustration was abbreviate | omitted.
As a result, an anodized film having a film thickness of about 8 μm was formed. As a result of the wear test, the wear resistance standard was sufficiently cleared by a wear test of about 10,000 cycles.
Although the die-cast product made of ADC12 material is excellent in castability, it is generally a material that is difficult to anodize. However, when the electrolytic apparatus according to the present invention is used, it can be uniformly anodized.
Further, the electrolysis conditions may be a combination of not only direct current but also alternating current. If necessary, the temperature of the electrolytic solution can be controlled by pumping the electrolytic solution through a cooling device.
1a 円盤部
1b 凸部
10 電解槽
11 外周壁
12 内周壁
13 端部壁
14 供給部
15 排出部
20 陰極
A 陽極酸化皮膜部
DESCRIPTION OF SYMBOLS
Claims (3)
円筒状の内周壁と、当該内周壁の外側に所定の間隔を設けて形成した円筒状の外周壁と、当該内周壁と外周壁との一方の端部側を端部壁で塞いだ電解槽を備え、
前記内周壁と外周壁との間の他方側の開口部を塞ぐようにワークをセットするものであり、
前記外周壁は接線方向から内部に電解液を供給する供給部と、接線方向に内部から外部に向けて電解液を排出する排出部を有することを特徴とする部分陽極酸化処理用電解装置。 An electrolytic apparatus for forming a ring-shaped partial anodic oxide film on a workpiece,
A cylindrical inner peripheral wall, a cylindrical outer peripheral wall formed at a predetermined interval outside the inner peripheral wall, and an electrolytic cell in which one end side of the inner peripheral wall and the outer peripheral wall is closed with an end wall With
The work is set so as to close the opening on the other side between the inner peripheral wall and the outer peripheral wall,
2. The partial anodizing electrolytic apparatus according to claim 1, wherein the outer peripheral wall has a supply part for supplying an electrolytic solution from the tangential direction to the inside and a discharge part for discharging the electrolytic solution from the inside to the outside in the tangential direction.
前記ワークの凸部を前記内周壁の内側に挿入し、前記ワークの円盤部で前記電解槽の開口部を塞ぐようにシールセット配置し、
前記円盤部にリング状の部分陽極酸化皮膜を形成することを特徴とする部分陽極酸化処理方法。 It is a processing method using the electrolytic apparatus for partial anodizing treatment according to claim 1 or 2, wherein the workpiece has a disk part and a convex part protruding from the disk part,
Insert the convex part of the work inside the inner peripheral wall, and place the seal set so as to block the opening of the electrolytic cell with the disk part of the work,
A partial anodizing method comprising forming a ring-shaped partial anodized film on the disk portion.
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0693498A (en) * | 1992-09-10 | 1994-04-05 | Toupure Kk | One-side anodic oxidation treating equipment |
JPH09217200A (en) * | 1995-12-04 | 1997-08-19 | Techno Kogyo Kk | Anodic oxidation treating device for aluminum or aluminum alloy |
JP2002275686A (en) * | 2001-01-15 | 2002-09-25 | Unisia Jecs Corp | Process and apparatus for anodic oxidation |
JP2004059936A (en) * | 2002-07-24 | 2004-02-26 | Aisin Keikinzoku Co Ltd | Surface treatment apparatus for aluminum alloy |
JP2009185334A (en) * | 2008-02-06 | 2009-08-20 | Mitsubishi Materials Corp | Plating equipment |
US20130068067A1 (en) * | 2011-09-20 | 2013-03-21 | Hyundai Motor Company | Rear-cover for a transmission and method for coating thereof |
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2015
- 2015-09-25 JP JP2015188881A patent/JP6529877B2/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0693498A (en) * | 1992-09-10 | 1994-04-05 | Toupure Kk | One-side anodic oxidation treating equipment |
JPH09217200A (en) * | 1995-12-04 | 1997-08-19 | Techno Kogyo Kk | Anodic oxidation treating device for aluminum or aluminum alloy |
JP2002275686A (en) * | 2001-01-15 | 2002-09-25 | Unisia Jecs Corp | Process and apparatus for anodic oxidation |
JP2004059936A (en) * | 2002-07-24 | 2004-02-26 | Aisin Keikinzoku Co Ltd | Surface treatment apparatus for aluminum alloy |
JP2009185334A (en) * | 2008-02-06 | 2009-08-20 | Mitsubishi Materials Corp | Plating equipment |
US20130068067A1 (en) * | 2011-09-20 | 2013-03-21 | Hyundai Motor Company | Rear-cover for a transmission and method for coating thereof |
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