JP2017017095A - Passage member and heat exchanger using the same and semiconductor manufacturing equipment - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a passage member that is able to withstand long term use while having excellent heat exchange efficiency and to provide a heat exchanger using the same and semiconductor manufacturing equipment.SOLUTION: A passage member 10 according to the present invention is made of ceramics and has a passage 3 therein. In a first area on an external surface 1 corresponding to a first wall 7 that is the thinnest among walls forming the passage 3 and a second area on an internal surface 2, if a peak count obtained from a roughness curve in the first area is Pc1 and a peak count obtained from a roughness curve in the second area is Pc2, Pc2 is greater than Pc1.SELECTED DRAWING: Figure 1

Description

  The present invention relates to a flow path member, a heat exchanger using the same, and a semiconductor manufacturing apparatus.

  A flow path member provided with a flow path for flowing a fluid therein is used in a cooling or heating system or the like in various manufacturing apparatuses. Then, by flowing a low-temperature or high-temperature fluid through the flow path of the flow path member, heat exchange is performed between an object to be placed on the flow path member or an object to be processed such as outside air outside the flow path member and a fluid flowing through the flow path. Is performed, and the object to be processed can be cooled or heated. For example, in the case where the object to be processed is a wafer, the wafer can be cooled by flowing a low-temperature liquid through the flow path to exchange heat between the wafer and the low-temperature liquid.

  The material of the flow path member has high corrosion resistance from the viewpoint that it can be used in a highly corrosive gas environment, or a highly corrosive gas or fluid can be used as a fluid flowing through the flow path. In addition, ceramics excellent in durability and insulation are used.

  For example, in Patent Document 1, a first ceramic base material in which a flow path for passing a refrigerant is formed, and a main surface and a side surface on a side on which a substrate of the first ceramic base material is placed are formed. Further, there is disclosed a substrate processing apparatus including a mounting table having a first conductive layer and an electrostatic chuck that is stacked on the first conductive layer and electrostatically attracts the mounted substrate.

JP 2014-160790 A

  In recent years, in order to efficiently cool or heat the object to be processed, among the walls forming the flow path of the flow path member, by reducing the thickness of the wall corresponding to the site where the most heat exchange efficiency is required, A configuration is adopted in which the distance between the object to be processed and the fluid flowing in the flow path is reduced to improve the heat exchange efficiency. However, if the wall forming the flow path is thin, the influence of the pressure of the fluid flowing through the flow path (hereinafter referred to as internal pressure) increases, and the internal pressure of the wall facing the flow path is compressed by this internal pressure. Stress acts, and tensile stress acts on the outer surface of the wall corresponding to the inner surface. Ceramics have a lower strength against tensile stress than compressive stress. Therefore, when internal pressure is applied, microcracks are generated on the outer surface of the wall, and the generated microcracks extend from the outer surface of the wall to the inner surface due to continued internal pressure. If this happens, cracks will occur and the fluid may leak or break. Therefore, it is required that the current flow path members have excellent heat exchange efficiency and can withstand long-term use. It has been.

  Accordingly, an object of the present invention is to provide a flow path member that can withstand long-term use while having excellent heat exchange efficiency, a heat exchanger using the same, and a semiconductor manufacturing apparatus.

The flow path member of the present invention is a flow path member made of ceramics and having a flow path therein, and is a first region on the corresponding outer surface of the thinnest first wall among the walls forming the flow path. And the second area on the inner surface, Pc1 represents the peak count obtained from the roughness curve in the first area, and Pc represents the peak count obtained from the roughness curve in the second area.
When 2, it is characterized in that Pc2 is larger than Pc1.

  Moreover, the heat exchanger of this invention is equipped with the metal member in said flow-path member, It is characterized by the above-mentioned.

  Moreover, the semiconductor manufacturing apparatus of this invention is equipped with the electrode in said flow-path member, It is characterized by the above-mentioned.

  The flow path member of the present invention can withstand long-term use while having excellent heat exchange efficiency.

  Moreover, since the heat exchanger of the present invention can efficiently transfer heat between the object to be processed and the fluid via the metal member, the heat exchanger has more excellent heat exchange efficiency.

  In addition, since the semiconductor manufacturing apparatus of the present invention can keep the temperature of the object to be processed constant, highly accurate processing and processing can be performed.

An example of the flow path member of this embodiment is shown, (a) is an external perspective view, and (b) is a cross-sectional view taken along line II-II in (a). As an example of the flow path of the flow path member of this embodiment, it is sectional drawing which shows a horizontal cross section with respect to the direction through which a fluid flows, (a) is a meandering flow path, (b) is a spiral flow path. It is. It is the schematic which shows an example of a semiconductor manufacturing apparatus provided with the flow-path member of this embodiment.

  Hereinafter, a flow path member of the present embodiment, a heat exchanger using the same, and a semiconductor manufacturing apparatus will be described in detail with reference to the drawings. In the drawings, parts having the same configuration and function will be described with the same reference numerals. Further, the drawings are schematically shown, and the sizes and positional relationships of various structures in the drawings are not accurately illustrated. Further, FIG. 1A shows a right-handed XYZ coordinate system in which the horizontal direction in the drawing is the X direction.

  First, an example of the flow path member of the present embodiment will be described with reference to FIG.

  The flow path member 10 of the present embodiment is made of ceramics, has a flow path 3 through which a fluid flows, and the corresponding outer surface of the first wall 7 having the thinnest thickness among the walls forming the flow path 3. When the peak count obtained from the roughness curve in the first region is Pc1 and the peak count obtained from the roughness curve in the second region is Pc2 in the first region in 1 and the second region in the inner surface 2, from Pc1 Pc2 is large. In addition, in FIG. 1A, although the inflow port and the outflow port used as the fluid inlet / outlet are not illustrated, each has at least one.

  Here, the thinnest first wall 7 among the walls forming the flow path 3 is a cut-out section of the flow path member 10 as shown in FIG. 1 (b), and at least five or more places on each wall. When the thickness is measured and the average value of the thickness of each wall is calculated and compared, the wall has the smallest average value of the thickness.

In the first wall 7, the inner surface 2 faces the flow path 3, and the region corresponding to the inner surface 2 is the outer surface 1. Here, the area | region corresponding to the inner surface 2 is an area | region pinched | interposed on the vertical line of the both ends of the inner surface 2 in a cross section as shown in FIG.1 (b). In addition, the first region on the outer surface 1 and the second region on the inner surface 2 are regions that overlap when transmitted through a plane, and in the cross section as shown in FIG. It is in a connected relationship. The fact that such a relationship is satisfied is expressed as “corresponding”.

  Moreover, the peak count calculated | required from a roughness curve is the number which exists per unit length (10 mm) of the part which becomes a peak and a trough with respect to a center line when the average height of roughness is made into a center line. It is an index showing.

  And since the flow path member 10 of this embodiment has Pc2 larger than Pc1, since the valley bottom shape in the 1st field is gentle, the 1st field where tensile stress works by the internal pressure by the fluid which flows through flow path 3 Microcracks are less likely to occur. In the second region, since the compressive stress applied can be relaxed due to the surface property that there are many valleys, microcracks are unlikely to occur in the second region. Thus, since the flow path member 10 of this embodiment is a thing in which generation | occurrence | production of the microcrack is suppressed in a 1st area | region and a 2nd area | region, since the crack which penetrates the 1st wall 7 does not arise easily. It can withstand long-term use while having excellent heat exchange efficiency.

  Here, the peak count obtained from the roughness curves in the first region and the second region can be obtained by measuring in accordance with JIS B 0601 (2001) using a contact-type surface roughness meter. As measurement conditions, for example, the measurement length may be 4 mm, the cutoff value is 0.25 mm, the stylus radius is 2 μm, and the stylus scanning speed is set to 0.25 mm / second. Then, in the first region and the second region, at least three points are measured with the measurement directions aligned, and the average values may be used as the peak counts Pc1 and Pc2.

  Further, the flow path member 10 of the present embodiment preferably has a peak count Pc2 of 50 or more and 200 or less. With such a configuration, it is possible to alleviate the compressive stress and further suppress the occurrence of microcracks.

  Moreover, it is preferable that the cultosis Rku calculated | required from the roughness curve in a 1st area | region is 2.2 or more and 3.8 or less. The kurtosis Rku obtained from the roughness curve is an index representing kurtosis, which is a measure of surface sharpness. And if kurtosis Rku is 3, it will show that the kurtosis of the part which becomes a peak in the surface, and the part which becomes a valley is a state of normal distribution. On the other hand, if the kurtosis Rku is larger than 3, the apex vicinity of the peak portion and the valley portion becomes more sharp, and if the kurtosis Rku is smaller than 3, the peak portion and the valley portion. The vicinity of the apex of the shape becomes more crushed.

  Therefore, if the kurtosis Rku obtained from the roughness curve in the first region is 2.2 or more and 3.8 or less, the kurtosis of the valley portion in the first region is in a substantially normal distribution state. The tensile stress acting on one region can be relaxed, and the generation of microcracks in the portion that becomes the valley in the first region can be further suppressed.

  Moreover, it is preferable that the cultosis Rku calculated | required from the roughness curve in the 2nd area | region of the flow-path member 10 of this embodiment is 4 or more. In such a configuration, the vicinity of the apex of the portion that becomes the valley in the second region has a sharper shape, so the width of the portion that becomes the valley becomes narrower, and the compressive stress acting on the second region can be relieved. It is possible to further suppress the occurrence of microcracks at the valleys in the second region.

  Here, the kurtosis Rku obtained from the roughness curves in the first region and the second region can be obtained by measuring with the same measuring instrument and measurement conditions as the above-described peak count.

  In addition, as the ceramic constituting the flow path member 10, alumina sintered body, zirconia sintered body, silicon nitride sintered body, aluminum nitride sintered body, silicon carbide sintered body, cordierite sintered body A ligature or a composite thereof can be used. Of these ceramics, it is preferable to use a silicon carbide sintered body from the viewpoint of rigidity, thermal conductivity, and light weight.

  Next, an example of the flow path of the flow path member of the present embodiment will be described with reference to FIG.

  The flow path 3 is not particularly limited, but is preferably formed so that the fluid flows through one path. For example, when the fluid is distributed to a plurality of paths with a single inlet, the fluid tends to flow through a flow path having a low pressure related to the fluid, which may cause unevenness in heat exchange with the object to be processed. is there. On the other hand, the flow path 3 through which the fluid flows is formed in one path, such as the meandering flow path member 20 shown in FIG. 2A and the spiral flow path member 30 shown in FIG. If it is, there is little possibility of causing unevenness in heat exchange with the object to be processed, and therefore it can be suitably used in applications that require little temperature variation.

  In the following description, the flow path member will be described with reference numeral “100”.

  The heat exchanger of the present embodiment includes a metal member in the flow path member 100 of the present embodiment. Here, the metal member is located on the outer surface 1 of the first wall 7. And the heat exchanger of this embodiment which satisfy | fills such a structure can perform the transmission of the heat | fever of a to-be-processed object and a fluid via a metal member efficiently, and can improve heat exchange efficiency more. . In addition to flowing a cold fluid through the flow path 3, it is possible to more precisely control the temperature of the object to be processed by appropriately performing heating by flowing a current through the metal member.

  Next, an example of the semiconductor manufacturing apparatus 40 of this embodiment will be described with reference to FIG.

  The semiconductor manufacturing apparatus 40 according to this embodiment includes the electrode 5 on the flow path member 100. Here, the electrode 5 is located on the outer surface 1 of the first wall 7. Although not shown, a dielectric layer is provided between the wafer 6 and the electrode 5. Here, by applying a voltage to the electrode 5, the wafer 6 can be attracted and held by an electrostatic attracting force such as a clone force or a Johnson-Rahbek force generated between the wafer 6 and the dielectric layer.

  Furthermore, when this semiconductor manufacturing apparatus 40 is used as a plasma processing apparatus, the electrode 5 can be used as a lower electrode for generating plasma, and is provided for generating plasma above the wafer 6. By applying a voltage between the upper electrode 4 and the lower electrode 5, plasma generated between the upper electrode 4 and the lower electrode 5 can be applied to the wafer 6. Yes. And since the semiconductor manufacturing apparatus 40 is provided with the flow path member 100 and the electrode 5 of this embodiment, it is possible to quickly cool the electrode 5 as the lower electrode that becomes a high temperature during plasma processing. Since the temperature effect of the electrode 5 as the lower electrode on the wafer 6 is reduced and the temperature of the wafer 6 can be kept constant, processing with high dimensional accuracy can be performed.

Further, as the semiconductor manufacturing apparatus 40 of the present embodiment, there are a sputtering apparatus, a resist coating apparatus, a CVD apparatus, an etching processing apparatus, etc. in addition to the plasma processing apparatus of FIG. Since the structure is provided with the electrode 5 in the flow path member 100, the temperature of the object to be processed can be kept constant, so that highly accurate processing and processing can be performed.

  Hereinafter, an example of a method for manufacturing the flow path member 100 of the present embodiment will be described. In the following description, a case where a silicon carbide sintered body is used as the ceramic will be described.

First, a silicon carbide powder as a main component is prepared, and a predetermined amount of a solvent, a sintering aid, and a binder are added to the powder, and the slurry is pulverized to a predetermined particle size using a ball mill or a bead mill. Is made. As the sintering aid to be added, B 4 _C system, it is possible to use a sintering aid of a rare earth oxide -Al ₂ O ₃ system. The binder to be added may be a synthetic resin.

  In addition, about the ball | bowl and bead used by a mill, since it is preferable to use the thing which does not affect the characteristic of the flow-path member 100, for example, a ball | bowl and a bead have the composition similar to or approximate to a silicon carbide sintered body. It is preferably made of ceramics.

  Next, a green sheet is formed from this slurry by a known doctor blade method or roll compaction method, and this is formed into a desired shape by mold processing or laser processing, thereby forming an upper wall including the first wall 7. Get the body. In addition, in order to make the molded object used as an upper wall into desired thickness, you may pile a some molded object by using the slurry mentioned above as a bonding agent. In addition, the molded body serving as the side wall and the molded body serving as the lower wall may be stacked on the green sheet so as to have a desired shape by die processing or laser processing or to have a desired thickness. In addition, even if it uses the granulated body which spray-dried the slurry mentioned above and cuts after a powder press method and a rubber press (CIP) method, even if the molded object with which the side wall and the lower wall were united is obtained. Good. Moreover, you may form an inflow port and an outflow port in the stage of a molded object.

  And after drying the molded object used as an upper wall, a side wall, and a lower wall, it hold | maintains to predetermined temperature in nitrogen gas, and degreasing is performed. Thereafter, this is fired in an argon gas at a temperature of 1900 to 2050 ° C. for 3 to 10 hours to obtain an upper wall sintered body, a side wall sintered body, and a lower wall sintered body.

  Next, the polishing process performed on the upper wall sintered body will be described with reference to FIG. First, the grindstone is such that the polishing location is a straight line along the −X-direction end of the first region 1A from the −Y-direction end of the location that becomes the first region 1A to the + Y-direction end. Polish with. Next, the grindstone is moved from the polishing location in the + X direction so as to partially overlap the polishing location, and polishing is performed again from the end portion in the + Y direction to the end portion in the −Y direction at the location that becomes the first region 1A. Hereinafter, the polishing speed for polishing from the end portion in the −Y direction to the end portion in the + Y direction is referred to as a feed rate, and the width for moving the grindstone in the + X direction is referred to as a feed width. Then, the first region 1A is formed by repeatedly performing this polishing from the −X direction end to the + X direction end of the portion to be the first region.

  Then, by reducing the feed width at the time of polishing the portion to be the second region to be smaller than the feed width at the time of polishing the portion to be the first region, the peak in the second region is larger than the peak count Pc1 in the first region. The count Pc2 increases.

  Moreover, if the feed width of the grindstone when polishing the portion to be the second region is 2 mm or more and 7 mm or less, the peak count Pc2 in the second region can be 50 or more and 200 or less.

  Furthermore, by setting the feed speed of the grindstone when polishing the portion that becomes the first region or the second region, the kurtosis Rku in the first region or the second region can be controlled to an arbitrary value. For example, in order to set the kurtosis Rku in the first region to 2.2 or more and 3.8 or less, the feed speed of the grindstone when polishing the portion to be the first region is 0.28 m / second or more and 0.32 m / second or less. In order to set the kurtosis Rku in the second region to 4 or more, the feed speed of the grindstone when polishing the portion to be the second region may be 0.26 m / second or less.

  And after grinding the place used as the 1st field and the 2nd field of an upper wall sintered compact with a whetstone as mentioned above, by joining a side wall sintered compact and a lower wall sintered compact by a publicly known joining method, The flow path member 100 of this embodiment can be obtained. Here, a well-known joining method is glass joining, diffusion joining, joining via a metal layer, etc.

  Further, as another method of manufacturing the flow path member 100 of the present embodiment, a pressing die having a surface property of Pc1 is pressed against one surface of a molded body serving as an upper wall, and the surface property is applied to the other surface. You may obtain by pressing the pressing die which is Pc2, using the slurry mentioned above as a bonding agent, stacking the molded body which becomes a side wall, and the molded body which becomes a lower wall, and baking them.

  It should be noted that the present invention is not limited to the above-described embodiment, and various changes and improvements can be made without departing from the gist of the present invention.

  Using the semiconductor manufacturing apparatus of the present embodiment shown in FIG. 3, the endurance test of the flow path member was performed.

  First, silicon carbide powder as a main component was prepared, and 0.3 parts by weight of boron carbide as a sintering aid and 3 parts by weight of graphite powder as a carbon component with respect to 100 parts by mass of the silicon carbide powder. , By adding polyethylene glycol and polyvinyl alcohol as a binder, each 5 parts by weight in terms of solid content, and water as a solvent, and using a ball mill or a bead mill to pulverize to an average particle size of 2 μm, A slurry was prepared. And using this slurry, the green sheet was formed by the well-known doctor blade method, and the molded object used as the upper wall containing the 1st wall was obtained by processing this into a mold. . Moreover, about the molded object used as a side wall, and the molded object used as a lower wall, after making into a desired shape by carrying out the die process to a green sheet, the molded object used as a side wall by stacking the slurry mentioned above as a bonding agent, and A molded body serving as a lower wall was obtained. Here, the obtained molded body serving as the side wall includes a fluid inlet and outlet and a penetrating portion serving as a flow path.

  Next, after drying the molded body that becomes the upper wall, the side wall, and the lower wall, it was degreased at a predetermined temperature in nitrogen gas for 5 hours, and then held in argon gas at a temperature of 2000 ° C. for about 10 hours. By firing, an upper wall sintered body, a side wall sintered body, and a lower wall sintered body were obtained.

  Next, the first region and the second region were formed by polishing the outer surface and inner surface of the upper wall sintered body with a grindstone having diamond abrasive grains having an average particle diameter of about 0.04 mm on the surface. Here, as the polishing conditions, the feed rate was set to 0.34 m / sec, and the feed width was set to the values shown in Table 1.

  And the peak count in the 1st area | region and 2nd area | region of the grind | polished upper wall sintered compact was measured based on JISB0601 (2001) using the contact-type surface roughness meter. The measurement conditions were a measurement length of 4 mm, a cutoff value of 0.25 mm, a stylus radius of 2 μm, and a stylus scanning speed of 0.25 mm / sec. Then, in the first region and the second region, the measurement direction was aligned and measured at three locations, and the average values were used as peak counts Pc1 and Pc2.

  And each sample was obtained by joining the upper wall sintered compact, the side wall sintered compact, and the lower wall sintered compact by glass joining. In addition, the thickness of the 1st wall in an upper wall sintered compact was 2 mm.

  Next, each of the obtained samples was incorporated in the semiconductor manufacturing apparatus shown in FIG. 3, and a pressure of 0.2 MPa was applied to circulate cooling water through the flow path. Then, the temperature of the cooling water was set to 20 ° C., the electrode was heated so that the outer surface of the first wall was 300 ° C., and the durability test was performed for each sample by holding in this state for 100 hours.

  Thereafter, a test piece having a width of 30 mm, a thickness of 2 mm, and a length of 80 mm was cut out from the first wall of each sample, and a four-point bending strength was calculated by a method based on JIS R 1616 (2008). Here, the four-point bending strength was calculated because it is very difficult to measure the number and length of microcracks, so by measuring the four-point bending strength after the durability test, This is to evaluate whether it can withstand use. The results are shown in Table 1.

  From the results shown in Table 1, the sample Nos. With the peak count Pc2 larger than the peak count Pc1. Nos. 1 to 7 have a four-point bending strength of 300 MPa or more, and were found to be flow path members that can withstand long-term use.

  And sample no. 1 to 7, the sample N o. Nos. 1 to 6 have a four-point bending strength of 340 MPa or more, and were found to be flow path members that can withstand longer use.

  Next, samples having different kurtosis Rku in the first region were prepared, and after endurance tests of each sample were performed in the same manner as in Example 1, the four-point bending strength of each sample was measured. In addition, as a manufacturing method, the sample No. 1 of Example 1 was used except that the feeding speed of the grindstone when the portion to be the first region was polished was set to the values shown in Table 2. 5 and the sample N. 12 is a sample N o. 5 is the same sample.

  And the kurtosis Rku in the 1st area | region of each sample was measured based on JISB0601 (2001) using the contact-type surface roughness meter. The measurement conditions were a measurement length of 4 mm, a cutoff value of 0.25 mm, a stylus radius of 2 μm, and a stylus scanning speed of 0.25 mm / sec. Then, three locations were measured in the first region, and this average value was defined as kurtosis Rku in the first region.

  Next, after performing an endurance test of each sample by the same method as in Example 1, the 4-point bending strength of each sample was calculated. The results are shown in Table 2.

  From the results shown in Table 2, sample Nos. 1 and 2 with a kurtosis Rku of 2.2 to 3.8 were obtained. It was found that 13 to 15 were flow path members having a high four-point bending strength of 400 MPa or more and having excellent durability.

  Next, samples having different kurtosis Rku in the second region were prepared, and each sample was subjected to a durability test by the same method as in Example 1. Then, the four-point bending strength of each sample was measured. In addition, as a manufacturing method, the sample No. 1 in Example 2 was used except that the feeding speed of the grindstone when the portion to be the second region was polished was set to the values shown in Table 3. 14 is the same as the manufacturing method of Sample No. 14. 17 is a sample N. 14 is the same sample.

  The kurtosis Rku in the second region of each sample was calculated in the same manner as in Example 2.

  Next, after performing an endurance test of each sample by the same method as in Example 1, the 4-point bending strength of each sample was calculated. The results are shown in Table 3.

  From the results shown in Table 3, the samples N o. 19 to 23 were found to be flow path members having a very excellent durability with a high four-point bending strength of 440 MPa or more.

1: outer surface 2: inner surface 3: flow path 4: upper electrode 5: electrode 6: wafer 7: thinnest wall (first wall)
10, 20, 30, 100: Channel member 40: Semiconductor manufacturing apparatus

Claims (6)

A channel member made of ceramics and having a channel inside,
The peak count obtained from the roughness curve in the first region in the first region on the corresponding outer surface and the second region on the inner surface of the first wall having the smallest thickness among the walls forming the flow path is Pc1, A flow path member, wherein Pc2 is larger than Pc1 when a peak count obtained from a roughness curve in the second region is Pc2.   Pc2 is 50 or more and 200 or less, The flow-path member of Claim 1 characterized by the above-mentioned.   The flow path member according to claim 1 or 2, wherein a kurtosis Rku obtained from a roughness curve in the first region is 2.2 or more and 3.8 or less.   The flow path member according to any one of claims 1 to 3, wherein a kurtosis Rku obtained from a roughness curve in the second region is 4 or more.   A heat exchanger comprising a metal member in the flow path member according to any one of claims 1 to 4.   A semiconductor manufacturing apparatus comprising an electrode in the flow path member according to claim 1.