JP2016205133A - Method for decreasing discharging of greenhouse effect gas - Google Patents

Abstract

PROBLEM TO BE SOLVED: To apply an internal combustion engine capable of reducing discharging of greenhouse effect gas "CO" to cope with global warming, as power generating facility.SOLUTION: The problem described above is resolved in such a way that there are provided taking-out facility Ms for reacting water and carbon with waste-heat of an internal combustion engine 1 to take out mixture gas of hydrogen and carbon mono-oxide and a storage gas tank MT for storing mixture gas of taken-out hydrogen and carbon mono-oxide, the taken-out mixture gas of hydrogen and carbon mono-oxide is stored or applied as fuel for the internal combustion engine 1 through the storage gas tank and further the taking-out facility Ms is installed at a transporting device and applied as fuel for the internal combustion engine installed at the transporting device, further carbon dioxide of the discharged gas is also made into mixture gas of hydrogen and carbon mono-oxide and the taken-out hydrogen and carbon mono-oxide are separated into hydrogen gas and carbon dioxide and taken out separately, quality of carbon dioxide is improved and the carbon dioxide is applied as starting material for generating synthesis gas.SELECTED DRAWING: Figure 1

Description

An internal combustion engine that contributes to the reduction of greenhouse gas emissions, particularly producing carbon C and water H ₂ O, mainly plant, into synthesis gas (H ₂ + CO) in the internal combustion engine, Further, carbon dioxide discharged from the combustion of the synthesis gas is separated as fuel for the internal combustion engine and reformed into synthesis gas H ₂ + CO and hydrogen in the internal combustion engine, and the synthesis gas and hydrogen are used as fuel for the internal combustion engine. To do.

Greenhouse gases are a major cause of global warming, and it is a common recognition in the world to think that “greenhouse gases should be reduced.” However, it is at the stage of “specific numerical targets…” In the era of international price competition, the current situation is that the story has not progressed because it will incur greenhouse gas reduction costs.
As a power source of an automobile (internal combustion engine) of a greenhouse gas emission reduction measure as of 2014, an electric vehicle, a hybrid with hydrogen, or an engine system using only hydrogen or "bioethanol" as fuel There is also a technology for reducing greenhouse gas emissions by reforming a fuel of 2008-298030 or “bioethanol” into a fuel containing hydrogen and carbon monoxide and using the reformed gas as a fuel. There are still problems that must be solved in order to commercialize products, and it is recognized that there is a part that each problem is lacking in the process of solving.
Of the technologies mentioned above, in the technology using electricity as the power source, according to the statistics of the Electricity Federation of 2011, about 82% of Japan's total power generation is thermal power generation. since the discharging "CO _2" and using the fossil fuels, including unless realized measures that do not emit "CO _2" from the power plant, a greenhouse global warming electricity as a power source It cannot be said that it is a power source of the internal combustion engine that contributes to reducing the effect gas.
Moreover, nuclear power generation is a power source that does not emit “CO ₂ ”, which uses electricity as the power source of the above technology to reduce greenhouse gases. However, there is a problem of “Fukushima nuclear power plant”, so it is difficult to establish a new one. And I think that the view that it goes to the direction of decommissioning occupies a lot.

Equipment for reducing the “CO ₂ ” already exists, and the method is a proposal to sequester the discharged carbon dioxide deeply (A) or sequestered (B). The world's largest coal-fired power plant in the United States was completed in 2014, but the treatment of “CO ₂ ” emitted by this power generation is a structure that can be contained in a 150,000-meter underground layer (A). However, the construction cost of this power plant is twice as usual, and there is a problem that it costs energy to contain it in the underground layer of 150,000 m, and this cost is added to the electricity bill and becomes a consumer burden. is there.

Various technologies have been proposed one after another for the technology to obtain synthesis gas or hydrogen gas by reforming the above-mentioned “CO ₂ ”, and have already been proposed in the in-service sector as an energy generation technology for blast furnace gas and converter gas in steelworks. There are many technologies that have been put to practical use, and the gas emitted in the power generation process of thermal power plants is also used to increase energy efficiency, but most of them are fixed-form features in the large-scale equipment industry. In addition, no feasible technology has been proposed (not found) for reforming “CO ₂ ” discharged from the internal combustion engine in the internal combustion engine that can be mounted on the moving form and using it as a fuel for the internal combustion engine.

Patent 5647364. Engine mechanism of rotary piston engine car. JP-A-11-106770. Power generation method and apparatus using dimethyl ether reformed gas Patent 4231735. Method and apparatus for separating and recovering carbon dioxide JP 2007-177684 A, a carbon dioxide recovery device for a vehicle, and a vehicle including the same. Reaction of hydrocarbons with water vapor or carbon dioxide. Patent 4,609,718 Hydrogen rotary piston engine fuel injection device Japanese Patent Application No. 10-543729 (patent 33455782) synthesis gas production method.

A rotary piston engine combusted by auxiliary fuel, a water supply means for supplying water to the rotor housing of the rotary piston engine from the introduction pipe, and the supplied water is steamed by the heat of the rotor housing, And a livestock gas means for storing the gas that is generated by the endothermic reaction using the exhaust heat after the combustion process of the rotary piston engine and generating the fuel while the auxiliary fuel is used. There is a technique (for example, Patent Document 1) characterized by a structure including a switching means for switching the livestock gas of the livestock gas means and the auxiliary fuel to be supplied to the rotary piston engine, and this application is based on this technique. as carbon dioxide in the exhaust gas from the combustion of the fuel (CO ₂₎ also to adopt a technique of reforming a fuel, further We are in a technology that is a greenhouse gas emission reduction measures that.

Uses dimethyl ether reformed gas, characterized in that dimethyl ether is reformed by adding steam or carbon dioxide gas to dimethyl ether to cause a catalytic reaction to obtain synthesis gas or hydrogen gas, and this gas is used as a fuel for a prime mover There is a power generation method, and the above power generation method (for example, Patent Document 2), characterized in that the reforming of dimethyl ether is performed using medium to low temperature waste heat from 200 ° C to 500 ° C.
In this application, by incorporating a part of this technique into the technique of Patent Document 1 above, the carbon dioxide exhausted by the technique of Patent Document 1 is also used as the fuel of the internal combustion engine, thereby improving the fuel consumption. Greenhouse gas (CO ₂ ) emissions from the institution are approaching “zero”, and the technology has become a greenhouse gas reduction measure by carbon assimilation of plants.

A method of separating and recovering carbon dioxide from a by-product gas generated at a steel works by chemical absorption method, which absorbs carbon dioxide from the gas with chemical absorption liquid and then heats the chemical absorption liquid to separate carbon dioxide A method for separating and recovering carbon dioxide, characterized by utilizing or utilizing low-grade exhaust heat of 500 ° C. or less generated at a steelworks. (For example, Patent Document 3)
In order to separate and recover the carbon dioxide of the present application, there is a problem that it is necessary to install a membrane type permeation device that allows several kinds of permeable membranes to pass through the exhaust gas, or to install a vacuum pump or the like.

And in silencers vehicle carbon dioxide device in an exhaust system of an automobile is mounted between the exhaust pipe, provided with a C0 ₂ absorption portion which is connected via an absorbent material and the three-way of the solenoid valve carbon dioxide , A structure in which carbon dioxide is released from the aqueous solution of alkanone compound that has absorbed carbon dioxide by absorbing heat from the engine cooling heat through a solenoid valve, and the separated carbon dioxide is used to regenerate used alkanolamine compounds. (For example, Patent Document 4). This technology is used to regenerate the aqueous solution of alkanone compound that has absorbed carbon dioxide as an application of carbon dioxide separated by the technology that separates carbon dioxide in automobile exhaust gas. It can be used as a technique for separating carbon.
* In this application, carbon dioxide separated from the exhaust gas or carbon dioxide in the exhaust gas is absorbed into water and produced in the fuel (gas) by the internal combustion engine of the present application, and the internal combustion engine fuel (gas ) Is the decisive difference in terms of action and effect.

A method of reacting a hydrocarbon with water vapor or carbon dioxide or a mixture thereof under a net endothermic condition to form a gas containing a carbon compound and hydrogen, which is acidic or amphoteric with nickel and cobalt compounds and alkali metal oxides. There is a technique (for example, Patent Document 5) relating to the above method characterized by using a catalyst comprising a water-insoluble compound with an oxide or mixed oxide.
In this application, by incorporating a part of this technique into the technique of Patent Document 1 above, the carbon dioxide exhausted by the technique of Patent Document 1 is also used as the fuel of the internal combustion engine, thereby improving the fuel consumption. Greenhouse gas (CO ₂ ) emissions from the institution are approaching “zero”, and the technology has become a greenhouse gas reduction measure by carbon assimilation of plants.

A fuel injection device for a hydrogen rotary piston engine, which is attached to a rotor housing that forms a working chamber of the hydrogen rotary piston engine and directly injects hydrogen into the working chamber of the hydrogen rotary piston engine, and the hydrogen injector is operated Hydrogen injection timing control means for controlling injection timing so that hydrogen is injected into the chamber at a predetermined timing during the compression stroke, and hydrogen from the hydrogen injector is in the low rotation range of the hydrogen rotary piston engine. And a hydrogen outflow direction setting means for setting the hydrogen injection direction so as to flow out toward the leading region and out toward the central region of the working chamber in the compression stroke in the high rotation region. (For example, Patent Document 6).
* The hydrogen gas and carbon monoxide in the synthesis gas of the present application are almost equivalent in terms of energy, that is, the (higher) calorific value is almost the same. Has taken up the prior literature describing the structure of a rotary piston engine that uses hydrogen as fuel because it is optimal.

A method for producing a synthesis gas by reacting a carbon-containing organic compound with steam and / or carbon dioxide in the presence of a catalyst, wherein the catalyst is composed of a metal oxide as a support, comprising rhodium, ruthenium, iridium, palladium, and platinum. There exists a technique (for example, patent document 7) regarding what uses the catalyst which carry | supported at least 1 type of catalyst metal chosen from these.

Combining the technology of the present application with the partial technology of any one of the above-mentioned prior art documents 1, 2, 3, 4 and 7 also reforms the “CO ₂ ” in the exhaust gas into the synthesis gas of the internal combustion engine of the present application to produce fuel consumption ( Km / L), “It became a new technology that produces a new effect of reducing global warming by reducing CO ₂ emissions.

The biggest challenge is the reduction of “CO ₂ ” (emissions) to cope with global warming.
Inventing one method of measures for that purpose and the mechanism constituting the method.

To solve the biggest problem,
The first invention is
Water (H ₂ O) and carbon (C) react with the exhaust heat of the internal combustion engine to extract a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) (for example, in an endothermic reaction channel) An endothermic reaction facility for steam reforming) and a livestock gas tank for stocking the mixed gas of hydrogen and carbon monoxide taken out, and the mixed gas of hydrogen and carbon monoxide taken out via the livestock gas tank The internal combustion engine is used as fuel, and the exhaust heat of the internal combustion engine absorbs heat mainly in a water passage (corresponding to a cooling coolant passage for engine block cooling water) in the engine block of the internal combustion engine, thereby converting the water into water vapor. The exhaust heat used for the exhaust gas and the exhaust heat obtained by endothermically reacting the heat in the exhaust gas through the exhaust gas pipe, and the exhaust heat generated by the endothermic reaction of the exhaust heat in the engine block and the heat in the exhaust gas through the exhaust gas pipe Mainly exhaust heat from two places of heat An internal combustion engine that contributes to greenhouse gas reduction and emission reduction is provided.
Furthermore, further heat can be used for the endothermic reaction by providing a means for absorbing the refrigerant compression heat from the aircon pipe.
The second invention is provided with either one or both of an absorption means for absorbing carbon dioxide (CO ₂ ) in combustion exhaust gas of the internal combustion engine described in the first invention by water and a separation means for separating the carbon dioxide. A livestock gas tank for stocking the carbon dioxide produced and a livestock water tank for stocking the carbon dioxide-containing water absorbed in the water are provided for the livestock gas and the livestock water. Either water is introduced into an introduction line for supplying water to the engine block or carbon dioxide-containing water absorbed in the water is introduced into the water introduction line. In the heat of combustion, water is converted into water vapor and carbon dioxide is converted into carbon dioxide as an endothermic gas. (Renamed) reformed flow Catalysts (for example, other metals or compounds can be used in addition to iron-based metals and / or compounds. Examples of other metals or compounds include zinc, nickel, chromium manganese, tin, cerium, and lanthanum. And these compounds, other metals or compounds), a hydrocarbon compound (for example, dimethyl ether) is introduced upstream of the reforming path, and the steam and the endothermic carbon dioxide that absorbs the heat of the exhaust gas. By contacting the catalyst in the reforming path, a synthesis gas of hydrogen and carbon monoxide is generated (reforming temperature is 200 ° C. to 500 ° C.), and another livestock gas tank is provided for livestock synthesis gas. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by having a structure that uses the livestock gas tank as fuel for the engine.

The third invention is a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) taken out by any one or both of the take-out equipment and the reforming path according to the first to second inventions ( A synthesis gas reforming path (for example, a proton conductive ceramic pipe reforming path) for reforming the synthesis gas) is provided in the exhaust gas flow path, and hydrogen (H ₂ ) and carbon monoxide (CO) are provided in the synthesis gas reforming path. In the synthesis gas reforming path, hydrogen (H ₂ ) and carbon dioxide (CO ₂ ) are separately taken out, and the extracted hydrogen (H ₂ ) and dioxide are removed. Carbon is provided with a livestock gas tank, and livestock gas is used, hydrogen is used as fuel for the internal combustion engine, and the carbon dioxide is used as carbon dioxide as a starting material to be reformed in the reforming path. Providing internal combustion engines that contribute to reducing greenhouse gases and emissions The

The fourth invention is a hydrogen (H ₂ ) and carbon monoxide (CO) take-out facility (for example, an endothermic reaction facility provided in an endothermic reaction channel) or reforming according to the first to third inventions. At least one of a flow path (reforming path for catalytic contact between hydrocarbon compound, water vapor, and endothermic carbon dioxide) or a synthetic gas reforming path (for example, proton conductive ceramic pipe reforming path) is provided. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that the internal combustion engine is mounted on a transportation device and used as an onboard engine of the transportation device.

A fifth invention is the internal combustion engine according to any one of the first to fourth inventions, wherein the internal combustion engine is operated under a certain condition, is generated with the rotational force, is stored in a capacitor, and the electricity is powered. Provided is an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that it has a structure in which an automobile is driven as a source.

The sixth aspect of the invention stops driving the internal combustion engine when the amount of electricity stored in the capacitor according to the fifth aspect of the invention reaches the upper limit set value and runs with electric power, and drives with the internal combustion engine when the amount of charge reaches the lower limit set value. Provided is an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by its structure.

The seventh invention is characterized in that a charging power receiving plug is provided in the internal combustion engine described in the fifth invention, and as a charging means for accumulating electricity in the livestock generator, the electric vehicle is used as a power source to drive the vehicle. To provide an internal combustion engine that contributes to greenhouse gas reduction and emission reduction.

The eighth invention is a means for using the rotational force of the internal combustion engine as described in the first to fourth inventions as it is as the power generation power of the power generator, or reforming the steam that has finished the role of turning the turbine of the thermal power generation. As a heat source, hydrogen (H ₂ ) and carbon monoxide (CO) extraction equipment (for example, endothermic reaction equipment provided in the endothermic reaction flow path) or reforming flow path (hydrocarbon compound, water vapor, and endothermic gas dioxide) Providing fuel (gas) for the internal combustion engine by providing at least one of a reforming path for catalytic contact with carbon and a synthesis gas reforming path (for example, a proton conductive ceramic pipe reforming path) Providing an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that it is provided as a means to merge with existing thermal power generation equipment To do.

In the ninth invention, in the manufacturing industry where heat or steam is discarded, either one or both of the discarded heat and steam is used as a heat source for reforming, and hydrogen (H ₂ ). Carbon oxide (CO) extraction equipment (for example, an endothermic reaction equipment provided in an endothermic reaction flow path) or a reforming flow path (a reforming path in which a hydrocarbon compound, water vapor, and carbon dioxide of an endothermic gas are in catalytic contact) Or a synthesis gas reforming path (for example, a proton conductive ceramic pipe reforming path), and providing a fuel (gas) for the internal combustion engine as a fuel for the internal combustion engine by providing at least one of them An internal combustion engine that contributes to greenhouse gas reduction and emission reduction according to any one of the first to third inventions, characterized in that the internal combustion engine is operated and the rotational force is directly used as power generation power of the power generator. I will provide a.

According to a tenth aspect of the present invention, the livestock gas means according to the first to fourth aspects of the present invention is the livestock gas tank {synthetic gas tank for endothermic reaction, hydrogen gas tank, carbon dioxide gas tank, reforming channel (hydrocarbon At least one of the synthesis gas tanks taken out from the reforming path that brings the compound, water vapor, and endothermic carbon dioxide into catalytic contact) is mounted on the top of the vehicle body or mounted on the chassis of the vehicle. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by being mounted on either of these.

The eleventh aspect of the invention is that the livestock gas means described in the tenth aspect of the invention is either a damage prevention means that prevents damage to the tank or a tank separation means that separates the tank from the vehicle installation part in the event of a collision. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by providing either means.

The twelfth invention is one of or both of a carbon-containing compound and a hydrogen-containing compound (for example, sodium hydrogen carbonate, NaHCO ₃ ) using the exhaust heat of the internal combustion engine according to the first to fourth inventions as a reforming heat source. Any one of hydrogen H ₂ , carbon C, or carbon dioxide CO ₂ is processed and pyrolyzed or reformed, and the livestock gas tank is fed with livestock gas, and the gas Whether the extracted compound (for example, sodium carbonate, Na ₂ CO ₃ ) is sold as a product, and the extracted gas is used as a fuel for the internal combustion engine or as a starting material to be reformed as a fuel An internal combustion engine that contributes to greenhouse gas reduction and emission reduction characterized by any of the above.

The thirteenth invention is characterized in that the main fuel of the internal combustion engine according to any one of the first to fourth inventions can be hydrogen (H ₂ ), and the internal combustion that contributes to greenhouse gas reduction and emission reduction Provide institutions.

According to a fourteenth aspect of the present invention, there is provided a water storage tank comprising water absorption means for absorbing heat into water from the fuel of the internal combustion engine according to the first to third aspects and the exhaust gas obtained by burning the fuel according to the thirteenth aspect of the invention. The greenhouse effect is characterized in that the water in the water storage tank is warmed by the water endothermic means, and the water vapor in the endothermic exhaust gas becomes liquid water and is separated and recovered by the water recovery means. An internal combustion engine that contributes to gas reduction and emission reduction is provided.

A fifteenth aspect of the invention is a small-scale carbon production apparatus for producing the carbon of the plant described in the first to fourth aspects of the invention, wherein the wood, etc. (plant raw material) is heated and carbonized in an oxygen-free environment. Carbonization chamber CS to be fired, combustion chamber FC for burning plant raw materials such as wood for heating the carbonization chamber, exhaust gas vent of combustion chamber FC, and pipe J of water vapor generating means for converting water H ₂ O into water vapor J Is provided along the inner wall of the carbonization chamber, and is configured to be a fuel that heats the carbonization chamber by introducing the steam generated by the steam generation means and the gas C4 generated in the carbonization process in the carbonization chamber into the combustion chamber. Provide scale carbon production equipment.

Detailed Description of the Invention

Specific examples of the invention Description of the first invention,
Although it is a take-out facility that takes out a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) by reacting water, (H ₂ O), and carbon (C) with exhaust heat of the internal combustion engine, for example, an internal combustion engine A water passage K is provided in the engine block 1, and either water H ₂ O is converted into steam J or steam is converted into heated steam as steam generating means,
An endothermic reaction channel S is provided in the exhaust pipe MS after the combustion stroke of the internal combustion engine, carbon (mainly carbon C from plants) is introduced into the endothermic reaction channel, and the steam or heated steam , Carbon is reacted in an endothermic reaction channel, hydrogen H ₂ and carbon monoxide CO (synthetic gas) are taken out, and a livestock gas tank MT for stocking the mixed gas of the taken out hydrogen and carbon monoxide is provided. The extracted hydrogen and carbon monoxide mixed gas is used as livestock gas or as the fuel for the internal combustion engine that generates the mixed gas via the livestock gas tank. And
The exhaust heat of the internal combustion engine is obtained by absorbing heat in a water passage (corresponding to a cooling coolant passage for engine block cooling water) in the engine block of the internal combustion engine and exhaust heat used for converting water into steam. Exhaust heat obtained by endothermic reaction of heat in exhaust gas, and exhaust heat mainly from two places of exhaust heat in the engine block and exhaust heat obtained by endothermic reaction of exhaust gas heat in the exhaust gas pipe line What should be emphasized is that the heat that was cooled by the radiator (discarded using power) to prevent engine overheat is utilized as a means for generating steam.
Furthermore, further heat can be used for the endothermic reaction by providing a means for absorbing the refrigerant compression heat from the aircon pipe.

This is a take-out facility that takes out a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) by reacting water, (H ₂ O), and carbon (C) with exhaust heat of the internal combustion engine. A water passage K is provided in the engine block 1 of the engine, and either water H ₂ O and carbon are injected under pressure to form water vapor J or water vapor to be heated water vapor as a water vapor generating means. {The pressurizing pressure at this time is about 5 kg / cm ² . (See FIG. 3B)}
Although the present application has a configuration exemplifying steam reforming, the known synthesis gas generation method includes the steam reforming method, and a catalyst (Ni is the mainstream) facing the endothermic reaction channel, which is approximately 200 ° to 300 °. There are also fuel generation means for performing the endothermic reaction with the heat of, a dry reforming method, a partial oxidation method, and an autothermal reforming method. Instead of the steam reforming method of the present application, the above syngas generating method may be adopted. I can do it.

In view of the energy efficiency of internal combustion engines (about 30% for rotary engines and about 60% of waste (waste) heat available for syngas reaction), it is not enough to produce 100% of the required amount of fuel. In this case, supplementary means for supplementing from other places are provided as supplementary, and as the supplementary means, the present application is provided with an auxiliary tank ST, and fuel in the auxiliary tank (bioethanol or synthesis gas mainly made from plant carbon) ) As supplementary fuel when it is not enough to produce 100% of the required amount of fuel.
Ultimately, the carbon is used as a measure to reduce greenhouse gas emissions by bringing the carbon closer to 100% use from the waste.

As an example, the present application adopts a composite fuel system in which a sub-tank fuel and a mixed gas generated in the internal combustion engine are switched and used.
However, if hydrogen H ₂ and carbon monoxide CO (synthetic gas), which are the main fuels, are produced while using the sub-tank fuel, there is no place where the produced gas is livestock gas and livestock gas that is livestock gas. It is necessary to provide means, and the present application is provided with a livestock gas tank for livestock gas means, and hydrogen H ₂ and carbon monoxide CO (synthetic gas) as main fuels continue to be generated even when sub tank fuel is used. We continue to fill the animal gas tank,
Accordingly, when the livestock gas tank is filled up to the set upper limit, the fuel switching valve switches the synthesis gas to use via the livestock gas tank, and when it reaches the set lower limit of the livestock gas tank, the engine structure is provided with fuel switching means that uses the subtank fuel. ,
The reason why the mixed gas generated by the internal combustion engine is used via the livestock gas tank is that the mixed gas also changes the composition of the gas component generated depending on the raw materials and the temperature of the production site. Uniformity is intended.

Second invention The carbon dioxide absorption means (A) for absorbing carbon dioxide in the combustion gas of the internal combustion engine by water or the separation means (B) for separating carbon dioxide in the exhaust gas are provided, A) and (B) are respectively provided with livestock water means and the livestock gas means to feed livestock water and livestock gas, respectively, and either one or both of (A) and (B) above It is introduced together with water into an inlet for supplying water to the engine block (FIG. 1B, H ₂ O inlet) and combustion heat in the internal combustion engine {the combustion heat of the internal combustion engine is a water passage (in the engine block of the internal combustion engine ( It corresponds to the cooling water channel of the engine block cooling water), and water is converted into water vapor.} The water is converted into water vapor, the carbon dioxide is converted into carbon dioxide as an endothermic gas, Reforming channel (carbon dioxide reforming In the reforming flow path of the reforming flow path of the steam reforming in order to distinguish from the steam reforming, as an example, other metals or compounds can be used in combination with iron-based metal and / or compound, Examples of other metals or compounds include zinc, nickel, chromium manganese, tin, cerium, lanthanum and their compounds, other metals or compounds, and a hydrocarbon compound (eg, dimethyl ether) upstream of the reforming path. CH ₃ OCH ₃ ) and the reforming channel of the reforming channel (name changed because of reforming of carbon dioxide) provided in the internal combustion engine together with the water vapor and endothermic carbon dioxide The catalyst is opposed to the gas {hydrocarbon compound (eg dimethyl ether CH ₃ OCH ₃ ) and either water vapor or endothermic carbon dioxide]. It is a structure that generates hydrogen and carbon monoxide syngas by contacting them, and uses it as a fuel for the engine via a livestock gas tank. The detailed explanation of (A) is omitted. }

The reaction formula when the hydrocarbon compound is dimethyl ether is
A. _{CH 3 OCH 3 + H 2 O} → 2CO + 4H 2 -48.9Kal / mol
B. CH ₃ OCH ₃ ++ CO ₂ → 3CO + 3H ₂ −58 · 8 Kal / mol
The reaction temperature is 200 to 500 ° C., preferably 250 to 450 ° C.
The reaction pressure is preferably atmospheric pressure to 10 kg / cm ² .
Many technologies using methane in addition to dimethyl ether as a hydrocarbon compound have been disclosed.

The carbon dioxide absorption means (A) and carbon dioxide separation and extraction means (B) for absorbing carbon dioxide by a known technique,
(A) is disclosed in JP 2010-526759, JP 33455782, JP 2009-77457, JP 2001-213545, JP 2007-177684, and the like.
(B) is disclosed in Japanese Patent Application No. 2001-48591 (Karman vortex), Japanese Patent Application Laid-Open No. 2007-177684, etc.
Prior art of the method for producing hydrogen and carbon monoxide by the carbon dioxide reforming reaction includes Japanese Patent Application Laid-Open No. 08-231204 and Japanese Patent Application Laid-Open No. Hei 11 of Japanese Patent Application Laid-Open No. H11-296275. -106770 etc.
Incorporating this technology into this application, the carbon dioxide in the exhaust gas is “a reforming of the internal combustion engine fuel only into the fuel of the internal combustion engine of this application” is a great greenhouse gas emission reduction measure, A feature of the present invention is that fuel is generated with the discarded energy (approximately 70%, and approximately 60% can be used for reforming), and fuel efficiency is improved by the amount of fuel generation.

Among the inventions of the present application, the carbon C of the synthesis gas generating material when the reforming means for reforming carbon dioxide is used may be carbon C using fossil fuel, and the carbon dioxide is reformed into synthesis gas. Therefore, it is possible to reduce CO ₂ emissions of at least several tens of percent, and this is a measure for reducing greenhouse gas emissions.

3rd invention The synthesis gas reforming path described in the 3rd invention includes a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) produced in the first to second inventions, and an internal combustion engine. The exhaust heat of the internal combustion engine {the exhaust heat of the internal combustion engine is exhaust heat obtained by converting water into steam in a water passage (corresponding to a cooling coolant channel for engine block cooling water) in the engine block of the internal combustion engine}. For example, the exhaust heat of the internal combustion engine (300 ° C. to 800 ° C.) again in the proton conductive ceramic tube (the exhaust heat of the internal combustion engine is exhaust heat obtained by absorbing the heat in the exhaust gas in the exhaust gas pipe) ), Hydrogen (H ₂ ) and carbon dioxide (CO ₂ ) are taken out separately, and a hydrogen livestock gas tank and a carbon dioxide livestock gas tank for stocking the hydrogen and carbon dioxide separately are provided. Carbon dioxide is the water As a starting material for extracting the raw material, the extracted hydrogen is used as a fuel for the internal combustion engine via a hydrogen livestock gas tank.

When exhaust gas temperature in the exhaust pipe is insufficient, an exhaust gas combustion section is provided upstream of the synthesis gas reforming path,
You may introduce and reheat the fuel and oxygen (air) which are the livestock gas of the extent which supplements the shortage temperature to the unburned fuel gas or unburned carbon particle in exhaust gas.

The carbon dioxide reforming is a technique in which a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) is taken out by contacting with a catalyst together with a reforming agent of carbon dioxide and steam (Patent Prior Art 2 Japanese Patent Application No. Hei 11- 106770) is incorporated into the present application, and carbon dioxide is also used as a fuel for the internal combustion engine, thereby improving fuel efficiency and further reducing greenhouse gas emissions.

The present application introduces carbon dioxide and water into an inlet (H ₂ O inlet in FIG. 1B) for introducing water into the engine block (rotary housing) of the engine for the carbon dioxide reforming. Heat is absorbed in a water passage K provided between the inner and outer walls of the engine block (rotary housing), water is absorbed into water vapor, and carbon dioxide is absorbed to raise the gas to a high temperature and mixed, and a catalyst is placed downstream of the engine exhaust port. There is an opposite reforming path (the name is changed because it is carbon dioxide reforming), and a hydrocarbon compound (for example, dimethyl ether CH ₃ OCH ₃ ) is introduced upstream of the reforming path and the steam and The gas {hydrocarbon compound (eg, dimethyl ether CH ₃ OCH ₃ ) and water vapor or endothermic carbon dioxide, or both} is added to the catalyst together with endothermic carbon dioxide} To remove the mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO), or add the water to steam in the water passage K of the engine block (rotary housing) of the engine. A water passage K ′ of the engine block (rotary housing) of the engine is further provided to be a two-line pipe line for heating carbon dioxide, and (exhaust gas after engine combustion process) It is configured to take out a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO), either by contacting with the catalyst that is confronting the exhaust pipe (including joining near the mouth). For example, the catalyst can be used in combination with other metals or compounds in addition to iron-based metals and / or compounds. Examples of other metals or compounds include zinc, nickel, and the like. Kell, chromium manganese, Suzuseryuumu, lanthanum and compounds thereof, there is another metal or compound.

The reforming temperature of the steam reforming described in the first invention is 700 ° C. to 1000 ° C., preferably 800 to 900 ° C., and the reforming temperature of the hydrocarbon compound (eg dimethyl ether CH ₃ OCH ₃ ) is 200 to 200 ° C. Since the temperature is 500 ° C., preferably 250 to 450 ° C., a steam reforming section is provided upstream of the exhaust pipe, and a reforming section of a hydrocarbon compound (for example, dimethyl ether CH ₃ OCH ₃ ) is provided downstream of the steam reforming section. A synthesis gas reforming path (reforming temperature is 300 ° C. to 800 ° C., the third invention) is provided downstream of the quality, or the synthesis gas reforming path is provided downstream of the steam reforming and further carbonized downstream. It is preferable to take any form of providing a reforming portion of a hydrogen compound (for example, dimethyl ether CH ₃ OCH ₃ ).

In the hydrogen (H ₂ ) and carbon monoxide (CO) extraction equipment, the reforming channel, and the syngas reforming channel, if it is desired to take a longer reaction time, or steam reforming or CO 2 is performed simultaneously. When it is desired to take at least one of reforming and syngas reforming, the water passage K provided between the inner and outer walls of the engine block (or rotary housing) of the engine is passed through the engine block 1 a plurality of times. Use a structure that allows the engine to circulate, or provide multiple exhaust lines from the engine block (for example, the same number of cylinders, half the number of cylinders, or the same number of lines as the number of rotors) Alternatively, it may be structured such that one or a plurality of exhaust pipe lines coming out from the engine block are further branched into a plurality of parts and sequentially switched to send the exhaust. A water channel K ′ is further provided, and at least one of the two systems of pipes for heating carbon dioxide is used, and at least one of the two lines is connected to the pipe downstream of the exhaust port after the engine combustion process. A configuration in which at least one of the reforming paths is provided and a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) or hydrogen gas / carbon dioxide may be taken out.

Proton conductive ceramics have heat resistance according to the combustion temperature and are provided with continuous vents through which combustion gas can pass. Proton conductive ceramics such as strontium serate-based and zirconate-based belogskite oxide ceramics are hydrogen conductive ceramics. This is particularly advantageous in that it has an action of activating oxygen.

The use of carbon dioxide or carbon as a raw material as a renewable energy source in equipment industries such as the manufacturing industry is a known technique.

Fourth invention An internal combustion engine provided with one or more of hydrogen (H ₂ ) and carbon monoxide (CO) extraction equipment, reforming flow path, and synthesis gas reforming path as a transportation device It is in the form of an on-board engine for transportation equipment, which includes motorcycles, munitions weapons vehicles, munitions weapons ships, and the like.

Fifth invention,
The existing hydrogen rotary piston engine car is used for the internal combustion engine described above. “The engine is operated under good fuel economy conditions (constant conditions) and is generated by the rotational force and stored in the capacitor. The electricity is used as the power source. By applying the configuration of `` A car is driven as '' to the internal combustion engine, stable combustion heat can be obtained, and the endothermic reaction conditions are also stabilized. Therefore, the present application operates the engine under conditions with good fuel consumption. The structure that generates electricity with the rotational force and stores it in a capacitor and uses the electricity as a power source produces a great effect of further improving fuel consumption and reducing greenhouse gas emissions.

* Driving conditions (for example, waiting for traffic lights, waiting for an oncoming vehicle on the right, waiting for crossing pedestrians when turning right or left at the intersection, choco-choco driving in a traffic condition, driving on a flat road, overtaking & overtaking rapid acceleration・ The control mechanism and control structure of the output of the internal combustion engine are simplified and improved by following the changes in the downhill driving, etc.
Furthermore, since driving is performed under a certain condition (good fuel efficiency), there is an effect of improving the fuel efficiency (Km / L).

According to the sixth aspect of the invention, when the storage amount of the capacitor is equal to or greater than the set value, the driving of the internal combustion engine is stopped and the vehicle is driven with electric power.
When the driving state that does not require power continues, the engine is continuously operated under certain conditions (good fuel economy conditions), so depending on the driving state, the electricity generated to drive the car becomes overcharged and is generated by the internal combustion engine. Since the electricity is discarded, the engine can be turned off and the vehicle can run with the stored electric power to improve the fuel consumption.

7th invention The internal combustion engine is provided with a charging / receiving plug and is used as a charging means for storing electricity in a livestock battery. It is expensive to cover all necessary power with a battery by using a structure that allows the vehicle to run using the electricity as a power source. It is not necessary to install a large number of batteries, and the power storage capacity of the internal combustion engine can be increased by several tens of percent. It will be a measure.

Driving conditions that do not require power (waiting for traffic lights, waiting for oncoming vehicles when turning right, waiting for crossing pedestrians when turning left or right, choco chocolate driving during traffic jams, downhill driving, coasting driving, etc.) During this period, the engine is continuously operated under certain conditions (good fuel efficiency). Depending on the driving condition, the electricity generated for driving the car becomes overcharged and the electricity generated by the internal combustion engine is discarded. Therefore, when the storage capacity of the livestock electricity reaches the upper limit set value, the engine is turned off and the vehicle runs with the stored power. When the storage capacity of the battery reaches the lower limit set value, the engine is turned on and the vehicle runs with the engine. The fuel consumption can be improved.

If the electric power is used as the driving power when running in the engine braking state during downhill driving, the motor can be used as a generator.Therefore, when running in the engine braking state, the motor is used as a generator to charge the battery. This will further improve fuel efficiency and reduce greenhouse gas emissions.

This is a repulsive driving run on the flat road, but a repulsive driving run is a speed at which a driver wants to drive for several minutes with an accelerator operation (approximately 2200 revolutions) that is about 10% higher than the speed at which the driver wants to drive. If it is 60Km / H, turning to 70Km / H will turn off the rotational drive power of the engine (this will be about 1000 revolutions, the number of revolutions when idling). Is a driving method that repeats the operation of turning on the rotational driving force connection of the engine when the speed reaches 60 km / H, which is a common driving method in the transportation industry 50 years ago. Automatic control of this travel mode can further improve fuel consumption and reduce greenhouse gas emissions.

Eighth Invention The internal combustion engine endowed by the internal combustion engine is the means for directly using the rotational force of the internal combustion engine as the power generation power of the power generator, or the steam that has finished the role of turning the turbine of the thermal power generation and the newly added mainly plant carbon. Either end up in the reaction channel and endothermically react, and the generated fuel (gas) can be used as a substitute for auxiliary fuel, which can be combined with existing thermal power generation equipment. Or an endothermic reaction facility is provided in the exhaust gas pipeline of the boiler of the thermal power generation facility to effect endothermic reaction, and the generated fuel (gas) is used as the fuel for the motive power generation via the livestock gas tank. May be.

A mixed gas of hydrogen and carbon monoxide can also be handled by using a liquefied product produced by other facilities (or transported in a compressed gas state by piping). A facility for producing a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) can also be installed in the vicinity.

Ninth Invention In a manufacturing industry (for example, steelmaking, iron forging, iron casting, aluminum refining & manufacturing, etc.) that discards heat or steam, either the heat or steam that is discarded or both Either of the above, mainly plant carbon to be newly introduced is introduced into the endothermic reaction flow path of the internal combustion engine to cause endothermic reaction, and the generated fuel (gas) is used as fuel for the internal combustion engine to operate the internal combustion engine. Furthermore, “CO 2” in the exhaust gas of the internal combustion engine is generated as a synthesis gas of hydrogen and carbon monoxide by the means described in the second invention, and is operated as a fuel for the internal combustion engine, and its rotational force is used as it is. This is an internal combustion engine that uses the power generated by the power generator.
For example, in the rolling process of a steel mill, the decarburized crimson steel plate is passed through a number of rolling mills to form a steel plate roll of about 10 mm. The plate is cooled, and the large amount of water applied at this time becomes steam, and a part of it is discarded, and the final rolled steel sheet roll is used for the ceiling crane to hang down in the steel sheet roll natural cooling place. They are lined up in order on a plurality of rows of roller conveyors that have been installed with the required clamping tool operating width. The temperature of the steel sheet roll at this time is 700 ° to 900 °, and the power generation of the motive power generator is performed using the fuel (gas) generated by providing the endothermic reaction section between the roller conveyors to effect the endothermic reaction as the fuel of the internal combustion engine. Using power as a means of reducing electric power will reduce greenhouse gas emissions.

Tenth Invention & Eleventh Invention The livestock gas tank {the tank does not require a high-pressure hydrogen gas storage tank of 35 MPa, and is a fuel necessary for operating at least about 10 minutes with the gas generated by the internal combustion engine. It is a damage prevention means to prevent the tank damage of the internal combustion engine (if the switching loss can be ignored) if it is a tank that can store livestock gas. A shock absorbing material HPE such as foamed polyethylene and boron fiber reinforced plastic is fixed to the vehicle body and fixed and held on the upper part of the vehicle, and the fixing device MT5 fixed and fixed to the upper part of the vehicle with the fixed holding device MT1. In the tank separating means, when an impact is applied to the fixture MT5, the V-shaped cutout portion MT6 breaks due to concentrated stress, and the shock absorbing material inclusion body MT3 (t It is possible to adopt a structure in which the support member MT2 is integrated with the fixing member MT5 but is not completely disengaged and is locked to the fixing device MT5 by a linear body or the like. MT3 is a preferred form because it is a measure to avoid secondary damage that completely flies off)
One or both of the damage prevention means for preventing damage to the tank or the tank separation means for separating the tank from the tank installation portion of the vehicle in the event of a collision are provided. Further, it is composed of a non-stationary facility (for example, an automobile) livestock gas tank of the livestock gas means, and the livestock gas tank is mounted on the upper body of a car or mounted on a chassis part of a truck. It is preferable to use one of the forms attached to the stationary equipment, but in the case of stationary equipment (for example, a power plant), the safety standard (in Japan, the registration of JIS B 8265 has been completed. Is ISO 16528), and the non-stationary livestock gas tank and the stationary livestock gas tank (eg chemical factory) It must be composed of those that are within the safety standards or at least have elements that can change the safety standards, so non-stationary equipment (eg automobile) livestock gas tanks and stationary equipment (eg chemical factories) livestock gas tanks Even if the function of storing gas is the same, the structure (standard) is completely different.

A twelfth invention for example to make a bicarbonate Natoryuumu (NaHCO ₃₎ and by processing and thermally decomposed in the exhaust heat of an internal combustion engine hydrogen _{(H 2)} and carbon dioxide Natoryuumu _(Na 2 CO _3), carbonate Natoryuumu _(Na 2 CO ₃ ) is taken out and sold as a product, and hydrogen (H ₂ ) is used as a fuel for the internal combustion engine via the livestock gas tank. The sodium hydrogen carbonate (NaHCO ₃ ) is an example as long as it is a product that adds value by use, and is not limited to sodium hydrogen carbonate (NaHCO ₃ ).

The thirteenth invention and the fourteenth invention are configured such that the main fuel of the internal combustion engine described in the fourth invention is hydrogen (H ₂ ),
If hydrogen is the main fuel (of the thirteenth invention), it is an exhaust mainly composed of water and nitrogen (the first invention to the second invention) and the fuel burns hydrogen and carbon monoxide. It is an exhaust mainly composed of water, carbon dioxide and nitrogen, and is an exhaust mainly composed of water, carbon dioxide and nitrogen when hydrogen and carbon monoxide are reformed from carbon dioxide in the exhaust.
Regardless of which fuel is used, the water is discharged in the form of water vapor, and the structure is such that the water of the reforming starting material is warmed from this water vapor by further heat absorption means, and the water is removed from the water vapor in the exhaust gas and filtered. It is returned to the storage tank as water for reforming starting material via filtration means,
The heat absorption means from the water vapor is provided, for example, by providing a water storage tank downstream of the exhaust pipe and passing the exhaust pipe through the water in the storage tank so that the water in the water tank absorbs heat and the water in the water tank is heated. Recovery means for recovering water, characterized in that water vapor in the exhaust pipe becomes water and recovers
The above-mentioned various reforming means reform water into fuel, so a considerable amount of water is required. However, if the on-board amount of water is increased, energy for transporting the on-board amount of water (weight) is required. Therefore, if water is collected and recycled, the amount of on-vehicle water can be reduced, and the water in the water tank can be warm water. This contributes to greenhouse gas reduction and emission reduction.

A fifteenth aspect of the invention is a small-scale carbon production apparatus for producing the carbon of the plant described in the first to fourth aspects of the invention, wherein the wood, etc. (plant raw material) is heated and carbonized in an oxygen-free environment. Carbonization chamber CS to be fired, combustion chamber FC for burning plant raw materials such as wood for heating the carbonization chamber, exhaust gas vent of combustion chamber FC, and pipe J of water vapor generating means for converting water H ₂ O into water vapor J Is provided along the inner wall of the carbonization chamber, and is configured to be a fuel that heats the carbonization chamber by introducing the steam generated by the steam generation means and the gas C4 generated in the carbonization process in the carbonization chamber into the combustion chamber. Provide scale carbon production equipment.

In the combination of the present invention, the carbon C of the synthesis gas generating material when the reforming means for reforming carbon dioxide is used may be fossil fuel use (for example, coal), which is a greenhouse gas emission reduction measure. is there.

The biggest challenge is the reduction of CO ₂ emissions to combat global warming.
By using mainly plant carbon C as a fuel, it was possible to make an internal combustion engine for a greenhouse gas reduction measure that constitutes one of the challenges of the greenhouse gas reduction measure that is the subject of the present application. In addition, CO ₂ generated by the combustion of plant carbon C is also reformed to fuel, and reforming this CO ₂ to fuel also has the effect of further increasing greenhouse gas reduction and fuel efficiency. This is the biggest effect.

The use of an internal combustion engine that generates this synthesis gas and uses the generated synthesis gas as a fuel as an alternative to a thermal power generator is a project that can be mentioned as the first solution to the current energy problem solution (2011) (2011). According to the statistics of the Federation of Electric Power Companies of the year, about 82% of Japan's total power generation is thermal power generation, and there is a request for power saving at the peak of midsummer power demand from each power company) Doing so has a great effect on power supply.

The great effect is that fuel is generated by utilizing the thermal energy that was discarded by the internal combustion engine.

The present application is an alternative to the auxiliary fuel supplied to the internal combustion engine for power generation using the rotational force of the internal combustion engine as it is as a power generation facility, and the endothermic reaction flow of heat, steam or hot water discarded in the manufacturing process, and newly input carbon. Auxiliary fuel, either petroleum liquefied gas (including natural gas), gasoline (including hydrocarbon-based fossil fuel), bioethanol, or synthetic gas, that was introduced into the road and supplied to the internal combustion engine A structure that eliminates the need for a fuel switching control structure including a sub-tank, a sub fuel use control structure, and a switching valve that switches and uses the synthesis gas of the auxiliary fuel, because the livestock gas tank is replaced with the synthetic gas or hydrogen gas of the present application. Is also possible.

The CO ₂ produced by burning the carbon of the plant is also generated in the synthesis gas to further reduce the greenhouse gas CO ₂ from the carbon neutral of the Kyoto Protocol on the use of carbon of the plant. CO ₂ can be reduced, and a greenhouse gas reduction measure that could not be achieved with existing technologies has the greatest effect.
Furthermore, even if carbon of the internal combustion engine of the present application is used for fossil fuel, CO ₂ can be reduced by at least several tens of percent even if 100% emission cut cannot be achieved.

While the purchase of greenhouse gas CO ₂ allowances is revitalizing, Japan's purchase amount is estimated to be about 1 trillions of billions, but this purchase amount can be reduced by several tens of percent.

The endothermic reaction efficiency can be obtained by operating the engine under the constant endothermic reaction condition by operating the engine under the “constant and fuel-efficient conditions” (different conditions at start-up) that are not related to the engine load fluctuation described in the fifth invention. The improvement of fuel efficiency (Km / L) is achieved by making the fuel efficiency good and the fuel efficiency is good.

The raw materials for generating the fuel for the internal combustion engine are water H ₂ O and carbon C. The plant that can regenerate the carbon C is used as a main raw material, and further, it is made from materials close to industrial waste that are produced during the production of sewage and food. Substances (e.g. methane gas or bioethanol) are preferred as sub-fuels,

Using the plant as the main raw material means that the plant absorbs carbon dioxide CO ₂ and produces oxygen O ₂ , so in the Kyoto Protocol it is defined as plus or minus “0” (carbon neutral), and global warming This is a great effect that can greatly contribute to prevention.

By providing a cycle for generating carbon dioxide in the exhaust gas into the synthesis gas, the “CO ₂ ” discharged from the internal combustion engine of the first invention is reformed into fuel, and further “CO ₂ ” Emissions can be reduced and fuel efficiency can be improved. (For example, it was possible to obtain an astonishing effect of improving 20 Km / L to 40 Km / L or more, not about 20 Km / L to 25 Km / L.
* Reforming water H ₂ O and CO ₂ into fuel

A radiator including the engine block cooling water passage and the cooling water piping of the internal combustion engine is not necessary.

The raw materials for generating the fuel for the internal combustion engine are water H ₂ O and carbon C. The plant that can regenerate the carbon is the main raw material, and the plant is the main raw material. The plant absorbs carbon dioxide CO ₂ . Since oxygen O ₂ is released, it is set to plus and minus “0” in the Kyoto Protocol, which can greatly contribute to the prevention of global warming.

The use of the plant as the main raw material makes it possible to turn abandoned forests and “rice fields” into factories with good “operation rate” to produce valuable things (carbon from plants). This is vital for agriculture and forestry. give.

In thermal power generation, the boiler is heated with thermal power to generate steam, and the steam is further heated to generate electricity by rotating the turbine. Therefore, the energy efficiency is less than 50% and the thermal power boiler is necessary to start heating. Since the initial energy is large, it is difficult to turn on / off following the power consumption fluctuations according to the time zone because it is difficult to turn off the fire for a long time once it is turned on, so depending on the season (spring / autumn) or time zone Surplus power that is not consumed is generated, and the excess production is discarded. However, if the power generation system using the internal combustion engine of the present application is used, the operation may be turned ON / OFF following the fluctuation of the time power consumption. Since it can be made freely, excess production power can be brought to zero as much as possible, so there is no need for a large-capacity power storage facility and a vast amount of power transmission / reception facilities when supplemented only by solar power generation.

Current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of this application do not need to be adjacent to the water source and can be installed as close to the power demand area as possible, so there are very few transmission / reception facilities I can do it.

The proportion of the Japanese economy affected by fossil energy price fluctuations (and exchange rate fluctuations) will be reduced.

The internal combustion engine according to any one of the first to third aspects of the present invention is used for automobiles (including two-cycle two-wheeled vehicles and four-cycle two-wheeled vehicles), marine and railway diesel engine vehicles, construction machinery, munitions weapon vehicles, and munitions weapons. It is implemented in the form of being mounted on a transportation device such as a ship, and the form in which the power generator is used as an alternative to the thermal power generation facility, or steam that has finished the role of turning the turbine in the existing thermal power generation facility, is newly input In this embodiment, the carbon to be introduced is introduced into the endothermic reaction flow path of the internal combustion engine and used for the fuel shortage, and is combined with the existing thermal power generation facility.

Each dimensional relationship in the drawings is enlarged for important portions, exaggerated where details are difficult to understand, and reduced when describing wide portions or portions that are less important in the present invention. Thus, the dimensions between and within the drawings are not proportional, and are not actual or scaled.
If the distance between the lines is narrow, it is likely to become a single line that is black and thick at the scanning stage. Therefore, the distance between the lines is widened or described with a single line.

Furthermore, parts other than the basic (main) mechanism of the present invention are omitted between the drawings.

Hydrogen and carbon monoxide are almost energetically equivalent, that is, the (higher) calorific value is almost the same. Therefore, the detailed description in the specification of the present application refers to a known technique using hydrogen as a fuel. There are many. Furthermore, there are many parts that cite known techniques for the technique of reforming “CO ₂ ” into synthesis gas.
The main structure of this application refers to a variety of known technologies (including some that are patent-registered and alive), but cannot be obtained by individual known technologies alone. In order to obtain the effect in the present application, it was possible to obtain a surprising effect in terms of reducing greenhouse gas emissions and improving fuel consumption.

An endothermic reaction flow path is provided in the engine block of the internal combustion engine, and water H ₂ O and carbon C are reacted with the exhaust heat of the internal combustion engine to take out a mixed gas of hydrogen H ₂ and carbon monoxide CO. It is an internal combustion engine that uses a mixed gas of carbon monoxide and fuel, but any manufacturer thinks that synthetic gas can be used as an alternative fuel to gasoline, light oil, heavy oil, etc., but hydrogen also Carbon monoxide is also very dangerous (explosive and toxic). Therefore, liquefied transport means (portability). The ratio of the volume of the liquefied gas to the weight of the container that satisfies safety standards is poor. I suspect that there was an explosion problem caused by the wreck, and I couldn't get it.

The means of the present application to solve this problem are:
* Instead of filling the tank with fuel consumption and supplying all the fuel required for driving, a subtank is provided to replenish the energy loss during the fuel generation process, and the fuel in the subtank is used for petroleum liquefied gas (including natural gas) ) Adoption of a composite fuel supply structure that uses gasoline, hydrocarbon-containing fossil fuel bioethanol, etc., or synthetic gas as a supplementary sub-fuel for the energy loss (this stored gas pressure) The installation position of the livestock gas tank in consideration of the above and the means of the structural part that can cope with an accident such as a car being severely damaged) are the main points that made the present application "practical plan"). (See Figures 1 and 2)

The storage gas, the synthesis gas generated in the livestock gas tank is stored in a certain amount (in the state of compressed gas), while the certain amount is accumulated, butane gas, gasoline, (including hydrocarbon-based fossil fuel) methane gas, bioethanol, etc., or Any of hydrogen, synthesis gas, reformed gas from plants, methane gas from plants, bioethanol of bioethanol, etc. is used as the storage gas in the auxiliary fuel tank, and the amount of generated synthesis gas is constant. And switch to synthetic gas, use synthetic gas in livestock gas tank while generating synthetic gas, and switch to using auxiliary fuel tank when the tank capacity is close to "0". Means to reduce the amount (including tank weight),

An example of a known technique for converting carbon dioxide to hydrogen, carbon monoxide, etc. in the presence of a catalyst is described in Japanese Patent Application Laid-Open No. 11-106770. In the description, a method for producing a synthesis gas by reacting a carbon-containing organic compound with steam and / or carbon dioxide in the presence of a catalyst and a catalyst suitable for the method are also disclosed. Is also used as a technology for reforming fuel.
Japanese Patent Application Laid-Open No. 2007-177684, a carbon dioxide recovery device for a vehicle, and a vehicle equipped with the same discloses that carbon dioxide is absorbed by a carbon dioxide absorber and carbon dioxide is recovered.

The main sources of greenhouse gas emissions are emissions from internal combustion engines and thermal power generation boilers, which account for about 82% of Japan's power generation (2012 Electricity Federation statistics). And 1/4 of the world ’s emissions from thermal power boilers,
The amount of CO ₂ released when 1 gallon of gasoline is burned is about 9 Kg combined with emissions from the car engine and emissions from the gasoline production process.
Therefore, in order to shift the consumption of carbon C from fossil fuels to carbon C from plants and achieve a 25% reduction in greenhouse gas CO ₂ emissions early,
It is necessary to implement an internal combustion engine for the greenhouse gas emission reduction measures of the present application and to make the procurement cost of carbon C, which mainly consists of fuel, the same as the procurement cost from fossil fuel.
The production of carbon C as fuel changes when carbonized organic material is heated while shutting off the flow of air and oxygen, and changes to a material rich in black carbon. This process is called carbonization, and charcoal produces this carbonization. This is a good example of a product, and what is produced is an aggregate composed mainly of amorphous oxygen and the like, and is mostly porous and has a very large surface area. Heating causes dehydration and dehydrogenation reaction to produce a condensed polycyclic aromatic compound, which further forms a network structure, which is called carbonization.

The technology to make solid carbon C from wood (nano-plant raw material) into nanoparticles is not yet a new technology because it has already been broadcast on TV, etc., but micronization (100 (About a micron) can be dealt with as the carbon C of claim 1 of the present invention.
If the solid carbon C is pulverized into fine particles, the surface area where the reaction takes place is increased. Therefore, the finer the particles, the more efficient the synthesis gas generation.
It can also be handled by adding water to the carbon C to form an emulsion fuel or gel.
Furthermore, the above-mentioned wood and the like (plant raw material C) is heated in an environment where oxygen does not enter, and carbon C gas can be obtained in the carbonization step.

It is a cycle in which steam in the engine → endothermic reaction in the exhaust line → synthesis gas or hydrogen of carbon monoxide and hydrogen or hydrogen is used as fuel for the engine.
* The proposed matter is that the livestock gas tank has a large internal volume, low pressure accumulation, a tank that can be built, where the vehicle is located, and what structure is used. It was possible to make a structure that does not.
* The above-mentioned proposed matter was solved with the following structure.
1. The place where the synthesis gas tank is installed is located in the upper part of the car body or in the chassis part of the car, which is provided in the upper part of the car body even if the car falls from the cliff, Even in an accident that is sandwiched between and crushed, a livestock gas tank is required to have a structure that does not explode. With the pressure of 300L, the volume in the container is 300L,
Mazda (Company name) Premasi Hydrogen RE hybrid vehicle equipped with 74L / 35MP of hydrogen can run only 123Km with full tank filling, so it can not run only with hydrogen, so to run 500Km, about 4 times 300L A / 35 MPa hydrogen tank is required, but in order to cover 300 L of hydrogen with a 74 L / 35 MP container, a container that can be filled with about 150 MPa compression is required, which is difficult with the current technology.
Therefore, it was planned to generate synthesis gas in a mounted internal combustion engine. However, in a pressurized pump with a mounted structure, if the compression pressure is increased, more power is consumed for the pressurized pump. At the start, the gas was accumulated with equipment equivalent to an accumulator of hydraulic equipment, but the car fell from the cliff due to an accident on the highway where the livestock gas equipment should be installed. If the accident is such that the car is flipped upside down or the passenger car is sandwiched between large trucks and crushed in a sandwich, the structure must be such that an explosion can be avoided when such an accident occurs. I gave up on board.
If you are searching for related documents on the Internet and searching for prior literature for planning other projects using synthetic resin, the following foamed polyethylene, (the above-mentioned member has anti-bullet properties and is used for military weapons, (As an example, polyethylene fired polyethylene is fixed to the outer surface of an army water hoat for army movement, and when it is sniped with a rifle etc., the bullet has a bullet-proof property that does not allow a hole to be made in the rubber hote) Can be found, and if this was used, it was able to solve even the place where it did not explode even if the accident occurred. However, the problem was the location of the last remaining tank.
While considering the eco-driving method filed last year and thinking about what to do with resin to reduce the weight of the car, when considering the roof of a passenger car, the livestock gas tank of the present application that had been neglected was used for the roof of the car The structure of this livestock gas tank is the key point of the present application. (See Figure 1A and Figure 2)
2. As shown in FIG. 2, the outer surface of the livestock gas tank is made of poron fiber reinforced plastic or foamed polyethylene. (The above-mentioned members are bullet-proof and are used for military weapons. The fired polyethylene is fixed on the outer surface of the water hoat for moving the water surface, and when it is sniped with a rifle, etc., the bullet has a bullet-proof property so that a hole cannot be made in the rubber hoat)) A tank separation means is provided that separates from the car body when it is impacted by falling or severely damaging the car. It has a structure that does not explode even if it bounces off. (It is preferable to provide a locking structure that does not jump too far.)
3. As an example of the separation structure of the tank inlet / outlet pipe from the vehicle body, the solenoid valve contact configuration is ON when energized. When the solenoid valve sequence circuit is turned off when not energized, and the synthetic gas tank is subjected to an impact force flying from the body of the car, the gas inlet / outlet pipe of the tank may come off (or be damaged). The gas pipeline from the tank is closed. (See Figure 2.H)
4). As for the problem of compression pressure of livestock gas, if the configuration of Mazda (Company Name) Premasi Hydrogen RE hybrid vehicle, which uses auxiliary fuel, the eco-driving method and the internal combustion engine of the last year's application only generate electricity, is the first of the present application. Combining the sixth and seventh inventions with the detailed explanation part of the invention in addition to the reforming technology of the invention from the third invention, the synthesis gas alone or only the hydrogen or synthesis without using auxiliary fuel An embodiment which may be used by switching between gas and hydrogen, and the stored gas pressure can be handled with a low compression pressure as described in the next paragraph.

In order to cover the fuel necessary for running 500 km with gasoline with hydrogen (synthetic gas), 5 kg of hydrogen (equivalent to 56,000 L of hydrogen) and (10 g / Km = hydrogen of 11.2 L).
Therefore, the capacity of a livestock gas tank for fuel (hydrogen, synthesis gas, carbon dioxide) required for about 10km travel is a livestock gas tank capable of livestock gas of 11.2L * 10 = 112L (normal pressure) if the fuel switching loss is ignored. It will be good if there is.
Therefore, it can be designed freely as long as it is within the scope of the law and the relationship between the tank manufacturing cost and the installation space and the switching cycle to be set.

A synthetic gas storage gas tank produced from the internal combustion engine according to the first to third aspects of the invention is provided in the upper part of the vehicle, and an impact buffer (fired polyethylene, boron fiber reinforced plastic, etc.) is fixed to the gas storage tank. A storage tank that protects against explosion or explosion in the event of a car wrecking by fixing either a coating or a multi-layered structure to the storage tank.

Referring to FIG. 1, the vehicle shown in FIG. 1 is a schematic configuration diagram in which the structure of the present application is installed in a commercial vehicle front engine type commercial vehicle, and an exhaust pipe from a hydrogen rotary piston engine (internal combustion engine) installed in the front engine room. The endothermic reaction synthesis gas generation section provided in the section generates gas, and the extracted synthesis gas is stored in the storage tank MT provided in the upper section and used as fuel for the hydrogen rotary piston engine. In the schematic configuration diagram, switching the loss to the fuel of the sub tank ST,
FIG. 1B is a schematic configuration of an engine block, a synthesis gas generation endothermic reaction flow path section, a fuel supply / injection system, and a spark plug of a reciprocating engine. a schematic configuration flow diagram parts and the fuel supply and injection system ignition plug, the water HO ₂ into the engine block of a four cylinder reciprocating engine provided with a water passage K of the steam J, water H _{2 O} (or water and carbon dioxide) is supplied from the supply port steam generating unit (or / and carbon dioxide heat absorbing means) and bookmarks, intake air 0 ₂ is provided for supplying duct 3 air 0 ₂ to the inlet port a _P are supplied to the mouth a _P, the exhaust port from E _P at the conduit 4 is connected to the exhaust pipe of the synthesis gas production unit, endothermic of said exhaust pipe MS syngas product endothermic reaction portion in the exhaust pipe Reaction tube It is provided in a coil shape, and the steam J generated in the engine block of the reciprocating engine is introduced into the coiled endothermic reaction tube and carbon is newly introduced, and the exhaust gas of the synthesis gas generation unit flowing MS to the tube, to produce the exhaust gas E _X of the exhaust heat in the synthesis gas CO + H ₂ generated in the engine combustion stroke, produced synthesis gas by livestock gas in the synthesis gas storage tank (slaughtering gas tank) MT In order to make up for the shortage of the generated fuel, a sub tank ST is provided to store the sub fuel. The sub tank fuel and the synthetic gas stored in the live gas tank are switched by the switching valve CB, and the fuel supply line 5 FIG. 2 is a schematic configuration diagram of an internal combustion engine that is supplied to the injector E _C H ₂ and has a configuration in which a plug P for forced ignition is provided.

A water passage K for converting water HO ₂ into water vapor J is provided in the engine block, water H ₂ O is supplied from the supply port, and in addition to the water passage K serving as a water vapor generating means, an air passage for heating CO 2 is provided. K ′ and a CO2 supply port are provided to supply at least one of the plurality of exhaust pipes to the pipe for reforming CO2 and any other pipe for reforming CO2. The steam J is supplied to all of the pipes as needed to make the steam reforming pipe line or the syngas reforming path of the third invention. It is also possible to add a configuration in which a supply path for switching supply from one to another is added.

FIG. 2A. 1 is a cross-sectional view taken along the line AA in FIG. 1. As an example, this figure shows a synthetic gas tank having four cylindrical MTBs, and a single package made of a shock absorbing material such as foamed polyethylene, boron fiber reinforced plastic, or the like. In the state where the vehicle is fixedly held on the upper part of the vehicle, and is fixed to the fixture MT5 that is fixedly fixed to the upper part of the vehicle with the fixed holding fixture MT1. The V-shaped notch MT6 breaks due to concentrated stress, and the shock absorbing material inclusion MT3 (for example, the tank support MT2 is integrated) is detached from the fixture MT5 (completely disengages). (It is a preferable form to take a structure in which it is locked to the fixing device MT5 or the like with a thread body or the like, because this is a measure for avoiding the secondary damage in which the inclusion body MT3 of the shock absorbing material completely comes off))

As an example, when a collision or falling force is applied to the tank, a holding structure in the event of an accident is provided, and a structure (part of which is preferably connected to the car) is provided. The tank that flies off from the vehicle is made of foamed polyethylene, boron fiber reinforced plastic, impact buffering material (HTP), etc., which is provided on the outer surface of the tank and fixed to the entire surface, and absorbs or diffuses impact force. So it does not explode.
The foamed polyethylene, boron fiber reinforced plastic, and shock-absorbing materials that are fixed to the entire surface of the coating or the entire surface may not be expensive at this time, but they are produced almost 20 million units / year (by the entire Japanese automaker). The cost is reduced due to the effect.

FIG. FIG. 6 is an example of a tank mounted on a rear engine vehicle in which the shock-absorbing material MT3 is mounted perpendicularly to the traveling direction; E. The figure shows that there are no restrictions on the number and shape of the tanks. E, the tank is housed in the front and rear recesses on the roof of the car, and the aesthetics from the side are improved. F. Is a type with an engine mounted under the cabin. The shape installation direction of the gas tank MTB and the tank package MT3 to be mounted is a design problem in the relationship between the tank capacity to be installed and the gas pressure.

FIG. FIG. 5 is a partial cross-sectional view of the structure of the gas inlet / outlet portion when there is only one gas tank MTB, and the gas taken out from the synthesis gas generator S is a tank open / close valve GTbsec (for example, the electromagnetic valve is turned on when energized and turned off when deenergized. It is a schematic diagram of a structure in which gas is stored in a tank via a contact circuit) and introduced into the fuel switching valve Cb of the engine. If the force is applied to the tank and the gas storage tank comes off, the electrical wiring will be disconnected and the electromagnetic valve will be turned off so that the gas in the tank will not leak.
2 and I are. A reverse J-shaped locking and fixing structure KRsec having elasticity is provided at both ends of the fixing device MT5 fixedly fixed to the upper part of the vehicle. (Lower view) When the car is severely damaged, the reverse J-shaped This is an example of a structure (upper view) in which the reverse J-shaped locking function part of the locking structure KRsec extends and the HPE body is detached from the upper part. As long as the HPE body has a function of separating to the upper part, it does not stick to metal, synthetic resin, other, material and shape.
It is preferable to provide a carbon dioxide livestock gas tank and a hydrogen livestock gas tank in the structure of the livestock gas tank.

Although the above-mentioned supplemental described, the synthesis gas produced by the steam reforming is a schematic substance amount 1 of CO and H _2: a mixture of 1. Since the gas volume is proportional to the amount of the substance, the amount of carbon monoxide = the amount of hydrogen and the gas has a volume of 22.4 L / mol in the standard state. (Transport efficiency of liquid hydrogen: high pressure hydrogen = 6: 1) Hydrogen is 39 g per liter (weight in tank of 700 atm).
The gas generated by the CO ₂ reforming is described in the paragraph of the second invention, but when the reforming substance is dimethyl ether as an example, the dimethyl ether is either water vapor or carbon dioxide, or both. In addition, if you react,
A. In the case of CH ₃ OCH ₃ + H ₂ O → 2CO + 4H ₂ −48.9 Kal / mol water vapor
B. In the case of CH ₃ OCH ₃ ++ CO ₂ → 3CO + 3H ₂ −58 · 8 Kal / mol carbon dioxide
C. In the case of both 2CH3OCH3 + H2O + CO2-107.7 Kal / mol become that way.
* Hydrogen properties, diffusion is quick and easy to leak, high reactivity, and especially brittle metals including steel.

FIG. 3A. FIG. 1A is a cross-sectional view in the front-rear direction of FIG. 1A, and a description of the hydrogen-compatible structure of the rotary piston engine is shown in FIG.
Rotary piston engine A water passage K that makes at least a half turn between the inner wall and the outer wall of the rotary housing is provided, and water is supplied from one water introduction pipe to the water passage K between the inner wall and the outer wall of the rotary housing. The water is sent to the endothermic reaction channel S through the carbon C insertion tube, and the water becomes steam J in the process of passing through the water passage that contacts the intake → compression → explosion → exhaust process part with the combustion heat of the fuel. The
Air O ₂ is sent into the other rotary piston engine, and then the fuel synthesis gas MTC or subtank ST fuel (any of butane, biofuel, synthesis gas, etc.) is sent into the engine, → compression → explosion → exhaust E _X next to be fed to the endothermic reaction flow path portion S, the exhaust E _X flows through the tube center portion of the endothermic reaction channel section S, carbon inserted with steam J thermal reaction channel is in the description of FIG. 3 flow synthesis gas generator tube provided in a coil shape in contact with the tube wall of the tube MS, the tube in the heat of the exhaust E _X flowing a central portion is generated in the synthesis gas is withdrawn from the take-out tube is transferred to savings gas tank MT FIG.
The explanation structure of FIG. 1B and FIG. 3 is applied to the structure of the water passage / ventilation path of the rotary housing corresponding to CO2 reforming and synthesis gas reforming.

FIG. 3B. FIG. A mixture of water vapor J and carbon C is fed into a water passage K between the inner wall and the outer wall of the rotary housing into the water (H ₂ O) introduction pipe portion of the water and comes into contact with the inner wall surface of the thermal reaction channel pipe MS in a coil shape the synthesis gas production tube provided in the flow, which is the tube structure schematic diagram central portion is generated heat in the synthesis gas in the exhaust E _X flowing retrieved from the take-out tube is transferred to savings gas tank MT.
The structure of the water passage / ventilation path of the rotary housing corresponding to CO ₂ reforming and synthesis gas reforming also applies the explanation structure of FIG. 1B to FIGS.

Figure 4 is provided to the synthesis gas production pipeline provided in a coil shape in contact with the tube inner wall surface of the thermal reaction flow pipe MS of FIG. 3 in a thin tube of a straight, exhaust between the thin tube and the thin tube E _X The design of the endothermic reaction flow path has been put to practical use in a system that makes the exhaust gas harmless by confronting the catalyst in the exhaust gas treatment system. good.

FIG. 5 is a schematic view showing a hydrogen rotary piston engine disclosed in Japanese Patent Application Laid-Open No. 2007-2111608.

FIG. 6 is a diagram showing a main configuration of an electronically controlled injection structure of a hydrogen rotary piston engine. The electronically controlled injection valve needs to inject a large capacity of 2300 NL / min in order to obtain an output of 100 KW, for example. The two injection valves 40 and 42 in the above figure are provided to inject a large volume.
Further, a large-capacity intake port 16 and an exhaust port 18 are provided on the side of the rotor housing, and the explosion chamber is divided into two when it is about to explode, and two spark plugs 14 and 15 are provided.

In recent years, hybrid vehicles and 100% electric vehicles have attracted attention.
However, if most of the automobiles are used as electric energy, there is a problem of the “Fukushima nuclear power plant” that overwhelms the power supply situation to follow the speed of electrification including home appliances, and the expansion of the power supply facilities is solved quickly It is an issue that should be done. However, the public disagrees with the current situation regarding the construction or restart of nuclear power plants, as the burden of electricity charges will increase if the nuclear power plant is abolished. I understand that there are many, and further public opinion is toward the direction of damming. Therefore, expansion of power supply facilities is a desperate situation that the weight of things by thermal power generation and natural energy becomes very high . Therefore, expanding the power generation facilities that suppress CO ₂ emissions is a problem that should be solved immediately.

In recent decades, cheap timber has been imported from foreign countries, the number of forestry workers has decreased dramatically, the forest has not been thinned, and dead trees devoured by pests such as pine wilt have been left unattended.
Furthermore, it is the vitalization of agriculture, but most of the “rice fields” have agricultural waterways, which have been fertilized for many years and have become fertile farmland. For example, “Kenaf”, which is a pulp material, and “Mulberry” in sericulture can be planted in this “rice field”, or “Yukari” from Uruguay in South America can be used. One plan is to use a small-scale carbonization device (see Fig. 10) that can be carbonized by a farmer with a single hand for lending use (lease method). For example, if the carbonization equipment that is cheaper with the price of the carbonized equipment is purchased in a five-year split, for example, a small scale that allows more forestry workers and farmers to use the purchased money with one hand. ”Carbonizing equipment” It is also possible to plant a thing that can become “bioethanol” that grows well in places where water supply is sufficient, such as taro.

The goal of reducing greenhouse gas (CO ₂ ) emissions by 25% by 2020 is being asked, and Japan's CO ₂ emissions are struggling to see how the world can reach this goal. The main players in this project are emissions from internal combustion engines and emissions from thermal power boilers, which account for about 82% of electricity generation (2012 Electricity Federation statistics). These CO ₂ starts with coal, oil and natural gas. Fossil fuels such as coal, oil, and natural gas are limited resources, and of course, resources that cannot be reproduced.

According to the Kyoto Protocol, carbon dioxide CO ₂ produced by the combustion of plant carbon C is consumed by plant carbon assimilation, so it is a plus or minus zero and is not counted as CO ₂ emissions. Therefore, in order to shift the carbon consumption of fossil fuels to plant carbon and achieve a 25% reduction in greenhouse gas CO ₂ emissions at an early stage, it is best to realize the above-mentioned synthesis gas generation cycle plan. think. (According to 2010 data from the Ministry of the Environment, greenhouse gas CO ₂ emits 30.3 billion tons worldwide, Japan is 3.8%)

The day when solar power generation (system using solar power generation panels, condensing sunlight, generating steam with heat → power generation) will become the mainstream of future power generation is not far away. However, solar power generation is not possible 24 hours full-time power generation at night, rain, and cloudy, and if it is installed on a large scale, it will be quite remote from the power usage area, so it will install new substation and transmission equipment The disadvantage is that large-capacity power storage equipment is necessary to cover only with solar power generation, and if it is a place with a good sunshine rate (for example, a desert with low annual rainfall is the leading candidate), a large amount of power transmission / reception equipment is required. (There is superconductivity invented by Japan in the above-mentioned large-capacity power storage equipment, large-scale power transmission / reception equipment, the experimental plant is already in trial operation, and the international standard of 1,100,000V was also established in 2008. Although it has just gained international approval, the gap with the estimated cost is a problem).
Therefore, if the internal combustion engine power generation of the present invention that can be operated for a short time other than the solar power generation time is used in combination with the fuel production mechanism of the present invention, it can be said that the reduction of greenhouse gas CO ₂ emission can be achieved earlier. .

Whether or not the procurement cost of carbon C as a fuel can be reduced holds the success or failure of practical use of the present application. In carbon production, when carbonized organic substances are heated with the air and oxygen flow cut off, they turn into black carbon-rich substances. The resulting product is an aggregate mainly composed of amorphous oxygen and the like, and is mostly porous and has a very large surface area. Heating causes dehydration and dehydrogenation reaction to produce a condensed polycyclic aromatic compound, which further forms a network structure, which is called carbonization.
Carbon charcoal used as a fuel while performing many operations such as thinning, pruning and undercutting. It is a concrete proposal that is a shortcut for realizing the present application to sequentially lend carbon production equipment that has a structure that can be handled in a procurement manner (subject to substituting for subsidies).

FIG. 10 is an assumed schematic diagram of the above-described small-scale carbonization apparatus. Carbonization plants suitable for the carbon material of the present application are placed in the carbon production chamber CS, and the combustion chamber FC serving as a pot door is approximately half carbonized of the carbon material of the present application. By burning the timber plant and collecting it in the collection area in the form of carbon C, it is possible to reduce the transportation cost much more than transportation with branch wood,
Fuel for heating (plants such as wood, etc.) that heats the carbonization chamber by introducing wood into the carbonization chamber CS that heats and carbonizes plant raw materials (wood, etc.) in an environment that does not contain oxygen The raw material or other combustion material) is introduced into the combustion chamber FC where it is combusted and combusted. The gas C4 generated in the carbonization process in the carbonization chamber and the water introduced from the exhaust gas of the combustion chamber FC and the water tank on the inner wall of the carbonization chamber A pipe for steam generating means for converting H ₂ O into steam is provided, and the gas is generated in the carbonization process together with the gas C4 to be introduced into the combustion chamber through the introduction pipe C4 to form a fuel that heats the carbonization chamber.

The reforming part (CO ₂ reforming) having the structure described in the paragraph of the second invention is provided in the discharge part (chimney) of the exhaust gas pipe, and as an example, the reforming substance is dimethyl ether, and the catalyst If the reforming section is made to react with either dimethyl ether or one of water vapor or carbon dioxide to produce fuel for a small-scale carbonization device, fuel consumed for carbonization can be further reduced, and the greenhouse Reduction of effect gas emissions.
Furthermore, by using a reforming section (CO ₂ reforming), it is possible to use fossil fuels such as coal, and it is possible to use it as a starting reforming material that reforms wood, etc., used as fuel into plant raw material C.
As an example, the catalyst can be used in combination with other metals or compounds in addition to iron-based metals and / or compounds. Examples of other metals or compounds include zinc, nickel, chromium manganese, tin, cerium, lanthanum, and the like. These compounds, other metals or compounds.

The synthesis gas described above is not limited to hydrogen and carbon monoxide. The synthesis gas represents a main component, and includes, for example, unburned carbon, carbon dioxide, moisture, and other gases and impurities present in the atmosphere. This includes cases where

The procurement cost of carbon (plant raw material C) is currently higher than that of natural gas (methane, butane, etc.), coal, and petroleum fossil fuels. Until it is obtained, or the law of strengthening the emission control of greenhouse gas CO ₂ is made, the procurement of carbon will be done with natural gas (methane etc.) or directly with natural gas (methane etc.) as fuel and the whole society There is also a way to switch when the desire for carbon increases and the cost of carbon procurement can be paid,
However, I think that the speed of progress in chemical technology is progressing in proportion to "needs",
Therefore, if the need for procurement of renewable carbon C, which is the main raw material of the present application, becomes high, we are confident that the procurement technology will evolve with acceleration.
The carbon used in the internal combustion engine cycle of the present application is the cheapest to use “coal” as powder for the time being, so the fossil fuel will be used until the renewable carbon C procurement system is complete. It will take the form of shifting to a carbon C procurement system that can be sequentially regenerated.

The amount of purchase of greenhouse gas CO ₂ emission allowances in Japan is estimated to be about 1 trillions of billions of yen. If this purchase amount is used as part of the carbon procurement cost, the time of realization of the present invention will be explained. Will be faster.
* If transportation from a chemical factory, steel factory, aluminum factory, dust incineration plant, etc., is carried out using a mixed gas of hydrogen and carbon monoxide, carbon dioxide, hydrogen, etc., the transportation cost will be much lower than transportation using transportation equipment. I can do it. Each US and European country has a hydrogen transport pipeline of thousands of kilometers, and should be realized early with the support of the government in order to survive the world as a competitor.

The power generation facility powered by the internal combustion engine of the present application is a relatively small-scale power generation facility. Because it can be a decentralized power generation system with self-sufficiency in units of mass such as remote islands, mountainous remote areas, industrial parks, submarine transmission cables and power demand It is possible to drastically reduce power transmission facilities, power transformation facilities, and power reception facilities that respond to changes in power consumption.
Furthermore, the current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of the present application do not need to be adjacent to the water source, and have the advantage that they can be installed as close to the power demand area as possible.

When methanol is used as a fuel for an internal combustion engine, methanol is originally synthesized from hydrogen and carbon monoxide at a high pressure advantageous from chemical equilibrium. Therefore, it is most efficient in terms of energy to use it in the form of synthesis gas of hydrogen and carbon monoxide, rather than converting it to hydrogen.

Although transportation of compressed hydrogen and liquid hydrogen is carried out, in order to compensate for the problem that the volume storage density of hydrogen gas is small, hydrogen is pressurized to 14.7 to 19.6 MPa and transported as compressed hydrogen. Mo steel hydrogen container is heavy. For example, a trailer vehicle that transports 100 kg of hydrogen requires 7 tons of hydrogen container. To reduce the cost of transporting compressed hydrogen, aluminum alloy liners and high-density polyethylene liners are used. It is necessary to make a tank reinforced with glass fiber or carbon fiber,
Under current regulations (in Japan, registration of JIS B 8265 has been completed and internationally there is ISO 16528) CFRP for transportation (tank with high-density polyethylene liner reinforced with glass fiber or carbon fiber on the entire surface) ) Since the container has a pressure of up to a capacity of 35 MPa, it is necessary to relax regulations in order to utilize the container. (Japan Industrial Gas Association, hydrogen gas container standards)

On the other hand, liquid hydrogen has a volume storage density 800 times higher than that of hydrogen gas, and tank trucks or insulated containers are used. However, liquid hydrogen requires energy for liquefaction and has a boiling point of −253 ° C. and evaporation loss. There are disadvantages that occur.

The internal combustion engine of the present invention uses synthesis gas as fuel, and the synthesis gas is a pipe supply in an automobile, and the accumulation pressure of the livestock gas tank for livestock synthesis gas produced by the internal combustion engine is the above-mentioned existing hydrogen There is no need to use a 35MPa livestock gas tank of compressed gas installed in the engine car, and it may be about 1/40 of the accumulated pressure, and the energy used for the pressurizing pump can be saved as much as the accumulated pressure can be reduced. The gas storage tank structure can also be a structure of at most several MPa within the current regulations.

Pipeline transportation is optimal for steady mass transportation of hydrogen, and the synthesis gas of this application is similar to hydrogen in Europe and the United States. It is the best way to do it.
As the pipe material of the hydrogen pipeline, in the current advanced technology, if it is a sour-resistant material with a reduced amount of vanadium and a small amount of nickel or chromium, compared with ordinary line pipe steel, it can be used in a normal transportation environment. It is said that the cost can be increased to 10% or less.

The rotary engine vehicle powered by hydrogen is a Mazda Premacy Hydrogen RE hybrid vehicle that has a structure that can be selected to travel using either hydrogen as fuel or gasoline as fuel. A high-pressure hydrogen fuel tank (35MPa, 74L) And a gasoline tank is mounted on the vehicle, electricity is generated by rotating a hydrogen (or gasoline) rotary engine and stored in a lithium ion battery, and driving of the wheel is electricity stored in the battery,
The feature of this car is that the engine is operated with good fuel economy, and the control of the vehicle speed fluctuations depending on the running state of the car is electric control.
Disadvantages include a short mileage of 100 km in a high-pressure hydrogen fuel tank, and the hydrogen transportation means (assuming transportation by car) has a poor ratio of hydrogen loading weight to the tank weight, leading to the development of infrastructure such as hydrogen stations. There are no points and high hydrogen production & transportation cost.

The hydrogen engine bus developed by Tokyo City University, which uses hydrogen as fuel, is loaded with six tanks compressed to 35MPa on the roof. The main improvements in the engine are the addition of an intake manifold, hydrogen injection valve and spark plug.

A hydrogen reciprocating engine and a wagon type Musashi 10 developed and developed by Tokyo City University using hydrogen as a fuel, is a hydrogen engine with a hydrogen cooling intercooler, equipped with a tank of 100 L of liquid hydrogen and continuously running at 300 Km per charge. It is a car that made it possible.
Disadvantages of the above-mentioned existing vehicles that use hydrogen as a fuel are that the ratio of hydrogen loading to the tank weight of the hydrogen transport means (assuming transport by car) is poor, the infrastructure development such as the hydrogen station does not progress, and the hydrogen production cost It is a high point.

The hydrogen rotary piston engine Mazda (company name), and generating the hydrogen H ₂ as a fuel, since by rotating the motor in the electric can use the power component as power generators, dwell as a power generator generating The components are applied to the internal combustion engine of the present application.

In the case of the power generation equipment in the previous paragraph, it is adjacent to steelworks, chemical factories, aluminum factories, foundries, forging factories, waste incinerators, etc. that are syngas as a by-product or a large amount of heat is discarded. If the power plant is installed in the vicinity, the running cost can be further reduced.

In the case of the internal combustion engine power generation equipment of the present application, a relatively small scale power generation equipment (if the internal combustion engine power generator is assumed to have an output machine of 1000 KW / H as 1 unit / unit, 1 unit to several hundred units The number of units can be set as a decentralized power generation system with self-sufficiency in units of mass, such as remote islands, mountainous areas, and industrial parks. It is possible to greatly reduce the power transmission facilities and power transformation / reception facilities corresponding to the changes.
Furthermore, the current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of the present application do not need to be adjacent to the water source, and have the advantage that they can be installed as close to the power demand area as possible.

The carbon sources mentioned above are dead trees that have been eaten by pests such as thinning and pine wilt, and rice husks and husks generated in Japanese rice farming are discarded. Cultivated kenaf (Hibiscus cannabinus L) in vacant land such as fallow land, which can be mixed gas production plant carbon (C) at a rate of carbon (C) of said plant It goes without saying that cultivating corn, sugarcane, etc. in vacant land such as fallow land can be used as biofuel for plants, but many rice fields have agricultural waterways. In addition, since it has been fertilized for many years, for example, cultivated taro, wheat, and actually edible, the waste part is made into the biofuel of the plant or the carbon of the plant (C) and the wheat straw is converted into the carbon of the plant ( There is also a method to make up for the difference between the income obtained from them and the income obtained from rice cultivation, etc.

Agricultural work with 2 to 3 small rice fields as a single rice field as a measure to expand the scale of agriculture, which has been implemented in the past 20 years as a measure against rice prices (Urg Island) for agriculture (rice farmers) that has been considered in the country. Measures to increase efficiency, measures to increase the size of several farmers as one company, agricultural income compensation system, a subsidy subsidy policy (2.5 trillion yen) to cope with a decrease in rice demand There is a policy to support, but none of these policies are far enough to make Japanese rice farmers an attractive profession for the next generation, using the carbon (C) of the plant as a fuel source. To achieve this policy, “Reducing CO ₂ emissions in response to global warming” and “Making agriculture and forestry an attractive occupation” and further revitalizing the Japanese automobile industry. We can expect effect of "one stone several birds" .

Various embodiments that can be easily conceived from the events described in the present specification and claims are included in the present invention as long as they do not depart from the scope of the claims.

Although this project is partly undeveloped, the internal combustion engine of the present application can be implemented. Furthermore, it can be used for those industries that spread to people in industries related to them.
Above all, creating a cycle that maximizes the use of your country's resources will create a foundation for Japan's 100-year total, leading to the development of those industries.

A. FIG. 3 is a schematic structural diagram of water and carbon as synthesis gas of H ₂ and CO in the engine in an internal combustion engine (rotary piston engine). B. The schematic block diagram of the engine block of a water vapor | steam production | generation part of a reciprocating engine, a synthetic gas production | generation endothermic reaction flow path part, a fuel supply / injection system | strain, and a spark plug. A-F FIG. The example of several types of storage gas tank installation of the storage gas tank installation procedure. H. The partial cross section of the cylinder of 1 unit of a gas storage tank, and the gas inlet / outlet pipe | tube partial view and partial sectional drawing of the said cylinder. i. Tank comprehensive body holding / removal diagram. A. FIG. 1B is a schematic cross-sectional view from the EAsec rotary engine of FIG. 1A to the endothermic reaction flow path portion. B. FIG. A. Type cross-sectional view of pressure inserting the vapor and carbon in H _{2 O} supply pipe. The schematic structural example figure which comprised the structure of the endothermic reaction flow-path part provided in the engine exhaust pipe part and the gas production | generation pipe | tube with several thin tubes. Schematic which shows the rotary engine of the control apparatus of Unexamined-Japanese-Patent No. 2007-2111608. A, electronic control of a rotor same as above, and hydrogen injection structure schematic cross-sectional view of a fuel injection device of a hydrogen rotary piston engine disclosed in Japanese Patent Application Laid-Open No. 2007-064169. B, A, the longitudinal cross-sectional view of a figure. The block diagram of embodiment of the fuel reformed gas engine of Unexamined-Japanese-Patent No. 2002-039022. 1 is a schematic configuration diagram of an electronically controlled hydrogen injection system, intake / exhaust ports, and spark plugs for reciprocating (diesel engine) fuel supply. FIG. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic structural diagram of an exhaust gas treatment device provided in an exhaust pipe that generates Karman vortices of Japanese Patent Application Laid-Open No. 2002-256849 and sucks CO ₂ of exhaust gas into water. An example figure of a small carbon generator. Annual bar graph that captures past years of carbon dioxide emissions statistics from fossil fuels around the world.

An internal combustion engine that contributes to the reduction of greenhouse gas emissions, particularly producing carbon C and water H ₂ O, mainly plant, into synthesis gas (H ₂ + CO) in the internal combustion engine, Further, carbon dioxide discharged from the combustion of the synthesis gas is separated as fuel for the internal combustion engine and reformed into synthesis gas H ₂ + CO and hydrogen in the internal combustion engine, and the synthesis gas and hydrogen are used as fuel for the internal combustion engine. To do.

Greenhouse gases are a major cause of global warming, and it is a common recognition in the world to think that “greenhouse gases should be reduced.” However, it is at the stage of “specific numerical targets…” In the era of international price competition, the current situation is that the story has not progressed because it will incur greenhouse gas reduction costs.
As a power source of an automobile (internal combustion engine) of a greenhouse gas emission reduction measure as of 2014, an electric vehicle, a hybrid with hydrogen, or an engine system using only hydrogen or "bioethanol" as fuel There is also a technology for reducing greenhouse gas emissions by reforming a fuel of 2008-298030 or “bioethanol” into a fuel containing hydrogen and carbon monoxide and using the reformed gas as a fuel. There are still problems that must be solved in order to commercialize products, and it is recognized that there is a part that each problem is lacking in the process of solving.
Of the technologies mentioned above, in the technology using electricity as the power source, according to the statistics of the Electricity Federation of 2011, about 82% of Japan's total power generation is thermal power generation. since the discharging "CO _2" and using the fossil fuels, including unless realized measures that do not emit "CO _2" from the power plant, a greenhouse global warming electricity as a power source It cannot be said that it is a power source of the internal combustion engine that contributes to reducing the effect gas.
Moreover, nuclear power generation is a power source that does not emit “CO ₂ ”, which uses electricity as the power source of the above technology to reduce greenhouse gases. However, there is a problem of “Fukushima nuclear power plant”, so it is difficult to establish a new one. And I think that the view that it goes to the direction of decommissioning occupies a lot.

Equipment for reducing the “CO ₂ ” already exists, and the method is a proposal to sequester the discharged carbon dioxide deeply (A) or sequestered (B). In 2014 has been completed is coal-fired power plant of the world's largest in the United States, but the processing of the "CO _2", which is discharged in the power generation is a structure to contain the underground layer of 15 00 m (the A), construction cost of this power plant is cage once usually twice or further takes energy costs for containing the underground layer of 15 00 m, the cost there is a problem that becomes a is plus in electricity rates consumers pay.

Various technologies have been proposed one after another for the technology to obtain synthesis gas or hydrogen gas by reforming the above-mentioned “CO ₂ ”, and have already been proposed in the in-service sector as an energy generation technology for blast furnace gas and converter gas in steelworks. There are many technologies that have been put to practical use, and the gas emitted in the power generation process of thermal power plants is also used to increase energy efficiency, but most of them are fixed-form features in the large-scale equipment industry. In addition, no feasible technology has been proposed (not found) for reforming “CO ₂ ” discharged from the internal combustion engine in the internal combustion engine that can be mounted on the moving form and using it as a fuel for the internal combustion engine.

Patent 5647364. Engine mechanism of rotary piston engine car. JP-A-11-106770. Power generation method and apparatus using dimethyl ether reformed gas Patent 4231735. Method and apparatus for separating and recovering carbon dioxide JP 2007-177684 A, a carbon dioxide recovery device for a vehicle, and a vehicle including the same. Reaction of hydrocarbons with water vapor or carbon dioxide. Patent 4,609,718 Hydrogen rotary piston engine fuel injection device Japanese Patent Application No. 10-543729 (patent 33455782) synthesis gas production method.

A rotary piston engine combusted by auxiliary fuel, a water supply means for supplying water to the rotor housing of the rotary piston engine from the introduction pipe, and the supplied water is steamed by the heat of the rotor housing, And a livestock gas means for storing the gas that is generated by the endothermic reaction using the exhaust heat after the combustion process of the rotary piston engine and generating the fuel while the auxiliary fuel is used. There is a technique (for example, Patent Document 1) characterized by a structure including a switching means for switching the livestock gas of the livestock gas means and the auxiliary fuel to be supplied to the rotary piston engine, and this application is based on this technique. as carbon dioxide in the exhaust gas from the combustion of the fuel (CO ₂₎ also to adopt a technique of reforming a fuel, further We are in a technology that is a greenhouse gas emission reduction measures that.

Uses dimethyl ether reformed gas, characterized in that dimethyl ether is reformed by adding steam or carbon dioxide gas to dimethyl ether to cause a catalytic reaction to obtain synthesis gas or hydrogen gas, and this gas is used as a fuel for a prime mover There is a power generation method, and the above power generation method (for example, Patent Document 2), characterized in that the reforming of dimethyl ether is performed using medium to low temperature waste heat from 200 ° C to 500 ° C.
In this application, by incorporating a part of this technique into the technique of Patent Document 1 above, the carbon dioxide exhausted by the technique of Patent Document 1 is also used as the fuel of the internal combustion engine, thereby improving the fuel consumption. Greenhouse gas (CO ₂ ) emissions from the institution are approaching “zero”, and the technology has become a greenhouse gas reduction measure by carbon assimilation of plants.

A method of separating and recovering carbon dioxide from a by-product gas generated at a steel works by chemical absorption method, which absorbs carbon dioxide from the gas with chemical absorption liquid and then heats the chemical absorption liquid to separate carbon dioxide A method for separating and recovering carbon dioxide, characterized by utilizing or utilizing low-grade exhaust heat of 500 ° C. or less generated at a steelworks. (For example, Patent Document 3)
In order to separate and recover the carbon dioxide of the present application, there is a problem that it is necessary to install a membrane type permeation device that allows several kinds of permeable membranes to pass through the exhaust gas, or to install a vacuum pump or the like.

And in silencers vehicle carbon dioxide device in an exhaust system of an automobile is mounted between the exhaust pipe, provided with a C0 ₂ absorption portion which is connected via an absorbent material and the three-way of the solenoid valve carbon dioxide , A structure in which carbon dioxide is released from the aqueous solution of alkanone compound that has absorbed carbon dioxide by absorbing heat from the engine cooling heat through a solenoid valve, and the separated carbon dioxide is used to regenerate used alkanolamine compounds. (For example, Patent Document 4). This technology is used to regenerate the aqueous solution of alkanone compound that has absorbed carbon dioxide as an application of carbon dioxide separated by the technology that separates carbon dioxide in automobile exhaust gas. It can be used as a technique for separating carbon.
* In this application, carbon dioxide separated from the exhaust gas or carbon dioxide in the exhaust gas is absorbed into water and produced in the fuel (gas) by the internal combustion engine of the present application, and the internal combustion engine fuel (gas ) Is the decisive difference in terms of action and effect.

A method of reacting a hydrocarbon with water vapor or carbon dioxide or a mixture thereof under a net endothermic condition to form a gas containing a carbon compound and hydrogen, which is acidic or amphoteric with nickel and cobalt compounds and alkali metal oxides. There is a technique (for example, Patent Document 5) relating to the above method characterized by using a catalyst comprising a water-insoluble compound with an oxide or mixed oxide.
In this application, by incorporating a part of this technique into the technique of Patent Document 1 above, the carbon dioxide exhausted by the technique of Patent Document 1 is also used as the fuel of the internal combustion engine, thereby improving the fuel consumption. Greenhouse gas (CO ₂ ) emissions from the institution are approaching “zero”, and the technology has become a greenhouse gas reduction measure by carbon assimilation of plants.

A fuel injection device for a hydrogen rotary piston engine, which is attached to a rotor housing that forms a working chamber of the hydrogen rotary piston engine and directly injects hydrogen into the working chamber of the hydrogen rotary piston engine, and the hydrogen injector is operated Hydrogen injection timing control means for controlling injection timing so that hydrogen is injected into the chamber at a predetermined timing during the compression stroke, and hydrogen from the hydrogen injector is in the low rotation range of the hydrogen rotary piston engine. And a hydrogen outflow direction setting means for setting the hydrogen injection direction so as to flow out toward the leading region and out toward the central region of the working chamber in the compression stroke in the high rotation region. (For example, Patent Document 6).
* The hydrogen gas and carbon monoxide in the synthesis gas of the present application are almost equivalent in terms of energy, that is, the (higher) calorific value is almost the same. Has taken up the prior literature describing the structure of a rotary piston engine that uses hydrogen as fuel because it is optimal.

A method for producing a synthesis gas by reacting a carbon-containing organic compound with steam and / or carbon dioxide in the presence of a catalyst, wherein the catalyst is composed of a metal oxide as a support, comprising rhodium, ruthenium, iridium, palladium, and platinum. There exists a technique (for example, patent document 7) regarding what uses the catalyst which carry | supported at least 1 type of catalyst metal chosen from these.

The present technique is the prior art document 1,2,3,4,7 fuel as a fuel reforming to synthesis gas of an internal combustion engine also "CO _2" in the exhaust gas by combining any portion Technology (Km / L) improved, “It became a new technology that produces new effects of reducing CO ₂ emissions and preventing global warming.

The biggest challenge is the reduction of “CO ₂ ” (emissions) to cope with global warming.
Inventing one method of measures for that purpose and the mechanism constituting the method.

To solve the biggest problem,
The first invention is
Water (H ₂ O) and carbon (C) react with the exhaust heat of the internal combustion engine to extract a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) (for example, in an endothermic reaction channel) An endothermic reaction facility for steam reforming) and a livestock gas tank for stocking the mixed gas of hydrogen and carbon monoxide taken out, and the mixed gas of hydrogen and carbon monoxide taken out via the livestock gas tank is intended to fuel of the internal combustion engine, the heat absorbing water in an internal combustion engine exhaust heat is primarily water passage in the engine block of an internal combustion engine (corresponding to cooling the coolant water passage of the engine block cooling water) to the steam The exhaust heat used in the exhaust gas pipe and the exhaust heat using the heat in the exhaust gas for the endothermic reaction . The exhaust heat in the engine block and the exhaust heat obtained by the endothermic reaction of the heat in the exhaust gas through the exhaust pipe pipe. Mainly two places as heat sink The present invention provides an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that the exhaust heat is reduced.
Furthermore, further heat can be used for the endothermic reaction by providing means for absorbing the refrigerant compression heat that has been discarded from the air-conduit line using power .
The second invention is provided with either one or both of an absorption means for absorbing carbon dioxide (CO ₂ ) in combustion exhaust gas of the internal combustion engine described in the first invention by water and a separation means for separating the carbon dioxide. A livestock gas tank for livestock gas, and a livestock water tank for stocking carbon dioxide-containing water absorbed in water are installed in one or both of livestock gas and livestock water. Carbon is introduced either together with water into an introduction line for supplying water to the engine block of the internal combustion engine or carbon dioxide-containing water absorbed in the water is introduced into the water introduction line. In the internal combustion engine, water is converted into water vapor by the combustion heat, and carbon dioxide is converted into carbon dioxide as an endothermic gas. The name has been changed to distinguish it from reformation. ) In the reforming channel of the catalyst (for example, other metals or compounds can be used in addition to iron-based metals and / or compounds. Examples of other metals or compounds include zinc, nickel, chromium manganese , Tin, cerium, lanthanum and their compounds, other metals or compounds, etc. ), and a hydrocarbon compound (for example, dimethyl ether) is introduced upstream of the reforming path to absorb the exhaust gas heat. with carbon dioxide water vapor and endothermic gas is brought into contact with the catalyst of the reforming path, to generate a synthesis gas of hydrogen and carbon monoxide (reforming temperature is 200 ° C~500 ° C) the synthesis gas An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that a separate livestock gas tank is provided for livestock gas, and the engine is configured as fuel for the engine via the livestock gas tank. To provide the relationship.

The third invention is a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) taken out by any one or both of the take-out equipment and the reforming path according to the first to second inventions ( modifying the synthesis gas) synthesis gas Aratameshitsuro (e.g. proton conductive ceramic tube reforming passage) provided in the exhaust gas line, wherein the synthetic gas reforming passage into hydrogen (H ₂₎ and carbon monoxide (CO ) And the reaction gas again reacts with the exhaust heat of the internal combustion engine in the synthesis gas reforming path to separately extract hydrogen (H ₂ ) and carbon dioxide (CO ₂ ), and the extracted hydrogen (H ₂ ) and Carbon dioxide is provided as a livestock gas tank by providing a livestock gas tank, hydrogen is used as fuel for the internal combustion engine, and the carbon dioxide is used as carbon dioxide as a starting material to be reformed in the reforming path. Provides internal combustion engines that contribute to reducing greenhouse gas emissions and emissions To do.

The fourth invention is a hydrogen (H ₂ ) and carbon monoxide (CO) take-out facility (for example, an endothermic reaction facility provided in an endothermic reaction channel) or reforming according to the first to third inventions. At least one of a flow path (reforming path for catalytic contact between hydrocarbon compound, water vapor, and endothermic carbon dioxide) or a synthetic gas reforming path (for example, proton conductive ceramic pipe reforming path) is provided. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that the internal combustion engine is mounted on a transportation device and used as an onboard engine of the transportation device.

A fifth invention is the internal combustion engine according to any one of the first to fourth inventions, wherein the internal combustion engine is operated under a certain condition, is generated with the rotational force, is stored in a capacitor, and the electricity is powered. Provided is an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that it has a structure in which an automobile is driven as a source.

The sixth aspect of the invention stops driving the internal combustion engine when the amount of electricity stored in the capacitor according to the fifth aspect of the invention reaches the upper limit set value and runs with electric power, and drives with the internal combustion engine when the amount of charge reaches the lower limit set value. Provided is an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by its structure.

The seventh invention is characterized in that a charging power receiving plug is provided in the internal combustion engine described in the fifth invention, and as a charging means for accumulating electricity in the livestock generator, the electric vehicle is used as a power source to drive the vehicle. To provide an internal combustion engine that contributes to greenhouse gas reduction and emission reduction.

The eighth invention is a means for using the rotational force of the internal combustion engine as described in the first to fourth inventions as it is as the power generation power of the power generator, or reforming the steam that has finished the role of turning the turbine of the thermal power generation. As a heat source, hydrogen (H ₂ ) and carbon monoxide (CO) extraction equipment (for example, endothermic reaction equipment provided in the endothermic reaction flow path) or reforming flow path (hydrocarbon compound, water vapor, and endothermic gas dioxide) or reforming path) to catalyst contact with carbon, or synthesis gas reforming channel (e.g. a proton conducting ceramic tube reforming path), is provided at least one of one or more of, of the internal combustion engine fuel (gas) An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that it is configured as a means to be combined with the existing thermal power generation facility, or is provided as any means provide.

The ninth invention is a manufacturing industry in which any one or more of heat, steam, carbon dioxide or hydrogen is discarded, and any one or more of the discarded heat or steam is used as a reforming heat source. Or combustion of any one or more of hydrocarbon compounds, hydrogen, and synthesis gas and using the combustion heat as a reforming heat source to remove hydrogen (H ₂ ) and carbon monoxide (CO). Outlet equipment (for example, endothermic reaction equipment provided in the endothermic reaction channel), reforming channel (reforming channel in which hydrocarbon compound, water vapor, and carbon dioxide of the endothermic gas are brought into catalytic contact), synthesis gas reforming channel (e.g. a proton conducting ceramic tube reforming channel) or by operating an internal combustion engine as a fuel for the internal combustion engine in the configuration for generating the fuel of at least one of the one or more provided the internal combustion engine (gas) of, Move the rotational force as it is That the generation power of the generator, characterized in, providing that contribute the internal combustion engine to reduce greenhouse gas emissions and emissions according to the first invention to third invention.

According to a tenth aspect of the present invention, the livestock gas means according to the first to fourth aspects of the present invention is the livestock gas tank {synthetic gas tank for endothermic reaction, hydrogen gas tank, carbon dioxide gas tank, reforming channel (hydrocarbon compound with steam and or the carbon dioxide endothermic gas equipped with more than one of the at least either of whether the synthetic gas tank taken out from the reforming passage) to catalyst contact} the upper body of the vehicle, or vehicle to the chassis of the car Provided is an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by being mounted on the vehicle.

The eleventh aspect of the invention is that the livestock gas means described in the tenth aspect of the invention is either a damage prevention means that prevents damage to the tank or a tank separation means that separates the tank from the vehicle installation part in the event of a collision. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by providing either means.

The twelfth invention is one of or both of a carbon-containing compound and a hydrogen-containing compound (for example, sodium hydrogen carbonate, NaHCO ₃ ) using the exhaust heat of the internal combustion engine according to the first to fourth inventions as a reforming heat source. either the processed hydrogen H ₂ or pyrolysis or reformed by the, or carbon C, carbon dioxide reduction CO _2, is taken out at least one of one or more of, and slaughter gas into the slaughtering gas tank, wherein The compound from which the gas is extracted (for example, sodium carbonate, Na ₂ CO ₃ ) is sold as a product, and the extracted gas is used as a fuel for the internal combustion engine or used as a starting material for reforming and fuel. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction characterized by any of the above.

The thirteenth invention is characterized in that the main fuel of the internal combustion engine according to any one of the first to fourth inventions can be hydrogen (H ₂ ), and the internal combustion that contributes to greenhouse gas reduction and emission reduction Provide institutions.

According to a fourteenth aspect of the present invention, there is provided a water storage tank comprising water absorption means for absorbing heat into water from the fuel of the internal combustion engine according to the first to third aspects and the exhaust gas obtained by burning the fuel according to the thirteenth aspect of the invention. The greenhouse effect is characterized in that the water in the water storage tank is warmed by the water endothermic means, and the water vapor in the endothermic exhaust gas becomes liquid water and is separated and recovered by the water recovery means. An internal combustion engine that contributes to gas reduction and emission reduction is provided.

A fifteenth aspect of the invention is a small-scale carbon production apparatus for producing the carbon of the plant described in the first to fourth aspects of the invention. Carbonization chamber CS to be fired, combustion chamber FC for burning plant raw materials such as wood for heating the carbonization chamber, exhaust gas vent of combustion chamber FC, and pipe J of water vapor generating means for converting water H ₂ O into water vapor J Is provided along the inner wall of the carbonization chamber, and the structure is such that the steam generated by the steam generation means and the gas C4 generated in the carbonization process in the carbonization chamber are introduced into the combustion chamber to serve as fuel for heating the carbonization chamber. Or the said 2nd invention technique is provided in the discharge part (chimney) of the said exhaust gas pipe line, the reforming substance is made into dimethyl ether as an example, and the reforming part facing the catalyst is made of dimethyl ether with water vapor or carbon dioxide. Reacting either one or both Providing small carbon maker provided in the either a configuration in which the fuel small carbonization apparatus.

Detailed Description of the Invention

Specific examples of the invention Description of the first invention,
Although it is a take-out facility that takes out a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) by reacting water, (H ₂ O), and carbon (C) with exhaust heat of the internal combustion engine, for example, an internal combustion engine A water passage K is provided in the engine block 1, and either water H ₂ O is converted into steam J or steam is converted into heated steam as steam generating means,
An endothermic reaction channel S is provided in the exhaust pipe MS after the combustion stroke of the internal combustion engine, carbon (mainly carbon C from plants) is introduced into the endothermic reaction channel, and the steam or heated steam , Carbon is reacted in an endothermic reaction channel, hydrogen H ₂ and carbon monoxide CO (synthetic gas) are taken out, and a livestock gas tank MT for stocking the mixed gas of the taken out hydrogen and carbon monoxide is provided. The extracted hydrogen and carbon monoxide mixed gas is used as livestock gas or as the fuel for the internal combustion engine that generates the mixed gas via the livestock gas tank. And
A waste heat using endothermic and water water passage in the engine block of an internal combustion engine (corresponding to cooling the coolant water passage of the engine block cooling water) to the steam in the exhaust heat of the internal combustion engine main exhaust gas pipe Exhaust heat resulting from endothermic reaction of heat in exhaust gas in the road, and exhaust heat from the engine block and exhaust heat resulting from endothermic reaction of exhaust gas in the exhaust gas pipe from two locations. It is a thing characterized by heat, and what should be emphasized is that heat that was cooled with a radiator (discarded using power) was used as a means of steam generation to prevent engine overheat It is.
Furthermore, further heat can be used for the endothermic reaction by providing a means for absorbing the refrigerant compression heat that is discarded from the aircon pipe using power .

This is a take-out facility that takes out a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) by reacting water, (H ₂ O), and carbon (C) with exhaust heat of the internal combustion engine. A water passage K is provided in the engine block 1 of the engine, and either water H ₂ O and carbon are injected under pressure to form water vapor J or water vapor to be heated water vapor as a water vapor generating means. {The pressurizing pressure at this time is about 5 kg / cm ² . (See FIG. 3B)}
Although the present application has a configuration exemplifying steam reforming, the known synthesis gas generation method includes the steam reforming method, and a catalyst (Ni is the mainstream) facing the endothermic reaction channel, which is approximately 200 ° to 300 °. of and the fuel generation unit operable by the heat to the endothermic reaction, drying and reforming and partial oxidation process, there is also autothermal reforming method or the like, adopting a production method of the synthesis gas in place of the steam reforming process of the present You can also.

In view of the energy efficiency of internal combustion engines (about 30% for rotary engines and about 60% of waste (waste) heat available for syngas reaction), it is not enough to produce 100% of the required amount of fuel. In this case, supplementary means for supplementing from other places are provided as supplementary, and as an example of the supplementary means, the present application is provided with an auxiliary tank ST, and fuel in the auxiliary tank (bioethanol mainly made from plant carbon) Or, synthesis gas or hydrogen ) is used as a supplementary fuel when it is not enough to produce 100% of the required amount of fuel.
Ultimately, the carbon is used as a measure to reduce greenhouse gas emissions by bringing the carbon closer to 100% use from the waste.

As an example, the present application adopts a composite fuel system in which a sub-tank fuel and a mixed gas generated in the internal combustion engine are switched and used.
However, if hydrogen H ₂ and carbon monoxide CO (synthetic gas), which are the main fuels, are produced while using the sub-tank fuel, there is no place where the produced gas is livestock gas and livestock gas that is livestock gas. It is necessary to provide means, and the present application is provided with a livestock gas tank for livestock gas means, and hydrogen H ₂ and carbon monoxide CO (synthetic gas) as main fuels continue to be generated even when sub tank fuel is used. We continue to fill the animal gas tank,
Accordingly, when the livestock gas tank is filled up to the set upper limit, the fuel switching valve switches the synthesis gas to use via the livestock gas tank, and when it reaches the set lower limit of the livestock gas tank, the engine structure is provided with fuel switching means that uses the subtank fuel. ,
The reason why the mixed gas generated by the internal combustion engine is used via the livestock gas tank is that the mixed gas also changes the composition of the gas component generated depending on the raw materials and the temperature of the production site. Uniformity is intended.

Second invention The carbon dioxide absorption means (A) for absorbing carbon dioxide in the combustion gas of the internal combustion engine by water or the separation means (B) for separating carbon dioxide in the exhaust gas are provided, A) and (B) are respectively provided with livestock water means and the livestock gas means to feed livestock water and livestock gas, respectively, and either one or both of (A) and (B) above It is introduced together with water into an inlet for supplying water to the engine block (FIG. 1B, H ₂ O inlet) and combustion heat in the internal combustion engine {the combustion heat of the internal combustion engine is a water passage (in the engine block of the internal combustion engine ( It corresponds to the cooling water channel of the engine block cooling water), and water is converted into water vapor.} The water is converted into water vapor, the carbon dioxide is converted into carbon dioxide as an endothermic gas, Reforming channel (carbon dioxide reforming In the reforming flow path of the reforming flow path of the steam reforming in order to distinguish from the steam reforming, as an example, other metals or compounds can be used in combination with iron-based metal and / or compound, Examples of other metals or compounds include zinc, nickel, chromium manganese, tin, cerium, lanthanum and their compounds, other metals or compounds, and a hydrocarbon compound (eg, dimethyl ether) upstream of the reforming path. CH ₃ OCH ₃ ) and the reforming channel of the reforming channel (name changed because of reforming of carbon dioxide) provided in the internal combustion engine together with the water vapor and endothermic carbon dioxide The catalyst is opposed to the gas {hydrocarbon compound (eg dimethyl ether CH ₃ OCH ₃ ) and either water vapor or endothermic carbon dioxide]. It is a structure that generates hydrogen and carbon monoxide syngas by contacting them, and uses it as a fuel for the engine via a livestock gas tank. The detailed explanation of (A) is omitted. }

The reaction formula when the hydrocarbon compound is dimethyl ether is
A. _{CH 3 OCH 3 + H 2 O} → 2CO + 4H 2 -48.9Kal / mol
B. CH ₃ OCH ₃ ++ CO ₂ → 3CO + 3H ₂ −58 · 8 Kal / mol
The reaction temperature is 200 to 500 ° C., preferably 250 to 450 ° C.
The reaction pressure is preferably atmospheric pressure to 10 kg / cm ² .
Many technologies using methane in addition to dimethyl ether as a hydrocarbon compound have been disclosed.

The carbon dioxide absorption means (A) and carbon dioxide separation and extraction means (B) for absorbing carbon dioxide by a known technique,
(A) is disclosed in JP 2010-526759, JP 33455782, JP 2009-77457, JP 2001-213545, JP 2007-177684, and the like.
(B) is disclosed in Japanese Patent Application No. 2001-48591 (Karman vortex), Japanese Patent Application Laid-Open No. 2007-177684, etc.
Prior art of the method for producing hydrogen and carbon monoxide by the carbon dioxide reforming reaction includes Japanese Patent Application Laid-Open No. 08-231204 and Japanese Patent Application Laid-Open No. Hei 11 of Japanese Patent Application Laid-Open No. H11-296275. -106770 etc.
Incorporating this technology into this application, the carbon dioxide in the exhaust gas is “a reforming of the internal combustion engine fuel only into the fuel of the internal combustion engine of this application” is a great greenhouse gas emission reduction measure, A feature of the present invention is that fuel is generated with the discarded energy (approximately 70%, and approximately 60% can be used for reforming), and fuel efficiency is improved by the amount of fuel generation.

Among the inventions of the present application, the carbon C of the synthesis gas generating material when the reforming means for reforming carbon dioxide is used may be carbon C using fossil fuel, and the carbon dioxide is reformed into synthesis gas. Therefore, it is possible to reduce CO ₂ emissions of at least several tens of percent, and this is a measure for reducing greenhouse gas emissions.

3rd invention The synthesis gas reforming path described in the 3rd invention includes a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) produced in the first to second inventions, and an internal combustion engine. The exhaust heat of the internal combustion engine {the exhaust heat of the internal combustion engine is exhaust heat obtained by converting water into steam in a water passage (corresponding to a cooling coolant channel for engine block cooling water) in the engine block of the internal combustion engine}. For example, the exhaust heat of the internal combustion engine (300 ° C. to 800 ° C.) again in the proton conductive ceramic tube (the exhaust heat of the internal combustion engine is exhaust heat obtained by absorbing the heat in the exhaust gas in the exhaust gas pipe) ), Hydrogen (H ₂ ) and carbon dioxide (CO ₂ ) are taken out separately, and a hydrogen livestock gas tank and a carbon dioxide livestock gas tank for stocking the hydrogen and carbon dioxide separately are provided. Carbon dioxide is the water As a starting material for extracting the raw material, the extracted hydrogen is used as a fuel for the internal combustion engine via a hydrogen livestock gas tank.

When exhaust gas temperature in the exhaust pipe is insufficient, an exhaust gas combustion section is provided upstream of the synthesis gas reforming path,
You may introduce and reheat the fuel and oxygen (air) which are the livestock gas of the extent which supplements the shortage temperature to the unburned fuel gas or unburned carbon particle in exhaust gas.

The carbon dioxide reforming is a technique in which a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) is taken out by contacting with a catalyst together with a carbon dioxide and steam reforming material (Japanese Patent Application Laid-Open No. H11-11). 106770) is incorporated into the present application, and carbon dioxide is also used as a fuel for the internal combustion engine, thereby improving fuel efficiency and further reducing greenhouse gas emissions.

The present application introduces carbon dioxide and water into an inlet (H ₂ O inlet in FIG. 1B) for introducing water into the engine block (rotary housing) of the engine for the carbon dioxide reforming. Heat is absorbed in a water passage K provided between the inner and outer walls of the engine block (rotary housing), water is absorbed into water vapor, and carbon dioxide is absorbed to raise the gas to a high temperature and mixed, and a catalyst is placed downstream of the engine exhaust port. There is an opposite reforming path (the name is changed because it is carbon dioxide reforming), and a hydrocarbon compound (for example, dimethyl ether CH ₃ OCH ₃ ) is introduced upstream of the reforming path and the steam and The gas {hydrocarbon compound (eg, dimethyl ether CH ₃ OCH ₃ ) and water vapor or endothermic carbon dioxide, or both} is added to the catalyst together with endothermic carbon dioxide} To remove the mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO), or add the water to steam in the water passage K of the engine block (rotary housing) of the engine. A water passage K ′ of the engine block (rotary housing) of the engine is further provided to be a two-line pipe line for heating carbon dioxide, and (exhaust gas after engine combustion process) It is configured to take out a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO), either by contacting with the catalyst that is confronting the exhaust pipe (including joining near the mouth). For example, the catalyst can be used in combination with other metals or compounds in addition to iron-based metals and / or compounds. Examples of other metals or compounds include zinc, nickel, and the like. Kell, chromium manganese, tin, Seryuumu, lanthanum and compounds thereof, there is another metal or compound.

The reforming temperature of the steam reforming described in the first invention is 700 ° C. to 1000 ° C., preferably 800 to 900 ° C., and the reforming temperature of the hydrocarbon compound (eg dimethyl ether CH ₃ OCH ₃ ) is 200 to 200 ° C. Since the temperature is 500 ° C., preferably 250 to 450 ° C., a steam reforming section is provided upstream of the exhaust pipe, and a reforming section of a hydrocarbon compound (for example, dimethyl ether CH ₃ OCH ₃ ) is provided downstream of the steam reforming section. A synthesis gas reforming path (reforming temperature is 300 ° C. to 800 ° C., the third invention) is provided downstream of the quality, or the synthesis gas reforming path is provided downstream of the steam reforming and further carbonized downstream. It is preferable to take any form of providing a reforming portion of a hydrogen compound (for example, dimethyl ether CH ₃ OCH ₃ ).

In the hydrogen (H ₂ ) and carbon monoxide (CO) extraction equipment, the reforming channel, and the syngas reforming channel, if it is desired to take a longer reaction time, or steam reforming or CO 2 is performed simultaneously. If you want to take more than at least any one-way of the modified or synthetic gas reforming water passage K which is provided between the inner and outer walls of the engine block of the engine (or rotary housing), a plurality in the engine block 1 Whether to provide a structure or multiple exhaust pipes from the engine block (for example, the same number of cylinders, half the number of cylinders, or the same number of pipes as the number of rotors) Alternatively, one or a plurality of exhaust pipes extending from the engine block may be further branched into a plurality of branches and sequentially switched to send exhaust gas) or the water flow At least one of the two systems of pipes for heating carbon dioxide by further providing K ′, and three kinds of pipes downstream of the exhaust port after the engine combustion process A structure in which at least one of the reforming paths is provided and a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) or hydrogen gas / carbon dioxide may be taken out.

Proton conductive ceramics have heat resistance according to the combustion temperature and are provided with continuous vents through which combustion gas can pass. Proton conductive ceramics such as strontium serate-based and zirconate-based belogskite oxide ceramics are hydrogen conductive ceramics. This is particularly advantageous in that it has an action of activating oxygen.

The use of carbon dioxide or carbon as a raw material as a renewable energy source in equipment industries such as the manufacturing industry is a known technique.

Fourth invention An internal combustion engine provided with one or more of hydrogen (H ₂ ) and carbon monoxide (CO) extraction equipment, reforming flow path, and synthesis gas reforming path as a transportation device It is in the form of an on-board engine for transportation equipment, which includes motorcycles, munitions weapons vehicles, munitions weapons ships, and the like.

Fifth invention,
The existing hydrogen rotary piston engine car is used for the internal combustion engine described above. “The engine is operated under good fuel economy conditions (constant conditions) and is generated by the rotational force and stored in the capacitor. The electricity is used as the power source. the form of and is running a car, "as, it is stable combustion heat obtained to be applied to the internal combustion engine, since further be stabilized endothermic reaction conditions, operating the application to" the engine in good condition of fuel and accumulated in the capacitor and generated by the rotating force of the basil and the electric by the structure "be operated as a power source, given rise to great effect to say to improve the greenhouse gas emissions further fuel economy.

* Driving conditions (for example, waiting for traffic lights, waiting for an oncoming vehicle on the right, waiting for crossing pedestrians when turning right or left at the intersection, choco-choco driving in a traffic condition, driving on a flat road, overtaking & overtaking rapid acceleration・ The control mechanism and control structure of the output of the internal combustion engine are simplified and improved by following the changes in the downhill driving, etc.
Furthermore, since driving is performed under a certain condition (good fuel efficiency), there is an effect of improving the fuel efficiency (Km / L).

According to the sixth aspect of the invention, when the storage amount of the capacitor is equal to or greater than the set value, the driving of the internal combustion engine is stopped and the vehicle is driven with electric power.
When the driving state that does not require power continues, the engine is continuously operated under certain conditions (good fuel economy conditions), so depending on the driving state, the electricity generated to drive the car becomes overcharged and is generated by the internal combustion engine. Since the electricity is discarded, the engine can be turned off and the vehicle can run with the stored electric power to improve the fuel consumption.

7th invention The internal combustion engine is provided with a charging / receiving plug and is used as a charging means for storing electricity in a livestock battery. It is expensive to cover all necessary power with a battery by using a structure that allows the vehicle to run using the electricity as a power source. It is not necessary to install a large number of batteries, and the power storage capacity of the internal combustion engine can be increased by several tens of percent. It will be a measure.

Driving conditions that do not require power (waiting for traffic lights, waiting for oncoming vehicles when turning right, waiting for crossing pedestrians when turning left or right, choco chocolate driving during traffic jams, downhill driving, coasting driving, etc.) During this period, the engine is continuously operated under certain conditions (good fuel efficiency). Depending on the driving condition, the electricity generated for driving the car becomes overcharged and the electricity generated by the internal combustion engine is discarded. Therefore, when the storage capacity of the livestock electricity reaches the upper limit set value, the engine is turned off and the vehicle runs with the stored power. When the storage capacity of the battery reaches the lower limit set value, the engine is turned on and the vehicle runs with the engine. The fuel consumption can be improved.

If the electric power is used as the driving power when running in the engine braking state during downhill driving, the motor can be used as a generator.Therefore, when running in the engine braking state, the motor is used as a generator to charge the battery. This will further improve fuel efficiency and reduce greenhouse gas emissions.

This is a repulsive driving run on the flat road, but a repulsive driving run is a speed at which a driver wants to drive for several minutes with an accelerator operation (approximately 2200 revolutions) that is about 10% higher than the speed at which the driver wants to drive. If it is 60Km / H, turning to 70Km / H will turn off the rotational drive power of the engine (this will be about 1000 revolutions, the number of revolutions when idling). Is a driving method that repeats the operation of turning on the rotational driving force connection of the engine when the speed reaches 60 km / H, which is a common driving method in the transportation industry 50 years ago. Automatic control of this travel mode can further improve fuel consumption and reduce greenhouse gas emissions.

Eighth Invention The internal combustion engine endowed by the internal combustion engine is the means for directly using the rotational force of the internal combustion engine as the power generation power of the power generator, or the steam that has finished the role of turning the turbine of the thermal power generation and the newly added mainly plant carbon. Introduced into the reaction channel and converted to endothermic reaction, the generated fuel (gas) can be used as a substitute for auxiliary fuel, and can be combined with the existing thermal power generation facility, or the thermal power generation An endothermic reaction facility is provided in the exhaust gas pipeline of the boiler of the facility to make the endothermic reaction, and the generated fuel (gas) is used as a fuel for the power generation via the livestock gas tank. Also good.

It also can be any one or more of the mixed gas or carbon dioxide or hydrogen in the hydrogen and carbon monoxide using a material obtained by manufacturing elsewhere equipment (or transported in a state of compressed gas in the piping) can correspond, for generating Cases and ships and large vehicles can also be equipped with hydrogen (H ₂ ) and carbon monoxide (CO) mixed gas production equipment in close proximity to the internal combustion engine.

In the ninth invention heat or steam or carbon dioxide or hydrogen manufacturing industries are discarded (e.g., cast-aluminum refining & manufacture and dust incineration forged iron steelmaking iron field, oil refining, etc.), the Any one or more of discarded heat, steam, carbon dioxide or hydrogen is modified by any one or more of the reforming techniques described in the first to third inventions. The generated fuel (gas) is used as the fuel for the internal combustion engine to operate the internal combustion engine, and the CO2 in the exhaust gas of the internal combustion engine is combined with hydrogen by the means described in the second invention. This is an internal combustion engine that is generated in a synthesis gas of carbon oxide and is operated as a fuel for the internal combustion engine, and its rotational force is directly used as the power generation power of the power generator.
For example, in the rolling process of a steel mill, the decarburized crimson steel plate is passed through a number of rolling mills to form a steel plate roll of about 10 mm. The plate is cooled, and the large amount of water applied at this time becomes steam, and a part of it is discarded, and the final rolled steel sheet roll is used for the ceiling crane to hang down in the steel sheet roll natural cooling place. They are lined up in order on a plurality of rows of roller conveyors that have been installed with the required clamping tool operating width. The temperature of the steel sheet roll at this time is 700 ° to 900 °, and the power generation of the motive power generator is performed using the fuel (gas) generated by providing the endothermic reaction section between the roller conveyors to effect the endothermic reaction as the fuel of the internal combustion engine. Using power as a means of reducing electric power will reduce greenhouse gas emissions.

Tenth Invention & Eleventh Invention The livestock gas tank {the tank does not require a high-pressure hydrogen gas storage tank of 35 MPa, and is a fuel necessary for operating at least about 10 minutes with the gas generated by the internal combustion engine. if the a slaughter gas can tank operating the internal combustion engine is a damage preventing means for preventing the tank damage (ignoring the switching loss) be able}, for example, 1 to a plurality of tanks one A shock absorber HPE such as foamed polyethylene and boron fiber reinforced plastic is fixed as a package and fixed and held on the upper part of the vehicle, and the fixing tool fixed and fixed on the upper part of the vehicle with the fixed holding tool MT1. The tank separating means is fixed to MT5. When the impact is applied to the fixture MT5, the V-shaped notch MT6 breaks due to concentrated stress, and the shock absorbing material inclusion MT (The tank support MT2 is integrated) is disengaged from the fixture MT5 (not completely disengaged but is locked to the fixture MT5 or the like with a wire body or the like). body MT3 is the preferred embodiment since the measures to avoid secondary damage fly completely off) has the illustrated structure,
One or both of the damage prevention means for preventing damage to the tank or the tank separation means for separating the tank from the tank installation portion of the vehicle in the event of a collision are provided. Further, it is composed of a non-stationary facility (for example, an automobile) livestock gas tank of the livestock gas means, and the livestock gas tank is mounted on the upper body of a car or mounted on a chassis part of a truck. It is preferable to use one of the forms attached to the stationary equipment, but in the case of stationary equipment (for example, a power plant), the safety standard (in Japan, the registration of JIS B 8265 has been completed. Is ISO 16528), and the non-stationary livestock gas tank and the stationary livestock gas tank (eg chemical factory) It must be composed of those that are within the safety standards or at least have elements that can change the safety standards, so non-stationary equipment (eg automobile) livestock gas tanks and stationary equipment (eg chemical factories) livestock gas tanks function to say that storing the gas can be the same structure (standard) are those completely different.

A twelfth invention for example to make a bicarbonate Natoryuumu (NaHCO ₃₎ and by processing and thermally decomposed in the exhaust heat of an internal combustion engine hydrogen _{(H 2)} and carbon dioxide Natoryuumu _(Na 2 CO _3), carbonate Natoryuumu _(Na 2 CO ₃ ) is taken out and sold as a product, and hydrogen (H ₂ ) is used as a fuel for the internal combustion engine via the livestock gas tank. The sodium hydrogen carbonate (NaHCO ₃ ) is an example as long as it is a product that adds value by use, and is not limited to sodium hydrogen carbonate (NaHCO ₃ ).

The thirteenth invention and the fourteenth invention are configured such that the main fuel of the internal combustion engine described in the fourth invention is hydrogen (H ₂ ),
If hydrogen is the main fuel (of the thirteenth invention), it is an exhaust mainly composed of water and nitrogen (the first invention to the second invention) and the fuel burns hydrogen and carbon monoxide. It is an exhaust mainly composed of water, carbon dioxide and nitrogen, and is an exhaust mainly composed of water, carbon dioxide and nitrogen when hydrogen and carbon monoxide are reformed from carbon dioxide in the exhaust.
Regardless of which fuel is used, the water is discharged in the form of water vapor, and the structure is such that the water of the reforming starting material is warmed from this water vapor by further heat absorption means, and the water is removed from the water vapor in the exhaust gas and filtered. It is returned to the storage tank as water for reforming starting material via filtration means,
The heat absorption means from the water vapor is provided, for example, by providing a water storage tank downstream of the exhaust pipe and passing the exhaust pipe through the water in the storage tank so that the water in the water tank absorbs heat and the water in the water tank is heated. Recovery means for recovering water, characterized in that water vapor in the exhaust pipe becomes water and recovers
The above-mentioned various reforming means reform water into fuel, so a considerable amount of water is required. However, if the on-board amount of water is increased, energy for transporting the on-board amount of water (weight) is required. Therefore, if water is collected and recycled, the amount of on-vehicle water can be reduced, and the water in the water tank can be warm water. This contributes to greenhouse gas reduction and emission reduction.

A fifteenth aspect of the invention is a small-scale carbon production apparatus for producing the carbon of the plant described in the first to fourth aspects of the invention. Carbonization chamber CS to be fired, combustion chamber FC for burning plant raw materials such as wood for heating the carbonization chamber, exhaust gas vent of combustion chamber FC, and pipe J of water vapor generating means for converting water H ₂ O into water vapor J Is provided along the inner wall of the carbonization chamber, and the structure is such that the steam generated by the steam generation means and the gas C4 generated in the carbonization process in the carbonization chamber are introduced into the combustion chamber to serve as fuel for heating the carbonization chamber. Or the said 2nd invention technique is provided in the discharge part (chimney) of the said exhaust gas pipe line, the reforming substance is made into dimethyl ether as an example, and the reforming part facing the catalyst is made of dimethyl ether with water vapor or carbon dioxide. Reacting either one or both Providing small carbon maker provided in the either a configuration in which the fuel small carbonization apparatus.
In the configuration of the small-scale carbon production device, the carbonization chamber CS and the combustion chamber FC are separated from each other, and the carbonization chamber CS section is provided with a generation section for steam J and a separation section for separating carbon dioxide from the exhaust gas. Thus, a heater using a fossil fuel such as coal (for example, a coal stove) can be used.
This means that many cold districts use coal stoves, and carbon dioxide emissions due to coal combustion cannot be ignored. The construction of the first and second inventions of this application Applying this is one of the measures to reduce (emission) “CO ₂ ” to cope with global warming, which is the biggest problem of the present application .

In the combination of the present invention, the carbon C of the synthesis gas generating material when the reforming means for reforming carbon dioxide is used may be fossil fuel use (for example, coal), which is a greenhouse gas emission reduction measure. is there.

The biggest challenge is the reduction of CO ₂ emissions to combat global warming.
By using mainly plant carbon C as a fuel, it was possible to make an internal combustion engine for a greenhouse gas reduction measure that constitutes one of the challenges of the greenhouse gas reduction measure that is the subject of the present application. In addition, CO ₂ generated by the combustion of plant carbon C is also reformed to fuel, and reforming this CO ₂ to fuel also has the effect of further increasing greenhouse gas reduction and fuel efficiency. This is the biggest effect.

The use of an internal combustion engine that generates this synthesis gas and uses the generated synthesis gas as a fuel as an alternative to a thermal power generator is a project that can be mentioned as the first solution to the current energy problem solution (2011) (2011). According to the statistics of the Federation of Electric Power Companies of the year, about 82% of Japan's total power generation is thermal power generation, and there is a request for power saving at the peak of midsummer power demand from each power company) Doing so has a great effect on power supply.

The great effect is that fuel is generated by utilizing the thermal energy that was discarded by the internal combustion engine.

The present application is an alternative to the auxiliary fuel supplied to the internal combustion engine for power generation using the rotational force of the internal combustion engine as it is as a power generation facility, and the endothermic reaction flow of heat, steam or hot water discarded in the manufacturing process, and newly input carbon. Auxiliary fuel, either petroleum liquefied gas (including natural gas), gasoline (including hydrocarbon-based fossil fuel), bioethanol, or synthetic gas, that was introduced into the road and supplied to the internal combustion engine A structure that eliminates the need for a fuel switching control structure including a sub-tank, a sub fuel use control structure, and a switching valve that switches and uses the synthesis gas of the auxiliary fuel, because the livestock gas tank is replaced with the synthetic gas or hydrogen gas of the present application. Is also possible.

The CO ₂ produced by burning the carbon of the plant is also generated in the synthesis gas to further reduce the greenhouse gas CO ₂ from the carbon neutral of the Kyoto Protocol on the use of carbon of the plant. it is possible to reduce the CO _2, produce the maximum effect that Do greenhouse gas reduction measures that could not be carried out in the existing prior art,
Furthermore, even if carbon of the internal combustion engine of the present application is used for fossil fuel, CO ₂ can be reduced by at least several tens of percent even if 100% emission cut cannot be achieved.

While the purchase of greenhouse gas CO ₂ allowances is revitalizing, Japan's purchase amount is estimated to be about 1 trillions of billions, but this purchase amount can be reduced by several tens of percent.

The endothermic reaction efficiency can be obtained by operating the engine under the constant endothermic reaction condition by operating the engine under the “constant and fuel-efficient conditions” (different conditions at start-up) that are not related to the engine load fluctuation described in the fifth invention. The improvement of fuel efficiency (Km / L) is achieved by making the fuel efficiency good and the fuel efficiency is good.

The raw materials for generating the fuel for the internal combustion engine are water H ₂ O and carbon C. The plant that can regenerate the carbon C is used as a main raw material, and further, it is made from materials close to industrial waste that are produced during the production of sewage and food. Substances (e.g. methane gas or bioethanol) are preferred as sub-fuels,

Using the plant as the main raw material means that the plant absorbs carbon dioxide CO ₂ and produces oxygen O ₂ , so in the Kyoto Protocol it is defined as plus or minus “0” (carbon neutral), and global warming This is a great effect that can greatly contribute to prevention.

By providing a cycle for generating carbon dioxide in the exhaust gas into the synthesis gas (second invention) , the “CO ₂ ” discharged from the internal combustion engine of the first invention is reformed into fuel. It is possible to reduce emissions of “CO ₂ ” and to improve fuel efficiency. (For example, it was possible to obtain an astonishing effect of improving 20 Km / L to 40 Km / L or more, not about 20 Km / L to 25 Km / L.
* The above effect could be obtained by providing means for reforming water H ₂ O and CO ₂ into fuel.

A radiator including the engine block cooling water passage and the cooling water piping of the internal combustion engine is not necessary.

The raw materials for generating the fuel for the internal combustion engine according to the first invention are water H ₂ O and carbon C. The plant that can regenerate the carbon is the main raw material, and the plant is the main raw material. sucking carbon dioxide CO _2, since out of oxygen O ₂ in the Kyoto Protocol plus, have been negative "0", a large becomes contribution possible to prevent global warming.

The use of the plant as the main raw material makes it possible to turn abandoned forests and “rice fields” into factories with good “operation rate” to produce valuable things (carbon from plants). This is vital for agriculture and forestry. give.

In thermal power generation, the boiler is heated with thermal power to generate steam, and the steam is further heated to generate electricity by rotating the turbine. Therefore, the energy efficiency is less than 50% and the thermal power boiler is necessary to start heating. Since the initial energy is large, it is difficult to turn on / off following the power consumption fluctuations according to the time zone because it is difficult to turn off the fire for a long time once it is turned on, so depending on the season (spring / autumn) or time zone Surplus power that is not consumed is generated, and the excess production is discarded. However, if the power generation system using the internal combustion engine of the present application is used, the operation may be turned ON / OFF following the fluctuation of the time power consumption. Since it can be made freely, excess production power can be brought to zero as much as possible, so there is no need for a large-capacity power storage facility and a vast amount of power transmission / reception facilities when supplemented only by solar power generation.

Current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of this application do not need to be adjacent to the water source and can be installed as close to the power demand area as possible, so there are very few transmission / reception facilities I can do it.

The proportion of the Japanese economy affected by fossil energy price fluctuations (and exchange rate fluctuations) will be reduced.

The internal combustion engine according to any one of the first to third aspects of the present invention is used for automobiles (including two-cycle two-wheeled vehicles and four-cycle two-wheeled vehicles), marine and railway diesel engine vehicles, construction machinery, munitions weapon vehicles, and munitions weapons. It is implemented in the form of being mounted on a transportation device such as a ship, and the form in which the power generator is used as an alternative to the thermal power generation facility, or steam that has finished the role of turning the turbine in the existing thermal power generation facility, is newly input In an embodiment in which carbon to be introduced is introduced into an endothermic reaction flow path of an internal combustion engine and used for the fuel shortage and merged with an existing thermal power generation facility, or in any one or more embodiments within the ninth invention is there.

Each dimensional relationship in the drawings is enlarged for important portions, exaggerated where details are difficult to understand, and reduced when describing wide portions or portions that are less important in the present invention. Thus, the dimensions between and within the drawings are not proportional, and are not actual or scaled.
If the distance between the lines is narrow, it is likely to become a single line that is black and thick at the scanning stage. Therefore, the distance between the lines is widened or described with a single line.

Furthermore, parts other than the basic (main) mechanism of the present invention are omitted between the drawings.

Hydrogen and carbon monoxide are almost energetically equivalent, that is, the (higher) calorific value is almost the same. Therefore, the detailed description in the specification of the present application refers to a known technique using hydrogen as a fuel. There are many. Furthermore, there are many parts that cite known techniques for the technique of reforming “CO ₂ ” into synthesis gas.
The main structure of this application refers to a variety of known technologies (including some that are patent-registered and alive), but cannot be obtained by individual known technologies alone. In order to obtain the effect in the present application, it was possible to obtain a surprising effect in terms of reducing greenhouse gas emissions and improving fuel consumption.

An endothermic reaction flow path is provided in the engine block of the internal combustion engine, and water H ₂ O and carbon C are reacted with the exhaust heat of the internal combustion engine to take out a mixed gas of hydrogen H ₂ and carbon monoxide CO. It is an internal combustion engine that uses a mixed gas of carbon monoxide and fuel, but any manufacturer thinks that synthetic gas can be used as an alternative fuel to gasoline, light oil, heavy oil, etc., but hydrogen also Carbon monoxide is also very dangerous (explosive and toxic). Therefore, liquefied transport means (portability). The ratio of the volume of the liquefied gas to the weight of the container that satisfies safety standards is poor. I suspect that there was an explosion problem caused by the wreck, and I couldn't get it.

The means of the present application to solve this problem are:
* Instead of filling the tank with fuel consumption and supplying all the fuel required for driving, a subtank is provided to replenish the energy loss during the fuel generation process, and the fuel in the subtank is used for petroleum liquefied gas (including natural gas) ) Adoption of a composite fuel supply structure that uses gasoline, hydrocarbon-containing fossil fuel bioethanol, etc., or synthetic gas as a supplementary sub-fuel for the energy loss (this stored gas pressure) The installation position of the livestock gas tank in consideration of the above and the means of the structural part that can cope with an accident such as a car being severely damaged) are the main points that made the present application "practical plan"). (See Figures 1 and 2)

The storage gas, the synthesis gas generated in the livestock gas tank is stored in a certain amount (in the state of compressed gas), while the certain amount is accumulated, butane gas, gasoline, (including hydrocarbon-based fossil fuel) methane gas, bioethanol, etc., or Any of hydrogen, synthesis gas, reformed gas from plants, methane gas from plants, bioethanol of bioethanol, etc. is used as the storage gas in the auxiliary fuel tank, and the amount of generated synthesis gas is constant. And switch to synthetic gas, use synthetic gas in livestock gas tank while generating synthetic gas, and switch to using auxiliary fuel tank when the tank capacity is close to "0". Means to reduce the amount (including tank weight),

An example of a known technique for converting carbon dioxide to hydrogen, carbon monoxide, etc. in the presence of a catalyst is described in Japanese Patent Application Laid-Open No. 11-106770. In the description, a method for producing a synthesis gas by reacting a carbon-containing organic compound with steam and / or carbon dioxide in the presence of a catalyst and a catalyst suitable for the method are also disclosed. Is also used as a technology for reforming fuel.
Japanese Patent Application Laid-Open No. 2007-177684, a carbon dioxide recovery device for a vehicle, and a vehicle equipped with the same discloses that carbon dioxide is absorbed by a carbon dioxide absorber and carbon dioxide is recovered.

The main sources of greenhouse gas emissions are emissions from internal combustion engines and thermal power generation boilers, which account for about 82% of Japan's power generation (2012 Electricity Federation statistics). And 1/4 of the world ’s emissions from thermal power boilers,
The amount of CO ₂ released when 1 gallon of gasoline is burned is about 9 Kg combined with emissions from the car engine and emissions from the gasoline production process.
Therefore, in order to shift the consumption of carbon C from fossil fuels to carbon C from plants and achieve a 25% reduction in greenhouse gas CO ₂ emissions early,
It is necessary to implement an internal combustion engine for the greenhouse gas emission reduction measures of the present application and to make the procurement cost of carbon C, which mainly consists of fuel, the same as the procurement cost from fossil fuel.
The production of carbon C as fuel changes when carbonized organic material is heated while shutting off the flow of air and oxygen, and changes to a material rich in black carbon. This process is called carbonization, and charcoal produces this carbonization. This is a good example of a product, and what is produced is an aggregate composed mainly of amorphous oxygen and the like, and is mostly porous and has a very large surface area. Heating causes dehydration and dehydrogenation reaction to produce a condensed polycyclic aromatic compound, which further forms a network structure, which is called carbonization.

The technology to make solid carbon C from wood (nano-plant raw material) into nanoparticles is not yet a new technology because it has already been broadcast on TV, etc., but micronization (100 (About a micron) can be dealt with as the carbon C of claim 1 of the present invention.
If the solid carbon C is pulverized into fine particles, the surface area where the reaction takes place is increased. Therefore, the finer the particles, the more efficient the synthesis gas generation.
It can also be handled by adding water to the carbon C to form an emulsion fuel or gel.
Furthermore, the above-mentioned wood and the like (plant raw material C) is heated in an environment where oxygen does not enter, and carbon C gas can be obtained in the carbonization step.

It is a cycle in which steam in the engine → endothermic reaction in the exhaust line → synthesis gas or hydrogen of carbon monoxide and hydrogen or hydrogen is used as fuel for the engine.
* The proposed matter is that the livestock gas tank has a large internal volume, low pressure accumulation, a tank that can be built, where the vehicle is located, and what structure is used. It was possible to make a structure that does not.
* The above-mentioned proposed matter was solved with the following structure.
1. The place where the synthesis gas tank is installed is located in the upper part of the car body or in the chassis part of the car. Even in an accident that is sandwiched between and crushed, the livestock gas tank is required to have a tank that does not explode, but the target hydrogen that can run 500Km in a cylinder that can be mounted on the vehicle is 4MPg of hydrogen and 20MPa. The pressure requires 300L of container volume,
Mazda (Company name) Premasi Hydrogen RE hybrid vehicle equipped with 74L / 35MP of hydrogen can run only 123Km with full tank filling, so it can not run only with hydrogen, so to run 500Km, about 4 times 300L A / 35 MPa hydrogen tank is required, but in order to cover 300 L of hydrogen with a 74 L / 35 MP container, a container that can be filled with about 150 MPa compression is required, which is difficult with the current technology.
Therefore, it was planned to generate synthesis gas in a mounted internal combustion engine. However, in a pressurized pump with a mounted structure, if the compression pressure is increased, more power is consumed for the pressurized pump. At the start, the gas was accumulated with equipment equivalent to an accumulator of hydraulic equipment, but the car fell from the cliff due to an accident on the highway where the livestock gas equipment should be installed. If the accident is such that the car is flipped upside down or the passenger car is sandwiched between large trucks and crushed in a sandwich, the structure must be such that an explosion can be avoided when such an accident occurs. I gave up on board.
If you are searching for related documents on the Internet and searching for prior literature for planning other projects using synthetic resin, the following foamed polyethylene, (the above-mentioned member has anti-bullet properties and is used for military weapons, (As an example, polyethylene fired polyethylene is fixed to the outer surface of an army water hoat for army movement, and when it is sniped with a rifle etc., the bullet has a bullet-proof property that does not allow a hole to be made in the rubber hote) Can be found, and if this was used, it was able to solve even the place where it did not explode even if the accident occurred. However, the problem was the location of the last remaining tank.
While considering the eco-driving method filed last year and thinking about what to do with resin to reduce the weight of the car, when considering the roof of a passenger car, the livestock gas tank of the present application that had been neglected was used for the roof of the car The structure of this livestock gas tank is the key point of the present application. (See Figure 1A and Figure 2)
2. As shown in FIG. 2, the outer surface of the livestock gas tank is made of poron fiber reinforced plastic or foamed polyethylene. (The above-mentioned members are bullet-proof and are used for military weapons. The fired polyethylene is fixed on the outer surface of the water hoat for moving the water surface, and when it is sniped with a rifle, etc., the bullet has a bullet-proof property so that a hole cannot be made in the rubber hoat)) A tank separation means is provided that separates from the car body when it is impacted by falling or severely damaging the car. It has a structure that does not explode even if it bounces off. (It is preferable to provide a locking structure that does not jump too far.)
3. As an example of the separation structure of the tank inlet / outlet pipe from the vehicle body, the solenoid valve contact configuration is ON when energized. When the solenoid valve sequence circuit is turned off when not energized, and the synthetic gas tank is subjected to an impact force flying from the body of the car, the gas inlet / outlet pipe of the tank may come off (or be damaged). The gas pipeline from the tank is closed. (See Figure 2.H)
4). As for the problem of compression pressure of livestock gas, if the configuration of Mazda (Company Name) Premasi Hydrogen RE hybrid vehicle, which uses auxiliary fuel, the eco-driving method and the internal combustion engine of the last year's application only generate electricity, is the first of the present application. Combining the sixth and seventh inventions with the detailed explanation part of the invention in addition to the reforming technology of the invention from the third invention, the synthesis gas alone or only the hydrogen or synthesis without using auxiliary fuel An embodiment which may be used by switching between gas and hydrogen, and the stored gas pressure can be handled with a low compression pressure as described in the next paragraph.

In order to cover the fuel necessary for running 500 km with gasoline with hydrogen (synthetic gas), 5 kg of hydrogen (equivalent to 56,000 L of hydrogen) and (10 g / Km = hydrogen of 11.2 L).
Therefore, the capacity of a livestock gas tank for fuel (hydrogen, synthesis gas, carbon dioxide) required for about 10km travel is a livestock gas tank capable of livestock gas of 11.2L * 10 = 112L (normal pressure) if the fuel switching loss is ignored. It will be good if there is.
Therefore, it can be designed freely as long as it is within the scope of the law and the relationship between the tank manufacturing cost and the installation space and the switching cycle to be set.

A synthetic gas storage gas tank produced from the internal combustion engine according to the first to third aspects of the invention is provided in the upper part of the vehicle, and an impact buffer (fired polyethylene, boron fiber reinforced plastic, etc.) is fixed to the gas storage tank. A storage tank that protects against explosion or explosion in the event of a car wrecking by fixing either a coating or a multi-layered structure to the storage tank.

Referring to FIG. 1, the vehicle shown in FIG. 1 is a schematic configuration diagram in which the structure of the present application is installed in a commercial vehicle front engine type commercial vehicle, and an exhaust pipe from a hydrogen rotary piston engine (internal combustion engine) installed in the front engine room. The endothermic reaction synthesis gas generation section provided in the section generates gas, and the extracted synthesis gas is stored in the storage tank MT provided in the upper section and used as fuel for the hydrogen rotary piston engine. In the schematic configuration diagram, switching the loss to the fuel of the sub tank ST,
FIG. 1B is a schematic configuration of an engine block, a synthesis gas generation endothermic reaction flow path section, a fuel supply / injection system, and a spark plug of a reciprocating engine. a schematic configuration flow diagram parts and the fuel supply and injection system ignition plug, the water HO ₂ into the engine block of a four cylinder reciprocating engine provided with a water passage K of the steam J, water H _{2 O} (or water and carbon dioxide) is supplied from the supply port steam generating unit (or / and carbon dioxide heat absorbing means) and bookmarks, intake air 0 ₂ is provided for supplying duct 3 air 0 ₂ to the inlet port a _P are supplied to the mouth a _P, the exhaust port from E _P at the conduit 4 is connected to the exhaust pipe of the synthesis gas production unit, endothermic of said exhaust pipe MS syngas product endothermic reaction portion in the exhaust pipe Reaction tube It is provided in a coil shape, and the steam J generated in the engine block of the reciprocating engine is introduced into the coiled endothermic reaction tube and carbon is newly introduced, and the exhaust gas of the synthesis gas generation unit flowing MS to the tube, to produce the exhaust gas E _X of the exhaust heat in the synthesis gas CO + H ₂ generated in the engine combustion stroke, produced synthesis gas by livestock gas in the synthesis gas storage tank (slaughtering gas tank) MT In order to make up for the shortage of the generated fuel, a sub tank ST is provided to store the sub fuel. The sub tank fuel and the synthetic gas stored in the live gas tank are switched by the switching valve CB, and the fuel supply line 5 FIG. 2 is a schematic configuration diagram of an internal combustion engine that is supplied to the injector E _C H ₂ and has a configuration in which a plug P for forced ignition is provided.

A water passage K for converting water HO ₂ into water vapor J is provided in the engine block, water H ₂ O is supplied from the supply port, and in addition to the water passage K serving as water vapor generating means, air passage K for heating CO 2. 'And a CO2 supply port are provided, and at least one of the plurality of exhaust pipes is supplied to a pipe for reforming CO2, and one of the other pipes for reforming CO2 is supplied. Whether it is a pipe for steam reforming or a syngas reforming path of the third invention, the steam J is supplied to all or a plurality of pipes, and the pipes K, K ′ as required. It is also possible to add a configuration in which a supply path for switching the supply from both is switched to either.

FIG. 2A. 1 is a cross-sectional view taken along the line AA in FIG. 1. As an example, this figure shows a synthetic gas tank having four cylindrical MTBs, and a single package made of a shock absorbing material such as foamed polyethylene, boron fiber reinforced plastic, or the like. In the state where the vehicle is fixedly held on the upper part of the vehicle, and is fixed to the fixture MT5 that is fixedly fixed to the upper part of the vehicle with the fixed holding fixture MT1. The V-shaped notch MT6 breaks due to concentrated stress, and the shock absorbing material inclusion MT3 (for example, the tank support MT2 is integrated) is detached from the fixture MT5 (completely disengages). (It is a preferable form to take a structure in which it is locked to the fixing device MT5 or the like with a thread body or the like, because this is a measure for avoiding the secondary damage in which the inclusion body MT3 of the shock absorbing material completely comes off))

As an example, when a collision or falling force is applied to the tank, a holding structure in the event of an accident is provided, and a structure (part of which is preferably connected to the car) is provided. The tank that flies off from the vehicle is made of foamed polyethylene, boron fiber reinforced plastic, impact buffering material (HTP), etc., which is provided on the outer surface of the tank and fixed to the entire surface, and absorbs or diffuses impact force. So it does not explode.
The foamed polyethylene, boron fiber reinforced plastic, and shock-absorbing materials that are fixed to the entire surface of the coating or the entire surface may not be expensive at this time, but they are produced almost 20 million units / year (by the entire Japanese automaker). The cost is reduced due to the effect.

FIG. FIG. 6 is an example of a tank mounted on a rear engine vehicle in which the shock-absorbing material MT3 is mounted perpendicularly to the traveling direction; E. The figure shows that there are no restrictions on the number and shape of the tanks. E, the tank is housed in the front and rear recesses on the roof of the car, and the aesthetics from the side are improved. F. Is a type with an engine mounted under the cabin. The shape installation direction of the gas tank MTB and the tank package MT3 to be mounted is a design problem in the relationship between the tank capacity to be installed and the gas pressure.

FIG. FIG. 5 is a partial cross-sectional view of the structure of the gas inlet / outlet portion when there is only one gas tank MTB, and the gas taken out from the synthesis gas generator S is a tank open / close valve GTbsec (for example, the electromagnetic valve is turned on when energized and turned off when deenergized. It is a schematic diagram of a structure in which gas is stored in a tank via a contact circuit) and introduced into the fuel switching valve Cb of the engine. If the force is applied to the tank and the gas storage tank comes off, the electrical wiring will be disconnected and the electromagnetic valve will be turned off so that the gas in the tank will not leak.
2 and I are. A reverse J-shaped locking and fixing structure KRsec having elasticity is provided at both ends of the fixing device MT5 fixedly fixed to the upper part of the vehicle. (Lower view) When the car is severely damaged, the reverse J-shaped This is an example of a structure (upper view) in which the reverse J-shaped locking function part of the locking structure KRsec extends and the HPE body is detached from the upper part. As long as the HPE body has a function of separating to the upper part, it does not stick to metal, synthetic resin, other, material and shape.
It is preferable to provide a carbon dioxide livestock gas tank and a hydrogen livestock gas tank in the structure of the livestock gas tank.

Although the above-mentioned supplemental described, the synthesis gas produced by the steam reforming is a schematic substance amount 1 of CO and H _2: a mixture of 1. Since the gas volume is proportional to the amount of the substance, the amount of carbon monoxide = the amount of hydrogen and the gas has a volume of 22.4 L / mol in the standard state. (Transfer efficiency of liquid hydrogen: high pressure hydrogen = 6: 1) Hydrogen is 39 g per liter (weight in tank of 700 atm).
The gas generated by the CO ₂ reforming is described in the paragraph of the second invention, but when the reforming substance is dimethyl ether as an example, the dimethyl ether is either water vapor or carbon dioxide, or both. In addition, if you react,
A. In the case of CH ₃ OCH ₃ + H ₂ O → 2CO + 4H ₂ −48.9 Kal / mol water vapor
B. In the case of CH ₃ OCH ₃ ++ CO ₂ → 3CO + 3H ₂ −58 · 8 Kal / mol carbon dioxide
C. In the case of both 2CH3OCH3 + H2O + CO2-107.7 Kal / mol become that way.
* Hydrogen properties, diffusion is quick and easy to leak, high reactivity, and especially brittle metals including steel.

FIG. 3A. FIG. 1A is a cross-sectional view in the front-rear direction of FIG. 1A, and a description of the hydrogen-compatible structure of the rotary piston engine is shown in FIG.
Rotary piston engine A water passage K that makes at least a half turn between the inner wall and the outer wall of the rotary housing is provided, and water is supplied from one water introduction pipe to the water passage K between the inner wall and the outer wall of the rotary housing. The water is sent to the endothermic reaction channel S through the carbon C insertion tube, and the water becomes steam J in the process of passing through the water passage that contacts the intake → compression → explosion → exhaust process part with the combustion heat of the fuel. The
Air O ₂ is sent into the other rotary piston engine, and then the fuel synthesis gas MTC or subtank ST fuel (any of butane, biofuel, synthesis gas, etc.) is sent into the engine, → compression → explosion → exhaust E _X next to be fed to the endothermic reaction flow path portion S, the exhaust E _X flows through the tube center portion of the endothermic reaction channel section S, carbon inserted with steam J thermal reaction channel is in the description of FIG. 3 flow synthesis gas generator tube provided in a coil shape in contact with the tube wall of the tube MS, the tube in the heat of the exhaust E _X flowing a central portion is generated in the synthesis gas is withdrawn from the take-out tube is transferred to savings gas tank MT FIG.
The explanation structure of FIG. 1B and FIG. 3 is applied to the structure of the water passage / ventilation path of the rotary housing corresponding to CO2 reforming and synthesis gas reforming.

FIG. 3B. FIG. A mixture of water vapor J and carbon C is fed into a water passage K between the inner wall and the outer wall of the rotary housing into the water (H ₂ O) introduction pipe portion of the water and comes into contact with the inner wall surface of the thermal reaction channel pipe MS in a coil shape the synthesis gas production tube provided in the flow, which is the tube structure schematic diagram central portion is generated heat in the synthesis gas in the exhaust E _X flowing retrieved from the take-out tube is transferred to savings gas tank MT.
The structure of the water passage / ventilation path of the rotary housing corresponding to CO ₂ reforming and synthesis gas reforming also applies the explanation structure of FIG. 1B to FIGS.

Figure 4 is provided to the synthesis gas production pipeline provided in a coil shape in contact with the tube inner wall surface of the thermal reaction flow pipe MS of FIG. 3 in a thin tube of a straight, exhaust between the thin tube and the thin tube E _X The design of the endothermic reaction flow path has been put to practical use in a system that makes the exhaust gas harmless by confronting the catalyst in the exhaust gas treatment system. good.

FIG. 5 is a schematic view showing a hydrogen rotary piston engine disclosed in Japanese Patent Application Laid-Open No. 2007-2111608.

FIG. 6 is a diagram showing a main configuration of an electronically controlled injection structure of a hydrogen rotary piston engine. The electronically controlled injection valve needs to inject a large capacity of 2300 NL / min in order to obtain an output of 100 KW, for example. The two injection valves 40 and 42 in the above figure are provided to inject a large volume.
Further, a large-capacity intake port 16 and an exhaust port 18 are provided on the side of the rotor housing, and the explosion chamber is divided into two when it is about to explode, and two spark plugs 14 and 15 are provided.

In recent years, hybrid vehicles and 100% electric vehicles have attracted attention.
However, if most of the automobiles are used as electric energy, there is a problem of the “Fukushima nuclear power plant” that overwhelms the power supply situation to follow the speed of electrification including home appliances, and the expansion of the power supply facilities is solved quickly It is an issue that should be done. However, the public disagrees with the current situation regarding the construction or restart of nuclear power plants, as the burden of electricity charges will increase if the nuclear power plant is abolished. I understand that there are many, and further public opinion is toward the direction of damming. Therefore, expansion of power supply facilities is a desperate situation that the weight of things by thermal power generation and natural energy becomes very high . Therefore, expanding the power generation facilities that suppress CO ₂ emissions is a problem that should be solved immediately.

In recent decades, cheap timber has been imported from foreign countries, the number of forestry workers has decreased dramatically, the forest has not been thinned, and dead trees devoured by pests such as pine wilt have been left unattended.
Furthermore, it is the vitalization of agriculture, but most of the “rice fields” have agricultural waterways, which have been fertilized for many years and have become fertile farmland. For example, “Kenaf”, which is a pulp material, and “Mulberry” in sericulture can be planted in this “rice field”, or “Yukari” from Uruguay in South America can be used. One plan is to use a small-scale carbonization device (see Fig. 10) that can be carbonized by a farmer with a single hand for lending use (lease method). For example, if the carbonization equipment that is cheaper with the price of the carbonized equipment is purchased in a five-year split, for example, a small scale that allows more forestry workers and farmers to use the purchased money with one hand. ”Carbonizing equipment” It is also possible to plant a thing that can become “bioethanol” that grows well in places where water supply is sufficient, such as taro.

The goal of reducing greenhouse gas (CO ₂ ) emissions by 25% by 2020 is being asked, and Japan's CO ₂ emissions are struggling to see how the world can reach this goal. The main players in this project are emissions from internal combustion engines and emissions from thermal power boilers, which account for about 82% of electricity generation (2012 Electricity Federation statistics). These CO ₂ starts with coal, oil and natural gas. Fossil fuels such as coal, oil, and natural gas are limited resources, and of course, resources that cannot be reproduced.

According to the Kyoto Protocol, carbon dioxide CO ₂ produced by the combustion of plant carbon C is consumed by plant carbon assimilation, so it is a plus or minus zero and is not counted as CO ₂ emissions. Therefore, in order to shift the carbon consumption of fossil fuels to plant carbon and achieve a 25% reduction in greenhouse gas CO ₂ emissions at an early stage, it is best to realize the above-mentioned synthesis gas generation cycle plan. think. (According to 2010 data from the Ministry of the Environment, greenhouse gas CO ₂ emits 30.3 billion tons worldwide, Japan is 3.8%)

The day when solar power generation (system using solar power generation panels, condensing sunlight, generating steam with heat → power generation) will become the mainstream of future power generation is not far away. However, solar power generation is not possible 24 hours full-time power generation at night, rain, and cloudy, and if it is installed on a large scale, it will be quite remote from the power usage area, so it will install new substation and transmission equipment The disadvantage is that large-capacity power storage equipment is necessary to cover only with solar power generation, and if it is a place with a good sunshine rate (for example, a desert with low annual rainfall is the leading candidate), a large amount of power transmission / reception equipment is required. (There is superconductivity invented by Japan in the above-mentioned large-capacity power storage equipment, large-scale power transmission / reception equipment, the experimental plant is already in trial operation, and the international standard of 1,100,000V was also established in 2008. Although it has just gained international approval, the gap with the estimated cost is a problem).
Therefore, if the internal combustion engine power generation of the present invention that can be operated for a short time other than the solar power generation time is used in combination with the fuel production mechanism of the present invention, it can be said that the reduction of greenhouse gas CO ₂ emission can be achieved earlier. .

Whether or not the procurement cost of carbon C as a fuel can be reduced holds the success or failure of practical use of the present application. In carbon production, when carbonized organic substances are heated with the air and oxygen flow cut off, they turn into black carbon-rich substances. The resulting product is an aggregate mainly composed of amorphous oxygen and the like, and is mostly porous and has a very large surface area. Heating causes dehydration and dehydrogenation reaction to produce a condensed polycyclic aromatic compound, which further forms a network structure, which is called carbonization.
Carbon charcoal used as a fuel while performing many operations such as thinning, pruning and undercutting. It is a concrete proposal that is a shortcut for realizing the present application to sequentially lend carbon production equipment that has a structure that can be handled in a procurement manner (subject to substituting for subsidies).

FIG. 10 is an assumed schematic diagram of the above-described small-scale carbonization apparatus. Carbonization plants suitable for the carbon material of the present application are placed in the carbon production chamber CS, and the combustion chamber FC serving as a pot door is approximately half carbonized of the carbon material of the present application. By burning the timber plant and collecting it in the collection area in the form of carbon C, it is possible to reduce the transportation cost much more than transportation with branch wood,
Fuel for heating (plants such as wood, etc.) that heats the carbonization chamber by introducing wood into the carbonization chamber CS that heats and carbonizes plant raw materials (wood, etc.) in an environment that does not contain oxygen The raw material or other combustible material) is introduced into the combustion chamber FC where it is combusted and combusted. From the gas C4 generated in the carbonization process in the carbonization chamber and the inner wall of the carbonization chamber, the exhaust gas exhaust line of the combustion chamber FC and the water tank A structure is provided in which a pipe for steam generation means for converting the introduced water H ₂ O into steam is provided as a fuel for heating the carbonization chamber by introducing it into the combustion chamber through the introduction pipe C4 together with the gas C4 generated in the carbonization process. To

The reforming part (CO ₂ reforming) having the structure described in the paragraph of the second invention is provided in the discharge part (chimney) of the exhaust gas pipe, and as an example, the reforming substance is dimethyl ether, and the catalyst If the reforming section is made to react with either dimethyl ether or one of water vapor or carbon dioxide to make the fuel of the small-scale carbonization device, the fuel consumed for carbonization is further reduced. Reduction of effect gas emissions.
Furthermore, by using a reforming section (CO ₂ reforming), it is possible to use fossil fuels such as coal, and it is possible to use it as a starting reforming material that reforms wood, etc., used as fuel into plant raw material C.
As an example, the catalyst can be used in combination with other metals or compounds in addition to iron-based metals and / or compounds. Examples of other metals or compounds include zinc, nickel, chromium manganese, tin, cerium, lanthanum, and the like. These compounds, other metals or compounds.

The synthesis gas described above is not limited to hydrogen and carbon monoxide. The synthesis gas represents a main component, and includes, for example, unburned carbon, carbon dioxide, moisture, and other gases and impurities present in the atmosphere. This includes cases where

The procurement cost of carbon (plant raw material C) is currently higher than that of natural gas (methane, butane, etc.), coal, and petroleum fossil fuels. Until it is obtained, or the law of strengthening the emission control of greenhouse gas CO ₂ is made, the procurement of carbon will be done with natural gas (methane etc.) or directly with natural gas (methane etc.) as fuel and the whole society There is also a way to switch when the desire for carbon increases and the cost of carbon procurement can be paid,
However, I think that the speed of progress in chemical technology is progressing in proportion to "needs",
Therefore, if the need for procurement of renewable carbon C, which is the main raw material of the present application, becomes high, we are confident that the procurement technology will evolve with acceleration.
The carbon used in the internal combustion engine cycle of the present application is the cheapest to use “coal” as powder for the time being, so the fossil fuel will be used until the renewable carbon C procurement system is complete. It will take the form of shifting to a carbon C procurement system that can be sequentially regenerated.

The amount of purchase of greenhouse gas CO ₂ emission allowances in Japan is estimated to be about 1 trillions of billions of yen. If this purchase amount is used as part of the carbon procurement cost, the time of realization of the present invention will be explained. Will be faster.
* If transportation from a chemical factory, steel factory, aluminum factory, dust incineration plant, etc., is carried out using a mixed gas of hydrogen and carbon monoxide, carbon dioxide, hydrogen, etc., the transportation cost will be much lower than transportation using transportation equipment. I can do it.
Each US and European country has a hydrogen transport pipeline of thousands of kilometers, and should be realized early with the support of the government in order to survive the world as a competitor.

The power generation facility powered by the internal combustion engine of the present application is a relatively small-scale power generation facility. Because it can be a decentralized power generation system with self-sufficiency in units of mass such as remote islands, mountainous remote areas, industrial parks, submarine transmission cables and power demand It is possible to drastically reduce power transmission facilities, power transformation facilities, and power reception facilities that respond to changes in power consumption.
Furthermore, the current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of the present application do not need to be adjacent to the water source, and have the advantage that they can be installed as close to the power demand area as possible.

When methanol is used as a fuel for an internal combustion engine, methanol is originally synthesized from hydrogen and carbon monoxide at a high pressure advantageous from chemical equilibrium. Therefore, it is most efficient in terms of energy to use it in the form of synthesis gas of hydrogen and carbon monoxide, rather than converting it to hydrogen.

Although transportation of compressed hydrogen and liquid hydrogen is carried out, in order to compensate for the problem that the volume storage density of hydrogen gas is small, hydrogen is pressurized to 14.7 to 19.6 MPa and transported as compressed hydrogen. Mo steel hydrogen container is heavy. For example, a trailer vehicle that transports 100 kg of hydrogen requires 7 tons of hydrogen container. To reduce the cost of transporting compressed hydrogen, aluminum alloy liners and high-density polyethylene liners are used. It is necessary to make a tank reinforced with glass fiber or carbon fiber,
Under current regulations (in Japan, registration of JIS B 8265 has been completed and internationally there is ISO 16528) CFRP for transportation (tank with high-density polyethylene liner reinforced with glass fiber or carbon fiber on the entire surface) ) Since the container has a pressure of up to a capacity of 35 MPa, it is necessary to relax regulations in order to utilize the container. (Japan Industrial Gas Association, hydrogen gas container standards)

On the other hand, liquid hydrogen has a volume storage density 800 times higher than that of hydrogen gas, and tank trucks or insulated containers are used. However, liquid hydrogen requires energy for liquefaction and has a boiling point of −253 ° C. and evaporation loss. There are disadvantages that occur.

The internal combustion engine of the present invention uses synthesis gas as fuel, and the synthesis gas is a pipe supply in an automobile, and the accumulation pressure of the livestock gas tank for livestock synthesis gas produced by the internal combustion engine is the above-mentioned existing hydrogen There is no need to use a 35MPa livestock gas tank of compressed gas installed in the engine car, and it may be about 1/40 of the accumulated pressure, and the energy used for the pressurizing pump can be saved as much as the accumulated pressure can be reduced. The gas storage tank structure can also be a structure of at most several MPa within the current regulations.

Pipeline transportation is optimal for steady mass transportation of hydrogen, and the synthesis gas of this application is similar to hydrogen in Europe and the United States. It is the best way to do it.
As the pipe material of the hydrogen pipeline, in the current advanced technology, if it is a sour-resistant material with a reduced amount of vanadium and a small amount of nickel or chromium, compared with ordinary line pipe steel, it can be used in a normal transportation environment. It is said that the cost can be increased to 10% or less.

The rotary engine vehicle powered by hydrogen is a Mazda Premacy Hydrogen RE hybrid vehicle that has a structure that can be selected to travel using either hydrogen as fuel or gasoline as fuel. A high-pressure hydrogen fuel tank (35MPa, 74L) And a gasoline tank is mounted on the vehicle, electricity is generated by rotating a hydrogen (or gasoline) rotary engine and stored in a lithium ion battery, and driving of the wheel is electricity stored in the battery,
The feature of this car is that the engine is operated with good fuel economy, and the control of the vehicle speed fluctuations depending on the running state of the car is electric control.
Disadvantages include a short mileage of 100 km in a high-pressure hydrogen fuel tank, and the hydrogen transportation means (assuming transportation by car) has a poor ratio of hydrogen loading weight to the tank weight, leading to the development of infrastructure such as hydrogen stations. There are no points and high hydrogen production & transportation cost.

The hydrogen engine bus developed by Tokyo City University, which uses hydrogen as fuel, is loaded with six tanks compressed to 35MPa on the roof. The main improvements in the engine are the addition of an intake manifold, hydrogen injection valve and spark plug.

A hydrogen reciprocating engine and a wagon type Musashi 10 developed and developed by Tokyo City University using hydrogen as a fuel, is a hydrogen engine with a hydrogen cooling intercooler, equipped with a tank of 100 L of liquid hydrogen and continuously running at 300 Km per charge. It is a car that made it possible.
Disadvantages of the above-mentioned existing vehicles that use hydrogen as a fuel are that the ratio of hydrogen loading to the tank weight of the hydrogen transport means (assuming transport by car) is poor, the infrastructure development such as the hydrogen station does not progress, and the hydrogen production cost It is a high point.

The hydrogen rotary piston engine Mazda (company name), and generating the hydrogen H ₂ as a fuel, since by rotating the motor in the electric can use the power component as power generators, dwell as a power generator generating The components are applied to the internal combustion engine of the present application.

In the case of the power generation equipment in the previous paragraph, steelworks, chemical factories, aluminum manufacturing factories, foundry factories, forging factories, garbage incinerators, and oil refineries that use synthesis gas and hydrogen as by-products or dispose of a large amount of heat. in Toka place, further running costs by installing the power plant adjacent or close to is reduced.

In the case of the internal combustion engine power generation equipment of the present application, a relatively small scale power generation equipment (if the internal combustion engine power generator is assumed to have an output machine of 1000 KW / H as 1 unit / unit, 1 unit to several hundred units The number of units can be set as a decentralized power generation system with self-sufficiency in units of mass, such as remote islands, mountainous areas, and industrial parks. It is possible to greatly reduce the power transmission facilities and power transformation / reception facilities corresponding to the changes.
Furthermore, the current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of the present application do not need to be adjacent to the water source, and have the advantage that they can be installed as close to the power demand area as possible.

The carbon sources mentioned above are dead trees that have been eaten by pests such as thinning and pine wilt, and rice husks and husks generated in Japanese rice farming are discarded. Cultivated kenaf (Hibiscus cannabinus L) in vacant land such as fallow land, which can be mixed gas production plant carbon (C) at a rate of carbon (C) of said plant It goes without saying that cultivating corn, sugarcane, etc. in vacant land such as fallow land can be used as biofuel for plants, but many rice fields have agricultural waterways. In addition, since it has been fertilized for many years, for example, cultivated taro, wheat, and actually edible, the waste part is made into the biofuel of the plant or the carbon of the plant (C) and the wheat straw is converted into the carbon of the plant ( There is also a method to make up for the difference between the income obtained from them and the income obtained from rice cultivation, etc.

Agricultural work with 2 to 3 small rice fields as a single rice field as a measure to expand the scale of agriculture, which has been implemented in the past 20 years as a measure against rice prices (Urg Island) for agriculture (rice farmers) that has been considered in the country. Measures to increase efficiency, measures to increase the size of several farmers as one company, agricultural income compensation system, a subsidy subsidy policy (2.5 trillion yen) to cope with a decrease in rice demand There is a policy to support, but none of these policies are far enough to make Japanese rice farmers an attractive profession for the next generation, using the carbon (C) of the plant as a fuel source. To achieve this policy, “Reducing CO ₂ emissions in response to global warming” and “Making agriculture and forestry an attractive occupation” and further revitalizing the Japanese automobile industry. We can expect effect of "one stone several birds" .

Various embodiments that can be easily conceived from the events described in the present specification and claims are included in the present invention as long as they do not depart from the scope of the claims.

Although this project is partly undeveloped, the internal combustion engine of the present application can be implemented. Furthermore, it can be used for those industries that spread to people in industries related to them.
Above all, creating a cycle that maximizes the use of your country's resources will create a foundation for Japan's 100-year total, leading to the development of those industries.

A. FIG. 3 is a schematic structural diagram of water and carbon as synthesis gas of H ₂ and CO in the engine in an internal combustion engine (rotary piston engine). B. The schematic block diagram of the engine block of a water vapor | steam production | generation part of a reciprocating engine, a synthetic gas production | generation endothermic reaction flow path part, a fuel supply / injection system | strain, and a spark plug. A-F FIG. The example of several types of storage gas tank installation of the storage gas tank installation procedure. H. The partial cross section of the cylinder of 1 unit of a gas storage tank, and the gas inlet / outlet pipe | tube partial view and partial sectional drawing of the said cylinder. i. Tank comprehensive body holding / removal diagram. A. FIG. 1B is a schematic cross-sectional view from the EAsec rotary engine of FIG. 1A to the endothermic reaction flow path portion. B. FIG. A. Type cross-sectional view of pressure inserting the vapor and carbon in H _{2 O} supply pipe. The schematic structural example figure which comprised the structure of the endothermic reaction flow-path part provided in the engine exhaust pipe part and the gas production | generation pipe | tube with several thin tubes. Schematic which shows the rotary engine of the control apparatus of Unexamined-Japanese-Patent No. 2007-2111608. A, electronic control of a rotor same as above, and hydrogen injection structure schematic cross-sectional view of a fuel injection device of a hydrogen rotary piston engine disclosed in Japanese Patent Application Laid-Open No. 2007-064169. B, A, the longitudinal cross-sectional view of a figure. The block diagram of embodiment of the fuel reformed gas engine of Unexamined-Japanese-Patent No. 2002-039022. 1 is a schematic configuration diagram of an electronically controlled hydrogen injection system, intake / exhaust ports, and spark plugs for reciprocating (diesel engine) fuel supply. FIG. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic structural diagram of an exhaust gas treatment device provided in an exhaust pipe that generates Karman vortices of Japanese Patent Application Laid-Open No. 2002-256849 and sucks CO ₂ of exhaust gas into water. An example figure of a small carbon generator. Annual bar graph that captures past years of carbon dioxide emissions statistics from fossil fuels around the world.

An internal combustion engine that contributes to the reduction of greenhouse gas emissions, particularly producing carbon C and water H ₂ O, mainly plant, into synthesis gas (H ₂ + CO) in the internal combustion engine, Further, carbon dioxide discharged from the combustion of the synthesis gas is separated as fuel for the internal combustion engine and reformed into synthesis gas H ₂ + CO and hydrogen in the internal combustion engine, and the synthesis gas and hydrogen are used as fuel for the internal combustion engine. To do.

Greenhouse gases are a major cause of global warming, and it is a common recognition in the world to think that “greenhouse gases should be reduced.” However, it is at the stage of “specific numerical targets…” In the era of international price competition, the current situation is that the story has not progressed because it will incur greenhouse gas reduction costs.
As a power source of an automobile (internal combustion engine) of a greenhouse gas emission reduction measure as of 2014, an electric vehicle, a hybrid with hydrogen, or an engine system using only hydrogen or "bioethanol" as fuel There is also a technology for reducing greenhouse gas emissions by reforming a fuel of 2008-298030 or “bioethanol” into a fuel containing hydrogen and carbon monoxide and using the reformed gas as a fuel. There are still problems that must be solved in order to commercialize products, and it is recognized that there is a part that each problem is lacking in the process of solving.
Of the technologies mentioned above, in the technology using electricity as the power source, according to the statistics of the Electricity Federation of 2011, about 82% of Japan's total power generation is thermal power generation. since the discharging "CO _2" and using the fossil fuels, including unless realized measures that do not emit "CO _2" from the power plant, a greenhouse global warming electricity as a power source It cannot be said that it is a power source of the internal combustion engine that contributes to the reduction of the effect gas.
Moreover, nuclear power generation is a power source that does not emit “CO ₂ ”, which uses electricity as the power source of the above technology to reduce greenhouse gases. However, there is a problem of “Fukushima nuclear power plant”, so it is difficult to establish a new one. And I think that the view that it goes to the direction of decommissioning occupies a lot.

Equipment for reducing the “CO ₂ ” already exists, and the method is a proposal to sequester the discharged carbon dioxide deeply (A) or sequestered (B). The world's largest coal-fired power plant in the United States was completed in 2014, but the treatment of “CO ₂ ” emitted by this power generation is a structure (A) that can be contained in a 1500 m underground layer. However, there is a problem that the construction cost of the plant is twice as high as usual, and there is an additional energy cost for containment in the 1,500m underground layer, which is added to the electricity bill and becomes a consumer burden.

Various technologies have been proposed one after another for the technology to obtain synthesis gas or hydrogen gas by reforming the above-mentioned “CO ₂ ”, and have already been proposed in the in-service sector as an energy generation technology for blast furnace gas and converter gas in steelworks. There are many technologies that have been put to practical use, and the gas emitted in the power generation process of thermal power plants is also used to increase energy efficiency, but most of them are fixed-form features in the large-scale equipment industry. In addition, no feasible technology has been proposed (not found) for reforming “CO ₂ ” discharged from the internal combustion engine in the internal combustion engine that can be mounted on the moving form and using it as a fuel for the internal combustion engine.

Patent 5647364. Engine mechanism of rotary piston engine car. JP-A-11-106770. Power generation method and apparatus using dimethyl ether reformed gas Patent 4231735. Method and apparatus for separating and recovering carbon dioxide JP 2007-177684 A, a carbon dioxide recovery device for a vehicle, and a vehicle including the same. Reaction of hydrocarbons with water vapor or carbon dioxide. Patent 4,609,718 Hydrogen rotary piston engine fuel injection device Japanese Patent Application No. 10-543729 (patent 33455782) synthesis gas production method.

A rotary piston engine combusted by auxiliary fuel, a water supply means for supplying water to the rotor housing of the rotary piston engine from the introduction pipe, and the supplied water is steamed by the heat of the rotor housing, And a livestock gas means for storing the gas that is generated by the endothermic reaction using the exhaust heat after the combustion process of the rotary piston engine and generating the fuel while the auxiliary fuel is used. There is a technique (for example, Patent Document 1) characterized by a structure including a switching means for switching the livestock gas of the livestock gas means and the auxiliary fuel to be supplied to the rotary piston engine, and this application is based on this technique. as carbon dioxide in the exhaust gas from the combustion of the fuel (CO ₂₎ also to adopt a technique of reforming a fuel, further We are in a technology that is a greenhouse gas emission reduction measures that.

Using dimethyl ether reformed gas, which is characterized in that dimethyl ether is reformed by adding water vapor or carbon dioxide to dimethyl ether to cause a catalytic reaction to obtain synthesis gas or hydrogen gas, and this gas is used as a fuel for a prime mover. There is a power generation method, and the above power generation method (for example, Patent Document 2), characterized in that the reforming of dimethyl ether is performed using medium to low temperature waste heat from 200 ° C to 500 ° C.
In this application, by incorporating a part of this technique into the technique of Patent Document 1 above, the carbon dioxide exhausted by the technique of Patent Document 1 is also used as the fuel of the internal combustion engine, thereby improving the fuel consumption. Greenhouse gas (CO ₂ ) emissions from the institution are approaching “zero”, and the technology has become a greenhouse gas reduction measure by carbon assimilation of plants.

A method of separating and recovering carbon dioxide from a by-product gas generated at a steel works by chemical absorption method, which absorbs carbon dioxide from the gas with chemical absorption liquid and then heats the chemical absorption liquid to separate carbon dioxide A method for separating and recovering carbon dioxide, characterized by utilizing or utilizing low-grade exhaust heat of 500 ° C. or less generated at a steelworks. (For example, Patent Document 3)
In order to separate and recover the carbon dioxide of the present application, there is a problem that it is necessary to install a membrane type permeation device that allows several kinds of permeable membranes to pass through the exhaust gas, or to install a vacuum pump or the like.

And in silencers vehicle carbon dioxide device in an exhaust system of an automobile is mounted between the exhaust pipe, provided with a C0 ₂ absorption portion which is connected via an absorbent material and the three-way of the solenoid valve carbon dioxide , A structure in which carbon dioxide is released from the aqueous solution of alkanone compound that has absorbed carbon dioxide by absorbing heat from the engine cooling heat through a solenoid valve, and the separated carbon dioxide is used to regenerate used alkanolamine compounds. (For example, Patent Document 4). This technology is used to regenerate the aqueous solution of alkanone compound that has absorbed carbon dioxide as an application of carbon dioxide separated by the technology that separates carbon dioxide in automobile exhaust gas. It can be used as a technique for separating carbon.
* This is a structure that releases carbon dioxide by absorbing the cooling heat of the engine. In this application, heat is absorbed directly from the engine block from the engine block, and the heat is used for water vapor generating means that turns water into water vapor. Although this point is different, this technique can also be adopted in the present application as a technique for separating carbon dioxide in the exhaust gas of an automobile.

A method of reacting a hydrocarbon with water vapor or carbon dioxide or a mixture thereof under a net endothermic condition to form a gas containing a carbon compound and hydrogen, which is acidic or amphoteric with nickel and cobalt compounds and alkali metal oxides. There is a technique (for example, Patent Document 5) relating to the above method characterized by using a catalyst comprising a water-insoluble compound with an oxide or mixed oxide.
In this application, by incorporating a part of this technique into the technique of Patent Document 1 above, the carbon dioxide exhausted by the technique of Patent Document 1 is also used as the fuel of the internal combustion engine, thereby improving the fuel consumption. Greenhouse gas (CO ₂ ) emissions from the institution are approaching “zero”, and the technology has become a greenhouse gas reduction measure by carbon assimilation of plants.

A fuel injection device for a hydrogen rotary piston engine, which is attached to a rotor housing that forms a working chamber of the hydrogen rotary piston engine and directly injects hydrogen into the working chamber of the hydrogen rotary piston engine, and the hydrogen injector is operated Hydrogen injection timing control means for controlling injection timing so that hydrogen is injected into the chamber at a predetermined timing during the compression stroke, and hydrogen from the hydrogen injector is in the low rotation range of the hydrogen rotary piston engine. And a hydrogen outflow direction setting means for setting the hydrogen injection direction so as to flow out toward the leading region and out toward the central region of the working chamber in the compression stroke in the high rotation region. (For example, Patent Document 6).
* The hydrogen gas and carbon monoxide in the synthesis gas of the present application are almost equivalent in terms of energy, that is, the (higher) calorific value is almost the same. Has taken up the prior literature describing the structure of a rotary piston engine that uses hydrogen as fuel because it is optimal.

A method for producing a synthesis gas by reacting a carbon-containing organic compound with steam and / or carbon dioxide in the presence of a catalyst, wherein the catalyst is composed of a metal oxide as a support, comprising rhodium, ruthenium, iridium, palladium, and platinum. There exists a technique (for example, patent document 7) regarding what uses the catalyst which carry | supported at least 1 type of catalyst metal chosen from these.

The present technique has the prior art document 1,2,3,4,7 feasible by combining portions technology lacking either decisive new technologies, in the exhaust gas of an internal combustion engine also "CO _2" It was reformed into synthesis gas to improve fuel efficiency (Km / L) as a fuel. “It has become a new technology that produces a new effect of reducing global warming by reducing CO ₂ emissions.

The biggest challenge is the reduction of “CO ₂ ” (emissions) to cope with global warming.
Inventing one method of measures for that purpose and the mechanism constituting the method.

To solve the biggest problem,
The first invention is
Water (H ₂ O) and carbon (C) react with the exhaust heat of the internal combustion engine to extract a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) (for example, in an endothermic reaction channel) An endothermic reaction facility for steam reforming) and a livestock gas tank for stocking the mixed gas of hydrogen and carbon monoxide taken out, and the mixed gas of hydrogen and carbon monoxide taken out via the livestock gas tank the are those as fuel for an internal combustion engine, in the exhaust gas in the exhaust heat of the internal combustion engine is mainly waste heat that absorbs water in the water flow path in the engine block of an internal combustion engine in order to steam and the exhaust gas conduit Exhaust heat using heat in an endothermic reaction. Exhaust heat in the engine block and exhaust heat obtained by endothermically reacting heat in the exhaust gas in the exhaust gas pipe. Greenhouse gas reduction and emissions characterized by An internal combustion engine that contributes to reduction is provided.
Furthermore, further heat can be used for the endothermic reaction by providing means for absorbing the refrigerant compression heat that has been discarded from the air-conduit line using power.
The second invention is provided with either one or both of an absorption means for absorbing carbon dioxide (CO ₂ ) in combustion exhaust gas of the internal combustion engine described in the first invention by water and a separation means for separating the carbon dioxide. A livestock gas tank for livestock gas, and a livestock water tank for stocking carbon dioxide-containing water absorbed in water are installed in one or both of livestock gas and livestock water. Carbon is introduced either together with water into an introduction line for supplying water to the engine block of the internal combustion engine or carbon dioxide-containing water absorbed in the water is introduced into the water introduction line. In the internal combustion engine, water is converted into water vapor by the combustion heat, and carbon dioxide is converted into carbon dioxide as an endothermic gas. The name has been changed to distinguish it from reformation. ) In the reforming channel of the catalyst (for example, other metals or compounds can be used in addition to iron-based metals and / or compounds. Examples of other metals or compounds include zinc, nickel, chromium manganese , Tin, cerium, lanthanum and their compounds, other metals or compounds, etc.), and a hydrocarbon compound (for example, dimethyl ether) is introduced upstream of the reforming path to absorb the exhaust gas heat. with carbon dioxide water vapor and endothermic gas is brought into contact with the catalyst of the reforming path, to generate a synthesis gas of hydrogen and carbon monoxide (reforming temperature is 200 ° C~500 ° C) the synthesis gas An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that a separate livestock gas tank is provided for livestock gas, and the engine is configured as fuel for the engine via the livestock gas tank. To provide the relationship.

The third invention is a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) taken out by any one or both of the take-out equipment and the reforming path according to the first to second inventions ( modifying the synthesis gas) synthesis gas Aratameshitsuro (e.g. proton conductive ceramic tube reforming passage) provided in the exhaust gas line, wherein the synthetic gas reforming passage into hydrogen (H ₂₎ and carbon monoxide (CO ) And the reaction gas again reacts with the exhaust heat of the internal combustion engine in the synthesis gas reforming path to separately extract hydrogen (H ₂ ) and carbon dioxide (CO ₂ ), and the extracted hydrogen (H ₂ ) and Carbon dioxide is provided as a livestock gas tank by providing a livestock gas tank, hydrogen is used as fuel for the internal combustion engine, and the carbon dioxide is used as carbon dioxide as a starting material to be reformed in the reforming path. Provides internal combustion engines that contribute to reducing greenhouse gas emissions and emissions To do.

The fourth invention is a hydrogen (H ₂ ) and carbon monoxide (CO) take-out facility (for example, an endothermic reaction facility provided in an endothermic reaction channel) or reforming according to the first to third inventions. At least one of a flow path (reforming path for catalytic contact between hydrocarbon compound, water vapor, and endothermic carbon dioxide) or a synthetic gas reforming path (for example, proton conductive ceramic pipe reforming path) is provided. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that the internal combustion engine is mounted on a transportation device and used as an onboard engine of the transportation device.

A fifth invention is the internal combustion engine according to any one of the first to fourth inventions, wherein the internal combustion engine is operated under a certain condition, is generated with the rotational force, is stored in a capacitor, and the electricity is powered. Provided is an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that it has a structure in which an automobile is driven as a source.

The sixth aspect of the invention stops driving the internal combustion engine when the amount of electricity stored in the capacitor according to the fifth aspect of the invention reaches the upper limit set value and runs with electric power, and drives with the internal combustion engine when the amount of charge reaches the lower limit set value. Provided is an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by its structure.

The seventh invention is characterized in that a charging power receiving plug is provided in the internal combustion engine described in the fifth invention, and as a charging means for accumulating electricity in the livestock generator, the electric vehicle is used as a power source to drive the vehicle. To provide an internal combustion engine that contributes to greenhouse gas reduction and emission reduction.

The eighth invention is a means for using the rotational force of the internal combustion engine as described in the first to fourth inventions as it is as the power generation power of the power generator, or reforming the steam that has finished the role of turning the turbine of the thermal power generation. As a heat source, hydrogen (H ₂ ) and carbon monoxide (CO) extraction equipment (for example, endothermic reaction equipment provided in the endothermic reaction flow path) or reforming flow path (hydrocarbon compound, water vapor, and endothermic gas dioxide) or reforming path) to catalyst contact with carbon, or synthesis gas reforming channel (e.g. a proton conducting ceramic tube reforming path), is provided at least one of one or more of, of the internal combustion engine fuel (gas) An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that it is configured as a means to be combined with the existing thermal power generation facility, or is provided as any means provide.

Ninth invention in the manufacturing industry has discarded any one or more of the heat or steam or carbon dioxide or hydrogen, reforming heat source of any one or more of heat or steam are the discarded Or hydrogen (H ₂ ) and carbon monoxide (CO) by burning any one or more of hydrocarbon compounds, hydrogen, and synthesis gas and using the combustion heat as a reforming heat source Equipment (for example, an endothermic reaction facility provided in an endothermic reaction channel) or a reforming channel (a reforming channel in which a hydrocarbon compound, water vapor, and carbon dioxide of an endothermic gas are in catalytic contact) or quality channel (e.g. a proton conducting ceramic tube reforming channel), the internal combustion engine is operated as a fuel of the internal combustion engine in the configuration for generating the fuel of at least one of the one or more provided the internal combustion engine (gas) of The rotational force is moved as it is That the generation power of the generator, characterized in, providing that contribute the internal combustion engine to reduce greenhouse gas emissions and emissions according to the first invention to third invention.

According to a tenth aspect of the present invention, the livestock gas means according to the first to fourth aspects of the present invention is the livestock gas tank {synthetic gas tank for endothermic reaction, hydrogen gas tank, carbon dioxide gas tank, reforming channel (hydrocarbon compound and carbon dioxide steam and endothermic gas mounting at least one of the one or more tanks} of either synthetic gas tank taken out from the reforming passage) to catalyst contact with the upper body of the car or, alternatively car chassis portion The present invention provides an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that it is mounted on a vehicle.

The eleventh aspect of the invention is that the livestock gas means described in the tenth aspect of the invention is either a damage prevention means that prevents damage to the tank or a tank separation means that separates the tank from the vehicle installation part in the event of a collision. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by providing either means.

The twelfth invention is one of or both of a carbon-containing compound and a hydrogen-containing compound (for example, sodium hydrogen carbonate, NaHCO ₃ ) using the exhaust heat of the internal combustion engine according to the first to fourth inventions as a reforming heat source. any processed pyrolysis or reforming to whether hydrogen of H _2, or the carbon C, carbon dioxide reduction CO _2, is taken out at least one of one or more substances of, and slaughter gas to the slaughtering gas tank The compound from which the gas is taken out (for example, sodium carbonate, Na ₂ CO ₃ ) is sold as a product, and the taken out gas is used as a fuel for the internal combustion engine, or is reformed and used as a fuel. Provided is an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that it is used as a raw material.

The thirteenth invention is characterized in that the main fuel of the internal combustion engine according to any one of the first to fourth inventions can be hydrogen (H ₂ ), and the internal combustion that contributes to greenhouse gas reduction and emission reduction Provide institutions.

According to a fourteenth aspect of the present invention, there is provided a water storage tank comprising water absorption means for absorbing heat into water from the fuel of the internal combustion engine according to the first to third aspects and the exhaust gas obtained by burning the fuel according to the thirteenth aspect of the invention. The greenhouse effect is characterized in that the water in the water storage tank is warmed by the water endothermic means, and the water vapor in the endothermic exhaust gas becomes liquid water and is separated and recovered by the water recovery means. An internal combustion engine that contributes to gas reduction and emission reduction is provided.

A fifteenth aspect of the invention is a small-scale carbon production apparatus for producing the carbon of the plant described in the first to fourth aspects of the invention, wherein the wood, etc. (plant raw material) is heated and carbonized in an oxygen-free environment. Carbonization chamber CS to be fired, combustion chamber FC for burning plant raw materials such as wood for heating the carbonization chamber, exhaust gas vent of combustion chamber FC, and pipe J of water vapor generating means for converting water H ₂ O into water vapor J Is provided along the inner wall of the carbonization chamber, and the structure is such that the steam generated by the steam generation means and the gas C4 generated in the carbonization process in the carbonization chamber are introduced into the combustion chamber to serve as fuel for heating the carbonization chamber. Or the said 2nd invention technique is provided in the discharge part (chimney) of the said exhaust gas pipe line, the reforming substance is made into dimethyl ether as an example, the steam or carbon dioxide is added to the reforming part which makes the catalyst confront Reacting either one or both Providing small carbon maker provided in the either a configuration in which the fuel small carbonization apparatus.

Detailed Description of the Invention

Specific examples of the invention Description of the first invention,
Although it is a take-out facility that takes out a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) by reacting water, (H ₂ O), and carbon (C) with exhaust heat of the internal combustion engine, for example, an internal combustion engine A water passage K is provided in the engine block 1, and either water H ₂ O is converted into steam J or steam is converted into heated steam as steam generating means,
An endothermic reaction channel S is provided in the exhaust pipe MS after the combustion stroke of the internal combustion engine, carbon (mainly carbon C from plants) is introduced into the endothermic reaction channel, and the steam or heated steam , Carbon is reacted in an endothermic reaction channel, hydrogen H ₂ and carbon monoxide CO (synthetic gas) are taken out, and a livestock gas tank MT for stocking the mixed gas of the taken out hydrogen and carbon monoxide is provided. The extracted hydrogen and carbon monoxide mixed gas is used as livestock gas or as the fuel for the internal combustion engine that generates the mixed gas via the livestock gas tank. And
The exhaust heat and the exhaust heat of the internal combustion engine mainly absorbs heat water flow path in the engine block of an internal combustion engine water and heat used for steam, the heat of the exhaust gas by the endothermic reaction in the exhaust gas line The exhaust heat in the engine block and the exhaust heat obtained by endothermic reaction of the heat in the exhaust gas in the exhaust gas pipe are mainly exhaust heat from two places and should be emphasized. Is to use the heat (discarded using power) that has been cooled by a radiator to prevent engine overheat as a means for generating water vapor.
Further, by providing a means for absorbing the refrigerant compression heat that is discarded from the air-conduit line using power, further heat can be used for the endothermic reaction.

This is a take-out facility that takes out a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) by reacting water, (H ₂ O), and carbon (C) with exhaust heat of the internal combustion engine. A water passage K is provided in the engine block 1 of the engine, and either water H ₂ O and carbon are injected under pressure to form water vapor J or water vapor to be heated water vapor as a water vapor generating means. {The pressurizing pressure at this time is about 5 kg / cm ² . (See FIG. 3B)}
Although the present application has a configuration exemplifying steam reforming, the known synthesis gas generation method includes the steam reforming method, and a catalyst (Ni is the mainstream) facing the endothermic reaction channel, which is approximately 200 ° to 300 °. of and the fuel generation unit operable by the heat to the endothermic reaction, drying and reforming and partial oxidation process, there is also autothermal reforming method or the like, adopting a production method of the synthesis gas in place of the steam reforming process of the present You can also.

In view of the energy efficiency of internal combustion engines (about 30% for rotary engines and about 60% of waste (waste) heat available for syngas reaction), it is not enough to produce 100% of the required amount of fuel. In this case, supplementary means for supplementing from other places are provided as supplementary, and as an example of the supplementary means, the present application is provided with an auxiliary tank ST, and fuel in the auxiliary tank (bioethanol mainly made from plant carbon) Or, synthesis gas or hydrogen) is used as a supplementary fuel when it is not enough to produce 100% of the required amount of fuel.
Ultimately, the carbon is used as a measure to reduce greenhouse gas emissions by bringing the carbon closer to 100% use from the waste.

As an example, the present application adopts a composite fuel system in which a sub-tank fuel and a mixed gas generated in the internal combustion engine are switched and used.
However, if hydrogen H ₂ and carbon monoxide CO (synthetic gas), which are the main fuels, are produced while using the sub-tank fuel, there is no place where the produced gas is livestock gas and livestock gas that is livestock gas. It is necessary to provide means, and the present application is provided with a livestock gas tank for livestock gas means, and hydrogen H ₂ and carbon monoxide CO (synthetic gas) as main fuels continue to be generated even when sub tank fuel is used. We continue to fill the animal gas tank,
Accordingly, when the livestock gas tank is filled up to the set upper limit, the fuel switching valve switches the synthesis gas to use via the livestock gas tank, and when it reaches the set lower limit of the livestock gas tank, the engine structure is provided with fuel switching means that uses the subtank fuel. ,
The reason why the mixed gas generated by the internal combustion engine is used via the livestock gas tank is that the mixed gas also changes the composition of the gas component generated depending on the raw materials and the temperature of the production site. Uniformity is intended.

Second invention The carbon dioxide absorption means (A) for absorbing carbon dioxide in the combustion gas of the internal combustion engine by water or the separation means (B) for separating carbon dioxide in the exhaust gas are provided, A) and (B) are respectively provided with livestock water means and the livestock gas means to feed livestock water and livestock gas, respectively, and either one or both of (A) and (B) above It is introduced together with water into an inlet for supplying water to the engine block (FIG. 1B, H ₂ O inlet) and combustion heat in the internal combustion engine {the combustion heat of the internal combustion engine is a water passage (in the engine block of the internal combustion engine ( It corresponds to the cooling water channel of the engine block cooling water), and water is converted into water vapor.} The water is converted into water vapor, the carbon dioxide is converted into carbon dioxide as an endothermic gas, Reforming channel (carbon dioxide reforming In the reforming flow path of the reforming flow path of the steam reforming in order to distinguish from the steam reforming, as an example, other metals or compounds can be used in combination with iron-based metal and / or compound, Examples of other metals or compounds include zinc, nickel, chromium manganese, tin, cerium, lanthanum and their compounds, other metals or compounds, and a hydrocarbon compound (eg, dimethyl ether) upstream of the reforming path. CH ₃ OCH ₃ ) and the reforming channel of the reforming channel (name changed because of reforming of carbon dioxide) provided in the internal combustion engine together with the water vapor and endothermic carbon dioxide The catalyst is opposed to the gas {hydrocarbon compound (eg dimethyl ether CH ₃ OCH ₃ ) and either water vapor or endothermic carbon dioxide]. It is a structure that generates hydrogen and carbon monoxide syngas by contacting them, and uses it as a fuel for the engine via a livestock gas tank. The detailed explanation of (A) is omitted. }

The reaction formula when the hydrocarbon compound is dimethyl ether is
A. _{CH 3 OCH 3 + H 2 O} → 2CO + 4H 2 -48.9Kal / mol
B. CH ₃ OCH ₃ ++ CO ₂ → 3CO + 3H ₂ −58 · 8 Kal / mol
The reaction temperature is 200 to 500 ° C., preferably 250 to 450 ° C.
The reaction pressure is preferably atmospheric pressure to 10 kg / cm ² .
Many technologies using methane in addition to dimethyl ether as a hydrocarbon compound have been disclosed.

The carbon dioxide absorption means (A) and carbon dioxide separation and extraction means (B) for absorbing carbon dioxide by a known technique,
(A) is disclosed in JP 2010-526759, JP 33455782, JP 2009-77457, JP 2001-213545, JP 2007-177684, and the like.
(B) is disclosed in Japanese Patent Application No. 2001-48591 (Karman vortex), Japanese Patent Application Laid-Open No. 2007-177684, etc.
Prior art of the method for producing hydrogen and carbon monoxide by the carbon dioxide reforming reaction includes Japanese Patent Application Laid-Open No. 08-231204 and Japanese Patent Application Laid-Open No. Hei 11 of Japanese Patent Application Laid-Open No. H11-296275. -106770 etc.
Incorporating this technology into this application, the carbon dioxide in the exhaust gas is “a reforming of the internal combustion engine fuel only into the fuel of the internal combustion engine of this application” is a great greenhouse gas emission reduction measure, A feature of the present invention is that fuel is generated with the discarded energy (approximately 70%, and approximately 60% can be used for reforming), and fuel efficiency is improved by the amount of fuel generation.

Among the inventions of the present application, the carbon C of the synthesis gas generating material when the reforming means for reforming carbon dioxide is used may be carbon C using fossil fuel, and the carbon dioxide is reformed into synthesis gas. Therefore, it is possible to reduce CO ₂ emissions of at least several tens of percent, and this is a measure for reducing greenhouse gas emissions.

3rd invention The synthesis gas reforming path described in the 3rd invention includes a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) produced in the first to second inventions, and an internal combustion engine. heat and those in steam at {the exhaust heat of the internal combustion engine from which exhaust heat of the water vapor in the water flow path in the engine block of an internal combustion engine}, for example, again an internal combustion proton conductive ceramic tube of Hydrogen (H ₂ ) reacts with the exhaust heat of the engine (300 ° C. to 800 ° C.) (the exhaust heat of the internal combustion engine is exhaust heat obtained by absorbing the heat in the exhaust gas in the exhaust gas pipe). Carbon dioxide (CO ₂ ) is taken out separately, and a hydrogen livestock gas tank and a carbon dioxide livestock gas tank for separately stocking the hydrogen and carbon dioxide are provided. As a raw material, the extracted hydrogen is hydrogen This is a configuration structure that uses the internal combustion engine as fuel via a tank.

When exhaust gas temperature in the exhaust pipe is insufficient, an exhaust gas combustion section is provided upstream of the synthesis gas reforming path,
You may introduce and reheat the fuel and oxygen (air) which are the livestock gas of the extent which supplements the shortage temperature to the unburned fuel gas or unburned carbon particle in exhaust gas.

The carbon dioxide reforming is a technique in which a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) is taken out by contacting with a catalyst together with a carbon dioxide and steam reforming material (Japanese Patent Application Laid-Open No. H11-11). 106770) is incorporated into the present application, and carbon dioxide is also used as a fuel for the internal combustion engine, thereby improving fuel efficiency and further reducing greenhouse gas emissions.

The present application introduces carbon dioxide and water into an inlet (H ₂ O inlet in FIG. 1B) for introducing water into the engine block (rotary housing) of the engine for the carbon dioxide reforming. Heat is absorbed in a water passage K provided between the inner and outer walls of the engine block (rotary housing), water is absorbed into water vapor, and carbon dioxide is absorbed to raise the gas to a high temperature and mixed, and a catalyst is placed downstream of the engine exhaust port. There is an opposite reforming path (the name is changed because it is carbon dioxide reforming), and a hydrocarbon compound (for example, dimethyl ether CH ₃ OCH ₃ ) is introduced upstream of the reforming path and the steam and The gas {hydrocarbon compound (eg, dimethyl ether CH ₃ OCH ₃ ) and water vapor or endothermic carbon dioxide, or both} is added to the catalyst together with endothermic carbon dioxide} To remove the mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO), or add the water to steam in the water passage K of the engine block (rotary housing) of the engine. A water passage K ′ of the engine block (rotary housing) of the engine is further provided to be a two-line pipe line for heating carbon dioxide, and (exhaust gas after engine combustion process) It is configured to take out a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO), either by contacting with the catalyst that is confronting the exhaust pipe (including joining near the mouth). For example, the catalyst can be used in combination with other metals or compounds in addition to iron-based metals and / or compounds. Examples of other metals or compounds include zinc, nickel, and the like. Kell, chromium manganese, tin, Seryuumu, lanthanum and compounds thereof, there is another metal or compound.

The reforming temperature of the steam reforming described in the first invention is 700 ° C. to 1000 ° C., preferably 800 to 900 ° C., and the reforming temperature of the hydrocarbon compound (eg dimethyl ether CH ₃ OCH ₃ ) is 200 to 200 ° C. Since the temperature is 500 ° C., preferably 250 to 450 ° C., a steam reforming section is provided upstream of the exhaust pipe, and a reforming section of a hydrocarbon compound (for example, dimethyl ether CH ₃ OCH ₃ ) is provided downstream of the steam reforming section. A synthesis gas reforming path (reforming temperature is 300 ° C. to 800 ° C., the third invention) is provided downstream of the quality, or the synthesis gas reforming path is provided downstream of the steam reforming and further carbonized downstream. It is preferable to take any form of providing a reforming portion of a hydrogen compound (for example, dimethyl ether CH ₃ OCH ₃ ).

In the hydrogen (H ₂ ) and carbon monoxide (CO) extraction equipment, the reforming channel, and the syngas reforming channel, if it is desired to take a longer reaction time, or steam reforming or CO 2 is performed simultaneously. When at least one of reforming and syngas reforming is desired, a plurality of water passages K provided between the inner and outer walls of the engine block (or rotary housing) of the engine are provided in the engine block 1. Whether to provide a structure or multiple exhaust pipes from the engine block (for example, the same number of cylinders, half the number of cylinders, or the same number of pipes as the number of rotors) Alternatively, one or a plurality of exhaust pipes extending from the engine block may be further branched into a plurality of branches and sequentially switched to send exhaust gas) or the water flow At least one of the two systems of pipes for heating carbon dioxide by further providing K ′, and three kinds of pipes downstream of the exhaust port after the engine combustion process A structure in which at least one of the reforming paths is provided and a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) or hydrogen gas / carbon dioxide may be taken out.

Proton conductive ceramics have heat resistance according to the combustion temperature and are provided with continuous vents through which combustion gas can pass. Proton conductive ceramics such as strontium serate-based and zirconate-based belogskite oxide ceramics are hydrogen conductive ceramics. This is particularly advantageous in that it has an action of activating oxygen.

The use of carbon dioxide or carbon as a raw material as a renewable energy source in equipment industries such as the manufacturing industry is a known technique.

Fourth invention An internal combustion engine provided with one or more of hydrogen (H ₂ ) and carbon monoxide (CO) extraction equipment, reforming flow path, and synthesis gas reforming path as a transportation device It is in the form of an on-board engine for transportation equipment, which includes motorcycles, munitions weapons vehicles, munitions weapons ships, and the like.

Fifth invention,
The existing hydrogen rotary piston engine car is used for the internal combustion engine described above. “The engine is operated under good fuel economy conditions (constant conditions) and is generated by the rotational force and stored in the capacitor. The electricity is used as the power source. By applying the form of “driving an automobile” to the internal combustion engine, stable combustion heat can be obtained, and the endothermic reaction conditions are also stabilized. However, it has a great effect of further improving fuel consumption and reducing greenhouse gas emissions by adopting a structure that generates electricity with the rotational force, stores it in a capacitor, and operates the electricity as a power source.

* Driving conditions (for example, waiting for traffic lights, waiting for an oncoming vehicle on the right, waiting for crossing pedestrians when turning right or left at the intersection, choco-choco driving in a traffic condition, driving on a flat road, overtaking & overtaking rapid acceleration・ The control mechanism and control structure of the output of the internal combustion engine are simplified and improved by following the changes in the downhill driving, etc.
Furthermore, since driving is performed under a certain condition (good fuel efficiency), there is an effect of improving the fuel efficiency (Km / L).

According to the sixth aspect of the invention, when the storage amount of the capacitor is equal to or greater than the set value, the driving of the internal combustion engine is stopped and the vehicle is driven with electric power.
When the driving state that does not require power continues, the engine is continuously operated under certain conditions (good fuel economy conditions), so depending on the driving state, the electricity generated to drive the car becomes overcharged and is generated by the internal combustion engine. Since the electricity is discarded, the engine can be turned off and the vehicle can run with the stored electric power to improve the fuel consumption.

7th invention The internal combustion engine is provided with a charging / receiving plug and is used as a charging means for storing electricity in a livestock battery. It is expensive to cover all necessary power with a battery by using a structure that allows the vehicle to run using the electricity as a power source. It is not necessary to install a large number of batteries, and the power storage capacity of the internal combustion engine can be increased by several tens of percent. It will be a measure.

Driving conditions that do not require power (waiting for traffic lights, waiting for oncoming vehicles when turning right, waiting for crossing pedestrians when turning left or right, choco chocolate driving during traffic jams, downhill driving, coasting driving, etc.) During this period, the engine is continuously operated under certain conditions (good fuel efficiency). Depending on the driving condition, the electricity generated for driving the car becomes overcharged and the electricity generated by the internal combustion engine is discarded. Therefore, when the storage capacity of the livestock electricity reaches the upper limit set value, the engine is turned off and the vehicle runs with the stored power. When the storage capacity of the battery reaches the lower limit set value, the engine is turned on and the vehicle runs with the engine. The fuel consumption can be improved.

If the electric power is used as the driving power when running in the engine braking state during downhill driving, the motor can be used as a generator.Therefore, when running in the engine braking state, the motor is used as a generator to charge the battery. This will further improve fuel efficiency and reduce greenhouse gas emissions.

This is a repulsive driving run on the flat road, but a repulsive driving run is a speed at which a driver wants to drive for several minutes with an accelerator operation (approximately 2200 revolutions) that is about 10% higher than the speed at which the driver wants to drive. If it is 60Km / H, turning to 70Km / H will turn off the rotational drive power of the engine (this will be about 1000 revolutions, the number of revolutions when idling). Is a driving method that repeats the operation of turning on the rotational driving force connection of the engine when the speed reaches 60 km / H, which is a common driving method in the transportation industry 50 years ago. Automatic control of this travel mode can further improve fuel consumption and reduce greenhouse gas emissions.

Eighth Invention The internal combustion engine endowed by the internal combustion engine is the means for directly using the rotational force of the internal combustion engine as the power generation power of the power generator, or the steam that has finished the role of turning the turbine of the thermal power generation and the newly added mainly plant carbon. Introduced into the reaction channel and converted to endothermic reaction, the generated fuel (gas) can be used as a substitute for auxiliary fuel, and can be combined with the existing thermal power generation facility, or the thermal power generation An endothermic reaction facility is provided in the exhaust gas pipeline of the boiler of the facility to make the endothermic reaction, and the generated fuel (gas) is used as a fuel for the power generation via the livestock gas tank. Also good.

It also can be any one or more of the mixed gas or carbon dioxide or hydrogen in the hydrogen and carbon monoxide using a material obtained by manufacturing elsewhere equipment (or transported in a state of compressed gas in the piping) can correspond, for generating Cases and ships and large vehicles can also be equipped with hydrogen (H ₂ ) and carbon monoxide (CO) mixed gas production equipment in close proximity to the internal combustion engine.

Ninth Invention In a manufacturing industry (for example, steelmaking, iron forging, iron casting, aluminum refining and manufacturing, dust incineration plant, oil refining industry, etc.) that disposes heat, steam, carbon dioxide or hydrogen, Any one or more of discarded heat, steam, carbon dioxide or hydrogen is modified by any one or more of the reforming techniques described in the first to third inventions. The generated fuel (gas) is used as the fuel for the internal combustion engine to operate the internal combustion engine, and the CO2 in the exhaust gas of the internal combustion engine is combined with hydrogen by the means described in the second invention. This is an internal combustion engine that is generated in a synthesis gas of carbon oxide and is operated as a fuel for the internal combustion engine, and its rotational force is directly used as the power generation power of the power generator.
For example, in the rolling process of a steel mill, the decarburized crimson steel plate is passed through a number of rolling mills to form a steel plate roll of about 10 mm. The plate is cooled, and the large amount of water applied at this time becomes steam, and a part of it is discarded, and the final rolled steel sheet roll is used for the ceiling crane to hang down in the steel sheet roll natural cooling place. They are lined up in order on a plurality of rows of roller conveyors that have been installed with the required clamping tool operating width. The temperature of the steel sheet roll at this time is 700 ° to 900 °, and the power generation of the motive power generator is performed using the fuel (gas) generated by providing the endothermic reaction section between the roller conveyors to effect the endothermic reaction as the fuel of the internal combustion engine. Using power as a means of reducing electric power will reduce greenhouse gas emissions.

Tenth Invention & Eleventh Invention The livestock gas tank {the tank does not require a high-pressure hydrogen gas storage tank of 35 MPa, and is a fuel necessary for operating at least about 10 minutes with the gas generated by the internal combustion engine. Is a damage prevention means for preventing damage to the tank of the internal combustion engine (if the switching loss can be ignored). A shock absorber HPE such as foamed polyethylene and boron fiber reinforced plastic is fixed as a package and fixed and held on the upper part of the vehicle. The tank separating means is fixed to MT5. When the impact is applied to the fixture MT5, the V-shaped notch MT6 breaks due to concentrated stress, and the shock absorbing material inclusion MT (The tank support MT2 is integrated) is disengaged from the fixture MT5 (not completely disengaged but is locked to the fixture MT5 or the like with a wire body or the like). (It is a preferable form because it is a measure to avoid secondary damage in which the body MT3 completely comes off)
One or both of the damage prevention means for preventing damage to the tank or the tank separation means for separating the tank from the tank installation portion of the vehicle in the event of a collision are provided. Further, it is composed of a non-stationary facility (for example, an automobile) livestock gas tank of the livestock gas means, and the livestock gas tank is mounted on the upper body of a car or mounted on a chassis part of a truck. It is preferable to use one of the forms attached to the stationary equipment, but in the case of stationary equipment (for example, a power plant), the safety standard (in Japan, the registration of JIS B 8265 has been completed. Is ISO 16528), and the non-stationary livestock gas tank and the stationary livestock gas tank (eg chemical factory) It must be composed of those that are within the safety standards or at least have elements that can change the safety standards, so non-stationary equipment (eg automobile) livestock gas tanks and stationary equipment (eg chemical factories) livestock gas tanks Even if the function of storing gas is the same, the structure (standard) is completely different.

A twelfth invention for example to make a bicarbonate Natoryuumu (NaHCO ₃₎ and by processing and thermally decomposed in the exhaust heat of an internal combustion engine hydrogen _{(H 2)} and carbon dioxide Natoryuumu _(Na 2 CO _3), carbonate Natoryuumu _(Na 2 CO ₃ ) is taken out and sold as a product, and hydrogen (H ₂ ) is used as a fuel for the internal combustion engine via the livestock gas tank. The sodium hydrogen carbonate (NaHCO ₃ ) is an example as long as it is a product that adds value by use, and is not limited to sodium hydrogen carbonate (NaHCO ₃ ).

The thirteenth invention and the fourteenth invention are configured such that the main fuel of the internal combustion engine described in the fourth invention is hydrogen (H ₂ ),
If hydrogen is the main fuel (of the thirteenth invention), it is an exhaust mainly composed of water and nitrogen (the first invention to the second invention) and the fuel burns hydrogen and carbon monoxide. It is an exhaust mainly composed of water, carbon dioxide and nitrogen, and is an exhaust mainly composed of water, carbon dioxide and nitrogen when hydrogen and carbon monoxide are reformed from carbon dioxide in the exhaust.
Regardless of which fuel is used, the water is discharged in the form of water vapor, and the structure is such that the water of the reforming starting material is warmed from this water vapor by further heat absorption means, and the water is removed from the water vapor in the exhaust gas and filtered. It is returned to the storage tank as water for reforming starting material via filtration means,
The heat absorption means from the water vapor is provided, for example, by providing a water storage tank downstream of the exhaust pipe and passing the exhaust pipe through the water in the storage tank so that the water in the water tank absorbs heat and the water in the water tank is heated. Recovery means for recovering water, characterized in that water vapor in the exhaust pipe becomes water and recovers
The above-mentioned various reforming means reform water into fuel, so a considerable amount of water is required. However, if the on-board amount of water is increased, energy for transporting the on-board amount of water (weight) is required. Therefore, if water is collected and recycled, the amount of on-vehicle water can be reduced, and the water in the water tank can be warm water. This contributes to greenhouse gas reduction and emission reduction.

A fifteenth aspect of the invention is a small-scale carbon production apparatus for producing the carbon of the plant described in the first to fourth aspects of the invention, wherein the wood, etc. (plant raw material) is heated and carbonized in an oxygen-free environment. Carbonization chamber CS to be fired, combustion chamber FC for burning plant raw materials such as wood for heating the carbonization chamber, exhaust gas vent of combustion chamber FC, and pipe J of water vapor generating means for converting water H ₂ O into water vapor J Is provided along the inner wall of the carbonization chamber, and the structure is such that the steam generated by the steam generation means and the gas C4 generated in the carbonization process in the carbonization chamber are introduced into the combustion chamber to serve as fuel for heating the carbonization chamber. Or the said 2nd invention technique is provided in the discharge part (chimney) of the said exhaust gas pipe line, the reforming substance is made into dimethyl ether as an example, the steam or carbon dioxide is added to the reforming part which makes the catalyst confront Reacting either one or both Providing small carbon maker provided in the either a configuration in which the fuel small carbonization apparatus.
In the configuration of the small-scale carbon production device, the carbonization chamber CS and the combustion chamber FC are separated from each other, and the carbonization chamber CS section is provided with a generation section for steam J and a separation section for separating carbon dioxide from the exhaust gas. Thus, a heater using a fossil fuel such as coal (for example, a coal stove) can be used.
This means that many cold districts use coal stoves, and carbon dioxide emissions due to coal combustion cannot be ignored. The construction of the first and second inventions of this application Applying this is one of the measures to reduce (emission) “CO ₂ ” to cope with global warming, which is the biggest problem of the present application.

In the combination of the present invention, the carbon C of the synthesis gas generating material when the reforming means for reforming carbon dioxide is used may be fossil fuel use (for example, coal), which is a greenhouse gas emission reduction measure. is there.

The biggest challenge is the reduction of CO ₂ emissions to combat global warming.
By using mainly plant carbon C as a fuel, it was possible to make an internal combustion engine for a greenhouse gas reduction measure that constitutes one of the challenges of the greenhouse gas reduction measure that is the subject of the present application. In addition, CO ₂ generated by the combustion of plant carbon C is also reformed to fuel, and reforming this CO ₂ to fuel also has the effect of further increasing greenhouse gas reduction and fuel efficiency. This is the biggest effect.

The use of an internal combustion engine that generates this synthesis gas and uses the generated synthesis gas as a fuel as an alternative to a thermal power generator is a project that can be mentioned as the first solution to the current energy problem solution (2011) (2011). According to the statistics of the Federation of Electric Power Companies of the year, about 82% of Japan's total power generation is thermal power generation, and there is a request for power saving at the peak of midsummer power demand from each power company) Doing so has a great effect on power supply.

The great effect is that fuel is generated by utilizing the thermal energy that was discarded by the internal combustion engine.

The present application is an alternative to the auxiliary fuel supplied to the internal combustion engine for power generation using the rotational force of the internal combustion engine as it is as a power generation facility, and the endothermic reaction flow of heat, steam or hot water discarded in the manufacturing process, and newly input carbon. Auxiliary fuel, either petroleum liquefied gas (including natural gas), gasoline (including hydrocarbon-based fossil fuel), bioethanol, or synthetic gas, that was introduced into the road and supplied to the internal combustion engine A structure that eliminates the need for a fuel switching control structure including a sub-tank, a sub fuel use control structure, and a switching valve that switches and uses the synthesis gas of the auxiliary fuel, because the livestock gas tank is replaced with the synthetic gas or hydrogen gas of the present application. Is also possible.

The CO ₂ produced by burning the carbon of the plant is also generated in the synthesis gas to further reduce the greenhouse gas CO ₂ from the carbon neutral of the Kyoto Protocol on the use of carbon of the plant. it is possible to reduce the CO _2, produce the maximum effect that Do greenhouse gas reduction measures that could not be carried out in the existing prior art,
Furthermore, even if carbon of the internal combustion engine of the present application is used for fossil fuel, CO ₂ can be reduced by at least several tens of percent even if 100% emission cut cannot be achieved.

While the purchase of greenhouse gas CO ₂ allowances is revitalizing, Japan's purchase amount is estimated to be about 1 trillions of billions, but this purchase amount can be reduced by several tens of percent.

The endothermic reaction efficiency can be obtained by operating the engine under the constant endothermic reaction condition by operating the engine under the “constant and fuel-efficient conditions” (different conditions at start-up) that are not related to the engine load fluctuation described in the fifth invention. The improvement of fuel efficiency (Km / L) is achieved by making the fuel efficiency good and the fuel efficiency is good.

The raw materials for generating the fuel for the internal combustion engine are water H ₂ O and carbon C. The plant that can regenerate the carbon C is used as a main raw material, and further, it is made from materials close to industrial waste that are produced during the production of sewage and food. Substances (e.g. methane gas or bioethanol) are preferred as sub-fuels,

Using the plant as the main raw material means that the plant absorbs carbon dioxide CO ₂ and produces oxygen O ₂ , so in the Kyoto Protocol it is defined as plus or minus “0” (carbon neutral), and global warming This is a great effect that can greatly contribute to prevention.

By providing a cycle for generating carbon dioxide in the exhaust gas into the synthesis gas (second invention), the “CO ₂ ” discharged from the internal combustion engine of the first invention is reformed into fuel. It is possible to reduce emissions of “CO ₂ ” and to improve fuel efficiency. (For example, it was possible to obtain an astonishing effect of improving 20 Km / L to 40 Km / L or more, not about 20 Km / L to 25 Km / L.
* The above effect could be obtained by providing means for reforming water H ₂ O and CO ₂ into fuel.

A radiator including the engine block cooling water passage and the cooling water piping of the internal combustion engine is not necessary.

The raw materials for generating the fuel for the internal combustion engine according to the first invention are water H ₂ O and carbon C. The plant that can regenerate the carbon is the main raw material, and the plant is the main raw material. sucking carbon dioxide CO _2, since out of oxygen O ₂ in the Kyoto Protocol plus, have been negative "0", a large becomes contribution possible to prevent global warming.

The use of the plant as the main raw material makes it possible to turn abandoned forests and “rice fields” into factories with good “operation rate” to produce valuable things (carbon from plants). This is vital for agriculture and forestry. give.

In thermal power generation, the boiler is heated with thermal power to generate steam, and the steam is further heated to generate electricity by rotating the turbine. Since the initial energy is large, it is difficult to turn on / off following the power consumption fluctuations according to the time zone because it is difficult to turn off the fire for a long time once it is turned on, so depending on the season (spring / autumn) or time zone Surplus power that is not consumed is generated, and the excess production is discarded. However, if the power generation system using the internal combustion engine of the present application is used, the operation may be turned ON / OFF following the fluctuation of the time power consumption. Since it can be made freely, excess production power can be brought to zero as much as possible, so there is no need for a large-capacity power storage facility and a vast amount of power transmission / reception facilities when supplemented only by solar power generation.

Current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of this application do not need to be adjacent to the water source and can be installed as close to the power demand area as possible, so there are very few transmission / reception facilities I can do it.

The proportion of the Japanese economy affected by fossil energy price fluctuations (and exchange rate fluctuations) will be reduced.

The internal combustion engine according to any one of the first to third aspects of the present invention is used for automobiles (including two-cycle two-wheeled vehicles and four-cycle two-wheeled vehicles), marine and railway diesel engine vehicles, construction machinery, munitions weapon vehicles, and munitions weapons. It is implemented in the form of being mounted on a transportation device such as a ship, and the form in which the power generator is used as an alternative to the thermal power generation facility, or steam that has finished the role of turning the turbine in the existing thermal power generation facility, is newly input In an embodiment in which carbon to be introduced is introduced into an endothermic reaction flow path of an internal combustion engine and used for the fuel shortage and merged with an existing thermal power generation facility, or in any one or more embodiments within the ninth invention is there.

Each dimensional relationship in the drawings is enlarged for important portions, exaggerated where details are difficult to understand, and reduced when describing wide portions or portions that are less important in the present invention. Thus, the dimensions between and within the drawings are not proportional, and are not actual or scaled.
If the distance between the lines is narrow, it is likely to become a single line that is black and thick at the scanning stage. Therefore, the distance between the lines is widened or described with a single line.

Furthermore, parts other than the basic (main) mechanism of the present invention are omitted between the drawings.

Hydrogen and carbon monoxide are almost energetically equivalent, that is, the (higher) calorific value is almost the same. Therefore, the detailed description in the specification of the present application refers to a known technique using hydrogen as a fuel. There are many. Furthermore, there are many parts that cite known techniques for the technique of reforming “CO ₂ ” into synthesis gas.
The main structure of this application refers to a variety of known technologies (including some that are patent-registered and alive), but cannot be obtained by individual known technologies alone. In order to obtain the effect in the present application, it was possible to obtain a surprising effect in terms of reducing greenhouse gas emissions and improving fuel consumption.

An endothermic reaction flow path is provided in the engine block of the internal combustion engine, and water H ₂ O and carbon C are reacted with the exhaust heat of the internal combustion engine to take out a mixed gas of hydrogen H ₂ and carbon monoxide CO. It is an internal combustion engine that uses a mixed gas of carbon monoxide and fuel, but any manufacturer thinks that synthetic gas can be used as an alternative fuel to gasoline, light oil, heavy oil, etc., but hydrogen also Carbon monoxide is also very dangerous (explosive and toxic). Therefore, liquefied transport means (portability). The ratio of the volume of the liquefied gas to the weight of the container that satisfies safety standards is poor. I suspect that there was an explosion problem caused by the wreck, and I couldn't get it.

The means of the present application to solve this problem are:
* Instead of filling the tank with fuel consumption and supplying all the fuel required for driving, a subtank is provided to replenish the energy loss during the fuel generation process, and the subtank fuel is oil liquefied gas (including natural gas) ) Adoption of a composite fuel supply structure that uses gasoline, hydrocarbon-containing fossil fuel bioethanol, etc., or synthetic gas as a supplementary sub-fuel for the energy loss (this stored gas pressure) The installation position of the livestock gas tank in consideration of the above and the provision of structural means that can cope with an accident such as a car being severely damaged) are the main points that made this application an “practicable plan”. (See Figures 1 and 2)

The storage gas, the synthesis gas generated in the livestock gas tank is stored in a certain amount (in the state of compressed gas), while the certain amount is accumulated, butane gas, gasoline, (including hydrocarbon-based fossil fuel) methane gas, bioethanol, etc., or Any of hydrogen, synthesis gas, reformed gas from plants, methane gas from plants, bioethanol of bioethanol, etc. is used as the storage gas in the auxiliary fuel tank, and the amount of generated synthesis gas is constant. And switch to synthetic gas, use synthetic gas in livestock gas tank while generating synthetic gas, and switch to using auxiliary fuel tank when the tank capacity is close to "0". Means to reduce the amount (including tank weight),

An example of a known technique for converting carbon dioxide to hydrogen, carbon monoxide, etc. in the presence of a catalyst is described in Japanese Patent Application Laid-Open No. 11-106770. In the description, a method for producing a synthesis gas by reacting a carbon-containing organic compound with steam and / or carbon dioxide in the presence of a catalyst and a catalyst suitable for the method are also disclosed. Is also used as a technology for reforming fuel.
Japanese Patent Application Laid-Open No. 2007-177684, a carbon dioxide recovery device for a vehicle, and a vehicle equipped with the same discloses that carbon dioxide is absorbed by a carbon dioxide absorber and carbon dioxide is recovered.

The main sources of greenhouse gas emissions are emissions from internal combustion engines and thermal power generation boilers, which account for about 82% of Japan's power generation (2012 Electricity Federation statistics). And 1/4 of the world ’s emissions from thermal power boilers,
The amount of CO ₂ released when 1 gallon of gasoline is burned is about 9 Kg combined with emissions from the car engine and emissions from the gasoline production process.
Therefore, in order to shift the consumption of carbon C from fossil fuels to carbon C from plants and achieve a 25% reduction in greenhouse gas CO ₂ emissions early,
It is necessary to implement an internal combustion engine for the greenhouse gas emission reduction measures of the present application and to make the procurement cost of carbon C, which mainly consists of fuel, the same as the procurement cost from fossil fuel.
The production of carbon C as fuel changes when carbonized organic material is heated while shutting off the flow of air and oxygen, and changes to a material rich in black carbon. This process is called carbonization, and charcoal produces this carbonization. This is a good example of a product, and what is produced is an aggregate composed mainly of amorphous oxygen and the like, and is mostly porous and has a very large surface area. Heating causes dehydration and dehydrogenation reaction to produce a condensed polycyclic aromatic compound, which further forms a network structure, which is called carbonization.

The technology to make solid carbon C from wood (nano-plant raw material) into nanoparticles is not yet a new technology because it has already been broadcast on TV, etc., but micronization (100 (About a micron) can be dealt with as the carbon C of claim 1 of the present invention.
If the solid carbon C is pulverized into fine particles, the surface area where the reaction takes place is increased. Therefore, the finer the particles, the more efficient the synthesis gas generation.
It can also be handled by adding water to the carbon C to form an emulsion fuel or gel.
Furthermore, the above-mentioned wood and the like (plant raw material C) is heated in an environment where oxygen does not enter, and carbon C gas can be obtained in the carbonization step.

It is a cycle in which steam in the engine → endothermic reaction in the exhaust line → synthesis gas or hydrogen of carbon monoxide and hydrogen or hydrogen is used as fuel for the engine.
* The proposed matter is that the livestock gas tank has a large internal volume, low pressure accumulation, a tank that can be built, where the vehicle is located, and what structure is used. It was possible to make a structure that does not.
* The above-mentioned proposed matter was solved with the following structure.
1. The place where the synthesis gas tank is installed is located in the upper part of the car body or in the chassis part of the car, which is provided in the upper part of the car body even if the car falls from the cliff, Even in an accident that is sandwiched between and crushed, the livestock gas tank is required to have a tank that does not explode, but the target hydrogen that can run 500Km in a cylinder that can be mounted on the vehicle is 4MPg of hydrogen and 20MPa. The pressure requires 300L of container volume,
Mazda (Company name) Premasi Hydrogen RE hybrid vehicle equipped with 74L / 35MP of hydrogen can run only 123Km with full tank filling, so it can not run only with hydrogen, so to run 500Km, about 4 times 300L A / 35 MPa hydrogen tank is required, but in order to cover 300 L of hydrogen with a 74 L / 35 MP container, a container that can be filled with about 150 MPa compression is required, which is difficult with the current technology.
Therefore, it was planned to generate synthesis gas in a mounted internal combustion engine. However, in a pressurized pump with a mounted structure, if the compression pressure is increased, more power is consumed for the pressurized pump. At the start, the gas was accumulated with equipment equivalent to an accumulator of hydraulic equipment, but the car fell from the cliff due to an accident on the highway where the livestock gas equipment should be installed. If the accident is such that the car is flipped upside down or the passenger car is sandwiched between large trucks and crushed in a sandwich, the structure must be such that an explosion can be avoided when such an accident occurs. I gave up on board.
If you are searching for related documents on the Internet and searching for prior literature for planning other projects using synthetic resin, the following foamed polyethylene, (the above-mentioned member has anti-bullet properties and is used for military weapons, (As an example, polyethylene fired polyethylene is fixed to the outer surface of an army water hoat for army movement, and when it is sniped with a rifle etc., the bullet has a bullet-proof property that does not allow a hole to be made in the rubber hote) Can be found, and if this was used, it was able to solve even the place where it did not explode even if the accident occurred. However, the problem was the location of the last remaining tank.
While considering the eco-driving method filed last year and thinking about what to do with resin to reduce the weight of the car, when considering the roof of a passenger car, the livestock gas tank of the present application that had been neglected was used for the roof of the car The structure of this livestock gas tank is the key point of the present application. (See Figure 1A and Figure 2)
2. As shown in FIG. 2, the outer surface of the livestock gas tank is made of poron fiber reinforced plastic or foamed polyethylene. (The above-mentioned members are bullet-proof and are used for military weapons. The fired polyethylene is fixed on the outer surface of the water hoat for moving the water surface, and when it is sniped with a rifle, etc., the bullet has a bullet-proof property so that a hole cannot be made in the rubber hoat)) A tank separation means is provided that separates from the car body when it is impacted by falling or severely damaging the car. It has a structure that does not explode even if it bounces off. (It is preferable to provide a locking structure that does not jump too far.)
3. As an example of the separation structure of the tank inlet / outlet pipe from the vehicle body, the solenoid valve contact configuration is ON when energized. When the solenoid valve sequence circuit is turned off when not energized, and the synthetic gas tank is subjected to an impact force flying from the body of the car, the gas inlet / outlet pipe of the tank may come off (or be damaged). The gas pipeline from the tank is closed. (See Figure 2.H)
4). As for the problem of compression pressure of livestock gas, if the configuration of Mazda (Company Name) Premasi Hydrogen RE hybrid vehicle, which uses auxiliary fuel, the eco-driving method and the internal combustion engine of the last year's application only generate electricity, is the first of the present application. Combining the sixth and seventh inventions with the detailed explanation part of the invention in addition to the reforming technology of the invention from the third invention, the synthesis gas alone or only the hydrogen or synthesis without using auxiliary fuel An embodiment which may be used by switching between gas and hydrogen, and the stored gas pressure can be handled with a low compression pressure as described in the next paragraph.

In order to cover the fuel necessary for running 500 km with gasoline with hydrogen (synthetic gas), 5 kg of hydrogen (equivalent to 56,000 L of hydrogen) and (10 g / Km = hydrogen of 11.2 L).
Therefore, the capacity of a livestock gas tank for fuel (hydrogen, synthesis gas, carbon dioxide) required for about 10km travel is a livestock gas tank capable of livestock gas of 11.2L * 10 = 112L (normal pressure) if the fuel switching loss is ignored. It will be good if there is.
Therefore, it can be designed freely as long as it is within the scope of the law and the relationship between the tank manufacturing cost and the installation space and the switching cycle to be set.

A synthetic gas storage gas tank produced from the internal combustion engine according to the first to third aspects of the invention is provided in the upper part of the vehicle, and an impact buffer (fired polyethylene, boron fiber reinforced plastic, etc.) is fixed to the gas storage tank. A storage tank that protects against explosion or explosion in the event of a car wrecking by fixing either a coating or a multi-layered structure to the storage tank.

Referring to FIG. 1, the vehicle shown in FIG. 1 is a schematic configuration diagram in which the structure of the present application is installed in a commercial vehicle front engine type commercial vehicle, and an exhaust pipe from a hydrogen rotary piston engine (internal combustion engine) installed in the front engine room. The endothermic reaction synthesis gas generation section provided in the section generates gas, and the extracted synthesis gas is stored in the storage tank MT provided in the upper section and used as fuel for the hydrogen rotary piston engine. In the schematic configuration diagram, switching the loss to the fuel of the sub tank ST,
FIG. 1B is a schematic configuration of an engine block, a synthesis gas generation endothermic reaction flow path section, a fuel supply / injection system, and a spark plug of a reciprocating engine. a schematic configuration flow diagram parts and the fuel supply and injection system ignition plug, the water HO ₂ into the engine block of a four cylinder reciprocating engine provided with a water passage K of the steam J, water H _{2 O} (or water and carbon dioxide) is supplied from the supply port steam generating unit (or / and carbon dioxide heat absorbing means) and bookmarks, intake air 0 ₂ is provided for supplying duct 3 air 0 ₂ to the inlet port a _P are supplied to the mouth a _P, the exhaust port from E _P at the conduit 4 is connected to the exhaust pipe of the synthesis gas production unit, endothermic of said exhaust pipe MS syngas product endothermic reaction portion in the exhaust pipe Reaction tube It is provided in a coil shape, and the steam J generated in the engine block of the reciprocating engine is introduced into the coiled endothermic reaction tube and carbon is newly introduced, and the exhaust gas of the synthesis gas generation unit flowing MS to the tube, to produce the exhaust gas E _X of the exhaust heat in the synthesis gas CO + H ₂ generated in the engine combustion stroke, produced synthesis gas by livestock gas in the synthesis gas storage tank (slaughtering gas tank) MT In order to make up for the shortage of the generated fuel, a sub tank ST is provided to store the sub fuel. The sub tank fuel and the synthetic gas stored in the live gas tank are switched by the switching valve CB, and the fuel supply line 5 FIG. 2 is a schematic configuration diagram of an internal combustion engine that is supplied to the injector E _C H ₂ and has a configuration in which a plug P for forced ignition is provided.

A water passage K for converting water HO ₂ into water vapor J is provided in the engine block, water H ₂ O is supplied from the supply port, and in addition to the water passage K serving as water vapor generating means, air passage K for heating CO 2. 'And a CO2 supply port are provided, and at least one of the plurality of exhaust pipes is supplied to a pipe for reforming CO2, and one of the other pipes for reforming CO2 is supplied. Whether it is a pipe for steam reforming or a syngas reforming path of the third invention, the steam J is supplied to all or a plurality of pipes, and the pipes K, K ′ as required. It is also possible to add a configuration in which a supply path for switching the supply from both is switched to either.

FIG. 2A. 1 is a cross-sectional view taken along the line AA in FIG. 1. As an example, this figure shows a synthetic gas tank having four cylindrical MTBs, and a single package made of a shock absorbing material such as foamed polyethylene, boron fiber reinforced plastic, or the like. In the state where the vehicle is fixedly held on the upper part of the vehicle, and is fixed to the fixture MT5 that is fixedly fixed to the upper part of the vehicle with the fixed holding fixture MT1. The V-shaped notch MT6 breaks due to concentrated stress, and the shock absorbing material inclusion MT3 (for example, the tank support MT2 is integrated) is detached from the fixture MT5 (completely disengages). (It is a preferable form to take a structure in which it is locked to the fixing device MT5 or the like with a thread body or the like, because this is a measure for avoiding the secondary damage in which the inclusion body MT3 of the shock absorbing material completely comes off))

As an example, when a collision or falling force is applied to the tank, a holding structure in the event of an accident is provided, and a structure (part of which is preferably connected to the car) is provided. The tank that flies off from the vehicle is made of foamed polyethylene, boron fiber reinforced plastic, impact buffering material (HTP), etc., which is provided on the outer surface of the tank and fixed to the entire surface, and absorbs or diffuses impact force. So it does not explode.
The foamed polyethylene, boron fiber reinforced plastic, and shock-absorbing materials that are fixed to the entire surface of the coating or the entire surface may not be expensive at this time, but they are produced almost 20 million units / year (by the entire Japanese automaker). The cost is reduced due to the effect.

FIG. FIG. 6 is an example of a tank mounted on a rear engine vehicle in which the shock-absorbing material MT3 is mounted perpendicularly to the traveling direction; E. The figure shows that there are no restrictions on the number and shape of the tanks. E, the tank is housed in the front and rear recesses on the roof of the car, and the aesthetics from the side are improved. F. Is a type with an engine mounted under the cabin. The shape installation direction of the gas tank MTB and the tank package MT3 to be mounted is a design problem in the relationship between the tank capacity to be installed and the gas pressure.

FIG. FIG. 5 is a partial cross-sectional view of the structure of the gas inlet / outlet portion when there is only one gas tank MTB, and the gas taken out from the synthesis gas generator S is a tank open / close valve GTbsec (for example, the electromagnetic valve is turned on when energized and turned off when deenergized. It is a schematic diagram of a structure in which gas is stored in a tank via a contact circuit) and introduced into the fuel switching valve Cb of the engine. If the force is applied to the tank and the gas storage tank comes off, the electrical wiring will be disconnected and the electromagnetic valve will be turned off so that the gas in the tank will not leak.
2 and I are. A reverse J-shaped locking and fixing structure KRsec having elasticity is provided at both ends of the fixing device MT5 fixedly fixed to the upper part of the vehicle. (Lower view) When the car is severely damaged, the reverse J-shaped This is an example of a structure (upper view) in which the reverse J-shaped locking function part of the locking structure KRsec extends and the HPE body is detached from the upper part. As long as the HPE body has a function of separating to the upper part, it does not stick to metal, synthetic resin, other, material and shape.
It is preferable to provide a carbon dioxide livestock gas tank and a hydrogen livestock gas tank in the structure of the livestock gas tank.

Although the above-mentioned supplemental described, the synthesis gas produced by the steam reforming is a schematic substance amount 1 of CO and H _2: a mixture of 1. Since the gas volume is proportional to the amount of the substance, the amount of carbon monoxide = the amount of hydrogen and the gas has a volume of 22.4 L / mol in the standard state. (Transfer efficiency of liquid hydrogen: high pressure hydrogen = 6: 1) Hydrogen is 39 g per liter (weight in tank of 700 atm).
The gas generated by the CO ₂ reforming is described in the paragraph of the second invention, but when the reforming substance is dimethyl ether as an example, the dimethyl ether is either water vapor or carbon dioxide, or both. In addition, if you react,
A. In the case of CH ₃ OCH ₃ + H ₂ O → 2CO + 4H ₂ −48.9 Kal / mol water vapor
B. In the case of CH ₃ OCH ₃ ++ CO ₂ → 3CO + 3H ₂ −58 · 8 Kal / mol carbon dioxide
C. In the case of both 2CH3OCH3 + H2O + CO2-107.7 Kal / mol become that way.
* Hydrogen properties, diffusion is quick and easy to leak, high reactivity, and especially brittle metals including steel.

FIG. 3A. FIG. 1A is a cross-sectional view in the front-rear direction of FIG. 1A, and a description of the hydrogen-compatible structure of the rotary piston engine is shown in FIG.
Rotary piston engine A water passage K that makes at least a half turn between the inner wall and the outer wall of the rotary housing is provided, and water is supplied from one water introduction pipe to the water passage K between the inner wall and the outer wall of the rotary housing. The water is sent to the endothermic reaction channel S through the carbon C insertion tube, and the water becomes steam J in the process of passing through the water passage that contacts the intake → compression → explosion → exhaust process part with the combustion heat of the fuel. The
Air O ₂ is sent into the other rotary piston engine, and then the fuel synthesis gas MTC or subtank ST fuel (any of butane, biofuel, synthesis gas, etc.) is sent into the engine, → compression → explosion → exhaust E _X next to be fed to the endothermic reaction flow path portion S, the exhaust E _X flows through the tube center portion of the endothermic reaction channel section S, carbon inserted with steam J thermal reaction channel is in the description of FIG. 3 flow synthesis gas generator tube provided in a coil shape in contact with the tube wall of the tube MS, the tube in the heat of the exhaust E _X flowing a central portion is generated in the synthesis gas is withdrawn from the take-out tube is transferred to savings gas tank MT FIG.
The explanation structure of FIG. 1B and FIG. 3 is applied to the structure of the water passage / ventilation path of the rotary housing corresponding to CO2 reforming and synthesis gas reforming.

FIG. 3B. FIG. A mixture of water vapor J and carbon C is fed into a water passage K between the inner wall and the outer wall of the rotary housing into the water (H ₂ O) introduction pipe portion of the water and comes into contact with the inner wall surface of the thermal reaction channel pipe MS in a coil shape the synthesis gas production tube provided in the flow, which is the tube structure schematic diagram central portion is generated heat in the synthesis gas in the exhaust E _X flowing retrieved from the take-out tube is transferred to savings gas tank MT.
The structure of the water passage / ventilation path of the rotary housing corresponding to CO ₂ reforming and synthesis gas reforming also applies the explanation structure of FIG. 1B to FIGS.

Figure 4 is provided to the synthesis gas production pipeline provided in a coil shape in contact with the tube inner wall surface of the thermal reaction flow pipe MS of FIG. 3 in a thin tube of a straight, exhaust between the thin tube and the thin tube E _X The design of the endothermic reaction flow path has been put to practical use in a system that makes the exhaust gas harmless by confronting the catalyst in the exhaust gas treatment system. good.

FIG. 5 is a schematic view showing a hydrogen rotary piston engine disclosed in Japanese Patent Application Laid-Open No. 2007-2111608.

FIG. 6 is a diagram showing a main configuration of an electronically controlled injection structure of a hydrogen rotary piston engine. The electronically controlled injection valve needs to inject a large capacity of 2300 NL / min in order to obtain an output of 100 KW, for example. The two injection valves 40 and 42 in the above figure are provided to inject a large volume.
Further, a large-capacity intake port 16 and an exhaust port 18 are provided on the side of the rotor housing, and the explosion chamber is divided into two when it is about to explode, and two spark plugs 14 and 15 are provided.

In recent years, hybrid vehicles and 100% electric vehicles have attracted attention.
However, if most of the automobiles are used as electric energy, there is a problem of the “Fukushima nuclear power plant” that overwhelms the power supply situation to follow the speed of electrification including home appliances, and the expansion of the power supply facilities is solved quickly It is an issue that should be done. However, the public disagrees with the current situation regarding the construction or restart of nuclear power plants, as the burden of electricity charges will increase if the nuclear power plant is abolished. I understand that there are many, and further public opinion is toward the direction of damming. Therefore, expansion of power supply facilities is a desperate situation that the weight of things by thermal power generation and natural energy becomes very high . Therefore, expanding the power generation facilities that suppress CO ₂ emissions is a problem that should be solved immediately.

In recent decades, cheap timber has been imported from foreign countries, the number of forestry workers has decreased dramatically, the forest has not been thinned, and dead trees devoured by pests such as pine wilt have been left unattended.
Furthermore, it is the vitalization of agriculture, but most of the “rice fields” have agricultural waterways, which have been fertilized for many years and have become fertile farmland. For example, “Kenaf”, which is a pulp material, and “Mulberry” in sericulture can be planted in this “rice field”, or “Yukari” from Uruguay in South America can be used. One plan is to use a small-scale carbonization device (see Fig. 10) that can be carbonized by a farmer with a single hand for lending use (lease method). For example, if the carbonization equipment that is cheaper with the price of the carbonized equipment is purchased in a five-year split, for example, a small scale that allows more forestry workers and farmers to use the purchased money with one hand. ”Carbonizing equipment” It is also possible to plant a thing that can become “bioethanol” that grows well in places where water supply is sufficient, such as taro.

The goal of reducing greenhouse gas (CO ₂ ) emissions by 25% by 2020 is being asked, and Japan's CO ₂ emissions are struggling to see how the world can reach this goal. The main players in this project are emissions from internal combustion engines and emissions from thermal power boilers, which account for about 82% of electricity generation (2012 Electricity Federation statistics). These CO ₂ starts with coal, oil and natural gas. Fossil fuels such as coal, oil, and natural gas are limited resources, and of course, resources that cannot be reproduced.

According to the Kyoto Protocol, carbon dioxide CO ₂ produced by the combustion of plant carbon C is consumed by plant carbon assimilation, so it is a plus or minus zero and is not counted as CO ₂ emissions. Therefore, in order to shift the carbon consumption of fossil fuels to plant carbon and achieve a 25% reduction in greenhouse gas CO ₂ emissions at an early stage, it is best to realize the above-mentioned synthesis gas generation cycle plan. think. (According to 2010 data from the Ministry of the Environment, greenhouse gas CO ₂ emits 30.3 billion tons worldwide, Japan is 3.8%)

The day when solar power generation (system using solar power generation panels, condensing sunlight, generating steam with heat → power generation) will become the mainstream of future power generation is not far away. However, solar power generation is not possible 24 hours full-time power generation at night, rain, and cloudy, and if it is installed on a large scale, it will be quite remote from the power usage area, so it will install new substation and transmission equipment The disadvantage is that large-capacity power storage equipment is necessary to cover only with solar power generation, and if it is a place with a good sunshine rate (for example, a desert with low annual rainfall is the leading candidate), a large amount of power transmission / reception equipment is required. (There is superconductivity invented by Japan in the above-mentioned large-capacity power storage equipment, large-scale power transmission / reception equipment, the experimental plant is already in trial operation, and the international standard of 1,100,000V was also established in 2008. Although it has just gained international approval, the gap with the estimated cost is a problem).
Therefore, if the internal combustion engine power generation of the present invention that can be operated for a short time other than the solar power generation time is used in combination with the fuel production mechanism of the present invention, it can be said that the reduction of greenhouse gas CO ₂ emission can be achieved earlier. .

Whether or not the procurement cost of carbon C as a fuel can be reduced holds the success or failure of practical use of the present application. In carbon production, when carbonized organic substances are heated with the air and oxygen flow cut off, they turn into black carbon-rich substances. The resulting product is an aggregate mainly composed of amorphous oxygen and the like, and is mostly porous and has a very large surface area. Heating causes dehydration and dehydrogenation reaction to produce a condensed polycyclic aromatic compound, which further forms a network structure, which is called carbonization.
Carbon charcoal used as a fuel while performing many operations such as thinning, pruning and undercutting. It is a concrete proposal that is a shortcut for realizing the present application to sequentially lend carbon production equipment that has a structure that can be handled in a procurement manner (subject to substituting for subsidies).

FIG. 10 is an assumed schematic diagram of the above-described small-scale carbonization apparatus. Carbonization plants suitable for the carbon material of the present application are placed in the carbon production chamber CS, and the combustion chamber FC serving as a pot door is approximately half carbonized of the carbon material of the present application. By burning the timber plant and collecting it in the collection area in the form of carbon C, it is possible to reduce the transportation cost much more than transportation with branch wood,
Plant material in an environment where oxygen from entering by introducing a timber or the like coking chamber CS to carbonized by heating (wood, etc.), heating fuel for heating the carbonizing chamber (plant material such as wood or other burnable material) The combustion chamber FC is made to burn and combusted, and the exhaust gas exhaust pipe Ex of the combustion chamber FC and the pipe J of the steam generating means for converting the water H ₂ O introduced from the water tank into water vapor are provided on the inner wall of the carbonization chamber. The gas C4 generated in the carbonization process is introduced into the combustion chamber together with water vapor through the introduction pipe C4, and is used as a fuel for heating the carbonization chamber,

The reforming part (CO ₂ reforming) having the structure described in the paragraph of the second invention is provided in the discharge part (chimney) of the exhaust gas pipe, and as an example, the reforming substance is dimethyl ether, and the catalyst If the reforming section is made to react with either dimethyl ether or one of water vapor or carbon dioxide to make the fuel of the small-scale carbonization device, the fuel consumed for carbonization is further reduced. Reduction of effect gas emissions.
Furthermore, by using a reforming section (CO ₂ reforming), it is possible to use fossil fuels such as coal, and it is possible to use it as a starting reforming material that reforms wood, etc., used as fuel into plant raw material C.
As an example, the catalyst can be used in combination with other metals or compounds in addition to iron-based metals and / or compounds. Examples of other metals or compounds include zinc, nickel, chromium manganese, tin, cerium, lanthanum, and the like. These compounds, other metals or compounds.

The synthesis gas described above is not limited to hydrogen and carbon monoxide. The synthesis gas represents a main component, and includes, for example, unburned carbon, carbon dioxide, moisture, and other gases and impurities present in the atmosphere. This includes cases where

The procurement cost of carbon (plant raw material C) is currently higher than that of natural gas (methane, butane, etc.), coal, and petroleum fossil fuels. Until it is obtained, or the law of strengthening the emission control of greenhouse gas CO ₂ is made, the procurement of carbon will be done with natural gas (methane etc.) or directly with natural gas (methane etc.) as fuel and the whole society There is also a way to switch when the desire for carbon increases and the cost of carbon procurement can be paid,
However, I think that the speed of progress in chemical technology is progressing in proportion to "needs",
Therefore, if the need for procurement of renewable carbon C, which is the main raw material of the present application, becomes high, we are confident that the procurement technology will evolve with acceleration.
The carbon used in the internal combustion engine cycle of the present application is the cheapest to use “coal” as powder for the time being, so the fossil fuel will be used until the renewable carbon C procurement system is complete. It will take the form of shifting to a carbon C procurement system that can be sequentially regenerated.

The amount of purchase of greenhouse gas CO ₂ emission allowances in Japan is estimated to be about 1 trillions of billions of yen. If this purchase amount is used as part of the carbon procurement cost, the time of realization of the present invention will be explained. Will be faster.
* From transportation by transportation equipment if it is used as a transportation means of mixed gas of hydrogen and carbon monoxide, carbon dioxide, hydrogen, etc. in pipelines from chemical factories, steel factories, aluminum factories, dust incinerators, oil refining and factories, etc. The transportation cost can be greatly reduced.
Each US and European country has a hydrogen transport pipeline of thousands of kilometers, and should be realized early with the support of the government in order to survive the world as a competitor.

The power generation facility powered by the internal combustion engine of the present application is a relatively small-scale power generation facility. Because it can be a decentralized power generation system with self-sufficiency in units of mass such as remote islands, mountainous remote areas, industrial parks, submarine transmission cables and power demand It is possible to drastically reduce power transmission facilities, power transformation facilities, and power reception facilities that respond to changes in power consumption.
Furthermore, the current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of the present application do not need to be adjacent to the water source, and have the advantage that they can be installed as close to the power demand area as possible.

When methanol is used as a fuel for an internal combustion engine, methanol is originally synthesized from hydrogen and carbon monoxide at a high pressure advantageous from chemical equilibrium. Therefore, it is most efficient in terms of energy to use it in the form of synthesis gas of hydrogen and carbon monoxide, rather than converting it to hydrogen.

Although transportation of compressed hydrogen and liquid hydrogen is carried out, in order to compensate for the problem that the volume storage density of hydrogen gas is small, hydrogen is pressurized to 14.7 to 19.6 MPa and transported as compressed hydrogen. Mo steel hydrogen container is heavy. For example, a trailer vehicle that transports 100 kg of hydrogen requires 7 tons of hydrogen container. To reduce the cost of transporting compressed hydrogen, aluminum alloy liners and high-density polyethylene liners are used. It is necessary to make a tank reinforced with glass fiber or carbon fiber,
Under current regulations (in Japan, registration of JIS B 8265 has been completed and internationally there is ISO 16528) CFRP for transportation (tank with high-density polyethylene liner reinforced with glass fiber or carbon fiber on the entire surface) ) Since the container has a pressure of up to a capacity of 35 MPa, it is necessary to relax regulations in order to utilize the container. (Japan Industrial Gas Association, hydrogen gas container standards)

On the other hand, liquid hydrogen has a volume storage density 800 times higher than that of hydrogen gas, and tank trucks or insulated containers are used. However, liquid hydrogen requires energy for liquefaction and has a boiling point of −253 ° C. and evaporation loss. There are disadvantages that occur.

The internal combustion engine of the present invention uses synthesis gas as fuel, but the synthesis gas is a pipe piping supply in a transport equipment on-board engine , and the accumulation pressure of a livestock gas tank for livestock synthesis gas generated by the internal combustion engine is There is no need to use a 35 MPa livestock gas tank of compressed gas mounted on the existing hydrogen engine vehicle mentioned above, and it may be about 1/40 of the accumulated pressure, and the energy used for the pressurizing pump can be used to reduce the accumulated pressure. There is no need, and the structure of the gas storage tank can be made to be at most several MPa within the current regulations.

Pipeline transportation is optimal for steady mass transportation of hydrogen, and the synthesis gas of this application is similar to hydrogen in Europe and the United States. It is the best way to do it.
As the pipe material of the hydrogen pipeline, in the current advanced technology, if it is a sour-resistant material with a reduced amount of vanadium and a small amount of nickel or chromium, compared with ordinary line pipe steel, it can be used in a normal transportation environment. It is said that the cost can be increased to 10% or less.

The rotary engine vehicle powered by hydrogen is a Mazda Premacy Hydrogen RE hybrid vehicle that has a structure that can be selected to travel using either hydrogen as fuel or gasoline as fuel. A high-pressure hydrogen fuel tank (35MPa, 74L) And a gasoline tank is mounted on the vehicle, electricity is generated by rotating a hydrogen (or gasoline) rotary engine and stored in a lithium ion battery, and driving of the wheel is electricity stored in the battery,
The feature of this car is that the engine is operated with good fuel economy, and the control of the vehicle speed fluctuations depending on the running state of the car is electric control.
Disadvantages include a short mileage of 100 km in a high-pressure hydrogen fuel tank, and the hydrogen transportation means (assuming transportation by car) has a poor ratio of hydrogen loading weight to the tank weight, leading to the development of infrastructure such as hydrogen stations. There are no points and high hydrogen production & transportation cost.

The hydrogen engine bus developed by Tokyo City University, which uses hydrogen as fuel, is loaded with six tanks compressed to 35MPa on the roof. The main improvements in the engine are the addition of an intake manifold, hydrogen injection valve and spark plug.

A hydrogen reciprocating engine and a wagon type Musashi 10 developed and developed by Tokyo City University using hydrogen as a fuel, is a hydrogen engine with a hydrogen cooling intercooler, equipped with a tank of 100 L of liquid hydrogen and continuously running at 300 Km per charge. It is a car that made it possible.
Disadvantages of the above-mentioned existing vehicles that use hydrogen as a fuel are that the ratio of hydrogen loading to the tank weight of the hydrogen transport means (assuming transport by car) is poor, the infrastructure development such as the hydrogen station does not progress, and the hydrogen production cost It is a high point.

The hydrogen rotary piston engine Mazda (company name), and generating the hydrogen H ₂ as a fuel, since by rotating the motor in the electric can use the power component as power generators, dwell as a power generator generating The components are applied to the internal combustion engine of the present application.

In the case of the power generation equipment in the previous paragraph, steelworks, chemical factories, aluminum manufacturing factories, foundry factories, forging factories, garbage incinerators, and oil refineries that use synthesis gas and hydrogen as by-products or dispose of a large amount of heat. If a power plant is installed adjacent to or close to a place, the running cost can be further reduced.

In the case of the internal combustion engine power generation equipment of the present application, a relatively small scale power generation equipment (if the internal combustion engine power generator is assumed to have an output machine of 1000 KW / H as 1 unit / unit, 1 unit to several hundred units The number of units can be set as a decentralized power generation system with self-sufficiency in units of mass, such as remote islands, mountainous areas, and industrial parks. It is possible to greatly reduce the power transmission facilities and power transformation / reception facilities corresponding to the changes.
Furthermore, the current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of the present application do not need to be adjacent to the water source, and have the advantage that they can be installed as close to the power demand area as possible.

The carbon sources mentioned above are dead trees that have been eaten by pests such as thinning and pine wilt, and rice husks and husks generated in Japanese rice farming are discarded. Cultivated kenaf (Hibiscus cannabinus L) in vacant land such as fallow land, which can be mixed gas production plant carbon (C) at a rate of carbon (C) of said plant It goes without saying that cultivating corn, sugarcane, etc. in vacant land such as fallow land can be used as biofuel for plants, but many rice fields have agricultural waterways. In addition, since it has been fertilized for many years, for example, cultivated taro, wheat, and actually edible, the waste part is made into the biofuel of the plant or the carbon of the plant (C) and the wheat straw is converted into the carbon of the plant ( There is also a method to make up for the difference between the income obtained from them and the income obtained from rice cultivation, etc.

Agricultural work with 2 to 3 small rice fields as a single rice field as a measure to expand the scale of agriculture, which has been implemented in the past 20 years as a measure against rice prices (Urg Island) for agriculture (rice farmers) that has been considered in the country. Measures to increase efficiency, measures to increase the size of several farmers as one company, agricultural income compensation system, a subsidy subsidy policy (2.5 trillion yen) to cope with a decrease in rice demand There is a policy to support, but none of these policies are far enough to make Japanese rice farmers an attractive profession for the next generation, using the carbon (C) of the plant as a fuel source. To achieve this policy, “Reducing CO ₂ emissions in response to global warming” and “Making agriculture and forestry an attractive occupation” and further revitalizing the Japanese automobile industry. We can expect effect of "one stone several birds" .

Various embodiments that can be easily conceived from the events described in the present specification and claims are included in the present invention as long as they do not depart from the scope of the claims.

Although this project is partly undeveloped, the internal combustion engine of the present application can be implemented. Furthermore, it can be used for those industries that spread to people in industries related to them.
Above all, creating a cycle that maximizes the use of your country's resources will create a foundation for Japan's 100-year total, leading to the development of those industries.

A. FIG. 3 is a schematic structural diagram of water and carbon as synthesis gas of H ₂ and CO in the engine in an internal combustion engine (rotary piston engine). B. The schematic block diagram of the engine block of a water vapor | steam production | generation part of a reciprocating engine, a synthetic gas production | generation endothermic reaction flow path part, a fuel supply / injection system | strain, and a spark plug. A-F FIG. The example of several types of storage gas tank installation of the storage gas tank installation procedure. H. The partial cross section of the cylinder of 1 unit of a gas storage tank, and the gas inlet / outlet pipe | tube partial view and partial sectional drawing of the said cylinder. i. Tank comprehensive body holding / removal diagram. A. FIG. 1B is a schematic cross-sectional view from the EAsec rotary engine of FIG. 1A to the endothermic reaction flow path portion. B. FIG. A. Type cross-sectional view of pressure inserting the vapor and carbon in H _{2 O} supply pipe. The schematic structural example figure which comprised the structure of the endothermic reaction flow-path part provided in the engine exhaust pipe part and the gas production | generation pipe | tube with several thin tubes. Schematic which shows the rotary engine of the control apparatus of Unexamined-Japanese-Patent No. 2007-2111608. A, electronic control of a rotor same as above, and hydrogen injection structure schematic cross-sectional view of a fuel injection device of a hydrogen rotary piston engine disclosed in Japanese Patent Application Laid-Open No. 2007-064169. B, A, the longitudinal cross-sectional view of a figure. The block diagram of embodiment of the fuel reformed gas engine of Unexamined-Japanese-Patent No. 2002-039022. 1 is a schematic configuration diagram of an electronically controlled hydrogen injection system, intake / exhaust ports, and spark plugs for reciprocating (diesel engine) fuel supply. FIG. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic structural diagram of an exhaust gas treatment device provided in an exhaust pipe that generates Karman vortices of Japanese Patent Application Laid-Open No. 2002-256849 and sucks CO ₂ of exhaust gas into water. An example figure of a small carbon generator. Annual bar graph that captures past years of carbon dioxide emissions statistics from fossil fuels around the world.

An internal combustion engine that contributes to the reduction of greenhouse gas emissions, particularly producing carbon C and water H ₂ O, mainly plant, into synthesis gas (H ₂ + CO) in the internal combustion engine, Further, carbon dioxide discharged from the combustion of the synthesis gas is separated as fuel for the internal combustion engine and reformed into synthesis gas H ₂ + CO and hydrogen in the internal combustion engine, and the synthesis gas and hydrogen are used as fuel for the internal combustion engine. To do.

Greenhouse gases are a major cause of global warming, and it is a common recognition in the world to think that “greenhouse gases should be reduced.” However, it is at the stage of “specific numerical targets…” In the era of international price competition, the current situation is that the story has not progressed because it will incur greenhouse gas reduction costs.
As a power source of an automobile (internal combustion engine) of a greenhouse gas emission reduction measure as of 2014, an electric vehicle, a hybrid with hydrogen, or an engine system using only hydrogen or "bioethanol" as fuel There is also a technology for reducing greenhouse gas emissions by reforming a fuel of 2008-298030 or “bioethanol” into a fuel containing hydrogen and carbon monoxide and using the reformed gas as a fuel. There are still problems that must be solved in order to commercialize products, and it is recognized that there is a part that each problem is lacking in the process of solving.
Of the technologies mentioned above, in the technology using electricity as the power source, according to the statistics of the Electricity Federation of 2011, about 82% of Japan's total power generation is thermal power generation. since the discharging "CO _2" and using the fossil fuels, including unless realized measures that do not emit "CO _2" from the power plant, a greenhouse global warming electricity as a power source It cannot be said that it is a power source of the internal combustion engine that contributes to the reduction of the effect gas.
Moreover, nuclear power generation is a power source that does not emit “CO ₂ ”, which uses electricity as the power source of the above technology to reduce greenhouse gases. However, there is a problem of “Fukushima nuclear power plant”, so it is difficult to establish a new one. And I think that the view that it goes to the direction of decommissioning occupies a lot.

Equipment for reducing the “CO ₂ ” already exists, and the method is a proposal to sequester the discharged carbon dioxide deeply (A) or sequestered (B). The world's largest coal-fired power plant in the United States was completed in 2014, but the treatment of “CO ₂ ” emitted by this power generation is a structure (A) that can be contained in a 1500 m underground layer. However, there is a problem that the construction cost of the plant is twice as high as usual, and there is an additional energy cost for containment in the 1,500m underground layer, which is added to the electricity bill and becomes a consumer burden.

Various technologies have been proposed one after another for the technology to obtain synthesis gas or hydrogen gas by reforming the above-mentioned “CO ₂ ”, and have already been proposed in the in-service sector as an energy generation technology for blast furnace gas and converter gas in steelworks. There are many technologies that have been put to practical use, and the gas emitted in the power generation process of thermal power plants is also used to increase energy efficiency, but most of them are fixed-form features in the large-scale equipment industry. In addition, no feasible technology has been proposed (not found) for reforming “CO ₂ ” discharged from the internal combustion engine in the internal combustion engine that can be mounted on the moving form and using it as a fuel for the internal combustion engine.

Patent 5647364. Engine mechanism of rotary piston engine car. JP-A-11-106770. Power generation method and apparatus using dimethyl ether reformed gas Patent 4231735. Method and apparatus for separating and recovering carbon dioxide JP 2007-177684 A, a carbon dioxide recovery device for a vehicle, and a vehicle including the same. Reaction of hydrocarbons with water vapor or carbon dioxide. Patent 4,609,718 Hydrogen rotary piston engine fuel injection device Japanese Patent Application No. 10-543729 (patent 33455782) synthesis gas production method.

A rotary piston engine combusted by auxiliary fuel, a water supply means for supplying water to the rotor housing of the rotary piston engine from the introduction pipe, and the supplied water is steamed by the heat of the rotor housing, And a livestock gas means for storing the gas that is generated by the endothermic reaction using the exhaust heat after the combustion process of the rotary piston engine and generating the fuel while the auxiliary fuel is used. There is a technique (for example, Patent Document 1) characterized by a structure including a switching means for switching the livestock gas of the livestock gas means and the auxiliary fuel to be supplied to the rotary piston engine, and this application is based on this technique. as carbon dioxide in the exhaust gas from the combustion of the fuel (CO ₂₎ also to adopt a technique of reforming a fuel, further We are in a technology that is a greenhouse gas emission reduction measures that.

Using dimethyl ether reformed gas, characterized in that dimethyl ether is reformed by adding water vapor or carbon dioxide to dimethyl ether to cause a catalytic reaction to obtain synthesis gas or hydrogen gas, and this gas is used as a fuel for a prime mover There is a power generation method, and the above power generation method (for example, Patent Document 2), characterized in that the reforming of dimethyl ether is performed using medium to low temperature waste heat from 200 ° C to 500 ° C.
In this application, by incorporating a part of this technique into the technique of Patent Document 1 above, the carbon dioxide exhausted by the technique of Patent Document 1 is also used as the fuel of the internal combustion engine, thereby improving the fuel consumption. Greenhouse gas (CO ₂ ) emissions from the institution are approaching “zero”, and the technology has become a greenhouse gas reduction measure by carbon assimilation of plants.

A method of separating and recovering carbon dioxide from a by-product gas generated at a steel works by chemical absorption method, which absorbs carbon dioxide from the gas with chemical absorption liquid and then heats the chemical absorption liquid to separate carbon dioxide A method for separating and recovering carbon dioxide, characterized by utilizing or utilizing low-grade exhaust heat of 500 ° C. or less generated at a steelworks. (For example, Patent Document 3)
In order to separate and recover the carbon dioxide of the present application, there is a problem that it is necessary to install a membrane type permeation device that allows several kinds of permeable membranes to pass through the exhaust gas, or to install a vacuum pump or the like.

And in silencers vehicle carbon dioxide device in an exhaust system of an automobile is mounted between the exhaust pipe, provided with a C0 ₂ absorption portion which is connected via an absorbent material and the three-way of the solenoid valve carbon dioxide , A structure in which carbon dioxide is released from the aqueous solution of alkanone compound that has absorbed carbon dioxide by absorbing heat from the engine cooling heat through a solenoid valve, and the separated carbon dioxide is used to regenerate used alkanolamine compounds. (For example, Patent Document 4). This technology is used to regenerate the aqueous solution of alkanone compound that has absorbed carbon dioxide as an application of carbon dioxide separated by the technology that separates carbon dioxide in automobile exhaust gas. It can be used as a technique for separating carbon.
* This is a structure that releases carbon dioxide by absorbing the cooling heat of the engine. In this application, heat is absorbed directly from the engine block from the engine block, and the heat is used for water vapor generating means that turns water into water vapor. Although this point is different, this technique can be adopted in the present application as a technique for separating carbon dioxide in the exhaust gas of an automobile.

A method of reacting a hydrocarbon with water vapor or carbon dioxide or a mixture thereof under a net endothermic condition to form a gas containing a carbon compound and hydrogen, which is acidic or amphoteric with nickel and cobalt compounds and alkali metal oxides. There is a technique (for example, Patent Document 5) relating to the above method characterized by using a catalyst comprising a water-insoluble compound with an oxide or mixed oxide.
In this application, by incorporating a part of this technique into the technique of Patent Document 1 above, the carbon dioxide exhausted by the technique of Patent Document 1 is also used as the fuel of the internal combustion engine, thereby improving the fuel consumption. Greenhouse gas (CO ₂ ) emissions from the institution are approaching “zero”, and the technology has become a greenhouse gas reduction measure by carbon assimilation of plants.

A fuel injection device for a hydrogen rotary piston engine, which is attached to a rotor housing that forms a working chamber of the hydrogen rotary piston engine and directly injects hydrogen into the working chamber of the hydrogen rotary piston engine, and the hydrogen injector is operated Hydrogen injection timing control means for controlling injection timing so that hydrogen is injected into the chamber at a predetermined timing during the compression stroke, and hydrogen from the hydrogen injector is in the low rotation range of the hydrogen rotary piston engine. And a hydrogen outflow direction setting means for setting the hydrogen injection direction so as to flow out toward the leading region and out toward the central region of the working chamber in the compression stroke in the high rotation region. (For example, Patent Document 6).
* Since hydrogen gas and carbon monoxide, which are syngas, are almost equivalent in terms of energy, that is, the (higher) calorific value is almost the same, the structure that uses the syngas of the present application as a fuel in an internal combustion engine is rotary. Prior literature describing a structure using hydrogen as fuel in a piston engine is the most appropriate, and is therefore taken up.

A method for producing a synthesis gas by reacting a carbon-containing organic compound with steam and / or carbon dioxide in the presence of a catalyst, wherein the catalyst is composed of a metal oxide as a support, comprising rhodium, ruthenium, iridium, palladium, and platinum. There exists a technique (for example, patent document 7) regarding what uses the catalyst which carry | supported at least 1 type of catalyst metal chosen from these.

The technology of the present application is a new technology that can be implemented by combining partial technologies lacking the decisive factor of any one of the above-mentioned prior art documents 1, 2, 3, 4, and 7, and the “CO ₂ ” in the exhaust gas is also converted into the internal combustion engine. It was reformed into synthesis gas to improve fuel efficiency (Km / L) as a fuel. “It has become a new technology that produces a new effect of reducing global warming by reducing CO ₂ emissions.

The biggest challenge is the reduction of “CO ₂ ” (emissions) to cope with global warming.
Inventing one method of measures for that purpose and the mechanism constituting the method.

The first invention to solve the biggest problem is
An internal combustion engine using hydrogen as fuel, and water and carbon dioxide (stock gas is stored in a livestock gas tank) are introduced into the water passage from the introduction port for introducing water by providing a water passage in the engine block of the internal combustion engine. And the heat of the engine block of the internal combustion engine due to the combustion of the engine is absorbed to turn the water into water vapor, and the carbon dioxide is converted into carbon dioxide as an endothermic gas and discharged from the water passage to the exhaust pipe. , whereas the hydrogen gas in the combustion of the fuel is discharged into the exhaust passage from the exhaust port of the engine block becomes a gas of high temperature mainly water vapor and nitrogen, the catalyst (Ni-based mainstream) the exhaust duct hydrocarbon compound with opposed (e.g. dimethyl ether) and water gas to water vapor reforming passage is provided with a steam reforming path to modify the water vapor to synthesis gas Nikki flowing hydrocarbon compound and the exhaust conduit Was introduced into Kiaratame matter tracts is reacted with steam and hydrocarbon compounds in the gas to the synthesis gas produced and to generate a synthesis gas of hydrogen and carbon monoxide to livestock gas in the synthesis gas slaughtering tank And
Further, a carbon dioxide steam reforming section for reforming carbon dioxide into synthesis gas is provided in the exhaust pipe, and a catalyst for reforming carbon dioxide into synthesis gas (for example, an iron-based metal) is provided in the carbon dioxide steam reforming section. Examples of other metals or compounds that can be used in combination with other metals or compounds in addition to compounds include zinc, nickel, chromium, manganese, tin, cerium, lanthanum and their compounds, other metals Alternatively, the hydrocarbon compound is introduced and the water vapor in the gas flowing in the exhaust pipe and the carbon dioxide of the endothermic gas are brought into contact with the catalyst to react with each other, so Carbon dioxide synthesis gas is generated and taken out, and the hydrogen and carbon monoxide synthesis gas taken out are fed into the synthetic gas livestock gas tank for livestock gas,
Hydrogen separation reforming unit (for example, proton conductive ceramic tube reforming) that reforms the synthesis gas of hydrogen and carbon monoxide generated in the steam reforming path and carbon dioxide steam reforming unit to extract hydrogen and carbon dioxide separately ) Is provided in the exhaust pipe, and hydrogen and carbon monoxide synthesis gas that has been stored in the synthesis gas animal gas tank is introduced into the hydrogen separation and reforming unit, and again in the hydrogen separation and reforming unit. Hydrogen and carbon dioxide taken out separately by reacting with the exhaust heat of the internal combustion engine and taking out the hydrogen and carbon dioxide are provided with separate livestock gas tanks, and the hydrogen is used as fuel for the internal combustion engine To provide a method for reducing greenhouse gas emissions.

(The carbon dioxide taken out is carbon dioxide introduced into the water passage from the inlet for introducing water described in the first invention.)
The second invention is
A method for reducing greenhouse gas emissions according to the first aspect of the present invention is provided , wherein the internal combustion engine is mounted on a transport device to be an onboard engine of the transport device .
According to a third aspect of the present invention, the internal combustion engine is mounted on an automobile, the internal combustion engine mounted on the automobile is operated under a certain condition, is generated with the rotational force, and is stored in a capacitor. characterized in that in the manner to run the motor vehicle as a source, to provide a greenhouse gas emission reduction method according to the first aspect of the present invention.
A fourth aspect of the present invention travels in the power to stop the operation of the internal combustion institutions when the storage amount of the storage battery becomes the upper limit set value, it Nikki the manner travels with the internal combustion institution when the storage amount becomes the lower limit set value The method for reducing greenhouse gas emissions according to the fourth invention is provided.
The fifth invention is
And providing a charging means for energy storage in the automobile, characterized in that the electricity charged by the charging means Nikki in the manner to run the motor vehicle as a power source, according to the third invention or the fourth invention Provide a method for reducing greenhouse gas emissions.
The sixth invention is
Characterized in that Nikki the generation power of the intact power generator rotational force of the internal combustion engine, to provide a greenhouse gas emission reduction method according to the first aspect of the present invention.
The seventh invention is
Waste hydrogen is used as a fuel for the internal combustion engine, and either waste heat or steam or carbon dioxide is used as a reforming material for steam reforming of the internal combustion engine. The greenhouse gas reduction method according to the first invention is provided.
The eighth invention is
The livestock gas means of the internal combustion engine includes the livestock gas tank (one or more of a synthetic gas tank, a hydrogen gas tank, and a carbon dioxide gas tank) mounted on the upper part of the vehicle body, or a chassis portion of the car. The method for reducing a greenhouse gas according to the first invention is provided , characterized in that the method is mounted on a vehicle or on a vehicle .
The ninth invention is
Above Ki畜gas means any damage preventing means for preventing the tank damage, to separate the tank from the installation portion of the vehicle in a collision, if the tank separating means, both of either one or, that Nikki a means A feature of the greenhouse gas reduction method according to the eighth invention is provided.

The tenth invention is
Using the exhaust heat of the internal combustion engine as a reforming heat source, either or both of a carbon-containing compound and a hydrogen-containing compound (for example, sodium hydrogen carbonate, NaHCO ₃ ) are processed and thermally decomposed or reformed to produce hydrogen H _2. The greenhouse gas according to the first invention , wherein at least one of at least one of carbon C and carbon dioxide CO ₂ is taken out and stored in the livestock gas tank. Provide reduction methods.

Detailed Description of the Invention

Specific examples of the invention Description of the first invention,
A steam reforming facility that takes out a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) by reacting water, (H ₂ O), and a hydrocarbon compound with exhaust heat of the internal combustion engine. A water passage K is provided in the engine block 1 of the engine, and either water H ₂ O is converted into steam J or steam is converted into heated steam as steam generating means,
An endothermic reaction channel S is provided in the exhaust pipe MS after the combustion stroke of the internal combustion engine, carbon (mainly carbon C from plants) is introduced into the endothermic reaction channel, and the steam or heated steam , Carbon is reacted in an endothermic reaction channel, hydrogen H ₂ and carbon monoxide CO (synthetic gas) are taken out, and a livestock gas tank MT for stocking the mixed gas of the taken out hydrogen and carbon monoxide is provided. The extracted hydrogen and carbon monoxide mixed gas is used as livestock gas or as the fuel for the internal combustion engine that generates the mixed gas via the livestock gas tank. And
The exhaust heat of the internal combustion engine is mainly exhaust heat used to absorb heat in a water passage in the engine block of the internal combustion engine and turn water into steam, and exhaust heat obtained by endothermic reaction of heat in the exhaust gas in the exhaust gas pipe. The exhaust heat in the engine block and the exhaust heat obtained by endothermic reaction of the heat in the exhaust gas in the exhaust gas pipe are mainly exhaust heat from two places, and should be emphasized. In order to prevent engine overheat, the heat that has been cooled by the radiator (discarded using power) is utilized as a means for generating water vapor.
Further, by providing a means for absorbing the refrigerant compression heat that is discarded from the air-conduit line using power, further heat can be used for the endothermic reaction.

This is a take-out facility that takes out a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) by reacting water, (H ₂ O), and carbon (C) with exhaust heat of the internal combustion engine. A water passage K is provided in the engine block 1 of the engine, and either water H ₂ O and carbon are injected under pressure to form water vapor J or water vapor to be heated water vapor as a water vapor generating means. {The pressurizing pressure at this time is about 5 kg / cm ² . (See FIG. 3B)}
This application ways to generate a synthesis gas of the known art is a configuration illustrated steam reforming, the steam reforming process, the endothermic reaction flow path catalyst the medium at about 200 ° to 300 ° is facing thermal There are also fuel generating means for endothermic reaction, dry reforming method, partial oxidation method, autothermal reforming method, and the like, and the above-mentioned synthesis gas generating method can be adopted instead of the steam reforming method of the present application.

In view of the energy efficiency of internal combustion engines (about 30% for rotary engines and about 60% of waste (waste) heat available for syngas reaction), it is not enough to produce 100% of the required amount of fuel. In this case, supplementary means for supplementing from other places are provided as supplementary, and as an example of the supplementary means, the present application is provided with an auxiliary tank ST, and fuel in the auxiliary tank (bioethanol mainly made from plant carbon) Or, synthesis gas or hydrogen) is used as a supplementary fuel when it is not enough to produce 100% of the required amount of fuel.
Ultimately, the carbon is used as a measure to reduce greenhouse gas emissions by bringing the carbon closer to 100% use from the waste.

As an example, the present application adopts a composite fuel system in which a sub-tank fuel and a mixed gas generated in the internal combustion engine are switched and used.
However, if hydrogen H ₂ and carbon monoxide CO (synthetic gas), which are the main fuels, are produced while using the sub-tank fuel, there is no place where the produced gas is livestock gas and livestock gas that is livestock gas. It is necessary to provide means, and the present application is provided with a livestock gas tank for livestock gas means, and hydrogen H ₂ and carbon monoxide CO (synthetic gas) as main fuels continue to be generated even when sub tank fuel is used. We continue to fill the animal gas tank,
Accordingly, when the livestock gas tank is filled up to the set upper limit, the fuel switching valve switches the synthesis gas to use via the livestock gas tank, and when it reaches the set lower limit of the livestock gas tank, the engine structure is provided with fuel switching means that uses the subtank fuel. ,
The reason why the mixed gas generated by the internal combustion engine is used via the livestock gas tank is that the mixed gas also changes the composition of the gas component generated depending on the raw materials and the temperature of the production site. Uniformity is intended.

1st invention The carbon dioxide absorption means (A) which makes water absorb the carbon dioxide in combustion gas of an internal combustion engine is provided, or the separation means (B) which isolate | separates the carbon dioxide in exhaust gas is provided, and the said ( A) and (B) are respectively provided with livestock water means and the livestock gas means to feed livestock water and livestock gas, respectively, and either one or both of (A) and (B) above It is introduced together with water into an inlet for supplying water to the engine block (FIG. 1B, H ₂ O inlet) and combustion heat in the internal combustion engine {the combustion heat of the internal combustion engine is a water passage (in the engine block of the internal combustion engine ( Is equivalent to the cooling water channel of the engine block cooling water), water is converted into water vapor, water is converted into water vapor, and carbon dioxide is converted into endothermic carbon dioxide. Reforming channel (carbon dioxide reforming In the reforming flow path of the reforming flow path of the steam reforming in order to distinguish from the steam reforming, as an example, other metals or compounds can be used in combination with iron-based metal and / or compound, Examples of other metals or compounds include zinc, nickel, chromium manganese, tin, cerium, lanthanum and their compounds, other metals or compounds, and a hydrocarbon compound (eg, dimethyl ether) upstream of the reforming path. CH ₃ OCH ₃ ) and the reforming channel of the reforming channel (name changed because of reforming of carbon dioxide) provided in the internal combustion engine together with the water vapor and endothermic carbon dioxide The catalyst is opposed to the gas {hydrocarbon compound (eg dimethyl ether CH ₃ OCH ₃ ) and either water vapor or endothermic carbon dioxide]. By contacting both or}, to generate a synthesis gas of hydrogen and carbon monoxide, which has a configuration shall be the fuel of the engine via livestock gas tank, described in {in this application Remarks (B) The detailed explanation of (A) is omitted. }

The reaction formula when the hydrocarbon compound is dimethyl ether is
A. _{CH 3 OCH 3 + H 2 O} → 2CO + 4H 2 -48.9Kal / mol
B. CH ₃ OCH ₃ ++ CO ₂ → 3CO + 3H ₂ −58 · 8 Kal / mol
The reaction temperature is 200 to 500 ° C., preferably 250 to 450 ° C.
The reaction pressure is preferably atmospheric pressure to 10 kg / cm ² .
Many technologies using methane in addition to dimethyl ether as a hydrocarbon compound have been disclosed.

The carbon dioxide absorption means (A) and carbon dioxide separation and extraction means (B) for absorbing carbon dioxide by a known technique,
(A) is disclosed in JP 2010-526759, JP 33455782, JP 2009-77457, JP 2001-213545, JP 2007-177684, and the like.
(B) is disclosed in Japanese Patent Application No. 2001-48591 (Karman vortex), Japanese Patent Application Laid-Open No. 2007-177684, etc.
Prior art of the method for producing hydrogen and carbon monoxide by the carbon dioxide reforming reaction includes Japanese Patent Application Laid-Open No. 08-231204 and Japanese Patent Application Laid-Open No. Hei 11 of Japanese Patent Application Laid-Open No. H11-296275. -106770 etc.
Incorporating this technology into this application, the carbon dioxide in the exhaust gas is “a reforming of the internal combustion engine fuel only into the fuel of the internal combustion engine of this application” is a great greenhouse gas emission reduction measure, A feature of the present invention is that fuel is generated with the discarded energy (approximately 70%, and approximately 60% can be used for reforming), and fuel efficiency is improved by the amount of fuel generation.

Among the inventions of the present application, the carbon C of the synthesis gas generating material when the reforming means for reforming carbon dioxide is used may be carbon C using fossil fuel, and the carbon dioxide is reformed into synthesis gas. Therefore, it is possible to reduce CO ₂ emissions of at least several tens of percent, and this is a measure for reducing greenhouse gas emissions.

Syngas reforming path described in the first invention, the hydrogen produced by the first inventions (H _2), a mixed gas of carbon monoxide (CO), the exhaust heat {the internal combustion engine of the internal combustion engine the exhaust heat is to that water vapor with water to a waste heat of the steam} in the water flow path in the engine block of an internal combustion engine, for example, again an internal combustion engine with a proton conductive ceramic tube heat (300 ° C ˜800 ° C.) (The exhaust heat of the internal combustion engine is exhaust heat obtained by absorbing the heat in the exhaust gas in the exhaust gas pipe) to separate hydrogen (H ₂ ) and carbon dioxide (CO ₂ ) The hydrogen hydrogen gas tank and the carbon dioxide livestock gas tank for separately gasifying the hydrogen and carbon dioxide are provided, respectively, and the carbon dioxide is used as a starting material from which the hydrogen is extracted. The internal combustion machine via the hydrogen livestock gas tank It is a structural structure used as a fuel for Seki.

When exhaust gas temperature in the exhaust pipe is insufficient, an exhaust gas combustion section is provided upstream of the synthesis gas reforming path,
You may introduce and reheat the fuel and oxygen (air) which are the livestock gas of the extent which supplements the shortage temperature to the unburned fuel gas or unburned carbon particle in exhaust gas.

The carbon dioxide reforming is a technique in which a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) is taken out by contacting with a catalyst together with a carbon dioxide and steam reforming material (Japanese Patent Application Laid-Open No. H11-11). 106770) is incorporated into the present application, and carbon dioxide is also used as a fuel for the internal combustion engine, thereby improving fuel efficiency and further reducing greenhouse gas emissions.

The present application introduces carbon dioxide and water into an inlet (H ₂ O inlet in FIG. 1B) for introducing water into the engine block (rotary housing) of the engine for the carbon dioxide reforming. Heat is absorbed in a water passage K provided between the inner and outer walls of the engine block (rotary housing), water is absorbed into water vapor, and carbon dioxide is absorbed to raise the gas to a high temperature and mixed, and a catalyst is placed downstream of the engine exhaust port. There is an opposite reforming path (the name is changed because it is carbon dioxide reforming), and a hydrocarbon compound (for example, dimethyl ether CH ₃ OCH ₃ ) is introduced upstream of the reforming path and the steam and The gas {hydrocarbon compound (eg, dimethyl ether CH ₃ OCH ₃ ) and water vapor or endothermic carbon dioxide, or both} is added to the catalyst together with endothermic carbon dioxide} To remove the mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO), or add the water to steam in the water passage K of the engine block (rotary housing) of the engine. A water passage K ′ of the engine block (rotary housing) of the engine is further provided to be a two-line pipe line for heating carbon dioxide, and (exhaust gas after engine combustion process) and on whether one of a configuration is brought into contact with a catalyst Nikki is facing the including) the exhaust pipe that monkey merging mouth near hydrogen (H ₂₎ and the configuration for taking out a mixed gas of carbon monoxide (CO) For example, the catalyst may be used in combination with other metals or compounds in addition to iron-based metals and / or compounds. Examples of other metals or compounds include zinc, nickel There chromium manganese, tin, Seryuumu, lanthanum and their compounds, other metal or compound.

The reforming temperature of the steam reforming described in the first invention is 700 ° C. to 1000 ° C., preferably 800 to 900 ° C., and the reforming temperature of the hydrocarbon compound (eg dimethyl ether CH ₃ OCH ₃ ) is 200 to 200 ° C. Since the temperature is 500 ° C., preferably 250 to 450 ° C., a steam reforming section is provided upstream of the exhaust pipe, and a reforming section of a hydrocarbon compound (for example, dimethyl ether CH ₃ OCH ₃ ) is provided downstream of the steam reforming section. A synthesis gas reforming path (reforming temperature is 300 ° C. to 800 ° C. ) is provided downstream of the quality, or the synthesis gas reforming path is provided downstream of steam reforming and further a hydrocarbon compound (for example, dimethyl ether) It is preferable to take one of the forms in which a reforming portion of CH ₃ OCH ₃ ) is provided.

In the hydrogen (H ₂ ) and carbon monoxide (CO) extraction equipment, the reforming channel, and the syngas reforming channel, if it is desired to take a longer reaction time, or steam reforming or CO 2 is performed simultaneously. When at least one of reforming and syngas reforming is desired, a plurality of water passages K provided between the inner and outer walls of the engine block (or rotary housing) of the engine are provided in the engine block 1. Whether to provide a structure or multiple exhaust pipes from the engine block (for example, the same number of cylinders, half the number of cylinders, or the same number of pipes as the number of rotors) Alternatively, one or a plurality of exhaust pipes extending from the engine block may be further branched into a plurality of branches and sequentially switched to send exhaust gas) or the water flow At least one of the two systems of pipes for heating carbon dioxide by further providing K ′, and three kinds of pipes downstream of the exhaust port after the engine combustion process A structure in which at least one of the reforming paths is provided and a mixed gas of hydrogen (H ₂ ) and carbon monoxide (CO) or hydrogen gas / carbon dioxide may be taken out.

With proton conductive ceramics has a heat resistance in accordance with the combustion temperature, which was equipped with communicating pores capable of passing the combustion gases, strontium cerate-based and the like Berogusukaito oxide ceramic zirconate-based proton conductive ceramics Is particularly advantageous in that it has an action of activating hydrogen and oxygen.

The use of carbon dioxide or carbon as a raw material as a renewable energy source in equipment industries such as the manufacturing industry is a known technique.

Second invention The internal combustion engine provided with one or more of hydrogen (H ₂ ) and carbon monoxide (CO) extraction equipment, reforming flow path, and synthesis gas reforming path as a transport device It is in the form of an on-board engine for transportation equipment, which includes motorcycles, munitions weapons vehicles, munitions weapons ships, and the like.

The third invention,
The existing hydrogen rotary piston engine car is used for the internal combustion engine described above. “The engine is operated under good fuel economy conditions (constant conditions) and is generated by the rotational force and stored in the capacitor. The electricity is used as the power source. By applying the form of “driving an automobile” to the internal combustion engine, stable combustion heat can be obtained, and the endothermic reaction conditions are also stabilized. However, it has a great effect of further improving fuel consumption and reducing greenhouse gas emissions by adopting a structure that generates electricity with the rotational force, stores it in a capacitor, and operates the electricity as a power source.

* Driving conditions (for example, waiting for traffic lights, waiting for an oncoming vehicle on the right, waiting for crossing pedestrians when turning right or left at the intersection, choco-choco driving in a traffic condition, driving on a flat road, overtaking & overtaking rapid acceleration・ The control mechanism and control structure of the output of the internal combustion engine are simplified and improved by following the changes in the downhill driving, etc.
Furthermore, since driving is performed under a certain condition (good fuel efficiency), there is an effect of improving the fuel efficiency (Km / L).

When the amount of electricity stored in the capacitor of the fourth invention is equal to or greater than the set value, the driving of the internal combustion engine is stopped and the vehicle is driven by electric power.
When the driving state that does not require power continues, the engine is continuously operated under certain conditions (good fuel economy conditions), so depending on the driving state, the electricity generated to drive the car becomes overcharged and is generated by the internal combustion engine. Since the electricity is discarded, the engine can be turned off and the vehicle can run with the stored electric power to improve the fuel consumption.

Fifth invention A charging / receiving plug is provided in the internal combustion engine, and charging means for storing electricity in the livestock battery, and it is expensive to cover all necessary power with a battery by using a structure in which the vehicle is driven using the electricity as a power source. It is not necessary to install a large number of batteries, and the power storage capacity of the internal combustion engine can be increased by several tens of percent. It will be a measure.

Driving conditions that do not require power (waiting for traffic lights, waiting for oncoming vehicles when turning right, waiting for crossing pedestrians when turning left or right, choco chocolate driving during traffic jams, downhill driving, coasting driving, etc.) During this period, the engine is continuously operated under certain conditions (good fuel efficiency). Depending on the driving condition, the electricity generated for driving the car becomes overcharged and the electricity generated by the internal combustion engine is discarded. Therefore, when the storage capacity of the livestock electricity reaches the upper limit set value, the engine is turned off and the vehicle runs with the stored power. When the storage capacity of the battery reaches the lower limit set value, the engine is turned on and the vehicle runs with the engine. The fuel consumption can be improved.

If the electric power is used as the driving power when running in the engine braking state during downhill driving, the motor can be used as a generator.Therefore, when running in the engine braking state, the motor is used as a generator to charge the battery. This will further improve fuel efficiency and reduce greenhouse gas emissions.

This is a repulsive driving run on the flat road, but a repulsive driving run is a speed at which a driver wants to drive for several minutes with an accelerator operation (approximately 2200 revolutions) that is about 10% higher than the speed at which the driver wants to drive. If it is 60Km / H, turning to 70Km / H will turn off the rotational drive power of the engine (this will be about 1000 revolutions, the number of revolutions when idling). Is a driving method that repeats the operation of turning on the rotational driving force connection of the engine when the speed reaches 60 km / H, which is a common driving method in the transportation industry 50 years ago. Automatic control of this travel mode can further improve fuel consumption and reduce greenhouse gas emissions.

6th invention Means for directly using the rotational force of the internal combustion engine as power generation power of the power generator, or steam that has finished its role of turning the turbine of thermal power generation and newly introduced mainly plant carbon, endothermic of the internal combustion engine Introduced into the reaction channel and converted to endothermic reaction, the generated fuel (gas) can be used as a substitute for auxiliary fuel, and can be combined with the existing thermal power generation facility, or the thermal power generation An endothermic reaction facility is provided in the exhaust gas pipeline of the boiler of the facility to make the endothermic reaction, and the generated fuel (gas) is used as a fuel for the power generation via the livestock gas tank. Also good.

It also can be any one or more of the mixed gas or carbon dioxide or hydrogen in the hydrogen and carbon monoxide using a material obtained by manufacturing elsewhere equipment (or transported in a state of compressed gas in the piping) can correspond, for generating Cases and ships and large vehicles can also be equipped with hydrogen (H ₂ ) and carbon monoxide (CO) mixed gas production equipment in close proximity to the internal combustion engine.

Seventh invention In the manufacturing industry (for example, steelmaking, iron forging, iron casting, aluminum refining and manufacturing, dust incineration plant, oil refining industry, etc.) that disposes heat, steam, carbon dioxide or hydrogen, Any one or more of discarded heat, steam, carbon dioxide or hydrogen is modified by any one or more of the reforming techniques described in the first to third inventions. The generated fuel (gas) is used as the fuel for the internal combustion engine to operate the internal combustion engine, and the CO2 in the exhaust gas of the internal combustion engine is combined with hydrogen by the means described in the second invention. This is an internal combustion engine that is generated in a synthesis gas of carbon oxide and is operated as a fuel for the internal combustion engine, and its rotational force is directly used as the power generation power of the power generator.
For example, in the rolling process of a steel mill, the decarburized crimson steel plate is passed through a number of rolling mills to form a steel plate roll of about 10 mm. The plate is cooled, and the large amount of water applied at this time becomes steam, and a part of it is discarded, and the final rolled steel sheet roll is used for the ceiling crane to hang down in the steel sheet roll natural cooling place. They are lined up in order on a plurality of rows of roller conveyors that have been installed with the required clamping tool operating width. The temperature of the steel sheet roll at this time is 700 ° to 900 °, and the power generation of the motive power generator is performed using the fuel (gas) generated by providing the endothermic reaction section between the roller conveyors to effect the endothermic reaction as the fuel of the internal combustion engine. Using power as a means of reducing electric power will reduce greenhouse gas emissions.

Eighth invention, & ninth invention the slaughter gas tank {said tank, high-pressure hydrogen gas storage tank 35MPa is no need, the fuel required for the operation of at least about 10 minutes with a gas generated in the internal combustion engine It is a damage prevention means that prevents the tank damage of the internal combustion engine (if the switching loss can be ignored) if it is a tank that can store livestock gas. A shock absorbing material HPE such as foamed polyethylene and boron fiber reinforced plastic is fixed to the vehicle body and fixed and held on the upper part of the vehicle. When the impact is applied to the fixture MT5, the V-shaped cutout portion MT6 breaks due to concentrated stress, and the tank cushion means includes the shock absorbing material inclusion body MT3. The tank support MT2 is integrated, and the impact buffering material has a structure in which the tank support MT2 is detached from the fixture MT5 (not completely disengaged but is locked to the fixture MT5 or the like by a linear body or the like). (It is a preferred form because it is a measure to avoid secondary damage that MT3 completely misses)
One or both of the damage prevention means for preventing damage to the tank or the tank separation means for separating the tank from the tank installation portion of the vehicle in the event of a collision are provided. Further, it is composed of a non-stationary facility (for example, an automobile) livestock gas tank of the livestock gas means, and the livestock gas tank is mounted on the upper body of a car or mounted on a chassis part of a truck. It is preferable to use one of the forms attached to the stationary equipment, but in the case of stationary equipment (for example, a power plant), the safety standard (in Japan, the registration of JIS B 8265 has been completed. Is ISO 16528), and the non-stationary livestock gas tank and the stationary livestock gas tank (eg chemical factory) It must be composed of those that are within the safety standards or at least have elements that can change the safety standards, so non-stationary equipment (eg automobile) livestock gas tanks and stationary equipment (eg chemical factories) livestock gas tanks Even if the function of storing gas is the same, the structure (standard) is completely different.

A tenth invention for example to make a bicarbonate Natoryuumu (NaHCO ₃₎ and by processed by exhaust heat of the internal combustion engine is thermally decomposed hydrogen _{(H 2)} and carbon dioxide Natoryuumu _(Na 2 CO _3), carbonate Natoryuumu _(Na 2 CO ₃ ) Is taken out and sold as a product, and hydrogen (H ₂ ) is used as a fuel for the internal combustion engine via the livestock gas tank. The sodium hydrogen carbonate (NaHCO ₃ ) is an example and is not limited to sodium hydrogen carbonate (NaHCO ₃ ).

If the hydrogen as a main fuel has a water and nitrogen in the exhaust gas as the main constituent
Fuel is hydrogen and the burning of carbon monoxide to water and carbon dioxide and nitrogen are exhausted to the main constituent, when the combustion of hydrogen and carbon monoxide modified carbon dioxide in the exhaust water and carbon dioxide And exhaust mainly composed of nitrogen,
Regardless of which fuel is used, the water is discharged in the form of water vapor, and the structure is such that the water of the reforming starting material is warmed from this water vapor by further heat absorption means, and the water is removed from the water vapor in the exhaust gas and filtered. It is returned to the storage tank as water for reforming starting material via filtration means,
The heat absorption means from the water vapor is provided, for example, by providing a water storage tank downstream of the exhaust pipe and passing the exhaust pipe through the water in the storage tank so that the water in the water tank absorbs heat and the water in the water tank is heated. Recovery means for recovering water, characterized in that water vapor in the exhaust pipe becomes water and recovers
The above-mentioned various reforming means reform water into fuel, so a considerable amount of water is required. However, if the on-board amount of water is increased, energy for transporting the on-board amount of water (weight) is required. Therefore, if water is collected and recycled, the amount of on-vehicle water can be reduced, and the water in the water tank can be warm water. This contributes to greenhouse gas reduction and emission reduction.

A small carbon maker to produce the carbon of the plant, wood or the like in an environment where oxygen from entering the coking chamber CS to carbonized by heating (plant material), plant material of the timber or the like for heating the carbonizing chamber A combustion chamber FC for combusting the gas, a gas exhaust passage for the combustion chamber FC, and a pipe J for water vapor generation means for converting water H ₂ O into water vapor J along the inner wall of the carbonization chamber. And the gas C4 generated in the carbonization process in the carbonization chamber is introduced into the combustion chamber and used as a fuel for heating the carbonization chamber, or the second invention is applied to the exhaust section (chimney of the exhaust gas pipe). As an example, the reforming material is dimethyl ether, and the reforming section facing the catalyst is reacted with either one or both of water vapor and carbon dioxide in the reforming section, and the fuel for the small-scale carbonization apparatus. Whether to make the configuration A manner to provide a small carbon maker provided either.
In the configuration of the small-scale carbon production device, the carbonization chamber CS and the combustion chamber FC are separated from each other, and the carbonization chamber CS section is provided with a generation section for steam J and a separation section for separating carbon dioxide from the exhaust gas. Thus, a heater using a fossil fuel such as coal (for example, a coal stove) can be used.
This means that many cold districts use coal stoves, and carbon dioxide emissions due to coal combustion cannot be ignored. The construction of the first and second inventions of this application Applying this is one of the measures to reduce (emission) “CO ₂ ” to cope with global warming, which is the biggest problem of the present application.

In the combination of the present invention, the carbon C of the synthesis gas generating material when the reforming means for reforming carbon dioxide is used may be fossil fuel use (for example, coal), which is a greenhouse gas emission reduction measure. is there.

The biggest challenge is the reduction of CO ₂ emissions to combat global warming.
By using mainly plant carbon C as a fuel, it was possible to make an internal combustion engine for a greenhouse gas reduction measure that constitutes one of the challenges of the greenhouse gas reduction measure that is the subject of the present application. In addition, CO ₂ generated by the combustion of plant carbon C is also reformed to fuel, and reforming this CO ₂ to fuel also has the effect of further increasing greenhouse gas reduction and fuel efficiency. This is the biggest effect.

The use of an internal combustion engine that generates this synthesis gas and uses the generated synthesis gas as a fuel as an alternative to a thermal power generator is a project that can be mentioned as the first solution to the current energy problem solution (2011) (2011). According to the statistics of the Federation of Electric Power Companies of the year, about 82% of Japan's total power generation is thermal power generation, and there is a request for power saving at the peak of midsummer power demand from each power company) Doing so has a great effect on power supply.

The great effect is that fuel is generated by utilizing the thermal energy that was discarded by the internal combustion engine.

The present application is an alternative to the auxiliary fuel supplied to the internal combustion engine for power generation using the rotational force of the internal combustion engine as it is as a power generation facility, and the endothermic reaction flow of heat, steam or hot water discarded in the manufacturing process, and newly input carbon. Auxiliary fuel, either petroleum liquefied gas (including natural gas), gasoline (including hydrocarbon-based fossil fuel), bioethanol, or synthetic gas, that was introduced into the road and supplied to the internal combustion engine A structure that eliminates the need for a fuel switching control structure including a sub-tank, a sub fuel use control structure, and a switching valve that switches and uses the synthesis gas of the auxiliary fuel, because the livestock gas tank is replaced with the synthetic gas or hydrogen gas of the present application. Is also possible.

The CO ₂ produced by burning the carbon of the plant is also generated in the synthesis gas to further reduce the greenhouse gas CO ₂ from the carbon neutral of the Kyoto Protocol on the use of carbon of the plant. CO ₂ can be reduced, and the greatest effect is achieved as a greenhouse gas reduction measure that could not be implemented with existing technologies.
Furthermore, even if carbon of the internal combustion engine of the present application is used for fossil fuel, CO ₂ can be reduced by at least several tens of percent even if 100% emission cut cannot be achieved.

While the purchase of greenhouse gas CO ₂ allowances is revitalizing, Japan's purchase amount is estimated to be about 1 trillions of billions, but this purchase amount can be reduced by several tens of percent.

The endothermic reaction efficiency can be obtained by operating the engine under the constant endothermic reaction condition by operating the engine under the “constant and fuel-efficient conditions” (different conditions at start-up) that are not related to the engine load fluctuation described in the fifth invention. The improvement of fuel efficiency (Km / L) is achieved by making the fuel efficiency good and the fuel efficiency is good.

The raw materials for generating the fuel for the internal combustion engine are water H ₂ O and carbon C. The plant that can regenerate the carbon C is used as a main raw material, and further, it is made from materials close to industrial waste that are produced during the production of sewage and food. Substances (e.g. methane gas or bioethanol) are preferred as sub-fuels,

Using the plant as the main raw material means that the plant absorbs carbon dioxide CO ₂ and produces oxygen O ₂ , so in the Kyoto Protocol it is defined as plus or minus “0” (carbon neutral), and global warming This is a great effect that can greatly contribute to prevention.

By providing a cycle for generating carbon dioxide in the exhaust gas into the synthesis gas (second invention), the “CO ₂ ” discharged from the internal combustion engine of the first invention is reformed into fuel. It is possible to reduce emissions of “CO ₂ ” and to improve fuel efficiency. (For example, it was possible to obtain an astonishing effect of improving 20 Km / L to 40 Km / L or more, not about 20 Km / L to 25 Km / L.
* The above effect could be obtained by providing means for reforming water H ₂ O and CO ₂ into fuel.

A radiator including the engine block cooling water passage and the cooling water piping of the internal combustion engine is not necessary.

The raw materials for generating the fuel for the internal combustion engine according to the first invention are water H ₂ O and carbon C. The plant that can regenerate the carbon is the main raw material, and the plant is the main raw material. sucking carbon dioxide CO _2, since out of oxygen O ₂ in the Kyoto Protocol plus, have been negative "0", a large becomes contribution possible to prevent global warming.

The use of the plant as the main raw material makes it possible to turn abandoned forests and “rice fields” into factories with good “operation rate” to produce valuable things (carbon from plants). This is vital for agriculture and forestry. give.

In thermal power generation, the boiler is heated with thermal power to generate steam, and the steam is further heated to generate electricity by rotating the turbine. Therefore, the energy efficiency is less than 50% and the thermal power boiler is necessary to start heating. Since the initial energy is large, it is difficult to turn on / off following the power consumption fluctuations according to the time zone because it is difficult to turn off the fire for a long time once it is turned on, so depending on the season (spring / autumn) or time zone Surplus power that is not consumed is generated, and the excess production is discarded. However, if the power generation system using the internal combustion engine of the present application is used, the operation may be turned ON / OFF following the fluctuation of the time power consumption. Since it can be made freely, excess production power can be brought to zero as much as possible, so there is no need for a large-capacity power storage facility and a vast amount of power transmission / reception facilities when supplemented only by solar power generation.

Current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of this application do not need to be adjacent to the water source and can be installed as close to the power demand area as possible, so there are very few transmission / reception facilities I can do it.

The proportion of the Japanese economy affected by fossil energy price fluctuations (and exchange rate fluctuations) will be reduced.

Transportation of the ship and so on of the vehicles and military weapons of the first of inventions (including the two-cycle two-wheel vehicles and four-stroke two-wheel vehicles) the internal combustion engine automobiles, ships and railroad diesel engine vehicles, construction machinery, military weapons It is implemented in the form of being mounted on equipment, either in the form of using the power generator as a substitute for thermal power generation equipment, or in the internal combustion of steam that has finished the role of turning the turbine in existing thermal power generation equipment and newly input carbon It is a form that is introduced into an endothermic reaction flow path of an engine and used for the fuel shortage and is combined with an existing thermal power generation facility, or one or more embodiments within the ninth invention.

Each dimensional relationship in the drawings is enlarged for important portions, exaggerated where details are difficult to understand, and reduced when describing wide portions or portions that are less important in the present invention. Thus, the dimensions between and within the drawings are not proportional, and are not actual or scaled.
If the distance between the lines is narrow, it is likely to become a single line that is black and thick at the scanning stage. Therefore, the distance between the lines is widened or described with a single line.

Furthermore, parts other than the basic (main) mechanism of the present invention are omitted between the drawings.

Hydrogen and carbon monoxide are almost energetically equivalent, that is, the (higher) calorific value is almost the same. Therefore, the detailed description in the specification of the present application refers to a known technique using hydrogen as a fuel. There are many. Furthermore, there are many parts that cite known techniques for the technique of reforming “CO ₂ ” into synthesis gas.
The main structure of this application refers to a variety of known technologies (including some that are patent-registered and alive), but cannot be obtained by individual known technologies alone. In order to obtain the effect in the present application, it was possible to obtain a surprising effect in terms of reducing greenhouse gas emissions and improving fuel consumption.

An endothermic reaction flow path is provided in the engine block of the internal combustion engine, and water H ₂ O and carbon C are reacted with the exhaust heat of the internal combustion engine to take out a mixed gas of hydrogen H ₂ and carbon monoxide CO. It is an internal combustion engine that uses a mixed gas of carbon monoxide and fuel, but any manufacturer thinks that synthetic gas can be used as an alternative fuel to gasoline, light oil, heavy oil, etc., but hydrogen also Carbon monoxide is also very dangerous (explosive and toxic). Therefore, liquefied transport means (portability). The ratio of the volume of the liquefied gas to the weight of the container that satisfies safety standards is poor. I suspect that there was an explosion problem caused by the wreck, and I couldn't get it.

The means of the present application to solve this problem are:
* Instead of filling the tank with fuel consumption and supplying all the fuel required for driving, a subtank is provided to replenish the energy loss during the fuel generation process, and the subtank fuel is oil liquefied gas (including natural gas) ) Adoption of a composite fuel supply structure that uses gasoline, hydrocarbon-containing fossil fuel bioethanol, etc., or synthetic gas as a supplementary sub-fuel for the energy loss (this stored gas pressure) The installation position of the livestock gas tank in consideration of the above and the provision of structural means that can cope with an accident such as a car being severely damaged) are the main points that made this application an “practicable plan”. (See Figures 1 and 2)

The storage gas, the synthesis gas generated in the livestock gas tank is stored in a certain amount (in the state of compressed gas), while the certain amount is accumulated, butane gas, gasoline, (including hydrocarbon-based fossil fuel) methane gas, bioethanol, etc., or Any of hydrogen, synthesis gas, reformed gas from plants, methane gas from plants, bioethanol of bioethanol, etc. is used as the storage gas in the auxiliary fuel tank, and the amount of generated synthesis gas is constant. And switch to synthetic gas, use synthetic gas in livestock gas tank while generating synthetic gas, and switch to using auxiliary fuel tank when the tank capacity is close to "0". Means to reduce the amount (including tank weight),

An example of a known technique for converting carbon dioxide to hydrogen, carbon monoxide, etc. in the presence of a catalyst is described in Japanese Patent Application Laid-Open No. 11-106770. In the description, a method for producing a synthesis gas by reacting a carbon-containing organic compound with steam and / or carbon dioxide in the presence of a catalyst and a catalyst suitable for the method are also disclosed. Is also used as a technology for reforming fuel.
Japanese Patent Application Laid-Open No. 2007-177684, a carbon dioxide recovery device for a vehicle, and a vehicle equipped with the same discloses that carbon dioxide is absorbed by a carbon dioxide absorber and carbon dioxide is recovered.

The main sources of greenhouse gas emissions are emissions from internal combustion engines and thermal power generation boilers, which account for about 82% of Japan's power generation (2012 Electricity Federation statistics). And 1/4 of the world ’s emissions from thermal power boilers,
The amount of CO ₂ released when 1 gallon of gasoline is burned is about 9 Kg combined with emissions from the car engine and emissions from the gasoline production process.
Therefore, in order to shift the consumption of carbon C from fossil fuels to carbon C from plants and achieve a 25% reduction in greenhouse gas CO ₂ emissions early,
It is necessary to implement an internal combustion engine for the greenhouse gas emission reduction measures of the present application and to make the procurement cost of carbon C, which mainly consists of fuel, the same as the procurement cost from fossil fuel.
The production of carbon C as fuel changes when carbonized organic material is heated while shutting off the flow of air and oxygen, and changes to a material rich in black carbon. This process is called carbonization, and charcoal produces this carbonization. This is a good example of a product, and what is produced is an aggregate composed mainly of amorphous oxygen and the like, and is mostly porous and has a very large surface area. Heating causes dehydration and dehydrogenation reaction to produce a condensed polycyclic aromatic compound, which further forms a network structure, which is called carbonization.

The technology to make solid carbon C from wood (nano-plant raw material) into nanoparticles is not yet a new technology because it has already been broadcast on TV, etc., but micronization (100 (About a micron) can be dealt with as the carbon C of claim 1 of the present invention.
If the solid carbon C is pulverized into fine particles, the surface area where the reaction takes place is increased. Therefore, the finer the particles, the more efficient the synthesis gas generation.
It can also be handled by adding water to the carbon C to form an emulsion fuel or gel.
Furthermore, the above-mentioned wood and the like (plant raw material C) is heated in an environment where oxygen does not enter, and carbon C gas can be obtained in the carbonization step.

It is a cycle in which steam in the engine → endothermic reaction in the exhaust line → synthesis gas or hydrogen of carbon monoxide and hydrogen or hydrogen is used as fuel for the engine.
* The proposed matter is that the livestock gas tank has a large internal volume, low pressure accumulation, a tank that can be built, where the vehicle is located, and what structure is used. It was possible to make a structure that does not.
* The above-mentioned proposed matter was solved with the following structure.
1. The place where the synthesis gas tank is installed is located in the upper part of the car body or in the chassis part of the car, which is provided in the upper part of the car body even if the car falls from the cliff, Even in an accident that is sandwiched between and crushed, the livestock gas tank is required to have a tank that does not explode, but the target hydrogen that can run 500Km in a cylinder that can be mounted on the vehicle is 4MPg of hydrogen and 20MPa. The pressure requires 300L of container volume,
Mazda (Company name) Premasi Hydrogen RE hybrid vehicle equipped with 74L / 35MP of hydrogen can run only 123Km with full tank filling, so it can not run only with hydrogen, so to run 500Km, about 4 times 300L A / 35 MPa hydrogen tank is required, but in order to cover 300 L of hydrogen with a 74 L / 35 MP container, a container that can be filled with about 150 MPa compression is required, which is difficult with the current technology.
Therefore, it was planned to generate synthesis gas in a mounted internal combustion engine. However, in a pressurized pump with a mounted structure, if the compression pressure is increased, more power is consumed for the pressurized pump. At the start, the gas was accumulated with equipment equivalent to an accumulator of hydraulic equipment, but the car fell from the cliff due to an accident on the highway where the livestock gas equipment should be installed. If the accident is such that the car is flipped upside down or the passenger car is sandwiched between large trucks and crushed in a sandwich, the structure must be such that an explosion can be avoided when such an accident occurs. I gave up on board.
If you are searching for related documents on the Internet and searching for prior literature for planning other projects using synthetic resin, the following foamed polyethylene, (the above-mentioned member has anti-bullet properties and is used for military weapons, (As an example, polyethylene fired polyethylene is fixed to the outer surface of an army water hoat for army movement, and when it is sniped with a rifle etc., the bullet has a bullet-proof property that does not allow a hole to be made in the rubber hote) Can be found, and if this was used, it was able to solve even the place where it did not explode even if the accident occurred. However, the problem was the location of the last remaining tank.
While considering the eco-driving method filed last year and thinking about what to do with resin to reduce the weight of the car, when considering the roof of a passenger car, the livestock gas tank of the present application that had been neglected was used for the roof of the car The structure of this livestock gas tank is the key point of the present application. (See Figure 1A and Figure 2)
2. As shown in FIG. 2, the outer surface of the livestock gas tank is made of poron fiber reinforced plastic or foamed polyethylene. (The above-mentioned members are bullet-proof and are used for military weapons. The fired polyethylene is fixed on the outer surface of the water hoat for moving the water surface, and when it is sniped with a rifle, etc., the bullet has a bullet-proof property so that a hole cannot be made in the rubber hoat)) A tank separation means is provided that separates from the car body when it is impacted by falling or severely damaging the car. It has a structure that does not explode even if it bounces off. (It is preferable to provide a locking structure that does not jump too far.)
3. As an example of the separation structure of the tank inlet / outlet pipe from the vehicle body, the solenoid valve contact configuration is ON when energized. When the solenoid valve sequence circuit is turned off when not energized, and the synthetic gas tank is subjected to an impact force flying from the body of the car, the gas inlet / outlet pipe of the tank may come off (or be damaged). The gas pipeline from the tank is closed. (See Figure 2.H)
4). The problem of compression pressure of livestock gas also uses auxiliary fuel, and if you use Mazda (Company Name) Premasi Hydrogen RE hybrid vehicle configuration where the eco-drive method and internal combustion engine of the previous application are only generating electricity, auxiliary fuel will be used However, an embodiment in which only synthesis gas or only hydrogen or switching between synthesis gas and hydrogen may be used, and the stored gas pressure can be handled with a low compression pressure as described in the next paragraph.

In order to cover the fuel necessary for running 500 km with gasoline with hydrogen (synthetic gas), 5 kg of hydrogen (equivalent to 56,000 L of hydrogen) and (10 g / Km = hydrogen of 11.2 L).
Therefore, the capacity of a livestock gas tank for fuel (hydrogen, synthesis gas, carbon dioxide) required for about 10km travel is a livestock gas tank capable of livestock gas of 11.2L * 10 = 112L (normal pressure) if the fuel switching loss is ignored. It will be good if there is.
Therefore, it can be designed freely as long as it is within the scope of the law and the relationship between the tank manufacturing cost and the installation space and the switching cycle to be set.

Provided savings gas tank of a gas generated from an internal combustion engine according to the first inventions the car top, the savings gas tank, shock-absorbing material (foamed polyethylene, boron fiber reinforced plastic, etc.) on the fixed or coating or multilayers A storage tank that can be used as a countermeasure against rupture or explosion in the event of a car being severely damaged by fixing one of the stacked objects to the storage tank.

Referring to FIG. 1, the vehicle shown in FIG. 1 is a schematic configuration diagram in which the structure of the present application is installed in a commercial vehicle front engine type commercial vehicle, and an exhaust pipe from a hydrogen rotary piston engine (internal combustion engine) installed in the front engine room. The endothermic reaction synthesis gas generation section provided in the section generates gas, and the extracted synthesis gas is stored in the storage tank MT provided in the upper section and used as fuel for the hydrogen rotary piston engine. In the schematic configuration diagram, switching the loss to the fuel of the sub tank ST,
FIG. 1B is a schematic configuration of an engine block, a synthesis gas generation endothermic reaction flow path section, a fuel supply / injection system, and a spark plug of a reciprocating engine. a schematic configuration flow diagram parts and the fuel supply and injection system ignition plug, the water HO ₂ into the engine block of a four cylinder reciprocating engine provided with a water passage K of the steam J, water H _{2 O} (or water and carbon dioxide) is supplied from the supply port steam generating unit (or / and carbon dioxide heat absorbing means) and bookmarks, intake air 0 ₂ is provided for supplying duct 3 air 0 ₂ to the inlet port a _P are supplied to the mouth a _P, the exhaust port from E _P at the conduit 4 is connected to the exhaust pipe of the synthesis gas production unit, endothermic of said exhaust pipe MS syngas product endothermic reaction portion in the exhaust pipe Reaction tube It is provided in a coil shape, and the steam J generated in the engine block of the reciprocating engine is introduced into the coiled endothermic reaction tube and carbon is newly introduced, and the exhaust gas of the synthesis gas generation unit flowing MS to the tube, to produce the exhaust gas E _X of the exhaust heat in the synthesis gas CO + H ₂ generated in the engine combustion stroke, produced synthesis gas by livestock gas in the synthesis gas storage tank (slaughtering gas tank) MT In order to make up for the shortage of the generated fuel, a sub tank ST is provided to store the sub fuel. The sub tank fuel and the synthetic gas stored in the live gas tank are switched by the switching valve CB, and the fuel supply line 5 FIG. 2 is a schematic configuration diagram of an internal combustion engine that is supplied to the injector E _C H ₂ and has a configuration in which a plug P for forced ignition is provided.

A water passage K for converting water HO ₂ into water vapor J is provided in the engine block, water H ₂ O is supplied from the supply port, and in addition to the water passage K serving as water vapor generating means, air passage K for heating CO 2. 'And a CO2 supply port are provided, and at least one of the plurality of exhaust pipes is supplied to a pipe for reforming CO2, and one of the other pipes for reforming CO2 is supplied. Whether it is a steam reforming line or a synthesis gas reforming path, the steam J is supplied to all or a plurality of pipes and supplied from both the pipes K and K ′ as necessary. It is also possible to add a configuration in which the supply path is switched to either of the above.

FIG. 2A. 1 is a cross-sectional view taken along the line AA in FIG. 1. As an example, this figure shows a synthetic gas tank having four cylindrical MTBs, and a single package made of a shock absorbing material such as foamed polyethylene, boron fiber reinforced plastic, or the like. In the state where the vehicle is fixedly held on the upper part of the vehicle, and is fixed to the fixture MT5 that is fixedly fixed to the upper part of the vehicle with the fixed holding fixture MT1. The V-shaped notch MT6 breaks due to concentrated stress, and the shock absorbing material inclusion MT3 (for example, the tank support MT2 is integrated) is detached from the fixture MT5 (completely disengages). (It is a preferable form to take a structure in which it is locked to the fixing device MT5 or the like with a thread body or the like, because this is a measure for avoiding the secondary damage in which the inclusion body MT3 of the shock absorbing material completely comes off))

As an example, when a collision or falling force is applied to the tank, a holding structure in the event of an accident is provided, and a structure (part of which is preferably connected to the car) is provided. The tank that flies off from the vehicle is made of foamed polyethylene, boron fiber reinforced plastic, impact buffering material (HTP), etc., which is provided on the outer surface of the tank and fixed to the entire surface, and absorbs or diffuses impact force. So it does not explode.
The foamed polyethylene, boron fiber reinforced plastic, and shock-absorbing materials that are fixed to the entire surface of the coating or the entire surface may not be expensive at this time, but they are produced almost 20 million units / year (by the entire Japanese automaker). The cost is reduced due to the effect.

FIG. FIG. 6 is an example of a tank mounted on a rear engine vehicle in which the shock-absorbing material MT3 is mounted perpendicularly to the traveling direction; E. The figure shows that there are no restrictions on the number and shape of the tanks. E, the tank is housed in the front and rear recesses on the roof of the car, and the aesthetics from the side are improved. F. Is a type with an engine mounted under the cabin. The shape installation direction of the gas tank MTB and the tank package MT3 to be mounted is a design problem in the relationship between the tank capacity to be installed and the gas pressure.

FIG. FIG. 5 is a partial cross-sectional view of the structure of the gas inlet / outlet portion when there is only one gas tank MTB, and the gas taken out from the synthesis gas generator S is a tank open / close valve GTbsec (for example, the electromagnetic valve is turned on when energized and turned off when deenergized. It is a schematic diagram of a structure in which gas is stored in a tank via a contact circuit) and introduced into the fuel switching valve Cb of the engine. If the force is applied to the tank and the gas storage tank comes off, the electrical wiring will be disconnected and the electromagnetic valve will be turned off so that the gas in the tank will not leak.
2 and I are. A reverse J-shaped locking and fixing structure KRsec having elasticity is provided at both ends of the fixing device MT5 fixedly fixed to the upper part of the vehicle. (Lower view) When the car is severely damaged, the reverse J-shaped This is an example of a structure (upper view) in which the reverse J-shaped locking function part of the locking structure KRsec extends and the HPE body is detached from the upper part. As long as the HPE body has a function of separating to the upper part, it does not stick to metal, synthetic resin, other, material and shape.
It is preferable to provide a carbon dioxide livestock gas tank and a hydrogen livestock gas tank in the structure of the livestock gas tank.

Although the above-mentioned supplemental described, the synthesis gas produced by the steam reforming is a schematic substance amount 1 of CO and H _2: a mixture of 1. Since the gas volume is proportional to the amount of the substance, the amount of carbon monoxide = the amount of hydrogen and the gas has a volume of 22.4 L / mol in the standard state. (Transfer efficiency of liquid hydrogen: high pressure hydrogen = 6: 1) Hydrogen is 39 g per liter (weight in tank of 700 atm).
The gas generated by the CO ₂ reforming is described in the paragraph of the second invention, but when the reforming substance is dimethyl ether as an example, the dimethyl ether is either water vapor or carbon dioxide, or both. In addition, if you react,
A. In the case of CH ₃ OCH ₃ + H ₂ O → 2CO + 4H ₂ −48.9 Kal / mol water vapor
B. In the case of CH ₃ OCH ₃ ++ CO ₂ → 3CO + 3H ₂ −58 · 8 Kal / mol carbon dioxide
C. In the case of both 2CH3OCH3 + H2O + CO2-107.7 Kal / mol become that way.
* Hydrogen properties, diffusion is quick and easy to leak, high reactivity, and especially brittle metals including steel.

FIG. 3A. FIG. 1A is a cross-sectional view in the front-rear direction of FIG. 1A, and a description of the hydrogen-compatible structure of the rotary piston engine is shown in FIG.
Rotary piston engine A water passage K that makes at least a half turn between the inner wall and the outer wall of the rotary housing is provided, and water is supplied from one water introduction pipe to the water passage K between the inner wall and the outer wall of the rotary housing. The water is sent to the endothermic reaction channel S through the carbon C insertion tube, and the water becomes steam J in the process of passing through the water passage that contacts the intake → compression → explosion → exhaust process part with the combustion heat of the fuel. The
Air O ₂ is sent into the other rotary piston engine, and then the fuel synthesis gas MTC or subtank ST fuel (any of butane, biofuel, synthesis gas, etc.) is sent into the engine, → compression → explosion → exhaust E _X next to be fed to the endothermic reaction flow path portion S, the exhaust E _X flows through the tube center portion of the endothermic reaction channel section S, carbon inserted with steam J thermal reaction channel is in the description of FIG. 3 flow synthesis gas generator tube provided in a coil shape in contact with the tube wall of the tube MS, the tube in the heat of the exhaust E _X flowing a central portion is generated in the synthesis gas is withdrawn from the take-out tube is transferred to savings gas tank MT FIG.
The explanation structure of FIG. 1B and FIG. 3 is applied to the structure of the water passage / ventilation path of the rotary housing corresponding to CO2 reforming and synthesis gas reforming.

FIG. 3B. FIG. A mixture of water vapor J and carbon C is fed into a water passage K between the inner wall and the outer wall of the rotary housing into the water (H ₂ O) introduction pipe portion of the water and comes into contact with the inner wall surface of the thermal reaction channel pipe MS in a coil shape the synthesis gas production tube provided in the flow, which is the tube structure schematic diagram central portion is generated heat in the synthesis gas in the exhaust E _X flowing retrieved from the take-out tube is transferred to savings gas tank MT.
The structure of the water passage / ventilation path of the rotary housing corresponding to CO ₂ reforming and synthesis gas reforming also applies the explanation structure of FIG. 1B to FIGS.

Figure 4 is provided to the synthesis gas production pipeline provided in a coil shape in contact with the tube inner wall surface of the thermal reaction flow pipe MS of FIG. 3 in a thin tube of a straight, exhaust between the thin tube and the thin tube E _X The design of the endothermic reaction flow path has been put to practical use in a system that makes the exhaust gas harmless by confronting the catalyst in the exhaust gas treatment system. good.

FIG. 5 is a schematic view showing a hydrogen rotary piston engine disclosed in Japanese Patent Application Laid-Open No. 2007-2111608.

FIG. 6 is a diagram showing a main configuration of an electronically controlled injection structure of a hydrogen rotary piston engine. The electronically controlled injection valve needs to inject a large capacity of 2300 NL / min in order to obtain an output of 100 KW, for example. The two injection valves 40 and 42 in the above figure are provided to inject a large volume.
Further, a large-capacity intake port 16 and an exhaust port 18 are provided on the side of the rotor housing, and the explosion chamber is divided into two when it is about to explode, and two spark plugs 14 and 15 are provided.

In recent years, hybrid vehicles and 100% electric vehicles have attracted attention.
However, if most of the automobiles are used as electric energy, there is a problem of the “Fukushima nuclear power plant” that overwhelms the power supply situation to follow the speed of electrification including home appliances, and the expansion of the power supply facilities is solved quickly It is an issue that should be done. However, the public disagrees with the current situation regarding the construction or restart of nuclear power plants, as the burden of electricity charges will increase if the nuclear power plant is abolished. I understand that there are many, and further public opinion is toward the direction of damming. Therefore, expansion of power supply facilities is a desperate situation that the weight of things by thermal power generation and natural energy becomes very high . Therefore, expanding the power generation facilities that suppress CO ₂ emissions is a problem that should be solved immediately.

In recent decades, cheap timber has been imported from foreign countries, the number of forestry workers has decreased dramatically, the forest has not been thinned, and dead trees devoured by pests such as pine wilt have been left unattended.
Furthermore, it is the vitalization of agriculture, but most of the “rice fields” have agricultural waterways, which have been fertilized for many years and have become fertile farmland. For example, “Kenaf”, which is a pulp material, and “Mulberry” in sericulture can be planted in this “rice field”, or “Yukari” from Uruguay in South America can be used. One plan is to use a small-scale carbonization device (see Fig. 10) that can be carbonized by a farmer with a single hand for lending use (lease method). For example, if the carbonization equipment that is cheaper with the price of the carbonized equipment is purchased in a five-year split, for example, a small scale that allows more forestry workers and farmers to use the purchased money with one hand. ”Carbonizing equipment” It is also possible to plant a thing that can become “bioethanol” that grows well in places where water supply is sufficient, such as taro.

The goal of reducing greenhouse gas (CO ₂ ) emissions by 25% by 2020 is being asked, and Japan's CO ₂ emissions are struggling to see how the world can reach this goal. The main players in this project are emissions from internal combustion engines and emissions from thermal power boilers, which account for about 82% of electricity generation (2012 Electricity Federation statistics). These CO ₂ starts with coal, oil and natural gas. Fossil fuels such as coal, oil, and natural gas are limited resources, and of course, resources that cannot be reproduced.

According to the Kyoto Protocol, carbon dioxide CO ₂ produced by the combustion of plant carbon C is consumed by plant carbon assimilation, so it is a plus or minus zero and is not counted as CO ₂ emissions. Therefore, in order to shift the carbon consumption of fossil fuels to plant carbon and achieve a 25% reduction in greenhouse gas CO ₂ emissions at an early stage, it is best to realize the above-mentioned synthesis gas generation cycle plan. think. (According to 2010 data from the Ministry of the Environment, greenhouse gas CO ₂ emits 30.3 billion tons worldwide, Japan is 3.8%)

The day when solar power generation (system using solar power generation panels, condensing sunlight, generating steam with heat → power generation) will become the mainstream of future power generation is not far away. However, solar power generation is not possible 24 hours full-time power generation at night, rain, and cloudy, and if it is installed on a large scale, it will be quite remote from the power usage area, so it will install new substation and transmission equipment The disadvantage is that large-capacity power storage equipment is necessary to cover only with solar power generation, and if it is a place with a good sunshine rate (for example, a desert with low annual rainfall is the leading candidate), a large amount of power transmission / reception equipment is required. (There is superconductivity invented by Japan in the above-mentioned large-capacity power storage equipment, large-scale power transmission / reception equipment, the experimental plant is already in trial operation, and the international standard of 1,100,000V was also established in 2008. Although it has just gained international approval, the gap with the estimated cost is a problem).
Therefore, if the internal combustion engine power generation of the present invention that can be operated for a short time other than the solar power generation time is used in combination with the fuel production mechanism of the present invention, it can be said that the reduction of greenhouse gas CO ₂ emission can be achieved earlier. .

Whether or not the procurement cost of carbon C as a fuel can be reduced holds the success or failure of practical use of the present application. In carbon production, when carbonized organic substances are heated with the air and oxygen flow cut off, they turn into black carbon-rich substances. The resulting product is an aggregate mainly composed of amorphous oxygen and the like, and is mostly porous and has a very large surface area. Heating causes dehydration and dehydrogenation reaction to produce a condensed polycyclic aromatic compound, which further forms a network structure, which is called carbonization.
Carbon charcoal used as a fuel while performing many operations such as thinning, pruning and undercutting. It is a concrete proposal that is a shortcut for realizing the present application to sequentially lend carbon production equipment that has a structure that can be handled in a procurement manner (subject to substituting for subsidies).

FIG. 10 is an assumed schematic diagram of the above-described small-scale carbonization apparatus. Carbonization plants suitable for the carbon material of the present application are placed in the carbon production chamber CS, and the combustion chamber FC serving as a pot door is approximately half carbonized of the carbon material of the present application. By burning the timber plant and collecting it in the collection area in the form of carbon C, it is possible to reduce the transportation cost much more than transportation with branch wood,
Plant material in an environment where oxygen from entering by introducing a timber or the like coking chamber CS to carbonized by heating (wood, etc.), heating fuel for heating the carbonizing chamber (plant material such as wood or other burnable material) The combustion chamber FC is made to burn and combusted, and the exhaust gas exhaust pipe Ex of the combustion chamber FC and the pipe J of the steam generating means for converting the water H ₂ O introduced from the water tank into water vapor are provided on the inner wall of the carbonization chamber. The gas C4 generated in the carbonization process is introduced into the combustion chamber together with water vapor through the introduction pipe C4, and is used as a fuel for heating the carbonization chamber,

The reforming part (CO ₂ reforming) having the structure described in the paragraph of the second invention is provided in the discharge part (chimney) of the exhaust gas pipe, and as an example, the reforming substance is dimethyl ether, and the catalyst If the reforming section is made to react with either dimethyl ether or one of water vapor or carbon dioxide to make the fuel of the small-scale carbonization device, the fuel consumed for carbonization is further reduced. Reduction of effect gas emissions.
Furthermore, by using a reforming section (CO ₂ reforming), it is possible to use fossil fuels such as coal, and it is possible to use it as a starting reforming material that reforms wood, etc., used as fuel into plant raw material C.
As an example, the catalyst can be used in combination with other metals or compounds in addition to iron-based metals and / or compounds. Examples of other metals or compounds include zinc, nickel, chromium manganese, tin, cerium, lanthanum, and the like. These compounds, other metals or compounds.

The synthesis gas described above is not limited to hydrogen and carbon monoxide. The synthesis gas represents a main component, and includes, for example, unburned carbon, carbon dioxide, moisture, and other gases and impurities present in the atmosphere. This includes cases where

The procurement cost of carbon (plant raw material C) is currently higher than that of natural gas (methane, butane, etc.), coal, and petroleum fossil fuels. Until it is obtained, or the law of strengthening the emission control of greenhouse gas CO ₂ is made, the procurement of carbon will be done with natural gas (methane etc.) or directly with natural gas (methane etc.) as fuel and the whole society There is also a way to switch when the desire for carbon increases and the cost of carbon procurement can be paid,
However, I think that the speed of progress in chemical technology is progressing in proportion to "needs",
Therefore, if the need for procurement of renewable carbon C, which is the main raw material of the present application, becomes high, we are confident that the procurement technology will evolve with acceleration.
The carbon used in the internal combustion engine cycle of the present application is the cheapest to use “coal” as powder for the time being, so the fossil fuel will be used until the renewable carbon C procurement system is complete. It will take the form of shifting to a carbon C procurement system that can be sequentially regenerated.

The amount of purchase of greenhouse gas CO ₂ emission allowances in Japan is estimated to be about 1 trillions of billions of yen. If this purchase amount is used as part of the carbon procurement cost, the time of realization of the present invention will be explained. Will be faster.
* From transportation by transportation equipment if it is used as a transportation means of mixed gas of hydrogen and carbon monoxide, carbon dioxide, hydrogen, etc. in pipelines from chemical factories, steel factories, aluminum factories, dust incinerators, oil refining and factories, etc. The transportation cost can be greatly reduced.
Each US and European country has a hydrogen transport pipeline of thousands of kilometers, and should be realized early with the support of the government in order to survive the world as a competitor.

The power generation facility powered by the internal combustion engine of the present application is a relatively small-scale power generation facility. Because it can be a decentralized power generation system with self-sufficiency in units of mass such as remote islands, mountainous remote areas, industrial parks, submarine transmission cables and power demand It is possible to drastically reduce power transmission facilities, power transformation facilities, and power reception facilities that respond to changes in power consumption.
Furthermore, the current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of the present application do not need to be adjacent to the water source, and have the advantage that they can be installed as close to the power demand area as possible.

When methanol is used as a fuel for an internal combustion engine, methanol is originally synthesized from hydrogen and carbon monoxide at a high pressure advantageous from chemical equilibrium. Therefore, it is most efficient in terms of energy to use it in the form of synthesis gas of hydrogen and carbon monoxide, rather than converting it to hydrogen.

Although transportation of compressed hydrogen and liquid hydrogen is carried out, in order to compensate for the problem that the volume storage density of hydrogen gas is small, hydrogen is pressurized to 14.7 to 19.6 MPa and transported as compressed hydrogen. Mo steel hydrogen container is heavy. For example, a trailer vehicle that transports 100 kg of hydrogen requires 7 tons of hydrogen container. To reduce the cost of transporting compressed hydrogen, aluminum alloy liners and high-density polyethylene liners are used. It is necessary to make a tank reinforced with glass fiber or carbon fiber,
Under current regulations (in Japan, registration of JIS B 8265 has been completed and internationally there is ISO 16528) CFRP for transportation (tank with high-density polyethylene liner reinforced with glass fiber or carbon fiber on the entire surface) ) Since the container has a pressure of up to a capacity of 35 MPa, it is necessary to relax regulations in order to utilize the container. (Japan Industrial Gas Association, hydrogen gas container standards)

On the other hand, liquid hydrogen has a volume storage density 800 times higher than that of hydrogen gas, and tank trucks or insulated containers are used. However, liquid hydrogen requires energy for liquefaction and has a boiling point of −253 ° C. and evaporation loss. There are disadvantages that occur.

The internal combustion engine of the present invention uses synthesis gas as fuel, but the synthesis gas is a pipe piping supply in a transport equipment on-board engine, and the accumulation pressure of a livestock gas tank for livestock synthesis gas generated by the internal combustion engine is There is no need to use a 35 MPa livestock gas tank of compressed gas mounted on the existing hydrogen engine vehicle mentioned above, and it may be about 1/40 of the accumulated pressure, and the energy used for the pressurizing pump can be used to reduce the accumulated pressure. There is no need, and the structure of the gas storage tank can be made as high as several MPa within the current regulations.

Pipeline transportation is optimal for steady mass transportation of hydrogen, and the synthesis gas of this application is similar to hydrogen in Europe and the United States. It is the best way to do it.
As the pipe material of the hydrogen pipeline, in the current advanced technology, if it is a sour-resistant material with a reduced amount of vanadium and a small amount of nickel or chromium, compared with ordinary line pipe steel, it can be used in a normal transportation environment. It is said that the cost can be increased to 10% or less.

The rotary engine vehicle powered by hydrogen is a Mazda Premacy Hydrogen RE hybrid vehicle that has a structure that can be selected to travel using either hydrogen as fuel or gasoline as fuel. A high-pressure hydrogen fuel tank (35MPa, 74L) And a gasoline tank is mounted on the vehicle, electricity is generated by rotating a hydrogen (or gasoline) rotary engine and stored in a lithium ion battery, and driving of the wheel is electricity stored in the battery,
The feature of this car is that the engine is operated with good fuel economy, and the control of the vehicle speed fluctuations depending on the running state of the car is electric control.
Disadvantages include a short mileage of 100 km in a high-pressure hydrogen fuel tank, and the hydrogen transportation means (assuming transportation by car) has a poor ratio of hydrogen loading weight to the tank weight, leading to the development of infrastructure such as hydrogen stations. There are no points and high hydrogen production & transportation cost.

The hydrogen engine bus developed by Tokyo City University, which uses hydrogen as fuel, is loaded with six tanks compressed to 35MPa on the roof. The main improvements in the engine are the addition of an intake manifold, hydrogen injection valve and spark plug.

A hydrogen reciprocating engine and a wagon type Musashi 10 developed and developed by Tokyo City University using hydrogen as a fuel, is a hydrogen engine with a hydrogen cooling intercooler, equipped with a tank of 100 L of liquid hydrogen and continuously running at 300 Km per charge. It is a car that made it possible.
Disadvantages of the above-mentioned existing vehicles that use hydrogen as a fuel are that the ratio of hydrogen loading to the tank weight of the hydrogen transport means (assuming transport by car) is poor, the infrastructure development such as the hydrogen station does not progress, and the hydrogen production cost It is a high point.

The hydrogen rotary piston engine Mazda (company name), and generating the hydrogen H ₂ as a fuel, since by rotating the motor in the electric can use the power component as power generators, dwell as a power generator generating The components are applied to the internal combustion engine of the present application.

In the case of the power generation equipment in the previous paragraph, steelworks, chemical factories, aluminum manufacturing factories, foundry factories, forging factories, garbage incinerators, and oil refineries that use synthesis gas and hydrogen as by-products or dispose of a large amount of heat. If a power plant is installed adjacent to or close to a place, the running cost can be further reduced.

In the case of the internal combustion engine power generation equipment of the present application, a relatively small scale power generation equipment (if the internal combustion engine power generator is assumed to have an output machine of 1000 KW / H as 1 unit / unit, 1 unit to several hundred units The number of units can be set as a decentralized power generation system with self-sufficiency in units of mass, such as remote islands, mountainous areas, and industrial parks. It is possible to greatly reduce the power transmission facilities and power transformation / reception facilities corresponding to the changes.
Furthermore, the current thermal power and nuclear power plants need to be adjacent to the water source, but the location conditions of the power generation facility of the present application do not need to be adjacent to the water source, and have the advantage that they can be installed as close to the power demand area as possible.

The carbon sources mentioned above are dead trees that have been eaten by pests such as thinning and pine wilt, and rice husks and husks generated in Japanese rice farming are discarded. Cultivated kenaf (Hibiscus cannabinus L) in vacant land such as fallow land, which can be mixed gas production plant carbon (C) at a rate of carbon (C) of said plant It goes without saying that cultivating corn, sugarcane, etc. in vacant land such as fallow land can be used as biofuel for plants, but many rice fields have agricultural waterways. In addition, since it has been fertilized for many years, for example, cultivated taro, wheat, and actually edible, the waste part is made into the biofuel of the plant or the carbon of the plant (C) and the wheat straw is converted into the carbon of the plant ( There is also a method to make up for the difference between the income obtained from them and the income obtained from rice cultivation, etc.

Agricultural work with 2 to 3 small rice fields as a single rice field as a measure to expand the scale of agriculture, which has been implemented in the past 20 years as a measure against rice prices (Urg Island) for agriculture (rice farmers) that has been considered in the country. Measures to increase efficiency, measures to increase the size of several farmers as one company, agricultural income compensation system, a subsidy subsidy policy (2.5 trillion yen) to cope with a decrease in rice demand There is a policy to support, but none of these policies are far enough to make Japanese rice farmers an attractive profession for the next generation, using the carbon (C) of the plant as a fuel source. To achieve this policy, “Reducing CO ₂ emissions in response to global warming” and “Making agriculture and forestry an attractive occupation” and further revitalizing the Japanese automobile industry. We can expect effect of "one stone several birds" .

Various embodiments that can be easily conceived from the events described in the present specification and claims are included in the present invention as long as they do not depart from the scope of the claims.

Although this project is partly undeveloped, the internal combustion engine of the present application can be implemented. Furthermore, it can be used for those industries that spread to people in industries related to them.
Above all, creating a cycle that maximizes the use of your country's resources will create a foundation for Japan's 100-year total, leading to the development of those industries.

A. FIG. 3 is a schematic structural diagram of water and carbon as synthesis gas of H ₂ and CO in the engine in an internal combustion engine (rotary piston engine). B. The schematic block diagram of the engine block of a water vapor | steam production | generation part of a reciprocating engine, a synthetic gas production | generation endothermic reaction flow path part, a fuel supply / injection system | strain, and a spark plug. A-F FIG. The example of several types of storage gas tank installation of the storage gas tank installation procedure. H. The partial cross section of the cylinder of 1 unit of a gas storage tank, and the gas inlet / outlet pipe | tube partial view and partial sectional drawing of the said cylinder. i. Tank comprehensive body holding / removal diagram. A. FIG. 1B is a schematic cross-sectional view from the EAsec rotary engine of FIG. 1A to the endothermic reaction flow path portion. B. FIG. A. Type cross-sectional view of pressure inserting the vapor and carbon in H _{2 O} supply pipe. The schematic structural example figure which comprised the structure of the endothermic reaction flow-path part provided in the engine exhaust pipe part and the gas production | generation pipe | tube with several thin tubes. Schematic which shows the rotary engine of the control apparatus of Unexamined-Japanese-Patent No. 2007-2111608. A, electronic control of a rotor same as above, and hydrogen injection structure schematic cross-sectional view of a fuel injection device of a hydrogen rotary piston engine disclosed in Japanese Patent Application Laid-Open No. 2007-064169. B, A, the longitudinal cross-sectional view of a figure. The block diagram of embodiment of the fuel reformed gas engine of Unexamined-Japanese-Patent No. 2002-039022. 1 is a schematic configuration diagram of an electronically controlled hydrogen injection system, intake / exhaust ports, and spark plugs for reciprocating (diesel engine) fuel supply. FIG. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic structural diagram of an exhaust gas treatment device provided in an exhaust pipe that generates Karman vortices of Japanese Patent Application Laid-Open No. 2002-256849 and sucks CO ₂ of exhaust gas into water. An example figure of a small carbon generator. Annual bar graph that captures past years of carbon dioxide emissions statistics from fossil fuels around the world.

Claims (15)

A facility for taking out a mixed gas of hydrogen and carbon monoxide by reacting water and carbon with exhaust heat of the internal combustion engine, and a livestock gas tank for stocking the taken out mixed gas of hydrogen and carbon monoxide are provided. The extracted hydrogen and carbon monoxide mixed gas is used as a fuel for the internal combustion engine via a livestock gas tank, and the exhaust heat of the internal combustion engine is mainly used to convert water into steam in a water passage in the engine block of the internal combustion engine. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that it is exhaust heat used to make the exhaust heat and exhaust heat obtained by endothermic reaction of the heat in the exhaust gas in the exhaust gas pipe.
A livestock gas comprising the absorption means for absorbing carbon dioxide in the combustion exhaust gas of claim 1 in water or the separation means for separating carbon dioxide, wherein the separated carbon dioxide is gasified. A gas tank and a livestock water tank for stocking carbon-containing water absorbed in water are provided to feed livestock gas and livestock water, and the livestock gas is supplied to the engine block of the internal combustion engine. The carbon dioxide-containing water absorbed in the water is introduced into the water introduction pipe, and the water is converted into water vapor by the heat of combustion in the internal combustion engine. The carbon dioxide is converted to carbon dioxide as an endothermic gas, and a catalyst is opposed to the reforming passage provided in the exhaust gas passage after the combustion process, and a hydrocarbon compound is introduced upstream of the reforming passage, And the endothermic gas carbon dioxide In addition, by contacting the catalyst in the reforming path, a synthesis gas of hydrogen and carbon monoxide is produced, and another livestock gas tank is provided for livestock gas production, and the livestock gas tank is passed through. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that the engine is structured to be a fuel for the engine.
3. A synthesis gas reforming path is provided in the exhaust gas passage according to claim 1, and a mixed gas of hydrogen and carbon monoxide is introduced into the synthesis gas reforming path, and the internal combustion is again performed in the synthesis gas reforming path. Hydrogen and carbon dioxide are separately taken out by reacting with the exhaust heat of the engine, and the extracted hydrogen and carbon dioxide are each provided with a livestock gas tank to produce livestock gas, and hydrogen is used as fuel for the internal combustion engine. Is an internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that it is carbon dioxide as a starting material to be reformed in the reforming path.
An internal combustion engine provided with at least one of the hydrogen and carbon monoxide extraction facility according to any one of claims 1 to 3 or a reforming channel or a syngas reforming channel is mounted on a transportation device. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by being an onboard engine for transport equipment
5. The internal combustion engine according to claim 1, wherein the internal combustion engine is operated under a certain condition, generates electric power with the rotational force, is stored in a capacitor, and the automobile is driven using the electricity as a power source. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by its structure.
When the amount of electricity stored in the capacitor according to claim 5 exceeds a set value, the driving of the internal combustion engine is stopped and the vehicle runs with electric power. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction.
A greenhouse gas characterized in that a charging / receiving plug is provided in the internal combustion engine according to claim 5, and the vehicle is allowed to run as a charging means for storing electricity in a livestock battery using the electricity as a power source. Internal combustion engine that contributes to reduction and emission reduction.
A means for directly using the rotational force of the internal combustion engine according to claim 1 as power generation power of a power generator or steam that has finished the role of turning a turbine of thermal power generation as a reforming heat source and hydrogen monoxide At least one of a carbon extraction facility, a reforming flow path, or a synthesis gas reforming path is provided to generate fuel for the internal combustion engine. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that it is provided as a means for merging.
In the manufacturing industry in which heat or steam is discarded, either hydrogen or carbon monoxide extraction equipment using either the discarded heat or steam or both of them as a reforming heat source, or The internal combustion engine is operated as the fuel for the internal combustion engine by providing at least one of the reforming flow path and the synthesis gas reforming path to generate the fuel for the internal combustion engine, and the rotation thereof The internal combustion engine contributing to greenhouse gas reduction and emission reduction according to claim 1, wherein power is directly used as power generation power of a power generator.
The livestock gas means according to any one of claims 1 to 4 is characterized in that the livestock gas tank is mounted on an upper portion of a vehicle body or mounted on a chassis portion of the vehicle. Internal combustion engine that contributes to greenhouse gas reduction and emission reduction
The livestock gas means according to claim 10 is either a damage prevention means for preventing damage to the tank or a tank separation means for separating the tank from the vehicle installation part in the event of a collision, either or both of them. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized by providing means.
The exhaust heat of the internal combustion engine according to any one of claims 1 to 4 is used as a reforming heat source to process either one or both of a carbon-containing compound and a hydrogen-containing compound to thermally decompose or reform hydrogen H ₂ . , Carbon C or carbon compound, or carbon dioxide CO ₂ , one kind or a plurality of kinds are taken out, and livestock gas is taken into the livestock gas tank, and the compound from which the gas is taken out is sold as a product and taken out An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that the gas is used as a fuel for the internal combustion engine or as a starting material that is reformed and used as a fuel.
5. An internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that the main fuel of the internal combustion engine according to claim 1 is hydrogen.
A water storage means for absorbing heat into the water from the exhaust gas obtained by burning the fuel according to claim 1 to claim 13 is provided in the water storage tank, and water in the storage tank is supplied by the water heat absorption means. The internal combustion engine that contributes to greenhouse gas reduction and emission reduction, characterized in that the water vapor in the exhaust gas that has been absorbed into heat becomes liquid water and is separated and recovered by water recovery means in the form of warm water
5. A small-scale carbon production apparatus for producing plant carbon according to claim 1, wherein the carbonization chamber is configured to heat and carbonize wood or the like (plant raw material) in an environment free from oxygen, and the carbonization chamber. A combustion chamber for burning plant materials such as wood to heat the gas, a vent passage for exhaust gas in the combustion chamber and a pipe for steam generation means for converting water into steam along the inner wall of the carbonization chamber, A small-scale carbon production apparatus having a structure in which water vapor and gas generated in the carbonization process in the carbonization chamber are introduced into the combustion chamber to serve as fuel for heating the carbonization chamber.