JP2016179678A - 犠牲コーティングおよび中間転写体上で犠牲コーティングを使用する間接的な印刷装置 - Google Patents
犠牲コーティングおよび中間転写体上で犠牲コーティングを使用する間接的な印刷装置 Download PDFInfo
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
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- B—PERFORMING OPERATIONS; TRANSPORTING
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Abstract
Description
種々の実施例の犠牲コーティング組成物を表1Aおよび1Bに示す。以下の実施例のすべてのパーセントは、特に言及されない限り、組成物の合計重量を基準とした重量パーセントである。
実施例1のサンプルを、代替的な試験方法を用いて実施した。本開示の上述の方法のような2つの別個の工程でスキンおよびインクを印刷するのではなく、スキンとインク配合物を合わせ、1つの層として塗布し、次いで、乾燥させた。スキンとインクを別個に塗布するとき、これらは、予想されるような2つの別個の層を生成せず、この2つの液体が合わさり、1回の通過で印刷されるときのように、1つの混合層中で混合することが示されている。本明細書に記載するように、この代替的な方法と、間接的な印刷試験に一般的に使用される2工程プロセスとの間に、特定の試験目的のための良好な相関関係が観察される。
(a)溶液の調製:コントロールサンプル1−1、実施例1−1Aおよび1−1Bのそれぞれの犠牲コーティング溶液を、プレミックスインクでスキン比率が1:1になるように実験用の水性黒色インクと混合した。コントロールサンプル1−2および実施例1−1Aの犠牲コーティング溶液を、3個の別個の溶液中、プレミックスインクでスキン比率が1:1、プレミックスインクでスキン比率が1:3、プレミックスインクでスキン比率が1:9になるように実験用の水性インクと混合した。したがって、犠牲スキンの保持量は、それぞれの場合に、インクの保持量と等しいか、それより多い。犠牲スキンの保持量が高いほど、水堅牢度が悪いことがわかっている。
(b)エアブラシプロセス:長方形のエアブラシによる画像を作成するために、ステンレス鋼金属片から2.5cm×15cmの長方形のスリットを切断することによって、画像テンプレートを作成した。エアブラシ処理の前に、長方形の画像を作成することができるように、テンプレートを紙の上に置いた。画像が不透明で均一になり、光学密度がほぼ1.5になるまで、Iwata HP−C Plus Japan MHエアブラシを用いて工程(a)からの溶液を紙の上に噴霧した。
(c)乾燥プロセス:エアブラシ処理されたシートを乾燥機に入れ、92℃、ファン速度700rpmの空気流で2分間乾燥させた。
(d)シート条件:エアブラシ処理されたシートを、23℃、相対湿度約50%で少なくとも1時間かけて平衡状態にした。
種々の犠牲コーティング組成物(実施例3−1A〜3−3Bとして示される)を、間接的な水性インク印刷試験のために作成した。その成分および量を表2および表3に示す。表2および表3のすべてのパーセントは、組成物の合計重量を基準とした重量パーセントである。
図1に一般的に示されるように、印刷工具を使用し、印刷試験を行った。犠牲コーティング(時に、本明細書で「スキン」と呼ばれる)を、溶液の形態で工具のブランケットに塗布し、次いで乾燥させた。これにより、厚みが約0.1〜約0.5ミクロンの強くて丈夫な膜層をブランケット上部に作成した。次いで、スキン上部にインクを吐出し、インクおよびスキンの層全体が基材に転写される前に、半分乾燥させた。種々の処理条件を変更してシステムの自由度を試験し、画像を調べ、システムの性能を評価した。架橋物を含まない配合物と比較して、新しい配合物は、濡れた画像の品質およびインクの転写という観点で同様の性能を示した。
上述のエアブラシサンプルおよび印刷試験サンプルの両方について、Taber線形摩耗試験機Model 5700を用い、水堅牢度の汚れ試験を行った。試験前に、布片(TIC Crockmeter Squares 2インチ×2インチ−製品コード:M238CT)をシャフト底部に接続し、クリップを用いて所定位置に保持した。次いで、体積が約0.10〜0.12mlの水滴を、針を用いて画像領域の上に置いた。1分経過後、インク表面に静止するようにシャフト(重量417.7g)を下げた。すぐに、線形摩耗試験機の開始スイッチを押し、サイクルの半分が終了したら停止させ、図5Bに示されるような汚れサンプルを作成した。
表4−1および表4−2に示されるように、実施例6−1および実施例6−2の犠牲コーティング溶液を異なるPAE保持量で作成した。犠牲コーティング溶液を、プレミックスインクでスキン比率が1:3になるように実験用の水性黒色インクと混合した。異なるPAE保持量を有する配合物について水堅牢度試験を行い、最良の水堅牢度性能を与える保持量を特定した。水堅牢度スクリーニング試験の手順は、実施例5で上に記載したのと同じであった。水堅牢度の結果を図10Aおよび図10Bに示す。表4−1および4−2の値は、組成物の合計重量を基準とした重量パーセントである。
Claims (10)
- 水性インク画像作成システムの中間転写体上の犠牲コーティングであって、前記犠牲コーティングが、
ワックス状デンプンと、
少なくとも1つの架橋物と、
少なくとも1つの吸湿性材料と、
少なくとも1つの界面活性剤とを含む成分から作られる、犠牲コーティング。 - 前記ワックス状デンプンが、ワックス状トウモロコシデンプン、ワックス状米デンプン、ワックス状キャッサバデンプン、ワックス状ジャガイモデンプン、ワックス状小麦デンプンおよびワックス状大麦デンプンからなる群から選択される少なくとも1つのデンプンを含む、請求項1に記載の犠牲コーティング組成物。
- 前記少なくとも1つの架橋物が、四ホウ酸塩およびその水和物、ジアルデヒドおよびその水和物、炭酸ジルコニウムアンモニウム、ヒドロキシル置換された四級アミン基を有するカチオン性樹脂およびこれらの組み合わせからなる群から選択される、請求項1に記載の犠牲コーティング。
- 前記少なくとも1つの架橋物が、四ホウ酸ナトリウム十水和物、グリオキサール、炭酸ジルコニウムアンモニウム、ポリアミド−エピクロロヒドリン樹脂またはこれらの組み合わせからなる群から選択される、請求項1に記載の犠牲コーティング。
- 濡れた犠牲コーティング組成物であって、前記コーティング組成物が、
ワックス状デンプンと、
少なくとも1つの架橋物と、
少なくとも1つの吸湿性材料と、
少なくとも1つの界面活性剤と、
液体担体とを含む成分から作られる、濡れた犠牲コーティング組成物。 - 前記ワックス状デンプンが、ワックス状トウモロコシデンプン、ワックス状米デンプン、ワックス状キャッサバデンプン、ワックス状ジャガイモデンプン、ワックス状小麦デンプンおよびワックス状大麦デンプンからなる群から選択される少なくとも1つのデンプンを含む、請求項5に記載の犠牲コーティング組成物。
- 前記少なくとも1つの架橋物が、四ホウ酸塩およびその水和物、ジアルデヒドおよびその水和物、炭酸ジルコニウムアンモニウム、ヒドロキシル置換された四級アミン基を有するカチオン性樹脂およびこれらの組み合わせからなる群から選択される、請求項5に記載の犠牲コーティング組成物。
- 前記少なくとも1つの架橋物が、四ホウ酸ナトリウム十水和物、グリオキサール、炭酸ジルコニウムアンモニウム、ポリアミド−エピクロロヒドリン樹脂またはこれらの組み合わせからなる群から選択される、請求項5に記載の犠牲コーティング組成物。
- 間接的な印刷プロセスであって、
中間転写体を備えるインクジェット印刷装置にインク組成物を提供することと、
前記中間転写体の上に、
ワックス状デンプンと、
少なくとも1つの架橋物と、
少なくとも1つの吸湿性材料と、
少なくとも1つの界面活性剤と、
液体担体とを含む成分から作られる濡れた犠牲コーティング組成物を堆積させることと、
前記濡れた犠牲コーティング組成物を乾燥させ、犠牲コーティングを作成することと、
前記犠牲コーティングの上に画像状のパターンにインク液滴を放出することと、
前記インクを少なくとも部分的に乾燥させ、前記中間転写体の上に実質的に乾燥したインクパターンを作成することと、
前記実質的に乾燥したインクパターンと前記犠牲コーティングの両方を前記中間転写体から最終基材に転写することとを含む、間接的な印刷プロセス。 - 前記ワックス状デンプンが、ワックス状トウモロコシデンプン、ワックス状米デンプン、ワックス状キャッサバデンプン、ワックス状ジャガイモデンプン、ワックス状小麦デンプンおよびワックス状大麦デンプンからなる群から選択される少なくとも1つのデンプンを含む、請求項9に記載のプロセス。
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US9816000B2 (en) | 2017-11-14 |
US20160280949A1 (en) | 2016-09-29 |
JP6527481B2 (ja) | 2019-06-05 |
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