JP2016176105A - ELECTRONIC COMPONENT Cu-Ni-Co-Si ALLOY - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an electronic component Cu-Ni-Co-Si alloy with improved reliability in which, in addition to a high strength and a high conductivity, also a bendability, which is in general difficult to be compatible with the strength, are imparted to a Corson copper alloy.SOLUTION: Provided is an electronic component Cu-Ni-Co-Si alloy containing Ni by 3.0 to 4.5 mass% and Co by 0.1 to 1.0 mass%, and in which the concentration (mass%) ratio of Ni to Co, (Ni/Co), is adjusted so as to be 3.5 to 30, as well as in which Si is contained so that the (Ni+Co)/Si mass ratio becomes 3 to 5, and in which the balance is composed of Cu and inevitable impurities, and the coefficient of variation of the concentration ratio of Ni to Co, (Ni/Co), measured for at least 100 second-phase particles is 20% or less.SELECTED DRAWING: None

Description

  The present invention relates to a Cu—Ni—Co—Si alloy for electronic components suitable for electronic components, particularly connectors, battery terminals, jacks, relays, switches, lead frames and the like.

  Conventionally, as materials for electrical / electronic devices, copper-based materials such as phosphor bronze, red brass, brass, etc., which are excellent in electrical conductivity and thermal conductivity, have been widely used as materials for electric / electronic devices. In recent years, there has been an increasing demand for miniaturization, weight reduction, high functionality, and high-density mounting associated therewith, and various characteristics are required for copper-based materials applied thereto.

  With the miniaturization of parts, the thinning of materials is progressing, and improvement in material strength is required. In applications such as relays, the demand for fatigue characteristics is increasing, and it is necessary to improve the strength. In addition, with the miniaturization of parts, the conditions for bending are becoming strict, and it is required to have excellent bending workability while having high strength.

  In Patent Document 1, in particular, 0.2% proof stress has a very high strength of 980 MPa or more, or 1000 MPa or more, and has a conductivity of 30% IACS or more, more preferably 34% or more. A Cu—Ni—Co—Si based copper alloy sheet with good press workability has been proposed. According to Patent Document 1, this copper alloy sheet material is used to promote heat treatment 1, hot rolling, cold rolling, solution heat treatment, and precipitation of a Co-Si based compound during aging. It is manufactured through heat treatment 2 that imparts a heat history including pretreatment heat treatment, and aging treatment performed in a low temperature range.

JP 2014-156623 A JP 2011-231393 A JP 2009-007666 A

  By the way, according to the description in Patent Document 1, it is described that, in a Cu—Ni—Co—Si alloy, precipitates are formed by two kinds of compounds, Ni—Si based compounds and Co—Si based compounds, depending on the aging temperature. It is presumed that the influence of the precipitates on the dislocation differs depending on the composition. That is, it is considered that the amount of dislocation introduced depends on the composition of the precipitate. Since dislocations are non-uniform, stress during bending is concentrated, and bending workability may be impaired.

  Therefore, in Patent Document 2, for example, by increasing the proportion of crystal grains having a {100} orientation (Cube orientation) with little anisotropy, the bending workability can be improved and the anisotropy of the bending workability can be improved. It is described that it can be remarkably improved, and specifically, a melting / casting process for melting and casting a copper alloy raw material, a hot rolling process performed after the melting / casting process, and after the hot rolling process A first cold rolling process in which cold rolling is performed at a rolling rate of 70% or more, an intermediate annealing process in which heat treatment is performed at a heating temperature of 500 to 650 ° C. after the first cold rolling process, and the intermediate annealing process. A second cold rolling process in which cold rolling is performed at a rolling rate of 70% or more later, a solution treatment process in which a solution treatment is performed after the second cold rolling process, and 400 after the solution treatment process. Aging treatment process for aging treatment at ~ 500 ° C It is realized by a method comprising.

  For example, in Patent Document 3, the diffraction intensity from the {111} plane on the plate surface is I {111}, the diffraction intensity from the {200} plane is I {200}, and the diffraction intensity from the {220} plane is I { 220}, the diffraction intensity from the {311} plane is I {311}, and the ratio of the diffraction intensity from the {200} plane among these diffraction intensities is R {200} = I {200} / (I {111} + I {200} + I {220} + I {311}), a technique for improving the bending workability by setting R {200} to a certain level or more is described. Specifically, the final recrystallization heat treatment Previously, it has been realized by introducing intermediate annealing to the extent that the work structure is not completely recrystallized, and in addition, intermediate rolling.

  In the future, Corson copper alloy will be required to have high strength and high conductivity in addition to bendability, and generally it will be difficult to achieve both strength and bendability, leaving room for improvement from the viewpoint of improving reliability. Yes.

  As a result of intensive research by the present inventors, in the Cu-Ni-Co-Si alloy, if the composition of precipitates can be unified, dislocations become uniform and stress during bending is dispersed, From the viewpoint that improvement in bending workability is expected, the optimum solution treatment conditions were found and the present invention was completed.

That is, the present invention
(1) It contains 3.0 to 4.5 mass% Ni and 0.1 to 1.0 mass% Co, and the Ni concentration (mass%) ratio (Ni / Co) to Co is 3.5. At least 100 second-phase particles that are adjusted to be ˜30, contain Si so that the mass ratio of (Ni + Co) / Si is 3˜5, and the balance consists of Cu and inevitable impurities A Cu—Ni—Co—Si alloy for electronic parts having a coefficient of variation of the Ni to Co concentration ratio (Ni / Co) of 20% or less.
(2) Further, at least one selected from the group consisting of Fe, Mg, Sn, Zn, B, P, Cr, Zr, Ti, Al, and Mn is contained in a total of up to 2.5% by mass in total (1) alloy.
(3) The alloy according to (1) or (2), wherein the average number of second phase particles having a particle size of 5 to 30 nm is 0.5 × 10 ⁹ particles / mm ² or more.
(4) The alloy according to any one of (1) to (3), wherein the 0.2% yield strength in a direction parallel to the rolling direction is 900 MPa or more and the conductivity is 30% IACS or more.
(5) Bending radius (R) / plate thickness (t) = 1.0, and the average roughness Ra of the bending portion surface when a W-bending test is performed in Badway (the bending axis is the same direction as the rolling direction) is 1.0 μm or less. The alloy according to any one of (1) to (4).
(6) -Step 1 of melt casting a copper alloy ingot having the composition according to (1) or (2);
Step 2 in which hot rolling is performed after heating at −900 ° C. or more and 1050 ° C. or less, and rapid cooling to room temperature is performed. Performing a solution treatment for heating for 10 minutes, and before and after the solution treatment, a step 3 in which a temperature rising rate and a cooling rate in a temperature range between 600 ° C. and 700 ° C. are 50 ° C./second or more;
An aging treatment step 4 of heating at a material temperature of 400 to 550 ° C .;
The manufacturing method of the copper alloy including performing sequentially.
(7) An electronic component comprising the alloy according to any one of (1) to (5).

  According to the present invention, there is provided a Cu-Ni-Co-Si alloy for electronic parts with improved reliability, in which, in addition to high strength and high conductivity, Corson copper alloy is also provided with bendability, which is generally difficult to achieve both strengths. Provided.

  Hereinafter, an embodiment of a Cu—Ni—Co—Si alloy for electronic parts according to the present invention will be described. In the present invention, “%” means “% by mass” unless otherwise specified.

(1) Composition of base material First, the alloy composition will be described. The copper alloy of the present invention is a Cu-Ni-Co-Si alloy. In this specification, a copper alloy obtained by adding other alloy elements such as Fe, Mg, Sn, Zn, B, P, Cr, Zr, Ti, Al, and Mn to the basic component of Cu—Ni—Co—Si. Are also collectively referred to as Cu-Ni-Co-Si alloys.

  Ni forms an Ni—Co—Si based precipitate together with Co and Si described later, and has an effect of improving the strength and conductivity of the copper alloy sheet. If the Ni content is too small, it is difficult to sufficiently exhibit this effect. Therefore, the Ni content is preferably 3.0% by mass or more, more preferably 3.2% by mass or more, and still more preferably 3.4% by mass or more. On the other hand, if the Ni content is too large, the strength improving effect is saturated and the conductivity is lowered. In addition, coarse precipitates are easily generated and cause cracks during bending. Therefore, the Ni content is preferably 4.5% by mass or less, and more preferably 4.1% by mass or less.

  Co, together with Ni and Si, forms an Ni—Co—Si based precipitate and has the effect of improving the strength and conductivity of the copper alloy sheet. When the Co content is too small, it is difficult to sufficiently exhibit this effect. Therefore, the Co content is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, and further preferably 0.3% by mass or more. On the other hand, since the melting point of Co is higher than that of Ni, if the Co content is too large, complete solid solution is difficult, and the undissolved portion does not contribute to the strength. Therefore, the Co content is preferably 1.0% by mass or less, and more preferably 0.8% by mass or less.

In addition, the present invention is characterized in that Ni—Co—Si based precipitates are generated to exhibit the effect of improving the strength and conductivity of the copper alloy sheet at a higher level. Therefore, unlike the case of generating ordinary Co—Si based precipitates and Ni—Si based precipitates, the coefficient of variation of the Ni to Co concentration ratio (Ni / Co) in the composition of each precipitate is reduced to some extent. It is required to do. From this viewpoint, the coefficient of variation of the Ni concentration ratio (Ni / Co) to Co, that is, “standard deviation / average value × 100” is set to 20% or less, preferably 16% or less. The variation coefficient of Ni / Co is a value that can be measured and estimated for 100 or more second-phase particles that are precipitates.
Further, in order to set the coefficient of variation of the Ni / Co concentration ratio in such precipitates to a predetermined value or less, the Ni / Co concentration (mass%) ratio in the alloy material before precipitation of the second phase particles is 3.5. It is good to adjust so that it may become -30, Preferably it is 5-15.

Si produces Ni—Co—Si based precipitates together with Ni and Co. However, Ni, Co, and Si in the alloy are not necessarily all precipitated by the aging treatment, and exist to some extent in a solid solution state in the Cu matrix. Ni, Co, and Si in the solid solution state slightly improve the strength of the copper alloy sheet, but the effect is smaller than that in the precipitated state, and causes a decrease in conductivity. Therefore, in general, the Si content is preferably as close to the composition ratio of precipitates (Ni + Co) ₂ Si as possible. That is, the (Ni + Co) / Si mass ratio is generally adjusted to 3 to 5 around 4.2, and Si is added so that the (Ni + Co) / Si mass ratio falls within this range. .

  If necessary, Fe, Mg, Sn, Zn, B, P, Cr, Zr, Ti, Al and Mn may be added to the copper alloy sheet of the present invention. For example, Sn and Mg have the effect of improving the stress relaxation resistance, Zn has the effect of improving the solderability and castability of the copper alloy sheet, and Fe, Cr, Mn, Ti, Zr, Al, etc. have the strength. Has the effect of improving. In addition, P has a deoxidizing effect, B has an effect of refining a cast structure, and has an effect of improving hot workability. However, if the amount of these additive elements is too large, the productivity is greatly impaired. Therefore, 0 to 2.5% by mass can be contained in total. In consideration of the balance of strength, electrical conductivity, and bendability, it is preferable to contain one or more of the above elements in a total amount of 0.2 to 1.0% by mass. In addition, for each additive element, in consideration of the balance of stress relaxation resistance, strength, solderability, castability, hot workability, etc., Zn is 0.1 mass within a range not exceeding the total amount. % And 2.0 mass% or less, Sn and Cr can be contained 0.1 mass% or more and 1.0 mass% or less, and Fe, Mg and Mn are 0.1 mass% or more and 0.1 mass% or less. 5% by mass or less can be contained, and B, P, Zr, Ti and Al can be contained by 0.01% by mass to 0.3% by mass.

(2) Strength and conductivity The alloy of the present invention has high strength and high conductivity, and is suitable for electronic components, particularly connectors, battery terminals, jacks, relays, switches, lead frames and the like.
Here, the rolling parallelism was measured by preparing a JIS 13B test piece using a press so that the tensile direction was parallel to the rolling direction, and performing a tensile test of the test piece in accordance with JIS-Z2241. Evaluated as 0.2% proof stress (YS) in the direction. From the viewpoint of the use described above, the 0.2% proof stress is preferably 900 MPa or more, and particularly 950 MPa or more.
Moreover, electrical conductivity is evaluated as electrical conductivity (EC:% IACS) measured by the 4-terminal method in accordance with JIS H 0505. From the viewpoint of the above-mentioned application, this conductivity is preferably 30% IACS or more, particularly 35% IACS or more.

(3) Bendability surface roughness In this invention, bendability is evaluated as average roughness Ra of the surface of a bending part when W bending test is carried out.
That is, the smaller the average roughness Ra of the surface of the bent part when the B-bending test is performed with a badway (bending axis is the same direction as the rolling direction) with a bending radius (R) / plate thickness (t) = 1.0, the bending processing is performed. The stress at the time is dispersed and the bending workability is expected to be improved. From this viewpoint, the average roughness Ra of the surface of the bent portion is preferably 1.0 μm or less.
(4) Number Concentration of Precipitates In the present invention, improvement of strength, electrical conductivity, and bendability is an issue by controlling the precipitates. Therefore, it is preferable to evaluate the number of the precipitates. That is, the number concentration of the precipitates was counted by counting the number of second phase particles having a particle size of 5 to 30 nm and divided by the observation area to calculate the number concentration (× 10 ⁹ particles / mm ² ). It calculates about a visual field (each visual field 1 micrometer x 1 micrometer), and evaluates it as the average value.
Specifically, after exposing a cross section by cutting a cross section parallel to the rolling direction with a focused ion beam (FIB), a scanning transmission electron microscope (JEOL Ltd. model: JEM-2100F) is used. The number concentration of precipitates to be measured is determined. The number concentration of the precipitates is preferably 0.5 × 10 ⁹ pieces / mm ² or more from the viewpoint of ensuring sufficient strength (0.2% yield strength), and more preferably 1.5 × 10 ⁹ pieces / mm ^2. it is preferably mm ² or more.
Here, the second phase particles are crystallized substances generated in the solidification process of melt casting, precipitates generated in the subsequent cooling process, precipitates generated in the cooling process after hot rolling, and cooling processes after the solution treatment. This refers to precipitates generated and precipitates generated during the aging treatment process. Usually, it has a Co-Si or Ni-Si composition, but in the present invention, it has a Ni-Co-Si composition. Is typical. The size of the second phase particles is defined as the diameter of the maximum circle that can be surrounded by precipitates when the cross section parallel to the rolling direction is observed with an electron microscope.

(5) Applications The Cu-Ni-Co-Si alloy according to the present invention can be processed into various copper products, such as plates, strips, tubes, bars and wires. Although not limited, the copper alloy of the present invention is suitable as a material for electronic components such as connectors, battery terminals, jacks, relays, switches, lead frames and the like.

(6) Manufacturing method Cu-Ni-Co-Si alloy for electronic parts according to an embodiment of the present invention is an ingot melt casting (step 1)-homogeneous annealing, hot rolling, rapid cooling (step 2)-cold rolling. It is manufactured through solution treatment (step 3) -aging treatment (step 4).

<Ingot manufacturing>
Using an atmospheric melting furnace, raw materials such as electrolytic copper, Ni, Co, and Si are melted to obtain a molten metal having a desired composition. Then, this molten metal is cast into an ingot. The additive elements other than Ni, Co, and Si are one or two or more from the group consisting of Fe, Mg, Sn, Zn, B, P, Cr, Zr, Ti, Al, and Mn in total 0 to 2.5 mass. % So that it is contained.

<Homogenization annealing and hot rolling>
Since solidified segregation and crystallized matter generated during the production of the ingot are coarse, it is desirable to make it as small as possible by dissolving it in the parent phase as much as possible by homogenization annealing. This is because they have an adverse effect on bending workability and are effective in preventing bending cracking by being dissolved in the matrix.
Specifically, after an ingot manufacturing process, after heating to 900-1050 degreeC and performing homogenization annealing for 3 to 24 hours, hot rolling is implemented. The pass from the original thickness to the overall rolling reduction of 90% is preferably 700 ° C. or higher. Thereafter, it is rapidly cooled to room temperature with water cooling.

<Cold rolling and solution treatment>
Thereafter, the solution is subjected to solution treatment after cold rolling under conditions of a working degree (rolling rate) of 50% or more, preferably 70% or more. Specifically, it is heated to 900 to 1050 ° C. and heated for 30 seconds to 10 minutes. The solution treatment is intended to solidify additive elements such as Ni, Co, and Si. Therefore, it is important to control the heating rate and the cooling rate in addition to the heating temperature and the heating time. At the time of temperature increase before the solution treatment, the temperature increase rate of 600 to 700 ° C. that affects the precipitation of the second phase particles containing Co is controlled to 50 ° C./second or more. On the other hand, the cooling rate in the same temperature range after the solution treatment is also controlled to 50 ° C./second or more. Also in other temperature regions, it is preferable to increase the heating rate and the cooling rate as much as possible. In addition, by adjusting the tension applied to the material to 1 MPa or more and 10 MPa or less, it becomes possible to more conveniently control the precipitation of the second phase particles, and the coefficient of variation of the Ni / Co concentration ratio in the precipitate. 20% or less, the number concentration of precipitates having a particle size of 5 to 30 nm can be sufficiently secured, and sufficient strength can be imparted.

  Thus, by increasing the temperature rise and cooling rate at 600 to 700 ° C. during the solution treatment, the precipitation of the Co—Si based compound is suppressed, and as a result, the precipitate of the Ni—Co—Si based compound is generated. It is thought that. Moreover, the strength was increased by lowering the tension of the material during the solution treatment to about 20 MPa. Although this mechanism is unknown, the strain introduced when cold rolling is performed in the previous process is released uniformly by controlling the temperature increase rate, and the strength is increased by the subsequent aging treatment. It is thought that.

<Aging treatment>
An aging treatment is performed following the solution treatment. Heating at a material temperature of 400 to 550 ° C. for 5 to 25 hours is preferable, and heating at a material temperature of 420 to 500 ° C. for 10 to 20 hours is more preferable. The aging treatment is preferably performed in an inert atmosphere of Ar, N ₂ , H ₂ or the like in order to suppress the generation of an oxide film.

<Final cold rolling>
Following the aging treatment, the final cold rolling is performed. Although the strength can be increased by the final cold working, in order to obtain a good balance between high strength and bending workability as intended in the present invention, the rolling reduction is 15 to 45%, preferably 20 to 40%. % Is desirable.

<Strain relief annealing>
Following the final cold rolling, strain relief annealing is performed. It is preferable to heat at a material temperature of 350 to 650 ° C. for 1 to 3600 seconds, a material temperature of 350 to 450 ° C. for 1500 to 3600 seconds, a material temperature of 450 to 550 ° C. for 500 to 1500 seconds, and a material temperature of 550 to 650 ° C. for 1 to 1. It is more preferable to heat for 500 seconds.

  A person skilled in the art will understand that steps such as grinding, polishing, and shot blast pickling for removing oxide scale on the surface can be appropriately performed between the above steps.

  EXAMPLES Examples (invention examples) of the present invention are shown below together with comparative examples, which are provided for better understanding of the present invention and its advantages, and are not intended to limit the invention. .

  A copper alloy containing each additive element shown in Table 1 and the balance consisting of copper and impurities was melted at 1300 ° C. in a high frequency melting furnace and cast into a 30 mm thick ingot. Next, this ingot was heated at 1000 ° C. for 3 hours, and then hot-rolled to a plate thickness of 10 mm, and cooled rapidly after the hot rolling was completed. Next, after surface chamfering to a thickness of 9 mm for removing scale on the surface, a plate having a thickness of 0.120 to 0.175 mm was formed by cold rolling. Next, solution treatment was performed at 950 ° C. for 120 seconds. Table 1 shows the heating rate, cooling rate, and tension in the temperature range of 600 to 700 ° C. Thereafter, aging treatment and cold rolling were added under the conditions shown in Table 1 to obtain a plate thickness of 0.1 mm. Finally, strain relief annealing was applied at a material temperature of 400 ° C. for 2000 seconds.

The following evaluation was performed about the produced product sample. The evaluation results are shown in Table 2.
(1) 0.2% yield strength A JIS No. 13B test piece was prepared using a press so that the tensile direction was parallel to the rolling direction. The specimen was subjected to a tensile test according to JIS-Z2241, and the 0.2% proof stress (YS) in the rolling parallel direction was measured.

(2) Conductivity Based on JIS H 0505, the conductivity (EC:% IACS) was measured by the 4-terminal method.

(3) Surface roughness of the bent portion In accordance with JIS-H3130 (2012), a W bending test was performed with Badway (bending axis is the same direction as the rolling direction), r / t = 1.0 (t = 0.1 mm), The outer peripheral surface of the bent part of this test piece was observed. As an observation method, the outer peripheral surface of the bent part was photographed using a laser tech confocal microscope HD100, and the average roughness Ra (conforming to JIS-B0601: 2013) was measured using the attached software and compared. In addition, when the sample surface before a bending process was observed using the confocal microscope, the unevenness | corrugation was not able to be confirmed but all average roughness Ra was 0.2 micrometer or less.
The case where the surface average roughness Ra after bending was 1.0 μm or less was evaluated as “◯”, and the case where Ra exceeded 1.0 μm was evaluated as “×”.

(4) Number concentration of precipitates with a particle size of 5 to 30 nm After exposing the cross section by cutting a cross section parallel to the rolling direction with a focused ion beam (FIB), a scanning transmission electron microscope (JEOL Ltd.) , Model: JEM-2100F), and the number concentration of the precipitates was measured.
Specifically, the acceleration voltage is 200 kV, the observation magnification is 1,000,000 times, the number of second phase particles having a particle size of 5 to 30 nm is counted, divided by the observation area, and the number concentration (× 10 ⁹ particles / mm ² ). Was calculated. Similarly, measurements were made for 20 fields of view, and the average value was taken as the number density.

(5) Coefficient of variation of Ni / Co concentration ratio in precipitates Using an energy dispersive X-ray analyzer (EDX, manufactured by JEOL Ltd., model: JED-2300) as a STEM detector, Ni / Co in the precipitates The ratio was measured. The acceleration voltage and observation magnification were the same as those described above, and the electron beam spot diameter was 0.2 nm. The Ni / Co ratio was measured for 100 or more second phase particles. Thereafter, an average value and a standard deviation were calculated to obtain a coefficient of variation (standard deviation / average value × 100).

  In Invention Examples 1 to 24, 0.2% proof stress is 900 MPa or more, conductivity is 30% IACS or more, and the surface roughness of the bent portion is 1.0 μm or less, which is favorable in the precipitate. The coefficient of variation of the Ni / Co concentration ratio was also well balanced with 20% or less. It can be said that these copper alloy materials have an excellent balance of high strength, high conductivity, and high bending workability.

Comparative Examples 1 to 18 are specific examples where it is considered that the precipitation of the second phase particles could not be sufficiently controlled.
Comparative Example 1 is a specific example in which the rate of temperature increase during solution treatment is less than 50 ° C./s, and Comparative Example 2 is a specific example in which the cooling rate during solution treatment is less than 50 ° C./s. In Comparative Examples 1 and 2, the coefficient of variation of the Ni / Co concentration ratio in the precipitate was 20% or more, and it was found difficult to exhibit sufficient bending workability.

  Comparative Examples 3 and 4 are a specific example (Comparative Example 3) and a specific example (Comparative Example 4) in which the tension applied to the alloy material during the solution treatment is too small. As a result, a sufficient amount cannot be secured in the number concentration of precipitates having a particle diameter of 5 to 30 nm which is considered to contribute to the strength, and the variation coefficient of the Ni / Co concentration ratio in the precipitates is 20% or more, which is sufficient. It was found that it was difficult to exert strength.

  Comparative Examples 5 and 6 are specific examples in which the heating conditions in the aging treatment after the solution treatment are out of 400 to 550 ° C. As a result, it is difficult to ensure a sufficient amount in the number concentration of precipitates having a particle diameter of 5 to 30 nm, which is considered to contribute to the strength, it is difficult to exert sufficient strength, and it is sufficient that the temperature of the aging treatment is too low. It turned out that it was also difficult to exhibit electrical conductivity.

Comparative Example 7 is a specific example in which the Ni content in the components of the copper alloy is smaller than 3.0% by mass. It has been found that it is difficult to exert sufficient strength when the Ni content is small.
Comparative Example 8 is a specific example in which the Ni content in the copper alloy components exceeds 4.5% by mass. When the Ni content was large, cracks occurred during hot rolling, and no product was obtained.

  Comparative Example 9 is a specific example in which Co is not contained in the copper alloy, and Comparative Example 10 is a specific example in which the Co content in the components of the copper alloy exceeds 1.0 mass%. It has been found that it is difficult to exhibit sufficient bending workability if the Co content is not within an appropriate range.

  Comparative Examples 11 and 12 are a specific example (Comparative Example 11) in which the (Ni + Co) / Si mass ratio in the copper alloy is too large and a specific example (Comparative Example 12) that is too small. If the (Ni + Co) / Si mass ratio was not in the proper range, the number concentration of precipitates having a particle size of 5 to 30 nm would not be sufficient, resulting in inferior strength and conductivity.

  Comparative Examples 13 and 14 are a specific example (Comparative Example 13) in which the Ni / Co concentration ratio before precipitation of the second phase particles in the copper alloy is too small and a specific example (Comparative Example 14) that is too large. In both Comparative Examples 13 and 14, the coefficient of variation of the Ni / Co concentration ratio in the precipitate was 20% or more, and it was found that it was difficult to exhibit sufficient bending workability.

  Comparative Example 15 is a specific example in which the total amount of the third additive element other than Ni, Co, and Si exceeds 2.5. When the third additive element was too much, the variation coefficient of the Ni / Co concentration ratio in the precipitate was 20% or more, which resulted in inferior bending workability and conductivity.

Comparative Examples 16 to 18 are specific examples in which the tension applied to the alloy material during the solution treatment is large.
Comparative Example 18 is a specific example representing the aspect of Patent Document 3. It was found that the coefficient of variation of the Ni / Co concentration ratio in the precipitate was 20% or more, and the number concentration of the precipitate having a particle size of 5 to 30 nm was small, making it difficult to exhibit sufficient strength.
Comparative Example 17 is a specific example that represents the aspect of Patent Document 2 by further reducing the cooling rate during the solution treatment to less than 50 ° C./s. The variation coefficient of the Ni / Co concentration ratio in the precipitate was 20% or more, and it was found that it was difficult to exhibit sufficient bending workability.
The comparative example 16 further reduced the cooling rate during the solution treatment to less than 50 ° C./s, and performed the aging treatment after the solution treatment under a temperature condition lower than a predetermined range. This is a representative example. Even in this case, the variation coefficient of the Ni / Co concentration ratio in the precipitate was 20% or more, and it was found difficult to exhibit sufficient bending workability.

Claims (7)

  Containing 3.0 to 4.5% by mass of Ni and 0.1 to 1.0% by mass of Co, the concentration ratio (Ni / Co) of Ni to Co is 3.5 to 30 In addition, Si was contained so that the mass ratio of (Ni + Co) / Si was 3 to 5, and the balance was made of Cu and inevitable impurities, and at least 100 second phase particles were measured. A Cu—Ni—Co—Si alloy for electronic parts, wherein the coefficient of variation of the concentration ratio of Ni to Co (Ni / Co) is 20% or less.   The alloy according to claim 1, further comprising a total of at most 2.5 mass% of at least one selected from the group consisting of Fe, Mg, Sn, Zn, B, P, Cr, Zr, Ti, Al and Mn. The alloy according to claim 1 or 2, wherein the average number of second phase particles having a particle size of 5 to 30 nm is 0.5 x 10 ⁹ particles / mm ² or more.   The alloy as described in any one of Claims 1-3 whose 0.2% yield strength in the direction parallel to a rolling direction is 900 Mpa or more, and whose electrical conductivity is 30% IACS or more.   Bending radius (R) / plate thickness (t) = 1.0, the average roughness Ra of the bending portion surface when a W-bending test is performed in Badway (the bending axis is the same direction as the rolling direction) is 1.0 μm or less. The alloy according to any one of claims 1 to 4. -Melting and casting a copper alloy ingot having the composition according to claim 1 or 2;
Step 2 in which hot rolling is performed after heating at −900 ° C. or more and 1050 ° C. or less, and rapid cooling to room temperature is performed. Performing a solution treatment for heating for 10 minutes, and before and after the solution treatment, a step 3 in which a temperature rising rate and a cooling rate in a temperature range between 600 ° C. and 700 ° C. are 50 ° C./second or more;
An aging treatment step 4 of heating at a material temperature of 400 to 550 ° C .;
The manufacturing method of the copper alloy including performing sequentially.   The electronic component provided with the alloy as described in any one of Claims 1-5.