JP2016125103A5 - - Google Patents

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JP2016125103A5
JP2016125103A5 JP2015000678A JP2015000678A JP2016125103A5 JP 2016125103 A5 JP2016125103 A5 JP 2016125103A5 JP 2015000678 A JP2015000678 A JP 2015000678A JP 2015000678 A JP2015000678 A JP 2015000678A JP 2016125103 A5 JP2016125103 A5 JP 2016125103A5
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Priority to EP16150037.6A priority patent/EP3042974B1/en
Priority to US14/988,018 priority patent/US20160194740A1/en
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上記目的は、下記の本発明により達成される。
本発明の粉末冶金用金属粉末は、Feが主成分であり、
Crが15質量%以上26質量%以下の割合で含まれ、
Niが7質量%以上22質量%以下の割合で含まれ、
Siが0.3質量%以上1.2質量%以下の割合で含まれ、
Cが0.005質量%以上0.3質量%以下の割合で含まれ、
Ti、V、Y、Zr、Nbおよびfからなる群から選択される1種の元素を第1元素とし、V、Y、Zr、Nb、HfおよびTaからなる群から選択される1種の元素であって元素周期表における族が前記第1元素より大きい元素または元素周期表における族が前記第1元素と同じでかつ元素周期表における周期が前記第1元素より大きい元素を第2元素としたとき、
前記第1元素が0.01質量%以上0.5質量%以下の割合で含まれ、
前記第2元素が0.01質量%以上0.5質量%以下の割合で含まれていることを特徴とする。
本発明の粉末冶金用金属粉末は、Feが主成分であり、
Crが15.5質量%以上25質量%以下の割合で含まれ、
Niが7.5質量%以上17質量%以下の割合で含まれ、
Siが0.4質量%以上1.1質量%以下の割合で含まれ、
Cが0.008質量%以上0.15質量%以下の割合で含まれ、
Ti、V、Y、Zr、NbおよびHfからなる群から選択される1種の元素を第1元素とし、V、Y、Zr、Nb、HfおよびTaからなる群から選択される1種の元素であって元素周期表における族が前記第1元素より大きい元素または元素周期表における族が前記第1元素と同じでかつ元素周期表における周期が前記第1元素より大きい元素を第2元素としたとき、
前記第1元素が0.03質量%以上0.2質量%以下の割合で含まれ、
前記第2元素が0.03質量%以上0.2質量%以下の割合で含まれていることを特徴とする。
本発明の粉末冶金用金属粉末は、Feが主成分であり、
Crが16質量%以上21質量%以下の割合で含まれ、
Niが8質量%以上15質量%以下の割合で含まれ、
Siが0.5質量%以上0.9質量%以下の割合で含まれ、
Cが0.01質量%以上0.08質量%以下の割合で含まれ、
Ti、V、Y、Zr、NbおよびHfからなる群から選択される1種の元素を第1元素とし、V、Y、Zr、Nb、HfおよびTaからなる群から選択される1種の元素であって元素周期表における族が前記第1元素より大きい元素または元素周期表における族が前記第1元素と同じでかつ元素周期表における周期が前記第1元素より大きい元素を第2元素としたとき、
前記第1元素が0.05質量%以上0.1質量%以下の割合で含まれ、
前記第2元素が0.05質量%以上0.1質量%以下の割合で含まれていることを特徴とする。
The above object is achieved by the present invention described below.
The metal powder for powder metallurgy of the present invention is mainly composed of Fe,
Cr is contained at a ratio of 15% by mass or more and 26% by mass or less,
Ni is contained in a ratio of 7% by mass or more and 22% by mass or less,
Si is contained in a proportion of 0.3% by mass or more and 1.2% by mass or less,
C is contained in a proportion of 0.005 mass% or more and 0.3 mass% or less,
Ti, V, Y, Zr, and one element selected from Nb and H f or Ranaru group as a first element, V, Y, Zr, Nb , 1 kind selected from the group consisting of Hf and Ta An element of which the group in the periodic table is greater than the first element or the group in the periodic table is the same as the first element and the period in the periodic table is greater than the first element When
The first element is included in a proportion of 0.01% by mass to 0.5% by mass,
The second element is contained in a proportion of 0.01% by mass or more and 0.5% by mass or less.
The metal powder for powder metallurgy of the present invention is mainly composed of Fe,
Cr is contained in a ratio of 15.5% by mass to 25% by mass,
Ni is contained in a proportion of 7.5% by mass or more and 17% by mass or less,
Si is contained at a ratio of 0.4% by mass or more and 1.1% by mass or less,
C is contained in a proportion of 0.008% by mass or more and 0.15% by mass or less,
One element selected from the group consisting of Ti, V, Y, Zr, Nb and Hf is the first element, and one element selected from the group consisting of V, Y, Zr, Nb, Hf and Ta An element whose group in the periodic table is larger than the first element or an element whose group in the periodic table is the same as the first element and whose period in the periodic table is larger than the first element is a second element. When
The first element is included in a ratio of 0.03% by mass to 0.2% by mass,
The second element is contained in a proportion of 0.03% by mass or more and 0.2% by mass or less.
The metal powder for powder metallurgy of the present invention is mainly composed of Fe,
Cr is contained in a proportion of 16% by mass or more and 21% by mass or less,
Ni is contained at a ratio of 8% by mass or more and 15% by mass or less,
Si is contained in a proportion of 0.5% by mass or more and 0.9% by mass or less,
C is contained in a proportion of 0.01% by mass or more and 0.08% by mass or less,
One element selected from the group consisting of Ti, V, Y, Zr, Nb and Hf is the first element, and one element selected from the group consisting of V, Y, Zr, Nb, Hf and Ta An element whose group in the periodic table is larger than the first element or an element whose group in the periodic table is the same as the first element and whose period in the periodic table is larger than the first element is a second element. When
The first element is included in a proportion of 0.05% by mass or more and 0.1% by mass or less,
The second element is contained in a proportion of 0.05% by mass or more and 0.1% by mass or less.

本発明の粉末冶金用金属粉末では、前記第2元素の含有率E2を前記第2元素の質量数で除した値X2に対する前記第1元素の含有率E1を前記第1元素の質量数で除した値X1の比率X1/X2は、0.3以上3以下であることが好ましい。
本発明の粉末冶金用金属粉末では、前記第2元素の含有率E2を前記第2元素の質量数で除した値X2に対する前記第1元素の含有率E1を前記第1元素の質量数で除した値X1の比率X1/X2は、0.5以上2以下であることが好ましい。
本発明の粉末冶金用金属粉末では、前記第2元素の含有率E2を前記第2元素の質量数で除した値X2に対する前記第1元素の含有率E1を前記第1元素の質量数で除した値X1の比率X1/X2は、0.75以上1.3以下であることが好ましい。
In the metal powder for powder metallurgy according to the present invention, the content E1 of the first element relative to the value X2 obtained by dividing the content E2 of the second element by the mass of the second element is divided by the mass of the first element. The ratio X1 / X2 of the obtained value X1 is preferably 0.3 or more and 3 or less.
In the metal powder for powder metallurgy according to the present invention, the content E1 of the first element relative to the value X2 obtained by dividing the content E2 of the second element by the mass of the second element is divided by the mass of the first element. The ratio X1 / X2 of the obtained value X1 is preferably 0.5 or more and 2 or less.
In the metal powder for powder metallurgy according to the present invention, the content E1 of the first element relative to the value X2 obtained by dividing the content E2 of the second element by the mass of the second element is divided by the mass of the first element. The ratio X1 / X2 of the measured value X1 is preferably 0.75 or more and 1.3 or less.

本発明の粉末冶金用金属粉末では、前記第1元素の含有率と前記第2元素の含有率の合計が0.05質量%以上0.6質量%以下であることが好ましい。
本発明の粉末冶金用金属粉末では、前記第1元素の含有率と前記第2元素の含有率の合計が0.1質量%以上0.48質量%以下であることが好ましい。
本発明の粉末冶金用金属粉末では、前記第1元素の含有率と前記第2元素の含有率の合計が0.12質量%以上0.24質量%以下であることが好ましい。
これにより、製造される焼結体の高密度化が必要かつ十分なものとなる。
In the metal powder for powder metallurgy according to the present invention, the total content of the first element and the content of the second element is preferably 0.05% by mass or more and 0.6% by mass or less.
In the metal powder for powder metallurgy of the present invention, the total content of the first element and the content of the second element is preferably 0.1% by mass or more and 0.48% by mass or less.
In the metal powder for powder metallurgy of the present invention, the total content of the first element and the content of the second element is preferably 0.12% by mass or more and 0.24% by mass or less.
As a result, the density of the sintered body to be manufactured becomes necessary and sufficient.

本発明の粉末冶金用金属粉末では、さらに、Moが1質量%以上5質量%以下の割合で含まれていることが好ましい。
本発明の粉末冶金用金属粉末では、さらに、Moが1.2質量%以上4質量%以下の割合で含まれていることが好ましい。
本発明の粉末冶金用金属粉末では、さらに、Moが2質量%以上3質量%以下の割合で含まれていることが好ましい。
In the metal powder for powder metallurgy of the present invention, it is preferable that Mo is further contained at a ratio of 1% by mass to 5% by mass.
In the metal powder for powder metallurgy of the present invention, it is preferable that Mo is further contained at a ratio of 1.2% by mass or more and 4% by mass or less.
In the metal powder for powder metallurgy of the present invention, it is preferable that Mo is further contained in a ratio of 2% by mass or more and 3% by mass or less.

本発明の焼結体は、Feが主成分であり、
Crが15質量%以上26質量%以下の割合で含まれ、
Niが7質量%以上22質量%以下の割合で含まれ、
Siが0.3質量%以上1.2質量%以下の割合で含まれ、
Cが0.005質量%以上0.3質量%以下の割合で含まれ、
Ti、V、Y、Zr、Nbおよびfからなる群から選択される1種の元素を第1元素とし、V、Y、Zr、Nb、HfおよびTaからなる群から選択される1種の元素であって元素周期表における族が前記第1元素より大きい元素または元素周期表における族が前記第1元素と同じでかつ元素周期表における周期が前記第1元素より大きい元素を第2元素としたとき、
前記第1元素が0.01質量%以上0.5質量%以下の割合で含まれ、
前記第2元素が0.01質量%以上0.5質量%以下の割合で含まれている粉末冶金用金属粉末を焼結して製造されたことを特徴とする。
本発明の焼結体は、Feが主成分であり、
Crが15質量%以上26質量%以下の割合で含まれ、
Niが7質量%以上22質量%以下の割合で含まれ、
Siが0.3質量%以上1.2質量%以下の割合で含まれ、
Cが0.005質量%以上0.3質量%以下の割合で含まれ、
Ti、V、Y、Zr、NbおよびHfからなる群から選択される1種の元素を第1元素とし、V、Y、Zr、Nb、HfおよびTaからなる群から選択される1種の元素であって元素周期表における族が前記第1元素より大きい元素または元素周期表における族が前記第1元素と同じでかつ元素周期表における周期が前記第1元素より大きい元素を第2元素としたとき、
前記第1元素が0.01質量%以上0.5質量%以下の割合で含まれ、
前記第2元素が0.01質量%以上0.5質量%以下の割合で含まれていることを特徴とする。
これにより、追加処理を施すことなく、高密度の焼結体が得られる。
The sintered body of the present invention is mainly composed of Fe,
Cr is contained at a ratio of 15% by mass or more and 26% by mass or less,
Ni is contained in a ratio of 7% by mass or more and 22% by mass or less,
Si is contained in a proportion of 0.3% by mass or more and 1.2% by mass or less,
C is contained in a proportion of 0.005 mass% or more and 0.3 mass% or less,
Ti, V, Y, Zr, and one element selected from Nb and H f or Ranaru group as a first element, V, Y, Zr, Nb , 1 kind selected from the group consisting of Hf and Ta An element of which the group in the periodic table is greater than the first element or the group in the periodic table is the same as the first element and the period in the periodic table is greater than the first element When
The first element is included in a proportion of 0.01% by mass to 0.5% by mass,
It is manufactured by sintering metal powder for powder metallurgy containing the second element in a proportion of 0.01% by mass or more and 0.5% by mass or less.
The sintered body of the present invention is mainly composed of Fe,
Cr is contained at a ratio of 15% by mass or more and 26% by mass or less,
Ni is contained in a ratio of 7% by mass or more and 22% by mass or less,
Si is contained in a proportion of 0.3% by mass or more and 1.2% by mass or less,
C is contained in a proportion of 0.005 mass% or more and 0.3 mass% or less,
One element selected from the group consisting of Ti, V, Y, Zr, Nb and Hf is the first element, and one element selected from the group consisting of V, Y, Zr, Nb, Hf and Ta An element whose group in the periodic table is larger than the first element or an element whose group in the periodic table is the same as the first element and whose period in the periodic table is larger than the first element is a second element. When
The first element is included in a proportion of 0.01% by mass to 0.5% by mass,
The second element is contained in a proportion of 0.01% by mass or more and 0.5% by mass or less.
Thereby, a high-density sintered compact is obtained, without performing an additional process.

本発明の焼結体では、酸化ケイ素の含有率が相対的に高い第1領域と、前記第1領域よりも酸化ケイ素の含有率が相対的に低い第2領域と、を含むことが好ましい。 In the sintered body of the present invention preferably includes a first region content is relatively high oxidation silicon, and a second region content is relatively low silicon oxide than the first region .

Claims (19)

Feが主成分であり、
Crが15質量%以上26質量%以下の割合で含まれ、
Niが7質量%以上22質量%以下の割合で含まれ、
Siが0.3質量%以上1.2質量%以下の割合で含まれ、
Cが0.005質量%以上0.3質量%以下の割合で含まれ、
Ti、V、Y、Zr、Nbおよびfからなる群から選択される1種の元素を第1元素とし、V、Y、Zr、Nb、HfおよびTaからなる群から選択される1種の元素であって元素周期表における族が前記第1元素より大きい元素または元素周期表における族が前記第1元素と同じでかつ元素周期表における周期が前記第1元素より大きい元素を第2元素としたとき、
前記第1元素が0.01質量%以上0.5質量%以下の割合で含まれ、
前記第2元素が0.01質量%以上0.5質量%以下の割合で含まれていることを特徴とする粉末冶金用金属粉末。
Fe is the main component,
Cr is contained at a ratio of 15% by mass or more and 26% by mass or less,
Ni is contained in a ratio of 7% by mass or more and 22% by mass or less,
Si is contained in a proportion of 0.3% by mass or more and 1.2% by mass or less,
C is contained in a proportion of 0.005 mass% or more and 0.3 mass% or less,
Ti, V, Y, Zr, and one element selected from Nb and H f or Ranaru group as a first element, V, Y, Zr, Nb , 1 kind selected from the group consisting of Hf and Ta An element of which the group in the periodic table is greater than the first element or the group in the periodic table is the same as the first element and the period in the periodic table is greater than the first element When
The first element is included in a proportion of 0.01% by mass to 0.5% by mass,
The metal powder for powder metallurgy, characterized in that the second element is contained in a proportion of 0.01% by mass or more and 0.5% by mass or less.
Feが主成分であり、  Fe is the main component,
Crが15.5質量%以上25質量%以下の割合で含まれ、  Cr is contained in a ratio of 15.5% by mass to 25% by mass,
Niが7.5質量%以上17質量%以下の割合で含まれ、  Ni is contained in a proportion of 7.5% by mass or more and 17% by mass or less,
Siが0.4質量%以上1.1質量%以下の割合で含まれ、  Si is contained in a proportion of 0.4 mass% or more and 1.1 mass% or less,
Cが0.008質量%以上0.15質量%以下の割合で含まれ、  C is contained in a proportion of 0.008% by mass or more and 0.15% by mass or less,
Ti、V、Y、Zr、NbおよびHfからなる群から選択される1種の元素を第1元素とし、V、Y、Zr、Nb、HfおよびTaからなる群から選択される1種の元素であって元素周期表における族が前記第1元素より大きい元素または元素周期表における族が前記第1元素と同じでかつ元素周期表における周期が前記第1元素より大きい元素を第2元素としたとき、  One element selected from the group consisting of Ti, V, Y, Zr, Nb and Hf is the first element, and one element selected from the group consisting of V, Y, Zr, Nb, Hf and Ta An element whose group in the periodic table is larger than the first element or an element whose group in the periodic table is the same as the first element and whose period in the periodic table is larger than the first element is a second element. When
前記第1元素が0.03質量%以上0.2質量%以下の割合で含まれ、  The first element is included in a ratio of 0.03% by mass to 0.2% by mass,
前記第2元素が0.03質量%以上0.2質量%以下の割合で含まれていることを特徴とする粉末冶金用金属粉末。  The metal powder for powder metallurgy, characterized in that the second element is contained in a proportion of 0.03% by mass or more and 0.2% by mass or less.
Feが主成分であり、  Fe is the main component,
Crが16質量%以上21質量%以下の割合で含まれ、  Cr is contained in a proportion of 16% by mass or more and 21% by mass or less,
Niが8質量%以上15質量%以下の割合で含まれ、  Ni is contained at a ratio of 8% by mass or more and 15% by mass or less,
Siが0.5質量%以上0.9質量%以下の割合で含まれ、  Si is contained in a proportion of 0.5% by mass or more and 0.9% by mass or less,
Cが0.01質量%以上0.08質量%以下の割合で含まれ、  C is contained in a proportion of 0.01% by mass or more and 0.08% by mass or less,
Ti、V、Y、Zr、NbおよびHfからなる群から選択される1種の元素を第1元素とし、V、Y、Zr、Nb、HfおよびTaからなる群から選択される1種の元素であって元素周期表における族が前記第1元素より大きい元素または元素周期表における族が前記第1元素と同じでかつ元素周期表における周期が前記第1元素より大きい元素を第2元素としたとき、  One element selected from the group consisting of Ti, V, Y, Zr, Nb and Hf is the first element, and one element selected from the group consisting of V, Y, Zr, Nb, Hf and Ta An element whose group in the periodic table is larger than the first element or an element whose group in the periodic table is the same as the first element and whose period in the periodic table is larger than the first element is a second element. When
前記第1元素が0.05質量%以上0.1質量%以下の割合で含まれ、  The first element is included in a proportion of 0.05% by mass or more and 0.1% by mass or less,
前記第2元素が0.05質量%以上0.1質量%以下の割合で含まれていることを特徴とする粉末冶金用金属粉末。  The metal powder for powder metallurgy, wherein the second element is contained in a proportion of 0.05% by mass or more and 0.1% by mass or less.
オーステナイトの結晶構造を有している請求項1ないし3のいずれか1項に記載の粉末冶金用金属粉末。 The metal powder for powder metallurgy according to any one of claims 1 to 3, which has an austenite crystal structure. 前記第2元素の含有率E2を前記第2元素の質量数で除した値X2に対する前記第1元素の含有率E1を前記第1元素の質量数で除した値X1の比率X1/X2は、0.3以上3以下である請求項1ないし4のいずれか1項に記載の粉末冶金用金属粉末。 The ratio X1 / X2 of the value X1 obtained by dividing the content E1 of the first element by the mass number of the first element with respect to the value X2 obtained by dividing the content E2 of the second element by the mass number of the second element is: The metal powder for powder metallurgy according to any one of claims 1 to 4, which is 0.3 or more and 3 or less. 前記第2元素の含有率E2を前記第2元素の質量数で除した値X2に対する前記第1元素の含有率E1を前記第1元素の質量数で除した値X1の比率X1/X2は、0.5以上2以下である請求項1ないし4のいずれか1項に記載の粉末冶金用金属粉末。  The ratio X1 / X2 of the value X1 obtained by dividing the content E1 of the first element by the mass number of the first element with respect to the value X2 obtained by dividing the content E2 of the second element by the mass number of the second element is: The metal powder for powder metallurgy according to any one of claims 1 to 4, which is 0.5 or more and 2 or less. 前記第2元素の含有率E2を前記第2元素の質量数で除した値X2に対する前記第1元素の含有率E1を前記第1元素の質量数で除した値X1の比率X1/X2は、0.75以上1.3以下である請求項1ないし4のいずれか1項に記載の粉末冶金用金属粉末。  The ratio X1 / X2 of the value X1 obtained by dividing the content E1 of the first element by the mass number of the first element with respect to the value X2 obtained by dividing the content E2 of the second element by the mass number of the second element is: The metal powder for powder metallurgy according to any one of claims 1 to 4, which is 0.75 or more and 1.3 or less. 前記第1元素の含有率と前記第2元素の含有率の合計が0.05質量%以上0.6質量%以下である請求項1ないしのいずれか1項に記載の粉末冶金用金属粉末。 The metal powder for powder metallurgy according to any one of claims 1 to 7 , wherein the total content of the first element and the content of the second element is 0.05% by mass or more and 0.6% by mass or less. . 前記第1元素の含有率と前記第2元素の含有率の合計が0.1質量%以上0.48質量%以下である請求項1ないし7のいずれか1項に記載の粉末冶金用金属粉末。  The metal powder for powder metallurgy according to any one of claims 1 to 7, wherein the total content of the first element and the content of the second element is 0.1 mass% or more and 0.48 mass% or less. . 前記第1元素の含有率と前記第2元素の含有率の合計が0.12質量%以上0.24質量%以下である請求項1ないし7のいずれか1項に記載の粉末冶金用金属粉末。  The metal powder for powder metallurgy according to any one of claims 1 to 7, wherein the total content of the first element and the content of the second element is 0.12% by mass or more and 0.24% by mass or less. . さらに、Moが1質量%以上5質量%以下の割合で含まれている請求項1ないし10のいずれか1項に記載の粉末冶金用金属粉末。 The metal powder for powder metallurgy according to any one of claims 1 to 10 , wherein Mo is contained at a ratio of 1% by mass to 5% by mass. さらに、Moが1.2質量%以上4質量%以下の割合で含まれている請求項1ないし10のいずれか1項に記載の粉末冶金用金属粉末。  The metal powder for powder metallurgy according to any one of claims 1 to 10, further comprising Mo in a proportion of 1.2 mass% to 4 mass%. さらに、Moが2質量%以上3質量%以下の割合で含まれている請求項1ないし10のいずれか1項に記載の粉末冶金用金属粉末。  The metal powder for powder metallurgy according to any one of claims 1 to 10, further comprising Mo in a proportion of 2% by mass to 3% by mass. 平均粒径が0.5μm以上30μm以下である請求項1ないし13のいずれか1項に記載の粉末冶金用金属粉末。 The metal powder for powder metallurgy according to any one of claims 1 to 13 , wherein the average particle size is 0.5 µm or more and 30 µm or less. 請求項1ないし14のいずれか1項に記載の粉末冶金用金属粉末と、前記粉末冶金用金属粉末の粒子同士を結着するバインダーと、を含むことを特徴とするコンパウンド。 Compound characterized in that it comprises a powder metallurgy metal powder according to any one of claims 1 to 14, and a binder for binding the particles of the said powder metallurgical metal powder, a. 請求項1ないし14のいずれか1項に記載の粉末冶金用金属粉末を造粒してなることを特徴とする造粒粉末。 A granulated powder obtained by granulating the metal powder for powder metallurgy according to any one of claims 1 to 14 . Feが主成分であり、
Crが15質量%以上26質量%以下の割合で含まれ、
Niが7質量%以上22質量%以下の割合で含まれ、
Siが0.3質量%以上1.2質量%以下の割合で含まれ、
Cが0.005質量%以上0.3質量%以下の割合で含まれ、
Ti、V、Y、Zr、Nbおよびfからなる群から選択される1種の元素を第1元素とし、V、Y、Zr、Nb、HfおよびTaからなる群から選択される1種の元素であって元素周期表における族が前記第1元素より大きい元素または元素周期表における族が前記第1元素と同じでかつ元素周期表における周期が前記第1元素より大きい元素を第2元素としたとき、
前記第1元素が0.01質量%以上0.5質量%以下の割合で含まれ、
前記第2元素が0.01質量%以上0.5質量%以下の割合で含まれている粉末冶金用金属粉末を焼結して製造されたことを特徴とする焼結体。
Fe is the main component,
Cr is contained at a ratio of 15% by mass or more and 26% by mass or less,
Ni is contained in a ratio of 7% by mass or more and 22% by mass or less,
Si is contained in a proportion of 0.3% by mass or more and 1.2% by mass or less,
C is contained in a proportion of 0.005 mass% or more and 0.3 mass% or less,
Ti, V, Y, Zr, and one element selected from Nb and H f or Ranaru group as a first element, V, Y, Zr, Nb , 1 kind selected from the group consisting of Hf and Ta An element of which the group in the periodic table is greater than the first element or the group in the periodic table is the same as the first element and the period in the periodic table is greater than the first element When
The first element is included in a proportion of 0.01% by mass to 0.5% by mass,
A sintered body produced by sintering metal powder for powder metallurgy containing the second element in a proportion of 0.01% by mass or more and 0.5% by mass or less.
Feが主成分であり、  Fe is the main component,
Crが15質量%以上26質量%以下の割合で含まれ、  Cr is contained at a ratio of 15% by mass or more and 26% by mass or less,
Niが7質量%以上22質量%以下の割合で含まれ、  Ni is contained in a ratio of 7% by mass or more and 22% by mass or less,
Siが0.3質量%以上1.2質量%以下の割合で含まれ、  Si is contained in a proportion of 0.3% by mass or more and 1.2% by mass or less,
Cが0.005質量%以上0.3質量%以下の割合で含まれ、  C is contained in a proportion of 0.005 mass% or more and 0.3 mass% or less,
Ti、V、Y、Zr、NbおよびHfからなる群から選択される1種の元素を第1元素とし、V、Y、Zr、Nb、HfおよびTaからなる群から選択される1種の元素であって元素周期表における族が前記第1元素より大きい元素または元素周期表における族が前記第1元素と同じでかつ元素周期表における周期が前記第1元素より大きい元素を第2元素としたとき、  One element selected from the group consisting of Ti, V, Y, Zr, Nb and Hf is the first element, and one element selected from the group consisting of V, Y, Zr, Nb, Hf and Ta An element whose group in the periodic table is larger than the first element or an element whose group in the periodic table is the same as the first element and whose period in the periodic table is larger than the first element is a second element. When
前記第1元素が0.01質量%以上0.5質量%以下の割合で含まれ、  The first element is included in a proportion of 0.01% by mass to 0.5% by mass,
前記第2元素が0.01質量%以上0.5質量%以下の割合で含まれていることを特徴とする焼結体。  A sintered body characterized in that the second element is contained in a proportion of 0.01% by mass or more and 0.5% by mass or less.
化ケイ素の含有率が相対的に高い第1領域と、前記第1領域よりも酸化ケイ素の含有率が相対的に低い第2領域と、を含む請求項17または18に記載の焼結体。 Sintered body according to claim 17 or 18 comprising a content of oxidation silicon is relatively high first region, and a relatively low second region the content of silicon oxide than the first region .
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