JP2016125070A - Lid for overhead hardware material excellent in maintainability - Google Patents

Lid for overhead hardware material excellent in maintainability Download PDF

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JP2016125070A
JP2016125070A JP2014264430A JP2014264430A JP2016125070A JP 2016125070 A JP2016125070 A JP 2016125070A JP 2014264430 A JP2014264430 A JP 2014264430A JP 2014264430 A JP2014264430 A JP 2014264430A JP 2016125070 A JP2016125070 A JP 2016125070A
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lid
hot
surface side
less
plating
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幹之 市場
Mikiyuki Ichiba
幹之 市場
渡邊 憲一
Kenichi Watanabe
憲一 渡邊
鈴木 千秋
Chiaki Suzuki
千秋 鈴木
潤 尾崎
Jun Ozaki
潤 尾崎
文泰 青野
Fumiyasu Aono
文泰 青野
祐二 田川
Yuji Tagawa
祐二 田川
顕比古 片岡
Akihiko Kataoka
顕比古 片岡
英章 佐藤
Hideaki Sato
英章 佐藤
考介 井上
Kosuke Inoue
考介 井上
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Tokyo Electric Power Co Holdings Inc
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Tokyo Electric Power Co Holdings Inc
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Abstract

PROBLEM TO BE SOLVED: To provide a lid for an overhead hardware material whose indication of corrosion can be observed before a hole is made due to corrosion in a lid upper part of the overhead hardware material installed on a utility pole by means of visual inspection from the ground, which does not require costly inspection such as inspection by climbing the pole, and which is excellent in corrosion resistance and maintainability and inexpensive, and to provide an overhead transformer and an overhead switch applying the same.SOLUTION: Provided is a coated or uncoated metal lid applied to an overhead hardware material, which is molded by using a plated steel sheet having both surfaces applied with hot-dip zinc plating or hot dip aluminum plating having a total content of Al and Mg of less than 6 mass% or 6 mass% and more. When an adhesion amount of a hot-dip zinc plating film on the lid outer surface side is tA(g/m), and an adhesion amount thereof on the lid inner surface side is tB(g/m), tA is less than 300-500 g/m, tB is 30-100 g/mand more, and tA/tB is a constant value and more. Also provided are an overhead transformer and an overhead switch applying the lid.SELECTED DRAWING: None

Description

本発明は、電柱に架設される変圧器や開閉器などの架空機材に適用される蓋に関し、詳細には、架空基材の腐蝕損傷を地上からの目視点検で容易に発見可能にし、穴あきに至る前に保全可能な点検を容易にする、耐食性及び保全性に優れた塗装もしくは無塗装の金属蓋に関する。   The present invention relates to a lid applied to an aerial equipment such as a transformer or a switch erected on a utility pole, and more specifically, corrosive damage of an aerial base material can be easily detected by visual inspection from the ground. The present invention relates to a painted or unpainted metal lid with excellent corrosion resistance and maintainability, which facilitates maintenance that can be maintained before reaching the point of view.

現在、密閉性が必要とされる架空変圧器や開閉器などに代表される配電機材は、腐食による穴あきでの故障を避けるため、作業員による地上からの目視点検及び高所作業車からの昇柱点検が行われている。特に蓋の上側の腐食は地上から判別することができず、高所作業車等による定期的な昇柱点検、あるいは特殊な冶具を用いた蓋上部の観察が行われており、大きな保全負荷となっている。   Currently, electrical distribution equipment such as aerial transformers and switches that require hermeticity must be visually inspected by workers from the ground and from aerial work vehicles in order to avoid failure due to holes due to corrosion. Ascending pillars are being inspected. In particular, corrosion on the upper side of the lid cannot be discriminated from the ground, and periodic climbing column inspections using an aerial work vehicle, etc., or observation of the upper part of the lid using special jigs are performed. It has become.

現在使用されている蓋の多くは、鋼板を蓋に成型した後、溶融亜鉛めっきを施した仕様となっている。この場合、蓋の内外面は同一の防錆仕様となるため、雨水が当たる蓋上部が優先して穴あきを生ずる可能性があり、費用が掛かる蓋上部の定期的な昇柱点検が必要となる。また、成型後に溶融めっきを行う仕様であるため、運搬費用や在庫管理費用が発生し、コスト高となる。   Many of the lids currently used have a specification in which a steel plate is molded into a lid and then hot dip galvanized. In this case, since the inner and outer surfaces of the lid have the same rust-proof specifications, there is a possibility that the upper part of the lid that is exposed to rainwater will be preferentially perforated. Become. Moreover, since it is the specification which performs hot dipping after shaping | molding, a conveyance expense and an inventory management expense generate | occur | produce and a cost becomes high.

現在使用されている蓋の一部には、溶融亜鉛系めっきを施した鋼板で蓋を成型することで、成型後に溶融めっきを行う場合に比較して運搬費用や在庫管理費用を抑制し、低コスト化をはかった蓋もある。しかし、この場合も、蓋の内外面は同一の防錆仕様となるため、蓋上部が優先して穴あきを生ずる可能性があり、費用が掛かる蓋上部の定期的な昇柱点検が必要となる。更に無塗装としてコスト低減をはかった蓋もあるが、塗装がないことによる防食性能の低下により、蓋上部の点検間隔を短くしなければならないなど費用面の問題を有している。   Some of the lids currently in use are made of hot-dip galvanized steel sheet to reduce the transportation and inventory management costs compared to the case of hot-dip plating after molding. Some lids are cost effective. However, in this case as well, the inner and outer surfaces of the lid have the same rust-proof specification, so there is a possibility that the upper part of the lid may be perforated, and it is necessary to periodically inspect the climbing column at the upper part of the lid, which is expensive. Become. In addition, there are lids designed to reduce the cost as no coating, but due to the deterioration of the anticorrosion performance due to the absence of coating, there is a cost problem such as the inspection interval of the upper portion of the lid must be shortened.

架空機材の腐食劣化の管理手法として、腐食環境モニタリングによる面的な管理も提案されているが、電柱の高さ位置が同じでも、塩害の影響を受け易いか否かなど、周囲の建築物や地形などにより腐食環境が大きく変動するため、やはり個別の点検は必須である。特許文献1には、同様の問題解決にあたり、高圧開閉器の中空部に有色液体を封入し、高圧開閉器の上部が劣化して孔が形成された場合に、この孔から有色の液体が流れ出し、高圧開閉器の上面から側面に流下することにより、高圧開閉器に故障の可能性があることを報知することができることが提案されているが、この方法では穴あきを未然に防止できない。   As a management method for corrosion degradation of aerial equipment, surface management by corrosive environment monitoring has also been proposed, but even if the height of the power pole is the same, whether it is easily affected by salt damage, etc. Since the corrosive environment fluctuates greatly depending on topography, individual inspection is still essential. In Patent Document 1, in order to solve the same problem, when colored liquid is sealed in the hollow part of the high-pressure switch and the upper part of the high-pressure switch deteriorates to form a hole, the colored liquid flows out from the hole. It has been proposed that it is possible to notify that there is a possibility of failure in the high-voltage switch by flowing down from the upper surface to the side surface of the high-voltage switch, but this method cannot prevent perforation.

特開2014−75891号公報JP 2014-75891 A

配電機材に対する劣化環境の定量評価 第69巻第3号(電気協同研究会編、平成25年発刊)Quantitative evaluation of degradation environment for electrical equipment materials Vol. 69, No. 3 (Electric cooperative research group, published in 2013)

上記のように、蓋の穴あきを許容しない架空機材の保全は、蓋の上部に穴あきの可能性があるため、昇柱点検などコストが掛かる点検を定期的に行う必要があり、現状の蓋では内外面が同一仕様であるため、蓋の全ての部分に穴あきの可能性がある。   As mentioned above, maintenance of aerial equipment that does not allow perforation of the lid is likely to be perforated on the top of the lid. Since the inner and outer surfaces have the same specifications, there is a possibility that all parts of the lid will be perforated.

本発明は上記事情に鑑みてなされたものであり、地上からの目視点検により、電柱などに設置する架空機材の蓋上部の腐食による穴あき前に腐食の兆候を察知することができ、昇柱点検などのコストが掛かる点検が不要で、耐食性及び保全性に優れる安価な架空機材用の蓋を提供することを目的とする。   The present invention has been made in view of the above circumstances, and by visual inspection from the ground, it is possible to detect signs of corrosion before the perforation due to corrosion of the lid upper part of the overhead equipment installed on the utility pole, etc. The purpose of the present invention is to provide a cover for an inexpensive overhead equipment that does not require any costly inspection such as inspection and has excellent corrosion resistance and maintainability.

前記目的を達成するため本発明者らは鋭意検討を行い、詳細に架空基材の蓋の機能を調べた。その結果、蓋の耐穴あき性が要求される部位は、蓋上部の密閉シール部の内側の部分であって、機材の側面にシール部からはみ出た蓋側面や端部は、腐食で穴があいても機材内部の密閉性には影響しないことがわかった。   In order to achieve the above object, the present inventors have intensively studied and investigated the function of the lid of the aerial base material in detail. As a result, the part where the hole resistance of the lid is required is the inner part of the hermetic seal part at the upper part of the lid, and the side or end of the lid that protrudes from the seal part on the side of the equipment has holes due to corrosion. However, it was found that the sealing inside the equipment was not affected.

そこで、地上からの目視による点検が可能で、かつ蓋の密閉性に対して無害な蓋側面や端部の防食性能を、蓋上部の防食性能よりも適度に低減させ蓋上部に先行して腐食させることで上記目的を達成することができ、しかも、蓋側面の適度な防食性の低減は、外面と内面とに差厚めっきを施しためっき鋼板を用いて蓋を成型することにより実現可能であることを見出し、本発明を完成するに至った。   Therefore, it is possible to visually inspect from the ground, and the anticorrosion performance of the lid side and end, which is harmless to the lid sealability, is moderately reduced from the anticorrosion performance of the upper lid, and corrodes ahead of the upper lid. In addition, the above-mentioned purpose can be achieved, and an appropriate reduction in the corrosion resistance of the side of the lid can be realized by molding the lid using a plated steel sheet with a difference thickness plating on the outer surface and the inner surface. As a result, the present invention has been completed.

すなわち、本発明は以下の通りである。   That is, the present invention is as follows.

(1)AlとMgの合計含有量が6質量%未満、かつMg含有量が3質量%以下である、溶融亜鉛めっきを両面に施しためっき鋼板を用いて成型された、架空機材に適用する塗装金属蓋であって、
蓋外面側となる溶融亜鉛めっき皮膜の付着量をtA(g/m)、
蓋内面側となる溶融亜鉛めっき皮膜の付着量をtB(g/m)としたとき、
tAが500g/m未満、tBが50g/m以上、かつtA/tBが1.8以上
であることを特徴とする塗装金属蓋。
(1) Applicable to aerial equipment formed using plated steel sheets with hot-dip galvanized coating on which both the Al and Mg content is less than 6% by mass and the Mg content is 3% by mass or less A painted metal lid,
The amount of adhesion of the hot dip galvanized film on the outer surface side of the lid is tA (g / m 2 ),
When the adhesion amount of the hot dip galvanized film on the inner surface side of the lid is tB (g / m 2 ),
A painted metal lid, wherein tA is less than 500 g / m 2 , tB is 50 g / m 2 or more, and tA / tB is 1.8 or more.

(2)AlとMgの合計含有量が6質量%以上、かつMg含有量が3質量%以下である、溶融亜鉛アルミニウムめっきを両面に施しためっき鋼板を用いて成型された、架空機材に適用する塗装金属蓋であって、
蓋外面側となる溶融亜鉛アルミニウムめっき皮膜の付着量をtA(g/m)、
蓋内面側となる溶融亜鉛アルミニウムめっき皮膜の付着量をtB(g/m)としたとき、
tAが300g/m未満、tBが30g/m以上、かつtA/tBが1.4以上
であることを特徴とする塗装金属蓋。
(2) Applicable to aerial equipment formed using plated steel sheets with hot-dip galvanized aluminum plating on both sides, with a total content of Al and Mg of 6% by mass or more and 3% by mass or less. A painted metal lid,
TA (g / m 2 ), the adhesion amount of the hot-dip galvanized aluminum plating film on the lid outer surface side,
When the adhesion amount of the hot dip aluminum plating film on the inner surface side of the lid is tB (g / m 2 ),
A painted metal lid, wherein tA is less than 300 g / m 2 , tB is 30 g / m 2 or more, and tA / tB is 1.4 or more.

(3)AlとMgの合計含有量が6質量%未満、かつMg含有量が3質量%以下である、溶融亜鉛めっきを両面に施しためっき鋼板を用いて成型された、架空機材に適用する無塗装金属蓋であって、
蓋外面側となる溶融亜鉛めっき皮膜の付着量をtA(g/m)、
蓋内面側となる溶融亜鉛めっき皮膜の付着量をtB(g/m)としたとき、
tAが500g/m未満、tBが100g/m以上、かつtA/tBが1.4以上
であることを特徴とする無塗装金属蓋。
(3) Applicable to aerial equipment formed using plated steel sheets with hot dip galvanizing on both sides, where the total content of Al and Mg is less than 6% by mass and the Mg content is 3% by mass or less. Unpainted metal lid,
The amount of adhesion of the hot dip galvanized film on the outer surface side of the lid is tA (g / m 2 ),
When the adhesion amount of the hot dip galvanized film on the inner surface side of the lid is tB (g / m 2 ),
tA is less than 500 g / m 2, unpainted metal lid, wherein tB is 100 g / m 2 or more, and tA / tB is 1.4 or more.

(4)AlとMgの合計含有量が6質量%以上、かつMg含有量が3質量%以下である、溶融亜鉛アルミニウムめっきを両面に施しためっき鋼板を用いて成型された、架空機材に適用する無塗装金属蓋であって、
蓋外面側となる溶融亜鉛アルミニウムめっき皮膜の付着量をtA(g/m)、
蓋内面側となる溶融亜鉛アルミニウムめっき皮膜の付着量をtB(g/m)としたとき、
tAが300g/m未満、tBが50g/m以上、かつtA/tBが1.2以上
であることを特徴とする無塗装金属蓋。
(4) Applicable to aerial equipment molded using plated steel sheets with hot-dip galvanized aluminum plating on both sides, with a total content of Al and Mg of 6% by mass or more and 3% by mass or less. An unpainted metal lid that
TA (g / m 2 ), the adhesion amount of the hot-dip galvanized aluminum plating film on the lid outer surface side,
When the adhesion amount of the hot dip aluminum plating film on the inner surface side of the lid is tB (g / m 2 ),
An unpainted metal lid, wherein tA is less than 300 g / m 2 , tB is 50 g / m 2 or more, and tA / tB is 1.2 or more.

(5)架空機材に適用する塗装もしくは無塗装金属蓋であって、両面に差圧めっきを施した溶融亜鉛めっきまたは溶融亜鉛アルミニウムめっき鋼板を用いて成型されており、めっき皮膜の付着量の大きい側を蓋外面側とし、付着量の小さい側を蓋内面側として成型されている金属蓋。
(6)蓋外面側となるめっき皮膜の付着量をtA(g/m)、蓋内面側となるめっき皮膜の付着量をtB(g/m)としたとき、塗装金属蓋の場合はtA/tBが1.2〜2.0の範囲、無塗装金属蓋の場合はtA/tBが1.4〜5.0の範囲である、上記(5)に記載の金属蓋。
(7)上記(1)〜(6)いずれか1項に記載の塗装金属蓋もしくは無塗装金属蓋を適用したことを特徴とする架空変圧器または架空開閉器。
(5) Painted or unpainted metal lid applied to aerial equipment, formed using hot dip galvanized or hot dip galvanized steel sheet with differential pressure plating on both sides, with a large amount of plating coating A metal lid formed with the side as the lid outer surface side and the side with a small amount of adhesion as the lid inner surface side.
(6) Futagaimen the coating weight of plating film serving as the side tA (g / m 2), when the tB (g / m 2) the coating weight of plating film serving as the lid inner side, when the coated metal lid The metal lid according to (5) above, wherein tA / tB is in the range of 1.2 to 2.0, and in the case of an unpainted metal lid, tA / tB is in the range of 1.4 to 5.0.
(7) An aerial transformer or an aerial switch characterized by applying the painted metal lid or the unpainted metal lid according to any one of (1) to (6) above.

本発明によれば、鋼板両面のめっき付着量が異なるめっき鋼板を成型することで、耐食性に優れるとともに、地上からの目視点検により架空機材の蓋上部の腐食の兆候を察知することが可能な、保全費用の掛からない安価な金属蓋を提供することができる。   According to the present invention, it is possible to detect signs of corrosion at the top of the lid of the aerial equipment by visual inspection from the ground, by forming a plated steel sheet having different plating adhesion amounts on both sides of the steel sheet. An inexpensive metal lid that does not require maintenance costs can be provided.

以下に本発明を実施するための形態について詳細に説明する。なお、特に断りの無い限り本明細書中では組成の「%」表示は「質量%」を意味する。   Hereinafter, embodiments for carrying out the present invention will be described in detail. Unless otherwise specified, in the present specification, “%” in the composition means “% by mass”.

めっき鋼板を使用して蓋を成型した場合には、めっき鋼板の切断面である側面端面の非めっき部分の防食性能が懸念される。一般的には、特に無塗装で板厚が厚い場合は、めっきされていない面積が大きくなるため発錆しやすくなると考えられる。ところが、板厚を2.3mmと3.2mmとした本発明の無塗装蓋を、腐食環境で評価したところ、蓋の端面は下端に向いており、蓋上部に当った雨水により蓋外面から溶出した亜鉛やアルミの白色生成物で覆われ、防食されるという知見が得られている。   When a lid is formed using a plated steel plate, there is a concern about the anticorrosion performance of the non-plated portion on the side surface that is the cut surface of the plated steel plate. In general, it is considered that rusting is likely to occur because the unplated area increases, especially when there is no coating and the plate thickness is large. However, when the unpainted lid of the present invention having a thickness of 2.3 mm and 3.2 mm was evaluated in a corrosive environment, the end face of the lid faces the lower end and is eluted from the outer surface of the lid by rain water hitting the top of the lid. It has been found that it is covered with a white product of zinc or aluminum and is anticorrosive.

上記の知見より、鋼板に施す最適な内外面のめっき範囲やめっき仕様は、蓋側面が成型時に受けるめっき皮膜の損傷の程度、皮膜厚の増加による外観不良、めっき皮膜の組成、塗装の有無により決定される。   Based on the above knowledge, the optimal plating range and plating specifications for the inner and outer surfaces applied to the steel sheet depend on the degree of damage to the plating film that the lid side receives during molding, the appearance defect due to the increase in film thickness, the composition of the plating film, and the presence or absence of coating. It is determined.

蓋成型用めっき鋼板としては、両面に差厚めっきを施した溶融めっき鋼板が望ましい。蓋成型後に溶融めっきを施す方法では、蓋内面の付着量の制御が難しくなるが、予め溶融めっきされた鋼板を成型すれば、付着量の制御が容易である。また、成型した蓋を溶融めっき工程へ搬送することが不要となり、搬送費用が大幅に削減される。
また、蓋を成型することにより、鋼材が変形してめっき皮膜に割れなどを生じることがあるため、めっき皮膜の基本組成は、鋼材を犠牲防食可能な亜鉛、アルミニウム、マグネシウムを主体することが望ましく、犠牲防食作用を持たないクロムやニッケルは好ましくない。
As the plated steel sheet for forming a lid, a hot-dip plated steel sheet having differential thickness plating on both sides is desirable. In the method in which hot dipping is performed after the lid is formed, it is difficult to control the amount of adhesion on the inner surface of the lid, but the amount of adhesion can be easily controlled by molding a steel plate that has been previously hot dipped. In addition, it is not necessary to transport the molded lid to the hot dipping process, and transportation costs are greatly reduced.
Moreover, since the steel material may be deformed and cracks may occur in the plating film by molding the lid, the basic composition of the plating film is preferably mainly composed of zinc, aluminum, and magnesium that can sacrifice and prevent the steel material. Chromium and nickel that do not have sacrificial anticorrosive action are not preferable.

蓋成型用の溶融めっき鋼板が有するめっき皮膜の平均組成は、AlとMgの合計含有量が6%未満の場合と6%以上の場合の、いずれにおいても、Al含有量は0〜56%、Mg含有量は0〜3%であり、残部がZnおよび不可避的不純物である。他の不純物元素からなる不可避的不純物(Siなど)は、合計1%以下の範囲である。Alはめっき面の高耐食性を付与する元素であり、Znは犠牲防食作用を付与する元素であることから、それらの特性バランスを考慮して、塗装するか無塗装にするかの事情に応じて、Al含有量は上記の範囲で決定される。従って、AlやMgを含有しない溶融亜鉛めっき鋼板も使用可能である。   The average composition of the plating film of the hot-dip plated steel sheet for forming the lid has an Al content of 0 to 56% in both cases where the total content of Al and Mg is less than 6% and in the case of 6% or more. The Mg content is 0 to 3%, and the balance is Zn and inevitable impurities. Inevitable impurities (such as Si) composed of other impurity elements are in the range of 1% or less in total. Since Al is an element that imparts high corrosion resistance to the plated surface, and Zn is an element that imparts sacrificial anticorrosive action, considering the balance of their characteristics, depending on whether to paint or not paint The Al content is determined within the above range. Accordingly, a hot-dip galvanized steel sheet that does not contain Al or Mg can also be used.

また、一般に溶融めっきにおけるMgは防食効果がある。めっき皮膜中にMgを含有させることにより防食効果が期待できるが、一方、溶融亜鉛めっき浴にMgを含有させると、Mg酸化物系ドロスの生成によりめっき性が低下する虞がある。そのため、溶融めっき皮膜中のMg含有量は3%以下であることが好ましい。前記ドロスの生成は、溶融亜鉛めっき浴中にAlを含有させることで抑制されることから、めっき性の低下を防止する観点より、MgとAlを含有させた溶融亜鉛アルミニウムめっき皮膜鋼板も使用可能である。この場合、Mg含有量をAl含有量よりも少なくすることで、めっき性が向上し、防食効果に優れる皮膜が形成される。   In general, Mg in hot dipping has an anticorrosive effect. The anticorrosion effect can be expected by including Mg in the plating film. On the other hand, if Mg is contained in the hot dip galvanizing bath, the plating property may be reduced due to the generation of Mg oxide dross. Therefore, it is preferable that the Mg content in the hot dip coating is 3% or less. Since the generation of dross is suppressed by containing Al in the hot dip galvanizing bath, a hot dip galvanized steel sheet containing Mg and Al can be used from the viewpoint of preventing deterioration of the plating property. It is. In this case, by making the Mg content less than the Al content, the plating property is improved, and a film having an excellent anticorrosion effect is formed.

成型用の溶融めっき鋼板が有するめっき皮膜の平均組成としては、AlやMgを含有しないめっき皮膜では、AlやMgによる防食効果が期待できないため、蓋内外面のめっき金属付着量は、Al−Mg−Znめっき皮膜<Al−Znめっき皮膜<Znめっき皮膜 の順に全体的に大きくすることが好ましい。   As the average composition of the plating film of the hot-dip plated steel sheet for forming, the plating film not containing Al or Mg cannot be expected to have an anticorrosive effect due to Al or Mg. -Zn plating film <Al-Zn plating film <Zn plating film It is preferable to increase the entire size in this order.

また、溶融亜鉛めっきあるいは溶融亜鉛アルミニウムめっきを両面に施しためっき鋼板を用いて成型された金属蓋に対する最適めっき皮膜の付着量は、塗装の有無によって異なる。塗膜を設ける場合は、塗膜に防錆効果があるため、めっき皮膜の付着量が少なくて良い。   In addition, the amount of the optimum plating film to be applied to a metal lid formed using a plated steel sheet that has been subjected to hot dip galvanization or hot dip galvanized aluminum plating varies depending on the presence or absence of coating. When providing a coating film, since the coating film has a rust-preventing effect, the amount of plating film deposited may be small.

本発明では、蓋外面側となる溶融めっき皮膜の付着量をtA(g/m)、蓋内面側となる溶融めっき皮膜の付着量をtB(g/m)としたとき、AlやMgの含有量、塗装の有無によって、それぞれ最適付着量が存在する。このような実施態様を実現する場合、鋼板両面に差圧めっきを施した、溶融亜鉛めっき鋼板または溶融亜鉛アルミニウムめっき鋼板を用いて、めっき皮膜の付着量の大きい側を蓋外面側とし、付着量の小さい側を蓋内面側として蓋を成型すれば容易である。蓋外面側となるめっき皮膜の付着量をtA(g/m)、蓋内面側となるめっき皮膜の付着量をtB(g/m)としたとき、塗装金属蓋の場合はtA/tBが1.2〜2.0の範囲、無塗装金属蓋の場合はtA/tBが1.4〜5.0の範囲で、とりわけ良好な結果となる。 In the present invention, the molten plating film tA (g / m 2) the adhesion amount of the Futagaimen side, when the coating weight of the molten plating film serving as the lid inner surface side was tB (g / m 2), Al and Mg Depending on the content and the presence or absence of coating, there is an optimum amount of adhesion. When realizing such an embodiment, using a hot dip galvanized steel sheet or a hot dip galvanized aluminum plated steel sheet that has been subjected to differential pressure plating on both sides of the steel sheet, the side with the larger coating film adhesion amount is the lid outer surface side, and the adhesion amount It is easy to mold the lid with the smaller side as the inner surface side of the lid. When the adhesion amount of the plating film on the outer surface side of the lid is tA (g / m 2 ) and the adhesion amount of the plating film on the inner surface side of the lid is tB (g / m 2 ), tA / tB in the case of a painted metal lid. Is in the range of 1.2 to 2.0, and in the case of an unpainted metal lid, tA / tB is in the range of 1.4 to 5.0, and particularly good results are obtained.

請求項1に記載した、AlとMgの合計含有量が6%未満である溶融亜鉛めっきを両面に施しためっき鋼板から成型した塗装金属蓋の場合は、tAが500g/m未満、tBが50g/m以上、かつtA/tBが1.8以上であることが好ましい。tAが500g/m以上の溶融亜鉛めっきでは、防食性能が飽和し、外観が悪化する。また、tBが50g/m未満では、腐食環境の厳しい海岸地帯では蓋内面側の発錆が早く、地上点検を行う場合でも塩害地域では点検頻度が多くなり保全費用が増加する。また、tA/tBが1.8未満では、蓋上面が先に腐食する場合が認められる。tAは、より好ましくは100〜500g/m、特に好ましくは150〜300g/mの範囲である。tBは、より好ましくは50〜200g/m、特に好ましくは60〜150g/mの範囲である。tA/tBは、より好ましくは1.8〜5.0の範囲である。 In the case of a coated metal lid formed from a plated steel sheet coated on both sides with a hot-dip galvanized aluminum alloy with a total content of Al and Mg of less than 6%, tA is less than 500 g / m 2 and tB is It is preferable that 50 g / m 2 or more and tA / tB is 1.8 or more. In hot dip galvanizing with tA of 500 g / m 2 or more, the anticorrosion performance is saturated and the appearance deteriorates. Further, when tB is less than 50 g / m 2 , rusting on the inner surface of the lid is quick in coastal areas where the corrosive environment is severe, and even when ground inspection is performed, the frequency of inspection increases in the salt damage area and maintenance costs increase. Moreover, when tA / tB is less than 1.8, the case where the upper surface of the lid is corroded first is recognized. tA is more preferably in the range of 100 to 500 g / m 2 , particularly preferably in the range of 150 to 300 g / m 2 . tB is more preferably in the range of 50 to 200 g / m 2 , particularly preferably 60 to 150 g / m 2 . tA / tB is more preferably in the range of 1.8 to 5.0.

請求項2に記載した、AlとMgの合計含有量が6%以上である溶融亜鉛アルミニウムめっきを両面に施しためっき鋼板から成型した塗装金属蓋の場合は、AlやMgに防食効果があるため、より少ない付着量で所望の性能を達成することができる。即ち、tAが300g/m未満、tBが30g/m以上、かつtA/tBが1.4以上であることが好ましい。tAは、より好ましくは80〜300g/m、特に好ましくは80〜200g/mの範囲である。tBは、より好ましくは45〜150g/m、特に好ましくは50〜100g/mの範囲である。tA/tBは、より好ましくは1.4〜4.0の範囲である。 In the case of a coated metal lid formed from a plated steel sheet coated on both sides with a hot dip galvanized aluminum plating having a total content of Al and Mg of 6% or more according to claim 2, Al and Mg have an anticorrosive effect. The desired performance can be achieved with a smaller amount of adhesion. That is, it is preferable that tA is less than 300 g / m 2 , tB is 30 g / m 2 or more, and tA / tB is 1.4 or more. tA is more preferably in the range of 80 to 300 g / m 2 , particularly preferably in the range of 80 to 200 g / m 2 . tB is more preferably in the range of 45 to 150 g / m 2 , particularly preferably in the range of 50 to 100 g / m 2 . tA / tB is more preferably in the range of 1.4 to 4.0.

請求項3に記載した、AlとMgの合計含有量が6%未満である溶融亜鉛めっきを両面に施しためっき鋼板から成型した無塗装金属蓋の場合は、tAが500g/m未満、tBが100g/m以上、かつtA/tBが1.4以上であることが好ましい。tAが500g/m以上の溶融亜鉛めっきでは、すでに防食性能が飽和しているだけでなく、外観が悪化するため実用化に適さなくなる。また、tBが100g/m未満では、腐食環境の厳しい海岸地帯では蓋内面側の発錆が早く、地上点検を行う場合でも塩害地域では点検頻度が多くなり保全費用が増加する。また、tA/tBが1.4未満では、蓋上面が先に腐食する場合が認められる。tAは、より好ましくは150〜500g/m、特に好ましくは200〜450g/mの範囲である。tBは、より好ましくは100〜400g/m、特に好ましくは100〜320g/mの範囲である。tA/tBは、より好ましくは1.4〜2.5の範囲である。 In the case of an unpainted metal lid formed from a plated steel sheet coated on both sides with a hot-dip galvanized coating with a total content of Al and Mg of less than 6% according to claim 3, tA is less than 500 g / m 2 , tB Is preferably 100 g / m 2 or more and tA / tB is preferably 1.4 or more. In hot dip galvanizing with a tA of 500 g / m 2 or more, the anticorrosion performance is already saturated, and the appearance is deteriorated, so that it is not suitable for practical use. In addition, when tB is less than 100 g / m 2 , rusting on the inner surface of the lid is quick in coastal areas where the corrosive environment is severe, and even when ground inspection is performed, the frequency of inspection increases and maintenance costs increase. Moreover, when tA / tB is less than 1.4, the case where the upper surface of the lid is corroded first is recognized. tA is more preferably in the range of 150 to 500 g / m 2 , particularly preferably in the range of 200 to 450 g / m 2 . tB is more preferably in the range of 100 to 400 g / m 2 , particularly preferably in the range of 100 to 320 g / m 2 . tA / tB is more preferably in the range of 1.4 to 2.5.

請求項4に記載した、AlとMgの合計含有量が6%以上である溶融亜鉛アルミニウムめっきを両面に施しためっき鋼板から成型した無塗装金属蓋の場合は、AlやMgに防食効果があるため、より少ない付着量で所望の性能を達成することができる。即ち、tAが300g/m未満、tBが50g/m以上、かつtA/tBが1.2以上であることが好ましい。tAが300g/m以上の溶融亜鉛めっきでは、すでに防食性能が飽和しているだけでなく、外観が悪化するため実用化に適さなくなる。また、tBが50g/m未満では、腐食環境の厳しい海岸地帯では蓋内面側の発錆が早く、地上点検を行う場合でも塩害地域では点検頻度が多くなり保全費用が増加する。また、tA/tBが1.4未満では、蓋上面が先に腐食する場合が認められる。tAは、より好ましくは80〜300g/m、特に好ましくは80〜200g/mの範囲である。tBは、より好ましくは50〜150g/m、特に好ましくは60〜100g/mの範囲である。tA/tBは、より好ましくは1.2〜2.0の範囲である。 In the case of an unpainted metal lid formed from a plated steel sheet coated on both sides with a hot-dip galvanized aluminum plating having a total content of Al and Mg of 6% or more according to claim 4, Al or Mg has an anticorrosive effect. Therefore, the desired performance can be achieved with a smaller amount of adhesion. That is, it is preferable that tA is less than 300 g / m 2 , tB is 50 g / m 2 or more, and tA / tB is 1.2 or more. In hot dip galvanizing with tA of 300 g / m 2 or more, not only the anticorrosion performance is already saturated, but also the appearance is deteriorated, so that it is not suitable for practical use. Further, when tB is less than 50 g / m 2 , rusting on the inner surface of the lid is quick in coastal areas where the corrosive environment is severe, and even when ground inspection is performed, the frequency of inspection increases in the salt damage area and maintenance costs increase. Moreover, when tA / tB is less than 1.4, the case where the upper surface of the lid is corroded first is recognized. tA is more preferably in the range of 80 to 300 g / m 2 , particularly preferably in the range of 80 to 200 g / m 2 . tB is more preferably in the range of 50 to 150 g / m 2 , particularly preferably in the range of 60 to 100 g / m 2 . tA / tB is more preferably in the range of 1.2 to 2.0.

本発明の無塗装溶融めっき皮膜の表面には、従来公知の方法で化成処理皮膜を設けることもできる。蓋成型時における鋼板の変形で化成処理皮膜が損傷を受けることがあっても本発明による効果が損なわれることはない。   A chemical conversion treatment film can also be provided on the surface of the unpainted hot-dip coating film of the present invention by a conventionally known method. Even if the chemical conversion film is damaged due to the deformation of the steel plate at the time of lid molding, the effect of the present invention is not impaired.

塗膜の厚さとしては、30〜60μm程度の電着あるいは吹付けによるエポキシ樹脂系塗膜を設け、必要に応じて30μm程度のメラミン、ふっ素、ポリウレタン、ウレタン等の耐候性を有する上塗り塗膜を設けた仕様が挙げられる。また、ポリエステル、ウレタンなどの粉体の焼付塗装も適用可能であるが、膜厚が200μmを超えるとめっきによる防食性能の差が明確でなくなり、蓋外面が優先して腐食する虞がある。
塗装金属蓋においては、塗装は成型後に行うことが塗膜の損傷を防止するうえで好ましいが、塗装しためっき鋼板を成型しても本発明による効果が損なわれることはない。
As the thickness of the coating film, an epoxy resin coating film is provided by electrodeposition or spraying of about 30 to 60 μm, and if necessary, a top coating film having a weather resistance of about 30 μm such as melamine, fluorine, polyurethane, urethane, etc. The specifications with Moreover, although baking coating of powders, such as polyester and urethane, is applicable, when a film thickness exceeds 200 micrometers, the difference in the anticorrosion performance by metal plating will become unclear, and there exists a possibility that a lid outer surface may corrode preferentially.
In the coated metal lid, coating is preferably performed after molding in order to prevent damage to the coating film, but the effect of the present invention is not impaired even if the coated plated steel sheet is molded.

本発明の塗装金属蓋および無塗装金属蓋は、電柱に架設される変圧器や開閉器などの架空機材に適用される。密閉シールが装着された変圧器や開閉器のケース本体の開口端部に蓋を被せるだけで、従来の変圧器や開閉器と同様に使用できるため、経済性に優れている。   The painted metal lid and the unpainted metal lid of the present invention are applied to aerial equipment such as a transformer and a switch installed on a utility pole. It is economical because it can be used in the same way as a conventional transformer or switch by simply covering the open end of the case body of a transformer or switch with a hermetic seal.

以下、本発明を実施例および比較例を用いて具体的に説明するが、本発明は以下の実施例にのみ限定されるものではない。   EXAMPLES Hereinafter, although this invention is demonstrated concretely using an Example and a comparative example, this invention is not limited only to a following example.

(実施例1〜14及び比較例1〜13)
[めっき鋼板]
溶融めっき基材は、板厚2.3mmのSS400の普通鋼材を用いた。一部、板厚3.2mmの溶融めっき鋼板を用いた。
上記基材に、溶融亜鉛めっき、溶融亜鉛アルミニウムめっき(いずれも差圧めっき)を施した、めっき組成が異なる6区分のめっき鋼板を用いて評価した。
表1に、めっき鋼板のめっき皮膜平均組成を示す。亜鉛めっきは、合計で1%以下の不可避不純物元素をめっき皮膜に含む。
(Examples 1-14 and Comparative Examples 1-13)
[Plated steel sheet]
As the hot-dip plating base material, a plain steel material of SS400 having a plate thickness of 2.3 mm was used. In part, a hot dip plated steel sheet having a thickness of 3.2 mm was used.
The above-mentioned base material was evaluated using 6-section plated steel sheets having different plating compositions, which were subjected to hot dip galvanization and hot dip galvanized aluminum plating (both were differential pressure plating).
Table 1 shows the average coating film composition of the plated steel sheet. Zinc plating contains a total of 1% or less of inevitable impurity elements in the plating film.

[成型]
所定の溶融めっき鋼板を、缶蓋状に成型し、成型物を評価した場合を「先めっき」と記した。
基材鋼板を、缶蓋状に成型した成形物に、所定の溶融めっきを施したものを評価した場合を「後めっき」と記した。
[Molding]
The case where a predetermined hot-dip steel sheet was molded into a can lid shape and the molded product was evaluated was described as “pre-plating”.
A case where a predetermined hot-dip plating was performed on a molded product obtained by forming a base steel plate into a can lid shape was described as “post-plating”.

[塗装]
成型後の缶蓋内外面に、下塗り層として、膜厚30μmのエポキシ系樹脂電着塗膜を形成し、上塗り層として、膜厚25μmのウレタン系樹脂塗膜を形成した(表1中の「塗装仕様A」)。比較のため、成型後の蓋内外面に、膜厚220μmのウレタン系の粉体塗装をした(表1中の「塗装仕様B」)。
[Painting]
An epoxy resin electrodeposition coating film with a film thickness of 30 μm was formed as an undercoat layer on the inner and outer surfaces of the can lid after molding, and a urethane resin coating film with a film thickness of 25 μm was formed as an overcoat layer (see “ Paint specification A ”). For comparison, a urethane-based powder coating with a film thickness of 220 μm was applied to the inner and outer surfaces of the lid after molding (“Coating Specification B” in Table 1).

試験に供した溶融めっき鋼板の種類、めっき方法、めっき皮膜の平均組成、塗装の有無を表1に示す。
実施例1〜3:溶融亜鉛めっきを両面に施しためっき鋼板を成型した金属蓋を塗装した塗装金属蓋
実施例4〜5:溶融亜鉛アルミニウムめっきを両面に施しためっき鋼板を成型した金属蓋を塗装した塗装金属蓋
実施例6〜9:溶融亜鉛めっきを両面に施しためっき鋼板を成型した金属蓋(無塗装)
実施例10〜14:溶融亜鉛アルミニウムめっきを両面に施しためっき鋼板を成型した金属蓋(無塗装)
Table 1 shows the types of hot-dip plated steel sheets subjected to the test, the plating method, the average composition of the plating film, and the presence or absence of coating.
Examples 1-3: Painted metal lids coated with a metal lid formed with a plated steel plate subjected to hot dip galvanizing Examples 4-5: Metal lids formed of a plated steel plate subjected to hot dip zinc aluminum plating Painted painted metal lids Examples 6 to 9: Metal lids formed from plated steel sheets with hot dip galvanized on both sides (no paint)
Examples 10 to 14: Metal lid (unpainted) formed from a plated steel sheet on both sides of hot-dip galvanized aluminum plating

缶蓋の特性は、以下の方法にて評価した。   The characteristics of the can lid were evaluated by the following methods.

(1)評価A(比較腐食試験):この試験では、缶蓋外面と缶蓋側面内面側の発錆時間を比較評価し、蓋外面の発錆が、蓋側面の発錆より遅いことを確認した。
蓋外面となる表面のめっき皮膜の付着量がtA(g/m)、蓋内面となる裏面のめっき皮膜の付着量がtB(g/m)の溶融めっき鋼板を用いて蓋を成型し、蓋側面内面側の評価用としては蓋端部から、蓋外面の評価用としては蓋中央部から、それぞれ試験片(150×70mm)を切り出した。切り出した試験片の一部については、蓋側面内面側めっき皮膜を研磨してめっき膜厚を低減させ、内面めっき厚を低減した板材から成型した蓋を模擬試験片として使用した。一部試験蓋ではめっき皮膜研磨後に塗装を施した。
(1) Evaluation A (comparative corrosion test): In this test, the rusting times on the outer surface of the can lid and the inner surface of the side surface of the can lid are compared and confirmed that the rusting on the outer surface of the lid is slower than the rusting on the side surface of the lid. did.
The lid is molded using a hot-dip plated steel sheet with a plating coating amount on the outer surface of the lid tA (g / m 2 ) and a plating coating amount on the back surface of the lid tB (g / m 2 ). A test piece (150 × 70 mm) was cut out from the end of the lid for evaluation of the inner side of the lid side surface and from the center of the lid for evaluation of the outer surface of the lid. About a part of the cut-out test piece, the lid molded from the plate material whose inner side plating thickness was reduced by polishing the inner side plating film on the side surface of the lid and used as a simulated test piece was used. Some test lids were painted after polishing the plating film.

切り出した試験片の切断面はエポキシ樹脂でシールした。
その後、試験片についてJIS K 5621:「一般用さび止めペイント」に定める複合サイクル試験を行い、蓋外面の発錆時間(Time−外面)を基準として、蓋側面内面側の発錆時間(Time−内面)を測定した。
(Time−外面/Time−内面)が1以下であれば「×」、(Time−外面/Time−内面)が1を超えていれば良好として「○」と評価した。
The cut surface of the cut specimen was sealed with an epoxy resin.
Thereafter, a composite cycle test defined in JIS K 5621: “General anticorrosion paint” was performed on the test piece, and the rusting time (Time− on the inner side of the lid side surface) was determined based on the rusting time on the outer surface of the lid (Time−outer surface). Inner surface) was measured.
If (Time-outer surface / Time-inner surface) was 1 or less, it was evaluated as "X", and if (Time-outer surface / Time-inner surface) exceeded 1, it was evaluated as "Good".

(2)評価法B(絶対腐食試験):この試験では、蓋側面の防食性能が低すぎると発錆穴あきから腐食が拡大し、架空機材のシール部分の気密喪失が蓋外面の腐食よりも著しく早くなることから、蓋側面の防食性能の下限を確認評価した。
蓋外面となる表面のめっき皮膜の付着量がtA(g/m)、蓋内面となる裏面のめっき皮膜の付着量がtB(g/m)の溶融めっき鋼板で蓋を成型し、中心角60°ピッチで区分分けし、蓋側面内面側の各区分の初期めっき膜厚を測定した。その後、蓋側面内面側のめっき皮膜を一部の区分については段階的に研磨し、めっき膜厚を極所的に低減させ、内面めっき厚を低減した板材から成型した蓋を模擬試験片として使用した。一部の試験蓋ではめっき皮膜研磨後に塗装を施した。
(2) Evaluation Method B (Absolute Corrosion Test): In this test, if the anti-corrosion performance on the side of the lid is too low, corrosion spreads from the rusting holes and the loss of airtightness in the seal part of the overhead equipment is more than the corrosion on the outside of the lid. Since it becomes remarkably quick, the lower limit of the anticorrosion performance of the lid side surface was confirmed and evaluated.
The lid is molded with a hot-dip plated steel sheet having a plating coating amount on the outer surface of the lid of tA (g / m 2 ) and a plating coating amount of the back surface of the lid on the inner surface of tB (g / m 2 ). The initial plating film thickness of each section on the inner side of the lid side surface was measured. After that, the plating film on the inner side of the lid side is polished stepwise for some sections, the plating film thickness is reduced locally, and a lid molded from a plate with reduced inner plating thickness is used as a simulated test piece did. Some test lids were painted after polishing the plating film.

試験蓋を実機材に取付け、塩害地域に機材を設置し、2年後に蓋側面内面側や端部の腐食状態を観察した。地鉄に達する赤錆が観察されるものを不可として「×」、赤錆がないものを良好として「○」と評価した。   The test lid was attached to the actual equipment, and the equipment was installed in the salt damage area. After two years, the corrosion state of the inner side surface and the edge of the lid side surface was observed. A case where red rust reaching the ground iron was observed was evaluated as “x”, and a case where no red rust was observed was evaluated as “good”.

(3)評価法C(外観試験):この試験では、めっき付着量が増加すると、めっき表面で凹凸を生じるようになり、蓋成型時の変形や仕上がりに影響を与えることから、成型前鋼板の外面側の凹凸に対応した評価として光沢度を測定した。
溶融亜鉛めっきではtAが250g/m、溶融亜鉛アルミニウムめっきではtBが90g/mを基準として、基準となる光沢度をGB、計測した光沢度をGMとして、GM/GBが0.7以上を光沢度の変化が許容範囲であるとして「○」、0.7未満を凹凸の変化が大きく許容範囲外であるとして「×」と評価した。
(3) Evaluation method C (appearance test): In this test, when the amount of plating adhesion increases, unevenness occurs on the plating surface, which affects deformation and finish during lid molding. The glossiness was measured as an evaluation corresponding to the irregularities on the outer surface side.
With hot dip galvanizing, tA is 250 g / m 2 , and with hot galvanized aluminum plating, tB is 90 g / m 2, and the standard glossiness is GB, the measured glossiness is GM, and GM / GB is 0.7 or more. Was evaluated as “◯”, assuming that the change in glossiness was within the allowable range, and “X” as less than 0.7, assuming that the change in unevenness was large and outside the allowable range.

評価結果を表1にまとめて示す。   The evaluation results are summarized in Table 1.

Figure 2016125070
Figure 2016125070

本発明例1〜3と比較例1〜2の対比から、本発明の塗装溶融亜鉛めっき蓋においては、蓋内面側となる成型前めっき鋼板のめっき皮膜付着量が50g/m以上ないと防食性能が不十分になること、成型前めっき鋼板のめっき皮膜付着量の比(tA/tB)が1.8以上ないと缶蓋外面と缶蓋側面内面側の発錆時間を比較評価不能になることがわかる。これらの結果より、蓋外面側となる成型前めっき鋼板のめっき皮膜付着量の最小値が90g/m程度であることがわかる。 From the comparison of Examples 1-3 of the present invention and Comparative Examples 1-2, in the coated hot-dip galvanized lid of the present invention, the coating coating amount of the pre-molded plated steel sheet on the inner surface side of the lid must be 50 g / m 2 or more to prevent corrosion. If the performance is insufficient and the ratio of the coating amount of the pre-molded plated steel sheet (tA / tB) is 1.8 or more, the rusting times on the outer surface of the can lid and the inner surface of the side surface of the can lid cannot be comparatively evaluated. I understand that. From these results, it is understood that the minimum value of the coating amount of the pre-molded plated steel sheet on the lid outer surface side is about 90 g / m 2 .

本発明例4〜5と比較例3〜4との対比から、本発明の塗装溶融亜鉛アルミニウムめっき蓋においては、蓋内面側となる成型前めっき鋼板のめっき皮膜付着量が30g/m以上ないと防食性能が不十分になること、成型前めっき鋼板のめっき皮膜付着量の比(tA/tB)が1.4以上ないと缶蓋外面と缶蓋側面内面側の発錆時間を比較評価不能になることがわかる。これらの結果より、蓋外面側となる成型前めっき鋼板のめっき皮膜付着量の最小値が50g/m程度であることがわかる。 From the comparison of Invention Examples 4-5 and Comparative Examples 3-4, in the coated hot-dip galvanized aluminum plating lid of the present invention, the coating film adhesion amount of the pre-molded plated steel sheet that is the inner surface of the lid is not 30 g / m 2 or more. Insufficient anti-corrosion performance, and the ratio of the coating thickness of the pre-molded plated steel sheet (tA / tB) is 1.4 or higher, the rusting times on the outer surface of the can lid and the inner surface of the side surface of the can lid cannot be comparatively evaluated. It turns out that it becomes. From these results, it is understood that the minimum value of the coating amount of the pre-molded plated steel sheet on the outer surface side of the lid is about 50 g / m 2 .

本発明例6〜9と比較例5〜8との対比から、本発明の無塗装溶融亜鉛めっき蓋においては、蓋内面側となる成型前めっき鋼板のめっき皮膜付着量が100g/m以上ないと防食性能が不十分になること、成型前めっき鋼板のめっき皮膜付着量の比(tA/tB)が1.4以上ないと缶蓋外面と缶蓋側面内面側の発錆時間を比較評価不能になることがわかる。これらの結果より、蓋外面側となる成型前めっき鋼板のめっき皮膜付着量の最小値が140g/m程度であることがわかる。 From the comparison between Invention Examples 6-9 and Comparative Examples 5-8, in the unpainted hot-dip galvanized lid of the present invention, the coating amount of the pre-molded plated steel sheet on the inner surface side of the lid is not 100 g / m 2 or more. Insufficient anti-corrosion performance, and the ratio of the coating thickness of the pre-molded plated steel sheet (tA / tB) is 1.4 or higher, the rusting times on the outer surface of the can lid and the inner surface of the side surface of the can lid cannot be comparatively evaluated. It turns out that it becomes. From these results, it can be seen that the minimum value of the coating amount of the pre-molded plated steel sheet on the outer surface side of the lid is about 140 g / m 2 .

本発明例10〜14と比較例9〜11との対比から、本発明の無塗装溶融亜鉛アルミニウムめっき蓋においては、蓋内面側となる成型前めっき鋼板のめっき皮膜付着量が50g/m以上ないと防食性能が不十分になること、成型前めっき鋼板のめっき皮膜付着量の比(tA/tB)が1.2以上ないと缶蓋外面と缶蓋側面内面側の発錆時間を比較評価不能になることがわかる。これらの結果より、蓋外面側となる成型前めっき鋼板のめっき皮膜付着量の最小値が60g/m程度であることがわかる。 From the comparison between Invention Examples 10 to 14 and Comparative Examples 9 to 11, in the unpainted hot dip galvanized aluminum plating lid of the present invention, the coating amount of the pre-molded plated steel sheet on the inner surface side of the lid is 50 g / m 2 or more. Otherwise, the anticorrosion performance will be inadequate, and the ratio of the coating amount of the pre-molded plated steel sheet (tA / tB) will not be 1.2 or more. It turns out that it becomes impossible. From these results, it is understood that the minimum value of the coating amount of the pre-molded plated steel sheet on the outer surface side of the lid is about 60 g / m 2 .

本発明例8と11から、少なくとも板厚3.2mmまでは無塗装蓋であっても、本発明仕様でめっきの存在しない蓋端面も防食されることがわかる。   From Examples 8 and 11 of the present invention, it can be seen that, even if the cover is uncoated at least up to a plate thickness of 3.2 mm, the end face of the cover where there is no plating is protected against corrosion.

比較例12から、塗装が200μmを超える厚さになると、本発明のめっき仕様であっても、内外面の防食性能の違いが発現せず、蓋外面が優先して腐食する可能性がある。比較例13から、後めっきで溶融亜鉛めっきを行った蓋は、蓋の内外面のめっきの防食性能の差異が小さく、蓋外面が優先して腐食する可能性があるため好ましくない。また、溶融めっきを行うための蓋の搬送費用などからコスト高となる。   From Comparative Example 12, when the coating thickness exceeds 200 μm, there is a possibility that the outer surface of the lid is preferentially corroded without the difference in the anticorrosion performance between the inner and outer surfaces even with the plating specifications of the present invention. From Comparative Example 13, a lid that has been hot dip galvanized by post-plating is not preferred because the difference in the anticorrosion performance of the inner and outer surfaces of the lid is small and the lid outer surface may corrode preferentially. In addition, the cost increases due to the cost of transporting the lid for hot dipping.

本発明の架空機材に適用する塗装もしくは無塗装の金属蓋は、蓋外面側と蓋側面内面側との比較評価により、地上からの目視点検により架空機材の蓋上部の腐食の兆候を察知することが可能になることで、保全費用を大幅に削減することができる。よって、本発明による産業上の寄与は大である。   For painted or unpainted metal lids applied to the aerial equipment of the present invention, a sign of corrosion on the top of the aerial equipment lid should be detected by visual inspection from the ground by comparative evaluation between the lid outer surface side and the lid side inner surface side. As a result, maintenance costs can be significantly reduced. Therefore, the industrial contribution by the present invention is significant.

Claims (7)

AlとMgの合計含有量が6質量%未満、かつMg含有量が3質量%以下である、溶融亜鉛めっきを両面に施しためっき鋼板を用いて成型された、架空機材に適用する塗装金属蓋であって、
蓋外面側となる溶融亜鉛めっき皮膜の付着量をtA(g/m)、
蓋内面側となる溶融亜鉛めっき皮膜の付着量をtB(g/m)としたとき、
tAが500g/m未満、tBが50g/m以上、かつtA/tBが1.8以上
であることを特徴とする塗装金属蓋。
Painted metal lid applied to aerial equipment, formed using plated steel sheets with hot dip galvanizing on both sides, the total content of Al and Mg being less than 6% by mass and the Mg content being 3% by mass or less Because
The amount of adhesion of the hot dip galvanized film on the outer surface side of the lid is tA (g / m 2 ),
When the adhesion amount of the hot dip galvanized film on the inner surface side of the lid is tB (g / m 2 ),
A painted metal lid, wherein tA is less than 500 g / m 2 , tB is 50 g / m 2 or more, and tA / tB is 1.8 or more.
AlとMgの合計含有量が6質量%以上、かつMg含有量が3質量%以下である、溶融亜鉛アルミニウムめっきを両面に施しためっき鋼板を用いて成型された、架空機材に適用する塗装金属蓋であって、
蓋外面側となる溶融亜鉛アルミニウムめっき皮膜の付着量をtA(g/m)、
蓋内面側となる溶融亜鉛アルミニウムめっき皮膜の付着量をtB(g/m)としたとき、
tAが300g/m未満、tBが30g/m以上、かつtA/tBが1.4以上
であることを特徴とする塗装金属蓋。
Painted metal applied to aerial equipment, formed using plated steel sheet with hot-dip galvanized aluminum plating, the total content of Al and Mg being 6% by mass or more and Mg content being 3% by mass or less A lid,
TA (g / m 2 ), the adhesion amount of the hot-dip galvanized aluminum plating film on the lid outer surface side,
When the adhesion amount of the hot dip aluminum plating film on the inner surface side of the lid is tB (g / m 2 ),
A painted metal lid, wherein tA is less than 300 g / m 2 , tB is 30 g / m 2 or more, and tA / tB is 1.4 or more.
AlとMgの合計含有量が6質量%未満、かつMg含有量が3質量%以下である、溶融亜鉛めっきを両面に施しためっき鋼板を用いて成型された、架空機材に適用する無塗装金属蓋であって、
蓋外面側となる溶融亜鉛めっき皮膜の付着量をtA(g/m)、
蓋内面側となる溶融亜鉛めっき皮膜の付着量をtB(g/m)としたとき、
tAが500g/m未満、tBが100g/m以上、かつtA/tBが1.4以上
であることを特徴とする無塗装金属蓋。
Unpainted metal applied to aerial equipment, formed using galvanized steel sheets with hot-dip galvanizing on both sides, with a total content of Al and Mg of less than 6% by mass and a Mg content of 3% by mass or less A lid,
The amount of adhesion of the hot dip galvanized film on the outer surface side of the lid is tA (g / m 2 ),
When the adhesion amount of the hot dip galvanized film on the inner surface side of the lid is tB (g / m 2 ),
tA is less than 500 g / m 2, unpainted metal lid, wherein tB is 100 g / m 2 or more, and tA / tB is 1.4 or more.
AlとMgの合計含有量が6質量%以上、かつMg含有量が3質量%以下である、溶融亜鉛アルミニウムめっきを両面に施しためっき鋼板を用いて成型された、架空機材に適用する無塗装金属蓋であって、
蓋外面側となる溶融亜鉛アルミニウムめっき皮膜の付着量をtA(g/m)、
蓋内面側となる溶融亜鉛アルミニウムめっき皮膜の付着量をtB(g/m)としたとき、
tAが300g/m未満、tBが50g/m以上、かつtA/tBが1.2以上
であることを特徴とする無塗装金属蓋。
Non-painting applied to aerial equipment formed using plated steel sheets with hot-dip galvanized aluminum plating on both sides, with a total content of Al and Mg of 6 mass% or more and Mg content of 3 mass% or less A metal lid,
TA (g / m 2 ), the adhesion amount of the hot-dip galvanized aluminum plating film on the lid outer surface side,
When the adhesion amount of the hot dip aluminum plating film on the inner surface side of the lid is tB (g / m 2 ),
An unpainted metal lid, wherein tA is less than 300 g / m 2 , tB is 50 g / m 2 or more, and tA / tB is 1.2 or more.
架空機材に適用する塗装もしくは無塗装金属蓋であって、両面に差圧めっきを施した溶融亜鉛めっきまたは溶融亜鉛アルミニウムめっき鋼板を用いて成型されており、めっき皮膜の付着量の大きい側を蓋外面側とし、付着量の小さい側を蓋内面側として成型されている金属蓋。   Painted or unpainted metal lid that is applied to aerial equipment, and is formed using hot-dip galvanized or hot-dip galvanized steel sheet with differential pressure plating on both sides. A metal lid formed on the outer surface side, and the side with a small amount of adhesion is formed on the inner surface side of the lid. 蓋外面側となるめっき皮膜の付着量をtA(g/m)、蓋内面側となるめっき皮膜の付着量をtB(g/m)としたとき、塗装金属蓋の場合はtA/tBが1.2〜2.0の範囲、無塗装金属蓋の場合はtA/tBが1.4〜5.0の範囲である、請求項5に記載の金属蓋。 When the adhesion amount of the plating film on the outer surface side of the lid is tA (g / m 2 ) and the adhesion amount of the plating film on the inner surface side of the lid is tB (g / m 2 ), tA / tB in the case of a painted metal lid. Is a range of 1.2 to 2.0, and in the case of an unpainted metal lid, tA / tB is a range of 1.4 to 5.0. 請求項1〜6いずれか1項に記載の塗装金属蓋もしくは無塗装金属蓋を適用したことを特徴とする架空変圧器または架空開閉器。   An aerial transformer or aerial switch, wherein the painted metal lid or the unpainted metal lid according to any one of claims 1 to 6 is applied.
JP2014264430A 2014-12-26 2014-12-26 Lid for overhead hardware material excellent in maintainability Pending JP2016125070A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7498801B2 (en) 2020-06-08 2024-06-12 首鋼集団有限公司 Hot-dip zinc aluminum magnesium coated steel sheet and its manufacturing method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7498801B2 (en) 2020-06-08 2024-06-12 首鋼集団有限公司 Hot-dip zinc aluminum magnesium coated steel sheet and its manufacturing method

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