JP2016101639A - Window member - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a window member high in transparency and scratch resistance.SOLUTION: The window member includes a hard coat layer made of the hard object of a hard coat layer forming composition containing polyfunctional (meth) acrylate, a translucent first base material, and a second translucent base material, and is characterized in that in a damage acceleration test for colliding a chip/lubricant oil mixture with a laminate from a hard coat layer side, when a difference in haze between before the damage acceleration test and after the damage acceleration test is a haze increase amount, the haze increase amount is 5 is more.SELECTED DRAWING: Figure 2

Description

  The present invention relates to a window member.

  When machining machine parts, machine tools such as a lathe, a drilling machine, a boring machine, a milling machine, a gear cutting machine, and a grinding machine are used according to the machining. In recent years, there is known a machining center that can automatically perform machining by NC machining and can automatically exchange a tool and a workpiece (base material) (for example, see Patent Document 1).

  The machining center described in Patent Document 1 is entirely covered with an exterior (cover) on the outside. As a result, a machining area where machining is performed and an operation area where an operator who operates the machining center can enter are partitioned, and safety for the operator is ensured. An openable / closable door is provided on the exterior of the machining center. The open / close door is fitted with glass as a window part that allows the inside of the machining center to be visually recognized from the outside, that is, the machine area is visible from the operation area.

  However, in the machine area of the machining center, for example, a fine flaw that cuts the workpiece may be attached. And such a chip collision is repeated over a long period of time, so that many fine scratches are generated on the glass, and as a result, the transparency of the glass is impaired. For this reason, it has been difficult to check the inside of the machine area through the window for a long period of time and to keep taking light inside. For this reason, development of a window portion having excellent scratch resistance while maintaining excellent transparency has been demanded.

  The above-described problems are not limited to the windows provided in the machining center. For example, the same problem occurs in windows provided on the outer wall portion of a building, the outer wall portion of a machine tool, the body of an automobile, and the like.

JP 2012-203782 A

  An object of the present invention is to provide a window member having excellent transparency and scratch resistance.

Such an object is achieved by the present inventions [1] to [7] below.
[1] A hard coat layer composed of a cured product of a composition for forming a hard coat layer containing a polyfunctional (meth) acrylate, a first substrate having translucency, and a second translucent material A window member comprising:
The hard coat layer composed of a cured product of the hard coat layer forming composition is the outermost layer,
The window member characterized by satisfying the following requirement A.
Requirement A: In the flaw acceleration test in which a chip / lubricant mixture is collided with the laminate from the hard coat layer side, the haze before the flaw acceleration test and the haze after the flaw acceleration test When the difference is the haze increase amount, the haze increase amount is 5 or less.

[2] The window according to [1], wherein either the first base material having translucency or the second base material having translucency is made of a polycarbonate resin and / or an acrylic resin. Element.

[3] The window member according to [1] or [2], wherein an average thickness of the hard coat layer formed of a cured product of the hard coat layer forming composition is 5 μm or more and 100 μm or less.

[4] A window member given in any 1 paragraph of [1] thru / or [3] whose average thickness of the 1st substrate which has the above-mentioned translucency is 50 micrometers or more and 500 micrometers or less.

[5] The window member according to any one of [1] to [4], wherein an average thickness of the translucent second base material is 1 mm or more and 50 mm or less.

[6] Ratio of average thickness of hard coat layer composed of cured product of composition for forming hard coat layer to average thickness of first base material having translucency ([for forming hard coat layer [1] thru | or [average thickness of the hard-coat layer comprised with the hardened | cured material of the composition] / [average thickness of the 1st base material which has translucency]] is 0.01 or more and 2.0 or less The window member according to any one of [5].

[7] The window member according to any one of [1] to [6], wherein the composition for forming a hard coat layer further contains a filler.

  According to the present invention, by improving oil resistance, cracks and the like are hardly generated on the surface even when oil adheres, and excellent scratch resistance can be imparted. Moreover, the said characteristic can be exhibited, preventing that a mass increases. Furthermore, high durability against flying objects can be imparted.

It is a perspective view which shows an example of the machine tool with which the window unit provided with the window for machine tools comprised with the window member of this invention was mounted | worn. It is the sectional view on the AA line in FIG.

  Hereinafter, the window member of the present invention will be described in detail based on a preferred embodiment shown in the accompanying drawings.

The window member of the present invention includes a hard coat layer composed of a cured product of a hard coat layer forming composition containing a polyfunctional (meth) acrylate, a first base material having translucency, and a translucency A hard base layer composed of a cured product of the hard coat layer-forming composition, which is an outermost layer, and satisfies the following requirement A: And
Requirement A: In the flaw acceleration test in which a chip / lubricant mixture is collided with the laminate from the hard coat layer side, the haze before the flaw acceleration test and the haze after the flaw acceleration test When the difference is the haze increase amount, the haze increase amount is 5 or less.

  According to such a configuration, the window member is excellent in transparency and scratch resistance.

  Such a window member of the present invention includes, for example, a vehicle body of an aircraft, automobile, motorcycle, railway vehicle, etc., an outer wall of an elevator, an exterior of a robot, an exterior of a construction machine, an exterior of an industrial machine such as a machine tool, an agricultural machine It can be used for windows such as exteriors of buildings and outer walls of buildings.

  Hereinafter, the window member of the present invention will be described. In the following, a machine tool window provided on the outer wall of a machine tool and having a function of visually recognizing the inside of the machine tool will be described.

  First, prior to explaining a machine tool window constituted by the window member of the present invention, a machine tool including the machine tool window will be described.

<First Embodiment>
FIG. 1 is a perspective view showing an example of a machine tool equipped with a window unit including a machine tool window constituted by the window member of the present invention, and FIG. 2 is a cross-sectional view taken along line AA in FIG. In the following, for convenience of explanation, the upper side in FIGS. 1 and 2 is referred to as “upper” or “upper”, and the lower side is referred to as “lower” or “lower”. Further, the right side in FIG. 2 is referred to as “inside” and the left side is referred to as “outside”. In FIG. 2, the thickness direction of each of the first machine tool window and the second machine tool window is emphasized.

"Machine Tools"
The machine tool shown in FIG. 1 can automatically perform machining by numerical control (NC), that is, NC machining, and automatically performs a tool and (base material) according to the machining. The machining center 10 is replaceable. The machining center 10 includes a structure 101 that actually performs machining on a workpiece, an exterior 102 that covers the entire structure 101, and an operation panel 103 that operates and controls the operation of the structure 101. Yes.

  As shown in FIG. 2, in the present embodiment, the structure 101 is a lathe that performs turning, that is, turning (outer rounding). The structure 101 that is a lathe includes a rotating mechanism (not shown) that holds the cylindrical body 20 that is a workpiece and rotates around the cylindrical body 20, and a tool 104. In addition, since it is the machining center 10, the structure 101 is not limited to having a function as a lathe, but also has a function as, for example, a drilling machine, a boring machine, a milling machine, a gear cutter, and a grinding machine. Yes.

  The exterior 102 is made of a metal plate, and is fixed to a frame (not shown) constituting the skeleton of the machining center 10 via bolts, for example. As a result, the machining area S1 where machining is performed on the structure 101 and the operation area S2 where an operator operating the machining center 10 can enter can be reliably partitioned. Therefore, safety for the operator can be ensured.

  The operation panel 103 includes a control unit 105 in which programs for performing various types of machining are stored in advance, a liquid crystal panel 106 for performing operations such as calling up the programs, and operation buttons 107.

  Incidentally, as shown in FIG. 2, during turning, the cutting tool 104 is broken due to, for example, metal fatigue due to metal fatigue, and a large number of chips 201 from the cylindrical body 20 generated during processing. In addition, the lubricating oil 30 for performing the processing smoothly in the form of droplets or mist (oil mist) may fly (fly) in the processing region S1 as the flying object 40. In this case, the flying object 40 collides with the exterior 102 from the inside depending on the degree of the scattering, and further scattering is reliably prevented. Thereby, the flying object 40 is prevented from scattering and entering the operation area S2. Therefore, the operator is prevented from being injured or dirty with the flying object 40.

  The flying object 40 may include a fixing member (a jig) such as a bolt for fixing the cutting tool 104 in addition to the fragments 104 ′, the chips 201, and the lubricating oil 30.

Examples of the material of the base material to be processed include (1) iron, cast iron, steel (carbon steel, stainless steel, etc.), and iron alloys, (2) inconel, titanium, and titanium alloys, and (3) aluminum, Non-ferrous metals such as magnesium, zinc and copper, and alloys thereof can be mentioned.
Examples of the aluminum alloy include A1050, A3600, A5052, A5056, A6061, and A6063.

  The material of the chip 201 is the same as the base material to be processed.

  Examples of the lubricating oil 30 include cutting oil, grinding oil, casting oil, forging oil, rolling oil, pressing oil, and drawing oil.

  As shown in FIGS. 1 and 2, the machining center 10 has a window unit (machine tool window) 1 that is mounted on an exterior 102 and constitutes a part of the exterior 102 in this state. The window unit 1 is used for visually recognizing the inside of the machining center 10, that is, the processing region S1, or taking light from, for example, a fluorescent lamp in the operation region S2 into the processing region S1 to improve visibility. . Thus, the window unit 1 has a function as a viewing window and a function as a daylighting window.

  As shown in FIG. 2, the window unit 1 includes a first machine tool window 2a, a second machine tool window 2b, a first packing 3a, a second packing 3b, and a frame (window). Frame) 4. Hereinafter, the configuration of each unit will be described.

  The first machine tool window 2a and the second machine tool window 2b are opposed to each other via the air layer 5 (intermediate layer 5), and the first machine tool window 2a is on the inside, the second The machine tool window 2b is arranged outside. In this arrangement state, the machine tool windows 2a and 2b are collectively supported by the frame body 4.

  The first machine tool window 2a and the second machine tool window 2b are both transparent substrates having transparency. The “transparent” includes colorless and transparent and colored and transparent. In the machining center 10, colorless and transparent are preferable.

  The first machine tool window 2a and the second machine tool window 2b have the same configuration in this embodiment. The first and second machine tool windows 2a and 2b are constituted by the window member of the present invention.

  The first machine tool window 2a has a rectangular shape in plan view, and is a laminate including a hard coat layer 21a, a first base material 22a, and a second base material 23a. The order is the hard coat layer 21a, the first base material 22a, and the second base material 23a from the processing region S1 side, and the second base material 23a is on the air layer 5 (intermediate layer 5) side. positioned. Thereby, the 1st window 2a for machine tools will be in the state arrange | positioned so that the hard-coat layer 21a and the 1st base material 22a may face the process area S1 rather than the 2nd base material 23a. With such an arrangement, the second base material 23a can be protected from the flying object 40 with the hard coat layer 21a and the first base material 22a. The first base material 22a has a function of supporting the hard coat layer 21a.

Similarly, the second machine tool window 2b has a rectangular shape in plan view, and is a laminate including a hard coat layer 21b, a first base material 22b, and a second base material 23b. The order is the hard coat layer 21b, the first base material 22b, and the second base material 23b from the operation region S2 side, and the second base material 23b is on the air layer 5 (intermediate layer 5) side. positioned. Thereby, the second machine tool window 2b is in a state in which the hard coat layer 21b and the first base material 22b are arranged so as to face the operation region S2 rather than the second base material 23b. With such an arrangement, for example, when an operator in the operation area S2 grips a tool such as a hexagon wrench or a driver for adjusting the structure 101, the tool is erroneously moved to the second machine tool window 2b. Even if it hits, the 2nd base material 23b can be protected with the hard-coat layer 21b and the 1st base material 22b.

  In addition, since the second machine tool window 2b is arranged outside the first machine tool window 2a, for example, the fragments 104 ′, which are flying objects 40, should be used for the first machine tool. Even if the first machine tool window 2a is damaged by colliding with the window 2a, the second machine tool window 2b can prevent the fragments from entering the operation area S2. Thus, the machining center 10 has a fail-safe structure. The fail-safe structure is a structure that always controls to the safe side when a failure due to an erroneous operation or malfunction occurs in the device / system.

  The first machine tool window 2a and the second machine tool window 2b are such that the base materials 21 face each other in the air layer 5 (intermediate layer 5), that is, the first machine tool window 2a. The second machine tool window 2b is in an inverted state. Thereby, when an assembly operation for attaching the window unit 1 to the exterior 102 of the machining center 10 is attempted, the assembly operation can be performed regardless of the front and back of the window unit 1. Thus, the window unit 1 has a structure that reduces the annoyance of having to consider the posture and direction during assembly.

  Further, as described above, the first machine tool window 2a and the second machine tool window 2b are of the same configuration, thereby making it possible to share components as a transparent substrate. The manufacturing cost of the window unit 1 can be reduced.

The average thickness t ₁ of the hard coat layers 21a and 21b is preferably 5 μm or more and 100 μm or less, and more preferably 3 μm or more and 80 μm or less. By hard coat layer 21a, the average thickness t ₁ of 21b within the range, for machine tool window, can exhibit excellent scratch resistance.

The average thickness _{t 2} of the first base material 22a, 22b is preferably 50μm or more 500μm or less, more preferably 80μm or more 400μm or less. The first substrate 22a, by the above range an average thickness t ₂ of 22b, for machine tool window, can exhibit excellent scratch resistance.

Incidentally, the second base material 23a, 23b mean thickness _{t 3} of is preferably 1mm or more 50mm or less, and more preferably 3mm or more 40mm or less. With the second substrate 23a, the range the average thickness t ₃ of 22b, for machine tool window, so will have a sufficient rigidity, and excellent impact resistance, flying It can prevent suitably that the thing 40 collides and a machine tool window is damaged.

The total thickness t _total of the first machine tool window 2a and the second machine tool window 2b is equal to the hard coat layer 2
1a, the sum of the average thickness _{t 1} and the first substrate 22a, and the average thickness _{t 2} of 22b second substrate 23a, 23b mean thickness _{t 3} of the 21b.

  The constituent materials of the hard coat layers 21a and 21b, the first base materials 22a and 22b, and the second base materials 23a and 23b constituting the first and second machine tool windows 2a and 2b will be described later. Detailed description.

As described above, the air layer 5 (intermediate layer 5) is interposed between the first machine tool window 2a and the second machine tool window 2b. When the fragment 104 ′ collides with the first machine tool window 2a, the first machine tool window 2a can be bent toward the air layer 5 (intermediate layer 5), that is, in the collision direction. And an impact is absorbed by this bending. Thus, the air layer 5 (intermediate layer 5) functions as a shock absorbing layer.

Further, the average thickness t ₄ of the air layer 5 (an intermediate layer 5) is equal to or thinner is more preferable than the total thickness t _total of the first machine tool window 2a. Accordingly, it suppressed that the average thickness t ₄ becomes excessive, thus contributing to the thinning of the window unit 1. Further, the average thickness t ₄ is even greater than the total thickness t _total, not be expected impact absorption improvement in an air layer 5 (an intermediate layer 5).

  The frame body 4 is a member that collectively supports the first machine tool window 2a and the second machine tool window 2b. As a result, the window unit 1 is in the assembled state shown in FIG. 2 in which the first machine tool window 2a, the second machine tool window 2b, and the frame 4 are assembled in advance, and thus remains in this assembled state. It can be easily attached to the exterior 102.

  In addition, it does not specifically limit as a constituent material of the frame 4, For example, various metal materials, such as aluminum and aluminum alloy, and various resin materials can be used.

  The frame body 4 has a rectangular frame shape along the edge of the first machine tool window 2a (second machine tool window 2b), that is, in plan view, and has through holes 41 at the four corners, respectively. Is formed. In the machining center 10, a portion of the exterior 102 where the window unit 1 is installed is open, and four stud bolts 102 a are supported and fixed around the opening. Then, the stud bolt 102a can be inserted into each through hole 41 of the frame body 4, and the nut 102b can be screwed into the stud bolt 102a. As a result, the window unit 1 is attached to the exterior 102.

  In addition, a first recess (first groove) 421 and a second recess (second groove) 422 are formed along the circumferential direction of the inner periphery of the frame body 4. The edge of the first machine tool window 2a is fitted into the first recess 421, and the edge of the second machine tool window 2b is fitted into the second recess 422. Thus, the first machine tool window 2a and the second machine tool window 2b are reliably supported by the frame body 4.

  The convex portion between the first concave portion 421 and the second concave portion 422 serves as a spacer 43 inserted between the first machine tool window 2a and the second machine tool window 2b. When the frame 4 is made of the above-described constituent material, the spacer 43 is also a substantially hard portion. The hard spacer 43 can regulate the separation distance between the first machine tool window 2a and the second machine tool window 2b to be constant, and thus the air layer 5 (intermediate layer 5) is formed. Secured surely.

  The first packing 3a is inserted into the first recess 421 together with the first machine tool window 2a. The second packing 3b is also inserted into the second recess 422 together with the second machine tool window 2b. Each of the first packing 3a and the second packing 3b is formed of a long band having elasticity.

  The first packing 3a is disposed on the machining area S1 side with respect to the first machine tool window 2a, and is compressed between the first machine tool window 2a and the frame 4. . Thereby, the air layer 5 (intermediate layer 5) can be hermetically sealed from the processing region S1 side. On the other hand, the second packing 3b is disposed on the operation region S2 side with respect to the second machine tool window 2b, and is compressed between the second machine tool window 2b and the frame 4. ing. Thereby, the air layer 5 (intermediate layer 5) can be hermetically sealed from the operation region S2 side.

Since the air layer 5 (intermediate layer 5) is hermetically sealed in this way, for example, dust, dust, moisture, etc. (hereinafter, “dust” is treated as a representative) is contained in the air layer 5 (intermediate layer). 5) It is possible to prevent intrusion. If dust once enters the air layer 5 (intermediate layer 5), the dust cloudes the first machine tool window 2a and the second machine tool window 2b, and removes the fog. Can be difficult. However, since the intrusion of dust is prevented as described above, the occurrence of such a problem can be prevented.

  Moreover, the pressure in the air layer 5 (intermediate layer 5) can be set to be equal to or higher than the atmospheric pressure by hermetic sealing. Thereby, compared with the case where the inside of the air layer 5 (intermediate layer 5) is a pressure-reduced state, the improvement of the shock absorption in the air layer 5 (intermediate layer 5) can be aimed at.

  It does not specifically limit as a pressure in the air layer 5 (intermediate layer 5), For example, it is preferable that it is 1-10 atmospheres, and it is more preferable that it is 5-10 atmospheres.

  The air layer 5 (intermediate layer 5) may be filled with an inert gas such as nitrogen. In this case, depending on the constituent materials of the second base material 23a and 23b of the first machine tool window 2a and the second machine tool window 2b, for example, the second base material 23a and 22b. The deterioration over time from the air layer 5 (intermediate layer 5) side can be prevented or suppressed.

  The constituent material of the first packing 3a and the second packing 3b is not particularly limited. For example, various rubber materials such as styrene-butadiene rubber, urethane rubber, silicone rubber, and fluoro rubber (especially those vulcanized) ) Various thermoplastic elastomers are mentioned.

  The first and second machine tool windows 2a and 2b included in the window unit 1 of the machining center 10 configured as described above are configured by the window member of the present invention.

  Hereinafter, the first and second machine tool windows 2a and 2b constituted by the window member of the present invention will be described in detail.

<< First Machine Tool Window 2a and Second Machine Tool Window 2b >>
The machine tool windows 2a and 2b are constituted by the window member of the present invention as described above.
A hard coat layer composed of a cured product of a composition for forming a hard coat layer containing a polyfunctional (meth) acrylate, a first substrate having translucency, and a second substrate having translucency And a hard coat layer composed of a cured product of the hard coat layer forming composition is the outermost layer, and the chip / lubricating oil mixture collides with the laminate from the hard coat layer side. In the flaw acceleration test to be performed, when the difference in size between the haze before the flaw acceleration test and the haze after the flaw acceleration test is defined as a haze increase amount, the haze increase amount is 5 or less.

  Hereinafter, the hard coat layers 21a and 21b, the first base materials 22a and 22b, and the second base materials 23a and 23b included in the machine tool windows 2a and 2b formed of the window member of the present invention will be described in order.

<First base material 22 and second base material 23>
The first base materials 22a and 22b and the second base materials 23a and 23b have translucency and contribute to improvement of impact resistance against the collision of the flying object 40. The first base materials 22a and 22b have a function of supporting the hard coat layers 21a and 21b.

The constituent materials of the first base materials 22a and 22b and the second base materials 23a and 23b are not particularly limited as long as they are translucent base materials. For example, various resin materials, various inorganic materials such as glass, and the like. Etc. can be used. Among these, it is preferable that it is a resin material as a constituent material of the 1st base materials 22a and 22b and the 2nd base materials 23a and 23b. Thereby, the impact resistance with respect to the collision of the flying object 40 of the 1st, 2nd machine tool window 2a, 2b can be improved more.

  Various resin materials may be used as long as they have translucency. Examples thereof include acrylic resins such as polymethyl methacrylate; polyesters such as polyethylene terephthalate (PET) and polyethylene naphthalate (PEN). Resin, polyarylate resin, polycarbonate resin, acrylonitrile-butadiene-styrene copolymer (ABS), polyethersulfone (PES), polyetheretherketone (PEEK), polyamide (PA), polyethersulfone (PES) ), Vinyl chloride resin, polypropylene (PP), and the like, and one or more of these can be used in combination. Of these, polycarbonate resins and acrylic resins are particularly preferable. By using the polycarbonate resin and the acrylic resin, the first base materials 22a and 22b and the second base materials 23a and 23b having excellent transparency and impact resistance against the collision of the flying object 40 are obtained. Can do. Therefore, if such first base materials 22a and 22b and second base materials 23a and 23b are used, the function as a viewing window and the function as a daylighting window can be remarkably exhibited, and flight can be performed. The first and second machine tool windows 2a and 2b that are particularly excellent in impact resistance against the collision of the object 40 can be obtained.

  The polycarbonate resin fat is not particularly limited, and for example, an aromatic polycarbonate resin in which bisphenol and phosgene or diphenyl carbonate are carbonate-bonded can be used. This aromatic polycarbonate resin is generally synthesized by interfacial polycondensation or transesterification.

  Examples of bisphenol include bisphenol A and bisphenol (modified bisphenol) represented by the following formula (1).

(In the formula, X is selected from an alkyl group having 1 to 18 carbon atoms, an aromatic group, and a cyclic aliphatic group, Ra and Rb are alkyl groups having 1 to 12 carbon atoms, m, n is 0-4 respectively, and p is an integer of 1 or more.)

Specific examples of the bisphenol represented by the formula (1) include 4,4 ′-(pentane-2,2-diyl) diphenol, 4,4 ′-(pentane-3,3-diyl) diphenol, 4,4 ′-(butane-2,2-diyl) diphenol, 1,1 ′-(cyclohexanediyl) diphenol, 2-cyclohexyl-1,4-bis (4-hydroxyphenyl) benzene, 2,3- Biscyclohexyl-1,4-bis (4-hydroxyphenyl) benzene, 1,1′-bis (4-hydroxy-3-methylphenyl) cyclohexane, 2,2′-bis (4-hydroxy-3-methylphenyl) Examples include propane.

In the present specification, polymer alloys and modified polycarbonate resins including the polycarbonate resins exemplified above are also treated as polycarbonate resins. Examples of such a resin include a polymer alloy made of a polycarbonate resin and an acrylonitrile-butadiene-styrene copolymer (ABS resin), a polymer alloy made of a polycarbonate resin and a polystyrene resin, and an acrylic-modified polycarbonate resin.

  Among the polycarbonate-based resins as described above, bisphenol-type polycarbonate resins having a bisphenol skeleton and acrylic-modified polycarbonate resins are preferable, and bisphenol C-type polycarbonate resins and acrylic-modified polycarbonate resins are more preferable. Thereby, it is possible to obtain the first base materials 22a and 22b and the second base materials 23a and 23b which are further excellent in transparency and further excellent in impact resistance against the collision of the flying object 40.

  In addition, the acrylic resin is not particularly limited, and for example, at least one selected from the group consisting of acrylic acid, acrylic acid ester, methacrylic acid, and methacrylic acid ester is used as the unsaturated bond-containing monomer, and the unsaturated bond The containing monomer can be prepared by a method such as a radical polymerization reaction, a cationic polymerization reaction, or an anionic polymerization reaction. Examples of the acrylic resin copolymer include a random copolymer, a graft copolymer, a block copolymer, and a graft copolymer, and a random copolymer is preferable.

  The unsaturated bond-containing monomer may include at least one selected from the group consisting of acrylic acid, acrylic acid ester, methacrylic acid, and methacrylic acid ester. Examples of the acrylate ester include methyl acrylate, ethyl acrylate, propyl acrylate, and butyl acrylate. Examples of the methacrylic acid ester include methyl methacrylate, ethyl methacrylate, propyl methacrylate, and butyl methacrylate.

  The unsaturated bond-containing monomer other than acrylic acid, acrylic acid ester, methacrylic acid, and methacrylic acid ester is not particularly limited as long as it has a reactive unsaturated bond. For example, ethylene, propylene, Examples include butene, vinyl acetate, acrylonitrile, and maleimide anhydride. Of these, polypropylene and maleic anhydride are preferred. Thereby, it is possible to obtain the first base materials 22a and 22b and the second base materials 23a and 23b which are further excellent in transparency and further excellent in impact resistance against the collision of the flying object 40.

  In addition to the above-described materials (such as various resin materials and various inorganic materials), the constituent materials of the first base materials 22a and 22b and the second base materials 23a and 23b may include, for example, It may contain a plasticizer, an antioxidant, a filler and the like.

  Further, for the purpose of improving the adhesion to the hard coat layers 21a and 21b, the first base materials 22a and 22b have a surface unevenness treatment by a sandblasting method or a solvent treatment method, a corona discharge treatment, or chromic acid. Surface oxidation treatment such as treatment, flame treatment, hot air treatment, ozone / ultraviolet irradiation treatment, and electron beam irradiation treatment may be performed.

<Hard coat layers 21a, 21b>
The hard coat layers 21a and 21b contribute to an improvement in impact resistance of the machine tool windows 2a and 2b against the collision of the flying object 40.

Such hard coat layers 21a and 21b are composed of a cured product of a hard coat layer forming composition containing polyfunctional (meth) acrylate. The hard coat layers 21a and 21b preferably contain a siloxane-modified (meth) acrylate and a filler in addition to the polyfunctional (meth) acrylate.

  Hereinafter, each material which comprises the composition for hard-coat layer formation is demonstrated in detail.

[Multifunctional (meth) acrylate]
The polyfunctional (meth) acrylate increases the strength of the hard coat layers 21a and 21b and contributes to the improvement of durability against the collision of the flying object 40 of the hard coat layers 21a and 21b.

  In particular, the polyfunctional (meth) acrylate preferably includes (A) a polyfunctional (meth) acrylate having 3 or more (meth) acryloyl groups. Thereby, the surface hardness of the hard coat layers 21a and 21b can be further increased, and thus the machine tool windows 2a and 2b that are particularly excellent in impact resistance against the flying object 40 can be obtained.

  Hereinafter, the polyfunctional (meth) acrylate having three or more (meth) acryloyl groups will be described in order.

  (A) polyfunctional (meth) acrylate having 3 or more (meth) acryloyl groups (hereinafter sometimes simply referred to as “(A) polyfunctional (meth) acrylate”) is a polymerization reaction in one molecule. It means (meth) acrylate containing 3 or more (meth) acryloyl groups contributing to the above.

  In the present specification, the acryloyl group and the methacryloyl group are collectively referred to as a (meth) acryloyl group.

  (A) Since polyfunctional (meth) acrylate has three or more (meth) acryloyl groups, the hardness after curing becomes relatively high. Therefore, by including (A) the polyfunctional (meth) acrylate, it is possible to more reliably obtain the machine tool windows 2a and 2b that are particularly excellent in impact resistance to the flying object 40. Moreover, when obtaining the hardened | cured material of the composition for hard-coat layer formation, (A) polyfunctional (meth) acrylate crosslinks (A) polyfunctional (meth) acrylate, and forms a three-dimensional crosslinked structure. As described above, (A) the polyfunctional (meth) acrylate forms a three-dimensional cross-linked structure, so that the hard coat layer is excellent in oil resistance against flying oil 40 such as lubricant droplets or mist (oil mist). 21a and 21b can be obtained. Therefore, by using such hard coat layers 21a and 21b, it is possible to obtain machine tool windows 2a and 2b that are particularly excellent in oil resistance to flying objects 40 such as lubricating oil.

  The (A) polyfunctional (meth) acrylate may be any (meth) acrylate containing 3 or more (meth) acryloyl groups contributing to the polymerization reaction in one molecule. The molecular weight and molecular structure are not particularly limited. That is, the polyfunctional (meth) acrylate is a polyfunctional (meth) acrylate monomer that is a (meth) acrylate monomer in which three or more (meth) acryloyl groups contributing to the polymerization reaction are contained in one molecule, The polyfunctional (meth) acrylate oligomer which is a (meth) acrylate oligomer in which three or more (meth) acryloyl groups contributing to the polymerization reaction are contained in the molecule is included.

  Examples of the polyfunctional (meth) acrylate monomer include dipentaerythritol hexaacrylate, pentaerythritol tetraacrylate, ditrimethylolpropane triacrylate, trimethylolpropane triacrylate, pentaerythritol triacrylate, dipentaerythritol triacrylate, and ethoxylated trimethylol. Examples include propane triacrylate, ethoxylated pentaerythritol triacrylate, and ethoxylated pentaerythritol tetraacrylate.

  Moreover, as a polyfunctional (meth) acrylate oligomer, polyfunctional urethane (meth) acrylate, polyfunctional epoxy (meth) acrylate, polyfunctional polyester (meth) acrylate etc. are mentioned, for example.

  The polyfunctional urethane (meth) acrylate oligomer is a reaction product of an isocyanate compound obtained by reacting a polyol with diisocyanate and a (meth) acrylate monomer having a hydroxyl group.

  Examples of the polyol include polyester polyol, polyether polyol, and polycarbonate diol.

  The polyether polyol is preferably a polyethylene oxide, polypropylene oxide, ethylene oxide-propylene oxide random copolymer having a number average molecular weight of less than 600. If it is 600 or more, the cured product may be too soft and hard coat performance may not be obtained. The polyester polyol can be obtained, for example, by subjecting a diol and a dicarboxylic acid or dicarboxylic acid chloride to a polycondensation reaction, or esterifying a diol or a dicarboxylic acid to cause an ester exchange reaction. Dicarboxylic acids include adipic acid, succinic acid, glutaric acid, pimelic acid, sebacic acid, azelaic acid, maleic acid, terephthalic acid, isophthalic acid, phthalic acid, etc., and diols include ethylene glycol, 1,4-butanediol, 1 , 6-hexanediol, diethylene glycol, dipropylene glycol, triethylene glycol, tetraethylene glycol, tripropylene glycol, tetrapropylene glycol and the like are used.

  Examples of the polycarbonate diol include 1,4-butanediol, 1,6-hexanediol, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, dipropylene glycol, 2-ethyl-1,3-hexanediol, 1,5-pentanediol, 3-methyl-1,5-pentanediol, 1,4-cyclohexanediol, polyoxyethylene glycol, etc. are used, and one or two You may use the above together.

  In addition, as the diisocyanate, linear or cyclic aliphatic diisocyanate is used. Of course, aromatic diisocyanates can also be used, and it is possible to easily obtain excellent hard coat properties such as hardness and scratch resistance. On the other hand, polyfunctional oligomers are the main components that form the hard coat skeleton. This is because when the component is used, the light resistance is lowered, and yellowing easily occurs upon exposure to light, so that the function as a transparent hard coat is impaired in practical use. Typical examples of the linear or cyclic aliphatic diisocyanate include hexamethylene diisocyanate, isophorone diisocyanate, dicyclohexylmethane diisocyanate, hydrogenated tolylene diisocyanate, and hydrogenated xylylene diisocyanate.

  Examples of acrylate monomers having a hydroxyl group include trimethylolpropane triacrylate, pentaerythritol triacrylate, dipentaerythritol triacrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 2-hydroxybutyl acrylate, 3-hydroxybutyl acrylate, Examples include polyethylene glycol monoacrylate.

  The polyfunctional epoxy (meth) acrylate oligomer can be obtained, for example, by an esterification reaction between a low molecular weight bisphenol type epoxy resin or a novolac epoxy resin oxirane ring and (meth) acrylic acid.

  The polyfunctional polyester (meth) acrylate oligomer is obtained by, for example, esterifying the hydroxyl groups of a polyester oligomer having hydroxyl groups at both ends with (meth) acrylic acid, obtained by condensation of a polyvalent carboxylic acid and a polyhydric alcohol. Can be obtained. Moreover, a polyfunctional polyester (meth) acrylate oligomer can be obtained by esterifying the terminal hydroxyl group of an oligomer obtained by adding an alkylene oxide to a polyvalent carboxylic acid with (meth) acrylic acid.

  Among the above-mentioned polyfunctional (meth) acrylate oligomers, it is preferable to use polyfunctional urethane (meth) acrylate oligomers. The cured product of the polyfunctional urethane (meth) acrylate oligomer has a relatively high hardness and has a skeleton formed by the reaction between the isocyanate compound and the (meth) acrylate monomer having a hydroxyl group. It has flexibility. For this reason, by using a polyfunctional urethane (meth) acrylate oligomer, it is possible to obtain the hard coat layers 21a and 21b having higher hardness and higher toughness, and therefore, impact resistance against the flying object 40. Thus, the machine tool windows 2a and 2b can be obtained.

  The polyfunctional (meth) acrylate monomer preferably has 4 or more (meth) acryloyl groups in one molecule, more preferably 4 or more and 13 or less, and more preferably 5 or more and 8 or less. Is more preferable. The polyfunctional (meth) acrylate monomer having the number of (meth) acryloyl groups within the above numerical range is particularly excellent in curability (curing speed), and the cured product has a relatively high hardness. Therefore, the machine tool windows 2 a and 2 b can exhibit particularly excellent impact resistance against the collision of the flying object 40.

  Further, in the polyfunctional urethane (meth) acrylate oligomer, the number of (meth) acryloyl groups in one molecule is preferably 6 or more, more preferably 8 or more and 15 or less, and 9 or more and 13 or less. Is more preferable. The polyfunctional (meth) acrylate oligomer in which the number of (meth) acryloyl groups is within the above numerical range is particularly high in surface hardness after curing and has appropriate flexibility. Therefore, by using a polyfunctional (meth) acrylate oligomer having the number of (meth) acryloyl groups within the above numerical range, it is possible to obtain hard coat layers 21a and 21b having superior hardness and superior toughness. it can.

  The polyfunctional (meth) acrylate preferably further contains a bifunctional acrylate.

  A bifunctional (meth) acrylate having two (meth) acryloyl groups (hereinafter sometimes simply referred to as “bifunctional (meth) acrylate”) means (meth) acryloyl contributing to a polymerization reaction in one molecule. It means (meth) acrylate containing two groups.

  Since bifunctional (meth) acrylate has a low viscosity as compared with polyfunctional (meth) acrylate, it contributes as a diluent for the composition for forming a hard coat layer. For this reason, by containing bifunctional (meth) acrylate, the composition for hard-coat layer formation can be made low-viscosity, and the handleability of the composition for hard-coat layer formation can be improved.

The bifunctional (meth) acrylate may be any (meth) acrylate in which two (meth) acryloyl groups contributing to the polymerization reaction are contained in one molecule, and indicates all monomers and oligomers. The molecular structure is not particularly limited. That is, the bifunctional (meth) acrylate is a bifunctional (meth) acrylate monomer that is a (meth) acrylate monomer in which two (meth) acryloyl groups contributing to the polymerization reaction are contained in one molecule, or one molecule. It contains a bifunctional (meth) acrylate oligomer that is a (meth) acrylate oligomer that contains two (meth) acryloyl groups that contribute to the polymerization reaction.

  Examples of the bifunctional (meth) acrylate monomer include a bifunctional (meth) acrylate monomer having a chain structure whose main skeleton is a chain, and a bifunctional (meth) acrylate monomer having a cyclic structure whose main skeleton is cyclic. Can be mentioned.

  Examples of the bifunctional (meth) acrylate monomer having a chain structure include 1,4-butanediol diacrylate, 1,6-hexanediol diacrylate, 1,9-nonanediol diacrylate, polyethylene glycol diacrylate, and the like. It is done.

  Examples of the bifunctional (meth) acrylate monomer having a cyclic structure include alicyclic acrylates such as ethoxylated cyclohexanedimethanol diacrylate and tricyclodecane dimethanol diacrylate; ethoxylated bisphenol A diacrylate and ethoxylated hydrogenated bisphenol And aromatic ring acrylates such as bisphenol type acrylates such as A diacrylate.

  Moreover, as a bifunctional (meth) acrylate oligomer, bifunctional urethane (meth) acrylate, bifunctional epoxy (meth) acrylate, bifunctional polyester (meth) acrylate etc. are mentioned, for example.

  Among the bifunctional (meth) acrylates as described above, the bifunctional (meth) acrylate is more preferably a bisphenol type (meth) acrylate, and more preferably a bisphenol A type (meth) acrylate. By using bisphenol-type (meth) acrylate, when bisphenol-type polycarbonate resin is used as the material constituting the first base material 22a, 22b, the material constituting the first base material 22a, 22b and the hard coat layer formation Together with the composition for use, it will have a bisphenol skeleton. For this reason, bisphenol type polycarbonate resin is used for the material constituting the first base materials 22a and 22b, and bisphenol type (meth) acrylate is used for the material constituting the hard coat layers 21a and 21b (hard coat layer forming composition). By using it, the affinity between the material constituting the first base materials 22a and 22b and the hard coat layer forming composition can be made particularly excellent. Thereby, the adhesiveness of 1st base material 22a, 22b and hard-coat layer 21a, 21b can be improved. Therefore, it is possible to further improve durability such as impact resistance and scratch resistance of the machine tool windows 2a and 2b with respect to the flying object 40.

  Moreover, when a siloxane modification (meth) acrylate and a filler are included and (A) polyfunctional (meth) acrylate is included as polyfunctional (meth) acrylate, the polyfunctional (meth) acrylate and the siloxane modified (meth) acrylate The content of (A) polyfunctional (meth) acrylate with respect to 100 parts by weight of the filler is not particularly limited, but is preferably 20 parts by weight or more and 80 parts by weight or less, and 30 parts by weight or more and 70 parts by weight. The following is more preferable. (A) When the content of the polyfunctional (meth) acrylate is less than the lower limit and less than the lower limit, depending on the combination of materials constituting the hard coat layer forming composition, the hard coat layer 21a , 21b may be slightly lower in hardness. Further, when the content of (A) polyfunctional (meth) acrylate exceeds the upper limit, the toughness of the hard coat layers 21a and 21b is slightly increased depending on the combination of materials constituting the hard coat layer forming composition. May be reduced.

Moreover, when a siloxane modification (meth) acrylate and a filler are included and a bifunctional (meth) acrylate is included as a polyfunctional (meth) acrylate, the polyfunctional (meth) acrylate, the siloxane modified (meth) acrylate, Although the content rate of bifunctional (meth) acrylate with respect to a total of 100 weight part of a filler is not specifically limited, 8 weight part or more and 40
The amount is preferably not more than parts by weight, and more preferably not less than 10 parts by weight and not more than 35 parts by weight. When the content of the bifunctional (meth) acrylate is less than the lower limit, depending on the combination of materials constituting the hard coat layer forming composition, the type of material constituting the first base materials 22a and 22b, and the like. There is a possibility that the adhesion between the first base materials 22a and 22b and the hard coat layers 21a and 21b is slightly lowered. Moreover, when the content rate of bifunctional (meth) acrylate exceeds the said upper limit, the content rate of the material which comprises the composition for hard-coat layer formation other than bifunctional (meth) acrylate reduces, and hard-coat layer 21a , 21b may be low in hardness.

  It is preferable that the composition for forming a hard coat layer containing such a polyfunctional (meth) acrylate further contains a siloxane-modified (meth) acrylate and a filler. Thereby, the machine tool windows 2a and 2b can exhibit particularly excellent impact resistance against the collision of the flying object 40.

  Hereinafter, the siloxane-modified (meth) acrylate and the filler will be described in detail.

[Siloxane-modified (meth) acrylate]
Siloxane-modified (meth) acrylate is a combination of a (meth) acrylic compound and a compound having a siloxane bond (—Si—O—Si—).

  By including the siloxane-modified (meth) acrylate having such a configuration, the surface hardness of the hard coat layers 21a and 21b can be further increased. Therefore, by providing the hard coat layers 21a and 21b containing the siloxane-modified (meth) acrylate, it is possible to obtain the machine tool windows 2a and 2b that are particularly excellent in scratch resistance against the chips 201. Further, the siloxane-modified (meth) acrylate exhibits excellent oil repellency by having a siloxane bond (—Si—O—Si—). For this reason, the hardened | cured material obtained from the composition for hard-coat layer formation containing a siloxane modified (meth) acrylate, ie, hard-coat layer 21a, 21b, is flying objects, such as a droplet of lubricating oil, or a mist (oil mist). The oil resistance to 40 is excellent. Therefore, by using such hard coat layers 21a and 21b, it is possible to obtain machine tool windows 2a and 2b that are particularly excellent in oil resistance to the flying object 40. The deterioration of the visibility of 2b can be particularly effectively suppressed.

  Specifically, the compound having a siloxane bond (—Si—O—Si—) has at least one structural unit of structural units having a siloxane bond represented by the following formulas (2) and (3). The thing which has. As a result, the hard coat layers 21a and 21b that are particularly excellent in oil resistance to the flying object 40 such as lubricant droplets or mist (oil mist) are obtained.

(In formula (2), X ₁ each independently represents a hydrocarbon group or a hydroxyl group.)

(In Formula (3), X ₂ and X ₃ each independently represent a hydrocarbon group or a hydroxyl group.)

  Examples of the hydrocarbon group include an alkyl group such as a methyl group, an ethyl group, a propyl group, and an isopropyl group, a cycloalkyl group such as a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, and a cyclohexyl group, a phenyl group, a naphthyl group, and 2 -An aryl group such as a methylphenyl group, an aralkyl group such as a benzyl group, a diphenylmethyl group, and a naphthylmethyl group, a phenyl group, and a biphenyl group.

  Specific examples of the compound having a siloxane bond (—Si—O—Si—) include polyorganosiloxane and silsesquioxane, and among these, silsesquioxane is preferable. The cured product of silsesquioxane has a relatively high hardness and moderate flexibility. Therefore, by using silsesquioxane, it is possible to obtain the hard coat layers 21a and 21b which are excellent in impact resistance and scratch resistance with respect to the flying object 40 and more excellent in toughness. Therefore, the machine tool windows 2a and 2b that are particularly excellent in durability such as impact resistance to the flying object 40 can be obtained.

  The silsesquioxane may be any structure such as a random structure, a cage structure, or a ladder structure (ladder structure), but a ladder structure is particularly preferable. Thereby, it is possible to obtain the hard coat layers 21a and 21b that are particularly excellent in impact resistance and scratch resistance with respect to the flying object 40.

  As described above, the siloxane-modified (meth) acrylate is a compound in which a (meth) acrylic compound is bonded to a compound having a siloxane bond. Since the siloxane-modified (meth) acrylate has a (meth) acrylic compound, it is excellent in affinity with the above-described (A) polyfunctional acrylate or bifunctional acrylate. Therefore, it is possible to obtain the hard coat layers 21a and 21b in which the siloxane-modified (meth) acrylate is uniformly mixed, and thus obtain the hard coat layers 21a and 21b that are homogeneous and particularly excellent in surface hardness and toughness. be able to.

  Moreover, as a (meth) acrylic-type compound, what has a structure represented by following formula (4) or Formula (5) is mentioned, for example, Especially, it is represented by Formula (4) and Formula (5). Those having both structures are preferred. As both structures represented by Formula (4) and Formula (5), the structure represented by following formula (6) is mentioned, for example. By using the siloxane-modified (meth) acrylate having the above structure, the surface hardness and toughness of the entire hard coat layers 21a and 21b can be made particularly excellent. Therefore, it is possible to more accurately prevent the occurrence of cracks and chips due to the flying object 40 colliding.

(In formula (4), n represents an integer of 1 or more, R 1 independently represents a hydrocarbon group, an organic group, or hydrogen, and R 0 independently represents a hydrocarbon group or hydrogen.)

(In Formula (5), m represents an integer of 1 or more, R2 independently represents a hydrocarbon group, an organic group, or hydrogen, and R0 independently represents a hydrocarbon group or hydrogen.)

(In Formula (6), m and n represent an integer of 1 or more, R1, R2, and R3 each independently represent a hydrocarbon group, an organic group, or hydrogen, and R0 is independently a hydrocarbon. Group or hydrogen.)

  The (meth) acrylic compound is not particularly limited with respect to the degree of polymerization of the (meth) acrylic compound, and the (meth) acrylic compound may be any monomer, dimer, trimer, oligomer, prepolymer, polymer, etc. The degree of polymerization (for example, the sum of m and n in formula (6)) is preferably 100 or more and 200 or less. As a result, the hard coat layers 21a and 21b in which the siloxane-modified (meth) acrylate is uniformly mixed can be obtained more easily and reliably, and the hard coat layers 21a and 21b are more uniform and more excellent in surface hardness. Can be obtained. Therefore, by using such hard coat layers 21 a and 21 b, the machine tool windows 2 a and 2 b can exhibit particularly excellent impact resistance and scratch resistance against the flying object 40.

  As the siloxane-modified (meth) acrylate having the above configuration, for example, compounds represented by the following formulas (7) and (8) are preferably used.

(In formula (7), Me represents a methyl group, and m, n, and p each represents an integer of 1 or more.)

(In the formula (8), Me represents a methyl group, m, n, and p each represents an integer of 1 or more, and R1, R2, R3, and R4 each independently represent a hydrocarbon group, an organic group, Or hydrogen.)

Moreover, when a siloxane modification (meth) acrylate and a filler are included, the content rate of the siloxane modification (meth) acrylate with respect to a total of 100 weight part of the said polyfunctional (meth) acrylate, the said siloxane modification (meth) acrylate, and the said filler. [Parts by weight] is not particularly limited, but is preferably 5 parts by weight or more and 35 parts by weight or less, and more preferably 8 parts by weight or more and 20 parts by weight or less. When the content of the siloxane-modified (meth) acrylate is less than the lower limit, depending on the combination of materials constituting the composition for forming a hard coat layer, a lubricant oil droplet or mist (oil mist) may be used. There is a possibility that the oil resistance to the flying object 40 is slightly lowered. Moreover, when the content rate of siloxane modification (meth) acrylate exceeds the said upper limit, the content rate of the material which comprises the composition for hard-coat layer formation other than siloxane modification (meth) acrylate reduces, and hard-coat layer 21a , 21b may be slightly reduced in hardness.

[Filler]
The filler contributes to further improvement of the surface hardness of the hard coat layers 21a and 21b. Therefore, the hard coat layers 21a and 21b obtained using the hard coat layer forming composition by including the filler are particularly excellent in impact resistance and scratch resistance against the chips 201.

  Examples of the filler include, but are not limited to, for example, silica such as amorphous silica and crystalline silica such as wet and dry, mica, talc, clay, alumina, glass, metal hydroxide such as aluminum hydroxide, magnesium hydroxide, and the like. Examples include inorganic fillers, wood powder, pulp, and organic fillers such as thermosetting resin cured products, and one or more of these can be used in combination. Among these, an inorganic filler is particularly preferable. Inorganic fillers are generally harder than organic fillers and are less likely to break. Therefore, the hardness of the hard coat layers 21a and 21b can be further increased by including an inorganic filler in the hard coat layer forming composition. As a result, the impact resistance of the machine tool windows 2a and 2b with respect to the flying object 40 can be further increased, and damage can be more effectively suppressed or prevented when the flying object 40 collides.

  As the filler, silica is particularly preferable among inorganic fillers. Thereby, the hardness of the hard coat layers 21a and 21b obtained can be further increased, and the generation of fine scratches resulting from the collision of the flying object 40 can be particularly effectively prevented.

  Further, when silica is used as the filler, and the siloxane-modified (meth) acrylate has an acrylic compound having a degree of polymerization of 100 or more and 200 or less, the affinity thereof is particularly high. can do. Therefore, the dispersibility of the silica in the composition for forming a hard coat layer can be enhanced, and thus the hard coat layers 21a and 21b in a state where the silica is uniformly mixed can be obtained. As a result, the surface hardness of the entire hard coat layers 21a and 21b can be further increased. Further, by using the hard coat layers 21a and 21b containing silica and a siloxane-modified (meth) acrylate having a degree of polymerization of the acrylic compound of 100 or more and 200 or less, the machine tool windows 2a and 2b with respect to the flying object 40 Impact resistance can be further increased.

  In addition, examples of the shape of the filler include a fibrous shape, a crushed shape, and a particulate shape. Among these, a particulate shape can be preferably used.

  When the shape of the filler is particulate, the average particle diameter of the filler is not particularly limited, but is preferably 0.001 μm to 5 μm, and more preferably 0.005 μm to 1 μm. Thereby, the hard coat layers 21a and 21b that are particularly excellent in smoothness and particularly high in hardness can be formed.

  The average particle size of the filler can be measured by, for example, a laser diffraction / scattering particle size distribution meter (“LA-500” manufactured by HORIBA).

The filler is preferably in the form of particles, and a compound having a (meth) acryloyl group is introduced on the particle surface. By introducing a compound having a (meth) acryloyl group on the surface of the filler, the filler, the polyfunctional acrylate, and the siloxane-modified acrylate all have a (meth) acryloyl group. For this reason, the affinity of each material (polyfunctional acrylate, siloxane-modified acrylate, and filler) can be made particularly excellent. Since the affinity of each material is excellent, the hard coat layers 21a and 21b in which the materials are uniformly mixed can be obtained. In addition, by introducing a compound having a (meth) acryloyl group on the surface of the filler, the filler, the polyfunctional acrylate, and the siloxane-modified acrylate can be chemically bonded. For this reason, it is possible to obtain the hard coat layers 21a and 21b that are homogeneous and have particularly high hardness. Therefore, the impact resistance and scratch resistance of the entire hard coat layers 21a and 21b to the flying object 40 are improved. It can be made better. Therefore, it is possible to obtain the machine tool windows 2a and 2b having excellent durability against the collision of the flying object 40.

  As a method for introducing a compound having a (meth) acryloyl group into the surface of the filler, a method using a silane coupling agent is particularly preferably used. Thereby, a (meth) acryloyl group can be more easily introduced into the surface of the filler.

  Moreover, when a siloxane modification (meth) acrylate and a filler are included, the filler content with respect to a total of 100 parts by weight of the polyfunctional (meth) acrylate, the siloxane modification (meth) acrylate, and the filler is not particularly limited. However, it is preferably 15 parts by weight or more and 48 parts by weight or less, and more preferably 20 parts by weight or more and 35 parts by weight or less. When the filler content is less than the lower limit, depending on the combination of materials constituting the hard coat layer forming composition, the hardness of the entire hard coat layer 21a, 21b may be slightly reduced. If the filler content exceeds the upper limit, the content of the material constituting the hard coat layer forming composition other than the filler may be reduced, and the oil repellency of the hard coat layers 21a and 21b may be slightly reduced. There is.

[Other materials]
The composition for forming a hard coat layer may contain other materials other than the materials described above (polyfunctional (meth) acrylate, siloxane-modified (meth) acrylate, and filler).

  Examples of other materials include resin materials other than the above-described polyfunctional (meth) acrylates and siloxane-modified (meth) acrylates (for example, monofunctional (meth) acrylates), polymerization initiators, sensitizers, and plasticizers. , Stabilizers, surfactants, antioxidants, anti-reduction agents, antistatic agents, surface conditioners, and solvents.

The photopolymerization initiator has a function as a polymerization initiator when the composition for forming a hard coat layer is cured by ultraviolet rays, and a known one can be used alone or in combination. Benzoin or benzoin alkyl ethers such as ether, benzoin ethyl ether and benzoin isopropyl ether, aromatic ketones such as benzophenone and benzoylbenzoic acid, alpha-dicarbonyls such as benzyl, benzyl ketals such as benzyldimethyl ketal and benzyl diethyl ketal Acetophenone, 1- (4-dodecylphenyl) -2-hydroxy-2-methylpropan-1-one, 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-pro -1-one, 1- (4-isopropylphenyl) -2-hydroxy-2-methyl-propan-1-one, 2-methyl-1- [4- (methylthio) phenyl] -2-morpholinopropanone- Acetophenones such as 1, anthraquinones such as 2-methylanthraquinone, 2-ethylanthraquinone, 2-t-butylanthraquinone, thioxanthones such as 2,4-dimethylthioxanthone, 2-isopropylthioxanthone, 2,4-diisopropylthioxanthone, Phosphine oxides such as bis (2,4,6-trimethylbenzoyl) -phenylphosphine oxide, and alpha-acyloximes such as 1-phenyl-1,2-propanedione-2- (o-ethoxycarbonyl) oxime P-dimethylaminobenzoic acid Le, and the like can be used amines such as p- dimethylaminobenzoic acid isoamyl.

  Examples of the solvent include aliphatic hydrocarbons such as hexane, heptane and cyclohexane, aromatic hydrocarbons such as toluene and xylene, alcohols such as methanol, ethanol, propanol and butanol, ketones such as methyl ethyl ketone, 2-pentanone and isophorone, Examples thereof include esters such as ethyl acetate, butyl acetate and methoxypropyl acetate, cellosolve solvents such as ethyl cellosolve, and glycol solvents such as methoxypropanol, ethoxypropanol and methoxybutanol. These can be used alone or in combination.

  The surface conditioner is added for the purpose of improving the wettability and uniformity of the coating film to the substrate, the smoothness of the surface, and the surface slip property of the cured coating film. Acrylic regulators can be used. Among these, those containing at least one of fluorine-based and modified silicone-based materials are preferable. Those composed of a polyether-modified product, an alkyl-modified product, and a polyester-modified product are preferable, and those composed of a polyether-based material are particularly preferable.

  The composition for forming a hard coat layer as described above preferably contains both (A) polyfunctional (meth) acrylate and (B) bifunctional (meth) acrylate as polyfunctional (meth) acrylate. ) A polyfunctional (meth) acrylate comprising (meth) acrylate monomer having 4 or more (meth) acryloyl groups and (meth) acrylate oligomer having 6 or more (meth) acryloyl groups, and (B) bifunctional (meth) acrylate It is preferable that bisphenol type (meth) acrylate is included. Furthermore, it is preferable that the composition for forming a hard coat layer contains a filler in addition to such a polyfunctional (meth) acrylate. Thereby, the machine tool windows 2a and 2b can exhibit particularly excellent impact resistance and scratch resistance against the flying object 40.

  The hard coat layer forming composition as described above may be in a liquid or solid form at room temperature.

  The window member configured as described above may have a haze increase amount of 5.0 or less when the difference in size between the haze before the flaw acceleration test and the haze after the flaw acceleration test is taken as the haze increase amount. The haze increase amount is preferably 4.0 or less.

  Here, the chip 201 from the processing object generated during processing collides with the window for the machine tool, and the transparency of the hard coat layer 22 is caused by a large number of fine scratches generated by repeating this collision over a long period of time. There was a problem of lowering.

  In addition, it is possible to approximately create such a state that the chip 201 collides with the hard coat layer over a long period of time by causing the chip / lubricating oil mixture to collide with the hard coat layer in the scratch acceleration test. became.

  For this reason, if the amount of increase in haze is within the above range, damage (fine cracks or chippings) is caused by the collision of the chip 201 generated by cutting the cylindrical body 20 (object to be processed). Even if it collides, it can prevent more effectively that a fine crack etc. arise in window 2a, 2b for machine tools. As a result, it is possible to more reliably prevent the visibility of the machine tool windows 2a and 2b from being deteriorated due to fine scratches.

Here, the haze increase amount is obtained by measuring a haze Hz1 after the scratch acceleration test and a haze (initial haze) Hz0 before the scratch acceleration test, and calculating a difference between these sizes, that is, Hz1-Hz0. Can be sought. More specifically, the haze increase amount ΔHz is a value calculated as follows. Note that haze is an index related to transparency and represents turbidity (cloudiness).

First, the prepared machine tool window 2a was cut into a size of 60 mm in length and 60 mm in width. About this cut out sample, the diffuse transmittance Td was measured with a haze meter (trade name: NDH2000, manufactured by Nippon Denshoku Kogyo Co., Ltd.). Then, the total light transmittance Tt is obtained, and haze T (haze Hz0 before scratch acceleration test) [%] is calculated by the following formula (9).
T [%] = Td / Tt × 100 (9)

  Next, the flaw acceleration test is performed as follows. The cut sample is fixed to the sample holder of the scratch acceleration test apparatus so that the chip / lubricant mixture collides with the hard coat layer 21a side of the machine tool window 2a.

  Next, chips of aluminum alloy: A6061 were prepared as chips. Castor Hysol MB-50 manufactured by BP Japan was prepared as a lubricating oil. Aluminum alloy: A6061 chips (70.0 parts by mass) and Castrol Hysol MB-50 (500.0 parts by mass) were weighed and mixed to obtain a mixture. Next, the chip / lubricating oil mixture is made to collide with the machine tool window 2a fixed to the sample holder using compressed air. The conditions for the chip / lubricating oil mixture to collide are a collision speed of 25 mm / sec, a distance of 10 cm with respect to the center of the surface of the machine tool window 2a, and a repetition count of 30 times.

  Next, for the machine tool window 2a after the scratch acceleration test, the haze T (haze Hz1 after the scratch acceleration test) [%] is calculated in the same manner as the method for calculating the haze described above.

  And haze increase amount (DELTA) Hz is calculated by calculating the difference (Hz1-Hz0) of haze Hz1 after a flaw acceleration test, and haze Hz0 before a flaw acceleration test.

  Further, the initial haze Hz0 is preferably 5.0% or less, and more preferably 0.1% or more and 4.0% or less. The machine tool windows 2a and 2b having an initial haze Hz0 within the above numerical range have sufficient transparency, and are particularly excellent in a function as a viewing window and a function as a lighting window. In addition, the machine tool windows 2a and 2b can be manufactured relatively easily and have excellent productivity.

  Further, the haze increase amount ΔHz is preferably 5.0 or less, and more preferably 4.0 or less. When the haze increase amount ΔHz is within the above range, fine scratches due to the collision of the chips 201 are not particularly likely to occur, and particularly excellent transparency can be exhibited over a longer period.

  Further, the hard coat layers 21a and 21b are formed using the hard coat layer forming composition containing each of the above materials.

  Specifically, the hard coat layers 21a and 21b are obtained by applying a varnish-like hard coat layer forming composition to be the hard coat layers 21a and 21b onto the surfaces 211a and 211b of the first base materials 22a and 22b. Thus, it is obtained by curing the coated material by irradiating with ultraviolet rays.

The method for applying the hard coat layer forming composition is not particularly limited, but for example, a known method such as a roll coating method, a flow coating method, a spray coating method, a curtain coating method, a dip coating method, or a die coating method may be used. Can do.

  Then, the hard-coat layer 21a and 21b which are the hardened | cured material of the composition for hard-coat layer formation are formed by having the process of hardening | curing the apply | coated composition for hard-coat layer formation.

  For example, when the composition for forming a hard coat layer is applied on the surfaces 211a and 211b of the first base materials 22a and 22b and contains a diluting solvent, the temperature of the atmosphere is raised and the diluting solvent is sufficiently dried. After forming the coating film, the hard coat layers 21a and 21b can be formed by curing the coating film by irradiation with ultraviolet rays. For example, general electroded or electrodeless high-pressure mercury lamps or metal halide lamps can be used for ultraviolet irradiation. Also, a low voltage electron beam irradiation apparatus of about 100 KeV can be used. When an electron beam is used as a curing means, a photopolymerization initiator described later is not necessary.

  The window member of the present invention has been described above.

  In addition, although the location which provides the window member of this invention is not limited to the thing of the said illustration, since the window member of this invention mentioned above is excellent in the durability with respect to the collision of a flying object, especially a flying object scatters. By being used in an easy-to-use location, the effect of suppressing or preventing breakage caused by the collision of flying objects can be exhibited particularly remarkably. For example, it can be said that the bodies of automobiles and railway vehicles, the exteriors of construction machines and industrial machines, earthwork machines, agricultural machines, forestry machines, and transport machines correspond to places where flying objects are likely to scatter.

  Moreover, although the window member of this invention was demonstrated about embodiment of illustration, this invention is not limited to this, Each part which comprises a window member is a thing of arbitrary structures which can exhibit the same function. Can be substituted. Moreover, arbitrary components may be added.

  Further, the window member of the present invention may be a combination of any two or more configurations (features) of the above embodiments.

  In addition, the window unit is configured to include the first machine tool window and the second machine tool window in each of the above embodiments, but is not limited thereto. For example, the third machine tool window The structure which has this may be sufficient. Further, the second machine tool window may not be provided, and only the first machine tool window may be provided.

  Moreover, although the window unit has an air layer in each of the embodiments, the air layer may be omitted.

  Further, the window unit may omit the frame and each packing, and the first machine tool window and the second machine tool window may be directly mounted on the exterior of the machining center.

  Further, in the machine tool window (the first machine tool window and the second machine tool window), an intermediate layer may be interposed between the base material and the hard coat layer. As an intermediate | middle layer, when affinity with a base material and a hard-coat layer is comparatively low, it can be set as the joining layer which joins a hard-coat layer to a base material, for example.

  Further, in the above-described embodiment, as a factor for generating fine scratches, the chip generated during processing has been described as a representative. However, according to the present invention, the factor for generating fine scratches is not the chip. It is not limited and may be a minute flying object other than chips.

Hereinafter, specific examples of the present invention will be described. Note that the present invention is not limited to this.
Example 1
1. Production of Base Material A polycarbonate 1: polycarbonate resin (trade name “Iupilon KH-3520UR”, manufactured by Mitsubishi Engineering Plastics) was prepared as a first base material.
Polycarbonate 3: polycarbonate resin (trade name “Iupilon E-2000”, manufactured by Mitsubishi Engineering Plastics) was prepared as the second base material.
The extruder (A) and the extruder (B) are connected to the multi-manifold die. From the extruder (A), polycarbonate 1: polycarbonate resin (trade name “Iupilon KH-3520UR”, Mitsubishi, Engineering Plastics Co., Ltd. is extruded, and from the extruder (B), polycarbonate 3: polycarbonate resin (trade name “Iupilon E-2000”, manufactured by Mitsubishi Engineering Plastics Co., Ltd.) is extruded as the second substrate. A laminate of the substrate and the second substrate was obtained. The first substrate thickness was 200 μm, and the second substrate thickness was 15 mm.

2. Preparation of composition for forming hard coat layer First, when preparing a composition for forming a hard coat layer, silica particles A into which an acryloyl group as a filler was introduced were prepared.

  Specifically, silica particles B (trade name “CP-102” manufactured by Tokuyama Co., Ltd., average particle size 0.020 μm) are dispersed in propylene glycol monomethyl ether, and this dispersion is stirred and mixed with a mixer. It was. Thereafter, a silane coupling agent 3-acryloxypropyltrimethoxysilane (manufactured by Shin-Etsu Chemical Co., Ltd., trade name “KBM-5103”) was added while stirring this dispersion. Thereby, the silica particle A in which the acryloyl group was introduced was obtained.

Next, a composition for forming a hard coat layer was produced as follows.
10-functional urethane acrylate (manufactured by Shin-Nakamura Chemical Co., Ltd., trade name “U-10HA”) and 6-functional acrylate (manufactured by Shin-Nakamura Chemical Co., Ltd., trade name “A-DPH”) as polyfunctional (meth) acrylates; Bifunctional bisphenol A acrylate (manufactured by Shin-Nakamura Chemical Co., Ltd., trade name “A-BPE-4”) as bifunctional (meth) acrylate, and silicon-modified (meth) acrylic resin (Tokushiki) as siloxane-modified (meth) acrylate Product name “SQ200”) and silica particles A introduced with the acryloyl group as a filler are blended, and the 10 functional urethane acrylate, 6 functional acrylate, 2 functional bisphenol A acrylate, The total concentration of siloxane-modified (meth) acrylate and silica particles A is 30 mass. Was diluted with propylene glycol monomethyl ether so that.

  To this, 1-hydroxycyclohexyl phenyl ketone (trade name “Irgacure 184”, manufactured by BASF) is added as a polymerization initiator, and modified silicone (trade name “Granol 450”, manufactured by Kyoeisha Chemical Co., Ltd.) is added as a surface conditioner. Then, a composition for forming a hard coat layer was prepared.

  In addition, each material in the composition for hard-coat layer formation was mix | blended so that it might become the content rate shown in Table 1.

  Thus, the prepared composition for forming a hard coat layer was sufficiently stirred and mixed, and then stored in a sealed container.

3. Manufacture of machine tool window Next, a metal bar coater is placed on the first substrate side surface of the laminate of the first substrate and the second substrate obtained in the preparation of the substrate. The composition for forming a hard coat layer was applied so that the wet film thickness was 55 μm. The laminate of the first substrate and the second substrate coated with the hard coat layer forming composition was placed in a hot air circulation oven at 60 ° C. and dried for 10 minutes, and then an electrodeless UV lamp (H Bulb) (manufactured by Heraeus Noblelite Fusion Ubuy Co., Ltd.), with the irradiation distance of 50 mm and the conveyor conveyance speed of 3 m / min, the coating film of the dried hard coat layer forming composition was irradiated with ultraviolet rays, The coating film was cured to obtain a machine tool window (base material provided with a hard coat layer) provided with a hard coat layer having a dry film thickness of 10 μm.

(Examples 2-9, Comparative Examples 1-3)
A composition for forming a hard coat layer was produced in the same manner as in Example 1 except that the type and content of the material constituting the composition for forming a hard coat layer were changed as shown in Table 1. Moreover, except having changed the film thickness of a hard-coat layer, and the kind and thickness of a 1st base material and a 2nd base material as shown in Table 1, the window for machine tools was carried out similarly to the said Example 1. Obtained. In Comparative Example 1, a machine tool window without a hard coat layer was prepared without applying the hard coat layer forming composition.

Table 1 shows the configuration of the hard coat layer of each example and each comparative example.
In Table 1,
10 functional urethane acrylate (trade name “U-10HA”, manufactured by Shin-Nakamura Chemical Co., Ltd.) as “polyfunctional (meth) acrylate”
6-functional acrylate (trade name “A-DPH”, manufactured by Shin-Nakamura Chemical Co., Ltd.) as “polyfunctional (meth) acrylate”
Bifunctional bisphenol A acrylate (trade name “A-BPE-4”, manufactured by Shin-Nakamura Chemical Co., Ltd.) as “bifunctional (meth) acrylate”
Bifunctional chain acrylate (trade name “A-NOD-N”, manufactured by Shin-Nakamura Chemical Co., Ltd.) as “bifunctional (meth) acrylate”
As a siloxane-modified (meth) acrylate, a silicon-modified (meth) acrylic resin (trade name “SQ200”, manufactured by Tokushi Co., Ltd.)
Silica particles B (average particle size 0.020 μm, trade name “CP-102”, manufactured by Tokuyama Corporation) as “silica particles B” as fillers,
As the filler, the silica particles A in which the acryloyl group is introduced are referred to as “silica particles A in which the acryloyl group is introduced”,
As a polymerization initiator, 1-hydroxycyclohexyl phenyl ketone (trade name “Irgacure 184”, manufactured by BASF) was used as a “polymerization initiator”,
Modified silicone (trade name "Granol 450", manufactured by Kyoeisha Chemical Co., Ltd.) as a surface conditioner
Acrylic modified polycarbonate resin (trade name “PCX-6611”, manufactured by Sumika Stylon Co., Ltd.) “polycarbonate 2”,
Methacrylic resin (trade name “SUMIPEX EX”, manufactured by Sumitomo Chemical Co., Ltd.) “acrylic 1”,
Methacrylic resin (trade name “Acrypet IRG”, manufactured by Mitsubishi Rayon Co., Ltd.) “Acrylic 2”
It showed in.

  In addition, the film thickness of the hard-coat layer of each Example and each comparative example was measured with the non-contact film thickness measuring apparatus MCS500 (made by Carl Zeiss).

3. Evaluation In performing the following evaluation, from the base material obtained in each example and each comparative example, the window for machine tool, using the sample cut out to the arbitrary size from the central plane portion, the following evaluation went.

<1> Pencil Hardness Evaluation After applying, drying, and curing a base material without a hard coat layer and a hard coat layer forming composition before applying the hard coat layer forming composition of each example and comparative example The scratch hardness according to the pencil method described in JIS-K5400 was measured using a cut-out sample (60 mm × 60 mm) for a machine tool window having a hard coat layer.

<2> Translucency evaluation <2-1> Evaluation of initial haze Hz0 About the machine tool window of each Example and Comparative Example, using a cut sample (60 mm × 60 mm), a haze meter (trade name: NDH2000, Nippon Denshi Kogyo Co., Ltd.) determined the diffuse transmittance Td and the total light transmittance Tt, and calculated the haze T (%) by the following formula (9). The results are shown in Table 1. Note that haze is an index related to transparency and represents turbidity (cloudiness). If it was 5% or less, the transparency was considered good.
T [%] = Td / Tt × 100 (9)

<2-2> Evaluation of Haze Hz1 and Haze Increase ΔHz After Scratch Acceleration Test For the machine tool windows of each Example and Comparative Example, first, using a cut sample (60 mm × 60 mm), each scratch acceleration The test was performed, and the haze after the scratch acceleration test was calculated by the same method as in <2-1> above, and the haze Hz1 of the sample after the scratch acceleration test was obtained.

  The flaw acceleration test was conducted as follows. First, the sample cut out was fixed to the sample holder so that the chip / lubricating oil mixture collided with the hard coat layer 21 side. Next, chips of aluminum alloy: A6061 were prepared as chips. Castor Hysol MB-50 manufactured by BP Japan was prepared as a lubricating oil. Aluminum alloy: A6061 chips (70.0 parts by mass) and Castrol Hysol MB-50 (500.0 parts by mass) were weighed and mixed to obtain a mixture. Next, the chip / lubricating oil mixture was collided with the cut sample fixed to the sample holder using compressed air. The conditions for the chip / lubricating oil mixture to collide were a collision speed of 25 mm / sec, a distance of 10 cm relative to the center of the hard coat layer surface, and a repetition count of 30 times.

  Next, by calculating the difference (Hz1-Hz0) between the obtained haze Hz1 and the initial haze Hz0 obtained in the above <1-1>, the haze increase amount ΔHz was obtained.

  Table 1 shows the obtained haze Hz1 and the haze increase ΔHz for the machine tool windows of the examples and the comparative examples.

  Moreover, the haze increase amount ΔHz was particularly good when it was 4.0 or less, and good when 4.0 and 5.0 or less.

<3> Oil resistance evaluation About the machine tool window of each example and comparative example, using a cut-out sample (60 mm × 60 mm), lubricating oil (trade name “Yushiroken Synthetic # 660”, manufactured by Yushiro Chemical Industry Co., Ltd.) It was immersed for 14 days at 40 ° C. Thereafter, the sample was taken out, the adhered lubricating oil was wiped off with a waste cloth, the state of the sample was observed, and evaluated according to the following evaluation criteria.
○: No change was observed in the appearance of the surface layer.
X: A change was seen in the appearance of the surface layer.

  The evaluation results in the machine tool windows of the respective examples and comparative examples obtained as described above are shown in Table 1 below.

  As shown in Table 1, the machine tool window of each example was excellent in translucency, scratch resistance, and oil resistance. On the other hand, in the comparative example, a satisfactory result was not obtained.

1 Window unit (machine tool window)
2a First machine tool window 2b Second machine tool window 21a, 21b Hard coat layer 22a, 22b First base material 23a, 23b Second base material 211a, 211b Surface 3a First packing 3b Second Packing 4 frame (window frame)
41 Through-hole 421 1st recessed part (1st groove | channel)
422 Second recess (second groove)
43 Spacer 5 Air layer (intermediate layer)
10 machining center 101 structure 102 exterior 102a stud bolts 102b nut 103 control panel 104 bytes 104 'debris 105 controller 106 liquid crystal panel 107 operation button 20 cylinder 201 chips 30 lubricating oil 40 flying structure S1 machining region S2 operating region t ₁ Hard the total thickness of the average thickness t _total window member average of the average thickness t ₂ the first average thickness of the substrate t ₃ the second base coat layer thickness t ₄ the air layer (intermediate layer)

Claims (7)

A hard coat layer composed of a cured product of a composition for forming a hard coat layer containing a polyfunctional (meth) acrylate, a first substrate having translucency, and a second substrate having translucency A window member comprising:
The hard coat layer composed of a cured product of the hard coat layer forming composition is the outermost layer,
The window member characterized by satisfying the following requirement A.
Requirement A: In the flaw acceleration test in which a chip / lubricant mixture is collided with the laminate from the hard coat layer side, the haze before the flaw acceleration test and the haze after the flaw acceleration test When the difference is the haze increase amount, the haze increase amount is 5 or less.   2. The window member according to claim 1, wherein one of the first base material having translucency and the second base material having translucency is made of a polycarbonate resin and / or an acrylic resin.   The window member according to claim 1 or 2, wherein an average thickness of the hard coat layer composed of a cured product of the hard coat layer forming composition is 5 µm or more and 100 µm or less.   The window member according to any one of claims 1 to 3, wherein an average thickness of the first base material having translucency is 50 µm or more and 500 µm or less.   The window member according to any one of claims 1 to 4, wherein an average thickness of the second base material having translucency is 1 mm or more and 50 mm or less.   Ratio of average thickness of hard coat layer composed of cured product of hard coat layer forming composition to average thickness of first base material having translucency ([hard coat layer forming composition 6. The average thickness of the hard coat layer composed of a cured product] / [the average thickness of the light-transmitting first base material]) is 0.01 or more and 2.0 or less. The window member according to claim 1. Furthermore, the said hard coat layer forming composition is a window member of any one of Claim 1 thru | or 6 containing a filler.