JP2016084285A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
- Publication number
- JP2016084285A JP2016084285A JP2014215767A JP2014215767A JP2016084285A JP 2016084285 A JP2016084285 A JP 2016084285A JP 2014215767 A JP2014215767 A JP 2014215767A JP 2014215767 A JP2014215767 A JP 2014215767A JP 2016084285 A JP2016084285 A JP 2016084285A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- component
- mass
- cleaning composition
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 239000003599 detergent Substances 0.000 title abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 28
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 8
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 7
- 239000002562 thickening agent Substances 0.000 claims abstract description 5
- -1 polyoxyethylene group Polymers 0.000 claims description 85
- 238000004140 cleaning Methods 0.000 claims description 36
- 238000005406 washing Methods 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 230000002209 hydrophobic effect Effects 0.000 claims description 5
- 239000012459 cleaning agent Substances 0.000 claims description 3
- 239000010954 inorganic particle Substances 0.000 abstract description 2
- 239000010420 shell particle Substances 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 25
- 239000000194 fatty acid Substances 0.000 description 25
- 229930195729 fatty acid Natural products 0.000 description 25
- 150000003839 salts Chemical class 0.000 description 25
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 23
- 229920001296 polysiloxane Polymers 0.000 description 23
- 238000011156 evaluation Methods 0.000 description 13
- 239000003921 oil Substances 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 13
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 12
- 239000004166 Lanolin Substances 0.000 description 12
- 235000019388 lanolin Nutrition 0.000 description 12
- 229940039717 lanolin Drugs 0.000 description 12
- 150000004665 fatty acids Chemical class 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 150000005215 alkyl ethers Chemical class 0.000 description 10
- 239000002649 leather substitute Substances 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 239000000284 extract Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
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- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 6
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical class C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- 235000010323 ascorbic acid Nutrition 0.000 description 5
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- 229960005070 ascorbic acid Drugs 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 4
- 241000283690 Bos taurus Species 0.000 description 4
- 102000008186 Collagen Human genes 0.000 description 4
- 108010035532 Collagen Proteins 0.000 description 4
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- 240000004808 Saccharomyces cerevisiae Species 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
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- 125000000217 alkyl group Chemical group 0.000 description 4
- CUFNKYGDVFVPHO-UHFFFAOYSA-N azulene Chemical compound C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 description 4
- KVYGGMBOZFWZBQ-UHFFFAOYSA-N benzyl nicotinate Chemical compound C=1C=CN=CC=1C(=O)OCC1=CC=CC=C1 KVYGGMBOZFWZBQ-UHFFFAOYSA-N 0.000 description 4
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
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- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 4
- 229920001436 collagen Polymers 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 239000004519 grease Substances 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 210000002826 placenta Anatomy 0.000 description 4
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 4
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 244000280244 Luffa acutangula Species 0.000 description 3
- 235000009814 Luffa aegyptiaca Nutrition 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000003973 alkyl amines Chemical class 0.000 description 3
- 229960000458 allantoin Drugs 0.000 description 3
- 235000011399 aloe vera Nutrition 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 235000001014 amino acid Nutrition 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- FJQXCDYVZAHXNS-UHFFFAOYSA-N methadone hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(CC(C)N(C)C)(C(=O)CC)C1=CC=CC=C1 FJQXCDYVZAHXNS-UHFFFAOYSA-N 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229940098465 tincture Drugs 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- 235000002961 Aloe barbadensis Nutrition 0.000 description 2
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- 235000018185 Betula X alpestris Nutrition 0.000 description 2
- 235000018212 Betula X uliginosa Nutrition 0.000 description 2
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- MPDGHEJMBKOTSU-UHFFFAOYSA-N Glycyrrhetinsaeure Natural products C12C(=O)C=C3C4CC(C)(C(O)=O)CCC4(C)CCC3(C)C1(C)CCC1C2(C)CCC(O)C1(C)C MPDGHEJMBKOTSU-UHFFFAOYSA-N 0.000 description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 2
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- PMBRBOODEWULOI-UHFFFAOYSA-N trichloromethanide Chemical compound Cl[C-](Cl)Cl PMBRBOODEWULOI-UHFFFAOYSA-N 0.000 description 1
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- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
本発明は、洗浄剤組成物に関する。 The present invention relates to a cleaning composition.
切削油やグリースのような強固な汚れを取り除くために、界面活性剤と、スクラブ粒子等の研磨剤とを含有する様々な組成物が用いられている。 In order to remove strong dirt such as cutting oil and grease, various compositions containing a surfactant and an abrasive such as scrub particles are used.
例えば、特許文献1には、有機研磨剤を含む組成物が開示されており、汚れを洗浄できることが記載されている。例えば、特許文献2には、生物分解性プラスチックから成る研磨剤を含む組成物が開示されており、無公害であることが記載されている。例えば、特許文献3には、テルペン炭化水素(アルコール)と、研磨剤と、脂肪酸塩を含む組成物が開示されており、洗浄性が優れ、皮膚に対する刺激性が小さいことが記載されている。例えば、特許文献4には、Na・Mg Silicateと、アニオン性界面活性剤を含む組成物が開示されており、使用感が高いことが記載されている。 For example, Patent Document 1 discloses a composition containing an organic abrasive and describes that dirt can be cleaned. For example, Patent Document 2 discloses a composition containing an abrasive made of a biodegradable plastic and describes that it is non-polluting. For example, Patent Document 3 discloses a composition containing a terpene hydrocarbon (alcohol), an abrasive, and a fatty acid salt, and describes that it has excellent cleanability and is less irritating to the skin. For example, Patent Document 4 discloses a composition containing Na · Mg Silicate and an anionic surfactant, and describes that the feeling of use is high.
しかしながら、上記の組成物では、グリース等の頑固な油汚れに対する高い洗浄力、水で洗い流す際の良好なすすぎ性、組成物の伸びの良さ、これらすべてを達成することはできず、使用者の満足を十分に得られない。 However, the above-mentioned composition cannot achieve all of high detergency against stubborn oil stains such as grease, good rinsing property when rinsed with water, and good elongation of the composition. I cannot get enough satisfaction.
そこで、本発明は、油汚れに対して高い洗浄力があり、使用時に良好な伸びが得られ、すすぎ性が良い、洗浄剤組成物を提供することを目的とする。 Therefore, an object of the present invention is to provide a cleaning composition that has a high detergency against oil stains, that provides good elongation during use, and has good rinsing properties.
本発明者は、上記従来技術の課題を解決するために鋭意検討を行った結果、ノニオン性界面活性剤とポリプロピレングリコールとスクラブ材とを含む洗浄剤組成物が、上記課題を解決できることを見出し、本発明を完成するに至った。 As a result of intensive studies in order to solve the above-described problems of the prior art, the present inventor has found that a cleaning composition comprising a nonionic surfactant, polypropylene glycol, and a scrub material can solve the above problems, The present invention has been completed.
すなわち本発明は、下記に記載する通りである。
[1]次の成分(a)と成分(b)と成分(c)とを含む、洗浄剤組成物。
(a)ノニオン性界面活性剤
(b)ポリプロピレングリコール
(c)スクラブ材
[2](d)増粘剤、をさらに含む、[1]に記載の洗浄剤組成物。
[3]成分(a)が、ポリオキシエチレン基を有するノニオン性界面活性剤である、[1]又は[2]に記載の洗浄剤組成物。
[4]成分(a)が、ポリオキシプロピレン基を有するノニオン性界面活性剤である、[1]〜[3]のいずれか一に記載の洗浄剤組成物。
[5]成分(a)が有する疎水部の炭素数が、10以上12以下であるノニオン性界面活性剤である、[1]〜[4]のいずれか一に記載の洗浄剤組成物。
[6]成分(b)の数平均分子量が、700以上3000以下である、[1]〜[5]のいずれか一に記載の洗浄剤組成物。
[7]成分(c)の平均粒子径が、10μm以上500μm以下である、[1]〜[6]のいずれか一に記載の洗浄剤組成物。
[8]手洗い洗浄又は身体洗浄に用いられる、[1]〜[7]のいずれか一に記載の洗浄剤組成物。
That is, the present invention is as described below.
[1] A cleaning composition comprising the following component (a), component (b) and component (c).
(A) Nonionic surfactant (b) Polypropylene glycol (c) Scrub material [2] (d) The detergent composition as described in [1] which further contains a thickener.
[3] The cleaning composition according to [1] or [2], wherein the component (a) is a nonionic surfactant having a polyoxyethylene group.
[4] The cleaning composition according to any one of [1] to [3], wherein the component (a) is a nonionic surfactant having a polyoxypropylene group.
[5] The detergent composition according to any one of [1] to [4], which is a nonionic surfactant having 10 to 12 carbon atoms in the hydrophobic portion of component (a).
[6] The cleaning composition according to any one of [1] to [5], wherein the number average molecular weight of the component (b) is 700 or more and 3000 or less.
[7] The cleaning composition according to any one of [1] to [6], wherein the average particle size of the component (c) is 10 μm or more and 500 μm or less.
[8] The cleaning composition according to any one of [1] to [7], which is used for hand washing or body washing.
本発明の洗浄剤組成物によれば、高い洗浄力、良好な伸び、良好なすすぎ性を同時に達成した洗浄剤組成物が得られる。 According to the cleaning composition of the present invention, it is possible to obtain a cleaning composition that simultaneously achieves high detergency, good elongation, and good rinsing properties.
以下、本発明を実施するための形態(以下、「本実施形態」という。)について具体的に説明する。以下の本実施形態は、本発明を説明するための例示であり、本発明は本実施形態のみに限定されるものではない。本発明は、その要旨の範囲内で種々変形して実施することができる。 Hereinafter, a mode for carrying out the present invention (hereinafter referred to as “the present embodiment”) will be specifically described. The following embodiment is an exemplification for explaining the present invention, and the present invention is not limited to this embodiment. The present invention can be implemented with various modifications within the scope of the gist.
本実施形態の洗浄剤組成物は、次の成分(a)と成分(b)と成分(c)とを含む。
(a)ノニオン性界面活性剤
(b)ポリプロピレングリコール
(c)スクラブ材
The cleaning composition of this embodiment contains the following component (a), component (b), and component (c).
(A) Nonionic surfactant (b) Polypropylene glycol (c) Scrub material
<成分(a)>
本実施形態における成分(a)のノニオン性界面活性剤として、具体的には、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンポリオキシプロピレンアルキルエーテル等のポリオキシアルキレンアルキルエーテル;ポリオキシエチレン多環フェニルエーテル、プロピレングリコール脂肪酸エステル、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレンアルキルアミンエーテル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンソルビット脂肪酸エステル、ポリオキシエチレンソルビットミツロウ、ポリオキシエチレンラノリン、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンステロール、ポリエチレングリコール脂肪酸エステル、ショ糖脂肪酸エステル、アルキルグルコシド、アルキルアミンオキシド等が挙げられる。
<Component (a)>
Specific examples of the nonionic surfactant of component (a) in the present embodiment include polyoxyalkylene alkyl ethers such as polyoxyethylene alkyl ether and polyoxyethylene polyoxypropylene alkyl ether; polyoxyethylene polycyclic phenyl ether , Propylene glycol fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene alkylamine ether, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester, polyoxyethylene Sorbit beeswax, polyoxyethylene lanolin, polyoxyethylene hydrogenated castor oil, polyoxyethylene sterol, poly Chi glycol fatty acid esters, sucrose fatty acid esters, alkyl glucosides, alkyl amine oxides, and the like.
洗浄力の観点から、成分(a)が、ポリオキシエチレン基を有するノニオン性界面活性剤であることが好ましく、具体的には、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンポリオキシプロピレンアルキルエーテル、ポリオキシエチレン多環フェニルエーテル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレンアルキルアミンエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンソルビット脂肪酸エステル、ポリオキシエチレンラノリン、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンステロールである。 From the viewpoint of detergency, the component (a) is preferably a nonionic surfactant having a polyoxyethylene group, and specifically, polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene group, Oxyethylene polycyclic phenyl ether, polyoxyethylene glycerin fatty acid ester, polyoxyethylene alkylamine ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester, polyoxyethylene lanolin, polyoxyethylene hydrogenated castor oil, polyoxyethylene It is a sterol.
成分(a)が、ポリオキシプロピレン基を有するノニオン性界面活性剤であることも、洗浄性の観点から好ましい。より好ましくは、ポリオキシエチレン基とポリオキシプロピレン基とを有するノニオン性界面活性剤であり、具体的には、ポリオキシエチレンポリオキシプロピレンアルキルエーテルである。 It is also preferable from the viewpoint of detergency that the component (a) is a nonionic surfactant having a polyoxypropylene group. More preferably, it is a nonionic surfactant having a polyoxyethylene group and a polyoxypropylene group, specifically, a polyoxyethylene polyoxypropylene alkyl ether.
洗浄性とすすぎ性の観点から、成分(a)が有する疎水部の炭素数は、10以上12以下であることが好ましく、より好ましくは10である。疎水部とは、界面活性剤における炭素原子が直鎖状に連続して連なっている部分であり、例えば、ポリオキシエチレンアルキルエーテルの「アルキル」部である。また、疎水部の炭素数とは、例えば、上記「アルキル部」の主鎖の炭素数である。10以上であることで、洗浄時の浸透性が優れる。12以下であることで、水への溶解性に優れる。 From the viewpoints of detergency and rinsing properties, the number of carbon atoms in the hydrophobic portion of component (a) is preferably 10 or more and 12 or less, more preferably 10. The hydrophobic part is a part in which carbon atoms in the surfactant are continuously connected in a straight chain, for example, an “alkyl” part of polyoxyethylene alkyl ether. The carbon number of the hydrophobic part is, for example, the carbon number of the main chain of the “alkyl part”. The permeability at the time of washing | cleaning is excellent because it is 10 or more. It is excellent in the solubility to water because it is 12 or less.
洗浄性、すすぎ性の観点から、成分(a)の含有量は、洗浄剤組成物100質量%に対して、0.5質量%以上35質量%以下が好ましく、より好ましくは1質量%以上25質量%以下であり、さらに好ましくは3質量%以上20質量%以下である。0.5質量%以上であることで、より優れた洗浄力を得ることができる。35質量%以下であることで、すすぎ性がより良好となる。 From the viewpoint of detergency and rinsability, the content of the component (a) is preferably 0.5% by mass or more and 35% by mass or less, more preferably 1% by mass or more and 25% with respect to 100% by mass of the cleaning composition. It is not more than mass%, and more preferably not less than 3 mass% and not more than 20 mass%. By being 0.5 mass% or more, more excellent detergency can be obtained. Rinsing property becomes more favorable because it is 35 mass% or less.
<成分(b)>
本実施形態における成分(b)のポリプロピレングリコールとしては、特に限定するものではないが、洗浄性、伸び、すすぎ性の観点から、数平均分子量が700以上3000以下であるものが好ましく、800以上2500以下であるものがより好ましく、900以上2200以下であるものがさらに好ましく、1000以上2000以下であるものが特に好ましい。700以上であることで、より優れた洗浄力を得ることができる。3000以下であることで、すすぎ性がより良好となる。
<Component (b)>
The polypropylene glycol of component (b) in the present embodiment is not particularly limited, but from the viewpoint of detergency, elongation and rinsability, those having a number average molecular weight of 700 to 3000 are preferred, and 800 to 2500. What is below is more preferable, What is 900 or more and 2200 or less is further more preferable, What is 1000 or more and 2000 or less is especially preferable. By being 700 or more, more excellent detergency can be obtained. When it is 3000 or less, the rinsing property becomes better.
洗浄性、伸び、すすぎ性の観点から、成分(b)の含有量は、洗浄剤組成物100質量%に対して、0.01質量%以上20質量%以下が好ましく、より好ましくは0.05質量%以上10質量%以下であり、さらに好ましくは0.1質量%以上5質量%以下である。0.01質量%以上であることで、より優れた洗浄力を得ることができる。20質量%以下であることで、すすぎ性がより良好となる。 From the viewpoints of detergency, elongation and rinsability, the content of component (b) is preferably 0.01% by mass or more and 20% by mass or less, more preferably 0.05% with respect to 100% by mass of the detergent composition. The content is from 10% by mass to 10% by mass, and more preferably from 0.1% by mass to 5% by mass. A more excellent detergency can be obtained by being 0.01 mass% or more. By being 20% by mass or less, the rinsing property becomes better.
<成分(c)>
本実施形態における成分(c)のスクラブ材として、具体的には、クルミの殻粒子、トウモロコシ穂軸粒子、アンズ核粒子、ポリヒドロキシブチレート粒子、ポリ(ヒドロキシブチレート/ヒドロキシヘキサノエート)粒子、エステル化澱粉粒子、酢酸セルロース粒子、キトサン/セルロース/澱粉混合物粒子、ポリブチレンサクシネート粒子、ポリブチレンサクシネートアジペート粒子、ポリ乳酸粒子、ポリエチレンサクシネート粒子、ポリカプロラクトン系樹脂粒子、ポリグリコール酸粒子、ポリテトラメチレンアジペート・コ・テレフタレート粒子、ポリブチレンアジペートテレフタレート粒子、ポリブチレンサクシネート・コ・アジペート・コ・テレフタレート粒子、ポリブチレンサクシネートカーボネート粒子、ポリブチレンサクシネートテレフタレート粒子、ポリエチレン粒子、無機系粒子等が挙げられる。
<Component (c)>
Specifically, as the scrub material of component (c) in this embodiment, walnut shell particles, corn cob particles, apricot kernel particles, polyhydroxybutyrate particles, poly (hydroxybutyrate / hydroxyhexanoate) particles , Esterified starch particles, cellulose acetate particles, chitosan / cellulose / starch mixture particles, polybutylene succinate particles, polybutylene succinate adipate particles, polylactic acid particles, polyethylene succinate particles, polycaprolactone resin particles, polyglycolic acid particles , Polytetramethylene adipate co-terephthalate particles, polybutylene adipate terephthalate particles, polybutylene succinate co-adipate co-terephthalate particles, polybutylene succinate carbonate particles, polybutylene sac Sulfonates terephthalate particles, polyethylene particles, inorganic particles, and the like.
洗浄性の観点から、成分(c)の平均粒子径が、10μm以上500μm以下であることが好ましく、より好ましくは50μm以上400μm以下であり、さらに好ましくは80μm以上300μm以下である。10μm以上、500μm以下であることで、より優れた洗浄力が得られる。 From the viewpoint of detergency, the average particle size of the component (c) is preferably 10 μm or more and 500 μm or less, more preferably 50 μm or more and 400 μm or less, and further preferably 80 μm or more and 300 μm or less. When the thickness is 10 μm or more and 500 μm or less, more excellent detergency can be obtained.
成分(c)の平均粒子径は、乾式粒度分布計(ロボットシフターRPS−105M セイシン企業株式会社製など)により、JIS Z 8801に準拠して測定することができる。 The average particle size of the component (c) can be measured according to JIS Z 8801 with a dry particle size distribution analyzer (Robot Shifter RPS-105M manufactured by Seishin Enterprise Co., Ltd.).
洗浄性の観点から、成分(c)の含有量は、洗浄剤組成物100質量%に対して、0.5質量%以上20質量%以下であることが好ましく、より好ましくは1質量%以上15質量%以下であり、さらに好ましくは3質量%以上10質量%以下である。0.5質量%以上、20質量%以下であることで、より優れた洗浄力が得られる。 From the viewpoint of detergency, the content of the component (c) is preferably 0.5% by mass or more and 20% by mass or less, more preferably 1% by mass or more and 15% by mass with respect to 100% by mass of the cleaning composition. It is not more than mass%, and more preferably not less than 3 mass% and not more than 10 mass%. When the content is 0.5% by mass or more and 20% by mass or less, more excellent detergency can be obtained.
<成分(d)>
本実施形態の洗浄剤組成物には、その安定性を高める効果として、成分(d)の増粘剤をさらに含むことが好ましい。成分(d)として、具体的には、カルボキシメチルセルロース、ヒドロキシエチルセルロースヒドロキシプロピルトリメチルアンモニウムクロリドエーテル、エチルセルロース、ヒドロキシプロピルセルロース、メチルヒドロキシプロピルセルロース、デンプン、可溶性デンプン、カルボキシメチルデンプン、メチルデンプン、アルギン酸プロピレングリコールエステル、メチルセルロース、アラビアガム、キサンタンガム、グアーガム、ローカストビンガム、クインスシード、カラギーナン、ガラクタン、ペクチン、マンナン、デキストラン、サクシノグルカン、カードラン、ゼラチン、カゼイン、アルブミン、コラーゲン、メトキシエチレン無水マレイン酸共重合体、両性メタクリル酸エステル共重合体、アクリル酸又はメタクリル酸とアクリル酸エステル又はメタクリル酸エステルとの共重合体、ポリ塩化ジメチルメチレンピペリジニウム、ポリアクリル酸エステル共重合体、ポリ酢酸ビニル、ポリビニルアルコール、ポリビニルピロリドン、ポリビニルメチルエーテル、カルボキシビニルポリマー、ポリアクリル酸、ニトロセルロース、ポリエチレングリコール脂肪酸エステル、ジステアリン酸ポリエチレングリコール等のポリオキシエチレン脂肪酸エステル、ポリオキシエチレンジオレイン酸メチルグルコシド等のポリオキシエチレン脂肪酸エステルメチルグリコシド等が挙げられる。
<Component (d)>
It is preferable that the cleaning composition of the present embodiment further includes a thickener of component (d) as an effect of increasing the stability. Specific examples of the component (d) include carboxymethylcellulose, hydroxyethylcellulose hydroxypropyltrimethylammonium chloride ether, ethylcellulose, hydroxypropylcellulose, methylhydroxypropylcellulose, starch, soluble starch, carboxymethylstarch, methylstarch, propylene glycol alginate , Methylcellulose, gum arabic, xanthan gum, guar gum, locust bin gum, quince seed, carrageenan, galactan, pectin, mannan, dextran, succinoglucan, curdlan, gelatin, casein, albumin, collagen, methoxyethylene maleic anhydride copolymer, Amphoteric methacrylate copolymer, acrylic acid or methacrylic acid Copolymers with acrylate or methacrylate, polydimethylmethylenepiperidinium chloride, polyacrylate copolymer, polyvinyl acetate, polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl methyl ether, carboxyvinyl polymer, polyacrylic acid And polyoxyethylene fatty acid esters such as nitrocellulose, polyethylene glycol fatty acid ester and polyethylene glycol distearate, and polyoxyethylene fatty acid ester methyl glycosides such as polyoxyethylene dioleic acid methyl glucoside.
すすぎ性、安定性の観点から、カルボキシビニルポリマー等のポリアクリル酸系増粘剤が好ましく、より好ましくはアクリル酸又はメタクリル酸と、アクリル酸エステル又はメタクリル酸エステルとの共重合体である。 From the viewpoint of rinsing properties and stability, polyacrylic acid thickeners such as carboxyvinyl polymer are preferable, and a copolymer of acrylic acid or methacrylic acid and acrylic acid ester or methacrylic acid ester is more preferable.
安定性、すすぎ性の観点から、成分(d)の含有量は、洗浄剤組成物100質量%に対して、0.05質量%以上10質量%以下が好ましく、より好ましくは0.1質量%以上5質量%以下であり、さらに好ましくは0.15質量%以上1質量%である。0.05質量%以上であることで、保存安定性がより良好となる。10質量%以下であることで、すすぎ性がより良好となる。 From the viewpoints of stability and rinsability, the content of the component (d) is preferably 0.05% by mass or more and 10% by mass or less, more preferably 0.1% by mass with respect to 100% by mass of the cleaning composition. The content is 5% by mass or less, and more preferably 0.15% by mass or more and 1% by mass. Storage stability becomes more favorable because it is 0.05 mass% or more. Rinsing property becomes more favorable because it is 10 mass% or less.
<添加剤>
本実施形態は、その効果を阻害しない範囲において通常用いられる添加剤を含んでもよい。添加剤として、具体的には、カチオン性界面活性剤、両イオン性界面活性剤、アニオン性界面活性剤、中和剤、天然動植物油脂類、合成トリグリセライド、炭化水素類、ワックス、ロウ類、高級アルコール類、高級脂肪酸類、コレステロール及びその誘導体、エステル類、極性オイル、シリコーン類、紫外線吸収剤、美白成分、保湿剤、金属イオン封鎖剤、酸化防止剤、殺菌剤、防腐剤、有機酸、ビタミン類、血行促進剤、局所刺激剤、抗炎症剤、収斂剤、清涼剤、その他の成分等が挙げられる。
<Additives>
The present embodiment may include additives that are normally used within a range that does not impair the effect. Specific additives include cationic surfactants, amphoteric surfactants, anionic surfactants, neutralizers, natural animal and vegetable oils, synthetic triglycerides, hydrocarbons, waxes, waxes, and higher grades. Alcohols, higher fatty acids, cholesterol and its derivatives, esters, polar oils, silicones, UV absorbers, whitening ingredients, moisturizers, sequestering agents, antioxidants, bactericides, antiseptics, organic acids, vitamins , Blood circulation promoters, local stimulants, anti-inflammatory agents, astringents, refreshing agents, and other components.
カチオン性界面活性剤として、具体的には、塩化アルキルトリメチルアンモニウム、塩化アルキルジメチルベンジルアンモニウム、塩化ジアルキルジメチルアンモニウム、臭化アルキルトリメチルアンモニウム、塩化アルキルペンタエトキシアンモニウム、エチル硫酸ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウム、カチオン化セルロース等のアンモニウム系化合物;アシルジエチルアミノエチルアミド、アシルジメチルアミノプロピルアミド、ポリオキシエチレン脂肪酸アミド等のアミド系化合物;ミリスチルジメチルアミンオキシド等が挙げられる。 Specific examples of the cationic surfactant include alkyltrimethylammonium chloride, alkyldimethylbenzylammonium chloride, dialkyldimethylammonium chloride, alkyltrimethylammonium bromide, alkylpentaethoxyammonium chloride, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium, Examples include ammonium compounds such as cationized cellulose; amide compounds such as acyl diethylaminoethylamide, acyldimethylaminopropylamide, and polyoxyethylene fatty acid amide; myristyldimethylamine oxide.
両イオン性界面活性剤として、具体的には、脂肪酸残基の炭素数が13以上のアルキルジメチルアミノ酢酸ベタイン、アシルアミドプロピルジメチルアミノ酢酸ベタイン等のベタイン系化合物;N−アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、N−アルキル−N―カルボキシメチル−N−ヒドロキシエチルエチレンジアミン・ラウリル硫酸およびその塩等のイミダゾリニウム系化合物;ポリオクチルポリアミノエチルグリシン等のグリシン型化合物;アルキルアミノプロピオン酸、アルキルアミノジプロピオン酸等のアミノプロピオン酸型化合物等;レシチン等のリン脂質等が挙げられる。 Specific examples of amphoteric surfactants include betaine compounds such as alkyldimethylaminoacetic acid betaines and acylamidopropyldimethylaminoacetic acid betaines having a fatty acid residue of 13 or more carbon atoms; N-alkyl-N-carboxymethyl -Imidazolium compounds such as N-hydroxyethylimidazolinium betaine, N-alkyl-N-carboxymethyl-N-hydroxyethylethylenediamine / lauryl sulfate and salts thereof; glycine-type compounds such as polyoctylpolyaminoethylglycine; alkyl Examples include aminopropionic acid type compounds such as aminopropionic acid and alkylaminodipropionic acid; and phospholipids such as lecithin.
アニオン性界面活性剤として、具体的には、炭素数が18以下のナトリウム、又はカリウム石鹸等の石鹸;脂肪酸残基の炭素数が17以下のアシルサルコシン及びその塩、アシルアミノ酸及びその塩、アシル化ペプチド及びその塩等のアミノ酸系化合物;ポリオキシエチレンアルキルエーテルカルボン酸及びその塩、ポリオキシエチレンアルキルエーテル硫酸及びその塩、ポリオキシエチレンアルキルエーテルスルホン酸及びその塩等のポリオキシアルキレン付加物;アルキルリン酸及びそのカリウム塩又はアルカノールアミン塩、ポリオキシエチレンアルキルエーテルリン酸及びその塩等のリン酸系化合物;スルホコハク酸ジアルキル及びその塩、ポリオキシエチレンスルホコハク酸アルキルエーテル及びその塩等のスルホコハク酸系化合物;アルキルフェノールエーテルリン酸エステル及びその塩等のアルキルフェノール系化合物等が挙げられる。 Specific examples of anionic surfactants include soaps such as sodium or potassium soaps having 18 or less carbon atoms; acyl sarcosine and salts thereof, fatty acid residues having 17 or less carbon atoms, acyl amino acids and salts thereof, acyl Amino acid compounds such as fluorinated peptides and salts thereof; polyoxyalkylene adducts such as polyoxyethylene alkyl ether carboxylic acid and salts thereof, polyoxyethylene alkyl ether sulfuric acid and salts thereof, polyoxyethylene alkyl ether sulfonic acids and salts thereof; Phosphoric compounds such as alkyl phosphoric acid and its potassium salt or alkanolamine salt, polyoxyethylene alkyl ether phosphoric acid and its salt; sulfosuccinic acid such as dialkyl sulfosuccinate and its salt, polyoxyethylene sulfosuccinic acid alkyl ether and its salt Compound ; Alkylphenol compounds such as alkyl phenol ether phosphate and salts thereof.
中和剤として、具体的には、水酸化ナトリウム、水酸化カリウム、アンモニア水等の無機物;トリメチルアミン、ジエタノールアミン、ジエチルアミン、トリエタノールアミン等の有機アミン類等が挙げられる。 Specific examples of the neutralizing agent include inorganic substances such as sodium hydroxide, potassium hydroxide and aqueous ammonia; organic amines such as trimethylamine, diethanolamine, diethylamine and triethanolamine.
天然動植物油脂類、合成トリグリセライドとして、具体的には、ホホバ油、マカデミアナッツ油、アボガド油、月見草油、ミンク油、ナタネ油、ヒマシ油、ヒマワリ油、トウモロコシ油、カカオ油、ヤシ油、コメヌカ油、オリーブ油、アーモンド油、ごま油、サフラワー油、大豆油、椿油、パーシック油、ヒマシ油、ミンク油、綿実油、モクロウ、パーム油、パーム核油、卵黄油、ラノリン、スクワレン等が挙げられる。 Natural animal and vegetable oils and fats, synthetic triglycerides, specifically jojoba oil, macadamia nut oil, avocado oil, evening primrose oil, mink oil, rapeseed oil, castor oil, sunflower oil, corn oil, cacao oil, palm oil, rice bran oil, Examples include olive oil, almond oil, sesame oil, safflower oil, soybean oil, cocoon oil, persic oil, castor oil, mink oil, cottonseed oil, owl, palm oil, palm kernel oil, egg yolk oil, lanolin, and squalene.
炭化水素類として、具体的には、スクワラン、流動パラフィン、ワセリン、セレシン、マイクロクリスタリンワックス、イソパラフィン等が挙げられる。 Specific examples of the hydrocarbons include squalane, liquid paraffin, petrolatum, ceresin, microcrystalline wax, and isoparaffin.
ワックス、ロウ類として、具体的には、カルナバウロウ、パラフィンワックス、鯨ロウ、ミツロウ、キヤンデリラワックス、ラノリン等が挙げられる。 Specific examples of waxes and waxes include carnauba wax, paraffin wax, whale wax, beeswax, chiyandelilla wax, and lanolin.
高級アルコール類として、具体的には、セタノール、ステアリルアルコール、ラウリルアルコール、セトステアリルアルコール、オレイルアルコール、ベヘニルアルコール、ラノリンアルコール、水添ラノリンアルコール、ヘキシルデカノール、オクチルドデカノール等が挙げられる。 Specific examples of higher alcohols include cetanol, stearyl alcohol, lauryl alcohol, cetostearyl alcohol, oleyl alcohol, behenyl alcohol, lanolin alcohol, hydrogenated lanolin alcohol, hexyl decanol, and octyldodecanol.
高級脂肪酸類として、具体的には、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、イソステアリン酸、オレイン酸、リノレン酸、リノール酸、オキシステアリン酸、ウンデシレン酸、ラノリン脂肪酸、硬質ラノリン脂肪酸、軟質ラノリン脂肪酸等が挙げられる。 Specific examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, oleic acid, linolenic acid, linoleic acid, oxystearic acid, undecylenic acid, lanolin fatty acid, and hard lanolin fatty acid. And soft lanolin fatty acid.
コレステロール及びその誘導体として、具体的には、コレステリル−オクチルドデシル−ベヘニル等が挙げられる。 Specific examples of cholesterol and derivatives thereof include cholesteryl-octyldodecyl-behenyl and the like.
エステル類として、具体的には、イソプロピルミリスチン酸、イソプロピルパルミチン酸、イソプロピルステアリン酸、2エチルヘキサン酸グリセロール、ブチルステアリン酸、リノール酸エチル等が挙げられる。 Specific examples of the esters include isopropyl myristic acid, isopropyl palmitic acid, isopropyl stearic acid, glycerol 2-ethylhexanoate, butyl stearic acid, and ethyl linoleate.
極性オイルとして、具体的には、ジエチレングリコールモノプロピルエーテル、ポリオキシエチレンポリオキシプロピレンペンタエリトリトールエーテル、ポリオキシプロピレンブチルエーテル等が挙げられる。 Specific examples of polar oils include diethylene glycol monopropyl ether, polyoxyethylene polyoxypropylene pentaerythritol ether, and polyoxypropylene butyl ether.
シリコーン類として、具体的には、メチルフェニルポリシロキサン、メチルポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、メチルシクロポリシロキサン、オクタメチルトリシロキサン、デカメチルテトラシロキサン、ポリオキシエチレン・メチルポリシロキサン共重合体、ポリオキシプロピレン・メチルポリシロキサン共重合体、ポリ(オキシエチレン・オキシプロピレン)メチルポリシロキサン共重合体、メチルハイドロジェンポリシロキサン、テトラヒドロテトラメチルシクロテトラシロキサン、ステアロキシメチルポリシロキサン、セトキシメチルポリシロキサン、メチルポリシロキサンエマルション、高重合メチルポリシロキサン、トリメチルシロキシケイ酸、架橋型メチルポリシロキサン、架橋型メチルフェニルポリシロキサン、架橋型メチルフェニルポリシロキサン、架橋型メチルフェニルポリシロキサン、アミノ変性シリコーン、エポキシ変性シリコーン、カルボキシル変性シリコーン、カルビノール変性シリコーン、メタクリル変性シリコーン、メルカプト変性シリコーン、フェノール変性シリコーン、片末端反応性シリコーン、異種官能基変性シリコーン、ポリエーテル変性シリコーン、メチルスチリル変性シリコーン、アルキル変性シリコーン、高級脂肪酸エステル変性シリコーン、親水性特殊変性シリコーン、高級アルコキシ変性シリコーン、高級脂肪酸含有シリコーン、フッ素変性シリコーン等が挙げられる。また、これらの各種誘導体であってもよい。 Specific examples of silicones include methylphenylpolysiloxane, methylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, methylcyclopolysiloxane, octamethyltrisiloxane, decamethyltetrasiloxane. , Polyoxyethylene / methylpolysiloxane copolymer, polyoxypropylene / methylpolysiloxane copolymer, poly (oxyethylene / oxypropylene) methylpolysiloxane copolymer, methylhydrogenpolysiloxane, tetrahydrotetramethylcyclotetrasiloxane , Stearoxymethyl polysiloxane, cetoxymethyl polysiloxane, methyl polysiloxane emulsion, highly polymerized methyl polysiloxane, trimethyl Roxysilicic acid, crosslinked methylpolysiloxane, crosslinked methylphenylpolysiloxane, crosslinked methylphenylpolysiloxane, crosslinked methylphenylpolysiloxane, amino-modified silicone, epoxy-modified silicone, carboxyl-modified silicone, carbinol-modified silicone, methacryl-modified silicone , Mercapto-modified silicone, phenol-modified silicone, one-end reactive silicone, heterogeneous functional group-modified silicone, polyether-modified silicone, methylstyryl-modified silicone, alkyl-modified silicone, higher fatty acid ester-modified silicone, hydrophilic specially-modified silicone, higher alkoxy-modified Examples include silicone, higher fatty acid-containing silicone, and fluorine-modified silicone. Moreover, these various derivatives may be sufficient.
紫外線吸収剤として、具体的には、パラアミノ安息香酸及びその誘導体、ホモメチル−7N−アセチルアラントイラニレート、ブチルメトキシベンゾイルメタン、ジ−パラメトキシケイ皮酸−モノ−2−エチルヘキサン酸グリセリル、オクチルシンナメート等のパラメトキシケイ皮酸誘導体、アミルサリシレート等のサリチル酸誘導体、2,4−ジヒドロキシベンゾフェノン等のベンゾフェノン誘導体、ジメトキシベンジリデンジオキソイミダゾリンプロピオン酸エチルヘキシル、酢酸液状ラノリン、コガネバナ根抽出エキス、トリアニリノ−p−カルボエチルヘキシルオキシ−トリアジン等が挙げられる。 Specific examples of ultraviolet absorbers include paraaminobenzoic acid and its derivatives, homomethyl-7N-acetylaranthranilate, butylmethoxybenzoylmethane, di-paramethoxycinnamic acid-glyceryl mono-2-ethylhexanoate, octyl Paramethoxycinnamic acid derivatives such as cinnamate, salicylic acid derivatives such as amyl salicylate, benzophenone derivatives such as 2,4-dihydroxybenzophenone, ethyl hexyl dimethoxybenzylidenedioxoimidazoline propionate, liquid lanolin acetate extract, trianilino-p -Carboethylhexyloxy-triazine and the like.
美白成分として、具体的には、アルブチン、コウジ酸、リン酸アスコルビン酸マグネシウム等のアスコルビン酸及びその誘導体、グルタチオン、甘草エキス、チョウジエキス、茶抽出物、アスタキサンチン、牛胎盤エキス、トコフェロール及びその誘導体、トラネキサム酸及びその塩、アズレン、γ−ヒドロキシ酪酸等が挙げられる。 As whitening ingredients, specifically, ascorbic acid and its derivatives such as arbutin, kojic acid and magnesium ascorbate, glutathione, licorice extract, clove extract, tea extract, astaxanthin, cow placenta extract, tocopherol and its derivatives, Examples include tranexamic acid and its salts, azulene, γ-hydroxybutyric acid and the like.
保湿剤として、具体的には、マルチトール、ソルビトール、グリセリン、プロピレングリコール、1,3−ブチレングリコール、ポリエチレングリコール、グリコール等の多価アルコール;ピロリドンカルボン酸ソーダ、乳酸ソーダ、クエン酸ソーダ等の有機酸及びその塩;ヒアルロン酸ソーダ等のヒアルロン酸及びその塩;酵母及び酵母抽出液の加水分解物、酵母培養液、乳酸菌培養液等の醗酵代謝産物;コラーゲン、エラスチン、ケラチン、セリシン等の水溶性蛋白;コラーゲン加水分解物、カゼイン加水分解物、シルク加水分解物、ポリアスパラギン酸ナトリウム等のぺプチド類及びその塩;トレハロース、キシロビオース、マルトース、ラフィノース、メリビオース、蔗糖、ブドウ糖、植物性粘質多糖等の糖類、結晶性セルロース、非結晶性セルロース、キシラン、マンナン、ガラクタン、アラビナン、アラビノキシラン等の多糖類及びその誘導体;水溶性キチン、キトサン、ペクチン、コンドロイチン硫酸及びその塩等のグリコサミノグリカン及びその塩;グリシン、セリン、スレオニン、アラニン、アスパラギン酸、チロシン、バリン、ロイシン、アルギニン、グルタミン、プロリン酸等のアミノ酸;アミノカルボニル反応物等の糖アミノ酸化合物、アロエ、マロニエ等の植物抽出液、トリメチルグリシン、ベタイン、尿素、尿酸、アンモニア、レシチン、ラノリン、スクワラン、スクワレン、グルコサミン、クレアチニン、DNA、RNA等の核酸関連物質等が挙げられる。 Specific examples of moisturizers include polyhydric alcohols such as maltitol, sorbitol, glycerin, propylene glycol, 1,3-butylene glycol, polyethylene glycol, and glycol; organics such as pyrrolidone carboxylate soda, lactate soda, and sodium citrate Acids and salts thereof; Hyaluronic acid such as sodium hyaluronate and salts thereof; Fermentation metabolites such as yeast and yeast extract hydrolyzate, yeast culture solution, lactic acid bacteria culture solution; water-soluble collagen, elastin, keratin, sericin, etc. Proteins: Collagen hydrolysates, casein hydrolysates, silk hydrolysates, peptides such as sodium polyaspartate and their salts; trehalose, xylobiose, maltose, raffinose, melibiose, sucrose, glucose, vegetable viscous polysaccharides, etc. Sugars, crystalline cellulose, Polysaccharides such as crystalline cellulose, xylan, mannan, galactan, arabinan, arabinoxylan and derivatives thereof; glycosaminoglycans and salts thereof such as water-soluble chitin, chitosan, pectin, chondroitin sulfate and salts thereof; glycine, serine, threonine, Amino acids such as alanine, aspartic acid, tyrosine, valine, leucine, arginine, glutamine, prophosphoric acid; sugar amino acid compounds such as aminocarbonyl reactants, plant extracts such as aloe and maronier, trimethylglycine, betaine, urea, uric acid, ammonia And nucleic acid-related substances such as lecithin, lanolin, squalane, squalene, glucosamine, creatinine, DNA and RNA.
金属イオン封鎖剤として、具体的には、エチレンジアミン四酢酸およびその塩類、ヒドロキシエチレンジアミン3酢酸およびその塩類、リン酸、アスコルビン酸、コハク酸、グルコン酸、ポリリン酸塩類、メタリン酸塩類等が挙げられる。 Specific examples of the sequestering agent include ethylenediaminetetraacetic acid and its salts, hydroxyethylenediaminetriacetic acid and its salts, phosphoric acid, ascorbic acid, succinic acid, gluconic acid, polyphosphates, metaphosphates, and the like.
酸化防止剤として、具体的には、ブチルヒドロキシトルエン、トコフェロール、フィチン酸等が挙げられる。 Specific examples of the antioxidant include butylhydroxytoluene, tocopherol, phytic acid and the like.
殺菌剤、防腐剤として、具体的には、安息香酸及びその塩、サリチル酸及びその塩、ソルビン酸及びその塩、パラオキシ安息香酸アルキルエステル(エチルパラベン、ブチルパラベン等)及びその塩、デヒドロ酢酸及びその塩類、パラクロルメタクレゾール、ヘキサクロロフェン、ホウ酸、レゾルシン、トリブロムサラン、オルトフェニルフェノール、グルコン酸クロルヘキシジン、チラム、感光素201号、フェノキシエタノール、塩化ベンザルコニウム、ハロカルバン、塩化クロルヘキシジン、トリクロロカルバニド、酢酸トコフェロール、ジンクピリチオン、ヒノキチオール、フェノール、イソプロピルメチルフェノール、2,4,4−トリクロロ−2−ヒドロキシフェノール、ヘキサクロロフェン、チアゾリノン系、イソチアゾリノン系等が挙げられる。 Specific examples of bactericides and preservatives include benzoic acid and its salts, salicylic acid and its salts, sorbic acid and its salts, paraoxybenzoic acid alkyl esters (ethyl paraben, butyl paraben, etc.) and their salts, dehydroacetic acid and its Salts, parachlorometacresol, hexachlorophene, boric acid, resorcin, tribromosaran, orthophenylphenol, chlorhexidine gluconate, thiram, photosensitizer 201, phenoxyethanol, benzalkonium chloride, halocarban, chlorhexidine chloride, trichlorocarbanide , Tocopherol acetate, zinc pyrithione, hinokitiol, phenol, isopropylmethylphenol, 2,4,4-trichloro-2-hydroxyphenol, hexachlorophene, thiazolinone, isothiazolino System, and the like.
有機酸として、具体的には、クエン酸、リンゴ酸、酒石酸、乳酸、アジピン酸、グルタミン酸、アスパラギン酸、マレイン酸等が挙げられる。 Specific examples of the organic acid include citric acid, malic acid, tartaric acid, lactic acid, adipic acid, glutamic acid, aspartic acid, maleic acid and the like.
ビタミン類として、具体的には、ビタミンA及びその誘導体;ビタミンB6塩酸塩、ビタミンB6トリパルミテート、ビタミンB6ジオクタノエート、ビタミンB2及びその誘導体、アスコルビン酸、アスコルビン酸硫酸エステル、アスコルビン酸リン酸エステル等のビタミンC類、αトコフェロール、βトコフェロール、γトコフェロール等のビタミンE類、ビタミンD類、ビタミンH、パントテン酸等が挙げられる。 Specific examples of vitamins include vitamin A and its derivatives; vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 and its derivatives, ascorbic acid, ascorbic acid sulfate, ascorbic acid phosphate and the like Vitamin C, vitamin E such as α-tocopherol, β-tocopherol and γ-tocopherol, vitamin D, vitamin H, pantothenic acid and the like.
血行促進剤、局所刺激剤として、具体的には、ニコチン酸アミド、ニコチン酸ベンジル、γ−オリザノール、アラントイン、グリチルリチン酸(塩)グリチルレチン酸及びその誘導体、ヒノキチオール、ムシジン、ビサボロール、ユーカリプトール、チモールイノシトール、サポニン類(キラヤサポニン、アズキサポニン、ヘチマサポニン等)、トラネキサム酸、パントテルエチルエーテル、エチニルエストラジオール、セファランジン、プラセンタエキス、センブリエキス、セファランチン、ビタミンE及びその誘導体、ガンマーオリザノール、トウガラシチンキ、ショオウキョウチンキ、カンタリスチンキ、ニコチン酸ベンジルエステル等が挙げられる。 Specific examples of blood circulation promoters and local stimulants include nicotinamide, benzyl nicotinate, γ-oryzanol, allantoin, glycyrrhizic acid (salt) glycyrrhetinic acid and its derivatives, hinokitiol, mucidin, bisabolol, eucalyptol, thymol Inositol, saponins (Quillaja saponin, azoxaponin, loofah saponin, etc.), tranexamic acid, pantotel ethyl ether, ethinyl estradiol, cephalandin, placenta extract, assembly extract, cephalanthin, vitamin E and its derivatives, gamma oryzanol, red pepper tincture, sho Tokyo tincture, cantalis tincture, nicotinic acid benzyl ester and the like.
抗炎症剤、収斂剤、清涼剤として、具体的には、グリチルレチン酸、グリチルリチン酸誘導体、アラントイン、アズレン、アミノカプロン酸、ヒドロコルチゾン、酸化亜鉛、硫酸亜鉛、アラントインヒドロキシアルミニウム、塩化アルミニウム、スルホ石炭酸亜鉛、タンニン酸、メントール、カンフル等が挙げられる。 Anti-inflammatory agents, astringents, and cooling agents, specifically glycyrrhetinic acid, glycyrrhizic acid derivatives, allantoin, azulene, aminocaproic acid, hydrocortisone, zinc oxide, zinc sulfate, allantoin hydroxyaluminum, aluminum chloride, zinc sulfocolate, tannin Acid, menthol, camphor and the like can be mentioned.
その他の成分として、具体的には、サッカロマイセス等の酵母、糸状菌、バクテリア、牛胎盤、人胎盤、人臍帯、酵母、牛コラーゲン、牛乳由来蛋白、小麦、大豆、牛血液、ブタ血液、鶏冠、カミツレ、キュウリ、コメ、シアバター、シラカバ、茶、トマト、ニンニク、ハマメリス、バラ、ヘチマ、ホップ、モモ、アンズ、レモン、キウイ、ドクダミ、トウガラシ、クララ、ギシギシ、コウホネ、セージ、ノコギリ草、ゼニアオイ、センキュウ、センブリ、タイム、トウキ、トウヒ、バーチ、スギナ、ヘチマ、マロニエ、ユキノシタ、アルニカ、ユリ、ヨモギ、シャクヤク、アロエ、アロエベラ、オウゴン、オウバク、コウカ、ベニバナ、サンシン、シコン、タイソウ、チンピ、ニンジン、ヨクイニン、ハトムギ、クチナシ、サワラ等の動植物・微生物及びその一部から有機溶媒、アルコール、多価アルコール、水、水性アルコール等で抽出又は加水分解して得た天然エキス、色素、香料、精製水等が挙げられる。 As other ingredients, specifically, yeast such as Saccharomyces, filamentous fungi, bacteria, bovine placenta, human placenta, human umbilical cord, yeast, bovine collagen, milk-derived protein, wheat, soybean, cow blood, pig blood, chicken crown, Chamomile, cucumber, rice, shea butter, birch, tea, tomato, garlic, clam, rose, loofah, hop, peach, apricot, lemon, kiwi, dodami, capsicum, clara, scallop, kohone, sage, sawtooth grass, mallow Senkyu, assembly, thyme, spruce, spruce, birch, horsetail, loofah, maronier, yukinoshita, arnica, lily, mugwort, peonies, aloe vera, aloe vera, ugon, buckwheat, cedar, safflower, sancin, shikon, tiso, chimney, carrot, Animal planting of Yokuinin, pearl barley, gardenia, sawara, etc. - microbial and organic solvent from a portion thereof, alcohols, polyhydric alcohols, water, natural extracts obtained by extraction or hydrolysis in aqueous alcohol, dyes, perfumes, purified water, and the like.
本実施形態の洗浄剤組成物は、手洗い洗浄又は身体洗浄に用いられることができる。手洗い洗浄又は身体洗浄に用いられることにより、頑固な油汚れを伴うような作業現場等で優れた洗浄力と使用感を得ることができる。 The cleaning composition of this embodiment can be used for hand washing or body washing. By being used for hand washing or body washing, it is possible to obtain excellent cleaning power and feeling of use at a work site where stubborn oil stains are involved.
以下、具体的な実施例を挙げて本実施形態について詳細に説明するが、本実施形態はその要旨を超えない限り、以下の実施例に限定されるものではない。 Hereinafter, although a specific Example is given and this embodiment is described in detail, this embodiment is not limited to a following example, unless the summary is exceeded.
[実施例1〜29]
表1、表2の実施例1〜29に示した各成分を、500gに対しての配合割合(質量%)でビーカーに量りとり、マグネティックスターラ―で15分撹拌し、実施例1〜29の洗浄剤組成物500gを得た。なお、実施例29については、スクラブ材の沈降が見られたが、評価試験前に撹拌して均一にしてから評価を行った。評価は、下記に示す方法にて、「洗浄性評価」、「官能評価」を行ったものであり、結果を表1、表2に示す。
[Examples 1 to 29]
Each component shown in Examples 1 to 29 in Tables 1 and 2 was weighed in a beaker at a blending ratio (mass%) with respect to 500 g, and stirred for 15 minutes with a magnetic stirrer. 500 g of a cleaning composition was obtained. In Example 29, although scrubbing material was found to settle, it was evaluated after stirring and uniforming before the evaluation test. The evaluation was performed by “detergency evaluation” and “sensory evaluation” by the methods shown below, and the results are shown in Tables 1 and 2.
[比較例1〜4]
表2の比較例1〜4に示した各成分を、500gに対しての配合割合(質量%)でビーカーに量りとり、マグネティックスターラ―で15分撹拌し、比較例1〜4の洗浄剤組成物500gを得た。評価は、下記に示す方法にて、「洗浄性評価」、「官能評価」を行ったものであり、結果を表2に示す。
[Comparative Examples 1-4]
Each component shown in Comparative Examples 1 to 4 in Table 2 was weighed into a beaker at a blending ratio (mass%) with respect to 500 g, stirred with a magnetic stirrer for 15 minutes, and the detergent composition of Comparative Examples 1 to 4 500 g of product was obtained. Evaluation was performed by “detergency evaluation” and “sensory evaluation” by the methods shown below, and the results are shown in Table 2.
「洗浄性評価」
洗浄液:実施例1〜29、比較例1〜4で得られた洗浄剤組成物
油モデル汚れ:カーボンブラック(東海カーボン社製 SEAST・KH N−339)1質量部に対して、シリコングリース(信越化学工業株式会社製 HIVAC−G)10質量部を良く混合したもの。
人工皮革A及びB:ソフトセメリー1003 カラー:1
洗浄評価機器:マーチンデール摩耗試験機(JAMES H.HEAL&CO.LTD.HALIFAX ENGLAND社製)モード:0.5、擦る回数20回
"Cleanability evaluation"
Cleaning liquid: Cleaning agent composition oil model dirt obtained in Examples 1 to 29 and Comparative Examples 1 to 4: Silicon grease (Shin-Etsu) against 1 part by mass of carbon black (SEAST / KH N-339 manufactured by Tokai Carbon Co., Ltd.) A well-mixed product of 10 parts by mass of HIVAC-G manufactured by Chemical Industry Co.
Artificial leather A and B: Soft semery 1003 Color: 1
Cleaning evaluation equipment: Martindale abrasion tester (manufactured by JAMES H. HEAL & CO. LTD. HALFAX ENGLAND) mode: 0.5, rubbing 20 times
マーチンデール摩耗試験機に、直径4cmの円型に切り取った白色の人工皮革A及び直径13cmの円型に切り取った白色の人工皮革Bをセットし、人工皮革Aに上記油モデル汚れ0.03gを塗付し、人工皮革Bに洗浄液0.2mlを塗付し、上記条件でマーチンデール摩耗試験機を用いて人工皮革AとBをこすり合わせ、その後、人工皮革Aを10秒間水洗し、人工皮革上の洗浄状態として黒色度を、画像解析PCソフトScion Image(Scion社製)を用いて解析した。具体的には、10秒間水洗後の人工皮革をスキャナによりPCに画像として取り込み、この画像データを上記の画像解析ソフトを用いることにより、黒色度合を2刻みで0〜256の数値として表し、表示される値を洗浄力の指標とした。0(洗浄力が低い)〜256(洗浄力が高い)の値で洗浄性を評価した。 Set the white artificial leather A cut into a circle with a diameter of 4 cm and the white artificial leather B cut into a circle with a diameter of 13 cm into a Martindale abrasion tester, and 0.03 g of the oil model stain was added to the artificial leather A. Apply and apply 0.2 ml of washing solution to artificial leather B, rub artificial leather A and B using the Martindale abrasion tester under the above conditions, then wash artificial leather A with water for 10 seconds, artificial leather The blackness was analyzed using the image analysis PC software Scion Image (manufactured by Scion) as the upper cleaning state. Specifically, artificial leather that has been washed with water for 10 seconds is captured as an image on a PC by a scanner, and this image data is displayed as a numerical value between 0 and 256 in units of 2 by using the above image analysis software. The value obtained was used as an index of detergency. The detergency was evaluated from 0 (low detergency) to 256 (high detergency).
「官能評価」
実施例1〜29及び比較例1〜4で得られた洗浄剤組成物で、パネラー10人に手洗いを行ってもらい、手洗い時の手の表面においての「伸びの良さ」と、水で洗い流す際の「すすぎ性」を評価した。評価基準は下記の通りとし、パネラー10人の評価点数の平均値を評価結果とした。
「伸びの良さ」
3点:伸びが良い。
2点:やや伸びが良い。
1点:やや伸びが悪い。
0点:伸びが悪い。
「すすぎ性」
3点:すすぎ性が良い。
2点:ややすすぎ性が良い。
1点:ややすすぎ性が悪い。
0点:すすぎ性が悪い。
"sensory evaluation"
With the detergent compositions obtained in Examples 1 to 29 and Comparative Examples 1 to 4, when 10 panelists perform hand washing, “goodness of elongation” on the surface of the hand during hand washing and washing with water The “rinsing property” was evaluated. The evaluation criteria were as follows, and the average of the evaluation scores of 10 panelists was used as the evaluation result.
"Good growth"
3 points: Elongation is good.
2 points: Slightly good elongation.
1 point: Slightly poor elongation.
0 point: poor growth.
"Rinse"
3 points: Good rinsing properties.
2 points: Easy to pass.
1 point: Poor ease.
0 point: The rinsing property is poor.
表1、表2から、実施例1〜29で得られた洗浄剤組成物は、比較例1〜4で得られた洗浄剤組成物より、洗浄力、伸び、すすぎ性に優れていることが分かる。 From Table 1 and Table 2, the cleaning composition obtained in Examples 1 to 29 is superior in cleaning power, elongation, and rinsing properties than the cleaning composition obtained in Comparative Examples 1 to 4. I understand.
本発明に係る洗浄剤組成物は、手洗い洗浄、身体洗浄、切削油やグリースのような強固な汚れを取り除く洗浄剤等の分野において、産業上の利用可能性を有する。 The cleaning composition according to the present invention has industrial applicability in fields such as hand cleaning, body cleaning, and cleaning agents that remove strong dirt such as cutting oil and grease.
Claims (8)
(a)ノニオン性界面活性剤
(b)ポリプロピレングリコール
(c)スクラブ材 A cleaning composition comprising the following component (a), component (b) and component (c).
(A) Nonionic surfactant (b) Polypropylene glycol (c) Scrub material
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