JP2016047917A5 - - Google Patents
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- JP2016047917A5 JP2016047917A5 JP2015160731A JP2015160731A JP2016047917A5 JP 2016047917 A5 JP2016047917 A5 JP 2016047917A5 JP 2015160731 A JP2015160731 A JP 2015160731A JP 2015160731 A JP2015160731 A JP 2015160731A JP 2016047917 A5 JP2016047917 A5 JP 2016047917A5
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- JP
- Japan
- Prior art keywords
- oxide
- layer
- oxide layer
- pigment
- structural color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000049 pigment Substances 0.000 claims 11
- 239000011248 coating agent Substances 0.000 claims 6
- 238000000576 coating method Methods 0.000 claims 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims 3
- OFJATJUUUCAKMK-UHFFFAOYSA-N Cerium(IV) oxide Chemical compound [O-2]=[Ce+4]=[O-2] OFJATJUUUCAKMK-UHFFFAOYSA-N 0.000 claims 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- 239000006096 absorbing agent Substances 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims 2
- 230000005670 electromagnetic radiation Effects 0.000 claims 2
- JPJZHBHNQJPGSG-UHFFFAOYSA-N titanium;zirconium;tetrahydrate Chemical compound O.O.O.O.[Ti].[Zr] JPJZHBHNQJPGSG-UHFFFAOYSA-N 0.000 claims 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims 2
- 230000001699 photocatalysis Effects 0.000 claims 1
- 230000005684 electric field Effects 0.000 description 6
- 239000000758 substrate Substances 0.000 description 1
Description
ゼロ又はほぼゼロの電場点の計算について言及すると、図12は反射率nsを有する基盤又は中心層2上の、全厚「D」、増分の厚さ「d」、及び反射率「n」を有する誘電体層4を表している。入射光は誘電体層4の外表面5を、外表面5に対して垂直な線6に対して角度θで当たり、そして同じ角度で外表面5から反射する。入射光は外表面5を透過して、線6に対して角度θFで誘電体層4に入り、基盤層の表面3に角度θsで当たる。 In reference to the calculation of zero or near zero electric field points, FIG. 12 shows the total thickness “D”, the incremental thickness “d”, and the reflectance “n” on the substrate or central layer 2 with reflectance n s. Represents the dielectric layer 4 having. The incident light hits the outer surface 5 of the dielectric layer 4 at an angle θ with respect to the line 6 perpendicular to the outer surface 5 and is reflected from the outer surface 5 at the same angle. The incident light passes through the outer surface 5 and enters the dielectric layer 4 at an angle θ F with respect to the line 6 and hits the surface 3 of the base layer at an angle θ s.
一つの誘電体層について、θs=θ F かつ電場/電界(E)はz=dのとき、E(z)と表現することができる。
マクスウェルの方程式から、電場は、s偏光について:
From Maxwell's equations, the electric field is about s-polarized light:
誘電体層4のz軸方向の電場の変化は、下記のように表現される、未知のパラメーターu(z)及びv(z)を計算することにより概算することができると理解されたい。
p偏光についてqs=ns/cosθs(40)
s偏光についてq=ncosθF (41)
p偏光についてq=n/cosθF (42)
φ=k・n・dcos(θF)(43)
u(z)及びv(z)は、下記のように表現することができる:
About p-polarized light q s = n s / cos θ s (40)
About s polarization q = ncosθ F (41)
About p-polarized light q = n / cosθ F (42)
φ = k · n · dcos (θ F ) (43)
u (z) and v (z) can be expressed as:
したがって、θF=0又は垂直な入射であり、φ=k・n・d、及びα=0である単純な状況において:
Claims (6)
前記顔料の外表面を被覆している酸化物層を含む耐候性コーティングであって、かつ前記顔料の光触媒活性を、前記耐候性コーティングを有しない前記顔料と比較して、少なくとも50%減少させる耐候性コーティング、
を有する、全方向構造色顔料。 The reflector layer , the dielectric layer extending over the reflector layer, and the absorber layer extending over the dielectric layer are included, and the reflector layer, the dielectric layer, and the absorber layer are substantially flat. Layer, given a given half-width (FWMH) less than 200 nm and less than 30 ° in the CIELAB color space when exposed to wideband electromagnetic radiation and observed from an angle between 0 ° and 45 °. A weather-resistant coating containing a pigment that reflects one band of visible electromagnetic radiation having color shift and an oxide layer covering the outer surface of the pigment, and the photocatalytic activity of the pigment is the weather resistance. A weather resistant coating, which reduces by at least 50% compared to said pigments without a coating.
An omnidirectional structural color pigment having.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/460,511 US10870740B2 (en) | 2007-08-12 | 2014-08-15 | Non-color shifting multilayer structures and protective coatings thereon |
US14/460,511 | 2014-08-15 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2020105083A Division JP7203790B2 (en) | 2014-08-15 | 2020-06-18 | Multilayer structure without color shift and protective coating on the structure |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2016047917A JP2016047917A (en) | 2016-04-07 |
JP2016047917A5 true JP2016047917A5 (en) | 2021-04-22 |
JP7040880B2 JP7040880B2 (en) | 2022-03-23 |
Family
ID=55235085
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015160731A Active JP7040880B2 (en) | 2014-08-15 | 2015-08-17 | Multilayer structure without color shift and protective coating on the structure |
JP2020105083A Active JP7203790B2 (en) | 2014-08-15 | 2020-06-18 | Multilayer structure without color shift and protective coating on the structure |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2020105083A Active JP7203790B2 (en) | 2014-08-15 | 2020-06-18 | Multilayer structure without color shift and protective coating on the structure |
Country Status (3)
Country | Link |
---|---|
JP (2) | JP7040880B2 (en) |
CN (2) | CN112126248A (en) |
DE (1) | DE102015112412A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107092046A (en) * | 2017-04-26 | 2017-08-25 | 上海默奥光学薄膜器件有限公司 | A kind of high reflective mirror of wide spectrum |
CN111417522A (en) * | 2017-09-29 | 2020-07-14 | 耐克创新有限合伙公司 | Structurally colored articles and methods for making and using same |
US11118062B2 (en) * | 2017-12-06 | 2021-09-14 | Toyota Motor Engineering & Manufacturing North America, Inc. | LiDAR reflecting dark colored pigments and vehicles comprising the same |
CN110543012B (en) * | 2018-05-29 | 2022-05-17 | 北京以色佳科技有限公司 | Design method of non-energy-consumption artificial intelligence filter with reflecting film and filter |
CN115770711A (en) * | 2022-11-30 | 2023-03-10 | 厦门凌太光学有限公司 | Environment-friendly coating process for surface of spectacle lens |
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ATE168713T1 (en) * | 1994-02-21 | 1998-08-15 | Basf Ag | MULTIPLE COATED METALLIC GLOSS PIGMENTS |
DE4405492A1 (en) * | 1994-02-21 | 1995-08-24 | Basf Ag | Metallic pigments with multiple coatings |
DE19515988A1 (en) * | 1995-05-02 | 1996-11-07 | Basf Ag | Goniochromatic gloss pigments with a coating containing metal sulfide |
GB9619781D0 (en) * | 1996-09-23 | 1996-11-06 | Secr Defence | Multi layer interference coatings |
DE19707805A1 (en) * | 1997-02-27 | 1998-09-03 | Merck Patent Gmbh | Multilayer interference pigment with an absorbent middle layer |
EP0984043A1 (en) * | 1998-08-31 | 2000-03-08 | Sicpa Holding S.A. | Optically variable pigments providing a colour shift between two distinct colours, coating composition comprising the same, method for producing the same and substrate coated with the coating composition |
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DE19901612A1 (en) * | 1999-01-19 | 2000-07-20 | Merck Patent Gmbh | Multilayer pearlescent pigments comprise a lamellar substrate with a high refractive index, a layer of a material with a low refractive index and a semitransparent metallic layer |
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US10690823B2 (en) * | 2007-08-12 | 2020-06-23 | Toyota Motor Corporation | Omnidirectional structural color made from metal and dielectric layers |
US10788608B2 (en) * | 2007-08-12 | 2020-09-29 | Toyota Jidosha Kabushiki Kaisha | Non-color shifting multilayer structures |
EP2212726A1 (en) * | 2007-10-30 | 2010-08-04 | 3M Innovative Properties Company | Multi-stack optical bandpass film with electro magnetic interference shielding for optical display filters |
KR101821431B1 (en) * | 2010-02-04 | 2018-01-23 | 바스프 에스이 | Pigment compositions with improved sparkling effect |
JP2013518946A (en) * | 2010-02-04 | 2013-05-23 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | Effect pigment |
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US20140162520A1 (en) * | 2011-08-05 | 2014-06-12 | Construction Research & Technology Gmbh | Water-proof coating system for reflecting solar radiation and water-borne coating for forming decorative and reflective layer in coating system |
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-
2015
- 2015-07-29 DE DE102015112412.2A patent/DE102015112412A1/en active Pending
- 2015-08-14 CN CN202010927458.7A patent/CN112126248A/en active Pending
- 2015-08-14 CN CN201510498432.4A patent/CN105974501B/en active Active
- 2015-08-17 JP JP2015160731A patent/JP7040880B2/en active Active
-
2020
- 2020-06-18 JP JP2020105083A patent/JP7203790B2/en active Active
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