JP2016047917A5 - - Google Patents

Download PDF

Info

Publication number
JP2016047917A5
JP2016047917A5 JP2015160731A JP2015160731A JP2016047917A5 JP 2016047917 A5 JP2016047917 A5 JP 2016047917A5 JP 2015160731 A JP2015160731 A JP 2015160731A JP 2015160731 A JP2015160731 A JP 2015160731A JP 2016047917 A5 JP2016047917 A5 JP 2016047917A5
Authority
JP
Japan
Prior art keywords
oxide
layer
oxide layer
pigment
structural color
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2015160731A
Other languages
Japanese (ja)
Other versions
JP7040880B2 (en
JP2016047917A (en
Filing date
Publication date
Priority claimed from US14/460,511 external-priority patent/US10870740B2/en
Application filed filed Critical
Publication of JP2016047917A publication Critical patent/JP2016047917A/en
Publication of JP2016047917A5 publication Critical patent/JP2016047917A5/ja
Application granted granted Critical
Publication of JP7040880B2 publication Critical patent/JP7040880B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Description

ゼロ又はほぼゼロの電場点の計算について言及すると、図12は反射率nを有する基盤又は中心層2上の、全厚「D」、増分の厚さ「d」、及び反射率「n」を有する誘電体層4を表している。入射光は誘電体層4の外表面5を、外表面5に対して垂直な線6に対して角度θで当たり、そして同じ角度で外表面5から反射する。入射光は外表面5を透過して、線6に対して角度θで誘電体層4に入り、基盤層の表面3に角度θで当たる。 In reference to the calculation of zero or near zero electric field points, FIG. 12 shows the total thickness “D”, the incremental thickness “d”, and the reflectance “n” on the substrate or central layer 2 with reflectance n s. Represents the dielectric layer 4 having. The incident light hits the outer surface 5 of the dielectric layer 4 at an angle θ with respect to the line 6 perpendicular to the outer surface 5 and is reflected from the outer surface 5 at the same angle. The incident light passes through the outer surface 5 and enters the dielectric layer 4 at an angle θ F with respect to the line 6 and hits the surface 3 of the base layer at an angle θ s.

一つの誘電体層について、θs=θ かつ電場/電界(E)はz=dのとき、E(z)と表現することができる。
マクスウェルの方程式から、電場は、s偏光について:

Figure 2016047917
及びp偏光について:
Figure 2016047917
したがって、s偏光について、
Figure 2016047917
及びp偏光について
Figure 2016047917
である。 For one dielectric layer, when θs = θ F and the electric field / electric field (E) is z = d, it can be expressed as E (z).
From Maxwell's equations, the electric field is about s-polarized light:
Figure 2016047917
And p-polarized light:
Figure 2016047917
Therefore, regarding s polarization,
Figure 2016047917
And p-polarized light
Figure 2016047917
Is.

誘電体層4のz軸方向の電場の変化は、下記のように表現される、未知のパラメーターu(z)及びv(z)を計算することにより概算することができると理解されたい。

Figure 2016047917
s偏光についてq=ncosθ(39)
p偏光についてq=n/cosθ(40)
s偏光についてq=ncosθ (41)
p偏光についてq=n/cosθ (42)
φ=k・n・dcos(θ)(43)
u(z)及びv(z)は、下記のように表現することができる:
Figure 2016047917
及び
Figure 2016047917
Figure 2016047917
及びp偏光について
Figure 2016047917
ここで、
Figure 2016047917
Figure 2016047917
及び
Figure 2016047917
It should be understood that the change in the electric field of the dielectric layer 4 in the z-axis direction can be estimated by calculating the unknown parameters u (z) and v (z) expressed as follows.
Figure 2016047917
About s polarization q s = n s cos θ s (39)
About p-polarized light q s = n s / cos θ s (40)
About s polarization q = ncosθ F (41)
About p-polarized light q = n / cosθ F (42)
φ = k · n · dcos (θ F ) (43)
u (z) and v (z) can be expressed as:
Figure 2016047917
as well as
Figure 2016047917
Figure 2016047917
And p-polarized light
Figure 2016047917
here,
Figure 2016047917
Figure 2016047917
as well as
Figure 2016047917

したがって、θ=0又は垂直な入射であり、φ=k・n・d、及びα=0である単純な状況において:

Figure 2016047917
これにより厚さ「d」を、即ち、誘電体層中の電場がほぼゼロ又は最小値である場所を解くことができる。 Therefore , in the simple situation where θ F = 0 or vertical incident, φ = k · n · d, and α = 0:
Figure 2016047917
This makes it possible to solve the thickness "d", that is, the place where the electric field in the dielectric layer is almost zero or the minimum value.

Claims (6)

反射体層と前記反射体層にわたって延在する誘電体層と、前記誘電体層にわたって延在する吸収体層とを含み、前記反射体層、誘電体層及び吸収体層が実質的に平坦な層であり、広帯域電磁放射に曝し、かつ0°〜45°の間の角度から観察したときに、200nmより小さい所与の半値幅(FWMH)及びCIELAB色空間において30°より小さい所与の色ずれを有する可視電磁放射の1つの帯域を反射する顔料、及び
前記顔料の外表面を被覆している酸化物層を含む耐候性コーティングであって、かつ前記顔料の光触媒活性を、前記耐候性コーティングを有しない前記顔料と比較して、少なくとも50%減少させる耐候性コーティング、
を有する、全方向構造色顔料。
The reflector layer , the dielectric layer extending over the reflector layer, and the absorber layer extending over the dielectric layer are included, and the reflector layer, the dielectric layer, and the absorber layer are substantially flat. Layer, given a given half-width (FWMH) less than 200 nm and less than 30 ° in the CIELAB color space when exposed to wideband electromagnetic radiation and observed from an angle between 0 ° and 45 °. A weather-resistant coating containing a pigment that reflects one band of visible electromagnetic radiation having color shift and an oxide layer covering the outer surface of the pigment, and the photocatalytic activity of the pigment is the weather resistance. A weather resistant coating, which reduces by at least 50% compared to said pigments without a coating.
An omnidirectional structural color pigment having.
前記酸化物層が酸化ケイ素、酸化アルミニウム、酸化ジルコニウム、酸化チタン、及び酸化セリウムからなる群より選択される、請求項1に記載の全方向構造色顔料。 The omnidirectional structural color pigment according to claim 1, wherein the oxide layer is selected from the group consisting of silicon oxide, aluminum oxide, zirconium oxide, titanium oxide, and cerium oxide. 前記耐候性コーティングが、第1の酸化物層及び第2の酸化物層を有し、前記第2の酸化物層が、前記第1の酸化物層と異なる、請求項2に記載の全方向構造色顔料。 The omnidirectional coating according to claim 2, wherein the weather resistant coating has a first oxide layer and a second oxide layer, and the second oxide layer is different from the first oxide layer. Structural color pigment. 前記第2の酸化物層が、2つの異なる酸化物の組み合わせである混合酸化物層である、請求項3に記載の全方向構造色顔料。 The omnidirectional structural color pigment according to claim 3, wherein the second oxide layer is a mixed oxide layer which is a combination of two different oxides. 前記第1の酸化物層が、酸化ケイ素であり、かつ前記第2の酸化物層が、酸化ケイ素、酸化アルミニウム、酸化ジルコニウム、酸化チタン、及び酸化セリウムからなる群のうちの少なくとも2つの組み合わせである混合酸化物層である、請求項3に記載の全方向構造色顔料。 The first oxide layer is silicon oxide, and the second oxide layer is a combination of at least two of the group consisting of silicon oxide, aluminum oxide, zirconium oxide, titanium oxide, and cerium oxide. The omnidirectional structural color pigment according to claim 3, which is a mixed oxide layer. 前記耐候性コーティングを除いた前記顔料が酸化物層を含まない、請求項1に記載の全方向構造色顔料。 The omnidirectional structural color pigment according to claim 1, wherein the pigment excluding the weather resistant coating does not contain an oxide layer.
JP2015160731A 2014-08-15 2015-08-17 Multilayer structure without color shift and protective coating on the structure Active JP7040880B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/460,511 US10870740B2 (en) 2007-08-12 2014-08-15 Non-color shifting multilayer structures and protective coatings thereon
US14/460,511 2014-08-15

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2020105083A Division JP7203790B2 (en) 2014-08-15 2020-06-18 Multilayer structure without color shift and protective coating on the structure

Publications (3)

Publication Number Publication Date
JP2016047917A JP2016047917A (en) 2016-04-07
JP2016047917A5 true JP2016047917A5 (en) 2021-04-22
JP7040880B2 JP7040880B2 (en) 2022-03-23

Family

ID=55235085

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2015160731A Active JP7040880B2 (en) 2014-08-15 2015-08-17 Multilayer structure without color shift and protective coating on the structure
JP2020105083A Active JP7203790B2 (en) 2014-08-15 2020-06-18 Multilayer structure without color shift and protective coating on the structure

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2020105083A Active JP7203790B2 (en) 2014-08-15 2020-06-18 Multilayer structure without color shift and protective coating on the structure

Country Status (3)

Country Link
JP (2) JP7040880B2 (en)
CN (2) CN112126248A (en)
DE (1) DE102015112412A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107092046A (en) * 2017-04-26 2017-08-25 上海默奥光学薄膜器件有限公司 A kind of high reflective mirror of wide spectrum
CN111417522A (en) * 2017-09-29 2020-07-14 耐克创新有限合伙公司 Structurally colored articles and methods for making and using same
US11118062B2 (en) * 2017-12-06 2021-09-14 Toyota Motor Engineering & Manufacturing North America, Inc. LiDAR reflecting dark colored pigments and vehicles comprising the same
CN110543012B (en) * 2018-05-29 2022-05-17 北京以色佳科技有限公司 Design method of non-energy-consumption artificial intelligence filter with reflecting film and filter
CN115770711A (en) * 2022-11-30 2023-03-10 厦门凌太光学有限公司 Environment-friendly coating process for surface of spectacle lens

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5569535A (en) * 1979-12-28 1996-10-29 Flex Products, Inc. High chroma multilayer interference platelets
US5423912A (en) * 1993-10-21 1995-06-13 The Mearl Corporation Weather resistant pearlescent pigments
ATE168713T1 (en) * 1994-02-21 1998-08-15 Basf Ag MULTIPLE COATED METALLIC GLOSS PIGMENTS
DE4405492A1 (en) * 1994-02-21 1995-08-24 Basf Ag Metallic pigments with multiple coatings
DE19515988A1 (en) * 1995-05-02 1996-11-07 Basf Ag Goniochromatic gloss pigments with a coating containing metal sulfide
GB9619781D0 (en) * 1996-09-23 1996-11-06 Secr Defence Multi layer interference coatings
DE19707805A1 (en) * 1997-02-27 1998-09-03 Merck Patent Gmbh Multilayer interference pigment with an absorbent middle layer
EP0984043A1 (en) * 1998-08-31 2000-03-08 Sicpa Holding S.A. Optically variable pigments providing a colour shift between two distinct colours, coating composition comprising the same, method for producing the same and substrate coated with the coating composition
US6157489A (en) * 1998-11-24 2000-12-05 Flex Products, Inc. Color shifting thin film pigments
DE19901612A1 (en) * 1999-01-19 2000-07-20 Merck Patent Gmbh Multilayer pearlescent pigments comprise a lamellar substrate with a high refractive index, a layer of a material with a low refractive index and a semitransparent metallic layer
JP2002080749A (en) * 2000-06-29 2002-03-19 Nittetsu Mining Co Ltd Film-coated powder, coating composition and coated article
US6686042B1 (en) * 2000-09-22 2004-02-03 Flex Products, Inc. Optically variable pigments and foils with enhanced color shifting properties
US6569529B1 (en) * 2000-10-10 2003-05-27 Flex Product, Inc. Titanium-containing interference pigments and foils with color shifting properties
US7604862B2 (en) * 2001-07-12 2009-10-20 Merck Patent Gesellschaft Mit Beschrankter Haftung Multilayer pigments based on glass flakes
US6749936B2 (en) * 2001-12-20 2004-06-15 Flex Products, Inc. Achromatic multilayer diffractive pigments and foils
DE10356357B4 (en) * 2003-11-28 2010-05-06 Von Ardenne Anlagentechnik Gmbh Heat-treatable solar and thermal insulation layer system and method for its production
DE102004037271A1 (en) * 2004-07-31 2006-03-23 Kronos International, Inc. Weathering stable titanium dioxide pigment and process for its preparation
DE102004041586A1 (en) * 2004-08-26 2006-03-02 Eckart Gmbh & Co. Kg Coated pearlescent pigments with SiO 2 and cerium oxide
DE102005050094A1 (en) * 2005-10-18 2007-04-19 Identif Gmbh Colored effect pigment with layer of discrete metal particles, process for its preparation and its use
US8951607B2 (en) * 2007-05-03 2015-02-10 Tronox, Llc Making co-precipitated mixed oxide-treated titanium dioxide pigments
US10690823B2 (en) * 2007-08-12 2020-06-23 Toyota Motor Corporation Omnidirectional structural color made from metal and dielectric layers
US10788608B2 (en) * 2007-08-12 2020-09-29 Toyota Jidosha Kabushiki Kaisha Non-color shifting multilayer structures
EP2212726A1 (en) * 2007-10-30 2010-08-04 3M Innovative Properties Company Multi-stack optical bandpass film with electro magnetic interference shielding for optical display filters
KR101821431B1 (en) * 2010-02-04 2018-01-23 바스프 에스이 Pigment compositions with improved sparkling effect
JP2013518946A (en) * 2010-02-04 2013-05-23 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング Effect pigment
US9508475B2 (en) * 2010-06-30 2016-11-29 Viavi Solutions Inc. Magnetic multilayer pigment flake and coating composition
WO2012141708A1 (en) * 2011-04-14 2012-10-18 Exatec Llc Organic resin laminate
US20140162520A1 (en) * 2011-08-05 2014-06-12 Construction Research & Technology Gmbh Water-proof coating system for reflecting solar radiation and water-borne coating for forming decorative and reflective layer in coating system
JP6276695B2 (en) * 2012-10-19 2018-02-07 日本化薬株式会社 Heat ray shielding sheet
WO2015153043A1 (en) * 2014-04-01 2015-10-08 Toyota Motor Engineering & Manufacturing North America, Inc. Non-color shifting multilayer structures

Similar Documents

Publication Publication Date Title
JP2016047917A5 (en)
JP2011132483A5 (en)
JP2017518529A5 (en)
EA200870318A1 (en) SUBSTRATE PROVIDED BY A LAYER PACKAGE WITH THERMAL PROPERTIES
JP2008100129A (en) Coating film forming method and coating film
JP2016048688A5 (en)
TR201906519T4 (en) Coated material with low dispersion coating with an absorbent layer designed for the desired bluish color at off-axis viewing angles.
EA200870317A1 (en) SUBSTRATE PROVIDED BY A LAYER PACKAGE WITH THERMAL PROPERTIES
RU2016104896A (en) METAL SHINING PIGMENTS BASED ON SUBSTRATE PLATES WITH THICKNESS FROM 1 nm TO 50 nm
JP7203790B2 (en) Multilayer structure without color shift and protective coating on the structure
JP6817407B2 (en) Omnidirectional high saturation red structural color with semiconductor absorber layer
JP7036886B2 (en) Durable hybrid omnidirectional structural color pigment for external coating
JP2010241976A5 (en)
EA201591834A1 (en) LOW-EMISSION AND SUNSHINE GLAZING
MY200383A (en) Substrate having a stack with thermal properties
EA201691007A1 (en) WINDOW GLASS CONTAINING A BASE COVERED BY A MULTILAYER SYSTEM CONTAINING A FUNCTIONAL LAYER BASED ON SILVER AND A THICK LOW BLOCKING LAYER FROM TiO
JP2014524955A5 (en)
CN107924004B (en) Reflective composite with painted aluminum substrate and silver reflective layer and method of making same
JP2006282886A5 (en)
JP6549525B2 (en) Omnidirectional high chroma red structural color with combination of semiconductor absorber layer and dielectric absorber layer
EA201790761A1 (en) SUBSTRATE EQUIPPED WITH THIN-LAYER SYSTEM WITH THERMAL PROPERTIES AND INTERMEDIATE SUPERSTEHIMMETRIC LAYER
JP2020535982A5 (en)
JP2014172399A5 (en)
WO2015077192A3 (en) Anti-powdering and anti-static polymer film for digital printing
EA201790760A1 (en) SUBSTRATE EQUIPPED WITH A THIN-LAYER SYSTEM WITH THERMAL PROPERTIES AND INTERMEDIATE SUBSTECHIOMETRIC LAYER