JP2016033266A - Sputtering device - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a sputtering device capable of optimizing an arrangement of a target and a substrate in film deposition with respect to a variety of targets.SOLUTION: A sputtering device 100 comprises a substrate holding table 131 having a mount surface where a substrate 130 is mounted, and a mask assembly 109A having an opening part 113 provided between a target 102 and the substrate holding table 131. The mask assembly 109A has a first shield part 110 and a second shield part 111 arranged in parallel with the substrate holding table 131, and the opening part 113 is formed between opposite sides of the first shield part 110 and second shield part 111, which are provided independently movably in a direction perpendicular to a long side of the target 102 and in a direction parallel with the mount surface or in a direction perpendicular to the mount surface.SELECTED DRAWING: Figure 3

Description

The present invention relates to a sputtering apparatus, and more particularly to an apparatus for forming a magnetic film.

A magnetic disk drive (HDD) includes a magnetic disk medium having a high coercivity polycrystalline magnetic film and a magnetic head. The magnetic head has a magnetoresistive reading unit and a high magnetic moment writing unit, and writes data to a magnetic disk medium and reads data recorded on the disk medium.

The writing portion is made of a relatively thick magnetic film with a finely processed pattern. An Fe—Co alloy having a high saturation magnetization (magnetic moment) is used for the magnetic film of the writing portion.

The magnetic head element used in the HDD is manufactured on an Al ₂ O ₃ —TiC wafer substrate having a diameter of 5 to 8 inches. Tens of thousands of magnetic head elements can be obtained from one wafer. Therefore, in order to ensure a high yield, it is very important that the entire wafer has a uniform and low skew. Here, the low skew means that there is little dispersion of the easy magnetization axis of the element in a predetermined direction, that is, the easy magnetization axes are aligned.

The reading section is generally composed of a multilayer film having a very thin film thickness. The multilayer film is made of, for example, Fe—Co—B and Ni—Fe soft magnetic alloy separated by a nonmagnetic spacer layer such as Cu or MgO. As in the writing unit, in the reading unit, it is preferable that the easy axis of the element is oriented in a predetermined direction. Since the heat treatment temperature in the heat treatment process after film formation is relatively low (<300 ° C), especially Fe
In the case of the -Co film, it is preferable to orient the easy magnetization axis during film formation in both the reading part and the writing part.

In general, the easy axis is oriented by applying an external magnetic field while forming the film. This external magnetic field promotes pair-ordering magnetic anisotropy. Therefore, in the sputtering process, a magnetic field parallel to the substrate surface is applied to the substrate using an independent magnetic field generation source. This magnetic field may have a slight vertical component with respect to the substrate surface, but is preferably substantially in-plane. For example, when the film incidence angle is substantially perpendicular to the substrate surface, a magnetic field is not applied to the substrate, and Fe-Co rich in Fe is formed, the easy axis of magnetization in the substrate surface is isotropic. The coercivity in any direction on the film surface is essentially constant.

Uniaxial magnetic anisotropy is induced by applying an external magnetic field during film formation. For example, the coercivity can be> 25 Oe (easy axis of magnetization) with respect to the magnetic field application direction and <1 Oe (hard axis of magnetization) with respect to the perpendicular direction. In a sputtering apparatus, it is very difficult to apply a parallel magnetic field to a substrate due to interference of a leakage magnetic field of a circular or rotating cathode magnetron. In addition, the parallel magnetic field applied to the substrate adversely affects the uniformity of the film. If the distance between the substrate and the target is increased, the uniformity of the film can be improved, but the deposition rate is greatly limited.

The oblique incidence film formation method is known to be effective for improving the uniaxial magnetic anisotropy of the Fe—Co film.
In permalloy (Ni ₈₁ Fe ₁₉ ) and high saturation magnetization Ms (for example, Fe ₇₀ Co ₃₀ film) which are important in application, the easy axis of magnetization changes by 90 ° when the incident angle of film formation is 45 °. When the incident angle is less than 45 °, the induced easy axis is in the same plane as the incident angle. Here, the incident angle is defined as an angle formed between the normal axis of the substrate and the direction in which the sputtered particles enter. Incident angle is 45 °
Is greater, the easy axis is oriented transversely or perpendicular to the plane of incidence. In the oblique incidence film formation method, a film having a considerably high magnetic anisotropy is compared with a method (film application method) in which an incident angle is close to the normal axis while applying a magnetic field to the substrate side. can get. This is Co, Fe
This applies to various material compositions with high coercivity such as Ni-Fe, Fe-Co, and Fe-Co-B. In particular, a very large magnetic anisotropy is obtained at an incident angle of 70 ° to 80 °. The induced magnetic anisotropy is due to stress or shape magnetic anisotropy due to the shadow effect of film formation. However, since the density of the film formed by oblique incidence decreases, the saturation magnetization density also decreases. When high saturation magnetization density is required, only film formation with a low incident angle can be applied.

By using a relatively thick seed layer (˜5 nm) formed by oblique incidence film formation as an underlayer, a high Hk can be given to the magnetic film formed on the seed layer. By doing so, a magnetic film having a high Hk can be formed at a high density. Further, even when a magnetic film is formed at a small incident angle that maintains the saturation magnetization density (for example, a Fe ₇₀ Co ₃₀ film is formed at <40 °), a high Hk is obtained compared to the magnetic field application film formation. . Therefore, oblique incidence film formation is high Hk
As a method for forming a write magnetic pole film having

If 2.4T saturation magnetization is required, such as the reading section of a magnetic head element, high incidence angle deposition may be used to obtain high Hk. On the high angle side, the dependence of Hk on the incident angle is large. Therefore, in order to obtain the uniformity of the magnetic characteristics in the large-diameter substrate, it is necessary to control the incident angle and the incident angle distribution.

The oblique incidence film formation is also effective for applications that require magnetic anisotropy due to stress. For example, by making a cut in a non-magnetic film having a large compressive stress, the stress of the magnetic film in the reading portion of the magnetic head is changed from isotropic to an anisotropic compressive stress in a direction perpendicular to the cut, and the magnetic A technique for improving the magnetic anisotropy of the film is used. This stress magnetic anisotropy can be improved by forming a film having a compressive stress at oblique incidence.

The Fe—Co film exhibits a larger coercive force Hc on the easy axis than the Ni—Fe film. Furthermore, in an Fe-Co alloy having a high saturation magnetization and a high Fe content, which is important for applications, the magnetic anisotropy (and the coercivity of the easy axis of magnetization) improves as the film thickness increases. This is mainly because the crystal grain size increases as the film thickness increases. The magnetic film is thin at the reading part of the magnetic head element (<5 n
m) In the writing area, the film thickness may be greater than 200 nm. Therefore, for film formation of the reading part,
A method of forming a seed layer capable of relaxing the growth of the particle size and reducing the mobility of adsorbed atoms is desirable.
It is also known that Cu, Ni-Fe and Ru seed layers are effective for reducing the grain size of Fe-Co films. Substrate cooling is also considered effective in order to suppress the increase in grain size accompanying the increase in film thickness.

Patent Document 1 discloses a method and an apparatus for forming a magnetic film under a fixed magnetic field applied to a substrate. In a large rectangular target and a small circular substrate, the leakage magnetic field of the cathode magnet is far away from the substrate, so that it does not interfere with the magnetic field on the substrate side. The leakage magnetic field of the cathode magnet in the vicinity of the substrate is substantially parallel to the magnetic field generated by the magnetic field source on the substrate side. The substrate is transported parallel to the substrate magnetic field and perpendicular to the long side of the target, and processed under the target. All portions of the linear transport method that are parallel to the length of the target on the passing substrate surface receive the same flux of incident sputtered particles. Excellent film thickness uniformity along the transport direction is expected. And for a sufficiently long target, this arrangement also results in a film having good lateral uniformity and low skew values. Very high film formation rates are feasible, and low film formation rates can be achieved by increasing the substrate transport speed.

Patent Document 1 discloses the advantage of a method of linearly extruding a substrate in a direction perpendicular to the long side of a rectangular target. By moving the substrate along the flux of sputtered particles from the target, the uniformity of the moving direction is ensured. Transverse uniformity is achieved by fully utilizing long targets. The normal erosion pattern for long targets is
An elongated track is formed. For erosion formed long and parallel, the sputtering rate is
It is relatively uniform. For a circular substrate arranged symmetrically under the target, the film formation rate at the center is the highest. Typically, in order to achieve a certain film thickness uniformity of 1σ <5% at a distance of 200 mm diameter substrate and 100-200 mm target to substrate, the target must be at least twice the substrate size. I must.

Patent Document 2 discloses a grazing incidence film forming method using a rotating target, a substrate stage, and a drum shutter. Magnetic anisotropy is achieved by oblique incidence, and the low skew value is
This is achieved without using a magnetic field parallel to the substrate. The film forming method disclosed in Patent Document 2 rotates a rectangular target that is rotatably held around a first rotation axis and a second rotation axis that is arranged in parallel with the first rotation axis. A film forming method using a sputtering apparatus, comprising: a substrate rotatably held at a center; and a shielding plate disposed between the target and the substrate and rotatable about the first rotation shaft or the second rotation shaft. It is. During film formation, the substrate and the shielding plate are rotated. Sputtered particles reach a part of the substrate from the gap between the shielding plates, and are deposited on the substrate.

When film formation is completed up to half the thickness of the film to be formed, the second rotating shaft is rotated while the substrate is rotated 180 ° about the third rotating shaft perpendicular to the second rotating shaft. The film is formed while rotating in the opposite direction around the center. This film forming method can further improve the film thickness uniformity as compared with the case where the film is formed in a single direction. The film thickness uniformity can be further improved by controlling the rotational angular velocity of the target and the substrate and the position of the shielding plate during the film formation.

JP 2005-526179 Gazette Japanese Patent No. 4352104

However, Patent Document 1 does not utilize the high induced magnetic anisotropy by the oblique incidence sputtering method. Control of the sputter incident angle and distribution has not been solved.

Further, Patent Document 2 has a problem that the nonuniformity of Hk is still large because the distance between the target erosion portion and the film formation region on the substrate changes during film formation. Since the substrate stage rotates, the distance between the region of the substrate to be deposited and the opening of the shutter is not constant. That is, the film formation arrangement can be changed everywhere on the substrate. If the shutter opening is fixed, it becomes difficult to control the uniformity of the horizontal axis. The optimum shape of the opening depends on the target material as well as process conditions such as gas pressure and cathode power.

Therefore, in order to control the magnetic anisotropy of the magnetic film, the present invention optimizes the arrangement of the target and the substrate during the film formation when forming at various incident angles and when using various targets. Another object of the present invention is to provide a sputtering apparatus capable of obtaining Hk uniformity, low skew value, and film thickness uniformity.

The present invention provides a sputtering apparatus for forming a magnetic layer on a substrate, a target holding unit that is provided in a vacuum vessel and holds a target having a rectangular surface, and a magnet unit that is disposed on the back surface of the target holding unit. A substrate holder having a mounting surface on which the substrate is mounted;
A mask assembly having an opening provided between the target and the substrate holder;
And a moving mechanism for moving the substrate holding base and the target holding portion relative to each other in parallel with the placement surface, wherein the mask assembly is arranged substantially parallel to the placement surface.
The first and second shielding portions include a shielding portion and a second shielding portion, and the opening is formed between opposing sides of the first shielding portion and the second shielding portion. It is provided so as to be independently movable in a direction substantially perpendicular to the long side of the target and parallel to the placement surface, or in a direction substantially perpendicular to the placement surface.

According to the present invention, in order to control the magnetic anisotropy of the magnetic film, when the film is formed at various incident angles, the arrangement of the target and the substrate during the film formation is optimized even for various targets. A sputtering apparatus capable of obtaining uniformity, a low skew value, and film thickness uniformity can be provided.

It is a top view which shows the structure of the magnetic writing part in the magnetic head of a hard-disk drive. It is a top view which shows the structure of the reading part in the magnetic head of a hard-disk drive. It is a longitudinal section showing the whole sputtering device composition concerning a 1st embodiment of the present invention. It is a perspective view which shows the structure of the mask assembly which concerns on 2nd Embodiment of this invention. It is a longitudinal cross-sectional view which shows the operation | movement procedure (1) of the mask assembly which concerns on 2nd Embodiment of this invention. It is a longitudinal cross-sectional view which shows the operation | movement procedure (2) of the mask assembly which concerns on 2nd Embodiment of this invention. It is a perspective view which shows the modification of the mask assembly which concerns on 2nd Embodiment of this invention. It is a front view which shows the target surface used by the simulation in the modification of the mask assembly which concerns on 2nd Embodiment of this invention. It is a schematic diagram which shows the positional relationship of the target used in simulation in the modification of the mask assembly which concerns on 2nd Embodiment of this invention, a mask assembly, and a board | substrate. It is a film thickness pattern which shows the simulation result (1) in the modification of the mask assembly which concerns on 2nd Embodiment of this invention. It is a film thickness pattern which shows the simulation result (2) in the modification of the mask assembly which concerns on 2nd Embodiment of this invention. It is a perspective view which shows another modification of the mask assembly which concerns on 2nd Embodiment of this invention. It is a longitudinal cross-sectional view which shows the whole structure of the sputtering device which concerns on 3rd Embodiment of this invention. It is a longitudinal cross-sectional view which shows the whole structure of the sputtering device which concerns on 4th Embodiment of this invention. It is a longitudinal cross-sectional view which shows the whole structure of the sputtering device which concerns on 5th Embodiment of this invention. It is a longitudinal cross-sectional view which shows the whole structure of the sputtering device which concerns on 6th Embodiment of this invention. It is a longitudinal cross-sectional view which shows the whole structure of the modification of the sputtering device which concerns on 6th Embodiment of this invention.

  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

(1) Magnetic Head First, the configuration of a magnetic head of a hard disk drive (HDD) will be described as an application example of a magnetic layer formed by a sputtering apparatus according to the present invention. As shown in FIG.
The magnetic writing unit 10 has a magnetic writing magnetic pole 11 surrounded by a side magnetic shield 15. The magnetic write pole 11 includes a seed layer 11a, a first layer 11b, a spacer layer 11c, and a second layer 11d. The first layer 11b and the second layer 11d are usually made of a cobalt iron (Fe—Co) film having a high saturation magnetization Ms. The seed layer 11a is made of permalloy. The spacer layer 11c is made of permalloy or Ru.

The magnetic write magnetic pole 11 extends from the upper part 15 a of the side magnetic shield 15 to the nonmagnetic spacer 12.
Separated by. The upper portion 15a is called a trailing shield when the magnetic head moves downward with respect to the recording medium. The trailing shield reduces the overall magnetic field from the magnetic write pole 11 but increases the magnetic field gradient of the magnetic disk medium. This is important for improving the recording density and reducing the bit modulation width and the boundary between magnetic bits on the magnetic disk medium.

The side magnetic shields 15 on both sides of the magnetic write pole 11 are separated from the magnetic write pole 11 by nonmagnetic spacers 13.

As shown in FIG. 2, the reading unit 20 includes a hard bias 31, a lower shield 29 a usually made of permalloy, and a magnetoresistive sensor 21 sandwiched between the upper shield 29 b. The hard bias 31 includes a seed layer 31a and a magnetoresistive sensor 21.
A ferromagnetic layer 31b and a cap layer 31c having a high saturation coercive force for providing a transverse field are provided.

The insulating layer 30 electrically isolates the magnetoresistive sensor 21 from the hard bias 31. The magnetoresistive sensor 21 normally includes an antiferromagnetic layer 22, a magnetic pinned layer 23, a spacer layer 24, a magnetic reference layer 25, an insulating tunnel barrier layer 26, a magnetization free layer 27, and a cap layer 28.

The moment of the magnetic reference layer 25 is transmitted through the spacer layer 24 to the magnetic pinned layer 23.
And antiferromagnetic coupling. The moment of the magnetic pinned layer 23 is pinned by the antiferromagnetic layer 22.

In some designs, there is no antiferromagnetic layer 22 and the moment of the magnetic pinned layer 23 is
It is arranged vertically on the opposite surface (ABS: Air Bearing Surface) by anisotropic stress. The moments of the magnetic pinned layer 23 and the magnetic reference layer 25 are substantially perpendicular to the opposing surface, but the moment of the magnetization free layer 27 is biased in the transverse direction by the magnetic field from the ferromagnetic layer 31b.

A detection current flows through the magnetoresistive sensor 21 through the upper shield 29b and the lower shield 29a. Due to the magnetic field from the bit on the magnetic disk medium, the moment of the magnetization free layer 27 rotates perpendicular to the ABS, resulting in a resistance change of the magnetoresistive sensor 21 and recorded as a voltage fluctuation.

The magnetic writing magnetic pole 11 is generally formed by electroplating or sputtering.
On the other hand, the magnetoresistive sensor 21 is deposited by sputtering.

(2) First Embodiment Next, a sputtering apparatus according to the first embodiment of the present invention will be described. As shown in FIG. 3, the sputtering apparatus 100 includes a target 102 as a cathode part and a target holding part (metal backing plate) 104 in a vacuum container 101, and a magnet unit 103 provided on the back surface of the target holding part 104. And a substrate holder 131 having a substrate placement surface 131a.

A process gas necessary for sputtering film formation is supplied to the vacuum vessel 101 from the outside through a process gas inlet 124. The vacuum vessel 101 is provided with a vacuum pump 122 for exhausting the process gas and the impurity gas flowing in from the external space. Further, the vacuum vessel 101 is provided with an introduction port 120 for carrying the substrate 130 into and out of the vacuum vessel 101.

Although not shown, the target 102 is supplied with power necessary for sputtering from the power supply line through the target holding unit 104. The power supply line is connected to a high frequency power source and a direct current power source (not shown). As a result, power supply of only high frequency is supplied to the target 102,
Either power supply by high frequency + DC superimposition or power supply only by DC power is possible. Further, the target 102 has a rectangular shape, and its long side is arranged in a direction perpendicular to the paper surface of this figure. The long side of the target 102 is formed longer than the diameter of the substrate 130. In order to ensure the uniformity of the film thickness on the horizontal axis, the long side of the target 102 has a substrate diameter of 2
It is desirable to form it twice or longer.

The practical target 102 length is limited by the manufacturing cost. With the limited target 102 length, the horizontal axis uniformity of the film characteristics is 1) the target 102 is reduced to the film formation region, and 2) the length of the target 102 as disclosed in JP-A-60-197869. It can be improved by extending the direction along the direction and providing slits that are wider at both ends than the central portion. 3) Increasing the magnetron intensity near the edge, or conversely decreasing the magnetron intensity at the center of the target 102.

When a high sputtering power is required to form a particularly thick film, the target holding unit 104 is desirably provided with a pipe (not shown) through which cooling water for effectively cooling the target 102 flows.

The substrate holder 131 is connected to the moving mechanism 132, and the moving mechanism 132 causes the y
It is provided so as to be linearly movable along the axial direction. In this case, the y-axis direction is the substrate surface 1
It is parallel to 30 a and is perpendicular to the long side of the target 102. The distance from the substrate placement surface 131a of the substrate holder 131 to the center of the target 102 is 150 m.
m or less.

The sputtering apparatus 100 according to this embodiment includes the characteristic configuration of the present invention in addition to the above basic configuration. The characteristic configuration will be described below. In the sputtering apparatus 100, a mask assembly 109 </ b> A is provided between the target 102 and the substrate 130.

The mask assembly 109 </ b> A includes a first shielding part 110 and a second shielding part 111 that are arranged in parallel to the substrate placement surface 131 a of the substrate holding table 131. The first shielding portion 110 and the second shielding portion 111 face the substrate surface 1 in a state where the edges are opposed to each other and a gap (200 mm or less) in width D1 is opened.
It is parallel to 30 a and is arranged in the direction perpendicular to the long side of the target 102. In addition,
The first shielding part 110 and the second shielding part 111 of the mask assembly 109A are made of a metal such as Ti or Al. However, the present invention is not limited to this, and the mask assembly 10
9A may be formed of, for example, alumina, glass, ceramic, dielectric, or the like to have a floating potential. Thereby, it is possible to prevent the plasma near the target 102 from being diffused to the ground.
An opening 113 having a width D1 along the y-axis direction is formed in a region sandwiched between the opposing edges of the first shielding part 110 and the second shielding part 111. The first shielding part 110 and the second shielding part 111 are independent of each other in the y-axis direction (parallel to the substrate surface 130a placed on the substrate holding base 131 and perpendicular to the long side of the target 102). And is provided so as to be movable. The mask assembly 109 </ b> A can change the position and width D <b> 1 of the opening 113 by appropriately moving the first shielding part 110 and the second shielding part 111.

That is, the first shielding part 110 can increase or decrease the width D1 of the opening 113 by moving along the y-axis direction with the second shielding part 111 fixed. Similarly, the second shielding part 111 can increase or decrease the width D1 of the opening 113 by moving along the y-axis direction with the first shielding part 110 fixed. In addition, by simultaneously moving the first shielding unit 110 and the second shielding unit 111 in the same direction by the same distance, the position of the opening 113 is kept on the first shielding unit 110 side or the first side while maintaining the width D1 of the opening 113. 2 It can move to the shielding part 111 side.

In the present invention, it is necessary to perform film formation at various incident angles in order to control the magnetic anisotropy of the magnetic film. In that case, it is necessary to increase or decrease the width D1 of the opening 113 in accordance with various incident angles.

Further, the target 102 is arranged such that a plane parallel to the long side of the target 102 including the normal 150 passing through the center of the target surface 102a does not overlap the normal passing through the center of the opening 113 of the mask assembly 109A. ing.

In the case of the present embodiment, the target 102 is arranged such that a normal line 150 passing through the center of the target surface 102a is inclined by a predetermined angle 151 with respect to a normal line passing through the center of the opening 113 of the mask assembly 109A. . The target 102 is disposed obliquely so as to have a downward gradient from the first shielding part 110 side toward the second shielding part 111 side. This
The surface 102a of the target 102 is diagonally opposed to the substrate surface 130a through the opening 113 of the mask assembly 109A.

In the vicinity of the target 102 between the target 102 and the substrate 130, the third
A shielding part 105 is provided. The third shielding part 105 is provided in the vacuum container so as to be rotatable around a rotation shaft 118 along the x-axis direction. The third shielding part 105 has a rotation direction of 10
By rotating along 5 a, the target 102 is arranged so as to cover a part of the target surface 102 a on the first shielding part 110 side.

As described above, the target 102 is disposed obliquely so as to have a predetermined angle 153 with respect to the normal passing through the center of the opening 113 of the mask assembly 109A. Therefore, the sputtered particles emitted perpendicularly from the target surface 102a. Is obliquely incident on the normal axis 152 of the substrate 130.

In the sputtering apparatus 100 configured as described above, the first shielding part 110 and the second shielding part 111 are appropriately moved in order to set the width D1 and the position of the opening 113 of the mask assembly 109A in accordance with the film forming conditions. Let At the same time, the third shield 105 is rotated according to whether or not the surface of the target 102 on the first shield 110 side is used. Therefore, according to the sputtering apparatus 100, the target 10 during film formation also in various targets.
2 and the arrangement of the substrate 130 can be optimized.

For example, in the case of film forming conditions where the incident angle is large, the third shielding unit 105 is arranged in a state where the surface is rotated substantially parallel to the target surface 102a as shown in the figure. By disposing the third shielding part 105 in this way, it is possible to shield sputtered particles that enter the target surface 102a from the first shielding part 110 side in a substantially direct downward direction. Accordingly, since the sputtered particles are incident on the substrate 130 only from the target surface 102a on the second shielding part 111 side of the target 102 through the opening 113, the incident angle is determined by arranging the opening 113 on the first shielding part 110 side. Only large sputtered particles can be incident on the substrate 130.

On the other hand, in the case of film formation conditions with a small incident angle, it is preferable that the third shielding unit 105 is rotated along the rotation direction 105a and the surface thereof is arranged substantially perpendicular to the target surface 102a in order to further increase the film formation rate. . By arranging the third shielding part 105 in this way, the first shielding part 110 is arranged.
Sputtered particles can also be incident in a direction substantially directly below the target surface 102a on the side. Therefore, since sputtered particles can be incident on the substrate 130 from a wider range of the target surface 102a, the deposition rate can be further increased.

In order to obtain a predetermined incident angle as described above, the sputtering apparatus 100 has the first shielding part 11.
After the arrangement of 0, the second shielding part 111 and the third shielding part 105 is determined, the film formation is started. At this time, the substrate holder 131 moves the substrate 130 at a constant speed along the y-axis direction. Thereby, the sputtering apparatus 100 can form a film on the entire surface of the substrate 130 under the same film formation conditions with the same incident angle and the distance until the sputtered particles emitted from the target surface 102a reach the substrate surface 130a. Therefore, a magnetic film having improved magnetic anisotropy and low skew can be obtained.

(3) Second Embodiment Next, a sputtering apparatus according to a second embodiment will be described. The sputtering apparatus according to this embodiment differs from the first embodiment only in the configuration of the mask assembly.
Hereinafter, only the configuration of the mask assembly will be described.

As shown in FIG. 4, the mask assembly 109 </ b> B according to this embodiment includes a first shielding part 140.
And the second shielding part 141, and are arranged in a state where the edges are opposed to each other with a gap of the width D1 therebetween.

The first shielding part 140 has a main shielding part 142 and a central shielding part 143. Main shield 142
Is coupled to the drive unit 142a and is provided to be movable along the y-axis direction. The central shielding part 143 is formed so that the length in the x-axis direction is shorter than the main shielding part.
2 is arranged at a position that can be opposed to the center of the upper surface side of 2, that is, the center portion of the substrate 130 placed on the substrate holding table (not shown in the figure). The central shielding part 143 is connected to the driving part 143a, and is provided to be movable along the y-axis direction independently of the main shielding part 142.

Similarly, the second shielding part 141 includes a main shielding part 145 and a central shielding part 146. The main shielding part 145 is connected to the driving part 145a and is provided to be movable along the y-axis direction. The central shielding part 146 is formed so that the length in the x-axis direction is shorter than the main shielding part 145, and is arranged at the center on the upper surface side of the main shielding part 145. The central shielding part 146 is a driving part 146.
It is connected to a and provided so as to be movable along the y-axis direction independently of the main shielding part 145.

As described above, the mask assembly 109B can change the position and width D1 of the opening 113 by appropriately moving the main shielding portions 142 and 145 of the first shielding portion 140 and the second shielding portion 141. The same effect as the embodiment can be obtained.

Further, the mask assembly 109B according to the present embodiment can shorten the width of only the central portion of the opening 113 by appropriately moving the central shielding portions 143 and 146.
Decreasing the film formation rate at the central portion of the substrate 130 to prevent the central film thickness along the x-axis direction of the substrate 130 from becoming thicker than both end portions of the substrate 130 along the x-axis direction. it can.

For example, in the case of a film forming condition with a small incident angle, as shown in FIG. 5, the first shielding part 140 and the main shielding parts 142 and 145 of the second shielding part 141 are arranged on the second shielding part 141 side. At this time, it is preferable that the third shielding part 105 is rotated along the rotation direction 105a and the surface thereof is arranged substantially perpendicular to the target surface 102a. As a result, the opening 113 is arranged on the second shielding part 141 side, and the trajectory of the sputtered particles emitted from a predetermined position on the target surface 102a is, as shown in the figure, the first shielding part 140 on the target surface 102a. The range 50 a to 50 b that is incident on the substrate 130 from the side through the opening 113 is limited. Further, the first shielding part 140
By arranging the central shielding portion 143 so as to protrude from the edge portion of the main shielding portion 142, the width of only the central portion of the opening 113 can be reduced. Thereby, it is possible to prevent the thin film formed in the central portion of the substrate 130 from becoming thick, and to improve the non-uniformity of the film thickness in the entire substrate 130. Moreover, it can restrict | limit that the sputtered particle which has the incident angle exceeding the locus | trajectory 50a injects into the board | substrate 130 by this.

On the other hand, in the case of the film forming condition where the incident angle is large, as shown in FIG.
The main shielding parts 142 and 145 of the shielding part 141 are arranged on the first shielding part 140 side. At this time third
The shielding part 105 is arranged in a state where the surface is rotated substantially parallel to the target surface 102a. As a result, the opening 113 is arranged on the first shielding part 140 side and the target surface 102a on the first shielding part 140 side is covered with the third shielding part 105, so that the sputter emitted from a predetermined position on the target surface 102a. The trajectory of the particles is the target surface 10 as shown in the figure.
2a, the range 50a to enter the substrate 130 from the second shielding portion 141 side through the opening 113
Limited to 50b.

Therefore, only sputtered particles having a large incident angle can be incident on the substrate 130. Furthermore, by arranging the central shielding part 146 of the second shielding part 141 so as to protrude from the edge of the main shielding part 145, the width of only the central part of the opening 113 can be reduced, so that the above-described film The effect of reducing thickness non-uniformity can be obtained. The second shielding part 1
By arranging the 41 central shielding portions 146 so as to protrude from the edge of the main shielding portion 145, it is possible to limit the incidence of sputtered particles having an incident angle smaller than the locus 50 b on the substrate 130.

(Modification)
Next, a modification of the mask assembly according to the second embodiment will be described. The mask assembly 109C shown in FIG. 7 has a first shielding part 160 and a second shielding part 161, and is arranged in a state where the edges are opposed to each other and a gap of the width D1 is opened.

The first shielding part 160 includes a pair of main shielding parts 162a and 162b arranged on the same plane,
And a central shielding portion 163 disposed between the pair of main shielding portions 162a and 162b.
The pair of main shielding parts 162a and 162b are connected to a driving part (not shown) and are provided so as to be integrally movable. The central shielding part 163 is connected to a drive part (not shown), and is provided so as to be movable along the y-axis direction independently of the main shielding parts 162a and 162b.

Similarly, the second shielding part 161 is a pair of main shielding parts 165a, 16 arranged on the same plane.
5b and a central shielding part 166 disposed between the pair of main shielding parts 165a and 165b. The pair of main shielding portions 165a and 165b is connected to a driving portion (not shown) and is provided so as to be movable integrally. The central shielding part 166 is connected to a drive part (not shown), and is provided to be movable along the y-axis direction independently of the main shielding parts 165a and 165b.

According to the mask assembly 109 </ b> C according to the present modification configured as described above, only the central shielding portions 163 and 166 are appropriately moved, so that only the width D <b> 2 of the central portion of the opening 113 is obtained.
Can be changed. As described above, since the opening width D2 of only the central portion of the opening 113 can be changed, the same effect as that of the second embodiment can be obtained.

In the case of this modification, the central shielding parts 163 and 166 are arranged between the pair of main shielding parts 162a and 162b and 165a and 165b along the x-axis direction, so that the mask assembly is compared with the second embodiment. Can be reduced in thickness.

In the second embodiment and the present modification, the opposite edge portions of the central shielding portions 163 and 166 are illustrated as being linear, but the present invention is not limited to this and protrudes in a curved shape. It may be formed.

(simulation)
Next, simulation using the mask assembly according to this modification as a model will be described. FIG. 8 shows an erosion pattern of the target 102 used for simulating the film thickness characteristic. The target 102 has a width 102d (130 mm) and a length 102e (
510 mm). The erosion pattern by the prescribed magnet unit is drawn on the target surface 102a.

In order to obtain a film forming condition with a large incident angle, the sputtered particles from the range surrounded by the broken line in the drawing of the target surface 102a were set to be incident on the substrate 130. The above range is
A long linear groove 102b is formed below the center 102c of the target 102.

FIG. 9 shows the positional relationship between the substrate 130 and the mask assembly 109C. In the mask assembly 109C, the width D1 of the opening 113 is set to 20 mm. The target 102 was set such that the target surface 102a was at an angle of 30 ° with respect to the substrate surface 130a and the distance L3 from the target 102 to the substrate surface 130a was 150 mm.

In the mask assembly 109C, the distance L1 from the substrate surface 130a was set to 27 mm, and the thickness was ignored in this simulation. The opening 113 was set at a position where the distance L2 from the center of the opening 113 to the center of the target 102 was 127 mm.

The third shielding part 105 shields the sputtered particles from the first shielding part 160 side of the target surface 102a and allows the sputtered particles from the target surface 102a on the second shielding part 161 side to pass. The incident angle of the sputtered particles from the target surface 102a on the second shielding part 161 side is 50 ° on average.

During film formation, the substrate 130 moves below the opening 113 along the y-axis direction parallel to the substrate surface 130a. Rate of sputtered particles, and a _{^{cos n φ-n 2 exp (}} -φ 2/1000). φ is an angle from the normal line of the target surface 102a, and n = 0.75 and n ₂ = 0.5.

FIG. 10 is a film thickness pattern on the substrate surface 130a obtained by simulation. As shown in FIG. 10, the dim region shows a state where the film thickness is thicker than the bright region. As a result of this simulation, the film thickness non-uniformity was 10.2%. The dim region mainly exists in the intermediate region of the horizontal axis of the substrate, and the width D3 is about 120 mm.

Next, the simulation was performed in a state where the central shielding portion 166 of the second shielding portion 161 protrudes 1 mm into the opening 113. As a result, as shown in FIG.
It was confirmed that it was reduced to 2%. Moreover, the film thickness of the outer peripheral part has increased compared with the central part.

Although the case where the tip of the central shielding part 166 of the second shielding part 161 is linear is examined,
It is considered that the film thickness non-uniformity can be further reduced by making the tip protrude in a curved shape.

(Another modification)
Next, another modified example of the mask assembly according to the second embodiment will be described. FIG.
A mask assembly 109D shown in FIG. 2 has a first shielding part 170, a second shielding part 171 and a central shielding part 172. The 1st shielding part 170 is connected with the drive part 170a, and is provided so that a movement along the y-axis direction is possible. Similarly, the 2nd shielding part 171 is connected with drive part 171a, and is provided so that movement along the y-axis direction is possible. The first shielding part 170 and the second shielding part 171 are arranged in a state where the leading edges 170c and 171c are opposed to each other with a gap of a width D1 therebetween.

The central shielding part 172 is composed of a plate-like member having a hole 175 penetrating in the thickness direction at the center, and is disposed on the upper surface side of the first shielding part 170 and the second shielding part 171. The central shielding part 172 is connected to the driving part 172a, and is provided to be movable independently of the first shielding part 170 and the second shielding part 171 along the y-axis direction.

The hole 175 is substantially H-shaped in plan view. Projections 172c and 172d are formed at substantially the center of the inner periphery of the hole 175 in the x-axis direction.

According to the mask assembly 109 </ b> D configured as described above, the position and width D <b> 1 of the opening 113 can be changed by appropriately moving the first shielding portion 170 and the second shielding portion 171, and the central shielding portion 172. Only the central portion of the opening 113 can be changed by appropriately moving only the central portion. Thereby, the effect similar to the said 2nd Embodiment can be acquired.

(4) Third Embodiment Next, a sputtering apparatus according to a third embodiment of the present invention will be described. The same components as those in the first embodiment are denoted by the same reference numerals, and description thereof is omitted.

A sputtering apparatus 200 shown in FIG. 13 has a first cathode portion 261 in a vacuum vessel 201.
And a second cathode portion 262 and a substrate holding base 231. First cathode portion 261
Are the first target 202, the target holding unit 204, and the target holding unit 20.
4 and a magnet unit 203 provided on the back surface. Similarly, the second cathode portion 262 is
It has the 2nd target 205, the target holding | maintenance part 207, and the magnet unit 206 provided in the back surface of the said target holding | maintenance part 207. The first target 202 and the second target 205 may be formed of the same material or different materials.

The first target 202 and the second target 205 are supplied with power necessary for sputtering from the power supply line through the target holding units 204 and 207 (not shown). Although not shown, the power supply line is connected to a high frequency power source and / or a DC power source. As a result, the first target 202 and the second target 205 can be supplied with only high frequency power, supplied with high frequency + DC superposition, or supplied only with DC power. Further, the first target 202 and the second target 205 have a rectangular shape, and the long sides are arranged in a direction perpendicular to the paper surface of this figure. The long sides of the first target 202 and the second target 205 are
It is formed longer than the diameter of the substrate 130.

The substrate holding table 231 is installed on the substrate cooling table 238 and is provided so as to be movable along the y-axis direction by the moving mechanism 239. The substrate cooling table 238 includes a cryogenic head 232 and a cryopump 233. The cryogenic head 232 and the cryopump 233 communicate with each other through a cooling gas passage 234. The cooling gas passage 234 communicates with a cooling gas supply pipe (not shown) that supplies the cooling gas for cooling the substrate holding table 231 and cooling the gas molecules in the vacuum vessel 201. The cooling gas supply pipe is disposed in the internal space 223 a of the bellows (expandable pipe) 225.

The bellows 225 communicates with the external space 123 and is configured to expand and contract in accordance with the movement of the substrate cooling table 238. The cooling gas supply pipe has a bellows 2 so that it can be flexed smoothly from the length when the bellows 225 is extended to the length when the bellows 225 is contracted.
25.

A cooling gas supplied from a cooling gas supply pipe (not shown) is supplied to the substrate holding table 231 to cool the substrate holding table 231. As a result, the cryopump 233 sets the substrate holding table 231 to a very low temperature, thereby condensing or adsorbing gas molecules in the vacuum vessel 201 to capture and evacuate the vacuum vessel 201 into an ultra-vacuum and hold the substrate. The substrate 130 on the table 231 is also cooled.

The moving mechanism 239 includes a driving unit 241 a provided on the floor surface of the vacuum vessel 201, a worm 242 extending along the y-axis direction, a linear moving unit 241 screwed into the worm 242, A carriage 240 connected to the moving part 241 and a guide rail 243 extending in parallel with the worm 242 are included. The worm 242 is connected to the drive unit 241a. Dolly 240
Includes a wheel 240a, and a substrate holding table 231 and a substrate cooling table 238 are placed thereon. The wheel 240 a is formed so as to be able to travel along the guide rail 243.

The drive unit 241a transmits the rotational force to the worm 242. The linear motion portion 241 screwed into the worm 242 moves linearly along the worm 242 by the rotation of the worm 242. Due to the linear motion of the linear motion portion 241, the carriage 240 connected to the linear motion portion 241 moves along the guide rail 243. In this way, the moving mechanism 239 can move the substrate holding table 231 disposed on the carriage 240 along the y-axis direction.

A mask assembly 209 disposed between the first target 202 and the second target 205 and the substrate 130 includes a first shielding unit 210 and a second shielding unit disposed in parallel to the substrate placement surface of the substrate holding table 231. 211. The first shielding part 210 and the second shielding part 211 are parallel to the substrate surface 130a and have the long sides of the first target 202 and the second target 205 with the leading edges facing each other and spaced apart by a width D1. Are arranged vertically. An opening 113 is formed in a region sandwiched between opposing edges of the first shielding part 210 and the second shielding part 211.

The first shielding unit 210 is connected to the driving unit 210a and is provided to be movable independently along the y-axis direction. Similarly, the second shielding part 211 is connected to the driving part 211a,
It is provided so as to be independently movable along the y-axis direction. The mask assembly 209 has a first
By appropriately moving the shielding part 210 and the second shielding part 211, the position and width D1 of the opening 113 can be changed.

The first target 202 and the second target 205 are the first and second target surfaces 2.
The planes parallel to the long sides of the targets 202 and 205 including the normal passing through the centers of 02a and 205a are arranged so as not to overlap the normal passing through the center of the opening 113 of the mask assembly 209. In the present embodiment, the first target 202 is the first target surface 202a.
A normal line passing through the center of the mask assembly 209 is inclined with respect to a normal line passing through the center of the opening 113 of the mask assembly 209 by a predetermined angle 255 (15 ° to 45 °). The first target 202 is disposed obliquely so as to rise upward from the first shielding part 210 side toward the second shielding part 211 side. Thereby, the surface 202a of the first target 202 is diagonally opposed to the substrate surface 130a through the opening 113 of the mask assembly 209.

The second target 205 has a normal line that passes through the center of the second target surface 205 a at a predetermined angle 251 (−15 ° with respect to the normal line that passes through the center of the opening 113 of the mask assembly 209.
The inclination is arranged by −45 ° or less). The second target 205 is disposed obliquely so as to have a downward slope from the first shielding part 210 side toward the second shielding part 211 side. As a result, the surface 205a of the second target 205 is diagonally opposed to the substrate surface 130a through the opening 113 of the mask assembly 209.

As described above, the first target 202 and the second target 205 are connected to the mask assembly 20.
9 are arranged on both sides of the opening 113, and the surfaces 202a and 205a face each other in a state of being inclined with respect to the substrate surface 130a. As a result, sputtered particles emitted from a predetermined position on the first target surface 202 a follow the locus 254 and enter the substrate 130 at an angle 255. On the other hand, sputtered particles emitted from a predetermined position of the second target surface 205a are
It follows the locus 250 and enters the substrate 130 at an angle 251.

As described above, the sputtering apparatus 200 includes the first shielding part 210 of the mask assembly 209.
Since the position and width D1 of the opening 113 can be changed by appropriately moving the second shielding part 211, the same effect as in the first embodiment can be obtained.

Moreover, according to the sputtering apparatus 200 of this embodiment, it is possible to sequentially perform sputtering from the first target 202 and the second target 205 while cooling the substrate 130.

Incidentally, in many device elements, multilayer films having different thicknesses are generally formed.
Along with the thick film, the thin film is used for the following purposes. First, the thin film improves the adhesion between the thick film and the substrate. Second, the thin film provides a crystal base to promote crystallographic texture in thicker films. Third, the thin film controls growth characteristics such as the crystal grain size of the thick film. 4th
In addition, the thin film covers a thick sensitive layer to prevent oxidation and degradation.

The thin film can also provide special functions such as isolating two thick metal layers from each other, providing a tunnel barrier, and providing antiferromagnetic coupling between the two thick ferromagnetic layers. For example, the writing part of the magnetic head of the HDD comprises two double layers of NiFe and FeCo alloy. Each bilayer consists of a 1 nm NiFe (permalloy) layer and 200 nm
And an FeCo layer with a high magnetic anisotropy. The thin permalloy layer not only promotes the formation of the FeCo layer, but also serves as a base for reducing the crystal grain size. A thin film of metal such as NiFe or Ru or Ta is used to protect the structure of the two double layers.

In order to form layers having different thicknesses, it is necessary to form a film at a wide range of film formation rates. By controlling the power supplied to the cathode, the film formation rate can be controlled to 1% or less of the maximum rate. However, the plasma distribution is not always the same in the range of available cathode power, especially when the cathode power is low, resulting in a plasma distribution concentrated in the center of the target, resulting in a negative impact on film thickness uniformity. .

In a sputtering apparatus equipped with a substrate holder that holds the substrate movably with respect to the target, in order to reduce the deposition rate, it is necessary to increase the moving speed of the substrate holder in order to reduce the exposure time to the sputtered particles. There is. However, since the substrate holder provided with the heating / cooling mechanism for controlling the substrate temperature is large, it is difficult to move the substrate holder at a high speed.

The sputtering apparatus 200 according to the present embodiment can solve such problems. That is, the sputtering apparatus 200 according to this embodiment includes a movable mask assembly 209 having an opening 113. By moving the position of the opening 113 with respect to the targets 202 and 205, the incident angle of the sputtered particles can be defined. Opening 11
By changing the width D1 of 3, the incident angle distribution can be controlled and the film formation rate at any incident angle can be controlled.

Changing the power supplied to the target changes the plasma profile on the target surface, and consequently affects the film thickness uniformity. For example, if the power is changed too much in order to cope with a sudden decrease in film thickness from 200 nm to 1 nm, the plasma distribution changes, which adversely affects the film thickness uniformity.

In contrast, the sputtering apparatus 200 according to the present embodiment has the targets 202 and 205.
The film formation rate can be changed by changing the width D1 of the opening 113 without significantly changing the power supplied to the substrate.

By correcting the position of the first shielding part 210 and the second shielding part 211 of the mask assembly 209 by about 0.2 mm, the maximum opening width of 0.4 mm can be changed to reproduce a film formation rate of 2% or less. Is possible. Therefore, as described above, the magnet units 203, 20
The effective film formation rate is reduced to 1/5 without changing 6 and without changing the moving speed of the substrate holder 231.
It can be reduced to zero.

(5) Fourth Embodiment Next, a sputtering apparatus according to a fourth embodiment of the present invention will be described. The same components as those in the third embodiment are denoted by the same reference numerals, and the description thereof is omitted. The sputtering apparatus according to this embodiment is different from the third embodiment in that the substrate holder is fixed and the first cathode portion and the second cathode portion are provided so as to be linearly movable.

As shown in FIG. 14, the sputtering apparatus 300 includes a target assembly 370 and a substrate holding table 231 in a vacuum container 301. The target assembly 370 includes an assembly main body 371, a first cathode portion 261, a second cathode portion 262, and a mask assembly 209, and linearly moves in the vacuum vessel 301 along the y-axis direction by the moving mechanism 305. It is provided to be movable. The long sides of the first target 202 and the second target 205 are formed longer than the diameter of the substrate 130.

The assembly main body 371 is configured by a cylindrical member having an inverted V-shaped portion 372. A first cathode portion 261 and a second cathode portion 262 are provided on each side constituting the inverted V-shaped portion 372. The first cathode portion 261 and the second cathode portion 262 are provided such that the first target 202 and the second target 205 are exposed to the opening of the inverted V-shaped portion 372. In the opening of the inverted V-shaped portion 372, the mask assembly 20 extends across the opening.
9 is provided.

A bellows 325 is provided so as to cross the exhaust space 121 from the side wall of the assembly body 371 to the side wall of the vacuum vessel 301. The bellows 325 communicates with the external space 123. A power supply line (not shown) for supplying power to the first target 202 and the second target 205 is inserted into the bellows 325.

The moving mechanism 305 includes a drive unit 341 a provided on the ceiling surface of the vacuum vessel 301, a worm 342 disposed along the y-axis direction, and a linear motion unit 341 that is screwed into the worm 342.
And two carriages 340 and guide rails 343 provided in parallel to the worm 342. The worm 342 is connected to the drive unit 341a. The carriage 340 has wheels 340a.
And are respectively connected to the vicinity of both ends of the upper surface of the assembly body 371. The wheel 34
0a is formed to be able to travel on the guide rail 343. The linear motion part 341 is fixed to the assembly body 371.

The drive unit 341 a transmits a rotational force to the worm 342. The linear motion part 341 screwed into the worm 342 moves linearly along the worm 342 by the rotation of the worm 342. The assembly main body 37 connected to the linear motion part 341 by linear motion of the linear motion part 341
1 moves along the guide rail 343. There are two carts 340 in the assembly body 371.
They are linked together. Thereby, the assembly main body 371 can move more stably. In this way, the moving mechanism 305 can move the assembly body 371 along the y-axis direction.

A substrate holder 231 having a substrate placement surface 231 a is fixed to the vacuum container 301. The substrate cooling table 238 on which the substrate holding table 231 is installed may communicate with an external vacuum apparatus (not shown) through the compressed gas line 335.

As described above, according to the sputtering apparatus 300, the first shielding part 210 and the second shielding part 211 of the mask assembly 209 are appropriately moved, so that the position and the width D1 of the opening 113 are obtained.
Therefore, the same effect as in the first embodiment can be obtained.

Also, the sputtering apparatus 300 according to the present embodiment can sequentially perform sputtering from the first target 202 and the second target 205 while cooling the substrate 130, as in the third embodiment. Further, since the target assembly 370 is formed to be movable, the substrate holding table 231 can be fixed, and the configuration can be simplified.

(6) Fifth Embodiment Next, a sputtering apparatus according to a fifth embodiment of the present invention will be described. The same components as those in the third embodiment are denoted by the same reference numerals, and the description thereof is omitted. The sputtering apparatus according to this embodiment differs from the third embodiment in the configuration of the cathode portion.

As shown in FIG. 15, the sputtering apparatus 400 includes a target assembly 470 and a substrate holding table 231 in a vacuum vessel 401. The substrate holding table 231 is moved by the moving mechanism 23.
9 is provided so as to be linearly movable in the vacuum vessel 401.

The vacuum vessel 401 is integrally formed with a storage chamber 402 having a substantially circular longitudinal cross section in which the target assembly 470 is stored in the ceiling portion. The target assembly 470
The assembly body 471, the first target group 478, the second target group 479, and the hub 472 are provided in the housing chamber 402 so as to be rotatable around the hub 472. A mask assembly 209 is provided at a ceiling portion in the vacuum vessel 401 and a portion communicating with the storage chamber 402.

The assembly main body 471 includes a target holding surface 450 that extends from the rotation center of the storage chamber 402 having a substantially circular longitudinal section toward the inner wall (outside) of the storage chamber 402 and has a substantially inverted V-shaped cross section. It is composed of members. Further, the cylindrical member is provided substantially symmetrically with respect to the target holding surface 450 and the rotation center, and the storage chamber 40 is arranged from the rotation center of the storage chamber 402 having a substantially circular longitudinal section.
2 has a target holding surface 451 having a substantially V-shaped longitudinal section extending toward the inner wall (outside). The holding surface 450 is provided with a first target group 478 and the other holding surface 451.
Is provided with a second target group 479.

The first target group 478 includes a first cathode part 461 and a second cathode part 462. The second target group 479 has a third cathode portion 463 and a fourth cathode portion 464.

The first cathode portion 461 includes a first target 474, a target holding portion 474d, and a magnet unit 474c provided on the back surface of the target holding portion 474d. First
The target 474 can face the substrate 130 with the surface 474a inclined. Further, the first target 474 has a rectangular shape, and the long side is arranged in a direction perpendicular to the paper surface of this figure. The long side of the first target 474 is formed longer than the diameter of the substrate 130.

The angle 474b formed by the first target surface 474a and the substrate 130 can be adjusted as appropriate according to the rotation angle of the hub 472. The magnet unit 474c is installed in an assembly main body 473 that is an atmospheric pressure space. The second to fourth cathode portions 462 to 464 are also the first cathode portion 461.
Since the configuration is the same as that in FIG.

The first cathode portion 461 and the second cathode portion 462 have target surfaces 474a and 475a.
Are fixed to the holding surface 450 so as to face each other obliquely. The third cathode portion 463 and the fourth cathode portion 464 are fixed to the holding surface 451 with the target surfaces 476a and 477a facing each other obliquely. The first target 474, the second target 475, the third target 476, and the fourth target 477 may be formed of the same material or different materials.

As described above, according to the sputtering apparatus 400, since the mask assembly 209, the substrate cooling table 238, and the moving mechanism 239 are provided, the same effects as those of the third embodiment can be obtained.

Further, since the sputtering apparatus 400 can select either the first target group 478 or the second target group 479 by rotating the target assembly 470 around the hub 472, the maintenance period such as target replacement is extended. can do.

The sputtering apparatus 400 includes the first cathode unit 461 in the first target group 478.
And the second cathode portion 462 are fixed to the holding surface 450 with the target surfaces 474a and 475a being obliquely opposed to each other, so that sputtering is performed on one of the target surfaces or sputtering is performed on the two target surfaces. can do.

In addition, the sputtering apparatus 400 includes an assembly body 471 in FIG.
Is rotated by 180 ° about the rotation center, in the second target group 479, the third cathode portion 463 and the fourth cathode portion 464 are fixed to the holding surface 451 in a state where the target surfaces 476a and 477a face each other obliquely. Therefore, sputtering can be performed on one of the target surfaces, or sputtering can be performed on the two target surfaces.

(7) Sixth Embodiment Next, a sputtering apparatus according to a sixth embodiment of the present invention will be described. The same components as those in the third embodiment are denoted by the same reference numerals, and the description thereof is omitted. The sputtering apparatus according to this embodiment differs from the third embodiment in the configuration of the cathode portion.

As shown in FIG. 16, the sputtering apparatus 500 includes a target assembly 570 and a substrate holding table 231 in a vacuum vessel 501. The substrate holding table 231 is moved by the moving mechanism 23.
9, the inside of the vacuum vessel 501 is linearly movable.

The vacuum chamber 501 is integrally formed with a storage chamber 502 for storing the target assembly 570 in the ceiling portion. The target assembly 570 includes the assembly body 5
71, a first cathode portion 561, a second cathode portion 562, a third cathode portion 563,
A fourth cathode portion 564 and a hub 572 are provided, and the housing chamber 502 is rotatably provided with the hub 572 as a rotation center. In the ceiling portion of the vacuum vessel 501, there is a storage chamber 50.
A mask assembly 209 is provided at a portion communicating with 2.

The assembly main body 571 is composed of a cylindrical member having a substantially square vertical cross section, and the first to fourth cathode portions 561 to 564 are evenly arranged on the surface which is a target holding surface. A drum shield 578 is provided around the assembly body 571. The drum shield 578 is formed of a cylindrical member having an opening 579 on the lower surface side and covering each surface of the assembly main body 571, and is provided so as to be rotatable coaxially with the hub 572.

The first cathode portion 561 includes a first target 574, a target holding portion 574d, and a magnet unit 574c provided on the back surface of the target holding portion 574d. First
The target 574 can face the substrate 130 with the first target surface 574a tilted. The first target 574 has a rectangular shape, and its long side is arranged in a direction perpendicular to the paper surface of this figure. The long side of the first target 574 is set longer than the diameter of the substrate 130.

The angle 574b formed between the first target surface 574a and the substrate 130 can be adjusted as appropriate according to the rotation angle of the hub 572. The magnet unit 574c is an assembly body 5 that is an atmospheric pressure space.
71 is installed. The second to fourth cathode portions 562 to 564 are also the first cathode portion 561.
Since the configuration is the same as that in FIG. When the target assembly 570 is rotated while the drum shield 578 is fixed, each target surface 574a, 575a, 576a is rotated.
577a faces the substrate surface 130a.

An angle 574b formed between each of the target surfaces 574a to 577a and the substrate 130 can be adjusted to form a film with a larger incident angle. For example, Fe ₇₀ having high saturation magnetization Ms
In order to improve the deposition rate of Co ₃₀ , it is preferable to set the angle 574b so that the incident angle is 30 °.

In order to form a film with a larger incident angle, the opening 113 is moved to the first shielding part 210 side,
The assembly body 571 is rotated counterclockwise in the drawing with the hub 572 as the center of rotation, and the angle 57
What is necessary is just to set so that 4b may become small. Further, in order to shield the sputtered particles generated from the first shielding surface 210 side of the first target surface 574a, the drum shield 578 is rotated counterclockwise, and the opening 579 of the drum shield 578 is arranged in a direction directly below the target surface. You may do it.

As described above, according to the sputtering apparatus 500, since the mask assembly 209, the substrate cooling table 238, and the moving mechanism 239 are provided, the same effects as those of the third embodiment can be obtained.

In the present embodiment, the assembly main body 571 has been described as an example of a cylindrical member having a substantially square vertical cross section. However, the present invention is not limited to this, and the vertical cross section having a cathode portion on each surface is substantially omitted. You may comprise with a polygonal cylindrical member.

(Modification)
Next, a sputtering apparatus according to a modification of the sixth embodiment of the present invention will be described. The same components as those in the sixth embodiment are denoted by the same reference numerals, and description thereof is omitted. The sputtering apparatus according to the present embodiment is different from the sixth embodiment in that a fifth cathode portion is added.

As shown in FIG. 17, the sputtering apparatus 600 is provided with a fifth cathode portion 665 in a vacuum vessel 601. The fifth cathode portion 665 is disposed on the first shielding portion 210 side with respect to the target assembly 570, and the fifth target 679, the target holding portion 679d, and a magnet unit provided on the back surface of the target holding portion 679d. 679c. The fifth target 679 is held with the surface 679a inclined.

(8) Modifications The present invention is not limited to the above embodiment, and can be appropriately changed within the scope of the gist of the present invention. For example, in the above embodiment, the magnetic recording writer and the thin film of the sensor are mentioned for convenience, but the embodiment of the present invention is not limited to such a device. For example, a magnetic layer used for MRAM can be effectively formed by the present invention.

In the case of the said embodiment, although the target demonstrated the case where the surface was arrange | positioned diagonally with respect to the substrate surface, this invention is not limited to this, It is parallel to the long side of the target including the normal passing through the center of a target surface. The surface of the target may be arranged parallel to the substrate surface as long as the normal passing through the center of the surface and the opening of the mask assembly does not overlap.

The mask assembly according to the second embodiment may be applied to the sputtering apparatus according to the third to sixth embodiments.

In the case of the above embodiment, the case where the first shielding portion and the second shielding portion constituting the mask assembly are movable in parallel to the substrate surface has been described. However, the present invention is not limited to this and is perpendicular to the substrate surface. It may be provided so as to be movable in the direction (perpendicular to the mounting surface of the substrate holder, the z-axis direction).

DESCRIPTION OF SYMBOLS 100: Sputtering apparatus 101: Vacuum vessel 102: Target 102a: Target surface 103: Magnet unit 104: Target holding part 105: Third shielding part 105a: Rotation direction 109A: Mask assembly 110: First shielding part 111: Second shielding part 113: Opening 118: Rotating shaft 130: Substrate 130a: Substrate surface 131: Substrate holder 132: Moving mechanism

Claims (6)

In a sputtering apparatus for forming a magnetic layer on a substrate,
A target holding unit that is provided in the vacuum vessel and holds a target having a rectangular surface;
A magnet unit disposed on the back surface of the target holding unit;
A substrate holder having a mounting surface on which the substrate is mounted;
A mask assembly having an opening provided between the target and the substrate holder;
A moving mechanism for moving the substrate holding table and the target holding unit relatively and parallel to the placement surface,
The mask assembly is
Having a first shielding part and a second shielding part arranged substantially parallel to the placement surface,
The opening is formed between opposing sides of the first shielding part and the second shielding part,
The first shielding part and the second shielding part are independent in a direction substantially perpendicular to the long side of the target and parallel to the placement surface, or in a direction substantially perpendicular to the placement surface. The sputtering apparatus is provided so as to be movable. The target holding unit includes a first target holding unit and a second target holding unit,
The first target holding part and the second target holding part are each provided with the magnet unit on the back surface,
The first target holding part has an angle between a plane parallel to the long side of the first target holding part including a straight line perpendicular to the surface and a normal passing through the opening part between 15 ° and 45 °. Installed at an angle,
The second target holding part has an angle formed between a plane parallel to the long side of the second target holding part including a straight line perpendicular to the surface and a normal passing through the opening part, from −15 ° to −45 °. The sputtering apparatus according to claim 1, wherein the sputtering apparatus is installed inclined at an angle between. A target assembly having a plurality of target holding surfaces for holding the target, wherein at least one of the targets is opposed to the opening, and is provided rotatably about an axis parallel to a long side of the target ,
The sputtering apparatus according to claim 1, wherein when the target assembly is rotated, another target holding surface faces the opening. The target assembly is
A pair of first target holding surfaces having a substantially V-shaped longitudinal section extending from the center of the target assembly to the outside while holding the pair of targets facing the opening,
A pair of the targets are held, provided substantially symmetrically with respect to the first target holding surface and the center, and extended outward from the center of the target assembly.
A pair of second target holding surfaces having a substantially V-shaped longitudinal section,
The sputtering apparatus according to claim 3, wherein the second target holding surface faces the opening when the target assembly is rotated. The sputtering apparatus according to claim 1, wherein the mask assembly includes a central shielding portion that narrows an opening width of a central portion of the opening. The sputtering apparatus according to claim 1, wherein the mask assembly has a floating potential.

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