JP2016004624A - Chemiluminescence body and process of manufacture of the same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a chemiluminescence body for a chemiluminescence body structure which has a higher degree of freedom in replacement and can be used in a wider application field than that of the prior art.SOLUTION: This invention relates to a chemiluminescence body including an inner cylinder and an outer cylinder into which each of two kinds of chemical compositions is filled and the two kinds of chemical compositions are mixed to each other to generate chemical light-emitting. The inner cylinder is a breakable ample containing one chemical composition of the two kinds of chemical compositions. The outer cylinder is a resin container in which the other chemical composition of the two kinds of chemical compositions is contained inside the outer cylinder and outside the inner cylinder included in the outer cylinder. The outer cylinder has a connecting part.

Description

  The present invention relates to a chemiluminescent material and a method for producing the same. In particular, the present invention relates to a chemiluminescent material that can be freely changed in accordance with a use mode by a connecting portion provided in the chemiluminescent material, for a hand-held luminescent material used for event lights such as concert lights and disaster prevention.

  Conventionally, fluorescent light for chemiluminescence and chemiluminescence, such as light used for events such as concert lights, hand-held lights such as light for disaster prevention, floating used for fishing at night, decoration of ceremony venues, etc. Chemiluminescent materials that generate chemiluminescence by mixing two kinds of liquids and solids such as a combination of oxidizing solutions are widely used (Patent Documents 1 and 2).

  These chemiluminescent bodies are provided with an inner cylinder such as a glass ampule in a cylindrical container (inside the outer cylinder) as shown in the aforementioned Patent Document 1 and Patent Documents 3 and 4, and one liquid (or Solid) is filled into this inner cylinder, and the other liquid is filled outside the inner cylinder and into the outer cylinder. During storage, two types of liquid are stored by the inner cylinder (in the case of glass ampules, glass). Although separated, the inner tube is broken by bending the chemiluminescent body during use, and two types of liquids (or liquid and solid) are mixed to produce chemiluminescence in the cylindrical container. Yes.

  When these chemiluminescent bodies are hand-held lights or the like, the outer cylinder of the chemiluminescent body container is often a cylindrical container in which a gripping part is integrally molded because of excellent molding processability.

  As a holder that can have a plurality of chemiluminescent bodies at the same time, Patent Document 5 discloses a luminous body holder that has an openable and closable holding section that can simultaneously hold one end portions of a plurality of elongated luminous bodies. Is disclosed.

Japanese Patent No. 4044934 JP 2011-137134 A JP-A-8-280421 Japanese Patent No. 3773244 Utility model registration No. 3125325

  A conventional cylindrical container integrally formed with a grip portion needs to be gripped and held in the integrally molded shape. For example, a plurality of chemiluminescent bodies are simultaneously held in a hand or placed in a predetermined place. There were cases where it was difficult to use for purposes other than the use combined with the grip part molded from the beginning. In addition, the chemiluminescent body stops emitting light after a certain period of time, and becomes a waste as an entire integrally formed chemiluminescent body. As a holder for simultaneously holding a plurality of chemiluminescent bodies in the hand, the above-mentioned Patent Document 5 is disclosed. However, this is intended to hold a cylindrical container integrally formed with a conventional gripping part through an openable / closable base, and in order to replace it, it is necessary to open and close the gripping part, and there is a degree of freedom of replacement. It was low.

  In manufacturing a chemiluminescent body with a grip part integrally molded, contents such as a chemical composition and an inner cylinder are placed in an open outer cylinder container with a grip part having a relatively complicated shape. After that, it was sealed by a method of attaching a substantially cylindrical lid portion or the like to the end portion on the light emitting portion side. When attaching this lid part side, it was easier to attach if there was sufficient space at the time of heat welding, and that space was generated at the end part of the light emitting part side as a large dead space not filled with chemical composition and not emitting light . However, there has been a demand for a shape in which the light emitting part on the end side looks wider and brighter than the light emitting body according to the conventional manufacturing method.

  As a result of intensive studies to solve the above problems, the present inventor has found that the following inventions meet the above object, and have reached the present invention.

  The present invention is a chemiluminescent body that has an inner cylinder and an outer cylinder in which two kinds of chemical compositions are respectively enclosed, and generates chemiluminescence by mixing the two kinds of chemical compositions, The inner cylinder is a breakable ampoule containing one of the two chemical compositions therein, and the outer cylinder is the other chemical composition of the two chemical compositions. And a chemiluminescent body characterized in that the outer cylinder has a connecting portion. With such a configuration, the chemiluminescent body of the present invention can be used in a wide range of applications because it can be freely attached to components such as various holders by the connecting portion provided in the outer cylinder. .

  The present invention relates to a chemiluminescent material that generates chemiluminescence by mixing two chemical compositions. Here, the two types of chemical compositions that cause chemiluminescence by mixing are, for example, a chemiluminescent fluorescent solution (oxalic acid ester, dye, solvent, etc.) and a chemiluminescent oxidizing solution (hydrogen peroxide solution). Such oxidizers and catalyst components, solvents, etc.) are generally liquid, but on the other hand, in the same manner as these liquids, they are mixed in a powdery or granular solid form that produces chemiluminescence A thing may be used. This chemical composition is preferable when both are in a liquid state, because it is excellent in mixing properties and easily produces uniform light emission as a whole. When one is solid, light emission occurs while the other liquid passes through and penetrates the splitting ampoule, resulting in a relatively slow reaction. In addition, what produces chemiluminescence by mixing here is generally prepared as a composition such as a plurality of compounds, but in the present invention, those that can be used as a single substance are also included. Including chemical composition.

  The chemiluminescent body of the present invention has an outer cylinder and an inner cylinder included in the outer cylinder. Here, in the present invention, this inner cylinder is a splitting ampoule that contains one of the two chemical compositions therein. The other outer cylinder includes the other chemical composition of the two chemical compositions inside the outer cylinder and outside the inner cylinder contained in the outer cylinder. The chemiluminescent body of the present invention is required to be separated by an inner cylinder in the chemiluminescent body so that the two chemical compositions are not mixed when not in use (during storage or the like). In order to perform this separation and mixing, the inner cylinder provided in the chemiluminescent body is provided as a splitting ampoule. At the time of use, the chemiluminescent material is bent to break the breakable ampule, which is an inner cylinder, and the chemical composition inside the ampule is mixed with the chemical composition outside the ampule, thereby generating light emission.

  The breakable ampoule used for the inner cylinder may be an ampoule that can be broken in the outer cylinder when a bending force is applied to the chemiluminescent body, and a glass ampoule is generally used. Because it is made of glass, mixing of the external liquid and the internal liquid can be shut off when not in use, and furthermore, it can be easily broken easily by the load applied by bending the chemiluminescent material. is there. In the present invention, it is sufficient that the chemiluminescent material is bent so that the splitting ampoule is broken. In particular, in the case of a glass splitting ampoule, the bending is such that a gentle curve is drawn. Can be bent.

  The chemiluminescent body of the present invention is a resin container in which the outer cylinder includes the other chemical composition of the two types of chemical compositions inside the outer cylinder and outside the inner cylinder. The outer cylinder has a connecting part. The outer cylinder of the chemiluminescent body of the present invention is generally a resin container, and this container is molded by a resin molding method such as injection molding using resin. As this resin, what mainly has polyethylene (PE), polypropylene (PP), etc. is used. For example, in the case of polypropylene, a polypropylene resin composition to which an additive has been added is commercially available, and a container manufactured using such a resin composition is not a chemiluminescent material made of a resin composition employing polypropylene as a resin. It becomes a cylinder. In addition, in order to improve the dispersibility of light due to chemiluminescence inside the chemiluminescent body at the time of use, an outer cylinder is manufactured by adding an appropriate light dispersing agent to the resin composition or mixing colorants to change the color tone. May be. Moreover, it is good also as a container with high light dispersibility of a cloudy state by controlling crystallization degree by control of manufacturing conditions.

  The present invention is characterized in that the outer cylinder has a connecting portion. This connection part refers to the site | part for connection with the components which have a corresponding to-be-connected part. By providing this connecting portion on the outer cylinder, it can be attached to an attachment target such as a grip portion with a high degree of freedom. The connecting portion is preferably a chemiluminescent body having a hooking portion with respect to the insertion direction when connecting to a component having a connected portion connected to the connecting portion or a joint portion. This insertion direction corresponds to the extraction direction when the chemiluminescent body and the component are to be removed. By providing a hooking portion in this insertion direction (extraction direction), resistance in the extraction direction is generated, so that it cannot be easily removed during use. A plurality of the hooks are provided on the same chemiluminescent body, so that it is more difficult to come off. Moreover, it is preferable that this connection part is a screwing part. The threaded portion provided in the outer cylinder may have a structure of either a male screw or a female screw. If the connection by the screwing part is performed, the screwing part functions as a hooking part and is difficult to be detached from a holding part (for example, a grip) to which the chemiluminescent body is attached.

  Further, the present invention can provide a chemiluminescent structure formed by coupling with a component having a connected portion connected to the connecting portion of the chemiluminescent material having the above-described characteristics. Examples of this component include a grip portion and a stationary table. By combining with these components, a chemiluminescent structure with a chemiluminescent attached is obtained. In addition, in coupling | bonding with these structural components, you may couple | bond via the coupling part which can be connected with both the connection part of a chemiluminescent body, and the to-be-connected part of a structural component. Or it can also be set as the structure which couple | bonds a several chemiluminescent body via a coupling part. An advantage of the structure through the joint portion is that it can be connected to a structural component having a screwing portion that does not directly correspond to the screwing portion of the chemiluminescent body.

  A gripping part which is an example of a structural part may be provided with a plurality of connected parts so that a plurality of chemiluminescent bodies of the present invention can be attached and used. At this time, the component does not need to be made of the same resin as the chemiluminescent body, and may be manufactured using metal, wood, resin having higher strength than PE or PP, or the like. Since the component having the connected portion does not need to be disposable, it can be used even after the emission of the chemiluminescent material is stopped. On the other hand, the chemiluminescent body of the present invention in which the gripping part or the like is not integrally molded can reduce the amount of waste. In addition, if a screw connecting portion corresponding to a standard such as JIS or ISO is used, it can be freely attached to various conventional screws. By using this, it can be attached to walls, floors, etc. to make decoration methods, production methods, and safety lights in disaster prevention.

  The present invention is a method for producing a chemiluminescent material, which has an inner cylinder and an outer cylinder in which two kinds of chemical compositions are encapsulated, and generates chemiluminescence by mixing the two kinds of chemical compositions. The inner cylinder, which is a splitting ampoule containing one of the two chemical compositions therein, and the other chemical composition of the two chemical compositions, In addition to the above, it is possible to provide a method for producing a chemiluminescent body, which is sealed with a lid portion having a connecting portion.

  The outer cylinder of the present invention is made of resin as described above. Here, after adding an inner cylinder (ampoule), a chemical composition for chemiluminescence, and the like to the outer container body container, the outer cylinder is sealed by a predetermined method to become an outer cylinder. As a typical method of this sealing method, there is a method of attaching a lid to a main body container for an outer cylinder, and a specific method of attaching the lid is a method of providing a lid by thermal welding. In providing this lid part, it is necessary that a space for providing the lid part is provided in the main body container for the outer cylinder. Furthermore, it is preferable that the lid portion has a relatively simple structure such as a columnar shape so that thermal welding or the like can be easily performed.

  Here, in this invention, it can be set as the manufacturing method which makes this cover part a cover part which has a connection part, and seals with the cover part. When this lid portion is a lid portion having a connecting portion, the light emitting portion on the end side, which is the opposite side of the connecting portion, can be easily manufactured in a shape that looks wider and brighter than before. When the chemiluminescent body obtained by this manufacturing method is a chemiluminescent structure that is combined with a component having a grip on the connecting part on the lid side, the chemiluminescent structure is on the side opposite to the grip. Since the chemiluminescent material is more easily filled, a chemiluminescent structure having a wider light emitting area and superior design is obtained. An advantage of this manufacturing method is that it is easy to manufacture when the lid is provided by thermal welding. In particular, when the connecting portion provided on the lid portion is a concave connecting portion with respect to the outer tube of the chemiluminescent body, the advantage of this manufacturing method is great, and the lid portion is welded when the connecting portion is a female screw. Sometimes, it is possible to perform simple and stable welding by a process of welding the end portions of the lid portion and the outer cylinder main body portion in a plane. Furthermore, in addition to the conventional cylindrical shape, the non-lid portion side structure can be provided with a decoration such as a heart shape, a spherical shape, or a block shape on the end portion side. Also, the degree of design freedom can be improved.

  According to the present invention, a chemiluminescent body that can be attached with a high degree of freedom can be obtained by providing the connecting portion in the outer cylinder. By setting it as such a structure, the chemiluminescent structure of various aspects can be obtained by couple | bonding with the component which has a to-be-connected part corresponding to a connection part. Furthermore, by making it easy to separate the chemiluminescent material and the component parts, there is an effect of reducing raw materials used for manufacturing and reducing waste. In addition, by using the manufacturing method in which the connecting part is a lid part, it becomes easy to manufacture a chemiluminescent body having a shape in which the light emitting part on the end side, which is the opposite side of the connecting part, looks wider and brighter than before.

It is sectional drawing which shows the example of the whole structure of the chemiluminescent body of this invention. It is a figure which shows an example of the external appearance of the chemiluminescent structure of this invention. It is a figure which shows an example which connects the chemiluminescent body of this invention by a coupling part. It is a figure which shows an example of the component of the chemiluminescent structure of this invention. It is a figure which shows the other example of the component of the chemiluminescent structure of this invention. It is a figure which shows the other example of the component of the chemiluminescent structure of this invention. It is a figure which shows the other example of the component of the chemiluminescent structure of this invention. It is a figure which shows an example of the external appearance of the chemiluminescent body of this invention.

  Preferred embodiments of the present invention will be illustratively described below with reference to the drawings. The description of the embodiment and the constituent elements described below is an example (representative example) of an embodiment of the present invention, and the present invention is not limited to the following contents unless it exceeds the gist.

  An embodiment of the chemiluminescent material of the present invention will be described with reference to FIGS. FIG. 1 shows a configuration of a chemiluminescent body 10 including an inner cylinder 2, and the outer cylinder container 1 functions as an outer cylinder by being sealed by a lid portion 4 having a female screw type connecting portion 3. It is sectional drawing which shows the whole structure of the chemiluminescent body 10 of a structure.

  The chemiluminescent body 10 shown in FIG. 1 has an inner cylinder 2 in which two kinds of chemical compositions are encapsulated and an outer cylinder in which an outer cylinder container 1 is sealed with a lid 4, and the chemistry encapsulated in each of them. It is a chemiluminescent substance which produces chemiluminescence by mixing a composition. Here, the inner cylinder 2 is a splitting ampoule containing one chemical composition of the two kinds of chemical compositions therein. Further, the outer cylinder made of the outer cylinder container 1 or the like has the other chemical composition of the two types of chemical compositions inside the outer cylinder and outside the inner cylinder 2 contained in the outer cylinder. It is a resin container. Here, the connecting part 3 of the outer cylinder is provided by attaching the cover part 4 after the inner cylinder 2 or the chemical composition is filled in the outer cylinder container 1, whereby the outer cylinder having the connecting part 3. It becomes.

  In this FIG. 1, the aspect which provided the screwing part of the internal thread as the connection part 3 is shown. When the outer cylinder container 1 is sealed by the lid portion 4 provided with the threaded portion of the female screw, it can be sealed by welding the welding portion 5. When this is performed by heat welding, it is possible to apply heat to the welding portion 5 in a planar manner from above by fitting the lid portion 4 to the outer cylinder container 1. The planar heating for welding that can be adopted when the connecting portion is a female screw is a method that can be welded very easily. Furthermore, since the connecting portion 3 is connected to a component having a gripping portion, the end portion side (downward in FIG. 1) of the chemiluminescent body 10 that is away from the gripping portion is the light emitting portion. The shape that looks wider and brighter than before and the shape of this end can be easily changed, and a wide range of light emitting portions can be achieved with a high degree of freedom. In addition, if heat is applied from above, contents such as chemical compositions and inner cylinders are less likely to leak during operation.

  Next, FIG. 2 is a diagram showing a chemiluminescent structure 30 formed by combining the chemiluminescent body 10 and a component 20 having a connected portion that can be connected to the connecting portion of the chemiluminescent body 10. Here, although not shown in FIG. 2, when connecting to the chemiluminescent body 10 having the female screw connecting portion as shown in FIG. 1, the component 20 has a male screw connected portion. By doing so, it is possible to make the coupling difficult to come off by simple attachment.

  FIG. 3 is a view showing a state in which two chemiluminescent bodies 10 shown in FIG. In this way, a plurality of chemiluminescent bodies 10 having female threaded joints as described with reference to FIG. 1 are connected via a joint section 6 having a plurality of male threads to form a chemiluminescent structure. You can also In FIG. 3, a long chemiluminescent structure can be obtained through the joint 6.

  4A to 4D are diagrams showing the component parts 21 to 24 each having a to-be-connected portion connected to the connecting portion of the chemiluminescent body of the present invention. As shown in the structural parts 21 to 24, it is possible to design various types of components having the connected portion 7 that can be combined with the connecting portion of the chemiluminescent body of the present invention, and by simply replacing this component, A chemiluminescent structure that can be used in various applications can be obtained.

  FIG. 5 is a view showing a chemiluminescent body 11 having a male screw connecting portion 8. As described above, in addition to the connecting portion shown in FIG. 1 and the like, a male screw connecting portion 8 as shown in FIG. 5 can be provided. In this case, the connected parts such as component parts may be of a female screw type.

  The chemiluminescent material of the present invention may be used as it is as a concert light or a guide light, or may be used as a chemiluminescent structure combined with a structural component having a connected portion.

1 Container for outer cylinder 10, 11 Chemiluminescent body 2 Inner cylinder
20, 21, 22, 23, 24 Component 3 Connection part (female screw)
30 Chemiluminescent Structure 4 Lid 5 Welded 6 Joint 7 Connected 8 Connected (Male Screw)

Claims (7)

A chemiluminescent material that has an inner cylinder and an outer cylinder in which two kinds of chemical compositions are encapsulated, and generates chemiluminescence by mixing the two kinds of chemical compositions,
The inner cylinder is a splittable ampoule containing one chemical composition of the two chemical compositions therein,
The outer cylinder is a resin container containing the other chemical composition of the two chemical compositions inside the outer cylinder and outside the inner cylinder enclosed in the outer cylinder;
The said outer cylinder has a connection part, The chemiluminescent body characterized by the above-mentioned.   The chemiluminescent body according to claim 1, wherein the connecting portion has a hooking portion with respect to an insertion direction when connecting to a component having a connected portion connected to the connecting portion.   The chemiluminescent body according to claim 1 or 2, wherein the connecting portion is a screwing portion.   The chemiluminescent structure formed by couple | bonding with the component which has a to-be-connected part connected with the connection part of the chemiluminescent body of any one of Claims 1-3. A method for producing a chemiluminescent material, which has an inner cylinder and an outer cylinder in which two kinds of chemical compositions are encapsulated, and generates chemiluminescence by mixing the two kinds of chemical compositions,
The inner cylinder, which is a splitting ampoule containing one of the two chemical compositions therein, and the other chemical composition of the two chemical compositions are added to an outer cylinder container. And then sealing with a lid having a connecting part.   6. The method for producing a chemiluminescent body according to claim 5, wherein the sealing by the lid portion having the connecting portion is performed by heat welding.   The manufacturing method of the chemiluminescent body according to claim 5 or 6, wherein the connecting portion of the lid portion having the connecting portion is a concave lid portion with respect to the outer cylinder container.