JP6509502B2 - Chemiluminescent body structure and method for producing chemiluminescent body - Google Patents

Description

  The present invention relates to chemiluminescers and methods of making the same. In particular, the present invention relates to a hand-held light emitter used as event light such as a concert light or for disaster prevention, and to a chemical light emitter which can be freely changed according to a usage mode by a connecting portion provided on the chemical light emitter.

  Hand-held lights, such as concert lights, used at the time of events and lights for disaster prevention, floats used for night fishing, decorations for ceremony venues, etc. A chemiluminescer that produces chemiluminescence by mixing two types of liquids or solids such as a combination of oxidizing liquids is widely used (Patent Document 1, Patent Document 2).

  These chemiluminescers are further provided with an inner cylinder such as a glass ampoule in the cylindrical container (in the outer cylinder) as shown in the above-mentioned Patent Document 1 and Patent Documents 3 and 4, and one liquid (or (Solid) is filled in the inner cylinder, and the other liquid is filled in the outer cylinder of the inner cylinder, and the two liquids are stored in the inner cylinder by the inner cylinder (glass in the case of a glass ampoule) during storage. Although separated, the inner cylinder is broken by bending the chemiluminescer at the time of use, and it is proposed and used as a configuration in which two types of liquid (or liquid and solid) are mixed and chemiluminescence occurs in a cylindrical container. There is.

  When these chemiluminescers are hand-held lights and the like, the outer cylinder of the chemiluminescer vessel is often a cylindrical vessel in which the grip portion is integrally molded because of excellent molding processability.

  As a holder capable of holding a plurality of such chemical light emitters simultaneously, Patent Document 5 discloses a light emitter holder provided with an open / close holding unit capable of holding one end of a plurality of elongated light emitters simultaneously. Is disclosed.

Patent No. 4044934 JP 2011-137134 A JP-A-8-280421 Patent No. 37 73 244 Utility model registration No. 3125325

  The cylindrical container in which the conventional grip portion is integrally molded needs to be gripped and held in the integrally molded shape, for example, a plurality of chemiluminescers can be simultaneously held by hand or placed in a predetermined place, etc. There were cases where it was difficult to use other than the use in accordance with the grip part that was molded from the beginning. In addition, the chemiluminescent substance ceases to emit light after a given time, and becomes a waste as a whole of the integrally molded chemiluminescent substance. As a holder for holding a plurality of chemiluminescers at the same time, the above-mentioned Patent Document 5 is disclosed. However, this is intended to hold a cylindrical container integrally formed with a conventional grip through an openable and closable base, and in order to replace it, it is necessary to open and close the grip and there is a freedom of replacement. It was low.

  In addition, in the production of a chemical light-emitting body in which the grips are integrally molded, the contents such as the chemical composition and the inner cylinder are contained in an open outer cylinder container in which the grips having a relatively complicated shape are integrally molded. Then, it is sealed by a method of attaching a substantially cylindrical lid or the like to the end on the light emitting unit side. In order to attach the lid side, it is easier to provide a sufficient space at the time of thermal welding, and the space becomes a large dead space where the chemical composition is not filled and does not emit light, and occurs at the end of the light emitting side . However, it has been required that the light emitting portion on the end portion side be wider and brighter than the light emitting material produced by the conventional manufacturing method.

  MEANS TO SOLVE THE PROBLEM As a result of repeating earnest research in order to solve the said subject, this inventor discovered that the following invention corresponded to the said objective, and came to this invention.

  The present invention is a chemiluminescer which has an inner cylinder and an outer cylinder in which two types of chemical compositions are respectively enclosed, and which generates chemiluminescence by mixing the two types of chemical compositions, The inner cylinder is a fractureable ampoule containing the chemical composition of one of the two chemical compositions therein, and the outer cylinder is an outer cylinder that is the other of the two chemical compositions. A container made of resin, which is contained in the inside of the above and outside of the inner cylinder contained in an outer cylinder, and the outer cylinder has a connecting portion. With such a configuration, the chemiluminescent body of the present invention can be used in a wide range of applications because it can be freely attached to various components such as holders by the connection portion provided on the outer cylinder. .

  The present invention relates to a chemiluminescer that produces chemiluminescence by mixing two chemical compositions. Here, the two types of chemical compositions that generate chemiluminescence by mixing are, for example, a fluorescence solution for chemiluminescence (oxalate ester and a dye, a solvent, etc.) and an oxidation solution for chemiluminescence (hydrogen peroxide water). Liquid state such as oxidizing agent and catalyst component, solvent, etc.) is generally used, but powdery or granular solid state that produces chemiluminescence by mixing with one of these liquids in the same manner. You may use a thing. When both are liquid, this chemical composition is excellent in mixing properties and is preferable because it is easy to rapidly generate uniform light emission as a whole. In addition, when one is solid, the other solution passes through the fractureable ampoule and light is emitted while penetrating, resulting in a relatively gentle reaction. In addition, although what produces chemiluminescence by mixing here is generally prepared as a composition of a several compound etc., respectively, what can be used with a single substance in this invention is also a thing. It is written including a chemical composition.

  The chemiluminescer of the present invention has an outer cylinder and an inner cylinder contained in the outer cylinder. Here, in the present invention, the inner cylinder is a breakable ampoule containing therein one of the two chemical compositions. The other outer cylinder contains the other chemical composition of the two types of chemical compositions inside the outer cylinder and outside the inner cylinder contained in the outer cylinder. The chemiluminescer of the present invention is required to be separated by an inner cylinder within the chemiluminesce so that the two chemical compositions are not mixed when not in use (such as when stored). In order to carry out this separation and mixing, the inner cylinder provided in the chemiluminescer is provided as a breakable ampoule. At the time of use, by bending the chemiluminescent substance, the fractureable ampoule which is the inner cylinder is broken, and the chemical composition inside thereof is mixed with the chemical composition outside the ampoule to generate luminescence.

  The fractureable ampoule used for the inner cylinder may be an ampoule which can be broken in the outer cylinder when a force of bending is applied to the chemiluminescer, and generally, an ampoule made of glass is used. By using glass, it is possible to shut off the mixing of the external liquid and the internal liquid when not in use, and further, because it can be suitably cracked by the load applied by bending of the chemiluminescer. is there. In the present invention, the bending of the chemiluminescer is sufficient if it is such a degree that the breakable ampoule breaks, particularly when the breakable ampoule is made of glass, the degree of bending is a gentle curve. It is good if it is bent.

  In the chemiluminescer according to the present invention, a resin container wherein the outer cylinder contains the other chemical composition of the two types of chemical compositions inside the outer cylinder and outside the inner cylinder contained in the outer cylinder And the outer cylinder has a connecting portion. The outer cylinder of the chemiluminescer of the present invention is generally a container made of resin, and this container is molded using a resin by a resin molding method such as injection molding. As this resin, those mainly composed of polyethylene (PE), polypropylene (PP) and the like are generally used. For example, in the case of polypropylene, a polypropylene resin composition to which an additive is added is commercially available, and a container manufactured by such a resin composition is outside of a resin composition-made chemiluminescer employing polypropylene as a resin. It becomes a cylinder. In addition, in order to improve the dispersibility of light due to chemiluminescence inside the chemiluminescent substance at the time of use, a light dispersant is appropriately added to the resin composition, or a colorant is mixed to change the color tone to produce an outer cylinder. May be In addition, the degree of crystallization may be controlled by controlling the production conditions, or the like, and the container may have a high light dispersibility in the white turbidity state.

  The present invention is characterized in that the outer cylinder has a connecting portion. The connection portion refers to a portion for connection with a component having a corresponding connected portion. By providing this connecting portion in the outer cylinder, it can be attached with high freedom to an object to be attached such as a grip. Preferably, the connecting portion is a component having a connected portion connected to the connecting portion or a chemiluminescent body having a hooking portion in the inserting direction when connected to the joint portion. This insertion direction corresponds to the removal direction when it is intended to remove the chemiluminescent body and the component. By providing the hook portion in the insertion direction (extraction direction), a resistance in the extraction direction is generated, so that it becomes difficult to be removed at the time of use. By providing a plurality of hooking portions in the same chemiluminescer, it becomes more difficult to remove. Moreover, it is preferable that this connection part is a screwing part. The screwing portion provided on the outer cylinder may be either a male screw or a female screw. If the connection by the screwing portion is performed, the screwing portion functions as a hooking portion, and it is difficult to be detached from the holding part (for example, a grip) to which the chemical light-emitting body is attached.

  Further, the present invention can be a chemiluminescent substance structure formed by bonding with a component having a to-be-connected part which is connected to the connecting part of a chemiluminescent substance having the characteristics described above. As this component, a grip part, a stand type stand, etc. are mentioned. By combining with these components, a chemiluminant structure attached with a chemiluminant is obtained. In addition, in bonding with these structural parts, it may be connected through a joint that can be connected to both the connection part of the chemiluminescent body and the connected part of the structural parts. Alternatively, a structure in which a plurality of chemiluminescers are coupled via a joint portion can be used. An advantage of the construction through the joint portion is that it can be connected to a structural component having a screwing portion which does not correspond directly to the screwing portion of the chemical luminescence body.

  The grip part which is an example of a structural component may be provided with a plurality of connected parts so that a plurality of the chemiluminescers of the present invention can be attached and used. At this time, the component parts do not need to be made of the same resin as the chemical light emitter, and may be manufactured using metal, wood, resin having a higher strength than PE, PP or the like. The component having the connected part does not have to be disposable, and therefore can be used even after the luminescence of the chemiluminescent body is stopped. On the other hand, the chemiluminescent substance of the present invention in which the grips and the like are not integrally formed can also reduce the amount of waste. Moreover, if it is set as the connection part of the screw made to respond | correspond to standard standards, such as JIS and ISO, it can attach freely to various conventional screws. Using this, it can also be attached to a wall or floor and used as a decoration method, presentation method, and safety light at the time of disaster prevention.

  The present invention is a method for producing a chemiluminescer having an inner cylinder and an outer cylinder in which two types of chemical compositions are respectively enclosed, and mixing the two types of chemical compositions to produce chemiluminescence. A container for the outer cylinder, the inner cylinder being a fractureable ampoule containing the chemical composition of one of the two chemical compositions therein, and the other chemical composition of the two chemical compositions, And then sealing with a lid having a connecting part.

  The outer cylinder of the present invention is made of resin as described above. Here, after the inner cylinder (ampoule), the chemical composition for chemical luminescence, etc. are added to the main container for the outer cylinder, the outer cylinder is sealed in a predetermined method to become the outer cylinder. As a representative method of this sealing method, there is a method of attaching a lid to a main body container for an outer cylinder, and a specific method of attaching a lid is a method of providing a lid by thermal welding. In order to provide the lid, it is necessary to have a space for providing the lid in the main container for the outer cylinder. Furthermore, it is preferable that the lid has a relatively simple structure such as a cylindrical outer shape so as to facilitate heat welding and the like.

  Here, in the present invention, the lid portion may be a lid portion having a connection portion, and the manufacturing method may be such that the lid portion seals the lid portion. If this lid part is a lid part having a connecting part, the light emitting part on the end side which is the opposite side of the connecting part can be easily manufactured as a shape that looks brighter than before. When a chemiluminescer obtained by this manufacturing method is a chemiluminescer structure combined with a component having a grip on the connecting part on the lid side, it extends to the end opposite to the grip. Since a state in which the chemiluminescent body is more easily filled is obtained, the chemiluminescent body structure is excellent in the designability in which the light emitting area is wider than the conventional one. An advantage of this manufacturing method is that it is easy to manufacture when the lid is provided by thermal welding. In particular, when the connection portion provided in the lid portion is a concave connection portion with respect to the outer cylinder of the chemical luminescence body, the advantage of this manufacturing method is significant, and in particular, the lid portion is welded if it is a screw portion of a female screw. At the same time, welding can be carried out simply and stably by the process of welding the ends of the lid and the outer cylinder main body on a flat surface. Furthermore, the structure on the non-lid side can be provided with a decoration such as a heart shape, a spherical shape, a block shape or the like on the end side in particular other than the conventional cylindrical shape, Can also improve the freedom of design.

  According to the present invention, by providing the connecting portion on the outer cylinder, it is possible to obtain a chemiluminescent material that can be attached with a high degree of freedom. With such a configuration, it is possible to obtain various modes of the chemiluminescent substance structure by bonding with the component having the connecting part and the corresponding connected part. Furthermore, the chemiluminescent substance and the component parts are easily separated, which has the effect of reducing raw materials used in manufacturing and reducing waste. In addition, by using the manufacturing method with the connecting portion as the lid portion, it becomes easy to manufacture a chemiluminescent material having a shape in which the light emitting portion on the end portion side opposite to the connecting portion looks brighter than before.

It is sectional drawing which shows the example of the whole structure of the chemiluminescent body of this invention. It is a figure which shows an example of the external appearance of the chemiluminescent body structure of this invention. It is a figure which shows an example which connects the chemiluminescent body of this invention by a coupling part. It is a figure which shows an example of the component of the chemiluminescent body structure of this invention. It is a figure which shows the other example of the component of the chemiluminescent body structure of this invention. It is a figure which shows the other example of the component of the chemiluminescent body structure of this invention. It is a figure which shows the other example of the component of the chemiluminescent body structure of this invention. It is a figure which shows an example of the external appearance of the chemiluminescent body of this invention.

  Hereinafter, preferred embodiments of the present invention will be exemplarily described with reference to the drawings. The description of the embodiment and constituent requirements described below is an example (representative example) of the embodiment of the present invention, and the present invention is not limited to the following contents unless it exceeds the gist.

  Embodiments of the chemiluminescer of the present invention will be described using FIGS. FIG. 1 shows the configuration of a chemical light emitter 10 including an inner cylinder 2, and the outer cylinder container 1 functions as an outer cylinder by being sealed by a lid 4 having a female screw type connection portion 3. It is sectional drawing which shows the whole structure of the chemiluminescent body 10 of a structure.

  The chemiluminescer 10 shown in FIG. 1 has an inner cylinder 2 in which the two types of chemical compositions are respectively enclosed and an outer cylinder in which the container 1 for the outer cylinder is sealed by a lid 4, and It is a chemiluminescent substance which produces chemiluminescence by mixing a composition. Here, the inner cylinder 2 is a fractureable ampoule containing therein one of the two chemical compositions. In addition, the outer cylinder consisting of the outer cylinder container 1 etc. is the inside of the outer cylinder and the outside of the inner cylinder 2 which is contained in the outer cylinder and the other chemical composition of the two types of chemical compositions. Containing resin container. Here, the connection portion 3 of the outer cylinder is provided by filling the inner cylinder 2, the chemical composition and the like into the outer cylinder container 1 and then attaching the lid 4, whereby the outer cylinder having the connection portion 3 is provided. It becomes.

  In this FIG. 1, the aspect which provided the screwing part of the female screw as the connection part 3 is shown. When the outer cylinder container 1 is sealed by the lid 4 provided with the screwing portion of the female screw, the welded portion 5 can be sealed by welding. When this is performed by heat welding, the lid 4 can be fitted to the outer cylinder container 1 and the heat can be applied to the welded part 5 from above from above. The planar heating for welding, which can be adopted when the connection part is a female screw, is a method which can be extremely easily welded. Furthermore, since the connecting portion 3 is connected to a component having a gripping portion, the light emitting portion of the end portion side (downward in FIG. 1) of the chemical light emitting body 10 which is away from the gripping portion It is easy to change the shape that looks wider and brighter than before and the shape of this end, and can be made into a wide light emitting part with a high degree of freedom. In addition, if heat is applied from above, contents such as the chemical composition and the inner cylinder are less likely to leak during work.

  Next, FIG. 2 is a view showing a chemiluminescent substance structure 30 formed by combining the chemiluminescent substance 10 and the component 20 having the coupling part that can be coupled with the coupling part of the chemiluminescent substance 10. Here, although not shown in FIG. 2, when connected with the chemical light emitter 10 having a female screw connection as shown in FIG. 1, the component 20 has a male screw connection. By doing so, it is possible to make the connection hard to come off by simple installation.

  FIG. 3 is a view showing how two chemical light emitters 10 shown in FIG. 1 are connected via the joint portion 6. In this manner, a plurality of chemical light emitters 10 having a female screw threaded portion as described with reference to FIG. 1 are connected via a plurality of joint portions 6 having a plurality of male screws to form a chemiluminescent body structure You can also In FIG. 3, the long chemiluminescent body structure can be obtained through the joint portion 6.

  FIGS. 4A to 4D are views showing components 21 to 24 having a connected part connected to the connected part of the chemiluminescent substance of the present invention. As shown in the structural parts 21 to 24, it is possible to design various aspects of the component having the coupled portion 7 that can be coupled to the coupling portion of the chemiluminescer of the present invention, only by replacing this component Chemiluminescent structures that can be used in a variety of applications can be obtained.

  FIG. 5 is a view showing a chemiluminescent body 11 having a male screw connection portion 8. Thus, in addition to the connection portion as shown in FIG. 1 etc., the connection portion 8 of the male screw as shown in FIG. 5 can also be provided. In this case, the connected parts such as the component parts may be of a female screw type.

  The chemiluminescer of the present invention may be used as it is as a concert light or a guide lamp, or it may be used as a chemiluminant structure in combination with a structural component having a connected part.

1 Container for outer cylinder 10, 11 Chemical luminous body 2 Inner cylinder
20, 21, 22, 23, 24 Component 3 Connection part (female screw)
Reference Signs List 30 chemiluminesce structure 4 lid 5 welded part 6 joint 7 connected part 8 connected part (male screw)

Claims (4)

A chemiluminescer having an inner cylinder and an outer cylinder in which two types of chemical compositions are respectively enclosed, and generating chemiluminescence by mixing the two types of chemical compositions,
The inner cylinder is a fractureable ampoule containing therein a chemical composition of one of the two chemical compositions;
The outer cylinder is a resin container containing the other chemical composition of the two types of chemical compositions inside the outer cylinder and outside the inner cylinder contained in the outer cylinder,
A chemiluminescer having a connecting portion in which the outer cylinder is a threaded portion;
The chemiluminescent substance structure formed by couple | bonding with the holding part which has the to-be-connected part connected with the connection part of the said chemiluminescent body. A chemiluminescer having an inner cylinder and an outer cylinder in which two types of chemical compositions are respectively enclosed, and generating chemiluminescence by mixing the two types of chemical compositions,
The inner cylinder is a fractureable ampoule containing therein a chemical composition of one of the two chemical compositions;
The outer cylinder is a resin container containing the other chemical composition of the two types of chemical compositions inside the outer cylinder and outside the inner cylinder contained in the outer cylinder,
A chemiluminescer having a connecting portion in which the outer cylinder is a threaded portion;
The chemiluminescent substance structure formed by combining with the stand-type base which has the to-be-connected part connected with the connection part of the said chemiluminescent body. A chemiluminescer having an inner cylinder and an outer cylinder in which two types of chemical compositions are respectively enclosed, and generating chemiluminescence by mixing the two types of chemical compositions,
The inner cylinder is a fractureable ampoule containing therein a chemical composition of one of the two chemical compositions;
The outer cylinder is a resin container containing the other chemical composition of the two types of chemical compositions inside the outer cylinder and outside the inner cylinder contained in the outer cylinder,
A chemiluminescer having a connected part in which the outer cylinder is a threaded part;
A chemiluminescent structure, comprising: a joint portion having a connection portion in which at least two or more of the chemiluminescent bodies are connected, and at least two or more of the chemiluminescent bodies being connected to the joint portion. A method for producing a chemiluminescer, comprising an inner cylinder and an outer cylinder in which two types of chemical compositions are respectively enclosed, and mixing the two types of chemical compositions to generate chemiluminescence,
The inner cylinder which is a fractureable ampoule containing the chemical composition of one of the two chemical compositions inside and the other chemical composition of the two chemical compositions are added to the container for the outer cylinder and then, the above-Rimitsu closed by the lid having a connecting portion which is threaded portion of the female screw is lid concave relative to the outer container, and the lid portion and an end portion of the outer cylinder chamber A method of manufacturing a chemiluminescer characterized by heat welding on a flat surface .