CN1214088C - White-light emitting chemiluminescent product - Google Patents
White-light emitting chemiluminescent product Download PDFInfo
- Publication number
- CN1214088C CN1214088C CNB031020119A CN03102011A CN1214088C CN 1214088 C CN1214088 C CN 1214088C CN B031020119 A CNB031020119 A CN B031020119A CN 03102011 A CN03102011 A CN 03102011A CN 1214088 C CN1214088 C CN 1214088C
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- Prior art keywords
- chemoluminescence
- goods
- anthracene
- white light
- solution
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B20/00—Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
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- Packages (AREA)
- Wrappers (AREA)
- Electroluminescent Light Sources (AREA)
Abstract
The present invention relates to a chemical luminescent product capable of emitting white light. The present invention is characterized in that the chemical luminescent product is composed of a chemical luminescent solution and an exterior plastic package for accommodating the chemical luminescent solution, wherein the chemical luminescent solution is composed of one organic solution containing hydrogen peroxide and the other organic solution containing oxalic ester and dyestuff. The proportion of the two organic solutions is determined by light intensity properly generated and required; the dyestuff is taken from single anthracene dyestuff; the exterior plastic package for accommodating the chemical luminescent solution is taken from red and/or yellow exterior plastic packages. The present invention has the advantages that the single anthracene dyestuff is used as the dyestuff of the chemical luminescent solution, and the exterior package made of red and/or yellow plastic materials is appended. The reasonable combination generates a new production approach of a chemical luminescent tube emitting strong white light and simultaneously reduces the production cost of the product; consequently, the application of the product has great economical efficiency and wide universality.
Description
(1) technical field:
The present invention relates to the chemoluminescence field, particularly a kind of chemoluminescence goods that emit white light.
(2) background technology:
Chemoluminescence is to utilize the different chemical matter interaction and the visible light sent out, United States Patent (USP) 3576987, patents such as 4313843,4508642 all are described in detail chemiluminescence principle and application, and the chemoluminescence goods of making different size by means of chemiluminescence principle are widely applied.According to chemiluminescence principle, the color of chemoluminescence goods is mainly determined by dyestuff kind of adding in the chemical luminescence for liquid and the material color of holding the plastics of chemical luminescence for liquid.The commercialization of chemoluminescence goods so far, the product glow color is purple, green by initial having only, yellow develops at present and can send orchid, orange, ruddiness again.The white light that needs of some application also is found, as U.S. Pat, among the pat.No.4678608, the white light of requirement has been used anthracene dye 9,10-diphenylanthrancene, 9,10-phenylacetylene base anthracene, 9,10-phenylacetylene base-1-chrloroanthracene Tong perylene based dye (N, N '-two (2, the 5-di-tert-butyl-phenyl)-3,4,9,10-two carbonyl Xian An perylenes) composite mixing is to produce white light.But the light intensity of the Shang Shu perylene of You Yu based dye generation for chemoluminescence is very weak, only color is had contribution in whole prescription, and very little to the light intensity contribution, Bing Qie perylene based dye costs an arm and a leg, and can cause product cost to rise.
(3) summary of the invention:
The object of the present invention is to provide a kind of chemoluminescence goods that emit white light, the light intensity that this kind light emitting articles produces white light is better than existing goods, and can reduce production costs.
Technical scheme of the present invention: a kind of chemoluminescence goods that emit white light, it is characterized in that it is made of chemoluminescence solution and the outer plastic packing material that holds chemoluminescence solution, said chemoluminescence solution contains the organic solution that barkite and dyestuff constitute by the organic solution that contains hydrogen peroxide with another kind to be formed, the light intensity that both ratios need with suitable generation and deciding; Said dyestuff is to get single anthracene dye, and the said outer plastic packing material that holds chemoluminescence solution is to get that to have red and/or yellow be the outer plastic packing material of color.
The above-mentioned said organic solution that contains hydrogen peroxide is fixed conventional ratio with the light intensity that produces needs with the ratio that another kind contains the chemoluminescence solution that organic solution that barkite and dyestuff constitute forms.
Above-mentioned said barkite is 2,4, and 5-three chloro-6-carbonyl amyl group phenyl oxalate esters with an organic solvent are ester class, ethers, halohydrocarbon usually.
Above-mentioned said anthracene dye is the mixture of two or more kinds.
The anthracene dye that the mixture of above-mentioned said two or more kinds constitutes can be:
The first 9,10-diphenylanthrancene and/or 9,10-two (4-p-methoxy-phenyl) anthracene;
It two is 9,10-tolane base anthracene and/or 9,10-tolane base-1-chrloroanthracene and/or 1,8-two chloro-9,10-tolane base anthracene;
The add-on of said dyestuff is with 9,10-diphenylanthrancene and/or 9,10-two (4-p-methoxy-phenyl) anthracene is a benchmark, 9,10-tolane base anthracene and/or 9,10-tolane-1-chrloroanthracene and/or 1,8-two chloro-9, the add-on and 9 of 10-tolane base anthracene, 10-diphenylanthrancene and/or 9, the mol ratio of the adding of 10-two (4-p-methoxy-phenyl) anthracene is 1 * 10
-1To 1 * 10
-3
Above-mentionedly saidly hold getting of chemoluminescence solution and have red and/or yellow to be that the outer plastic packing material of color can be the multiple shape that can make according to mould, to comprise tubulose and other three-dimensional shape of multiple shaped cross.
The above-mentioned said desirable entire body of outer plastic packing material of holding chemoluminescence solution is of the same colour, and to have red and/or yellow be the outer plastic packing material of color, also desirable part is red and/or yellow to be the outer plastic packing material of color, and other look outer plastic packing material is got at other position.The colour mixture outer plastic packing material that holds chemoluminescence solution has White Patches coloured light and the effect of other color of light is sent out at other position.
Above-mentioned said chemoluminescence goods can be made new molectron again with other goods or material.
Principle of work of the present invention is: having red and/or yellow is that the outer plastic packing material of color holds its inside and outside coefficient effect of color of anthracene dye chemical luminescence for liquid wherein, can make light emitting articles send strong white light.
Superiority of the present invention is: 1, adopting single anthracene dye to be aided with red and/or yellow as the dye well of chemoluminescence solution is the outer packaging thing of plastic material, this reasonable combination has produced the new production approach of strong white light chemoluminescence pipe, in theoretical and application bigger value is arranged; 2, this reasonable combination makes the chemoluminescence pipe light intensity that turns white that raising arranged, and has reduced the production cost of goods simultaneously, thereby makes its application have bigger economy and ubiquity widely.
(4) embodiment:
Embodiment 1: to be equipped with red and yellow be the outer plastic packing material of color of being mixed to chemical luminescence for liquid to adopt the composite dye preparation of 9.10-diphenylanthrancene and 9.10-tolane base anthracene to emit white light, the add-on of dyestuff is with 9, the 10-diphenylanthrancene is a benchmark, get 9, the mol ratio of the adding of 10-tolane base anthracene is 1 * 10
-1, its inside and outside color acting in conjunction becomes the chemoluminescence pipe that emits white light.
The add-on of dyestuff is with 9,10-diphenylanthrancene and/or 9,10-two (4-p-methoxy-phenyl) anthracene is a benchmark, 9,10-tolane base anthracene and/or 9,10-tolane-1-chrloroanthracene and/or 1,8-two chloro-9, the add-on and 9 of 10-tolane base anthracene, 10-diphenylanthrancene and/or 9, the mol ratio of the adding of 10-two (4-p-methoxy-phenyl) anthracene is 1 * 10
-1To 1 * 10
-3
Embodiment 2: adopt the chemical luminescence for liquid that emits white light of single anthracene dye, be aided with the be mixed outer plastic packing material of color of the red and yellow system of entire body and make the chemoluminescence goods that all emit white light.
Embodiment 3: the chemical luminescence for liquid that emits white light that adopts single anthracene dye, be aided with local red and yellow be mixed outer plastic packing material, other position of color be red and/or yellow be the outer plastic packing material of color color in addition, make the chemoluminescence goods of the light that White Patches light, other position sends out color other.These chemoluminescence goods have the effect of different sites different colours.Or some positions are that the plastic raw materials true qualities make the chemoluminescence goods send white light at the position with the specific color that emits white light.
Embodiment 4: the chemoluminescence goods that adopt routine 1-3 to make can be made new molectron again with other goods or material.
The compound method of chemical luminescence for liquid: use the said single anthracene dye of this case, send white light after chemical luminescence for liquid that uses other general component of chemical luminescence for liquid and general compound method to prepare simultaneously to emit white light and available usual method make its activation.
Using said single anthracene dye of this case and the red and/or yellow of outer plastic packing material is the pigment of color, uses plastic materials such as polyethylene, polypropylene, the chemoluminescence goods that adopt general working method promptly to can be made into to emit white light.
Claims (8)
1, a kind of chemoluminescence goods that emit white light, it is characterized in that it is made of chemoluminescence solution and the outer plastic packing material that holds chemoluminescence solution, said chemoluminescence solution contains the organic solution that barkite and dyestuff constitute by the organic solution that contains hydrogen peroxide with another kind to be formed, the light intensity that both ratios need with suitable generation and deciding; Said dyestuff is to get single anthracene dye, and the said outer plastic packing material that holds chemoluminescence solution is to get that to have red and/or yellow be the outer plastic packing material of color.
2,, it is characterized in that the said organic solution that contains hydrogen peroxide is fixed conventional ratio with the light intensity that produces needs with the ratio that another kind contains the chemoluminescence solution that organic solution that barkite and dyestuff constitute forms according to the said a kind of chemoluminescence goods that emit white light of claim 1.
3, according to the said a kind of chemoluminescence goods that emit white light of claim 1, it is characterized in that said barkite is 2,4,5-three chloro-6-carbonyl amyl group phenyl oxalate esters with an organic solvent are ester class, ethers, halohydrocarbon usually.
4, according to the said a kind of chemoluminescence goods that emit white light of claim 1, it is characterized in that said anthracene dye is the mixture of two or more kinds.
5,, it is characterized in that the anthracene dye of the mixture formation of said two or more kinds can be according to the said a kind of chemoluminescence goods that emit white light of claim 4:
The first 9,10-diphenylanthrancene and/or 9,10-two (4-p-methoxy-phenyl) anthracene;
It two is 9,10-tolane base anthracene and/or 9,10-tolane base-1-chrloroanthracene and/or 1,8-two chloro-9,10-tolane base anthracene;
The add-on of said dyestuff is with 9,10-diphenylanthrancene and/or 9,10-two (4-p-methoxy-phenyl) anthracene is a benchmark, 9,10-tolane base anthracene and/or 9,10-tolane-1-chrloroanthracene and/or 1,8-two chloro-9, the add-on and 9 of 10-tolane base anthracene, 10-diphenylanthrancene and/or 9, the mol ratio of the adding of 10-two (4-p-methoxy-phenyl) anthracene is 1 * 10
-1To 1 * 10
-3
6, according to the said a kind of chemoluminescence goods that emit white light of claim 1, it is characterized in that saidly holding getting of chemoluminescence solution and having red and/or yellow to be that the outer plastic packing material of color can be the multiple shape that can make according to mould, to comprise tubulose and other three-dimensional shape of multiple shaped cross.
7, according to the said a kind of chemoluminescence goods that emit white light of claim 1, it is characterized in that the said desirable entire body of outer plastic packing material of holding chemoluminescence solution of the same colour to have red and/or yellow be the outer plastic packing material of color, also desirable part is red and/or yellow to be the outer plastic packing material of color, and other look outer plastic packing material is got at other position.
8, a kind of application according to the said a kind of chemoluminescence goods that emit white light of claim 1 is characterized in that the chemoluminescence goods of said white light can be made new molectron again with other goods or material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031020119A CN1214088C (en) | 2003-01-28 | 2003-01-28 | White-light emitting chemiluminescent product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031020119A CN1214088C (en) | 2003-01-28 | 2003-01-28 | White-light emitting chemiluminescent product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1448462A CN1448462A (en) | 2003-10-15 |
| CN1214088C true CN1214088C (en) | 2005-08-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031020119A Expired - Fee Related CN1214088C (en) | 2003-01-28 | 2003-01-28 | White-light emitting chemiluminescent product |
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| Country | Link |
|---|---|
| CN (1) | CN1214088C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100422284C (en) * | 2004-03-25 | 2008-10-01 | 金朝阳 | Chemiluminescent composition |
| KR100893034B1 (en) * | 2004-04-27 | 2009-04-15 | 가부시키가이샤 루미카 | Chemiluminescent compositions |
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2003
- 2003-01-28 CN CNB031020119A patent/CN1214088C/en not_active Expired - Fee Related
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| CN1448462A (en) | 2003-10-15 |
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