JP2016002648A - Diamond bonding tools - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide diamond bonding tools which can reduce the amount of diamond abrasive particles and, therefore, is extremely economical.SOLUTION: Diamond bonding tools have such a configuration that non-peelable metal-coat diamond prepared by non-peelably coating diamond surfaces with metal is bonded to a metal part of the tools. In the concrete, the diamond bonding tools are scriber point (wafer cutting cutter) 10, a brazing type pivot, a brazing type pivot bearing, a measurement terminal, a forming dresser, a large-scale measurement terminal, a diamond sliding surface, a shaft core measuring device, a soldering iron, thermal relations (for example, a heat-sensitive sensor for measuring temperature), acoustic relations (acoustic sensitive lever, record reproducing needle), electric relations (heat sink for power IC, a circuit), a window, a gimlet, drill relations and the like. The scriber point 10 is made by connecting metal coat 11b of the non-peelable metal-coat diamond 11 to flat edge parts of a rod-like metallic base stand 12. Bonding surfaces of the edge parts get to a brazing surface 13.

Description

  The present invention relates to a diamond bonding tool that is bonded to a tool after a non-peelable metal coating is applied to the diamond surface. More specifically, a scriber point, a butt joint pivot, a butt joint pivot bearing, a measuring terminal, a forming dresser, a large measuring terminal, a diamond sliding surface, a shaft measuring device, a soldering iron, provided with a non-peelable metal-coated diamond. It relates to tools such as thermal relationship (for example, temperature sensor for temperature measurement), acoustic relationship (acoustic sensing lever, record reproducing needle), electrical relationship (heat sink for power IC, circuit), window, drill, drill relationship and the like.

  First, diamond will be described. Diamond is generally an aggregate of carbon, such as charcoal and graphite, and has a chemical symbol of “C” and an element number of 16. However, the difference from carbon is that the inter-element distance of the diamond crystal lattice is half that of the graphite crystal lattice. In terms of appearance, it is not a graphite black but a transparent crystal.

  Diamond crystals have previously been melted in an environment of 30,000 atmospheres and 3,000 ° C, and solidified into graphite and gas without being diffused by rapid changes in the crust (decompression). It was thought that it became.

Has been produced. Conductive diamond has also been developed by doping certain elements. Furthermore, polycrystalline diamond (poly-crystallin diamond = PCD) is also produced without changing the properties of diamond by applying high temperature and pressure to the diamond fine powder with a special binder.

    The main physical and chemical properties of diamonds known today, including natural and artificial, are as follows.

1) Crystal Type A diamond crystal has an equiaxed crystal shape (tetragonal shape) as shown in FIGS. 1 to 4 and a plurality of different crystal shapes and complex shapes.
The hexahedron type (dice-like hexahedron) diamond crystal shown in FIG. 1 rarely exists in nature.
FIG. 1 (a) shows a cube-shaped positive hexahedron type diamond crystal 1a that is rarely produced but rarely produced from nature. The plane orientation is (1.0.0.).
FIG. 1B shows an icosahedral octa-octahexedron type diamond crystal 1b having a large (1.0.0.) Plane, (1.1.0.) Plane, and (1.1. 1.) The surface changes in size and becomes cubic.
The octa-octahexedron type diamond crystal 1c in FIG. 1 (c) represents a state when the surface is burned due to environmental changes.
Thus, various crystal structures are also known for hexahedron diamond crystals.
The octahedron (octahedron, octagonal octahedron, and atypical) type diamond crystal shown in FIG. 2 is the main crystal shape of the diamond crystal.
FIG. 2 (a) shows a positive octahedron type diamond crystal 2a having all crystal planes of (1.1.1.) Plane.
FIG. 2B shows a modified octahedron-type diamond crystal 2b obtained by extending a regular octahedron in the (1.1.0.) Plane orientation. The plane orientation of the positive octahedron-type diamond crystal 2a in FIG. 2 (a) is (1.1.1.) Plane and has a cleavage property parallel to all the eight faces. Surface polishing and finishing are considered to be extremely difficult techniques.
The dodecahedron type (with dodecahedron, rhombic dodecahedron, and variant) diamond crystal shown in FIG. 3 is also the main crystal shape of the diamond crystal.
The dodecahedron-type diamond crystal 3a in FIG. 3 (a) is naturally produced in a spherical shape and a flat shape.
The deformed dodecahedron type diamond crystal 3b shown in FIG. 3B has a (1.1.0.) Plane on all sides. The plane orientation of the dodecahedron type diamond crystal 3a shown in FIG. 3 (a) is (1.1.0.) Plane, and it is often produced in a flat type rather than a spherical body in nature.
Hexaoctahedron type diamond crystals 4a and 4b shown in FIGS. 4 (a) and 4 (b) are hexahedrons and are the mainstream of artificial diamond crystals. Recently, even in artificial diamond crystals, the existence of octahedron type has been confirmed in artificial diamonds having a small particle size of about 500 pce (grain) / carat (200 mg). Hexaoctahedron diamond crystals are the main crystal shape of conventional high-pressure synthetic diamond for tools. Many diamond crystals produced from nature are hexa-octahedral diamond crystals. In recent years, even artificial diamonds have been made with natural, unchanging quality diamonds by changing the catalyst, pressure and temperature.
Naturally produced natural crystals may be produced in a polyhedral structure depending on various conditions such as environment and components, but the polyhedron seen industrially is mainly the above structure.
2) Chemical resistance Not violated by ordinary acids and alkalis.
3) Combustion temperature In the atmosphere, combustion starts at 650 ° C., generally 700 ° C. under favorable conditions. Transition to graphite due to loosening of interatomic bonds at 2000 ° C. in vacuum.
4) Hardness The hardest substance in the world. There is some unevenness depending on the crystal orientation.
5) Heat transfer The heat transfer rate is the fastest among the substances in the world.
6) Sound transmission speed The fastest sound transmission speed of any substance in the world.
7) Chemical properties When diamond is put into a chemical substance that is melted at a high temperature of 700 ° C. or higher in a burning substance, it reacts with oxygen in the atmosphere and burns. However, it has been evaluated as a stable substance except that it burns under such high temperature conditions.

  On the other hand, diamond is not only used as a decorative product, but is also used in industrial fields. There is a great demand as a tool for civil engineering work, such as road cutters, from parts processing of ultra-precision industrial products.

  Naturally produced diamonds are excellent in hardness and strength, but especially medical (surgery scalpels, microtomes, etc.), physics and chemistry (heat sinks, chemical resistant windows, acoustic systems, etc.), and even industrial use. However, precision metal cutting systems (such as surface finishes for watch parts and ultra-precision parts) often require higher quality in terms of performance and quality than diamond for decorative jewelry.

  However, it has been recognized worldwide that diamonds cannot be completely bonded to metal. For this reason, it has been impossible to use the raw stone used in a compact form with a small size. When manufacturing the tool, it was necessary to use a caulking or structurally large holding method for the purpose of fixing.

  Furthermore, even if the abrasive grains are referred to as fixed abrasive grains, the gripping force is reduced due to impact during machining as a tool because the metal matrix and organic synthetic adhesive matrix that are fixed are not completely bonded. The method of use has been mainstream because it has been reduced, dropped and discarded in the middle of work, leading to a reduction in work capacity.

  As described above, diamond has been conventionally evaluated as being chemically inert. Also, it does not react with any metal, and diamond easily falls off in the metal matrix due to the impact of processing.

  Therefore, there has been a long-awaited development of technology that enables sufficient strength of use and service life regardless of whether the tools are bonded with diamond, regardless of whether they are large or small.

  Under such a demand, the inventor found a non-releasable metal-coated diamond in “Patent Document 1”. And patented. Patent Document 1 shows that diamond and metal are chemically bonded (coexisting bonds) by a chemical reaction (coexistence reaction), and diamond has chemical activity.

In general, in the bonding of different elements, the properties of the basic elements are almost lost and the reaction partners are completely different. For example, aluminum oxide (Al ₂ O ₃ ) is produced by oxidation of aluminum, but aluminum melts at a low melting point, that is, about 660 ° C., and exhibits good conductivity. On the other hand, in aluminum oxide in which oxygen is bonded to aluminum, the melting point jumps to 2050 ° C., and the conductivity becomes equal to zero. In this way, the material before the reaction and the heterogeneous reaction product have similar properties even if they are similar.

  On the other hand, in the non-peelable metal-coated diamond according to the technique of Patent Document 1, the diamond portion maintains the properties of diamond at the boundary between the diamond and the metal coating, and the metal-coated portion maintains the original properties of the metal. It is. The metal-coated portion can be brought into contact with other metals.

  And in order to measure the coating strength of the diamond and the coated metal of the non-peelable metal-coated diamond of Patent Document 1, a metal rod (φ2 mm) is brazed perpendicularly to the diamond plane and a tensile test with a force of 25 kg or more (5 Example). As a result, the metal was covered with the metal coating and the metal rod, and the diamond and metal coating were not peeled off or separated from each other. The same phenomenon was observed in all five tests. Eventually, the bond strength between diamond and metal coating could not be measured.

  Brazing is a process of joining metals together, and metal can never be brazed to diamond. On the other hand, in the non-peelable metal-coated diamond of Patent Document 1, other metal can be in contact with the surface metal coating, and when the metal coating other than the indented portion is polished, the transparency and hardness of the diamond are exposed, It can be seen that the properties of diamond are maintained. In the technique of Patent Document 1, it was considered that diamond and the metal coating were firmly bonded without changing the properties of each other.

  In the non-peelable metal-coated diamond of Patent Document 1, since the bonding is firmly performed on the bonding surface without changing the properties of the diamond and the metal coating, the reaction is called a coexistence reaction, and the bond generated by the reaction is called It was called coexistence bond.

    In the invention of Patent Document 1, the father of the inventor, Yoshio Ogura, who supplied the record needle, joined the expensive diamond needle, and the diamond of the required size to the tip of the metal rod. It was conceived to buy diamond needles at low cost from customers. The present invention has been found and completed when the inventor realized a diamond needle for record reproduction in which diamond is bonded to a metal rod.

    In addition, in the non-peelable metal-coated diamond of Patent Document 1, there was a defect that the welding fails. The drawback was manifested due to the difference in expansion coefficient between the diamond and the metal in contact with the metal because the metal coating was firmly bonded to the diamond, and occurred during cooling after the heat welding. It occurred more frequently as the adjacent stones became larger. Therefore, it was necessary to select a metal material close to the expansion coefficient of diamond as the metal to be welded.

  The invention of Patent Document 1 has changed the way of thinking of almost all products that use diamond for industrial purposes.

Japanese Patent No. 5127007

  However, in patent document 1, the specific application example of the non-peelable metal-coated diamond could not be shown.

  Accordingly, the object of the present invention is to provide a specific application method to tools of non-peelable metal-coated diamond obtained by a method of non-peeling a metal on a diamond surface by chemical reaction. It is. More specifically, tools with higher workability, operability, economy, etc. can be obtained by applying non-releasable metal coating to medical, scientific and industrial diamonds (natural and artificial diamonds in general). The purpose is to contribute to social development by providing products and parts.

In order to solve the above problems, the present invention
(1)
A diamond bonding tool characterized in that a non-releasable metal-coated diamond in which a metal is non-removably coated on a diamond surface is bonded to a metal part of the tool.
(2)
Disintegration aid for preventing non-peelable metal-coated diamond from being baked and mixed with either a mixed powder of diamond, Cr metal powder and Cr oxide powder, or a single Cr metal powder and promoting disintegration of the cooling mixture A non-releasable metal-coated diamond obtained by heating, causing the metal powder and the diamond surface to chemically react in the air, cooling the mixture, and separating and recovering the metal-coated diamond. The diamond joining tool according to (1), which is characterized.
(3)
The disintegration aid is a disintegration aid that does not react with diamond even if it coexists with diamond at 1150 ° C. to 1160 ° C. and does not inhibit the chemical reaction between the coexisting Cr metal powder and / or Cr oxide and diamond. The diamond bonding tool according to (2), which is characterized.
(4)
The disintegration aid is one or more selected from silicon carbide, silicon oxide, tungsten, tungsten carbide, chromium oxide, aluminum oxide, magnesium oxide, cubic boron nitride, and zirconia oxide. The diamond joining tools according to (3).
(5)
(1) to (4), wherein the metal powder is Cr metal powder, and the Cr metal powder and the disintegration aid are blended at a weight ratio of 1: 1 to 1: 5. Diamond joining tools.
(6)
The diamond joining tool according to any one of (1) to (5), wherein the diamond is diamond obtained by applying a metal coating inhibitor to a portion that does not require a non-peelable metal coating.
(7)
The diamond coating tool according to (6), wherein the metal coating inhibitor is a metal coating inhibitor obtained by mixing a powder of a disintegration aid in a solution of 30% pure water and 70% water glass.
(8)
The diamond joining tools according to (1) to (7) use the metal portion of the tools as a scriber point base metal, and put the metal-coated portion of the non-peelable metal-coated diamond on the end of the base metal. A scriber point characterized by contact.
(9)
The diamond joining tools according to (1) to (7) are configured such that the metal portion of the tools is a pivot bearing shaft, and the end portion of the shaft is in contact with the metal coating portion of the non-peelable metal-coated diamond. A pivoting pivot bearing characterized by
(10)
The diamond bonding tool according to any one of (1) to (7), wherein the metal portion of the tool is a pivot shaft, and an end portion of the shaft is provided with a receiving surface of a pivot shaft that is recessed in an arc shape. A pivot-type pivot bearing characterized by comprising a metal-coated portion of a conductive metal-coated diamond.
(11)
The diamond joining tools according to (1) to (7) are configured such that the metal portion of the tools is a shaft of a metal sensor, and the end portion of the shaft is in contact with the metal covering portion of the non-peelable metal-coated diamond. A measuring terminal characterized by
(12)
The diamond joining tools according to any one of (1) to (7) use a metal portion of the tools as a base of a forming dresser, and a metal coating portion of the non-peelable metal-coated diamond in a groove at an end of the base Forming dresser, characterized by being in contact with each other.
(13)
The diamond joining tools according to (1) to (7) have a metal portion of the tools as a sensor shaft, and a plurality of spherical non-peelable metal-coated diamonds are arranged at the end of the shaft. In addition, a measuring terminal is formed by joining a metal material that is in contact with the metal coating portion.
(14)
The diamond joining tools according to (1) to (7) use a metal portion of the tools as a sensor shaft, and spread a plurality of plate-like non-peelable metal-coated diamonds on the end of the shaft. And a measuring terminal characterized by being in contact with the metal covering portion.
(15)
(1) to (7), wherein the diamond bonding tools have a metal part of the tools as a base metal of a rocking surface, and a metal material to be joined to a groove on the upper surface of the base metal or to the base metal A diamond oscillating surface comprising a plurality of spherical non-peelable metal-coated diamonds disposed in the grooves and polished by contact with the metal-coated portion and then polished to form a flat surface.
(16)
(1) to (7), in the diamond joining tools, the metal portion of the tools is a base metal of a rocking surface, and a plurality of plate-like non-peelable metal-coated diamonds are formed on the top surface of the base metal. A diamond oscillating surface characterized by being flattened by polishing after being laid down and in contact with the metal coating portion.
(17)
A groove having a V-shaped cross section is provided on the top surface of the non-peelable metal-coated diamond of the saddle-type pivot bearing described in (9), and the non-peelable metal-coated diamond molded into a conical shape is welded to the tip of the pivot shaft. A V-shaped endstone and a pivot bearing structure.
(18)
A groove having a U-shaped cross section is provided on the upper surface of the non-peelable metal-coated diamond of the saddle-type pivot bearing described in (9), a hard ball is placed in the U-shaped groove, and a cross-section is provided at the tip of the pivot shaft. A U-shaped endstone and a pivot characterized by contacting a non-peelable metal-coated diamond provided with a substantially V-shaped groove and contacting the V-shaped groove of the non-peelable metal-coated diamond with the hard sphere. Bearing structure.
(19)
A ring jewel having a hole formed therein, a rotating shaft inserted into the hole and rotated and held, and an end stone in contact with a base metal with a non-peelable metal-coated diamond that contacts and holds the tip of the rotating shaft; A ring jewel and an end stone structure, comprising: an elastic body disposed on a bottom surface of the end soot; and a container for storing the end stone and the elastic body.
(20)
The diamond joining tools according to (1) to (7) are plate-like on a surface in which a metal portion of the tools is a bearing base of a shaft measuring bearing device, and an end portion of the bearing base is cut obliquely. A shaft measurement base for measuring the roundness and eccentricity of the shaft, characterized in that the metal coating portion of the non-peelable metal-coated diamond is used as a shaft measurement bearing.
(21)
(2) The two shaft core measuring bearing bases described in (20) are arranged with their oblique surfaces facing each other, a V-shaped groove is formed, the shaft core is placed in the V-shaped groove, and the shaft core is rotated. And measuring the roundness and the eccentricity of the shaft core.
(22)
The shaft center measuring device according to (21), wherein the shaft measuring bearing is disposed above the V-shaped groove, and the shaft core is held on three surfaces.
(23)
The diamond joining tools according to (1) to (7) have a metal portion of the tools as a surface of a rotating shaft, and a spherical metal-coated portion of the non-peelable metal-coated diamond is formed on the surface of the rotating shaft. A rotating shaft comprising a non-releasable metal-coated diamond, wherein the rotating shaft is contacted and polished to form a finished surface, and is inserted into a cylinder serving as a bearing and rotated.
(24)
The diamond joining tools according to any one of (1) to (7), wherein the metal portion of the tools is a surface of an internal cavity of the bearing, and the spherical metal of the non-peelable metal-coated diamond is formed on the surface of the bearing cavity. A bearing comprising a non-releasable metal-coated diamond, characterized in that the coated portion is welded and polished, a finished surface is formed, and the rotating shaft is inserted and rotated.
(25)
A high heat capacity metal part, a non-peelable metal-coated diamond having a metal cover part in contact with the large heat capacity metal part, and an IC mounted on the diamond surface of the non-peelable metal-coated diamond. Power IC heat sink.
(26)
A temperature measurement sensor comprising: a sensor having a built-in temperature sensor; and a non-peelable metal-coated diamond in which a metal coating portion is in contact with a metal end portion of the sensor.
(27)
It consists of a metal temperature sensor and a non-peelable metal-coated diamond in which the metal coating part is in contact with the metal part of the temperature sensor, and the non-peelable metal-coated diamond is brought into direct contact with the object to be measured, A temperature measurement sensor characterized by measuring a temperature of a fluid to be measured.
(28)
A non-releasable metal-coated diamond, which is a needle tip having a metal coating that is non-peelingly coated on the bottom with a triangular pyramid or a triangular prism in contact with the sound groove of the record, and a diamond cantilever with a metal coating non-peeling at both ends And a coil bobbin, the metal coating of the non-peelable metal-coated diamond that is the needle tip and the metal coating of the cantilever are joined to one end of the cantilever, and the metal coating and the coil bobbin are joined to the other end. A diamond cantilever characterized by comprising
(29)
The diamond joining tools according to (1) to (7), wherein the metal portion of the tools is a tip portion of a metal rod of a soldering iron, and the tip portion of the metal rod is molded into a desired shape. The tip of a soldering iron characterized in that a metal-coated portion of a peelable metal-coated diamond is in contact.
(30)
Solder characterized by mixing non-peelable metal-coated diamond into a solder material.
(31)
Solder characterized by molding the solder according to (30) into a drop shape or a rod shape.
(32)
A non-releasable metal-coated diamond, wherein a circuit line is drawn with a conductive metal on a diamond surface, a non-peelable metal-coated diamond is formed with the diamond and the circuit line, and gold is in contact with the circuit line. circuit.
(33)
A non-peelable metal-coated diamond drawing, characterized in that a picture is drawn with a metal on a diamond surface, and a non-peelable metal-coated diamond is formed with the diamond and the metal.
(34)
A non-releasable metal-coated diamond window fitted between metal partitions with an interior space,
A non-releasable metal-coated diamond window characterized in that a metal coating portion is provided at a portion in contact with the partition wall, and the inner space can be monitored by being brazed to the partition wall by the metal coating portion.
(35)
The diamond joining tools according to (1) to (7) use the metal portion of the tools as a notch boundary of the end face of the rotating shaft, and a plurality of the non-peelable metal-coated diamonds having a square bar shape at the boundary. A non-peelable metal-coated diamond drill, which is arranged individually and is in contact with the metal-coated portion.
(36)
The diamond joining tools according to (1) to (7) use the metal portion of the tools as an end face of a rotating shaft, leave a balancer on the end face, and leave the balancer in a position balanced with the balancer. A non-releasable metal-coated diamond drill characterized by comprising a metal-coated diamond in contact with the metal-coated portion.
The configuration was as follows.

Incidentally, a method for producing a non-peelable metal diamond in which diamond is non-peeled metal-coated is disclosed in detail in Patent Document 1.
The gist of the invention is
(1)
A method of applying non-peelable metal coating to diamond in the atmosphere, comprising a mixed powder of diamond, Cr metal powder and Cr oxide powder, or a single metal powder of Cr metal powder, a disintegration aid, and a heating device. A first step to prepare, a second step in which the metal powder prepared in the first step, the disintegration aid and diamond are mixed and confined in a container; the container prepared in the second step is heated; and the metal powder and diamond A third step of chemically reacting the surface, a fourth step of taking out and cooling the container heated in the third step from a heating device, and cooling the mixture of the diamond, the metal powder and the disintegration aid, and the cooling mixture. And a fifth step of separating and recovering the metal-coated diamond from the metal, and the disintegration aid prevents the shrinkage and promotes the disintegration of the cooling mixture. Non peeling to a method for coating a metal by a chemical reaction Yamondo surface (claim 1),
(2)
The disintegration aid is a disintegration aid that does not react with diamond even if it coexists with diamond at 1150 ° C. to 1160 ° C. and does not inhibit the chemical reaction between the coexisting Cr metal powder and / or Cr oxide and diamond. (1) characterized in that the diamond surface according to (1) is coated with a metal non-peelingly by chemical reaction;
(3)
The disintegration aid is one or more selected from silicon carbide, silicon oxide, tungsten, tungsten carbide, chromium oxide, aluminum oxide, magnesium oxide, cubic boron nitride, and zirconia oxide. A method of non-peeling a metal coating on the diamond surface according to (2) by chemical reaction,
(4)
Any of (1) to (3), wherein the metal powder is Cr metal powder, and the Cr metal powder and the disintegration aid are blended at a weight ratio of 1: 1 to 1: 5. A method of non-peeling a metal on the diamond surface by chemical reaction,
(5)
The diamond surface according to any one of (1) to (4), wherein the diamond in the first step is a diamond in which a metal coating inhibitor treatment is applied to a portion that does not require a non-peelable metal coating. A method of non-peeling a metal coating by chemical reaction,
(6)
The non-peelable metal for diamond according to (5), wherein the metal coating inhibitor is a metal coating inhibitor obtained by mixing a powder of a disintegration aid in a solution of 30% pure water and 70% water glass. Coating method,
(7)
The method for joining diamond to metal according to any one of (1) to (4), comprising a sixth step of joining a metal to a non-peelable metal-coated portion of diamond after the fifth step. (Claim 7).

The pre-treatment and post-treatment for the non-peelable metal coating treatment are based on the following scheme.
(1) Prepare a material for applying a non-peelable metal coating.
(A) Using a single stone, shape and surface treatment according to the purpose,
a) Diamonds that require partial coating
b) Is it possible to coat the whole surface with diamonds?
(B) Is it possible to cover the entire surface by using abrasives, etc.
The diamond material is prepared according to the condition sorting.
(2) For (1) a), in order to apply the metal coating to the necessary parts, the resist is applied to the places where coating is not required.
(3) The non-peelable metal coating process is performed on the diamond material prepared as described above by the method shown in Patent Document 1.
(4) The non-releasable metal diamond obtained in (3) based on a) and b) of (1) is bonded to a base metal or a container with silver iron or solder, and further required as a tool for polishing and finishing processes. Send to.
(5) The non-releasable metal diamond obtained in (3) based on (B) in (1) is used as a material for abrasive grains such as general-purpose tools (including meshes and micron) and is provided to the tool manufacturing process.

  Since this invention is the said structure, the following effects are exhibited. As disclosed in Patent Document 1, the use of diamond is greatly changed by the discovery of the chemical activity of diamond at high temperatures and the invention of a non-peelable metal coating method utilizing this property. In the use of conventional diamond rough stone, non-peelable metal diamond that can be directly joined without using caulking and expensive large rough stones for fixing, the same quality diamond is cheaper and smaller. Can be realized. In the case of abrasive grains, it is possible to bond hard with metal by soldering or soldering, which greatly improves work and economy.

  For tools, etc., simply adding an appropriate amount of non-peelable metal-coated diamond to the conventional ingredients will greatly improve productivity, economic efficiency, etc. Expected to improve. In addition, the amount of conventional diamond abrasive grains can be reduced.

  That is, by using non-peelable metal-coated diamond in which diamond and metal are firmly bonded non-peelingly by a chemical reaction, the tool has less dropout and wear, and the service life of tools is greatly increased. Economical.

It is explanatory drawing 1 of a diamond crystal (hexahedronic type). It is explanatory drawing 2 of a diamond crystal (octahedron type). It is explanatory drawing 3 of a diamond crystal (dodecahedron type). It is explanatory drawing 4 of a diamond crystal (hexa octahedron type). It is explanatory drawing of the scriber point which contacted the non-peelable metal coating diamond to the rod-shaped metal base which is an example of embodiment of this invention. It is explanatory drawing of the pivot and pivot receiver which contacted the non-peelable metal-coated diamond to the rod-shaped metal rod which is an example of embodiment of this invention. It is an application example of a measurement terminal. It is an application example of a forming dresser. This is an application of a large measuring terminal. This is an application of the diamond sliding surface. It is explanatory drawing about an end stone. It is explanatory drawing about an end stone. It is explanatory drawing about the combination of an end stone and a ring jewel. It is an application example of the bearing for shaft center measurement. This is an application example to a rotating shaft and bearing that rotate in a cylinder. This is an application example of a power IC to a heat sink. It is an application example to a temperature measurement sensor. It is an application example to a temperature measuring sensor for fluid. This is an example of application to a diamond cantilever. This is an example of application to the tip of a soldering iron. It is explanatory drawing of a non-peelable metal coating diamond window. It is explanatory drawing of a non-peelable metal coating diamond window. It is explanatory drawing of a non-peelable metal coating diamond drill. It is explanatory drawing of a non-peelable metal-coated diamond drill.

  Embodiments of the present invention will be described below in detail with reference to the accompanying drawings. In addition, this invention is not limited to the following Example.

First, an outline of these embodiments will be described.
(1) Tool FIGS. 5 to 15 are examples of the tool and parts of the present invention in which non-peelable metal-coated diamond is in contact. FIGS. 5 to 8 are examples of a single stone tool, and FIGS. 9 to 15 are examples of tools and parts in which a plurality of non-peelable metal-coated diamond grains are arranged and in contact with each other. When a plurality of non-peelable metal-coated diamonds are arranged, the crystal plane orientation may be taken into account, but depending on the application, the crystal orientation need not be considered.

  The tools that have contacted a single stone non-peelable metal-coated diamond include record regeneration needles, writing pens, engraving pens, various engraving swords, medical scalpels, sword tips, tools, dressers, scriber points (Fig. 5), A pivot (FIG. 6), a measurement terminal (FIG. 7), a single stone homing dresser (FIG. 8), etc. can be illustrated. When the non-peelable metal-coated diamond of Patent Document 1 is in contact with the metal portion of the tools as in the present invention, the tools can be miniaturized. And by miniaturizing the tools, it is possible to miniaturize precision parts.

  The conventional single stone tool is manufactured by making the diamond large and fixing it with holding metal fittings or supporting the fixing with powder metallurgy because diamond and metal base metal could not be joined. It was impossible.

  As an example in which a plurality of non-peelable metal-coated diamond grains are arranged in alignment and in close contact with each other, each side has the same dimensions, such as a polylithic forming dresser (Fig. 8), a triangular square hexagon, and the like. A material (FIG. 9) having a polished surface constituting a plane can be exemplified. It is used especially when enlargement is impossible due to the difference in expansion coefficient. For example, sliding surface (Fig. 10), end stone (Fig. 11), two surfaces are arranged in the front and back as 60-120 ° V shape, shaft core measuring surface bearing (Fig. 14), shaft using three or more surfaces There are rotary bearings (Fig. 14) that are installed on both sides and have three or more points.

  A flat surface of a sphere whose surface is finished to the same size with a glossy surface, a flat surface that is finished by mirror-polishing to close to 40 to 45% of the sphere diameter by aligning in close packing, and in the case of a shaft or bearing (Fig. 15) In consideration of the diameter and inner diameter, non-peelable metal-coated diamond is brazed onto the outer surface of the shaft and the inner surface of the bearing and polished.

(2) Thermal relationship, acoustic relationship, electrical relationship, window relationship FIGS. 16 to 20 are examples in which the welding of non-peelable metal-coated diamond is applied to the thermal relationship, acoustic relationship, electrical relationship, and window relationship. FIGS. 16 and 17 are temperature sensors for temperature measurement, FIG. 18 is an acoustic sensing lever, a record reproducing needle, FIG. 19 is a heat sink for a power IC, and FIG. 20 is an application example to the tip of a soldering iron.

(A) Use of non-peelable metal-coated diamond as a heat sink and thermal sensor terminal for ICs, etc. Using the world's fastest heat transfer coefficient, wire with non-peelable metal coating on the surface of non-conductive diamond It is possible to use it as a heat sink (FIG. 16) such as a power IC with a non-peelable metal coating partially drawn. In this case, it should be noted that a material that can generate heat, such as a power IC, can be directly placed on one surface of diamond with fast heat transfer, and the opposite surface is fixed to a metal having a large heat capacity by brazing or soldering. It can be done. It is also possible to braze and fix a non-peelable metal-coated diamond to a thermal sensor terminal where metal contact is denied.

(B) Application of non-peelable metal-coated diamond to metal heating element for soldering One end of a round bar or square rod-shaped diamond is coated with non-peelable metal to provide a low-temperature soldering heating element that does not deteriorate the brazed part. I will give it. This is a powerful tool when it is necessary to avoid soldering heat generating metal from being mixed into the solder. Further, it is possible to avoid that the heat generating metal is gradually melted into the solder and deformed during soldering.

  When used as a crimp terminal, it can also be used as a thermocompression terminal (FIGS. 17 and 18). When used as a crimp terminal, a natural crystal (naturally produced industrial ore, artificially produced hydrostatic synthesis and microwave plasma) In the case of CVD diamond), it is required to consider and take into account the dynamic expansion coefficient due to crystal orientation. On the other hand, when polycrystalline diamond is used, it is not necessary to take account of the crystal orientation because it is evenly distributed, and it is not necessary to take into account the early and late temperature transmission orientation because of the homogeneity.

(C) Application to acoustic field
One of the characteristics of diamond is the speed of sound transmission. However, since diamond has been chemically inactive in the past, no metallic bond is formed, and the diamond is fixed using a “caulking” method or an adhesive having strength. For this reason, the acoustic transmission speed inherent in diamond has not been exhibited by the acoustic component (FIG. 19).

  In this case, the diamond was pressed with a force that did not crack or bend, or the adhesive strength was increased by applying a little more strong adhesive. By using coated diamond, the metal can be strongly welded with a small amount of brazing material, and the volume does not become larger than necessary to increase the strength as in the case of using an adhesive.

(D) Use as conductive diamond Conductive diamond can be used. A few conductive diamonds are naturally produced. On the other hand, it can be artificially obtained by doping boron with a certain amount of additive during diamond synthesis. A non-peelable metal coating is formed on one end of the conductive diamond, and it is completely grounded to the bonding metal by brazing to the sensor tip, so the grounding resistance is not taken into consideration, and the other end is processed into the required shape do it. Since this is not a metal terminal, it is possible to measure the electrical conductivity without the contamination of the metal fine powder due to the contact of the conventional metal terminal or the contact metal remaining by rubbing, which is a concern at the time of grounding. In this case, it is necessary to measure the resistance value of diamond with a measuring instrument with a measurement correction device.

  On the other hand, a technique for producing a non-peelable metal-coated diamond is developed, a conductive line is drawn on the surface of the non-conductive diamond, and a wiring (circuit) is formed on the diamond. It is also possible to apply gold plating on the wiring in order to ensure maintenance. The wiring brazed on diamond is stable until the diamond breaks, as described in the metal coating strength test above.

(D) Method of Drawing Line Drawing, Character, and Painting with Non-Releasable Metal on Diamond Surface This technique was invented based on the technique disclosed in Patent Document 1. It was devised as the best for the thing that requires efficient heat removal such as power IC on the surface of diamond with the world's fastest heat transfer rate.

  Traditionally, diamond has been used in the fields of science and industry, taking advantage of the characteristics of hardness. However, it is certain that diamond surface chemistry was stagnant due to the chemically inert nature of diamond. Therefore, Patent Document 1 is applied, and the diamond surface is drawn with a non-peelable metal coating, and a conductive gold plating or the like is applied on the diamond surface. Completed the parts.

1) Material (diamond)
a. Natural diamond surface b. Natural diamond cut and polished surface c. Surface of artificial diamond surface d. An artificial diamond cut and polished surface e. Surface of diamond synthesized by vapor phase f. Gas-phase synthesized diamond cut and polished surface g. Surface of insulating poly-crystallin diamond synthesized using inorganic material as catalyst h. Insulated poly-crystallin diamond synthesized using an inorganic material as a catalyst and cut and polished i. Other artificial diamonds synthesized with the same quality as natural diamonds and their processed products 2) Metal materials for line drawing A group. Metal powder a. Cr metal submicron powder b. Ni metal submicron powder c. Ni-Cr alloy metal submicron powder d. Ni-Cr-Fe stainless steel submicron powder B group. Metal thin wire e. Ni-Cr alloy wire
f. Ni-CrFe alloy fine wire As described above, the powder is used as it is, or an appropriate amount of Cr and Ni powder is mixed and suspended in an oil agent.
3) Oil agent A submicron pure metal or alloy powder is mixed in the oil agent and adhesively coated, and the material used to draw metal conductive lines and images on the diamond surface. It needs to be.
a. Drying oil at elevated temperature in vacuum b. Elution with a grease-like oil at the time of temperature rise and viscosity that does not flow to the diamond surface
c. Mixing PEG low and high chain substances with appropriate flexibility d. Good grease mixed with high-grade grease and low-grade grease e. Sublimable substances such as naphthalene 4) Inorganic materials Submicron SiO ₂ , Al ₂ O ₃ (silica), MgO (magnesia), etc. in water glass and other chemicals with an inorganic consistency are mixed with the viscosity of water glass. And draw or draw on the diamond surface.
5) Drawing method
a. Written by suspending the metal powder in the oil agent and drawing it, or drawing the oil agent in advance and scattering and spreading the metal powder.
b. Printing Metal powder is suspended in oil and is engraved in the form of a suspension grease.
c. Crimping
A room temperature transfer sheet that coats and transfers metal powder uniformly onto a sheet that conforms to the method on the left.
d. Thermocompression bonding c. This is a type of transfer (50 to 170 °) using heat during transfer.
e. Place a very thin oil coating on the diamond, and leave the finely bent metal wire.
f. Extrude Line drawing as a grease form in which metal powder is suspended in an oil from an ultra-fine hole needle, or draw oil grease and fix the metal powder on the grease.
g. High-temperature vapor deposition When a heat-resistant resist is coated on a diamond surface in a state where a non-peelable metal can be drawn, drawing is performed using the method of Patent Document 1, or surface-polished alumina, ceramics or silica Then, draw a line with a dent of reversal drawing on the glass, stuff the metal powder for drawing on the diamond surface into the dent, and align the drawn surface with the surface of the diamond.
h. Laser light Oil is applied on diamond, metal material powder is uniformly applied, and laser light is irradiated on it to draw.
i. Ultraviolet rays A metal material is mixed in an ultraviolet curable resin and applied uniformly.
The necessary lines, characters and images are drawn on the diamond surface.
6) Baking process equipment The heat source is at a maximum of 1,500 ° C, and it must be able to withstand long-term use in normal use at 1,200 ° C.
a. General electric furnace and gas furnace b. Vacuum furnace (including gas replacement such as hydrogen and carbon dioxide)
c. Dielectric furnace (including gas replacement such as vacuum and hydrogen carbonate gas)
By combining the above items 1) -6), it becomes possible to draw a non-peelable metal on the diamond surface using a hand-held equipment.
(Example 1)
It is optimal to perform 5) g high-temperature deposition on the diamond surface coated with resist as shown in 4) for all 1) and 2) A group, and 6) equipment uses a. Then, line drawing and drawing are possible.
(Example 2)
It is possible to perform drawing and drawing using all of 1), 2) all of B groups, 5) using the e-placement method of e, and 6) of b or c.
As described above, it is possible to draw a line drawing on the diamond surface by making full use of the work group of six items.

(E) Windows Recently, many measuring instruments have become smaller and have higher performance. Various sensors are also shifting to miniaturization and high performance. If the sensor or the like needs to be shielded from the outside air and needs internal monitoring, a non-peelable metal-coated diamond window may be provided (see FIGS. 21 and 22).

(F) Drill, drill Accurately locate the center point of the rotating shaft used for drilling (milling cutter), leave 1/4 of the end face of the shaft approximately the same weight as the diamond that touches (balancer), and remove the end face Finishing, brazing diamond with non-peelable metal coating in a 45-degree rotation direction from a point-symmetrical position with the balancer to make a precision milling cutter and precision engraving drill. Since the diamond can be contacted, the diamond can be fixed to the rotating shaft without fixing by caulking or pressing (see FIGS. 23 and 24).

(3) Use of non-peelable metal-coated diamond as an additive for grinding tools A grinding tool is a tool that uses a grindstone-shaped cutting tool while standing, a tool that uses a cutting tool such as a hand tool, and a rotating body. A tool that uses an electric drill or reamer as a grinder, a tool that is installed on a precision machine with numerical control, a cutting machine that requires a radius of several centimeters to 1 meter or more (including a load cutter), and forming Most heavy grinding tools, such as dressers, are manufactured with a technique of fixing diamond with metal bonds.

  However, since the diamond abrasive grains used do not have a non-peelable metal coating on the surface, the strength for grasping diamond in the tool is left to the bond strength. The diamond abrasive grains may fall off due to loose bonds while grinding the workpiece. This is because metals are firmly solidified by a fusion phenomenon at high temperatures, but diamond and metal do not have a fusion phenomenon.

  However, there are many cases in which the amount of metal bond or diamond (concentration) is determined for the material to be processed on the user side in the production process so far. Tools that contain diamonds, except for commercial products, can be used according to the characteristics of each company, such as the type of material to be ground, processing equipment, and coolant, in the processing operations and processing conditions at the supplier. Determines the amount of diamond used by understanding the main characteristics and sub-materials of the mixed powder metal, the manufacturing process that is characteristic of tool makers, and the performance and characteristics of diamond by the diamond supplier.

  In the future, the productivity and precision of the materials to be ground will be improved, and when planning to reduce the cost of products, it is expected that the hope can be fulfilled by appropriately mixing non-peelable metal-coated diamond.

  For this reason, the non-peelable metal coating may not be replaced suddenly for all amounts of diamond abrasive grains, but it is more closely bonded when the metal that is the silver candy component is used in the metal bond of the tool manufacturer. It shows a high strength. However, if the amount of mixing is increased darkly, a non-peelable metal-coated non-peelable metal-coated diamond flat surface is generated on the tool, creating a wear-resistant surface, which reduces grinding efficiency. Become.

  Furthermore, there is a concern that the processing tool itself becomes a wear-resistant part. For this reason, non-peelable metal-coated diamond should be gradually added to a conventional tool composition that matches the processing machine and workpiece, and the matching point of the mixing amount should be searched.

(4) Non-releasable metal-coated diamond-containing silver candy, solder Non-releasable metal-coated diamond-containing silver candy, solder shape is a flat sphere (drop), or a round bar or square bar type (bar (Material = bar), and the shape can be changed freely.
Natural diamonds, such as complete single crystals, are not collected in combination with other substances when they are produced, but are easily separated from the rocks that serve as the host rock. It is a great advantage and disadvantage of diamonds.

  In particular, when diamond is crushed and used as an abrasive grain, which is the hardest substance in the world, the strength of the material to be shaved exceeds the strength of the material gripping the diamond abrasive grain if the adhesion with other objects is not perfect. If it is, the phenomenon that the strong teeth loosen and fall off from the gums will occur, the metal holding the diamond abrasive will loosen, and the diamond will fall off and do not work .

  So everyone thinks about finding a stronger material that grips the diamond. However, as the work is repeated several times, a gap is formed between the grip and the diamond, and the abrasive grains fall off and finish.

  Therefore, in the coating strength measurement test, a non-peelable metal-coated diamond having a bonding performance such that the brazed surface is not non-peeled and the diamond is damaged is mixed in the iron material or leadless solder, and the iron plate It is possible to create a working tool by applying it to the required dimensions and shape, the surface of any metal material or used file, etc., and create a tool optimal for prototype processing.

(A) When adding non-peelable metal-coated diamond powder to a drop or bar Although there are differences in the effect depending on the size of the abrasive grains, it is important to consider not to make the abrasive grains dense as the diamond grains become larger It is. Even diamonds are crushed by force and shock, and the lower half of the abrasive grains is fixed to the base metal, so the upper half becomes a flat surface, as if a diamond flat surface was created, and the work piece The processing speed is reduced or processing becomes impossible.

  In many cases, a larger plane is formed as the mesh size is larger. The surface of the used file is thoroughly cleaned, and a non-peelable metal-coated diamond of an appropriate size can be brazed into a hole after the shaving blade of the file that has been worn away and regenerated. In addition, a cut is made on the outer periphery of the disk with the required dimensions, and the disk cut is filled and brazed using a drop bar or chip of non-peelable metal-coated diamond of the required size. Can be used as

  In this way, it is necessary to include the diamond abrasive grains in the brazing material and solder, and to make them flexibly correspond to the desired shape to manufacture the tool, which requires the necessary shape and dimensions. This has been a long-time demand for the processors.

(B) When obtaining the effect of diamond cutting edge by dispersing non-peelable metal-coated diamond moderately When non-peelable metal-coated diamond abrasive powder is mixed in brazing material or solder, it is coated at regular intervals. It is often difficult to fix to the material. In such a case, a hard metal (for example, a metal such as tungsten) or other abrasive grains (SiC, Al ₂ O ₃ , GC, etc.) that does not melt and mix with a glaze or solder of a mesh that is the same as diamond or a slightly smaller mesh. Prepare a heat-resistant material, or a dispersion agent (electroless or electrolytically plated Cu, Ni, Ag, etc. on the surface), mix and drop or bar to achieve the required surface dispersion value of diamond Is applied to a tool having a desired shape or a tool having an arbitrary shape, so that an optimum tool in which a well-dispersed non-peelable metal-coated diamond is bonded can be prepared by itself.

  Round bars and square bars in which non-peelable metal-coated diamonds are appropriately dispersed can be used as a file or a tool for expanding holes as they are, and can be easily thermally deformed to form pellets and required shapes. It can also be finished to form a file.

(C) When used as pellets
Conventional pellets are mixed in the metal matrix without processing diamond as described above, fixed to the pedestal, sliding or rotating, and necessary movement of the material to be ground, curved surface, uneven surface, etc. To shape the surface.

  In the present invention, a part of the diamond used in the conventional pellet is replaced with a non-peelable metal-coated diamond, or a non-peelable metal-coated diamond is added while bare diamond is mixed in a conventional pellet. By adding, it is possible to improve the wear speed of the tool and improve the finishing accuracy of the workpiece.

(D) Non-releasable metal-coated diamond-containing silver candy, solder is applied to a pedestal that has a required shape such as a wave shape or a dent, and the balance is adjusted. Luther for dental, ceramic, glass, plastic letters and drawings, etc. It can also be used as a drill or a grinding blade used in a grinder tool.

  As described above, a conventional tool or a new tool can be developed using the characteristics of the non-peelable metal-coated diamond.

  Hereinafter, embodiments of the present invention will be described more specifically with reference to the drawings.

  FIG. 5 is an explanatory diagram of a scriber point that is a rod-shaped tool in which a non-peelable metal-coated diamond is in contact with a rod-shaped metal pedestal that is an example of an embodiment of the present invention. 5A is a plan view, and FIG. 5B is a cross-sectional view taken along line AA in FIG.

  The scriber point 10 (wafer cutting cutter) is formed by joining a flat end of a rod-shaped metal base 12 with a metal coating 11b in which the hemispherical bottom surface of the diamond 11a of the non-peelable metal-coated diamond 11 is non-peeled. Become. Their joint surfaces become the brazing surfaces 13.

  In this embodiment, the non-peelable metal coating 11d may be brought into contact with the end of the base 12 of the metal rod, the unnecessary metal coating may be removed, and the diamond 11a may be polished, or the metal coating is partially performed in advance. Therefore, the scriber point 10 having the diamond 11a at the end can be easily manufactured regardless of the particle size of the diamond 11a. The scriber point 10 can be easily downsized. Moreover, compared with the conventional scriber point 14, the service life is dramatically increased.

  FIG.5 (c) is a top view of the conventional scriber point which equips an edge part with a diamond, (d) is the BB 'sectional view taken on the line of (c). The conventional scriber point 14 includes a holder 15 having a concave portion 15 a at the tip, a diamond 11 a located in the concave portion 15 a, and powder metallurgy 16 that fixes the diamond 11 a to the holder 15. Because of such a structure, the conventional scriber point 14 is not good in manufacturing workability and is extremely difficult to downsize. Further, since the diamond 11a is fixed using the powder metallurgy 16, the diamond 11a is dropped from the holder 15 before the diamond 11a is worn and cannot be used, and the service life is short.

  FIG. 6 is an example of an embodiment of the present invention. A barb pivot (a) (b), a barb pivot receiver (c), and a caulking system in which a non-peelable metal-coated diamond is barbed on a rod-shaped metal shaft. It is explanatory drawing of (d).

  FIG. 6A is a saddle-type pivot 17 (swivel axis), with the upper part being a front view and the lower part being a longitudinal sectional view thereof. The saddle-type pivot 17 is formed by joining the metal end 18b of the non-releasable metal-coated diamond 18 and the flat end of the shaft 19 which is a diamond 18a that is non-peeled to the bottom of the hemisphere 18b. Their joint surfaces become the brazing surfaces 20. It can be manufactured regardless of the size of the diamond 18a (the same applies to the next paragraph).

  FIG. 6B shows a saddle-type pivot 21 in which the shape of the diamond 22a is different from that in FIG. 6A. The diamond 18a in FIG. 6 (a) is substantially semicircular, and the diamond 22a of the non-peelable metal-coated diamond 22 in FIG. 6 (b) has an arcuate tip.

  FIG. 6C shows a saddle-type pivot bearing 23, in which the upper stage is a perspective view and the lower left and right are A-A ′ line longitudinal sections (the sizes of the receiving surfaces 24 c and 24 d are different). The butt-contact type pivot bearings 23, 23a are non-peeled with a metal coating 24b on the bottom surface, and a shaft 25 with a metal coating 24b of a non-peelable metal-coated diamond 24, which is a catch stone diamond 24a with recessed receiving surfaces 24c, 24d. It joins the edge part of. Their joint surfaces become the brazing surfaces 26. Since the receiving surfaces 24c and 24d are recessed at the center, it is difficult to round the small hole, but the outer frame is not required, so the pivot bearing can be downsized.

  FIG. 6D is a conventional caulking pivot 27, 27a, in which the upper end is a perspective view, the interruption is a B-B 'line cross-sectional view, and the lower part is a vertical cross-sectional view corresponding to another form of interruption. In the conventional caulking type pivot 27, the receiving diamond 28 is disposed in the groove 29a of the shaft 29, and the shaft 29 around the groove 29a is fastened to the stone diamond 28 side to fix the receiving diamond 28 to the shaft 29. . A conventional caulking pivot 27 a is different in shape from the caulking pivot 27. That is, the receiving diamond 28 is a diamond 28a, the shaft 29 is a shaft 29b, and the groove 29a is a groove 29c. Larger size is inevitable due to the problem of fixing strength (the same applies to the next paragraph).

  FIG. 6 (e) is a conventional caulking pivot receiver 30, in which the upper end is a perspective view, the interruption is a cross-sectional view taken along the line C-C ′, and the lower stage is a vertical cross-sectional view corresponding to an interruption of another form. In the conventional caulking type pivot receiver 30, a receiving stone 31 having a receiving surface 31 a is disposed in the groove 32 a of the shaft 32, and the shaft 32 around the groove 32 a is tightened to the stone diamond 31 side. Is fixed to the shaft 32.

  The conventional caulking type pivot receiver 30 a is different in shape from the caulking type pivot receiver 30. In other words, the receiving stone 31 having the recessed receiving surface 31a is the receiving diamond 31b having the receiving surface 31c, the shaft 32 is the shaft 32c, and the groove 32a is the groove 32d.

  FIG. 7 is an explanatory diagram of a measurement terminal having a diamond at the tip. The measurement terminal 33 includes a shaft 35 of a metal sensor and a non-peelable metal-coated diamond 34 that is in contact with an end portion of the shaft 35. The non-peelable metal-coated diamond 34 includes a diamond 34a and a metal coating 34b that is non-peelably coated on the bottom of the diamond 34a. The metal coating 34 b and the shaft 35 are joined at the butt surface 36.

  An example of the measurement terminal 33 is a surface roughness measurement terminal. Since the surface roughness measuring terminal scans on the surface of the substance, wear resistance and polishing accuracy are required. It is preferable to use the tip of the record needle reproducing needle which is sharpened and is finished with high accuracy in contact with the shaft 35. Even when the diamond 34a contacts the object at a point or at a surface, the R accuracy of the plane is required. The shape and size of the diamond 34a are selected according to the shape and size of the object to be measured.

  FIG. 8 is an explanatory diagram of a forming dresser using single-stone and multi-stone non-peelable metal-coated diamond. FIG. 8A is a single stone forming dresser, FIG. 8B is a multi-stone forming dresser, the upper part is a front view, and the lower part is a longitudinal sectional view. The right column is a conventional forming dresser.

  The forming dresser is generally used to shape a grindstone into a desired shape, grind an object to be ground with the grindstone, and when the grindstone is worn or deformed, the grindstone is shaved so that it can be reused.

  As shown in the left column of FIG. 8A, the non-peelable metal-coated diamond monolith forming dresser 37 includes a base metal 39 having a triangular pyramid-shaped groove 39a at a rod-shaped end, and a groove 39a of the base metal 39. And non-releasable metal-coated diamond 38 brazed at the butted surface 40. The non-peelable metal-coated diamond 38 is composed of a metal coating 38b that is non-peelably coated on the surface of the bottom triangular pyramid of the diamond 38a having a shape obtained by combining the bottom surfaces of two triangular pyramids. The metal coating 38 b is joined to the base metal 39 at the flange surface 40.

  Since the non-peelable metal-coated diamond 38 is in contact with the base metal 39, the manufacturing, re-polishing, and adjustment operations are simplified without requiring knowledge and experience as in the conventional powder metallurgical sintering fixation. Strength is increased by making the contact surface 40 a triangular pyramid. The same applies to Example 6.

  On the other hand, as shown in the right column of FIG. 8 (a), a conventional diamond monolith forming dresser 41 includes a base metal 43 provided with a groove 43a at a rod-like end, and a powder metallurgy located in the groove 43a of the base metal 43. The diamond 42 is fixed by the sintered fixing portion 44 that has been sintered. Sintering and fixing the diamond 42 and processing into the desired shape require a high degree of knowledge and long experience. Also, the frequency of dropout during use is high. The same applies to the conventional multi-stone forming dresser of Example 6.

  As shown in the left column of FIG. 8B, the non-peelable metal-coated diamond polylithic forming dresser 45 includes a base metal 47 having a plurality of triangular pyramid-shaped grooves 47 a at a rod-like end, It consists of a non-peelable metal-coated diamond 46 brazed to the groove 47a at the butt surface 48. The non-peelable metal-coated diamond 46 is composed of a metal coating 46b that is non-peelably coated on the surface of the bottom triangular pyramid of the diamond 46a having a shape in which the bottom surfaces of two triangular pyramids are combined.

  On the other hand, as shown in the right column of FIG. 8 (b), the conventional diamond polylithic forming dresser 49 includes a base metal 51 provided with a plurality of grooves 51a at a rod-shaped end, and a powder positioned in the grooves 51a of the base metal 51. It consists of diamond 50 fixed by a sintered fixing part 52 obtained by sintering metallurgical metal. Conventionally, expensive long diamond was buried in order to achieve stable fixation, and the cost was high.

  FIG. 9 is an explanatory diagram of tools, for example, large measurement terminals, in which a wide diamond plane is formed using small diamond. FIG. 9A shows an example in which spherical diamonds are arranged (the left side is a plan view, the right side is a cross-sectional view taken along line AA ′), and FIG. 9B is an example in which triangular plate-like diamonds are densely arranged. The left side is a plan view, the right side is a front view), and FIG. 9C is an example (a left side is a plan view and a right side is a front view) in which hexagonal plate-like diamonds are closely arranged.

  A small diamond can be formed into a spherical shape, spread on the tip of the tool to form a wide diamond plane, and the size of the tools can be increased. This is effective when the welding is not successful due to the difference in expansion coefficient. In addition, it is inexpensive because small diamonds are used.

  As shown in FIG. 9A, the large measuring terminal 53 is made of a metal shaft 55 and a plurality of small-diameter spheres that are closely arranged with the metal material 56 at the end of the metal shaft 55 and are in close contact with each other. A wide diamond plane 59 is formed by the peelable metal-coated diamond 54.

  The non-peelable metal-coated diamond 54 includes a spherical diamond 54a and a metal coating 54b that is non-peeled onto the diamond 54a. The metal material 56 is silver iron, solder, or the like, and melts with the metal shaft 55 and is in contact with the non-peelable metal-coated diamond 54. Alternatively, a spherical non-peelable metal-coated diamond 54 may be disposed in a hole previously formed in the metal shaft 55, and the metal coating 57b and the metal shaft 55 may be brought into contact with each other.

  As shown in FIG. 9B, the large measurement terminal 53a is made of a metal shaft 55 and a plurality of triangular plate-like non-peelable metal-coated diamonds arranged and in contact with the end portion of the metal shaft 55. And a wide diamond plane 59a is formed.

  The non-peelable metal-coated diamond 57 includes a triangular plate-like diamond 57a and a metal coating 57b that is non-peeled on the diamond 57a. The metal coating 57 b and the metal shaft 55 are joined at the butt surface 60.

  As shown in FIG. 9 (c), the large measuring terminal 53b includes a metal shaft 55 and a plurality of hexagonal plate-like non-peelable metal coatings arranged and in contact with the end portion of the metal shaft 55. It consists of diamond 558 and forms a wide diamond plane 59b.

  The non-peelable metal-coated diamond 58 includes a hexagonal plate-shaped diamond 58a and a metal coating 58b that is non-peeled and coated on the diamond 58a. The metal coating 58 b and the metal shaft 55 are joined at the butt surface 60.

  FIG. 10 is an explanatory diagram of a sliding surface in which diamond is arranged on the surface of the base metal. It can be used for parts that are slippery and require low friction. FIG. 10A shows an example in which spherical diamonds 62a are arranged on a base metal 63 (the upper part is a perspective view, and the lower part is a schematic sectional view), and FIG. 10B shows an example in which plate-like diamonds 62d are arranged on the base metal 63d. FIG. 10C is an example in which spherical diamonds are arranged and polished to form a diamond 65a having a flat surface 65c, and FIG. In this example, the diamond 70a having the flat surface 70c is formed by polishing after being arranged on the upper surface of the substrate. Since diamond is highly resistant to frictional wear, it can be used for a long time and is economical. Since sliding between diamonds wears, it is not preferable.

  The diamond sliding surface 61 is composed of a metal plate-like base metal 63 having V-shaped grooves 63a, 63b or U-shaped grooves 63c, and non-peelable metal-coated diamond 62 disposed and fixed in the grooves. The non-peelable metal-coated diamond 62 is composed of a spherical diamond 62a and a non-peelable metal coating 62b coated on at least a portion of the surface of the diamond-coated metal 62 that is bonded to the base metal 63 at the butt surface 64. After the soldering, the surface may be polished.

  The diamond sliding surface 61a includes a metal plate-shaped base metal 63d and a non-peelable metal-coated diamond 62c disposed and fixed on the upper surface of the base metal 63d. The non-peelable metal-coated diamond 62c is composed of a plate-like diamond 62d and at least a non-peelable metal coating 62b for joining the base metal 63 with a butt-contact surface 64 on the bottom surface. In order to make the sliding distance the same, the plate-like diamond 62d is preferably the same square or rectangle.

  The diamond sliding surface 61b is composed of a metal plate-shaped base metal 64 and a non-peelable metal-coated diamond 65 which is disposed (aligned or irregularly) on a metal material 66 on the upper surface of the base metal 64 and fixed. The non-peelable metal-coated diamond 65 includes a spherical diamond 65 a and a non-peelable metal coating for joining the metal material 66 with the butted surface 67. The metal material 66 is silver or solder, and is joined to the base metal 64 by the molten surface 67 and is in contact with the non-peelable metal-coated diamond 54. After the diamond is in contact with the upper surface of the base metal 64, the top surface of the diamond is polished to form the flat surface 65c. The flat surface 65c is a sliding surface.

  The diamond sliding surface 61 c includes a metal plate-like base metal 69 and a non-peelable metal-coated diamond 70 disposed and fixed on the upper surface of the base metal 69. The non-peelable metal-coated diamond 70 is composed of a plurality of plate-shaped diamonds 70a (with an R-surface around and aligned), and a non-peelable metal coat for joining the base metal 69 with a butt-contact surface 71 on the bottom surface. 70b. After the diamond is in contact with the upper surface of the base metal 69, the upper surface is polished to form the flat surface 70c. The flat surface 65c is a sliding surface.

  11A is an end stone 72 obtained by dividing the octahedron (1.1.1.) Plane into three parts, FIG. 11B is a diagram of the uppermost surface and the lowermost surface of the three divided end stones 72a, and FIG. (C) shows the middle part of the three divisions of FIG. 11 (b), and the upper and lower surfaces have a pseudo hexagonal shape. When the top surface and the bottom surface divided into three are reversed, the shape is as shown in FIG. In the end stone 72b of FIG. 11 (c), the shape is a shape of the center part of the three divisions, and the shape cannot be considered that the octahedron is divided at first glance. Here, three divisions are taken as an example, but more divisions may be made depending on the size of the stone.

  The wear-resistant surface of diamond is the (1.1.1.) Surface, and it has been used as a receiving stone in a direction perpendicular to the surface, but the diameter of diamond is reduced to (1. 1.1.) Even if the surface is made smaller, the bearing part of the measuring instrument can be made smaller and lighter if the non-peelable metal-coated diamond is in contact.

  12 and 13 are explanatory diagrams of end stones. End stones are bearings that support a rotating body (shaft) using jewels (sapphire and diamond), and are roughly classified into two types of shapes shown in FIGS.

  In FIG. 12, column (A) is a V-shaped endstone, and column (B) is a U-shaped endstone. (A) is a perspective view, (b) is a longitudinal sectional view, and (c) is a longitudinal sectional view when used with a rotating body.

  As shown in FIG. 12, on the shaft (general portable pointer-type bolt, ampere meter, etc.) which is a relatively lightweight rotating body 72e, a cylindrical sapphire is polished into a V shape and the groove 72d is polished. And a V-shaped endstone 72c that receives the pointed rotating body 72 is used. In some cases, use a spring or rubber damper under the end stone to reduce the shock.

  The household watt-hour meter uses a slightly hard cylindrical sapphire that is internally polished into a U-shape and uses a small hard ball 72k that fits the inner U-shaped R-groove 72g. An end stone 72f that receives a shaft that is a rotating body 72h having a groove 72i is used.

  As described above, conventionally, an end stone made of sapphire monolith has been used, but it can be replaced with non-peelable metal-coated diamond. The hard ball 72k is used to secure a sufficient installation area for the U-shaped end stone 72f and the rotating body 72h.

  In FIG. 13, (A) row is for light load, (B) row is for medium load, and (C) row is an explanatory diagram of a combination of ring jewel and end stone for heavy load. (A) Stage is a sectional view of a jewel ring, (b) Stage is a schematic view of the tip of a pivot, (c) Stage is a sectional view of a diamond-contact endstone, (d) Stage is a jewel ring and pivot shaft It is a combination partial cross-sectional schematic diagram.

  As shown in FIG. 13, a precise measuring instrument of a heavily-weighted rotating shaft 72o (a large-scale and large-capacity measuring instrument is used for a distribution station and a distribution board of a large building because the capacity of power is large). The ring type bearing (ring jewel 72m) provided with a hole 72n for supporting the rotation of the rotating shaft 72o and the end stone 72p serving as a stopper for supporting the weight and supporting the pivot shaft 72o and suppressing vertical vibrations (general) In the name, super-finished plane) is used.

  In this case, the endstone 72p is not fixed, and an elastic body 72u (rubber damper (such as anti-seismic rubber)) or adjustment is provided on the surface of the endstone 72p opposite to the surface in contact with the rotation shaft 720 for the purpose of reducing the stimulation of the rotation shaft 72o. May be housed in the container 72t together with the end stone 72p. The end stone 72p and the elastic body 72u are used as a pair, and may be arranged above and below the rotating shaft 72o or may be arranged on the left and right. The ring jewel may be sapphire, but it is also possible to use diamond because it can be miniaturized. By using non-peelable metal-coated diamond for the end stone, it is possible to obtain a rotational operation stably for a longer time than the sapphire bearing.

  FIG. 14 is an explanatory diagram of an example in which plate-like diamond is used as a bearing for measuring an axis. FIG. 14A is a perspective view and a side view of the shaft measuring bearing 73. FIG. 14B is an explanatory diagram of an axis measuring device 75 that measures the roundness and eccentricity of the axis. FIG.14 (c) is explanatory drawing of the form from which a bearing stand differs.

  As shown in FIG. 14A, the shaft measuring bearing 73 is a non-peelable metal-coated diamond composed of a plate-shaped diamond 73a and a non-peelable metal coating 73b coated on the bottom surface. The top surface 73c is flat and the side surface angle is the R surface 73d.

  As shown in FIG. 14B, the shaft measuring device 75 includes a metal first bearing base 75d having an A surface 75a and a metal second bearing base 75e having a B surface 75b. The bearing plate is arranged in a V shape with the B surface facing each other and formed with a V-shaped groove. The metal coating 73b of the shaft measuring bearing 73 is joined to the A surface 75a and the B surface 75b, respectively. 73a is brought into contact with a bearing stand by a contact surface 74. The shaft core 76 is placed in a V-shaped groove 75f of a bearing base formed by the A surface 75a and the B surface 75b, and roundness, eccentricity, and the like are measured.

  FIG. 14C illustrates different forms of the V-shaped bearing base. The interruption in FIG. 14C corresponds to FIG. 14 (c) is a form in which the shaft core 77d is held by a bearing base in which the shaft core measuring bearing 73 is in contact with the three surfaces of the A surface 77a, the B surface 77b, and the C surface 77c. is there. This is particularly effective when the shaft core 77d is thin.

  The shaft measuring device 78 in the lower stage of FIG. 14 has a configuration in which the opening angle of the bearing base formed by the A surface 78a and the B surface 78b that are in contact with the shaft measuring bearing 73 is wider than that in the middle stage. This is effective when the shaft core 78c is thick.

  FIG. 15 shows an example of application to the rotating shaft 80 in which the A row is in contact with the diamond and rotates in the cylinder, and the B row is applied to a bearing in which the diamond is in contact with the cylinder and the rotation axis is rotated in the cylinder. Example 84.

  In the application example 79 to the shaft rotating in the cylinder, as shown in FIG. 15A, the non-peelable metal-coated diamond 81 is in close contact with the rotating shaft 80. The non-peelable metal-coated diamond 81 includes a spherical diamond 81a and a non-peelable metal coating 81b. The diamond 81a is in contact with the shaft through the contact portion 82 of the metal coating 81b.

  Next, as shown in FIG. 15 (b), the surface of the non-peelable metal-coated diamond 81 in contact with each other is defined as a finished surface 81c. The finished surface 81c is polished and polished with the outer third of the diameter of the spherical diamond 81a as the upper limit. The finished surface 81c is preferably super-finished. The same applies to row B.

  Next, a rotating shaft 80 having a diamond 81a, finished to the target diameter, is inserted into the cylinder 83 and rotated.

  In the application example 84 to the bearing that rotates the rotating shaft in the cylinder, as shown in FIG. 15D, the non-peelable metal-coated diamond 86 is closely in contact with the inside of the bearing 88 of the internal cavity 88a. The non-peelable metal-coated diamond 86 includes a spherical diamond 86a and a non-peelable metal coating 86b. The diamond 86a is in contact with the bearing 88 through the contact portion 87 of the metal coating 81b.

  Next, as shown in FIG. 15 (e), the inner surface of the non-peelable metal-coated diamond 81 that is in contact with each other is defined as a finished surface 88b. The finished surface 88b is polished and polished with the outer one third of the diameter of the spherical diamond 86a as the upper limit.

  Next, the rotary shaft 85 is inserted into a bearing 88 having a diamond 81a and finished to a desired inner diameter, and is used for rotation. Note that both the rotating shaft and the bearing may be a rotating shaft and a bearing provided with non-peelable metal-coated diamond.

  FIG. 16 is an explanatory diagram of an application example of the power IC for removing heat generated by the non-peelable metal-coated diamond IC to the heat sink 89. The IC 93 is arranged with a non-peelable metal-coated diamond 91 interposed in a heat large-capacity metal part 90 that absorbs heat.

  The non-peelable metal-coated diamond 91 includes a plate-like diamond 91a and a metal coating 91b that is non-peelably coated on the bottom surface of the diamond 91a. The diamond 91a is joined to the heat large-capacity metal part 90 at the welded part 92 of the metal coating 91b. The diamond 91a has a high heat transfer property, and can effectively transfer the heat generated by the IC to the heat large-capacity metal part 90.

  FIG. 17 is an explanatory diagram of an application example of a non-peelable metal-coated diamond to a temperature measurement sensor. 17 (a) and 17 (b) are embodiments in which the structure of the sensor end is different. Temperature can be measured with high sensitivity by arranging diamond at the end of the temperature measurement sensor. Also, it is extremely effective for measuring places, parts, etc. where metal cannot be contacted.

  As shown in the partially transparent perspective view of FIG. 17A, the temperature measurement sensor 94 has a non-peelable metal-coated diamond 96 in contact with the metal end portion 95 of the sensor that includes the existing temperature sensor 95a. It becomes. The non-peelable metal-coated diamond 96 includes a disk-shaped diamond 96a and a metal coating 96b that is non-peelably coated on the bottom of the diamond 96a. The diamond 96a is joined to the tip of the metal end portion 95 of the sensor at the butt surface 97 of the metal coating 96b. In this case, the metal is partially covered so that the sensor and the outer metal do not contact each other.

  As shown in the cross-sectional view of FIG. 17 (b), the temperature measuring sensor 98 has a non-peelable metal-coated diamond 100 in contact with the tip of a metal end portion 99 of the sensor having an existing temperature sensor 99a therein. It becomes. The non-peelable metal-coated diamond 100 is composed of a diamond-shaped diamond 100a whose corner is processed to R, and a metal coating 100b that is non-peelably coated on the bottom of the diamond 100a. The diamond 100a is joined to the tip of the metal end portion 99 of the sensor at the welding surface 101 of the metal coating 100b.

  FIG. 18 is an explanatory view of an application example of non-peelable metal-coated diamond to a fluid temperature measurement sensor. As shown in FIG. 18, the fluid temperature measurement sensor 102 is inserted into the passage 103 through which the fluid 103 a flows, and measures the temperature of a fluid (measurement object) such as a gas or a liquid. In particular, when the fluid is strong alkali, corrosive gas, etc., the diamond 104a is effective because it has corrosion resistance. In addition, it is also effective as a temperature sensor for an object to be measured that dislikes metal conductivity or metal ions in a substance.

  The fluid temperature measurement sensor 102 includes a non-peelable metal-coated diamond 104 and a temperature-sensitive sensor 103 b bonded to the non-peelable metal-coated diamond 104. The non-peelable metal-coated diamond 104 includes a substantially cylindrical diamond 104a inserted into the passage 103 and a metal coating 104b that is non-peelably coated on the bottom of the diamond 104a. The non-peelable metal-coated diamond 104 is bonded to the metal portion of the temperature sensor 103b at the butt surface 105 of the metal coating 104b. The diamond 104a and the passage 103 are fitted in an airtight manner.

  FIG. 19 is an explanatory view of an application example of non-peelable metal-coated diamond to a diamond cantilever. The cantilever is an example of a record player used in a cartridge that converts a sound groove of a record into an electric signal. The cantilever of a record player has a needle tip that contacts the sound groove at the tip. Attach a permanent magnet or coil at the base to change the vibration of the cantilever into an electrical signal.

  The diamond cantilever 106 includes a non-peelable metal-coated diamond 108 in contact with the sound groove of the record, a cantilever 109 having a non-peelable metal-coated diamond 108 at the tip, and a coil bobbin 107 joined to the end of the cantilever 109.

  The non-peelable metal-coated diamond 108 comprises a triangular pyramid or triangular prism 108a whose tip is in contact with the sound groove of the record, and a metal coating 108b that is non-peelably coated on the bottom. The non-peelable metal-coated diamond 108 is joined to the tip of the cantilever 109 at the butt surface 108 c of the metal coating 108 b.

  The cantilever 109 is covered with a metal coating 109 a in a non-peeling manner at the bottom with diamond, and transmits vibration to the coil bobbin 107. The cantilever 109 and the coil bobbin 107 are joined to each other by a flange surface 109b of the metal coating 109a.

  FIG. 20 is an explanation of an application example in which non-peelable metal-coated diamond is joined to the tip of a soldering iron. (A)-(C) differ only in the shape of the diamond 113a at the tip. The shape of the solder tip can be appropriately selected depending on the object of use. This is effective when it is inconvenient if the metal rod 112 melts into the solder. However, a low melting point below the temperature at which diamond burns is required. For example, the pressure bonding of a resin sheet can be exemplified.

  Soldering iron tips 111, 111 a, 111 b, 111 c are composed of a metal rod 112 that generates heat and a non-peelable metal-coated diamond 113 bonded to the tip of the metal rod 112. The non-peelable metal-coated diamond 113 includes a diamond 113a whose tip is processed into a desired shape, and a metal coating 113b that is non-peelably coated on the bottom of the diamond 113a. The diamond 113a is joined to the tip of the metal rod 112 at the welding surface 114 of the metal coating 113b. In this case, the melting point of the solder used is preferably a low melting point solder having a difference of 200 ° C. or more from the melting point of silver solder.

  21 and 22 show a plurality of different embodiments of the non-peelable metal-coated diamond window 120. FIG. FIG. 21A is a side view of the non-peelable metal-coated diamond window 120 (al). The diamond 120a portion is represented by white in various shapes such as a side view, a rectangle, an ellipse, and a hexagon. The metal covering portion 12b is represented as black areas on the top and bottom. FIG. 21 (B) is a schematic cross-sectional view when the non-peelable metal-coated diamond window 120 is fitted into the partition wall 120c having an internal 120d space. The right side of the non-peelable metal-coated diamond window 120 is an inside 120d such as a chamber, and the left side is an outside 12e.

  The non-peelable metal-coated diamond window 120 is composed of a diamond 120a and a metal-coated portion 120b that is non-peelably coated on a portion of the diamond 120a that is in contact with the partition 120c, and a metal partition 120c having an interior 120d space, The metal cover 120b is butt-contacted between 120c (welded surface 120i) and fitted into the partition wall 120c so that the internal 120d space can be monitored.

  As shown in FIG. 21, the (A) -stage non-peelable metal-coated diamond window 120 and the partition 120c are combined in accordance with the situation of the interior 120d. The (A) stage A type partition 120c can be suitably combined with the (A) stage a, b, d, g, h and other non-peelable metal-coated diamond windows 120. It is the combination of shapes that are most easily processed. The strength of the welded surface 120i is further increased by brazing the metal ring to the joint between the diamond 120 and the partition wall 120c.

  A non-peelable metal-coated diamond window 120 such as a, b, c, d, e, f, g, h, i, etc. in the (A) stage is suitably used for the B type partition 120c in the stage (B) of FIG. Can be combined. The partition wall 120c on the right side of the B type is provided with a stopper 120f on the outer side 120e (monitoring side), and can be prevented from being damaged even if the internal 120d becomes a high pressure (explosion-proof type).

  FIG. 21 (B) stage C type partition 120c has (A) stage g, h, i, etc., and D type partition wall 120c has (A) stage g, h, j, k, etc. (A) stage g, h, i, etc. can be suitably combined with the type partition wall 120c, and (A) stage L, etc. non-peelable metal-coated diamond window 120 can be suitably combined with the F type partition wall 120c.

  The E and F types include rings 120g and 120h that firmly fix the non-peelable metal-coated diamond window 120 to the partition wall 120c. Even when the internal pressure 120d suddenly becomes negative pressure, damage can be prevented.

  FIG. 22 also shows another form of non-peelable metal-coated diamond window 120. As shown in (A) to (B), the non-peelable metal-coated diamond windows 130, 140, and 150 are formed by connecting the metal-coated portion of the non-peelable metal-coated diamond to the partition wall at the butt surface and the butt portion. Become. In (A), the diamond 130a has a convex shape in a cross-sectional view and is locked to the stopper 130g, so that it is more difficult to fall off even if the inside becomes high pressure.

  As described above, the tool and the apparatus can be reduced in size by bringing the non-peelable metal-coated diamond window 120 into contact with the partition wall of the container. Small diamonds are also available. As long as it is not at the temperature at which diamond burns, it is chemically stable and therefore has a very wide range of applications. Conventionally, packing has been used for the fitting part, but the metal-coated diamond is sandwiched between the partition walls so that the window is not corroded and stable even in a chamber containing a corrosive substance inside. The inside observation becomes possible.

  A non-peelable metal-coated diamond drill 160 (drill), which is an example of another tool shown in FIG. 23, includes a rotating shaft 170 and a square-bar-shaped non-peelable metal-coated diamond 180.

  The rotating shaft 170 includes two metal first rotating shaft portions 171 and 171, and two metal second rotating shaft portions 172 and 172 disposed therebetween. Together, these form one rotating shaft 170.

  The first rotating shaft portion 171 has a shape obtained by cutting a cylinder into approximately ¼ in the longitudinal direction, the end surface 171a forms a part of a cone, and a portion other than the end surface is a notch 171b lower than the end surface. At the boundary between the end surface 171a and the notch 171b, a groove 171c is formed from the center toward the outer periphery. A non-peelable metal-coated diamond 180 is in contact with the groove 171c.

  In addition, a magnet 171e is embedded in one side surface of the first rotating shaft portion 171, and the magnets of different polarity are embedded in one side surface of the second rotating shaft 172. The strip 171d protrudes, fits into a groove formed in the same side surface of the second rotating shaft 172, and is fixed in position.

The metal-coated diamond 180 is provided with a metal-coated portion 180b in a non-peeling manner on two side surfaces that fit into the square-shaped diamond 180a and the groove 171c. The metal covering portion 180b and the groove 171c form a butt surface 160a. The corner portion 180c facing the rotation direction of the square bar-shaped diamond 180a becomes a grinding portion, and the center portion 180d becomes a cut portion. Thus, the center point 180d can be easily positioned by dividing | segmenting and connecting the rotating shaft 170. FIG.

  FIG. 24 shows a non-peelable metal-coated diamond drill 190 which is an example of another tool. FIG. 24A is a front view (b), a rear view (c), a left side view (d), and a right side (e) with respect to the plan view (a). (B) is a perspective view, and FIG. 24 (C) is a front view of a non-peelable metal-coated diamond drill of a different form.

  The non-peelable metal-coated diamond drill 190 includes a rotating shaft 200, a stopper 200b and a balancer 200c on an end surface 200a, and a non-peelable metal-coated diamond 210.

  The stopper 200b and the balancer 200c are left uncut on the end surface 200a of the rotating shaft 200, and the metal-coated portion 210b of the non-peelable metal-coated diamond 210 is brought into contact with the balancer 200c at a position balanced with the weight. The stopper 200b is substantially point-symmetric with the balancer 200c.

  The non-peelable metal-coated diamond 200 is a diamond 210a having a triangular shape and a blade portion 210c having a rotation center portion as a vertex and a taper in the rotation direction. A metal coating portion 210b is provided on the bottom surface and the back surface of the diamond 210a in a non-peeling manner, and is in contact with the stopper 200b and the end surface 200a of the rotating shaft 200 with the metal coating portion 210b.

  As shown in FIG. 24C, the non-peelable metal-coated diamond 210 and the balancer 200c can have various shapes depending on the object.

1a hexahedron type diamond crystal 1b octa-octahexedron type diamond crystal 1c octa-octahexedron type diamond crystal 2a positive octahedron type diamond crystal 2b irregular octahedron type diamond crystal 3a dodecahedron type diamond crystal 3b irregular type Dodecahedron diamond crystal 4a Hexaoctahedron diamond crystal
4b Hexaoctahedron type diamond crystal
DESCRIPTION OF SYMBOLS 10 Scriber point 11 Non-peelable metal-coated diamond 11a Diamond 11b Metal-coated 12 Pedestal 13 butt surface 14 Conventional scriber point 15 Holder 15a Recess 16 Powder metallurgy 17 butt-type pivot 18 Non-peelable metal-coated diamond 18a Diamond 18b Metal coating 19 shaft 20 butt contact surface 17 butt contact pivot 18 non-peelable metal coated diamond 18a diamond 18b metal coating 19 shaft 20 butt contact surface 21 butt contact pivot 22 non detachable metal coated diamond 22a diamond 23 butt contact pivot bearing 23a Butt-type pivot bearing 24 non-peelable metal-coated diamond 24a talc diamond 24b metal-coated 24c basing surface 24d basing surface 25 shaft butt-contacting surface 27 caulking pivot 28 basin diamond 28a Catchstone diamond 29 Shaft 29a Groove 29b Shaft 29c Groove 30 Caulking pivot receiving 30a Caulking pivot receiving 31 Cavity diamond 31a Receiving surface 31b Cavity diamond 31c Receiving surface 32 Shaft 32a Groove 32c Shaft 32d Groove 33 Measuring terminal 34 Non-peelable Metal-coated diamond 34a Diamond 34b Metal-coated 35 Shaft 36 butt surface 37 Non-peelable metal-coated diamond monolith forming dresser 38 Non-peelable metal-coated diamond 38a Diamond 38b Metal coating 39 Base metal 39a Groove 40 butt surface 41 Conventional diamond Single Stone Forming Dresser 42 Diamond 43 Base 43a Groove 44 Sintered Fixed Part 45 Non-peelable Metal-Coated Diamond Polystone Forming Dresser 46 Non-Peelable Metal-Coated Diamond 46a Diamond 4 b Metal coating 47 Base metal 47a Groove 48 Bracing surface 49 Conventional diamond polylithic forming dresser 50 Diamond 51 Base metal 51a Groove 52 Sintered portion 53 Large measurement terminal 53a Large measurement terminal 53b Large measurement terminal 54 Non-peelable metal coated diamond 54a diamond 54b metal coating 55 metal shaft 56 metal material 57 non-peelable metal coating diamond
57a Diamond 57b Metal coating 58 Non-peeling metal coating diamond 58a Diamond 58b Metal coating 59 Diamond plane 59a Diamond plane 60 Bracing surface 61 Diamond sliding surface 61a Diamond sliding surface 61b Diamond sliding surface 61c Diamond sliding surface 62 Non-peeling Metal-coated diamond 62a Diamond 62b Metal-coated 62c Non-peelable metal-coated diamond 62d Diamond 63 Base metal 63a Groove 63b Groove 63c Groove 63d Base metal 64 Bracing surface 64 Base metal
65 Non-peelable metal-coated diamond 65a Diamond 65c Flat surface 66 Metal material 67 Melted surface 69 Base metal
70 Non-peelable metal-coated diamond 70a Diamond 70b Metal-coated 70c Flat surface 71 Bracing surface 72 Endstone 72a Endstone 72b Endstone 72c V-shaped endstone 72d Groove 72e Rotating body 72f U-shaped endstone 72g Groove 72h Rotating body 72i Groove 72k Hard sphere 72m Ring jewel 72n Hole 72o Rotating shaft 72p End stone 72q Non-peelable metal coated diamond 72r Base metal 72s Contact surface 72t Container 72u Elastic body 73 Bearing for shaft measurement 73a Diamond 73b Metal coating 73c Top surface 73d R surface 74 Contact surface 75 Axle measuring device 75a A surface 75b B surface 75d First bearing base 75e Second bearing base
76 Shaft core 77 Shaft core measuring device 77a A surface 77b B surface 77c C surface 77d Shaft core 78 Shaft core measuring bearing 78a A surface 78b B surface 78c Shaft core 79 Application example to rotating shaft rotating in cylinder 80 Rotating shaft 81 Non-peeling metal-coated diamond 81a Diamond 81b Metal-coating 81c Finishing surface 82 Contact portion 83 Tube 84 Application example to bearing that rotates a rotating shaft in a cylinder 85 Rotating shaft 86 Non-peeling metal-coated diamond 86a Diamond 86b Metal coating 87 Contact part 88 Bearing 88a Cavity 88b Finishing surface
89 Power IC heatsink 90 Thermal large capacity metal part 91 Non-peelable metal coated diamond 91a Diamond 91b Metal coated 92 Bracing surface 93 IC
94 Temperature measurement sensor 95 Sensor metal end 95a Temperature sensor 96 Non-peelable metal-coated diamond 96a Diamond 96b Metal-coating 97 Barbed surface 98 Temperature measurement sensor 99 Sensor metal end 99a Temperature sensor 100 Non-peelable Metal-coated diamond 100a Diamond 100b Metal-coated 101 butt surface 102 Fluid temperature measurement sensor 103 Passage 103a Fluid 103b Temperature sensor 104 Non-peelable metal-coated diamond 104a Diamond 104b Metal-coated 105 butt surface 106 Diamond cantilever 107 Coil bobbin 108 Non-peel Metal-coated diamond 108a Diamond 108b Metal-coated 108c Bracing surface 109 Cantilever 109a Metal-coated 109b Bracing surface 111 Soldering iron tip 111a Soldering iron tip 111b Half Soldering iron tip 111c Soldering iron tip 112 Metal rod 113 Non-peelable metal-coated diamond 113a Diamond 113b Metal-coated 114 Bracing surface 120 Non-peelable metal-coated diamond window 120a Diamond 120b Metal-coated portion 120c Bulkhead 120d Inner 120e Outer 120f Stopper 120g Ring 120h Ring 120i Bracing surface 130 Non-peelable metal-coated diamond window 130a Diamond 130b Metal-coated portion 130c Partition 130d Bracing surface 130e Inside 130f Outer 130g Stopper 140 Non-peelable metal-coated diamond window 140a Diamond 140b Metal-coated portion 140c Partition 140d Bracing portion 140e Inside 140f Outside 150 Non-peelable metal-coated diamond window 150a Diamond 150b Metal-coated portion 150c Partition 50d butt portion 150e inner 150f outer side 160 non-peelable metal-coated diamond drill 160a butt surface 170 rotating shaft 171 first rotating shaft portion 171a end surface 171b notch 171c groove 171d ridge 171e magnet 172 second rotating shaft portion 180 non-peeling Metal-coated diamond 180a Diamond 180b Metal-coated portion 190 Non-peelable metal-coated diamond drill 190a Bracing surface
200 Rotating shaft 200a End face 200b Stopper 200c Balancer 210 Non-peelable metal-coated diamond 210a Diamond 210b Metal-coated portion 210c Blade portion

Claims (36)

A diamond bonding tool characterized in that a non-releasable metal-coated diamond in which a metal is non-removably coated on a diamond surface is bonded to a metal part of the tool. Disintegration aid for preventing non-peelable metal-coated diamond from being baked and mixed with either a mixed powder of diamond, Cr metal powder and Cr oxide powder, or a single Cr metal powder and promoting disintegration of the cooling mixture A non-releasable metal-coated diamond obtained by heating, causing the metal powder and the diamond surface to chemically react in the air, cooling the mixture, and separating and recovering the metal-coated diamond. The diamond bonding tool according to claim 1, wherein the tool is a diamond bonding tool. The disintegration aid is a disintegration aid that does not react with diamond even if it coexists with diamond at 1150 ° C. to 1160 ° C. and does not inhibit the chemical reaction between the coexisting Cr metal powder and / or Cr oxide and diamond. The diamond joining tool according to claim 2, wherein the tool is a diamond joining tool. The disintegration aid is one or more selected from silicon carbide, silicon oxide, tungsten, tungsten carbide, chromium oxide, aluminum oxide, magnesium oxide, cubic boron nitride, and zirconia oxide. The diamond joining tools according to claim 3. The said metal powder is Cr metal powder, Comprising: The Cr metal powder and the said disintegration adjuvant were mix | blended in the weight ratio of 1: 1-1: 5, The any one of Claim 2 thru | or 4 characterized by the above-mentioned. The diamond joining tool according to item 1. The diamond bonding tool according to any one of claims 1 to 5, wherein the diamond is diamond obtained by applying a metal coating inhibitor to a portion that does not require a non-peelable metal coating. . The diamond bonding tool according to claim 6, wherein the metal coating inhibitor is a metal coating inhibitor obtained by mixing a powder of a disintegration aid in a solution of 30% pure water and 70% water glass. The diamond bonding tool according to any one of claims 1 to 7, wherein a metal portion of the tool is a base metal of a scriber point, and an end of the base metal is made of the non-peelable metal-coated diamond. A scriber point characterized by being in contact with a metal coating. The diamond bonding tool according to any one of claims 1 to 7, wherein the metal portion of the tool is a shaft of a pivot bearing, and the end of the shaft is coated with the non-peelable metal-coated diamond. A pivot-type pivot bearing characterized in that the parts are brought into contact with each other. The diamond bonding tool according to any one of claims 1 to 7, wherein the metal portion of the tool is a pivot shaft, and a receiving surface of the pivot shaft that is recessed in an arc is formed at an end of the shaft. A scissor-type pivot bearing characterized by comprising a metal-coated portion of the non-peelable metal-coated diamond provided. The diamond bonding tool according to any one of claims 1 to 7, wherein the metal portion of the tool is a shaft of a metal sensor, and the end portion of the shaft is coated with the non-peelable metal-coated diamond. A measurement terminal characterized by being in close contact with each other. The diamond bonding tool according to any one of claims 1 to 7, wherein a metal portion of the tools is a base of a forming dresser, and the groove of an end portion of the base is covered with the non-peelable metal coating. A forming dresser characterized by being in contact with a metal coating of diamond. The diamond bonding tool according to any one of claims 1 to 7, wherein the metal portion of the tool is a sensor shaft, and the non-peelable metal-coated diamond having a spherical shape at an end of the shaft. A measuring terminal comprising a plurality of metal members and a metal material brazed with the metal coating portion. The diamond bonding tool according to any one of claims 1 to 7, wherein the metal part of the tool is a shaft of a sensor, and the plate-like non-peelable metal coating is provided at an end of the shaft. A measuring terminal characterized in that a plurality of diamonds are laid down and in contact with each other with the metal coating portion. The diamond bonding tool according to any one of claims 1 to 7, wherein a metal portion of the tool is a base metal of an oscillating surface, and a groove on an upper surface of the base metal or the base metal. A plurality of spherical non-peelable metal-coated diamonds are arranged in a groove of a metal material to be joined, and are flattened by polishing after being in contact with the metal-coated portion. Oscillating surface. The diamond joining tool according to any one of claims 1 to 7, wherein the metal portion of the tool is a base metal of an oscillating surface, and the plate-like non-peelable metal is formed on an upper surface of the base metal. A diamond oscillating surface characterized in that a plurality of coated diamonds are spread and polished by forming a flat surface after being in contact with the metal coating portion. A groove having a V-shaped cross section is formed on the upper surface of the non-peelable metal-coated diamond of the saddle-type pivot bearing according to claim 9, and the non-peelable metal-coated diamond molded into a conical shape is welded to the tip of the pivot shaft. A V-shaped endstone and a pivot bearing structure. A groove having a U-shaped cross section is provided on the upper surface of the non-peelable metal-coated diamond of the saddle-type pivot bearing according to claim 9, a hard ball is placed in the U-shaped groove, and a cross-section is provided at the tip of the pivot shaft. A U-shaped endstone and a pivot characterized by contacting a non-peelable metal-coated diamond provided with a substantially V-shaped groove and contacting the V-shaped groove of the non-peelable metal-coated diamond with the hard sphere. Bearing structure. A ring jewel having a hole formed therein, a rotating shaft inserted into the hole and rotated and held, and an end stone in contact with a base metal with a non-peelable metal-coated diamond that contacts and holds the tip of the rotating shaft; A ring jewel and an end stone structure, comprising: an elastic body disposed on a bottom surface of the end soot; and a container for storing the end stone and the elastic body. The diamond joining tool according to any one of claims 1 to 7, wherein the metal portion of the tool is a bearing base of a shaft measuring bearing device, and an end portion of the bearing base is cut obliquely. A shaft-core measuring bearing for measuring the roundness and eccentricity of a shaft core characterized in that a plate-like metal-coated portion of the non-peelable metal-coated diamond is in contact with the surface as a shaft-core measuring bearing. Stand. 21. Two shaft core measuring bearing bases according to claim 20 are arranged with their oblique surfaces facing each other, forming a V-shaped groove, placing the shaft core in the V-shaped groove, and rotating the shaft core. And measuring the roundness and the eccentricity of the shaft core. The shaft center measuring device according to claim 21, wherein the shaft measuring bearing is disposed above the V-shaped groove, and the shaft core is held on three surfaces. The diamond bonding tool according to any one of claims 1 to 7, wherein the metal portion of the tool is a surface of a rotating shaft, and the surface of the rotating shaft is made of the non-peelable metal-coated diamond that is spherical. A rotating shaft comprising a non-releasable metal-coated diamond, characterized in that the metal-coated portion is welded and polished to form a finished surface, and is inserted into a cylinder serving as a bearing and rotated. The diamond bonding tool according to any one of claims 1 to 7, wherein the metal portion of the tool is a surface of an internal cavity of the bearing, and the spherical non-peeling property is formed on the surface of the cavity of the bearing. A bearing comprising a non-releasable metal-coated diamond, characterized in that a metal-coated portion of a metal-coated diamond is welded and polished, a finished surface is formed, and a rotary shaft is inserted and rotated. A high heat capacity metal part, a non-peelable metal-coated diamond having a metal cover part in contact with the large heat capacity metal part, and an IC mounted on the diamond surface of the non-peelable metal-coated diamond. Power IC heat sink. A temperature measurement sensor comprising: a sensor having a built-in temperature sensor; and a non-peelable metal-coated diamond in which a metal coating portion is in contact with a metal end portion of the sensor. It consists of a metal temperature sensor and a non-peelable metal-coated diamond in which the metal coating part is in contact with the metal part of the temperature sensor, and the non-peelable metal-coated diamond is brought into direct contact with the object to be measured, A temperature measurement sensor characterized by measuring a temperature of a fluid to be measured. A non-releasable metal-coated diamond, which is a needle tip having a metal coating that is non-peelingly coated on the bottom with a triangular pyramid or a triangular prism in contact with the sound groove of the record, and a diamond cantilever with a metal coating non-peeling at both ends And a coil bobbin, the metal coating of the non-peelable metal-coated diamond that is the needle tip and the metal coating of the cantilever are joined to one end of the cantilever, and the metal coating and the coil bobbin are joined to the other end. A diamond cantilever characterized by comprising The diamond bonding tool according to any one of claims 1 to 7, wherein the metal portion of the tool is a tip portion of a metal rod of a soldering iron, and a desired shape is formed at the tip portion of the metal rod. A tip of a soldering iron characterized in that the metal-coated portion of the non-peelable metal-coated diamond formed into a metal is in contact with each other. Solder characterized by mixing non-peelable metal-coated diamond into a solder material. 30. A solder obtained by molding the solder according to claim 29 into a drop shape or a rod shape. A non-releasable metal-coated diamond, wherein a circuit line is drawn with a conductive metal on a diamond surface, a non-peelable metal-coated diamond is formed with the diamond and the circuit line, and gold is in contact with the circuit line. circuit. A non-peelable metal-coated diamond drawing, characterized in that a picture is drawn with a metal on a diamond surface, and a non-peelable metal-coated diamond is formed with the diamond and the metal. A non-releasable metal-coated diamond window fitted between metal partitions with an interior space,
A non-releasable metal-coated diamond window characterized in that a metal coating portion is provided at a portion in contact with the partition wall, and the inner space can be monitored by being brazed to the partition wall by the metal coating portion. The diamond bonding tool according to any one of claims 1 to 7, wherein the metal portion of the tool is a notch boundary of an end surface of a rotating shaft, and the non-peelable shape in the form of a square bar at the boundary. A non-peelable metal-coated diamond drill comprising a plurality of metal-coated diamonds and being in contact with the metal-coated portion. The diamond bonding tool according to any one of claims 1 to 7, wherein the metal portion of the tool is an end surface of a rotating shaft, and the balancer is left uncut on the end surface, and is balanced with the balancer. A non-releasable metal-coated diamond drill, characterized in that the non-releasable metal-coated diamond is in contact with the metal-coated portion at a position.

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