JP2015503654A5 - - Google Patents
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- Publication number
- JP2015503654A5 JP2015503654A5 JP2014550254A JP2014550254A JP2015503654A5 JP 2015503654 A5 JP2015503654 A5 JP 2015503654A5 JP 2014550254 A JP2014550254 A JP 2014550254A JP 2014550254 A JP2014550254 A JP 2014550254A JP 2015503654 A5 JP2015503654 A5 JP 2015503654A5
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- stage
- ethylenically unsaturated
- emulsion
- processing aid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 claims description 90
- 239000000178 monomer Substances 0.000 claims description 53
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 42
- -1 sulfone azide Chemical class 0.000 claims description 36
- 239000004908 Emulsion polymer Substances 0.000 claims description 24
- 125000000524 functional group Chemical group 0.000 claims description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 18
- 238000004945 emulsification Methods 0.000 claims description 17
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 14
- 125000004971 nitroalkyl group Chemical group 0.000 claims description 11
- 150000003573 thiols Chemical class 0.000 claims description 10
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical group CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 claims description 8
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 8
- 150000004798 β-ketoamides Chemical class 0.000 claims description 8
- MLIREBYILWEBDM-UHFFFAOYSA-M 2-cyanoacetate Chemical compound [O-]C(=O)CC#N MLIREBYILWEBDM-UHFFFAOYSA-M 0.000 claims description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 238000010094 polymer processing Methods 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 150000002690 malonic acid derivatives Chemical class 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 3
- MLIREBYILWEBDM-UHFFFAOYSA-N cyanoacetic acid Chemical class OC(=O)CC#N MLIREBYILWEBDM-UHFFFAOYSA-N 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 150000003926 acrylamides Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 9
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 238000007306 functionalization reaction Methods 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000004801 Chlorinated PVC Substances 0.000 description 2
- 239000004709 Chlorinated polyethylene Substances 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- ISRGONDNXBCDBM-UHFFFAOYSA-N 2-chlorostyrene Chemical compound ClC1=CC=CC=C1C=C ISRGONDNXBCDBM-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2011/067655 WO2013100997A1 (en) | 2011-12-28 | 2011-12-28 | Processing aids and polymer formulations containing the same and method for producing the same |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016226158A Division JP6817039B2 (ja) | 2016-11-21 | 2016-11-21 | 加工助剤およびこれを含有するポリマー配合物およびこれを製造するための方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015503654A JP2015503654A (ja) | 2015-02-02 |
| JP2015503654A5 true JP2015503654A5 (enExample) | 2016-04-21 |
| JP6329908B2 JP6329908B2 (ja) | 2018-05-23 |
Family
ID=45509712
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014550254A Active JP6329908B2 (ja) | 2011-12-28 | 2011-12-28 | 加工助剤およびこれを含有するポリマー配合物およびこれを製造するための方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9908958B2 (enExample) |
| EP (1) | EP2797961B1 (enExample) |
| JP (1) | JP6329908B2 (enExample) |
| KR (2) | KR101838344B1 (enExample) |
| CN (2) | CN105968265B (enExample) |
| BR (1) | BR112014015830B1 (enExample) |
| IN (1) | IN2014CN04779A (enExample) |
| WO (1) | WO2013100997A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3154929B1 (en) | 2014-04-21 | 2020-09-16 | Firestone Building Products Company, LLC | Method of preparing a foam |
| US10851192B2 (en) | 2015-08-11 | 2020-12-01 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Dihydropyridazine-based antioxidants and uses thereof |
| US10619023B2 (en) | 2015-08-11 | 2020-04-14 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Green chemistry method of synthesizing polymer structures that can function as a built-in antioxidant |
| US10731018B2 (en) | 2015-08-11 | 2020-08-04 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Antioxidant polydihydropyridazine and polypyridazine foams from 1,2,4,5-tetrazine |
| EP3344669B1 (en) * | 2015-08-31 | 2021-09-29 | Rohm and Haas Company | A processing aid for foam molding, a vinyl chloride resin-based foam molding composition comprising the same and a foam molded product |
| US11655319B2 (en) | 2015-08-31 | 2023-05-23 | Rohm And Haas Company | Processing aid for foam molding, a vinyl chloride resin-based foam molding composition comprising the same and a foam molded product |
| US11352475B2 (en) | 2016-06-29 | 2022-06-07 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Method of formation of a robust network of foam through Diels-Alder reaction |
| CN106366234B (zh) * | 2016-08-30 | 2019-12-20 | 山东东临新材料股份有限公司 | 丙烯酸酯共聚物及其制备方法和用途 |
| US10633517B2 (en) | 2017-03-10 | 2020-04-28 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Hydrogenated tetrazine-based antioxidants and free radical reaction inhibitors and uses thereof |
| JP7581764B2 (ja) * | 2019-10-17 | 2024-11-13 | 三菱ケミカル株式会社 | 加工助剤および樹脂組成物 |
| KR102994968B1 (ko) | 2019-10-30 | 2026-07-24 | 알케마 인코포레이티드 | 기포형 pvc용의 관능화된 가공 조제 블렌드 |
| CN116947640B (zh) * | 2023-09-21 | 2023-12-15 | 深圳市普利凯新材料股份有限公司 | 一种乙酰乙酸基甲基丙烯酸乙酯的提纯方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1595679A1 (de) | 1951-01-28 | 1970-08-20 | Bayer Ag | Mit Licht vernetzbare Polymerisate |
| US2646417A (en) | 1951-02-20 | 1953-07-21 | Goodrich Co B F | Rigid thermoplastic compositions comprising vinyl halide polymers with interpolymersof styrene and acrylonitrile |
| US3261785A (en) | 1963-06-25 | 1966-07-19 | Hercules Inc | Modified vinyl chloride polymers |
| US3833686A (en) * | 1969-10-09 | 1974-09-03 | Rohm & Haas | Sequentially produced alkyl acrylate polymers blended with poly(vinyl halides) |
| US3975315A (en) | 1972-02-14 | 1976-08-17 | The B. F. Goodrich Company | Expandable rigid vinyl chloride polymer compositions |
| FR2602776B1 (fr) | 1986-08-12 | 1988-11-10 | Rhone Poulenc Chimie | Diorganopolysiloxane a fonction beta-cetoester utile comme stabilisant des polymeres a base de polychlorure de vinyle |
| DE3879660T2 (de) | 1987-12-26 | 1993-08-12 | Sumitomo Chemical Co | Vinylchloridharzzusammensetzung fuer pulverformverfahren und verfahren zu ihrer herstellung. |
| JP2887478B2 (ja) | 1988-03-29 | 1999-04-26 | 三菱レイヨン株式会社 | 熱可塑性樹脂用加工助剤及びそれを用いた熱可塑性樹脂組成物 |
| US5206296A (en) | 1989-04-26 | 1993-04-27 | General Electric Company | New processing aid (8-CB-10.483) |
| DE4125477B4 (de) | 1990-08-10 | 2004-02-12 | Basf Ag | Polyvinylhalogenidharzmasse mit verbessertem Verarbeitungsverhalten, deren Verwendung sowie Verwendung eines Emulsionspolymerisats als Verarbeitungshilfsmittel |
| DE4041186A1 (de) | 1990-12-21 | 1992-06-25 | Basf Ag | Zweistufiges emulsionscopolymerisat |
| DE69520916T2 (de) | 1994-08-30 | 2001-11-08 | Agfa-Gevaert N.V., Mortsel | Neuer Kern-Hülle Latex zur Verwendung in photographischen Materialien |
| US5663266A (en) * | 1995-04-12 | 1997-09-02 | Eastman Chemical Company | Waterborne coating compositions |
| EP1065242B1 (en) | 1999-01-18 | 2008-09-03 | Kaneka Corporation | Expandable vinyl chloride resin composition |
| DE60104594T2 (de) | 2000-05-12 | 2005-08-04 | Rohm And Haas Co. | Kunststoffaditive, verbessertes Verfahren, Produkte und Gegenstände die diese enthalten |
| CN1331925C (zh) | 2000-08-08 | 2007-08-15 | 钟渊化学工业株式会社 | 发泡性氯乙烯系树脂组合物 |
| US6670419B2 (en) | 2000-09-14 | 2003-12-30 | Rohm And Haas Company | Method of toughening thermoplastic polymers and thermoplastic compositions produced thereby |
| US6852800B2 (en) | 2001-03-30 | 2005-02-08 | Rohm And Haas Company | Plastic composition |
| US7557158B2 (en) | 2004-09-15 | 2009-07-07 | Rohm And Haas Company | Gloss reducing polymer composition |
| AU2006246467B2 (en) * | 2005-12-13 | 2011-11-10 | Rohm And Haas Company | Polymer composition |
| US7795343B2 (en) | 2005-12-13 | 2010-09-14 | Rohm And Haas Company | Polymer composition |
| US9309397B2 (en) * | 2007-10-05 | 2016-04-12 | Rohm And Haas Company | Processing aids and polymer formulations containing the same and method for producing the same |
| JP5346192B2 (ja) * | 2007-10-05 | 2013-11-20 | ローム アンド ハース カンパニー | 改善されたポリマー組成物 |
-
2011
- 2011-12-28 CN CN201610429361.7A patent/CN105968265B/zh active Active
- 2011-12-28 EP EP11811281.2A patent/EP2797961B1/en active Active
- 2011-12-28 JP JP2014550254A patent/JP6329908B2/ja active Active
- 2011-12-28 IN IN4779CHN2014 patent/IN2014CN04779A/en unknown
- 2011-12-28 CN CN201180075715.8A patent/CN104011082B/zh active Active
- 2011-12-28 KR KR1020147017292A patent/KR101838344B1/ko active Active
- 2011-12-28 WO PCT/US2011/067655 patent/WO2013100997A1/en not_active Ceased
- 2011-12-28 US US14/366,749 patent/US9908958B2/en active Active
- 2011-12-28 BR BR112014015830-4A patent/BR112014015830B1/pt not_active IP Right Cessation
- 2011-12-28 KR KR1020187005926A patent/KR101890098B1/ko active Active
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