JP2015215957A - Fuel cell - Google Patents

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JP2015215957A
JP2015215957A JP2014096522A JP2014096522A JP2015215957A JP 2015215957 A JP2015215957 A JP 2015215957A JP 2014096522 A JP2014096522 A JP 2014096522A JP 2014096522 A JP2014096522 A JP 2014096522A JP 2015215957 A JP2015215957 A JP 2015215957A
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gas diffusion
electrode assembly
diffusion layer
membrane electrode
outer peripheral
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JP6287556B2 (en
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川角 明人
Akito Kawakado
明人 川角
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Toyota Motor Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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Abstract

PROBLEM TO BE SOLVED: To provide a technique capable of arranging an adhesive in a prescribed position of an outer periphery of a membrane electrode assembly in just proportion.SOLUTION: A fuel cell 100 comprises a membrane electrode assembly 20, a first gas diffusion layer 31 and a second gas diffusion layer 32, a frame-like member 40, an adhesion part 50, and a separator 60. The membrane electrode assembly 20 includes an extension region ER extending to the outside of the first gas diffusion layer 31. The frame-like member 40 is arranged on the extension region ER, and includes an inner peripheral part 42 which is an adhesion site in contact with the adhesion part 50. The adhesion part 50 covers the region between an outer peripheral end of the first gas diffusion layer 31 and the inner peripheral part 42 of the frame-like member 40, and includes an elevation 51 locally raised more than a surface of the first gas diffusion layer 31. The separator 60 includes a passage groove 61 formed so as to be able to accommodate the elevation 51.

Description

本発明は、燃料電池に関する。   The present invention relates to a fuel cell.

固体高分子形燃料電池(以下、単に「燃料電池」とも呼ぶ。)は、電解質膜の両面に電極が配置された膜電極接合体を備える。膜電極接合体は、セパレータと呼ばれる2枚の板状部材に挟まれて発電体(以下、「単セル」とも呼ぶ)を構成する。一般に、単セルにおいては、膜電極接合体の外周に、膜電極接合体を保持するとともにその発電領域をシールするための部材や、ガス流路を構成するための部材が配置される(特許文献1−5等)。これらの部材は接着剤によって構成される場合や、接着剤を介して膜電極接合体に接着される場合がある(特許文献2−5)。   A polymer electrolyte fuel cell (hereinafter also simply referred to as “fuel cell”) includes a membrane electrode assembly in which electrodes are arranged on both surfaces of an electrolyte membrane. The membrane electrode assembly is sandwiched between two plate-like members called separators to constitute a power generator (hereinafter also referred to as “single cell”). In general, in a single cell, a member for holding a membrane electrode assembly and sealing its power generation region and a member for constituting a gas flow path are arranged on the outer periphery of the membrane electrode assembly (Patent Document). 1-5 etc.). These members may be composed of an adhesive or may be adhered to the membrane electrode assembly through the adhesive (Patent Documents 2-5).

特開2013−89517号公報JP 2013-89517 A 特開2007−087763号公報JP 2007-087763 A 特開2005−216802号公報JP 2005-216802 A 特開2006−156176号公報JP 2006-156176 A 特開平11−312528号公報JP 11-31528 A

燃料電池は、通常、複数の単セルが積層されて締結されるスタック構造を有し、燃料電池の各単セルでは、膜電極接合体が常に面圧を受け、応力が生じている状態で保持されている。特許文献2−5のように、膜電極接合体の外周に接着剤が配置される場合には、製造誤差に起因して所定の部位以外に余分な接着剤が固着し、固着した接着剤によって膜電極接合体に生じる応力が大きくなってしまう可能性があった。また、膜電極接合体の外周に配置されるべき接着剤が不足してしまうと、電解質膜の端部の保護性や発電領域の気密性が低下してしまうなどの不具合が生じる可能性があった。このように、燃料電池においては、膜電極接合体の外周に接着剤を過不足なく所定の位置に配置することについて依然として改良の余地がある。この他にも、燃料電池においては、その小型化や、低コスト化、省資源化、製造の容易化、生産効率の向上等が望まれている。   A fuel cell usually has a stack structure in which a plurality of single cells are stacked and fastened. In each single cell of the fuel cell, the membrane electrode assembly is always subjected to a surface pressure and is held in a stressed state. Has been. When the adhesive is disposed on the outer periphery of the membrane electrode assembly as in Patent Document 2-5, an extra adhesive is fixed to a part other than a predetermined part due to a manufacturing error, and the adhesive is fixed. There is a possibility that the stress generated in the membrane electrode assembly is increased. In addition, if the adhesive to be disposed on the outer periphery of the membrane electrode assembly is insufficient, there is a possibility that problems such as a decrease in the protection of the end of the electrolyte membrane and the airtightness of the power generation region may occur. It was. As described above, in the fuel cell, there is still room for improvement with respect to arranging the adhesive at a predetermined position on the outer periphery of the membrane electrode assembly without excess or deficiency. In addition, in the fuel cell, it is desired to reduce the size, reduce the cost, save resources, facilitate the production, improve the production efficiency, and the like.

本発明は、上述の課題の少なくとも一部を解決するためになされたものであり、以下の形態として実現することが可能である。   SUMMARY An advantage of some aspects of the invention is to solve at least a part of the problems described above, and the invention can be implemented as the following forms.

[1]本発明の一形態によれば、燃料電池が提供される。この燃料電池は、膜電極接合体と、ガス拡散層と、外周部材と、接着部と、セパレータと、を備えて良い。前記膜電極接合体は、電解質膜の両面に電極が配置されている構成を有して良い。前記ガス拡散層は、前記膜電極接合体の少なくとも一方の電極の上に配置されて良い。前記外周部材は、前記膜電極接合体の外周縁部に配置されて良い。前記接着部は、前記外周部材と前記膜電極接合体の外周縁部とを接着する接着部材が配置されて良い。前記セパレータは、前記ガス拡散層と対向するように配置されて良い。前記膜電極接合体の外周縁部は、前記ガス拡散層の外周輪郭線が前記膜電極接合体の前記電解質膜の外周輪郭線よりも内側に位置していることによって、前記ガス拡散層の外側に延出している延出領域を有して良い。前記外周部材は、前記延出領域の上に配置され、前記接着部を介して前記延出領域と接着されていて良い。前記接着部は、前記ガス拡散層の外周端と前記外周部材の前記接着部位との間の領域を被覆するとともに、前記ガス拡散層の外周縁において前記ガス拡散層の表面よりも前記接着部材が局所的に盛り上がっている隆起部を有するように、前記膜電極接合体が前記セパレータに挟まれる前に形成されていて良い。前記セパレータは、前記ガス拡散層と対向する面に、前記隆起部を収容可能に形成されている凹部を有して良い。この形態の燃料電池によれば、接着部に隆起部が形成されるように接着部材が露出領域に不足なく配置される。また、隆起部はセパレータに予め形成されている凹部に収容されるため、隆起部に起因して膜電極接合体に応力が生じることが抑制される。 [1] According to one aspect of the present invention, a fuel cell is provided. The fuel cell may include a membrane electrode assembly, a gas diffusion layer, an outer peripheral member, an adhesive portion, and a separator. The membrane electrode assembly may have a configuration in which electrodes are arranged on both surfaces of the electrolyte membrane. The gas diffusion layer may be disposed on at least one electrode of the membrane electrode assembly. The outer peripheral member may be disposed on an outer peripheral edge portion of the membrane electrode assembly. The adhesive member may be provided with an adhesive member that adheres the outer peripheral member and the outer peripheral edge of the membrane electrode assembly. The separator may be disposed so as to face the gas diffusion layer. The outer peripheral edge of the membrane electrode assembly is located on the outer side of the gas diffusion layer because the outer peripheral contour of the gas diffusion layer is located inside the outer peripheral contour of the electrolyte membrane of the membrane electrode assembly. It may have an extended region extending to the surface. The outer peripheral member may be disposed on the extension region and bonded to the extension region via the bonding portion. The adhesive portion covers a region between an outer peripheral end of the gas diffusion layer and the adhesion portion of the outer peripheral member, and the adhesive member is located on the outer peripheral edge of the gas diffusion layer rather than the surface of the gas diffusion layer. The membrane electrode assembly may be formed before being sandwiched between the separators so as to have locally raised bulges. The separator may have a recess formed on the surface facing the gas diffusion layer so as to accommodate the raised portion. According to the fuel cell of this aspect, the adhesive member is disposed in the exposed region without a shortage so that the raised portion is formed in the adhesive portion. Moreover, since the raised portion is accommodated in a recess formed in advance in the separator, it is possible to suppress the stress from being generated in the membrane electrode assembly due to the raised portion.

上述した本発明の各形態の有する複数の構成要素はすべてが必須のものではなく、上述の課題の一部又は全部を解決するため、あるいは、本明細書に記載された効果の一部又は全部を達成するために、適宜、前記複数の構成要素の一部の構成要素について、その変更、削除、新たな他の構成要素との差し替え、限定内容の一部削除を行うことが可能である。また、上述の課題の一部又は全部を解決するため、あるいは、本明細書に記載された効果の一部又は全部を達成するために、上述した本発明の一形態に含まれる技術的特徴の一部又は全部を上述した本発明の他の形態に含まれる技術的特徴の一部又は全部と組み合わせて、本発明の独立した一形態とすることも可能である。   A plurality of constituent elements of each aspect of the present invention described above are not indispensable, and some or all of the effects described in the present specification are to be solved to solve part or all of the above-described problems. In order to achieve the above, it is possible to appropriately change, delete, replace with another new component, and partially delete the limited contents of some of the plurality of components. In order to solve part or all of the above-described problems or to achieve part or all of the effects described in this specification, technical features included in one embodiment of the present invention described above. A part or all of the technical features included in the other aspects of the present invention described above may be combined to form an independent form of the present invention.

本発明は、燃料電池以外の種々の形態で実現することも可能である。例えば、燃料電池の製造方法やその製造方法の工程において用いられる器具や装置等の形態で実現することができる。   The present invention can also be realized in various forms other than the fuel cell. For example, it can be realized in the form of a manufacturing method of a fuel cell or an instrument or device used in the steps of the manufacturing method.

燃料電池の構成を示す概略図。Schematic which shows the structure of a fuel cell. 単セルの製造工程(第1工程から第3工程)を示す概略図。Schematic which shows the manufacturing process (1st process-3rd process) of a single cell. 単セルの製造工程(第4工程)を示す概略図。Schematic which shows the manufacturing process (4th process) of a single cell. 単セルの製造工程(第5工程)を示す概略図。Schematic which shows the manufacturing process (5th process) of a single cell. 単セルの製造工程(第6工程)を示す概略図。Schematic which shows the manufacturing process (6th process) of a single cell.

A.実施形態:
図1は、本発明の一実施形態としての燃料電池100の構成を示す概略図である。燃料電池100は固体高分子形燃料電池である。燃料電池100は、複数の単セル10が積層されているスタック構造を有している。単セル10は、それぞれが単体で発電可能な構成を有する発電体である。燃料電池100では、各単セル10は締結部材(図示は省略)によって積層方向に締結されている。
A. Embodiment:
FIG. 1 is a schematic diagram showing the configuration of a fuel cell 100 as an embodiment of the present invention. The fuel cell 100 is a polymer electrolyte fuel cell. The fuel cell 100 has a stack structure in which a plurality of single cells 10 are stacked. The single cell 10 is a power generator having a configuration capable of generating power independently. In the fuel cell 100, each single cell 10 is fastened in the stacking direction by a fastening member (not shown).

各単セル10は、膜電極接合体20と、第1と第2のガス拡散層31,32と、枠状部材40と、接着部50と、2枚のセパレータ60と、を備える。膜電極接合体20は、電解質膜21と、第1と第2の電極22,23と、を備える。電解質膜21は、湿潤状態で良好なプロトン伝導性を示すイオン交換樹脂(例えば、パーフルオロスルホン酸系ポリマー)の薄膜によって構成される。   Each single cell 10 includes a membrane electrode assembly 20, first and second gas diffusion layers 31 and 32, a frame-shaped member 40, an adhesive portion 50, and two separators 60. The membrane electrode assembly 20 includes an electrolyte membrane 21 and first and second electrodes 22 and 23. The electrolyte membrane 21 is composed of a thin film of an ion exchange resin (for example, perfluorosulfonic acid polymer) that exhibits good proton conductivity in a wet state.

第1と第2の電極22,23はそれぞれ電解質膜21の対応する面に配置されている。各電極22は、触媒が担持された導電性粒子によってガス拡散性および導電性を有する薄膜層として構成されている。本実施形態では、各電極22,23は、白金担持カーボンの分散溶液である触媒インクの乾燥塗膜として形成される。本実施形態の燃料電池100では、第1の電極22はカソードとして機能し、第2の電極23はアノードとして機能する。   The first and second electrodes 22 and 23 are respectively disposed on the corresponding surfaces of the electrolyte membrane 21. Each electrode 22 is configured as a thin film layer having gas diffusibility and conductivity by conductive particles carrying a catalyst. In the present embodiment, each of the electrodes 22 and 23 is formed as a dry coating film of catalyst ink that is a dispersion solution of platinum-supporting carbon. In the fuel cell 100 of the present embodiment, the first electrode 22 functions as a cathode, and the second electrode 23 functions as an anode.

第1のガス拡散層31は膜電極接合体20の第1の電極22の上に積層配置され、第2のガス拡散層32は膜電極接合体20の第2の電極23の上に積層配置されている。第1と第2のガス拡散層31,32はそれぞれ、ガス拡散性および導電性を有する基材(例えば、カーボン繊維)によって構成される。   The first gas diffusion layer 31 is stacked on the first electrode 22 of the membrane electrode assembly 20, and the second gas diffusion layer 32 is stacked on the second electrode 23 of the membrane electrode assembly 20. Has been. The first and second gas diffusion layers 31 and 32 are each composed of a base material (for example, carbon fiber) having gas diffusibility and conductivity.

本実施形態では、第1のガス拡散層31は電解質膜21よりも小さいサイズで構成されており、その外周輪郭線の全体が電解質膜21の外周輪郭線(膜電極接合体20の外周輪郭線)の内周側に位置するように膜電極接合体20の上に配置されている。これによって、膜電極接合体20の第1の電極22側の面には、第1のガス拡散層31の外周端から延出し、ガス拡散層31を囲む枠状の領域である延出領域ERが形成されている。延出領域ERによって、第1と第2のガス拡散層31,32の端部同士の間の距離が確保され、両者の間で未反応の反応ガスが行き来してしまう、いわゆるクロスリークが発生が抑制される。   In this embodiment, the 1st gas diffusion layer 31 is comprised by the size smaller than the electrolyte membrane 21, and the whole outer periphery outline is the outer periphery outline of the electrolyte membrane 21 (the outer periphery outline of the membrane electrode assembly 20). ) Is disposed on the membrane electrode assembly 20 so as to be located on the inner peripheral side. As a result, the surface of the membrane electrode assembly 20 on the first electrode 22 side extends from the outer peripheral end of the first gas diffusion layer 31 and is an extended region ER that is a frame-shaped region surrounding the gas diffusion layer 31. Is formed. The extension region ER secures a distance between the end portions of the first and second gas diffusion layers 31 and 32, and a so-called cross leak occurs in which unreacted reaction gas flows back and forth between the two. Is suppressed.

枠状部材40は、外周部材に相当し、膜電極接合体20の外周縁を囲むように配置される。枠状部材40は、単セル10において膜電極接合体20を支持する支持部として機能と、単セル10からの流体の漏洩を抑制するシール部としての機能とを有している。本実施形態では、枠状部材40は、例えば、ポリプロピレン(PP)やポリエチレン(PE)などの樹脂部材によって構成されている。   The frame-shaped member 40 corresponds to an outer peripheral member, and is disposed so as to surround the outer peripheral edge of the membrane electrode assembly 20. The frame-shaped member 40 has a function as a support part that supports the membrane electrode assembly 20 in the single cell 10 and a function as a seal part that suppresses leakage of fluid from the single cell 10. In this embodiment, the frame-shaped member 40 is comprised by resin members, such as a polypropylene (PP) and polyethylene (PE), for example.

枠状部材40は、厚みが異なる外周部41と内周部42とを有している。外周部41は、膜電極接合体20の外周端より外側に位置している部位であり、膜電極接合体20の厚みと第1と第2のガス拡散層31,32の厚みの合計以上の厚みを有している。内周部42は、膜電極接合体20の外周端より内側に位置しているシート状の部位であり、第1のガス拡散層31の厚み以下の厚みを有している。内周部42は接着部位に相当し、膜電極接合体20の延出領域ERに含まれる外周縁部の上に配置され、接着部50によって接着されている。   The frame-shaped member 40 has an outer peripheral portion 41 and an inner peripheral portion 42 having different thicknesses. The outer peripheral portion 41 is a portion located outside the outer peripheral end of the membrane electrode assembly 20 and is equal to or greater than the sum of the thickness of the membrane electrode assembly 20 and the thickness of the first and second gas diffusion layers 31 and 32. It has a thickness. The inner peripheral portion 42 is a sheet-like portion located inside the outer peripheral end of the membrane electrode assembly 20 and has a thickness equal to or smaller than the thickness of the first gas diffusion layer 31. The inner peripheral portion 42 corresponds to an adhesion site, is disposed on the outer peripheral edge portion included in the extension region ER of the membrane electrode assembly 20, and is bonded by the bonding portion 50.

接着部50は、接着部材によって構成されている部位であり、膜電極接合体20と枠状部材40とを接着する。接着部50は、膜電極接合体20の延出領域ER全体を被覆するように形成されている。これによって、第1のガス拡散層31に被覆されていない延出領域ERにおいて電解質膜21が折れ曲がったり損傷してしまうことが抑制される。接着部50は、第1のガス拡散層31の表面よりも局所的に盛り上がっている隆起部51を有するように形成されている。本実施形態の燃料電池100において接着部50が隆起部51を有する理由については後述する。   The bonding part 50 is a part constituted by an bonding member, and bonds the membrane electrode assembly 20 and the frame-shaped member 40 together. The adhesion part 50 is formed so as to cover the entire extension region ER of the membrane electrode assembly 20. This suppresses the electrolyte membrane 21 from being bent or damaged in the extended region ER that is not covered with the first gas diffusion layer 31. The bonding portion 50 is formed to have a raised portion 51 that is locally raised above the surface of the first gas diffusion layer 31. The reason why the adhesive portion 50 has the raised portion 51 in the fuel cell 100 of the present embodiment will be described later.

2枚のセパレータ60は、膜電極接合体20を挟むように配置される導電性を有する板状の部材である。2枚のセパレータ60は、枠状部材40を厚み方向に狭持し、第1のガス拡散層31または第2のガス拡散層32と面接触する。各セパレータ60の内側の面(膜電極接合体20と向かい合う側の面)には、発電領域に反応ガスを供給するための、または、発電領域から排ガスを排出するための流路溝61が形成されている。流路溝61は凹部に相当し、接着部50の隆起部51を収容している。   The two separators 60 are conductive plate-like members arranged so as to sandwich the membrane electrode assembly 20. The two separators 60 sandwich the frame-shaped member 40 in the thickness direction, and are in surface contact with the first gas diffusion layer 31 or the second gas diffusion layer 32. On the inner surface of each separator 60 (the surface facing the membrane electrode assembly 20), a flow channel 61 for supplying a reaction gas to the power generation region or discharging exhaust gas from the power generation region is formed. Has been. The channel groove 61 corresponds to a recess and accommodates the raised portion 51 of the bonding portion 50.

後述するように、本実施形態の接着部50は、セパレータ60が第1のガス拡散層31の上に配置される前に硬化が完了している。従って、完成後の燃料電池100において接着部50がセパレータ60の配置前に形成されている場合には、隆起部51はセパレータ60の流路溝61の内壁面に接着していない状態となる。つまり、隆起部51の接着状態によって、接着部50の形成がセパレータ60の配置前であるか否かを判別することができる。   As will be described later, the adhesive portion 50 of this embodiment has been cured before the separator 60 is disposed on the first gas diffusion layer 31. Therefore, when the bonded portion 50 is formed before the separator 60 is arranged in the completed fuel cell 100, the raised portion 51 is not bonded to the inner wall surface of the flow channel groove 61 of the separator 60. That is, it is possible to determine whether or not the formation of the adhesive portion 50 is before the separator 60 is arranged based on the adhesion state of the raised portion 51.

単セル10の外周縁部には、マニホールド孔70が2枚のセパレータ60と枠状部材40とを貫通する貫通孔として形成されている。マニホールド孔70は、単セル10が燃料電池100に組み付けられたときに各単セル10に反応ガスを流通させるためのマニホールドを構成する。単セル10には、マニホールド孔70とセパレータ60の流路溝61とを連通する反応ガスのための連通路が形成されている(図示および詳細な説明は省略)。   A manifold hole 70 is formed in the outer peripheral edge of the single cell 10 as a through hole that penetrates the two separators 60 and the frame member 40. The manifold hole 70 constitutes a manifold for allowing the reaction gas to flow through each unit cell 10 when the unit cell 10 is assembled to the fuel cell 100. The single cell 10 is formed with a communication path for a reactive gas that communicates the manifold hole 70 and the flow channel 61 of the separator 60 (illustration and detailed description are omitted).

このように、本実施形態の燃料電池100では、膜電極接合体20と枠状部材40とが接着部50によって接着されている。接着部50は、発電領域をシールする機能を有するとともに膜電極接合体20の延出領域ERを保護する機能を有している。本実施形態の燃料電池100では、以下に説明するように、単セル10の製造工程において、接着部50が隆起部51を有するように形成されていることによって、接着部50による延出領域ERの保護性が高められている。   Thus, in the fuel cell 100 of the present embodiment, the membrane electrode assembly 20 and the frame member 40 are bonded by the bonding portion 50. The bonding portion 50 has a function of sealing the power generation region and a function of protecting the extension region ER of the membrane electrode assembly 20. In the fuel cell 100 of the present embodiment, as will be described below, in the manufacturing process of the single cell 10, the bonding portion 50 is formed to have the raised portion 51, so that the extension region ER by the bonding portion 50 is formed. The protection of is improved.

図2〜図5を参照図として、単セル10の製造工程を工程順に説明する。図2,図4,図5は図1と同様な概略断面図によって図示されており、図3は膜電極接合体20の第1のガス拡散層31が配置されている側の面に対して垂直な方向から見たときの正面図によって図示されている。   The manufacturing process of the single cell 10 will be described in the order of steps with reference to FIGS. 2, 4, and 5 are illustrated by a schematic cross-sectional view similar to FIG. 1, and FIG. 3 illustrates the surface of the membrane electrode assembly 20 on the side where the first gas diffusion layer 31 is disposed. It is illustrated by a front view when viewed from a vertical direction.

第1工程では、第1と第2のガス拡散層31,32が第1と第2の電極22,23の上に配置されている膜電極接合体20が準備される(図2の上段)。第2工程では、膜電極接合体20の延出領域ERに、後述する隆起部51が形成されるくらいの余剰分を考慮した十分な量の硬化前の流動性を有する接着部材52が塗布される(図2の中段)。   In the first step, a membrane electrode assembly 20 in which the first and second gas diffusion layers 31 and 32 are disposed on the first and second electrodes 22 and 23 is prepared (upper part of FIG. 2). . In the second step, a sufficient amount of the adhesive member 52 having fluidity before curing is applied to the extension region ER of the membrane electrode assembly 20 in consideration of the surplus enough to form a raised portion 51 described later. (Middle of FIG. 2).

第3工程では、膜電極接合体20の外周に枠状部材40が配置される(図2の下段)。具体的には、膜電極接合体20の接着部材52が塗布されている領域上に枠状部材40の内周部42が配置され、外周部41が膜電極接合体20の外周端部と接触するように、枠状部材40が第1のガス拡散層31側から膜電極接合体20に取り付けられる。なお、この段階では、接着部材52の流動によるはみ出しを抑制するために、枠状部材40は膜電極接合体20に完全に嵌まり込むようには押圧されない。   In the third step, the frame-shaped member 40 is disposed on the outer periphery of the membrane electrode assembly 20 (lower stage in FIG. 2). Specifically, the inner peripheral portion 42 of the frame-like member 40 is disposed on the region where the adhesive member 52 of the membrane electrode assembly 20 is applied, and the outer peripheral portion 41 contacts the outer peripheral end of the membrane electrode assembly 20. As described above, the frame member 40 is attached to the membrane electrode assembly 20 from the first gas diffusion layer 31 side. At this stage, the frame-like member 40 is not pressed so as to be completely fitted into the membrane electrode assembly 20 in order to suppress the protrusion due to the flow of the adhesive member 52.

第4工程(図3)では、接着部材52の流動を制御するための治具である接着部材制御板200が枠状部材40および接着部材52の塗布領域の上に積層配置される。接着部材制御板200は、第1の制御板201と第2の制御板202の組み合わせによって構成されている。本実施形態では、第1の制御板201と第2の制御板202とはそれぞれ、同じ厚みを有するとともに板面の形状がほぼ同一の板状部材によって構成されている。   In the fourth step (FIG. 3), the adhesive member control plate 200, which is a jig for controlling the flow of the adhesive member 52, is stacked on the frame-shaped member 40 and the application region of the adhesive member 52. The adhesive member control plate 200 is configured by a combination of a first control plate 201 and a second control plate 202. In the present embodiment, each of the first control plate 201 and the second control plate 202 is configured by a plate-like member having the same thickness and substantially the same plate surface shape.

第1と第2の制御板202の板面はそれぞれ略L字形状を有しており、長さが異なる第1の長方形部位203と第2の長方形部位204とが端部同士で互いに直交するように連結されている。第1の長方形部位203の長さは第2の長方形部位204の長さよりも短い。第1と第2の制御板202はそれぞれ、第1のガス拡散層31の外周を囲むように組み合わされて配置される。具体的には以下の通りである。   The plate surfaces of the first and second control plates 202 each have a substantially L shape, and the first rectangular portion 203 and the second rectangular portion 204 having different lengths are orthogonal to each other at the ends. So that they are connected. The length of the first rectangular portion 203 is shorter than the length of the second rectangular portion 204. The first and second control plates 202 are arranged in combination so as to surround the outer periphery of the first gas diffusion layer 31. Specifically, it is as follows.

本実施形態では、膜電極接合体20と第1のガス拡散層31とは略長方形形状を有しており、それぞれの長辺おいよび短辺に沿った方向が一致するように組み合わされている。第1と第2の制御板201,202のそれぞれは、第1の長方形部位203が第1のガス拡散層31の対向する2つの短辺のそれぞれに隣接するように配置される。また、第2の長方形部位204は第1のガス拡散層31の対向する2つの長辺のそれぞれに隣接するように配置される。すなわち、第1と第2の制御板201,202は、それぞれのL字の内角が第1のガス拡散層31の対角する角部に勘合されるように、互いに対角する位置に配置される。   In the present embodiment, the membrane electrode assembly 20 and the first gas diffusion layer 31 have a substantially rectangular shape, and are combined so that the directions along the long side and the short side thereof coincide with each other. . Each of the first and second control plates 201 and 202 is disposed such that the first rectangular portion 203 is adjacent to each of the two opposing short sides of the first gas diffusion layer 31. Further, the second rectangular portion 204 is disposed adjacent to each of the two opposing long sides of the first gas diffusion layer 31. That is, the first and second control plates 201 and 202 are arranged at positions that are opposite to each other so that the inner angles of the respective L shapes are fitted to the opposite corners of the first gas diffusion layer 31. The

ここで、第1のガス拡散層31の短辺の長さをLaとし、第1の長方形部位203における第1のガス拡散層31の短辺と対向する辺の長さをLbとする。本実施形態では、La>Lbである。これによって、上述のように第1と第2の制御板201,202を配置した場合には、第1の制御板201と第2の制御板202との間にはそれぞれ間隙GPが生じる。この間隙GPは接着部材52の逃げ部として機能する(後述)。なお、間隙GPが形成される位置は、セパレータ60の流路溝61が配置される位置に対応するように予め規定されている。   Here, the length of the short side of the first gas diffusion layer 31 is La, and the length of the side of the first rectangular portion 203 facing the short side of the first gas diffusion layer 31 is Lb. In the present embodiment, La> Lb. Accordingly, when the first and second control plates 201 and 202 are arranged as described above, gaps GP are generated between the first control plate 201 and the second control plate 202, respectively. The gap GP functions as an escape portion for the adhesive member 52 (described later). Note that the position where the gap GP is formed is defined in advance so as to correspond to the position where the flow channel 61 of the separator 60 is disposed.

ところで、第1のガス拡散層31の長辺または短辺のサイズには寸法誤差が生じる場合がある。本実施形態の接着部材制御板200であれば、第1のガス拡散層31の寸法誤差は間隙GPの間隔に吸収されて調整される。そのため、そうした寸法誤差が生じている場合であっても、第1と第2の制御板201,202の内角側の辺を第1のガス拡散層31の外周辺に隣接させて配置することが可能である。   Incidentally, there may be a dimensional error in the size of the long side or the short side of the first gas diffusion layer 31. In the case of the adhesive member control plate 200 of the present embodiment, the dimensional error of the first gas diffusion layer 31 is absorbed and adjusted by the gap GP. Therefore, even when such a dimensional error occurs, the inner corner sides of the first and second control plates 201 and 202 can be arranged adjacent to the outer periphery of the first gas diffusion layer 31. Is possible.

第5工程(図4)では、接着部材制御板200の第1と第2の制御板201,202を厚み方向に押圧して、膜電極接合体20の外周部への枠状部材40の嵌め込みを完了させる。この工程によって、延出領域ER上に塗布されている接着部材52は、枠状部材40と接着部材制御板200とに押圧されて、延出領域ERの全体に行き渡るように流動する。   In the fifth step (FIG. 4), the first and second control plates 201 and 202 of the adhesive member control plate 200 are pressed in the thickness direction, and the frame-shaped member 40 is fitted into the outer peripheral portion of the membrane electrode assembly 20. To complete. By this step, the adhesive member 52 applied on the extended region ER is pressed by the frame-like member 40 and the adhesive member control plate 200 and flows so as to reach the entire extended region ER.

図4の下段には、図4に示された矢印Pの方向に見たときの第1と第2の制御板201,202の間隙GPの様子が模式的図示されている。延出領域ERに塗布されている接着部材52の一部の余剰分は、枠状部材40と接着部材制御板200との押圧によって図3で説明した第1と第2の制御板201,202の間の間隙GPへと流動する。これによって、一部の接着部材52が第1のガス拡散層31の表面よりも盛り上がり、接着部50の隆起部51が形成される。   The lower part of FIG. 4 schematically shows the state of the gap GP between the first and second control plates 201 and 202 when viewed in the direction of the arrow P shown in FIG. The surplus part of the adhesive member 52 applied to the extension region ER is the first and second control plates 201 and 202 described with reference to FIG. 3 by pressing between the frame-shaped member 40 and the adhesive member control plate 200. Flows into the gap GP between. As a result, a part of the adhesive member 52 rises from the surface of the first gas diffusion layer 31, and the raised portion 51 of the adhesive portion 50 is formed.

ここで、図3で説明したように、本実施形態の接着部材制御板200は、第1のガス拡散層31に寸法誤差が生じている場合であっても、間隙GP以外の部位では、第1のガス拡散層31との間に隙間が生じないように配置可能である。そのため、本実施形態の接着部材制御板200によれば、間隙GPの形成部位以外において、接着部材52が第1のガス拡散層31の上などにはみ出して固着してしまうことが抑制される。   Here, as described with reference to FIG. 3, the adhesive member control plate 200 according to the present embodiment has the first gas diffusion layer 31 in a region other than the gap GP even when a dimensional error has occurred. The gas diffusion layers 31 can be arranged so that no gap is generated between them. Therefore, according to the adhesive member control plate 200 of the present embodiment, it is possible to prevent the adhesive member 52 from sticking out of the first gas diffusion layer 31 or the like other than the portion where the gap GP is formed.

接着部材52が硬化された後に、接着部材制御板200は取り外される。なお、接着部材52からの剥離を容易にするために、接着部材制御板200は、表面が接着部材52に対して離型性を有する材料で構成されていることが望ましい。具体的に、接着部材制御板200は、離型シートによって構成されても良いし、表面がテフロン加工(「テフロン」は登録商標)された板状部材によって構成されても良い。   After the adhesive member 52 is cured, the adhesive member control plate 200 is removed. In order to facilitate peeling from the adhesive member 52, it is desirable that the adhesive member control plate 200 be made of a material whose surface has releasability from the adhesive member 52. Specifically, the adhesive member control plate 200 may be constituted by a release sheet, or may be constituted by a plate-like member whose surface is Teflon-processed (“Teflon” is a registered trademark).

第6工程(図5)では、膜電極接合体20の両面にそれぞれセパレータ60が一枚ずつ配置される。各セパレータ60は枠状部材40に接着されても良い。各セパレータ60の第1または第2のガス拡散層31,32と対向する側の面には流路溝61が予め形成されている。接着部50に形成されている隆起部51は、セパレータ60の流路溝61に収容される。この工程の後、枠状部材40が配置されている外周縁部の打ち抜きによって、マニホールド孔70(図1)が形成され、単セル10が完成する。   In the sixth step (FIG. 5), one separator 60 is disposed on each side of the membrane electrode assembly 20. Each separator 60 may be bonded to the frame member 40. A channel groove 61 is formed in advance on the surface of each separator 60 facing the first or second gas diffusion layer 31, 32. The raised portion 51 formed in the bonding portion 50 is accommodated in the flow channel 61 of the separator 60. After this step, the manifold hole 70 (FIG. 1) is formed by punching the outer peripheral edge where the frame-shaped member 40 is disposed, and the single cell 10 is completed.

以上のように、本実施形態の燃料電池100によれば、その製造工程において、接着部50を形成する際に隆起部51が形成されるくらいの余剰分を考慮した十分な量の接着部材52が塗布される。また、接着部材制御板200によって、接着部材52が余計な部位への付着が抑制された状態で延出領域ERの全体に行き渡らされる。従って、接着部50による膜電極接合体20の保護性や発電領域のシール性が高められている。   As described above, according to the fuel cell 100 of the present embodiment, a sufficient amount of the adhesive member 52 in consideration of the surplus that the raised portion 51 is formed when the adhesive portion 50 is formed in the manufacturing process. Is applied. In addition, the adhesive member control plate 200 distributes the adhesive member 52 over the entire extension region ER in a state in which the adhesion of the adhesive member 52 to an unnecessary portion is suppressed. Therefore, the protection of the membrane electrode assembly 20 by the adhesive portion 50 and the sealing performance of the power generation region are enhanced.

また、接着部50における隆起部51の形成位置は接着部材制御板200によってセパレータ60の流路溝61が配置される位置に予め規定されている。従って、接着部50に隆起部51が形成されていることに起因して、膜電極接合体20や第1のガス拡散層31に余分な応力が生じてしまうことや、セパレータ60と第1のガス拡散層31との間の密着性が低下してしまうことが抑制されている。   In addition, the formation position of the raised portion 51 in the bonding portion 50 is defined in advance by the bonding member control plate 200 at the position where the flow channel 61 of the separator 60 is disposed. Therefore, extra stress is generated in the membrane electrode assembly 20 and the first gas diffusion layer 31 due to the formation of the raised portion 51 in the adhesive portion 50, or the separator 60 and the first gas It is suppressed that the adhesiveness between the gas diffusion layers 31 falls.

B.変形例:
B1.変形例1:
上記実施形態では、接着部50の隆起部51はセパレータ60に形成されている反応ガスのための流路溝61に収容されている。これに対して、接着部50の隆起部51はセパレータ60に形成されている流路溝61以外の凹部に収容されても良い。例えば、接着部50の隆起部51は、セパレータ60に予め形成されている隆起部51を収容するためのみの凹部に収容されても良い。
B. Variation:
B1. Modification 1:
In the above embodiment, the raised portion 51 of the bonding portion 50 is accommodated in the flow channel 61 for the reactive gas formed in the separator 60. On the other hand, the raised portion 51 of the adhesive portion 50 may be accommodated in a recess other than the flow channel 61 formed in the separator 60. For example, the raised portion 51 of the bonding portion 50 may be accommodated in a recess only for accommodating the raised portion 51 formed in advance on the separator 60.

B2.変形例2:
上記実施形態では、接着部材制御板200は、板面が略L字状の同様な形状を有し、互いに分離している第1と第2の制御板201,202の組み合わせによって構成されている。これに対して、接着部材制御板200は、3枚以上に分離されている複数の異なる板面形状を有する板状部材の組み合わせによって構成されていても良い。接着部材制御板200は、間隙GPを有しつつ第1のガス拡散層31の外周辺に隣接させて配列可能な複数の部材によって構成されていれば良い。なお、間隙GPを形成が形成される位置や個数、間隙GPの間隔は特に限定されることはなく、セパレータ60の流路溝61などの凹部の構成に応じて適宜設定されれば良い。
B2. Modification 2:
In the above embodiment, the adhesive member control plate 200 has a similar shape with a substantially L-shaped plate surface, and is configured by a combination of the first and second control plates 201 and 202 that are separated from each other. . On the other hand, the adhesive member control plate 200 may be configured by a combination of plate-like members having a plurality of different plate surface shapes separated into three or more. The adhesive member control plate 200 may be configured by a plurality of members that can be arranged adjacent to the outer periphery of the first gas diffusion layer 31 while having the gap GP. In addition, the position and number of formation of the gap GP and the interval of the gap GP are not particularly limited, and may be set as appropriate according to the configuration of the recess such as the flow channel 61 of the separator 60.

B3.変形例3:
上記実施形態では、膜電極接合体20の外周には枠状部材40が配置されている。これに対して、膜電極接合体20の外周には枠状部材40以外の外周部材が配置されても良い。例えば、膜電極接合体20の外周には反応ガスの流路を構成するための板状の流路部材が接着部50によって接着されても良い。
B3. Modification 3:
In the above embodiment, the frame-shaped member 40 is disposed on the outer periphery of the membrane electrode assembly 20. On the other hand, an outer peripheral member other than the frame-shaped member 40 may be disposed on the outer periphery of the membrane electrode assembly 20. For example, a plate-like channel member for constituting a reaction gas channel may be bonded to the outer periphery of the membrane electrode assembly 20 by the bonding part 50.

本発明は、上述の実施形態や実施例、変形例に限られるものではなく、その趣旨を逸脱しない範囲において種々の構成で実現することができる。例えば、発明の概要の欄に記載した各形態中の技術的特徴に対応する実施形態、実施例、変形例中の技術的特徴は、上述の課題の一部又は全部を解決するために、あるいは、上述の効果の一部又は全部を達成するために、適宜、差し替えや、組み合わせを行うことが可能である。また、その技術的特徴が本明細書中に必須なものとして説明されていなければ、適宜、削除することが可能である。   The present invention is not limited to the above-described embodiments, examples, and modifications, and can be realized with various configurations without departing from the spirit thereof. For example, the technical features in the embodiments, examples, and modifications corresponding to the technical features in each embodiment described in the summary section of the invention are to solve some or all of the above-described problems, or In order to achieve part or all of the above effects, replacement or combination can be performed as appropriate. Further, if the technical feature is not described as essential in the present specification, it can be deleted as appropriate.

10…単セル
20…膜電極接合体
21…電解質膜
22,23…第1と第2の電極
31,32…第1と第2のガス拡散層
40…枠状部材
41…外周部
42…内周部
50…接着部
51…隆起部
52…接着部材
60…セパレータ
61…流路溝
70…マニホールド孔
200…接着部材制御板
201,202…第1と第2の制御板
203,204…第1と第2の長方形部位
GP…間隙
DESCRIPTION OF SYMBOLS 10 ... Single cell 20 ... Membrane electrode assembly 21 ... Electrolyte membrane 22, 23 ... 1st and 2nd electrode 31, 32 ... 1st and 2nd gas diffusion layer 40 ... Frame-shaped member 41 ... Outer peripheral part 42 ... Inside Peripheral part 50 ... Adhesive part 51 ... Raised part 52 ... Adhesive member 60 ... Separator 61 ... Channel groove 70 ... Manifold hole 200 ... Adhesive member control plates 201 and 202 ... First and second control plates 203 and 204 ... first And second rectangular part GP ... gap

Claims (1)

燃料電池であって、
電解質膜の両面に電極が配置されている膜電極接合体と、
前記膜電極接合体の少なくとも一方の電極の上に配置されているガス拡散層と、
前記膜電極接合体の外周縁部に配置される外周部材と、
前記外周部材と前記膜電極接合体の外周縁部とを接着する接着部材が配置されている接着部と、
前記ガス拡散層と対向するように配置されるセパレータと、
を備え、
前記膜電極接合体の外周縁部は、前記ガス拡散層の外周輪郭線が前記膜電極接合体の前記電解質膜の外周輪郭線よりも内側に位置していることによって、前記ガス拡散層の外側に延出している延出領域を有しており、
前記外周部材は、前記延出領域の上に配置され、前記接着部を介して前記延出領域と接着されており、
前記接着部は、前記ガス拡散層の外周端と前記外周部材の前記接着部位との間の領域を被覆するとともに、前記ガス拡散層の外周縁において前記ガス拡散層の表面よりも前記接着部材が局所的に盛り上がっている隆起部を有するように、前記膜電極接合体が前記セパレータに挟まれる前に形成されており、
前記セパレータは、前記ガス拡散層と対向する面に、前記隆起部を収容可能に形成されている凹部を有している、燃料電池。
A fuel cell,
A membrane electrode assembly in which electrodes are arranged on both surfaces of the electrolyte membrane;
A gas diffusion layer disposed on at least one electrode of the membrane electrode assembly;
An outer peripheral member disposed on an outer peripheral edge of the membrane electrode assembly;
An adhesive portion in which an adhesive member for adhering the outer peripheral member and the outer peripheral edge of the membrane electrode assembly is disposed;
A separator disposed to face the gas diffusion layer;
With
The outer peripheral edge of the membrane electrode assembly is located on the outer side of the gas diffusion layer by the outer peripheral contour of the gas diffusion layer being located inside the outer peripheral contour of the electrolyte membrane of the membrane electrode assembly. Has an extension area extending to
The outer peripheral member is disposed on the extension region, and is bonded to the extension region via the bonding portion,
The adhesive portion covers a region between an outer peripheral end of the gas diffusion layer and the adhesion portion of the outer peripheral member, and the adhesive member is located on the outer peripheral edge of the gas diffusion layer rather than the surface of the gas diffusion layer. Before the membrane electrode assembly is sandwiched between the separators so as to have a locally raised bulge,
The separator has a recess formed in a surface facing the gas diffusion layer so as to accommodate the raised portion.
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