JP2015212218A5 - - Google Patents
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- JP2015212218A5 JP2015212218A5 JP2015093945A JP2015093945A JP2015212218A5 JP 2015212218 A5 JP2015212218 A5 JP 2015212218A5 JP 2015093945 A JP2015093945 A JP 2015093945A JP 2015093945 A JP2015093945 A JP 2015093945A JP 2015212218 A5 JP2015212218 A5 JP 2015212218A5
- Authority
- JP
- Japan
- Prior art keywords
- hydride
- zero
- complex
- valent
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- -1 metalloid hydride Chemical class 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000012448 Lithium borohydride Substances 0.000 claims description 4
- NZTNZPDOBQDOSO-UHFFFAOYSA-N lithium;boron(1-) Chemical compound [Li+].[B-] NZTNZPDOBQDOSO-UHFFFAOYSA-N 0.000 claims description 4
- 229910000619 316 stainless steel Inorganic materials 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims 12
- KLGZELKXQMTEMM-UHFFFAOYSA-N hydride Chemical group [H-] KLGZELKXQMTEMM-UHFFFAOYSA-N 0.000 claims 10
- 239000000203 mixture Substances 0.000 claims 10
- 229910052755 nonmetal Inorganic materials 0.000 claims 9
- 238000009472 formulation Methods 0.000 claims 8
- 229910052752 metalloid Inorganic materials 0.000 claims 8
- BUGBHKTXTAQXES-UHFFFAOYSA-N selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims 6
- 229910052711 selenium Inorganic materials 0.000 claims 6
- 239000011669 selenium Substances 0.000 claims 6
- 150000002843 nonmetals Chemical class 0.000 claims 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 4
- 229910052799 carbon Inorganic materials 0.000 claims 4
- 238000000498 ball milling Methods 0.000 claims 3
- 229910052987 metal hydride Inorganic materials 0.000 claims 3
- 150000004681 metal hydrides Chemical class 0.000 claims 3
- 150000002738 metalloids Chemical class 0.000 claims 3
- 230000003647 oxidation Effects 0.000 claims 3
- 238000007254 oxidation reaction Methods 0.000 claims 3
- 230000002194 synthesizing Effects 0.000 claims 3
- CROBTXVXNQNKKO-UHFFFAOYSA-N borohydride Chemical compound [BH4-] CROBTXVXNQNKKO-UHFFFAOYSA-N 0.000 claims 2
- 239000002131 composite material Substances 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 1
- 239000000843 powder Substances 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
Description
例１
−３２５メッシュ粒径の１部のマンガン金属粉末を、マンガン金属および水素化ホウ素リチウム粉末の質量が合計で１０グラム未満となる１部または２部のＬｉＢＨ４と混ぜ合わせ、１（３／４）インチ、３（１／２）インチおよび５（１／４）インチの３１６ステンレス鋼玉軸受を用いて、２５０ｍＬのステンレス鋼の気密ボールミルジャーにおいて、（Ｆｒｉｔｓｃｈ ｐｕｌｅｒｖｉｓｅｔｔｅ ７のプラネタリボールミルを用いて）４００ｒｐｍで４時間、プラネタリボールミルでボールミル粉砕する。
Example 1
1 part manganese metal powder with -325 mesh particle size is mixed with 1 part or 2 parts LiBH 4 with a total mass of manganese metal and lithium borohydride powder of less than 10 grams, 1 ( 3/4 ) In a 250 mL stainless steel hermetic ball mill jar using an inch, 3 ( 1/2 ) inch and 5 ( 1/4 ) inch 316 stainless steel ball bearings (using a planetary ball mill with a Fritsch pullersetet 7) at 4 rpm Ball mill with planetary ball mill for time.
例２
−３２５メッシュ粒径の１部の錫金属粉末を、錫金属および水素化ホウ素リチウム粉末の質量が合計で１０グラム未満となる１部または２部のＬｉＢＨ４と混ぜ合わせ、１（３／４）インチ、３（１／２）インチおよび５（１／４）インチの３１６ステンレス鋼玉軸受を用いて、２５０ｍＬのステンレス鋼の気密ボールミルジャーにおいて、（Ｆｒｉｔｓｃｈ ｐｕｌｅｒｖｉｓｅｔｔｅ ７のプラネタリボールミルを用いて）４００ｒｐｍで４時間、プラネタリボールミルでボールミル粉砕する。
Example 2
1 part tin metal powder with -325 mesh particle size is mixed with 1 part or 2 parts LiBH 4 with a total mass of tin metal and lithium borohydride powder of less than 10 grams, 1 ( 3/4 ) In a 250 mL stainless steel hermetic ball mill jar using an inch, 3 ( 1/2 ) inch and 5 ( 1/4 ) inch 316 stainless steel ball bearings (using a planetary ball mill with a Fritsch pullersetet 7) at 4 rpm Ball mill with planetary ball mill for time.
Claims (20)
Ｑ０・Ｘｙ
（上記式において、Ｑ０は酸化状態０である０価元素であり、Ｘは、２元素メタロイド水素化物、複合金属水素化物、複合メタロイド水素化物の少なくともいずれか一つを含む水素化物であり、ｙは０よりも大きな整数値または小数値である）
を有する複合体を含む試薬複合体。 The following formula:
Q 0・ Xy
(In the above formula, Q 0 is a zero-valent element in the oxidation state 0, and X is a hydride containing at least one of a two-element metalloid hydride, a complex metal hydride, and a complex metalloid hydride, y is an integer or decimal value greater than 0)
A reagent complex comprising a complex having:
Ｑ０・Ｘｙ
（上記式において、Ｑ０は０価の非金属であり、Ｘは水素化物であり、ｙは０よりも大きな整数値または小数値である）
を有する複合体を含む試薬複合体。 The following formula:
Q 0・ Xy
(In the above formula, Q 0 is a zero-valent non-metal, X is a hydride, and y is an integer or decimal value greater than 0)
A reagent complex comprising a complex having:
２元素メタロイド、複合金属水素化物、複合メタロイド水素化物の少なくともいずれか一つを含む水素化物と、酸化状態０である０価元素を含有する調合物との両方を含む混合物をボールミル粉砕するステップと、
以下の式：
Ｑ０・Ｘｙ
（上記式において、Ｑ０は酸化状態０である０価元素であり、Ｘは、２元素メタロイド水素化物、複合金属水素化物、複合メタロイド水素化物の少なくともいずれか一つを含む水素化物であり、ｙは０よりも大きな整数値または小数値である）
を有する試薬複合体を合成するステップと、を含む、方法。 A method for synthesizing a reagent complex comprising:
Ball milling a mixture containing both a hydride containing at least one of a two-element metalloid, a composite metal hydride, and a composite metalloid hydride, and a preparation containing a zero-valent element in an oxidation state of 0. ,
The following formula:
Q 0・ Xy
(In the above formula, Q 0 is a zero-valent element in the oxidation state 0, and X is a hydride containing at least one of a two-element metalloid hydride, a complex metal hydride, and a complex metalloid hydride, y is an integer or decimal value greater than 0)
Synthesizing a reagent complex having:
水素化物と、０価非金属を含有する調合物との両方を含む混合物をボールミル粉砕するステップを含む、方法。 A method for synthesizing a reagent complex comprising:
Ball milling a mixture comprising both a hydride and a formulation containing a zerovalent non-metal.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/269,909 US9260312B2 (en) | 2013-10-04 | 2014-05-05 | Stable complexes of non-metal elements and hydride as novel reagents |
| US14/269,909 | 2014-05-05 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015212218A JP2015212218A (en) | 2015-11-26 |
| JP2015212218A5 true JP2015212218A5 (en) | 2016-10-06 |
| JP6085331B2 JP6085331B2 (en) | 2017-02-22 |
Family
ID=54696735
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015093945A Active JP6085331B2 (en) | 2014-05-05 | 2015-05-01 | REAGENT COMPLEX AND METHOD FOR SYNTHESIZING REAGENT COMPLEX |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6085331B2 (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5206758B2 (en) * | 2010-07-15 | 2013-06-12 | トヨタ自動車株式会社 | Negative electrode material, metal secondary battery, and negative electrode material manufacturing method |
| JP2013073839A (en) * | 2011-09-28 | 2013-04-22 | Toyota Motor Corp | Negative electrode material, and battery |
| JP2013131366A (en) * | 2011-12-21 | 2013-07-04 | Toyota Motor Corp | Anode active material for metal ion battery |
| US9346676B2 (en) * | 2013-10-04 | 2016-05-24 | Toyota Motor Engineering & Manufacturing North America, Inc. | Stable complexes of zero-valent metallic element and hydride as novel reagents |
-
2015
- 2015-05-01 JP JP2015093945A patent/JP6085331B2/en active Active
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